Document 1Q2mVw1K53Xrz6DeeB05q7zYa
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GENERAL ELECTRIC COMPANY, ONE RIVER ROAD, SCHENECTADY, NEW YORK 12345 Phono (5181 374-2211
REAL ESTATE AND CONSTRUCTION OPERATION
November 21, 1973
Dr. C. Hugh Thompson, Chairman Hazardous and Toxic Substance
Regulation Task Force Office of Water Program Operations
Environmental Protection Agency Washington, D.C. 20460
SUBJECT: COMMENTS OH TOXIC POLLUTANT EFFLUENT STANDARDS (38 FR 21342, Sept. 7, 1973)
Dear Dr. Thompson:
In the above Federal Register announcement, the Environmental Protection Agency invited comments that might assist it in setting effluent standards for the pollutants on EPA's first list of toxic pollutants. On behalf of the General Electric CcmDany, I am pleased to submit for your consideration the following comments that we believe are relevant to the establishment of effluent standards for polychlorinated biphenyls (PCBs). The General Electric Company is a major manufacturer of sealed capacitors and transformers that incorporate PCBs as insulating liquids.
COMMENTS
.
In promulgating its list of toxic pollutants, EPA stated that "Polychlorinated biphenyls are on the list because of their high order of _toxi_ci_W__to_ rr^an__an_d aquatic organisms, and because of their bToaccumulative pote'ntiaf! The'data are adequate, and the point source discharges require prompt control." (uriderfinings added) '
r In an earlier section of this same promulgation (I, 3), which
explains the criteria of toxicity, appears the statement that "substances which have an oral LD50 of 50 mg/kg of body weight or less ... are defined as highly toxic to mammals ...". This definition would seem to exclude PCBs, because the'LD50rs of all commercial preparations are many times greater, that of a typical material (Aroclor 1242) being 8650 mg/kg LJ.
I1 IpCBs and the Environnent, Interdepartmental Task Force on PCBs, May 1972, p. 131.
SEEVIVG PROGRESS
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QGENERAL
ELECTRIC
Dr. C. Hugh Thompson
-3- November 21, 1973
"Some of the more important considerations are:
"
(1) The nature of the environmental effect of the presence of pollutants in water (e.g., long or short term, temporary or permanent, localized or widespread, etc.).
(2) The economic and social impact of the standards and control measures and the impact of the environmental damage to be alleviated.
(3) The practicality and enforceability of the standards and
control measures, including the availability of techniques and
instrumentation for determining whether particular standards
are being met."
Regarding the third consideration, we have already indicated that there is no practical method of enforcing a standard based upon the recommended maximum concentration of 0.002 ppb of PCBs for fresh water.
The following additional points, which we believe should be considered in establishing effluent standards for PCBs, are germane to the other two considerations.
(1) In 1971 the Monsanto Company (the sole U.S. producer of PCBs) began a program that has led to a total ban on sales of PCBs
for all uses ex_c_ept_ the manufacture of sealed electrical equipment (capacitors and' transformers). As a result there has been a large decrease in the number of point source discharges of PCBs. Since there are probably not more than 25 major users of PCBs throughout the country, current production-type discharges of PCBs are no longer as ubiquitous as when PCBs were a component of paints, inks, plastics, adhesives, textile coatings, hydraulic and heat transfer fluids, etc. Indeed, "production and sales figures for PCBs in 1971 were roughly half of those for 1970, when these volumes were at their peak ...(and) projections for 1972 indicate an even lower volume " (Ref. 1, pp. 5-10).
Thus, even apart from the introduction of improved control
.
pleasures by present PCB-users, there has been a major decrease in the
amount of PCBs to which the environment can possibly be exposed. Although
current PCB discharges can and should be more carefully controlled, the
situation is one whose magnitude is decreasing. There is, therefore,
no need for emergency-type controls, which might be reflected in
technically infeasible standards and compliance schedules.
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QGENERAL ELECTRIC
Dr. C. Hugh Thompson
-4- November 21, 1973
(2) PCBs are not a unique chemical species. More than 100 Isomers are possible, and major commercial products may contain as many as 18 distinct compounds. As pointed out by the Interdepartmental Task Force on PCBs:
"Full evaluation of actual or potential effects in the environment is hampered by the complex nature of the mixtures that compose PCBs, and by the inclusion of contaminants in these mixtures. As experimental studies have been conducted with the unaltered products, as sold, the results may not properly reflect the effects of the components as they exist in the environment." (Ref. 1, p. 19).
Furthermore, it was reported to the Interdepartmental Task Force
"... that all PCB products cannot be lumped together in terms of either their environmental impact or persistence."
Other points made in this report to the Task Force are:
(1) As the degree of chlorination (of PCBs) decreases, the bacterial degradation rate increases. (Ref. 3, p. 4).
(2) The residue storage levels (in albino rats) decrease
exponentially as the weight percent chlorine decreases.
(Ref. 3, p. 6)
'
(3) PCB residues found in wild life are dominantly penta-, hexa-, hepta-, and octa- chloro biphenyls. (Ref. 3, Chart 4).
In recent years the Monsanto Company has developed a special product, Aroclor 1016, which is the only grade of Aroclor now used in capacitor manufacture. Although its gross chlorine content is almost
the same as that of Aroclor 1242 (i.e. about 4251 of Cl), Aroclor 1016 has been specially distilled to remove most of the higher boiling homologs, which are found in wild life residues. Indeed, more than 99% of Aroclor 1016 comprises homologs with 4 or less chlorine atoms per biphenyl (Ref. 3, Chart 1); and these homologs have not been found in wild life residues.
In light of the foregoing we recommend that the specific commercial preparation, Aroclor 1016, not be considered as a toxic pollutant. We are encouraged to see that in promulgating its list of toxic pollutants, EPA has recognized that not all compounds of cadmium and cyanide are . toxic and has stated that distinctions will be made when the final
Tucker, E.S., "Assessment of the Biological Persistence of Polychlorinated
Biphenyls," from Presentation to the Interdepartmental Task Force on PCBs
by Monsanto Company,"May Ilf, 1972 , p. 2.
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GENERAL Q ELECTRIC Dr. C. Hugh Thompson
November 21, 1973
effluent standards are published. We recommend that similar distinctions be made in writing effluent standards for PCBs.
(3) The "economic and social impact" (consideration number 2) of a uniform effluent standard would be much more severe upon an existing plant than upon a new plant. Most of the existing plants that manufacture sealed electrical equipment containing PCBs were in operation for many years before there was any recognition of the possible environmental hazards of PCBs, and during these years no special precautions were taken concerning the handling and disposal of these liquids. Thus, accumulations of PCBs over the years in and around the drainage systems of these plants could result in continued discharge of PCBs even if the plants were to eliminate PCBs from their current operations. Elimination of such reservoirs of PCBs might well require a major and prohibitively expensive renovation of plant and site. However, with the institution of internal control measures such as described in proposed American National Standard Guidelines W, older plants are preventing further build-up
of such reservoirs.
WHAT EFFLUENT STANDARDS ARE FEASIBLE FOR THE ELECTRICAL MANUFACTURING INDUSTRY?
We have already noted that the Monsanto Company now sells PCBs only to manufacturers of sealed electrical equipment, such as capacitors anF ' transformers. The soundness of this decision is supported by the findings of the Interdepartmental Task Force on PCBs (P.ef. 1, p. 4) and the regulations promulgated by the Food and Drug Administration (33 FR 18096, July 6, 1973). These documents recognize the unique combination of fire safety and design efficiency that the use of PCBs imparts to capacitors and transformers and the minimal risk of environmental contamination associated with such use.
We believe that the special conditions pertaining to the past and present use of PCBs in the electrical industry warrant recognition in the setting of effluent discharge standards. These should not necessarily be Identical to those deemed appropriate for the chemical industry.
The manufacture of transformers and capacitors involves a multiplicity
of operations including vacuum impregnation, heat treatment, filling,
sealing, washing operations and the like. Provision must be made for the
handling of large apparatus containing up to 1500 gallons/unit (in the case
of transformers) and for the filling and sealing of millions of small units
"per year (in the case of capacitors).
Control of PCB discharges in such electrical manufacturing plants
requires a combination of process design and good housekeeping. For
example, waste lines and operating procedures may be designed to eliminate
contact between PCBs and water not directly used in the PCB operations
themselves (e.g. cooling water). No effective end-of-line treatment has been
demonstrated on a plant scale.
'
KTdf?icial Standards Proposal. Proposed American National Standard Guidelines
for Handling and Disposal of Capacitor- and Transformer-Grade Askarels
Containing Polychlorinated Biphenyls, Cl07.1 - (
), National Electrical
. Manufacturers Association Pub. No. CP-PI -1973 and Pub. No. TP.-PC-1973,
January 25, 1973.
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GENERAL ELECTRIC
Dr. C. Hugh Thompson
*6- November 21, 1973
Segregation of operations and waste lines is feasible in the
design and construction of a new plant but would be prohibitively
expensive for an old plant. If such controls are incorporated into
a new transformer or capacitor plant on a new site, it should be
'
possible to limit the discharge of PCBs to'less than 5 pounds per day
depending upon the volume and complexity of the production processes.
The attainable discharge from an existing plant that had already been
in production before the mid-60's may be as much as 15 pounds higher
as the background level, depending on the size of the plant, its age,
and the nature of its earlier operations, all of which would have
affected the location and extent of its reservoirs of PCBs. Such
a plant could install the control measures mentioned above and still
be unable to reach the discharge levels for a new plant at a new site.
He believe that the foregoing numbers can provide the basis for realistic effluent standards because they reflect the actual technology of the capacitor and transformer industry. As we have mentioned earlier, the recommended water quality standards provide no practical basis for effluent standards.
SUMMARY
In the foregoing comments we have raised the following points:
1) Available data do not support categorizing PCBs as a "highly
toxic" material, nor setting standards on the basis of this arbitrarily
assigned hazard rating.
2) The maximum recommended concentration of 0.002 ppb of PCBs in fresh water is an operationally meaningless number that is unsupported by convincing ecological data. Any effluent standards based upon such a water quality standard could not be attained in existing plants and could lead to shut-down of capacitor and transformer operations.
3) Actions already taken by Monsanto and PCB users in the electrical industry have substantially reduced the exposure of the environment to PCBs and should result in a decreasing impact of PCBs in the environment.
A) Existing data suggest that Aroclor 1016 should not be considered a toxic pollutant.
5) Older plant sites will continue to have significant background levels of PCBs in their discharges because of accumulated reservoirs from years of operation before anyone recognized the possible environmental hazards of PCBs. These background levels should be considered apart from those levels contributed by current operating procedures.
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GENERAL ELECTRIC
Dr. C. Hugh Thompson
-7- November 21, 1973
Ke appreciate the opportunity to submit these comments and hope that they will be of assistance to EPA in setting effluent standards for PCBs.
Very truly yours, Jr'
ELS: 1
/ Dr. E. L. Simons, Kanager Environmental Protection Operation
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