Document 1Q8GgLp94dVG5MLwO6wqk4dD5

ORGANIC CHEMICALS DIVISION r REPORT NO. P-1605 JOB NO. 2-21-760.01-1113115 TENTATIVE PROCESS FOR PYDRAUL 5^QB DATE- February 17, 1971 WRITTEN BY p. d. Fowlkes V Monsanto ST. LOUIS, MISSOURI DSW 620363 J STLCOPCB4094390 ) pn. ctUA^ 54-0 & " {UiuJ (LMT jftAJ- /tJUJL^CXstrf y^f, Pft t.U~4fit 0A~^t-.4.AHt&--n~4w /Q_ A. V. ^ < ) bdUbu /u*J2el~AA C ~ P^- 5< MONSANTCr COMPANY " Organic Chemicals Division St. Louis Research Department St. Louis Research Report No. P-1605' SAFETY REVIEW COMMITTEE TENTATIVE PROCESS FOR PYDRAUL 5^0B Job. No. 2-21-760.01-1113115 DO NOT REPRODUCE, TRANSFER, STORE OR DESTROY RETURN REPORT TO: GaGaN.C ^cS-.-.RCH iZ-AENT TcCriNiCAL INrOi^.VvATION oAsAUP T700 SOUTH SECOND STREET EFl . * Ifv -f% %.* "C fc E-iis s* & V iT Net Tt Be Taken From Liisran? Date: February 17, 1971 Written by: P. D. Fowlkes - Work done by: P. D. Fowlkes . P. F. Heimsch / L. F. Smith L. R. Stark DSW 620364 STLCOPCB4094391 DISTRIBUTION OF REPORT NO. P-1605 File Copy 2. Technical Reports Library 3. Extra 4. Extra 5. Extra 6. Circulate to <Organic Res. Mgr./Library 7. L. R. Stark 8. W. R. Richard 9. J. E. Maurer - Patent Department 10. J. R. Savage - Manufacturing Department 11. R. M. Kountz - Central Engineering 12. E. M. Potter - Manufacturing Department 15. R. L. Wagner - J. F. Queeny Plant 14. P. D. Fowlkes 15. Standards Department - J. F. Queeny Plant 16. Standards Department - J. F. Queeny Plant 17. Standards Department - J. F. Queeny Plant 0. DeGarmo/J. F. Quinn This report contains confidential information which iB the property of the Monsanto Company and which shall be disclosed only to duly authorized persons. The recipient is held accountable for the filing and safe custody of the report, which must be returned on demand. DSW 620365 STLCOPCB4094392 0H0 TABLE OP CONTENTS INTRODUCTION .............................................................. SYNOPSIS OF PROCESS ........................................... FLOW SHEET.................................................................. RAW MATERIAL REQUIREMENTS ............................. PROCESS IN DETAIL ................................................ DISCUSSION OF IMPORTANT VARIABLES ... MATERIAL SPECIFICATIONS .................................. ANALYTICAL METHODS ................................................ TOXICITY AND HAZARDS........................................... POLLUTION CONTROL ................................................ APPENDIX ....................................................................... Page No. 1 1 1 2 2 3 3 4 4 5 5 DSW 620366 STLCOPCB4094393 -1 - INTRODUCTION Pydraul 5^0B is a low cost fire resistant hydraulic fluid which does not contain chlorinated biphenyl. This blend was developed to replace Pydraul 5^0A. SYNOPSIS OF PROCESS Pvdraul 5^0B is prepared by blending Aroclor 5^32, Santicizer 140, tributyl phosphate, Santicizer 711> petroleum oil and addi tives. The finished product is then filtered to remove any stray debris from raw materials or blending, and transferred to con tainers or storage. FLOW SHEET Aroclor 5^32 --------------------- Santicizer 140------------------ Tributyl Phosphate 7- Santicizer 711------------------ Mobil 750 Stock---------------- Jeffox 0L-2700------------------ Additives---------------------------- ___ r r ' ' 1 [a:n BLENI) TANK __________________ 1 POLISHING FILTER TO STORAGE, CANS, OR DRUMS DSW 620367 STLCOPCB4094394 -2 RAW MATERIAL REQUIREMENTS Basis, 100 lbs. of product Raw Material Wt., lbs. 45051 86840 80781 83621 48073 46310 10575 51331 60015 31100 20640 80151 Mobil 750 Stock Santicizer 711 Tributyl Phosphate Aroclor 5432 Jefferson Jeffox OL-2700 _ Paraplex 0-62 or Admex 710 Santolube 70-A Tolyltriazole DC-200, 350 cs. Fluid DuPont Oil Blue A Dye Santicizer l4o PROCESS IN DETAIL 26.0 7.2 1.6 42.0 3.0 0.3 0.3 0.1 0.003 0.003 19.5 The blending operation may be carried out in any suitable metal or glass lined vessel. The materials are not corrosive and carbon steel equipment is suitable. An agitator should be pro vided. Due to the great difference in solubilities of the various ingredients, the order of addition of materials is important. If the suggested blending order is not followed, product cloudi ness may result. To the clean, dry vessel charge the Mobil 750 Stock, tributyl phosphate, Santicizer 711, 5432 and Jeffox 0L-2700. Warm to 125-150F. (50-65C.) and stir for a minimum of 1/2 hour. Aroclor 5432 is a resinous, sticky solid at room temperature. It may be handled easily if it is heated to 150-l8oF. (65-82C.). At 150F. viscosity is 100-400 cs. and at l8o, 40-100 cs. If convenient, the Santolube 70-A, Paraplex G-62 (or Admex 710), tolyltriazole, DC 200 fluid and dye may be added to the blending tank with the initial charge. The tolyltriazole and dye require 15-30 minutes to dissolve completely. After the blend has been mixed for at least 30 minutes at 125-150F. (50-65C.), add the Santicizer l4o and blend another 15-30 minutes at the same temperature. DSW 620368 STLCOPCB4094395 -3 - The batch is then circulated through a polishing filter. Samples are -taken as required for analytical purposes. The batch may be held for possible viscosity adjustment or be sent to storage. After blending is complete, it is recommended that the temperature be reduced to 80-129F. (26-4g0C.). Prolonged exposure at higher temperatures may cause some product quality deterioration. DISCUSSION OF IMPORTANT VARIABLES The most important specification property of Pydraul 540B is viscosity. Adjustments in the blend should be made to keep the 100F. viscosity within the required specification range. If the 100F. viscosity is low, add Aroclor 5432. One pound of 5432 per 100 pounds of blend will increase the viscosity about 1.9 centistokes. If the 100F. viscosity is high, add Santlcizer l4o. One pound of Santlcizer 140 per 100 pounds of blend will decrease the viscosity about 3.1 centistokes. The quantity of dye added should be carefully measured on a suitable small balance or scale. This is important to insure uniform color from batch to batch. Another caution mentioned in the previous section concerned prolonged heating. It is suggested that maximum temperatures of 125-150F. be limited to 2 or 3 hours. Also, manner of heating the batch should control film temperatures so there are no significant hot spots. Prolonged heating may cause gradual darkening of the product as well as gradual increase In acidity due to decomposition of the CDP. MATERIAL SPECIFICATIONS Raw Materials Refer to raw material specification sheets included in the Appendix. Finished Pydraul 54QB Typical analyses and suggested specification limits follow: DSW 620369 STLCOPCB4094396 -4 Property Tentative Specification Typical Value JFQ Method Appearance Viscosity, cs. at 100 F. at 210F. Acidity, mg. KOH/gm. Specific Gravity 25/25C. Moisture, KF Pour Point (each 10th lot) Clear to slightly hazy green- liquid 111-118 7.7-8.4 0.30 max. 113.0 8.03 0.24 1.115-1.135 .15 max. +15F. max. 1.125 .05 +10F. 16 -B 126-A 80-B 116-A 78-B 100-A ANALYTICAL METHODS No new or special analytical procedures are required for this product. A cross reference table appears In the Appendix list ing standard analytical procedures used at J. F. Queeny Plant, W. G. Krummrich Plant, and at the Anniston Plant. These pro cedures are currently used on similar products. TOXICITY AND HAZARDS No unusual toxicity or hazards are expected with the raw ma terials or finished blend. The process is a simple blending procedure and no hazardous reactions should occur between the various components. Animal testing Indicates that the components used in this blend have a very low order of acute and oral toxicity. (Note: Current specific toxicity information Is being obtained from the Medical Department on these materials and It is sug gested these be included in the Appendix of this report.) General precautions include the following: 1. Goggles should be worn where splashing or spillage may occur. 2. Any material in contact with the skin should be removed by washing with soap and water. 3. Prolonged or repeated exposure to the skin may cause Irri tation due to removal of skin oils with resulting dryness and chapping. DSW 620370 STLCOPCB4094397 -5 4. Material may be irritating to sensitive skin areas and eyes. In case of contact with eye tissue, flush copiously with water and then get medical attention. 5. In case of internal ingestion get immediate medical atten tion. 6. Avoid inhaling volation material or mists. POLLUTION CONTROL No waste by-products are generated by this process. Used fil tering material, flushings from the system during cleaning, as well as any spoiled product should be disposed of as dictated by local regulations. While the materials used In Pydraul 5^0B have not been identi fied as environmental contaminants, it is strongly recommended that care be exercised In preventing any tank flushings or other residue from entering the sewers. Since Pydraul 5^0B Is highly Insoluble in water, any material Introduced into the sewer would be an easily Identifiable oily pollutant. Used filters and tank flushings should be drummed and disposed of either In the WOK Incinerator or sent to the toxic land fill. APPENDIX File Copy Approved by: (j ' JJP. D. Fowlkes / L. R. Stark - / '/ 7 ) 3/Vhi '' (jJ Manager of R&D 3/tlv (date) Manager of Manufacturing > - //. / f (date) Manager of Process Technology , /is 2/17/71 ' (date) DSW 620371 STLCOPCB4094398 \ Analyttcal Procedures Property Appearance WGK 12809 Viscosity 12857 Plash & Fire Point 12803 JFQ 16-B 126-A 50-A Ann!s ton G-l 049 114 Specific Gravity Pour Point Cloud Point 12804 13005 - 116-B 100-A 36-A 052 053 - 0 0 Acidity Moisture 12794 12810 80-B 78-3 047 Foam 12805 54-A - Refractive Index 13123 Distillation Range 10117 104-A - 048 054 Approximate equivalent ASTM method. ASTM ^ - D-445 D-92 - D-97 D-2500 D-664/D-974 D-1744 D-8Q2 D-1213 Modified D-20 DSW 620372 STLCOPCB4094399  \ ..................- v.' 'u > v-x. - sic al - Csvi^iON J. QHEFNY PLANT L\:;\v.vr;v^: - :::.VfF.U specification :.1A7 ;* i ,\ L coOt i 45051 . U-Z`J IN Pydraul Blends iipofo:co cr A. F. Uelncr Dnr^iavnc i ' R, L. Wagner--2- JFQ M.J.Smid -I-JFQ R. A.Cc-isman -4- JFQ W.E. Ault/WAULT -l- GO/32 OIL, MOBIL 750 STOCK (MZY-227N) C S.dl C AL KO-L-lUi. A / L. R. Stark/LSTAR -2GO/Rcscarch J. D. Lcycrlo -l- IFQ H. L. Powell -l- JFQ Standards Department -4- JFC Ol. oT. datl 2-3-71 | LPrLcriv.; until j 2-3-72 * iUCPUSR UMPLC row ANALYSES * Mobil Oil Corporation 1 x 16-ounce XN Bottle A'Oi l: All zzr.plcs processed by this tenia ivs spccificciion uili require die position of the authofijtd releasing e'er.:. TEST . 0;: each lor Appearance Color (ASTM D-1500) Fire point Flash point Neutralization Number Specific g'evity (5- 15. 6/15. 6C Viscosity: 100F @ 210F LIMITS k Brown, mobil liquid 3.0 to 4.0 500F min. 450F min. 0. 04 max. 0.916 to 0.929 151 to 183 cs. 11. 0 to 12. 0 cs. METHODS 16-B 38-1 50-A 50-A 80-B 116-B I26-A Uoen request aniline ooirn Carbon residue, Conradson, M by weight Gravity, API Pour point ~ SuHur: Corroriv. Torn' / by weight LC:, .ne'ex O CO Vendor Typical 198F 21 - 23 - 15F Non-corrosive 0.477 40 ASTM Do 11-64 ASTM D1S9-65 ASTM D2S7-64 100-A ASTM D1275-64 124-A 126-A DSW 620373 STLCOPCB4094400 MONSANTO COMPANY OROANIC CHEMICALS DIVISION EVERETT PLANT FINISHED PRODUCT SPECIFICATION RROOUCT (Trad* Almm*T SANTICIZER 711 PROOUCT (ChmticMl Nmmm) CHEMICAL FORMULA PRODUCT CODE DEPT. OR JOE 86848 USE Sales and internal SALESCOOE 3960-300-04-011 TYPE SSUED Dec. 26, 1969 ITANDARDS DEPARTMENT John F. Queeny Plant MOL VT SUPERSEDES SPECS OP January % 1969 (Tentative) SAMPLE FOR ANALYSIS 1 x 16 ounce NN Bottle TEST On each lot Acidity, meqAOO grams Appearance Color Moisture (By KF in methanol) UNRESTRICTED SALES LIMITS INTERNAL CONTROL LIMITS 0.12 maximum Clear, oily liquid APHA 50 maximum 0.10% maximum -- -- -- -- EVERETT PROCEDURES 801-01-03 600-01-02 801-01-04 801-01-02 Odor Refractive Index @ 25C Slight, characteristic 1.480 to 1.483 .... f 600-15-01 600-18-01 Specific Gravity @ 25/25C Upon request 0.965 to 0.973 Composition: Low boilers including alcohols Rasticizers other than Santicizer 711 Sampling procedure - - -- 0. 8% maximum 1. 5% maximum 801-01-05 GLC 1. Tank Cars or Trucks a. Take one or two 16-ounce dip samples, as per plant practice, after tank or car is filled. b. Submit one bottle to the laboratory for analysis. When a spare is taken, hold in the department for reference. -- -- ____ 2. Drums DSW 620374 a. Withdraw a thief sample from every fifth drum and composite to give one or two 16-ounce bottles, as per plant practice. b. Submit one bottle to the laboratory for analysis. When a spare is taken, hold in the department for reference. STLCOPCB4094401  IIOHSAfITO COMPANY ON0AN1C CHEMICALS DIVISION PURCHASED FOR RESALE* FINISHED PRODUCT SPECIFICATION MOQUCI <Trd Nmn) _ TRIBUTYL FH OS PHATE PRODUCT (Chemical Nmnmj RROOUCT CODE 80781* OEPT. OR JOB USE Sales - W. F. Waychoff, Manager SALES CGOE 8483-100-04 -001 TYPE TYPE CHEMICAL FORMULA (C4H9-0)3P = 0 ISSUED MARC! STANDARDS Of; " John F. Quecny f- 'u. By 266.32 SUPERSEDES SPECS OP Februarv 10, 1966 SAMPLE FOR ANALYSIS 1 x 16-ounce NN Bottle From Stauffer Chemical Company & FMC TEST On each lot UNRESTRICTED SALES LIMITS Acidity Appearance Color Moisture (By KF in methanol) Odor Refractive index @ 25 C Specific gravity 0. 03% max. as phosphoric acid Clear, mobile liquid APHA 25 max. 0.20% max. Characteristic 1.420 to 1.425 0.977 to 0.980 PROCEDURES 4-A 16-B 38-D 78-B 84-A 104-A 116-B : DSW 620375 STLCOPCB4094402  I. . i:u < .......... i- r>: i- i: V \ i I: Y A T i V !;. s-i-ifoiric/Vf if-i: /-U . i . ... I -.1 ' L \ - '" ` 1.. Oc-y^ ^ '* cm,, ;M_ i v. _c.:i intj !_ ...An-; jD-ziVi. to.! A 11 5632 >' . <.*. .. ridL'.'L L IV;.: Yll-. co;.- .cui'ci: 6:` f-i'vcini/.'.K':: -r CMKwcf.L For; t i <- C11M0 r*sV i.v. ur __ 1 Ciurcc t t:1: t i c. J.'i L tirruci tve u; ;/!.`)/.71____ c.:j r.H^LVSij 1 y ] /? rr.l . . 00 Color, Ki'A 00 Cneeil;c C,; vil:y ( 90cC 00 A;^oor once 2 Me x. 1.263-1.290 Clear Yellow Oil - civ: jam .:;oorui.(.v.; Chlorine Content, % 30.5-33.0 IV.ULD (, V _J . T. J>1] G-A 052 G-l 093 (r,) i. DSW 620376 STLCOPCB4094403 MONSANTO CHEMICAL COMPANY ORGANIC CHEMICALS OIVISION RAW MATERIAL SPECIFICATION- MATERIAL PARAPLEX G-62 CHEMICAL FORMULA material code 46310 USING DEPTS. Santicizer Blends SUPPLIER Rohm & Haas . .. ISSUED OCT. 18, 1965 FYf C* A ^ ~ f* f Y -K *:'[" ` Jrffl P. J", . ; ev-J(''A MOL WT. ----- - SUPERSEDES SPECS OF September 7, 1962 SAMPLE FOR ANALYSIS 1 x 16-ounce NN Bottle TEST UNRESTRICTED PURCHASE LIMITS INTERNAL CONTROL LIMITS On each lot Appearance @ 30C Sparkling clear -- Color Gardner #1 max. -- Neutralization No. Acid. 1.0 max. -- Refractive index @ 25C -- 1. 469 to I! 473 Specific gravity @ 25/25C -- 0.988 to 0.998 Upon request Iodine number About 0. 7 to 0. 8 ---- Viscosity @ 25C (Gardner-Holt) M to Q -- Product information - Typical Analysis Flash point 315C F reezing point Oxirane oxygen +5C . 6. 7 to 6. 8 (6. 5 min.) Refractive inctex @ 25C 1.471 Saponification number 182 Specific gravity @ 25/25C 0.993 ` PROG 16-B 38-N 80-B 104-A 116-A 68-C 126-D DSW 620377 STLCOPCB4094404 ORGANIC- -'EWiCiU OlVUlON J. F, QUEENY PLANT. USlf^G CCMTJ RAW MATERIAL Fluid Blends lUPPLif.R \ . SPECIFICATION Monsanto - Nitro Fiant MA TRUL _ SANTOLUBE 70-A CHEMICAL FORMULA * Blend of: Santolube 70 Santolene C 98. 35% 1. 65% rSSUID may l b;> Mims: n?i2T::; - pt Gy Pl_l MOL. WT. SUPERSEDES SPECS OP 6'2 I " 6 7 fO T Santolube 70; Nitro code 81787 SAMPLE FOR ANALYSIS 1 x 16-ounce \VM Bottle TEST On each lot RESTRICTED INTER-PLANT LIMITS PROCEDURES NITRO JFQ Appearance Color, ASTM Dilute Neutralization No. Solubilities: 5%/vol. in PE Dark, oily liquid 5. 5 max. 51 to 61 Clear 6-C-01 6-C-21 6-A-24 6-V-15 16-B 38-1 80-A 112-B Specific gravity @ 25/25C 0. 89 to 0.97* 6-D-07 116-B Upon request Emulsification test Santolene C presence Viscosity @ 210F 40, 40, 0 (30 min.) Positive phosphorous test 70 to 300 SUS* 6-S-28 -- 6-X-02 ----- -- 126-A `Typical ranges submitted by Nitro. Special requirements This material is shipped upon invoice certification of compliance with specifications. Prior permission will be obtained to ship non-specification grade material. This specification is the property of Monsanto and is intended for internal use only. DSW 620378 PV. t j . ft 7 STLCOPCB4094405 I* 4 w * v** - * * * ^ V* V - 4 k: . 0.^0 AS'.C CXSMiCAUS 3v:sion t r q----.",-v PLANT . Hu*'/ Coot .j 60015 !; u:oo m ' Pyclraul Blends j .a in i A i ! VH RAW A7c RIAL S PACIFICATION j o?c;:'j cv !j P. D. Fowlkes KAMI ; T0LYLTRIAZ0LE (Cobra tec TT-100) C2:CAU i-OAUULA . DlITJlIOUTiC.-; R. L. Wagner - 1 - JFQ P. F. Calais-- 1 - JFQ R. A. Geisman - 4 - JFQ J. D. Leycrie - 1 - JFQ H. L. Powell - 1 - JFQ N.T. Johnson - l - CO/32S J. R. Savage - 1 - GO/C2X B. Petty - 1 - GO/B2N P. D. Fowlkes - 1 - GO/Re -1/;JOp/Rc^e. Standards..- 4 - WOL. WT. Oatc r.;o:jo:^o 4/30/70 EKF^CTIVS UNTIL ? CU^r* L12.`i 4/30/71 j Sherwin Williams SAU?L *03 ANALYSIS 1 x 8-ounce WM Bottle ft'OTS: All ss.-.slss processed by ibis lerScSivc sps c ificc'.ioi will rcr-sirs disposition oj tbs oy `horized releasing ejer.:. TESTS Appearance Melting point Product information ' Bulk density Screen test: Retained on 6 mesh Retained on 60 mesh Solubility @ 25C (by wt.) Benzene Ether Methanol Polyethylene Glycol Water Water LIMITS Light tan granules 81 to 84C . 40 - 45 lbs. /ft. 0% 99% 1.7% 23.0% . 92.5% 53.3% * 1.03% (1.90% @ 60 C) 0.7% maximum . PROCEDURES 16-A 76-A ' DSW 620379 STLCOPCB4094406 J. F. OIL HNY PLANT!s:w/.;no cg:p.\;;y tSO.UilC CUldlOv AIS UlyljlOH RAVI .MATE.*;!AL CPLeiriCATtOi! mat r.'iAt cor*a . 31100 ' ' : . USiNS CS r*T3* Fluid Blends . F'OPLIER Dow Corning Corporation now* CORNING 200 FI.UJD - 350 cs. ct;.* ;Cr'- Kr;.:-u!A Ijp * ft FEB, 8,- -j ^ p, o ^ tMiV. t-rp f i ..ft ~P] ( P.y u v October 28, 1954 ' TEST On each lot Appearance Refractive index @ 25C Specific gravity 25/25C Vlsccnity 2 25"C ' Uponjrequef.t Color - modified Barrett Flash point Neutralization No. Volatility (24 lire. /150'C) sampue Fo.* AK\Lvr:a 1 x 8-ounce Bottle UNRESTRICTED PURCHASE LIMITS Syrupy liquid 1. 4020 to 1.4040 - 0.969 .to 0.975 332. 5 - 367. 5 1. 5 max. 6001F min. 0.01 max. 0. b% max. METHODS 16-B 104-A 116-A 126-31100 38-H 50-A 80-B 128-B DSW 620380 STLCOPCB4094407 TEST UNRESTRICTED SALES LIMITS On each lot Acidity , Appearance ' , 0.20 meq/100 g. max. (0.0.1% max. as II^PO^) Clear, mobile liquid Color APHA 40 max. Moisture 0.1S% max. (By KF in methanol) Odor Essentially odorless Specific gravity @ 25/25C 1.203 to 1.213 ' Stability to KMnO^ 65% transmission, min. CONTROL LIMITS METHODS 0.15 meq/100 g. max. 4-A Clear, mobile liquid APHA 15 to 35 0.12% max. 16-B ' 38 -D 78-B Essentially odorless 1.205 to 1.208 84-A 116-B 65 to 90% transmission 118-D . Unon request Refractive index ' @ 25C 1.550 to 1.570 1.558 to 1.563 104-A Sampling procedure 1. Circulate storage tank the night before filling shipping containers. 2. While filling drums or tank car, take one 16-ounce bottle from the filling line and submit to the laboratory for analysis. DSW 620381 STLCOPCB4094408 I M flv STLCOPCB4094409 DSW 620383 STLCOPCB4094410