Document 15VgrYL1OmzzG09kba0oE3Y8q

fif 2 .6 _ 1 / ^ 3 JULY 2002 SURFACE WATER MONITORING REPORT FOR WASHINGTON WORKS FACILITY AND LOCAL, LETART AND DRY RUN LANDFILLS WASHINGTON, WV Date: September 2002 Project No.: D6WW7423.01 18983635.20000 CORPORATE REMEDIATION GROUP An Alliance between DuPont and URS Diamond Barley Mill Plaza, Building 27 Wilmington, Delaware 19805 Surface water Monitoring Report Table of Contents TABLE OF CONTENTS 1.0 Introduction...................................................................................................................1 2.0 C-8 Analytical Reporting.............................................................................................2 3.0 Washington WorksFacility..........................................................................................3 4.0 Local Landfill............................................................................................................... 4 5.0 Letart Landfill.............................................................................................................. 5 6.0 Dry Run Landfill.......................................................................................................... 6 7.0 References.................................................................................................................... 7 Table 1.0 Table 2.0 Table 3.0 Table 4.0 Figure 1.0 Figure 1.1 Figure 1.2 Figure 2.0 Figure 2.1 Figure 2.2 Figure 3.0 Figure 3.1 Figure 3.2 Figure 4.0 Figure 4.1 Figure 4.2 TABLES C-8 in Surface Water - Washington Works Facility C-8 in Surface Water - Local Landfill C-8 in Surface Water - Letart Landfill C-8 in Surface Water - Dry Run Landfill FIGURES Site Location Map - Washington Works Facility Surface Water Sample Location Map - Washington Works Facility C-8 Concentration Map July 2002 - Washington Works Facility Surface Water Site Location Map - Local Landfill Surface Water Sample Location Map - Local Landfill C-8 Concentration Map July 2002 - Local Landfill Outfalls Site Location Map - Letart Landfill Surface Water Sample Location Map - Letart Landfill C-8 Concentration Map July 2002 - Letart Landfill Outfalls Site Location Map - Dry Run Surface Water Sample Location Map - Dry Run Landfill C-8 Concentration Map July 2002 - Dry Run Landfill Outfalls JULGMR.doc Sep. 17. 02 Wilmington, DE 000444 Surface water Monitoring Report Table of Contents Appendix A Appendix B Appendix C Appendix D Appendix E Appendix F Appendix G Appendix H APPENDICES Laboratory Analytical Data Reports - Washington Works Facility Chain-of-Custody Records - Washington Works Facility Laboratory Analytical Data Reports - Local Landfill Chain-of-Custody Records - Local Landfill Laboratory Analytical Data Reports - Letart Landfill Chain-of-Custody Records - Letart Landfill Laboratory Analytical Data Reports - Dry Run Landfill Chain-of-Custody Records - Dry Run Landfill JULGMR.doc Sep. 17. 02 Wilmington, DE 060445 ii Surface water Monitoring Report Introduction 1.0 INTRODUCTION A multi-media consent order (Order No. GWR-2001-019) was entered into between the West Virginia Department of Environmental Protection (WVDEP), the West Virginia Department of Health and Human Resources - Bureau for Public Health (WVDHHRBPH) and DuPont on November 15, 2001 (Consent Order). The Consent Order identified a series of requirements and tasks to be performed by the parties to determine whether there has been an impact on human health and the environment as a result of releases of ammonium perfluorooctanoate (C-8), CAS Number 3825-26-1, to the environment from DuPont operations at the Washington Works facility and the associated landfills (Local, Letart and Dry Run). The Consent Order established the C-8 Groundwater Investigation Steering Team (GIST) to oversee investigations and activities that will be conducted to assess the presence and extent of C-8 in drinking water, groundwater, and surface water at and around the Washington Works facility and the Local, Letart and Dry Run Landfills. An additional component of the Consent Order relates to the National Pollutant Discharge Elimination System (NPDES) permit sampling requirements. In this portion of the Consent Order, specific outfalls and outlets (outfalls) are to be sampled monthly for C-8 by DuPont. Pursuant to Attachment A of the Consent Order, three tasks will be performed by DuPont and evaluated by the GIST, Tasks A, B, and C. Task A: Groundwater Use and Well Survey/Groundwater Monitoring has been completed (DuPont, 2002a; 2002b). Task B: Assessment of Existing Groundwater and Surface Water Monitoring Data includes the compilation of historical C-8 data, monitoring all wells at the landfills and the development of a Groundwater Monitoring Plan (GMP) for the Washington Works facility. The first part of the task, the historical C-8 data compilation report has been submitted to the GIST for evaluation (DuPont, 2002c). The second part of this task, monitoring C-8 in groundwater at the landfills, began in December 2001 and was performed monthly for four months and quarterly thereafter. The third part of the task, the proposed GMP for the Washington Works facility, was submitted to the GIST for evaluation (DuPont, 2002d) and groundwater sampling on the Washington Works facility began in January 2002. Groundwater sampling at the Washington Works facility was conducted monthly for four months and continues quarterly. Task C: Plume Identification/Groundwater Assessment is ongoing. This report presents the results of the C-8 sampling that was performed in July 2002. Surface water results are presented for the Washington Works facility and the Local, Letart, and Dry Run Landfills. JULGMR.doc Sep. 17, 02 Wilmington, DE 000446 1 Surface water Monitoring Report C-8 Analytical Reporting 2.0 C-8 ANALYTICAL REPORTING The analytical method, method detection limit, and laboratory utilized for C-8 analysis has changed over time. Prior to 1991, DuPont performed C-8 analysis at the DuPont Experimental Station in Wilmington, Delaware. In 1991, when the RCRA Verification Investigation was conducted, the analysis was contracted to the CH2MHill Laboratory in Montgomery, Alabama. Both labs used a Gas Chromatography/Electron Capture Detector (GC-ECD) based analytical method with detection limits for C-8 that ranged from 0.1 to 1.0 ug/1. CH2MHill conducted C-8 analysis for DuPont into the fall of 1998 when the laboratory ceased operation. At that time, DuPont had completed one round of analysis for the RCRA Facility Investigation (RFI). The analytical work was transferred to Lancaster Laboratories, Lancaster, PA, for the RFI second round analysis in March 1999. Lancaster Laboratories continued to conduct C-8 analysis using GC-ECD for DuPont until October 2001, when development and testing was completed on a new analytical method developed by Exygen Research, Inc. (Exygen; located in State College, PA) that utilizes Liquid Chromatography/Tandem Mass Spectrometry (LC/MS/MS). DuPont adopted the regular use of LC/MS/MS for C-8 analysis in water in November 2001 and Exygen was contracted to perform the analyses for DuPont. Exygen reports C-8 results for the laboratory replicate of each field sample. These results are evaluated for precision by comparing the field sample result to the corresponding laboratory replicate result. If both results are less than the practical quantitation limit (PQL), the replicate sample for that analyte is considered to have passed the precision criteria. If one or both results are between one and five times the PQL, the replicate is considered to have met the precision criteria if the two results differ by less than the PQL. If one result is less than the PQL and the other is not, and if the two results differed by a value less than the PQL, the replicate is said to have met the acceptance criteria. Finally, if both results are at least five times the PQL, the replicate is considered to have met the criteria if the relative percent difference (RPD) between the two results is less than or equal to 20%. The RPD is the absolute value of the difference of two measurements divided by their average. When the precision criteria outlined above are met, Exygen reports the average of the field sample and lab replicate results reported by the laboratory. If criteria for precision are exceeded, Exygen reports the higher of the sample and lab replicate results. Finally, when one result (from the sample/lab replicate pair) is above the PQL and one below, the result that is above the PQLs is reported. C-8 results are recorded in the Corporate Environmental Database (CED) and are reported as FC-143 for consistency with historical results. JULGMR.doc Sep. 17, 02 Wilmington, DE 2 Surface water Monitoring Report Washington Works Facility 3.0 WASHINGTON WORKS FACILITY Figure 1.0 shows the location of the Washington Works facility. On July 23rd, 2002, six outfalls were sampled for C-8 (001, 002, 003, 005,007, and 105). All of these outfalls collect process water and stormwater runoff. Sampling of these outfalls is required by the Consent Order and WV NPDES permit No. WV0001279. The locations of these outfalls are shown in Figure 1.1. Table 1.0 provides the C-8 analytical results for surface water. For each sampling point listed in this table, historical data is summarized with the most recent results listed first. Figure 1.2 presents the C-8 concentration map for the outfalls sampled in July 2002. Laboratory analytical data reports and the Chain-of-Custody records are included in Appendix A and B, respectively. JULGMR.doc Sep. 17, 02 Wilmington, DE 000448 3 06449 TABLES 000450 09/17/02 Table 1.0 Summary of Analytical Results: C-8 in Surface Water DuPont Washington Works Facility Washington, WV Sample OUTLET 001 OUTFALL 002 OUTLET 003 | OUTFALL 005 Date 7/23/02 6/25/02 5/20/02 4/16/02 3/19/02 2/5/02 1/17/02 12/20/01 7/23/02 6/25/02 6/25/02 (dup) 5/20/02 4/16/02 3/19/02 2/5/02 1/17/02 12/20/01 11/26/01* 10/25/01 9/19/01 7/11/01 6/14/01 5/31/01 4/11/01 3/21/01 2/14/01 7/23/02 6/25/02 5/20/02 4/16/02 3/19/02 3/19/02 (dup) 2/5/02 1/17/02 1/17/02 (dup) 12/20/01 7/23/02 6/25/02 5/20/02 5/17/02 4/16/02 3/19/02 2/5/02 1/17/02 12/20/01 12/20/01 (dup) 11/26/01 10/25/01 9/19/01 8/30/01 7/11/01 6/14/01 5/31/01 4/11/01 3/21/01 2/14/01 C-8 (ugA) 8.63 17.9 22.4 19.7 21.4 9.43 10.9 3.720 2.29 3.86 3.81 4.13 2.45 5.85 4.66 4.23 1.980 4.84 2.8 0.118 0.558 0.594 0.436 1.5 8.54 1.74 0.291 0.175 0.503 2.76 2.91 2.81 1.33 0.956 3.99 0.713 19.2 17.9 98.6 65.7 3.8 9.26 141.0 137.0 31.40 35.20 915 65.7 2.86 2.16 120 7.4 1.43 4.31 199 153 1 of 2 000451 Table 1.0-doc Table 1.0 Summary of Analytical Results: C-8 in Surface Water DuPont Washington Works Facility Washington, WV Sample OUTLET 007 OUTLET 105 Data 7/23/02 6/25/02 5/20/02 4/16/02 3/19/02 2/5/02 2/5/02(dup) 1/17/02 12/20/01 7/23/02 6/25/02 5/20/02 4/16/02 3/19/02 2/5/02 1/17/02 12/20/01 C-8(ug/I) 0.597 0.284 0.490 0.567 0.483 0.320 0.339 0.871 1.99 34.7 3.86 6.27 15.9 13.2 14.6 7.53 9.78 Note: Analytical method changed as of November 2001 (see Section 2.0 for details). 09/17/02 2 of 2 000452 Table I.O.doc Table 2.0 Summary of Analytical Results: C-8 in Surface Water Local Landfill Washington, WV Sample OUTFALL 004 (New) OUTFALL 004 (Old) OUTFALL 005 (New) OUTFALL 005 (Old)/SS1 OUTLET 101 Date 7/1/02 6/13/02 5/21/02 4/29/02 3/26/02 7/1/02 6/13/02 5/21/02 4/29/02 3/26/02 2/20/02 1/24/02 12/13/01 9/27/2000 12/10/1999 6/3/1999 6/2/1998 5/29/1997 4/2/1996 2/16/1994 7/1/02 6/13/02 5/21/02 4/29/02 3/26/02 7/1/02 6/13/02 5/21/02 4/29/02 3/26/02 2/20/02 1/11/02 12/13/01 9/27/2000 12/10/1999 6/3/1999 6/2/1998 5/29/1997 4/2/1996 2/16/1994 7/1/02 6/13/02 5/21/02 4/29/02 3/25/02 2/20/02 1/23/02 12/13/01 9/14/2000 6/3/1999 6/2/1998 C-8(ug/I) 11.2 9.29 No-flow conditions 14.5 14.6 11.6 10.0 No-flow conditions 15 1.54 10.9 11.4 No-flow conditions 4.73 7.1 3.06 12 13 13 11 No-flow conditions No-flow conditions No-flow conditions 34.3 16.0 32.1 27.3 No-flow conditions 40.9 39.0 46.0 51.4 No-flow conditions 13.3 34 6.8 39 41 39 35 63.0 38.0 40.0 48.2 36.4 63.10 81.4 82.40 12 15 54 Note: Analytical method changed as of November 2001 (see Section 2.0 for details). 000453 09/17/02 1 of 1 Table 2-0.doc Table 3.0 Summary of Analytical Results: C-8 in Surface Water Letart Landfill Letart, WV 'Sam ple 002(LEACHATE BASIN) 003 RT 33 STREAM CAP RUNOFF S a te 7/30/02 6/23/02 5/30/02 4/30/02 3/28/02 2/19/02 1/25/02 12/14/01 11/27/2001 7/20/01 7/25/2000 4/3/2000 1/14/2000 10/21/1999 7/30/02 mm2 5/30/02 4/30/02 mmz 2/19/02 1/25/02 12/14/01 5/30/02 4/30/02 mm2 2/19/02 1/25/02 7/20/2001 7/31/2000 7/20/1999 7/23/1997 4/17/1996 mm2 5/30/02 4/30/02 mm2 2/19/02 1/25/02 c-8 fue/i) 1410 Not Analyzed* 1630 443 131 355 50.1 36.1 53.2 159 1350 1900 920 3240 No-Flow Conditions Not Analyzed* 0.282 0.0653 0.198 No-Flow Conditions 0.148 0.390 1.570 0.845 1.26 3.92 1.9 2.01 0.573 2.23 2 1.8 Not Analyzed* 371 279 Not Sampled No-Flow Conditions 119 Note: Analytical method changed as of November 2001 (see Section 2.0 for details). * Samples were taken at the respective surface water locations. However, due to an error by the courier, the samples arrived at the lab warm and were not analyzed. 09/17/02 1 of 1 000454 Table 3.0.doc Table 4.0 Summary of Analytical Results: C-8 in Surface Water Dry Run Landfill Lubeck, WV Sample OUTLET 001 OUTLET 003 OUTLET 004 PROPERTY BOUNDARY STREAM SAMPLING POINT#1 STREAM SAMPLING POINT#2 Date 7/31/02 7/1/02 6/28/02 5/28/02 4/24/02 3/25/02 2/25/02 1/28/02 12/12/01 10/3/2000 12/29/1999 5/19/1998 4/9/1996 7/1/02 6/28/02 5/28/02 4/29/02 3/26/02 2/25/02 1/28/02 12/12/01 7/1/02 6/28/02 5/28/02 4/27/02 3/26/02 2/25/02 1/28/02 12/12/01 5/28/02 4/24/02 3/25/02 2/25/02 1/28/02 12/12/01 10/3/2000 12/29/1999 7/14/1998 4/9/1996 5/28/02 4/24/02 3/25/02 2/25/02 1/28/02 12/12/01 10/3/2000 12/29/1999 5/19/1998 5/28/02 4/24/02 3/25/02 2/25/02 1/28/02 12/12/01 10/3/2000 12/29/1999 5/19/1998 C-8 (ur/I) Noflow conditions Noflow conditions Noflow conditions 30.9 41 71.6 43.9 41.6 Noflow conditions 31.5 66 17 86 25.3 Noflow conditions Noflow conditions 20.1 6.77 Noflow conditions Noflow conditions Noflow conditions 0.70 Noflow conditions Noflow conditions Noflow conditions 158 Noflow conditions Noflow conditions Noflow conditions 9.41 6.69 22.8 3.81 11.1 3.99 10.3 39 0.88 9.9 1.63 0.932 1.06 0.850 0.893 1.19 0.758 0.54 1 51.0 28.9 66.6 24.3 42.4 20.5 27.6 87 4.6 000455 09/17/02 1 of 2 Table 4-0.doc Table 4.0 Summary of Analytical Results: C-8 in Surface Water Dry Run Landfill Lubeck, WV Sample Date C -8 (ag/1) DRLEACHATE 5/28/02 150 4/24/02 237 3/25/02 334 2125102 256 1/28/02 398 12/12/01 109 10/3/2000 27.4 12/29/1999 34 5/19/1998 56 7/22/1997 62 POND UNDERDRAIN 5/28/02 4/24/02 67.4 33.4 3/25/02 66.7 2125102 37.1 1/28/02 29.3 12/12/01 35.4 Note: Analytical method changed as of November 2001 (see Section 2.0 for details). 09/17/02 2 of 2 000454 Table 4.0.doc 000457 FIGURES 00045* SCALE 700 0 700' OEStCNED K. DAV IS DRAWN O.H. EN G LISH CHECKED K. O A VIS APPRCVED(OES)CH) INfTViLS APPROVED(CONSTRUCTION) <SffPOWt) Corporate Remediation Group An Alliance between DuPont and UPS Diamond Barley Mill Plaza, Building 27 Wilmington, Delaware 19805 SURFACE WATER SAMPLE LOCATION MAP DuPont Washington Works Facility Washington, West Virginia SCALE A s Shown OATC CAO r a x no. 05/02/2002 FG -1.1 000460 na 1.1 SCALE 700 0 700' DESIGNED mn>LS SUO DRAWN DEL CHECKED TDL APPROVED(DES>CN) ASH APPROVED(CONSTRUCTION) Corporate Remediation Group An Alliance between DuPont and URS Diamond Barley Mill Plaza. Building 27 Wilmington. Delaware 19805 C--8 IN SURFACE WATER JULY 2002 DuPont Washington Works Facility Washington, West Virginia SUI As shown turc <JO FU HO. 08/02/2002 74238004 ncusc 1 .2 o in Source: USGS Little Hocking, Ohio -- West Virginia Quadrangle SITE LOCATION MAP Corporate Remediation Group An Alliance betw een DuPont and URS D iam ond Barley Mill Plaza, Building 27 Wilmington, Delowore 19805 Local Landfill Washington, West Virginia 9CM Not to eeale one MNM DEL /v e n a CAO F IX MO. 7 *2 1 ADO1 2.0 STATE ROAD #892 SCALE SOURCE* NEW HAVEN, W -O H IO QUADRANGLE 7.5' SERIES DuPont and Tho W-C D iam ond Croup 00465 Barley Mill Plaza, Building 27 m ington, Deloware 19880--0027 SITE LO C ATIO N MAP Letart Landfill Site Letart, WV SCALE As shown EMIC 12/21/9 0C90NCD TOL OCCKEO OAMM DEL apw m p CAO FLE MO. 7239AOOZ noue 3 .0 99*000  004fi7 OO04S8 E 1.378.500 LEGEND SURFACE WATER SAMPLE LOCATION 66.6 CONCENTRATION C -8 (ug/l) Aon n N 257.500 /in n ' < m t> Corporate Remediation An Alliance between DuPont and URS Diamond A \7 Group uai r j .. :i .-- m C--8 IN SURFACE WATER JULY 2 00 2 Dry Run Landfill DuPont Washington Works Lubeck, West Virginia scMX A i thown f|eaNKM.D{MVS imOuHM. DtCUSH |lown7u42m24o010 APPENDICES 000470 APPENDIX A LABORATORY ANALYTICAL DATA REPORTS WASHINGTON WORKS FACILITY RESEARCH Precise Research. Proven Results. H I] Analytical Results Washington Works C8 Sampling 7/02 DuPont Sample Identification APFO (ng/L) WWK-Z-Outfall-001 WWK-Z-Outfall-002 WWK-Z-0 utfaII-003 WWK-Z-Outfall-005 WWK-Z-Outfall-007 WWK-Z-Outfall-105 WWK-Z-Outfall-007-2 WWK-K-EQBLK-1 8630 2290 291 19200 597 34700 544 ND Limit of Detection (LOD) for the procedure is appoximately 10 ng/L Limit of Quantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sample and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sample and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0007 000472 3058 Research Drive State College, PA 16801, USA T: 814.272.1039 F: 8 1 4 .2 3 1 .1 5 8 0 exygen.com APPENDIX B CHAIN-OF-CUSTODY RECORDS WASHINGTON WORKS FACILITY 000473 6000 f t V s f ARCH 1 v / l C U J I K J U I / M INJM LT 5 D K C U U t b l F O R M Exygen Research Sample Receiving *3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P ag e____ of PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): . /)...... , / f /://> * > s tS *?/ / W ,, /W " /<>**>' Phone: . u - , , V >> - *> Fax: v S a m p le r: Project Manager (Name & E-mail Address): / h - J , 1). Project Name: RO. #: .? xxa y w Q u o ta tio n # : \ .,/..... 7 / * ^ /s - Please fill out this form completely to ensure correct analysis and proper handling of your samples. Composite Number of Containers SAMPLE ANALYSIS m u t w : Client Sample Identification Collection Collection rud. Date Time o Specify Matrix 'JsJSsrob'i' lt/Ls$' 7. - tit f/-* // *&+*/ i/*//".// - - 'i / i \M O 7 rlv.- i, ^ S<^ A U pTeb'- J A'Vtf- :v**&+*-`* r.J-pin i j i r o t . A l. c-.tf.H - ve : - o't /' r \u n 'TQ iV-a w * j I - B - T-(> ^ - 2 -"- fZ"/f CiClT - -2 -V \*> s .1/ - 4<- *'/, LAB USE ONLY -! X Vc X -, > < .-l i J ______1 < k___ T ~ 7 Com ments X(r<*} S* y %/ / XJ-l>0-i-r yis.i J yxf.h^ ffXLU-'/ y . i -, .%>r #i / / y j i - S i y>-Xf`f / .Jr* r j j i ' -J-\ X \- J ,0 T */>-> X sSh / VJI-.YJl CHAIN OF CUSTODY Relinquished by --\ 0 Date Time ' / / / / y ,. i- 7 m V .x \ Cooler ID # '/ '***> * mm Cooler Temp. (C) fumetto OTHER INFORMATION ; '.'J1: LAB USE ONLY 4 vA- 'V N.' s.. 1 < \ 'k y < \ yV X r K' .J L f-.) !'{ r-f U l 7,5 7.> 7,? 77 7? iy f S.T PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Q Sam ple results only Q A d d case narrative I I A d d quality control sum m ary I I A d d calibration sum m ary r~1 A d d raw data D O t h e r _________________ 000474 APPENDIX C LABORATORY ANALYTICAL DATA REPORTS LOCAL LANDFILL TM w /P re c ise Research. Proven Results. RC H Analytical Results Local Landfill C8 Sampling 7/02 DuPont Sample Identification APFO (ng/L) LCL-K-EQBLK-1 LCL-Z-Outfall 004 Old WestStream LCL-Z-Outfall 004 New West Stream LCL-Z-Outfall 005 Old Centrai Stream LCL-Z-Outlet 101 238 11600 11200 32100 63000 Limit of Detection (LOD) for the procedure is appoximately 10 ng/L Limit of Quantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sample and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sample and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0007 000476 ,3 0 58 Research Drive LState College, PA 16801 LT: 814.272.1039 Ik F : 814.231.1580 exygen.com APPENDIX D CHAIN-OF-CUSTODY RECORDS LOCAL LANDFILL 000477 PROJECT INFORMATION Client (name & address): v-1 .vniiM u r LU31 UUY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving *3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P age____ o f _____ ANALYSES REQUESTED 1 Project Manager (Name & E-mail Address): Composite Number of Containers /*# -- 0009 / / //./H i D - ifrc < r Phone: ...... ~ C 9 iT Fax:____ ~ . ______ t v _______________ S a m p le r:^ ^ v \re Q ^ C \rV % ^ i^ . /lAtcln>?ff.i>. /4<s&<''<&) (AH Project Name: / ? 1**y*JU r f / " P.O. # : Quotation # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS Client Sample Identification Is m 'irL L C L ~ K ~ l i/-l Collection Collection Date Time. ak. 1A-G X. O^QCJ Specify Matrix Comments , 2_ 2 2 < / 9 i j2 T 2 ? 9 H i $N \ \ l* $ /L T \ v*f * Vs f * VT,*;. V;. s' Tvr-'--. -0,>S.0V ;'> LABUSE ONLY CHAIN OF CUSTODY Relinquished by v Date Time OTHER INFORMATION Cooler ID # LAB USE ONLY -.o Cooler Temp. (C) c?. B i PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 1 IAdd case narrative 0 Add quality control summary 0 Add calibration summary 0 Add raw data 0 Other_________________ ------- 00047------- CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving *3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P age_____o f _____ PROJECT INFORMATION ANALYSES REQUESTED I Client (name & address): Project Manager (Name & E-mail Address): Si0<XHn /ify s w /t-r'? -- `hr rf/h i** ^v( /f/< cL *jrf, > / - On- ______ > 0 ^ / t S * ? Project Name: Phone: f ? m ) -r9 z - A *9f ' /T TA Fax: v RO. # : LtfJTo - r i A v C rl^ /v j. f-/o W S a m p le r:M fe ^ T C Q ^ ^ V c ^ l^ trO Quotation # : ____ ..... Please fill out this form completely to ensure correct analysis and proper handling of your samples. \i $> \ < i '1 1 Composite Number of Containers SAMPLE ANALYSIS Client Sample Identification L O L- 2 -Cksf-T*/I ooq /J VA*VW Collection Collection Date Time ; c a *s -O w O Specify Matrix Comments 2 - % 2S * ? ? / ?2<o0ao "k iL 2cL >,r 0100 r. ;*>" ' i 1 LAB USE ONLY CHAIN OF CUSTODY Relip^uished by - / ^ K " " "" Datp ------ Time /ecu \\ip Q OTHER INFORMATION PROJECT REQUIREMENTS it t i Laboratory Report Options: 0 Sample results only 5^111111 l ilp p ! Q Add case narrative a m K M M $ & ; i l H Add quality control summary LAB USE ONLY l~ l A dd raw data Other ~ H 00479 _n/AiiM v jr u u IUUY/A NA LYSIS REQUEST FO RM ^7 RESEARCH Exygen Research Sample Receiving *3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 * exygenresearch.com Page of PROJECT INFORMATION ANALYSES REQUESTED Client (ty m e & address): A D Q fr i { ? { * > /* 27 f r A /H i / A /Li U3.k)lIiZ. D 9% ?______ Phone: r?2-/G 9!T Fax: Sampler: Project Manage;rrJAIame SyrlE-mail Address): .. /lA tcL s* (K> _____________ eg? (/X/, -f- CP/'*-1 Project Name: . ___________________________________________ RO. # : -Zb J d o .F /o Hb Quotation # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. SAMPLE ANALYSIS Collection Collection Client Sample Identification Date Time " k l L C L - ? ~ tX r f/ llC o n AJ*u, 22m ~ <u -fQe.nSt Ea co H U Specify Matrix 2-- Comments I tt i 'i * X ST \ ! 7.Y >7 V - r 0011 H7`* ' . pj,` i ^n'.Vvv LAB USE ONLY CHAIN OF CUSTODY RelinqM&hed by _ /A --r-- ~ ~ -------- P& , Time I______________ OTHER INFORMATION Cooler ID # fo o o G e& Q 5- LAB USE ONLY Cooler Temp. (C) 0> > PROJECT REQUIREMENTS Results Deadline: W M m Laboratory Report Options: Q Sam ple results only f~ l A d d case narrative I I A d d Quality control sum m ary Q A d d calibration sum m ary A dd raw data C H O t h e r ______________ . 000480 ........ .. w i i v/u / m ^ n u j d rscuutzD I l"U K A A RESEARCH Exygen Research Sample Receiving *3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P age_____o f _____ PROJECT INFORMATION ANALYSES REQUESTED 1 /1 Client (name & address): / i ^>2/<-> J f j Phone: /fW # -2 -T - h e ./fc g / M (. . D 198S~ { ? * ? ) -j m - JL9r F a x : ________................................................................. Sampler: ____ Project Manager (Name & E-mail Address): Project Name: D. T fT RO. # : Quotation # : ___ UU . fA * . U r - AP. Please fill o u t th is fo rm c o m p le te ly to en sure co rrect analysis an d p ro p e r h a n d lin g o f y o u r sam ples. ' 5P s v. -i i Si' SAMPLE ANALYSIS E gyU M S #- C lient Sample Identification Li.. sy 7 ~ /lo 4 s ^ . , '" T : **** Collection Collection Date Time m so . rkd. o Composite Number of Containers Specify Matrix C om m ents / X??9?C 1* * *< Id . f.i *>*!*' 0012 LAB USE ONLY CHAIN OF CUSTODY RelipdOished by J P r ------------ -Pate Time t .. . Aw -l-V -C A OTHER INFORMATION Cooler ID # LAB USE ONLY Cool er Temp. (C) 0 : < ; K T r . ' ' `V . R SB^-WlWAi a f i w #1111 'a^Ti^i^Vl Sfe W f i& i& PROJECT REQUIREMENTS Results Deadline: Laboratory R eport O ptions: [~1Sample results only CD Add case narrative CD Add quality control summary CD Add calibration summary CD Add raw data CH Other__________ - 000481 C H AIN OF CUSTODY/ANALYSIS REQUEST FORM Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P age_____o f _____ PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): A tX X fa f 5&y-Vn:-rT _____ fa /* A~f A /____ P hone:____ f j o z ) - n z - M F ____________ FdX* Sampler: ________________ Project Manager (Name & E-mail Address): /W tL AcjSot^, /b tc b ** ( . D . 3roject Name: /<-. _______ 6~/cv-_________________________ jiO . # : - M foC* Z>UfPAJb. Quotation #: Please fill out this form completely to ensure correct analysis and proper handling of your samples. * Si N b SAMPLE ANALYSIS m i f e Client Sample Identification Collection Collection .Otd Date Time O -----------------------------------------------------------1 Specify Matrix Comments L t L - T - J t* t /o / 1 -V a x cA oo g Z y 2 5 T 2 ///'2 5 -W X 7^ 4**"' `if*'L :r (..'..',V.j K V 'S l > Composite Number of Containers 0013 &s' .,*V- r ' ri.v'.' LAB USE ONLY CHAIN OF CUSTODY Relinquished by Pate , ------- ------------ --------- -- Time /o c o \L \0 O OTHER INFORMATION Cooler ID # j Cooler Temp. (C) <9<> PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: [~l Sample results only d Add case narrative CDAdd quality control summary n Add calibration summary CDAdd raw data CD Other 0048* APPENDIX E LABORATORY ANALYTICAL DATA REPORTS LETART LANDFILL 000483 TM Proven Results. RC H Analytical Results LeTart Landfill C8 Sampling 7/02 DuPont Sample Identification APFO (ng/L) LTL-Z-Outlet 002 LTL-K-EQBLK-1 1410000 ND Limit of Detection (LOD) for th procedure is appoximately 10 ng/L Limit of Quantitation (LOQ) for the procedure is 50 ng/L ND - Compound not detected NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sample and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sample and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0007 000484 exygen.com APPENDIX F CHAIN-OF-CUSTODY RECORDS LETART LANDFILL 000485 V-FIAHM U l- U J b I U D Y /A N A L Y b lb KfcQUhbT FORAA m ESEARCH ) Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P age____ o f _____ PROJECT INFORMATION ANALYSES REQUESTED Client (name & address): /7/V* ,< 7 /, A > Phone: Fax: Sampler: ,,,,,,s, / ?.?<' >/ / 9-F- e'/ K'N'- J Project Manager (Name & E-mail Address): ________(H K-. , JkX Project Name: ....`________________ _________ ______________7 / ; > RO. # : / j~e- i z7/ , y y t / Quotation # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. s, \ Q . > \v X SAMPLE ANALYSISExyLlMS# Client Sample Identification Collection Collection Date Time .Onko_ oQ. Eo u C3SJCoS z u Specify Matrix 7 Z- J t- X lX 3 _ K x I* * L T L ? c . / / . / 2_S X f-L - ?- L 7i~ u ,{t-,S - / \->AS j- Comments I ' j - r f j - f / , U r j j (> yjfVls/ / JU-r/j /!''/( / / f J r y - jj $ LL i,? A 0009 LAB USE ONLY _0*-^ CUSTODY Relinquished by T. i \ 1 Date Time cr- l^O C ) OTHER INFORMATION Received by LAB USE ONLY Date Time C f\C \C \ a-- PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 1 I Add case narrative I I Add quality control summary l~~l Add calibration summary f~] Add raw data 0 Other 000486 APPENDIX G LABORATORY ANALYTICAL DATA REPORTS DRY RUN LANDFILL 000487 Ilf * Analytical Result? Dry Run Landfill C8 Sampling 7/02 DuPont Sample Identification APFO (ng/L) DRL-Z-Outlet 003 DRL-Z-Outlet 004 25300 700 Limit of Detection (LOD) for the procedure is appoximately 10 ng/L Limit of Quantitation (LOQ) for th. procedure is 50 ng/L ND - Compound not detected NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. ND < LOD < NQ < LOQ Results are calculated according to the following criteria If the sample and laboratory duplicate are greater, than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported. If the sample and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. 0007 000488 ,^^3058 Research Drive -# m s ta te College, PA 16801, USA ^ T : 814.272.1039 m F : 814.231.1580 exygen.com APPENDIX H CHAIN-OF-CUSTODY RECORDS DRY RUN LANDFILL 000489 RESEARCH -/ Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P age____ of PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): Aba-.h J c - ....... - A A ft* O , b. Phone: ' .?*> / 6 9# Fax: _ ^ Sampler: /v / Project Manager (Name & E-mail Address): /h /*,. .- ..i A <...<f . h Project Name: Of s RO. # : 6 */sro6 & /*.,. sU, fy . e x i Quotation # : Please fill out this form completely to ensure correct analysis and proper handling of your samples. Composite Number of Containers SAMPLE ANALYSIS Client Sample Identification sSJSS b ^ L - ,, ,, Hi t - 6 i vii Collection Collection Date Time 7h!>.>- O 'tX S Stni O Specify Matrix ,2 -';i h s Comments bj-L- />i / v a i ' 7 79 I N \ 5\ K 4 i JC_ A x \, -:y: >I* 7 \ '!, y 'Y W' .. . **'*:+ 3V . 1. ti: LAB USE ONLY CHAIN OF CUSTODY Relinquished by Date Time v\ tTv n - \ - o v V\ OTHER INFORMATION Cooler ID # Cooler Temp. (C) S ll^ l tS S lS S ia ,i-. "A?''-; i,. ^ -' -- *"i','v ^ -O " 7''- ,.;s>5.v PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: f~~l Sample results only I I Add case narrative I I Add quality control summary CDAdd calibration summary CDAdd raw data CD Other___ 0004 v-i i/"u i m v r v . u j i u u i / n iN M u i j i j i n c m u c d i rv ^ i\iv i Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P a g e _____ o f ______ PROJECT INFORMATION ANALYSES REQUESTED 1 Client (name & address): tfbO/h - A, u 'p ^ ^ ^.-7 , 6 s /<yyor /? //-// Phone: ' -,/? MO.r Fax: . S am D len 'S ^.C V s^^*--^ Project Manager (Name & E-mail Address): A? Project Name: C -P RO. # : l g jo - 6 ^(->6 Quotation # : A* /v,, x >s-.? Please fill out this form com pletely to ensure correct analysis and proper handling of your samples. 1V \ \ \ i K VV Grab Composite Number of Containers X // SAMPLE ANALYSIS Client Sample Identification /CU - U h t W Collection Collection Date Time \0 0 0 *.ir yy.Y-.-'ft,J1'v Specify Matrix Comments a Ax-i A ?x(. Ul / f'XS-U*> it X -V t: y,/ V*./ ' ''3,* . ' ''-r LAB USE ONLY CHAIN OF CUSTODY Relinquished by Date Time rf/x*-*- > \-< T X \ ^ o n OTHER INFORMATION Cooler ID # Cooler Temp. (C) < r TBaaHtpew-{j>f;e';S'iti i c S 'W/;Sr*T mmm mmt PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: 0 Sample results only 1 I Add case narrative I I Add quality control summary O Add calibration summary [~~l Add raw data Other 000491