Document 1QVna16qJY9rOgvk3y57Yw4Do

pty resrin ARYE, O52, Multi Stu-dyCSaimpt linyg Task(N100666) Effective Date: May 14, 1999 Page iofiv. --. 5R-0800-373 Gi wn Me PE Quality Assurance Project Plan EA-=1Y ote pL ) for ~ Empi`rMiucltail-HCiutmy aStnudEyxpSoasmuprleiAnsgsTeassskment 2 = To (Confidential) 2 2 May 14,1999 Prepared by Tn ~~ Battelle 3D97uWxabshuirnMygtA,on0S2t3r3e2et & EPA-OTS AFRREARE (781) 934-0571 000811789 APERa OVALS pl JA -- 54] 2 ~ `Sampling Task Leader Raasgu hall Die 5-18-99 = 3a fosaana BattelleSampling Task QAOfficer . =o 35 g-7 eht ------ pS----=5 = 8 5% . = BattleProjectManager . NU 4. itty 7: 51) we ---- usinADbaY B `Battelle Program QA Offic - J Date :: 000439 Quality AssuranceProject Plan Muli-City Study Sampling Task (100666) . Joseph Fiksel `MSauracniAabNbigsyhioka ``DRoonsaalndnaGuBnusbtler Wayne Talli ScottMacomber Chis Gagaon RKeolbleyrtIrMiaznardreyville RKiicmhaArnddRreeswtsucei Distribution List 2 Revision No.: 1 `Effective Date: MaPya1g4e,i1i9o9fv9 000440 Quality Assurance Project Plan MuliSt-udCySiamptliyng Task (100666) Revision No. | Effective Date: May 14, 1999 ro----------p ------ee set eeetens ECLEi E, ; CONTENTS 1 PROJECT NAME-ecoecomermmmsssemsemeesesemmmeeeemssmssesmmreres| 2. REQUESTED BYcoments 3. DATE OFREQUESTcomereenememereescemseemesessmemereemeeseee1 4. DATEOFINITIATeIoONe.cereeemremremeemseseeeteeeeemremeeoee1 5. PROJECTMANAGEMENT m reese emes1 6. QUALITYASSURANCE (QA) MANAGEMENTcorrrmeemecrememmmemeontrecremmeeeme1 7. 71PROBAJCEKCGTRODUENSDCcRIPeTIOnNw nee emr esoe eeessn os t on : e2 TIL PETRISHONS.erconesreoesomsssmeonrms sessment 1 7733.56 SWeadtiemreSnatmSpalmipnlgincgfroomoMunwicnipael WartersSource nee eoere ecsre enme) rs 10 FE oS ------ SCHEDULEOFMILESTONESAND DELIVERABLES rrr un 9. 9.1ORPRGOATNEICZTPAETRISOONNNAENLDe RESPOv NSTBLe ITIESr crs emeo ren eremmrrmeemmiemr1111 10.TOEQUALAICTCYRAASScUoRrArNmsCeEmmOeBeJsEsmCsTmIeVmEeSomcsoenreeermemeseerneeroeeermerrreeremerermeeeeeeerreeeremeeneeenreemnrommeroene1Js3 11, SAMPLING PROCEDURESeee A 18 --"| 112.1 PUFand FilerPreparatimmmmmemsoseseereeiosemssenrnmsensonnre 11 R 1113130DSR urfacI WeA-TWEaNtReor KCoellI etsionNmosGsmmmeroemoesmereoeerersssnereetneesrsoesseosssoenstosnonroes 290 11113332 WWaatteerrSQaumalpilteySCoHntErnoltS.aemeepwlsessnmsmmnmemeorssssosers esen reee tees nrn: rr 2200 S 1114 41SEDIMSEedNiTmFeRnOtMSaDmRpIlNeKICNOGEWCAHTOERNSOoURCsE v sc rroeo ersr rrere ecernessnnsssnsrsennisns22s00 1042 Sediment QualityCORTolssserseeerere senses 21 11.43 SedimentSAmple SHIPPING.owevrvemsrsrsserssnmmmsmsssensmnmsmmss 24 : 000441 Quality Assurance Project Plan Revision No.: 1 Multi-City Study Sampling Task (N100666) Effective Date: May 14, 1999 - A ---- 1.1 - 115 PUBLICLY-OWNEDTREATMENT WORKS w.covrcrsesssssmmsssssssssssssssmsssssssssssssssssmmsssssssssssssssss 21 111T61I.553L2ANDOFPIOTLTLWLWEaQAUmGApHHlEEeYTCESOHMeEMOe Nscovsersrremrm smssnmmmsssse mssamssssesesrsr sescsesmssesnsmesess rssosrsesmsaomsrsseso mssssssssmasn sssssssi22se28s TT1A1T1112 Se PrrohceiedtMPesrtar ts ero memo --------t --I ------s --r)3 I2LTZ DalryandBgOgArommemm-- meeesmsemes-- messssmmionon28 rg UE " ---- A 11742 Orgyhpmodoccd--Seaeh cseee--e--e--e--e--eTemo--e--e--e--e--r)24 TEBE NEIS Mlb Seo Prem ssion r----------------------I--I--I glil 12. SAMPLECUSTODYcorrec 26 2 13. CALIBRATION PROCEDURES,REFERENCES,ANDFREQUENCY coven 21 132 12KL GLOBALPOSTINGSYSTEM reesommsemreesonesem21 14, ANALYTICAL PROCEDURESerrr emer 3 15. DATA REDUCTION, VALIDAANDTREIPOORTNIN,G weeoemrerreemesemmeree3s 16. 17. IQNUTAELRINTAYLAQSUSAULRIATNYCECOPNTERORLCFHEOCKRASUADMNITDASF,RNSEYQCSUTEEENMCYAUwDoIrTeSer,vAmNrDrmFrrRsrEsmQrrUemEsaNssnCmns2Y2e88s. 18. 19. PQRUEAVLEINTTYIAVSESMUARIANNTCEENRAENPCOERTPSRTOCOEMDAUNRAEGSEAMNEDNSTCwHsoEvrDensULsEmSemsemssessmemssrse22s98 20. CALCULATION OF DATA QUALITY INDICATORScommen29 21. CORRECTIVE ACTION meeeemmrmrremnemrsmssmmsessssessee3s A FC ------------------------ : TABLES S Table 1. FCReSiduals forARBIYSIS.......ccusrssmmmssmssmssmmsmssmsssssmsssssssssssssssssssssssssssssssss3s Table 2. Table3. SStaumdpyleanTdypCeosn,trSoalmCpiltiinesgfDoerviBcaesse,liannedSSIYA.M.P.L..E.V..OvIuUrMwEwmSm.sm.mvssimsvssssvsssmmssssmsssssssssssssssssnmsmsmisnssisess43ss 000442 MQuulaslii-tCyiAtsysSutruadnycSeaPmrpoljienctgPTlaasnk (100666) Revision No.1: Effective Date: MaPyag14e, v19o9f9 Table 4. Sample Types and Numbers at Sampling Locations Within Each City rns Table 7. Table 8. MieSK00ES ad Key Personnel, DAEdHdVreEsTsGeBsI,ESanrdeTecleeprhoonrenNrUrIDrEoTSmerre rerrs ssms ssse ssssr nmse ens 1 13 Table 9. Sample Containers, Storage Conditions, and SIPPINGvse 16 FIGURES : FIGURES-1 PROTECTORGANIZATIONCHARTFORTHEEMPIRICALHUMANEXPOSUREASSESSMENTMULTI FIGURE 11-1, BS-1 SAMPLINGEEAD everestetree 18 Appendix A: `Appendix B: `AppendCix: APPENDICES EMuxlam-pClietys SotfuRdeyqSuuersvtesy fPolranPermissions Sampling Forms 000443 MQduatlii-tCyiAtsysSutruadnycSeaPmrpoljienctgPTlaasnk (N100666) Effective Date:ReMvaisyio1n4,No1.9:991 Page 10/30 1. PROJECT NAME Empirica"l HMuCmiatuynSEaxlmppolstiunrgeATsasskessment 2. REQUESTED BY Confidential `3. DATE OF REQUEST January 1999 4. DATE OF INITIATION i February 15,1999 5. PROJECT MANAGEMENT MrM.s.DoMnaarlcdiaGNuinsstheiro,kBaa,tBtaetltlelelSeaPmrpolginrgamTaMsaknLaegaedrer 6. QUALITY ASSURANCE (QA) MANAGEMENT Ms.RMso.sSaunsnaanBuAhblb,gyB,aBtaetltleelSleamPprloignrgamTaQsAk OOfAfiOcfefricer 000444 QMuialditt-yCiAtsysSutruadnycSeaPmrpoljiencgtPTlaasnk (100666) Effective DatRee:vMiasiyo1n4N,o1.9:919 Page 20/30 - 7. PROJECT DESCRIPTION 71 Background Ildinimtsihctoeevde1r9i5yn0ta'rnso,ddsuuicrntftiarocontd,uaDcnittviseaornsnoidffbincauatmthieaordnodouiftstiNvhe-esmPbeOatSshFey-dlbouarpsoeNn-dcptehhreyfmlliupsoetrrrofyolicutnoyrltoshoueclt1yf9lo6ns0yu'llsffalonundoarmi1id9de7o(0Pe'sOylSe!Fd)atblocetoghbaeoln`ppaacskeadg(inFgO,SEn)dcchaermpiectasltso.iTmhpearFtOsSpEec-ibfaiscepdrfolpeurotrioecshreemliaceadlts(osFtCa)nW,emroeisitnucroer,paonrdatfedtnretsoitsetxatniclee.sA,flotohdough F"soouelmfmeousnuiammtbieelr(a,PsciFhtOeeSsm).i,cANal-llcdftiohvryemlrus(lioatrytN,ia-omnnesdhthraayvnleg)teproeafrcafeplpulloevirecolaostcoitfoannseseosvfuerlFafCloianmrapemuirqdiuetiit(esNse-ixEnteFcuOosSimvAme)o,,an:lanpfdeorrNfm-lueultaohtryioloon(costrsaNhnea-re mmEeeAttFhaybOloS)lAipmseimrdsfetuu(odroioreosNct-saMungcegsFeOstuStAhmlaiadflel)fooirnmndulNaa-atElimctoonFhFOioCSlEsd(auNln-ocdEoeSbcrFogOloS(tEsooarhmlNce-yolhMioelmlFi)tO.eSIdndEaegarldacdohaotdli)otniihtneorhteuPsmFuaOilntSss,ooafNnc-dunirnre,tnhte cavironment,viamicrobialand/orenzymatic mechanisms. `dlRievceerensteocrfvhePgeFimoeOincSsatollhfaentraheslieynUs.neBisetocefdapSuotsoaetleePsdFhOhaSuvimesasunhnboilwqonuoedatsgoaemnFpeCrlsae,lsPcaoFnnOdsSissemtlaeencyctbyeiednadnitsahtlerydisbeeutsteoecdftiiboninotrthaaetsgearamenpadtldeeerstfercotmed SSeutagvbgioerusontnktmnheaontvtinnawcshre2eateshsiuenlrgltteohvfeetPlhesFouOfsSeiPanFnOhdSudiimnsaphnoubslmiotaionodbniolsofdopurdeopdaturoacltFlsCecleoxtnphtoeaisinuntrrieonsdgiuFcnCttsiho.enTrhaeosniuddvgeohnuclenifmeri/otuemds,tethohefeudFsaCetsao.f 5 products,ortotheslowbiosocamulationofFCinthefoodwebduetowidespreaddispersion ofFCs = throughmultiplesources. `Several hypothesesare consideredtounderstandthe lifecycleofFCsinthe environment. Dispersion + EffluentdisochfaFrgCefsr,oimndsuosutrricaelssrpeislusl,tusirnbalnosnugrfraancgeerturnaonfsfpaorntdvfiiarea-ifriagnhtdinwgtfeora.m contibute FCs tionsukrifnagcweawtateerrabnoddifiessh,,FaCndsailnsaugrrficaucletwuartaleprrcoaduncatfsftehcattarlelalsypiendcitrseocftltyhoenhuthmaatnwadtieetr:(lmoecaalt and + dairy,fritsvegetaandbglraeinss,). Leachatesfrom solidwastespercolateintogroundwater andultimately i contribute FCs to some Direct drinkingwater sources, surface water andeveatually fish. airdeposition of FCstofoodchainconstituentsand airdepositionofFCstosurfacewaters The contributesFCsto humanfoodcommodities. FC levelsinandaroundcities associated withFC productionanduse willbe higher thanthe levelsin andaroundcitieswherether i onlygeneralpopulationuseofsuchproducts 72 Objectives `"mTnehtihsetporodoscjfeoeoncdrturpdcrotev.iTdphesetrihneitefioaFlusfnCodicaentueisnnwovniifltrorobaanelmtlehtsneutabasisslemeqvseusdemieneatn.etTx,hpodisesuvtreaelsaokspwsmieelsnlstaamlnesdona/tossrstveuadmlibielsdeatbthaiaostnetolhifenacenliainleyfntotirwcmiaalltlion "bbouittoheadisctricbuiutnitomnhoeufhFulCmiaannsfteoloeidcctehodaimnne.diathatrepresentenvironmentaldispersionfrom asourceand r"CTehhsaeiidnou.bajlSesac(tmipTvleaoebsfwti1hletlobsaescsaoeslsmsloteuparcscftkelriseo,dmidoic1son2plelirtegsicietosn:rmienparjtehoserecnFtaCatpirvvoedsuaicmtpirlaoennsffodaochinruliamtciameens-leeoexrvpFneoCls-uutarsnsaevlryissaaitrshoeepfrfFeosCoedntin 000445 MuQutaili-tCyiAtsysSutruadnycSeaPmrpoljiencgtPTlasakn. (N100666) Revision No.: 1 Effective Date: May 14, 1999 - er------------------------------30 gtehoegsriaxp"hsitcadlyoc"atciitoine,spo(pTualblaet2i)o,na,annddtthyepseioxf"wcoantterroslu"pcpitleysfaorredmraitnkcihnegdwtaotetrh.e"study" cites by general Table 1. FC Residuals for Analysis - 0 PFOSAA--|-- N-EFO-- SE Ami-- de/ N--- MicFOS-- E Amid-- e [M356|N"N--EEtiFFOOSSEE AClhcloohroli/de/NN--MMeeFFOOSSEEAClhcloohroilde N-EFOSEA/ N-MeFOSEA EEcop TT Table2, Study and Control Cities for Baseline Study Water Sagres [Seodyor | 1990 Ces wl de |[SCmodyol [MCeobolmebs [[GAAL [[11986.776881|] "Definbeyd the rat ofFC prodo uusecagtepoipuloatinon 73 Technical Approach GTohoisdquLaalbiotryaatsosruyrParnaccetpircoeje(cGtLpPl)apnro(tQoAcoPlPs)d(eRfeivniesdiionn 40)0iCFiR Pnartt7t9o2ecToonmxpicldSyuwbiestthadtnhceesreCoqnutirroleAmcetnftosr (TSCA);GoodLaboratory Practice Standards; FinalRule (uly 1, 1998) totheextentpossible at this `point in the program. TThheetottyaplesonufmsbaemrpsloesf,sasmapmlpelseovfolcuacmhets(yoperw,ceoilglhetcste)daantdeasacmhpsliien,gardeevliicsetsedairne sTaubmlmea4r.izTehdiisnliTsatibnlge 3. p`arnaolvysiisdaefnosrtihndepicoaltairoanonfitohnset(yPp),eothfesmaomdpelraetaenlaylypsoilsarinnteeutnrdaeldsfo(Nr)t,hoart TsoatmapllePwFiOtSh.aTnhailsystiasblbeeianlgsoeither . . niencdeicsastaersytfhieenldumabndelraobfQsCamspalmepsltehsa.twTihllebQeCcsoallmepclteedsoafreeaocuthltiynpeedsapnedc/iofricaallcyaicnhloTcaabtlie5on,taonpdrtohveildeevelof 000446 Quality AssuranceProject Plan Multi-City Study Sampling Task (N100666) | Revision No.: 1 Effective Date: May 14, 1999 Pa4gofe30 --SoTable 3. Sample Types, Samples Sampling Devices, and Sample Volumes | Volumeor Ammar ph Sof] collectedpersdmple (3locations ~ 500ftapart) (3locatmaitchown/wsat,er `wanottseurrfa,ce Gon main re [Water fom gromdwater sous" |Samplebole ------11L | aye [Shige available) [Se Sop [0g | a Co ObmAr | [ cartridge) Le Mern arene [PRR [GrowdbeetGsior)-- [Soropackagng [1H | [BrySemamie Sompeiene [TROVE | (3 stores) et a conta(3istnoreesr) [ome [WW [mstoyres) o brees Sore [TR | &. woayNtSeoirxmspopluirccmbeeetd(eafsboovMe)lwsoCEiStEySry e`cbarl cikpeadckpm saholcka yereG,ols 000447 QualityAssurance ProjectPlan MaltiStu-dyCSaimptlinygTask(N100666) RevisionNo.: 1 EffectiveDate: May14, 1999 eT PPaaggee5S0fo30 Table4. Sample Types and NumabtSeamprlisng Locations at Each City pat of anSER RS Sie [She TSER| Si26t3Saemplses oVams e [[SPeempllieToalPE ROS mMaple agi? L[IALLT [ T | T - Ee 1 ----------] Sime [r|E-- SSCiarmeandpi bolorm-- ateorysCQCE(aoRGelId-- smpEeTy ETPEN;|-- WF[70-- 8[--0%]---- [Field TowiprOS | (plot [Fiddle& bomb dpiaie [CaboosePN | IL [| | CL | | | by | EE Twas [SmplePEN | IL [IC[IL[PEN | Tome |Nnaros r= 11 M[sFbeodrgsoiriyepplaeNP~EN~~ [FedpmePeN [ [IL L | | T| 1 || | andfil "Samplesand laboratoryQC(80held spikesP)&: IE wo [[S| RaemdplBeadcBPbeoNydpePAN | TL [|]| Shares == 1] Uber [SmpePEN [ERerOF|[| [Fedplkenoar---- [Fwewpor| | | | | enna | | | | | a lobia pen ares ||| LT|etband i. To PEOS -- [TpEEE [MlQwerPeN [IL | FL polis EOS, PFOAA, PFOSA, PFOSAA, M56; N= mesial EVE of FOSE-OF, FOSECT FOSE Aide 000448 QMuialldi-tCyiAtsysSutruadnycSeParmopjleicntgPTlaasnk (N100656) . Revision No.: 1 EffectiveDate:MaPayge146, o1f93909 A `Table 5. QCSamples by Matrix F_PeNp EmC emos| To Tor qo JOFT (0 J lo To JT 1 [_FaN[T___ Tr qm --mmwos|T [0 _Jm TT JC TC Tom [0 Jo Jo TT | | Pen To To [o To TT ay _ PeN[T____Jo [mmm fo Tmo To To [oT o_o lo ToT & vs eT - TT TToT s --TemTp o r fmo __JS o J[ o jT o 1 _--__ 1 To TT F POT AA | _ PMUeF.FO1S0E0-gOEHx-& FaNpy To qo qo Jo po TT] "TNruimplbiecrasteiannpaalrycsaitsboefsoesniesndeidciamteesntaspampleth.atwillbecreatedfom spits or aliquots athe aborator. P"=O"rpgoalDnaricufPlaFonpOuaSlra,ytlsPiosOnoAeifAsti,htcPe,foFinOsalShys.Aat,mpFlFeeOsS.AA,Mss;Nenets:EUMeof FOSE-OH,-FOSE-Cl,FOSE-Amide 000449 Quality Assurance Project Plan Multi-City Study Sampling Task (N100666) an - Revision No.1: Effective Date: May 14, 1999 Page 7 of30 tehaicshQfAiPelPd.QCThsepiaknealaydtdiictailoQn AisPlPistweidllalbseo.prSoOvPidsedaruenldiesrtedseipnaTraatbelceo6v,era.nd the methods are summarized in ew [ow Table6. StandardOperating Procedures "CoalndlHanedlc ingtofiAiroSamnplesfor the Multi-Cities Project CoSlpilkeicntgiFoinealdndSampHlaensdfloinrgtohfeWMautletr-CSiatmipelsePsrfoojrectthe Multi-Cities Project ""CAoslsliegcntiionnSgaamnpdlHeIaDnsdlfionrgtohfeSMeudilmteint-SCaimPtprloijeeescstfor the Muli-Cities `PGrPoSjeOcpteration and Calibration(drat) Sample Shipping forthe Multi-CitPrioejes [SempleCosody -- [MEET| [MES| [Bawlle60I0 Anoutline ofthe survey plan that willdescribe all sampling logisticsis provideidn AppendiAx. la) 731 Permissions cFaollllsowweirnegmaandientitoiailniItnitaetmeectonsteaarccthw,iatlhitshteofofmfiucniiaclispaanldoafsfisceisalsswfhooriesarcehsptaorngseitbclietfyowragsracnotmipnigled. Phone. permissions for the collection of environmental samples.`Once determined, this person was informed of thslenudagteu,roerolfeatchheatper)o.jeFcotlalnodwtihneg tnheapthoounfrethceeonvsearmspalteisotnh,aatwwreitwtoeunlldetleirokeftorecqoulelsecttto(i.ceo.l,ltercetaatesdawmaptleer,was faxedtothe municipal official. The letter was then taken under consideration anda decision was.issued from the municipal official as to whether or not we can conduct the sampling. `The collectionof an atmospheric sample using EPA method TO-13 (EPA 1990) (SOP M3-F-1) requires tahsastistthaencseaomfplleorcarlunficreondteipnaurotumselnytfsfoorrttwheelvpelhaocuermse.ntToocfotlhleecstatmhpilsets.amTphlee rwaetihonaavlefdorectihdeeudsteoo f`efnilirset.the stations is that they are constantly manned and therefore provide secure areas where the sampler will not be subject to interference. The same method for attaining approval fromothermunicipal facilities was employedfor departments' tchheoicfei.reIsftaadtioonnsa.tiTohnisisanleseodiendc,ltuhdeednatnheoapfprtof opdroienaatterea.p$p5r0otvaolsa local must charityofthe besecured in advance so the donation can be presented when sampling is initiated. `Based on the confidential natureofthe study being conducted the following information may or may not be discussed with the municipal officials. . Information that MAY be revealed to the officials includes: < + dWreinakriengsewaktienrg, ttroecaotleldedctrivnakriinoguswamtaetrriacneds siednimecntlfPrOuoTmWdthieinfslunrufeangcte, wefaftleurenbto,daynd(ifslaupdpglei;carblaew); landfill leachate; and atmospheric samples These samples arebeing collected and analyzed conductingfor aconfidentialclient. to supporta life cycle analysis that is being 000450 Q`uMallii-tCyiAtsysuSraanyceSaPmrpoljienctgPTlaasnk (N100666) Effcive Date:ReMvaisyio1n4,No1.9:991 Page 80f30 + The chemical ofinterestare NOTlistedasregulatedpolutansocarcinogensby EPA. + Twhoeurledsaudsioscfltohseusreetoefsttshewirleslubletsrbeeconptetomopclruatretcdlieentadnd onlyunder extenuatingcircumstances Information that MAY NOT be revealed to the officals includes: + Whothe dientis . What chemicalweare looking - What the chemical is used for + Whatthenatureofthechemicalis (chemicalclassorstructure) TMSheaeprascrehaftoe1r9rm9ea9q.uleGrseetnqseu.ersaTtlhslewyseetrhfeeacmwiaalsidttieeewstaowtitlehlretavrgaeariaintomubesenfctaocpniltlaiantc,ettsehdwei0dtrhciionnknaifgniigmvweatnhteemruppneliracmniitps,aslaiiontnydsitghnreFalenabtnerddufiadlrulyrariennqgdutihreed. Wdienntieedr,atnhdentaoensatlatbelrinsahtaivessatmeplmiangysbcehesdouulgehbtatsoecdoollnetchtemsaatmrpilceetshtaotbiescroelplreecstenetda.t1ifvaenofatpheprreoqvuaiilsred matrix. ExamopfRlequeesstsforPermisrsepiroovindesdinAppendix B.. dCiosmcumsusniioncarteiloatnedlotgosdaarteamraeipnotrtaiinngewdialnlbdeicnlcleuadrelywdhoocuwmaesnctoendtaacntdesduamnmdatroipziecsddiinscaulsestetde.rtAotnhye client's Tegal representative. 7 7``Sa3avfo2eitdysacoPmnrpselicedaecrotanittoianomnsisnawtiillonb,e sinucocrahpotrhaeteodfcilnetahneiSnugrsveyaPlman.pgeTlnarabidedtintwoegnentounsoersamnaldtmheeasuuereosftaken to preclancd sample boules, th following precautions will be taken to void contamination during sample Collection. + + PFioesldtsscenwtilsltsnowtilblewuesaerdoantlaynoyldt,imweedlurlianugndsearmepdlaethalneadsltin6g,waosrhmionbgislsiiznacieonp/udrecmhaabsiel)iczlaottihoinn.g. "The useof water-resistant clothing will be avoided as much as possible. + Tyvek suits will Nile gloves wil not l be be worn during s wom atal times ample while handling. collecting and handling samples, except in grocery + sMtaorneys afnooddoathnedrsrneatacikl persoadbulcitsshm--enmtisc.rowave popcorn, fas-food (sandwiches chicken, French fcrhieems)icpailzzsao,fbiankteerreysti.teTmhse,rebfeovreer,agheasn,dcsawnidlyl,bceotohkoireosu--ghalryewpaaschkeadgeadftinrwhraanpdpleirnsg tfarsetatfeododw,ith the: cpaorsrsyeosustiofnooofd,thoressnaamcpklsi.ngPrteewarmadpupreidngfosoadmsploirnsgn.acks (lke candy bars) will not be in the: + FiNeolbdlupeercsoennweilllmbaeyusneodt cduornisnugmtehimsipcrroojewcatve papcom during the surveys "4: the7Th3es3almocpalStiaonmngp,llioingnc.lguALdoiGncgaatrtimroeinenst1wa2idtdXhrLiensh,aEnoadfc-hshealCmdiptlGyePsSco(lglleocbtaeldpforsoitmimounninigcispyasltefma)ciorliesquwiivallbenetrweiclolrbdeeduosned Lo determinetheexact location (coordinates) ateach sample collection location. The position wil be read 000451 Quality AssuranceProjectPlan Multi-CityStudySamplingTask(N100666) RevisionNo.: I EffectiveDate: May 14, 1999 Page 90f30 fromthedisplayandrecordedbyhandontheSiteLog.Theunitvillbeoperatedaccordingto SOP No. 3-164.Also,cachsampling location sillbemaornaklocealmdap. 734 Air Sampling Airsampling willbeaccomplishedbyusing aGeneralMetal WorksModalPS-1AirSampler.ThePS-1 `samplinghead(showninAttachment1),whichis coutainedwithinthesampler,consistsof a4"diameter icnolnettafiinlitnerg(amaPdUeFo,fwhTiecfhloinsco3a"itneldgelnagstshfainbdefriftislstemrumgeldyiinutmo)tahnecdarat2r.i3d"gde.iamxe5t" gelarss cartridge Thehighvolume (~250 lpm)polyurethanefoam(PUF)samplingmethodbasedon U.S. EPA'sMethod TO-13isapplicabletomeasuringambientairconcentrations oforganiccomponentsatconcentrations fsremoim-v0o.l0a0t1l-e5o0rpgga/nmicocvheermiac4a-l2s4phroesuerastianmptlhienagiproernioadg.lTahsse-pfberr foilecr (paealrltdoiwcsuulfaotrre)tehaendcoPUlFle(cvaotpfiotrohne phase). Thelimitsofdetectionarespecifictothenatureoftheanalyteandthelengthofthesampling period. Ofrnacetio1n2-chooluleraciterdsaamnpploel,ycuornestihsatninefgoofamapa(rPtiUc)u,lwatiellfrbaecctioolnleccotleldeacttecdaocnhcaigtlya.sAsifirbsearmfpillteesrwainldlbaevapor Icdoelallelcyte,daatirgrostuantidolnesvheloauldabneycsihtoesfeonrbwehciacushpeeirt miissssoimoenwthoastasmepcluereGaannbduesoubatlaliynheadisspaecrcseopntnaeblloen.-site 24 hperday.Other locationsmayinclude alocalcollegeoruniversity,retailestablishment,the POTW plant,or inkingwaterplant fthefacilitystaffarewillingtoaccommodatethe sampler. Thesampler TM rcequoirness1h2ii0gVshpwotiwneedrs,n(a>nt2d5smhpohu)l.dnIoFptobsesirbulne,fiactoispryaoinfitnhge.wSeaamtphleirsnegcatlisoonifsrnoomttpheelorcafldoaiifrltyhmereeardc `cnoenwdsiptiaopnesr.wiOlnlcbeetohbetfaiienleddsaanmdpaldedies cdoltoletchteedf,ireoludltoignebaoiorksfaomrptlheerscalemapnliinnggidsapteertfoodromceduamnednttwheeaqtuahleirty control samplesare collected as descriniSebcteiodn 11.2.3. 735 Water Sampling `sWhaotwernsbaemlpolwe.sw(Nioltle:beMcioclrloelcatyeedfsraommpsleevsewrailllpnoottbsewciotlhliencttehdedmuurniincgiptahledMruilntkii-nCgiwtayStetrusdyysbtuetmm,aays be collecteddurigg subsequentsamplingsundertheprogram). [Sez le} [=| SafeWater `MunicipalWate TrestmeatPlast TopWate `(Wch.ogl,el(akbeu,lpko)nwda,treersewrivlolibr)eocfoldlreicntkeidnfgrwoamttehrr,eaesnidtaetst(haetlweaatsetr t5r0e0aftmaepanrttp)lwaintthinifnlauseunrtfaancdeo-uwtaftleorws.ourTcaep waterwilbecollectedfrom threeretail establishmetswithinthecity. Onewa-terlsamipltesweillrbe ccoonltlaeicnteerdiinnttootIh-eLwEatSeErpsrter-elaema,noerd,i(fcaervtiaflivede)wpiotlhydertahwyallesnyesstaemmpilseavboatitllaebslbe,ybeyiuthseirndgitrehcetvlyapllvaec.iDnugtchteo co thmiendiimffiizceulvtaryiianboiblittayindiunegtoa tsraumepsluirnfgacteescahnmipqluee.wiFtohratbhoettelnev,itrhoensmeesnatmalpslaemspwlielslb(lefker,omfibvuerl,krweasterevrotiro), & tshaembpoltetlisewcoillllecbteeldotwheereqdubaleiltoywctonhterosl usarmpfloeafstchaereewcatoerlanldawesidlcelsbtcerfeiibledldedinwiStehctbiuolnk1w1a.t3e2r..Oncethe field 000452 Quality AssuranceProjectPlan Mulsi-City Study Sampling Task (N100666) . Revision No.: | Effective Date: May 14, 1999 Page 100f 30 ~ Isfetlheecdterdinlkakien,gwpoantde,rosrourirvceeri,sugsrionugnmde-twhaotdesrtdhesecnrtihbeesduarbfoavcee.watersampleswillbecollectedfromany 736 SedimentSamplingfrom Municipal WaterSource S`oSuerdciemse.ntTshaempilteesswwiillll bbeecloolclaetcetdedatslyenaosptt5ic0a0llfyt awpiatrht.thAeftbeurlktwhaetweartefrrsoammptlhrienegsiitsecsowmiptlheitnseudr,ftahcee:water `Tsheeditmoepnt2wcilmlobfesceodlilmeectnetdwaitltlhbeesraemteaisnietdefobyraunsailnygsias.0.0Al4t-emr'naYtoivuenlyg,agrasbtasianmlpeslsersttehealtspisoohannodr-dsecpoloopyewidl.l beused. 731 POTW Sampling BPaOttTelWleowfifilcliaplr,ovwihdoe waiplplrocporlilaectteesaacmhplienfclounetntai(npeorsst-acnhldodreitnaaitlieodn)w,rsiltuidegnei,nsatnrducetfifolnusetntostahmepdlees.igBnaattteedlle fwiolrlaanaslsyusimse. cOusntcoedytohfetfhieeldssaammpplleessaanrde wciollllebceterde,sptohnesqiuballeiftoyrcpoanctkroilngsaamnpdlesshiaprpeicnogltlehcetsedamapsldeesstcoriBbCedL in Section 11.4.2. 738 Landfill Leachate Sampling Bcaotltleelclteeawiclhlsparmopvlideeaacpcporrodpirnigatteo sdeatmapilleedcownrtitatiennerisnsttortuhcteidonessipgrnoavtieddemdubnyicBiaptatlelllaen.dfBialtltoeflflieciwail,lwahsosuwmiell custody of the samples and will be responsible for packing and shipping the samples to BCL foranalysis. ( Noindustrial landfill willbe sampled. : 739 Food Sampling Iwnilclabcehccoiltyl,ecttweod ofrrotmhreeaemchajcoharignr.oTcehrey-isnttoenrteofcthhaiinssswaimlpllbiengidiesnotifdieedtearnmdinreeptrheesedniteattairvyeefxopoodsusraemspolfes rleisstiedde,natsndwiatshpiancekaacghedr.eFgioorntbhaesemdiolknatnypdiecaglgsf,ootdhse sceolnesctuimoenod.ftThheesefofoododpsrtoudfufcstsinwtihlel sbteorceolwlielcltebdeas cthheercekaerdetnodoeltoecralmionrerweghieotnhaelrstoeurrceesa,arenyantyypferoims regional or acceptable. lTohcaelgrsooucrecreys,satnordetfhiessheswhiolullbdbe eselected. If rienplraensdesntoauttihveeasotefarniUshStchiattii,ttyhpiiscwaolluyldraiisnecdluodreccaautgfihsth.inFtihsaht gmeanyerbael frreegsihonofofftrhozeenU,Sa.ndFsohromuladnbye:of the sicdaelnetidf,ifedilalnedd,eiwtihtehrtahelohaefaodforrgeamonviecdb.reIandaodrdaitpioonu,nodonefoorrggaanniiccaglrloycreariysesdtofrleouinr weialclhbceitpyuwriclhlabseed. eEachgffoorgotdrsatsnusfpfo)writl.lTbheepbaackgalgaebdelisnwdiilvilduiandlilcyatientahzeigpr-osecaelrbyasgt,orweiftrhobmubwbhliecwhrtahpefifonoedceistseamrsyw(eer.ge., for the purchased. 7310 Finfish Fiinntfhieshviscpienciityeso(fitch.e paerrecahinanwdhibcluhegwialtle)rwislalmpbleecsolalreecctoeldlefcrtoemd.waFtienrfbiosdhiweisll(ibce.csolmlaelcltesdtrteharmosugohr ponds) . eAlCecterloecftirsihcincgurorresneti(neiintgh.erEwlietchtr2ofgiasshoilnigine-apofiwsehreerdiegsetneecrhantioqruoerwbhaitecrhieisn)votlhvreosuggehnvearraitoiunsgsatDylCesoorfan &on ccollelcetcrtoeddesbyintdoiptnhete.waSteeirntiongcrienavtoelavneseleencctirricclifineglda.sFhiosrheltihnaet aparsesa wtihtrhougfhinthee-mfieeslhd naerte astnudnneendt,ratphpeinng fish present in this location. [Note: Finfish samples wil not be collected during the Mult-City Study but may be collected during subsequent samplings under the program]. 000453 Quality Assurdnce Project Plan Mulsi-City Study Sampling Task (N100666) = Revision No.: | Effective Date: May 14, 1999 Page 11 of 30 8. SCHEDULE OF MILESTONESAND DELIVERABLES The scheduleofdeliverables and milestones is shown in Table 7. : `Table 7. Milestones and Deliverables IClintapproves Muli-CitySway) [Jn9 | Team [Greemville,IN [Tobedetermined. | [Spariansburg, SC [Tobedetermined. | each city sampling 9. ORGANIZATION AND RESPONSIBLITIES 9.1 Project Personnel Ee to somos soon, i pring repos 0 management for is asc. She wil report `The organization and linesof communication for this project are illustrated in Figure 9.1. Dr. Joseph `Fiksel is the Program Manager for this smdy. MarciaNishioka, the Project Manager, will be responsible. for the tchoeorcdoionradtiinoantoifotnhaenfdieclodmmefufnoirtc,aatnidotnhewitrheptohreticnlgioenft,daatsaw.eMlsl .asStuhseaenvaAlbubatgiyoniosftahneaPlryotgicraalmQmueatlhiodtsy, `Sampling Task Assurance Officer. Don Gunster, the Sampling Task Leader, will be responsible for selection of media associated with environmental dispersion, and will coordinatethecollectionofthese tshaamtplalelsf.ieMlds.acRtiovsitainensaarBeucholnidsutchteeBdaattceclolrediSnagmptloitnhge Task Q QAPP. AThOifsfiicnecrl,uadneds risevrieeswpoinnsgiablned faoprpernosvuirnigngfield `SOPs, ensuring that staff training is complete and documented, conducting at least two field inspections, quality assurance issues to the Program QA Officer. Mr. Wayne Trulli the Battelle Duxbury Field Coordinator, and will provide technical guidance to the Sampling TeamLeaders. The Sampling Team on `Laecatdiveirtse,s,Mri.nclScuodtitngMmaocboilmibzeatrio(nle,adde)maonbdilMirz.atCihorniasnGdargenpoonrt,iwnigl.l Tbheeryeswpiolnlsailbsloe bfeorraelslpsonasmipbllienfgor & `idSeanmtpilfiynigngTapsrkobLleeamdsera,ntdhceoDrruexcbtuivreyaQctAionOffwihcielre, ianntdhethfeiePlrdo,jaenctd cMaonmamguenri,caatsianpgprtohpersieataec.tiAvidtdersestosetsheand telephone numbers of key personnel are shown in Table 8. 000454 QualityAssurance ProjectPlan Multi-CityStudy Sampling Task (N100666) Joseph Fiksel Program Manager Revision No.: 1 Effective Date: May 14, 1999 Page 1203f0 `Susan Abbgy ProQgArOffaicmer PMraorjceicatNMiasnhaigokear MaTracsika NLiesahdieorka AnalyticalChemistry TDaosnkGLuenasdteerr Field Sampling RoQsAanOnffaicBeurhl Fleld Sampling Task Figure 9-1. PSrtoujdeyct Organization Chart for the Empirical Human Exposure Assessment Multi-City & 92 Training Nospecialcertificationsare requiredfortheperformanceofthis project. AQAP reviewmeetwiilnlbge: conducted pritoothre.first survey to ensure thatfield personnel arc familiar withthe requirementsofthe eQnsAuPrPe.thIantatdhdeiytaiorne,ffiaemlidlp iarewitrhasllwsoialmlnpblen itnrgeapirnloecdoednureeasc.hsamSpOPlpriiorn totg he firstsurveyto Lo 000455 MQluatl-iCtiytAysSstuurdanycSeaPmrpoljienctgPTlaasnk (N100666) . Effective Date:ReMvaisyio1n4,No1.9:991 Page 13030 . Table 8. Key Personnel, Addresses, and Telephone Numbers EEMarcia Nishioka Program Manager Rosana Bull Sampling QA Officer rayne Trl Manager Michael Mz ott Macomber Chics Gagaon Battelle Columbe 505 King Avenue Room 5-228 Columbus, OH 43201 ERSo aing Set Duxbury,MA 02332 `3B9a7ttWelalsehDiunxgbton Street Duxbury, MA 02332 `Battelle Duxb Duxbury, MA 02332 "Battelle Duxb BiDuxbury, MA 02332 Battelle Duxb Ee Duxbury, MA 02332 Battelle Duxb Qr=i= TR1-952-5309 (ork) | 7ARLI4-39.526-6353280on(vod) TRT-952-5270 (work) TETS5Z5379 (vom) TEI oi : Kim And Duxbury, MA 02332 Battelle Columbus STA24525% (vo) Multimedia Chemist 505 King Avene 614-875-3344 (home) RCooloummb1u1s-,1-O0H60 43201 AiTronCyheWmiisbsitth Bastele Columb 505 King Avenue T224-5481 (vo 740-587-7439 (home) Room 6-131 Deas Dab] CBoatltuelmlbeusR,icOhlHand43201 ITE wah Richland,WA 99352 ddauble@pnl.gov 10. QUALITY ASSURANCE OBJECTIVES Requirefomreensnurtinsgthatthedataaefitfortheirintendeduse (thats,are ofsuitable quality) reiqnculiurdeemeancctusraarcey,mperetctihsieofni,nraledpraetsaepntraotdiuvcetniessst,ecchonmipcaarlalbyidleiftey,nsainbdlec.omDpalteateenesls. eWfhomeratehtihsepsnreojtectasre discussed in temsofthe appropriate characteristic as defined below. The field quality control program Pr. isdesignedtoprovidedatatoassessfieldproceduresandissuesthatcouldaffectdataquality. 000456 Quality Assurance Project Plan Mulsi-City Study Sampling Task (N100666) i Revision No. | Effective Date: PMaagye1144,01f93909 10.1 Accuracy Aocfctuhreafcieyldisatchteiveixtteesntwoiflalgbereaessmeesnstebdebtywetheencaolmleecatsiuorneadnvdalaunaelaynsdisthoeftfrieuled bvlanakos,flitnrituperbelesatn.ks,"Afciecludracy" spikes, and through the acceptable calibrationofthe irsampler and the hand-held GPS. ~ Air be esmapmtpylisnagmfpileeldcbolnatnaiknsearrsetdheastcarriebheadnidnlSeedctasiiofnth1e1.y2.w3e.rFe fiolledorwtihteharamastlraimcplelse,fbiuetladrbelaacntkusawlilyll alelfltocwatphpeedantahlryostusghtoouatstsheessscaomnptlaimnignaptriocoensisnatnroddaurceednobtyftihlleesdawmiptlhisnagmcpolned.itiTohniss. sample will Trtoitphebslaamnpklsiwniglslibteetshaamtpalreeschonitpapienders(o(noenpeeprecritcyit)yf)rofimlletdh wfiitehlddetiootnhiezeldabwoartaetrorpyriaonrdtroesmhaiipnment `unopened until analysis. This sample allows the analysts to assess contamination introduced by sample shipment. Equipment blanks will notbecollected, a the only tool to be used (the sampler for sediment samples) will be deployed for only one matrix. The collectionoffieldspikesamples ismatrix-specific andisdescribedinSection 11.SOPM3Fe4 details field sample spiking for the program. 2 1T0h0eGmdaremipn e12nXoLdnGtPihSeulnneivgtehloafsdaedgersaidganteidonpoismiptoiosneadlbacyctuhreaUcnyoitfed1S5tma.teTshDeepaabsrotlmuetnetaocfcuDreafceyasmea.ybe + 55 Although detection limit s not strictly applicable to this unt, the minimum detection limit is defined by the digital display: 0.001 minutes or approximately 6 fect. 102 Precision `PrSeacmipsliionngiprtehceiseixotnenwtilolfbmeutaussaelssaegdrebeymtehnetcaomlloenctgiionndaenpdenadneanlty,sissoimfildaurp,loitcarteelastaedmpmleeassuarseimnednitcast.ed in Table 5. 103 Representativeness aRlelptrheesednattaatgievneenreastseids utnhedeerxttehnits tQoAwPhPicdhempeeansduprreimmeanritlsyruepporensetnhtetserluecstyisotnoemfst.hTehsearmepplriensgenstiatteisvaenndess of CmiattryiScetsu,dyw.hiRcehprweesreentdaettievremneisnseodfbtyheinfiiteialldpprroocgerdaumrestsudwiielsbceonednuscutreeddptrhriooutrgohtthheeuinsietioaftidooncoufmtehnetMeudl,tistandard sampling methods and trained field staff. 104 Comparability ``cCoommppaarraabbiilliittyyoifasltlhetehxetdeanttatgoewnheircahteddautnadferrotmhiosnQe AstPuPdydceapnenbdesctoomspoamreedexdtierencttulypotonstihmeilsaerlescttuidoineso.fTthhee: `siatmipaltiinong osiftetsheanMudlmtait-rCiicteys,Stwuhdiyc.hCwoemrpeardaebtielrimtiyneisdebnysuirnietdiatlhprroouggrhatmhestuusdeieosfcsotnadnudcatreddsapmprliitnoogthre pede. 000457 QualityAssuranceProject Plan MltSitud-ySCampilintgTaysk (N100666) EfectiveDate:RMevaisyio1n4,No1.9:99 Page 15of30 5 10.5 Completeaess Completenessisthe measureof theamountofdataacquiredversustheamountofdatarequiredto ``aFbualfsielllitnheeostfadtiasttaicaaglacirnitsetrwihafiocrhtfhuetiunrtesenadmepdluisnegoeffftohretdscataan.beTdheesM igneud. SlStautdymiw- siiplntbCeenldceoidnitdoudt cnetveedgylaotp every ite wherepermissionhasbeengranted;thecompletiongoalis 100%butthe project goalsvillnot nboetcaolmlpsraommpliessecdainfb8e0c%oollfetchteeidantsepnldaendnseadm.pFluerstahreer,coslalmepcltiendg. wSialmlpbleicnognwdiulcltceodanttiomneeastictae c(hsstiutdey oevrenif control)eve ifthestepair(studyorcontrol)cannotbesampled. 11. SAMPLING PROCEDURES 111 DocumenatndaSthiippoinng A`olult diolclumneonttbaetuisoendw.ilAllflolrlaowdwaStOawPi6l-l0b1e7:rdeactoradweidlilnbreeraelctoirmdeeadinndwiinlkl;bpeeamciali,nteariasnaebdleaps epanr,taonfdthwehiteprojectfiles.Errorswillbecorrectedbydrawing asingleline throughtheincorrect eatrysothatthe daotedratidtahtegatiamreieostfinltlhreeaeaadtabrllye.. Anexplanationwillaccompanyeachcross-out,whichwillbeinitialedand 11.11 SamplingLogs on A3-tingFieldSamplingLogbookwillbemaintainedbyeachfieldteam.Alldocumentaotffiioelnd activitieswillbemainitntaheiLongbeoodk. ASiteLogwillbecompletedfor cachsamplinglocation. Aseparatesamplingformwillbecompletedforcachmatrixsampledat asite.Theshweilliencltudesall sasimteplsaemdpelsicnrgipitnifoonr(maatttiaocnh:gsrocaermyrepdcaetliep,tisstanompdlgoecucmolelnetctpourrc(haansderse)c,oarndedra,nifyoditfheerrepnet)r,tisnaemnptliinnfogrlmoactaitoionn., Examplesof sampling formsareprovidedin AppendixC. 1112 Sample Shipping iAnlTsaabmlpel8easnwdilalcbcoersdhiinpgpteodtvhieasopevceimfiicgahtti(omnsomliisntegd)idnelTiavbelrey9t.oEMasc.hKcioomlAernwdirlelwcsoantttaihnetahdedsraesmspslihoogwn forms,whichinclude aChain ofCustodysection.Theseformsidentifysamplebeingshipped. Sample IabelingproceduresaredescribedinSection 11.1.4, SampleshippingisdescribedinSOP5-210. 1113 Sampling Location `Sample locationswilbe determined during telephonecontactswith Municipal officals. The site e`qucivoaleontrhwaidnldli-bheendledatgeltrombaeilnpesodsaittieovneirnygsylstoem cu(sGaiPnSgt)auinGiato.rmTnihneuGnPiSt 1wi2lXlbLePeorpseornataeldNaacvciogradtionrgotro BattelleSOPNo. 3-164;thesamplesitecoorwdillibenrecaordtedoentshesamplingform. 000458 QMuualli-tCyiAtsysuSrtaudnyceSaPrmopjleicntgPTlaasnk (N100666) . Effective DateR:evMiasiyo1n4,No1.9:991 Page 16 of 30 Table 9. Sample Containers, Storage Conditions, and Shipping aCl -. [Co "Vaporphase rTUbe Polyurethanefoam 1 | Wrapcariinprreciiedanegdolel. Placewrapped Storecool (4C) + SPtlaanctieowaakteersource TTopwrateewratfserrotmrroemeapllladnt SHiemesnatbflsohmmesnat cswaier source (TcLanpirfeicelde)ancd |polyethylene jars | (0ce0rtmifpireddiened No presrvaion Sr6001 (FC) |Sera 070) p+oPowschlormtionfe || TLprecieased Sorecol C) + EShfiegex p(coelniyfcictdh)yijcaorse mam 1 ~ + Groundbeef cpeachflemints |Starecool (4C) Pork chops (bonein) `original container, Bobnreealsetsss,skinlesschicken. `sanedkpeeap iintnetsmosered- + RePgoikoannadlbfeicafhotdops | specificcoolers. . WEhmolemik * FrWohzietenbgrreeaednibeans ++ FOrrehpaappmliescborfelaoudr : wm | (electroshock) b`ogas.lumfoiil;nplaustmic 000459 QMuuallii-tCyiAtsysuStruadnycSeaPmrpoljiencgtPTlaasnk (N100666) - Effective DateR:evMiasyio1n4,No19:9|9 Pagellefn | 11.14Sampling Labeling sMiatteriTxhaenfdosrammpslwei-lslpeaclsiofsiecrsvaemapslicnugsftoodrymfsowrimlsl.bEeaprcehpfaorremdwbiyltlhienpcrlougdreaalmimstanoaftgheersfaomrpelaecshtshaamtpmluisntg pbreocviodeldlfeorcaettatechhdessaimtepl(estteobreeplcioclalteesc,izid.eOdndueplliacbaetlesi, pfilealcdesdpoinketsh,etsca)m.pTlwecoopnrteapirnientraednldatbheloswthielribse pl`uamcbeedri,nwthhiecfhiielsddlogoboock. Tuohnetlmahbeesleampprlnoivnigtdfeoarsmnsar.atAipvepedensdcriix3ptipornoovifdtehseesxaammpplleesaasmwpellinagsfoaurnmisqfuoer `aecity. SOP M3-F-6describestheassignofmueninqute samIDpsfolrteis project. 112 UrbanAir 112.1 PUFandFilter Preparation 'SPoUxFhlaentdexatirrafctiiloenrswaiothpdreiclcehanledoinrBoatmte(ellDte'ChsMaa)irfnaoneral1y6shiosulrabsoarnatdodrryi.edTwhiethBaUFniwtirlolgbeengcalsesatrnebeamyd, The PdS-1gilascscarhtridalgnedspaolnadcserhduimnioazummumffolieleovtoebateauts4he5d0aasCo&vpneromtieegctti.veTwhreacppleera)n wPiUlFlbweilrilnbseepdlwaictehdinthe lasscartridgeandwrappedincleanfol thenpackagedinbubble-wrap. Thefilterswillberinsedwith cdointcahilnotrhoe mPUeaFntadhndardintehdee.c`lTehaenceldeafnilftielrtweirls wlibleslbeeatptloatcheedfiinezlidps-iltoecs.k bTahges.aThsesglaesissmcsahrbtorwlindgyien Figur1e. (2, 1122 Air Sample Collection x 1. WuhsiedlfeowreasraimnpgldeicsopolsalbleecglRteotviaeio,ncntahr.eeffoull,lyzempovet-bhaegpalancdkbaougbibncglferworkmatph.eglasscartridgetobo 2. Isnuspppeocrttt.hIenssearmtptlhiengglahsesacdatrotirnidsguerietnthoetrheisadasgoarsbkeeattasutphpeotrotp. andbotiomoftheadsorbent 3. Screwthefiler supportbas ontotheadsorbentsupport. Donotover-ghtea. 4 Ppllaacceoaasmebcboenrdrguabsbkeetrognastkoeptoofntthoepiotfetrhseufpiploterrt.bRaeset.z Pltahcefetohielafnildtezroinpt-olpbooafcgtkh.eTghaesgkaestkaentds SalrteenrostusphpoorwtnbiansAewtittahcthhmetehnr1et.ePwliancgethnuetfs.ilterretainingring onthetopgasketandattach ttthe pl`aCtAeUoTnItOhNe:sIaftmhpeslamhipelnaindgg.Thheaedciovaesrspleamtbelemduastwbaeyfrreommovtehdeisammmpeldiinagtelstyep,ripolracteothtehpesrtaorttoef csatcmoipvvleeer collection. 1. Connectthesampleheadtothevacuumpumpbysecuringit withth ringclips ontopofthe vacuum pur. . 2. P`lmuingutthe.eAvdajcuusutmtpheuamipriflnotwotaotaipmeprr.Sotxairtmathte2ev5lac0yulupmm (pbuamspedanondtalhlcowatloirubnfroarutsatiineogatsnht)oene o.S Vmaeritaetrorre.Radeicnogrfdrtohmethsteaatiprasraammpetleerrso,nstuhcehdaastdaasthee,etti.mAe,nmaegnahxelidacaeaasmdhienegtp,aisnsdlhrouwnneniinngtime `Attachmen2t. 000460 QualityAssuranceProjectPlan Muti CityStudySamplingTask(N100666) RevisionNo.: I EffectiveDate:May14, 1999 Page18 of 30 - po -- SEFarRetakingRiog ------ oe ey R_ {) Uv i-- - a eemon psy DN 1 -1 - Swe L HE Adsorbeat Tame, sion oover bo ---- (ES c 1, = =ecum Aceon Support . Figure 11-1. PS-1Sampling Head 000461 Quality Assurance ProjectPlan Midti-CityStudySamplingTask (100666) . RevisionNo. 1 EffectiveDate:May 14, 1999 Page 19.030 . 3. Setthetimertoshutoffater 12hours. 4 Porniaonrtdoadlilsoawssfoemublnifnogrtahelseaasmtpl1imnignhuetaed.aRfeecrotrhdetshaemrpelaidnignigsfrcoommptlheetas,rtsuammtphleevramacgunuamhpeluimop ``sgaamupgleeornrtuhnendiangttaismheeetm.etSehrounttthheevdaatcausuhmepetu.mDpetoeffr.miRneecotrhdetehneddiantgelapnmdftrhoemrtehadeignrgaopnhbthaesaeidron themagnahelic gaugeinthesamemannerasduringairsamplercalibration (Section5.8). 5. Cgarlacpuhltaottehtehdetaottaaslheiemte.andaverageflow rateand recordonthedatasheet.Attachthecalibration 1123AirQuality Control Samples DsupeiktesotamhpedliefwfiiclullbtieespirnegpeatrteidangtBaaptrtoeplelrelaynpdlatcheedasfhieilpdpsepditkoeothnetofitehledfillotcaetriaonnd.IPnUtFhmefeideilad,,thefield the spiskpeidkfieldtfeirlitsetrwhienlrlbemeopvleac,efdiolndeadsaamnpdlreerphleaaceddaisniiftsinssttoalrlaegdebtoacgoflloercrtetaurrenaslshiapmmpelnet..TAhse indicatedinTable the fieldspikewillbe 100ngcachof PFOSandPOAA. + tshheibpamegncto.ntAasiininngdtihecspaiintkeTedadbPl,Ue5F,witlhlebfeieolpdsenpedfiwoirklalbbeoeut115s0ecoofn0dMse,g-t&hen-rEeste-aFlOeSdEf-oOrHr.etum the samfpileel,dtbhleannrkefimlotveerdanadndPrUeFpwlialclebdienplsatocreadgienbaagssafmoplrerrehteuamsdahispimf einntst.alledtocollectareal - the bagcontainingthe fieldblank PUFwillbe openedforabout 15 seconds,then rescaled for retumshipment. 11.24 Air SampleShipmeat 1. Rreemmoovveeththeeffiilltteerrrreotmaitnhiensgarmipnglfirnogmhetahde.saFmopllditnhgehfeialtde.iWnhhiallefswoetahriednigrdtipsaprotsiacblleseagrloevteusm,edin. F`oRelcdotrhdetfhielcteirtiynahnadldfaatgeaiinnf.orWmraatpitohnoefnilttheerlianbtehleofnotlhaenbdapgl.aceinthe labeledfilterzip-lock bag. 2. cRoenmtaoivneintghtehefiltPeUrsFufprpoomrttbhaesaedfsrorobmetnthesuapdpsoorrtb.enWtrsauppptohretg.lCaasrsecfaurltlryirdegmecoovnetthaeiglnaitsnhscgearPtUrFidigne foilandplaceinthelabeledzip-lockbag.Recordthecityanddateinformationon thelabelon thebag. Wrapthe zip-lockbaginbubble-wrap- 3. I`mSmaemdpileaCtoelllyecptliaocneDsaatmapSlheesietnicnooalzeirps-wliotckhbiacegtaonmdapilnataciinnatchoeoclotnetmapienreartwuirteh.tPhlaesceatmhpeleA.irFresh iceshouldbeaddedtothecoolerinpreparation for shipping. 113 Drinking Water . th`Weabtoetrtlseaompnlceesiinirivteotrasl,lypsuo bmen orrgrededs,esravnod, irres-acraeppciolnlgetchteedbobtytlseubwmheilregsiunbgmtehregceadp.peSdsamapmlpelebobtoltetlse,wiflillling (3) notbo prisedwihtwaterpriorocollectingth sample 000462 QualityAssurance Project Plan Mlsi-Ciry Stuy Sampling Task (N100665) RevisionNo.:| Effective Date: May 14, 1999 Page 20 of30 . 113.1 Surface-Water Collection Sample collections ofdrinking water require prior permission before attempting to collecta sample. Odenpceendaippnrgoovnalthiseraegcreeiveemde,nstawmiptlhetshemafayciblietyc.oIlflefcatceidlibtyy peietrhseornBnaetltewlillel ocrtohllectftachielistaymppelressontnheely,will be: provided with writen instructions to facilitate comparability. Water samples are collected according to `SOP M3-F-2 and summarized below. 1. pUosliynegthNiytlreinleesgalmovpelsetcoonptraeivneenrtscboynetiatmhienradtiiroenc,tlcyolplleatcitnhgetwhaetceornstaamipnelresinitno t1h-eLwparteecrlesatnreedam(,ceorrtiifi2fed) valve withdrawal system is available, using the valve. 2. Whencollecting trough avalvesystem flushthesystembyrunningthewaterfora minimumoftwo `minutes prior to collection. 3. Oncethesamplehasbeencollectedplacethecoveronthecontainer,dryandlabel accordingto Section 11.14. 1132 Water Quality Control Samples Aspsiekpianrgastoelsuctrieonw-rceaqupvirieadlwfoirlelabcehprfieepladrsepdiiknetshaemlpalbeo.ra`tToheryftioelcdo-nstpaiikendthseapmrpel-emweialslubreedparleipaqrueodtsboyffield `personnelaftercollectionofthe water samples as follows. " 1. Theoutsideofthevialwillberinsedwith highpuritymethanol(HPLCgrade)andwipeddrywith a [5 Chem wipe. 2. Tthheescaamppolfetchoentsapiinkeirng(msaorlukteidonwivtiahl wllinebeforunaspcprroexwiemdaatnedltyhae1cLoqnuatnteoitnfyt)t.hse vial will be poured into 3. The vial that contained the spiking solution will be dropped into the field spike sample bottle. 4. The bottle will be capped and then shaken, and inverted several times to assur mixing and dispersion ofthe spike solution. 1133 WaterSample Shipment Plinacperespaamraptlieosn fionrcsohoilpeprisnwgi.th iceto mai: ntaacoionl temperature. Fresh ice should be added tothecooler 114- Sediment from Drinking-Water Source 114.1 Sediment Sample Collection cSoeldliemcteendtawciclolrbdeincgoltloecStOedPsMyn3o-pFt-ic7alwliythwictithhterheat0h.r0e4e smu*rfYaocuenwgatgerrasbasmapmlpelse.rSoerdaimsetanitnlseasmspslteeeslwsiploobneor scoop. Undisturbed samples will be achieved by careful attention to established deployment and recovery procedures. Battelle's procedures cover the following aspects of sediment sample collection: + thorough wash-downofthe equipment before each deployment using deionized waterand methanol; & foadrjutshteinggratbhesaamppplleire,d controlofpenetration downward pressure; by adding or removing weights to the frame and + slow recovery until the samp?ler breaks the water surface; 000463 Quality AssuranceProjectPlan Milt-City Study SamplingTaste(N100666) RevisionNo.: 1 EffectiveDate:May 14, 1999 Pa21gofe30 Eachgrabsamplewillbeinspectedforsignsofdisturbance. Thefolclriteoriawidenitifnyidegal charafcoratnaeccerptaiblsegrtabisacmplse. + Sbaemlpolwetrhielsneovetlovofertfhielolpedewniitnhgsdeodoirmse.at;the jawsmustbefullyclosedandthe top of the sediment + Overlyingwaterispreseatandnotexcessivelyturbid. - + Samplersatlcasthalffull,indicatingthatthedesiredpenetrationwasachieved. sIcinecnetritsatin.lMoiclatdioovnesr,-hpoewnecvtreart,iolnimgahtyobveera-cpceneepttreadtaicocnomradyinbgetaoctcheepftoeldlaotwtihngesdtiasncdreatridosn:ofthe sampling + thesedimentsurfucei intacton at leastonesideofthegraband + gtahebr,siis.el.it1t0lveiosrinb0leeviimdpreinncteftrhoamttthheessucrrfeaecneisnegdioumtesnitdehoafspthuasthgerditdhroughthegridsurfaceofthe No evidencethatsedimenthassquirtedoutthroughthehingeortheedges. tIhftehgergarbaabnsdatmhpele(m0epe2tcsmth)esaecdciepmteanbtiwliitlybcrei:tceorlilae,cttheedwwaittehraovstearilayleisnsgsttheeslasmcpoloepawinldltbreasnsifpehrornedetdofraom certified, pre-csalmpeleaconntaienedr. Tominimize exposure oairbomecontaminants,thesediment willbenotbe homogenized inthe fieldbefore beingtransferredtotheprecleaned,certifiedcontainers. n Scoop sampleswillbeconsideredacceptableifthescoopisremains 50%filledaterbreakingthewater surface. Giventhedifficultyof obtainingundisturbedsedimentinareaswithexceptionallyfinesediments,these s`tacacnedpatarbdislmitayoyfhaalvlegtroabbse,arnedlatxheedfouvretrhaelrl,cTonhdeitfiieolndotfeatmhelgeraadber(w.i.ll"mslaikgehtthoevefripneanledtercaitsiionoonrneognaerdsiindge") willbedocuomn tehesnamptlineglodg. 11.42SedimentQuality Control Sedimentqualitycontrolsampleswil notbe preparedinthe field. Rather,bulksedsiammpleeswnilltbe shitotphelpaboreatodry. 11.43SedimentSampleShipping Placesamplesincoolerswithicetomaintain cooltemperature. Fresh iceshouldbeaddedtothecooler inpreparfoarsthiippoinng. 115 Publicly-OwnedTreatment Works 1151 POTW SampleCollection Influeat,effluent,andsladgesamplesvillbecollected a the POTWs.It santicipatedthatBattelle : p`preorvsiodnenedlinwiSllOPoMt3b-eFgr-a2natneddwaiclelsbsetporotvhiedPeOdtToWpsl.anWtrpietriseonninelntosachticfrvoercsuoammpcpalrteacbolilelseaoctmipnolniasnrge: . techniques. Sampleswillbecollectedandshippedaccordingtothemethods describedfordrinking water & samples(Section 113). 000464 QualityAssuranceProjectPlan Midi-City Study Sampling Task (N100666) Revision No.1: Effective Date: May 14, 1999 r-- e ----------------A-- A 2 . 11.52 POTWQualityControl `One fieldspikewil bepreparedforthe POTWefflucatsamplecollected a cachsteasfollows: 1. Theoutsideofthevialwillberinsedwithhighpurity methanol(HPLCgrade)andwipeddrywith 2 Chemwipe. 2._ tThheescaamppolfetchoenstapiinkeirn(gmsaolrukteidonwviitahlawinllefbeournaspcprroexwiemdaatnedltyahe1coLqnutaennttistoyf)t.h vialwillbe pouredinto 3. Thevial thatcontainedthespikingsolutionwillbedroppedintothefieldspikesamplebottle. 4, oThfethbeostptilkevesiolllubteicona.ppedandthenshaken,and invertedseveraltimestoassuremixinganddispersion. Nofieldqualitycontrolsampleswil becollectedforinflucatorsludgesamples. 1153 POTWSampleShipping `Placesamplesincoolerswith icetomaintain 2cooltemperature.Freshioeshouldbeaddedtothecooler inpreparfoarsthiippoinng. 11.6 LandfillLeacheate Pp. sLaanmdpslielsll(eSaecchtaitoens1a1m.p3)l.esNwoiflilebledcqoulalleicttyecdobntyrtohlesmaemtphloedswsiulslebdetporceoplalreecdt.andshipdrinkingwater ~~ 117 Food dIinectaacryhicnittaykiedOenftiFfiCebd,yrleopcraelsreenstiadteinvtesf.oTohdseaimnptlenetsowfitlhibsesacomlplleicntgedti otopdreotveirdmeianneetshteidmiaettiaornyoefxtphoesures o`pfrroecseisdseendtslwociatlhlyionrcraecghiroengailolnyabraesperdeofenrrteydpi,chaolfwoeovdesr,ciotnissurmeecodg.aiIzdeedatllhya,tfsouocdhspgrroodwunc,tspmroadyucneodt,alorways ' beavailable. "rTehperefsiesnttistnegpduifpfoenreanmtirveiginoginanlrtehtedaielscignhataeidfcpiiotsysniwbilslel,bIetnosiodmeenctiitfiyetsh,irtemlaocyalngortobceepryostosresst,cioaidbcehnltiefy tphrreefeerdeinsttiianlcltycohvaeirnssm;atlwloesrhcoounlvdebnieeindecnetsitfoireedsaotr sapmeicniialmtuymf.oLoadrsghoeprssasutpheeyarremmwoiarlelrbliekkseelelytetocthseadveall ofthefoodtypesrequiredandaremorerepresentativeof thetypical consumer. Samofpalllproeducsts identified forevaluation willbepurchasedincachstore. Aresgpiorneavliloyuassliysntdaitceadt,eadnonepffaocrktwaiglilnbgelambaedlseotroopnusricghnassoerprloadbuecltsspporsotdeudbceydtohreprertoacielsessetadlbolciaslhlmyenotr. Ifa localorregionalbrandofaspecificproduct cannotbelocated,thanthenextclosestlocationforwhich productsareavailablefortha foodtypeshouldbeselected. : TFhoeordepfroordu,cntastsieolneaclbtreadnsdhso,uslpderceipalrteysoenrtigtoeumrsmetthfatowoodsuolrdbberpanudrscshhaosuelddbbyetahveoitdyepidc,ualncloensssutmheery.arethe onlyproductsproduced locallyorregionally.Whenselectingfieshfood (e.g.meat, uit,milk,bread S reitpc.e)nefascst)osrhsonuolrdmbaellcyoncsoindseirdeedrtedobeynstuhreectohnatstuhmeesra(im.pc.l,efastrceopnrteesnetn,tdaattievepoafcktaygpeicda,l cgeonnesraulmaeprpepaurrcahnacseeso.r 000465 QualityAssurance ProjectPlan Miulti-CityStudySampling Task (100666) Revision No.:1 EffectiveDate:May 14, 1999 Pa23g0/e30 `pTohsesmiebltehiondteorfmssaomfphlaencdollilnegc,ttiroansnshpoourltdadnudpplaiccaktaegtihnega.ctFivoiotdieistoemfstsheelteycptiecdaslhcoounlsdubmeetrarsaclnosseployatrsottehde cfhoeocdkiotuetmcsofurnotmecraancdhhsatonrdelsehdobuyltdbheecpllearckeinitnhseetpyapriactaeclmoaonlneresrf.oArfsheirppmenuttorthbeclaavbheobraeateonryms.adPeee,rtisshhaeble: sfhoooudltdebmeslsahbeoluelddwbietphatchkesedtweictihtsy,uftfhiecsiteonrteIicDe ,taonendsuaurneitqhuaetIthDe.y TwihlelSniottesLpooigl eannrdosutae.mFpoloifdponrrogmduwcitlsl linkthisinformation tothestorelocation(address),thefood brandpurchased,andthe dateofpurchase. 117.1 MeatandFish Fromeachstoreideatified,meatand fishproductswillbecollectedforanalysisasdescribedbelow. Ap1p.r7o.x1i1mateFlryes1h1MboefatthPefrooldluocwtisngproductswillbeselected fromthemeatcounter: Groundbeef Pork chopswithbone (-2) = Wholechickenbreast(2 -boneless,skinless) ``Qpuaacnktaigteiessaivanidliacbaltee.dIanrdetihetmiiontniomquuamnrteiqtuyi,rceonmseiadtesr;avtairoinasthioounlmdabyebgeinveecnetsostahreyddaetpeeinnddiincgaotendtohnethe oo farbeeslh,aansdweoltlhaerswtihseegreenperreaselnatpapteiaveroanfcteypaincdaflactocnosnutmeenrt(p.ur.c,ha1s5e%s.orIlfepsre)-opfatchkaegperdodpurocdtucotcsaasruernetohtat tis 7 ahvaainldalbeldei,tnhaemsapencniefriceodnasmiostuennttswsihtohtulhdebacetrievqiutieessteofdtfhrotmytphiceacllceornks.Aumlelr.packagesselectedshouldbe Athsipsirnefvoiromuastliyodnicsacunsnsoetdb,aedneetfefrormtisnheodubladsbeed moandaetreoviideewnotifftypherloadbueclt,siptrmoadyubceedpoorsspirbolceetsoseiddelnotcifaylltyh.eIf `rsouercecthiornoturhgehcldogoebonodk.vIefthrweistsohusratcoertoefeimapvaloiolynaebelsseb.rAanndysicnafnonromtabtieoindeonbttiafiineeddithnrtohuigsmcaintnheerrsehvoiuelwdobfe the packaging ordiscussions with thestoreemployees,thegenericbrand shouldbepurchased. 117.12 ProcMeeastPsrodeucdts tOhneegpraocckeraygsetoorfeh.otAdpogso(i.c.r,apmipkxrtouxr-iemiastbteloybee1pIrt)ecfsehrarflelbd.es1etlselcitkeedlfyrtohmattnhuemperreopaucskbargaenddsdoelfihseocttdioognsof iillnbeavfailaoavbalierl;apbrlemefeornaetnhceetspahcoikualgdobeeangbievle.aItnotbhreanevdesntthathtaatrelpocraolcbersasneddslaorceanlloytaavsadileatbelmen,isneeldebctyitohne shmoaunlndebrebcaonsseidstoenartewliatthitvheceoasctti;vgietnieesroicfbtrhaendtyspaircaelpcreofnesrurmeedr.A.llpackagesselected shouldbebandledin 11713 Fish Fishrepresenting alocalfisheryshouldbeidentified fromthe ishcounterin eachstore. Inselectingfish, ionrfroergmiaotniaolnfmisaheyrnieese.dFtiosbheobotbatianiendevdifraoamcoamsmteorreciclaelrfkitshoerdyeaterrempirneefewrhaibclhei,hsomwoesvterre,pirnetsheentaabtsievneocfeloofcaal ~ ldocaelcpomemeornncaivdaalifliiasbihnleirtgyy,.fFiishsrhafiseidolnarleaplroeecfaeltrirseshd;fhaorwmeavreera,cicnetphtaebalbes.eFnicseohmfafyilbleetsfrwohzoelnefoirsfhrmesahy,be & sctoalnldecatreddp.roAcmeduries (nc.o5.f,i1weIibmgihserdeuq,uwirrmaepdp.eTdh,eecf.i)sphrsihoorutlodpbuerchhaansdel.eAdlblypsatcokraegpeesrsseolnencetleadcschoorudlidnbgteo handled in amannerconsistentwiththeactivites ofthe typical consumer. 000466 Quality Assurance Project Plan MultS-tudCySiamptliyng Task (N100666) EffctiveDate:ReMvaisyio1n4,No1.9:991 Page 24030 je 11.72 Dairy andEggs `A$croamrtthoenodafirgy ssec(t1i2o)naonfdca1cqhugarrotcoefrwyhstoolreem.iAlskpirnepvliaosutsilcoydricsacrudsbsoeadr,dapnaecfkfaorgtisnhgosuhlodubldebmeaodbettaoiindeedntify tphreodluabcetls,pirtomdauycbedeoprospsirbloetcoeilsdoecsnatleilfydy.thIefstohuisricneftohrrmoautigohcnocnavnenrosattbieodnestweirtmhisnteodrbeaesmepdlooyneeasr.evAienwyof `icnafnonromtabteioindeonbttiafiineeddtihnrtohuigshmeaitnhneerrresvhioeuwlodfbtehreepcoarcdkeadgiinngtoherldoisgcbuososkio.nIsftwhietshotuhrescteoorfeaemvpalioyleabsr,batnlhdees genericbrandshouldbepurchased. Inaddition,thedatesindicatedonthepackagingshouldbe consideredtoensurethatthe productisfresh. wv 11.73 Produce : Freshandfrozenproduce(i.c.,fruitsandvegetables)willbe collectedfrom eachstore,asdescribed below. 1.73.1 Frozenvegetables Onepackage offrozengreen beans(i. approximately11)shallbeselectedfrom thefrozen food `sebcetainosnwiolfltbheeagvariloabclseet;oprrreey.feCruetngcerseheonubledabnesgairvepernetfoebrrreadn.dIstthias tlaikreelpyrtohcaetsnsuemdelroocuasllbyraasnddestoefrmgirneeednby tShheoiuldbnebafsedoaovanirrlealbalmteiovenactohstet,pgaecnikearigoceblraabnenld.sIanretphreeefveerartetdh.Aaltllopcaaclkbargaensdssealreecntoedtsavhaoiulladbblee,hsaenledclteidoinn `2mannerconsistent withtheactivitiesofthetypicalconsumer. : T11w.o7f.3r.e2shaFpprleessh(pr1odIbu)csehouldbeselectedfromtheproducesectionofeachgrocerystore,Selectapples `bbrausiesdeosonrgoetnheerraldapepefartaehnactcew,oftruelssdhnreesnsd,erolthoerseatmc.plCeaurneastthroaucltdibveettoatkheenatvoearvaogiedcaopnpsluemsewri.tThhobevityopues of alpopglboeo(ki. ,Asgrparenvniyosumsilytdhivsecrussussemda,cainnetfofsohr)tisshnooutlidmbpeormtaadnte;thooiwdeevnteirf,ytphreotdyupcetssphrooudludbceedorercporrodceedissnetdhe lorcalely tchironouthgrehncdoitteheebrosodikg.nIsotri lraebceolgspnoizsetdetdhbayttmhaensytoorfet.hTeheloscoatuirocnessopreocriifigeidnaorfetnheoatpwpiltehsisnhroeuglidonbseof ltohceacloluyintsruynclioknedluyc,piavrettioctulhaerglryionwtthheawnidnptreordmuocuttihosn.ofapples.As aresult,findingapplesproduced 1174 Bread Breadproductswillbecollectedfromeachgrocerystoreasdescribedbelow. O1n.e7.l4o1afof bWrheiadtsehborueladdbe selectedfromthebreadaisleofeachgrocerystore.White,pre-slicedbreadis `prefaerrvedo.aPnrteihfeelrpeancackeasbgheollualbdeelb.eIgnitvheenetvoebnrtatnhdasttlhoactaalrberparnodcseasrsoendolotcaavlaliylaabslei,nsdeilceactteidobnysthhoeulidnbfoerbmaasteiodn o`ncornesliasttievnetcwoistth,tahnedagcetinveirtiiecsborfatnhdesatrypeipcraelfcerornesdu.mAelrl.packagesselectedshouldbe.handledin amanner O1n1e7l4oa2fofOorrggaanniiccaalllylgyrporwonduacneddpbrroeduacdedbreadshouldbeobtained.Inthe eventthat organicbread is % " localnly oas dteteaorrmgivanneidacbfyliotuhrelmianafyobrebmasutlbisotnieatvuta,eidl.abPlreeofnertehaecepsahcokualgdebleagbeil voertthrooaubgrhacnodntvheartsiastpirooncsewsistehdthe Store personnel.Intheevtehatnloctal brands are not available, selection shouldbebased on relative: 000467 QMuiaulli-tCyitAyssSurtayncSeaPmrpoljiencgtPTlaasnk (N100666) Effective Date:ReMvaisyio1n4,N1o9.9:|9 Page 250f30 : tchoseta;cgievnieireiscobrfatnhdestaypriecparlecfeornrseudm.eArl.lpackagesselectedshouldbehandledin amannerconsistentwith 1138 FishOtherthan Food 1181 Finfish (Electrofishing) iAnstthreevaicinrietaycohsfhtohuelsudbrfeadceeswiagtneatrseodfurocresoamfpdlriinngkibnyg wfiaetledrp,earnsdonaleslo.sThohueldrieancchlsuhdoeuhalbdibteaatdsjpapcreonptrtiaotoer sfeorttahtetthaerugpesttsrpeeacimeasn(did.o,wpnesrtcrheaanmdeblnudesgoilflt)h.eInretahcehparbiseonrcteoothf pinhiytsiiactailobnaorfrtiehres,abnlyoscakmnpeltisnsghaocutlidvibiees. Seiningmaybeused asanaltemateorsupplementarymethodforcollectingfinfish. 11811 Method bAesttarkeeanmorfetahcehsoarmppolnindgshsotueladbndetdhesliogcantaitoendsfhorosualmdpbleirnegcboyrdfeiedludspienrgsaonaeald.DhieglidtGaPlpSh.oTthogerrapehaschshould sShhoouullddibnecaldujdaehcaebnitttoaotraippnrtohprviiactienfiotrythoefttahregaertaspeicniwehsi(cLhc.thpeewractheransdabmipulcegsilb)a.veIbnetchenacoblsleecnteocdafend p`hysincalboiafraentsy,saabmlpolciktnngeatscosthvoinuilsd.besetattheupstreamanddownstream adsofthereachprior o the cOrnecwemtehmebbelro,cknideetnstiafriedsaes,tehleeecltreocftirsohfiinsghmeraynibteogpiernaattotrh,ecdaoswenssttrheeabmaclkipmiatcokfutnhietsaanmdpmlaenriepualcaht.esOnthoe = 75 aarneoadceoavenrdacgaet.hTodoepmoalxeism.iAzseividseitboilsiitdyeaonrdbsaunbskteqoubeanntkssawmepleipnigncgftfeccihcnaicqyu,ecsahcohutledabme umsecmdbteormsahxouilmdize a`wnedarflpoolwa.rizedsunglasses,andsamplingshouldbeconductedonlyduringperiodsofoptimalwaterclarity A"TLherfieshmamientiendgcshroeuwldmbeembplearcsesdhionubludcfkoeltlsoowtrhieveelewcetlrlosffiosrhfeururnthietropeexraamtionraatnidonneanttdhiedefnitsihfwiicatthidoni.pnUeptos.n etxhceecpotmbpllueetgiiolnlonfdspameprlcihnrge,tucamcehditsohtchoelsltercetaedms.hIonutlhdebeeviednetnttihfaitpedewricthharnedgabrlduetgoislpleacrieensoatnadvaaillalbplee,ciacs Similar,substitu specieswillbe identifiedbythe eldpersonnel. Ahingahl)tmearnyabteefuisshecdoflolreccotliloencmteintghfoidnmfiasyh.iOnvnoleviendaisvmiadlualmlweislhlw(ae.dg.et102m2dme)pstehinofe 1(1m0amnldownaglbkypa1ramlel teontchirecylsihnograenlyifniesfhoprraedsiesnttainnctehoatfl~oc2at0imon..TFhiesnh,wbioltlhbiendpilvaicdeudailnswiblulckaeutlftohrefnuerttihneroextahmeisnhaotrieolnianen,d identification. Itmomweedl.iTatheelyyuwpiollnbceapptluarcee,deiancoh fasisehpwairlaltbeeZKiipllloecdpblyascteircvbiacgaladnidslsoecaalteidownainthdtwaippee. dEdarcyhwbiatghwaiplalbpeer slaambpelleidnwgiftohrtmhsetciottyheacnodllsetcetIiDonaprnodceaduunrieqs,uesspaemcipelsenIaDm.eTahnidsrielantedfsamoplwriinlgmlibneafolritmnkaetidiooonn.tFnhieshwill b"eThpelicaecewdiolnlbiecerienplaaccoeodlweirtfhofrrseasmhie-dapryiosrhtiopmsehnitptpionBga.ttelle'sDuxburylaboratory forprocessiag. i 11812 Datarecorded . = anFidshtucmoollresc)t;edalwl obisbeercvolautnitloend,vielxbearecmforoidreednxitneetmhdaelfiaenlodmlaolgibeoso(k..cF,isdhefloernmgitthieasn,dewreoidgehdftinwsilllelssioonsb,e recordedtothenearestmmandg,respectively. Thefishcollectedfromcachstswillbeweighedusing 000468 MuQulaltitCyiAtsysSutruadnycSeaPmrpoljienctgPTlaasnk (N100666) . Effective DatRe:evMiasyio1n4,No1.9:9|9 Pa26gofe30 ~- husainndg-haelfidsbhamleaanscuertionegnsbuoraertdhaastrtehqueitriessdbueymtahsescoislaldeecqtiuoantpeefromriatn.aTlyhseisst.aFritsthilme,eendinwnigltglibmeet,mdeuahrsautriseondof a`lssamopilnicnlgu,daensdaemsptliimnagtecdonmdaitxiiomnsusmuacnhdamsivinsiibmiluimtsytarndeafmlwoiwdrtahes.wil alsobe recorded. Commentswill 11813 SpecialPrecautions Aolpelraftieilodnteparmocemdeumrebseirdsenmtuisfitebdebtyratihneedmaonrubfraicetfuerdeirn.tEhaecehletcetraomfmisehminbgesrafmeutsyptrbeecianustuiloantseadnfdruonmitthe wcaotnsetrraunctdetdhoefeilnescutlraotdiensgwmiattehrcihaelsstw(ca.dge,rwsoaonddsr,ufbibbeerrgglalsosv)e.s.EElleeccttrordoeafnidsdihpenertsh/mauendsllteebscmetueqsrutoibdpepeesd withfunctsafietoyswnitcahels. 12. SAMPLECUSTODY 12.1. EvideChnaitnoifCausrtoydy BcautstteoldlyefpireolcdeadcutirveistairesewdielslcbriebceodnidnucStOePdt6o-e0n1s0uarnedthianctlaufdueltlhpearpeeqrutirraielmeexnitsstfsofroercviadcehnstiaamrpylceh.ainSoafmple `tcurstoadynwashnicdphsitosodrreafgtieneodfaa ssA sapecbiem aldtoycppuemoeflnstaeme dpilnecwuristtiondgy. wThhiecrherceoqrudisremsusthtaat tchepchyofsoiurcaatllpopsesreisosdisoonf, tlhiemseafmrpolmescaumsptloedycroenqtuaiinreermeacaqtusifsoirttiohnistphrroojuegchts.ample disposal. The followingkeyelementscomprise - Batellesfull-timesamplecustodianwillberesponsibleforthecustody recordsoftheprecleaned botles. + Orneemsepmboefnroosrfseiaambcphllfeiceeulsdtteodaymawnidlfboerdmeasiingtaniantiendgaasltlhesatmepalmescuasmtpoldeycruesctoorddisa.nandwillbe The thatcaursotroecdeyiovfedebacyhtshaemlpalbeobraetgoirnyscwuistthodtihaenreacnedirpetlionfqpurieschleeadnteodt,hceerftiieflidedcu(sEtSodEi)ans.amplebottles ItPiUsFtchleeraensipnogn.siMbaitleirtiyaolsfBraetcetilveeadiirnatnhaelyfsiieslldsahbopuelrdsbonenlealbteolmedasiuntcahitnhraectohredusnoiftascirafniblteetrarancded backtodocumentedcleaning proceThedfuielrdcuestosdi.anwilleczivecustooftdheyse: Thecustodian is responsibleforthecustodyofallmaterialsreceived(signedfor). Samplesare contosbeiinadperseon'rscusetodydif ~Thesamplesarein person'sactualpossession ~Thesamplesarein aperson'sviewaterbeinginthatperson'spossession -Thesampleswerein tampering aperson'spossessionandthenwerelockedorseal.edup to prevent ~Thesamareipnalsecuere asrea The samplecollection formwilldocumentthecertifiedbotlelot numberand,forsi samples,the & clealontniumnbegr. Any docufmieenltdeedq,uiinpcmleudnitdnegccolnetaanmiinngoatfifoonilpuesrefdotrmoewdprraiposratmopltehsec,ocltlse.ctionof asamplewillbe 000469 MQuaalitly AtsSstu-ruadCnycSeiaPmrpotljieyncgtPTlaasnk (N100666) Revision No.: 1 Effective Date: MPaagye 1247,o1f93909 Tfhoreanlaolcyastiisownoifl abcehtsraacmepalbleectohnrtoauignehtrfhrecoumstroedycreeacitorptdhtse.laboratorythroughshipmeatto Battelle: Torhieginfiaellsdcaumsptloidnigafnowrimlslirenliasnqcuailsehdtphleasstaimcpblaegsinwshiednetchaecyhasrheipppaicnkgecdofnotrasihnierp.mTehnteanfideplldac the `custodianwillretain acoopfyal samforpmsalndtihesnhippgerscopyoftheshipping bill nthe SurveyLogbook. 122 Sample Shipping wSillbaepwamicklelbp dionshlciopopleeedraswts itthheiecnedaonfdcbaucbhbcloelwlrzepcstuifdfoainycifeonrtnteoxetn-sduaryetdhealitvdearym.aEgnevwiirlolnnmoetnotcaclusradmuprliensg d"haimpapgien.g.TNhono-spaemrpilsihnagbfloerfmo(osd)s,wwihlilbchesshhoiuplpdebdedsrcyailnedcionolZeirpslwoictbhasgufsfaincdietnatpbeudbtboltehwerianpnteorpirdeovefntthe `l`ococotlrero,sThhocekceodofilsehrasrtehsehnitpappeeddtsohKuitamnAdntdhreeawdsdraetstshleaabdedlrsaetstsalcihsetde.diAnlTlasbalmepl8e,sEexlceecptttrheoshfoicshkaerds `S2enndtatloerMtre,dtMoitchheadeellMiveearryadaatttehaenaddtdirmees,stlhisetenduimnbTearbolfe c8o. oMlesrs.bAenidnrgeswhsipapnedd,Mtrh.eMneuamrbaesrhoofuclodobloercsa,lalnedd the numberandtype ofsamples. SOP M3-E-5 defines sample shipping procedures for the project. 13. CALIBRATION PROCEDURES, REFERENCES, AND FREQUENCY o 131 PS AirSampler uTshiengPSa-G1eanierrsaalmMpeltearlwsilGl4b0eCaclailbirbartaitoendkaitc,ccoornsdiistntigongSoOfPacMa3l-iFb-ra1tiiomnmeodriifaitceelayndparmaitnoooumsreeteinrt.heTfhieeld c`suarmvpel,ewhheiacdhbwrialclkceotnsttahinetaaPrgUeFtaednadirfiflltoerwdourfi2n5g0thlietecrapliebrrmatiinountper(olcpems)s.,wiAlmlbeugenlerptoaitneitdcuaspliinbglrtahteieonpm $Trhoemctalhiebcraaltiibornaotriiofniocreiwfiiclelbgrearpehmvoevresdufsrtohemitnhcehseasmopflweartaefrtfrrcoamltibhreatmiaognniashceolmipclgeatuegde.Tohnetchaelsibarmaptlieorn.is considered acceptableifthe calibration points are within 10%ofexpected. Ifapoiisnnott within ths range,theoutlyingpoint orpointsshouldberepeated. 132 12XLGlobalPositioning System "T`ShOePG3a-r1m6i4dneGscPrSiwbeisltlhbeecchaleicbkraetdifono,rorpeelraattivieopno,saintdiomnaailnatcecnuarnacceyoofntcheeaGtacramcihncit1y2.XLThhaend-held GPS. Jactoiotruddien/alteosn.giTthudeeccoooorrddiinnaatteessfforrotmheakknnoowwnnloorccahtairotnweidlllobcaeticoantewrieldlibnetcotohmpeaGrPeSdwaistahwtahyepoGiPnSt(i taosctcabofwoiirtrhltmdhiienuuzatseeesrn.mTahncueaGle)P.STchoeorGdiPnSautneiswtiwlillblbeerheaconrddceadrtroietdhteonteahreeksnto0w.n01liocnatthieosnuarnvdeayllloogwoend wnayapoivnti).cgThheacekdtilsoitgafnoocrenma.nTdhbeeasreicnogotroditnhaeteksnwoiwlnlbcoeorcdoimnpaatreseddtisoptlhaeykednoonwtnhceoGoradrimniatnecso(menptaesrsepdaagsea wrielaldbinegrtehactoridswediitnhithne1s0u0rvmeeytlerosgoof nthtehaecntauvailgaptoisointicohnetchkelntohgfeomramn.uaIlftshheoGulPdSbuenictofnasiullstetod afotrapionssaible: soursof orand the rferencspsifionverified 000470 MQuaililtyAtssSiutru-adnyCcSeaiPmrpotljienycgtPTlaasnk (N100666) Revision No.: | EffectiveDate: PMaagye124,801/93909 14. ANALYTICAL PROCEDURES ProceduresforanalyzingsamplescollectedunderthisQAPParedescribedunder scparatscover. 15. DATA REDUCTION, VALIDATION, AND REPORTING `No datareductionwillberequired toreportthe resultsof the fieldactivities. 16. INTERNAL QUALITY CONTROL CHECKS AND FREQUENCY Acceptablequality controllimitsforfieldspikesamples,field blanks,andfieldduplicatestriplicatesaro `documentedunderseparate cover. 17. QUALITY ASSURANCE PERFORMANCE AUDITS, SYSTEM . AUDITS, AND FREQUENCY tQhueaplriotyduacstssugreannecreaetnecdo,mapnadstsheessaelrvpilcaensnpeedrafnodrsmyesdtbeymaBattitcealclteivmieteietscnoercpeosrsaatreysttoaandsasrudrse.mTahneapgreimmeanrtythat fe t`hmeecQhaAniPsrmogfroarmaancdicsoefmfecpttilvheinsiegsossa.lDhiusriaiunndgitgasn.aAuduidti,tstrheefaegrrteoetmheenftowrimtahlaQsAsepsoslmiecnytdoofccuomnefnotrsma(en.cge.to ~ `SinOcPrsea)siesaewvaarlueanteesds,adenfdiucnideenrcisetsaanrdeiindgeonftifQiAedp,oalnicdiceosrraencdtpirvoecaecdtuiroens.istTahkeefn. oIldleaQouAdwaiatusdialiltnssloasgreeyrve,to `planned for the sampling program. A thtaetcthhneisccaolpseyostfewmo(rikniatniadtailolnr)eaquduiitreisdceolnedmuecnttesadarespaadrdtreosfstehdeardeevqiueawtoelfyt,h(i2s)vQeArPifPyttoha(t1)aelnlsure rqeuqauliirfeicdaStiOoPnssaanrdeadpopcruomveendtaenddtcruarinrienngt,taonpde(rf3o)rtmo vteheriirfyatshsiagtnaeldlptaarstkisc.ipAatnttshheatviemteohfetrehqeuired anptriecpiapraattieodntohfattthhsesQeAwiPlPlbscevefrianlalSizOePdsprairoretboeitnhgefdiesvetsluoprevdeyf.or the field program. Itis The * activQitAeOsfafriebceeriwniglclopnedrufocrtmedaafnidelddoicnusmpeecnttieodnafcocroeradcihnsgutrovtehyetQeaAmPtPoavnerdiafsystohcaiattseadmpSlOiPnsg. The survey reports will be reviewed for completeness and accuracy. 18. QUALITY ASSURANCE REPORTS TO MANAGEMENT Rerseapolrttss woifllQdAeafuidnietasnwyilerlrboersr,epdeofritceidetncoitesh,eoSradmepvliiatnigoTnassfkrLoematdheerQaAndPtPhaenPdroSOgPasm.MaTnheagreesrp.oTnshieblaeudit . `amnaanlaygsetrdfoocrurmeevniteswtahnedcoarprpercotviavle.acTthioenPornogtrhaemaMudaintaregpeorrtmaunsdtsaupbpmriotvsetahlelaauuddiittreeppoorrttroestphoenpsreosgbrefaomre oond dataarereleaassfienadl. Any deviationsmustbedocumentedandreportedwiththefinalsurveyreport. 000471 MQuuadlii-tyCiAyssSutruadnycSeaPmrpoljienctgPTlaasnk (N100666) Effective Date:ReMvaisyio1n4,N1o99.|9 Page 29of30 - 19. PREVENTIVE MAINTENANCE PROCEDURES AND SCHEDULES 191 Air Sampler "Tshaemapliiensgahmepaldeawtillll mbeekseputininsthpersoatmecptliivneghappoaratuwushseisnbneiointgninruesagedi.eTdhfoerpsarmploe ctocloleevcetircoins.tkTehpietosvnirthee Samplers cleanedbetweensamples asfollows: - 1. Disassemble th samplingheadprior tosample coletin. 2. Wciarpveidoguet.thesampling headwith aKirwipewetedwithmethanol pictoinsallingthglass 3. chaertcrkidgteomseaakt.esurethatthegaskets ar insidethesamplinghead athe topandbottom ofthe 192 Global Positioning System "ITahbeorhaatnodr-ybpeelrdsoglnonbealltphoesrittihoanninrg seysptelmahacsofenbomamtaetiennrtste.naAnlcle tprhoecremdauirnetsetnhaatncaenibpe eperrffoormrebdmybteyhde manufactures. Pp. 193 Young Grab Sampler "dTehieonriazbedswaamteprlaenodrrailntseerdmawtiitvhemteatlheasnolstbeeetlwsepeonosnaomrplceos.op) willberinsedandscrubbedwith 194 Fish Measuring Apparatus b`eThcelbeaalnaendcweitahndamiesthhmaenaoslusroisnkgebdoaKridrusweidpetobweetiwgehetnaenadchmesaasmuprlee.ish afe electroshock collection wil 20. CALCULATION OF DATA QUALITY INDICATORS "aTnhdeecraslecpualraattieoncoofvdera.a quality indicators will be addressed in the analytical QAPP that will be provided 21. CORRECTIVE ACTION rAolulttiencehpneicraflorpemrasnocnenoefl sthheairdrueisspo.nsMisbi.ltMyarfcoriaidNeinsthiifoykisn,g nBdatreaso'lvPirnogjepcrtobMlaenmasgeern,cowuilnltebreeadcicnotuhnetable "an{do thtelchinnictalnpdertfoorBamtatneclele. mSahneagisermeesnptonfsoirbolveefroarlidceonntdifuycitngofatnhdeepsroclevcitn,gipncrloubdlienmgsthtatschhaevduelneo,tcobsetesn, (5)| andecdersessisteadtetcimhealnygeosr sinutchciesssCuWlIlyQAatPalPo,woersrelqevueilr, cinofnlsueunlcaeomnulwiilheBcaotmlploenemnatnsagofetmhentproojewcti,th the "diem Problems identified by the QA Officer will be reported and corrected as described earlier. 000472 MQuaalittyAissSu-truadCnycSeiaPmrptoljieyncgtPTlaasnk (100665) Revision No. 1 EffectiveDate: PMaagye134,01093909 22. REPORTS Osnamepllietntgerlsoucravtieoynrse,pono-rstivtielslabmepplrienpgaorbesdefrovractiaocnhsc,iatnydsaurnvyeyS.OTPhoerrQepAoPrPtvdievlialitsitotnhse,scfacm.plTehsecfololremctaetd, ~ `willbe deaticaltothepilotstudysurveyreportsubmittedinDecember 1998tothe ProgramManager. - 23. REFERENCES iEnPAAm,bi1e9n90t.AiMr,eStehcoodnTdOSLu3p,plCeommepnet,ndUiSumEPoAfM,eRtehsoedarsfcohrTtrhieanDgelteePramkin,aNtiCo,noEfPTAo-x6i00c/O4r-g90a-n0i1c0C,oMmapyo,unds 1990. : 000473 APPENDIX A Outline for Multi-City Study Survey Plan 000474 QualityAssuranceProject Plan MiltStuidy-SamcpliingtTaysk (N100666) EffectiveDate:ReMvaisyio1n4,No.1:9991 Page 4-1 het Survey Plan Empirical Human Exposure Assessment Multi-City Study Sampling Task 1. GENERAL INFORMATION Project Tide . ``OPrrgojaencitzMatainoangReesrpaonndsiSbulrevfeyorTSausrkveMya;naAdgderressandTelephoneNumber 2. OBJECTIVES 3. SGeCnHerEiDcUsaLmEpling schedule TheCity SurveyPlanwilldetailthesurveyscheduleforeachsurvey loop 4. GeSnUeRrVicEdYesLcrOiCptAiToInoOfNsSampling collectionlocationsandmaiccs The City SuPlranwivllde etailythespecificsampling locafotrcaichomantrisx,includingaddresses and contactsacach location on 5. SURVEY/SAMPLING METHODS or `The QAPPwillbereferenced forallmethods. 6. "SThEeQstUeEp-NbCy-EstOeFpsSeqUuReVncEeYofTsAaSmKplSe/cEolVlEeNctTiSonandqualitycontrolpreparationwillbedetailed. 7. TNhAeVuIseGoAfTtIhOeNGPCSOwNilTlRbOeLdescribedgenerically. "TheCity SurveyPlanwilldefinespecificcalibrationinstructionsforeachcity. 8. CEhQecUkIlPsMtENoTfeAxNpeDndaSbUlPePaLnIdEnSou-cxpeadablesuppli. eswillbecreated. Solvent and wastecontainmentwill be addressed. 9. QDeAc/onQtCamPiRnOatCiEonDpUrRocEeSdures will be described `The QAPP will be referenced 10, HEALTH AND SAFETY CHECKLIST 11.TShUegReVnEerYalTEreAquMirementsfor asurtevamewiyllbedefined. . . "TheCitySurveyPlanwilldefinethespecificsamplingteamsand TeamLeadersforcachcity &= 12.TRhEePcOonRtTeIntNsGoRfeEaQcUhsIuRrvEeMyErNepToSrtwillbedefined. 000375 ~ APPENDIX B Examples of Requests for Permissions - 000476 DraftQualityAssuranceProject Plan MultSitu-dyCSaimpt linyg Task (N100666) Revision No.: 1 EffectiveDate:May 14, 1999 Page B-1 " w%eBraale fBatioelle Vink VIAFACSIMILE February 25,1999 ime ie _ Dwbuy,Masschustis 02332 Tei: "Telephone 781-934-0571 Columbus GeorgiaFireDepartment ColumGbAu31s90,7 Cprrcnoe -- hneee y-- escat CpaSci oktmektvil stl.AtslperWoocromPmaoni,sLod placeanoutdoorairsamplerat afirestationinthe citytoobtain arepresentativeairsample. te wd het selecaio 12 sting ht3p fms, Wie avesl te `stationas a samplinglocationbecauseitis asecurefacilityandpowerwouldbeavailablethroughoutthedayand TP boos abe @ `epvoewneirn.g.ThWeeawiirslalmbeploenrspiutemfporisspetr-ougpraanmdmteadkteo-hdaolwtnaotpetrhaetcioonncsl,uasinodnsoifmtphley1r2heouqrau snaamve paliis lnagbptleer1i2o0daVnoduwtileltlfnoort appro3.5xfoi ot hm ighaant d 1.e 5folotbyy 1.5foot. yw dcoBle avyponsnitscpinta llseni rs. My particulardepartmentconducts avarityof environmentalsamplingandanalysisstdics throughoutthe U.S.and Co wasFhpspoor investigation, wehavestatisticallyidentified asetof citiesthroughouttheU.S.wherewewouldliketocollect a peat cok on br spt. regulatedby EPAnorisit listedas ahazardouschemical.Theplannedanalysesarespecifictothisinvestigation only.Theresultsoftheseanalyseswillbecombinedwith rawmaterial inventories,releaseinventories of manufacturing facilitiesandinformationonproductconsumerstounderstand thelifecycleoftheseproducts. B l ugfmftoiEipveSm yofebte ieeidiia osn no,7et nCTmpe eintoyveeorleoffMooaclohtvy19o9,pientthsyouoWvpee orPn,dewee `canhavestaffinschedulethe ripappropriately.Ifyou haveanyquestionsconcerningthsrequest,pleasefeelfree GoC eC gal n mnb cc: DonaldGunster 000477 DMrualftit-QCuiatlyiSttyuAdsysuSraamnplciePnrgoTjaesckt (PNl1a0n0666) Foray 5,1 DeF Erxet cl maroon w%<Bativeeltleo EffectiveDateR:evMiasyio1n4N,o1.9:991 Page B-2 . L E -- DrmE o,m. Decatur,AL 35601-4848 Fox 781-534-2124 LF a =pgretdR efmnesyoonnot, k omekkvilheccoDDoecre,, AAsppeo rston mdeeooforly `shudgefrom yourwastewatertreatmentfacilityandinfluentandeffluentwaterfromthedrinkingwatertreatment `B{gattielilerisdotahsceuiUUeLnStSgi.,fmaihcndrdeetoshaerwucpohrooltdrdg..anCCiuzaaertnittonltyyhooantoceoofnfdoouucwirsclaivmeanrtssihtaysoalfseknedvdivrsontmoecnotnaddluicsttaaaLLimefepaCCynlcdlaeirnaanlnaylsiygissis ooff, In f2rospmecwihfiiccchhteomcioclallecctormepproeusnendttahtaitvseseavmepslaessoafmawraskteerwoatreoruarncdlidernitsnpkirnogdwuactetr..TThhisecseshampeleissmwnioltilrbeegcaulnaaateldlybzyfeodr ~4 "reEsPuAlntsoorfitshietsleisatneadlaysseashwaizlalrbdeocuoscmhbeimniecdawli.tThhrewplmaantneerdiaanlaInlvyesnetsoraireess,peecaisfiectiontvheinstoirniveesstoigfatmiaonnuofnalctyu.riTnghe oatgemirmetfa o opteben tga TALStTES Vatu tocollectthesamplesourselves,withyoursupervision,orprovidethe appropriatecontainers andallowyour staffto. Pl colthlese ampclets.Thesamples weareinterestedincollectingfromyourfacilitiesaresummarizedinthe [r vee|e T [e m= Wevont er ocll hsminmm vk=ofD| ene 1v ,197. [ W] ithyo go= sve mc il DGeconae Detceumbrer r 15,J199,8e ,Ifyouhaveany questionsconocrniag hisrequest,pleasefelfee ocontact Sincerely, * Room psoas ResearchAssociate 000478 . APPENDIX C Sampling Forms G 000479 Draft QualityAssurance ProjectPlan Multi-City Study Sampling Task (N100666) Revision No.: 1 Effective Date: May 14, 1999 Page C-1 a FINFISH DATA SHEET Project: N100666-01 Ee Efre ee pre [oo ass[m so | -------- rT TT 1 rr 11 -- rT 1 1 rT r T rT 1 1 rT rr 1 rr11 -------- rT 1 1 rT rT 1 1 rT11 CC 1 T 1 7] sigue pa, 000480 "Draft Quality Assurance ProjectPlan Multi-City Study Sampling Task (N100666) Revision No.: 1 Effective Date: MayP1a4g,e1C9-929 - AIR SAMPLE COLLECTION DATA SHEET Project: N100666-01 City: Sampling Site: Collected By: Air Sampler ID: PUF CleaningLotNo. Fler CleaLnoitNnog: Calibration: Calibration Orifice No: `TefaromdMagiaanbelgic| Inches ofWateron `Gauge on Sampler. Calibrator Orifice p r rr r rr 11 1 1 1 1 Maralgraph the calibration curve (Miagrahelic reading on the x-axis;calculatedIm on theis). Attach the graph tothissheet. & Sample Collection: o[ we 1| ([ Tme 1 777-- | FDaemimnigsTiemeMei(eFromgap) |[ |] | Total Sample Time, min = Stop ranning time meter value-Start running time meter value AverageFlowRate = (Determined Ipm at Start + Determined Ipm at Stop)'2 @ "ero Com) is dtmined rom he calbrsion ure 000481 MDrauftQtuailiSt-tyuAdCsysSuiarmaptnlcieynPgroTjaesckt(P1l0a0n666) Confidential Revision No.: 1 EffectiveDate: May 14, 1999 Page C-3 ~ DECATUR, AL - SURFACE WATER SAMPLING Lotion: Date: BottleLotNumber: CollBeyc(ftnteilds) Atotalofninebottles willbeused(seven 1Lwatersamplesand 2emptybottlesfor ieldblanks). Recorded by (Initials) MCH01: Surface water- Decatur- Site 1-PIN MC-102:Surfacewater -Decatur- Site 1-Total PFOS MC-103: Surfacewater-Decatur- Site 1-Field/Lab Dup-P MC-104: Surface water -Decatur- Site 1-Field Spike-PIN __ MC-105: Surface water- Decatur- Site 1-Lab Spike-PIN MC-106: Surface water -Decatur- Site 2-PIN MC-107: Surface water-Decatur- Site 3-PIN o~ < MC-108: Surface water -Decatur-Field Blank-PIN MC-109: Surface water -Decatur-FieldBlank - Total PFOS Example Labels: cewater Decaf PN Sie T= | Surface water "DecaturSie 1+ Total PFOS | SFuireflad/cLeawbaDtuerp-P Decatur SHE T= Face water DecaMfucr-1Si0e 11- |Surfacewaier-DecauMr-cS1ie021- | Surface water-DecatuMr-C-1S0t 3 Field SpikePN MC-104 Lab Spike-P/N MC-108 PN MC-106 SPurNface wer"DecatMSCut-re1037 |BS lankuPwNraierfDeacatMcurCF1ee0ld8| BSurlfaac~eTwnoattkearl PDReOcaSturMC-1Field09 SamplesshouldbesenttoBattelle Coluintmhebpreuseasceofice. Relinquished By: . Received By: Date: Date: Lejncluded: YN Condition: 000482 Draft Quality Assurance ProjectPlan Mdti-City Study Sampling Task (N100666) - -_ Revision No. Effective Date: May 14, 1999 ed Location: `Bottle Lot Number: DECATUR, AL - SEDIMENT SAMPLING Date: CollectBeyd (Initials)_ Atotalof5botswillbeused (treecontaining200gramsuplesand 2emptybole fo fedblanks). Recorded by (Initials) MC-110: Sedi-mDeecantutr- Site 1-PIN/Total PEOS/QC MC-111: Sediment -Decatur- Site 2-P/N/ Total PFOS/QC MC-112: Sediment -Decatur- Site3-PIN/Total PFOS/QC MC-113: Sediment Decatur-Field Blank-PIN MC-114; Sediment Decatur-Field Blank ~ Total PROS Example Labels: cdiment --Decatur-Site TPN| Sediment Decatur Total PFOS/QC Me110 Total PFOS/QC nN mes Total PFOS Se 7F/N] | TSeodtinatlePatROSI-DeQcaCturme mote Ste 3-P/N/ mez Samples should be sent to Batelle Columbus in the presenceof ice. ~, Ps Relinguished By: Received By: Date: lecincloded: Y Date: Condition: N 000483 MDarlaif-tCQiuatlyiSttyuAdsysuSraamnpcleinPgroTjaesckt(PNl1a0n0666) Effective Date:ReMvaisyio1n4,No1.:999| Page C-5 - DECATUR, AL - DRINKING WATER (INTAKE) SAMPLING Loto 0 pws BottleLotNumber: CollectBeyd (nial) Atotalofsixbotleswillbeused (five1Lwatersamplesand 1emptybot forfieldblank). Recorded by (Inidials) ___ MCA15: Drinking water-intakeDecatur-PIN MC-116: Drinking water --intake-Decatur- Total PFOS MC-117: Drinking water --intake-Decatur- Field/Lab Dup-P. MC-118: Drinkingwater -intake-Decatur- FieldSpike BIN ee) MC-115: Drinking water- intake-Decatur- Lab Spike PIN ___ MC120:Drinkingwater-intake-Decatur-FieldBlankPIN `Example Labels: DeDrciaatkiunrg-PwIaNterWake DDreicnaktiunrg.wToattaelrP-RTOaSke: Braking water rakeMets "riakdngwaterIntakeme Decatur.FieldSpikePIMNCa18 Decatur-Lab Spike-PIMNc DDecraitnurg-Fwiaetledr/L-aBbaDkuep Dringwater Taf MCa1 Decatur Field Blank-MB/CN120 `Samplesshouldbescatto BattelleColumbusinthepresenceof ice. * & Relinquished By: Received By: Dae: Jeeinchded: Y N Date: Condition 000484 "MDlratf-tCQiuatlyitSytuAdsysSuarmapnlcienPgroTjaecst.P(lNa10n0666) Effective Date:ReMvaiysio1n4,N1o9.991 Page C6 " DECATUR, AL - DRINKING WATER (OUTFLOW) SAMPLING Location: BoteLotNumber: Date: CollBeyc(tGneiddal)___ + Atotaloffivebottleswillbe used (Sve Iwate). Recorded by (nial) MC121:Drinkingwater- outflow-Decatur- PIN MC:122: Drinking wate - outflow-Decatur- Total PFOS MC-123: Drinking water - outllow-Decatur-Field/Lab Dup-P MC-124: Drinking wate-r outllow-Decatur- FieldSpike PIN @ MC125: Driaking water- outllow-Decatur- LabSpikeBIN Example Labels: DbecraitnugrPwIaNte oul Dreicnaitiunrg.TwoattaelrFoOuSlow- |DeDcraaktiaugr:FveiledirLaobulDluop-n?- ra ai oug llMone- n | Diag waterooMoez2 Mes DecaturField SpkeM-PIeN |DecLaabStpikue-PrIMNens . `Samplesshouldbesea tBateleColumbusinthepresenceof ce. & Relinquished By: Received By: Date: Keeincluded: YN Date Condition: 00048s MDdre-eCiQutaylSittyuAdsysSuarmapnlcienPgroTjaesckt(PNl1a0n0666) Effective Date:ReMvaisyio1n4,No1.9:991 Page C7 DECATUR, AL - TAP WATER SAMPLING Yomow ____ obae_ `Bottle Lot Number: CollectBeyd(Initials)________ Atotalofightbottleswillbeused (seven1Lwatersamplesand 1emptybottleforfieldblank). Recorded by (Initials) MC-126: Tap water- Decatur- Ste 1-P/N MC-127: Tap waterDecatur- Site 1-Total PFOS MC-128: Tapwater -Decatur- Site 1-Field/Lab Dup-P MC-129: Tap water -Decatur-Site 1-Field Spike-PIN MC-130: Tap water- Decatur- Site 1-Lab Spike-B/N MC-131: Tap water- Decatur- Site 2-IN MC-132: Tap water- Decatur- Site PIN & MC-133: Tap water -Decatur-FieldBlankB/N MC:134: Tap water Decatur-Field Blank ~ Total PFOS Example Labels: [Tap water: Decafar-Sie TN | TToatpawlaPtFeOrSDecamur-Sie T= | TFaipewlaLtaebr D"uDp-e?caStiueTr= "Top water "Desafur-Sile me112d6 | Tapwater Decatur SiteM1e-1La2b7 |Tap water Decatur mFiceld s SpikeBIN Me SpikePIN meas BlankcIN mess BalpawnakteTrotDaelcPatOuSrFeMled134 | Tap water-DecaSHtmCueTParNt|Tap water- Decafar- Sme e3132 `SamplesshouldbeseattoBattelleColumbusinthepresenceof ice. Relinquished By: : Received By: Date: lecincluded: YN Dat: Condition 000486 "MDrauftQtuailiStt-yuAdCsysSuiarmaptnlcieynPgroTjaesckt(PNl1a0n0666) Revision No.: 1 EffectiveDate:May 14, 1999 Page C3 -~ DECATUR, AL - LANDFILL LEACHATE SAMPLING Low _____ bm__ BottleLotNumber: CollectedBy (Tn). Atotalofonebottlewillbeused (IL landfill leachatesample). Recorded by (Initials) MC-135: Landfill Leachate- Decatur P/N/Total PFOSIQC MC136: Landfill Leachate -Decatur-Field Blank-PN & Example Labels: PINTotal PFOSIQCMC-135 FieldBlank P/N MC136 Samples should beseatto Battelle Columbus in the presence ofice. Relinquished By: . Reczived By: Date: Date: Iejucluded: YN Condition: 000487 "DraftQuality AssuranceProjectPlan Midei-CityStudySampling Task (N100656) Revision No.: | Effective Date: May 14, 1999 Page C9 - DECATUR, AL - POTW INFLUENT SAMPLING Location: BotileLotNumber: RI J--- Collected By (Intl) Atotaloftwobottleswillbeused (two1Lwatersamples). "RecordedMbCy1(3I7ni:tialPs)OTW Influent- Decatur- BIN - MC138: POTW Influent -Decatur- Total PROS DECATUR, AL - POTW EFFLUENT SAMPLING Loesiow 000 bme___ Atotalof ivebottleswillboused(four 1 L samplesandoneemptybottleforthefieldblank). RecordeMdCb-y1(3I9ni:tiaPls)OTW Effluent. Decatur- PIN MC140: POTW Effluent -Decatur- Total PFOSP&N Dup MC-141: POTW Efflueat- Decatur- FieldSpike-PIN : MC-142: POTW Effluent -Decatur- LabSpike P/N MC143: POTW Effluent -Decatur- Field Blaak-PIN - DECATUR, AL - POTW SLUDGE SAMPLING Loom 0 opwe_ Atotaloftwobottleswillbused (one 200 gandoneemptybottleforthefieldblank). RecordeMdCb-y1(4I4ni:tialPs)OTW Sludge- Decatur-P/N/Total PFOS/QC MC-145: POTWSludge-Decatur- Field Blank-PIN FOTW ExTaafmtpuclaet-LaDbeelcsa:far- P/N | POTWIfucat-Decatur- OTWEffcat Decatur OTW MC137|Total PROS Eiffacsi Decatur. |POTWEiffucat- DecatMurC.-1F3ie8ld | FOTWEffi -DecaturM- c1L3a9b Total PROS/P&N Dup MCc-10 SpikePIN MC141 Spike PIN. Mca . BFlOaTnkWPEIfNfocst DecatuMrC.-Fi1e4l3d||PFOITVWToSwiIuPdgFeO.SDIecQaCturMC-144|FBOlaTnWk SPIiNudgsDecaturM-C-1Fie4d5 `Samples shobeuselntdtoBattelleColuinmthebpreusensce ofc. = Relinguished By: Date: Ieincluded: YN Received By: - Date: Condition: 000488 D`raMftuQualliStttyu-AdsyCsSuarimapntlcienyPgroTjaescktP(Nl1a0n0666) - EffectiveDate:ReMvaisyio1n4,No1.:9991 Page C-10 DECATUR, AL - URBAN AIR SAMPLING Location: Date: PufCleaningLotNumber: Filer ClomingLotNomber: Atoaooftnhesruemspumpflosrwaiflilebdebgaennke)r,ated (nesamplefrom thePS-laiesampler,cuesampleforafieldspike,and - Recordebyd (Iicials) Collected by (Tnidals) _ - MC-146: UrbanAir-DecatuPrU-F z MC-147: Urban Air -Decatur- Filter MC-148: Urban Air -Desatur- PUF-Field Spike MC-149: Urban Air -Decatur- Fiter-Field Spike e MC-150: UrbanAir-Decatur-PUF-FieldBlank MC-151: Urban Air- Decatur-Filter-Field Blank Example Labels: 3 OrbanAirDec PMFC146 UrbsAlr Decatur MVCi1e4r7 || UFirelbdsSpAiklerTecarar-mFUCF-i FOieldrSAplibkre"Daecantur MFCli1er4:9 |BUlrabnakn Ar Decatar-MPeUsR)I | UFicdrBAllabskDeacsianr MeFiest SamplesshouldbeseattoBattelleColumbus inthe presenceof ce. Relinguished By: Received By: Date: Ieeincuded: YN Date: Condition: 000489 Draft Quality AssuranceProjectPlan Multi-City Study Sampling Task (N100666) Revision No. 1 Effective Date: May 14, 1999 Page C-11 ~ DECATUR, AL - FOOD SAMPLING Amaximumofthreesamplesofeachfoodtypewilbepurchased(onesamplefrom up tothree grocery stores). Grocery Store 1: Date Initials Grocery Store 2: Grocery Store 3: Date_ __ Date Initials Initials Organic Store: Date_ Initials Fordogs | betestpon MCTNCTr-- NCIS [Bread 1-- Whe |McIn| MCE TMCIE | [Omele Twy MCR -- | -- | i. 3 maotlrilceecstoornethsracempslouercof eseitoher fonocrogafntihcebsreemaatdriocfeosr.ganic flour. t1snotnecestsoacorllyect both Example Labels: fh `Samplesshouldbesentto BattelleColumbusinthe presenceof ice. & Relinquished By: Received By: Date: Date: Iecincluded: Y Condition: N 060490