Document 10QED4YGvZb57kMggRoRMREDa
FORM N0.45A 201-12
PERCHLOR SHIPMENTS
1967 Avg .
TYPE 207
Color
APha
Specific gravity
20/20 C
Distillation Range
C
Lor
Hi gh
Water Content Cloud Point
C
Non-Volatile
GM-100 ML
pH
Acid Acceptance
* as NaOH
Coper Corrosion
Acioity Ml of O.CI N NaOH Flask MG/30 CM2
Soxhlet MG/30 CM2 CONOENSER MG/30 CM2 Chlorides
ppm
9. 1.624
120.8 121.7 To t.ooic 8.4
-- -- -- 0.15
JAN
ft
_ Co
ft. 9
-- -- --
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY PRODUCT REPORT
FEB
MAR
APR
MAY
JUNE JULY
AUG
SEP
5
wm
(0
-- 8.4
8 1.622
7
mm
_
-- 8.6
--
_ (o
8.6
7 --
--
-
XO---------
--
8.4
_ -- -- _ --
--
- ----
--
--
- ----
-
-
- ---
-
-
---
-
-
- _-
-
-
10 7
-
1.624
-
-
CO --
8.4
-
-- "TO (.oOoi
8.4
-
-
- - ~I----------
-4 -4 - 0.06
,
--
OCT
NOV
DEC
1968
1Avg .
8
* (0 8.2 -
-
10 8 --
8 1.623
-- (0
8.3
(0
_ 8.2
-
(0
(.0001
8r.4 _
- --1 - --1
- -4
- -4
- - 0.06
TYPE 208 Color Specific Gravity
APHA ,, 20/20 C
9
"5----------
7
1.624 1.624 1.624
Distillation Range Low
c
Hi gh
Water Content Cloud Point
C
Non-Volatile
Gm/IOO ML
PH
120.7
121.6 (0 (.001 T78
121.0 121.6
(0 C.001
6.9
121.0 121.6
(0
C.ooi
"775
Copper Corrosion Acidity ML of 0.01 N NaOH flask mg/30 cm^
Soxhlet mg/30 CM2 Condenser MG/30 CM2 Chlorides
ppm
22
1 (1 "5------- 5
75 0.07 CO.06
2 1 5
4
0.06
7 77 1.624 1.624 1.624
10 8 8
1.624 T7623T 1.624
120.8 120.7
121.6 121.5
(0
(.001 .001
7.0
6.8
120.7 120.7
121.4 121.5
(0 CO .000? 6.9. ^7?
<0
i
9 .
120.6
121.5
(0 .0003
6.9
120.7
121.6 (0
.0006 6.8
3
22
2
2
--
"I------3-----
XL-----HB------
1 5
7 "7-- ~l------ 5
"(0.06 0705
Co.06 0.06
2 1
5
6 0.06
2
(1
5
6
0.06
8
L.624
8 1.624
120.5
121.5
(0
.0004
6,7.
120.8 121.6
Co
(.0001
6.7
1 1
6
5
0.66
2
(1
5
6
0.18
SL 013054
"'Converted to Wt. %
CONr
j?ui) jec T" fct?
of 1 4 th ij ii'.l i c
88
8
1.624 1.623 1.624
120.8 120.8 120.8
121.5 121.4 121.5
CO To
CO
- (.6001 .ooo3#
6.8 6.8
6.8
22
2
1
6 6
0.06
1 4 5
'0.06
U
5
6
0.06
i,T. L ... - i up ( : rdei -x 1 n i 5 r i C Court
0 \ -- 1 1 116 '
*Wt ./&
FORM NO.45A 201-13
perchlor shipments
TYPE 203 Color
apha
Specific Gravity 20/20 C Distillation Range
Low
C
Hi GH
Water Content Non-volatile
Cloud Point C GM-IOO ML
PH Acid Acceptance
% as NaOH
Copper Corrosion Acidity ML or 0.01 N NaOH Flask MG/30 CM2 Soxhlet MG/30 CM^
Condenser MG/30 CM* Chlorides
PPM
1947 Avg.
JAN
8 8' _
* to -- 6.6 -
-
(0 8.6
--- --- ---
FEB
6 --
(0
-- 6.6
-
-
-
-
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY PRODUCT REPORT
MAR
APR
MAY
JUNE JULY
AUC
8 --
-- to 8.7 -
-
76 --
-- to
-- 8.5
(0 8.6
-_ --- ---
8 10 8 1.624
-- to
"576"
-
120.8 121.2 --
to (0
.0002 8.5 ITS --
- -- -- -- -- ---
SEP
OCT
8 --
-- (0 8^6
-
-
7 -
to 8.6 -
*
NOV
DEC
1946 Avg .
8-- --
-- (0 8.6 -
.ta --
-
---- ----
8 1.624
120.8 121.2
to .0CX2 8.6 -
--
-- --
TYPE 209
Color
APHA
Specific gravity 20/20 C
Distillation Range Low
C
Water Content
Hi gh Cloud Point
C
Non-Volatile pH Acid Acceptancr
Gm-IOO ML % as NaOH
Copper Corrosion Acidity ml or 0..0I N Nach
Flask MG/30 CM2 Soxhlet MG/30 CM2 Condenser MG/30 CMZ Chlorides .
ppm
10
(0
6.9
--
_
__
- ... - -
SL 013055
-- .-
_
-- -- ---
-
* 8
-
--* *
-
-
8 -
-
---
---
-
-
---
- -- -- -
_
---
-
---
- - -- - --
- -- to
--
---
-
- to
---
- -- --
-
- 8.6 -
--
- 8.6-
-
- .-
-
--
-*
-
-
- - -- - -- -
- -- - -- -
- ---
---
---
-- - -- - -- -_
- - - - -- ---
---
-
---
---
-
---
--- - - -
---
-
--
-- - - --
CO vr I DBS ri-fttr;-
OOl-I.DL . ecfc--fcr ) Prcrt /ctrve ordei
t>f mh4A
)iolix L L Cl/l rtr-----
No. 91-1145
FORM
5A202- 13 .
HEAVIES STILL BOTTOMS
Till CIILOROETHYLENE 1.1,2Trichloroethane Perchloroethylene U-Tethachloroethane 5-TETRACHLOROETHANE
Pentachloroetkane
Hexachloroethane
ft ft
%
ft ft
ft
ft
PPG It STRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA laboratory operations report
1*67
Avg.
JAN
FEB MAR
"TOT (0.01 0.00 0.00 (0.01 (0*01 (0.01. 0.00
"22702 24.48 21.33 23.10
3.15 2.57 2.16 2.44
35.2* 32.51 30.32 32.44
28.43 33.87 39.59 35.93
2.27 2.74 2.13 1.92
APR MAY JUNE JULY AUG
0.00 (0.01 25.76 _ 2.31
28.66
36.14 227
0.00 0.00 0.00
0.00 (0.01 (0.01 25.13 w&r 22.94
2.50 2.57 2.47 30.72 28.55 38.60 34.58 34.18 34.68
2.20 '5T33" 1.74
(0.01 '(U.D1 23.22
2.01 40.19 32.33
1.39
SEP
(0.01 (0.01 18.85 1.93 43.59 28.26 1.05
OCT NOV OEC
(0.01 (0.01 18,16 2.10
44.73 29.18 1.10
0.00 0.00 (0.01 (0.01
14.39 13.84 1.85 2.22 48.76 48.12
28.99 30.00 0.94 1.03
1968
Avg.
(0.01 (0.01 21.57 2.26 37.27 33.09 1.74
Heavy Unknowns
ft 1.49 0.96 6.96 0.94 1.22 1.31 1.21 1.U2 0.79 1.14, 1.44 1.00 1.01 1.08
FeCl? Non-Volatile
ppm "505 ft 1.14
-
2s 18 26 .30 .19 .45
40 .15 .12
67 78 .28 .32
31 49 .15 .64
(12 u:rr
66 0.58
1 HFAVIFS STILL REFLUX
(PER STILL FEED)
Trichloroethylene
ft
1,1,2 Trichloroethane
ft
Perchloroethylene
ft
U.Tetbachloroe thane
ft
S.Tctrachloroethane
ft
--
-- --
-
-- ---
---
--
-- --
--
-
- --
- -
-
- ---
--
---
- - "-
--
--
-- --
-- - --- -- - ---- - - -- --- -- ---
DRIED UNSTAB. PERCHLOR
Trichloroethylene
ft
1.1.2 Trichloroethane
Perchloroethylene
ft ft
U-Tetrachloroethane
*
H70 pH
NaI Test Oxides
ppm ppm
_ SL 013056
0 (0.01
99.93 0.03
0
(o.oi
99.73 0.02
--
_ -- . -*
_ ----
---
---
- --- -- -
--
-
--
---
--* -------
-- _0 -- (0.01 -- 99.73 -- -- 0.02
(-5. 6.4 Neg.
--
6,3
Nsg.
6.8 5.3 Neg. Nee.
.-
Neg
--
6.7 67 Nee. Neg.
6.7 6.7 6s 7 Nee. Nee. Nee.
--
6.8
Neg.
-
6.7
Neg.
-
6.5 Neg.
t
-
"STS Neg.
'
ii ________
Mr t
rI* T AT
fT r rl o _
l A n i c L r r*P rn trf;
............f,.
H-
FORM N0.45A 202.14
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY OPERATIONS REPORT
PERCHLOR STABILIZATION
TYPE 208
WT. %
Perchloboethylene 1.J-DlCHLOROBROMOETHYLENE
1,2-DlCHLOROBROMOETHYLENE
1,1,2-TH1CHLOROETHANE
UiTetrachloroethane
EPE
Unknown, Total
1*7 .Avg
JAN
FEB
99. 87 QQ-88 QQ rtrt TCTT fo.oi (am 0.01 fo.oi (n.rvj
(0.01 (0.01 (n.ni
0.05 0.06 0.06 0.04 0.06 0.06 -
MAR APR
99.87 (O.Ql (0.01
(0.01 0.06
0.04
99.88 (0.01
(O.Ql
(0.01 0.05 0.04 .--
MAY JUNE JULY
99.87 99.37 99.89 0.01 (0.01 (0.01 (0.01 (0.01 (0.01 (0.01 ,(0.01 (0.01 0.06 0.06 0.04 0.04 0.04 0.04 ---
AUG SEP OCT NOV
99.88 99.87 99.87 99.87
(0.01 (0.01 (0.01 (0.01
(0.01 0.01 0.01 0.01
(0.01 to.oi (0.01 (0.01
0.06 0.05 0.04 0.05
0.04 0.04 0.04 0.04
- --
--
T*I
DEC
Avg .
99.87 99.88
(0.01 (O.QL 0.01 (Q.Q1 (0,101 lKL21_ 0.06 0.05
0.04 0.04 ----
TYPE 207 Perchloroethylene
WT
l,1 -DichlorobbomoeTHYLENE
t.2->t CHLOROBROMOETHYLENE 1.. J ,2-iTRI CHLO HO ETHANE UiTetrachloroethane
EPE
Unknown, Total
%
99.84 0 0 0.01 0.04
0.03" TJ------
-
-
-
-- 99.80 -
A- 0 -
-- 0 --
- (0.01
-
-- 0.05 -
-
0.04
-
- - .-
-- -
-
-- - 99781 - 99.79 99.30 99.80 99.80
- -u -- 000 0
- -0 -- 000 0
- - 0.01 -- (0.01 (0.01 0.01 (0.01
--
-
0.04 *
0.05 0.06 0.05 0.05
- .-
0.04 -
0.05 0.05 0.04 0.05
- -- -- --
--
-
SL 013057
-
of
Jubjec 14 th
COMF1 t tr> p Tudi
No.
^fcNTiJ rtect *jFJ1i* -yi11is4.
ive o trict 5
"der CourP
FORM N0745A 202-if 5
TRICHLOR STABILIZATION
1967 avg.
TYPE 115 BLM
THE Carbon Tetrachloride ADH
NPL Trichloroethylene
Perchloroethylene 1.t.2-Trichloroethane GDL Unidentified. Total
WT.%
--
0.02 0.02 (0.61
"99757 (CF.01
fo.oi
0 (0.01
JAN
_
-- --
--
-
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY OPERATIONS REPORT
FEB
MAR
APR
MAY
JUNE JULY
AUG
SEP
OCT
NOV
DEC
--
--
(0.01
0.02 0.01 99.69
0.02 (0.01
(O'. 01
-- -- (0.01 n,m 0.03 Q.nj, (0.01 (0.01 99.51 99.49 (0.01 (0.01 (0.01 (o.cn
(0.01 (0.01
----
mm
(0.01 0.00
0.03 (0.01
0.02 0.00
99. S3 99.53
0.00 0.00 (o.m (0.01
(0.01 (0.01
-_ --
(0.01 0.01 (0.01 iCu.oi
0.03 0.01 99.65
(0.01 (0.01
-- (0.01
0.03 (0.01
99.53 (0.01 (0.01
(O.Ol
0.03 (0.01
99.50 (0.01 (0.01
0.05 (0.01
0.U3 (0.01
99.47 (0.01 (0.01
(0.01
-- (0.01
0.03 (0.01 99.63 0.00 (0.01
(0.01
--
-
1968 Avg .
-- -- (0.Q1 0.03 (P.01-
(0.01 (0.01 0.05 (0.01
TYPE 122 BLM THF Carbon Tetrachloride
ADH NPL Trichloroethylene
Perchloroethylene
It t,2-Trichloroethahe
GDL Unidentified.
Total
WT. %
--
--
_--
0.01 (0.01
0.04 0.03 . 0.14 0.14
99.51 99.50 (0.01 (0.01 (0.01 (0.01 "5755~ 0705" (0.01 (0.01
_ -- (0.01
0.U3 0.14 99.38 (0.01 (0.01 0.06 (0.01
---
-- (0.01 (0.01
0.03 0.16 99.45 (o!oi
0.03 u.15 99.43 (0.01
0.01 0.07 (0.01
(otot "U7D5 (O.Ol
-- (0.01
-- (0.01
0.03 0.15 99. AS (0.01
0.03 0.15 *99.48 (0.01
(0.01 (0.01
0.06
0.07
(0.01 (0.01
---
(6.01 (0.01
0.03 0.15
0.03 0.14
99.45 99.49
(0.01 (0.01
(0.01 (0.01 0.06 o.o7
(O.Ol1 (0.01
-- (O.Ol
(0.01
O.03 0.03
0.14 99.50 (0.01
0.01 0.06 (0.01
0.14 99.47
(0.01 (u.01
0.06 (0.01
-
-
0 0
H
(0.01
(0.01
0.03 0.15 99.47 (0.01
0.03 0.-03_ 0.15 0.1599.47 99.42. (o,m. (.0^01.
(0.01 0.06
0.01 0.06
(0.01 0.06
(0.01 (0.01 (0.01
SL 013058
^
CONFIl iENTIA j: s ubiect to p otect i ve Or ffTTT of 14th v. udici* il Dis :r ict Cour t
No . 11-114 5
FORM N0.45A 202-16
PPG INDUSTRIES
TRICHLOR STABILIZATION
1967 Avg.
JAN
FEB
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY OPERATIONS REPORT
MAR APR MAY JUNE JULY
AUG SEP
19^6 OCT NOV DEC Avg ,
TYPE t 10E BLM
THF Carbon Tetrachloride ADH
NPL Tr1CHLOROETHYLENE
Perchloroethylene 1,1,2-TRICHLOflOETHANE GDL Unidemtimeo.i Total
WT_. %
--
(o.oi fn.m 0.03 0.03 0.27 0.27 99.15 99.04 (0.01 0.00 (0.01 0.01 0.14 0.14 0.03 (0.01
_
--
0.01 0.06 0.34 99.85 (o!oi
0.01 0.08 (0.01
_
(o.m (0.0]
0.06 0.29
--
99.01 99.98
(0.01 0.00
0.01 0.01
0.18
--
0.02 0.01
m,
-- -- --
--
_
(0,01 (0 01 0.06 0.0*5 0.31 0 99.01 99.50 (0.01 (0.01 0.01 0.01 0.16 0.12 0.01 (0.01
-
-
--
-
_---
-
---
-
_ (14.01. (0JQ1 (Q.Q1
0.06 0.06 0.05
-- 0.30 0.28 0.26
-- 98.96 99.03 99.30
-- 0.00 (0.01 (0.01
-- (o.oi 0.02 0.01
- 0.12 0.12 0.13
co
- (0.01 (0.01
,
TYPE 1 1 3 BLM THF Carbon Tetrachloride ADH NPL Trichloroethylene
Perchloroethylene
1.1,2-Trichloroethane
GDL
UnioemtiFted. Total
WT. %
--
- ---
--
- ---
(0.01 (0.01 "0------- 0 "75------- 0
99.99 "T070T (0.01
(0.01 (0.01
(0.01 0
T07037
99.93 (0.01
(0.01
(0.01
0 0 99.98 (0.01 (0.01
(0.01 0-----
~"0----99795'
(orur
(unn-
(0.01 0 0
99; 98 (0.01 (0.01
(0.01 0
(0.01 99.97
(0.01
(0.01
0n-------------
0 0 --o-- 0 0
(0.01 (0.01 ("0.01 (oror (0.01 0
--
--
(0.01 (0.01 00 0----- 0
99.81 99.95
(0.01 (0.01 (0.01 (O.oi
0 "0
(o.oi (0.01
-
-
(0.01 0 0
99.98 (0.01 (0.01
0
(0.01
--
--
(0.01 0 0
99.98 (0.01 (0.01
0 (o.oi
--
-
(0.01 0 0
99.98 0.00 (0.01
0
(o.oi
(0.01 0 0 99.98 0.00
0.01
0
(0.01
-
(0.01 0 (0.01
99.97 (0.01 (0.01
0
(0.01
SL 013059
IT1U mrlDG
All:
SUL JGCt 1 tt--Ft o' ,ec L'i v s Ortk r
OI I Li# JU(
i'i'Slr LL L Ll art
1* \0*
yn X1
* -* * p-
TTT3
*
FORM '*5A 202-1 7
PPG ir STRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY OPERATIONS REPORT
DRIED UNSTAB. TR1CHLOR
Carbon Tetrachloride Trichloroethylene
_ 1.1.2 Trichlohoethane Perckloroethylene
% %
% %
1947 AVG (O.Ol 99.9 (6.01
(0.01
JAN
99i99 (o.m 0,00
FES
(n.m 99.99 fo.oi O. O 0
MAR
(o.oi 99a 98
6.60 0.00
APR
_
MAY
-
JUNE
-- -
--
--
JULY
-
-
-
--
AUG
--
-
--
SEP
-
-
OCT
_ --
NOV
-
-
-
--
DEC
...
1968
Avg (0.01 99.99 (O.Ol 0.00
H?0 pH na) Test - Oxides
pph (50
--
"578-- 6.8
ppm Neg.
Meg.
6.9 Nee.
5.3 Neg.
--
7.0 Neg.
6.8 Nee.
6.3 Neg.
6.9 Neg.
6.9 Nee.
-
6,8 Neg.
-- 6.8
Neg,
6.3" Neg.
---
6.9 6.2 Meg 7 TTegT
1
1
013060 1
.
-
*
Pl,K1 Ai
nrv pipCM ri'AL *
yi pc.-i u. . 0 1 - 145
f l rfla i
rt-
FORM NO 45A 210-1
f-------------------------------------------
GENERAL DEPARTMENT
W.
PPG IiNrD^USTRIES
CHEM:AICWA^^ ISION
LAKE CHARLES, LOUISIANA
c u- CONFIDENTIAL:
of
14th
to Protet*^,
Judicial Dr^R-
Wo. 91-1145
e r':der ict Court
PERCHLOPETHYL ENE-TRICHLORETHYLENE DEPARTMENT OPERATIONS REPORT
JAN
FEB MAR APR MAY JUNE JULY
AUG
SEP
OCT NOV OEC 1968 Avg .
Perchlor (Stab.) Production T/0 Shipments T/D
iNVtftluRV 16ns iftJCHLOfl (|PfcOOUtt1 OK l/U
Shipments T/D
Inventory Tons
80.3 94.2 116.0 115.5 121.7 125.5 123.4 109.8 102.4 106.3 106.4 103.4 102.1 110.6
79.1 68.5 132.4 97.8 102.5 117.9 150.8 141.5 87.1 129.4 54.0 85.1 77.8 103.7
2181.4 2173.6 159571 2248.2 2825.2 3060.1 2240.3 1255.4 1725.3 1031.1 2623.5 3172.9 3927.0 2331.7
89.0 84.7 83.2 85.8
88.5 93.8 84.6 85.3 97.4 116.0 116.3 118.3 117.0 97.6
85.7 61.8 100.2 97.6
93.2 144.8 82.1 98.0 109.9 114.6 79.1 119.2 129.8 102.5
3067.2 4598.0 4107.1 3739.4 3598.8 2018.3 2092.6 1698.9 1310.4 1354.6 2505.9 2478.4 2079.9 2631.9
Unstab. Penchlor Production T/D
81.4 96.2
EOC T/T 0.738 0.742
Cl2 T/T 0.476 0.563
Tri-Eth.Bot. T/T
-
-
117.3 0.669
0,435
NH^ LBS./T 12.8 7.3 2.7
Clo from HC1 t7t" -
-
Unstab. Trichlor Production T/D
edc t/t
Clz
t/t
91.0' 79.4 83.3 0.92$ 0.937 0.845 0.30O 0.256 0.275
Tri-Eth.Bot t/t
-
-
--
NH, LBS./T 9.6 10.1 7.2
Oln from HC1 T/T -- --
--
Unstab, Product 0;
T/T 0.280 0.278 0.259
n2 T/T 0.364 3.34Catalyst Lbs./T *
400w Stm.(actual) Lbs./T
2844
KWH/T
80.9
0.294 0.292 2.46 3.89 3494 362$ 91.7 69.6
mc Hvy. Still Bottoms
Unstab. Product Cl" Yield
C Yield
T/T
% 82.9 % 79.4
0.050 0.063 78.5 87.8
76.8 83.5
117.6 0.700 0.461
--
5.3
-
87.8 0.884 0.291
--
12.4
-
0.259 0.251 3.10 2955 43.1 0.025 36.2' 5z78
MAN HOURS/T STAB. PRODUCT
Production Maintenance Salaried Total Contract Man Hrs. Included
MAN HOURS/T SHIPPED
Bulk Drum Salaried
0.542 0.628 0.210 1.3&> 0.O30
0.522 0.490
0.262
1.274 0.010
0.447 0.489
0.235 1.171 0.002
0.420 0.442
0.214 1.076
0.029
0.062
0.799 0.021
0.076 0.037 0.050 0.825 0.461 0.964 Q.P25 3*012- 0.020
li2.7 0*653 0,416
5l9
.-
90.6 0,815 0,311
7 *4
-
0*252 0,246 2.47 2710 68.0 0*075 87.5 84.1
0.407 0.462 0.214 1*083 0.000
0.046
oMt>
0.019
125.8 tf.675 0.459
-
4.9
-
93.6 [>.852 3.290
--
6.2
-
0.261 0.229 3.34 2628 77.1 0.025 88.2 86.0
0.385 0.340 0.136 0.861 0.000
0.044 0.599 0.018
119.0 111.2 0.668 0.671 0.466 0.320
--
7.9 1O.0 -
87.1 0.843 0.294
-
36.6
0.847 0.202
-
7.9 4.4
-
0.264 0.291
0.238 0.160
2.62 4.U
2392 2663 73.2 72.8
0.039 0.060 86.6 84.1 84.9 83.6
0*378 o;43l 0.521 0.517 0.136 0.149 1.035 1.097 0.014 0.002
0.051 0.047 0.780 0.830 P,t.01g 0.018
103.7 0.669 0.393
-
TITS -
98.5 0.845 0.248
--
2.3
0.282 0.170 1.54 2707 76.4 0.030 85.7 86.0
0.437 0.473 0.147 1.057 0.000
0.083 0.664 0.029
105.3 0.663 0.448
7.0
114.7 0.837 0.283
-
5.6
-
0.264 0.192
3.41 2718 67-. 7 0.035 87.8 86.8
105.5 104.6 102.3 110.9
0.637 0.617 0.619 0.665 0.368 0.340 0.268 0.411
--
---
10.2 12.3 12.2 8.1
0.097 0.148 0.218 0.154
116.9 117.5 114.7 97.6
0.804 0,779 0.782 0.839
0.233 0.215 0.169 0.256
- ---
4.9 4.5 4.0 6.4 0.061 0.093 0.138 0.097 U.itOd 0.263 0.275 0.268
0.179 0.182 1*58 2.53
2833 3257
64.3 47.0 0.053 0.072 88.6 87.0 . 88.0 88.7
0.147 0.215 1.53 2.72 3521 2950 68.6 68.3 O.084 0.051"
86.2 86.2 87.1 84.9
0.339 0.398" 0.302 0.423 0.127 0.140 0.813 0.961
0.000 U.Ou?
0.376
0.593 0.120
1.089 0.250
0.367 0.413 0.556 "0^57 0.131 0.168 1.054 1.048 0.316 0.052
0.054 U.081 0.498 0.530 0.017 0-026
0.051 0.052 0.673- 0.451
0.013 0.009
0.056 0.668
0.019
SL 013061
ri
}------------------------------------------MATERIAL BALANCE
CARBON - TONS
perchlorethylene-trichlorethylene department operations report
JAN FEB MAR APR MAY JUNE JULY AUG SEP /tf7
OCT
NOV
DEC 1968 ftV6-
Total Carbon in Feed Carbon in Unstab. Product Process Loss by Difference
1084.0 1147-5 1118.9 1238.8 1224.; 1273.4 1172.0 1183.9 1190.0 1251.7 1290.7 1239.4 1273.8 1217.0 364.9 881.8 934.1 1025.4 1029.' 1094.8 994.6 990.0 1023.6 1086.6 1136.1 1098.9 11Q9.4 1033.8
219.1 265.7 184.8 213.4 194. f 178.6 177.4 103.9 166.4 165.1 154.6. HO, 5 16A.A 183.2
Accountable Process Losses
Blowdown
Reactor
Ml SCELLANEOUS
Sue Total
Unaccountable Process Losses
15.0 22.0
134.1 223.7 20.0 20.0
219.1 265.7 OTfT 0.0
24.4 140.4 20.0 184.8
0.0
18.1
175.3 20.0-
213.4 0.0
17.7 156.
20. t
194.5 ; O.C
25.1
133.5 20.0
178.6 0.0
23.1 20.2 134.3 153.7 20.0 20.0 177.4 193.9
0.0 0.0
19.8 13.1 17.1
126.6 127.0 117.5
20.0 20.0 20.0
166.4 165.1 154.6
0.0
0.0
0,0
19.5
12007..00 HO. 5
0.0
18.7
125i7 20.0
164.4 0.0
20.2 H3.0 20.0
183.3 0.0
Carbon Loading Loss
1
Total Carbon Losses
16.7 235.8
6.1 9.3 16.7 271.8 194.1 230.1
17.5 6.7 10.2 14.1 -2.6 6.7
7.7
212. C 185.3 187.6 208.0 163.8 171.8 162.3
-2.4 -12.0 4.9 138.1 152.4 189.8
CHLORINE-TONS
Total Chlorine in Feed Chlorine in Unstab. Product Process Loss by Difference
Accountable Pbocess Losses Blowdown Reactor Miscellaneous Sub Total
Unaccountable Process Losses
Chlorine Loading Loss
Total Chlorine Loss
-- SL 013062
5238.9 5788.0 5540.3 6175.2 6114.C 64387? 5966.0 6091.3 6094.6 6253.7 6469.2 6367.4 6488.0 6H8.9
4359.9 4542.9 4864.4 5320.4 5347.0 5632.4 5168.7 5121.6 5220.5 5438.1 5730.7 5537.9 5591.5 5301.3
879.0 1245.1 675.9 854.8
767.0
756.5
797.3 969.7
874.1
765.6
738.5 829.5 896.5 847.6
83.2
695.9 100.0 879.0
0.0
122.2 135.6
1022.9 44.Q.3 100.0 100.0
1245.1 675.9 0.0 0.0
200.7
554.1 100.0 854.3
0.0
80.3 43.0 49.5 8T.2
959.3 1283.1 725.4 938.0
1
98.4 568.6 100.0 767.0
0.0
139.4 128.8 517.1 568.5 100.0 100.0 756.5 7973
0.0 0.0
134.6 TTO7T
735.1 663.9
100.0 100.0
969.7 874.1
0.0
0.0
100.2
565.4 100.0 765.6 0.0
94.9 543.6 IOU.O
738.5 0.0
108.4 621.1
100.0
829.5 0.0
103.9 692.6
100.0
896.5 0.0
123.1 624.4
100.0
847.6 0.0
84.5 36.3 .45.9 72.7 -12.6 35.3 42.6 -5.3 -51.8 35.2
851.5 792.8 843.2 1042.4 861.5 800.9 781.1 82Zl.2 844.7 882.8
CO* FT I3EW1 lAu * Subl ecfc tt trot* iCtivo
h 3uvJ- cial 045--
flrdfiT COL rt
FORM N^5A 210-3 .
REACTOR NO. t
On Stream Time DisCh. Press.
1967 avg.
Has ?90ht
psig 11.2
Temp. f Vaporizer Liouor Dow THE RM Out
Highest Tube
Lowest Tube
272
t,9\
8X8
"750
Sec. Cond. Oisch
Catalyst Charged
Catalvst From Centrifix
Flow GPM
EOC
SCFH Cl2
Air
Lbs. Lbs.
______________ 22_________________
37 50644* 47592*
5.0 6332
1534 10282
JAN
744 8.7 255 482
18
2000 2000 3.9 6439 1541 9621
FEB
696 875 250 416
-- -
13 2550 2550 4.4 6928 1530 9712
MAR
672 7.2 243 463
24 10818 10818
4.8 6694 1525 9270
PPG I
STRIES
CHEMICA^^V ISION LAKE CHARLES, LOUISIANA
' COMF1 DENTJ!AL: Subject: to
APR MAY JUNE
-720 10.5
271 i,39
- 17 2643 2643
4.0 7549 X519 8301
744 12.5
250" 443
-- ------- IT
2438 2A.38
4.4 7473 1517 11378
687 8.9 247 481
-- 26
1988 1988
4.5 6851 1496
10190
JULY
743 9.8 277 440
22 2625 2625 3.98076 1484 12313
AUG
744 8.8 276 455
""35
2100 2166 3.9 6631
10930
SEP
670 7.1 255 408
-- -- 2b 13860 13860 3.6 5763
9229
OCT
744 9.8 "282 440
U-1J-4
NOV OEC
719 744 -- 281 279 448 445
196*
Avg .
8627* 9.2
"255 446
"T3------
2184 2184 4.0 6152
--
10974
_ --
13 16
20
2300 2660 ` 47566*
2300 2060 47566*
4.3 4.3 6638 6908 --
4.2 6867
1516
11619 11960 10458
Vent Analysis CO; HCL
Per.Thi Ratio Per i Tri in crude
% 39T7 25.7 23.1
-
%
7.9 2.1 1.5
4.0
1.10 1.41 1.50 1.51
ft 80.99 31.15 81.44 79.83
37.8 -5.0 1.61 85.09
--
3.6 1.61 86.58
3.9 1.89 87; 56
44.0 8.0 1.59 87.41
45.3 17.4 1.18 86.57
18.7 23.6 0.87 82.92
36.6 22.6 23.1 23.1 1.3? 1.17 8575^ 80.99
-- 31.7 21.6 11.4
1.02 1.39 84.40 83.96
REACTOR NO. 2 Oh Stream Time Disch. Press.
Temp. f Vaporizer Liouor Oowtherm Out Highest Tube Lowest Tube Sec. Cond. Disch.
Catalyst Charged
Catalyst trom Centrifix
Plow GPM
EDC
SCFH Cl2
At R
'5
vent Analysis CO2
HCL Per-Tri Ratio
1Pew Tri in Crude
SL 013063
Mrs. "5015* psig.- 11.2
283 489 820 767
40 lbs. 42241* lbs. 42956*
5.2 6272 1506 10238
639 696
743
647
7.0 11.7
12.8 11.1
256 273
473 - 430 --
279 - 426 -
-
274
434 -
--
--
22 15 5460 3079
5400' 3079
"25 5150 2120
` 43
7138 7138
4.4 4.9 4.9 4.8 5734 6177" 6254 1 6608
1529 1551 1517
1494
3810 10373 10770 10450
744 720 713
744 720
12.4 11.5 IT 8.0 10.3
272 268 257
276 279
432 436 ---
441 -
473 457 --
- ---
--
------- 19" 28
35 w~ ~ 23
2762 2182 14700 1575 2160
2762 2162 14700 1575 2156
4.6 4*4 4'. 7
4.6 4.9
6524 "5OT" 7855' "`5555' 6296
1501 1463 1238
339
11025 11104 13286 11485 12381
% 33.9 37,3 24.0 -
-
-
28.4
50.9 38.2
% 7.6 6.5 8.3
6.5 15.9 16.0 10.9 18.3 14.0 19.9
" 1.11 1.40 1.54 " 1.49 1.48 1.36 1.79 1.64
1.32 1.22
ft 79.90 82.83 P6.37 55:15' 87.01 -82.1ft 90.53 85.27 -J&JA 3245
^Totals
736 10.0 276
443 -
24 2184 2184 5.o "7198"
356 11734
703 710 _
8515* 10.4
272 280
272
441 430 --
443 -
--
-
18 20
26
5766 2060 48040*
5766
h* 8
7511
567
2060 4.8 8371
48040*
4.7 6750
1152
11404
11812
t
11220
47.9 19.9 1.55 88.42
20.4 1.10 8 5.. 49
37.4 24.0 14.7 1.02 1.41 83.73 86.67
form r 5A 210.4
SL 013064
PPG i: ISTRIES
'r-^ioct to Protective c*rr)or
CHEMICAL DIVISION
of I*t Judicial District Court
LAKE CHARLES, LOUISIANA
No. 91-1145
PERCHLORETHYLENE. * TRI CHLORETHYLE NE DEPARTMENT OPERATIONS REPORT
REACTOR NO. 3
iW.
JAN
FEB MAR
APR MAY JUNE JULY
AUG
SEP
OCT NOV
DEC | 196t AVG.
On Stream Time 0i scm. Press.
Tmp.F "Vaporizer Liouor Dowtherm Out Highest Tube
Lowest Tube
Sec. Coho. Oisch. Catalyst charged
Catalyst from Centriftx Flow GPM EOC
SCFH Cl? At n Oz
Hrs. psic. 10.6
W
741 620 7.0 8.8
251 241
744 9.6
270
720 744 720 743 744
12.4 12.3 11.2 7.8 6.2
576" 2b6 257
244 237
508 534 453
437 430 451 436 424 444
m 772 - -
-
- ---
-- ---
~~w~ 23 25------- 23 --vr
20 24
24
lbs. mm* 2000 i22l5 2120 1993 2418 1988 2625 5100
lbs. A 520?# 2000 12215 2120 1993 2438 ~vm 2625 2100
5.4 4.2 4.9
4.5 4.8 4X 4.8 4.8. 5.0
6268 5875 5274 1455 1214 1490
?294 7930 814O 8539 8643 6812 1465 "itfr ' K5B 1470 1466"' -
IOIU 8754 9397 10310 li230 10865 10813 9687 8357
720 7.2 256
439 -
23 2160 2160 4.5 6637
-
9469
744 9.3 274 443 _
19 2184 2184 4.4 7882
-
10811
674 720 8634*
--
9.2
255 ~259 "253 419 441 446
--
- --
12 16
22
6480 2060 40363*
6480 2060 40363*
4.6 5.1 4.7
7045 7694 7314
- - 1451
- - 9969
Vent Analysis Cog
HCL Per-Tri Ratio
Per < Tni in Crude
1
% 38.7 22.8 25.0 % 8.1 5.5. 2.2
1.15 1.73 1.92
--
5.6 i!6o
36.3 7.0
1.73
-
4.3 1.53
-- i 45.3 43.4 4.5 18.8 579 1.84 1.64 1.65
38.6 10.1
1.19
47.9 19 :t
1.55
3^*4 -- 20.5 18.3 1.10 1.14
36.8
10J 1.55
% 82.71 86.35 88.51 84.93 87.70 1
85.66 84.51 84.12 3430 88.42 85.49 78.44 85.3LQ,
REACTOR NO. 4
On Stream Time
Hrs. 7902* 739 696
Oisch pBESS.
psi& 12.0 10.4 11.4
Temp, of Vaporizer Liouor'
26l 2o3 286
Dowtherm Out Highest Tube
499 431 . 424 815 - -
Lowest Tube
783 -
Sec. Cond. Disch.
.38 24
19
Catalyst Chargeo
Catalyst prom Centrifik
Flow GPM
EDC
SCFH CL2
At R
lbs. A952* , lbs. *5339*
5.1 . i324 1541
2000 2000 4.6 6776
--
2645
2645
4.4 6928
-
2 LOO66 10014 10145
744 720 10.8 12.4
265 264 413 422
---- --
21 23 2550 1993 2550 1993
4.5 . 4.5
7106 '7119
_-
10600 io8io
1
' "72D 623
i 11.5 10.1
' 243 245
i 481 439 '-
1-
--
25 39 2438 8099 l 2438 8099
1 4.4 4.4 6490 7407 - ,-
i 9482 11822
!
739 "
' 9.7 267 468 -
732. 8.6 271
494 -- -
720
10.5 230 433
-
744 10.3 "276
449 --
-
67
2625 2625
4.7 8315
79
1750 1750 "476 7767
--
72
2160 2l60
4.5 7805
-
67 . 2184 2184 4.6 8564
Z-i
11335 11033 11264 11311
719 744
263 265
461 479 -
-
48 2700 2700 4.8 8832
41 2060 2060
4.4 8929
--
11068 10315
8640* 10.6
264 454 -
44 33204* 33204*
4.5 7670
-
10767
Vent Analysis C02 HCL
Per-Tri Ratio Per t Tri ii^rude
% 44.4 30,3 29.8: * *m
. -x i "*
-- . 48.5 51.1 7.4 45.1
35.8
38.3
%
10.5 12.4 9.0 1.07 1.15 1.85
5.4
a.49
4.4 t2.U3
1 ' 6.6 1.69 '1.66
' 8.5 "776 i 1.44 7T:20'
10.4 15.8 1.0? 1.48
9.8 11.2 8.7 1707 0.99 1.43
% 85.23 33.13 39.06 i&:t5 $8.66 88f4? 189.83 187.60 181.68 34.68 85.44 82.93 85.20 86.10
^Totals
FORM ' '5A 210-4A
REACTOR NO. 5
1567 AVG.
PPG IN JTRIES
CHEMICAl DIVISION LAKE CHARLES, LOUISIANA
PERCHLORETHYLENE- TR1CHL0RETHYLENE DEPARTMENT OPERATIONS REPORT
JAN FE8 MAR APR MAY JUNE JULY AUG SEP
ON STREAM TIME OrsCH. PRES5. TEMP. OF VAPORIZER LIQUOR
OOWTHERM OUT HIGHEST TUBE
LOWEST TUBE
SEC. COMO. OfSCH.
CATALYST CHARGED
CATALYST FROM CENTHIFIX
FL W PM 5CFM
EDC Cl i
AIR Oi
HRS. PS! <3
6549* --
-
~8II "783
LBS. 50396* LBS. 37160*
-
-
*
--
744
- -
--
-
-
20t>0 2OO0
" -- "
696
-
-
-
2120 2120
-- --
744
-
-
-
--
2120 2120
-
-
664 701 697
- --
----
-- ----
- *-
-_ -
--
2035 15650 2035 12650
-
-
1988 1988
-
-- ---
----
- ---
731 744 720
--
_
--
-
2625 2625
-
-
-
-
--
-
2100 2100
-
-
-- -
2155 2155
-- -- --
OCT NOV DEC
1966 AVG.
725 719 744 8629*
--
-- --
2184 2184
-
--
2700 2700
--
-
2060 2060
a
-
36737* 36737*
_
*--
mi
VENT ANALYSIS CO*
HCf
PER* TRI RATI
+PER
TRT IN CRUDE
% 42.9
It __6*4 1.10
* 83.22
19.6
6.2
1.43 33.28
24.3 1.8 1.50
83.92
--
1.5 1.67 85.67
2.34 68.32
-
6.0
1.39 83.23
--
10.2 1.72 84.92
49.8 8.5
1.72 84.10
48.8 9.2
1.51 86.44
39.7
12.4
1.26 85.48
30.6
16.1
1.62 85.10
35.1 19.3 0.92
81.21
35.3 10.7 1.24
80.95
35.4 8.8 1.53 84.38
a
,
-- SL 013065
*Totals
.
0
f
Sllh 1 4F|j
rmi r*b 4-
.lia/t1 , Mrt
-1 LMSFiT
VXOZGi 'lux U -- 01. 1
LAL. ;t.i vr-r
rsirrrc r#-5------
Girder t Cour
--------t' "
FORM Nf A 210-5
PPG INF TRIES
CHEMICAL u.rlSlON LAKE CHARLES, LOUISIANA
PERCHLORETHYLENE-TRICHLORETHYLENE DEPARTMENT OPERATIONS REPQRT
REFRIGERATED BRINE
Temp. F
Warm (OotI
Colo (in)
1
j DRYING STILL
1 Temp. F
l
Bottom Top
' Bottom Pressure
psig
PER-TRI
Feed Reflux Bottom Temp. Overhead Temp.
STILL
gpm gpm
F F
1967
Avg.
21 16
JAN
14 9.
202 164 1.24
203
167 1.42
23.0
33.7 28.6
187 '
21.4 34.0 280 176
FEB
8 4
206 173 1.33
22.3 33.0 280 180
MAR
APR MAY JUNE JULY
AUG
SEP
OCT NOV
12 _ 9 7 16 7 5 08
16 39 0 8 36 -4
6 1
1 -3
205 207 267 171 174 '1.75 ' 1.33 1.35 1.53
208
171 1.59
209 175 1.59
207 "195 201 198 177 170 T7I 165
1.39 1.27 1.35 L.52
23.4
35.9 285 182
39.5 288
184
24.0 35.8
286
185
22.5 36.7 286 186
22.1 28.3 279 185
23.2 27.2 280
185
24.7 31.9 285 186
25.1 31.2
284 184
24.4 28.6
276 L78
DEC
4 -4
1968 Avg .
11 6
192 203 161 171 1.33 1.42
24.3 26.2
273 175
23.4 32.4 282 182
HEAVIES STILL
Feed Reflux Bottom Temp. Overhead Temp.
gpm gpm
F F.
10.7
105.0
337 250
12.2
134.4 333 242
12.0 139.8 340 252
12.2 12.5
145.0 153.7 340 340 256 256
12.3 137.6
340
258
12.0
154.4 340 260
11.4 119.7
341 265
11.5 12.1 100.2 108.7
338 340
240 ~255
11.9 118.2
340 256
11.6 108.3
340 250
11.2 110.7
340
247
11.9 127.6
340
253
PER STILL
Feed Reflux Recycle To Wash Column Bottom Temp. Overhead Temp.
gpm 10.18 11.22 11.44 11.50 12.05 12.16 11.89 11.16 12.18 12.55 12.19 11.77 11.21 11.78
gpm 19.93 19 .`66 20.50 20.45 2i; 85 20.76 21.06 21.43 16.32 14772 15.43 15.63 15.56 18.61 gpm 0.118 oa58 0.165 0.179 0.181 0.180 0.248 0.248 0.241 0.220 0.375 3.382 0.380 0.246
gpm 9.45 11.13 11.89 11.94 11.39 12.67 12.55 11.55 11.33 12.19 11.10 10.95 10.65 H.6l
F 274 276 279 282 283
284 284 283 267 "285 283 279 278 ~~2fS0
uF 233 231 237 238 238
242 242 242 232 245 246
236 239
Feed
TRI-STILL
Reflux Bottoms Recycle Bottom Temp. Overhead Temp.
.Ql 1 incc
, gpm 10.81) 9.41 10.10 gpm 5?.,47. 66.64 65.76 gpm 9.67 6.61 6.69 gpm 1.687 3.930 0.851 F 231 227 227 F l4l 136 145
"
10.47
0.12 0.854 227
~U$
10:20
66.13 7.88
1.687 : 230
140
10.48 9.75 63.64 64.35
5^3 7.63 1.274 1.220
232 230
138 139
9.93 11.08 12.67 12.75 12.47 12.49
61.32 56.86 58.52 53.30 51.86 63.05
7.69 8.52
9.85 9-85 9.47
1.284 1.579 1.424 2.407 1.927 2.072
~22$
227 228
226 227
224
141 141 136 138 132 129
------ err IF I DEM I'XAL:
Sub' 6ct tc ' Prat ?cti ve Orrlpf
10.98 62.38
8.25 1.709
228 138
No. . 91.-1J45
FORM N0.45A 210-6 ;
TRI TOPPING STILL
Bottom Temp. Overhead Temp.
F F
PPG INDUSTRIES
CHEMICAL
UON
LAKE CHARLES, -JU1SIANA
perchlorethylene-trichlorethylene department operations report
19*7 JAN Avg.
"192" 185 192 184
FEB
185 184
MAR
187 ~185
APR MAY JUNE JULY
189 190 191 187 189 190
192 190
AUG
193 191
SEP OCT
194 193 190 189
NOV DEC
'IBB"" 187 184 182
1968
Avg. 190 187
NEUTRALIZATION
Perchlor NH3
Flow To Sts.
Trichlor
NH3
ToFlow
Sts.
sf-
\
psig gpm
.
7.62
PSIG "572 gpm 6.80
6.7 2.2 0.17 0-86
5.0 2.9 6.03 6.91
5.3 9.88
9.3 6.53
7.6 9.0 13.2 11.6 12.5 12.5 ll.4 10.55 10.56 10.36 9.54 8.89 9.31 9.08 8.76
6.2 4.0 4.5 4.5
2.7 7.5 7.1
4.?
5.79 5.96 6.46 7.11 8.23 8.15 8.62
O
00
W
13.2 9.3 8.61 9.55
4.9 5.3 8.46 7.03
*
SL 013067
*
-
MtO JriDfiN riftL ;
nf 1 At fjl__1l.j ----------- L____u,
> >
I'POt -w-
?Ct i'VT
JisLri US"
Ordei
u't Coi
rfc