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^interoffice Communication (conoco) o* Subject September 8, 1981 HOPE MATERIAL SAFETY DATA SHEETS Enclosed are the final drafts for the HDPE Material Safety Oata Sheets. These sheets will have the Conoco Chemicals product name, plant address and telephone numbers added when they are available. _ tfiacte oq the sheets. Please-. iy further Tonments you may have to me by September 28. Thomas G. Grumbles ajo Distribution: aaMewtHM Ken Mievre - PC "(V Oi'otas** -PC - ' * .arry^flfubbard - Houston Bill Broddle -PC Dr. Whetstone - PC Tom Williams - Houston Michele Malloy - Houston Susan Litzau - Houston. MATERIAL SAFETY DATA SHEET Conoco Chemicals 3 Greenway Plaza East Houston, Texas 77001 fl PRODUGriDEffTlFOTIONV MANUFACTURER'S NAME Conoco Chemicals REGULAR TELEPHONE NO. EMERGENCY TELEPHONE NO. AOORESS P. 0. Box 2197 - Houston. TX 77001 TRADENAME Conoco 1150 SYNONYMS i,;It, -- ~ High Density Polyethylene ...........-- II HAZARDOUS INGREDIENTS! r; >. - ` HAZARD DAW ' . BOILING POINT (*F.)YAPORPRESUR(mnrH*) VAPOR DENSITY (AIR = t) SOLUBILITY IN WATER APPEARANCE ANO ODOR N/A N/A N/A N/A SPECIFIC GRAVITY (H^l 1) PERCaiT VOLATILE BTV0tUME(%) EVAPORATION RATE ( -1) MELTING POINT Translucent Odorless Pellets 0.957q/cm^ N/A N/A 133 C FLASHPOINT (TEST METHOD) N/A AUT0IGNIT10N TEMPERATURE N/A FLAMMABLEJLIMITS IN AIR. % 8Y VOL. LOWER N/A UPPER N/A EXTINGUISHING MEHA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL HRE AN0 EXPLOSION HAZARD Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxideyirri tating fumes and smoke. Self-contained breathing apparatus should be wuni if enLei iiiu lUiiPined sparer VEV-274 \! i HALTti HAZARtt INFORMATION; FIRST AID STEk if dUSf enters the eye, flush with large amounts of water. i SION: N/A INHALATION: N/A WESTON: Seek Medical Aid ** -*&*'-** `V,. ;4?W6'c<&ed to the eyes. ttnu This material is not expected to present a hazard to the intact skin. S*B,: Molten resins will produce thermal burns. * MuummH This material is not expected to present an inhalation hazard under normal use. ^ ~=rtimTmm- 1,115 materia1 is not expected to present an ingestion hazard. ERECTS OF OVEREXPOSURE: , --EroiUtt.LJmUL No adverse health effects are expected to occur with exposure to this material. Irritation to the upper r1aQtWoUryI J trUaBcvtywJaWyJ.o,wcvcv<uari wnit* hw* exposure to fumes or smokes produced when heating or burning polyethylene THRESHOLD UMIT VALUE (TLV) ACGIH: 10 mg/m nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtQNTACT: N/A INHALATION: N/A INGESTION: N/A SPECIAL PRECAUTIONS: upj-2?4i'?7 '_________________________________ ______________| CONOmaKS wNTrtnoTMSTO INSTABILITY FitACTIVITY1 DATA. MCOMPAHMUTY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMFOSTTION PRODUCTS Burning or heating to high"-temperatures may release irritating low molecular weight composition products. CONOmONS COHTRiSUTMG TO HAZARDOUS POLYMERIZATION . Will not occur.- VII SFiLilOR LAICPROCEDURES" ns? * i IF MATERIAL IS RSAASEO OR SPILLED Sweep up pellets and place In suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. "rufi?' NEUTRAUZMG CHBMCALS N/A WASTE DISPOSAL METHOD May be disposed "of in landfill in accordance with local, state or federal TeguTHtTOpS. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY in DETAIL): If dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. 4 GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A VEV-274I SPECIAtPRECAUTIONSl IMCO HAZARD CLASS AMD NUMBER M/A HAZARB CLASSIFICATION INFORMATION; US DOT CLASSIFICATION N/A EEC 0ANGEROUS SUBSTANCE CLASSIRCAHON AOR CLASS NUMBER EEC Spam RISKS AND SAFETY ADVICE ... .9002-88-4 -THANSPORIAnONANaSTORAGE STORAGE TRANSPORT TEMPERATURE STORAGE/TRANSPORT PRESSURE LQADING/UNLOAOING T0HPERATURE % VISCOSnY AT LOAOING/UNLOAOING TEMPERATURE HANDLING. AND STORAGE MATERIALS AND COATINGS. UNSUITABLE* l The aoove data is based on tests and expenencs which Conoco oelieves reiiaoie and are supplied for informational ourooaes only. Conoco disclaims any liability for damage or injury whicn rasults from m# use of me above data and noming contained therein shall constitute a guar antee, WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent liaoiiity) by Conoco with resoect to me data, the product oesenbed, or their use for any soeofic purpose, even if met purpose is known to Conoco. / l.]EV~2741 Q9 ** ^ y 1 * ?< . - (conoco) MATERIAL SAFETY DATA SHEET Conoco Chemicals 5 Greanway Plaza East P.0. Box 2197 Houston, Texas 77001 | , --V PROnUCTTIDENTIFlCATlON* - ____________ ____ Mwiuimiunen s iwurc Conoco Chemicals REGULAR TELEPHONE NO. EMERGENCY TELEPHONE NO. ADDRESS p Q Box 2197 - Houston. TX 77001 TRADENAME Conoco T070 SYNONYMS High Density Polyethylene ...............----- ---------------- ---------- -------------------------------------------------------------------------- 1 JIt HAZARDQU&TNGREDIENTST. BOILING POINT (*P.) . WORPRESURE(ntN*> VAPOR DBiSTTY (AIR-t) SOLUBILITY IN WATS* APPEARANCE AND ODOR N/A N/A N/A N/A SPECIFIC GRAVITY (H,0 = 1) PERCENTV0LAT1LE BY VOLUME (%) EVAPORATION RATE ( =D MELTING POINT Translucent Odorless Pellets 0.953g/cm3 N/A N/A 132 C FLASH POINT (TESTMETHOO) N/A AUTOIGNITION TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % BY VOL. __________ t__ LOWER m/a UPPER N/A EXTINGUISHING: MEDIA Water spray on dry chemical (Ammonium phosphate Base) SPECIAL FIRE FIGHTING PR0C8MJRES UNUSUAL FIRE AND EXPLOSION HAZARD Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide,irri tating fumes and smoke. Self-contained breathing apparatus should be vninr-rf- enLei inu hjh fined spate. ............... 70.;-' t!' .i i FIRST AID mEhLIH hazahq, information If dust enters the eye, flush with large amounts of water. 4 Sot N/A INHALATION: N/A Seek Medical Aid t* ) IffWWaffCthe eyes. ^ This material is not expected to present a hazard to the Intact skin. 5KH,: Molten resins will produce thermal bums. jMMjtngil; This material is not expected to present an inhalation hazard under normal use. M6ESTI0N: Th'*s mater'ial is not expected to present an ingestion hazard. No adverse health effects are expected to occur witn EFFECTS OF 0V6TEXP0SURE: exposure to this material. Irritation to the upper *,***-. ____ --- .xesjMnatory tract may occur .with exposure to fumes r or-smokes produced when heating or burning polyethylen 5 ** ................. ............................. THRESHOLD UMIT VALUE (TLV) 3 ACGIH: 10 mg/m nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A SPECIAL PRECAUTIONS: 1 u yEU-274 ______1 . . il-. HCACTiVlTY; DATA: MCOMMTBIUTY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to hlgbVteifiperatures may release Irritating low molecular weight composition products. CONOfllONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION . Will not occur.- * PILL Off LEAK" PROCEDURES' IPHaTEUAL IS RELEASED OR SPILLED Sweep up pellets and place In suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRAUZMQ CHEMICALS N/A WASTE DISPOSAL METHOO May be disposed of in landfill in accordance with local, state or federal --regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY in DETAIL): if dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING ANO EQUIPMENT: N/A yU-2?42Q2 11 i IMCO HAZARD CUSS ANO NUMBER N/A 1 - SPECIAt PRECAUTIONS^ INFORMATION , US DOT CLASSIFICATION N/A EC OANGEROUS SUBSTANCE CLASSIFICATION ADR CLASS NUMBS) SC SPECIAL RISKS ANO SAFETY ADVICE CAS NUMB 9002-88-4 ftAtfU`5TURAU%_ - . "- ."'' >Tk-' STORAGE TRANSPORT TEMPERATURE STORAGE/TRANSPORT PRESSURE LOADING/UNLOADING TEMPERATURE 1 VISCOSITY AT LOAOING/UNLQAQING TEMPERATURE `tiaototflh HANDLING. AND STORAGE MATERIALS ANO COATINGS "SUITABLE 1 UNSUITABLE The acovs data is based on tests and experience whicn Conoco oelieves reiiaote and are supplied for infdrmanonai purposes only. Conoco disclaims any liaoiiity for damaga or injury whicn results from the usa of the aPova data and nothing contained therein shall constitute a guarantaa. WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent liaoiiity) by Conoco with respect to the data, the product aascnbaC, or their usa for any specific purpose, even if that ouroosa is known to Conoco. v'EV~2?42n J MATERIAL SAFETY DATA SHEET Conoco Chemicals S Groanway Plaza East P.O. Box 2197 Houston, Texas 77001 1 . - : MANUFACTURER'S NAME producthdentifotion; ^ . - Chem1calV REGULAR TELEPHONE NO. EMERGBMTT TELEPHONE NO. -r-- P. 0. Box 2197 - Houston. TX 77001 TRADE NAME Conoco DR 721 SYinNiOu -Ni iYi_.Ml* S . Mr1 High Density Polyethylene ................ 1 II HAZARDOUS INGREDIENTS : 1 *' r HGnuttorac ; imh ur BOILING POINT (*F.) VAPOR PRESUREtmtHe:) VAPOR DENSITY (AIR - 1) SOLUBILITY IN WATER APPEARANCE AND 000R *1 Qlifil N/A SPECIFIC GRAVITY (H,0 * 1) 0.964g/cm3 PERCENTVOLATILE N/A BY VOLUME (%) N/A N/A EVAPORATION RATE ( U N/A N/A MELTING POINT 136 C Translucent Odorless Pellets Ji'--*' '1 <1 AU*UPlU iVuttoiB FLASHPOINT (TEST METHOD) N/A AUTOIGNITION TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % BY VOL LOWER N/A UPPER N/A EXTINGUISHING MEDIA SPECIAL FIRE BGHTWG PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARD Water spray on dry chemical (Ammonium phosphate Base) Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide^irri tating fumes and smoke. Self-contained breathing apparatus should be wum if entering confined spate.-------------------------- ---------------------- - 1 VEU-'. RRST AID HtALl h HAZARil INFORMATION! If dust enters the eye, flush with large amounts of water. SUN: N/A MHALKIHM: N/A MGESTKM: Seek Medical Aid Dm - -bo-prwreht a-Haz.ard to the eyes. ,Aim! This material is not expected to present a hazard to the intact skin. Molten resins will produce thermal bums. ftlHftlffnnn- This material is not expected to present an inhalation hazard under normal use. ffmrrnot). This material is not expected to present an ingestion hazard. EFFECTS OF OVEREXPOSURE: ^leUltUDfllgXFOAUHE: - No adverse health effects are expected to occur witn .exposure to this material. Irritation to the upper ;.r$sfii!'atory tract may occur with exposure to,fumes or smokes produced when heating or burning polyethylene. i .a* * THRESHOLD UMIT VALUE (TLV) 3 ACGIH: 10 mg/m nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A -------------------------------------------------------------------------------------------------------------------------- ----------------------------------- ------- INGESTION: N/A SPECIAL PRECAUTIONS: MEU-274 j i HEACTiViTYTDATiU; MCOMPATntUTY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to high'.-temperatures may release irritating low molecular . weight composition products. COWHHONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur.- SFIIC OR LEAIC PROCEDURES'- "in IS RELEASS) OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. -*"* * *c NBJTRAUZMG CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local, state or federal --------- regulations. TE an VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY in DETAIL); If dust is produced during handling of material an approved air-purifying respirator should be used. EYE Standard safety glasses or chemical goggles. 4 4 GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A UEV-274206 SPECrACPRECAimONSt W^S^WfS: ^Hl^ttCO^RCffnOrilNFQRMAnOH IMCO HAZARD CLASS AND NUMBS! US DOT CLASSIFICATION N/A N/A ^*'r!r y~- C DANGEROUS SUBSTANCE CLASSIFICATION fvviT;-< ii*j ADR CLASS NUM88) SC SPECIAL RISXS AND SAFETY ADVICE CAS NUMBS! 9002-88-4 STURAGE TRANSPORT TBPSRATURE STORAGEftRANSPORT PRESSURE LDA0IN6/UNLDA0IN0 TBWPERATURE 9 RStsaKttWtf VISCOSITY AT LOAOING/UNLOAOING TEMPERATURE HANDLING. AND STORAGE MATERIALS AND COATINGS .' *" UNSUITABLE The above data is Dased on taata and expenence which Conoco oeiieves raiiaoie and are suppliad for informational purposas only. Conoco disclaims any liability for damapt or injury which rasuits from ma usa of tha abova data and nothing contained theram shall constitute a guar antee. WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent liability) by Conoco with respect to the data, the produo described, or their use for any soactfic purpose, even if that purpose is known to Conoco. ypJ-2742 1 I Cconoco) MATERIAL SAFETY DATA SHEET Conoco Chemicals 5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 II MANUFACTURER'S NAME PRODUCTIDENHFICAHQF: Conoco Chemicals REGULAR TREPHONE NO. BNER6BICY TELEPHONE NO. aowkss P. 0. Box 2197 - Houston. TX 77001 TRADE NAME Conoco T010 SYNONYMS High Oensity Polyethylene WWr 'nr n hazardous: ingredients: ^.MATGOAtOirCOliPONBfr : af\ HAZARD OXIX BOIUNG POINT (*F.) VAPORPRESURE (mm Hy.) vapor oasrrY (ajr -i) SOLUBILITY INWATER APPEARANCE AND 000R N/A N/A N/A N/A SPECIFIC GRAVITY (H^J = 1) PERCENTVOLATILE BTV0tUME(%) EVAPORATION RATE ( "IV MaTING POINT Translucent Odorless Pellets J|'m TM!W ^ i'i i ft ki 0.950g/cm3 N/A N/A 130 C FLASHPOINT (TEST METHOD) N/A AUTOIGNITION TEMPERATURE N/A FLAMMABLEJLIMITS IN AIR. % BY VOL. LOWER. _ N/A UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL HRE AND EXPLOSION HAZARD Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide^irri tating fumes and smoke. Self-contained breathing apparatus should be --wm i'i if eiiLenug uni fined space.--------------------------------------- --- MEV --1 FIRST AID HtAUH HAZARD. INFQHMATIQM^; If dust enters the eye, flush with large amounts of water. SION: N/A MHAUmON: N/A MOTION: Seek Medical Aid <Lmj This material is not expected to present a hazard to the intact skin. OT,: Molten resins will produce thermal burns. miiimrai This material is not expected to present an inhalation hazard under normal use. itimTTHffl Th"fs material 1S not expected to present an ingestion hazard. EFFECTS OF OVEREXPOSURE: No adverse health effects are expected to occur with exposure to this material. Irritation to the upper -*jcSfiiratGry tract may occur with exposure to fumes $r smokes produced when heating or burning polyethylenb OVEREXPOSURE: THRESHOLD UMIT VALUE (TLV) 3 ACGIH: 10 mg/m nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A SPECIAL PRECAUTIONS: ^EV-2?420 CONOmONS C0NTRI8UTMG TO INS lABRJTY REACTIVITY DATA-^, INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to high'.-temperatures may release irritating low molecular weight composition products. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur.- VII SPILL OR LEAK' PROCEDURES"-' STEPSTM SHAKEN IF MATERIAL IS RELEASED OR SPILLED ** Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposdd`of in landfill in accordance with local, state or federal : 'regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT* I respiratory (SPECIFY in DETAIL): if dust is produced during handling of material an approved air-purifying respirator should be used. eye Standard safety glasses or chemical goggles. GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A YEV-2742IG I 1 SPEinBEPRECBimffllS^^ > r # HAZARD: CLASSIFICATION INFORMATION MCO HAZARD CUSS AND NUMBS) N/A USOOTCUSSmCAHON N/A W&S&F- EEC DANGEROUS SUBSTANCE CLASSIFICATION AOR CLASS NUM88) SC SPECIAL RISKS AND SAFETY ADVICE CASNUMBai 9002-88-4 STORAGE TRANSPORT TEMPERATURE SWATUMtAN&GWRAfle^ STORAGE/TRANSPORT PRESSURE LOAOING/UNLOADING TEMPERATURE ; J '-* \ ^<LL. vw u'- 5" jrv;. vu % > - - --Vf VISCOSITY AT LDADING/UNLOAOING TEMPERATURE HANDLING. AND STORAGE MATERIALS AND COATINGS UNSUITABLE Th aoov data is basad on tests ana exoenence whicti Conoco oeiieves reiiaole and ars supotied for informational ourposes only. Conoco dfadaims any liability for damage or iniury whtcn raaults from the use of tha aoova data and nothing contained therein shall constitute a guar antee. WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent liaoiiity) by Conoco with respect to the data, the product described, or their use for any specific purpose, even if that purnose is known to Conoco. VEU-274211 i I MATERIAL SAFETY DATA SHEET Conoco Chemicals 5 Graonway Plaza East Houston, Texas 77001 1 -' WWW^,S,<AME PRODUCT IDENTIFICATION^ . ^ ^ - Conoco Chemicals ` REGULAR TELEPHONE NO. SRERGENCY TELEPHONE NO. AOONCSS p Q Box 2197 - Houston. TX 77001 TRADENAME Conoco 2010 SYNONYMS High Density Polyethylene : '... -- V- II h:>'1; HAZARDOUS: INGREDIENT? waBNAtORamraiiBir' ^ (HSBUBOMlt _ l*V/ , 'll SOILING POINT (*F.) . YAPORPRESUREfmnrHo;) VAPOR DENSITY (AIR t) SOLUBILITY IN WATER APPEARANCE ANO 000R N/A N/A N/A N/A SPECIFIC GRAVITY (HJ1 1) PERCENT VOLATILE BYVOLUME (%) EVAPORATION RATE ( *1) MaUNG POINT Translucent Odorless Pellets =*\i i1 * =>W W I.'1 * k\ 0.960g/cm^ N/A N/A 134 C 1 FLASHPOINT (TEST METHOD) N/A AUTOIGNITTON TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % BY VOL. d LOWER .... N/A UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium Phosphate Base) SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE ANO EXPLOSION HAZARD Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide>irri tating fumes and smoke. Self-contained breathing apparatus should be vfum if enLei iim tuiifiued space-.1- ... 1 V HEALTH HAZARD: INFORMATION: : : FIRST AID EYES: T' '* if dUst enters the eye, flush with large amounts of water. N/A /r MHAUmON: N/A ingestion: Seek nedical Aid *yar-".1 BBPMMwaiijr t^1**"* - . '*> : v4'i -fSerial"ls not expected to present a hazard to the eyes. This material is not expected to present a hazard to the intact skin. Molten resins will produce thermal bums. This material is not expected to present an inhalation hazard under normal use. BtnnrT10r|: This material is not expected to present an ingestion hazard. EFfECTSOFOVEREJCPOSURE: ifc- CHRONIC OVEREXPOSURE: No adverse health effects are expected to occur witn exposure to this material. Irritation to the upper i ratory tract may occur with exposure to fumes "smoke* produced when heating 4jr burning ..polyetbylen^. THRESHOLD UMIT VALUE (TLV) ACGIH: 10 mg/m3 nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: M/A INHALATION: N/A INGESTION: N/A SPECIAL PRECAUTIONS: VEU-274213 r UMUIWRS UMiniBUimU TO MSTMHjTt REACTIVITY QATit MCOMPXTmiUTY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PROOUCTS Burning or heating to high'temperatures may release irritating low molecular weight composition products. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur.* - SPILL Off LEAIC PROCEDURES*: iWji rr;rcinwKEr VUmbnal is roeased or spilled Sweep up pellets and place in suitable containers for recycle or disposal Pellets on walking surfaces may be a slipping hazard. N8JTRAUZMG CHEMICALS N/A WASTE DISPOSAL METHOD May be d1spos3^f in landfill in accordance with local, state or federal " regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT* 4 RESPIRATORY (SPECIFY in OETAil): If dust is produced during handling of material an approved air-purifying,respirator should be used. EYE; Standard safety glasses or chemical goggles. 44 GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING ANO EQUIPMENT; N/A VE^-2742i4 I SPECFACPRECAimONS! r HAZARD: CLASSIFICATION INFORMATION NNCO HAZARD CLASS AMO NUMBS) us oot classification N/A 4^ w ijji miwh.*** \' N/A EEC DANGEROUS SUBSTANCE CLASSIFICATION ADR CLASS NUMBS) SC SPECIAL RISKS AND SAFETY ADVICE CAS NUMBS) 9002-88-4 STORAGE TRANSPORT TEMPERATURE RTATlOff AND:STORAGE aK^srAn^gEMM STORAGE/TRANSPORT PRESSURE LOAOING/UNLOAOING TEMPERATURE % VISCOSITY AT LOAOING/UNLOAOING TEMPERATURE ........... .. HANDLING AND STORAGE MATERIALS AND COATINGS f unsuitable The acove aaca is based on casts ana axoansncs which Conoco oaiiavas raiiaoie and are supplied for informational purposas only. Conoco disdaims any liability for damage or injury which rasuits from the usa of tha aoova data and nothing contained therein shall constitute a guar antee. WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent liaoiiity) by Conoco with respect to the data, the product oescnbed, or their use for any soectfic purpose, aven if chat purpose is known to Conoco. VEV-274215 4 X* ' % DRAFT ,?Vjfc r*4 ' v - ''-** ' 'V- (conoco) MATERIAL SAFETY DATA SHEET Conoco Chemicals 5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 PRODUCTHDENTIHCATIONK -,1...^ : , V . . -'v MANUFACTURER'S NAME Conoco Chemicals REGULAR TELEPHONE NO. BIERGBtCY TELEPHONE NO. Aooness P. 0. Box 2197 - Houston. TX 77001 TRADENAME Conoco 3003 SYNONYMS High Density Polyethylene II HAZARDOUS INGREDIENTS! t^^^^WOBMEOItCOMPOl^ ` : % r ^ HAZARD OATAr SOILING POINT (*F.) VAPOR PRESURE(nwtHg.) VAPOR DENSITY (AIR SOLUBILITY IN WATER APPEARANCE ANO ODOR N/A .... _ N/A N/A N/A SPECIFIC GRAVITY (HjO = 1) PERCENTVOLATILE. BY VOLUME (%) EVAPORATION RATE ( *D MELTING POINT Translucent Odorless Pellets 0.954g/cn^ N/A N/A 132 C FLASHPOINT (TEST METHOD) N/A AUTOIGNITION TEMPERATURE N/A ____ _xebss AfcwtMV " FLAMMABLE OMITS IN AIR. % BY VOL. -___________ i___ LOWER N/A UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium phosphate Base) SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARD Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide,irri tating fumes and smoke. Self-contained breathing apparatus should be WUMI T enter inu confined space.------------------------------------------------ -- `/EU _ *5*7 V HtALIH HAZARD. INFORMATION? FIRST AID W If dust enters the eye, flush with large amounts of water. SION: N/A INHALATION: N/A M6GSTI0N: Seek Medical Aid * ----------- n~-,i/r sr............. ot Expected to presenT*cltt^ the eyes. ~ ~": ---........................... ......................... tlflll This material is not expected to present a hazard to the intact skin. Molten resins will produce thermal bums. -MHAumoN: This material Is not expected to present an inhalation hazard under normal use. INGESTION* Thls mateT"ial Is not expected to present an ingestion hazard. EFFECTS OF OVEREXPOSURE: rMUflrPVtWCCPOCTWL' *' ^iy.&CnirAtutnHInCi'i uVci niiVcXi PrOr SU"?RE~ ^r No adverse health effects are expected to occurwith exposure to this material. Irritation to the upper respiratory .tract may occur with exposure to fumes or smokes produced when heating or burning polyethylene V ` w r *- '` \ - . ' < .. * - THRESHOLD LIMIT VALUE (TLV) 3 ACGIH: 10 mg/m nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A JSPECIAL PRECAUTIONS:" VEU 274217 REACTIVITY! DATA-: MCOMFftnBflJTY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PROOUCTS Burning or heating to high'-temperatures may release irritating low molecular weight composition products. commons comtributmo to hazardous polymerization . Mill not occur.* - VII ^ SPILC Off LEflICPROCEDURES' rrtSVTOK'OQBFPHKTBUAL IS RELEASED OR SPILLED............... n** Sweep up pellets and place In suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. ' 'T- f ---tty"*" NBITRAUZMO CHEMICALS N/A WMSTE DISPOSAL METHOD May be disposed;.;pf in landfill in accordance with local, state or federal i - regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (specify in DETAIL): If dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A v*iV~2?42l i SPECIALPRECAUTIQNSI S'-,-.'.---. HAZARUCtASSIRCATlOW INFORMATION HUGO HAZABO CLASS AMO NUMBS) US 00T CLASSIFICATION N/A uia * .. -k,u"h ~ "" N/A EEC OANGEROUS SUBSTANCE CLASSIFICATION AOA CLASS NUMBER EEC SPECIAL RISKS AND SAFETY AOVICE CAS NUMBCR ^9002-88-4 STORAGE TRANSPORT TEMPERATURE GKWnQN.AND SSiSAGB^ agerriosTiiTKi>csoi>No^i^ STORAGE/TRANSPORT PRESSURE LOAOING/UNLQAOING TEMPERATURE . "r w ,. axf' VISCOSITY AT LQAOING/UNLOAOING TEMPERATURE HANDLING AND STORAGE MATERIALS AND- COATINGS UNSUITABLE * The above data is based on tests and oxpenonca which Conoco oeiieves reiiaoie and are supplied for informanonal purposes only. Conoco disclaims any liability for damage or injury which results from the use of the above data and nothing contained therein shall constitute a guar antee. WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent lianiiiiy) by Conoco with respect to the data, the product described, or tneir use for any soectfic purpose, even if that purpose is known to Conoco. 4 yE'J-27421* ,i *- MATERIAL SAFETY DATA SHEET (conoco) Conoco Chemicals 5 Greenway Plaza East P.O. Box 2197 Houston, Texas 77001 K) FLASH POINT (TEST METH00) N/A AUTOIGNITION TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % BY VOL s LOWER N/A UPPER N/A EXTINGUISHING MEDIA Water spray on dry chemical (Ammonium phosphate Base) SPECIAL FIRE FIGHTING PROCBNIHES UNUSUAL FIRE AND EXPLOSION HAZARD Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide/irri tating fumes and smoke. Self-contained breathing apparatus should be worn If ent-eiing1 Lunimeu space.----------------------------------------------- - VE REACTIVITY: DATA-' INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PROOUCTS Burning or heating to high'-temperatures may release irritating low molecular Wight composition products. CONDITIONS CONTRiSUTWO TO HAZAROOUS POLYMERIZATION Will not occur.* - VII ' SPIIC.0R LEAK* PROCEDURES" 11 ^b^'t^* 'tlB^y'iMTBIIAL IS RELEASED OR SPILLED Sweep up pellets and place in suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NEUTRALIZING CHEMICALS N/A WASTE DISPOSAL METHOD May be disposd&df in landfill in accordance with local, state or federal "-regulations. VENTILATION REQUIREMENTS General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY in DETAIL): If dust is produced during handling of material an approved air-purifying respirator should be used. EYE Standard safety glasses or chemical goggles. GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A mj-27422 $4 IMCO HAZARD CLASS AND NUMBS) N/A UN NUMBS) t N/A AOBCUSSNUMSa US DOT CLASSIFICATION N/A SC DANGEROUS SUBSTANCE CLASSIFICATION SC SPECIAL RISKS ANO SAFETY ADVICE CAS NUMBS) 9002-88-4 L ^ ^T^TRANSPORIAnOW AND STORAGE * USUAL SHIPPING CONTAINERS ELECTROSTATIC ACCUMULATION HAZAflO STORAGE/TRANSPORT PRESSURE STORAGE TRANSPORT TBIIPERATURE LOAOING/UNLOAOING TEMPERATURE ,v\' ; m VISCOSITY AT LOAOING/UNLOAOING TEMPEHATURE ' HANDLING. AND STORAGE MATERIALS AND-COATINGS SUITABLE UNSUITABLE [ The aoovB data is baaed on tests ana exoenence which Conoco believes retiabie and are supotied for informational purposes only. Conoco disclaims any liability for damage or injury which results from the use of the above data and nothing contained therein shall constitute a guar antee. WARRANTY OF MERCHANTABILITY, or representation (including freeaom from patent liaoility) by Conoco with resoect to the data, the product described, or their use for any specific purpose, even if mat purpose is known to Conoco. VEV-274223 DRAFT MATERIAL SAFETY DATA SHEET conoco Conoco Chemicals 5 Greanway Plaza East Houston, Texas 77001 FLASHPOINT (TEST METHOD) N/A AUTOIONmON TEMPERATURE N/A FLAMMABLE LIMITS IN AIR. % 8Y VOL. LOWER N/A UPPEH N/A EXT1NGUISHINS MEDIA Water spray on dry chemical (Ammonium phosphate Base) SPECIALHRE FIGHTING PROCEDURES UNUSUAL FIRE ANO EXPLOSION HAZARD Cool exposed resins with water spray to prevent melting and dripping. Incomplete combustion can lead to formation of carbon monoxide,irri tating fumes and smoke. Self-contained breathing apparatus should be woin-fr eiiLei inu tuiiPmed spate. VEU-27 42 __ 1 HEALTH HAZARDS INFORMATION! FIRST AID EVES: jf dust enters the eye, flush with large amounts of water. SKIN: N/A INHALATION: N/A INGESTION: Seek Medical Aid NATURE OF HAZARD EYES: This material is not expected to present a hazard to the eyes. aiflu This material is not expected to present a hazard to the intact skin. 5WH: Molten resins will produce thermal bums. inhalation: material is not expected to present an inhalation hazard under normal use. . irmnnirn- This materia1 *s not expected to present an ingestion hazard. ffFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: No adverse health effects are expected to occur with exposure to this material. Irritation to the upper respiratory tract may occur with exposure to fumes 0r smokes produced when heating or burning polyethylens. CHRONIC OVEREXPOSURE: THRESHOLD UMIT VALUE (TLV) ACGIH: 10 mg/rn^ nuisance dust TOXICITY DATA SKIN CONTACT: N/A EYEtONTACT: N/A INHALATION: N/A INGESTION: N/A SPECIAL PRECAUTIONS: -27 4 ^ 1 VJ; \ CONDITIONS CONTRIBUTING TO INSTABILITY REACUVTODATO^ A INCOMPATIBILITY Can be affected by oxidizing acids and some chlorinated hydrocarbon solvents. HAZARDOUS DECOMPOSITION PRODUCTS Burning or heating to highVtemperatures may release irritating low molecular weight composition products. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Will not occur. - VII ..... SPILL OR LEAK* PROCEDURES STEPS T0 8E TAXB4 IF MATERIAL IS RELEASED OR SPILLED Sweep up pellets and place In suitable containers for recycle or disposal. Pellets on walking surfaces may be a slipping hazard. NBJTHAUZM6 CHEMICALS N/A WASTE DISPOSAL METHOD May be disposed of in landfill in accordance with local, state or federal regulations. General ventilation for thermal processing and nuisance dust control. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY (SPECIFY IN detail): If dust is produced during handling of material an approved air-purifying respirator should be used. EYE: Standard safety glasses or chemical goggles. * 4 GLOVES:Generally not required unless handling hot or molten resins. OTHER CLOTHING AND EQUIPMENT: N/A ! spEcrfltPHECflonoMsr^f - N^xj^^^#^^^HftZAflgCASSIHOniON: INFORMATION IMCQ HAZARO CLASS ANO NUMBER US DOT CLASSIFICATION N/A N/A UN NUMBER N/A EEC 0ANGEROUS SUBSTANCE CLASSIFICATION ADR CLASS NUMBS) SC SPECIAL RISXS ANO SAFETY ADVICE CAS NUMBER 9002-88-4 USUAL SHIPPING CONTAINERS STORAGE TRANSPORT TEMPERATURE TRANSPORTATION AND STORAGE ELECTROSTATIC ACCUMULATION HAZARD STORAGE/TRANSPORT PRESSURE LOADING/UNLOADING TEMPERATURE VISCOSITY AT LOAOING/UNLOADING TEMPERATURE HANDLING ANO STORAGE MATERIALS AND COATINGS SUITABLE UNSUITABLE J The *jdov data is baaed on tests and sxoenanc* which Conoco oeiieves reiiaole and are suopiied for informational purposes onty. Conoco disclaims any liaoiiity for damage or injury wtncn results from the use of the above data and nothing contained therein shall constitute a guar* ante#, WARRANTY OF MERCHANTABILITY, or representation (including freedom from patent liaoiiity) by Conoco with rasped to the data, the pradua described, or their use for any soectfic purpose, even if that purpose is known to Conoco. i,,!EV,J-274227