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MATERIAL SAFETY DATA SHEET (in compliance with 29 CFR 1910.1200 and WHM1S)
IDENTITY: Polycizer* ESO
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SECTION I- Preparation/Product Information
MANUFACTURED FOR AND SUPPLIED BY:
Harwich Chemical Corporation 60 South Seiberling Street P. O. Box 9360 Akron, OH 44305-0360
EMERGENCY TELEPHONE NO.: (216) 798-9300 DATE PREPARED: December 20, 1990 PREPARER: Health, Safety, & Environment PRODUCT USE: Plasticizer
SECTION II- Ingredients/Identity Information
COMPONENTS CHEMICAL IDENTITY/CAS#/UN#
EXPOSURE LIMITS PEL TLV OTHER
Epoxidized Soybean Oil
*15mg/ro3 *10g/m3
CAS #8013-07-8
**5rag/m3
*PEL k TLV for vegetable oil mist, total particulate.
**PEL for vegetable oil mist, respirable fraction.
TOXICITY LD50/LC50
AMOUNT %
90-100
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SECTION III- Physical/Chemical Characteristics
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BOILING POINT: >600F
SPECIFIC GRAVITY (HzO=l): 1.0
FREEZING POINT: Not Determined
pH: Not Determined
VAPOR PRESSURE (mm Hg): Not Determined
ODOR THRESHOLD (ppm): Not Determined
VAPOR DENSITY (AIR=1): Not Determined
COEF. HATER/OIL D1ST.: Not Determined
SOLUBILITY IN WATER: Insoluble
EVAPORATION RATE: Nil
APPEARANCE (PHYSICAL STATE) AND ODOR: Liquid; Light Yellow
Odor; Characteristic
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FLASH POINT (Method): 590F (COC)
EXTINGUISHING MEDIA: COz, foam, dry chemical. Class B extinguishers).
(National Fire Protection Association
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus and protective clothing. Water spray may be ineffective. Use water to cool closed containers,
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers may explode when exposed to
extreme heat or fire. If burned, material could give off toxic fumes.
HMIS RATING: 1
FLAMMABLE LIMITS LEL: Not Determined UEL: Not Determined
AUTOIGNITION TEMPERATURE: Not Determined SENS. TO MECHANICAL IMPACT: Not Determined SENS. TO STATIC DISCHARGE: Not Determined HAZARDOUS COMBUSTION PRODUCTS: COx
**********************iM:**************************************************************** SECTION V- Reactivity Data
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STABILITY STABLE: X UNSTABLE:
CONDITIONS TO AVOID (Cond. of Reactivity): None known
INCOMPATIBILITY (Materials to Avoid): Strong oxidising agents
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: COx
HAZARDOUS POLYMERIZATION MAY OCCUR: WILL NOT OCCUR: X
CONDITIONS TO AVOID: None known
HMIS RATING: 0
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SECTION VI- Health Hazard Data * s^****#**********#*******#*************************************************************'*
PRIMARY ROUTES OF EXPOSURE
INHALATION: X SKIN ABSORPTION:
SKIN CONTACT: X INGESTION:
EYE CONTACT: X
HEALTH HAZARDS
ACUTE: Prolonged eye and skin contact may cause mild irritation. Overexposure to vapors generated at high temperatures may result in eye and respiratory tract irritation.
CHRONIC: None known NOTE: Product form should minimize exposure making health effects less likely.
CARCINOGENICITY NTP: No
IARC: No
SIGNS AND SYMPTOMS OF EXPOSURE: See Health Hazards above.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known
OSHA: No
OECD TEST VALUES FOR:
IRRITANCY: Not Determined SENSITIZATION: Not Determined MUTAGENICITY: Not Determined
REPRODUCTIVE TOXICITY: Not Determined TERATOGENICITY: Not Determined
SYNERGISTIC PRODUCTS: Not Determined
HMIS RATING: 1
s**^**^^*********************************************#******************************* SECTION VII- First Aid Measures
EMERGENCY AND FIRST AID PROCEDURES
INHALATION: Move to fresh air,
INGESTION: Consult a physician.
SKIN CONTACT: Wash with soap and water.
EYE CONTACT: physician.
Flush with water for 15 minutes. If irritation persistsj consult a
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SECTION VIII- Precautions for Safe Handling and Use
STEPS TO BE TAKEN IN CASE MATERIAL TS RELEASED OR SPILLED: Wear apron, rubber gloves, and chemical eye goggles. Cover with inert, absorbent material and remove to disposal containers. Wash clothing before reuse.
WASTE DISPOSAL METHOD: Refer to Section X.
In accordance with all Federal, State, and Local regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Avoid contamination of this material by other materials. Avoid contact with eyes, skin, and clothing.
SECTION IX- Control Measures * ***#**!|! fc****************^*****************************#** ****** ***********************
RESPIRATORY PROTECTION: (Specify Type) A NIOSH/MSHA approved respirator above PEL or TLV or as necessary.
VENTILATION LOCAL EXHAUST: Recommended to minimise exposure. MECHANICAL (General): Recommended to minimize exposure.
PROTECTIVE GLOVES: Impervious to oils
EYE PROTECTION: Chemical goggles
OTHER PROTECTIVE CLOTHING OS EQUIPMENT: Eyewash station.
If product is hot, wear
protective clothing that covers all skin areas (e.g., long sleeve shirt).
WORK/HYGENIC PRACTICES: Wash thoroughly after handling.
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;*********************#************************************************************** SECTION X- Additional Information
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SPECIAL SHIPPING INFORMATION: Not Available TSCA INVENTORY STATUS:
Chemical component(s) are listed on the TSCA Inventory, SARA TITLE III:
This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 and of 40 CFR 372:
None
RCRA STATUS: The following chemical component(s) are listed under (40 CFR 261):
None
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA THAT IS ACCURATE
AND RELIABLE TO THE BEST OF HARWICH'S KNOWLEDGE AND BELIEF.
WITH RESPECT TO THE
INFORMATION AND RECOMMENDATIONS. HARWICH MAKES NO REPRESENTATIONS OR WARRANTIES OF ANY
KIND OR NATURE, EXPRESS OR IMPLIED.
6/90
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