Document 10k5oGx7wE8vd8m8GwMBMwdrj

fXS BETZ PROCESS |w| CHEMICALS, INC P.O. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 MATERIAL SAFETY DATA SHEET 0 S 7 57 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) (215) 355-3300 DISTRIBUTED: OCT-24-1990 PRODUCT : BETZ DM-1502 (PAGE 1 OF 3) EFFECTIVE DATE 01-29-90 PRINTED: 10-Apr-1990 REVISIONS TO SECTIONS: 1,APPENDIX/9 PRODUCT APPLICATION : A WATER BASED DEFOAMER. --------- SECTION 1...................... --HAZARDOUS INGREDIENTS--------------------------------- INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS, PEL'S AND TLVrS FOR SPECIFIC PRODUCT INGREDIENTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PAGE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. MINERAL OIL(MILDLY SOLVENT-REFINED OR HYDROTREATED OILS)***CAS#64742-30-9 ; POTENTIAL SKIN TUMORIGEN(BASED ON CHRONIC ANIMAL SKIN PAINTING STUDIES); PEL:5MG/M3;TLV:5MG/M3. TRADE SECRET INGREDIENT(E043);EYE IRRITANT;PEL:NONE;TLV:NONE.THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. TSRN 125438 - 5031P SECTION 2........... ............... TYPICAL PHYSICAL DATA PH: AS IS (APPROX.) FL.PT.(DEG.F): >200 SETA(CC) VAPOR PRESSURE(nunHG) : 22 VISC cps70F: 1300 EVAP.RATE: <1 ETHER*1 PHYSICAL STATE: EMULSION 5.0 ODOR: HYDROCARBON SP.GR.(70F)OR DENSITY: 8.0 LBS/GAL VAPOR DENSITY(AIR=1): <1 %SOLUBILITY(WATER): 0 APPEARANCE: WHITE FREEZE POINT(DEG.F): 30 --------- SECTION 3......................... -REACTIVITY DATA---------------------------------------------------------- STABLE.MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY 'B' THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. SAL OOGOICOO* flAS BETZ PROCESS IJXJJ CHEMICALS, INC P.O. BOX 4900 The Woodlands, Texas 77367 (713) 367-2442 S767 MATERIAL SAFETY DATA SHEET (PAGE 2 OF 3) PRODUCT: BETZ DM-1502 ........... SECTION 4-......................... HEALTH HAZARD EFFECTS............................................................. ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE SLIGHTLY IRRITATING TO THE SKIN.MAY CAUSE DERMATITIS. ACUTE EYE EFFECTS *** MODERATELY IRRITATING TO THE EYES ACUTE RESPIRATORY EFFECTS *** VAPORS,GASES,MISTS OR AEROSOLS KAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** PROLONGED OR REPEATED EXPOSURES MAY CAUSE DEFATTING-TYPE DERMATITIS; LIFETIME SKIN PAINTING STUDIES IN MICE HAVE PRODUCED SKIN TUMORS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** PROLONGED EXPOSURE MAY CAUSE DRYING AND CRACKING OF SKIN. ----------SECTION 5-........................... FIRST AID INSTRUCTIONS-------------- ------------------- ------------SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING.WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES.IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*** REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMMED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ........... SECTION 6........................... SPILL,DISPOSAL AND FIRE INSTRUCTIONS------------------SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. FLUSH AREA WITH WATER. WET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL/C02/F0AM OR WATER. SLIPPERY CONDITION. USE SAND/GRIT SAL OOqoio 005 tfXS BETZ PROCESS CHEMICALS, INC P.0. BOX 4300 The Woodlands, Texas 77387 (713) 367-2442 GS7S7 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT: BETZ DM-1502 ........... SECTION 7----------------------- SPECIAL PROTECTIVE EQUIPMENT...................................... .. USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE USE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY. USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** NEOPRENE GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES ............SECTION 8----------------------- STORAGE AND HANDLING PRECAUTIONS--------------------------STORAGE INSTRUCTIONS*** KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION,STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** NORMAL CHEMICAL HANDLING THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) VrtWoWoWrVoV** VoV-**VoV>'r>V**-*-*>'(VrjWnt***VrVr>VVriWrA-AtShAtV 'jWWr* iWr APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OF THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. ANY CHANGES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ...REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: TREAT AS OIL SrILL ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: NOT APPLICABLE ...DOT HAZARD/UN#/ER GUIDE# IS: NOT APPLICABLE ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: MINERAL OIL(64742-30-9) ...SARA SECTION 313 CHEMICALS: TRADE SECRET(E043)--GLYCOL ETHER , 2.0-5.0% ...SARA SECTION 312 HAZARD CLASS: DELAYED(CHRONIC) ...MICHIGAN CRITICAL MATERIALS: NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 1 ; FIRE - 1 ; REACTIVITY - 0 ; SPECIAL - NONE ; PE - B SAL 000010006 |JftJl BETZ PROCESS chemicals, INC The woodlands, Texet /***( (713) 367*3442 material safety data sheet 24 HOUR EMERGENCY TELEPHONE (HEALTH OR ACCIDENT) <215) 355-3300 6S7&7 DISTRIBUTED: SEP-26-1990 PRODUCT ; BETZ DM-1502 (PACE 1 OP 3) EFFECTIVE DATE 01-29-90 PRINTED: lO-Apr-1990 REVISIONS TO SECTIONS: 1.APPENDIX/9 PRODUCT APPLICATION : A WATER BASED DEFOAMER. ........... SECTION 1..........................HAZARDOUS INGREDIENTS..................................... INFORMATION ON PHYSICAL HAZARDS, HEALTH HAZARDS. PEL'S AND TLV'S FOR SPECIFIC PRODUCT XNCREDI2NTS AS REQUIRED BY THE OSHA HAZARD COMMUNICATIONS STANDARD ARE LISTED. REFER TO SECTION 4 (PACE 2) FOR OUR ASSESSMENT OF THE POTENTIAL ACUTE AND CHRONIC HAZARDS OF THIS FORMULATION. MINERAL OILCMILDLY SOLVENT-REFINED OR HYDROTREATED 0ILS)***CAS#64742-30-9; POTENTIAL SKIN TUMORIGEN<BASED ON CHRONIC ANIMAL SKIN PAINTING STUDIES); PEL: 5HC/M3 ; TLV: 5MG/M3 . TRADE SECRET INGREDIENT(E043) ;EYE IRRITANT; PEL .NONE; TLV: NONE. THIS CHEMICAL IS NOT ON ANY STATE RIGHT-TO-KNOW LIST. TSRN 12543B - 5031P ........... SECTION 2--------------------- TYPICAL PHYSICAL DATA............................................................. PH: AS IS (APPROX.) FL.PT.(DEG.F): >200 SETA(CC) VAPOR PRESSURE(mnHG) : 22 VISC cps70F: 1300 EVAP . RATE: <1 ETHER**1 PHYSICAL STATE: EMULSION 5.0 ODOR: HYDROCARBON SP.GR.(70P)0R DENSITY: $.0 LBS/GAL VAPOR DENSITY(AIR1): <1 %SOLUBILITY(VATER): 0 APPEARANCE: WHITE FREEZE POINT(DEG.P): 30 --SECTION 3......................... REACTIVITY DATA _ .*BLE .MAY REACT WITH STRONG OXIDIZERS.DO NOT CONTAMINATE.BETZ TANK CLEAN-OUT CATEGORY *B* THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. 30`d jn^ding 09 01 SAL 000010007 W3-OQdd 2138 WOdd 6*:ST 066T-?2-d3S BETZ PROCESS CHEMICALS, INC. 6 S 7 57 P.0. BOX 4300 Thw Woodlands, Tsxas 77307 (713) 367-244^ MATERIAL SAFETY DATA SHEET (RACE 2 OF 3) PRODUCT: BETZ DH-1502 --------- SECTION 4---------------------- HEALTH HAZARD EFFECTS................ ......................................... ACUTE SKIN EFFECTS *** PRIMARY ROUTE OF EXPOSURE SLIGHTLY IRRITATING TO THE SKIN.MAY CAUSE DERMATITIS. ACUTE EYE EFFECTS *** MODERATELY IRRITATING TO THE EYES ACUTE RESPIRATORY EFFECTS *** VAPORS, GASES .MISTS OR AEROSOLS MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE DIZZINESS AND HEADACHE. CHRONIC EFFECTS OF OVEREXPOSURE*** ^^ PROLONGED OR REPEATED EXPOSURES MAY CAUSE DEFATTING-TYPE DERMATITIS; LIFETIME SKIN PAINTING STUDIES IN MICE HAVE PRODUCED SKIN TUMORS. MEDICAL CONDITIONS AGGRAVATED *** NOT KNOWN SYMPTOMS OF EXPOSURE *** PROLONGED EXPOSURE MAY CAUSE DRYING AND CRACKING OF SKIN. ........... SECTION 3.............................FIRST AID INSTRUCTIONS..................................................... SKIN CONTACT*** REMOVE CONTAMINATED CLOTHING .WASH EXPOSED AREA WITH A LARGE QUANTITY OF SOAP SOLUTION OR WATER FOR 15 MINUTES EYE CONTACT*** _ IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATELY CONTACT A PHYSICIAN FOR ADDITIONAL TREATMENT INHALATION EXPOSURE*-** _ ___ REMOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR.APPLY APPROPRIATE FIRST AID TREATMENT AS NECESSARY INGESTION*** DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM DO NOT INDUCE VOMITING.IMHED.CONTACT PHYSICIAN.DILUTE CONTENTS OF STOMACH USING 3-4 GLASSES MILK OR WATER ........... SECTION 6......................... SPILL,DISPOSAL AND FIRE INSTRUCTIONS...................... SPILL INSTRUCTIONS*** VENTILATE AREA,USE SPECIFIED PROTECTIVE EQUIPMENT.CONTAIN AND ABSORB ON ABSORBENT MATERIAL.PLACE IN WASTE DISPOSAL CONTAINER. THE WASTE CHARACTERISTICS OF THE ABSORBED MATERIAL,OR ANY CONTAMINATED SOIL, SHOULD BE DETERMINED IN ACCORDANCE WITH RCRA REGULATIONS. FLUSH AREA WITH WATER. VET AREA MAY BE SLIPPERY. SPREAD SAND/GRIT. DISPOSAL INSTRUCTIONS*** WATER CONTAMINATED WITH THIS PRODUCT MAY BE SENT TO A SANITARY SEWER TREATMENT FACILITY,IN ACCORDANCE WITH ANY LOCAL AGREEMENT,A PERMITTED WASTE TREATMENT FACILITY OR DISCHARGED UNDER A NPDES PERMIT PRODUCT(AS IS)- INCINERATE OR BURY IN APPROVED LANDFILL FIRE EXTINGUISHING INSTRUCTIONS*** FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS(FULL FACE-PIECE TYPE).PROPER FIRE EXTINGUISHING MEDIA: DRY CHEMICAL/C02/F0AM OR WATER. SLIPPERY CONDITION. USE SAND/GRIT sal ocociCQca fjXS BETZ PROCESS 1^1 CHEMICALS, INC 6 S 7 57 P.o. BOX 4300 The Woodlands, Texas 77387 (713) 367*2443 MATERIAL SAFETY DATA SHEET (PAGE 3 OF 3) PRODUCT: BETZ DM-1502 ........... SECTION 7..........................SPECIAL PROTECTIVE EQUIPMENT.......................................... USE PROTECTIVE EQUIPMENT IN ACCORDANCE WITH 29CFR SECTION 1910.132-134. USE RESPIRATORS WITHIN USE LIMITATIONS OR ELSE DSE SUPPLIED AIR RESPIRATORS. VENTILATION PROTECTION*** ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS RECOMMENDED RESPIRATORY PROTECTION*** IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY. USE A RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. RECOMMENDED SKIN PROTECTION*** neoprene GLOVES WASH OFF AFTER EACH USE.REPLACE AS NECESSARY RECOMMENDED EYE PROTECTION*** SPLASH PROOF CHEMICAL GOGGLES ........... SECTION 8.......................... STORAGE AND HANDLING PRECAUTIONS............................... STORAGE INSTRUCTIONS*** KEEP DRUMS A PAILS CLOSED WHEN NOT IN USE. STORE IN COOL VENTILATED LOCATION. STORE AWAY FROM OXIDIZERS HANDLING INSTRUCTIONS*** NORMAL CHEMICAL HANDLING ***^**************^'*^***4^-4*******-*****^***** ****>************** THIS MSDS COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD HAROLD M. HERSH (ENVIRONMENTAL INFORMATION COORDINATOR) * A * * ********'A **~/rw***A*,A~A-A** AAAAAAAA******* *** ************** ****** * ******** APPENDIX: REGULATORY INFORMATION THE CONTENT OF THIS APPENDIX REPRESENTS INFORMATION KNOWN TO BETZ ON THE EFFECTIVE DATE OP THIS MSDS. THIS INFORMATION IS BELIEVED TO BE ACCURATE. NY CHANCES IN REGULATIONS WILL RESULT IN UPDATED VERSIONS OF THIS DOCUMENT. ...TSCA: ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY ..REPORTABLE QUANTITY(RQ) FOR UNDILUTED PRODUCT: treat as oil spill ...RCRA: IF THIS PRODUCT IS DISCARDED AS A WASTE,THE RCRA HAZARDOUS WASTE IDENTIFICATION NUMBER IS: NOT APFLICABLE ...DOT HAZARD/UN#/ER GUIDE# IS: NOT APPLICABLE ...THIS PRODUCT CONTAINS THESE CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY: MINERAL 0IL(64742-30-9) -- ...SARA SECTION 313 CHEMICALS: TRADE SECRET(E043)--GLYCOL ETHER , 2.0-5.0% ...SARA SECTION 312 HAZARD CLASS: DELAYED(CHRONIC)-- ...MICHIGAN CRITICAL MATERIALS; NONE PRESENT IN SIGNIFICANT AMOUNTS NFPA/HMIS : HEALTH - 1 ; FIRE - 1 ; REACTIVITY - 0 ; SPECIAL - NONE : FE - B SAL 00001C009