Document 0qGmNr4YRZGYxj8qDm72M9vmd

PAUL. 1(4 | CAPTIVE USAGE T/D LIQUID PHASE EDC To TCE Mfq. & MC Mixes Pernhlor TrieMor Mfg. St Mixes Vinyl Chloride i ) OHC EDC To Perch lor ! Trichlor rf No. 2 EDC Plant L____ ____ !| __________ f i* 1970 AVG. 117 r2 8.6 12.A. 792.6 PF'L-j il `US'c .. *CHEW!CAL DIVISION LAKE CHAR LES, LOUIS IANA JAN. jjr RED. J MAR. APR. ) WAY JUNE 1 ( .! ......... 1 is f ji loi.a 127.6 ^147.5 100.7 i 130.3 122.3 0.0 0.0 n.O 1.6 *0.0 0.7 0.0 o.o So.o 1.8 io.O 1.0 863.2 817.3 988.6 _967.7 > 946.2J 928.2 y-yjnr luownAL : Subject to Protective* o- ' Judicial District court No. 91-1145 JULY AUG. SEP. 105.8 24-7 35.8 553.2 105.0 1.2 1.7 934.1 120.5 3.9 5.4 880.1 OCT. 159.7 4-5 5.5 969.6 NOV. DEC. 138.8 112.4 0.0 5.7 0.0 5.6 888.7 790.4 jW | J AVG. { 11 i {122.7 3.5 .... 14.7 877.3 37.6 58.0 63.7 45.4 54.2 54.0 59.7 56.3 61.4 106.5 117.4 146.8 57.2 59.8 55.0 62.7 79-0 7/, 7 108.4 90.4 179:3 25.1 36.4 67.8 3271 36.8 47.8" 51.0 I32.7"1 123.7 43.7 TITO"" 5.6 40.0 53.2 16.6 10.5 51.5 112-7 139.6 108.1 ill.l 1 co r* CD --* CJ cn "J s 1 ( j 1 FORM 201 - b Piw i! SI K i L j CHCMICAl DIVISION LAKE CHARtES, LOUISIANA CONFIDENTIAL: Subject ter Protective O^r of 14th Judicial District Court No. 91-1145 LABORATORY PRODUCT REPORT EDC SHIPMENTS 1970 JAN . FEB MAR APR WAY JUNE JULY AUG SEP OCT NOV | DEC 1971 | Avg. . ! Avg . 1 v i n ct Cm nn i re PPM 0 0 00 0 00 0 0 0 0 lo !0 Vi NYL1DENE PPM 0 0 00 0- 000 0 0 00 0 MffMYt. 0't.PIMnF PPM 0 0 0 0 0 n-------- 0 0 0 0 0 0 0 :o 1 Trans 1.2. Di cm ornETMYLENE PPM 0 0 00 0 0 0 0 0 0 0 0 !0 \ 1.1 DlCHLOROETHANE PPM 22 12 13 15 12 -- 17 11 13 17 18 12 8 13_____ CIS 1.2 Dl CHLOROETHYl.rNE PPM 1 Chloroform PPM 21 U 21 86 4-- 11 21 no? - 0 15 12 8 0 11 11 14------- IJ'------ 0 63 !6 ..... j to 5112 Ethyltke Dichloride % 99.985 99.988 99o990 99.992 99.983 99.992 99.991 99.989 99".957 99.985 99.988 99.987 99.988 ^ R 1 Oll.OROr THYLFNE PPM 3 0 0 0 0 0 5 3 4 O 20 1 '*FCf4I.OPOtTHYLEN PPM * 1 0 00 0- 00 0 0 0 00 0 1.1.2 Tr|CHLOHOETHANE t r11 an E TPM 44 45 29 20 77 - 23 3 9 Aft 78 62 53 4i PPM 0 0 00 0. F-------- 0 0 ID--------- 0 n 00 0 Propane PPM 0 0 0 0 0 - 00 0 0 O 00 0 i Ethylene Ciilovorrom i oe 6PPM 6 44 12 - 6 (1 0 6 20 9 7 7 i Ethyl Chlorioe PPM 9 | Un i i.tmt i r 11 o (Won-Polar) PPM 0 l Uh i t*EN r i r i eo (Polar! PPM 0 22 0 0 A 0 0 6 16 ~o------- 0 00 -- -- 17 23 18 16 11 9 34 l6 0 TT------- 0 0 0 ~v------- 0__ 0 00 0 0 0 00 io [Color (aphA) | AffM. ARANC.E 1 Ac 1 0 1 TV 'Vate r> Free Chlorine non-volatiles Total Iron Specific Gravity 60u/60F PPM PPM PPM PPM PPM 7 Clear 2 42 0 1 0.20 1.262 81 Clear Clear (1 _(1... 26 22 00 (X (1 0.23 0.10 1.262 1.262 8 Clear (1 30 0. 9 0.18 1.262 88 Clear Clear 11 34 42 n0 (1 0.24 om 1.262 - 88 Clear Clear is (1 64 00 6- 7 0,11 0.11 1.262 1.260 66 Clear Clear TI--------- Ti 65 59 0--------- 0 3------------ 2 0.13 (57155 1.262 1.262 7 87 Clear Clear Ciear a (1 7 85 51 69 0 00 1--r ~z-------- 2 0.12 0.06. 0.07 17267 1.262 1.262 1* '7 (Clear [(1 (50 0 3 ...... i 0.13 1.262 CO 1 --- ' <--> GJ 1 cn CD * t1 1 - PAu l.: ' METHYLCHLOROFORM SHIPMENTS 1970 AVG. JAN. Type 314 i Color Specific Gravity APHA 25/25 C 7 1.333 71.352^ Distillation Range C Low 74.U 74.2 Moisture High PPM 74.9 75.2 39 41 Acidity Non-Volatile Residue PPM asHCI 1 71 % {.0001 (.0003 Soluble Chlorides PPM {0.5 (0.5 FES. - -- -- P.i'*frV3 O^ i CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY PRODUCT REPORT j* MAR. APR. | MAY JUNE JULY i i 1- 9 )9 5 - j-- 1 1.332 72.8 -- _ (1 " 74.4 34 13 t 35 29 (1 3 !2 0- -- -- .0002 (.0001 - -, - - (0.5 Type 321 Assay Moisture Distillation Range Lev/ High Specific Gravity Color Acidity Mon-Volatile Residue Soluble Chlorides % PPM C 99.80 28.5 -- 25/25 C APHA PPMasHCI % PPM ---- -- 6 (1 .0002 {0.5 -- - - - _ 14.0 -- -- 7 (3 .0003 (0.5 -- - - - - 27.0 -- tm 1- -- -------------------------------------------------------------- j -- I 1- - 7 I- (i i.0001 (0.5 - - -- 50 i (l AUG. SEP. -- am -- *-- --* --- -- 78 OC.T. -- -- - NOV. i 1 -- mm -- -- -- - DEC. 1971 1t AVG; j _______ 88 i 1.332 1.3.32 ] i 73.8 73.6 1 74.3 74.6__ J 45 33 11 (.0001 (.0001 (0.5 (0.5 1t ---- 42.3 ) --- --- - -7 -1 -- - - .0007 to/i -- -- ---- --- -- ------ --- * -- 7 (1 .0004 (0.5 ry--jj L2 <0 t G..H nf J 4 Nr I LTCrJ psec--c utu--aa fiti o Prut LCidl y-.--Srr= 11 Al : active Hstri L145 Ordei ct Cot rt i 1 TRI-ETHANE SHIPMENTS 1970 AVG. JAN. Type 324 Color SDecific Gravity APHA 7 8 25/25 C 1.304 1.303 Distillaiian_Ranqe Lov/ High C 73.4 73.6 82.6 82.8 | Moisture PPM 60 ~ST | Aciriity PPM as HCI (1 1 l Soluble Chlorides \ Aluminum Scratch PPM APHA Mon-Volatile Hesidue (0.5 (0.5 31 25 .oOol .0001 Tvoc 333 Color Specific Gravity Distillation Ranee Low High Moisture Acidity Non-Volatile Residue Soluble Chlorides Aluminum .Scratch APHA L1_____ 25/25 C 1.319 - C 74.4 84.7 PPM 48 PPM as HCI (1 % .0003 -- -- -- PPM (0.5 - APHA -- (/) r o c> CD o FED. _b. * - 'J II n* * * ' * CKEL'.ICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY PRODUCT REPORT MAR. \ APR. WAV JUNE JULY 87 1.303 1.30? \ 8 I9 8 5 1.302 j 1 r.304 1.303 1.304 AUG. SEP. OCT. 66 7 1.305 1.303 1.304 NOV. ' DEC. 1971 AVG. 87 7 1.304 1.304 1.303... 73.6 73.4 73.0 i 73.5 73.6 73.5 73.5 73.6 73.5 73.8 I73.4 73.5___ 83.6 44 (1 (0.5 83.0 50 2 (0.5 83.5 45 ^60 32 (0.5 i ^0.5 84.4 61 2 (0.5 184.0 54 (1 (0.5 86.3 81.8 65 63 "XI 1 X075" (o;5 82.7 55 XI~ (0.5 64.1 61 (1 (0.5 82.8 69 1 (0.5 183.6 158 51 (0.5 38 60 45 40 0 50 0 (.0001 (.0001 --(1-.--0-0--0--:. (.0001 (.0001 .0002 27 42 40 20 32 1.0002 .0002 .0002 (.0001 .0001 77 1.318 1.319 I 7 19 8 5 1.3201 1.320 1.320 a.320 6 57 1.321 1.320 i 87 1? 1.317 1.321 jl.320 74.0 74-4 84.0 8/f T 6 14 PL (1 J________ Loooilr.oooi (0.5 (0.5 - 1 74.1 J 74.2 86.0 86.3 37 36 22 .0002 1 .0003 (0.5 i (0.5 - !- 74.2 83.8 32 2 .0001 (0.5 74.3 55.1 i3 ~53 4 (1 {.0002 (0.5 _ 1 74.3 74.1 74.2 74.3 74.2 S4*5_ 45 A3 85.0 S4*B__ i!4j8---- 32 fti 42 (1 1 11 1 .0001 .0002 (.0001 .0005 -flosaJ (0.5 (0.5 To75~ (0.5 (0.5 I -i T . ---- i t 1i : l ----------- i i i j " - -----------,----- ,1 i | \ \ ---------- 1 . Cl TRFTTTEn JT1"AL; Su! ijech \o i'tro ;gCt j. v J" O l TTTj z------------- Of L` tin uu< 1 i c i a 1 TTtrrtrr rert:--frcj urt----. ^ 1 - i Irl 8 i-ORM < tL/1 * SODIUM CHLORATE SHIPMENTS 1970 Avg . ________ PRODUCT - %_________ N aCi.O-j 99.96 `/Cl 0.04 .U0038 m*?so4' 0.U01 Tr lies 1 DUE Moistune .U0004 .001 0.02 JAN FEB 99.97 99.97 0.03 0.03 .00031 .00034 (0.001 (G.001 .00005 .00003 (.001 .002 0.02 0.02 PRO li > 1 a IL j r CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT MAR APR f Jt 1A1W1 JUNE JULY AUG 1 99.98 99.98 99.97 1 99.97 0.02 0.02 0.03 0.03 .00024 .00027 .00042 .00045 (0.001 (0.001 (0.001 ^0.001 .0003 .00001 .00006 *00004 .OOF (.poi K.ooi (.001 0.04 0;02 0.04 0.03 99.97 0-03 -00023 (0.001 .00001 (.001 -- -- SEP OCT NOV DEC 1971 11 AVG . i f '99.94 99.96 99.96 99.97 0.04 a.cti. 0.04" 0.04 0-03 -OOO/iT .onoAT .00064 -OOOA.4 .00040 (0.001 (0.001 (0.001 (0.001 (0.001 .00005 .00005 (.0000 JL 00001>.00003 (;ooi 3O (.001 (.001 (.001 0.04 0.04 37o5 0.09 0.04 SI EVE ANALYS1S % Larger than screen Size Mesh 20 40 100 _34~L__ [35.9 80,4 79.5 86.X 93.2 31.4 72.3 89.4 39.9 33.1 WX 29.3 82.5 74.8 ST7B-- 73.2 94.4 ~9Z7T 95.1 91.9 27.8 - 78.3 93.4 - 20.6 74.5 92.6 47.0 80.0 97.2 27.2 90.0 99.8 44.2 S7.0 0T-A 33.4 79.4 QT.Q i - CO 1 o CO CT1 Screen Test - U.S, Standard i i - -- com-'j DENTI; lL: --------or Gubjec tin 14 LI) Judlci rotecl aT~PIj ive o trict tier Court --NOY 5 FORM 6 A <iOl - lU 4 j TR1CHLOR SHIPMENTS [ 1970 Avg . JAN j iVPL t 22 (Deo;reai>irvi ft So Lvent C rode) Lninn apha (5 7 |Specific Gravity ZO/eO C 1.460 | Eh s Til,cation Range C j Low | High [ .Vatch Content Ci.oud Point | rjONiVOLATILC C % Arto Acceptance pH % as NaOH Acidiby/Alkalinity 86. j 87.7 l-io .0013 0.15 7.6 .0002 -- (-10 -- 7.4 .0002 FEB Pr ^ i1 R!tS CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT MAR APR j MAY JUNE JULY AUG SEP OCT NOV DEC 1971 ( Avg. | t 7 6 89 9 (5 7 7 99 10 8 1.461 1.460 1.468 1-461 1.461 1.460 1.460 i ,it6n 1.460 1.460 1 r/,62 1.461 86.0 87.8 (-10 .0006 0.15 7.6 .0002 86.0 87.7 (-10 .0021 0.15 7.4 .0001 86.0 86.5 88.2 87.8 (-10 (-10 .0011 .0018 0.14 0.15 7.7 7.8 .0002 .0002 86.4 36.3 87.8 37.9 (-10 (-10 .0019 .0015 0.15 0.16 7.7 3.1 .0002 .0002 86.2 88.0 (-10 .0018 0.16 8.1 .0002 86.1 87.9 (-10 .0015 0.15 8.0 .0002 86.3 86.3 86.2 88.0 87.8 87.6 (-10 (-10 (-10 .0016 .0018 .0012 0.14 Op 14 0.16 8.0 8.2 8.6 .0002 .0002 .0003 86.2___ (-10.,, .0015 7.9 .0002 TYPE .110 Co:.on Sprctric Gravity 20A20 C Distillation Range Low HI Gil Wateii Content Cloud Point apha C C Noflf VOLAT 1 Lt Acid Acceptance % %/as NaOH 5 -- -- (-10 - - - - - 7 -- -- -- (-10 7 - (-10 - - - -- -- - - -- -- 5 -- - -- ----- -- -- - (-10 -- mm mm - 7 10 13 8 ---- - - ---- ---- - (-10 (-10 - (-10 - -- - - - IYPE 1 1 3 (Hieh Puri tv Or ide) Color apha i________ Specific Gravity 20/20 C 7 -- Distiilation Range C Low - -- H 1 Gil --- (-10j Water Content Cloud Point C (-10 : NOH-:VOLATI LC % (.0001 .0001 7 7 8- - --_ (-10 (-10 (-to" (.0001 (.0001 (.0001 L [ 1. SL 013162 r. 9 (5 6 6 -- 1.460 8 9 8 -_ 7 -- 86.6 --- 88.0 (-10 (-10 (-10 .0002 (.0001 .0003 -- -- (-10 .0001 -- - (-10 .0001 - - (-10 .0002 (0 .0002 (-10 *GQQ1_ "nwFTnt ENTIAt c t K j <=> e-1- t- n Pr ofcecti ve Ore er of ! 4 f-h J nr! i c:i a l rist rich C lourt No. 9 1-1142 FORM N(^A201 It j>RG [r^|STR|ES 9 TR!CHLOR SHIPMENTS m JAN FEB Type t15 (Dual Purpose Gr Rde ) Colon apha -ptcimc Gravity 20/J20 C Dl ST kLLATi ON RANGE C 5- 8 Lo H r gm Watei* Content Cloud Point C Non-Volatile acid Acceptance U % as NaOH -- (-1Q (-10 .0002 (.0001 .12 8 -- _ (-10 .0001 CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT MAR APR WAY JUNE JULY AUG SEP | OCT NOV DEC 1971 ! AVK, 8- -- --- -(-to 4M .0002 - - 10 8 -- (5 6 7 9 to 9 8 n 1-10.. i(.oooi -- ---- -- '(-10 (-10 .000T (.0001 o0002 --_ (-10 .0001 _ (-10 .0002 -- (-10 .0001 -- (-10 .0001 (-10 .0001 , . CO ......... o r.i at C' --CONI 'JLUENT AL: Sub je ct to Frote< rtive 5rder ii f rrtti J lid it ial d] stric : Cour : No. 7I=IJ 45 uI L, r( f.i tu i i *. PERCHLOR SHIPMENTS 1 Vi 'C 207 Co1, oh APHA Si'rcirir Gravity 20/20 C Oi r,T 1 L.LAT 1 04 Range C tow H l r,H v/nui! Content Cloinj Point C Nf N - VOL A T 1 t_ E wfc . % v\\ Ac n> Acciptanm: % as N0H CO^PEiI CORROSION Acidity Ml of 0.01 N NaOH Flask mg/30 CM^ Soxole t mg/30 cm2 Condenser MG/30 CM2 Colorides ppm 1970 Avg . JAN 8. 8 1.624 -- 121.4 121.9 (0 (0 (.0001 - 3.3 8.1 - 3 i 6 6 0.25 - FEO 9 -- (0 -- 8.4 - -- -- iN_ ,, o I RIL S CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT WAR APR WAY JUNE JULY AUG SEP OCT 8 12 IM -- (0 8.2 (6 3.2 - ---- --- ---- -- 12 (0 8.1 r 10 -- (0 ^72 - - 10 w (0 i.2 . , 12 -- -- (0 -- 8.0 - -- 11 9 (0 8.4 (0 ft r6 _ -- -- -- -- NOV DEC 1971 j Avg . 12 -- -- (0 -- 8.4 - -- 14 (0 _ 8.4 -- -- -- - 11 _ (0 8.3 -- - TYPE 208 Color Specific Gravity APHA 20/20 C Distillation Range C Low H 1 on .vater Content Cloud Point C Non-volatile PH \jt.% Copper Corrosion Acidity ML or 0.01 N NaOH FLASI; MG/30 CM2 Sov.iileT MG/30 CM2 CONorNsrn MG730 CM2 Ch^oriof.3 ppm 3_ 8 1.624 121.2 121.9 (0 -- _ (0 .0004 6.7 6.6 2(1 _5_________ - 5- 0.08 - SL 013164 8 8 8 10 10 i------------- 8 10 11 12 12 1.624 1.624 1.625 1.623 1.62? 1,6Oi, 1.624 1 .624 _ -- (0 (.0004 6.7 (20.9 120.9 . J 122.0 121.9 (0 "to (0 (.0001 SO002 f.nooi 6.4 6.4 6.3 . 121.1 121.9 (o ;0oooi 6.5 121.1 122.0 (0 (.0001 53 121.0 122.0 (0 6.5 121.2 121.2 121.0 122.0 122.0 122.0 (0 (0 (o (0 (.0001 (.0001 .U003 6.6 6.4 6.3 6.2 1 '1 1 1 0.12 3 (t 3 ... 3- 0.06 1 2 5 5 0.06 L (i 6 6 (0.06 2 2 6 10 (0.06 r------------ 1 1------------- 2 5--------- 7 5--------- 5 XT05-- (0.66 41 22 J6 65 (0.06 0.06 rm1 1itf? Xt nUrrwjC<t 1 1IfMtlJf. 2 1 5 5 0.03 -- -- -- fyF 1 AI 1__________ bL -0 ' JjU_____ 9 1.624 121.1 12^Q_ (0 .0001 6.4 2 1 5 5 0.06 FORM N A 201-13 PERCIILOR SHIPMENTS 1970 Avg . TYPE 203 Co i, o ft APHA Specific Gravi tv 20/20 C instillation Ranch Low C H 1 CM v.virn Content Cloud Point C Non volatile PH Acid Acceptance % AS NaOH Coirrn Corrosion Acidity ML of 0.01 N NaOH Cl ask MG/30 ai2 5okiiLCT MG/30 CM*- Condenser MG/30 OA^ Chlorides PPM (5 _l (-10 (.UUOl 9-S -- -- - JAN a. -- -- -- - FEB -- _, a - a. PPG INKSTRiES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT MAR APR MAY JUNE JULY CONFIDENTIAL! Subject to Protective or<Ki of 14th Judicial District Court No. 91-1145 ' ~Tm AUG SEP OCT NOV DEC A VG . --- _ --- - - aa a. " a -- ---- -- - a. -- a - -- a. a. - - -- - -- -- -- _ -- -- -- -- -- --- -- - -- --- ---- - -- -- -- -- - -- -- - --- ---- - --- ** -- - . -- -- -- - _a - a. - a --- ---- --- _ mm mm aa amm -- -- a. -- ----- ---- ---- .. mm 4a -- -- -- -- -- ~ -- ~ - TYPE 209 Color APHA Sor.ciric Gravity 20/20 C LNsthlation Rance C Low HI Oil Water Content Cloud Toint C Non-Volatile P'H wt,% AUO Af.Cr.PTANCH % AS NaOH Cooper Corrosion ArmiTY ML of 0..01 N NaOH Flask MG/30 CM*1 SOKULET MG/30 CM2 Condcnser MG/30 CMz Chlorides . ppm -- -- -- -- -- -- - SL 013165 * -- a. __ mm - a -- a. _ _--- -- a. a. -- - - -- .-- - , - --- - -- .4. - - - a. - - - - a. - - - - --- *- a - - - -- -- -- - aa - - - -- * -- --- -- -- --- - -- -- -- -- ---- a- mm a* aw -- -- - a. - mm a aa mm _ mm _ mm mm mm mm mm * mm a mm a. a- a, -- -- - - - a. - .. -a - a. --- - a. ---- ---- --L "-- mm aa w -- aa* a. -- -- -- - FORMI0.A2OI.M WCi#jS,KltS 5----- - . | ETHYL CHLORIDE SHIPMENTS 1970 Avg- JAN CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY PRODUCT REPORT FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1971 Avg . COi.OS * -0 1STUHC Srcnr.ic Gravity APHA PPM 0/4 C j ACIDITY AS HCL | Non- VfiL ai l le Re SI out I ethyl Chloride ionCist ill-", t Ranee low Hiph Wt. % Wr. % Wt. % C (5 16 o.q?3 (5 10 17 0.922 0.922 (5 (5 (5 (5 (5 (5 IS 14 14 24 29 n.cm 0.924 0.92L 0.922 0.923 0.923 (5 (5 (5 (5 (5 1 h 19 All____ 24 18 Or922 0.923 -Q.923- 0.923 iL.223- (.0001 (.0001 (.0001 (.0001 .OOOli (.0003 (.0001 .0002 QQ QM 99-90 99.98 99.96 (.0001 (.0001 (.0001 .0002 .0001 ,0003 .0009 .000L (.0001 .0003 -.j 99.95 99.97 99.97 99.98 99.96 (.0001 (.0001 (.0001 (.0001 (.0001 .0008 .0001 .0003 .0005 .0003 99.95 99.97 99.97 99.98 99.97 12.3 12.3 12.2 12.6 12.4 12.4 12.3 12.2 12.3 12.4 12.4 T2^T~ 12.3 12.3 12.3 12.3 12.3 12.5 12.3 12.5 12.8 12.7 12.7 ~~ 12.6 12.4 12.5 12.5 12.6 1 1 1 j , > ! i CrP r0 CP CD iF.NTlA , A. V nhect i've ol Lt*?*"--------- i Kib^ec iU tcict ot '14 tK' JUCl 1 w * 9.1-11 4 6 ' C4U " FORM N , 201 - IS VINYL CHLORIDE SHIPMENTS lfjO PPM 4CI PPM phenol re ppm PPM sol run ACETYLENE ppm PPM ALCEHYOC5, AS ACET AtOEHY OE PPM PEnOXlOE', AS MjOj PPM 1970 AVG. JAN FEB 35 fl 11.3 n.l fl (1 (1 0.01 37 31 (1 (1 - 0.1 0.1 (1 (1 ~0~ (1 (l (1 0.02 0.02 |V ^ j J i k II.-j CHEMICAL DIVISION lAKc CHARLES, LOUISIANA LABORATORY PRODUCT REPORT MAR i APR I MAY JUNE JULY AUG 35 (T 0.1 (1 (1 (1 . 0.02 29 >33 Tf 1(1 ^ I 50 0.1 0.2 (1 (1 ~n (1 ~TI-- Tt (o.ot 0.02 31 fl fo.i fl fl (1 0.03 34 39 o (1 40 50 0.1 (0.1 (1 (1 or-- (1 a (1 0.01 (0.01 SEP 28 (1 48.. 0.1 (1 (1 (1 0.01 non-volatile residue PPM 4 13 3 9 %----------- 5 n 10 11 OCT 27 (1 fo.i (1 . (1 (1 _ 0.02 9 NOV 1 1971 0 EC AVG. 35 U ~tfj (0.1 (1 (1 (1 (0.01 y______ 33 (1 (1 tiO ____ (0.1 (0.1 (1 (l (1 (l uU 0.02 0.(52 4 3 . JL_#_ OXVCCM IN VUCOB SPACE PPM (100 - -- -- mm -- - "\ J 11 _----------- 1r---------------- i________ ---- f f11 ____ I--,_____________________________ t \ \ I CD { r~ \ CO CD ''J i -------------- j-------------i * , I -------------- ! rriMP] IIPH'P T ut S- Kuh jfsr F I-a | of 1 4t-h .liwli pi X ve U! tter cnct Cour L Nn. Ol-l 1/1 c ... ! i r 0 fi m i ' ' *. U 2 - H >I w 3 1 l\t L L> CHEMICAL DIViSiON LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT j 1970 i 1 1971 * . ...ED.C.. 1 AVG- JAN FEB MAR APR MAY JUNE | JULY AUG SEP OCT NOV DEC f 1 Avg. 1 PPOOL'CT PPM* ... 1 i t f i'l N YL Cut OH I DC 0 |0 0 00 00 0 oo 0 00 o! ''( Tin i Cnt.oni nr V i *, vi i n f n r Tr,'M,S *1.2 Dl niLOPOC TMYtENE 1.1 Di ctiL ownr thane Clr, 1,2 Otchloholthylene Che oro yohm Ethylene 0;rnufiRiOE 1.1.2 Tli ClllOROE T !!AWE (WT. Y 1 n A?. z IT 0 o fo 10 i0 0 0 ... n 0. o n 0 0 0___ 0 0 (1 0 0 0 O o jo n d So 0 ob 20 10 10 (1 2 7 14 314 5........ !! 1(13 14 3 12 16 0.7 3 5 B 22 26 15. 16. 15 j 14 9 6 11 111 99.984 99.990 99-995 99-990 99.983 199.993 99.991 99.988 99.987 {99.984 44 ^3 {1 14 23 j 3 2 13 49 169 00 0 0 0 |0 u----------- 0 --------- 0 O 00 n 00 0! 0 0 0 0 (1 13 10 9 13 2 J* (1 13 16 9 13 k?9T99T 99-989 99.985 99.989 34 55 55 03 0 130 <0 I'UIPA'J C Ethylene CiiLononROMiOE 0o 9 17 io (1 0d 5... 7 10 !2 0 2 0 --------- P------------ 0 0 o_ pjgj 4 7p 7 9 Ethyl Chloride L-n 1 0 e n r 1 F 1 e n 7 7 .. 1 (l 0 0 i 11 | 10 10 (i "0--------- ro---------- 0 6 TZ Pn-- 6 p P 3 7 43 ill -o----------- 0 o In i 1,0 ke hc.l . 1 !. rn ......... ! r p !^ 1 CO 1 o> i co 1 26 0-02 1.47 21 0.03 0.68 19 0.04 0.?2 21 0.01 "'0774' 29 0.02 0.40 30 0.02 0.43 29 0.01 0.20 31 fn.m o_i,n 40 V6 (0.01 0.01 0.53 0.41 * 41 0.01 0.52 i 34 0.06 0.54 43 0.01 0.95 32 0.02 0.54 1 i i i i ! -------------- 1-------------!| 1 < --nbUnMWPP inPMTT M.: j cr Sub 3^ ;--1'4 tTl - A. 4/^ Drnhpr u uu i w j P 1 Hi live C strict rdef Courl Hn Ql -1 45 j r O RM i1 \/ C. ' ^ EDC RCAf/lOR ifj. F Tn v L rr. r Di cut. OR I t)(. WT. % r t r t i n sj 'ir nn'L r r PriirMl OHOt Til Y*. r .iu 1.1.2 Tnn hlohoe tma*)E U* Ti. 1 II A CHl.OROE TH A!IE S-TETr:AriiLOnc>LinAijt I'm iC'ii jpor KtAJjc fir <Acm.o#u> than e F;iiTi.tME Chlorodhomire E TiiYi, Cih. on i nr Li.-i i ntn T l r i ed H-0 Total ft as FeClj T A FI s Specific Gravity PPM % !V 6G.GOF f CHEMICAL DIVISION LAKE CHAKLES, LOUISIANA LABORATORY OtTiRAT I ONS RETORT 1970 Ave. 98.17 0,04 (o.oi 0.86 (0.01 0.03 (0.01 0 (0,01 o.oi o.ol JAN 97.78 0*02 (0.01 1.17 0 u 0 0 (0.01 U .02 1.00 | FEB t 1 { 97.12 I 0.03 0| 1-37 1 01 01 01 0 0.01 ! 0.05 1 1.43 MAR j APR MAY 1 ___ 97.72! 98.34198.72 0.01! n.02 0.06 0.01 0.02 io 1.04 0.60 \ 0.60 0 0 S0.06 0 "O' 0 ~o 0 0.01 [0726 10.04 !0 O O ! s; j 0 0.01 r7ur 0.46 0724 1 JUNE JULY j AUG I 97.42 98.62 197.62 n.05 0.06 D.07 0.05 0.01 K0.01 0.88 0.45 |D. 84 0.17 0.01 p.05 0*7? 073S p743 o.ov 0.02 p.13 00 P (0.01 (0.01 (0.01 0.02 0701 0.01 0.50 0.34 0.65 - (254 T2l2 0.58 0.49 2.41 1.30 1.273 1.272 (188 0.44 2.05 1.270 (180 0.42 1.29 1.266 (268 0.51 0.56 1.278 (259 0.60 0.36 1.283 (261 0.64 0.77 - (250 0.58 3.84 1.294 (254 5751 2719 1.279 SEP OCT NOV DEC | W | 1 Avr,. ) i, 98.30 0.03 0.04 0.76 0.04 0.53 0.02 0 (0.01 0.02 0.35 98.27 97.74 97.99 97.97 S 0.03 0.03 _ 0*06___ 0.04 \ (0.01 0.01 (0.04 0.02 i 0.67 1.20 0o56 10.85 | (0.01 0.02 0.63 fo.08 \ 0.34 0.48 0.30 (0.29 i 0.08 UTJl o.oi [07d5 i 0 0 0 fc>.........! (o.oi" (0.01 (0.01 1(0.01 ) 0701 0.03 0.02 jO.02 1 "0757 0.18 0.27 10.54 j 11 ij (193 (152 GJJi__ 1.76 1 -88 1.276 1.269 (213 0.50 0.91 1.267 (320 0.74 4.98 1.287 i 1(229 jO. 53 il.74 il.276 ! j * * . * - * *r 1 1 CO 1 o CO io i j COMF1 lENTiA L: | i i of ?ubiec 14 th E to P Judici No. roteet fve- m 7T- OTs crfct- yi-m 5--------- tter-----cvui L _______ 1_______ r 0 R (< i m,, CHEMICAL DIVISION LAKE CHARI ES, LOUISIANA LABORATORY OPERATIONS REPORT EDC RT ACTOR it 2 LUIYLCAE Dirm.OUIPE Tw j r>in of - hyl f ?x i I'f rr.HLonor TiiYLCfiE 1,1,2 'Toil MLOROE UtANC U- 7t 7 U-IOILGROC INANE 3. i r TBACHi.oitociMAric f r t TACmL O^OE THANE > \ f a a M \ 0 rr o e T h a N E LTlfYiCM; CliLOffO 0 ROM 1 DC Ethyl Cmlofiinc L'n i a in t i r i to WT. % 1970 Avc-. JAN .98.2k 98.26 n.,03 (O.Oi 4n,m 0 6.88 10.01 0.02 (0.01 0 0.99 0 0 0 0 (0.01 (0.01 0.02 0.07 0.77 0.67 FEB MAR 97.50 98. 14 0.02 0.C1 0 ... 0.01 1.10 0.92 0 0.03 0,32 O.Oi 0 o3'6 OTTO 0 {0.01 0.01 0.07 0.02 0.93. 0.40 APR MAY 1t 97.73 98.88 0.06 0.04 0.03 0.01 0,67 0.50 OiOl j 0.06 0.68 I0.24 0*06 jO.01 0 to 0.02 j(0.01 0.03 0.02 0.72 0.18 JUNE JULY AUG SEP OCT NOV DEC ! W1 | 1 AVG . | ..... L _.J 97.82 78.84 97.87 98.05 98.46 97.31 98.19 |98*09 0,06 0.01 0704" ' 0.04 n,n? 0.06 0.08__ lQ.04 (0.01 0.01 0.71 0.43 0.02 0.01 0.92 0.69 n.ni 0.74 0.03 0 1 0.01 -- 1.31 0.52 Q.79___ 0.02 0.01 COT 0.04 0.01 0.08 0.82 10.10 O.65 OTIS COT-- oOT 0.36 o.67" 0.46 10.43 0.06 0.08 0.15 oOT 00 0 0 0.11 0 0.29 10.06 j0.08 0 10 io ,K (0.01 0.01 (0.01 "0.02 3702 0.02 0.60 3724-- 0.43 0.01 (0.01 0.02 (0.01 1(0.01 COT-- 0.02 0703--0.06 {0.03 0.46 0.25 0.20 0.30 10.45 j ii,0 Total Fe as FcCl^ .. Spccirif. Gravity _______L_____ PPM (TOT t(205 (230 (265 % 5 Iq 7q 13 * 37 0.47 1 0.53 2.14 2.68 0.6.1 1.97 C"G__-G_O__F______j _]___2_7_7___1_._2_7__0___1_._2_7_6___1_.2R1 (318 (245 0.73 0.57 1.05 j 0o20 1.284 1.287 | i (310 0.74 0.31 {195 0.45 3.05 1.279 X279 0.68 2OT 1.279 (156 0.36 1.67 1.269 (130 (294 T3T3T~^ 0.68 1731 ' 1.55 1.267 1.271 (317 0.73 4.21 1.282 (245 0.58 1.87 1.277 * cn r~ CD rj ---.... -- - - - -j - ! 1 1 ) ........i i 1* .. .. | 1 _ __ 1 1 ! i * CONFll tsN'i'l AI T---------------- s object to Pi ertrectn ve--re yx of 1JLTth J udicic Diisl net <j oufc No. S 1*114. j 1 }\ | _______ i . JKA. . _ EDC REAP70R //3 L 1 1`YLr HE D 1 OtLOH 1 DE To f c ml mi nr thyi r :t r f'frr'H.cirrnfiHYL.rNE 1 . 1 . 7. 'Tf= 1 ( tiLOftOE Til Ar'E U - 3 L TfTACMLODOCTliAMi j- 1 E 1 fT/lf.ll^OnOE 1 li Ml E r*Fi TAC^lOt'OL THAIIC Hr \ \cu:.onoc than c EtpiYlE'iE Chloiioouoh I oe E rim. CiiLOn i nc U *J 1 p f N T 1 F 1 c D 1970 Avg. WT. % t 98.38 0.04 (0.01 0.72 (0.01 0.03 (O.ol <T " ' (0.01 TT70I 07IT0 H.,0 Total Fe as FECL3 Thus Srccinc Gravity ppm % 7. 60o.GOF (.29.9. 0.69 4.49 1.284 - Cry r~ r-s CO K) ^'CHEMICAL^JiVlSiON LAKE CHARLES, IOULSIANA --j---------L--A--B- ORATORY OPERATIONS REPORT JAN FEB | MAR APR MAY JUNE JULY AUG SEP 98.52 (0.01 0 U.69 0 0 0 0 (0.01 0.02 u.y4 ! i 98.76 1 98.02 0.01 0.02 0______ 0.01 0.67 i0.80 0 [0.04 0 10.39 0 0.12 00 (0.01 (0.01 0.03 0.01 0.78 0.60 (190 0.46 3.31 1.275 (187 0.43 2.26 1.272 (159 0.37 1.09 1.263 f 97.62 98.01 1 97.30 98.84 96.50 96,72 0.04 j 0.06 j 0.0? 0.01 0.05 0.04 0.02 ! (n ni 0.01 0.01 0.07 0.02 1.21 ! f:sr 1.68 0.43 1.48 2.01 0.04 } 0.04 0,65 | 0.35 0.0? ! 0.04 0 0 j1 0 0 i 0.01 0*3> j 0.26 0.03 0.01 0.47 C35 0.05 i0.13 1.11 0.58 0.14 0T08 0.18 0.03 00 0------------ 0 (0.01 0.01 0 0.01 0.01 (OT-- 0.02 0.01 0*34 tas-- 'DOT- 0.38 t 1 j (280 [ (249 0.66 i 0.57 1.37 ! 0.47 1.272 1 -------------- 1-------------1I--------------- (273 ny>jnFtl 0.98 (248 0.57 1.39 1.272 7278 0.65 1.76 1.277 (226 n.5? 1 .34 1.276 . ' i 1 * OCT NOV 0 lC 11971 ! Avr, . t 1 \ J <t 4 97.67 96.64 96.07 ! 97.56 J (0-.01 0.04 0.05 1 0.03 J 0.01 0.04 (0.01 ! 0.02 ! 1.33 1.87 0.01 0.16 2.20 1 1.30 \ 0.23 0,06 | 0.66 13750 0.88 0.51 ! 0.12 O.26 0.28 10,11 j 0 0 10 f0 j (0.01 0.02' 0.04 |(0.01 | 0.01 (.01 (UTUr'jSTGI 1 0.14 0.23 0.21 10,41 ! i] 1! (233 "TOT 0.54 0.55 1.39 1.83 1.274 1.278 (244 0.56 3.95 1.302 1 1; (7234 | !o,55 : 11776 } 1.276 i --^ ii * i .. ..... ^ i ii 1 ii |, j! 1i * 11 j1 j !i 1I -------------- 1t!---- --------1 _______ L______ CON] 1DENT AL: Subit ;ct to Prote :ti ve )rder c if 14 tl Judi :ia 1 D ls trie : Cour p No 91-1 .45 j 1 rG R 1.1 i.. <-u. i EDC J STILL BOTTOMS #1 | LlMVUDC Dichloride 1 Tr, i i:ttLoar>F in vttrj r 1 Pi" RCHLOROE HIYLENE ! 1.1.2 Tr 1 OIL OHOC THANE 11 Tr. 1 R.'. till OR ETHANE ! $- Tt 7rACi:LO!^>C TH ANt j Pi N EACH LOROE THAN E 1 Ur xaciilorpe thane | lthylehe Chlorobrou i tic ! E ihye Chloride | UN 1 OENTI F 1 ED i 1970 Avg . JAN WT% 52.18 44.77 o.oe 0.10 0.09 0 40.20 43.24 1.14 1.76 4.93 8.07 0.17' 0.08 u0 0.43 0.51 0 0.73 0.68 t r v> ') 1> ! k it- j PE3 41.67 0.16 (0,01 43.33 1.93 11.55 0.01 0 0.04 0 0.95 CHEMICAL PIVISiON LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT MAR i APR i MAY JUNE JULY AUG 66.60 38.10 135.77 40.13 46.41 43.57 0.09 T0 0 1 0 0 0 0 0 0.16 I 0.04 0-0*5 0.0*5 36.98 45.04 52.51 44.63 41.83 46.79 t .72 1.76 0.57 0.50 0.48 0.25 6.84 72795" 13.43 9.25 8.49 0.03 0 0.40 0 TOT "0 U.5U o 0705 0.12 o 0----------------- 0.47 0 0.35 0 0.07 0.04 00 0.69 0.32 c.oi....... TM 0.53 --~KT7 0.58 0.77" 1.22" 0.47 SEP OCT 45.35 33.35 00 O.OZl 0.18 39.84 5 5.62 0.25 0 12; 35 8.64 10.09 0.16 10 0 0.32 0.60 o 0----------------i:7T' 1.14 ~r97r"| NOV 0EC __ Avg. j 11 53.66 46.32 (44.64 0 0.16 10.04 0.96 10.04 10.13 41.26 {39.30 j44.20 (0.01 0.02 10.77 3.57 13.11 [8.92 6.04 0.07 !0.09 00 !0 0.18 0.45 0.43. o in (0.01 0.26 0.53 0.84 J I f H,0 1 Fr | hcl Sj pecific Gravity 1 i----------------------- i ----- G0-60F ----- - - PPM ppm ppm 31 37.7 1017 1.335 30 18.9 826 1.360 31 26.8 750 .1.362 19 13.1 461 1.334 16 126 50.3 b.3 2059 1948 1.379 1.365 42 59 42.1 37.7 1928 1312 1.382 1.358 65-------- 26 86.8 76.4 1 Pl 7 880 1.362 1.354 45 39.1 1588 1.381 25 13.4 1044 1.328 . 57 63387.5 * 37 (141022.51 1.354 U.360 I1 i i \ i j l 1___ CO r- CD UJ co 1- - i (TON I 7 JTRMV AT. . * l 1| --.--------------------------------- 1| Suhip rt to Frntpi t 4 wo 1 o f 14th Judi r i'a 1 n p.Lri r> No. 91-1J 45 . .... I- UK i.i EDC STILL POT TOMS"^2 Ethylfne Diciiloride Tr 1 CIILOROE THYLENE r E RCHLOROC THYLENE 1.1.2 Till CHLOROE THANE U-TeTRACHLORETHANE S-Te TRACKED ROC THANE rcnTACMLOROC THANE He xachloroe thane deEthyi.ene Chlorooromi Ethyl Chloride Un r OENTI TIED Pr a J $ IKI 5 1 CHEMICAL DIVISION IAKE CHARLES, LOUISIANA LABORATORY OPERATIONS RKPORT 1970 JAN FEO MAR APR MAY JUNE JULY AU6 5GP Avg. W1% 40.61 24.16 21.41 24.23 28.64 19.62 16.34 16.63 0.14 0.47 0.13 oa2__ 0 7)-------- 0 10 0.38 0 1.14 1,03 0.43 0o60 0.25 in 1? 43.57 10.43 00 0.05 47.94 56.36 1.23 3.12 7.84 13.63 73720'" 0.14 u0 0,2l 0.47 U0 TJ793 1.15 56.51 51*15- 56.13 71.01 71.62 66*55- 46.79 73a9 1.35 3.20 1.62 i.16 0.71 0.6.2__ 0.25 0.48 13.81 13,10 fb.11" 7>.f0~ 9.14 14.67 8.49 U:47 0.04 1.69 0.22 0.32 0.41 0.35 0.04 J -?6 n0 73------- 0 00 0n 0*23__ 0.25 00 0.35 0.30 0.25 0.23 7) if-------- 0 0 0.32 0.25 "flOTT 0 0.89 1.12 0.82 U751-- TO5~ 0.39 T74T~ 1.43 -- 1 tiro\ OO 1971 OCT NOV DEC AvG. 27.29 0 0.44 58.53 0.00 10.84 0.38 0 1.19 23.80 io7i7 ~:ds*L 0 _0*6J-_ QJJ__ 0.38 1*34-- _G*27_-- 62.23 68.10 62.18 0.00 1.15 1.14 10.90 jo,74, 11.08 1 .04 00 0.87 0 0.20 0.42 0.30 O-------- 0 (0.01 0.62 "0795" 0.05" HjO Fe HCL Specific Gravity 60-60F ppm ppm ppm 22____ 2? 70.28 69.62 840 950 1,367 1.400 31 53.68 317 1.400 15 20 43775" 44.96 TT57 2337 1.404 1.395 15 47.00 1 -413 13 25 38.39 30.47 2290 2331 1.415 1.420 35 23 473.94 5757 1460- 2372 1.435 1.433 39 34*7Q. 1564 1.430 69 33 29 33705 "1757 1.366 230.06 J96*-502349-- 18^3 1*450. 1.413- CO 1-- ------------- CO "O Ja. , * r v*k fin L J L/ IiZ?r LM4 'JiL t ar --Ourr] 7 C Tl ' T- fJ J. "1 V- - 3-14 ^i \ r Mr -* Q 1 - 14 5 t- Pnii t* FORM N A <dO <!-/ . "1R1 - ETHANE' ice REAC 10R i. TflVL CHLOnt DC WT . % To';' 1.? Dt f-MI rinfir THYLCNE Cit 1.2 Diou.onorTHYi.iNE Me 111 YL LOBOECPM 1.2 Pt CIUOROE THANE In 1 ClllOiJOr THYI.EN r 1 , ! . 2 Til 1 CliLOPOC THANE :U . T E T H A r M L 0 FTO E T H A N r_ j STerbachlorocthant ft N TACHt.OnO ETHANE 1970 Avg- JAN (0.01 (0.01 0. 0 (nrm (0.01 n0 70.96 78.48 (0.01 (0.01 25.75 19.97 1.02 0752 1.22 0.66 0.06 0.02 H,0 PPM S6 - Fr PPM 1 2 'heavies still reelux wt.% Iwaus 1.2 D i c*a.Ofot TtfYLCue 1 Cl S 1.2 OU-HLOnOC THYU NE 1 1 . ? Ol CHLOKOE THANT j THICHLOnOETHYLi'NC 1 1 - ljpoMo-2-Cucnnor thane ! I . 1 .2 1P1CHLOHOt THANE !J- Tethachl oho ethane 0 0 (0.01 0.04 (0.01 99.84 0.09 3 b (0.01 (0.01 0 99.94 0.02 FEB PpL^ i 5! i\l LS CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY i AUO j SEP OCT NOV DEC (1971 ! (Avg. J 00 00 (0.01 to.01 00 72.50 63.38 (0.01 (0.01 25.03 32.47 1.22 1.7ft 1.29 2.02 0.05 0.11 P\ S| CM (0.01 0 rn.m 0; 51.85 (0.01 34.92 2.55 0.22 0 0 (0.01 0 73.22 ! (1 28.31 1.44 '0707" (0.01 0 (0.01 0 73.84 (0.01 23.95 0.87 0.91 0.02 (0.01 (0.01 0 0 (0.01 0 (0.01 (0.01 XQ^Q1_ 0 0.02 0 75.44 82.01 66.05 0 0 0.01 22.08 34.46 30.09 0.72 O^g 1.58 0.82 l.Ul 1.37 0707 " U70J-- oTog 00 0 (0.01 0 (0 0 n 00 Cd.01-- (0,01 00 61.07 72.26 70.43_ 70.71 (0.011 0 (0i01_ (0.01 34.20 26,88 26,27 20.22 2.05 1.14 1.30 2.41 1.30 1.50 0.12 TJ705---- 0.07 '1.30 11.48 10.08 - 86 - 72 44 40 0 76 00 22 3 2 2 (1 3 12 2 1 ) 0 I 35 1 13 ( 00 00 0 0 '(o.oi 0 0 TF7T52 0.01 (0.01 0.01 O.05 0.33 0.12 00 00 99.89 QQ.78 ~W7W 99.72 0.05 0.14 0.09 0.03 0 0 0.01 0.02 0 99.82 0.09 0 0 (0.01 0.01 0 99.59 0.09 0 0 0.02 0.01 0 99.69 0.19 0 0 0715 0.04 n Qft-53 0.54 1 0 0 0 0.01 00 00 0----------- 0 tOTUI (0.01 00 0 99.16 99.53 (0.01 0.20 (0.01 So 0 (0.01 0.05 0 qg.sft 0.12 H.O PPM lIQ_____ -- -- 66 . -- Fr. ppm 1 3 30 (1 (1 3t --.... LIGHT iV ^ ft ] .------------------ - .. - still reflux PPM 135 1 l l ij oi SL pUl1ion1/co 1 i _ .3 3 3 - 2 n (i (1 ' ~67-------- 70 ~2---------- 3 -tl---------- - 84 42 2 3 T, 48 4 * 47 5---------- 4 38 30 - 60 19 1 Tl------ 11 4 --COI F rt*rrW T m. * --Srrtrj of i+t errt fcc h Jtro i t rtvv' .-C;loA1 ' iI lfcl-ri Order '.t Cou bt -------- 04 UL5 1 "TR 1 .ETHANE" AViFS STII.I. eeeo ,1.2 Till C MLOPOE THANE . ! r T r? /. '-fIL ^ F0 r TM AN T - Tr Tf! ACHLOGOC T.l ANt i :*TftCia'Ol,OF.TMAMe r, K fJ OWN 1970 AVG. JAN wt% 90.26 94.23 J7Z8 2.61 4. l6 3.09 0.20 0.05 00 VDC REFLUX WT. % 1 il VI. Olton 1 DE r.vi_ Cm LOR i DC r.VL i OLME Cmlom I 0 ms. i .2 DlCMLOrtOElKYLENE 3 1.2-OirMLnROCTHYLENE 7-0lluloroctmane ICHLOnOCTMYLtNI 0 0 99.1)4 0.12 0.07 (0.01 0.04 0 0 99. S3 0.03 0 0 0 CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1971 . Avn. 91.93 90.53 3- 61 4.61 A-2S 5.58. 0.17 0.37 00 00 00 99.81 99.77 0.04 0.03 (0.01 0 00 00 87.35 91.48 4.29 4.03 6.68 1 4.33 1.47 j 0.14 0 |0 ! 92.81 93.07 3.23 3.27 3.83 3.57 0.10 0.08 00 ! i o [o 00 00 0 O' 99.73 99.77 99.78 "0.06 0.03 0.03 P.01 (0.01 fTo.oi 0 0.01 (0.01 (0.01 0 0 roTon 0.01 u-------- (U.U1 93.27 3.07 3.56 0.10 0 tJ3.46 5.38 0.23 0 88.25' 93.06 5.18 2.98 6.25 3.84 0.32 0.11 00 92.42 2.85 3.35 0.15 0 90.99 3.76 0.27 0 0u 00 00 o---------- 0 0 T5--------- 0 0 199.66 99.83 99.68 '99.57 99757" 99:72" 0.02 0.01 0.05 0.14 0716" 0.05 0D D---------- (0.01 0 "o-------- is---- ho-------- 0 0 XQ.Q1_ fn.m P---------- 3--------- ~o-------- 0 O XD^H_ ,0 PPM 12_____ - ---- mm _ 'ME PTM 71 177 JLS5 140 173 136 201 1160 190 203 197 205 176 7 'J tr VDC PRODUCT PPM |35 J 9L6 11 ia____ 291 275 23 241 19 20 y 239 i~205 19 243 &3- 318 23 875 32 256 25 i9 . 20 21 271 "255 255 270 * 1 -- SL 013176 -------- ct 'NFIDEl IT! ALT - " out ftp 1 A jecfe--( rfl--dU( 0 Prul ieial- .tiut ivi Distl ; Orde TYtT CO trt------- ^--yr 1115-- FORM U M ' TR1-ETHANE" E.'r R|`ACTOR WT. % Cth> t_ Oil on p or v r ;.m i rv:i: OJtm t pf 7''ant 1 . ?. -iT l rut o n o L Tipyi. cnc I . 1 -Pi CHLnrioc tpianc C i 1 . T-Dl rnL(inoi:THYLENE f "r Tiiyl Chloroform 1 . ? .()! CMLO'iOr THANE Tr i rut prof rifY*.rrjr 1 .1 .?. -Tn 1 Ciaor.OETPIAUE " U-TC TTU'CllLOROC TMAMt ' F'ENTACIILOPOE T'lANC ' tjHKMOWN it \ \ H>0 : re PPM fpm i 1970 Avg. JAN 0.07 0.01 8.31 8.75 2.]*: 0.08 (0.01 0 0.05 0 88.9k 90.61 00 0.02 (0.01 0.22 0.32 0.07 0.03 0.06 (0.01 0.07 0.11 173 465 275 FED I . . t. J I i\ i L. j chemical Division LAKE CHARLES, LOUISIANA laboratory operations report MAR !j APR 1 j MAY JUNE JULY AUG. SEP OCT NOV DEC I\ (0.01 0.01 7.30 4.94 0.16 b.n 0P 0 (0,01 92.09 94.52 00 (O.Oli0701 0.30 0.22 0.04 10.13 00 0.06 0.Q3 _ 296 412 i, ! 1(0.01 i(0.01 3.81 6.72 nna lO-Rl o io (0.01 io 95.78 192.49 0 10 0.02 10.02 0.11 0.16 0.13 0.05 (Q.01 (0.01 .0.02 |(0.01 i11 - h 731 J2B (0.01 0.61 0 0 92.45 0 0 0.21 0.01 (0.01 (0.01 _ 445 1( (0.01 1(0.01 (0.01 0.01 5759 k.oo 4.73 4.75 0.63 b.31 0.41 o.iq ob 0 0 ob 00 93.45 93.51 94.55 94.45 0--------- 3 o--------- 0.01 o--------- 3 b--------- 0 tare-- 5715 0.23 0.26 (0.01 3---------- 0.03 taoi fn.m 3---------- 0 (O.Ol fo.m 3.11 0 ^0.01 278 T32-- 690 410 j ( U.01 (0.01 (0.01 6.16 i 4.64 5.68 0.46 0.18 0.32 00 0 (0.01 93.06 0 0 94,97 0 (o.oi 93.49 0 0 0 (0.01 0.24 0.18 0.21 0.02 0 i0.04 0 0 (0.01 0 0 0.03 *0 465 0 ! 397 ! TOpP1 NO FT 1LL PRODUCT WT % i V 1 *JY L 1 D F. Mt CWtOfiJDC i t1 Tn AVI, 1 ,1 - Ti i 1 .2-n 1 r.ltLOfiOi: THYI.ENE ni Lonor thane C 1 S ! ,2 O1 CHI OROE THYLENE Hr TPIYL CHLOROFORM 1 ,2-DiriPLOBOCTiPAuE J Tip 1 CPPLOftor THYLEHC X; ,1 1 J EPE 1 CHI.OflCF TMAPiE 1 0.01 0.06 (0.01 0.04 99.80 0.02 0.02 0.05 0 0.01 0.02 0 0 99.93 (0.01 (0.01 0.03 0 \ i 1 j___ { w 13177 i 0.02 P01 (0.01 3.02 0p 0 (0.01 99.94 199.88 0.01 o.ni (0.01 3,02 0.01 3-0h 0. 3 0.01 (0.01 0.02 lO.OI 0 !0 (0.01 1(0.01 98.76 j99.93 0.02 1(0.01 0.02 0.02 0,05 0.03 00 (0.01 3.02 3 (0.01 30.0*; p 3T02 fo.m 3 (0.01 (0.01 3 (0.01 *99.97 (0.01 (0.01 3.01 3 0.01 0.01 0.01 0.01 (0.01 n.m 0 0.01 0 (0.01 o--------- (0.01 99.95 99.95 99.85 ,o.oi 0.01 0.04 0.01 '(0.01 (0.01 5701 0.01 "0----------- 0 0.03 0 (0.01 0.03 0.06 0.07 00 TOTcrr (o.oi fWTHT 99.84 0702 0.01 (0.01 0.05 0.04 0.04 00 0.01 0.02 0 (0.01 99.82 0.01 0.01 0.03 0 , CON '1DENT r Ali: Subi< ict to Prote :t. i ve 3rder i cff 1 4 tl Judi :ia 1 D Lstr ic t Cour t i No 91-1 .45 FORM N riJo If s S l i< i b i> CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT 'TRI- ETHANE' IM'E 324 STABILIZATION WT. % VINLYIDEttE ClILflll 1 OE PLM MTE 1 ,1 ,Dl nm.oiini: thane Ml TMYL ClILOHOFOHM noL Cl" 1 ,7.'OlO(t.OHOETIIYLENC In i rm.nnor thylCNi: 1 . 2 - Dl CHLOBOETHANE 1 |1L Mm: Cl T 11(11.THAHE 2-Hi iboi'hopane TLC 1 ,1 , 2i Tn i aiLonoc tiiane EPE 1970 A V6 1 JAN FEB MAR APR MAY JUNE JULY AUG SEP 0.02 0.30 0.78 0 93.96 1.06 0.03 0.03 0.02 0.02 0.36 _ 0,76.. 0 94.14 1.06 (0,01 0.01 (0.01 0,76 0.74 2.05 _ 2.01 0.05 0.06 00 0.83 0.06 0 0.79 0.03 0 0.02 0.01 0.34 0.32 0.01 (0.01 0.01 0.36 ~u:w 0.39 (0.01 0.33 (0.01 0.36 3.01 0.7Zi 0.73 00 0.42 D 0.71 0 0.72 0.70 00 Q.JZ1____ 3.74 0D 94.13 1.08 0 94.14 94.20 94.24 TyCer^ i .03 7702" (0.01 TC70T~ lO.UT 94.24 94.36 1.03 1.01 0 (0.01 94.23 1.03 0 74.09 1.03 3 0.01 0.02 0.03 0.01 0.01 To7oT~ (0.01 3.01 0.01 0.02 0.03 (0.01 0 0 (0.01 (0.C1 0.75 2.01 0.80 2.00 0.75 1.61 0.78 1.91 0.78 CJ775-- 0.75.... 3.79 1.91 3729-- 2701-- P.10 0.06 0 0.83 o.ol 0 0.06 0 0.78 0.04 0 0.07 0 "D.9T u.u4 "U--~ 0.06 0 0.78 0.04 0 0.05 0.20 00 0.81 0.63 U,U2 0.04 TT-------- 0 0705 0 0.82 0.01 0 i.n6 3 3.75 p.02 3 OCT NOV OEC 1971 Avg . 0.01 0.01 0.01 0.36 0.38 0.41 0.70 0 0.69 0 0.77 0 93.48 1.02 0 93.90 1 .05 0 93,36 1.11 (0.01 0.02 0701' ~ 0.01' 0.06 ~ 0.04 0-02 0.88 2.34 0.82 27T6 0-85 2-10 0.05 0 0.05 0 1.07 " 7JTB3 0.05 0.U6 0.06 0 0.91 0.07 0U 0 0.01 0-36 0.70 0 94-04 1.05 (0.01 0,,01 0.02 5*79____ 2.04 0-07 0 0.83 0.04 0 STABILIZING TANKS M(iiSTunr ppm pH hcl. Aciditr Non-Volatile Residue ppm % COL on hr LCIFIC GRAVITY APHA AVfi. Oil TILLATION RANGE C SOLUrtl.E Cmcobiocs At . SntA Ten Low High PPM --- Si. 0Aji3. 178 63 54 31 46 47 47 -7..0____ 6*2_____ 6.9 6.7 .6.6 ii_____ (1 (1 (1 2 .0001 .0001 (.0001 ".TOT r'.booi 77 7 1----------- ? , .6.7 3 7(OT 10 1.304 1.303 1.303 1.302 1.-303 1.303 73.5 82.8 (0.5 25 73.6 33.2 (0.5 - 73.8 84.3 (0.5 - 73.5 84.1 (0.5 - 74.2 'BJ.TT '(0.5 -- 73.4 84.8 (0.5 31 47 58 60 6.8 6.8 6.9 6.9 2a 1 (1 .0001 (;oooi (.0001 .0002 8 5------------ z------------ 6 1.303 373m~ I.3O3 1.303 73 7.0 ~d .0002 7 1.304 too-- 102 6.8 6.8 12 .0004 -0002 15 7 t .304" 1.303 ^8 6.8 1 .0001 8 3.303 73,4 ti3.fi (0.5 - 73.2 |R2-6 (O.S 7375 73*6 83.9"' 30.6 (0.5 W5 _ 73.5 84.0 (0.5 - 73.5 73.4 TT377T" 84-0 (0.5 (0.5 -- 73-5 83.5 (0.5 * r+vr\v%r. c*i npu'i 1 t hr. "UtlD j C t" 'tL OE H* Ati- pL i vu Ordpr il eFrii Com ^t_ . .. 01 - 145 J__________ _ FORM In 1 202.U, iVu 16 j i i< I i: J CHEMICAL DIVISIOM LAKE CHARLES, LOUISIANA LABORATORY OPEFM7 1 ONS REPORT SODIUM CHLORATE TJ.I LIQUOR FEED GPL l.'f Cl. a pCnpQj N */'<> 4 CA Cl M3 as CaO COOLING TOWER 5^ -o JAN FED 566 128 1.9 6.05 0.008 591 573.. 128 121 1.5 1.5 4.21 4.66 0.026 0.023 MAR 580 124 1.6 5.60 0.034 APR j MAY JUNE JULY i ! 590 586 127 121 1.9 2.0 586 567 125 125 1.6 1.8 5.12 3.68 i 6.76 1.87 0.030 0.025 0.020 10.008 AUG SEP 575 127 1 08 0.31 0.034 ^79 125 1.5 2.32 0.010 OCT 563 125 1.6 3.47 0.034 NOV OEC 1 1971 \ avg, i 552 129 1 .S 2.82 0.046 604 579 | 126 126 ! 1 r4 3.63 13..662 11 0.028 0.026 i 1 ------------ 1 IH Ch1',) lO.CL GlO*. FO.j -- 6.5 ppm 27 TPM 1174 --- -------- - PPM 151 PPM 11 6.0 7.3 27 38 668 9?/, .90 il6 98 8.7 7 1102 124 3 8.4 b:v 12 "TO----- 1260 2277 "138' 734 - ------ -~z------- 8.8 7 1109 109 3 877 7.6 74 951------ 990 U7------ 123 54 8.1 12 2079 103 6 8.8 (1 1089 77 3 9.0 9.0 8.3 - (1 9 "743 627 1152 "55~ 43 102 5 6---- -- 5 | ! | 1 ! ! yell v/ater ppm ;1 1 f r if 7i 308 "270 313 333 297 377 "382 " r9i------ 276------ 153 381 162 282 28 s i sio? iJS___ 47 55 47 48 ' 42 43 42 w-- 37 37 Y7 22 50 PRODUCT N/iCtO-, % KaCL % U.\rCt-?07 % i.n-SO,. % Ft % Pnsiour '.VATra Ins, " moisture * % Hulk Dr..JSirr /VCu.ft. 99.96 0.05 .0005 0.001 .00005 0.001 0.05 78 ! i 99.96 99.97 99.97 99.981 99.96 99.97 99.97 99.94 99.96 99.95 99.96 99.96 j 99.96 0.05 0.03 0.03 0.03 1 0.03 0.03 3.03 0.06 0.04 0,05 0.04 0.05 I 0J05 .0005 .0003 Toobs .00041 .0004 .00019 i,00058 .00076 .00071 .00105 .00052 .00055! .00052 O.OGl! (O.OOlj (n.ooi (O.OoP (O.O0T (0.001 (0.001 (0.001 (0.001 (0.001 0.001 _ jlcuQcaJ .00001 .00009 .00004 .00010 .00008 .00007 .00004 .00002 .00005 ,00002 (.00001 kOOOO/t ] 0. U01| 0.001 0.001 3*001 (0.001 (0.001 (0.001 (0.001 (0.001 (0.001 (o.ooi (0.001 (0.001 0.05 10.05 0.08 3,05 0.07 0.08 p^5 0.06 0.07 0.05 0.05 0.08 0.06 77 78 81 80 80 79 81 80 81 79 80 82 80 * S1 EVE ANALYSIS % Larger than screen size mcsh 20 50.2 40 85 .A.. 100 JL*2__ 41.2 87.7 98.6 48.5 94.4 99.3 36.3 83.9 98.4 42.8 32 .'8.... 43.0 ~8'9.3 877 sr- 90,0 -w?r 98.8' 98.7 57.8 96.6 99.7 39.2 80.9 95-9 24.6 86 T 6 98.1 4 32.1 80.2 98.1 28.7 88.8 98.8 23.2 90.0 98.7 37.5 88.0 98.5 nS.L nU11*J31I7/Qy u^roen lest Li. S. Standard CON FIDEN'i 1AL: Sub 7 2Ct tO Prote cti ve Order of 141 i Judi cia 1 f istric i Coui t Nq . 911 TT5----- I ( Ij V luO HEAVIES STILL BOTTOMS Ti: i rpi<. rv r>ri tmyi ru r 1 . 1 . ?T PM CMLOnol. Ill AH C Pr rjcin.nnor THYI.mt U- Tr ip* r>i. nr nr tm ane S-l c TUfcC'lLOnor. TM AH E r rti 1 .\CI!t-OBOET!!AftC He YACHLOROt TKAtir. 7* % % " % % % t-i E A VY UlJKfWrtS % ' ^ It Kith ' CHEMICAL DIVISION LAKE CHARTS, LOUISIANA LABORATORY OPERATIONS REPORT 1970 Avg . fo.01 (0.01 25.95 1.79 12.51 22.84 1.71 JAN 0.01 (0.01 24.15 2.05 38.37 19.52 1.34 3.34 " 4.79 ' FEB 0.02 (0.01 39.16 1.48 24.13 19.57 1.00 2.78 MAR 0.01 (0.01 49.73 1.35 22.58 15.27 0.93 2.14 APR MAY JUNE JULY 0.01 ;(o.oi 0.02 0.02 0.01 f 0.02 0.01 (0.01 "597391 46.77 36.22 34.88 1.42 j 1.46 1.33 1.62 23-961 28.84 39.15 40.28 14.93111.44-13.85 113.15 1.35 13.83 1 1.00 Hof l 2.23 i 1.71 1.54 1.65 rF.Cl? '-(('l . VOLAT 1 LE PPM 13.6 % 0.98 9.8 18.9 6.3 1.68 (0.01 1.24 8.4 7.4 7.6 19.2 (1.00 (1.00 1.10 0.59 AUG SEP OCT NOV DEC 0.11 (0.01 0.02 0.03 24.25 27.35 2.37 1.98 49.27 43.30 13.97 15.31 1.13 1.24 0.01 (0.01 (0.01 (o.oi 35.52 2,90 34.82 16.54 43'. 957 3.90 26.75 14.12 1-18 T7J7 2.44 2.98 |ptT16 ~Z7U5~ _ -- - -- 1971 \ Avg. ^ 0.02 t 0.01 \ yr&r] T79V! 33.77 \ 15.24 ; r.4o~"s 2.40 1372 39.7 114,1 0."65 i .75 1.42 12.2 0.88 14.3 0.94 ! . SL n\3^8 010 I .; | , : |: -- --------------( .Uffl11 D lINTl iMj -----------m b TAViTi /c'uru 5 r " or j ^ l?n U 1 idieia ilLSt L 1 (r V w q 1 U(i FORM N A 202-14 perchlor stabilization 1 Vt i, 208 WT. % f1 r n TIM. rtftiH. TIIYL f Ml' ' 1 . 1 - D I cmi on ii dm or. tiulcne \ ,7,- Ph:iii. jhhhhoMi'i. liiylene K1,,2* Tfl I CHLOHOCTHANC j i;-: fr rFiAciaonncTiiAriE 1 rpc \ i \ 1970 Avg. JAN FEB PPO i i R115 CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT WAR APR j WAY JUNE JULY AUG SEP OCT NOV 99.8; (0.01 0.01 (0.01 0.05 0.04 99.87 (O.ol O.ol (0.01 0.05 0.05 99.86 (0.01 o.m (0.01 0.06 0.05 99.86 (o.ot (0.01 0.01 0.07 0.04 99.86 (0.01 0.01 0.02 0*06 0.04 WISE- 99.88 99.85 (0.01 (0.01 (0.01 0.01 0.01 (0.01 0.02 (0.01 0.02 0.06 0.05 0.07 0.0L 0.05 0.04 99.86 (0.01 n,m (o.m 0.06 3.05 99.88 99.86 (o.oi (0.01 flofil-.- Q.Q1 (0.01 0.01 0.05 0.06 0.05 0.04 99.85 (0.01 o.ol 0.02 0.06 0.04 OEC 1971 ; Avg . r ! -- _?2,.86 | -Xua_i (naoi 0,01 jQ.Q.6__ 0.04 1 TVPL 207 WT % ^ Pf ririfi. or, or 7 in i. rw i. 99.80 99.81 1,1- IN cm. ntioiiHOMor tmylene (0.01 0 l . 3-01 I'm o ho nitom ethylene 00 1 .1 . ?-T;: r r.ui.onoE tiiane (0.01 0.01 11 - L 1.1 n A r.nt-n n n r l n A n E 0.05 . 0.05 EPF 0.04 0.04 99.7fl - o.m 0 -- -- (0.01 0.06 -- -- 0.05 -- 99.81 0 0 0.02 0.02 0.05 M -- -- -- ~ 99.83 0 0 0 0.04 0.05 99.76 0 0 (0.01 0.06 0.08 99.81 3 3.01 (0.01 3.05 3.04 -- - - 99.77 (.01 T7oT~ 0.01 0.07 0.05 -- . -- -- -- -- - 99.80 (0.01 0 (0.01 0.05 0.05 ; I , .... !___ SL 013181 t1 i --------------------------- ---------------------------- 1 ff 1 Sub} of 141 1 ____________________ COt! ect t c h 3ud Nl FI DENI PioD t. i a .1 1 1 At,: ct i ve Oi tier lisTTlihrt--Cij u Ft---- f- l- f'OSM NO * 202 - '1 5 trjchlor stabilization 1970 AVG. JAN FEB IYPL lib R.M THF Ca R RRN Tr TflACHLOfM LIE ADH NE'E TR i r.HLOROLTHYLENE Ff t>r 1.1.0 ROC THYLENE 1 . 1 . 2-TR 1 OILtmOFTIiANE GDI. LuincsTifieo, Total WT.% -- fo.oi 0.C3 (0.01 99.47 (0.01 ToToT 0 (0.01 _ 0 0.03 0 0.02 00 99.51 99.54 00 (0.01 0.01 00 00 .PPG inRsiries CHEMICAL DIVISION LAKE CHARLES. LOUISIANA L'.BGRATCRY OPIRATIOPS REPORT WAR APR WAY i [ JUNE 1 JULY AU& -- -- -. - -- - -- -_ -- am 0.01 0*03 _ (0.011 _ 99.54 _ 0 0,01 (o;oi -- _ -- - -- -- -- (Q.Q1- - 99.55 99.11 - (0.01 -- ~ 0.01 0.01 - (0.01 - SEP OCT -- (0.01 0.04 !(o.oi ,(0.01 0.04 99.45 (0,01 0.01 0.03 99.42 0 0.02 -- 0 NOV -- -- - - DEC _ _ -- 1971 j AVG.` - [ .6 J 1 ! | (0.01 0.03 iO.Ql_ 99.45 (0.01 ,.0^01- 0 (0.01 TYPE 122 TUT CAlflON TE TRACMLOHIOC r:y\{ NPL T 1' 1 CilLCROt 1UVLENE PerciiLORoethylene L 1,Z-Tn(CHLOROCTKAKE GDI. Um i dentifieo. Total WT. % -- (0.01 0.03 0.14 99.49 (0.01 0.01 0,06 (0.01 ---- - (0.01 (0.01 0.03 0.03 0.14 0.12 99.42. 99-*53 (0.01 (n m (o.oi! 6.6i" 0.06 n.n? (O.Ul j[0J2F -- ---. (0.01 (0.01 (0.01 (0.01 -- (0.01 0,03 0.03 0.03 0.08 0.03 0.14 0.19 0.13 0.13 0.13 99.49 99.49 oq.46 99.47 99.49 (0,01 (0,01 (0.01 Toll (0.01 0.02 0.06 0.02 |0.03 0.0510.06 0.02 0.03 0.66~ ojo6 (0.01 (Oioi Ko.or (0.01 (0.01 i i \ t i j (0.01 0.02 0.13 99.48 (0.01 0.02 0.06 (0.01 (0.01 0.03 0.13 99.49 (0.01 0.03 0.07 (0.01 _ (0.01 0.03 0.12 99.49 (0.01 0.03 0.06 (0.01 (0.01 - 0.03 -- 0.14 99.58 (o.oi" -- -- o.oi -- - (0.01 -- _-- -! (0,01 0.03 i 0.13 99.49 (0.01 0,02 0.06 (o.oF j ' 1 SL 0/3/g2 i i I i i -1.1 COMF1 TENT1A r.* i fub-Jec * ^ Q p rotecl itfg Or of 14th i ludici al Pis trict Court No. 91-114 5 FORM f 5A 202-16 PPG 1 oS i Kits CHEMICAL OIVtSlON IAKE OtAHlES, LOUISIANA IABC.RATGRY CPYG/riCYS REPORT 1970 TRICULCiR STAG JL I2AT ION AVG. JAN FES WAR APR M AY JUNE JULY t iype i lot i ii.r ; .'nr.-niv Tetraciilorioc l A OH i NPL J 7 M OiLOKOCTHYLCNT j PC RCHLOROr TH YLCNE ; 1 . 1 . 2- Tn1CHLOROC THANE f GDI j L"J 1 OENTI f 1 CD .1 TOTAL t i l i 1 TYPE 113 | PLM {I 7 KF I CARDIN TETnACHLORI DC \ ADM ! f.PL ) ini >:iilohocthyli:nc PCRCHLOnOETHYLCNC j 1.1.2-TR1CHLOROETHANE j GDI Unipentifieo. Total i i i ... i wt.. % (n.m 6.06 0.28 99.09 (0.01 0.02 0.15 (0.01 - - -- -- - \_ nrm 0.06 0.23 99.11 0 (n.m 0.08 (0.01 - 10.Q1 0.06 0.28 99.00 0 0*02 0,10 (0.01 - WT. % -- - - (0.01 (0.01 00 "(0,01 0 99.9S 99.98 (0.01 0 (0.01 0.01 00 (0.01 (0.01 -- -- 0.01 0 0 9998 0 0.01 0 0 - (0,01 0 0 99.98 (0.01 0.02 0 0 (0.01 0 0 99.97 (0.01 0.01 0 (0.01 1 r- _ (0.01 n,n? - 0.06 n"o6 j.0.28 0.2/t 98.94 1 99.06 0 mm 10.02 0.01 -- lo.io 0.13 -- [0.01 0.01 ( \ -- - --* - - (0.01 (0.01 - 00 -- 00 -- 99.98 99.98 --0 - (5701 0.01 --T 0 0mm- (d.oi mm AUG SEP ! OCT NOV --- - (0.01 (OrOI 0.06 0.06 0.30 0.32 99oQ8 99.02 0 (0.01 0.O1 0.02 0.21 0.13 (0.01 (0.01 - (0.01 (0.01 0.05 0.06 0.29 o.33 98.86 98.54 00 0.02 "07731 0.15 - (0.01 T07ur -- (0.01 (0.01 0n 0n 99.97 99.97 0 (0.01 0.02 0.01 0~0------------(o.ol (0.01 .. ---- (0.01 0 0 (0.01 U.02 0 99.96 (o!oi 0.01 99.96 (0.01 U.01 0o-------------- (0.01 (o.ot I OEC * -- -- - ~ -- - mm --, _ m. 1 1 1971 AVG. | | -- mm (0.01 0.06 0.28 90,95 (o.oi '! 0.01 0.13 (0.01 1 ** (0.01 0 0 99.97 1QJ21_| 0.01 0 (0,01 * \ < Sf. 0/]1<3. 183 i i ........ ----------------1 cJL rnir? THENT AL: f~* t* O Protei :tive 1 3 r tier i1 'AftMl Tucl 5 ( ial D istri c : Cour t No 91-1 L4S FORM Nj BA 202-16 SL 013184 ETHYL CHLORIDE uri. rrfp C;IU Frrn % % I'EACrCR IT CL 3 rrC' . C?HcCl H,,0 WT. % ppm 1970 Avg JAN -- 99.70 99.86 PPG iN"iTRIcS CHEMICAL DIVISION LAKE CHARLES, LOUISIANA laboratory operation's report CONFIDENTIAL: Subject to Protective of 14th Judicial Distil No, 91-1145 ,OW*t 1FE8 MAR il APR j MAY j JUNE JULY AUG SEP OCT NOV DEC 1971 Avg j -- 99.86 99.84 99.79 -- 99.90 99.81 ---- -- 99.97 99.9in 99.95 99,92 99.93 99.97 99.90 --- -- 99.07 99.29 99.45 99.41 --- -- -- *> 99.23 - ---- -- 99.14 -- -- -~ --- -- - -- ---- 9 - -- -- 99.30 - ---- PRIMARY STRIPPER rrj.n C?rlr,CL ErCi.i, \'?0 * WT. % PPM P^M - --- -_ --- liO 1 1U To HCl. nr.L3 "z PPM 37.1 7.7 ja____ -- -- - - 10.4 1.9 35 STILL OVERHEAD CzllbCt. HCL ll?0 Wt. % PPM PPM 99.97 99.97 99.97 99.96 14C 211 124 1/.3 59 33 27 L2 Stile Dottoms C2H5Cl Wt. % _ -- SECONDARY STRIPPER I'R.jDL'CT 1 ON l-jHrjCL HCL ITCi.3 Color WT. % PPM PPM PPM APHA -- -- -- -- -- _ ToUbCL 1 HCL VENT ANALYSIS WT# % -- " --- -- -- -- - -- - -- -- - - -- ---- -- -- - - ---- ---- 536.1 42.8 99.1 106.6 2367.7 1153.6 616.6 ---- 7.7 44.3 51-4 7.2 17.5 56.3 26*6 -- ---- 36 85 335 121 53 91 108 99.92 99.96 99.96 69 62 73 43 101 72 '- - 99.95 99.87 130 1671 91 107 99.86 2379 140 99.95 129 139 99.97 T232 7>5 99.96 35L*3k-- _2jLLL 211____ 140____ 83 -- - -- mm mm ---- ---- ---- ---- --- - -- -- --- - -- --- _ -- _ _ - _ mm mm mm -- - i- - 1- . ..In I.. VINYL CHLORIDE 1970 AVG. JAN FE8 chemical DIVISION lAKc CHAKIXS, LOUISIANA LABORATORY OPERATIONS REPORT 1 MAR aph MAY j JUNE JULY AUG SEP OCT A3S0RCLR-S7RIPPER COLUMNS LEAN o: u V!*) Y L C'^LOPIDI* WT.Y, VINVUOUN C C-'UOf'lPi; t* 1.2- I'ICHLOnOETHYLENC nT.y. WT.H 1.1- O'CHLOROtTHANC wt.% CHLOROPI- r:.MC C- 1.7" OICMLOMOETHYIEWC C.HL0!O*Oi1M !.; OICHLONOCTHANr. OTHERS H;.Oy WT.r, wt.% WT.'A WT. % WT,% PPM MCI PPM FPPM UPPER INTERCOOLER VINYL CHLCRIUE HjO HCI FC WT.X PPM WT.H PPM (o.oii 0 0.01 0.01 00 0.09 0.09 0 0.11 0.09 0.10 0 77705 98.78 98.69 0.08 T7709 36 34 " ' 2.47 i .18 0.42 0.49 i1 0 0.01 0 0.12 0.09 0 0,l6 98.30 0.13 24. 1.27 0.37 0 "0--------- 0 0.01 0.02 0.02 0b 0 0.11 0.09 "0709"' orrtr 0.08 .0 0 0.08 0 0.19 0.51 0 f p/, 98.46 98.26 98.79 0.12 0.10 0.10 37 54 44 2.32 5.41 5.26 0.40 0.45 1.05 0 (0.01 0 0.03 0.02 0.02 0^02 0.02 0 0.02 00 0 0 0 0.09 0.16 0.10 0.10 0.06 0.04' 0757 0.09 0 o-------- 0--------- 0 0.11 0.10 0 0.15 0754" 0724-- 0725----- 0.60 98.71 99.04 98.62 98.79 98.22 0.14 TE708 0,,13 0.13 0.14 l, 7 7.59 0.A2 35 50 6.06 1.67 1.76- 0.63 165 n.29 i1 o.60 45 3*42 0.36 2.03 .124.. 2.05 8.27 1.19 181 1.83 4.25 3.59 75 ` 2.07 3.97 1.55 115 1.48 3.01 4.52 203 1.53 3.19 (OTT ! 25b 1753 3785' 0.89 221 1.61 2.68 0.56 931 1.90 3.77 0.21 819 1.52 18.24 . 2,74 0.66 551 1.31 1.85 17.29 ' *3.81- LOWER INTCRCOOLER VINYL. CHLORIDE HiO HCI FC WT.% PPM WT.% PPM 9.03 "102 1.81 2.47 8.75 55 1723 2.84 11.06 45 1.18 5.91 9.85 82 W9 1 .08 tT77 37T2 1 17.16 ( 139 | 1.78 3.63 6.60 243 0.89 31.81 5.33 208' 1.29 4.79 5.63 146 2.73 5.91 3.97 1491 1.42 13.61 6.14 1.55 2.69 NOV 0 0.03 0 0.12 0.08 0 0.69 97.97 0.12 38 6.00 0.75 0.41 -- 1.90 1.79 2.61 1971 I 0EC AVG. 1 0 0.Q2. 0 0.12 0.07 0 i i 70701" \ . n.02 [ 0 "1 0.11 0.08 0 ! i 1 0.53 0,32___i 97.90 (98.48 1 0.12 10.12 Iffl 1 56 4.76 j 4.02 0.44 10.64 i -------------------------------- 1 \ i 0.68 -- 1066 3.76 10.05 1.49 1 _f 1.68 { 5.80 :.) 8.59 ! 1 f 1 1.38 1.42 1.44 ! 3.84 1.83 6.94 k i, l \: r SL O'3186 ` \ * -L i , * SvJ b vt J Un n nNFlDE ho Pro tecti'Y . fUciai Disti Ho* r r*r art FORM JJi 4 2W - 21 . ... 1 Jl VINYL CHLORIDE '' --' 1 TWO AVG. JAN F B PPO> IN Its CHtMlOU OIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY AUG SEP ----------- pr97T~-; OCT NOV OEC 1 AVG. j .VC ERQ01LCI_SULL rrso VINYL CrlLOfilDE VIMVUOUSl ChLOniDE Yf T-. \ 1&.59. 19.79 WT,H 0.01 22.06 76.18 19.04" 17,15 14.87 13772 ' 14.84 11.02 f.0.01 0.01 0.02 0.02 0.02 0.02 1 0.02 0.03 0.04 16.37 0.05 1 1 17.29 I17.C8 0.03 10.02 } I j j J.l- DICHLOnOLTHANE CHLOMOPHENE CHLOPO POi\M 1.2- dichloroethame other: H-O H'.'l F^ WTA wt. 7, WT. \ 0.07 0.07 0.10 wt.% VY T. * PPM 80.39 0.07 36 PPM 4.59 PPM 1.09 0.07 0.09 o^S 79.18 TJ70S 24 2745 1.86 0.07 0.09 0.09 |0,08 0.07 0.09 O1O8 (07o5 0.09 0.15 '0.30 fOTT? 75.99 . 76,66 82.52 0.08 0.TU 0.10 20 "40 30 2.92 5.25" ^.32 0.08 84 (8.35 2.14 0.94 T7T8 (1740 0.09 0.08 0,,09 io.09 0.12 0.11 0.10 10.09 0.06 0,06 0.07 *0.08 0.05 0.06" 0.07 i0.07 0.13 0.23 0.22 (0.26 0752---- 1.10 0.36 10.30 81.59 83.28 84.56 (84.04 87.58 80.95 80.81 181.42 0.08 0.32 0.11 ioTH 0.T8 o.iO 0.1C S0.12 47 26 54 |109 40 36 45 !W t:4ct 2700---- T2.30 {3.22 13.24 3.403. err' |5.49 0.85 1745' 7 1.17 PJ- 1.67 0.57" 0.51 tl.21 1 j 1 3K^DUCTONOMF.n(oy TANK;) >! i .... '( i VtrJVL CHLORIDE WT.% 99.990 99.993. 99.99: 99.992 29.993 * 99.991 99.940 99.990 99.990 99.990 99.990 99.990 99.990 1 99.9871 v.j TADIC METHYL CHLOmne PPM PPM 618 7 18 6 22 8 87 19 22 23 76 19 18 46 4 19 24 25 64 6 i 30 20 |21 fiTHYI. CHLORIDE 2` -l.CHLOPOPROPCNE OTMuRS PPM PPM PPM 34 10 (1 11_____ 28 42 36 38 - 1- 0.3 0.2 0.1 0.2 '(0.2 51 61 0.1 0.1 40 40 20 -- 30 27 - >37 0.1 0.1 0.2 0.1 0.2 b.2 Hj.O 35PPM 35 35 36 33 {33 33 29 TT------ 28 32 42 bu rc ppm_ 0.09 0.05 0.06 0.12 j 0.07 .0.07 0.13 0.08 TJTuT 0.14 n.fiA U.06 b.05 10.00 i 1J^ ".V1 ''*TX. 7.7 7.9 (i (1 7.5 7.6 7.4 1773j 7.2 6.9 7.4 7.5 7.8 (1 U -71--|fr--m-- U TI a-- (1 ! 8.1 7.8 * 7.5 U (1 (1 1 iK! . 1 1t 1 l * I SL 013187 -[ i ________________ CO JFIDKN L'lAL: Sub ject t ) Prot ;ctiv? Order of 14 ;h Jud Lcia 1 llstri Cou rt N 3. 91- L14 5 1 ---- -- 0K subject ^ 'rict court Of I i - *3 . .\ 11_ *2 r' CHEMIC/U DIV!3!0N IAKE CHAKtES, LOUISIANA SL 013188 LABORATORY OPERATIONS REPORT VINYL CHLORIDE LEAViES STILL 1970 AVG. JAN FE8 WAR APR MAY JUNE JULY AUG 5EP OCT j NOV DEC "19*71 AVG. 1 '1 ' i \ } i% F Z r \j V'*JYL CHLOAIor. ,.TIVLfOr,'iF CHLOntDE t* : ni'HLor'OizTHYLrNe :.1- DICHLOnCFTHAIJC c- 1.7- OlCHLC'RO E.7HY LCM E CMLC'POrO F1M i 2- r/c LOnorTunr 1,1,7- 7MOHLOHOE1HAKE O TH cr<s vi P Cl FO '-'2 \0 T 7O' **_ Y/T.% (0.01 wt.% 0.03___ WT,r. 0 WT. % 0.09 W T. % lO.Ql >7 T, 7, _Q.11__ WT. * YY T . % 0.10 YY T. % 0.16 PPM _22______ YY T. % 0,11 PPM 1.95 PPM 4 : 0 0.01 0 0.09 0 0.07 92.54 0.10 0.12 35 0.03 0.47 2 0 (0.01 0 0.10 (0.01 0.12 93.58 0.12 O.ll 22 fl.Oit 1-8*1... 2 0 0 (0.01 0.01 0.02 0.01 (0,01. o 0,11 0.08 0 10 o 0.10 R073T .0.18 98.40 0,10 0.37 0.22 98.26 log.72 16 tO. 18 0.18 U*T^ 10.13 0.04 2.3<J 8 i 44 0.01 3.26 15 !44 0.04 4.44 10 TJ----------- 0 0.02 0-01 0 |0.11 |o 9 0.16 0 1 0.18 0,18 ! 98,61 98.75 0.18 0.18 i 0.12 (TO At 45 0-04 p.04 TX"5A1 25 7 0 0.02 0 0.10 o *21 1*78.65 0.18 p.16 40 0704 7.73 22 0.03 0 10.11 | (0.01 so i0.30 Jog A4 lO,14 fo.16 |63 0.14 17.29 24 0-- 0.04 0.04 00 0.13" u.14 0 0.01 0r62 1.27 98.02 96.87 0.16 0.17 0.18 M-1? 60 0.19 7.13 10 - 41 0.09 '7728 IV - 0.02 6 o to.01 jo j ; ` ; 0.12 JO. 10 i 0.02 0,46 t (0.01J so. 35 ! 97-88 0.15 0.13 iv8.33 S3.15 0.14 i 1 \ 33 fT5 ! 0.03 0.06 4,50 .. t .88 -L3 13 S ! CMI.OHO FORM 1-2- DICHLOROCTHAME tmckuopo r:iHYLt.'j z 1-n^OMO, r-CMLOAOCTH ANC PCRCKLOROETHYLTNIi TniCMLOnoCTHANE J-TrTr<ACIaOBOF.THAKi: STHTPACHLOHOETHANE O TH i;H3 HCI fe W T. % YYT. % YY T. % WT. WT. % WT, 7. W T. 7, WT.% WT. % WT. % PPM {0.01 72.61 0.01 (o.ol TOT " 19.17 0.06 . 0.19 7.62 0.02 33.32 0.01 80.98 0.01 0. 0 12.44 0 0 6.66 0.02 18.83 (0.01 80.72 0.01 0 0 11.19 0 0 6.61 0.01 49.17 (0.01 i (0.01 77.94 ! 79.00 0,02 ! (0.01 0 T3 00 12.99 16.23 0 00 9-04 3.99 0.02 -0.02 20.20 18.55 (0.01 177.00 " 0.02 (0.01 0 TT77T -------------- V 5.60 0.02 29.61 (0.01 73.93 0.08 0.02 0 19.38 0 0 6.90 0.01 32.34 (0.01 " 0.01 (0.01 65.22 78.31 85.93 P.05 0.13 (0701" 0.02 0.05 0.03 3 L0.70 3 > 00 nT77T" 9.04 3---------- 0 3 P , 0--------- + W LU75JT 4.34 OT-- 0.02 0.02 38774" 35.42 29.30 0,,G1 85.82 0.-05 0.02 0 10.24 0 0 4.80 0.01 26.87 (0.01 (0.01 (0-01 > 87.03 83.29 0.09 b.22 07(12' G.01 u0 81.26 t 0.06 \ 0.01 01 8.77 9.30 . 12.38 0 o 3.22 137o1 3 b 6.49 0.01 O 0- 5.58 0.02 ! S i 20.63 '9.60 33.23 | LASTE-POPP. KETTLE BOTTOMS r ?- oichlooocthamf WT. 7. - - - pcrchlorocthyleue W 7,7. - L_ ____ 1 -- - j- -- A- - -- -- ------ --- - J t l.t.a* TPfCMLCHOCTHAflE W T. 7* - - -- - - ;^ -- r- - -- u-n:TfucHi.ono(-;rnANE WT.% - - -- rf etn AcutoriocTH an e WT. % - -- -- --- -- --- --- -- 1 ECN1 AC H L. Of FTO ETH AN E 0 TH FTPS rc WT.% **T,% PPM * - -- '-- -- -- ---- -- mm. - - - --- - - ---- --- -- -----, - 1 T a rts ntsi ou e "WT. 7, ** - WT.% -- - 1 ** -- -- -- -- -- w -1 _=>' CHEMICAL DIVISION LANE CHARLES, LOUISIANA j ) OHC-EDC CONDENSED ORGANIC i' 1970 1 AVG* , JAN. !j LABOR4 ATORY.OPERATIONS REPORT FED. WAR. APR WAY | JUNE JULY s AUG. | SEP. ! REACTOR NO. 1 ! M-lliyl Chloriflo J Ujnvl ChforkJa [ I.th /! Hliloi k!o | Vinylidinc Clilorido j litfr.s-1, 2 nichJoroclhY'onc 1 1, 1 Ufchlorocthylorto ! r.'.'.-l, 2Dir:hloroothy!cno | CliUtioiorm [ T: CC j C.-irbontctiHchlorido 1 Tricklnroc'Jiylcfic | CMor.il j 1,1, 2 Trichloroo(hylono J PcrcMorootiiyfcno U-ToirncSi loroothnns [ S-Tclrachf&roothano Pontachloroethano liexachlcroulhano Unknowns Wntor f=n 1 : ! i 11 %* 0.01 0.02 0.02 P.02 10.02 j 0.01 jo.02 i0.03 !o.03 10.03 0.05 {0.06 0.07 P.06 (O.OO 0.03 ?0.04 107Q3 fo.03 P.03 0.24 \0.22 ! 0.24 Y),2I, !0.l6 ? 0.14 P.6l P.38 lo_39 fo.38 OAR io.01 j 0.02 b.01 10.01 ! 0.01 io.OI !0.01 io.02 !0.02 o jo \o b 0 1 0 0 10 j0 So 0.21 io.23 i 0.20 b.23 0.21 0.18 0.20 b.19 lO. 21 10.19 o.io io.ug ! 0.09 b.io 0.11 0 08 P*10 P9 fO.ll 10.10 0.07 in.07 i o.io o.io 0.09 nil [0.10 P*12 0.13 io.11 97.54197.66 j 97.36?97.36 96.71 97.38196.67 {97.05 96.52 196.91 0*25 jo.22 1 0.28 b.30 0.35 0.37 b.33 P.40 0.44 P.34 0.12 jo.13 1 0.18 0.15 0.13 0.14 io.if, p.14 0-15 P.JA 0.39 Jo. 39 ! 0.32 p.42 0.31 0.34 i0.43 P.35 0.35 P*35 0-80 jo.tJO j 0.97 P*86 1.08 | 0.99 h .13 tL.Ol 1.29 P.96 ^OTOJlo.03 I o.m P-7* {u.uij(o.oi | o!m P*UT o.-i^ jo.09 (O.Olio --s1 (O.Oljo 0.08 P'n 0P 0b 0.03 b 0.02 0.05 0.17 P702 0 TJ702 j 0.03 1(0.01 j 0.02 jO.03 j 0.16 io.19 ! (0.01 IIP.01 j 0 jo jO jO P.05 b.ol P*oi 1(0.01 p P (0.01 0.04 0.28 (0.01 0 0 <0.03 *0.05 SO. 19 j(0.01 b (0.01 PPM 0 PPM 0 1 jo O i 0b 0p ij 0 to (0 0 ID JO 3--------- 0 D0 p 0 OCT. ' 0.03 n.03 1 08 0.02 0 0.18 0.13 0.17 95.60 0.33 0.15 0.52 1.26 o7o6 0.00 0.23 (0,01 0 0 0 0 NOV. j DEC. ; 1971 _A_V_O_. 1 1 i 0.03 [0.02 0.04 Ip 06 0.93 il.'A J ! Q,Q2__J &sH 0.03 i0,02 io.02 (J lo 0.16 I0.12 0 0,19 u*^2 io.08 10.12 1 0.21 jo.08 10.12 j 95-72195,57 196.73 1 0.42 10.44 10,35 I 0.16 *0,24 0.36 p.58 1.21 {0.95 o,iiJ 0.39 ! S1.04 ! U.03 jo.04 O.03 | o.05"T(C7n~ 0,G2~ i 0.21 b 10 (0.01 U 0b 0,15_ j Covou0 0b 1 ko.oi "0 b D 0b 0- | ii______________________________ i ! 1i t! + i t1 j -----------!ft-------- t ! } 1i 1 i1 \1-----------1 ! ! 11j 1 SoiL un 1i o31'8u9s L j "ouins utlierwiio Indicated 1 t_______________________________ 1-- i .. 1 i 1 ( i j----------1 CONF1 IDENTIAU: I Subie ct to Protective d rder i ----------- 1----------- \ ofr 14th Judiciial Djstrid ; Gout T Mo. '9i -riis-- i1 i _____ !_____ i_____ i____ ------ 1------ 1 "i1 I I (1 CHL.'.ECA;. DIVISION LAKE CrlARLES, LOUISIANA j I ! OHC-EDC CONDENSED ORGANIC 1 1970 a vr* ! JAN. FEB. LABORATORY OP -,B ATTONS REPORT WAR. ; 1 i APR. 1;s_W__A_Y___j!! JUNE JULY :_____ AUG. SEP. OCT. i"37)71 j NOV. j DEC. AVG. j | REACTOR NO. 2 | ti i 1 ' ... --------- i 1 r.:shvi Chtcrido %* (0.01 * 0.02 *,0.02 0.03 : 0.03,0.03 i 0.02 !o.C2 0.02 0.02 0.02 U.02 0.04 0.02 * Vinyl Chloride I 0.07 o.o6. 0.07 0.07 0.05 ( 0.05 : 0.04 !0.03 1 0.03 10.04 n.03 0.03 0.06 0,05 1: tf.yl Chloride 1 0.25 0.22 0.29 0.23 0,18 > 0,20 -! 0.47 >0.33 i 0,47 LOJ.8 i in 0.70 2r;,3 0.57 1 Vinvliriino Chiorido ) 0*01 0.01 0.01 1 0.02 0.02 ! 0.02 0.02 i0.02 1 0.02 lO.OZ 0.02 0.02 Bj cJ oj o 1 ! 2 Dirhlorcethylcrtc i 1. `i-DicMorncthyleno 0 0 o io 0 jO 0.21 0.22 0.19 i 0.22 ,0.24 ! 0.30 0 0.19 io.20 ! n 5n 10.18 0.18 0 u7T4 0 10 0.20 I 0.21 j ci*: T, 2 OicidGrocthyluno 0.10 0.13 0.14 i 0.14 0.21 ; 0.13 0.10 [0.11 0.32 I0*10 0.11 0.12 0.15 ! 0,13 i OJoroform 0,09 0.11 0.10' j 0.14 0.14 { 0.13 1 0.10 !0.14 0.14 10,14 0.17 0.15 0.12 1 0.13 ii [ koc C>'t l)oiitctrfcSi(oridQ l Trich'^fortiiylono 97.58 j 97.28 97.06 : 96.92 96.53 ! 95724"!_9676Ti96.79 0.24 ! 0.28 0.24 | 0.31 j O.39 10752 0.43 0.52 6.12 f 0.16 0.15 ! 0.16 1 0.16 i u*^u U. 16" 0715 96.74 97.12 96.13 96.28 0.33 0.31 0.37 0.33 0.17 0.17 0.18 0.16 94.34 1 96.50 0.27 ) 0.36 0.19 1 0.17 1 Chloral ; 1, 1,2-TrichIcroethylcno !1 Perddorocthylcno U Tctmclilorcclhana < S Tetrachloroothuno . Pcnincldorocthano ! Hco.acldoroatharta P Unknowns ! 0.39 | 0.45 0.52 0.79 o.<n 1.07 0.04 Q.04 0.03 (0.01 (o.m TT7DX 0.10 0.10 0.08 (0.01 _Q_____ 0 0 00 (0.01 0 0.04 U#>^ ! 0.46 1 0.49 1.05 j 1.38 ! 1.29 0,05 1 0.04 ! 0.02 0*01 0.03 S0.04 i 0.12 0.15 1 0.19 sO 0.02 1 (0.01 0 0 |0 0 00 0.49 0.33 0.37 0.36 0.38 1.14 17I2~ 1.15 1.11 1.07 0.02 0.03 ~(0.01 0.05 0.06 0.03 0.02 0.04 0.04 0.00 0.16 0.17 0.18 0.13 0.19 (0.01 (0.01 (0.01 U7CS (0.01 00 0 XJ-------- 0 00 0 (o.oi (0.01 0.41 1.32 0.03 ~07U2~ U.24 (0.01 0 0 0.50 1.32 0.04 0 0.22 0 0 0 I 0.44 1.16 0,03 | 0.02 j 0.16 (0.01 0 (0.01" 1 1 Water i Fa 1i PPM 0 PPM 0 00 00 u '0 U 0 o--------- o 0 u n TJ-------- 0 0 00 0 0 T5--------- 0 00 00 i i `' ! 1 i - SL 013190 < ! ; * Unless Otherwise Indicated % t> i it ----------- r1 t it l .... 1 } i1 CON FT )ENT 1 A 1 1 !! ! >ubiec : to P 'OtPOt i vp Or \<> r i 1 t of 14tb Jndici, 11 uicj " r i r?F Yu t rh 1 i rj No. I 11-114 > 1 11 1 11 1 i 1 Pac. i * ^-' J'l *'***t; i 4 _ * ':chzi:'.ca>- division LAKE! CK ARlES, LOUISIANA I.flBOR ATORY OPERATIONS REPORT ! ! OHC-EDC J 1970 ! AVG* JAN. 1 S f } r j FES. WAR. i APR. j WAV j JUKE \ JULY AUG. SEP. 11t!1! 1 OCT. | DH STILL BOTTOM i _______ )_______ i ! ! 1 1 1 f flctlivl Chluritin % |(0,01 0 o io | 0 l (0.01 1 (0.01 0 lo 1(0.01 0 \ Vinyl CU'orirte { \0*01 o ) jo | (o.oi i (o.oi 1 (o.oi o Korn i(0.01 (n.m i Eiliyl Chlorlflo |0.03 0.05 1.07 I0*08 ! 0.08 `0.10 io.34 n_2rt lfKi7 So.09 n,26 j Vinylfdinf* CMorida 0.01 0.01 0.02 r*02 i 0.03 \ 0.0? 10-01 Old 0.01 i0.02 oi02 | tratisT, 2 Diehl oroctliylcno 0 0 o iu ho ! 0 lo 0 o6 0 | 1, l-DLhlortM'hylcr.o 0.25 0.22 0.22 iu*21 f p.19 :0.21 j 0.21 0.19 0.21 P.17 0.18 crs-l, Z-nicliluroothvlano 0.12 0.10 0.12 f 0.17 jo.io j0.10 0.09 0.11 P.n 0.12 i Chloioform 0.69 0.52 6.62 io,,64 ! o.Aft fQ755~j6.52 0.59 0.50 P.50 0.62 i [ DC 97.57 97.69 97.35 *97.13 ! rtrt.Qni96TFn96.98 97.10 95.20 195.73 96.47 J C'Tlit'WiiotrzchlorirJft jf Trichlorrioihytcno J0*25 jO*X/t 0.23 0.30 ?o.30 ! 0.33 {0.41 0.42 0.50 0.15 0.13 t0.14 1 Or17 10.20 0.16 0.14 0.40 b.32 0.14 (0.13 0.34 0.15 ! Chlnm! jO.05 (0,01 (0.01 fo.01 1 0.13 S 0.03 0.11 0.07 0.08 jo,,G3 0.07 | 1. 1,2-TriciTln'ce.hylona {0*hi4 0.09 0.96 {0.98 1 1.16 `0.90 0.93 1.02 1.20 JL.20 1.49 J Porciilcrocihy'.cno (0*03 0.03 0.03 10*04 i 0.07 i 0.06 }u*ui 0.02 1(0.01 9,04 0.06 f U'Vc;m~hJrro^t!iano j C-Tct.ochlcruntJianc j P* iitschloroatlvino MO.OX j 0,11 j (0*0X (0.01 0.02 10.01 0.10 0.11 10.12 0 i o so (0.01:0.03 i 0.05 o .err 07U4 0,332-- (0.01 i 0.13 ,0.13 i0.12 TJTK 0.22 p.22 0.22 ( (o.Oi S (0.01 | (n.ni (U.Dl (n.ni KO.01 (0.01 i Hpxacliloroathano 1 Unknowns 1___ j0 j(0,01 j() . 1J 0 |0 (0.01 p i 0 iO io (o.oi \ (o.oi jo f} 0 0 0P 0 0---------pj---.-o---r---- (0.01 i Wptor PPM 129 t 18 22 J33 53 ! 67 82 22 42 El 50 i Fa PPM SO SO 00 0 !0 Io 0 0 00 i _________________________ _______ ni i ii i1 NOV. (0.01 (0.0) 0.57 0.06 0 0.24 0.31 > R?S 1 0 o 0.58 0.11 0 0.51 0.75 ii !; 1 (o.oi i i (o.oi ! i0.22 j io.03 1 io io.23 ; !0.18 S u.64 2.02 10.68 ! 94.39 90.97 ; 95.40-! 0.37 0.74 0,39 ; 0.30 0.29 10.18 i 0.05 0.14 !o.o6 i 1.28 1.31 tl.ll i 0.07 0.61 '-0.09 ! (0.01io.05 !0.02 j 0*26 i0.21 j 0.17 j (0.01 0.01 !(0.01 ; 0 o So i (0.01 0.02 iToToi ! i 120 51 m 0 -0---------- )i-0----------- t \ j_____ fj!t--------------------------i___ sr J!-------- S_,L n011 3*111 3Q11 I _______________________________ 1_______ i * Unloss Otherwise Indicated | _______________________________ i__ 1 t i! i 1! 1 ~1 1i i* ----------- [ t ff 1 u- ... 1. ! ! (11 ! ...J_______ S_ _ _ _ j i OUti Fi&EN* X AL i --Sntrj ect Lc Prott ctive Order of 1+t li~ Judij uidl I is tri< :fc~ Couj "t--------- --------Nc . 91-J 14p----- | j ji 1 {t 1 1i ' 1 1 ! OHC-FDC 1970 AVG. LIGHTS STILL BOTTOMS (Product! rWiliyl Clilorirtn %* 0 Vkv/I Chloride '(0.01 : E;livl Ciilorir!'! \ VinYocIiiii! Cliloritiu [ tr.'ms-l* 2 Dichiornoiliylono t 1, lOicJilorontliylmo 1 rir*1.7-DichIororlhvfonc 0.03 (0.01 0 0.11 0.07 ! rjitfipofonn 0.24 r;DC I C. if honfolrr.r.litnricta [ Trirhic^cnl'.iYlcno Ch In-.il 11 ", 1. 2-'friclilnroctliylanii r'vchJoroG'hylom 1 IJ rn:rBn:hforocllKir>o S-Toirncliloroodi.ino 98.09 0.15 0.11 0.01 T725 0, Ob 0.01 TJ7X5 iVnt.ichlorcictlicno (0.01 HrX'irhforontliDfia Unknowns 0.01 (0.01 VVnior Fn PPM 8 PPM 0 _________________________ * _____ JAN. FEB. - ^ .1 l . .i LAKiL CHARLES,LOUISIANA LABOR ATORY OP ER ATIONS REPORT 'i MAR. APR. j MAY JUNE JULY AUG. SEP. OCT. NOV. DEC. 1971 AVg, 0 0 0 0 0 0 0 (0.01 98.72 0 0.09 (0.01 0.96 0.04 0.01 0.11 0 0 (0.01 0 0 00 00 n,m (0.01 (0.03 (0.01 00 0.03 0.02 0.02 0.02 0.03 0*08 98.58 98.57 0.02 0.04 0.11 0.12 0.02 0.01 1.06 0.99 0.03 0*04 0.02 0701 0.10 0.12 00 00 0.02 (0.01 1 l 00 00 u |o *0 1 11 000 0 0 0 00 0 (0.01 0 0 00 (0.01 0.12 0.05 0.03 00 (0.01 (0.01 (0.01 (0.01 .0 ID--------- 0 0 0 0 (0.01 (0.01 0.06 0.05 o.c6 0.02 (0.01 TOUT 0.03 0.02 3.04 0.15 0*05 0706" 0:i9-- 0.13 0.18 1 98.26 98.47 98.26 97.97 97.81 97.72 (1. 07 ' 0;02 0.04 0.23 TOT-- 0.13 0.13 uvnr- 0.13__ 0;ur~ TJ7I3 0.11 0.04 0.04 0.14 0707 0.10" 0.12 1.06 rO-.99 1.15 0775 1*40 1.22 0.04 0.11 (0.01 0.14 (0.01 0.05 0.03 0.02 0.04 0.04 0.06 (0,01" 0.12 0.14 0.14 0.15 0.25 0.24 (0.01 (0.01 (0.01 (0.01 0.01 (n m 00 (0.01 0 00 0 V--------- 0--------- 0 0 (0.01 "0-------- 0 0 0 0 0 "0-------- 0_____ 0 0 00 t '1 i i 00 0 0 0 0 0 1Q.P1- n 0 (0.01 0.02 _ (0.01 (0.U1 0 (0.01 00 0 0 (0.01 0.02 (0.01' 0.02 urn (0.01 0.03 0.30 u;o;r~ d;i7t" 47.27 95.65. 96.17 97.78 0.22 0.22 0.02 0.09 0.14 0.28 0.20 0.14 0.06 0.05 0.06 0.06 1.62 1 .30 2.71 1.27 0.06 0.07 0.35 0.08 (0.01 0 0.07 0.03 0.25 0.25 0.29 0.18 (0.01 (0.01 O.o2~~ Ig.ut 0 u u--------- 15--------- (0.01 (0.0T 0.04 (0.01 0 0 16 1 0 00 0 11 1 ----------- --11} 1 !. 013192 /> * Unlost Otherwise Indicator! Cu NFI1TEN PIATT ----- !mb jerct--t j mvt active Order (Ml Juu l L'i'cTl" TfSTTT ~fc Cdu rrfc "1 --- -rJ > ~ 71"" bir&tj-- I \T* - ' la l b' -i ch:;.::cal Division late c h ap. l e s, lo u i e i am a LABORATORY OPERATIONS REPORT ! VINYLIDENE CHLORIDE j 1970 JAN. FES. | MAR. | APR. j UAY | JUME j JULY | MONOMER j AVG_ | VCCM REACTOR CRUDE ___ii !f ) !i (! *t AUG. ( SEP. i ) ! Acetylene 1 Monockioroacetylene PPM PPM 7 - !- i - i - i- h - 1- n> iTj ! 5 t i- i- p Dichloroacctylcne PPM 33 ~ Tt L >595 '2 t2 'l (_ i- Vtnyiidene Chloride Wt. To 99.55 i 99.60'99.36 (99.49 !99.99 199.99 199.99 U !- Iran;-; .2 DichlorocthyicncPPM cJs-!,?. Dichloroethylene PPM 2067 26 - i 533 477 -.1511 j- 1 22 y !59^ i- jp !- f h j- 7 ricldoroLthy'cnn PPM ~643 - IT Ifi^7* i- F F i ,2-Oichloroct!idne PPM 433 ~ To fi f?!- r h -- P* --- Unknowns (Total) Toluene r PPM 2226 - 6 fc 126 h r h PPM 750 - 667 541 1571 i" - r \ \i i ---- - DAY TANK Acetylene PPM j. 1 S -H 1- C 1 - OCT. -- -- - i NOV. -- -- -- - 1 DEC. \ 1 - - i 1971 l ( AVG. j ii -I !3 J 102 ! re^2Q 1 _5Q8___! 33 I 92 ! 3___ __ 14 593 .. -- hienoahloroacetylenc PPM 8 Dicidoioscctylcno PPM ( 9 n Vmylidene Chlor ide Wt. % trans-1,2 DiehlorocthylonePPM cis-l,2 Dichloroethylene PPM Trichloroethylene PPM 99.93 "618 2 18 -- - 1,2-Dichloroethane Unknov/ns (Total) Toluene PPM (1 - PPM J._____ - PPM 6 - t___ H ;;0 PPM 30 ' Acidity, As HCI PPM (1 ~ Color APHA (5 " Peroxide, As H90? PPM Cl HQMME PPM 194 Phenol Wt.% 2.5 Appearance Clear _ Morpholine PPM 1.0 m Specific Gravity 20/20 1.212. i 3 jr 1 i <3 ci 4 34 6 {8 (3 J4 12 99.97199.97 199.98 -99.89 |99.94 j99.99 300 258 ! 192 8576 417 p.37 3 sret ro n re Cl id |2 ! ci 1 h o !d Co 3p if 2 !l Ip XT 3b 2h K in: Si 1 22 To M5 !1 S lj k9 i 2t *24 Ki To Ui (5 ^K5 1(5 5i 525 10 :f5 1t i27 id 1(1 (i 10 187 ,146 j- ITT |149 To '220 1- 10 {206 f- Ki p.90 h Clear*2.0 9*0 re re j Clear (Clear jClear {Clear |1.0 i2.0 B.O i= t f r f 5 8 2 1 1 .J___ __ 7 17 1 34 6! 99,99 99.99 99.99 99.99 99.99 99.97 u 60 T9 0 (1 (1 00 Cl 0 XT (1 1 1* 2 (--i-------- F--------- --, 1 1 39 {33 30 17 ri d 24 45 -- 3 (1 reg5 187 2 (1 2 2 fl i j-33 _ (1 fl 5 (5 (1 ~n TI !"TI (5 5 "T5 iT5 (1 (1 (1 TT Cl 1 (l 143 187 L_ 191 199 Prr6 389 -- Cl sac Clear Clear Clear C3.ear s Clear i U.o 2.0 (1.0 1 ,0 1 P.6 .... - 1- _______________________________ j 1 . RL 013193 1 * i1 1i )1 {S i i !! j rnup hPM'PT i it . 1 [ 1 j 1 i iSllhifaf P tn I rr\f or )j \ i i i i od i4th Judici al tf Dii strict jCourJL _______ 1________) Wo. 9J-iJ 45 ) GENERAL DEPARTMENT EDC Production ]' T/D EDC Area Production T/D EDC Shipments T/O Purchased Ethylene to EDC T/D %'C2H4 in Purchased Ethylene Ci2 to EDC T/D i YIELDS Area Production Basis Cl2 C Records Production Basis Cl2 C Area Prod. + Trans. Credits Basis Cl2 Records Prod. + Trans. r Credits Basis C Ci2 C CHEMICAL DIVISION LAKE CHARLES, LOUISIANA Wo. 91-1145 LIQUID PHASE ETHYLENE DiCHLORIDE DEPARTMENT OPERATIONS REPORT 1970 JAN. FEB. MAR. APR. WAV l JUNE J JULY AUG. SEP. AVG. OCT. NOV. DEC. 1971 ; avg. 1 1073.9 1052.7 869.5 1947.8 109.2 1017.7 984.5 1035.6 1074.9 1080.2 1116.2 1124.3 1082.9 1041.3 1075.? 1051..' 883.2 951.6 M12.9 1018.7 984.8 1037.4 1076.8 1072.4 1119.7 1125.6 10S2.0 1043.2 1 216 .4 240.6 2.7 lm .2 61.3 9.6 155.4 193.5 143.0 246.3 51.3 250.9 337.5 ,149.5 1 3.12.3 306.4 294.7 321.7 |310.7 317.0 324.7 99.69 99.86 99.86 99.8/r 99.79 99.90 99.81 99.97 99.95 99.95 99.92 99.93 99.97 99.90 766.3 770.5 642.9 696.3 829.7 748.0 725.6 755.3 787.6 794.9 826.3 821.5 794.1 766.1 97.9 97.8 97.9 97.7 98.4 ..aa .a 98.3 97.9 R7.4 97.8 97.3 98.4 98.3 96.9 96.8 99.0 99.2 98.6 98.9 99.1 97.7 98.3 97.4 97.9 96.1 98.3 . 98.1 97.5. 95.8 97.9 "97.'r - 98.8 99.0 97.1 98.8 97.6 99.2 97.5 99.0 98.4 99.7 97.2 98.0 97.2 98.0 98.0 W75 98.4 98.6 96.8 "9H73 Wo ~W.T~ 99.5" 98.6 ---- --_ 99.0 99.6 98.9 99.4 98.8 99.3 98.8 99.1 -- --_ - ---- - ---- 96.3 97 ,,8 99.4 97.3 98.1 99.2 97.6 97.5 99.3 98.6 97.8 99.1 ------ -- -- 98.3 98.6 99.9 98.4 98.3 100.0 98.5 Excess CjHd Excess C?H/i Still hot to ms To F/T Total Losses Loading Losses EDC Inventory % T/Wio. T/D T/D T/D Tons 2.4 2.8 1.7 1.9 213-9 259.5 122.0 157.0 8.7 11.7 6.3 7.9 SL____ -1.3 13.7 3.8 .7 -1.3 13.7 3.8 8097.4 6922.6 8023.8 3599.3 1.9 0.8 2.0 1.4 1.6 3.5 2,4__ 1 .j_ 0.6 1.9 186.5 76.7 170.3 134.9 153.0 324.4 241.3 L69.4 58.0 171.1 10.5 7.3 7.1 5.1 14.1 9.6 7.4 12.7 i7.1 8.9 3.7 1.0 0.3 1 .8 3.9 7.8 3.5 1.2 -1.0 3,2 3.7 1.0 0.3 ,1.8 3.9 7.8 3.5 1 .2 -1.0 >3.2 613-6.0 6814.4 2500.9 8404-2 9107.2 6409.5 7594.3 7137.8 5261.0 6492.6 EDC REACTOR NO. 1 Pressure Bottom PSIG Temp. F Bottom Top EDC REACTOR NO. 2 Prrssure Bottom PSIG Temp. E Bottom Top EDC REACTOR NO. 3 Pressure Bottom Temp. F Bottom | Tfin 14.5 213 202 17.8 221 212 13...9 16.8 709 1 217 ,199 210 28.4 229 220 23 A 226 218 18.1 221 2.11 17.5 218 209 46.6 274 216 17.9 220 210 17.8 . 217 210 35-9 225 217 18.4 222 212 18.5 220 211 33.0 225 217 SL 013194 18.1 222 212 18.2 222 212 18.5 18-8 223 223 213 213 18.2 21Q 2in 18.4 219 ' 211. . JR-/. 210 209 18.9 220 212 32.1 224 216 27 ..6 226 219 37.4 47.7 230 228 LJ122 _ 220 19.3 224 215 18.7 219 212 25.5 228 220 19.0 224 214 18*. 8 219 212 16.8 223 El 3 18.7 219 211 13 J_ 18.5 ---- ',)OT 213 - -r2~12 -n 18,7 219 21.1 J6.3 219 2.U 24.fi 229 223 24.5 229 25-1 228 220____ |el9 32.0 227 1L219 1 ! j FORM I5A 2U8-2 V GENERAL DEPARTMENT EOC STRIPPER NO. 1 PRESSURE TOP ! TTMP. F DO T TOM TOP FGF.D PATE P SIG GPM 1970 AVG. JAN 5,6 200 10ft 63.5 8.3 s>njp 5ft ,1 CONFIDENTIAL: A PPG f -U SIR l;S Subject to Protect i v?'^ ` CHEMICAL DIVISION of 14th Judicial District Court LAKE CHARLES, LOUISIANA No. 91-1145 * ETHYLENE DICHLORIDE DEPARTMENT OPERATIONS REPORT FEB WAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 1971 AVG.- 8.1 21 n 202 48.7 8.6 210 2n/( 51 T'n 9.2 211 204 66.1 9.1 211 207 62.9 9.5 212 207 58.6 9.7 211 20ft 62.7 9.7 211 207 68.1 9.7 212 208 66.4 10.0 212 211 69.7 10.0 212 200 65.1 9.4 211 205 65.6 9.2 211 206 61.9 EOC STRIPPER NO. 2 Pnc&SURL TOP TbMP, eF DOTTOM TOP FEED PATE P5IG GPM 13. A 220 213 83. A 14.0 219 213 82.1 12.7 218 211 67.9 12.8 218 212 88.7 13.1 219 214 93.4 13.1 220 216 85.9 14.4 223 218 81.0 16.1 227 221 83.1 15.2 15.1 16:7 "225 "225 230 220 221 226 9TI3 ' "9375" 94.6 15-2 _ 227 223 101 .0 14.1 219 92.1 3-4.4__ 223 218 67.9 EDO STILL NO. I TEMP. *JF GOT TOM 217 - - - -- -- --- -- TOP 195 ~T95 - - - --- -- --- --- 196 FEED PATE GPM 49 .2 44.4 33.3 38.4 49.1 43.1 38.5 46.2 47.8 48.3 45.0 48.2 47.8 44.2 PgFLUK RATE PRODUCTION GPM 2i,4 21.9 22.0 72173 22.0 21.9 22.2 22.5 21.8 22.0 22.2 23.3 23.0 22.2 GPM 48.6 46.4 36:9 7+078" 51 .2 44.5 19.4 47.9 50.3 51.1 /. 7.0 51 .2 51.4 46,6 EOC STILL NO. 2 TF.MP. *r no T TOM l . . TOP j FI-ED PATE ncFLU* PATE PRODUCTION 1 '236 245 243 245 247 '247 249 248 255 256 255 263 260 251 194 194 193 194 195 195 . 194 193 199 197 198 10ft 3 06 3 06 GPM 106.1 108.2 98.5 109.2 117.4 112.0 107.5 104.8 118.1 117-6 121.3 121 .7 135.ft 112.7 GPM 75.1 68.2 68.0 68.0 70.7 73.9 73.1 71.0 71.2 74.3 77.9 77.8 74.4 JZA-- GPM 100.0 105.3 93.0 102.5 110.0 105.5 101.5 99.4 nr; 9" 111*5 115.5 106.6 i | S T E AM LMO# BASIS) L81./T EOC 1 k vim/ r eoc 1 ei.L WATER M GALS./T EOC | GAS MC F/T EOC 1 NITROGEN TONS/ T EOC | QP ERA T1P ^ nr..-- - - 555 12.9 0.48 0.24 0.022 504 14.4 0.64 0.24 0.025 461 14.9 0.45 0.30 0.013 454 13.9 0.39 0.30 0.012 ,'394 395 399 12.6 -17770 10.3 1439 0.37 0.41 '"0730' 0.T'6" 0.15 0.009 ''0.012 0.022 411 15.5 0.36 0.12 0.023 441 10.1. 0.73 0.13 0.024 455 13.8 0.37 0.13 0.027 452 12.4 0.29 0.13 0.027 99.6 100.0 94.4 100.0 100.0 100. a 100.0 100. d 98.7 98.0 100.0 411 12.9 0.27 0.13 0,028 457 13.1 0,40 0.15 0.026 436 13.2 0.62 0.15 0.021 98.6 98.4 99.0 _____ SL 013195 FORM Ci' 1 GENERAL DEPARTMENT 1 EOUIPMENT HOURS Ain COMPRESSORS tf 1 Hi 83 # Us 1970 AVG. JAN JU ji.JLJ CHEMICAL DIVISION LAKE CHARLES, LOUISIANA ETHYLENE DICHLORIDE DEPARTMENT OPERATIONS REPORT FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1971 AVG., Uil * 456 163 4829 * AT 2 ;,96 8?nq * 600 672 0 *0 8 0 00 0 7/Ji 7/, A 0 0 0 152 603 720 ~7W 569 720 hos 80 0 00 0 00 744 629 614 396 0 T4D 654 530 744 512 16 396 0 0 00 00 00 * 610 560 238 0 0 686 5063* 686 6375* . J2______ 5132* 0 8* 0 0* MAN HOURS PER TON EDO P HODU C Tl ON i M AIN TLNANCE 0.036 0.024 1A L A131 il O. 0.012 JO.IAL. 0.072 CONTRACT MMNT. iUCCyDCO IN A DO V (' C.C04 MAN HOURS/TON SHIPPED** BULK DRUMS | SALARICO 0.023 - 0.003 0.038 0.040 0.021 0,027 0.01] 0.015 0,070 0.082 O.OOC 0.000 0.037 0.021 0.014. 0.072 0.000 0.031 0.021 0.011 0.063 0.000 0.034 0.035 0.028 U.U21 0.011 0.013 0.073 nro6P 0.000 0.000 0.033 0.017 0.012 0.062 0.000 0.034 0.022 0.012 0.068 0.000 0.039 0,014 0.012 0.065 0.000 0.031 0.013 0.011 0.055 0.000 0.031 0-015 0.011 0.057 0.000 0.032 n. c)?:j 0.0]] 0.06.5. 0.000 0.035 Q.Q2Q . 11.067. 0.000 0.022 0.564 0.022 --- O.OO; 0.053 0.003 0.041 0.004 0.134 0.041 --- 0.013 0.004 0.023 0.003 0.017 0.002 0,026 0.036 0.003 0.004 0.013 0.015 iljDaa_ 0.001 0.001 0.008 (\ . . .. 1: 1........ n13l96 * TOTALS * OPERATIONS MAINTENANCE * < f iNF TDfj ;MT IA 4 En irl i C, PtC icl Itectr Diet : .1 c L C. 0; - . Tt't' NO . 9 L-1I46 r. CONFIDENTIAL: P/xv ^fcubject to Protective Order ^Tl4th Judicial District Court i H C'.J t i it Ho. 91-1145 CHEMICAL DIVISION LAKE CHARLES,LOUISIANA "TRI-ETHANE" DEPARTMENT OPERATIONS REPORT SL 013197 GENERAL DEPARTMENT MC Production MC Area Production "Tri-Ethane" Production "Tri-Ethane" Shipments 1. Chlorine Consumed EDC Consumed C2Hd Consumed T/D T/D T/D T/D T/D T/D T/D 1970 AVG. 7 4.4 77.7 7B.7 76.1 91.4 117.2 (0.1 JAN. FEB. MAR. APR. WAV 69.8 65.7 76.4 37.8 29-3_. 70,6 75-2 31.1 72,9 54.0 77.8 TT7CT 89.3 43.5 97.1 48,3 95.8 105.6 06.4 JUNE JULY 82.2 32^ 81.4 46-7 65.5 72.7 72.8 86.3 AUG. SEP. 64.9 66.3 68.3 68 T 6 51.1 44.2 55.2 47.2 OCT. 77.3 88.7 86.8 122.4 72.3 96,6 109.6 101.8 127.6 147.5 0.0 0.0 0.4 71.1 100.9 95.6 89.7 84.4 90.4 124.0 100.6 '130.3 122,3 105.8 105.0 120.5 159.7 0.1 0.0 0.0 0.0 0.0 TJ7D 0.0 NOV. DEC. 104.3 84.6 1 12.4 81.9 114.3 88.6 73.6 106.2 79.7 138.8 112.4 0.0 0.0 1971 AVG. 69.6 72.4 74.5 23.08.. 93.4 122.7 (0.1 YIELDS Area Production Basis Cl2 C Records Production Basis CI2 C 1 Area Prod. + Trans. Credits ( Basis Cl2 1 Records Prod. + Trans. C Credits Oasis Cl2 C TO Is TO FKR-TRI 1ICI to HCI Pross. T/D T/D VDC to VDCM T/D | Tons CI-i/T TOO f Tons EDC/T TCK Tons C2H,,/T MC Tons N2/T MC [ Steam (MO# Basis) Lbs./T MC Well Water M Gals/T MC Tons Cell Liquor/T MC Catalyst Lbs./T MC IPP Lbs./T MC i-IQMME Lbs./T VDC AiBN Lbs./T TCE "Tii-Ethane" Invent ry Tons Operating Time % 83,2 79, 6 61.1 77.4 82.0 80.6 85-0 83.6 84.0 60.6 77.8 74,3 79.2 73.0 77.0 70.7 74.2 69.1 72.4 67.3 81.3 75.3 77.1 70.9 84.7 81.6 84.3 81.2 -- -- - - -- ---- --* mm -- -- *-- -- 90.6 89.3 95.0 92.1 60.0 88.3 93.0 87.5 92.8 94.2 88.9 8975 91,0 83.0 90.4 88.8 89.8 95.0 94.9 91.1 89.0 86.9 100.2 95.6 92.5 97.0 89.8 LiiQ.3 66,5 66,1 45.5 7: ,2 4.4 0.494 0.8?/. 0.000 0.172 10370 15. V 0.394 2.7 6.3 0.9 0.106 92.3 88.9 89,9 91.0 90.0 90.7 78.4 91.3 86.7 85.2 87.1 85.2 88.4 6/. .7 43,4 93.9 ... 63.1 48.3" 22.0 41.3 46.3 18,8 19,6 30.4 T9; 3 T87T vkg J4.7 0,0 8,2 8.4 0.6 ill.5 97B " 26.6 0.670 0.620 O.69? 0.709 (0.708 TO92"| 0.764 0,942 u.817 0,939 1.003 0.914 0.885 0.901 0.000 0,000 0.000, 0.002 0.000 0.000 0.000 0.160 0,227 0.C31 0.028 0.075_ 0.096 0.111 n 047 Ii?78 3728 3455 963 3870 5463 23.3 38.8 15.0 29.0 11.8 14.9 17.8 0.345 0.517 0.305 . 0.356 p.410 0.4.03 0.381 2.4 3.7 2 l 1.6 2.4 2.5 5.8 8,8 9.8 7.1 10.3 6.4 5.6 10,2 3.4 3.3 2.0 TTTt 0.2 2.4 3.8 0.108 0.078 0.113 1 0.179 p.224 0,092 0.176 89.5 93.9 50.9 16.7 1.1 0.699 0.870 0.000 0.111 5686 18.6 n i,i31 t. s. 1 s> n 5 ,4 n, 18? 3255 3933 3292 3141 88 100 100 '85 1423 il698 2739 51 199 100 _______ 1_______ 2319 2300 100 97 97.6 96.6 64.2 26.7 17.3 0.638 0.850 0.000 0.097 8047 24.7 0.552 2.9 17.4 4.0 0.146 86.0 81.6 60.8 32.2 12.7 0.672 0.866 0.000 0.095 1923 16.0 0.471 4.7 11.6 4.4 0.389 2530 1422 63 49 98.6 27.4 _20.2_ 95.4 .89.0 40.4 jL6-9 51-0 19.7 18.2 21.2__ 14.3 4.6 4.4 0.630 0.6.10 0.676 TT7H23 0.859 U . 81 a 9 i 0.000 0.009 (o.ooii 0.076 0.086 r0.104 1 2512 27 68 5270 10.8 13.8 19.5 0.433 0.504 0.435 1 .4 3.8 3.2 7.2 f\ - S 44 1.0 2.9 3.0 0.156 0.146 (1166 2194 2485 100 71 2456 85 j 1 CHt.KtlV.. . L. DIVISION LATE CHARLES, LOUISIANA "TRI-ETHANE" DEPARTS.iNT OPERATIONS REPORT \ GENERAL DEPARTMENT | ^ 1 J*K | F"3` 1 WAR- APR. i WAV \ JUNE j JULY 1 ' AVG. ! ! j i!1 j MAN HOJRS/T ,\'C PRODUCED i Production ! Maintenance i Salaried J1 !)1 0.781 0.76311.289 ! 0,707 1.431 `0.532 10.603 0.714 0,,32Ci 0,369^O..a>3 10.^ 1-1.93 10.292 fl.314 0.181 0.2 a 9- n oo'jO.'oO j 0.237 1 0.343 >0,,l60 0.212 0.224 * Total 1.84C-! l'.373 12-592 jl.AS7S2.972 `0.934 L.129 U-119 1! Contract. Main-t. Inclu. ded in Above 0.0S6I 0.000 [0.000 i '.MAN HOURS/T "TRI-ETI-IAME" @.. SSHIPPED ii i1 I ritiik. 0.0E6 0.096 10,082 j Drum n 'vra 1.055 iO-862 ! Salaried . 0.012 0.015 !rs ni i !J!i ! f f jk_______________________________ 0.000 1 0.000 jo.000 :t :i i 1 '; 0.C90 j 0.053 10.068 0,711 M`U3V 11 .130 0.013 iO.OOd i !l n'ni1 ) i i1 il ! 1ji 0.000 r 0.103 0.595 0,017 10.000 f 0.078 1.361 ft mt } )! 1 i| 1, 1 i i| jt__________________________________________ i .... j- cc HFIDE& TTTnri-- Subject tj U--X 1. w * -j Ordel ' bn"^ jutj n icisa OT n 1t 1 iun1i*e*t*r i"'et . 1 1 A*i | COl irt i 1i it --------------- 1 ! ! .. i ii [E ii ! i> _____ 1 i t;1j i\ i fif i1 \__ Co|L 0u 1* 3J 11 98 ! ! ! 1 I......... ! Ii ii !1 AUG. j SEP. 0.870 0.269 0.257 1.396 0.000 t '1.249 1.035 0.380 2.664 0.000 0.083 0.094 0.671 0.925 0.011 0.018 OCT. j NOV. | DEC. ! iV/1 j 1 \ ! AVG. i 1i j : 0.615 ! 0.451 j 0.653 1JL&2&J 0.385 0.186 P-/.SS 0.506 ! 0.183 0.142- 0.178 0.252 i 1.183 0.779 i 1.306 i 1.582 i 0.000 0.000 ! 0.000 1 0.000 i 1! 1 0.043 0.255 n.no*i ! i .........) it 0.057 1 0.072 1 0.077 ; 0.807 | 0.597 1 0.836 j 0.017 i 0.010 f 0.013 ; ii ii !! !i ! ! 1 !. i !i i )i 1 ii 1i i t i ... i i *i *1 :! !i !t i1 i! 'i i1 i i i ..... _R 1 f L_ 1 i !! 1i ___. rOR Wl4th CONFIDEirrIftV1 to protective Order judicial District Court ti o i .*> I klL j Ho. ' CHEMICAL DIVISION LAKE CHARLES. LOUISIANA "TRi-ETHANE* DEPARTMFNT OPERATIONS REPORT MATERIAL BALANCE CARRON - TONS Tutal Car non in Feed Carhon in Production 1970 Avg . JAN FED MAR APR MAY JUNE JULY AUG 864.1 765.6 866.8 1109.5 736.1 981.6 890.5 796.0 790.2 741.2 66.7" 857.5 1005.0 660.4 860,9 846.8 751.4 688.4 SL 013199 SEP OCT NOV DEC 877.4 1201.9 1010.5 845.5 625.2 1167.3 1020.5 812.3 1971 | Avg . 906.0 832.7 CathuuJ Cogs in Process SAcer. Logs in till Bottoms Mi sc. .Acct Losse s Unaccpuntudle CunnON Loss If: P n o r r s S CannoN Loading Loss 122.9 68.9 77.7 64.8 0.0 0.0 9.3 104.7 107.7 160.7 0.0 0.0 75.7 320.7 43.7 44.6 145.3 140.8 64.4 67.0 0;0 0.0 0.0 0.0 101.8 252.1 34.6 97.8 105.2 127.8 0.0 UTS 0.0 -9.4 89.4 0.0 33.2 61.7 0.0 73.3 102,7 0.0 45.2 4.1 -98.3 -56.0 -69.6 -20.1 -20.7 -22.4 4.0 18.2 -23.1 44.3 25.4 13.2 43.2 3.4 40.1. 8.2 146.9 -93.2 -98.8 -28.5 -29.4 -37.2 63.8 16.8 -14.8 15.3 Total Carron Loss CHLORINE - IUNS !otal Chlorine in Freo CHLORINE IN PnomjClION Chlorine Loss in Process acct. Loss in Still Bottoms Mi sc. Acer, Lossfs Loss from VDC Reaction Plus other Umaccountmile Losses Chlorine Loaoikg Loss Total Colorimf Loss 141.1 45.8 * 53.6 130.1 "5971r- 163.9 47.0 84.7 110.0 214.9 98.4 ~T7T~ 18,4 88.6 5327.3 4502.9 5270.8 6673.4 4298.2 6022.3 5497.5 51 31.3 49/,g. 5 5300.8 7392.4 6171.7 4967.3 5514.9 3811.2 3534.3 4716.8 534Qt5 3535.4 4334.3 4238.3 3843.0 1707.7 3^23.4 6107.4 5131.4 4080.5 4329.0 1516.1 068.6 412.9 3 59.8 0.0 0.0 554.0 1324.0 762.8 799.3 0.0 0.0 0.0 1688.0 1209.4 1288.3 1245.8 1977.4 1285.0 1039.8 886.8 1185.9 774.6 349.0 361.6 521.9 565.1 691.5 488.5 328.2 556.7 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1103.2 608.8 . -28.1 46'4.8 >36.5 913.4 860.4 926.7 723.9 1412.3 593.5 551.2 5 SB. 6 629.1 79.5 -108.3 207.7 119.1 62.2 '202.5 15.8 188.4 33.8 -174.7 299.6 78.6 -69.4 71.7 1595.6 860.3 761.7 1443.1 825.0 1890.6 1225.^ 1476.7 1284.6 1802.6 1584.5 1116.4 617.4 1257-6 TOE REACTOR SYSTEM Iron, Brers. Bottom Tor F tsig EDC ABSORBER True. Tiro FLow Chilled HCL ?F GRM 229 44 17 1173 220 45. 82 12.0 192 169 . 47 48 9 17 12. U 12.0 173 48 16 9.6 145 47 16 11.9 152 187 47 47 67 1 3,0 12.0 184 177 47 46 5---------- 21 12.0 12.3 185 . 211 47 48 22 12.5 7 ~nr.o 220 47 14 11.9 165 47 14 11.9 1 CMP. El CUTS STILL flo TTOM rEE0 Flow Vapor F 234 F 201 gpm 86.7 291 20S 85.4 292 203 85.0 295 212 83.2 297 592------ 211 207 irr.T" 89.7 292 208 91.3 291 207 86.9 m-- 294 m-- 211 J5T?-- 87.3 287 200 86.2' 283 192 100.2. 283 193 108.1 291 205 89.7 F u M ..i CONFIDENTIAL* - Subject to prly'j!1trict court o 14th Judtctal Dtstrx t' VJ7 *1 . \ 1 I t~ HEAVIES STILL 1{ up , f F rp FtOW 1 nvtnjo bv 5TE AM Top 1970 Avg. F F GPM Tons 281 235 "20.6 - "TR I ETHANE '* DEPAR1 MLrN T OPf-RAT f ONS REPORT JAN I FEB MAR APR MAY JUNE JULY AUG 283 235 i6.6 -- 283 233 23.5 - 280 230 21.7 283 231 31-9' - 281 233 22.1 231 233 19.0 -- 281 233 16.5 282 231 18.5 -- SEP OCT 281 233 231 231 17.7 12.5 NOV OEC 285 283 231 231 21.5 19.0 1971 Avg.' 283 233 20.6 VDC REACTOR SYSTEM r 1 Oh S Kt lr(D GPU li. 6 16.6 C.L. FEED CPU 'to.it 27.5 Pcjttom Column Press. 7 nip, Onno'.i VAron psi g . F F 18.3 217 131 20.1 230 130 ML RhAciOK SYS 1 EM Fi.o*s lEMP. VDC Feed hcl fepo \0C Vap. Doitom fJOlJOM gpm scff; I OF Top F 9.6 370 ~l38 101 101 8.3 271 135 96 98 6.2 12.6 . 16.7 11.9 18.1 27.7 10.1 19.7 20.0 19.8 19.8 19.0 212 ~ZTJ~ 230 227 129 ""150 ~"T50 131 5.9 .167 133 95 97 11.0 366 137 90 98 361 ' 136 96 96 12.1 339 137 97 97 FLASHER SYSTEM Tt.mp, F Dopp Kettle Temp. F STRIPPER SYSTEM Free Flow Temp . Uo-i om gpm UF VAPOH Of. Top Prcss. psig 1 OPPING Si ILL SYSitM Top Temp. op -177 175 176 17.5 233 220 21.6 11.9 230 20.1 10.3 231 - 20.9 167 165 167 ----- 177 181 178 18.0 , "17.6 230 "252 - 20.9 20-A s 17.8 231 _ 20.1 167 168 153 'mc PRODUCT Flow gpm 12.8 9.0 11.8 12.1 12.9 11.0 11.1 12.0 19.3 228 129 9.6 9.8 11.1 11.3 33.6 5570'" 36.5 50.6 19.2 229 123 19.1 228 180 19.0 228 130 21.9 231 126 10.0 312 138 96 97 9.0 280 133 98 95 3.6 271 137 98 96 9.2 3 0.6 281 280 136 131 99 99 95 91 179 16,7 229 -- 19.8 180 171 171 17.2 231 -- 21.0 17.3 738 20. Q 178 180 170 171 16.6 232 21.1 21.1 . 236 -- 22.7 168 168 168 168 169 13.5 113.0 9.1 8.3 11.9 15.1 15.1 58.8 71.2 21.7 19.8 230 228 129 129 12.7 119 138 97 95 13.1 131 133 93 91 17V 173 173 175 21.8 21.2 235 233 22.5 21.3 169 169 12.3 13-1 12,6 10.8 19.9 22 6 129 10.2 321 137 97 96 179 176 2323~ 21.0 163 . 11.8 SWLL- nu ni o^cfuinu PACW.C, to McCt, !4tV J MO 9i 1 of ** * PPG INDUSTRIES SL 013201 CHEMICAL DIVISION LAKE CHARLES,LOUISIANA PERCHLORETHYLENE -- TRICHLORETHYLENE DEPARTMENT OPERATIONS REPORT GENERAL DEPARTMENT 1970 AVG. JAN. PEB. MAR. APR. MAY JUNE JULY AUG. SEP. OCT. NOV. DEC. 1971 1 Records Per Prod. T/D a '96.7 103.8 158.2 136.2 132.8 121.5 120.8 99.2 71.7 108.6 118.9 38.2 6.8 101.4 Shipments Inventory Records Tri Prod. ...... Shipments T/D Tons T/D T/D A 94.1 147.9 125.1 128.6 148.7 134.1 61.6 V' JfO?6T9 1450.8 2195.8 2715-6 2303.5 3815.0 35<J2.1 ns.^ 107.6 119.1 126-A; 118.3 128.2 113.8 n7.5 85.5 117.4 73.8 105.0 144.1 115.1 110.2 k8-0 3250.3 3987.1 n6.8 102.6 102.8 93.6 131.1 104 ..6 98.6 36.6 3311.2 3755.8 *2954.8 r2029.J 117.1 n8.2 42.1 n .7 1A7.3 125.3 113.2 AA..2 106.3 2780.1 im .8 105.6 Inventory Area Per Prod. EDC Cl, as Cl, Tons T/D T/T T/T 28S0.2 2517.9 2752.0 4457-1 89.4 103.4 153.1 0.474 0.440 0.354 141.1 0.383 0.361 0.375 0.319 0.352 4892.9 4314.7 138.4 120.9 O.424 0.495 0.391 0.457 4273.< 4707.0 4987.1 106.8 101.5 83.7 0.520 0.489 3.397 0.487 0.494 1.412 4079.8 3859.1 *d 995.8 *1789.; 112.5 n7.2 36.2 n.5 0.361 0.411 0.302 1.093 0-A1 9 O.A61 0.432 0.345 3710.5 102.2 0.472 0.412 Cl, as HCl T/T 0.001 0 0 00 00 0 0 0 0 0 00 NHn LbsJT ... Area Tri Prod.____________T/D 5.0 4.9 2.9 3.5 2.3 3.7 375" 3.5 3-9 118.6 107.6 126.0 127.0 120.3 126.4 115.0 116.7 90 4.0 4.0 T79-- 5.4 123.3 n2.9 9.1 3.9 102.2 EDC Clj ss Clj Cl, as HCl _ NH3 * Total Area Prod. 02 N, T/T T/T T/T Lbs^T T/T T/T o*5Sl 0,555 0.447 0.228 0.236 0.201 (0.001 0 0 2.9 3*2___ 2.9 0.232 0.219 0.215 Q.081 0.008 0.079 0,483 0.222 U 3.1 0.225 0.076 0.536 0.246 0 2.7 0.230 0.080 0.624 0.288 0 3n n.2/,1 0.097 n.A57 0:307 0 3Tn 0.242 0.081 0.618 0.312 0 3.1 0.232 0.062 1.501 0.456 0.260 0.264 0---------- 0 3.1 3.0 0.225 0.180 1.0A5 0.044 0.519 0.291 0 3.8 0.226 0.023 0.382 0.273 0 1^2 0.225 0.059 1.380 0.596 0.217 0.260 00 "157J~ "572 0.102 0.214 '1.381 -o:i7ir Catalyst Lbs./T 3.06... 4.76 1.27 2.95 1.48 3.11 3.80 4.32 7.27 1.60 2.19 14.72 69.74 9.77 400 # Stm.{actual} LbsJT KWH/T Total Stillbottoms T/T 3244. 4197 3170 68.1 61.2 51.3 0.334 0.572 0.459 3144 3276 3390 54.7 ` 52.4 62.2 0.391 0;'461' 0.478 3574 3633 4652 48.6 65.4 [76.2 0.599 0.627 1.494 2990 5570 0.382 3385 69.6 0.595 4081 ` 5862 104.0 179.8 U7 722 6.089" 3780 74.2 0.489 MAN HRS./T RECORDS PROD. Production Maintenance Salaried Total Contract Man Hrs. Included 0.373 0.369 0.135 0.877 0.002 0.388 0.518 0.128 1.034 0.000 0.276 0.196 p.107 0.579 0.003 : 0.302 0.298 0.379 "0.116' 0.797 11.000 0.226 0.114 0.638 0.000 0.334 0.293 0.110 0.737 0.000 0.281 0.331 0.105 0.717 0.000 0.365 O. AA7 0.130 0.9A2 o.obo 0.460 0.340 1.804 U.392 0.163 0.125 17427 " 0.857 0.000 0.000 0.367 0.303 0.124 0.794 0.000 0.506 2.186 0.352 3.044 0.000 -- -- - -- "0355" 0.552 0.143" 1:051 (0.003 MAN HRS./T SHIPPED ___________ Bulls______________________ Drum Salaried 0.069 0.017 0.651 0.694 0.008 0.005 0.056 0.671 O.uu? 0.056 0.536 0.008 0.044 0.247 0.004 0.037 0.850 0.004 0.055 0.038 0.079 0.580 1 .Ail 0.550 0.008 0.006 0.010 0.033 0.853 0.005 0.040 0.049 0.886 0.709 0.008 0.014 -- -- TCE T/T PER AREA PROD. TCE T/T TRI AREA PROD. CL18Q 0.181 0.301 0.227 0.229 J-180 0.209 0.166 0.1378" 0.163 0.186 0.244 D.239 0.236 0.264 0.210 0.098 0.206 0.235 0.308 0.302 0.295 0.444 0.560 0.046 0.729 0.007 0.222 0.281 ^Includes purchased r't > i | YIELDS \ Area Production Basis ! ci2 c Records Production Basis Cl, C 1 CHEMICAL DIVISION LAKE CHARLES,LOUISIANA PERCHLORETHYLENE --TRICHLORETHYLENE DEPARTMENT OPERATIONS REPORT 1970 JAN. '( FEB. MAR. APR. j MAY JUNE JULY AUG. SEP. AVG. OCT. NOV. DEC. 1971 AVG. 90.2 90./,. 89.0 92.2 9u.9 92.6 90.7 92.7 V0.5 92.7 90.4 92,8 88.6 87.8 94 ,,2 90.3 89.9 93.0 86.8 88.3 94.4 -88.6 90.5 87.4 89.2 91,3 93.9 90.6 88.4 94.0 93.0 88.4 87.9 85.6 85.9 89.5 89.1 95.7 95.0 86.8 90.7 92.7 96.9 83.9 90.5 _ 84.5 90.8 . - 09-.1__ _92^Q_ 88.9 _ 91.8 ` -- SL 013202 -5 CONFH . of i] iubjec 14 til , :--TO" r p |J|0 i. 1 --NO-:-- r*--ui* n9 X -*n* A* |ya Br - r i rF ler ?ourt . ' . OH......... # 1 L. MATERIAL BALANCE CARBON - IONS Total Campon in Feed Campon in <Jnstap. Product Process Loss nr Difference 1 Accountable Process Losses OL OTffjClAN frACTOR Ml SCFI. L aneous Sun total U . cn a ehat count Process Losses Catpon Loading Loss Total C*nru>N Lossrs CHLORINE-TONS Total Chlominl in Feed Chlorine in Unstao. Product Process Loss nv Fjifference Accountarlc Process Losses Oloadoan fiE ACTOR Mlscellaneous Sun Total Unaccountable Process Losses CiiLoniMr Loading Loss Total Cm Lon hie Loss -- SL 013203 PiJ L^ I O i iv tL 3 / CHEMICAL DIVISION LAKE CHARltS, LOUISIANA PFfiO-'LORETHYLENE.TRICJiLORETHYLENE DEPARTMENT OPERATIONS REPORT 1970 Avg. JAN EEB MAR APR MAY JUNE JULY AUG SEP OCT NOV 1536.8 1900.0 2113,1 2011,7 2085.6 2110.0 1976.1 2049.0 1630.3 1707.7 2020.0 778.5 1372.0 -1759.0 1916.i 1895.2 1883.8 1897.9 innt. A 191*1.9 1432.8 l635_f 1919.4 704.7 166.8 141,0 197.1 116^5 201.8 212.1 17V.5 133.1 197.5 77.7 10Q-6 73.8 3.7 163 .1 20.0 166.8 0.0 0,0 121.0 20.0 ' 141.0 0.0 U.U 0.0 177.1 96.5 20.0 20.6- 197.1 116.5 0,0 0.0 o.p 181.8 20.0 201 .8 o.p (733------ 0.0 192. r 151.5 20.0 20.0 212.1 171.5 0.0 0,0 0.0 0.0 0/0 113.1 177.5 52.7 20.0 20.0 20.0 133.1 197.5 72.7 0.0 1170----- 0.0 0.0 80.6 20.0 100.6 0.0 0.0 53.8 20.0 73.8 0.0 4.1 13,9. 24.8 -26.9 -4.2 10.8 *-*3.8 6.5 6.6 47.3 -26.4 -36.7 170.9 154.9 221.9 89.6 T9775- 222.9 157.7 139.7 204.1 120.0 74.2 37.1 DEC 1971 A V FT . 602.1 1748.7 115.5 1573.3. 486.6 1Z1..4-. 0.0 0.0 466.6 155.4 20.0 20.0 486.6 175.4 0.0 0.0 31.1 2.8 517,8 178,2 -- 7632.3 9215.8 10374;. 10645.f 10719.c 100855 101734 7913.6 9062.2 10591.9 AQUu& 25`5.0 881576" 6896.2 8498.3 9457.7 9633,2 9432.0 19408.0 88J1.3 9070.0 6997.1 8114.3 9434.3 3394.8 579 q 7735.9 736,1 717.5 .247.7 741,2 1213.8 1311.9 1274.2 j.103.4 916.5 947.9 1157.6 650.0 1975.1 1079.7 20.3 615.8 100.0 736 .T 0.0 0.0 617.5 100.0 717.5 0.0 O.C 847.7 100.0 547.7 0.0 0.0 0*0 0.0 7770 0.0 0.0 641 .2 1113.8 1211.9 1174.2 1003.4 816.5" 100. 0 11)0.0 100.0 100,0 100.0 100.0 74T.Tr 1213.8 1311.9 1274.2 1103.4 916.5 070 0,0 0.0 0.0 0.0 070 0.0 0.0 . 847.9 0.057,6 100.0 100.0 947.9 1157.6 0.0 0.0 0.0 550.0. 100.0650.0 0.0 0.0 0.0 1875,1 931.4_ IOO. 0 107). 0 1975.1 1079.7 0,0 >0.0 22.1 69.9 147.5 -149.8 -25,1 56.6 -103.7 53.7 73.4 23Q.4 -106.4 --211.1 204.0 1975 758.2 ?87. 4 1095.2 3 91 .4 1188.6 L368.5 1165.5 1157.1 989.9 JIZIU 10^. 438.9 2179.1 1099.2 row FTDKN'T TAT, : j R11 h j (' V L 0 P r n T p rrt- i VP Orrlrr i I ( 14L i-J.ufli IJjLLJ? i. s t r i c t Com i-i____ ' No., 91-1145 Rf,, .. -- iO-- I 1 '.J * I ' -I I I L. t .'"CHEMICAL DIVISION f Ju^far Drs,v*'-'!"r LAKE CHARLES. LOUISIANA PERCEILORETHYLENE* TRI CHLORETI IYLT.NE DEPARTMENT OPERATIONS REPORT REACTOR NO. 1 1970 Avg. 'in S T ff r A; 1 Time Hrs. 8127* D i sCu. Purpsi c JAN 711 FEB MAR APR MAY 659 737 630 711 JUNE 720 JULY 721 AUd 631 SEP OCT 712 711 NOV 262 OEC 0 " 1* 1971 Avg . 730? it'tr. F Vapopi /rn Liouor Do* nit mm Out - P.90_. 287 189 . 115 283 175 282 276 175 167 275 7267-- 266 461 179 163 281 160 289 271 512 549 272 586 -- 277 489 - Src. Como. Disch _1Q____ 22 -56 55 63.: 70 79 76 11 47 42 -- 51 'atal'st Charged Lns. 51719' 1592 1981 _ ... 4896 2720 1200 5056 6500 13707 1911 3128 7013 52710- >t(i.vsr Fnr-.i Ctntrifix Lns. 5-1719' 1 CO? 1981 . 1896 2720 1200 5056 6500 ! 3707 ^ nu. 3128 701 3 52710- : loi, C-TM 1 DC 8.6 10.8 13.2 10.1 10.7 12.2 10.9 10.6 10.5 10.1 10.5 10.3 SCFH Cl? 6215 71.70 7527 8152 7836 7816 7215 6913 6511 8501 6680 5856 -- 7116 ____________ __________________ 9571. 10632 10350 10?6f, 10262 10020 9771 8810 9612 9271 8464 7125 -- 9580 ER-TnlflATIO Tn i Tni in Crude 1.00 1.16 1.61 1*60 1.19 T:25" 1.35 1.09 1.29 % L86..32. 90 03 91.13 91.78 91.71 91.12 90*02 89.11 83.80 86.8 REACTOR NO. 2 Sn Stream Time Has. 8.53.1* 610 672 --wr 696 7/i A 720 621 0 385 rrMp. <>r Vapori/eh Liouoh hoatihrm Out 295 293 288 280 278 273 270 256 - 576 165 " 1G9 ' 513- 521 53O 512 171 - 3'20 559 1.57 1.24 89.3 83.7 73.1 "235 325 333 578 556 1.36 18.76 117 6368- 312 293 607 528 Sec. Cono. Oisch. ATAi.VST Cm A RCr [> at At. vst FiuiM CrriTRiM* LOW C-FM EPC scru CL 2 LBS. ns. ----- -----1-- - 0c, aOfsj CO 39 28 16071- 7992 16071- 7992 C.3 . 8.2 6315 1)131 9568 8836 o 'rn.Tm Ratio 'ER 1 tri tn Cuuuc -------------------------- 0.92 1.09 _J J CO --1 2*62- ^Totals 32 1961 1981 iL-iL 7398 10868 37 38 1896 2200 1896| 2200 9.8 7779 75U 10611 9790 10 1200 1200 9.1 7811 11 12 5056 3229 5056 1 3229 9.6..... 9.7 7273 7155 -- -- -- 10111 10756 9865 - 56 2121 2121 12.9 9460 52 3127 3127 17.2. 9002 10011 10447 1.60 1.81 1.65 ` 1.60 1.11 1.39 0.52 1.01 1.36 -2102. --22*21 91.71 . 9.0-12 92.U. 78-99., 2ks5SL 80.2 15 7656 7656 .14.5 7703 10380 1 .09 77.1 18 12 8928 51692* 8928 51692* 13.2 11.3 6267 7648 9133 10109 1.33 - 8.5^., CO^^V^tive Or^et CV, 0' to TuOicvaL CouTt it 1 tiu- 91-114- : CUEMIC/P^-.VISION LAKE CHARtES. IOU1SIANA PERCHLORETHYLENF.-TRICHLORETUYLENE DEPARTMENT OPERATIONS SL . 013205 REACTOR NO. 3 On SmrAM liHf 1970 avg. JAN Hrs. 7207- 618 FED 659 MAR APR w 726 MAY 728 JUNE JULY AUG 673 766 651 SEP OCT 708 766 NOV 310 OEC 91 1971 | AVG. 7166* rr*ip.F VAPortirrn Liouon Dokthcpm Out 291 330 366 365 360 332 826 326 316 327 JW- 326 306 336 . A91 568 502.. 501 681 676 670 656 655 673 682 661 662 695 * Sec. Cond. oiscii. Catalyst OiAnsro Catalyst rnou CcHTRiriY Flow GF'M EPC scm cl? Los. lbs. 02 32 26 A 3629' ] 8392 A3629^ .16392 9-0 13.0 6051 6765 26... 1986 1986 16.0 6612 11326 11867 -1 Or?xl A| 28 3S 6896 2200 .6896 2200 17*3 17.5 5.175 5739 33 7395 7395 17.0 6510 36 5056 5056 17.1 W55 15800 16367 16265 12328 37 65006500 15.3 9381 38 13707 13707 16.1 . 9230 38' 3066 3066 12.2 9562 60 3128 3128 12.6 9986 39 8298 8298 16.1 9796 52 35 17856 9267617856 92676* 13.2 15.3 6233 7866 J 1993 12323 12637 10600 Tno9~ 8639 11661 Fttt-Tni fUttO I'rn < Tni in Cpuoc 1 % 0.97 0.58 l.Cl 1*15 1.20 1.13 0.88 0.96 0.89 1.09 1.11 63.77 78.31 85.36 . 86.19 82.26 80.29 76.59 76.11 75.93 79.97 79.0 1.19 -- 80.7 1 3 .02 60.0b REACTOR NO. A i On sirea Time Has, 8636- .766.... 672 706 686 726 661 766 686 706 756------ 233 0 7265'" , Hme, pf" VAPoni7fft Liouon Doatutom Out 290 267 285 232 270 267 278 278 233 262 263 1M 666 - 696 . 682 506 522 511 696 U'i5~ SI 6' 556 250 579 _ 271 ... 509 Die. Coho. Discit. Catalyst CtiAncto . lbs. Catalyst rnon Cent-iifik . lbs. ELOfl t-l'M EDC SCFll Cl i 6? .mf 6,3 . 6361 'P .1 692 1592 9-6 96b 6 59 3.966 1936 .9wl 6736 t 57 66 76 6896 2200 6375 6896 2200 6375 8.2 9*0 370 7966 3356 8562 80 5056 5056 8.5 8139 75 6500 '6600 7.5 7776 31 6853 6853 8 .6 69 1966 1966 8.6 6680 67 3128 3128 7.8 5783 *637" 6371 5.3 5652 -- mm | 59 l- 6899 " 'A 6899* 8.2 7 J05 _______________ 10396 1 10072 Pca-Tm Ratio I'm i Tni in Crude 1.01 ;1.30 . % 67.99 738.33 * Total 9606 , a. 67 187.50 10116 10962 i 1 1.82 1.88 j 91.13 $7.85 10276 ( l 1 9869 '9921 9900 * 1.36 87.98 11.35 0.97 91.98 88.26 8865 7651 1.60 1.36 88.53 89.6 6883 _ "I 7iT~ -- 83-0 9627 1.68 89.12 REACTOR NO. 5 1970 AVG. . U(C>. A DIVISION IAKC OlAfUrS; IOUIjIAHA PERCHLORETHYLENE-TRICIILORETUYLENE DEPARTMENT OPERATIONS REPORT JAN FEB MAR APR MAY JUNE JULY AUG 6EP OCT ON STflEAM TIM It HR3. SATA* 744 660 705 696 729 713 729 631 697 744 TCMP. OF VAPORIZER LIQUOR oowtmcrm out , 206 ~W\ 273 274 A90 696 512 494 271 517. 278 278 *5"2"3* ' 539 277 500 P7A 933 /t36 snn 259 616 SEC. CON D. OISCH. CAULYST CHAMCCO CATALYST FROM CCNTRIFJX FL O if G PM EDC CHI Cl 2 33 - 24 LOS. "333IV; 1592 LOS. 53814* 1592 3.2 9.7 636a. 6978 27 1966 198A 10.0 7094 28 35 4896 2200 liS%~ 2200 d 8.5 T7T9 SI3? 40 35 3650 5055 3650 5056 8.6 9.3 9ZE0-- S99S 30 6500 6500 8.6 77A5 . 32 6353 6353 9.3 8150 55 1944 194A 8.1 8040 52 3128 3128 9.5 5972 Oi 10310 9737 13149 10712 10639 1057A 10429 TOOIO 10176 9376 7535 Per-Tri Ratio Per + Tri in Crude 0.96 1.12 1.71 2,15 - 2.02 1.5ft 1.10 1.35 0.96 1.30 1.39 % 88.17 92.2A 9A.0A 93.09 90.24 37.67 SY.V5" 91.23 37.50 88.53 87.9 NOV OEC 216 90 261 . 211 602 .. 1971 AVG, 735'A* 267 __ 526 47 5782 5732 5.8 6223 707L 1 .02 86.1 55 17856 17856 5.1 4975 38 . 1441* 61441s 8.4 7441 6300 9642 - 1.43 - 89-66 DRIED UNSTAB. 7R1CHL0R nH K-iI Teat - Oxides nom 7.0 MEG. DRIED UNSTAB. P5RCHL0R dH Nal Test - Oxides ppm .* 6.3 MEG. __________ ___ _ 7.0 7.0 6.9 PEG. KEG. 6.8 KEG.. l77T----------- 7.0 7.1 keg;"' ees;-- NIT,. 6.8 .Kill 6.9 KEG. 6.9 ; 6.9 KEG. NEG. 6.9 . 6.9 6.9 wise. NEG.- NEG. 7.1 NEG. 4 7.J NEG. 7.1 NEG. 6.9 7.0 7.0 NEG. NEG.___ NEG. 7.2 NEG. -- - . 7.0 NEC. . 7.0 A EG, ... 6.9 NEG. SL 013206 * Total CONF 1DENTI MilSubje ct to Protec tive 0 rder 0 F. 14th Judic ial Di strict Court No. 91-11 45 _J______ J r 0 fi if. i* . tiu -j REFRIGERATED DRINE Temp. F Warm IOut) Colo (in) CONFIDENTIAL: I'i Cj if .T H\f UJ Subject to Protect] t,rj ' CHEMICAL DIVISION LAKE CHARLES, LOUISIANA of 14th Judicial Distriul No. 91-1145 PERCHLORETHYLENE * TR I CHLORETHYLENE DEPARTMENT OPERATIONS REPORT wuurfe 1970 Avg. 16 10 JAN .9 3 FEB JLA____ _9 MAR 17 12 APR 19 13 MAY 19 12 JUNE JULY 18 21 10 12 AUG 19 -- SEP 26 35 OCT 25 24 NOV 28 22 DEC 25 24 1971 ; A VG . 1 0 16 ' DRYING STILL Temp, F Bottom Top no etom 1'ncssunc psig PER-TRI r c. f o p-'rri.wx Bottom Tlmp. Ovr rtHCAD TCMP . STILL gtm C.pm F F HEAVIES STILL Fr r n RErLUV Bottom Temp. 0vt nor:ao Temp . gpm GPM uF F. PER STILL Frni f:r r lux rtrr.voi r Fo v.'ush Column Bottom Temp. OvrnutAO Ttmp, gpm gpm GPU gpm F llF rrrD ITfILUX TRI -SI ILL BOTTOMS r?r r vri. E Bottom Temp. Ovepiif.Fi!> Temp . Gpm gpm GPM gpm F F 201 160 1.14 201 148 143 114 1.12 1.00 32.4 .36,6 292 189 ' 32.2 39,0 29.3 26.0 287 288 188 190 15.4 95.6 3U 261 12,6 17.8 97.2 33.0.6 343 363 262 270 ..il .3. 0.86 12.2 286 245 ..11,2 15.1 14.6 14.6 0.52 0,38 3 4.7 14.0 295 287 245 253 19.0 62 14.3 1.94 230 152 . 18.5 18.4 85 67 15.1 15. *7 1.73 x ,46 230 236. 147 146 --- 147 144 1712 1;09 -- 148 1.35 -- 152 149 1.42 1.67 41,6 27-5 286 186 41.5 29.1 285 186 39.9 33.9 295 190 36.0 36.1 34,0 85.0 293 294 190 190 20-? 20.9 139, C 145.0 338 335 26? 257 20.4 138.0 337 265 187 4" 19.3 116.C 98.0 336 332 "265 265 16,4 15.7 14,6 14.5 0,97 1,05 14.2 13.8 283 284 252 251 14.5 13.8 0.93 11.7 238 253 13.2 14.5 0.46 11.2 289 254 13.8 16.8 1.08 9.5 287 254 19,4 15-2 67.? 60 15.1 15.2 .. 1 ;fi> ,1.80 272 282 145 141 id. 9 70.0 15.1 2.10 237 144 16.9 16.5 65-0 66.0 14.3 14.8 K90 . 1.97 235 236 145 145 - 148 1.88 189 152 1.61 184 141 1.73 180 139 1.72 16 5 33 0.85 32.4 33.7 292 139 39.0 j.n.T 2m 191 41.6 38.8 303 186 39.6 28.7 294 186 31.8 36.1 293 - 16.5 91.0 335 262 19.1 19.4 10.2.0 106.0 343 341 267 IE5 i(;,i 126.0 339 266 20. 96.3 270 241 11.0 13.9 13.7 16.8 17.'5 18.1 1.10 T739" 1.46 . 10.0 10.2 10.7 7235 287 287 "249-- ~Z50-- 248 4 3.0 17.0 1.71 10.4 286 246 9.7 7.1 3.90 -- 250 226 15.2 69.0 13.5 1.91 237 144 19.4 66.0 J3-P 2.33 237 149 17.9 62.0 13.8 2.84 236 145 19.1 67.0 14.2 3.00 239 140 15.4 15.8 18.8 6.10 223 188 178 134 1.38 37.6 32.7 292 183 I ! 1 18 * T__ | M5.6 333 284 13.4 15.0 11.9 264 248 - .17.6 62.3 14.9 2.41 234 148 -- si 013207 , o a... - TRI TOPPING STILL HriTTOM TrMP. Ovrmir.AO Temp. F F r' CHEMICAL DIVISION Jake Charles, Louisiana PERCHLORETHYLENE-TRI Cl ILORETHYL ENE DEPARTMENT OPERATIONS REPORT 1970 Avg. 199 195 JAN FEQ 199.. 204 195 197 MAR APR t97 197 193 193 MAY 201 197 JUNE JULY 200 202 196 200 AUG 201 197 SEP 199 197 OCT 201 197 NOV 200 196 OEC 195 190 -- 1971 Avg . 200196 NEUTRAL 1ZAT 1 ON *'e Rciaon NH3 Tloc To Stg. psic gpm Tn1CHEOR RH 3 Flow To Stg. PSIG gpm 7.1 10.7 2.3 13.1 8.4 5.a 9.2 ii. a 2.5 2^ 12.9 L13.2 . 6.5 6.5 it. 7 11.7 6.3 6.4 5.6 11.7 11.3 S.7 6.2 5.a 5.2 8.6 6.4 R.R 10.it n .o noun-- i.i 1.6 1.3 774-- 1.2 1 mU 1.0 1.9 1.6 8.1 2.1 13.it 11.4 11.6 13.1 11.9 9.9 10.7 ii.a 15.7 10.1 SL U13206 * C'ONFll ) fjr* .1 i- ** 1 , ( lubjec ; ' to T - of 14th Jiicli'cn 3 J_ --mrr~ ) t-' UIp -ritT ** S*. ier lourt FORM NO^TA 2 t t-1 GENERAL DEPARTMENT G?.A DRY HCL llfl Solo T/O fpiinmnc 10 02# T/t) Hvonnorn to 6?A MCF/D Ci.? T t I I r 1 LUCY Ci_2 Yitlii % % 1970 Avg. PPG INDUSTRIES CHEMICAL DIVISION LAKE CHARLES, lOL'ISIANA HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT JAN FEB MAR APR MAY JUNE JULY AUC. SEP OCT 47.5 49.6 49,5 45d 47,5. 49-6 MU5_ 45.1 537.6 564.7 570.6 523.6 51.9 43.1 42.6 53.1 42.7 46.0 49.6 51.9 43.0 42.6" 52.q 42,7 46.0 49.6 590.4 506.6 535.1 612,6 518.7 5A5 n 571.6 97.2 97.2 97.2 97,2 97.2 97,2 97,2 97.2 97.2 97.2 97.2 97.2 97.2 97.2 97.2 97.2 97.2 97.2 97.2 97.2 97-2 97.2 NOV 1 DEC 19A7V1G, 44.0 35.5 46.1 44-0 35.5 46.1 527.0 449.0 544.8 97.2 97.2 97.2 97.2 97.2 97.2 (. liCLSS Hz Too.; rx,Ai'ON HCt. Souti Ml r h,/Ton ltd. Solo Kivi 1/1 on Will water M Gal/(Ton llpSO^L os/ron % 3.6 3.7 5.3 6.1 5.2 8.2 14.9 5.9 11.0 6.5 5.3 9.5 15.5 8.1 1-1X30 1.000 3 .000 1 .020 1.000 0.997 0.995 0.996 1 non 1.000 1.000 1 .000 1.000 1.084 11.3 -11.3 JT7B 11.4 11.8 12.6 11.5 12.2 12.3 11.5 12.0 12.6 11.9 316.6 301.6 260,4 334.5 280.4 352.6 262". 7" 237.8 368.3 339.9 353.5 400.5 467.6 331.7 4.5 A,_ 6.6 7.2 20.9 19.6 20.3 ?qri 4.1 4.0 127$ ' 5.0 7.1 5.1 4.3 13.9 31.6 3074... 30.0 37.7 33.1 34.5 5.5 7.0 30.6 26.Q r"tiz MAH HC'IJFJS/TON HCL Fnnnuc.r ton MA 1 IIIFIIA'ICE Saladitn Total >ntuac r Mmnt. inclloeo in Above od'ik ncid Sbronf; Acid vt.Jg wt.$ 0.293 0.443 0.070 O.B06 0.026 0.290 0.374 0.062 0.726 0.000 0.269 0.457 0.069 0.615 0,000 0.316 0.524 0.079 0.919 0.000 --- - 33.4 32.4 31.4 31.5 0.253 0.245 0,065Q,568; 0l024 0.326 0.707 0.072 1,107 0.000 0.314 0.823 0.C33 1.220 0.000 0.253 0.347 0.061 0.661 0.000 0.348 0.890 0.060 1.318 0.069 0.302 1.125 0.073 1.500 0.359 &zza... 0.578 0.295 0.378 on 0.982 0.066 "0773 0.091 0.922 1 .499 1.451 0.113 0.74Cj 0.000 0.304 0,662 '0.073 1.059 0.109 31.8 *. --* 31.4 30.7 31.4 -- -- 30.7" 31.0 30.8 --- - 3 1.4 30.8 31.2 si 0n 1I* 3O 2O 0flQJ 1 , cor FI DEN' 'IAL: Sub- ect tc ProU ;ctive Ordfir of 141 h Judj cial ] ?istri Nt >. 91-. 145 ----------- FORM N A 2 t I- 2 1 general department i 1 PRESSURE j Li nr Out, Dl snti. Co^r. Suct l on PSIG PSIG *' H?0 1970 Avg. 19 35 -32 PPG ir Zi STRIPS CHEMICAL DIVISION LAKE CHARLES, LOUISIANA HYDROGEN CHLORIDE DEP'AIUMENi OPERATIONS REPORT JAN FEB MAR APR MAY JUNE JULY AUG SEP 24 24 25 29 31 33 --32 -30 -20 25 24 25 23 24 23 33 32 33 35 33 34 -31 -26 -26 --33 -32 -34 OCT 22 33 --32 TEMPERATURE F No. 5 tlmiNt: rt , Gas ruou Phimahy Gas rnoM Secondary No. 2 FlURNm 73 - 65 61 35 33 34 37 70 74 -- 33 34 -- _ 98 95 61 53 50 46 Gas tnow Primahy Gas lrom SrcnwiARY Compressor Oiscnaroi: IlT ho, 1i Bnurner PmFm-f'O.iintir 104 103 99 J03 98 105 109 104 98 - -- 37 32 33 37 33 33 42 AO 49 - - 277 253 250 256 258 260 268 256 260 247 244 as 89 88 83 76 --G.TS From SnennHn i~y /.a 39 55 48 "53 Cell Liouor Lrs/.Ton RCl 9.6 12.6 21.6 4573 0 5.6 11 A 9.7 2.6 0 9.6 LVrll Watch To HCl gpm 229 219 221 239 267 273 285 262 215 153 1 A3 OPERATING TIME No, 1 RuRiirn No. 2 DiiRnrn Compressor No, 5 CoiripresGor No.3 (DryJ Compressor No.4 No. 5 Burner 1667-- 0 0 7636- 744 656 8226-- 744 658 5879-- 73 70 7322- 102 198 6882- 744 550 y 691 737. 167 676 623 . 0 720 720 256 720 720 254 667 683 638 684 676 231 279 690 632 430 0 152 554 691 732 96 0 744 714 696 32 312 0 744 587 705 0 0 T% 744 0 744 412 744 681 No. 2 Absorbers No. 3 Absorbers No. 4 Absorbers 8250- 679 557 763 714 744 - - 7703* 679 565 666 714 ~703 _- 7818* 679 545 743 714 "703-- --_ - -- -- -- NOV DEC 1971 1 avg, i 23 24 32 33 -28 -34 24 33.... . -31 87 AO 37 . _ 237 39 22.3 93 39 253 67 38 12.6 159 174 79 40 101 38 254 oi 44 15.6 2.1.8 706 0 677 150 636 683 ' 526 17 571 0 576 575 ---- 4303* 4957* 8363* 2*:82* 7111* 5802*- 34373312* 3389* SL 013710 -- i *Totals comp: TTEFFTT1 Sub jet; :t to 'rotec TfTTrr tt LTtet-- ol 14th J LI cl i c .a'TTTi jTTTcrt Court ----- FToT 91-11 T3-------- FORM N A 2 11-3 1 ; GENERAL DEPARTMENT 1 62B WET HCL i Wi t HCi. Pnotiucio i ! 11 i. 1 1/0 1970 Avg. B2.1 P P L-; IN > I i\ I b 6 chemical division ' LAKE CHARLES, LOUISIANA HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT JAN FE0 MAR APR MAY JUNE JULY AUG CONPIDEKTIArr Sub-joct to Protect*'-.' 0f 1 J*.i. , .. .' j* L>J.SttAE.L .XT3----- court SEP OCT NOV DEC 1971 Avg.. 39.7 99.3 89,0 104.3 98.1 94.9 53.2 80.0 90.3 112.7 96.9 85.3 91.1 iICl Sold as Muriatic 1 1 I j ! i [ Excess ll2 i j Cl2 Tons/Ion Her HCL Pnoo | 'R KCf-ATM | N. Tans/Ton | f ir( (actual) M Lnr/Ton 1 Wwill atch M Gals/iph | II .,50^ Lus/tcin KV.ii/rcH 1 KWIi/Ton (Drv HCI) OPKimriNG TIME | No 3 fiintm it \ No 4 niiPNi n | MO 5 nilHMI R No 1 Str IrrtH ! No 2 StntrPF. n No 1 Compressor 1 no 2 Compressor \/ Cj 1 No 3 Compressor 1[--.-.-.----------- -- -------- _^J T/0 39.5 40.1 44.4 43.2 %-- ---- - - 0.133 2722 3.3 2.3 . 55.0... --- - -- 0.072 0,039 0.0/2 1743 1661 1606 0.9 0.7 2.2 3.0 0.9 2.3 23.1 23.0 27.0 - 0 _jQ__________ _Q__________ _6862* 6419* ..56007587* LG* 0 0 0 543 673 744 614 73 0 0 0 672 423 656 331 422 0 0 n 476 709 744 744. 0 ^Totals 48.8 50.0 46.4 29.8 41.4 --- -- -- -- 0.064 1656 1.4 3 .5 21 1 --- - 0.066 0.097 1413 1723 ] .4 1.5 2.6 0.9 21.7 23.2 -- - 0.197 1705 0\ 7.1 >,n,n *. * 0.111 1 .0 5,9 26.6 _ 0 00 0 00 0 00 720 481 668 716 686 675 536 668 563 586 594 672 0 00 00 n0 n0 397 549 167 471 6A5 554 432 725 00 41.2 -- 0.101 2236 0.8 3.6 24.4 0 0 0 645 633 600 624 105 49 .A 47.4 '38.0 43.3 -- - 0.072 2164 0.7 2.2 J8.9 -- --" 0,086 0.095 2295 2529 0.8 0.9 4.0 22.7 25.0 -_ -- " 0.02L. 1796 ] .1 2.9 .24*5__ 0 00 0 0 00 0 0 00 0 720 712 622 7205"* 735 640 616 7373 559 643 736 7593- 669 614 726 7381- 412 0 0 1012* FORM U( \ 211-4 GENERAL DEPARTMENT 62D WEi: HCL REl RIGERATION UNIT P n c o r> i > ri r P S1G Su-cti on Di scHAnr.t Sr al Tempi, nature s Op (Jut,ie Ik nrinr Out Amps 1970 AVG PPL-- iNW^lRihb CONFIDENT!*^ CHEMICAL DIVISION IAKE ClIAK1.ES, LOUISIANA to Protective m-T . of X4th Judicial District Court HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT No. 91-1145 JAN FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 1A9v7g1 : -23.8 -23.3 -23. c 10.1 8.6 7.9 22.3 21.6 21.4 -23.5 -22.1 -22.1 -22.9 -22.9 -21.1 8.2 9*2 10.4 12.0 11.1 12.3 21.2 2b.6 21.0 21.1 21.0 22.0 -17.5 -19.3 -13.3__ 11.3 26.1 27.0 -21.7 -20.3 9-2 9.5 27TCT 26.9 -21.6 10,2 23.1 24 27 27 30 24 27 37 33 w~ 40 38 34 34 32 20 21 23 28 21 23 34 01 jn 36 36 34 36 30 155 .151 146 147 152 154 158 155 157 157 154 150 149 153 NO- i STRIPPER F to*s SmoNG acid Feed gpm STEAM Temperatures Lns/HH op Top tVTT TDM Trim ary 40.7 42.9 5 462 5915 237 236 _ 3/, 32 42.9 6133 234 - 33 42.8 6121 234 38 39.8 42.1 43.7 5691 5946 5624 233 234 236 --- 33 34 44 42.0 5939 2L0 A6 45.6 4726 243 47 44.9 6988 249 50 49.1 7528 251 45 47.5 48,4 44.3 6726 8059 6033 251 253 241 40 39 40 NO- 2 STRIPPER rut,!, Strong Ac ID FEED GPM Steam Lee /Mb Trwr r ha i unr.S Op Ton FIOTTOM 1r in i ady 40,1 49.3 2834 3566 242 ' 246 -- 33 29 43.6 45.2 33.6 -40.9 35,0 2970 ~JlZo~ 2682 3106 2310 248 241 241 244 245 - -- ;- -- - 31 36 32 36 45 35.1 2349 247 -- 48 26.1 2259 248 - 47 22.7 3810 249 49 14.2 4305 251 -- 44 'JETT 48.9 4059 4482 250 249 ---- 38 39 35.5 3256 247 -- 40 MAW HOURS/TOW HCL f'nnnticTlON Ma 1 N T TNANCE Salaried TOTAL Contract maikt. Included in Above 0.200 0,142 0-117 0.024 0.053 0.035 0.370 0.201 0.008 0.000 0.122 0.037 0.035 0.194 0.000 0.137 0.041 0.040 0.218 o.oco 0.120 0.021 0.032 0.173 0.000 0.127 0.009 0.032 0.168 O.OoO 0.129 0.011 0.037 0.177 O.COO 0.227 0.038 0.061 0.326 0.000 0.157 0.045 0.043 0.2A5 O.OCO 0.138 0.018 0.037 0.193 0.000 0.104 0.013 0.029 0.146 0.000 0.123 0.148 0.034 0.088 0.033 0.038 0.190 0.274 0.000* 0.000 iLIAQ_ Xi*032__ 0.038 0.209 0.000 SL 01371? FORM NO' 2 1 1 -b COMPRESSION No 1 Cnwritrssoh Pnr ssunr Gi'c T i on 'Pi G f'lA OC>E To-mtn/vTunc Sue 11 on U i schaint rslG Op 1970 Avg _ 16s L P.PG INi^TRIES CHEMICAL DIVISiON LAKE CHARLES, LOUISIANA HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT JAN FE8 MAR APR MAY JUNE JULY AUG CONFIDENT IA!. ' *n Protectiv SEP OCT NOV DEC * 1971 Avg ---- _ _ 170 -- ---- - _ -- ic. -- _ -- -- -- -- ---- -- -- ML - - 170 - --- -- - --- _ No 2 CournLsson Puts SHIN Son i on P 1 5( HAnsC Erun rm unit Sur 1 I ON D i sen Alter. PS 1 G -- ---- -- ---- - - -- 170 177 164 130 130 132 159 - - - Op - --- -- ---- - --- - - --- - - -- 2M___ --- * No 3 CoMrnrsson Pnr r.suiif SUCTION Ol SCHAlier Trui'r. itATijnr Sun i on Discunner psig --- - 145 _ 107 84 87 Op - --- --- -- --> _ --- 146" -- --- -- -- -- -- _ ----- 106 -- --- -- -- --- -- SL 013213 ________________________ i * FORM f jA 2M'` coF'uE,"rtiU order to V^nistrict Court Pro iM, CHEMICAL DIVISION IVuUCial V;AC cf I4tu *- ^ 5----------------------------------------------- GENERAL DEPARTMENT 1970 Avg JAN E 111 VI CHLORIDE PRODUCTION EC Aitrd Production rc siitpxfNrs MO 147.4 T/D 147.1 T/D 147,2 .114,6 114.1 98.5 IAKE CHARLES. LOUISIANA ETHYL chloride department operations RTPORT Sl_ fl 1 0 ,14, FEB MAR APR 93.1 141.4 323.3 98.7 141.7 121.0 105.2 165.5 109.8 MAY JUNE JULY 142.3 138.7 92.2 143.4 136.6 92.6 162.9 132*0 96.0 AUG SEP OCT 146.8 134.0 150.0 146.4 134.8 149.1 163.8 118.0 153.3 1' v . 162.8 161.5 139.9 C 172.2 172.1 166.8 3.9A7v1g 134.7 134.3 134-J-. IICl To EC I PlPfU TV T/D 90.6 %- 68.5 59-2 88.3 73.1 87.9 32.6 - 57.6 89.7 81.7 89.9 - 98.6 108.4 82.1 -- -- CmYi.rtir to EC [ PURITY T/O 66,6 50.8 43.2 63.5 54.7 65.1 59.5 41.7 65.3 60.8 67.8 7. 99.69 99.86 99.86 99.84 99.79 09.90 99.81 99.97 99.95 99.95 99.92 [ net Errfcicncr | MCI. yield 1 > ... Ca rron El P 1 Cl END t Cab non Yirto 7> 91.0 % 7173 "A 96.2 % 96.2 94.7 92tl_ 91,9 _94-4_ 91.0 90.7 95.9 96.7 97.8 95.8 9570~ 97.0 94.4 92.2 93.5 92.1 96.8 95.8 9^1~ 95.7 94.2 93.4 100.4 99.8 91.4 93.0 94.0 97.0 98.0 97.O ---- 94.4 96.0 Exr.rsj HCl CAi r.r-s HCl VD 4.1 7. 4.8 8.5 3,1 5.7 2.0 3*3 5.2 3.6 5.4 Z79 2.8 3.9 3.4 4.8 <;.7 1.7 6.3 5.7 1.4 1.9 HCl To EC Tons/]on EC Ptioo CpI G TO EC fONs/lllN EC Np to CC Tons/Ion EC 0.609 0r 453 O.C'49 0.601 D,62l 0.623 0.604 0.613 Tt604 0.622 0.612 0.606 0.603 0.445 07453 0.4A 3 0.4 52 0.454 1.435__ 0.445 0.450 0.453 0.056 0.090 0.046 0.055 0.045 . B.048 0.070 0.044 0.049 0.043 73:4 76.3 99.93 9l). 97 93,0 89.7 - 60.2 95*20 } _ 96.0 - _ ,93.2 34*2 .... j 3.4 9.3 a,o . 0.610 0.629 0.612 0.454 0./.43 0.449 0.041 0.037 0.052 frCl-3 In -./Ton re r>TTAM (ACTUAL! LUs/TON EC r7,'tll WA 1 ii M Gals/Ton hv.i]/ roN EC EC 8^___ ,1 838 1.813 193.3." 7.1 2700 2.261 113,9 5.3 5*7 384.1 2640 2,ii93r_ 1.821 93.6 6.8 2461 2.203 103.9 6.7 ,10.0 2435 2549 rauc' 1.950 9471-- 72,3 81 .9 1285 2.786 113.6 11-3 1019 1 .762 95.6 10.1 1076 1.977 98.3 12.8 1056 1.731 92.1 | MAIJ HuUKS/TON EC j riioniirrioN 1 MA f Ml 5 FI ANCF. Sai arild L _Tjlial___________ | Contract Maiht. Included in Above 1 ['an fioura/T KC Shipped | Bulk | Salaried 0,245 0.21.2 0.087 0.544 O.C25 0.019 0.C02 0.291 0.330 0.120 0.133 0.104 0.133 0.515 0.596 U.OOlT 0,000 0,022 0,026 0.002 0.002 0.234 0.068 0.096 0.393 0.000 0.019 0.002 6.283 0728.3 0.106 0.672 0.000 b.240 0.098 0.083 b,A21 0.000 0.028 0.015 0.003 0.002 0.253 O.357 0.122 0.115 0.099 0.135 OT4T 0.607 TJ7WXT 0.000 0,021 0.023 0.002 0.003 0.246 0.16.2 0.089 0.497 0.000 0,260 0.180 0.096 0.536 0.000 0.020 0.025 0.002 0.286 0.319 0.084 0.629 0.000 0.020 0.002 9.0 6_,7 1092 1958 1.641 1.499 84.8 27-1. 9,4__ 14.66 2.028 51.1 .. 0.212 0,196 3L261_ 0.323 JL181. _OJQ_ '',076 0.072 0.098 0.6J 1 0.389 0.529 0.000 0.044 0.004 0.023 0,081 0*022 0.002 0.002 _LLQ2L FORM MATERIAL BALANCE CHLORINE-- TONS To im. Chlor lor l n L r f i> Chi nn inl hi rnoournoN CnLonifir Loss IN Puor.ESS DLn*mm; (non HfAVir.s STILL VrrtT Loss Tun DuroY Loss iifinccnim t/innr Pnoccss Loss ClILOKINf l.OAOINfi LOSS Total Chlorint Loss 1970 Avg JAN .PPG I^JSTRIES _s,,MctC^FpDBNTj^r'.* CHEMICAL DIVISION ^ ^ th LAKE CHARLES', LOUISIANA FTHYL CHLORIDE'DEPARTMENTiQPERATIONS REPORT . rtCt 1 > . , * FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV 1 c<JUrfc DEC 1 1971 1 j Avg j 2704.8 2066.1 1668.7 2660.7 2133.6 2649.9 241O.C 1737.7 2702.5 2382.4 2709.7 2877.; 3268.2 142L4 2450.2 195.6 .,2 1S37-.IL 2445f3 3>Q1S*2 2444*3 12270.8 25M*6 2513.8 .2219*6 2558.0 -2476t( 02931.8 li264.2 254.5 0 - - 254.5 109.8 12.7 w 97.1 121.7 18.4 -- - 113.3 215.4 31.2 - -- 184.2 TIP /, 19 ,R Stf ,6 205.6 2.5 - 203.1 139.2 149.1 188.7 142.8 151.7 201 .2 336.4 174.2 18.7 10.8 19-5 16.9 19.1 13.4 0.0 15.2 -- --- - - - -- -- -- - - - 120.5 .138.3- 369.2 -125.1 132.6- JL82*8 _336_Ji_ 152*0. -6.0 -7,6_ 9^9 6,0 -36 .A 17.9 -33.9 8.2 -5.2 13.7 -13.4 -20.3 =4*1 248.5 102.2 141.6 221.4 82.0 223.5 105.3 157.3 183.5 156.5 138.3- 180.9 335.9 169.0 . CARBON -- TONS Iotal Cahson in fe.no CAUnnij IN PlinnuoiiiN Caudon Loss in Process tiLOAormi Trom llr.AVIF.S STILL VruT t oss Tar niir.ov LOSS UNftr.coiJNtAni.C PROCESS LOSS Cannon loading Loss Total Caiuion Loss 1 SL 013215 ! J733.7 1349.2 1C72.5 1686.5 1406.3 1728.7 1529.2 1107.1 1733.0 1560.7 1801.1 tS85.c 2026.G 1571.9. 1665.8 3322.0 1037.6 lAsn t 1361.3 1655.8 1534.7 1074.2 1699.3 1514.0 1729.1 1810.1 1986*7. 1531.4 37.9 0 ~ 67.9 -5.2 62.7 26.2 5.9 -- - 20.2 -5.2 34.9 8.5 26.4 6.7 36.2 3 4.4 _ 21.8 4.1 , 45.0. 72.9 9.1 1.2 -- '- --- : 35.9 71.7 , - -24.7 12.1 -5.5 - - -14.1 32.9 5.0 -- 27.9 -23.0 5.6 21.0 4l JT. 40.3 20.3 85.0 -28. '38.5 33.7 9.0 24.7 46.7 71.fi,, 7.8 _ 8.8 -- - -38.9-- 63.0 75.4 6.2 - - 69.2 39.8- .. 42-5 0.0 2*0______ ---- - 39.8 -- -3.5 9.2.,, -9.1 -13.7 -0.3 -3.5 30.2 55.9 62.7 61.7 39.5 39.0 ___ ' | j\ . i 1 j 1 t! f ii . I F 0 ft M ! iA 1 i j reactor Pur ssuiir Tr>tprnAiune FLASHER TcMF-nirt runr Op nnT10M Tor ps i g oF PRIMARY STRIPPER I'ru. r.r.uur ps i g 1 etjip tpa njUE op }nrBottom HEAVIES STILL s ,fn.n f~<ATt opm RrrLU* GPM STTAM (actum. ) T CWP CHATUPF Op Lns/tUi Top Bottom SECONDARY STRIPPER I'm 3Gurrr. PSI G TCMrEPATUHE Op | TOP t Bottom 1970 Avg 123 130 JAN 113 123 PFV7 ii^PjSTkfuS Subject 7,NFiUENmt! ( CHEMICAL BIVISION of L4th Judici^`wstrT trder LAKE CHARLES, LOUISIANA ethyl chloride department operations report No. 91-ii|strict Couft FEB MAR 110 131 121 131 Apr MAY 121 125 133 131 JUNE 136 110 JULY 123 139 AUG 132 143 SEP 133 139 OCT 113 111 NOV 12? 133 DEC 136 135 1971 Avg 128 135 160 162 158 165 119 121 121 128 161 3 68 128 135 165 ~T58 134 134 164 133 161 161 TSo 159 163 132 132 132 131 130 87 33 83 08 111 109 111 110 150 150 150 153 79 88 112 109 151 153 81 82 84 111 117 105 150 147 134 RZl 85 86 88 81 1 OF m 107 10? 110 132 119 116 144 147 AO. 8 25.9 3188 119 193 35.7 25.7 3175 150 192 35.9 39.A 27.0 26.4 3001 3218 151 153 186 786 11.1 37.6 25.5 2o70 3079 3103 37.1 3rnr 11 -0 26.0 26.0 2l ,3 3123 3373 1017 -- W)-- 150 ~IB9-- 191 191 118 151 193 191 JO.-Q_ 10.5 26.0 26.2 3852 3719 118 117 160 193 11. 1 26.0 1089 /,/, .8 26.0 ~26?1~ 4711 3594 116 "" 111 191 T 9? TflR 75 72 .72 76 152 159 158 160 160 158 158 161 76 71 160 159 161 160 74 74 71 158 158 150 159 T5o 159 71 76 148 160 160 162 71 71 151 153 1H3 160 74 356 160 ! i SL 013216 ,, -- CHEW.C/J^iVi5I0N LAKE CHARLES, LOUISIANA CUN FIPENTIA Li Subject to Protective o GENERAL DEPARTMENT VC Records Production VC Area Production VC Shipments T/O T/D T/D 1970 JAN. AVG. 486.2 1 523.5 492.0 1 532.2 40 5.1 1 634.5 FEB. WAR. | APR. 500.7 603.3 704.2 608.3 352.7 604,5 578.9 599.1 694.6 WAY JUNE JULY AUG. 586.0 564.5 331.2 558.6 592.2 574.61 337.8 573.0 496.9 561.7 350.6 645.1 SEP. 554.9 562.7 496.6 ---------- 1 OCT. NOV. DEC. 1971 j AVG. | 587.9 535.0 493.9, 534.9, 602.5 544.6 490.3 543.5 576.9 565.4 422.5 533-5 YIELDS Area Production Basis Records Production Basis Area Prod. + Trans. Credits Basis Records Prod. + Trans. Credits Basis CL C CI-> C Cl2 C Cl2 C 97.6 98.3 97.0 97.1 98.3 98.8 97.9 98. C HCi By-Product Prod. J IC( By-Prod. Utilized PI Cl By-Prod. Utilization T/D 286.9 T/D 280.9 % 97.9 97.6 97.6 96.8 96.0 97.7 97.6 97.3 97.0 97.4 97.4 97.0 96.6 99.3 99.0 98.6 99.0 96.7 98.4 98.6 98,7 98.2 97.4 78,0 .97.6 310.4 294.1 354.7 309.1 293.3 346.8 99.6 99.7 97.8 97.8 98.0 96.2 94.7 99.1 99.0 98.6 98.0 99.2 99.6 99.0 100.2 97.5 99.1 95.7 99.1 348,0 345.2 345.3 338.4 99.2 98.0 98.0 98.0 97.1 96', 2 -- - - 99.1 98.9 98.3 97.2 98.7 98.6 98.3 98.3 97.8 97.4 96.4 95.9 335.0 197.0 334.0 325-6 J92.7 325.5 97.2 97.8 97.4 -- --- - - - -- - - -- - - _- - - 99.4 99.9 98,9 100,0 99.2 _ 99.1 99.6 98,5 99,6 99.0 <>8.8 97. B 98.7 98.0 97.2 96.8 100.3 98.4 100.3 lii+U___ 328.0 203.0 97.5 351.3 317.5 342.6 311.3 97.5 98.0 285.8 276.1 96.6 316.7 008.3 96.0 Heavies Still Bottoms Prod. T/D tj * r>rf..j Dopp Kcitie Waste Lbs./T VC 3-46 10.23 10,11 11.08 11.68 6.50 2.22 3.55 2.50 2.28 4.64 9.48 1.32 10.18 12.86 12.47 13.67 15.23 12.91 j 1.37 1.13 436 5.11 -- 5.88 4.40 3-40 EDC Consumption LOG Consumption CL Consumption Steam Consumption Gas Consumption '.Veil Water Used Nitrogen Used Power Consumption T/D 792.6 T/T VC 1.61 Lbs./T VC O5> * O4/r|7 Lbs./T MCr/T M Gals./T Lbs./T KWH/T 1790 _ 3.84 0.68 57.4 97.2 qOiL 0U 11 3O2L1\ 7* 863.2 817.3 i.fc>2 1752 3-HI 4.15 1990 3.46 0.61 73.1 98.2 2<>9 2.63 0,77 e.1.0 3.07.6 988.6 967,7 1,68 1.1.62 3.74 | 3.47 j, 946.2 x. ou 4.00 928,2 553.2 934.0 1.62 "1.64 1.67 4,59 '"4725" 4.42 2065 i 2196 2231 i 2051 ` 2123 1977 2.75 06,45.33 89.2 1 3.82 1 602.5.86 I -04.6 3.82 0,54 52.4 88.0 3.80 0,58 46.9 69.2 3.96 3.76 0.95 0.56 92.9 37.4 3.32.7 97.6 i ! . . I .. . i i1 _______ !_______ 1_______ 909.5 969.6 888.0 T76IT T35~ 7763 4.24 -rnr~ 4.62 1927 3.77 0.59 41.3 99.2 1859 3.68 0.54 40.2 89.3 1978 132 TJTFi 45.7 101.8 790.4 1.61 5.92 87. 7 .L Cud 4.53' 1799 4,13 0.66 45-3 97.9 2039 3.62 0,61 56.9 97.1 f 1 j1 LAKE CHARLES,LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT GENERAL DEPARTMENT MAN HOURS/TON VC PROD. 1970 AVG. reduction .Inirdnnnnco ..i l.irietl '"i , 0.129 0.C7S O.C34 J 0.241 or.ErAct Man Hours includc!d0.C02 RAN hours/t vc shipped :uik .ilaricd 0.031 0.003 JAN. o.m 0.052 0.029 0.194 0.000 0.021 0.002 FEB. WAR. 0.3 2V, 0.119 0.034 0.277 0.000 0.098 0.050 0.029 0.177 0.000 O.C26 0.019 0.002 0,002 APR. WAY JUNE 0.097 0.029 0,028 0.154 0.000 0.101 On 102 0.023 0.040 0.026 0.031 0.150 0.173 0.000 0.000 0.021 0,024 0.026 0.002 "07005" 0.003 JULY AUG. 0.194 0.343 0.019 0.559 0.000 0.112 0.042 0.030 0.184 0.000 0.032 0.020 0.004 (HOOP SEP. OCT. -- NOV. DEC. 1971 AVG. 0.114 0.054 0.030 0.198 0.000 0.098 0.043 0.027 0.168 0.000 0.113 6.056 0.029 0.198 0.000 0.128 0.0 0.033 0.206 0.000 0.116 Pi. 071 0.02V 0.220 0.000 0.034 0.019 0.027 0.022 0.024 0.003 0..Q02. "0.003 0.002. 0.002 -- SL 013218 i 1 * f - - a. 1 | 1 ! i 1' i nf ! tnhnecl 14th . conPic ."to Pi tudlci^ NO. ! TTNT7A1 Citect' ii Ols d-it4 ti vc--Or< .riet 1 if---------- '/.nrh * * | j J 1 . . li ROCESS CONDITIONS VAPORIZING FURNACE oc rrxo temp. f 'louAcr nmoCrCWALL temp, *f f' AVC., PASSFS^I 1 P>'- # ? 'UPMACr. HEAT ErriCICNCY PSI X hacking FURNACC fecd temp. *f 1970 AVG. 217 m9.. 190 73-4.. 402 JAN .CUtMICAtTT. VISION lAKE CHARtfS, LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT FEB MAR APR MAY JUNE JULY AUG 267 1433 205 - 397 5 36 1337 227 - 418 322 ~TWi 230 421 308 1404 230 420 306 1365 241 -- 414 302 1392 247 415 313 1352 213 -- 416 331 1356 208 - 419 CRACKING F(JHNACE#1 urn; ACC DHIPGF WALL TEMP. p AVCm PAS5E5#t, #2, #3 & ff4 LIHHACE HEAT EFHCICNCV VC PASS OUTLET TEMP.. #4PASSES #1, Sj, #3, fir, *F P5I % F 1302 126 74. C 049 1-305 no? 139 143 --- 649 643 . 1325 146 -- 1323 151 -- 824 835 131-6 T309 152 159 -- \Tzar~ 1285 140 136 * 830 813 856 857 CRACKING FURNACE 2 'JON ACr. OniOGLWALL TCMP. n tfi. ^2 HUavc., passes 3 flu UHNACt: MEAT FFFIC1CNCY *F pst % vg. p ou ri.r.T ttmp ' # A # ('PMsr. I. I. J f.-. 4 F VG- COrtvrnstON OF COC TO VC * 1263 127 63.7 1236 1288 137 160 - 049 J. 17.7 326 306 1323 153 - l305 158 - 1305 164 _ 1301 163 UT7 781791------------- 757 -_ - 1285 152 - 835 1297 159 860 . QUENCH TOWER on rcMn. on rnrss, *F fsic 262 _22_________ 263 9.5 266 96 266 97 , fe 97 270 271 259 268 98 99 103 99 _ SEP OCT NOV DEC 1971 AVG. 329 1333 214 415 1210 140 332 1353 224 -- 419 1300 156 - 325 1327 236 - 414 281 313 1343 1365 238 . 226 _ 413 415 TJU9" 1281 161 150 --. 1296 146 -- 906 903 887 846 854 1297 141 _ 856 1307 146 -- - 848 - 7295 163 - 794 1236 162 751 1294 152 810 - - -- ,, 268 269 99 100 266 266 93 . 90 261 98 _______ SL 013Z19 -j --- -------------------- . 5ub jec of 1.4th * CUN F11 1 ^13 > i ** * 1 to "F 0 tucfe ..rt. On \P\- ; rjrf- ( lourt lucllOi< \i iTl'^ [JO . H r ** 3 - i _______ i_______ FORM U A6 iliij'xi PROCESS CONDITIONS -1-V70 AVG. JAN Pro I KIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT FEB MAR APR MAY ' JUNE JULY AU0 SEP agsoho hi"Column SCC. QUENCH CONO. CAS rrro tcmp. F POTTOM CIQ. TCMP, T O AY f?7 T CMP, __ ir *F Til VY * 1 I TEMP, TRAY ti 3 3 T CMP. "F *F LiQ, FROM UPPER INTERCOOLER T CMP. F L1O- rnOM LOWER INTERCOOLER T EMP. *F LpAM O i L TO AnsORPr.H TEMP. * F LEAN OIL FLOW AVG. G PM AnSQRPER TOP PRESSURE PSIG STRIPPER COLUMN OUPICH LIQ. FEED TEMP. BOTTOM LfQ. TEMP. STflIPPEn TOP temp. DOT TOM P R CSS PRODUCT STILL COLUMN LI QUI D F ECU TEMP, POTTOM LIQ. TEMP. Til AY # |B TCMP* TOP TEMP, STILL TOP PRESSURE F F *F PSIC F F 'F ? P SI S U.43.1ft 85 56 16 ITT -JL2Q- 92 58 -18 135 114 88 58 17 138 T19 92 59 17 J3____ 33 31 34. 1 -28 .168 74 -1 -1 -27 Y.J 170 171 ___8Q_ 80 -1 -28 177 80 121 116 116 TV9" 206 210 208 TU7 123 12 T 119 122 91 91 94_____ 95 207 212 2-Q3L. 2C8 322 721 m____ 321 222 222 221 222 106 105 103 105 81 79 77 78 143 149 TO-- 138 121 123 122 119 91 83------- 74 76 59 58 57 55 IT------- 18 20 T9------- 131 no 77 57 19 137 120 81 57 20 33 34 33 38 38 35 -1 -28 179 80 I-------- 4 -28 -26 181 195 80 80 (1 -26 187 80 -2 -1 -27 -28 181 186 80 80 122 126 209 210. 121 124 96 ' 96 732----- 126 211 211 117 124 96 96 ~2l0 212----- 213 212 312 324 327 325 222 . 222 222 222 106 109 -79------ 83 111 m 86-------- 86 129 1.29 200 210 1 ?7 123 96 96 212 210 323 328 222 222 108 109 M------ 84 OCT NOV DEC 1971 j AVG. } 127 T29----- 127 135 119 119 111 119__ 72 73 61 80 55 55 53 57 19 18 23 19` 32 32 34 0 Tl------- U -28 -2.8 -28 188 182 171 80 79 75 128 121 lie 211 211 212 127 123 126 97 94 89 3^4------- ;i (1 -28 180 80 1 124 210 .122 95 212 211 215 211 324 318 317 ' 321 222 222 222 . 222 106 104 103 106 si 7 7 77 81 * -- 91 013220 --Strtrj y. ot l** roM VO ?XDEMT prote Lftlj1 etive- Qrrier V: Coui t 111A i cial L N( ,7W! 14U - FORM Kt A 215-4 PROCESS CONDITIONS 1970 AVG. JAN VU "j J [ K I L i CHEMICAL DIVISION LAKE CIIAIUES, LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT : FE0 MAR APR MAY JUNE JULY AUG SEP HEAVIES STILL COLUMN UO rcco TEMP. POTTOM LIQ. TEMP. top T'r.wn, top paE5sunc REFRIGERATION *F 163 . . -151L .159 ... T58 162 lS4 167 167 " F 236 2'32. ?3? 233.. 233 234 234 228 *F 195 -19/1 1Q6 195 "195 196 196 194 PSic 1.2 1.1 .1-2 1.2 "TT2 1.2 1.2 1.2 PIRST STAGE SUCTION TEMP, *F -31 sccono st ach suet(cn tcmp. THinD STAGE SUCTION TEMP. *f _0____ *F TO roUPTH STAGE SUCTION PRESS. #COMP Re 5 SOU l - AMP5 Z-100V P51G 63 236 OISCHARCE PRESS DISCHARGE TEMP. @G0MPRC55On#!-`AMI5 2400V DISCHARGE PRESS DISCHARGE T CMP. PS1C *F PSIG *F 137 172 2 A3 136 170 -29 (0 32 60 233 145 179 235 138 168 -30 -31 -31 -31 -30 {0 (0 (0 (1 (o Jl____ 32 61 62 23S 3245 TT5 127 32 32 26 62 M------- 67 251 255 254 145 158 152 "I67 174 183 176 180 239 249 255 259 261 136 .. 150 136 , 140 135 181 T74-- 7I3T" 180 TSD -29 (0 36 67 2/, 8 146 ' 180 259 139 176 PRODUCT STORAGE -DAY TANKS A VC. TEMP. *F 64 -6.0-- as____ 64.: 68 76 84 81 AVG. PH ESS. JPHCnE*- ftvr., TTMP, A VO. PR ESS PSIG *F PSIG 39 67 39 _1Q___ 31 61 54 28 25 34 60 30 39 46) 51 47 67 72 82------------ 80 40 43 52 49 MISCELLANEOUS WC1 DY-PRODUCT to OUTniOUTIONt TCMI*. - F -17 -IL- -15 . -15 -15 -16 -20 -20 COOLING TOWER WATER TO PLANT, TEMP, * F JO___ _ 81 SO 82 ,78 87 91 92 163 156 230 291 197 196 1.2 1.3 -30 -31 -2 -2 36 36 70 68 247 233 140 163 176 18? 756 247 141 148 174 178 82 79 49 42 80` 78 47 48 "=I9 -18----------- 91 91 OCT NOV 166 233 3 97 . 1.2 . 167 231 196 1 .2 -30 -30 (0 (-1 37 33. 60 54 226 218 142 TUo 185 175 241 238 134 TV 3.77 169 77 . 41 72 _ _ 44 69 29 60 35 -3 6 -14 87 81 1971 i OEC AVG. j 168 229 196 1.2 163 232 196 1.2 -2ti -28 u l-l 95 3462 63 226 240 1 125 141 i 174 178 j 244 249 125 138 j 177 176 1 1 64 71 30 39 61 63 32 39 - -16 -17 .... 84 85 r_ SL 013221 COHF :t to fOENTTI kL: ^rotec XVt? " k Cl L. 1 l 1 4 hh J utile Lai ft i- No. 91-11 15 ---- 1-- TM " ' ---- PALp U H * 1. V '0 t CHEMICAL DIVISION ' LAKE CHARLES,LOUISIANA OHC-EDC DEPARTMENT OPERATIONS REPORT i [ GENERAL DEPARTMENT 1970 Avg. JAN. FEB. MAR. | OHC-EDC Production 1L, 1 HCL to OHC-EDC ( HCL Consumed .. T/D 161.2 1 T/D 121.3 T/T EDC 0.749 207.0 222J_ 261.4 155.9 165.9 196.8 0.744 0.742 0.753 !' ! Purchased C2H4 to OHC-EDC % C7H4 Purity T/D 47.5 61.2 _ 65.0 78.2 99.69 99.36 99.86 99.84 YIELD % Cl? Basis C7H4 Basis ( t 1 F.xc*>stC?H4 f Excess C7H4 97.9 99.1 _ 99.3 3L3__ 95.9 97.5 97.8 94.7 % 3.8 4.3 . 2.6 5.6 T/M ^8_ 7^.8 S45.3 129.2 | Excess CjH4 i Lbs/T ED #2.7 24.2 14.5 31.9 ! Oxygen to OHC-EDC T/D 28.2 37.6 39.3 47.9 Oxygen to OHC-EDC ; Excess 02 \ Excuse Oy i Excess O? T/T EDC 0.174 % 5.5 T/M 48.1 Lbs/T ED fcPL9-9 0.182 0.176 10.2 7.4 419.4. 81.6 37.2 26.1 0.183 10.9 145.8 36.0 APR. 235.3 180.8 0.755 68.1 99.79 f tfl.5 99.7 0.3 6.6 1.8 43.5 0.181 9.6 114.3 31.8 WAV JUNE JULY 223.6 221 .7 122.0 166.5 167.6 91.6 0.744 0.755 0,750 64.6 63.7 34.8 99.90 99.81 99.97 99.0 9775 98.1 98.0 9577 99.4 2.0 39.3 11.3 7.6 fcs 25.4 . 6.1 1.34 3.22 38.2 38.5 0.170 P.173 4.7 4.7 52.8 51.9 15.2 15.6 21.3 0.174 A, O 37.6 19.9 CONFIDENTIAL: M______L-rth t Vi Court AUG. SEP. 218.4 220.8 OCT. NOV. DEC. 216.0 169-6 130.0 1971 Avg.'1 204.0 165.9 165.2 l6l.l 129.0 97.2 153,5.. 0.759 0.748 0.745 0.761 0.747 0.750 62.8 64.2 63.3 48.6 37.0 59.3 99.95 99.95 99.92 99.93 99.97 99.90 97.0 98.5 98.6 97.5 98.8 96.7 96.8 93.6 98.8 99-5 96.2 y?.9 1.5 276 28.2 48.0 8.32 14.5 3.4 64.5 19.3 1.2 16.7 6.6 0.5 5.8 2.9 2.7 . 41.1__ 11.7 39.9 38.6 0.182 0.174 9.6 6.4 108.7 69.8 32.1 21.3 38.0 0.175 7.5 81.8 24.4 35.0 0.206 23.6 200.2 78.7 23.7 0.182 11.4 75.0 37.2 36.6 0.180 9.3 94.9 31.3 CRUDEEDC INVENTORY For Pcr-Tri Feed For EDC Still No. 2 Food TONS TONS TONS 460.3 434.6 291.3 187.0 229.9 141.5 151.6 204.7 149.3 263,5 476.4 143.6 160.2 119.9 276,2 244.6 545.6 223.9 319./,. 20.7 C26.2 263.3 138.6 124.7 351.7 468.0 140.4 263.5 211.3 204.7 553.7 642.7 199.3 _221*2_ 299.3 331 .9 126.1 209.9 254.4 310.8 73.2 J ol .4 Transferred to Por^Tri Transferred 1o EDC Still No. 2 TONS TONS 2903,3 3258.3 3095.8 3575.4 3597.7 4304.9 [3888.4 1905.3 2477.5 2633.8 3004.8 825.1 781.0 2/7.9 1941.8 7301.7 3285.9 4551.2 3253.0 2800.9 2379.3 2101.8 4113.9 3710.8 3492.2 4170.C 3349.6 3375.9 MAN HOUR S/TON EDC PRODUCED Produclion 0.303 0.212 b, 204 Mnintcnanco 0.148 0.030 b.069 RMnrfatl 0.148 0.100 0.102 Total 0.599- 0.392 P.375 Contract Man Hours Included O.COO 0.000 p.000 0.168 0.044 0.001 0.303 0.000 0.170 0.189 0.175 0.133 0.136 O.C67 0.094 > 0,092 0.105 0.397 0.417 0.347 0.000 0.000 0.000 0.346 0.304 0.J78 n AOst o'ooo 0.191 0.179 0.073 0.108 0.104 0.101 0.368" 0.388 0.000 0.000 k).2W~ 0.179 0.097 0.145 0.100 0.126 0.376 0.520 0.000 0.000 0.265 0.211 0.255 0.126 0.167 0.113 0.687 0.450 O.GOO j 0. coo 11 . SL 013222 PAc L. : <;0HE1',Etlll('w oci'et t, rtotect;^ict coaIl .,V-c< t" ... uistti ot i* <T` O 11 t Lj -. t i 2,0 bHCWICAL DIVISION LAKE CHARLES, LOUS SIAMA SL 013223 OHC-KOC REACTOR //I 1970 A VC. JAN. FEB. tOn-Stremn Time Top Pressure Dov.'thcrm Temp. (From) (Into) Reactor Temp. Hrs. .4695 w! 658 psig JL6_____ 15 F 365 383 F 3PO 359 608 17 381 854 Catalyst fiottom Middle Top Vapor Space Refrig. Cond. Outlet F 569 P 527 F 512 UF 512 UF 44 FEE i53 Co Ha schf 41200 Oo schf 21200 HC1 schf 77000 RECYCLE ANAI YS1S(Vol. %) 569 572 525 525 518 514 520 515 JJ_____ 40 39900 40900 2A3 00 20200 69700 79600 COp CpHr 02 Catalyst Charged % 25*8 % 54 r l % 3.7 Lbs. E22.fi 27.7 47.8 4.2 _2S65 32.2 44-6 4.3 3606 MAR* 694 19 859 828 569 518 511 512 46 45700 22800 87800 32.3 48.8 At7 in?46 APR. WAY 650 638 14 14 369 373 340 346 565 518 509 511 47 39700 20500 78500 352 504 511 516 146 38400 18900 74400 35.1 31.6 48.8 ' 49.4 4.5 *4.9 3988_ (21504 JUNE JULY 712 422 13 13 380 357 352 336 568 568 520 529 515 516 W1 512 53 52 37100 35400 18000 17100 7/, too. 71900 40.7 49.1 4.3 309 31.3 49.6 3.4 4066 AUG. SEP. 646 616 14 15 170 361 334 335 OCT. NOV. 674 "555 14 14 370 356 3 42 330 DEC. 154 14 17 5 '353 1971 AVG. , 6808" 15 169 342 ... 563 578 522 533 521 509 522 511 50 49 38800 40900 19000 19300 74400 73800 592 586 534 "545 510 ~520 511 517 47 45 39300 39800 18900 20000 74000 75000 565 526 513 513 55 40000 19100 76600 571 525 514 515 48 39^00 19S0C 75800 34.0 49.1 3.5 8306 37.4 45.6 3.3 8946 34.4 48.2 3.4 5 588 34.3 47.3 2.6 7047 28.5 33.3 .MSLS~\ _4dLJL__ 3.0 3.9 9002 17706 REACTOR ][2 On-Stream Time Hrs. 5684 * 628 Top Pressure psig 18 16 Dowthcrm Temp. (From) F 368 378 542 18 367 (Into) iieactor Temp. F 335 350 339 Catalyst'Do ttom F 565 Middle F 524 Top F 510 vapor Space F 509 Kofrig, Cond. Outlet F 45 FEEDS CpHA schf 44300 Op schf 22700 HC1 schf 82900 RECYCLE ANALYSIS!Yol. %) 573 573 521 519 510 403 512 510 41 44 39500 43100 20500 21800 74500 77600 COp CpifA 02 Catalyst Charged % 24.6 % 54.6 % 3.8 Lbs. 9183 34.8 47.3 3.7 9415 35.4 44.2 3.8 3214 Totals* 692 18 357 321 570 523 508 510 47 44600 22900 33800 37.5 47.3 3.7 10215 716 658 716 400 18 16 12 14 358 365 395 390 325 335 369 353 574 574 560 536 522 520 518 509 503 519 511 510 49 47 55 43500 40200 35800 22700 19800, 18100 81100 i 73600 70000 575 520 531 513 56 35800 19400 70700 38.7 47.5 3.7 4387 35.7 48.9 4.7 |20566 31.3 48.5 3.6 311 34.3 45.8 2.5 3854 656 622 15 14 377 367 349 338 548 581 518 516 523 506 511 509 50 49 58400 39400 20700 20000 75400 72100 672 12 363 337 573 519 509 511 48 35600 18200 67200 550 404 72 56* 20 22 16 346 351 368 331 330 340 1i 573 578 573 i 530 542 524 516 524 512 ! 517 525 49 52 513 49 1 447C0 49000 ..42I0CL- 24000 267GO 21200 83800 91500 76800 30.6 46.9 3.1 8434 26.6 46.6 3.7 9Q34 27.1 49.4 4.5 5572 29.7 47.3 4.2 13553 26.6 55.4 4.5 23618 32.4 tCf - y 3.8 9346 OilC-EDC WANT DATA 1970 AVG. del'rigerated Brine Temp. Warm F 37 Cold F 37 Clilorol Treatment Feeds Organic (gpm 18.2 Coil Liquor(gpm 18 Drying Still Ternp. Bottom F ~IS3 Vapor Cutlet F 159 Press. Bottom psig -0.7 Lights Still Fe^d (gpm 19.6 ileilux (gpm 19.6 Te?np. Bottom F 3 98 Overhead F ISO JAN. 36 36 Pir*G i; ..> i r CHEMICAL DIVISION LAKE CHARLES,LOUISIANA OXYHYDROCS.1 CRTlihTION OPERATIONS FEB. MAR. APR. J MAY i i JUNE JULY JJ5____ 42 35 41 43 ! 40 42 38 147 47 41 40 22.6. 21.8 21.0 18 20 19.7 19.0 25.2 25.1 14.6 9.5 9.3 25.0 10.7 184 156 +0.3 20.7 15.7 200 175 134 157 -C.9 22.5 3.8.1 199 178 184 156 +2.4 23.3 18.6 200 163 184 159 +0.6 28.1 14.1 199 174 184 165 +1.1 21.9 14.7 199 174 134 193 166 168 (0.1 -0.2 19.6 25.2 11.3 14.3 199 . 200 173 175 AUG. SEP. OCT. NOV. 41 41 40 41 24.0 26.8 7.6 11.4 187 183 142 164 +0.06 +0.1 18.9 26.5 3d. 8 12.0 200 196 163 173 42 41 24.8 8.3 184 158 +0.2 29.8 8.2 199 170 43 43 23.1 13.2 185 1 56 +0.3 26.4 12.1 108 153 DEC. 48 48 1971 AVG., t MJ 41 26.5 8.4 23.7 12.6 185 146 -10.7 28.5 17.5 204 172 385 158 -:0.4 24.3 14.2 199 171 30:/ Steam Produced Lbs. "7556 10439 10942 15902 Flee trie Power (K'./H/T EDC) Pell Water (il Cal/T EDC) wat! x ra 1 _Ca"s__ (KCF/T_EDC) Nitrogen (T/T EDC) Coll Liquor (T/T EDC) Hit. 5 1.471 0.072 0.121 -p 39-3 1.340 0.013 0.094 -- 79.1 1.230 0.000 0.095 - 71.1 1.037 0.000 0.035 11259 12043 11699 5998 10587 10158 10616 5678 75.5 85.2 1.072 1.163 0.000 0.000 0.044 0.043 _- 7d.6 f.398 0.000 0.037 101.1 2.672 0.000 0.135 89.9 88.9 1.418 1.570 0.000 0.000 0.096 0.084 -- 88.7 1.673 0.007 0.079 2.182 0.000 0.102 4066 9949 sjlA. 3.46.4 1.961 1.560 ' 0.0OO 177002" 0,162 0.084 _ Catalyst Lb./T EDC 3.57 3.00 1.09 2.53 1.17 6.07 0,,C9 2.09 2.47 2.71 1.67 4.05 8.10 2,y2 L SL 013224 CO HFIDEt TIM.: Sub iect t y Prot ectivf Ordei of 14 th Jud icial Distr: ct Cot irt N 0. 91- 1145 .. . i; ..... _______________________________ , GENERAL DEPARTMENT No. ot Ostctici Mi'ihcit Ftcactor Temp. Avq. Avcj. Timeol Reaction F lira. 1970 AVG. 13 138 4.0 DIVISION LAKE CHAfTTES, LOUISIANA VINYLIDENE CHLORIDE DEPARTMENT OPERATIONS REPORT JAN. FEB. MAR. APR. MAY JUNE JULY AUG. SEP. 19 25 8 19 29 7 10 17 -- 136 131 137 135 132 131 135 135 30.3 10.0 7.0 8.0 9.6 8.0 8.0 6.0 OCT. 137 12.0 r.l.lt Fred Still Prcuure Still Top Temp. GPM PSIG F B.2 12.8 122 mm -- 3.8 13.1 122 4.0 13.0 120 4.2 3.8 12.4 12.8 120 120 2.9 3.2 14.2 i6.i~ 122 124 3.4 11.2 121 4.3.... 4.4 11.1 10.5 122 122" NOV. 135 9.5 2.9 10.9 120 DEC. -- 129 6.2 1971 . AVG__ _12___ JJA__ 8.6 2.8 3.6..... 10.4. , 120 .121 j Rcboilcr Steam Flow j Rcboiler Temp. j \ i Gottorns to VDC #/Hr. 1107 F 136 >M Roto.% 65 mm 373 372 374 3o5 127 126 , 12& 126 41 43 "31 36 220 193 128 132 35 48 712 679 .... 853 . 715 iis___ 485 132 132 132 132 130 129 45 32 33 yr _____ 39 ! MAN HOURS/TON J Production i Maintenance i Supervision Total Contract Man Houra/T inc. 2.878 1.782 - 0.032 Production Tona/'Pay T7T -- -- -- 1.472 Ui>5-- 0.000 1.549 21.807 1.057 0.095 0.000 0.000 0.000 1 ,22( 12.480 11.869 0.241 7.480 9.496 -- -- - 0.000 0.000 0.000 0.724 1.016 0.115- 0.397 ---- 0.000 0.000 0.813 0.058 -- 0.000- 2.629 0,266 - 0.000 8.2 8.4 0.5 11.5 9.8 0.8 1.1 17,3 12.7 14.3 /+, 6 5 -149 1.694 0.000 8.1 SoLi mUluiozZicb -% , . CO MF1DEN l'l AL: Rub ject t o Prot active Order of 1^ th Jud icia 1 Distri at i.ou N . 31- rns