Document 174ydeMaBVeBg37xxMMEMkBK
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THE IAITE1) STATES OF MIKHHA
AmiOTtHHOaBUHlESE! BRESENTS1, SHAitTi.^MlElh UNITED STATES DEPARTMENT OF COMMERCE
United States Patent and Trademark Office
January 12,2000
TfflS IS TO CERTIFY THAT ANNEXED HERETO IS A TRUE COPY FROM THE RECORDS OF THIS OFFICE OF:
U.S. PATENT: 2,986,379 ISSUE DATE: MAY30,1961
By Authority of the COMMISSIONER OF PATENTS AND TRADEMARKS
. MONTGOMERY Certifying Officer
May 30, 1961
Filed June 4, 1957
R. E. KRAMIG, JR HEAT EXCHANGER
2,986,379
3 Sheets-SJieet i
Vr H[ 2
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INVENTOR ROBERT E. KRAMIG,JR, DECEASED, BY ANNA LOUISE KRAMIG .EXECUTRIX
BY
ATTOZHtyS.
May 30, 1961
Filed June 4, 1957
R. E. KRAMIG, JR HEAT EXCHANGER
2,986,379
3 Sheets-Sheet 2
74*.
BY ANNA LOUISE KRAMIG, EXECUTRIX
BY
ATTOZUSyS.
May 30, 1961
Filed June 4, 1957
R. e. kramig, jr
heat exchanger
,2 986,379
3 Sheets-Sheet 3
Q
i
INVENTOR. ROBERT E. KRAMIG , JR.,DECEASED BY ANNA LOUISE KRAMIG, EXECUTRIX BY
ATTOHEy&.
12
air passageways from becoming clogged so that the effi
ciency of the heat exchanger does not decrease with age.
2,986,379
A still further advantage of the present heat exchange unit is that it is economical to manufacture and install.
HEAT EXCHANGER
8 In the present process of producing heat exchangers,
Robert E. Kramig, Jr., deceased, late of Wyoming, Ohio,
by Anna Louise Kramig, executrix, 615 S. Springfield
commercial asbestos papers having fibers running par allel to the length of the paper, is first impregnated with
Pike, Wyoming 15, Ohio
a phenolic resin, such as Bakelite. The impregnated
sheet is then heated sufficiently to partially set the resin
Filed June 4,1957, Ser. No. 663,544 8 Claims. (CL 261---28)
10 after which the sheet is corrugated. Subsequently, this corrugated sheet is brought into contact with a similarly impregnated flat sheet, a layer of adhesive, such as poly
vinyl acetate or a phenolic glue being applied between
the two sheets. The two sheets are pressed together
' This invention relates to heat exchangers and is par ticularly directed to novel core units for use in water
15
with the adhesive between them and are heated in any suitable maimer, such as by means of an infra-red heat
cooling towers and to a method of fabricating such core
oven to a sufficiently high temperature to fully set the
units.
phenolic resin. The composite corrugated and flat sheets
Heretofore, many different types of heat exchangers
are then cut to proper size for assembly into a contact
have been proposed for use in connection with water 20 core. The contact core is fabricated by placing a plu cooling towers. In such devices, it is conventional to rality of composite sheets next to one another, the sheets
introduce air at the bottom of the exchanger and water
being arranged so that the corrugated and flat sheets are
at the top of the exchanger so that the water drips down
alternated. Adjacent sheets are secured together by
wardly through a core member. At the same time, air
means of a suitable adhesive to produce a core sub
is forced upwardly through the core to create a counter current flow in which the water is cooled by evaporative
25
unit. Finally, these core sub-units are stacked together to form a heat exchanger core of any desired dimension.
action.
Alternatively, large sections of the composite sheets are
The principal object of the present invention is to stacked and glued together after the sheets have been
provide a novel core for use in water cooling towers of
finally set The large sheet sections which are secured
this general type which will provide a maximum amount 50 together in this manner form a large unit which can
of cooling action in a minimum space and which even
be sawed or otherwise cot to produce cores of the desired
after extended periods of use, will not deteriorate or size.
become covered with fungus growth.
Cores fabricated in this manner are very light in
More particularly, the present invention contemplates
weight and may be preassembled at the factory and
' heat exchange core comprising a plurality of sinuous, r corrugated, sheets separated by generally planar
35
readily can be
transported to the installation site, where erected by a relatively small labor force.
they The
divider sheets. In die preferred embodiment, die corru
ernes are inherently rigid and self-supporting so that
gated sheets and divider sheets are formed of an asbestos
it is only necessary to support the edges of the core
paper impregnated with a phenolic resin which is ther
within the tower, eliminating the need for expensive sup
mally define
set The corrugated sheets and divider sheets a plurality of vertical tubular passageways, the
40
porting structure including perforated platforms or the like. Consequently, the present cores are not only eco
sheets being oriented so that the asbestos fibers extend
nomical to produce, but they are economical to install as
transversely of the passageways. In use, water is sprayed
welL
onto the core and flows downwardly through the tubu
These and other objects and advantages of the present
lar passageways. Hus water is contacted and cooled by streams of air flowing upwardly through the same pas
45
invention will be more readily apparent from a considera tion of the following detailed description of the drawings
sageways.
illustrating a preferred embodiment of the invention.
A heat exchange core of this type is substantially
In the drawings:
more efficient than comparable heating cores formed of
Figure 1 is a vertical cross sectional view in diagram
wood, metal or the like. I have determined that this 50 matic form of a water cooling tower constructed in ac
increased efficiency is doe in part to the excellent weta-
cordance with the present invention;
bility of an asbestos sheet impregnated with a thermally
Figure 2 is a partial perspective view of a typical
set phenolic resin. I have farther determined that the
water-air contact core to be used in a tower, such as
orientation of asbestos fibers transverse to the passage
the tower shown in Figure 1;
ways also contributes to the increased efficiency, since 55 Figure 3 is a vertical cross sectional view of a tower
the transverse fibers tend to break up any stream of
similar to the one shown in Figure 1, the section being
water causing the water to Sow in a thin film over the
taken at right angles to the section of Figure 1;
entire surface of the sheet. Thus, the rate of water passage is retarded and a maximum surface of water is exposed to contact with the counter current air stream.
A heat exchanger of the present invention is also highly advantageous since it can be kept in use for an indefinite length of time without cleaning or repair. The resin impregnated asbestos sheets are not affected by
Figure 4 is an end view of a modified form of con tact core which may be used in a tower such as that 60 shown in Figure 3;
'Figure 5 is an end view of a second modified form of contact core;
Figure 6 is a diagrammatic view of equipment for the
contact with water and do not rot, corrode or deteriorate in any other manner.
practice of the initial steps of the method of preparing 65 phenolic resin impregnated asbestos paper according to
Moreover, 1 have discovered that an asbestos sheet
this invention;
having a thermally set phenolic resin is self-disinfecting-,
Figure 7 is a diagrammatic view of equipment for the
that is, the material inhibits fungus or other microorganic
practice of farther steps in the manufacture of the contact
growth so that no slime coating forms on the heat ex changer in use. This self-cleaning action of die core
70
core, utilizing inFignre6;
paper
made
by
the
Initial
steps
disclosed
is extremely important since it prevents the water and
Figure 8 shows diagrammatically a cutting mechanism
Coev provided bv USPTO from the CSIR Imaoe Database on 01-07-2000
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shown in Figure 7 in lieu of the rolling mechanism;
per inch.
Figure 9 is an enlarged side elevational view of the
In operation, the water to be cooled flows downwardly
phenolic resin impregnated composite sheet as it emerges, through the passageways or interstices 31 formed between
from the oven in Figure 7;
6 the corrugations and the adjacent divider sheets. The
Figure 10 is a top plan view of the sheet shown in Fig
water thoroughly wets the sheets and is spread over the
ure 9;
entire surface of the sheet by the transverse ridges formed
Figure 11 is an enlarged top plan view of a typical por
by the horizontally oriented fibers. These fibers function
tion of any of the cores shown in Figures 1-5; and
very effectively to diffuse the water, to slightly impede its
Figure 12 is an end view of a third modified form of 10 flow and to prevent the formation of any streams or rivu
core.
lets. At the same time that water drips downwardly over
One preferred form of evaporating water cooling tower
the core surface, air flows upwardly through the passage
embodying the present invention is shown in Figure 1. As
ways so that a heat transfer is effected between the air
there shown, cooling tower 10 comprises a housing 11 of and water, and the water is further cooled by evaporative
rectangular or other suitable cross section. A water sump 16 action.
12 is located at the bottom of the casing to receive and
A modified form of core is shown in Figure 4. As there
temporarily store the cooled water. Water is withdrawn from the sump and Is delivered to the place of use bv
shown, modified core 32 comprises a plurality of sub-core units 33 constructed in substantially the same manner as
means of a pump 13 having an intake line 14 connected
the sub-core units of core 29 shown in Figure 2. Each of
to the sump and discharge line IS leading to the apparatus 20 the sub-cores includes alternate corrugated and planar
(not shown) requiring cooling water. Such apparatus
sheets defining a plurality of vertical passageways as de
may be a water cooled condenser for a refrigerating sys
scribed above.
tem, air conditioning system or the like.
However, in modified core 32, each of the sub-core units
Air is forced upwardly through housing 11 by any suit
33 has its lower surface cut in some suitable manner as
able means, such as blower 16 having an air intake 17 25 by sawing along a downwardly extending inclined plane
and an air discharge conduit 18 leading to the lower end
so -that each of the sub-units includes a short vertical edge
of the housing. The air rises upwardly through the hous
34 and a long edge 35. The sub-units are alternately
ing and passes upwardly through a core 20, the construc
joined together along their short and long edges to form
tion of which is explained in detail below. After the air
depending ridges 36 from which water drops from the
has passed through core 20, it is eventually discharged 30 core unit. The function of the downwardly directed, or
from, housing 11 through an exhaust stack 21.
inverted, ridges 36 is to increase the efficiency of the
Water is distributed or sprayed over the top of core 20
blower by facilitating discharge of water from the core
in any suitable way, such as by means of a rotatable spray
without interfering with air flow upwardly through the
head 22 which is turned at a predetermined rate to pro
core passageways.
vide proper distribution of water over the top of the core. 35 More particularly, when water passes through a core 32
Water is supplied to the spray head through an inlet pipe
having downwardly extending ridges which are preferably
23 which is connected to a source of water, such as the
inclined, approximately 60 from a horizontal plane, the
outlet connection of the condenser mentioned above.
water trickles from the lower edges of the tubular pas
Contact core 20 extends over substantially the entire cross
sageways and flows along the lower edges 37 of the sheets
section area of the housing and is supported at two or 40 comprising the sub-core units until the water reaches the
more of its edges by means of mounting brackets 24. In
lowermost point of the ridge from which it drops in the
the embodiment shown, these mounting brackets are in
form of enlarged drops into sump 12. Thus, the water is
the form of angle irons having a depending leg 25 secured
not picked up by the air from blower 16 as that air flows
to the inner wall of the housing and an inwardly extend
along horizontal passageways 38 between the ridges and
ing leg 26 forming a support for the core. These angle 45 passes upwardly into the vertical passageways. It will be
irons may either extend continuously along the side of the
appreciated that the water is directed around the openings
tower or may be in the form of a plurality of separate
of the vertical passageways to the bottom edges 37 of the
spaced angle irons, as shown in Figure 3.
ridges so that the water does not form, a film over the
One preferred form of contact core. 29 is best shown, in
bottom of the. vertical air passageways which might block
Figures 2 and 11. As there shown, contact core 20 com 50 or interfere with the upward air flow.
prises a plurality of assembled sub-core units 27. These
Figure S shows a second form of modified core 40 com
sub-units 27 may be firmly adhered together as by
prising component core units 41. These component core
gluing or by some suitable mechanical securance means;
units include alternate corrugated and planar sheets form
or alternatively, they may be assembled loosely together
ing vertical air passageways, as described above. How-
and held in place by the walls of housing 11. If desired, 55 ever, in modified core 40, the lower surface of core sub
core 20 can be constructed as a single unitary structure.
units 41 converges upwardly toward the center of the
As shown in Figure 2, each of the subunits 27 com
sub-units so that two downwardly directed semi-ridges
prises a plurality of sinuous or corrugated sheets 28 sepa
42 are formed. When the sides of adjacent sub-units 41
rated by generally planar divider sheets 30. The divider
are brought together, complete ridges are formed which
sheets and corrugated sheets are joined together by means 50 are generally similar to the ridges shown in Figure 4.
of any suitable adhesive, such as a polyvinyl acetate ad
The manner in which water is discharged from core 49
hesive or a phenolic resin glue. Corrugated sheets 28
to eliminate interference with, the upward flow of air is
and dividers 30 define a plurality of vertical passageways
the same- as that described above in connection with the
3L The upper ends of the passageways are open to re
description of modified core 32.
ceive water from the spray head 22 and the lower ends of 55 A third modified form of core 43 is shown in Figure 12.
the tubular passageways are open to discharge water into sump 12 and to receive air from blower 16. Both cor
As there shown, modified core 43 includes a plurality of sub-core units 44 which are glued or otherwise se
rugated sheets 28 and divider sheets 30 are formed from
cured together. In this embodiment, the lower surface
asbestos paper impregnated with a phenolic resin, such as
of each of the sub-core units 44 is sawed-or otherwise
Bakelite, which as explained below, is thermally set to 10 cut to form a centrally disposed downwardly directed
form a hard durable sheet The fibers in corrugated sheets
ridge 45, the sides of which are preferably inclined at 60
28 and divider sheets 30 preferably extend at right angles
from a horizontal plane. These ridges function to facili-
to- passageways 31, Le-. in a horizontal direction. The - fate the discharge of water in the same manner as de
exact size of the corrugations is not critical; however, I scribed above.
have determined that good results are obtained when 78 While- the precise give of the overall core unit is not
h,, i mp-rn from the CSIR imane Database on 01-07-2000
Critical, it has been found that in some installations the foe corrugated sheet 74, with foe adhesive being disposed
core need be only fifty percent as large as previous cores
between foe sheets. The sheets are firmly adhered or
of the same capacity. For example, for one three-ton
glued to each other, to form a composite sheet 75 which
air conditioning unit, a core of adequate capacity is 11%
enters oven 76 where the phenolic resin in foe papers is
inches by 27% inches by 27%. inches, or about 5.12 cu- 5 brought to the final fully set or "C" stage. For this
feet in size. Water is circulated through this unit purpose, oven 76 may be an infra-red oven which heats
approximately ten gallons per minute. For a five ton foe composite sheet to a temperature of approximately
refrigerating unit, the core size is 16 inches by 27%
400" F. The composite sheet, now indicated by foe
inches by 27% inches. It is to be understood, of course,
numeral 77 Leaves foe oven 76 and is rolled into a roil
that these dimensions are merely given by way of exam 10 78 for future use.
ple and that cores or other sizes may be employed.
Alternatively, if it is desired to. use roll 78 as a cylin
The manner in which heat exchanger cores are con
drical contact core, another adhesive applicator 80, simi
structed by the present method is best illustrated in Fig
lar to applicator . 67, is placed at foe end of foe oven.
ures 6. and 7. ' As there shown; the starting material is Its applying roll 81, applies an adhesive to foe underside
in the form of a roil 46 of commercial asbestos paper. IS of the composite sheet 77, so foe various layers of the
One. preferred material is six pound asbestos paper, .015 composite sheet within the roll 78 are glued to each other,
inch thick having an asbestos stock fiber and a sulphite and such roll can be used .as a cylindrical contact core,
and starch binder constituting approximately 7% by or may be sawed to different lengths for use as shorter
weight of .'the paper; the remaining 93% being pure as
contact cores.
bestos fibers which run lengthwise of the paper.
20 It is to be understood that roll 81 is omitted when it
The paper is fed .from roll 46 through guiding rollers
is desired to subsequently unwind roll' 50 to produce
47 and undere rollers 48 mounted within bath 50. This
cores of a rectangular cross section. Roll 81 is also
bath contains'an initially soluble phenolic resin, prefer omitted when it is desiredto make a cylindrical core which
ably a phenol formaldehyde condensation product, com
is held in assembled relationship by a mechanical means,
mercially known as Bakelite, dissolved in isopropyl alco 25 such as tie bands. More specifically, such a core is
hol in the proportion of two parts of phenolic resin to formed by winding composite sheet 77 convolutely upon
one part of 91% isopropyl alcohol.
itself to form a cylinder of foe desired diameter. The
The absorption of the phenolic resin solution in the material is then held in this cylindrical shape by applying
asbestos paper is controlled by the squeezing action of tie bands or bails formed of aluminum or the like around
a pair of squeeze rolls 51. These rolls squeeze out a 30 foe circumference of foe cylinder.
portion .of- the solution absorbed by the paper and return
As a further alternative, .cuffing mechanism 82 shown
it to bath 50 so as to leave a predetermined amount of
in Figure 8 may be substituted for applicator roll 81 and
phenolic resin absorbed in the paper. When the paper winding means 83 at foe right end of oven 76. In such
reaches its final stage, later to be described, the phenolic
an installation, sheet 77 leaving oven 76 is fed directly
resin in the paper is between 25% and 40% by weight 35 to foe cutting mechanism 82 of Figure 8 which may in
of the final product. A ratio now preferred is 34%.
clude a longitudinally movable anvil 84, and a longitudi
Such phenolic resin is an irreversible thermo setting com-
nally and downwardly movable knife 85, which moves
ound, which after the final stage is water insoluble, and
down against composite sheet 77 to cut it into the desired
tacts with the asbestos paper to prevent the formation lengths as determined by foe frequency of operation of
of fungus slime when such product is used in a water- 40 the knife 85. The longitudinal movement of the anvil
air contact core. .
84 and knife 85 is in foe same direction and at substan
The impregnated sheet' 52 leaving rolls 51 enters, an tially foe same speed of travel as composite sheet 77, so
oven 53 where, foe. phenolic resin within the paper, is
that there is no relative movement between these ele
heated and cufed.to a. "B7 stage,, foe paper remaining in ments. Such cutting mechanism, per se, are well known
a relatively flexible condition. For example, in one in 45 in the art and need not be further described.
stallation, foe paper remains approximately three minutes
The composite sheet 77 leaving the oveu 76 is shown
in the oven and.is heated to a temperature of 285" F.
in enlarged scale, in Figures 9 and 10. The corrugated
After foe paper leaves oven S3, it passes through pinch sheet 74 and the uncorrugated sheet 72 which entered
rolls 54 and thereafter, passes guiding rolls 55. Finally, oven 76 are now indicated by the numerals 74a and 72a
the impregnated sheet is rolled into a roll 56 in which 50 respectively in Figures 9 and 10. The right angled rela
form it can be stored for future use in foe method as
tionship of foe ridges formed by the asbestos fibers at the
disclosed in Figure 7.
surface, with respect to the corrugation 86 of the
Rolls 56 are used as a starting material for foe process paper 75d, is apparent in these enlarged figures. The.
steps disclosed in Figure 7. One such roll 56 is rotata
ridge3 increase the relative surface area of the paper and
bly mounted in any suitable manner at 57. Another 55 hence the film of water wetting foe paper, and also insure
roll 58 which is preferably but not necessarily of the
a for '"h distribution of the water as it descends through
same weight and texture and impregnated and cured in foe
me core. The composite sheet 77 is relatively stiff and
same manner as roil 56 is rotatably mounted at 60. The self-supporting and can be glued to form sub-core units 27
"B" stage sheet 61 drawn from roll 56 passes over various
and cores 30 or foe modified sub-cores and cores as do-
guiding rolls 62, and then passes through the hot corru 60 scribed above.
gating rolls 63, where the paper is corrugated and the
Having described my invention I claim:
resin is partially set. The rolls preferably are maintained
1. In a gas and liquid contact apparatus, the combina
at 350* F. to 400 F. The paper, which is corrugated tion with the elements of such an apparatus of a contact
to form 2 to 8 corrugations per running inch leaves core and means for passing a gas and liquid through said
the rolls 63 and passes over a support roll 64.
65 core in intimate contact with one another, said core com
Meanwhile, foe impregnated sheet 65, leaving the roll
prising a plurality of composite sheets adhered together
58, passes under guiding roll 66 and travels over an ad
side by side, each of said composite sheets comprising two
hesive applicator 67 which includes an applying roll 68,
asbestos sheets, one of said asbestos sheets being corru
a dipping roll 70 and an adhesive container 71. The
gated, the other being substantially planar, each of said
cement or ahesive in container 71 may be a polyvinyl ace- 70 sheets being impregnated with a phenolic resin heated and
ite adhesive, or a phenolic resin glue of any suitable
cured in foe sheet to an advanced stage of thermo setting.
type. The paper with foe adhesive applied thereto, and
2. In a gas and liquid contact apparatus, the combina
now indicated by the numeral 72, passes around roil
tion with the elements of such an apparatus of a contact
73 and over support roll 64. Sheet 72 passes between roll 64 and foe corrugated sheet 74 and is pressed against
75
core and means for passing a gas and liquid through said core in intimate contact with one another, said contact
'irwin
2,080,379
78
core comprising a plurality of asbestos sheets disposed
said core in intimate contact with one another, said core
side by side and impregnated with thermally set phenolic
comprising sheets of asbestos paper approximately .015
resin, alternate sheets of said core being corrugated to
inch thick impregnated with a thermally set phenolic
form a plurality of parallel passageways through said
resin, said sheets being alternately corrugated and planar
core, and the asbestos fibers in the said asbestos sheets (T and being secured in assembled relationship to form a
being oriented at substantially right angles to the passage
plurality of vertical passageways through, the core of the
ways to form ridges within the passageways.
size for the flow of gas and liquid therethrough.
3. In a gas and liquid contact apparatus, the combina
8. In a gas and liquid contact apparatus, the combi
tion with the elements of such an apparatus of a contact
nation with die elements of such an apparatus of a con
core and means fen passing a gas and liquid through said Ht tact core and means for passing a gas and liquid through
core in intimate contact with one another, said core com
said core in intimate contact with one another,, said core,
prising sheets of asbestos paper impregnated with a phe
comprising, a mass consisting essentially. of paper ar
nolic resin, said sheets being alternately corrugated and
ranged in plies, at least some of the plies being corru
planar and being secured in assembled relationship to
gated, and the .corrugations of such plies being arranged
form a plurality of vertical passageways through the core IS in parallel- alignment, and the corrugations of the corru
of the size for the flow of gas and liquid therethrough.
gated plies cooperating with an adjacent ply to- form pas
4. In a gas and liquid contact apparatus, the combina
sageways extending continuously from an upper surface
tion with the elements of such an apparatus of a contact
of the mass to a lower surface of the mass through which
core and means for passing a gas and liquid through said
passageways liquid and gas may flow in contact with one
core in intimate contact with one another, said core com 20 another, the said plies being constituted of thin asbestos-
prising sheets of asbestos paper impregnated with a phe
fiber paper, the said paper being impregnated with a resin
nolic resin, the surface of said sheets substantially retain
bonding together the asbestos fibers of which the paper
ing the surface roughness of the asbestos paper prior to
is made, thereby rendering the paper physically inert to
impregnation, said sheets being alternately corrugated and
liquid to which said mass is exposed during use, but with
planar and being secured in assembled relationship to 25 the surfaces of the corrugations of said paper conform
form a plurality of vertical passageways through the core
ing substantially to the surface texture of conventional
of the size for the Sow of gas and liquid therethrough.
unimpregnated asbestos paper, whereby the fibers rela
5. In a gas and liquid contact apparatus, the combina
tively exposed at the surfaces of said asbestos paper
tion with the elements of such an apparatus of a contact
present obstructions to films of liquid Sowing over such
core and means for passing a gas and liquid through said 30 surfaces and thereby promote the wettability of the sur
core in intimate contact with one another, said core com
faces of said corrugations by said liquid to increase the
prising sheets of asbestos paper impregnated with a resin,
exposure of the liquid flowing through said passageways
said sheets substantially displaying the surface roughness
to gas also flowing through said passageways.
of the unimpregnated asbestos paper, whereby the sur
faces of said sheets are wettable and are effective to retard 35
References Cited in the file of this patent
liquid Sow, said sheets being alternately corrugated and planar and being secured in assembled relationship to
UNITED STATES PATENTS
form a plurality of vertical passageways through the core
639,523 Chapin____________ ------- Dec. 19, 1899
of the size for the flow of gas and liquid therethrough. 6. In a gas and liquid contact apparatus, the combina 40
869,747 941,605
Starr
---------Oct 29, 1907
Baekeland_________ - - Nov. 30, 1909
tion with the elements of such an apparatus of a contact
1,695,912 Brown_____________ -------- Dec. 18, 1928
core and means for passing a gas and liquid through
2,035,970 MacDdowie_______ - _ Mar, 31, 1936
said core in intimate contact with one another, said' core
2,104,060 Spafford ___________ -----------Jan. 4, 1938
comprising sheets of asbestos paper impregnated with a
2,231,088 Richardson________ --------Feb. 11, 1941
thermally set phenolic resin, die surface of said sheets 45 2,434,466
substantially retaining the surface roughness of said un
2,609,314
Marc_____________ Engel et al.________ ---------- Sept. 2, 1952
impregnated asbestos paper, said sheets being config
2,661,197 Norman---------------------------- Dec. 1, 1953
urated and secured in assembled relationship to form a
2,793,017 Lake------------------------------May 21, 1957
plurality of vertical passageways through the core of die
2,809,81* Munters--------------------- _ Oct 15, 1957
size for the flow of gas and liquid therethrough.
50
7. In a gas and liquid contact apparatus, the combi-
FOREIGN PATENTS
___Tea with the elements of such an apparatus of a con
550,561 Great Britain______--------- Jan. 14, 1943
tact core and means for passing a gas and liquid through
571,510 Great Britain____ _