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SET ARG-002 3M Identification of Fluorochemicals in Human Tissue `The objeetiveofthis study is to determine the concentration ratios, in humans,ofliver to serum, liver to bile and bile to serum for perfluorooctanesulfonate (PFOS). An application for securing liver, gallbaldder, bile and serum from donors was approved by the International Institute for the Advancementof Medicine (TAM). IAM is a non- profit organization whose purpose is to faciliate the placementofnon-transplantable `human organs and tissuesfor biomedical research and education. All tissues are procured `with the informed consentofthe donor or the donor's nextofkin, in accordance with the Uniform Anatomical Gift Act. Donors may be from anywhere in the United States and Canada. It is estimated to take approximately | year to secure tissues from 12 donors. A final report should be available by March 1, 2001 000955 CProorppoosraaltetoOcEcHupSa&tiRonCaolmMmeidtitceiene Section/Epidemiology Unit 3/1/98 Title: Identificationof Fluorochemicals in Human Tissue WbPioutnrhpdioensdett:hoeEcpvaairsdbteonn1c2cemanothnabttehosfrogiuatnnwdiacsinceohsmutpimomaauntnedbdlstohcoaodtnthsaaeisrnubimengePntFhkOenSeolw(epnmeerfnfotlrufmoloruorooercittnhaeancneh3seu0mlifycoeaanlraslt,ye) levels are on pooled within serum the 20 to samples. 50 ppb range in the Although POS is kgnenoewrnaltpoocpounlcateinotnr.ateThiin sthies primarily liver and based to uanmdoenrggohuemnatnesr.ohepTahtiecpcuirrpcuolsaetiooftn,hiwsesdtoudnyotis know what tissue to determine the concentrations level of several may be fluorochemicals from the serum, liver and bileofthe same individual (human). pSirgonviifdiecfaonrcea:moDreteesrpmeicniafitciounnodfertshteantdisisnugeofctonhceendtirsattriiobnustoifonsoefltehcetsede fcloumoproocuhnedmsicianltshweill human. The data obtained ratio of liver from studies to in serum, liver nonhuman to bile and primates. Ublitliematotesley,rutmhewsielldabteacwoimllpabreeudsetdo in defining and confirming assumptions necessary in human health risk assessment. aOnbjdecbitliev:esse:ruTmhteo otbhjeefcotilvleoowfintghifslusotruodcyheimsitcoaldse:terPmFiOnSe,thPeFrOaStiAoo,fPlFivOeSrAsAer,umM,57l0iv,er:bile aMnSaSl6y,zePdFsHhSouladndanPalOyAtiAcalammoenthgod1s2 human permit donors. Total organic fluorine will also be wPirloltobceosl:ubAminttaepdpltiocatthieonInftoerrnsaetciuornianlgInlsivteirt,utgealflobrltahdedeArdv(bainlec)eamnedntseorfuMmedfircoimndeon(oIrAsM) tIraAnMspliasnatanbolne-phruomfiatnoorrgganainzsaatniodntwishsousese fpourrbpioosmeedisictaolfarceislietaartcehthaendpleaducceamteinotn.of nonTAM is aacdcirveidsiitoend opfrtohgeraPemnwnhsiyclvhamneiaetRsegoiroenxacleeTdisssaulelofantdheTrFanosopdla&ntDBraungk,Adamniniinsstpreacttieodnand W(iFtDhAt)heanidnftohremAemdecroincsaenntAosfsotchieatdioonnoorfToristhseuedoBnaorn'kssnsetxatn-doafr-dksi.n,Ailnlatcicsosuredsanarcee pwriotchutrheed UalnwiafyosrmpoAsnsaibtloemibceaclauGsieftit Act. may Pinvrolvooefdtohoenfpohrotcooncsoepnytintgootfhperaipvpilliecgaendt (i.., 3M) is information. not cHoonwseevnetrf,oarmdoisnoarvaiidleanbtliefiucpatoinonrenquuemsbt.er Disonpororvsimdeadytboethferoampplaincyanwth.erAe cion ptyheofUnaibtleadnk Ssytpahtielsisa.ndICAanMadpar.ocuAlrlesdoannodrdsisatrreibtuetsetsedtfiosrsuHeIsVo,n ahnepaitnivteisstiBg,athoeprarteiqtiusesCt,baHsiTs.LVTahned sTcIieAnMtifAipcplmiecraittiaonndRfeevasiiebiwliCtyo.mmUitptoenearpeprvoiveawls, etahceh 3aMpplriecqauteisotn ifsoprleatcheidcalin ctohnesirdoetraattiioonns, ffoorr tohregatnistsiusesoufeindtoenraetsito.n, [tLheAMpraotbeicdteisonbyofUSh.umlaengissulabtjieocntsgotvherronuignhgctohneficdoenntsieanltitpyrocess Page 1 of2 000956 T(HreaanlstphlaanntdAcHtu,mwahnicSherpvriocheisbi4t5s tChFeRbuPyAinRgTan4d6)saelnldinTgiotfloerIgIIaonfstahnedNattiissouneasleOxrcglaudning reasonable reimbursementofexpenses associated with recovery and placement aLnidv/eorraanpdpsreorvuemd banya3lyMs'ess EarneviprloannmneendtafolrLaanbaolryattiocraly.anaTlhyesemseutshiondg fmoertfhloudosrodcehveemliocpaeld aEnnavliyrsoinsomfebnitalle Lisabcourrraetnotrlyygbueiidnagncdee.veAlotpoetdalionfa1E2udroonpoerasnwlialblorbaetoobrtyaiunnedde.r 3IMA'sM estimates that ona monthly they basis. will send 1 to 3 Total quantity setsoftissue per donation (liver, gallbladder/bile and serum) to is: liver (10 grams); gallbladder/bile 3M (intact); and serum (5 to 10 cc). MPlalnodcealtiaorne/ccoo-sitn:vesGteiagratyorOsl.seKnrwiisllHabnestehne wPiIllonsetrhvies aprsojtehcet.conJteaacntBwuirtrhiisnatnhde 3JeMff cEonnvdiurcotnemdenbtyalNoLrabtohrwaetsotryL.aborItatsorcyu.rreTnhtley3exMpeEcntveidrotnhmatentthaelseLarbuomraantaolryysweisllwicllonbdeuct the liver analyses. determination A European laboratory currently validating in the bile ofprimates will likely extend this a method validation for to fluorochemical human bile. sAhpipprpoixnigomaftseatmoptallec$o5s0t;peorbtdaoinnionrgiss a$m16p6l5e. frTohmeIdiAstMri$bu7t1i0on(olfitvehri,s1c0ogsrtaimsst,he$1f2o0l;lowing: gallbladder/bile, intact, $545; serum, 5 to 10 cc, $900 (liver $300; gallbladder/bile $300; serum $50); $300). tissue fluorochemical analysis Total cost for 12 donors: 12 x $1665 bile by = $19,980. This cost does the European Laboratory. not include the validationoffluorochemicals in human `Timeline: 3M. Thus, t[oAobMtaeisntismaamtpelsetshaftrotimss1u2e from 1 donors to 3 may dtoankoerbseptewreemnon4tahncdan12bemopnrtohvs.ideDduteo to sthaempilmemsedwiilaltebeneseudbmtiottuenddefrosrtaannadlytshiiss fulpuoonrorcehceemiiptcablyd3iMst.ribIuftthioen lwaistthsianmhpulmeains otbitsasuiense,d cboymtphleeteendd woifthaisnix90modnatysh atfitmeer rfercaemiep,towfetehsetilamsattdeoanofrin'asl triesspuoer.tofTahlel f1i2nadlorneoprosrtcwainllbe riancceluadnedtgheeofglruaoprhoicchaelmilcoacalttiiosnsu(estcaotnecoern)troafttihoensn/loenviedlesn,tifdieasbclreipdtoinoonrsosf,tahned apgeer,tigneenndter, medical history information liver disease)ofthe donor. that may be supplied by IAM (e.g. causeofdeath, known Page 20r2 000957