Document 15Ebyx7YwjXgN3DLmZkqdrJwm

Hi AJ ALGO MATERIAL SAFETY DATA SHEE'i PRODUCT NALCO 5709 IROCESS ANTIFOAM Emergency Telephone Number ^ *S7 58Medical (708) 9201510(24 hours) SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5709 PROCESS ANTIFOAM DESCRIPTION: Polyglyool blend in a hydrocarbon solvent NFPA 704M/HMT.q RATING: 1/1 HEALTH 2/2 FIAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=Slight 2=Moderate 3=High 4=Extreme 0 OTHER SECTION 2 HAZARDOUS INGREDIENT8 Our hazard evaluation has identified the following chemical ingredient (s) as hazardous under OSHA's Hazard Ccmiiinication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard (s). INGREDIENT(S) CAS # APFRQX.% Hydrotreated light distillate 64742-47-8 20--40 SECTION 3 PRECAUTIONARY LABEL INFORMATION CAUTION: Ocmhustible. May cause irritation to skin and eyes. Avoid contact with skin, eyes, and clothing. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Elcpty containers may contain residual product. Do not reuse container unless properly recx>nditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Flush with water for 15 minutes. Call a physician. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat synptcms. call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control synptons and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vaaiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION HUMAKY ROUTE(S) OF EXPOSURE: Eye, Skin, Inhalation PAGE 1 OF 7 SAL 000010110 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 N NALCO GS758 MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5709 FROCESS ANTIPOAM Emergency Telephone Number Medical (708) 920-1 SI 0 (24 houra} SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED ) EVE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Can cause transient irritation. Can cause moderate irritation. Can cause central nervous system depression, nausea, dizziness, vccdting or unconsciousness depending an the length of exposure and on the first aid action given. Can be harmful. Prolonged inhalation of mist or vapor may cause nausea, dizziness, light-headedness, vomiting or unconsciousness depending on the length of exposure and the first aid action given. SYMPICMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. AGGRAVATION OF EXISTING CONDITIONS: a review of available data does not identify ary worsening of existing conditions. 8ECTI0N 6 TOXICOLOGY INFORMATION ACL7IE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but toxicity studies of the ingredients in Section 2 have been reviewed. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS) : Paraffinic/naphthenic solvent LD50 * 40,000 mg/fcg ACUTE DEPMAL TOXICITY (ALBINO RABBITS): Paraffinic/naphthenic solvent LD60 2,000 - 4,000 mg/kg PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS): SKIN IRRITATION INDEX ERAIZE RATING: 5.2/8.0 Paraffinic/naphthenic solvent PRIMARY EYE IKRITATICN TEST (ALBINO RABBITS) : EYE IRRITATION INDEX ERAIZE RATING: 5/110.0 Paraffinic/naphthenic solvent 8ECTI0N 7 PHYSICAL AND CHEMICAL PROPERTIES 00ICR: Light straw DENSITY: SOLUBILITY IN WATER; SPECIFIC GRAVITY: FCR4: liquid 8.17 Ibs/gal. Dispersible 0.98 70 Degrees F ODOR: Hydrocarbon ASTM D-1298 RAGE 2 OF 7 SAL 000C10011 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE ILLINOIS B05B3-1198 A AIALCO MATERIAL SAFETY DATA SHEET a ^ tj PRODUCT NAIOO 5709 PROCESS ANITPQAM Emergency Telephone Number gM*dlc*l (708) 20-1510(24 hour*) C$758 SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES ( CONTINUED ) pH (at 20%) = VISCOSITY: POUR POINT: FLASH POINT: 7.0 380 SUS 100 Degrees F Less than 10 Degrees F 188 Degrees F (FMCC) ASIM E-70 ASTM D-2983 ASTM D-97 ASIM D-93 NOTE: These physical properties are typical values for this product. 8ECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 188 Degrees F (FMCC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. SECTION 9 REACTIVITY INFORMATION INOCMPATIBIUTY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THEFMAL DEXXMP06ITTON PRODUCTS: In the event of ocnhustion 00, 002 may be formed. Do not breathe snbke or fumes. Near suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator. For large spills, entry into large tanks, vessels or enclosed snail spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recortnended. VENTILATION: General ventilation is roocnmended. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles when attaching feeding equipment or doing maintenance. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. PAGE 3 OF 7 SAL QC0C1C012 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 A MATERIAL SAFETY DATA SHEET NAIOO 5709^CSS^NrnTCftM NALCO GS758 Emergency Telephone Number Medical (708) 920-1510 (24 hour*) SECTION 11 SPILL AND DISPOSAL INFORKATION IN CASE OF TRANSPORTATION ACCIDENTS, CAIL THE FOLLOWING 24-HOUR TELEEHCNE NUMBER (703-920-1510) SPHi OONIRDL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any oaranercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CXR&A in Section 14. DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RGRA) 40 CFR 261, since it does not have the characteristics of Subpart c, (i.e. D001 through D017) nor is it listed under Subpart D. As a rKxvhazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be incinerated in accordance with local, state and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION AQUATIC LATA: 96-hour static acute LC50 to Bluegill Sunfish * 135 ppm 96-hour static acute LC50 to Rainbow Trout = 83.0 ppm If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT TRDPER SHIPPING NAME/HAZARD CQCE - (XMBOSTIRTE LIQUID, N.O.S. CO-ffiCSTIBLE LIQUID NA 1993 CONTAINS - ALIHiATIC HYEROCARBCNS SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. PAGE A OF 7 SAL 0CCC1C113 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60^53-1198 MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5709 FROCESS ANTIFOAM emergency Telephone Number Mftdlcal (706) 620-1510 (24 hour*) GS7 58 8ECTION 14 REGULATORY INFORMATION ( CONTINUED ) FEDERAL REGULATIONS: OSHA'S HAZARD COMMUNICATION HJIE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shown below. Hydrotreated light distillate - Skin irritant, combustible Hydrotreated light distillate (oil mist) = TWA 5 mg/m3 AQGIH/TLy CERCTVSUrER^i^NDr 40 CFR 117, 302: Notificaticn of spills of this product is not required. SARA/SUFfRFUND AMENDMENTS AND REAUTHCRIZA3TCN ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) : This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370) : Oar hazard evaluation has found this product to be hazardous. The product should be reported under the following ERA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning oenmission, state emergency response octmissicn and local fire department is required after October 17, 1987 if you have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. TOXIC SUBSTANCES OCNIRDL ACT (TSCA): RAGE 5 OF 7 SAL 000010014 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALOO 5709 PROCESS anitkmm Emergency Telephone Number Medical (70S) 920-1510 (24 hour*) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND KEOOVtRY ACT (RCRA) , 40 CFR 261 SUBPART C & D: If this product becomes a waste, it does not meet the criteria of a hazardous waste* FEDERAL WATER POLUJITON CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (formerly Sec. 307), 40 CFR 116 (formerly Sec. 311): None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the dean Air Azt: Itolyprcpylene glycol - Section 111 STATE REGULATIONS: CALEPCNNIA FRDPOSITTCW 65: None of the chemicals car the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient (s) are disclosed for compliance with State Right To Know Laws: Hydrotreated light distillate Polyglycol ester Polypropylene glycol 64742-47-8 Trade secret 25322-69-4 SECTION 15 ADDITIONAL INFORMATION None SECTION 16 U8ER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with cur product literature. Individuals handling this product should be PAGE 6 OF 7 0C00lCl5 NALCO CH MICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B MATERIAL SAFETY DATA SHEET PRODUCT NAIOO 5709 IWXESS AOTTPQBM slALCO Emergency Telephone Number Mtdlcftl (708) 920-1510 (24 hour*) GS758 8ECTION 16 USER'S RESPONSIBILITY ( CONTINUED ) informed of the reccmnended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT CN CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., KLaassen, C. D., and Adirur, M. O., eds., Maanillian Publishing Ccnpany, Inc. N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Ccupany, N.Y., 1981. PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Reinhold Ccnpany, N.Y., 6th edition, 1984. IAKC MDNOQATHS CN THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D. , Clayton, F. E., eds., John Wiley and Scts, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS CN CHEMICAL SUBSTANCES, U.S. Department of Health and Hunan Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Sutpart Z, Toxic and Hazardous Substanaes, Occupational Safety and Health Administration (QSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. PREPARED BY: Ricky A. Stackhouse FhD., Toxicologist CATE CHANGED: 05/16/90 DATE PRINTED: 10/08/90 PAGE 7 OF 7 SAL 0C0C1C0I6 NALCO CHEMICAL COMPANY ONE NA _CO CENTER NAPERVILLE, ILLINOIS BO563-1190 IVIALCO MATERIAL SAFETY DATA SHEET PRODUCT <rS 7 58 Emergency Telephone Number Medical <706) 920-1510(24 hours) ( S,,L 00QC1C17 NALCO CHEMICAL COMPANY ONE NALCP CENTER NAPERVILLE. ILLINOIS 60563-1 198 'Wf