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Material Safety Data Sheet BASF Wyandotte Corporation HMIS: HI FI RO BASF 491 Columbia Avenue Holland. Ml 49423 (616) 392-2391 chemical name See Below(*) SYNONYMS Pigment Blue 15:3, CI#74160 MOLECULAR WEIGHT 576 CAS REGISTRY NO. 147-14-8 -FORMULA r| - Vr 253 581 TRADENAME HEUOGEN* Blue K 7090 CHEMICAL _ , family Phthalocyamne C32H16CuN8 >11 INGREDIENTS NAME TLV TOXICOLOGICAL DATA HELIOGEN Blue K 7090 Contains: Copper 100 Not For similar products: estab Rat, Oral LD50 > 6,400 mg/kg Rabbit, skin: not irritating Rabbit, eyes: not irritating ell 1 mg'm dusts and mists as Cu (ACGIH, 1984) inato 4-1) This BWC product is supplied ir compliance with the reporting requirements of TSCA. * *&<*$$%*& Boiling/Melting Point S> 760 mm Hg N/A pH N/A Vapor Pressure mm Hg 9 20C N/A Specific Gravity or Bulk Density______ approx 1.5 Solubility in Water insoluble Appearance blue powder 0dor No characteristic lnteniitv i^fe^t^ECTJON W*&F1REIAND EXPLOSION HAZARD DATA FLASH POINT (TESTMETHOD) N/A FLAMMABILITY LIMITS IN AIR (K BY VOL.) LOWER N/A AUTOIGNITION TEMPERATURE UPPER N/A N/A n/A EXTINGUISHING MEDIUM [3 Water Fog X2 Foam 13 CO2 )ffl Dry Chemical QOther SPECIAL FIREFIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HA2ARDS Firefighters should be equipped with self-contained breathing apparatus and turnout gear. Adequate ventilation and clean-up must be maintained to minimize dust accumulation. May form explosive dust-air mixture. ERGE DO 086195 CONFIDENTIAL CHEMTREC: 800-424-9300 BASF WYANDOTTE CORPORATION: 616-392-2391 F 1570 REV 1/83--- __________ Thlt numbtr h tttlltblt dtvt. nlahtt. wttktndt, and holiday*._____________ _____________ Poe 1 Of 4 253 581 SECTION V --'HEALTH HAZARD DATA * threshold limit value See Section II EFFECTS OF OVEREXPOSURE Contact with eyes may result In Irritation. Contact with skin may result In irritation. Ingestion may result in gastric disturbances. Inhalation of dust may Irritate respiratory tract. EYES: FLUSH WITH FLOWING WATER AT LEAST 15 MINUTES FIRST AID PROCEDURES Flush eyes with flowing water at least 15 minutes. If Irritation develops, consult a physician. Wash affected skin areas thoroughly with soap and water. If irritation develops, consult a physician. Remove and launder contaminated clothing before reuse. If swallowed, dilute with water and induce vomiting. Get imnediate medical attention. If inhaled, move to fresh air. Aid in breathing, if necessary, and get medical attention. NEVER OIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAVING CONVULSIONS STABLE UNSTABLE X CONDITIONS TO AVOID: N/A CHEMICAL INCOMPATIBILITY Unknown hazardous decomposition products Carbon monoxide, carbon dioxide and oxides of nitrogen HAZARDOUS POLYMERIZATION CORROSIVE TO METAL MAY OCCUR DOES NOT OCCUR X 0NO VES.TYPE: CONDITIONS TO AVOID-' N/A_____________ OXIDIZER: (}NO QyES ^SRECIAUTOOTEGTION^NFORMATION *4** RESPIRATORY PROTECTION NIOSH/MSHA approved dust respirator as necessary. VENTILATION local exhaust: To control dusts. MECHANICAL (GENERAL): EYE PROTECTION Goggles PROTECTIVE CLOTHING Glvoes, coveralls, apron, boots as necessary to prevent skin contact. OTHER N/A DO 086196 C0NFTDFNTTA1 Page 2 of 4 VIII ^CNVIRONMENTALOATA ENVIRONMENTAL TOXICITY DATA None available 253 581 SPILL AND LEAK PROCEDURES This Is a regulated product. Spills should be contained and placed in suitable containers for disposal In a licensed facility. HAZARDOUS SUBSTANCE ,`SUPERFUND" PNC WASTE DISPOSAL METHOD fUlYES-->RO = 1 lb (cQDPerl Bury at a licensed facility. Do not discharge into waterways or sewer systems. HAZARDOUS WASTE 40CFR261________ QnO CONTAINER DISPOSAL DyES--H*-HAZARDOUS WASTE NUMBER Dispose of in licensed facility. Recommend crushing or other means to prevent unauthorized reuse. ^^^(SSECTION IX ^SHIPPING ATA D.O.T. PROPER SHIPPING NAME (49CFR172.101) HAZARDOUS SUBSTANCE (40CFR116) None No I REPORTABLE QUANTITY (RQ) D.O.T. HAZARD CLASSIFICATION (49CFR172.101) PRIMARY None SECONDARY None None D.O.T. LABELS REQUIRED (49CFR172.101) None D.O.T. PLACARDS REQUIRED None POISON CONSTITUENT (49CFR173.343I None BILL OF LADING DESCRIPTION Pigments NOI Dry DATE PREPARED CC NO. 618 UN/NA CODE None Page 3 of 4 While BASF Wyandotte Corporation believe* the data let forth herein ere accurate at of the date hereol, BASF Wyandotte Corporation make* no warranty with ratpect thereto end exprenly dladaimi all liability for reliance thereon. Such data are offered eolely for your consideration, Inveetlgatlon. end verification. DO 1 97 C'ONF Tr>FNTl6l 253 581 ^^t^SECTION X PRODUCT 1ABEL HELIOGEN* Blue K 7090 CAUTION: CONTACT WITH EYES AND SKIN MAY RESULT IN IRRITATION. INGESTION MAY RESULT IN GASTRIC DISTURBANCES. INHALATION OF DUSTS MAY IRRITATE MUCOUS MEMBRANES. Use with local exhaust. Wear a NIOSH/MSHA approved dust respirator, goggles, gloves, coveralls, apron, boots and other protective clothing as necessary to prevent contact. FIRST AID: Eyes - Immediately wash eyes with running water for 15 minutes. If irritation develops get medical attention. Skin - Wash affected areas with soap and water. Remove and launder contaminated clothing before reuse. If irritation develops get medical attention. Ingestion - If swallowed, dilute with water and inmediately induce vomiting. Never give fluids or induce vomiting if the victim is unconscious or having convulsions. Get immediate medical attention. Inhalation - Move to fresh air. Aid in breathing if necessary and get medical attention. IN CASE OF FIRE: Use water fog, foam, COg or dry chemical extinguishing media. Fire fighters should be equipped with self-contained breathing apparatus and turn out gear. Adequate ventilation and cleanup must be maintained to minimize dust accumulation. May form explosive dust-air mixtures. EMPTY CONTAINERS: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Do not re-use this container unless it is professionally cleaned and reconditioned. DISPOSAL: Spilled material, unused contents and empty containers must be disposed of in accordance with local, state and federal regulations. Refer to our Material Safety Data Sheet for specific disposal instructions. IN CASE OF CHEMICAL EMERGENCY: Call CHEMTREC day or night for assistance and information concerning spilled material, fire, exposure and other chemical accidents. 800-424-9300 ATTENTION: This product is sold solely for use by industrial institutions. Refer to our Technical Bulletin and Material Safety Data Sheet regarding safety, usage, applications, hazards, procedures and disposal of this product*; Consult your supervisor for additional information. CAS No.: 147-14-8 Made in West Germany Pigments HMIS: HI FI R0 Pag4of4 DO 086198 CONFIDENTIAL HCR - OCTOBER, 1985 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) MANUFACTURER'S NAME SECTION 1 EMERGENCY TELEPHONE NO. HARWICK CHEMICAL CORPORATION (2161 798-9300 address (Number, Street, City, State, and ZIP Code) _____ 60 South Seiberlino Street - Akron. Ohio 44305______ _ CHEMICAL NAME AND SYNONYMS Wood Rosin: coloDhonv 1 TRADE NAME And synonyms 1 HARWICK FF WOOD ROSIN CHEMICAL FAM.ILY Natural Rosin Formula ,, . . ., ., Not Available SECTION II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES, & SOLVENTS % TLV (Units) ALLOYS AND METALLIC COATINGS PIGMENTS BASE METAL CATALYST VEHICLE SOLVENTS ADDITIVES N/A N/A N/A ^ ALLOYS METALLIC COA-INGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS N/A ,. N/A OTHERS HAZARDOUS MIXTURES OF OTHER LIOUIDS, SOLIDS, OR GASES TLV % (Units) TLV % (Units) .N/A. BOILING POINT (F.) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR>1) SOLUBILITY IN WATER APPEARANCE AND ODOR SECTION III - PHYSICAL DATA 500 Nil Nil SPECIFIC GRAVITY (HaO=l> PERCENT, VOLATILE BY VOLUME (%) EVAPORATION RATE ( 'D Negligibli i Melting Point, R & B 1.02 Nil Nil 165F Pale Yellow Solid: No Odor._______________________________ SECTION IV * FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) 220DC C0C FLAMMABLE LIMITS EXTINGUISHING MEDIA ...... CO.. Drv chemical, foam, water_fog. special Fire fighting procedures ______ None________________________________________________________ Lei ----- NTft----- Uei unusual fire and explosion hazards None UO 086199 rOMFTn 1c. MIN T| 1TH.,I -. PAGE (1) N/A s Not Applicable (Continued on reverse side) Form OSHA-20 Rev. Miy 71 SECTION V - HEALTH HAZARD DATA threshold limit value , None established Eri-ECTS OF OVEREXPOSURE History of use provides no information showing ill effects; dust may be mildly irritating or abrasive. EMERGENCY ANO FIRST AID PROCEDURES Ingestion: Induce vomiting and see physician. Skin: Mash with soap and water Eves: Flush with water for 15 minutes, see physician. SECTION VI - REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID None known STABLE XX INCOMPatability (Materials to avoid) Nnnp know...................................... HAZARDOUS DECOMPOSI /TON PRODUCT^ , Normal organ- c decomposition HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR ............. . products. CONDITIONS TO AVOID None known XX SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Sweep and shovel for reuse, if not contaminated. .............. WA5TE DISPOSAL METHOD ______ May be disposed in landfill in accordance with all regulations: Federal. State and Local.___________________________________________________________________ SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) Not, rpnni red______________ ... . _ __ VENTILATION local exhaust SPECIAL _______To reduce dust__________________________ None MECHANICAL (General) OTHER To reduce dust. ........ None PROTECTIVE GLOVES EYE PROTECTION _______flntinnal__________________________________ ___________Safety nlactoc....... .......... OTHER PROTECTIVE EQUIPMENT v ' " ' Not reauired. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING ______ Acrid fumes may be produced upon heating which may irritate the eves, nose and throat. OTHER PRECAUTIONS None known ' PAGE (2) SPO (M-940 Form OSHA-20 Rtv. My 12 086?oo CONFroeNTTAl H 2* F0 R 1 HMIS PP Sec. VIII SYSTEM NPCA Also Chronic Effects See Sec. VII H&lst&b A DIVISION OF HAMMOND LEAD PRODUCTS, INC. STABILIZERS MATERIAL SAFETY DATA SHEET PRODUCT NAME HALTHAL SECTION 1 - MANUFACTURER AND PRODUCT INFORMATION MANUFACTURERS NAME HALSTAB DIVISION OF HAMMOND LEAD PRODUCTS DATE 10-28-85 ISSUE # 1 STREET ADDRESS 3100 MICHIGAN CITY, STATE, & ZIP HAMMOND, INDIANA 46323 INFORMATION TELEPHONE NUMBER (219) 844-3980 EMERGENCY TELEPHONE NUMBER (219) 931-9360 ASK FOR ENVIRONMENTAL COORDINATOR CHEMICAL FAMILY BASIC LEAD CHEMICALS (STABILIZERS) TRADE NAME HALTHAL CAS # FORMULA SECTION II -- HAZARDOUS INGREDIENTS CHEMICAL NAME PbO % TLV-TWA mg/m3-8hr. TLV-STEL mg/m3 TLV-C BLV DIBASIC LEAD PHTHALATE 78.5 .1 0.03 as Pb 0.45 as Pb LEAD NA 50 mmg/100 g blood Material is a lead compound. Refer to Federal Register Vol 43 #220 pp 53007-53014, Nov. 14, 1978. Standard (OSHA) - Occupational Exposure to Lead. Also code of Federal Regulation CFR Title 29 1910.1025. LEL NA SECTION III -- PHYSI CAL DATA SPECIFIC GRAVITY HjO = 1 4.4+ .1 MOLECULAR WEIGHT SOLUBILITY IN HjO 0/1 APPEARANCE AND ODOR NIL WHITE POWDER ODORLESS MELTING POINT DECOMPOSES BOILING POINT @ 760 MM Hg EVAPORATION RATE VAPOR PRESSURE MM Hg VAPOR DENSITY % VOLATILES BY VOLUME NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE SECTION IV - REACTIVITY DATA REACTIVITY NPCA HMIS RATING = 1 STABILITY CONDITIONS TO AVOID INCOMPATIBILITY (Materials to Avoid) HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION STABLE TEMPERATURES IN EXCESS OF 400F. NONE KNOWN HIGH TEMPERATURES OR FIRE MAY PRODUCE FUME, VAPOR OR DUST NOT APPLICABLE DO 086701 CONFTDFNTTAl SECTION V - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY NPCA HMIS RATING = 0 (HALPHOS = 1) DOT CATEGORY HALPHOS - FLAMMABLE SOLID -- ALL OTHERS NOT APPLICABLE FLASH POINT NOT APPLICABLE AUTO IGNITION TEMPERATURE NOT APPLICABLE FLAMMABLE LIMITS NOT APPLICABLE EXTINGUISHING MEDIA WATER FOG OR FLOOD, CO, AND DRY CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES Wear full body protective clothing and full face piece, self-contained breathing apparatus operated in positive-pressure mode. UNUSUAL FIRE AND EXPLOSION HAZARD Fume, vapor, and/or dust may occur and are considered toxic and respiratory ir ritants. The product or dust can react vigorously with strong oxidizing agents. Refer to FIRE PROTECTION GUIDE ON HAZARDOUS MATERIALS By N.F.P.A. for specific individual problem combinations. SECTION VI - SPILL OR LEAK PROCEDURES CLEAN UP METHODS Clean the area of spill, returning all material possible to container. Wear gloves, goggles, respirator. Do not breathe or ingest dust. For a SMALL spill, use a vacuum. Do not broom sweep. Excess material should be stored in dry containers for later disposal. Do not use compressed air for cleaning. Exclude all individuals not wearing protective equipment from the spill area until clean up Is completed. WASTE DISPOSAL Disposal of waste and hazardous material should be handled in a manner which complies with local, state and federal Environmental Protection Agency regulations. It is preferable to send waste material to a recycling facility which is approved by the state and federal EPA. City, state and federal regulations must be followed at all times. NEUTRALIZING CHEMICALS Not Applicable SECTION VII - HEALTH HAZARD INFORMATION HEALTH HAZARD NPCA HMIS RATING = 2 ROUTES OF EXPOSURE WHEN HANDLING OR PROCESSING Mode of entry into body: 1. By INHALATION of dust or fumes, the respiratory system may be irritated and both acute and chronic overexposure can result. 2. By INGESTION of lead compounds coming from dust trapped in the upper respiratory tract or introduced into the mouth on food, tobacco, fingers or other objects, both acute and chronic overexposure can result. 3 SKIN CONTACT of dust may cause irritation. 4. SKIN ABSORPTION does not apply, as dusts are not absorbed 5 EYE CONTACT of dust or fume may cause irritation EFFECTS OF OVEREXPOSURE ACUTE OVEREXPOSURE: Lead intoxication will occur with accompanying symptoms of constipation, sleep disturbance, fatigue, headache, loss of appetite. Where inhalation is severe from heavy dusting or a large quantity is ingested and left un treated, colic, anemia, vomiting and neuritis will follow as evidenced by intense periodic cramps, aching bones, muscles, un coordinated body movements. Worst case situations could result in convulsions, stupor, coma, and encephalopathy. CHRONIC OVEREXPOSURE: Normal ingestion of lead from the ambient air, foods and beverages is about 0.25 to 0.35 mg. per day The normal adult metabolism can eliminate almost one mg. of lead per day. When lead ingested exceeds the body's abili ty to eliminate it, accumulation can reach the point where symptoms and disability occur. In this context, lead has cumulative toxic effect. Early effects of chronic overexposure to lead are difficult to detect, but symptoms include persistent fatigue, sleep disturbance, headache, aching bones and muscles, constipation, abdominal pains and loss of appetite. Prolonged Ingestion may be indicated by intense periodic cramps and constipation, nausea and vomiting. Excessive exposure may affect blood, nervous, digestive sytems. Synthesis of hemoglobin is inhibited and will result in anemia. Apathy and depression may be symptoms. If left untreated, neuromuscular dysfunction, possible paralysis and encephalopathy can result. Unusual occur rence of symptoms should prompt immediate contact of a physician. For industrial exposure, a worker's lead accumulation can be detected by an increase in blood lead above the base level established upon the employee's entry to the workplace. Blood lead above the biological limit value requires job removal. D 08 C0NFt08NTTAI, EMERGENCY AND FIRST AID PROCEDURES: INHALATION Remove from exposure. Get medical attention if experiencing effects of acute overexposure. INGESTION Induce vomiting in a conscious Individual. Get immediate medical attention. Call a physician. SKIN Wash thoroughly with soap and water. EYES Flush with copious quantities of water. Get immediate medical attention. NOTES TO PHYSICIAN: Lead in Its inorganic compounds are neurotoxins which may produce peripheral neuropathy. For an overview of the effects of lead exposure, consult Occupational Safety and Health Adm. App. A of Occupational Exposure to Lead (29CFR1910.1025). "A Guide for Physicians, Health Maintenance of Workers Exposed to Inorganic Lead" is available from Lead industries Association, Inc., 292 Madison Ave., New York, NY 10017. SECTION VIII -- SPECIAL PROTECTION SPECIFIC PERSONAL PROTECTION EQUIPMENT RESPIRATORY: As specified by 29CFR1910.102S(f) of the Federal Occupational Safety and Health Administration Standard for Occupational Exposure to Lead When handling, use a dust/fume respirator with NIOSH/MSHA approval. Respirator must be worn if TL V is exceeded. Refer to Table II as specified In 29CFR1910.102S(fk2Xi) for various exposure levels. Other local, state, and federal regulations may also apply. PROTECTIVE GLOVES: Not required, but recommended. EYE PROTECTION: Not required, but recommended. OTHER CLOTHING AND EQUIPMENT: Protective clothing is required if lead exposures exceed PEL or TLV; otherwise, full body clothing should be worn during product use and handling, be left at the work site and be properly laundered after use, with the wash water disposed of in accordance with local, state and federal regulations. Hard hat, safety boots, and other safety equipment should be worn as appropriate for the industrial environment. Personal clothing, including shoes, should be protected from contamination. VENTILATION REQUIREMENTS Ventilation as described in the Industrial ventilation Manual, by ACGIH shall be provided where exposures exceed PEL or TLV specified in and in accord with OSHA Standard 29CFR1910.9-4. Currently 0.050 mg/m3 maximum and 0.030 mg/m3 set as trigger and action levels. Other local and state regulations may apply. SECTION IX -- DEFINITIONS TLV-TWA - Threshold Limit Value-Time Weighted Average TLV-STEL - Threshold Limit Value-Short Term Exposure Limit BLV - Biological Limit Value LEL Lethal Exposure Limit TLV-C - Threshold Limit Value Ceiling PEL - Permissible Exposure Limit SECTION X -- SPECIAL PRECAUTIONS PRECAUTIONS: There are two major means of lead absorption; namely inhalation and ingestion. Most inhalation problems can be prevented with attention to ventilation and respirator use. Ingestion can be prevented with good hygiene practices. Do not inhale or swallow dust. Wash thoroughly alter handling. Use gloves and avoid spilling on hands, face, or body, to pre vent secondary contamination by ingestion or inhalation. Do not smoke, eat, or apply cosmetics in work area. Wash thoroughly before entering into eating areas. Do not wear any part of work clothing home. This includes shoes. Keep lead materials away from feed and food products. Keep away from children. Do not reuse containers. This product is in tended for industrial use only. DO 086203 DO Kip- Tr)frNTTAl ------ SECTION XI - OTHER HANDLING AND STORAGE REQUIREMENTS Store in dry area where accidental contact with acids or bases Is not possible. When a spill releases material into the environment, it may be necessary to file a report of the discharge. Contact your local environmental authorities to determine what rules apply. Avoid Skin contact. Adhere to all personal protection procedures and ventilation requirements when exposure limits exceed PEL or TLV. Before using this product, be familiar with information contained in: The Federal Standard For Occupational Exposure To Lead (29CFR1910.1025), first published in the Federal Register on Tuesday, November 14, 1978, by the Occupational Safety and Health Administration, and as also later modified. PREPARED BY: TECHNICAL SERVICE DEPARTMENT HALSTAB DIVISION HAMMOND LEAD PRODUCTS 3100 MICHIGAN, HAMMOND, INDIANA 46323 VENDEE AND THIRD PERSONS ASSUME THE RISK OF INJURY PROXIMATELY CAUSED BY THE MATERIAL IF REASONABLE SAFETY PROCEDURES ARE NOT FOLLOWED AS PROVIDED FOR IN THE DATA SHEET, AND VENDOR SHALL NOT BE LIABLE FOR INJURY TO VENDEE OR THIRD PERSONS PROXIMATELY CAUSED BY ABNORMAL USE OF THE MATERIAL EVEN IF REASONABLE SAFETY PROCEDURES ARE FOLLOWED. ALL PERSONS USING THIS PRODUCT, ALL PERSONS WORKING IN AN AREA WHERE THIS PRODUCT IS USED, AND ALL PERSONS HANDLING THIS PRODUCT SHOULD BE FAMILIAR WITH THE CONTENTS OF THIS DATA SHEET. THIS INFOR MATION SHOULD BE EFFECTIVELY COMMUNICATED TO EMPLOYEES AND OTHERS WHO MIGHT COME IN CONTACT WITH THE PRODUCT. WHILE THE INFORMATION ACCUMULATED AND SET FORTH HEREIN IS BELIEVED TO BE ACCURATE AS OF THE DATE HEREOF, HAMMOND LEAD PRODUCTS, INC. MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFOR MATION IS CURRENT, APPLICABLE, AND SUITABLE FOR THEIR PARTICULAR CIRCUMSTANCES. Oo cOA/^ 'Product `Date Siaet TYPICAL ANALYSIS HaBs4ab A OIVISION OF HAMMOND LEAD PRODUCTS. INC. PRODUCT HALSTAB 60 HALSTAB 6& EP COMPOSITION Complex Lead Salt APPEARANCE Fine White Powder PERCENT PbO 83.5 .6 SIEVE ANALYSIS % THROUGH 325 MESH (WET) 99.5 - 100 SPECIFIC GRAVITY 5.4 .1 PERCENT MOISTURE 0.0 - 0.3 SOLUBILITY, WATER Nil Complex Lead Salt Coated Fine White Powder 77.6 .6 99.5 - 100 4.4 i .1 0.0 - 0.3 Nil APPLICATIONS: Very versatile heat stabilizers. Both can be used in all wire and cable applications from 60C UL to 105 C UL, Compatible with virtually all plasticizer systems. Also - Flexible & Rigid Extruded Profiles Rigid Molding Plastisols Calendering WE SPECIALIZE IN HIGH QUALITY LEAD CHEMICALS 3100 MICHIGAN STREET - HAMMOND. INDIANA 46323 (219) 844-3980 00 0B6P05 CONFTDFNTT H 2' F0 R 1 HMIS PP Sec. VIII SYSTEM NPCA L~ Halstab PRODUCT NAME HALSTAB 60 * Also Chronic Effects See Sec. VII STABILIZERS MATERIAL SAFETY DATA SHEET DATE PREPARED 08/15/1988 SECTION 1 -- MANUFACTURER AND PRODUCT INFORMATION MANUFACTURER HALSTAB DIVISION OF HAMMOND LEAD 3100 MICHIGAN HAMMOND, IN 46323 FOR INFORMATION (219) 844-3980 FOR EMERGENCY (219) 931-9360 ASK FOR ENVIRONMENTAL COORDINATOR PRODUCT TRADE NAME CHEMICAL NAME BftLSXU 60 COMPLEX LEAD SALT CHEMICAL FAMILY CAS # FORMULA Basic Lead Chemicals NA - Mixture Proprietary Composition MATERIAL OR COMPONENT COMPLEX LEAD SALT (83,5% PfcO) SECTION II -- HAZARDOUS INGREDIENTS NOT TO TLV-TWA EXCEED /o mg/m3-8hrs. PEL mg/m3 100 0.15 as Pb 0.05 as Pb (ACGIH) (OSHA) TLV-C NA BLV LEAD 50 mmg/100 g blood LEL NA Material is a lead compound. Refer to Federal Register Vol 43 #220 pp 53007-53014, Nov. 14. 1978. Standard (OSHA) - Occupational Exposure to Lead. Also code of Federal Regulation CFR Title 29 1910.1025. SECTION III -- PHYSICAL DATA SPECIFIC GRAVITY HjO = 1 MOLECULAR WEIGHT R.A SOLUBILITY IN H20 9/1 APPEARANCE AND ODOR NTT. WHITE POWDER MELTING POINT BOILING POINT @760 MM Hg EVAPORATION RATE VAPOR PRESSURE MM Hg VAPOR DENSITY % VOLATILES BY VOLUME NOT xt>tFT.TninT.p NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE SECTION IV -- REACTIVITY DATA REACTIVITY NPCA HMIS RATING - 1 STABILITY CONDITIONS TO AVOID INCOMPATIBILITY (Materials to Avoid) HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION STABLE TEMPERATURES IN EXCESS OF 400F. NONE KNOWN HIGH TEMPERATURES OR FIRE MAY PRODUCE LEAD OXIDE FUME. VAPOR OR DUST NOT APPLICABLE D 086206 CONFTDFNTTA! SECTION V -- FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY NPCA HMIS RATING - 0 (HALPHOS - 1) LASH POINT NOT APPLICABLE EXTINGUISHING MEDIA WATER FOG OR FLOOD. C03 AND DRY CHEMICAL DOT CATEGORY HALPHOS - FLAMMABLE SOLID -- ALL OTHERS NOT APPLICABLE AUTO IGNITION TEMPERATURE NOT APPLICABLE FLAMMABLE LIMITS NOT APPLICABLE SPECIAL FIRE FIGHTING PROCEDURES Wear full body protective clothing and full face piece, self-contained breathing apparatus operated in positive-pressure mode. UNUSUAL FIRE AND EXPLOSION HAZARD Fume, vapor, and/or dust may occur and are considered toxic and respiratory irritants. The product or dust can react vigorously with strong oxidizing agents. Refer to FIRE PROTECTION GUIDE ON HAZARDOUS MATERIALS by N.F.P.A. tor specific individual problem combinations. SECTION VI -- SPILL OR LEAK PROCEDURES CLEAN UP METHODS Clean the area of spill, returning all material possible to container. Wear gloves, goggles, respirator. Do not breathe or ingest dust. For a SMALL spill, use a vacuum. Do not broom sweep. Recovered material should be stored in dry containers tor later disposition. Do not use compressed air for cleaning. Exclude all individuals not wearing protective equipment from the spill area until clean up is completed. WASTE DISPOSAL Disposal of waste and hazardous material should be handled in a manner which complies with local, state and federal Environmental Protection Agency regulations. It is preferable to send waste material to a recycling facility which is approved by the state and federal EPA. City, state and federal regulations must be followed at all times. NEUTRALIZING CHEMICALS Not Applicable SECTION VII -- HEALTH HAZARD INFORMATION 1 HEALTH HAZARD NPCA HMIS RATING - 2 ROUTES OF EXPOSURE WHEN HANDLING OR PROCESSING Mode of entry into body: 1. By INHALATION of dust or fumes, the respiratory system may be irritated and both acute and chronic overexposure can result. 2. By INGESTION of lead compounds coming from dust trapped in the upper respiratory tract or introduced into the mouth on food. tobacco, finger or other ob/ects, both acute and chronic overexposure can result. 3. SKIN CONTACT of dust may cause irritation, 4. SKIN ABSORPTION does not apply, as dusts are not absorbed. 5. EYE CONTACT of dust or fume may cause irritation. EFFECTS OF OVEREXPOSURE ACUTE OVEREXPOSURE: Lead intoxication will occur with accompanying symptoms of constipation, sleep disturbance, fatigue, headache, loss of appetite. Where inhalation is severe from heavy dusting or a large Quantity is ingested and left untreated, colic, anemia, vomiting and neuritis will follow as evidenced by intense periodic cramps, aching bones and musclBs, uncoordinated body movements. Worst case situations could result in convulsions, stupor, coma, and encephalopathy. CHRONIC OVEREXPOSURE: Normal inhalation and/or ingestion of lead from the ambient air, foods and beverages is about 0.25 to 0.35 mg. per day. The normal adult metabolism can eliminate almost one mg. of lead per day. When lead ingested and/or inhaled exceeds the body's ability to eliminate it, accumulation can reach the point where symptoms and disability occur. In this context, lead has cumulative toxic effect. Early effects of chronic overexposure to lead are difficult to detect, but symptoms include persistent fatigue, sleep disturbance, headache, aching bones and muscles, constipation, abdominal pains and loss of appetite. Prolonged ingestion and/or inhalation may be indicated by intense periodic cramps and constipation, nausea and vomiting. Excessive exposure may affect blood, nervous (brain), digestive (stomach), renal (kidneys), or reproductive systems. Synthesis of hemoglobin is inhibited and will result in anemia. Apathy and depression may be symp toms. If left untreated, neuromuscular dysfunction, possible paralysis and encephalopathy can result. Unusual occurrence of symptoms should prompt immediate contact of a physician. For industrial exposure, a worker's lead accumulation can be detected by an increase in blood lead above the base level established upon the employee's entry to the workplace. Blood lead above the biological limit value requires job removal. THE STATE OF CALIFORNIA has determined that lead compounds cause birth defects. The product of this MSDS is not listed on the National Toxicology Program "Annual Report of Carcinogens". DO 086207 OONFIDFNTTAL EMERGENCY AND FIRST AID PROCEDURES: INHALATION Remove from exposure. Get meaicel attention if experiencing effects of scute overexposure. INGESTION - Induce vomiting in a conscious individual. Get immediate medical attention. Call a physician. SKIN - Wash thoroughly with soap and water. EYES * Flush with copious quantities of water. Get immediate medical attention. NOTES TO PHYSICIAN: Lead and its inorganic compounds are neurotoxins which may produce peripheral neuropathy. For an overview of the effects of lead exposure, consult Occupational Safety and Health Adm. App. A of Occupational Exposure to Lead (29CFR1910.1025). "A Guide for Physicians, Health Maintenance of Workers Exposed to Inorganic Lead" is available from Lead Industries Association, Inc., 292 Madison Ave., New York. NY 10017. SECTION VIII -- SPECIAL PROTECTION SPECIFIC PERSONAL PROTECTION EQUIPMENT RESPIRATORY: As specified by 29CFRl9t0.l025ff) of the Federal Occupational Safety and Health Administration Standard for Occupational Exposure to Lead -- When handling, use a dust/fume respirator with NIOSH/MSHA approval. Respirator must be worn if TLV is exceeded. Refer to Table II as specified in 29CFRl9t0.l025(t)(2)(i) for vanous exposure levels. Other local, state, and federal regulations may also apply. PROTECTIVE GLOVES: Not required, but recommended. EYE PROTECTION: Not required, but recommended. OTHER CLOTHING AND EQUIPMENT: Protective clothing is required if lead exposures exceed PEL or TLV; otherwise full body clothing should be worn during product use and handling, be left at the work site and be properly laundered after use. with the wash water disposed of in accordance with local, state and federal regulations. Hard hat. safety boots, and other safety equipment should be worn as appropnate lor the industrial environment. Personal clothing, including shoes, should be protected from contamination. VENTILATION REQUIREMENTS Ventilation as described in the Industrial Ventilation Manual, by ACGIH shall be provided where exposures exceed PEL or TLV specified in and in accord with OSHA Standard 29CFR1910.94. Currently 0.050 mg/m3 maximum and 0.030 mg/m3 set as trigger and action levels. Other local and state regulations may apply. SECTION IX -- DEFINITIONS TLV-TWA - Threshold Limit Value - Time Weighed Average TLV-C - Threshold Limit Value - Ceiling ACGIH - American Conference of Governmental Industrial Hygenists BLV - Biological Limit Value PEL - Permissible Exposure Limit LEL - Lethal Exposure Limit SECTION X -- SPECIAL PRECAUTIONS PRECAUTIONS: There are two major means of lead absorption: namely inhalation and ingestion. Most inhalation problems can be prevented with attention to ventilation ano respirator use. Ingestion can be prevented with good hygiene practices. Do not inhale or swallow dust. Wash thoroughly after handling. Use gloves and avoid spilling on hands, face, or body, to prevent secondary contamination by ingestion or inhalation. Do not smoke, eat, or apply cosmetics in work area. Wash thoroughly before entering into eating areas. Do not wear any part of work clothing home. This includes shoes. Keep lead materials away from feed and food products. Keep away from children. Do not reuse containers. This product Is intended for industrial use only. DO CONF SECTION XI -- OTHER HANDLING AND STORAGE REQUIREMENTS Store in dry area where accidental contact with acids or bases is not possible. When a spill releases material into the environment, it may be necessary to file a report of the discharge. Contact your local environmental authorities to determine what rules apply, 1 Avoid Skin contact. Before using this product, be familiar with information contained in: The Federal Standard For Occupational Exposure To Lead (29CFR1910.1025), first published in the Federal Register on Tuesday, November 14, 1978, by the Occupational Safety and Health Administration, and as also later modified. Section 313 Supplier Notification: This product contains chemicals subiect to the reporting requirements of the Emergency Planning and Community Right to Know Act of 1986 and of 40 CFR 372. Refer to Sections I and II for reporting information. PREPARED BY: TECHNICAL SERVICE DEPARTMENT HALSTAB DIVISION HAMMOND LEAD PRODUCTS 3100 MICHIGAN, HAMMOND, INDIANA 46323 VENDEE AND THIRD PERSONS ASSUME THE RISK OF INJURY PROXIMATELY CAUSED BY THE MATERIAL IF REASONABLE SAFETY PROCEDURES ARE NOT FOLLOWED AS PROVIDED FOR IN THE DATA SHEET. AND VENDOR SHALL NOT BE LIABLE FOR INJURY TO VENDEE OR THIRD PERSONS PROXIMATELY CAUSED BY ABNORMAL USE OF THE MATERIAL EVEN IF REASONABLE PRO CEDURES ARE FOLLOWED. ALL PERSONS USING THIS PRODUCT, ALL PERSONS WORKING IN AN AREA WHERE THIS PRODUCT IS USED. AND ALL PER SONS HANDLING THIS PRODUCT SHOULD BE FAMILIAR WITH THE CONTENTS OF THIS DATA SHEET. THIS INFORMATION SHOULD BE EFFECTIVELY COMMUNICATED TO EMPLOYEES AND OTHERS WHO MIGHT COME IN CONTACT WITH THE PRODUCT. WHILE THE INFORMATION ACCUMULATED AND SET FORTH HEREIN IS BELIEVED TO BE ACCURATE AS OF THE DATE HEREOF, HAMMOND LEAD PRODUCTS. INC. MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT. APPLICABLE. AND SUITABLE FOR THEIR PARTICULAR CIRCUMSTANCES. ANY PHOTOCOPY MUST BE OF THIS ENTIRE DOCUMENT. (ESSENTIALLY SIMILAR TO FORM OSHA 20 -- U.S. DEPARTMENT OF LABOR) 086709 ^onfidfnttai.. 0389HAL98 MATERIAL SAFETY DATA SHEET ************************** The C.P. Hall Company 7300 S. Central Avenue, Chicago, IL 60638 Emergency Telephone Nos 312/767-4605 ________________________SECTION I_______________________ Chemical Name: Fatty acid soaps Product Name: HALLCOtE) LUBE Chemical Family: Liquid Postash Soaps Formula: CH3(CH2)nCOOK n=8-16 HMIS Number: 100 Gloves & Safety Goggles SECTION II - HAZARDOUS INGREDIENTS None SECTION III - PHYSICAL DATA Boiling Point (F): Vapor Pressure @ 212F: Vapor Density; Solubility in Water: 212 760 N/A complete Specific Gravity: (H20=1) % Volatile by Vol: Evaporation Rate: (H20=1) 1.015 70 approx. 1 Appearance & Odor: Green liquid, soapy odor SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): NONE Extinguishing Media: CO2, Dry Chemical, Water Fog Flammability Limits: Not Available Special Fire Fighting Procedures: Wear MESA/NIOSH approved selfcontained breathing apparatus (Sch. 13). Use water spray to cool fire-exposed containers. Unusual Fire and Explosion Hazards: Water may cause frothing. SECTION V - HEALTH HAZARD DATA Threshold Limit Value: Not determined by the ACGIH. Effects of Overexposure: Liquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation. Emergency & First Aid Procedures: Inhalation: Move subject to fresh air. Eve and Skin Contact: Flush eyes with large amounts of water for at least 15 minutes; consult a physician if irritation persists. Wash affected skin areas with soap and water. N/A = NOT AVAILABLE DO 086?'' 0 tdfnttal. CONF 1 Product Name: HALLCO LUBE SECTION VI ~ REACTIVITY DATA stability Unstable: Stable: X Incompatibility Conditions to Avoid: Not Available (Materials to Avoid): Strong oxidizing agents Hazardous Decomposition Products: None under normal use conditions; oxides of carbon when burned. Hazardous Polymerization May Occur: Conditions to Avoid: Will Not Occur: X Not Available SECTION VII - SPILL OR LEAK PROCEDURES Steps To Be Taken In Case Material Is Released or Spilled: Dike and contain spill with inert material (sand, earth, fuller's earth, etc.) and transfer liquid and solid diking material to separate containers for recovery or disposal. Wash floor area with hot water solution of OAKITE or equivalent. Remove contaminated clothing and wash before reuse. Wash affected skin areas with soap and water. Keep spill out of all sewers and open bodies of water. Waste Disposal Method: Incinerate liquid in approved equipment. Landfill contaminated diking material according to current local, state and federal regulation. SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type): None required for normal operations. Ventilation Local Exhaust: Normal room ventilation Special: Mechanical (General): Other: Protective Gloves: Impervious Eye Protection: Splash Goggles Other Protective Equipment: Eyewash facility (ANSI Z87.1, 1968) and Impervious Apron SECTION IX - SPECIAL PRECAUTIONS Precautions To Be Taken In Handling And Storing: Avoid open flames and excessive heat. Other Precautions: Do not freeze. If frozen, thaw gradually. Revision Date: 5/86 JTH 2300 Supersedes: 11/85 JTH DO 086211 CONFIDENTIAL 2