Document 1Q0jRn4Bokr5KLrmxkNxzaKEE

} BEST COPY AVAILABLE ARI6-O 122 st comnts -- -- i Perforning Laboratory | ) aie 1 at 15 1 Pomc chs,nc. SunyofMULPORE 001689 1. sommar ccoonpdruicctoTrehnduetufno,arcuteis the Tovirosystens Cotndoepxsaiccnriyitbyfeodr o9f6inboatTrhNsis 3f2i0nal during toretpohret. Moril 33 sigs,The. to Nay Setleesst.sstwrauss 3, 1991, at Divisio of Resource Aaslysts, Toc. ia Eakptors Her RSatmapnafboirxde,."RoberItt Bovearsi,`caonndduTcitneodthybyWarJde.sase Megas, Peter Kowalsii, Flies tceonnpceernattTruharetei'onsotfestof"23.vE0aessC.t SpuebrTsfhtoearnsdcsidelutiaoubndndew4radtielrsuttavitaoisncsvyacatotenhrdeitticcioonntmrseodliaviattphreapamfreiewvden Lviisthht ht swvtaedsr'ileagjBduoesutireosdnizdetudock.'w4a0teNrou.abiinns/Flsleacsc/kossntcevenrtveriatthiinocnausbaotPfehdFotIoonpe3r582i6ordovteaorrfey:2s40hhimtaoelwrts. F(ocwoinatarlol)c,once62n.t5ratwiao/nis.'ver1e35use`dwiffL,or a21510 cmatgc/uliatiSo0n0s.m/l. sad 1.000 seri. mrveisntteeidnMead {enunsduesred72tesiton ucrotnhdeiCtSitDoensst.11v4aEsxwposfaurroTesH/o3fa8l3s0lgieansn-dhto2ousnetohecoubltsteesutrrveesdutbhsaettffaenvccites c25o5nc2e0nt/r1at4inodn125"(WmOgK/C)L, rleesspsecttihvaesly6.2.5 g/L. The 96 hour BESO. aed ROC are Page 2.00 15 resem 001590 EE BEST COPY AVAILABLE A-- xr na VIL. References n 001691 Im. nom or mus ne ble 1. CSLhieeaa?mpilcemaeldofiacdheafirooarncittezorenidizcaiwttaiytoenrtesuotfsed3 vroeprpreespeaartea.tive . Table 2. Growth data from toxicity test 5 Table 3. PSeprecceintticchgarnagveidfrroantecofnrtormoltoaxnidcitayvertaegset 10 Table 4. Mferdoinantoexfifceicttyivteestconcentrations (E508) n Table A.1. Temperature seasured durisg toxicity test 1 Tebl1e A.2. 5H nessureded duciduringng ttooxicciityty tentesty 15 Paoge dot 15 cn etore.Sm AALS 001692 . omoscrion bjectivTehis"ofsttuhdeystwuadsy wassptooadsatoberryaeiIsdNe tCohmepuarcyu,teStt.oxPiacsilt,y oNfismFeNso3t8a3.0 tTohse aEnrdesbumaatteerria"allsga. eapTlhoyeedreporitn conttheainsstsaeicrt.ionsantdhatthdeescrriedmelttshe onfetdotdhse tihnevewsattiegratiqouna.lityThedaFtepocrotlleacltseedcdounrtiaiongsthaen atperpte:ndix that presents Tost sTasTance: v. Tons wo mms EboovtitcloesyTsUttheant0s20vaoso (EFlaoavrbieeraloblSeeyrdstesw13si,thSu1m9tp3h0le.e foNIltelodvveiarass ci9onn6ftHoari)mnaetdwioainsa:a d8e3l5i02v8e6Ar0L-e5dg,lasTtsXo 3Bu0s0h "AvenTuHe, 31St2.0 PGaaul,paleMioymeelslootws.liquidP)riovrastosupupsleietdhebytes3t1 mCoamtpearniya,l v9a3s5 1st.o0regdramsi)a +1f1h1e bedarakrcahtivezdoosattEesnpveirraatbuyrset.nsAforreservaeissiemmepnleof(1s0pppreoaxrisr.atels DruorIon vam: atepsptrionxgiWmaatwteaersly usst"8ee.dr0i.leforRsaearsciuccllhtiessdatoifmoendicaohfemit(ce0as.lt5.osrEmgFiaAln,yissimss19o7a8sf)dafworiretpharlelsaetnot3xaHitciivtoefy Tsatbalpele1.`of deioaiied water used to prepare the media are presented in Test organs: tdheelivCeurleKtdiugraeeto CEuouslvelidercoftsoriroanttehsesofteosnAtlgAawpearsilatfr12ot,nhes19Uc9n0ui.lvetrusrTiehteyorioidfgeisTnteiaxtlaylsyopforotcAhuuersetcidunltfu1rrnoedn wSirsamaVteerricteidsdtouaisntgerilien Aenprpircohperdiatemedfsaosicdaeiscticakley.fo medTihae usceudltufroer tvhaiss test 20d maatained at test conditions. TorterTy TestonG: c3.ondu19c9t0eT.d7he adta"Tltiani"litasirvgeeBrasettdoexmoipceoirtapytruorceteedsoutfrew3s2aso3fpertCfheorvsOietRdhDdtui(rr1ie9n8g0c)o.nAcpeeniTtlhera2t9tieosttnosMvaoasfy 3] diTisels.tutiposrunebpsatrwaeandtceer'fo"4c2dodln1tuaatiainioelndutwiadotnner,aihteeTrhetecsostn.ttorcokvle.sssoellXusti1o,nv0i0t0vhaormsats/ikdetsdhteodckiruesecoteltyoifotno SToclovnetnrto.l), 6N2.o5sinwaaflt,co1n3c5enat/ria.tio5n0s nogf/L,t5he00 staefslt, maaatder1i,a0l00 svearseh:. 0 sift ; { | Page Sot 15 i Table 1. Cdheeimciaciatled wcahtaerractuesredizaftoipornepoafre afestrepperdeissentfaotrivteoriscuimtpyletesotf Parameter Kaeristuroefsent Reiponritting orpgeasntoicchildoesrine wan 2 Opersgtaincoipdheossphorus walt os Pbioplhyeennrtlosrinated wn os Note: WD = sot detected st or above the reporting Timit WVeaaslaureed EB Page 6 of 15 re sg c2epticpaetNretososreaoefd a"SsSaach2rt50raessdatolaaslgnyltassaatnSdtrhleesesFeaqytueelrloyffl1ad0si,k0ss0t0etihabctietllecsdo/natlasiannegdToe1t0ht0resentel STetersitn(gli"tta"sTsheselcsi.u3t6ivohenor.uerrTuLhneesdtonfll(ay4skaTsrarnavdneogrneedncuaompnbpeeradsrvtoiattbahlreyjsvoahvsaekrteuersdedignltaaosossielbneecacuktbeartsto.hre Jvaoscatinoenintu`oifnedeavchithvescsoeoll)-.bitAe24flhsoourrescleiagthtlaiagdhts0 htohautr pdraorvkidpehdotoapelriighotd intensity of 0 upstart. vReimssucayltloyTnheeteevres.rayber34Thoefboaaprlhsg.a(lbbeyccekslalseans/sawloodfealdeipraFeccht12tneismtcetreovrse)csosepvliacsvacdsoeutnedtresatiesrvemidinteih4dn STihcehn te`smetrcuCrlyashthem`astoatshteen)b"eginvnaisngsaensdsucroedd ofadtherteecsotr,dedanddtaeimlpyeriantutrhee incubator. smarzsTion. wevRons: sRteatthiosttiRcevasalusltsuresceohdfaigDutyehse thte(oSrtaieucpthihatonyr, t1to9e8sc3ta)l.cwuTelhraeetebiEinCnoSta0eirspvlraeltoufeedsmoubvsiyinnggstasavosemdirsnacagdle CDVTouahnnrecgieeantn`ttcmr'aetasitria(olRntOseVlsAot]og.f|owlfheiTscthh[etheiasnvbcemslrutuaaadgbseeecsres.opafe|cicfpeTialhcrleassgerpWtoerwrOitEchalrvoaaattnsee-9wvacaysahloccuuarsllsaacutulweylidsanitssuesditnoahgfse fSbaxttpruoarsaculrteiolgopgeritoohfde. |tshwemTphlese.umbpieevrrecreanogtfe Average. specific groeth rate, cesclphleascnigfepiecr dividing fagrlroonwattcho0ntrbraootulersfisrdoincvailtdcheuedlactuoeyadtrtohbley that vile by the mrerage Specifpirc e"trowtchhagreaketirnontheconctorntorlolmahnd mwieetdipl1y0iocgomtehtast v8a5l3ue4bdy 1B00C. Page Tot 15 sar 001695 I. wos t40o0xieltthyBeiopletoragcnitecnatlaroyf acornndetsreonwltaetdea,rnd qfavuaelrbiatlgyees2dpietcaaificpgeesgrenorwdstthiexd,FatbeyTemtipnehfteorrimvaaectluiyto:en ia presented in Tle 3. Daoruer p'rWTeOhsBeeCnt1e2s6d,lesisn45,t`hTaan7b2l,e2.1545.8m9g6/TLoheTuXr723B8hE2oS0.u0rs TfEho5er0s9l6igshe2ou0er4xmpBoEasSleOsdLastnod2T55Hthes3a473/20l andthe' 96 dour WORT in 125 207i Pa3ge 8 ot 15 oe cSmv ctLSE 01696 Tele 2. Growth data from toxicity test CoHnocC setnotnrlatioE n ) -- uaberI ofaCells perwI NllilitieQrR x 10h (h5our) t0.e0 re 12 1100 FHx 5 m2 aaes s3n 1010 2n %2 33250 0ue as 125 1110 110 %5a B05l4 m1E6n am 10 5 @ 100 5 1s 2T 110 1120 15026 m3% 3 1100 1u0n 5 5a awm 50 123 11100 1n1 saat m1i3n0 m2i5s6 wn 10 i 5 126 m 500 215 11100 1110 N2u 2"5 12fl an 10 Bn i a 1 1,000 12 110 10. 11 1. 1u wa5 i1]0 5' 1i 5i 1i] Page 9 ot 15 Sse cnmr oAL. FOSE Table 3. Pferrocenttoxcihcaintgyetefsrtom control aad average specific growh rate ConWcoernltration of TeesaetsS)ubatames 0.0 (control) as 1s 30 500 1,000 Mverrsogewssreatecific PeTrrcoenntcocnhtarrogle --L or o amr n Tr e se [ er ame e mem ser 0.04 0.03 0.045 0.00 0.000 0.009 0.0m 0.0m 10 15 0.003 0.03 0. os sm 18 0.03 00m 00 002m 3 0.010 0.0 0.00 002 Ma 0.000 0.008 0.000 0.001 100 6 0 0% TA 31 Bm 56% 100 5 Page 10 01 15 Becnve. mo 150K Table 4. Wediun effective concentrations (BESO) from toxicity test Tpreproisoudre so cof3i5depnecrecenTtints Taleeatthaotdion hows 48 hours 72 hours 56 hours 25 man 07 mart. nn 5 mn -- 500 - 1,000 ng/L 2 - 325 warn. 22 - 293 mn -- bisonial soviog average moving average Page 11 ot 15 mc ec ve.Abo ALSO 001699 viz. arom OBEiCoDt.ic 41m s1y5s8t4e.ss.GuideMleitnheosd f20o1r,TAelsgtai,ngGorfowtChhemTiacbailbsi.tionSeTcetsito.n 2:AdEofpfteecdtsJunoen PSetrespobnuanl, cComEmaica1t9i03o.n.C.omputer'progran for calculation of LCSD values. BU.oSt.tle ETes1t.9T0A-.G00/3T-h7e8-0S1e8l.essJsultyr,s 15c7a8p,ricorsutus Prints Mgsl Assay Pagoee1122 0tot 15 Be cme ocAI 01700 ESTCOPY AVAILABLE Aspen TATE GOUITT BAT TonTOSICITLTSE - TT * BESTCOPY AVAILABLE tim en adel ~ BESTCOPY AVAILABLE Tote de Tepes semen te vty tet .. oIo" ., awe i . wa Page 14 of 15 i" ----m .) co1703 [IR Table 2. DE measured ducing tosicity test conocveinntar]ation [2 0 (eonteon) as 1s 230 s00 1,000 Replicate 123 135 125 12 5 12 : 125 Tarwr de 210 1100.330 bet 103 w0Beo 13b2e 0abx} 7bb2xx Pae 7723 bt Ex} 5he2t 7722 ao 72 011 7722 07 Page 15 ot 15 mrceve. ton LS i # i Environmental Lab. Data Report Form | Parameter B=TC50-Algae -- 4p | Tien7[Teso 350 |mall|ufal| i ro Thos-g |zes|om_a3e fao t |] rr Thess |Tese 87 |wate |ofa | Ties-Bslmm uo] | I I Theg-4leo 14 |w|w| 11 1 Thos lhreensol1i7m0i|ow| || | Tliog= [ew bso (=)| | | TiboAz To ow ] JI SE EE _-- COTY BEST COPY AVAILABLE St rey p La Osa n petFor Parametor_qk-HR-LC5O FE freer] Se ow[m ome gmtallem lwo| mallba)| o heeReersk eoye T[maolo e[Tal]a | pene ia c po ee A|me e rehe sia Jem] pT efete T1 ---- T-- | T 1-- 1 I ---- T|T 1 ---- 001706 | MDAATTAERTSAHLEETSAFETY (Intermediate) a3mM Center s5t5.144P-a1u0l,00 Minnesota 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, ALL rights 2r0e0s0e,rveMdi.nnesCootpayinMginianngd/oanrd dMoawnnluofaadcitnugrinogf Company. this iisnfaolrlmoawteidonpfroorvidtehde pthuartp:ose of properly utilizing 3M products 1) tphreiorinfaogrrmeaetmieonnt iiss coobptiaeidnedinfrfuolmlaw,ithandno changes unless 2) neither the distributed copy with nor the the original intention of is resold earning a or otherwise profit thereon. DIVISION: SPECIALTY MATERIALS MANUFACTURING DIV. MATFELRUIOARLO:CHEMICAL SALT FM-3820 F-8656 FN-4547 FM-4561 F-9459 0 NUMBER: 41-24610-02-780605-64-5081-241-2600-9459-8 41-2700-3820-5 41-2700-4547-3 ISSUSPUEERDS:EDEFSe:bruFaerbyrua29r,y 2105,002000 DOCUMENT: 04-1601-6 1. INGREDIENT C.A.S. NO. PERCENT DIETHYLENE GLYCOL BUTYL ETHER........... DL PERFLUOROALKYL SULFONATE SALTS.......... RESIDUAL ORGANIC FLUOROCHEMICALS........ 112-34-5 35 LIC TradeSecret 24 Mixture - a0 --4208 Unknown TnhoeticfoimcpaotnieonntsreoqfuirtheimsentpsrodofuctTSCaAr.e iAnLLcomapplpilainccaeblewitchhemtihcealchemical iExnigsrteidnigentCshemiincatlhisSubmsattaenrcieasl a(rEeINElCiSs)t,edoronatrheeexEeumrpotpeapnolyImnevresntowrhyoseof monomers are listed on EINECS. Tthheis rperpoodrutcitng cornetqauiinrsemetnhtes fooflloSweicntgiontox31i3c chemical of Title or chemicals subject III of the Emergency to Planning and DIETHYLENE CGLoYmCmOuLnitByUTYRLighEtT-HTERo-Know Act of 1986 and 40 CFR Part 372: 2. PHYSICAL DATA BVAOPIOLRIPNRGEPSOSIUNRTE::......v.v.u.e.e.e.s.n.e.n.s.s.s. > < 212 F 18 mmHg [3 VAPOR DENSITY:.......vveeereess EVAPORATIONRATE:.............. NNI/DD SOLUBILITY INWATER:........... SPECIFIC GRAVITY:.............. a1@.p0p8recK.ater=t Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately 01707 MSDS: FLUOROCHEMICAL SALT FM-3820 F-8656 FM-4547 FM-4581 F-0459 February 29, 2000 *** 3M Internal Use Only *** PAGE 2 2. PHYSICAL DATA (continued) PERCENT VOLATILE:.......coouuen 72% PHEcveseiieaiienieinreeeneenes 10 = 10.5 VISCOSITY:.....eusvsssesssensns < 100 contipoise MELTING POINT: ..vvvvvvnennnnen. N/A APPEARANCE AND ODOR: Slightly tinted liquid with butyl carbitol odor. 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT:...evovuunarennsns > 212 F CC estimated FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE: ...... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: None known. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Sulfur, Hydrogen Fluoride, Toxic Vapors, Gases or Particulates. 01708 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: FLUOROCHEMICAL SALT FM-3820 F-8656 FM-4547 FM-4581 F-9450 February 29, 2000 *++ 3M Internal Use Only *** PAGE 3 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Observe spill. Cporveecrauwtiiotnhsafbrsoomrbeontthermatseercitailo.ns. ColVleencttilastpeillaerdea.mateCroinatla.in Clean up residue with water. Place in a closed container. RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility. Combustion products will include HF. ENVIRONMENTAL DATA: BIODEGRADATION: Chemical Oxygen Demand (COD): 1.00 g/g 5-Day Biochemical Oxygen Demand (BODS): 0.170 g/g 10-Day Biochemical Oxygen Demand (BOD10): 0.355 g/g 20-Day Biochemical Oxygen Demand (BOD20): 0.531 g/g 28-Day Biochemical Oxygen Demand (BOD28): 0.428 g/g AQUFAaTtIhCeadTOXmIiCnInToYw: (Pimephales promelas) 96-hr LC50: 9.3 mg/L Water flea (Daphnia magna) 48-hr EC50: 115 mg/L Algae (Selenastrum capricornutum) 72-hr IC50: 380 mg/L Microtox (Photobacteriun phosphoreum) 30-min EC50: > 1000 mg/L Activated Sludge Respiration Inhibition 3-hr EC50: > 1000 mg/L REGULATORY INFORMATION: Volatile Organic Compounds: N/D. VOC Less H20 & Exempt Solvents: N/D. since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). The components of this product are in compliance with the chemical registration requirements of: TSCA, EINECS, CDSL, AICS, MITI. OTHER ENVIRONMENTAL INFORMATION: This product contains one or more organic fluorochemicals that have the potential to resist degradation and persist in the environment. EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: No 01709 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: FLUOROGHEMICAL SALT FM-3820 F-8656 FM-4547 FM-4581 F-9459 February 29, 2000 *++ 3M Internal Use Only *** PAGE 4 6. SUGGESTED FIRST AID EYE CONTACT: Inmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. INHALATION: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate medical attention. IF SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact with vapor, spray, or mist. Wear vented goggles. SKIN PROTECTION: Avoid skin contact. Wear appropriate gloves when handling this material. A recommended: pair of gloves butyl rubber, made from neoprene. the following material(s) Use one or more of the are following contact: personal protection items as necessary apron, coveralls. Protective garments to prevent skin (other than gloves) sphooluyledthbyelemnaed/epolofyvieintyhleirdenofe the following materials: chloride (Saranex). RECOMMENDED VENTILATION: If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide concentrations below ventilation recommended adequate exposure to control vapor limits and/or control spray or mist. RESPIRATORY PROTECTION: Avoid breathing of airborne material. Select one of the following NIOSH approved respirators based on contaminants and in accordance With airborne concentration of OSHA regulations: Half-mask ovragpaonricrevsappiorratorreswpiitrahtodruswti/tmihstdusptr/emfiilstterp.refilter, full-face organic 01710 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MFSeDbSr:uarFyLU2O9R,OCH20E0M0ICAL SALT FM-+3+8+203MF-I8n6t5e6rnaFlN-4U5se47OFnMl-y45*8*1* F-9459 PAGE 5 7. PRECAUTIONARY INFORMATION (continued) PREDoVENnTotIONeatO,F AdCrCiInDkENoTrALsmoIkNeGESwThIeOnN:using this product. Wash exposed abreefaosretheoatrionugg.hly with soap and water. Hash hands after handling and RECSOtMorMeENDaEwDaySTfOrRoAnGEa:reas Where product may come into contact with food odregrpeheasrmaC)c.eutiSctaolrse. atSttoermeperaattutreemsperaabtouvrees32bdeelgowree1s20Fde(g0redeesgreFes(49). Kveeenptilcaotnetdainaerera.closed when not in use. Keep container in well- FIRKEeeApNDcoEntXaPiLnOeSrIONtiAgVhOtIlDyANcClEo:sed. Keep away from heat, sparks, open flame, and other sources of ignition. Combustible liquid and vapor. OTHNEoRsmPoRkEiCnAgU:TISOmNoAkRiYngINFwOhRiMlAeTIuOsNi:ng this product can result in cofonttaheninhaatziaorndouofs tdheecontpoobsaicctoionandp/roorducstusokemeanntdionleedadintothteheRfeoarcmtaitviiotny Data section of this SDS. HHIS HAZARD RATINGS: HPEEARLSTOHN:AL2PROFTLEACMTMIAOBNI:LITXY:(S0ee RpErAeCcTaIuVtIiToYn:s, 0 section 7.) EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN WDAITEETRH.Y.LE.N.E..G.L.Y.C.OoLcoBUoTeYsLiiEeTeHeEsR.i.i.i.i.i.e.s. PREESRIFDLUUAOLROAOLRKGYALNICSULFFLOUNOARTOECHESMAILCTASL.S........... 3N5ONE NPOPNME 00..11 MMGG//MMa3 TNHOANE CNHOANGE TTWWAA 33MM YY t+heSKIpNotNeOnTtAiTaIlONc:ontrLiibstuetdionsutbostatnhceesoveirnadlilcateexdpowsiutrhe b'yY' thuendecrutSaKnIeNousrefreoruteto ibynclduidriencgt cmounctoaucstmweimtbhranteheansdubseytea,ncee.itheVrehibcyleasirbcoarnnealtore,r msokrien apabrstoircputliaornl.y, SO3UMR:CE OFaMEXRPOeScUoRmEmenLdIeMdITEDxApToAs:ure Guidelines CMR: Chemical Manufacturer Recommended Exposure Guidelines - NONE: None Established 01711 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately FMSeDbSr:uarFyLU2O9R,OG2H0E0M0ICAL SALT FH-+3+8+20aMF-I8n6t5e6rnaFlN-U4s5e47OnFlMy-45*8*1* F-0459 PAGE 6 8. HEALTH HAZARD DATA EYESevCOeNrTeACETy:e Irritation: signs/synptoms can include redness, swelling, ppaoisns,iblteearpienrgm,anecnltoluydyiampppaeiarreadncveisioofn.the cornea, impaired vision and SKMIiNldCONSTkAiCnT:Irritation: signs/synptons can include redness, swelling, and itching. tMhaoysebecaaubsseodrbebdy tihnrhoaulgahtiotnheansdk/ionranidngepsrtoidounc.e effects similiar to INCHeAnLtATrIaOlN:Nervous Systes Depression: signs/symptoms can include shelaudrarcehde,spedeiczhz,inegsisd,dindersoswsiannedssu,ncoinnsccoioorudsinneastsi.on, slowed reaction tine, single overexposure, above recommended guidelines, may cause: sIorrreinteastsionof (tuhpepernosreesapnidrattohrryo)a:t, sciogungsh/isnygnptaonmdssncaeneziinngc.lude IFASnWiAmLaLlOWsEtDu:dies conducted on organic fluorochemicals which are present linosst,hislospsrodoufctappientdiitcea,teleetfhfaercgtys, ianncdludnienugrolloigviecrald,istpuarnbcarnecaetsi,c, Weight eafdfreecntasl farnodmhaenmattiocliopgaitcedefefxepcotssu.reThteoretheasree onrogaknniocwnflhuuomraonchheemailctahls when used as intended and instructed. Ingestion may cause: Adsipfifriactuilotny bPrreeautmhoniintgi,s:wheseizginnsg/,syacpotuognhsingcanupinbclloouddeancdougphnienugm,onia, which can be fatal. WIHNIDLIEVIDTUHAELFIONLLGORWEIDNIGENTESFFEICNTSTHIASREPARSOSDOUCCTIATAENDD AWRIETHROENQEUIROERDMTOOREBEOF THE TIHNECYLUADREED NOONTTEHEXPEMCSDTSEDBYEFTFHEECTSU.SD.URIONSGHAFHOAREZSAEREDABCLOEMMUUSNEICAOFTIOTNHISSTAPNRDOADRUDC,T. Ingestion may cause: iInrcrliutdaetiopnaino,f vGoamsittrionign,tesatbidnoamlinaTlisstueensd:ernseisgsn,s/snyaauspetao,msblcaonod in vomitus, and blood in feces. Central Nervous System Depression: signs/symptoms can include ihenacdoaocrhdei,natdiioznz,inesslso,weddrorwesaicnteisosn, tmimues,culfaartigwueea,knebslsu,rred vision, 01712 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: FLUOROGHEMICAL SALT FH-3820 F-B656 FM-4547 FM-4581 F-9450 February 29, 2000 + 3M Internal Use Only *** PAGE 7 8. HEALTH HAZARD DATA (continued) slurred speech, giddiness, tremors and convulsions. OTHTEhRisHEpArLoTdHuctHAZcAoRnDtaiInNsFORoMnAeTIoOrN:more organic fluorochemicals that have the potential to be absorbed and remain in the body for long periods aofcctuimmuel,ateeitwhietrh arseptehaetedpareexnptosumroelse.culTeheroer aasrementoabkonloiwtnesh,umaanndhmeaalyth effects from anticipated exposure to these organic fluorochemicals when used as intended and instructed. The presence of organic fluorochemicals in the blood of the general pdaotpiunlgatiboanckantdo tshuebpo1p9u7l0a'st.ionGsM,'ssuecphideasmiowolrokgeircsa,l hsatsudybeeonf pitusblioswhned workers indicates no adverse effects. SECTION CHANGE DATES PHYSICAL DATA SECTION CHANGED SINCE February 15, 2000 ISSUE Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately TbehecoirnrfeocrtmataisonofinthtehidsateMatiesrsuieadl. Sa3fMetyMADKaEtSaNSOheWeAtRRA(NMTSIDESS), isEXbPeRlEiSeSvEeDdOtRo IWPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF wPhEeRtFhOeRrMANtChEe O3RM UpSrAoGdEuctOFisTRAfDiEt. foUrsearpaisrtirceuslpaornsipbulreposfeoranddetesrumiitnaibnlge for ucasner'asffmecetthotdheofuseuseandoraapppplliiccaattiioonn.of GaivGeMnprthoeducvta,riestoymeofoffWahcitocrhsartehat uthneiquuesleyr weivtahliunatethetheus3eMr'sprokdnuocwtledtgoedaentdermcionnetrowlh,ethietrisitesissenftiitalfotrhaat particular purpose and suitable for user's method of use or application. 3DuMeptroovitdheesriemnoftoermaptoisosnibiinliteylectthratonieclefcotrrmoniacs atrasnesrfveircematyo ihtasvecursetsoumletresd. irneperrersoernst,atioomnisssiaosnstooritsaltceormaptlieotnesnesisn this information, 3M makes or accuracy. In addition, no iinnffoorrmmaattiioonn oinbtatihenedMSfDrSomavaaidlaatbalbeasdeiremcaytlynotfrobme aGMs. current as the 01713