Document 1Q0jRn4Bokr5KLrmxkNxzaKEE
}
BEST COPY AVAILABLE
ARI6-O 122
st comnts --
-- i Perforning Laboratory
|
)
aie 1 at 15
1
Pomc chs,nc. SunyofMULPORE
001689
1. sommar
ccoonpdruicctoTrehnduetufno,arcuteis the Tovirosystens
Cotndoepxsaiccnriyitbyfeodr
o9f6inboatTrhNsis
3f2i0nal during
toretpohret. Moril 33
sigs,The. to Nay
Setleesst.sstwrauss 3, 1991, at
Divisio of Resource Aaslysts, Toc. ia Eakptors Her
RSatmapnafboirxde,."RoberItt Bovearsi,`caonndduTcitneodthybyWarJde.sase Megas, Peter Kowalsii, Flies
tceonnpceernattTruharetei'onsotfestof"23.vE0aessC.t SpuebrTsfhtoearnsdcsidelutiaoubndndew4radtielrsuttavitaoisncsvyacatotenhrdeitticcioonntmrseodliaviattphreapamfreiewvden
Lviisthht ht
swvtaedsr'ileagjBduoesutireosdnizdetudock.'w4a0teNrou.abiinns/Flsleacsc/kossntcevenrtveriatthiinocnausbaotPfehdFotIoonpe3r582i6ordovteaorrfey:2s40hhimtaoelwrts.
F(ocwoinatarlol)c,once62n.t5ratwiao/nis.'ver1e35use`dwiffL,or a21510 cmatgc/uliatiSo0n0s.m/l. sad 1.000 seri.
mrveisntteeidnMead {enunsduesred72tesiton ucrotnhdeiCtSitDoensst.11v4aEsxwposfaurroTesH/o3fa8l3s0lgieansn-dhto2ousnetohecoubltsteesutrrveesdutbhsaettffaenvccites
c25o5nc2e0nt/r1at4inodn125"(WmOgK/C)L, rleesspsecttihvaesly6.2.5 g/L. The 96 hour BESO. aed ROC are
Page 2.00 15
resem
001590
EE
BEST COPY AVAILABLE A--
xr
na
VIL. References
n
001691
Im. nom or mus
ne ble 1. CSLhieeaa?mpilcemaeldofiacdheafirooarncittezorenidizcaiwttaiytoenrtesuotfsed3 vroeprpreespeaartea.tive .
Table 2. Growth data from toxicity test
5
Table 3. PSeprecceintticchgarnagveidfrroantecofnrtormoltoaxnidcitayvertaegset
10
Table 4. Mferdoinantoexfifceicttyivteestconcentrations (E508)
n
Table A.1. Temperature seasured durisg toxicity test
1
Tebl1e A.2. 5H nessureded duciduringng ttooxicciityty tentesty
15
Paoge dot 15
cn etore.Sm AALS
001692
. omoscrion bjectivTehis"ofsttuhdeystwuadsy wassptooadsatoberryaeiIsdNe tCohmepuarcyu,teStt.oxPiacsilt,y oNfismFeNso3t8a3.0 tTohse aEnrdesbumaatteerria"allsga. eapTlhoyeedreporitn conttheainsstsaeicrt.ionsantdhatthdeescrriedmelttshe onfetdotdhse tihnevewsattiegratiqouna.lityThedaFtepocrotlleacltseedcdounrtiaiongsthaen atperpte:ndix that presents
Tost sTasTance: v. Tons wo mms EboovtitcloesyTsUttheant0s20vaoso (EFlaoavrbieeraloblSeeyrdstesw13si,thSu1m9tp3h0le.e foNIltelodvveiarass ci9onn6ftHoari)mnaetdwioainsa:a d8e3l5i02v8e6Ar0L-e5dg,lasTtsXo 3Bu0s0h "AvenTuHe, 31St2.0 PGaaul,paleMioymeelslootws.liquidP)riovrastosupupsleietdhebytes3t1 mCoamtpearniya,l v9a3s5 1st.o0regdramsi)a +1f1h1e bedarakrcahtivezdoosattEesnpveirraatbuyrset.nsAforreservaeissiemmepnleof(1s0pppreoaxrisr.atels DruorIon vam: atepsptrionxgiWmaatwteaersly usst"8ee.dr0i.leforRsaearsciuccllhtiessdatoifmoendicaohfemit(ce0as.lt5.osrEmgFiaAln,yissimss19o7a8sf)dafworiretpharlelsaetnot3xaHitciivtoefy Tsatbalpele1.`of deioaiied water used to prepare the media are presented in Test organs:
tdheelivCeurleKtdiugraeeto CEuouslvelidercoftsoriroanttehsesofteosnAtlgAawpearsilatfr12ot,nhes19Uc9n0ui.lvetrusrTiehteyorioidfgeisTnteiaxtlaylsyopforotcAhuuersetcidunltfu1rrnoedn wSirsamaVteerricteidsdtouaisntgerilien Aenprpircohperdiatemedfsaosicdaeiscticakley.fo medTihae usceudltufroer tvhaiss test 20d maatained at test conditions. TorterTy TestonG:
c3.ondu19c9t0eT.d7he adta"Tltiani"litasirvgeeBrasettdoexmoipceoirtapytruorceteedsoutfrew3s2aso3fpertCfheorvsOietRdhDdtui(rr1ie9n8g0c)o.nAcpeeniTtlhera2t9tieosttnosMvaoasfy 3] diTisels.tutiposrunebpsatrwaeandtceer'fo"4c2dodln1tuaatiainioelndutwiadotnner,aihteeTrhetecsostn.ttorcokvle.sssoellXusti1o,nv0i0t0vhaormsats/ikdetsdhteodckiruesecoteltyoifotno SToclovnetnrto.l), 6N2.o5sinwaaflt,co1n3c5enat/ria.tio5n0s nogf/L,t5he00 staefslt, maaatder1i,a0l00 svearseh:. 0 sift ;
{
|
Page Sot 15
i
Table 1. Cdheeimciaciatled wcahtaerractuesredizaftoipornepoafre afestrepperdeissentfaotrivteoriscuimtpyletesotf
Parameter
Kaeristuroefsent Reiponritting
orpgeasntoicchildoesrine wan
2
Opersgtaincoipdheossphorus walt
os
Pbioplhyeennrtlosrinated wn
os
Note: WD = sot detected st or above the reporting Timit
WVeaaslaureed EB
Page 6 of 15
re sg
c2epticpaetNretososreaoefd a"SsSaach2rt50raessdatolaaslgnyltassaatnSdtrhleesesFeaqytueelrloyffl1ad0si,k0ss0t0etihabctietllecsdo/natlasiannegdToe1t0ht0resentel STetersitn(gli"tta"sTsheselcsi.u3t6ivohenor.uerrTuLhneesdtonfll(ay4skaTsrarnavdneogrneedncuaompnbpeeradsrvtoiattbahlreyjsvoahvsaekrteuersdedignltaaosossielbneecacuktbeartsto.hre Jvaoscatinoenintu`oifnedeavchithvescsoeoll)-.bitAe24flhsoourrescleiagthtlaiagdhts0 htohautr pdraorvkidpehdotoapelriighotd intensity of 0 upstart. vReimssucayltloyTnheeteevres.rayber34Thoefboaaprlhsg.a(lbbeyccekslalseans/sawloodfealdeipraFeccht12tneismtcetreovrse)csosepvliacsvacdsoeutnedtresatiesrvemidinteih4dn STihcehn te`smetrcuCrlyashthem`astoatshteen)b"eginvnaisngsaensdsucroedd ofadtherteecsotr,dedanddtaeimlpyeriantutrhee incubator.
smarzsTion. wevRons:
sRteatthiosttiRcevasalusltsuresceohdfaigDutyehse thte(oSrtaieucpthihatonyr, t1to9e8sc3ta)l.cwuTelhraeetebiEinCnoSta0eirspvlraeltoufeedsmoubvsiyinnggstasavosemdirsnacagdle
CDVTouahnnrecgieeantn`ttcmr'aetasitria(olRntOseVlsAot]og.f|owlfheiTscthh[etheiasnvbcemslrutuaaadgbseeecsres.opafe|cicfpeTialhcrleassgerpWtoerwrOitEchalrvoaaattnsee-9wvacaysahloccuuarsllsaacutulweylidsanitssuesditnoahgfse
fSbaxttpruoarsaculrteiolgopgeritoohfde. |tshwemTphlese.umbpieevrrecreanogtfe Average. specific groeth rate,
cesclphleascnigfepiecr dividing
fagrlroonwattcho0ntrbraootulersfisrdoincvailtdcheuedlactuoeyadtrtohbley that vile by the mrerage
Specifpirc e"trowtchhagreaketirnontheconctorntorlolmahnd mwieetdipl1y0iocgomtehtast v8a5l3ue4bdy 1B00C.
Page Tot 15
sar
001695
I. wos
t40o0xieltthyBeiopletoragcnitecnatlaroyf acornndetsreonwltaetdea,rnd qfavuaelrbiatlgyees2dpietcaaificpgeesgrenorwdstthiexd,FatbeyTemtipnehfteorrimvaaectluiyto:en ia presented in Tle 3. Daoruer p'rWTeOhsBeeCnt1e2s6d,lesisn45,t`hTaan7b2l,e2.1545.8m9g6/TLoheTuXr723B8hE2oS0.u0rs TfEho5er0s9l6igshe2ou0er4xmpBoEasSleOsdLastnod2T55Hthes3a473/20l andthe' 96 dour WORT in 125 207i
Pa3ge 8 ot 15
oe cSmv ctLSE
01696
Tele 2. Growth data from toxicity test
CoHnocC setnotnrlatioE n ) -- uaberI ofaCells perwI NllilitieQrR x 10h (h5our)
t0.e0 re 12 1100 FHx 5 m2 aaes
s3n 1010 2n %2 33250 0ue
as 125 1110 110 %5a B05l4 m1E6n
am 10 5 @ 100 5
1s
2T 110 1120 15026 m3%
3 1100 1u0n 5 5a awm
50
123 11100 1n1 saat m1i3n0 m2i5s6
wn 10 i 5 126 m
500
215 11100 1110 N2u 2"5 12fl
an 10 Bn i a 1
1,000
12 110 10. 11 1. 1u
wa5 i1]0 5' 1i
5i 1i]
Page 9 ot 15
Sse cnmr oAL. FOSE
Table 3. Pferrocenttoxcihcaintgyetefsrtom control aad average specific growh rate
ConWcoernltration of TeesaetsS)ubatames
0.0 (control) as 1s 30 500 1,000
Mverrsogewssreatecific PeTrrcoenntcocnhtarrogle --L or o amr n Tr e se [ er ame e mem ser
0.04 0.03 0.045 0.00 0.000 0.009 0.0m 0.0m 10 15 0.003 0.03 0. os sm 18 0.03 00m 00 002m 3 0.010 0.0 0.00 002 Ma 0.000 0.008 0.000 0.001 100 6
0 0% TA 31 Bm 56% 100 5
Page 10 01 15
Becnve. mo 150K
Table 4. Wediun effective concentrations (BESO) from toxicity test
Tpreproisoudre
so
cof3i5depnecrecenTtints Taleeatthaotdion
hows 48 hours 72 hours 56 hours
25 man 07 mart.
nn 5 mn
-- 500 - 1,000 ng/L 2 - 325 warn. 22 - 293 mn
--
bisonial soviog average moving average
Page 11 ot 15
mc ec ve.Abo ALSO
001699
viz. arom
OBEiCoDt.ic 41m
s1y5s8t4e.ss.GuideMleitnheosd
f20o1r,TAelsgtai,ngGorfowtChhemTiacbailbsi.tionSeTcetsito.n
2:AdEofpfteecdtsJunoen
PSetrespobnuanl, cComEmaica1t9i03o.n.C.omputer'progran for calculation of LCSD values.
BU.oSt.tle ETes1t.9T0A-.G00/3T-h7e8-0S1e8l.essJsultyr,s 15c7a8p,ricorsutus Prints Mgsl Assay
Pagoee1122 0tot 15
Be cme ocAI
01700
ESTCOPY AVAILABLE
Aspen TATE GOUITT BAT TonTOSICITLTSE
-
TT
* BESTCOPY AVAILABLE tim en
adel
~ BESTCOPY AVAILABLE
Tote de Tepes semen te vty tet
..
oIo"
.,
awe
i
.
wa
Page 14 of 15
i"
----m
.)
co1703 [IR
Table 2. DE measured ducing tosicity test
conocveinntar]ation [2 0 (eonteon) as 1s 230 s00 1,000
Replicate
123 135 125 12 5 12 : 125
Tarwr de
210 1100.330 bet 103 w0Beo 13b2e 0abx} 7bb2xx Pae 7723 bt Ex} 5he2t 7722 ao 72 011 7722 07
Page 15 ot 15
mrceve. ton LS
i
#
i
Environmental Lab. Data Report Form
|
Parameter B=TC50-Algae -- 4p |
Tien7[Teso 350 |mall|ufal|
i
ro
Thos-g |zes|om_a3e fao t |]
rr
Thess |Tese 87 |wate |ofa |
Ties-Bslmm uo]
|
I I
Theg-4leo 14 |w|w|
11 1
Thos lhreensol1i7m0i|ow| || |
Tliog=
[ew
bso (=)| | |
TiboAz
To ow ]
JI
SE EE
_--
COTY
BEST COPY AVAILABLE
St rey p La Osa n petFor
Parametor_qk-HR-LC5O
FE freer]
Se ow[m ome
gmtallem lwo| mallba)|
o heeReersk eoye T[maolo e[Tal]a | pene
ia c po ee A|me e rehe
sia Jem] pT efete T1 ---- T-- | T 1-- 1 I ---- T|T 1
----
001706 |
MDAATTAERTSAHLEETSAFETY (Intermediate)
a3mM Center s5t5.144P-a1u0l,00 Minnesota 1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, ALL rights
2r0e0s0e,rveMdi.nnesCootpayinMginianngd/oanrd dMoawnnluofaadcitnugrinogf
Company. this
iisnfaolrlmoawteidonpfroorvidtehde pthuartp:ose of properly utilizing 3M products
1) tphreiorinfaogrrmeaetmieonnt iiss coobptiaeidnedinfrfuolmlaw,ithandno changes unless
2)
neither the distributed
copy with
nor the
the original intention of
is resold earning a
or otherwise profit thereon.
DIVISION: SPECIALTY MATERIALS MANUFACTURING DIV. MATFELRUIOARLO:CHEMICAL SALT FM-3820 F-8656 FN-4547 FM-4561 F-9459 0 NUMBER: 41-24610-02-780605-64-5081-241-2600-9459-8 41-2700-3820-5 41-2700-4547-3 ISSUSPUEERDS:EDEFSe:bruFaerbyrua29r,y 2105,002000 DOCUMENT: 04-1601-6
1. INGREDIENT
C.A.S. NO.
PERCENT
DIETHYLENE GLYCOL BUTYL ETHER...........
DL PERFLUOROALKYL
SULFONATE
SALTS..........
RESIDUAL ORGANIC FLUOROCHEMICALS........
112-34-5 35
LIC TradeSecret
24
Mixture
- a0 --4208
Unknown
TnhoeticfoimcpaotnieonntsreoqfuirtheimsentpsrodofuctTSCaAr.e iAnLLcomapplpilainccaeblewitchhemtihcealchemical iExnigsrteidnigentCshemiincatlhisSubmsattaenrcieasl a(rEeINElCiSs)t,edoronatrheeexEeumrpotpeapnolyImnevresntowrhyoseof monomers are listed on EINECS.
Tthheis rperpoodrutcitng cornetqauiinrsemetnhtes fooflloSweicntgiontox31i3c
chemical of Title
or chemicals subject III of the Emergency
to
Planning and DIETHYLENE
CGLoYmCmOuLnitByUTYRLighEtT-HTERo-Know
Act
of
1986
and
40
CFR
Part
372:
2. PHYSICAL DATA
BVAOPIOLRIPNRGEPSOSIUNRTE::......v.v.u.e.e.e.s.n.e.n.s.s.s.
> <
212 F 18 mmHg
[3
VAPOR DENSITY:.......vveeereess EVAPORATIONRATE:..............
NNI/DD
SOLUBILITY INWATER:........... SPECIFIC GRAVITY:..............
a1@.p0p8recK.ater=t
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
01707
MSDS: FLUOROCHEMICAL SALT FM-3820 F-8656 FM-4547 FM-4581 F-0459
February 29, 2000
*** 3M Internal Use Only ***
PAGE 2
2. PHYSICAL DATA (continued)
PERCENT VOLATILE:.......coouuen 72% PHEcveseiieaiienieinreeeneenes 10 = 10.5 VISCOSITY:.....eusvsssesssensns < 100 contipoise MELTING POINT: ..vvvvvvnennnnen. N/A APPEARANCE AND ODOR:
Slightly tinted liquid with butyl carbitol odor.
3. FIRE AND EXPLOSION HAZARD DATA
FLASH POINT:...evovuunarennsns > 212 F CC estimated
FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE: ...... N/D EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion.
4. REACTIVITY DATA
STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
None known. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Oxides of Sulfur, Hydrogen Fluoride, Toxic Vapors, Gases or Particulates.
01708 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: FLUOROCHEMICAL SALT FM-3820 F-8656 FM-4547 FM-4581 F-9450
February 29, 2000
*++ 3M Internal Use Only ***
PAGE 3
5. ENVIRONMENTAL INFORMATION
SPILL RESPONSE:
Observe spill.
Cporveecrauwtiiotnhsafbrsoomrbeontthermatseercitailo.ns. ColVleencttilastpeillaerdea.mateCroinatla.in
Clean up residue with water. Place in a closed container.
RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility. Combustion products will include HF.
ENVIRONMENTAL DATA: BIODEGRADATION: Chemical Oxygen Demand (COD): 1.00 g/g 5-Day Biochemical Oxygen Demand (BODS): 0.170 g/g 10-Day Biochemical Oxygen Demand (BOD10): 0.355 g/g 20-Day Biochemical Oxygen Demand (BOD20): 0.531 g/g 28-Day Biochemical Oxygen Demand (BOD28): 0.428 g/g
AQUFAaTtIhCeadTOXmIiCnInToYw: (Pimephales promelas) 96-hr LC50: 9.3 mg/L Water flea (Daphnia magna) 48-hr EC50: 115 mg/L Algae (Selenastrum capricornutum) 72-hr IC50: 380 mg/L Microtox (Photobacteriun phosphoreum) 30-min EC50: > 1000 mg/L Activated Sludge Respiration Inhibition 3-hr EC50: > 1000 mg/L
REGULATORY INFORMATION: Volatile Organic Compounds: N/D. VOC Less H20 & Exempt Solvents: N/D.
since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous).
The components of this product are in compliance with the chemical registration requirements of: TSCA, EINECS, CDSL, AICS, MITI.
OTHER ENVIRONMENTAL INFORMATION: This product contains one or more organic fluorochemicals that have the potential to resist degradation and persist in the environment.
EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No
REACTIVITY: No
ACUTE: Yes
CHRONIC: No
01709 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: FLUOROGHEMICAL SALT FM-3820 F-8656 FM-4547 FM-4581 F-9459
February 29, 2000
*++ 3M Internal Use Only ***
PAGE 4
6. SUGGESTED FIRST AID
EYE CONTACT: Inmediately
flush
eyes
with
large
amounts
of
water
for
at
least
15
minutes. Get immediate medical attention.
SKIN CONTACT: Flush skin with
large
amounts
of
water.
If
irritation
persists,
get
medical attention.
INHALATION: Remove person
to
fresh
air.
If
not
breathing,
give
artificial
respiration. If breathing is difficult, get immediate medical
attention.
IF SWALLOWED: If swallowed,
call
a
physician
immediately.
Only
induce
vomiting
at
the instruction of a physician. Never give anything by mouth to an
unconscious person.
7. PRECAUTIONARY INFORMATION
EYE PROTECTION: Avoid eye contact with vapor, spray, or mist.
Wear vented goggles.
SKIN PROTECTION: Avoid skin contact.
Wear appropriate gloves when handling this
material. A recommended:
pair of gloves butyl rubber,
made from neoprene.
the following material(s) Use one or more of the
are
following contact:
personal protection items as necessary apron, coveralls. Protective garments
to prevent skin (other than gloves)
sphooluyledthbyelemnaed/epolofyvieintyhleirdenofe
the following materials: chloride (Saranex).
RECOMMENDED VENTILATION: If exhaust ventilation
is
not
adequate,
use
appropriate
respiratory
protection. Provide concentrations below
ventilation recommended
adequate exposure
to control vapor limits and/or control
spray
or mist.
RESPIRATORY PROTECTION: Avoid breathing of airborne material.
Select one of the following
NIOSH approved respirators based on contaminants and in accordance With
airborne concentration of OSHA regulations: Half-mask
ovragpaonricrevsappiorratorreswpiitrahtodruswti/tmihstdusptr/emfiilstterp.refilter, full-face organic
01710 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MFSeDbSr:uarFyLU2O9R,OCH20E0M0ICAL SALT FM-+3+8+203MF-I8n6t5e6rnaFlN-4U5se47OFnMl-y45*8*1* F-9459 PAGE 5
7. PRECAUTIONARY INFORMATION (continued)
PREDoVENnTotIONeatO,F AdCrCiInDkENoTrALsmoIkNeGESwThIeOnN:using this product. Wash exposed abreefaosretheoatrionugg.hly with soap and water. Hash hands after handling and
RECSOtMorMeENDaEwDaySTfOrRoAnGEa:reas Where product may come into contact with food odregrpeheasrmaC)c.eutiSctaolrse. atSttoermeperaattutreemsperaabtouvrees32bdeelgowree1s20Fde(g0redeesgreFes(49). Kveeenptilcaotnetdainaerera.closed when not in use. Keep container in well-
FIRKEeeApNDcoEntXaPiLnOeSrIONtiAgVhOtIlDyANcClEo:sed. Keep away from heat, sparks, open flame, and other sources of ignition. Combustible liquid and vapor.
OTHNEoRsmPoRkEiCnAgU:TISOmNoAkRiYngINFwOhRiMlAeTIuOsNi:ng this product can result in cofonttaheninhaatziaorndouofs tdheecontpoobsaicctoionandp/roorducstusokemeanntdionleedadintothteheRfeoarcmtaitviiotny Data section of this SDS.
HHIS HAZARD RATINGS: HPEEARLSTOHN:AL2PROFTLEACMTMIAOBNI:LITXY:(S0ee RpErAeCcTaIuVtIiToYn:s, 0 section 7.)
EXPOSURE LIMITS
INGREDIENT
VALUE UNIT TYPE AUTH SKIN
WDAITEETRH.Y.LE.N.E..G.L.Y.C.OoLcoBUoTeYsLiiEeTeHeEsR.i.i.i.i.i.e.s. PREESRIFDLUUAOLROAOLRKGYALNICSULFFLOUNOARTOECHESMAILCTASL.S...........
3N5ONE NPOPNME 00..11 MMGG//MMa3
TNHOANE CNHOANGE TTWWAA 33MM YY
t+heSKIpNotNeOnTtAiTaIlONc:ontrLiibstuetdionsutbostatnhceesoveirnadlilcateexdpowsiutrhe b'yY' thuendecrutSaKnIeNousrefreoruteto ibynclduidriencgt cmounctoaucstmweimtbhranteheansdubseytea,ncee.itheVrehibcyleasirbcoarnnealtore,r msokrien apabrstoircputliaornl.y,
SO3UMR:CE OFaMEXRPOeScUoRmEmenLdIeMdITEDxApToAs:ure Guidelines CMR: Chemical Manufacturer Recommended Exposure Guidelines
- NONE: None Established
01711
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
FMSeDbSr:uarFyLU2O9R,OG2H0E0M0ICAL SALT FH-+3+8+20aMF-I8n6t5e6rnaFlN-U4s5e47OnFlMy-45*8*1* F-0459 PAGE 6
8. HEALTH HAZARD DATA
EYESevCOeNrTeACETy:e Irritation: signs/synptoms can include redness, swelling, ppaoisns,iblteearpienrgm,anecnltoluydyiampppaeiarreadncveisioofn.the cornea, impaired vision and
SKMIiNldCONSTkAiCnT:Irritation: signs/synptons can include redness, swelling, and itching.
tMhaoysebecaaubsseodrbebdy tihnrhoaulgahtiotnheansdk/ionranidngepsrtoidounc.e effects similiar to
INCHeAnLtATrIaOlN:Nervous Systes Depression: signs/symptoms can include shelaudrarcehde,spedeiczhz,inegsisd,dindersoswsiannedssu,ncoinnsccoioorudsinneastsi.on, slowed reaction tine,
single overexposure, above recommended guidelines, may cause:
sIorrreinteastsionof (tuhpepernosreesapnidrattohrryo)a:t, sciogungsh/isnygnptaonmdssncaeneziinngc.lude
IFASnWiAmLaLlOWsEtDu:dies conducted on organic fluorochemicals which are present linosst,hislospsrodoufctappientdiitcea,teleetfhfaercgtys, ianncdludnienugrolloigviecrald,istpuarnbcarnecaetsi,c, Weight eafdfreecntasl farnodmhaenmattiocliopgaitcedefefxepcotssu.reThteoretheasree onrogaknniocwnflhuuomraonchheemailctahls when used as intended and instructed.
Ingestion may cause:
Adsipfifriactuilotny bPrreeautmhoniintgi,s:wheseizginnsg/,syacpotuognhsingcanupinbclloouddeancdougphnienugm,onia, which can be fatal.
WIHNIDLIEVIDTUHAELFIONLLGORWEIDNIGENTESFFEICNTSTHIASREPARSOSDOUCCTIATAENDD AWRIETHROENQEUIROERDMTOOREBEOF THE TIHNECYLUADREED NOONTTEHEXPEMCSDTSEDBYEFTFHEECTSU.SD.URIONSGHAFHOAREZSAEREDABCLOEMMUUSNEICAOFTIOTNHISSTAPNRDOADRUDC,T.
Ingestion may cause:
iInrcrliutdaetiopnaino,f vGoamsittrionign,tesatbidnoamlinaTlisstueensd:ernseisgsn,s/snyaauspetao,msblcaonod in vomitus, and blood in feces.
Central Nervous System Depression: signs/symptoms can include ihenacdoaocrhdei,natdiioznz,inesslso,weddrorwesaicnteisosn, tmimues,culfaartigwueea,knebslsu,rred vision,
01712
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: FLUOROGHEMICAL SALT FH-3820 F-B656 FM-4547 FM-4581 F-9450
February 29, 2000
+ 3M Internal Use Only ***
PAGE 7
8. HEALTH HAZARD DATA (continued)
slurred speech, giddiness, tremors and convulsions. OTHTEhRisHEpArLoTdHuctHAZcAoRnDtaiInNsFORoMnAeTIoOrN:more organic fluorochemicals that have
the potential to be absorbed and remain in the body for long periods aofcctuimmuel,ateeitwhietrh arseptehaetedpareexnptosumroelse.culTeheroer aasrementoabkonloiwtnesh,umaanndhmeaalyth effects from anticipated exposure to these organic fluorochemicals when used as intended and instructed. The presence of organic fluorochemicals in the blood of the general pdaotpiunlgatiboanckantdo tshuebpo1p9u7l0a'st.ionGsM,'ssuecphideasmiowolrokgeircsa,l hsatsudybeeonf pitusblioswhned workers indicates no adverse effects.
SECTION CHANGE DATES
PHYSICAL DATA SECTION CHANGED SINCE February 15, 2000 ISSUE
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
TbehecoirnrfeocrtmataisonofinthtehidsateMatiesrsuieadl. Sa3fMetyMADKaEtSaNSOheWeAtRRA(NMTSIDESS), isEXbPeRlEiSeSvEeDdOtRo IWPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF wPhEeRtFhOeRrMANtChEe O3RM UpSrAoGdEuctOFisTRAfDiEt. foUrsearpaisrtirceuslpaornsipbulreposfeoranddetesrumiitnaibnlge for ucasner'asffmecetthotdheofuseuseandoraapppplliiccaattiioonn.of GaivGeMnprthoeducvta,riestoymeofoffWahcitocrhsartehat uthneiquuesleyr weivtahliunatethetheus3eMr'sprokdnuocwtledtgoedaentdermcionnetrowlh,ethietrisitesissenftiitalfotrhaat particular purpose and suitable for user's method of use or application.
3DuMeptroovitdheesriemnoftoermaptoisosnibiinliteylectthratonieclefcotrrmoniacs atrasnesrfveircematyo ihtasvecursetsoumletresd.
irneperrersoernst,atioomnisssiaosnstooritsaltceormaptlieotnesnesisn
this information, 3M makes or accuracy. In addition,
no
iinnffoorrmmaattiioonn oinbtatihenedMSfDrSomavaaidlaatbalbeasdeiremcaytlynotfrobme aGMs. current as the
01713