Document 0gKz4zkn1nZORpbxzdJrB8m3m
STLS E V E R N
TRENT
STL Chicago 2417 Bond Street University Park, IL 60466
Tel: 708 534 5200 Fax: 708 534 5211 mvw.sf/-/ni:.com
S ig n a tu re
Name : Rij^yCrrl C , Wright Title: Pt o jecL Manager E-Mail : rwright@st.l- inc .com
Thi.s Report Contains
Leaders in F.nvironmenta! Testing
Date STL Chicago 2417 Bond Street University Park, TL 6046G
PHONE: (708) 534 5200 FAX. . : (708) 534-521.1
Pages
Severn Trent Laboratone?., Inc.
WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION
JOB# 233858
Data Summary............................................................... 1 Chain of Custody..........................................................12 Case Narrative............................................................. 17 Raw Data...................................................................... 19
STL Chicago is part of Severn Trent Laboratories, Jnc.
$ A M P L E IN F O R M A T I O N
Date: 02/11/2005
Job NuMiber.: 233858 Customer...: Ueston Solutions, Inc. Attn...... : Jai (Cesari
Project Number.... . 2 0 0 0 4 8 9 1 Customer Project ID___ : CONFIDENTIAL DECATUR Project Description___ : Confidential Decatur Fc Investigation
Laboratory Sampl e ID
233858-1 233858-2 233858-3 233858-A 233S5S -5 233858-6
Customer '/ Sample ID DBKG-SS-0001-0-0000 DBKG-SS-0001-0-0003 DBKG-SS-0D02-O-00aa DeKG-SS-0002-0-0003 DBKG-SS-0003-0-0000 DBKG-SS-003--Q003
Sample : ..'HatriA!
Date Sampled
Soil
01/27/2005
Soil
01/27/2005
Soi l
01/27/2005
Soi 1
01/27/2005
Soil 01/27/2005
Soi 1
01/27/2005
Time Sampled
15:30 15:40 15:55 16:05 15:45 15:50
Date Received 01/29/2005 01/29/2005
01/29/2005 01/29/2005 01/29/2005 01/29/2005
Time:' Received
09:00 09:00 09:00 09:00 09:00 09:00
Page 1
1
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Number: 233858
; CUSTOMER: Weston: Solutions, ine. r
Customer Sairple [$: DBKG-SS-OQOT-Q-QOOO Date Sampled....... ;01/27/2005 Time Sampled........ :15:30
LABORATORI
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR
Laboratory Sample ID: 233858-1 Date Received........ :01/29/2DG5 Time Received........ :09:00
C\
Date:02/11/2005 ATTN-. Jai Kesari-
* in Description = Dry Wgt.
Page 2
STL Chicago is part oi Severn Trent Laboratories, Inc.
Job NLfnber: 233858
CUSTOMER: Weston Solutions,, Inc.
Customer Sample ID: OBKG-SS-0001--00Q3 Date S a i l e d ...... :01/27/2005 Time Sampled...... :15:40 Sample Matrix..... :Soi I
TEST METHOD Lloyd Kahn
PARAME TER/TST DESCRIPTION
Total Organic Carbon {Soils} TOC Average Duplicates, Solid
LABORATORY
TEST
RESULTS
PROJECT:.tOWFlDE HT IAL DECATUR
Laboratory Sample ID: 233858-2 Date Received....... :01/29/2005 Time Received....... :09:DO
Date:D2/1T/2005 ATTW: Jai Kesari
SAMPLE RESULT 3 FLACS I, 13000
MDL 688
- RL 2700
PILUT IOH- UNITS BATCH DT DATE/TIME TECH:
1
mg/Kg 141703
02/09/05 1455 cIs
I * In Description = Dry Wgt.
______ i________________ Page 3
1
STL Chicago is part of Severn Trent Laboratories, Inc.
In Description = Dry Wgt.
Page 4
STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 23335B
CUSTOMER: Weston Solutions / Inc. .
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR
Date:Q2/11/2005 ATTN : Jai Kesari
In Description = Dry Ugt.
Page 5
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Nunber: 233858
CUSTOMER: Weston Solutions, Inc.
Customer Sample ID: DBKG-SS-0003-0-0GD Date Sampled...... :01/27/21)05 Time Sampled...... :15 :45 Sample Matrix..... :Soi I
TEST METHOD Lloyd Kahn
PARAME TER/TEST ;O ESCRIPTION ;
Total Organic Carbon (Soils) TOC Average Duplicates, Solid
LABORATORY
TEST
RESULTS
PROJECT:' CONFIDENTIAL DECATUR
Laboratory Sample ID: 233358-5 Date Received...... : 01/29/2005 Time Received...... : 09:00
Date:Q2/T/2005 ATTN: Jai Kesari
SAMPLE RESULT .0-,FLAGS 13000
MOL 700
rl: 2700
L:. DI LUTION UM ITS
BATCH ; DT DATE/IME TECH
,1
mg/Kg 141703
02/09/05 1540 els
* In Description = Dry Ugt.
Page 6
STL Chicago is part of Severn Trent Laboratories, ]nc.
* [n Description = Dry Wgt.
Page 7
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Number: 233858
LABORATORY
CHRONICLE
Date: 02/11/2005
CUSTOMER: Weston Solutions, Inc.
Lab ID: 233858-1 METHOD
DD PKG INO (WC) Lloyd Kahn
Client ID: DBKG-SS-0001-0-0000 DESCRIPTION Electronic Data Deliverable PKG INO (UET CHEMISTRY)
Total Organic Carbon (Soils)
Lab ID: 233858-2 Client ID: DBKG-SSn0001-0-0003
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (SoiLs)
Lab ID: 233858-3 Client ID: DBKG-55-0002-0-0000
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 233858-4 Client ID: DBKG-SS-0002-0-0003
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 233858-5 Client ID: DBKG-SS-0003-0-0000
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 233858-6 Client ID: DBKG-SS-0003-0-0003
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
PROJECT: CONFIDENTIAL DECATUR '
ATTN: Jai Kesari
Date Recvd: 01/29/2005 Sample Date: 01/27/2005
RUN# BATCH# PREP BT #(S)
DATE/T1ME ANALYZED
1
1
1 141703 141703
02/09/2005 1437
Date Rccvd: 01/29/2005 Sample Date: 01/27/2005
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 141703 141703
02/09/2005 1455
Date Recvd: 01/29/2005 Sample Date: 01/27/2005
RUN# BATCH# PREP BT #($)
DATE/TIME ANALYZED
1 141703 141703
02/09/2005 1508
Date Recvd: 01/29/2005 Sample Date: 01/27/2005
RUN# BATCH# PREP BT #(S>
DATE/TIME ANALYZED
1 141703 141703
02/09/2005 1524
Date Recvd: 01/29/2005 Sample Date: 01/27/2005
RUN# BATCH# PREP BT #<S)
DATE/TIME ANALYZED
1 141703 141703
02/09/2005 1540
Date Recvd: 01/29/2005 Sample Date: 01/27/2005
RUN# BATCH# PREP BT #(S)
DATE/TIME ANALYZED
1 141703 141703
02/09/2005 1557
DILUTION
DILUTION DILUTION DILUTION DILUTION DILUTION
Rage 8
7
Job Nimber.: 233858 CUSTOMER: Weston Solutions, Inc.
QUALITY CONTROL RESULTS PROJECT: CONFIDENTIAL DECATUR
Report Date.: 02/11/2005 ATTN.: Jai Kesari
Teat Method....... : Lloyd Kahn .'Method .Dose ript ton. 'TotalOrganic Carbon (Soils> Parameter.. . . ; ;OrganicCarbon,:Tot.. (TOC)
QC Lab ID
Reagent
Units
ICV 141703-002 I05ASTTC2 MB 141703-003 LCS 141703-004 I00FSTLK3 LCD 141703-005 IQFSTLK3
mg/Kg
mg/Kg mg/Kg
mg/Kg
QC Result
QC Result
1821.76
32.00 U
4620.49
3491.99
4620.49
CCV 141703-016 I05ASTTC2 CCB 141703-017
CCV 141703-016 I05ASTTC2 CCB 141703-017
mg/Kg
mg/Kg
mg/Kg mg/Kg
1922.51 32.00
2033.29
32.00
U U
Batch.......... Equipment Code.
.141703 TOC4
Analyst...: cla Test Code.: TOC
True Value 2000.00
47S.00 4780.00
2000.00
2000.00
Orig. Value QC Cslc u F * Limi ts
Date Time
91
176.55 U 97 170.10 U 73
28 96
102
LT LCTO1
% 85-115
% 53-140 % 53-140 R 28 % 85-115
%
02/09/2005 0836 02/09/2005 0842 02/09/2005 0904 02/09/2005 0912
02/09/2005 1412 02/09/2005 1417 02/09/2005 1609 02/09/2005 1612
Page 9
* %=% REC, R=RPD, A=AB5 Dtff., Ds% [iiff.
8
.a s s u r a n c e
m ethqd s
E N C E S A N D / N/O T E S
.
Report'Date: 02/11/2005
REPORT COMMENTS 1) All pages of this report are integral parts of the analytical data. Therefore, this report should
be reproduced only in its entirety. 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when analyzed for
Landfill disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis unless noted differently. 3) Reporting Limits are adjusted for sample size used, dilutions and moisture content if applicable. 4) The test results for the noted analytical method(s) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 4QCFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sample collection. When these parameters are not indicated as field (e.g. pH Field) they were not analyzed immediately, but as soon as possible on Laboratory receipt.
Glossary of flags, qualifiers and abbreviations (any number of which may appear in the report) inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the stated Limit. < Not detected at or above the reporting limit. J Result is less than the RL, but greater than or equal to the method detection Limit. B Result is less than the CRDL/RL, but greater than or equal to the IDL/MDL. S Result was determined by the Method of stahdard Additions. F AFCEE: Result is less than the RL, but greater than or equal to the methoddetection Limit. Inorganic Flags (Flag Column)
ICV,CCV,ICB,CCB,ISA,I SB,CRI,CRA,MRL: Instrument related QC exceed the upper or lower control limits. * LCS, LCD, MD: Batch QC exceeds the upper or lower control limits. + MSA correlation coefficient is less than 0.995. 4 MS, MsD: The analyte present in the original sample is 4 times greater than the matrix spike concentration; therefore, control limits are not applicable. E SD: Serial dilution exceeds the control limits. H MB, EB1, EB2, Eb3: Batch QC is greater than reporting Limit or had a negative instrument reading tower than the absolute v a l u e of the reporting Limit. N MS, MSD: Spiko recovery exceeds the upper or lower control Limits. W AS(GFAA) Postrdigestion spike was outside 85-115% control limits. Organic Qualifiers (Q - Column) U Analyte was not detected at or above the stated limit. ND compound not detected. J Result is an estimated value below the reporting Limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. Y The chromatographic response resembles a typical fuel pattern. I The chromatographic response does not resemble a typical fuel pattern. E Result exceeded calibration range, secondary dilution required. F AFCEE:Result is an estimated value below the reporting Limit or atentativelyidentified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater than reporting limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or lowercontrol limits. EB1, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The lower of the two values is reported when the % difference between the results of two GC columns is
Page 10
Q U A L I T V A S S U R A N C E M ::;i H O D S
R E F E R E N C E S A N D N 0 r. .e "S'
.. Report Date: 02/11/2005
greater than 25%. Abbreviations AS Post Digcstioh Spike (GFAA Samples Sco Note 1 below) Batch Designation given to identify a specific extraction, digestion, preparation set, or analysis set CAP Capillary CoLuim CCB Continuing calibration Blank CCV Continuing Calibration Verification CF Confirmation analysis of original C1 Confirmation ana Lysis of A1 or Dl C2 Confirmation ana Lysis of A2 or D2 C3 Confirmation analysis of A3 or D3 CRA Low Level Standard Check - GFAA; Mercury CRI Low Level standard Check - ICP cv Calilbrat ion Verification standard Dil Fac Dilution Factor - Secondary dilution analysis Dl Di Lution 1 D2 Dilution 2 D3 Dilution 3 DLFac Detection Limit Factor DH Distilled Standard - High Level DSL Distilled standard - Low Level DSM Distilled standard - Medium Level EB1 Extraction Blank 1 EB2 Extraction Blank 2 EB3 DI Blank ELC Method Extracted LCS ELD Method Extracted LCD ICAL Initial calibration ICB Initial Calibration Blank ICV Initial Calibration Verification IDL Instrument Detection Limit ISA Interference Check Sample A - ICAP ISB Interference Check Sample B - ICAP Job No. The first six digits of the sample ID which refers to a specific client, project and sample group
Lab ID An 8 number unique laboratory identification LCD Laboratory control Standard Duplicate LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation Blank MD Method Duplicate MDL Method Detection Limit MLE Medium Level Extraction Blank MRL Method Reporting Limit Standard MSA Method of standard Additions MS Matrix Spike MSP Matrix Spike Duplicate ND Not Detected PREPF Preparation factor used by the Laboratory's Information Management System <LIMS) pds Post Digestion Spike (ICAP) RA Re-ana lysis of original A1 Re-analysis of Dl A2 Re-analysis of D2 A3 Re-analysis of D3 RD Re'cxtraction of dilution RE Re-extraction of original RC Re-extract ion Confirmation RL Reporting Limit RPD ReLative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor RT Retention Time
Page 11
.. Q U A L I T f A S S U R A. N .c E M E T H O D
R F E ? E N C E S A N D N O T E S
eoortDate: 02/11/2005
RTU Retention Time Window Sample ID A 9 digit number unique for each sample, the first six digits are referred as the job nunber
SCB Seeded Control Blank SD serial Dilution (Coleulated when sampLe concentration exceeds 50 times the MDL) UCB Unseeded Control Blank SSV Second Source Verification Standard SLCS Solid Laboratory Control Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory Control Sample LCDP pH Laboratory Control Sample Duplicate MDPH pH Sample Duplicate MDFP Flashpoint Sample Duplicate LCFP Flashpoint LCS G1 Gelox check standard Range 0-1 G2 Gelex Check Standard Range 1-10 G3 Gelex Check Standard Range 10-1 DO G4 Gelox Check Standard Range 100-1000 Note 1: The Post Spike Designation on Batch QC for GFAA is designated with an "SM added to the current abbreviation used, EX. LCS 5=LCS Post Spike (GFAA); MSS=MS Post Spike (GFAA) Note Z: The MD calculates an absolute difference (A) when the sample concentration is Less than 5 times the reporting limit. The controL limit is represented as +/- the RL.
Page 12
11
CHAIN OF CUSTODY
12
23385^
CHAIN OF CUSTODY/ ANALYSIS REQUEST FORM
tH
Severn Trent Laboratories
T: 708-534-5200
F: 708-534-5211
2417 Bond Street
University Park, IL 60466
PAGE
PROJECT INFORMATION Client: Weston Solutions, Inc.
1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401
Project Manager: Jai Kesari email: LkesariiS?westernsolutions.com
Project Name: Reference No:
Decatur, Alabama 02181-129-081-0001
ANALYSES REQUESTED
Sampler:
T Frinak, A Murphy 256-552-6189
P.O. #: Quotation #:
SAMPLE ANALYSIS
ExyLIMS # 1
3
T
Client Sample identification
DBKG SS 0001
0000
DBKG SS 0001
0003
DBKG SS 0002
0000
DBKG SS 0002
0003
DBKG SS 0003
0000
DBKG SS 0003
0003
C o lle c tio n
Date 27-Jan-05 27-Jan-05 27-Jan-05 27-Jan-05 27-J a r-05 27-Jan-05
C d lection
T im e
15:30 15:40 15:55 16:05 15:45 15:50
X X
c 'oS. Jco zc
S a m p le M atrix
SOIL
SOJL
SOIL
SOIL
SOIL
SOIL
Comments 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES
CHAIN OF CUSTODY
CoolerlDNo.:
Relinquished
^ Pate - Time
---- ^ B ^ ----- * /
Received By: Fed Ex
U
Cooler Temp. (C): D*ite Time
'Ik * { o 6 tf o
PROJECT REQUIREMENTS
Results Deadline: Laboratory Report Options:
Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other:
Sample Lot#:
z f t s?
STL Chicago Internal Sample Custody Transfer Record
Client:
Sample No.
/--
' /-
Analysis
< /etc
Relinquished by: Received by: ___ ______________
Date
Time
Comments
V
2/f/^" 2 / f v ^ r /s;/<
tH
CHI-22-11-O01fC-1/99
rpjsckl
Job Sample Receipt checklist Report
Job Number,: 23385S
Location.: 57222 Check List Number.: 1
Description.:
Customer Job ID.... :
Job Check List Date.; 01/29/Z005
Project Number.: 20004891 Project Description.: Confidential Decatur - FC Investigation
Customer...... : Weston Solutions, Inc.
Contact.: Jai Kesari
Questions ?
(Y/h) Comments
V2
Date of the Report..: 02/11/2005 Project Manager.... : rew
Chain-of" Custody Present?.......
Y
Ucre samples dropped off at or picked up by STL?.. N
Custody seal on shipping container?.... ........., Y
...If "yes", custody seal intact?... ............ Y
Custody seals on sample containers?.............. N
...If "yes1*, custody seaL intact?................
Samples iced?.,...........................
Y
Temperature of cooler acceptable? (4 deg C +/- 2). Y 3.2
Samples received intact (good condition)?........ Y
Volatile samples acceptable? (no headspace)......
Correct containers used?............
Y
Adequate sample volume provided?................ . Y
Samples preserved correctly?....,... ............. Y
Samples received within holding-time?............ Y
Agreement between COC and sample Labels?......... Y
Radioactivity at or below background levels?..... Y
A Sample Discrepancy Report (SDR) was needed?..... N
If samples were shipped was there an air bill #?.. Y
Sample Custodian Signature/Date........... .... .. Y
Page 1
15
Express US A i r b i l l ; 4fl4% 4flaBlL,
! f
Sender's Menu
! "T~f .
Cnrnpeny
C cM
f As / / :
4a ExpressPackage Service_ [CX-JjFHNessdiEhxtiPnraionrintywOyvernight II-- II MFaetdtExuSntsanafdlavrmdonO*vernight
fo dtyw+TivkJ^iffsasrtfetn* f1--" |' FEdoeiirdwfEtiaxftiFfgwvtscotboOtikmvxKeaMrMnionig*hhat
Pr "tii1H" "B X. N.
S2 . ---S------\-- ----2--L------ *- --> /-`i r:.' y
_ j' /
/v ^ C
' I FSKadHE^*bZtMDaiirtrdaV
I-- i :Tn_Fe_WHd_bEMxwEnxnlp,lrnierrss Sever
1-- -- fftti&t&EEiwwettaaMwtmiaBnnaatteaHnlMeitah.. thffcciwndiare:C-Paadrn&
Express Freight Service
Ad^ft*tTeinwwlllSWtilaBuL
~ r ^ ^
Fe^1D a|fJB igtit*
r~ |
F rsjjht
[ J fe d |t^ B ^ fr9 ig h t
Aridhess / / ^ B it f -^ x - C . jj
J fi V
( C
,4
StfltB /~ f *
2 Your bABrwdSilKng Reference
3 To RKpnfi
J H .- 1 1i i-
f \ Cv.-t- " '' '
i1
1P
Comcerw
} -: ^ r _
{ ` 'X - ^
J - T /"":
Hscipient'e M irata
l-t 1!
/
Wttctmfl lebirta PjO.bras k P.D.Z fc ^ u
|/S'_"..=r - -
______
png
/LfcSn
!D FedEt Rek*
~ ] FedEx
-- twukeibliWa^rEAxiiaiuiiJiixt.eieif^h--i Box
^SodmlYt*hiSU
FedEx W ibt Tube
Special Handling
iKUthCi aMNn Swami,
S M IM W M e e rv
i-- IHOU)Weekday
r-- tHOiOSMwdn
I I et R ii t L icanon
MiMMert
OMttbla entbrxrallthf*ecnMarroti*BMi?~1
I ! .arfDtaFnwtienlidUiEttixWniTLditoWrfP^aiMda&EtiitnfJkTvrrti'
R No In-- IIfes
. =--n IS*tfcftrsIlKhiiHon I--n : rfhljrVynfic,aUJ
DnpanaKttsftKludSnKgDfriYflsrDil*uHnintnbmBstifipednioitFrtet^OntpfiEfc^r
rO--- Carne Aircraft Only
1 Pijmant ffiffac EwFaEKAcaAl(U*DirtNt.bfcM
DbtiinAidpL I" - !
1 Aitt.No.
1
itottikL
[j flecipiet* [3] ThirdParty: Q CradtCaid PI CasWheck
Address Tatv$MOtAFU|p b*baUrtft if H f
torteti pristFtCxrttnmhtr.
'
// CitV C' r : -
I_____ / -
ff State 1 * -
ZIP
&0
:
>4 1
L
,, __L t m
jdv tn fm liL s to A ta r ttiiH ttp tr ^ ir tiW rta n n a a sbram a iaxCigre$ tv naniV U d htftl teh erri cssinor STfrajutlirijdHHs.
..':Bc1r. W['T(,lwtiEiXr*obfT&tJndA#h1triHbili.9lItIlJ~lB+IieLMir-SiXnvrMaffeeldSif'lxPTjttarTniD.HU3A XW1SM`**
.. J
H
CASE NARRATIVE
Client: Job#:
STL Chicago Wet Chemistry Case Narrative
Weston Solutions, Inc. 233858
DateRec'd: 01/29/05
1. This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kahn Method.
The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on aDohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content. The average of the sample bums is reported.
2. The method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates o f sampling, receipt, and analysis.
3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria.
4. The method blank was less than the reporting limit.
5. The LCSs were within acceptance limits.
6. No matrix QC was done on these samples.
"C - visf U Diane L. Harper Wet Chemistry Section Manager
Date
18
RAW DATA
*** RUN LOG
***
(V2 >
2/10/05 15:17
Total, organic Carbon (Soils) Method Code..: TOCS Batch Code...: 141703
Status...... : RVWD Batch Date__ : 02/10/05 Batch Time.**: 1335
User Name...... ; els QC Code........ :TOCS Calc code...... :TOCS
Location code.*: 57222 Equipment Code.: TDC4 Import Code___ :
TEST CODE
TTT TTT TTT TT TT
00000CCC III
C c C C C cC S S S C CC
2 3 4 A A A 2 A ssS
VVV
V 2A
234
22
SAMPLE: Grp Pas Sample ID
Di lution
TEST POS Date / Time
12 3 4 56 7 1 1 122 2 7890 12
11
ICAL I05ASTTC1
0
12
__ ICV_I05ASTTC2_
2/9/05 1 0836 0
13
MB
2/9/05 1 0842 0
14
___LCS_I00FSTLK3_3
2/9/05 1 0904 0
15
___LCDJ00FSTLK3J
2/9/05 1 0912 0
16
233991_1_S__
2/9/05 1 10Q0
0
17
233992_1_S__
2/9/05 1 1019
0
18
23365 7_15_S___
2/9/05 1 1038
0
19
233857_15_S_MS_105AST TC2_8
2/9/05 1 1056
0
1 10 233857J 5_SJ1SDJ 05ASTTC2_8
2/9/05 1 1113
0
1 11 233857 16 s
2/9/05 1 1123
0
1 12 233857_17_S___
2/9/05 1 1236
0
1 13 233857_18_5__
2/9/05 1 1304
0
1 14 233857_19__S__
2/9/05 1 1321
0
1 15 233857_20_S__
2/9/05 1 1336
0
1 16 __ CCV_I05ASTTC2_
2/9/05 1 1412 0
1 17 __ CCB__
2/9/05 1 1417 0
1 18 233858J_S___
2/9/05 1 1437
0
1 19 233858_2_Si__
2/9/05 1 1455
0
1 20 233858_3_S__
2/9/05 1 1508
0
1 21 233858_4_s__
2/9/05 1 1524
0
1 22 233858 5 S
2/9/05 1 1540
0
1 23 233858_6_s___
2/9/05 1 1557
0
1 24
CC9 I05ASTTC2
2/9/05 1 1609 0
1 25 __ CCB__
2/9/05 1 1612 0
Page 1
--
20
*** QC Summary
#**
(V2 )
Total Organic Carbon (Soils)
Method Code.*: TOCS Batch Code...: 141703 Status...... : RVWD
Batch Date...: 02/10/05 Batch Time!..: 1335 User Name,..,; els
QC Code....... : TOCS Calc Code..... : TOCS Location Code..: 57222
Grp $mp sampLe ID
Pos Test Result
Known
Original
1 2 __ JCVJD5ASTTC2_
1 TOC 1821.76 2000
13
...MB
1 TOC -2.14
1 4 ___ICS_IOOFSTLK3_3
1 TOC 4620.49 4780
-2.14
1 5 __ LCD_100FSTLK3_3
1 TOC 3491.99 4780
-2.14
1 9 23385 7J5_S_MS_105ASTTC2_8
5 TQCAV2 9888.89 2000
6139.47
1 10 233857_15_S_MSD_I05ASTTC2_8
5 OCAV2 9488.10 2000
6339.47
1 16
CCV I05ASTTC2
1 TOC 1922.51 2000
1 17 ___CCD__
1 TOC -2.98
1 24 __ rCCV_I05A5TTC2_
1 TOC 2033.29 2000
1 25 __ CCS__
1 TOC -3.68
Report Date: 2/10/05 15:17
Equipment Code.: T0C4 Import Code.,.,:
Alternate QC Res 91
F QC Re$
F
4620,49
97 73 72 66 96
28 8.7
102
Page 1
21
*** RAW TEST PATA
***
(V2 )
Tetal Organic Carbon (Soils)
Method code.* TOCS
Batch Code. .. 141703
Status.rr.
RVWD
Batch Date...: 02/10/05 Batch Time...; 1335 User Name___ : els
SAMPLE:
Gtp Pos Sample ID
11
ICAL I05ASTTC1
12
ICV I05ASTTC2
13
MB
14
LCS IQFSTLK3 3
15
LCD I0FSTLK 3
1 6 233991 1 S
1 7 233992 1 S
1 S 233857 15 S
1 9 233857 15 S MS I05ASTC2 8
1 10 233857 15 S MSD I05ASTTC2 8
1 11 233057 16 S
1 12 233857 17 S
1 13 233857 18 S
1 14 233857 19 S
1 15 233857 20 S
1 16
CCV I05ASTTC2
1 17
CDS
1 10 233858 1 S
1 19 233S58 2 S
1 20 233858 3 S
1 21 233858 4 S
1 22 233358 5 S
1 23 233858 6 S
1 24
CCV I05ASTTCZ
1 25
CCB
0C Code..., Calc Code. Location Code..: 57222
Di Lution
TOC mg/Kg
T0C2 mg/Kg
Report Date: 2/10/05 15:17
Equipment Code.: T0C4 Import code.... ;
T0C3 mg/Kg
TQC4 mg/Kg
T0CAV2 mg/Kg
1821.76 "2.14 4620,49 3491.99 861036.50 391869.38
5555.71 9BB8.89 9488.10 5264.93 11715.02 4884.24 8024.53 6565.24 1922.51 "2.98 27408.08 14928.04
6655.65 3921.65 20712.70 8671.09 2033.29 -3.68
767109.20 406765.50 7123.22
5762.03 12068.69 5256.29 5384.98 6954.60
27690.76 11545.22 9772.00 1862.60 15212.28 6747.67
814072.B5 399317.44 6339.47 9888.89 9488.10 5513.48 11891.85 5070.26 6704.75 6759.92
27549,42 13236.63 8213.83 2B92.12 17962.49 7709.38
Page 1
22
#** RAW TEST DATA
###
V2 )
Total Organic Carbon CSoits>
Method Code.,: TOCS Batch Code...: 141703 Status.,,frr.: RVWD
Batch Date...: 02/10/05 Batch Time...: 1335 User Name.... ;els
SAMPLE:
Grp Pos sample id
11
ICAL I05ASTTC1
12
ICV 05ASTTC2
13
MB
14
LCS I00FSTLK3 3
15
LCD I0QFSTLK3 3
1 6 233991 1 S
1 7 233992 1 S
1 S 233857 15 S
1 9 233857 15 S MS J5ASTTC2 8
1 10 233857 15 S MSD I05ASTTC2 8
1 11 233857 16 S
1 12 233857 17 S
1 13 233857 13 S
1 14 233857 19 S
1 15 233857 20 S
1 16
CCV I05ASTTC2
1 17
CCB
1 IS 233B5S 1 S
1 19 233858 2 S
1 20 233858 3 S
1 21 233858 4 S
1 22 233858 5 S
1 23 233858 6 S
1 24
CCV I05STTC2
1 25
CCB
OC Code........ : TOCS Calc code..... : TOCS Location Code..: 57222
Dilution
TCAV3 mg/Kg
T0CAV4 mg/Kg
Report Date: 2/10/05 15:1/
Equipment Code.: DC4 import Code___ :
TDCR1 ug
T0CR2 ug
TCR3 ug
91.0879 -0.3422
133.9942 105.1089 172.2073 313.4955 102.2250 199.7555 198.3013 113.7225 250.7015 71.7983 125.1827 138,5266 96.1255 -0.4764 178.1525 120.9171 99,1692 58.0404 124.2762 118.7939 101.6647 -0.5882
383.5546 325.4124 133.9166
149.2366 232.9257 98.8182 88.3137 167.6059
174.4518 79.6620 150.4888 38-3696 132.3468 84.3459
Page 2
23
*** RAW TEST DATA
**#
CV2 )
Total Organic Carbon (Soils)
Method Code.. : TOCS Batch Code... : 141703 statu...... : RVWD
Batch Date.. : 02/10/05 Batch Time.. : 1335
User Name... : els
SAMPLE:
Grp Pos Sample id
11
ICAL I05ASTTC1
12
ICV I05ASTTC2
13
MB
14
LCS 100FSTLK3 3
15
LCD IFSTLK3 3
1 6 233991 1 S
1 7 233992 1 S
1 8 233857 15 S
1 9 233857 15 S MS 5ASTTC2 8
1 10 233857 15 S MSD I05ASTTC2 8
1 11 233857 16 S
1 12 233B57 17 S
1 13 233857 18 S
1 14 233857 19 S
1 15 233857 20 S
1 16
CCV I05ASTTC2
1 17
CCB
1 18 233858 1 S
1 19 233858 2 S
1 20 233858 3 S
1 21 233858 4 S
1 22 233858 5 S
1 23 233858 6 S
1 24
CCV I05ASTTC2
1 25
CCB
QC Code.
TOCS
Cale Code..... : TOCS
Location Code..: 57222
Dilution
TCR4 ug
UT1 g
Report Date: 2/10/05 15:17
Equipment Code.; TOC4 Import code,,..:
UT2 UT3 W4 ggg
0.05 0.16
0.0290 0.0301 0.0002 0.0008
0,0184 0.0202 0.D2D9 0.0216 0.0214 0.0147 0.0156 0.0211 0.05 0.16 0.0065 0.0081 0.0149 0.0148 0.0060 0.0137 0.05 0.16
0,0005 0.0008 0.0188
0.0259 0.0193 0,0188 0.0164 0.0241
0.0063 0.0069 0.0154 0.0206 0.0087 0.0125
Page 3
24
RAW TEST DATA
(V2 )
Total Organic Carbon CSoi Is)
Method Code..: TOCS Batch Code...: 141703 Status.......: RVWD
Batch Date...: 02/10/D5 Batch Time...; 1335 User Name :els
SAMPLE:
Grp Pos Sample Id
11
ICAL I05ASTTC1
12
ICV I05ASTTC2
13
MB
14
ICS I0FSTLK3 3
15
LCD I00FSTLK3 3
1 6 233991 1 S
1 7 233992 1 S
1 8 233857 5 S
1 9 233857 15 S MS I05ASTTC2 8
1 10 233857 15 S MSD I5ASTTC2 8
1 11 233857 16 S
1 12 233857 17 S
1 13 233857 18 S
1 14 233857 19 S
1 15 233857 20 S
1 16
CCV I5ASTTC2
1 17
CCB
1 I S 233858 1 S
1 19 233858 2 S
1 20 233858 3 S
1 21 233858 4 S
1 22 233858 5 S
1 23 233858 6 S
1 24
CCV I05ASTTC2
1 25
CCD
QC Code........ :TOCS Calc Code......: TOCS Location Code..: 57222
Dilution
DLFAC N/A
TCS mg/Kg
Report Date: 2/10/05 15:17
Equipment Code.: TOC4 Import Code----:
TCS2 mg/Kg
TCSAV2 mg/Kg
TICS mg/Kg
3.2000 1.0000 5.5172 5.3156
457.1429 200.0000
8.6022 7.9208 7.6555 6.7368 7.8624 9.5522 10.0000 7.0796 3,2000 1.0000 25.0000 21.3333 10.5611 9.0395 21.7687 12.2137 3.2000 1.0000
Page 4
25
Calibration Report Print Date/Time: 2005/02/09 7:14:15
Cal. Curve ID:
SOILCURVE
Created:
01/17/2005 11:33
Calibration Factor (m): 8.538e+04
Y Intercept (b): 436425
r-squared:
0.99800
Standard ID Y X Expected Measured Message
Date &
Raw Data ug C ug C
Time
0 ugram C
-4530 0.000 5.165 No Sample Det 01/17/2005 09:53
10ugramC
1085240 10.000 7.599
01/17/200510:15
20 ugram C 1870210 20.000 16.794
01/17/2005 10:26
40 ugram C 3806480 40.000 39.473
01/17/2005 10:34
80 ugram C 7357282 80.000 81.062
01/17/2005 10:45
120 ugram C 11114689 120.000 125.072
01/17/2005 10:58
200 ugram C 18428840 200.000 210.740
01/17/2005 11:07
300 ugram C 26478564 300.000 305.025
01/17/2005 11:15
400 ugram C 33682344 400.000 389.401
01/17/2005 11:32
Multiple Analysis Report Print Date/Tme: 2005/02/10 8:05:27
Sample ID
Result Std. Dev. RSD Mode ALT
ICV
910879
TC
ICB-MB
-0.3422
TC
LCS
133.9942
TC
LCD........................ ....... 105.1089............. ...TC
233991-1
742.3906
TC
233991-1
172.2073
TC
233991-1................ .......... 383.5546...
.......... TC
233992-1
33.2797
TC
233992-1
313.4955
TC
233992-1........................... 325.4124... ...........TC
233857-15
102.2250
TC
233857-15
133.9166
TC
233857-15.............. ........... 199.7555...
.......... TC
233857-15msd
198.3013
1
233857-16
113,7225
TC
233857-16.......................... 1.2880...
. ...TC
233B57-16
149.2366
TC
233857-17
250.7015
TC
233857-17.......................... 232.9257... .......... TC
233857-18
71.7983
TC
233857-18
98.8182
TC
233857-19............... ...........125.1827...
...........TC
233857-19
88.3137
TC
233857-20
138.5266
TC
233857-20............... ...........167.6059...
ccv 96.1255
...........TC TC
CCB
-0.4764
TC
233858-1................. ..........542.9560...
...........TC
233858-1
178.1525
TC
233858-1
174.4518
TC
233858-2................. ......... 120.9171...
...........TC
233858-2
79.6620
TC
233858-3
99.1692
TC
233858-3................. ......... 150.4888...
.......... TC
233858-3
58.0404
TC
233858-4
0.0137
TC
233858*4................. ......... 38.3696...
. ...TC
233858-5
124.2762
TC
233858-5
132.3468
TC
233858-6................. ......... 118.7939...
.......... TC
233858-6
84.3459
TC
CCV
101,6647
TC
CCB................................ -0.5882.............. ...TC .
Detailed Analysis Report Print Date/Time: 2005/02/10 8:05:39
Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02090830
Timestamp: 02/09/200 Sample Type: Cal. Verification-
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 910879 91.0879 8213256
1.176 2,175 266
Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 02090839
f
Timestamp: 02/09/2006 08:42
Sample Type: Sample V . .
R ep# p pm C u g C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 -0.3422 -0.3422 -3453
1.332 1281 120
Last Message: No Sample Detected
Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02090859
Timestamp: 02/09/2 Sample Type: Sample
R ep# ppm C u g C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 133.9942 133.9942 11465814
1517 2.517 267
Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02090908
Timestamp: 02/09/2005 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 105.1089 105.1089 8999669
4.884 5.877 210
Sample ID: 2339911 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
lode: TC Filename: 02090941
lestamp: 02/09/200^09:4 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning\Ending Integration Baseline Baseline Ti
v
Sample ID: CCV Method: boat Calr Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 02091406
y"
Timestamp: 02/09/20G5 14:12
Sample Type: Cal. Verification""
R ep# ppm C u g C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 96.1255 96.1255 8643346
1541 2.539 306
Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02091414
Timestamp: 02/09/20Cp 14:17 y Sample Type: Sample y
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 -0.4764 -0.4764 -14907
1.939 1765 120
Last Message: No Sample Detected
Sample ID: 233858-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode:
'Filename: 02091422^ ' ^
Timestamp: 02/09/20054128
Sample Type: Sample y
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 542.9560 542.9560 46381816
1874 2.873 338
Sample ID: 2338584 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02091432
Timestamp: 02/09/; Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 178.1525 178.1525 15235919
2.272 3.272 266
Sample ID: 233858-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02091438
Timestamp: 02/09/2005 14:44 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 174.4518 174.4518 14919964
2.450 3.447 253
Sample ID: 233858-2 Method: boat Cal. Curve: SOILCURVE Operator ID; CAROL
Mode: TC Filename: 02091450
Timestamp: 02/09/ Sample Type: Sample -,--
X\ i
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 120.9171 120.9171 10349327
1744 2741 267
Sample ID: 233858-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02091458
Timestamp: 02/09/2005 15:03 Sample Type: Sample
Rep# ppm C u g C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 79.6620 79.6620 6827080
2.126 3.122 236
Sample ID: 233858-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Rep# ppm C u g C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 99.1692 99.1692 8492551
2.509 3.508 238
Sample ID: 233858-3 Mode; TC
Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL
Filename: 02091511 Timestamp: 02/09/2005 15:17
Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 150.4888 150.4888 12874076
1.899 2,898 266
Sample ID: 233858-\
i \o\
Method; boat
Cal. Curve: SOILCURVE '
Operator ID: CAROL
Mode: TC Filename: 02091519
Timestamp: 02/09/200615:24 Sample Type: Sample y ^
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 58.0404 58,0404 4981088
2,120 3.117 227
Sample ID: 233858-4
Mode: TC
Method: boat \
/Filename: 02091525
Cal. Curve: SOILCURVE * L (
Timestamp: 02/09/2005 15:27
Operator ID: CAROL \ ( y j r
Sample Type: Sample
R ep# ppm C u g c \ Raw Data Beginning Ending Integration
\Baseline Baseline Time
1 0.0137 0.0137 26938
2.443 3.439
18
Sample ID: 233858-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02091530
Timestamp: 02/09/2005 15:33 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 38.3696 38.3696 3301656
9.028 10.008 159
Sample ID: 233858-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02091535
Timestamp: 02/09/200: Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 124.2762 124.2762 10636120
2.452 3.447 252
Sample ID: 233858-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02091542
Timestamp: 02/09/2005 15:48 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 132.3468 132.3468 11325157
1.885 2.882 261
Sample ID: 233858-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
^
Filename: 02091552
S* \
Timestamp: 02/09/200515:57 /
Sample Type: Sample (
,/
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 118.7939 118.7939 10168049
2.014 3.012 267
Sample ID: 233858-6 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02091557
Timestamp: 02/09/2005 16:02 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 84.3459 84.3459 7226980
2.714 3.709 225
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 02091604
X"
Timestamp: 02/09/2005 16:09 /
Sample Type: Cal, V e rific a tio n -^
Rep# p p m C u g C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 101.6647 101.6647 9116269
1.810 2.808 264
Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 02091609
Timestamp: 02/Q9/200i Sample Type: Sample
Rep# p p m C u g C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 -0.5882 -0.5882 -24452
2.103 1.800 120
Last Message: No Sample Detected
STL Chicago TOC in Soils
Page No.:___^ 1 3 9
Book No.: ' T 9 Y ^7
Method: Lloyd Kahn
Instrument; Phoenix 3000 (TQC4)
LabNet Batch:
Calculations: TOC (mg/kg) ug C / grams sample
Data of Standard Curve: / / / 7
.
Book # n T ^ T Page * / 2 /
MS, MSD Known Cone, (mg/kg) 100 ug C / grams sample
MS, MSD Observed (mg/kg) = ug C / grams sample
MS. MSP Ree. fobserved mo/ka - ava, sample result (mo/kall x 100 known concentration in mg/kg
Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.
Stock I (Curve) 2 ~ - ^ $ / K '7 7 C f stock II (ICV/CCV) S &
S7JV
LCS Source ID TOO P f i ^ Z LCS True Value 9 9 J/ cc, Acceptance Range - / Y d ^
Sample (0:
Sample Weight (g)
ugC
Comment:
.C A
^3POrfilrb a / &
l ip 5 : n . o z Y n
.0 O
o . hi% o\
TT/
Ti , --
9/ ^<^7^22
/? ? , TT K f m / o * ? d!.S 2./?A*>V
<Z"
-/
r>' o a o z_
~ ___ rt . n n O I ~ 3 t r r t O
~~0'.
-------
T s y r T r ----
. > / - no. tnnCs O. c a r y
Y / 3. i f r < ^ r.i/z Y
q .TV 3?"7t/< " 0 . 0 f f Y ~ / r o, o / s f
YC2 , 3 2-rr T C
/3 . . TCC Z
.
^ T , r . a o cj-
T J tz T r ?f F?
-/K c oTl
9. V /-J rYYT.to
-- /C? <3, 0 3 U 0
f n , 72.2 r
_Q_r X X J l ^ j -------
_ &M
J
y 2.0 j c .o / y"
-Y -n
\ ~ ti
O .O Q _ ^ Y .0 a / 7 y. O / Y v
.O lY rt
r t Sr , 0 / ty - Y 7 o -r ? t r
l i T3 2LC,_ l l r t T J i T ?
n i, v m
9.
/ 2 r; /p 2.7
Prep Analyst: Analyst: / ^ ~ r . Reviewed by:.
/ v AJ ./ M M
T X --^
-- rc --
Date: ' x / i C f T H ;e /-/{, ^
Date:__2 ( q / 2_
Date:
CH(*22-12-095Q^ijQ1
STL Chicago TOC in Soils
140
Page No.
Book No.: *3 7 V 7____
Method: Lloyd Kahn
Instrument: Phoenix 8000 (TOC4^
LabNet Batch:
______
Calculation:
Date of Standard Curve: ~f/ /2 .A - r~ :
TOC (mg/kg\ = ua C / arams samole
Book# T 7 f/ ? Paae# ^ --
MS, MSD Known Cone, (mg/kg) 100 ug C / grams sample
MS, MSD Observed (mg/kg) = ug C / grams sample
MS, MSD Rec. = robserved ma/ko ~ avg, sample result (mq/ko)1 x100
^
known concentration in mg/kg
Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.)
Stock I (Curve)_____________ ') ^Steck(CV/CCV1__________________
LCS Source ID
--- "LCS True Value___________Acceptance Range___________________
Sample ID:
Sample Weight (g)
ug C
Comments:
X C l 2 7 - A 6 i0 9 ... 1 ~20 ( 3~n
^ ? /? 7
/ ? , c^tc
0 Ci i \
C <?U
, CUMI
!f i Loe S
O. 0 X
HI
I _(
w c-- --
- ( O- O J f X
n r,/a x '
-/
o. O O it/
ny k x /,X cm
a , < x f m rH s n - ~ / 9 U ? o
- 3 . <? / v ? 4/-&7 ^{4r' 9 9 , t i n
o , c? / r y
. /CO, H\?P
- y n>c} f '*?' S t.& fC i
J j-- O- 0
-- IX m -
_ -iw-i_T yV-1
r: f) x v tf O, 00 0 c
~ r ?. d r 7
jy i.iiiz
JX - Q
-C J 2
s c {cnA)
7 ./S7 J3-C / 7 T
O:0 < O fC?
nt nw ? V 'V /t*/ lo !, iQ v ;
X, ax
7
Prep Analyst:. Reviewed by:
x.-<-- -
k\.\ i
Date: nata-
0--h f#
7f
O ^ ft
' . h i *V r
