Document 0g750gXEkrwOykvRkkLoNOX0b
conoco
Interoffice Communication
To From Oats Subject
A. H. Sather
J. V. Uptain
December 20, 1978
CHEMICAL EXPOSURE MONITORING SUMMARY -FOURTH QUARTER, 1978
RECEIVED JAN 8 1979 MEDICAL DIV
I. Spray Metalizing
wt
*
For some time we have utilized a crude "flame coating" process in the main tenance shop for building up metal parts, particularly shafts and similar round objects. The process consists of metering finely divided metal powders, made for the purpose, into a flame, which contacts the metal part to be built up. Some concern developed that workers in the area might, as a result,, be overly exposed to heavy metals, since no controls for limiting the air borne concentration were present.
On 10/4/78, eleven (11) air samples were taken, while the various powders were used. The results appear in Table I and clearly show that better controls are needed. Since generation of the fumes is confined to one place in the shop, the most efficient control appears to be an adequately designed, local ventilation/exhaust system. This subject is imder discussion at writing.
II. Compound Line I Air Sampling
r
The final results of the high volume air samples taken on Compound Line I appear in Table II. Although one antimony result (sample 78-102) and one barium result (sample 78-116) are disturbingly high, the most significant problem appears to be lead - especially in view of the new OSHA Lead Stand ard.
III.
Color Weigh Room
p
Final analysis results of color weigh room sampling done since connection of the weigh hood to the compound ventilation system appear in Table III. As can be seen, the concentrations of heavy metals are still too high and little, if any, improvement was realized by the hood change. At writing, plans are being cast for re-vamping of the entire operation, including the ventilation equipment.
IV. 1978 Lead-in-Air Measurements
In anticipation of the questions to be raised as the effective date of the new OSHA Lead Standard approaches, all of the 1978 lead^in-air measurement s made with the high volume technique were summarized (see Table IV).
VAB.0001050071
A. H. Sather * December 20, 1978
Chemical Exposure Monitoring Summary
Fourth Quarter, 1978 Page 2
A
IV. 1978 Lead-in-Air Measurements (Cont.)
These measurements were all area-type in nature and, although they are no substitute for the dosimetry specified in the new standard, will be helpful during the "initial determination" that will be required.
V. Trimellitic Anhydride
n
During bag charging of trimellitic anhydride to a plasticizer reactor, one sample was taken. The airborne concentration was found to be 13 milligrams per cubic meter, somewhat i high. More samples are needed to better define the hazard. In the meantime, operators are required to wear respiratory protection during the task, which occurs only during the occasional pro duction of TOTM.
VI. Carbon Black
Several samples were taken of worker breathing zone air while they were charging carbon into plasticizer reactors. All results were essentially zero, with no significant danger being apparent.
VII. Hydroquinone
Six air samples were taken in the PVC reactor areas to define airborne concentration of hydroquinone. All results were negative.
erald V. Uptain
Attachments c: Plant Manager, Department Heads
DSC, EDS, DAK, JJH, 0D8
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Sample No.
78-1 78-2 78-3 78-4 78-S 78-6 78-7 78-8 78-9 78-10 78-11 78-12 78-13 78-94 78-98 78-101 78-104 78-105 78-109 78-110 78-111 78-112 78-118 78-102
*
78-106 78-107 78-108 78-115 78-116 78^117 78-125
78-126 78-128 78-17
78-27 78-33 78-46 78-47 78-65
TABLE IV
RECAP OF 1978 LEAD IN AIR MEASUREMENTS
>
1 " 1
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-HIGH VOLUME AIR SAMPLING-
Location
Concentration, Micrograms per Cubic
.Meter of Air
Color Weigh Room
< 0.5
Color Weigh Room
217.4
Color Weigh Room
390.0
Color Weigh Room
170.4
Color Weigh Room
171.4
Color Weigh Room
>327.3
Color Weigh Room
291.9
Color Weigh Room
162.6
Color Weigh Room Color Weigh Room
70.0
i*
575.0
Color Weigh Room
34.8
Color Weigh Room
*
Color Weigh Room
516.9 26.4
Color Weigh Room `
10.68
Color Weigh Room
6.53
Color Weigh Room
-
0.38
Color Weigh Room
201.27
Golor Weigh Room
47.19
Color Weigh Room
62.14
Color Weigh Room
1 <038.53
Color Weigh Room
9>*178.66
Color Weigh Room
Color Weigh Room
^376.54 22.57
Compound Line I - Between Blenders
103.24
Compound Line I - SE Comer, "B" Blender
7.28
Compound Line I - Between Blenders 8 Banbury 34.38
Compound Line I - SW Comer of Mill
22.87
Compound Line I - Between Blenders 6 Banbury^52.49
Compound Line I - SE Comer, "B" Blender
15.77
Compound Line 1 - SW Comer of Mill
5.56
Compound Line I - Between Blenders 6 Banbury
m
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Compound Line I - Compounder's Desk
272.94 2.55
Compound Line I - SW Comer of Mill
9.04
Compound .Line III - 3' W of SE Comer of Master Batch Charge Platform
1.76
Compound Line III - 3' E of E. Dicer Line
3.66
Compound Line III - SE Comer, FCM Room
45.48
Compound Line III - SE Comer, Feeder Deck 18.31
Compound Line III - E of FCM/Mi11 Conveyor 46.9S
Compound Line III - SE Comer, Feeder Deck 198.36
78-140 78-141 78-142 78-143 78-144
Maintenance Shop - Spray Metalizing Maintenance Shop - Spray Metalizing Maintenance Shop - Spray Metalizing Maintenance Shop - Spray Metalizing Maintenance Shop - Middle of Room
1.37 2.29 1.97 S.22 0.96
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Sample No.
78-66 78-67
78-68 78-76 78-77 78-84 78-86
78-87
78-88
78-89 78-90 78-92
78-93
78-20 78-21 78-25 78-51 78-52 78-73 78-54 78-5S 78-56 78-78 78-79 78-80
78-81
78-91
78-134 78-135 78-136 78-137 78-138 78-139 78-140 78-141 78-142 78-143 78-144
TABLE IV (Continued)
Location
. Concentration, Micrograms per Cubic Meter of Air
Compound Line III- SW Corner, Feeder Deck 20.07
Compound Line III - E. of FCM/Mill Conveyor
46.63
Compound Line III- 3* E of E Dicer Line
3.31
Compound Line III- Mill Oper. Station
0.72
Compound Line III- Mill, Oper. Station
4.46
Compound Line III - Mill, Oper. Station
8.82
Compound Line III- SE Comer, Blender Platform
14.71
Compound Line III - 4* E of Blenders, Floor 6.44 level
Compound Line III - 4' E of Blenders, Floor 20.61 level
Compound Line III - Blender Platform
^460.46
Compound Line III - Control Room
2.45
Compound Line III - SE Comer, Blender Platform
35.14
Compound Line III - Between Line 3 8 Dry
12.78
Blend Charge Platforms,
Floor level.
Dry Blend -Mezzanine Above 2nd Floor
27.9
Dry Blend -Mezzanine Above 2nd Floor
2.1
Dry Blend -Mezzanine Above 2nd Floor
3.7
Dry Blend - Mezzanine Between 1st 6 2nd Floor 2.11
Dry Blend - Mezzanine Between 1st 6 2nd Floor 3.73
Dry Blend Mezzanine Between 1st 8 2nd Floors 3.04
Dry Blend - Basement, Blender Platform
4.05
Dry Blend - Basement, Blender Platform
9.03
Dry Blend - Basement Blender Platform
8.10
Dry Blend - Mezzanine Above 2nd Floor
23.15
Dry Blend - Mezzanine Above 2nd Floor
21.79
Dry Blend - Mezzanine Between 1st 8 2nd Floors
35.26
Dry Blend - Mezzanine Between 1st 8 2nd Floors
31.50
Dry Blend - Master Batch Platform, Between 10.35 Hoods
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5.24
Maintenance Shop -Spray Metalizing
3.19
Maintenance Shop -Spray Metalizing
0.75
Maintenance Shop -Spray Metalizing
1.64
Maintenance Shop -Spray Metalizing
2.23
Maintenance Shop -Spray Metalizing
4.33
Maintenance Shop -Spray Metalizing
1.37
Maintenance Shop -Spray Metalizing
2.29
Maintenance Shop -Spray Metalizing
1.97
Maintenance Shop -Spray Metalizing
5.22
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0.96
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