Document 0Xdg0vy7E3gv3aqQ3qL3OXzM

From lh dtsk of PAULA CLINE, THE ARCHIVES OFFICE First Printing 1942 see "Monsanto Magazine" June, 1942 - last page 0683738 TOWOLDMON0041822 0683?<t0 TOWOLDMONOQ41824 MONSANTO CHEMICALS 0683741 TOWOLDMONOQ41825 District Office' \ k U< hY < Ml l< > Jm. 1 National Building Telephone: II l\ml< rk <>l`M 1 < >S WGLI.I S. <. U If. fj(G \\ *t < )|\ mpic Bl\ ||. I'elephone: Michigan OOlK III B M 1 \CII \M. \l.\. Bphaii \lar\ Building 1 I**[ 1 hm: 7-DH77 M< *\TRE XL. C W VI) \ 37H St. Paul Street Wet Telephone: \| Vrket 1 J Wi If (STUN. \1 \SS. K\ i-rrit Station l'**lo|H<m**r 1 \ I-.r** t NEW VnRK. N. 1 , hi B< >.'keteller Pla/d Telephone: ( Irele 7(< 1 "0 charlotte. \ <: Johnston Building Telephone: JO lo I CHICAGO, ILL. Tribune Tower Telephone: \X HI Khali 677)0 DETROIT, MICH. IJ7 Fisher Building Telephone: TRinit. J*>7JH LONDON, ENGLAND Victoria Station House ST. LiH IS. Ml). 1 700 South Second Xreet Telephone: ( T.ntral OJ t t SVN FRANCISCO. C\l IK. !') Mil'll Street Telephone: DOuglas 11 JO TORONTO, CAYVD V 183 Front Street East Telephone: W AverU 1 1 M MELHOLR.NE, Al STB \ 1 I \ Somerville Road Bravhrook W. 19 MANCHESTER. ENGLAND King** House Ring'* Street West ------------------------ Jf'orA-*_____________ ANNISTON, ALA HAM A CARONDELET, MISSOLRI CAMDEN. NEW JERSEY DAYTON. OHIO EVERETT, MASS. KARNACK. TEXAS MONSANTO, ILLINOIS MONSANTO, TENNESSEE NITRO. W EST VIRGIN \ NORFOLK. \ 1 KOI N1 V TEXAS CITY. TEX IS TRENTON. MICIIIC IN SPRINGFIELD. MASS. ST. LoLIS, MISSOLRI MONTREAL. CAN ADA RLABON, N. W ALES SUNDERLAND, F.NGHNI) MELBOURNE. AUSTR II I 1 I'jlie 2 MONSANTO 1 II E M M \ 1 ' 0683742 TOWOLDMONOQ41826 Divisions and Associated Companies MERRIMAC DIVISION. Everett Station, Boston, Maas. ORGANIC CHEMICALS DIVISION, 1700 S. Second St., St. Louis. Mo. PHOSPHATE DIVISION, 1700 S. Second St., St. Louis, Mo. PLASTICS DIVISION, Springfield, Mass. TEXAS DIVISION. Karnack. Texas. RUBBER SERVICE DEPARTMENT, 2nd National Building, Akron, Ohio. CENTRAL RESEARCH DEPARTMENT, Dayton, Ohio. NEW ENGLAND ALCOHOL COMPANY, Everett Station. Boston, Mass. SHAWINIGAN RESINS CORPORATION, Springfield, Mass. MONSANTO (CANADA), LTD., 378 St. Paul St. West, Montreal. Quebec. MONSANTO CHEMICALS LTD., Victoria Station House, Victoria St., London, S. W. 1, England. MONSANTO (AUSTRALIA) PTY. LTD., Somerville Road, Bravbrook W. 19, Melbourne, N. S. W., Australia. Cable Address "Monsanto" St. Louis Codes: ABC. 6th and 7th Acme, Bentley's and Bentley's Second 26TH EDITION Page 3 0683743 TOWOLDMONOQ41827 CONTENTS Mow To Lse This Hook................ A Viord About Containers................ Monsanto--The Organization. . Industries Served by Monsanto...................................................... 11 Monsanto Products .........................................................................IT Monsanto Literature........................................................................145 General Data........................................................................................ 149 Testing Liquids With the Hydrometer....................................... 149 Dilution and Concentration of Liquids.....................................151 Sulfuric Acid Tables......................................................................152 Hydrochloric Acid Tables............................................................154 Nitric Acid Tables........................................................................156 Acetic Acid Tables ......................................................................158 Aqua Ammonia Tables............................................................... 159 Anhydrous Ammonia Tables......................................................161 Aluminum Chloride Tables ........................................................162 Aluminum Sulfate Tables ..........................................................163 Sodium Bisulfite Tables..............................................................165 Merclor Tables................................................................................ 166 Weights Per Gallon......................................................................167 Conversion Tables for Volumeand Weight.................................168 Page 4 MONSANTO CHEMICALS 06837*. A J TOWOLDMONOQ41828 HOW TO USE THIS BOOK This is an entirely new book, designed to bring together in the most convenient and useful form possible, sufficient information on all Monsanto products to serve as a buying guide and to enable users of chemicals to determine whether a material unfamiliar to them is of sufficient interest to merit further consideration. Those desiring more detailed information on specific products are referred to the Mon santo literature listed on page 14o or to their nearest Monsanto dis trict office. Locations of these offices are given on page 2. All products are listed alphabetically in the main section of the book according to their common chemical names or Monsanto trade names. Where a product has more than one common name, or both a trade name and a chemical name, it has been attempted to list all of these along with proper cross references, thus making the book self indexing and eliminating the trouble of referring to an index first and then to a given page number. To assist users of chemicals in acquainting themselves with the Monsanto products applicable in their particular industry, a classi fication of products according to industries is given on page 11. This classification should not be considered final or complete. New uses for Monsanto chemicals and plat-tics are opening up dailv, some in fields entirely unsuspected a snort: time before. Likewise, no product should be considered as limited to the uses mentioned in this book. The general data section beginning on page 149 contains a varietv of physical and chemical information which will be useful in connec tion with certain products described in the alphabetical section. Specific reference to this data is made under products to which any ot it applies. If as you use this book suggestions come to mind as to how it might be made more helpful we would appreciate your passing them along to us. In this wav we will be able to make our next edition even more useful to you and the many other users of Monsanto products. A WORD ABOUT CONTAINERS Because of the rapid changes taking place in the availability of con tainers at the time this book was compiled, no attempt was made to include container data of any kind. Users of Monsanto products mav rest assured, however, that at all times their orders will be shipped in the highest quality and most satisfactory containers available. For current container information write your nearest Monsanto district office. CAUTION: The products described in this book are primarily for manufacturing use. They should not be used on the human body, either internally or externally, until their safety for the use intended is clearly established, and then not unless under competent direction. 26TH EDITION Page 5 0683745 TOWOLDMONOQ41829 06837*6 TOWOLDMONOQ41830 MONSANTO -- The Organization Monsanto Chemical Company, founded in 1901 by John Francis Queenv and given his wife s maiden name, today is one of the major American producers of chemicals and plastics. Stemming from broadly diversified chemical raw materials such as coal tar. petroleum, phos phorus. cellulose, salt and sulfur. Monsanto products number in the hundreds and find use in virtually every branch of manufacturing industrv. The company's five divisions and Canadian affiliate operate four teen plants in North America, and subsidiary companies operate three overseas. Four government plants are in operation or under construction. ORGANIC CHEMICALS DIVISION The Organic Chemicals Division is the lineal descendent of the original Monsanto works. To considerable extent, the division's products, too, derive from the research program begun in the first days. The original Monsanto product, saccharin, is now one of manv made and sold by the division. Others fall in a wide varietv of classi fications including pharmaceuticals, drug intermediates, dve inter mediates, petroleum additives, flavorings, plasticizers, resins, insect icides and neavy chemicals. The division's largest plant is on the site of the original works at St. Louis. Here are manufactured the fine chemicals, many derived from coal tar, that established Monsanto's early reputation, as well as numerous other classes of products. Across the Mississippi River from St. Louis, in Monsanto, Illinois, the Organic Chemicals Division operates a large plant producing heavy chemicals and organic inter mediates. At Norfolk, Virginia, the division operates a plant manufacturing intermediates. Rubber Service Department Monsanto's Rubber Service Department, part of the Organic Chem icals Division, specializes in supplying the needs of one industrv. It provides the rubber industry with many chemicals sucb as accelera tors, antioxidants, mold lubricants, pigments, colors, preservatives, softeners and plasticizers. A modern laboratory is maintained for solving compounding problems. The facilities of this laboratory and the help of its trained and experienced staff is available without cost to users of Rubber Service materials. The Rubber Service headquarters are at Akron, Ohio, in the 26TH BDITtON Page 7 0683747 TOWOLDMONOQ41831 heart of the rubber manufacturing district. The plant is at Nitro, West Virginia. MERRIMAC DIVISION Monsanto's Merrimac Division, headquartered at Everett Station, Boston, manufactures a diversified line of heavy and industrial chem icals. Included among its products are acids, lacquers, alcohol, sol vents, intermediates, tanning chemicals, commercial gases and lampblack. The division operates thne plants, the largest being at Everett Station, Boston. Adjoining this are the facilities of the .New England Alcohol Company, a partly owned subsidiary of Monsanto. At Camden, New Jersey, Monsanto lampblack is manufactured. Some of the products of the Merrimac Division duplicate those made at other plants of the company and thus provide an eastern source of supply for Monsanto customers. PHOSPHATE DIVISION The phosphates and other compounds of phosphorus are, as a class, increasing in importance. They are finding use in such varied fields as medicinals, water treatment, dentifrices, soaps, metal treatment, and foods. Operations of Monsanto's Phosphate Division are based on the production of elemental phosphorus at Monsanto, Tennessee. At this location, phosphate earth ts dug from large open pit mines and charged into huge electric furnaces where the phosphorus is freed in elemental form. From elemental phosphorus comes phosphoric acid, the parent of the large family of phosphates which are made in the division's other plants at Anniston, Alabama, Carondelet, Missouri, and Trenton, Michigan. At Anniston, in addition to phosphates, those products of the division not derived from phosphorus, such as diphenyl, Aroclors, Santowax, calcium carbide and aluminous abrasives are made. Head quarters for the division are at St. Louis. PLASTICS DIVISION Monsanto's Plastics Division has attained a leading position in the new and growing plastics industry. The development of new plastics and their application is a continuing and accelerating process, a fact Page 8 MONSANTO CHEMICALS 0683746 TOWOLDMONOQ41832 Monsanto, Tennessee, phosphorus furnace plant at night which guides the policies of the division from research through pro duction to sales and advertising. Monsanto's plastics opetations are consolidated at Springfield, Massachusetts. As a result oi a construction program begun in 1938 there have been several major additions at Springfield, including a plant for the production of Kesinox phenol-formaldehyde resins and molding materials, and the plant of the Shawinigan Resins Corpora tion, a Monsanto affiliate manufacturing vinyl resins. TEXAS DIVISION In 1941 Monsanto was requested by the Rubber Reserve Company, a government agency, to design, construct and operate a plant to manufacture an important raw material for synthetic rubber. The same year, at the request of the Ordnance Department of the United States Army, the company contracted to operate a major plant for the manufacture of munitions. The Texas Division was created to operate these two plants. The division makes no products for general sale. CENTRAL RESEARCH DEPARTMENT Research at Monsanto is both a divisional and a centralized function. Each division maintains its own research laboratories--Organic 26TH EDITION |agf Q 06837<i9 TOWOLDMONOQ41833 Chemicals Division at St. Louis and Nitro, Phosphate Division at Anniston and Carondelet, Plastics Division at Springfield, and Nlerrimac Division at Everett. In each, the reasearch function is kept separate from other laboratory operations, such as analytical control and testing. The work of the divisional research laboratories is supplemented and augmented by the Central Research Department at Davton, Ohio. It is here that much of the fundamental research of the com pany is carried out. The Central Research laboratories are equipped with the latest t\ pe of research aids, including such equipment as the electron microscope and X-ray, The department carries on special investigations in cooperation v% ith the operating divisions ami also carries out studies of an exploratory nature that may not he related to the company's present products. TECHNICAL SERVICE Each of the Monsanto divisions maintains a technical service staff comprised of qualified personnel who are experienced in the chemical problems and requirements of a wide variety of industries. Industrial users of chemicals are invited to make use of these men. Their func tion is to provide sound technical counsel on problems relating to the use of chemicals. Plant of the Shawtnigan Resins Corporation, a Monsanto affiliate 0683750 TOWOLDMONOQ41834 SOME INDUSTRIES SERVED BY MONSANTO AND PRODUCTS SUPPLIED agricultural U>ra<ives Calcium Phrwi.hare. Oi * '.ilrinni Sulfate I' I'rrir (Jiloride I >Troplio-qihnniM Lacquers Muriatic Arid Nitre Cake N ilric Acid Phosilage Phosphoric Acid Plastics Sodium Sulfate Sulfur Sulfuric Acid " citing Agents (Santomerse) APPLIANCES \brasives Cresol Ferric Chloride (.arquers Lampblack Maleic Anhydride Muriatic Acid Nitric Acid Phosphoric Acid Phthalic Anhydride Plastics Solvents Sulfuric Acid AUTOMOTIVE Abrasives Acetic Acid Alcohol Aluminum Sulfate Amyl Acetate Aroclors (Chlorinated Diphenyl) Battery Acid Benzene Butyl Acetate Butyl Alcohol Caustic Soda Chlorine Cresol Diacetone Alcohol Dibutyl Phthalate Diethyl Phthalate Ethyl Acetate Ferric Chloride Ferrophosphorus Lacquers Muriatic Acid Nitric Acid Phenol Phoph >ric Acid Phlhali Anhvdride Plastics ' Rubber Accelerators Bone Ash Muriatic Acid Phosphoric Acid Salt Cake Sodium Pv rophosphate, Tetra Sulfuric Acid W el ting Agent Rubber Ami-Oxidants Santici?er ') (Santomerse) Sodium Acetate Sodium Phosphates CHEMICAL Sodium Sulfate Sulfur Sulfuric Acid Tanning Chemicals Thinner* Tricress l Phosphate PROCESS Acetic Acid para-Ace tv I- Vminn-Ben- zenesulfonechloride Alcohol Aluminum Sulfate AVIATION Ammonia, Aqua Abrasives Amyl Acetate Alcohol ortho-Anisidine \myl Acetate Butyl Acetate Butyl Acetate Calcium Pyrophosphate Ethyl Acetate Caustic Soda Finishes Chlorine Lacquers meta-Cresol Phosphoric Acid ortho-Cresol Plastics para-Cresol Primers Cresylic Acid Solvents Diacetone Alcohol Sulfuric Acid Dinitrochlorobenzenc Surfacers Ethyl Acetate Thinnen Mersol (Solvent) Methvl Salicylate CARPET and RUGS Mixed Acid Acetic Acid Monochlorobenzene Aluminum Sulfate Glauber's Salt Monsanto Sail Muriatic Acid Lacquert Nitric Acid Latex A< celerators ortho-Xitroaniline Nitre Cake para-Nitroaniline Sodium ftisulfite. ortho-Nitroanisole Anhydrous Nitrocellulose Solution Sodium phosphate, Tri ortho-Nitrochlorobenzene Sodium Pyrophosphate, Tetra Sodium Sulfate, Anhydrous para-Nit rochlorobenzenc para-Phenetidin Phenol Phosphoric Acid Sulfuric Acid Phosphorus Oxychloride Wetting Agent Phosphorus Trichloride (Santomerse) Phthalic Anhydride CERAMICS Abrasives Piperidine Pyridine Salicylic Acid 2 6TH EDITION Page 11 0683751 TOWOLDMONOQ41835 Sale Cake Sodium Muminaie >odium Bisulfite Sodium Pyrophosphate, Tetra Sodium Sulfite Solvents Sulfuric Acid Sulfuryl Chloride Thiourea Trirresv I Phosphate paru.Tolueneuironamide IMru-TolueiKxiilfou. chloride Calcium Pyrophosphate CnsJlu ' Methy I Salicylate Plastics " Phosphoric Acid Saccharin Sodium Benzoate DYESTUFF MANl FACTURE Arefir \rd Muminnm Sulfate ortho- \mmodiphenvl VnilineOd ` Sodium BUulfite Sodium Sulfate Sulfuryl Chloride Thiourea para-Toluencsulfonamidr ]>ara-Ti>hienesulfon chloride para-Toluenesulfonic Acid Wetting and Spreading Agents ( \reskap. Vresket, Vrc'-klene. Santomerse) W el ling \gcnl< COSMETICS AND PERFUMES M.ol.ol Benzoic Acid Benzyl Chloride < .aleium Phosphate, Di Calcium Phosphate, Tri Caustic Soda ortho-\niidine naru- \nisidine Benzotrirldoride Itenzov I ( hloride Benzyl Chloride oritjo-Cfiliroaniline ineta-Chloroaniline para-Chloi oaniline para-Chloio-meta-Cresol orlho-Chlnrophenol ELECTRICAL \nxlors Cable Dope Lacquers Lampblack Nitric Acid Phosphoric Acid Plastics Sulfuric Acid < .oiimarin meia-Cresol Diethyl Phthalate Manicure Lacquer Manicure Lacquer Remover Methyl Salicylate Phosphoric Acid Phlhalic Anhydride para-Chloiophenol engraving Chlorosulfonic Acid ortho-Chloro-para- Toluene Sodium Sulfon ate (Monsanto Salt) ortho-Cresol para-Creso1 Cyclohexylamine Dichloroaniline Acetic Acid Nitric Acid Perchloride of Iron Plastics Sulfuric Acid W Ptting Agent (Santomerse) Potassium Pvrnphosnhate. or t ho-Dirh'orobenzene , Tetra ' Dichlorophenol FLORISTS AND Salicylic Acid Dinitroanihne FRUITGROWERS \uepak Dinitrochlorobenzene Ammonia, Anhydrous W el ling Agent Glauber's Salt ortho-Dirhlorobenzene H Acid DAIRY PRODUCTS Mixed Acid para-Dichlorobenzene Muriatic Acid Ammonia. Anhydrous Monochlorobenzene Sodium Phosphate, Tri Ammonium Phosphate, Monsanto Salt Vuepak Mono Nitre Cake Wetting Agent Coumarin Kthavan ortho-Nitroaniiine para-Nitroflniline (Santomerse) Merclor (Sodium Hvpo* chlorile) ' Santamine Sodium Acid Pyro* phosphate Sodium Phosphate, Di Sodium Phosphate, Tri Sodium Pyrophosphate, Tetra Sulfuric Arid Vanillin DENTAL PRODUCTS Alcohol Benzoic Acid Calcium Phosphate, Di Calcium Phosphate, Tri ortho-Nitroanisole FOOD ortho-Nitrochlorobenzene Ammonium Benzoate meta-N'itrcx hiorobenzene Benzoic Acid L . S. P. para-Nitrochlorobenzene Calcium Phosphates Nitrodiehlotobenzene Calcium Pyrophosphate ortho-Nitrophenol Calcium Sulfate para-Nitropnenol Coumarin Monsanto Oil of Vitriol Dry Ice ortho-Phenttidin Etnavan para-Phenetidin Phenol Ferric Phosphate Methyl Salicylate Phosphoric Acid Muriatic Acid Phosphorus Oxvchloride Phosphoric Acid Phosphorus Trichloride Phosphoric Acid Paste Phthalic Anhvdride Saccharin Monsanto Sodium Acetate Sodium Acid Pyro. Sodium Acid Pyro. phosphate phosphate Sodium Benzoate l .S.P. Page 12 MONSANTO CHBMICAI.S 0683752 TOWOLDMONOQ41836 Sodium Bisulfale Sodturn Phosphate, Di Sodium Phosphate, Mono Sodium Phosphate, Tri Vanillin Monsanto GLASS AND VIT REOUS WARE Abrasives Bone Ash Chlorine Muriatic Acid Plastics Salt Cake Wetting Agent (Santomerse) INSECTICIDES Cresol Dibutyl Pbtbalate ortho Dichlorobenzene nara-Dichlorobenzene Methyl Salicylate Sulfur Trichlorobenzene Wetting Agent (Santomerse) LAUNDRY Chloramine T Chlorine Merclor (Sodium Hypochlorite) Sodium Bisulfate Sodium Bisulfite Sodium phosphate, Tri Sodium pyrophosphate, Tetra Wetting Agent (Santomeree) Sodium Sulfide Sulfuric Acid Wetting and Spreading Agents, (Areskap, Aresket, Aresklene, Santomerse) LUMBER LEATHER AND Lacquers TANNING Permasan Santobrite Aluminum Sulfate Santophen 20 Ammonia, Aqua Belt Cement METALS Caustic ftoda Abrasives para-Chloro-meta-Cresol Ammonia, Aqua para-Chloro-meia-Xylenol Bone Ash ortho*Dicblorobenzene C. P. Acids Dopes Caustic Soda Glauber's Salt Cresylic Acid Lacquers Fernsul (Ferric Sulfate) Lampblack Ferrophosphorus Merclor (Sodium Hibitite Hypochlorite) Inhibited Acids Mertanok (Syntan) Mixed Acid Muriatic Acid Muriatic Acid Permanol Nitric Acid Phenol Phosphoric Acid Salicylic Acid Sodium Phosphate, Di Santotan (Basic Chrome Sodium Phosphate, Tri Sulfatt) Sodium Pyrophosphate, Sodium tyisulfate Tetra Sodium bisulfite. Sulfuric Acid Anhydrous Wetting Agent Sodium phosphate, Di (Santomerse) Sodium Sulfhydrate Zinc Chloride Solutions 0683753 TOWOLDMONOQ41837 Inspecting safety valves on the electrolytic chlorine cells at Monsanto, Illinois. MINING Abrasives Hone Ash C. P. Acids Flotation Agents (Xanthates) Nitre Cake Sodium Sulfide Sodium Sulfite - OIL REFINING Caustic Soda Chlorine Cresols Muriatic Acid Phenol Phosphoric Acid Santolubes Santopoid Santopour Sulfuric Acid PACKAGING Cast Phenolic Resin Cellulose Acetate Cellulose Nitrate Lacquers Polystyrene Santicizer-8 V'uepak PAINT, VARNISH AND LACQUER Amyl Acetate Antioxidants Benzoic Acid Butyl Acetate Cotton Solutions Diacetone Alcohol Dibutyl Phtl-alate Diethyl Phtbalate Dimethyl Phtbalate Ethyl Acetate Lampblack Maleic Anhydride Mertee (Chlorinated' Rubber Base Paint) Monochlorobenzene Paint Anti-Skinning Materials Phenol Phthalic Anhydride Resins Santicizers (Phthalyl Glycollates and other Plasticizers) Santolites (Resins) Santomask (Deodorant) Solvent Alcohol (Mersol) Thinners Tricresyl Phosphate Triphenyl Phosphate PAPER Alcohol Aluminum Sulfate, Com mercial and Iron Free Ammonia, Anhydrous Ammonia, Aqua Benzoic Acid Bone Ash C. P. Acids Chlorine Coumarin Dibutyl Phthalate Ferric Sulfate Ferrisul Lacquers Muriatic Acid Page 14 MONSANTO CHEMICALS 0683754 TOWOLDMONOQ41838 Sail Cake Santicizers Santicizers (Specialty plasticizers) Sulfuric Acid Wetting Agent Santobrite Santolitf (Synthetic (Santomerse) Ssntolites resins) Santosite Thiourea TEXTILES Sodium Aluminate Tricresyl Phosphate Acetic Acid Sodium Bisulfale Triphenyl Phosphate Alcohol Sodium Bisulfite. Vuepak Aluminum Chloride Sodium Hypochlorite Sodium Phosphate, Tri Sodium Sulfide POWER AND POWER PLANTS Ammonium Phosphate, Mono Ammonia Sodium Sulfite Aluminum Sulfate Amyl Acetate Sulfuric Acid Chlorine Butyl Acetate Tricresy I Phosphate Wetting Agents ortho-Dichlorobenzene Ferrisul Calcium Phosphate, Tri Calcium Sulfate PHARMA CEUTICAL Acetanilid L. S. P. Aoetophenelidin L. S. P. Acetyl Salicylic Acid (Aspirin) Benzoic Acid U. S. P. Caffeine U. S. P. Calcium Phosphate, Di Chloral Hydrate V. S. P. Chloramine-T l'. S. P. Dichloramine-T N. F. Glycerophosphates Magnesium Phosphates. Mrlhvl Salicvlate U.S.P. Phenol U. S. P. Phenolphthalein U. S. P. Phosphoric Acid Potassium Ammonium Phosphate Santobrile Santophen Santosite Sodium Alternate Sodium Phosphates Sodium Sulfate PRINTING INKS Aluminum Chloride Aluminum Sulfate Antioxidants Anti-Skinning Agents Aroclors Coumarin Lampblack Methyl Salicylate Nitrate of Iron Phenol Santocel Santomask Sodium Aluminate Potassium Phosphate, RUBBER Mono Accelerators Saccharin U. S. P. Antioxidants Salicylates Caustic Siida Salol C^cline Oil Sodium Benzoate U. S. P. Piperidine Sulfanilamide U. S. P. PLASTICS AND Santobrite Sodium Sulfite SYNTHETIC RESINS Ammonia, Aqua Benzoic Acid, Technical Softeners Sulfur Sulfuric Acid SOAPS AND Caustic Soda Chlorine Cresol Dibnlyl Phthalate Ethyl Acetate Ferric Sulfate Glauber's Salt Lacquers Merclor Mixed Acid Nitrate of Iron Nitre Cake Oil of Vitriol Plasticizers Potassium Pyrophos phate. Tetra Santobrite Santophen 20 Sodium Acetate Sodium Acid Pyro phosphate Sodium Bisulfite Sodium Phosphate, Di Sodium Phosphate, Tri Sodium Pyrophosphate, Tetra Sodium Sulfate Sodium Sulfite Sopet Sulfuric Acid Tricresyl Phosphate Wetting Agent (Santomerse) Cast Phenolic Resin Cellulose Acetate DETERGENTS Antioxidants WATER Cellulose Nitrate C. P. Acids TREATMENT Cresols Calcium Sulfate Aluminum Sulfate Dibutyl Phthalate Caustic S(ida Ammonia, Aqua Diethyl Phthalate Chlorosnllonic Acid Chlorine Dimethyl Phthalate Coumartn Ferrisul (Ferric Sulfate) Maleic Anhydride Cresol Santobrite Monsanto Plastics Phenol Santosite (Reducing Phenol Soda Ash Agent) Phthalic Anhydride Sodium Phosphate, Di Sodium Aluminate Polystyrene Sodium Phosphate, Tri Sodium Hypochlorite Polyvinyl Acetals Sodium Pyrophosphate, Sodium Phosphate, Di Resinox (Phenol* Tetra Sodium Phosphate, Tri Formaldehyde) Sopanox Sodium Sulfate 26TH EDITION Page 15 0683755 TOWOLDMONOQ41839 0683756 TOWOLDMONOQ41840 ACCELERATORS- MONSANTO PRODUCTS ABRASIVES (See Aluminum Oxide Abrasive Grain). ACCELERATORS* RUBBER........... ........................................ ><< iihIinxIii.iI accelerators below for specification* ami properties. K.K. Classifications Rubber Accelerators NOIBN. Available l.iteratures "Monsanto (diemicols for (he Rubber Industry," 12 pages. "Latex Compounding." 36 page*. Rubber Compounding for the Wire Industry," 18 pages. "Santocnre-- Vn Accelerator for Rubber \ ulcanizaiion," 32 pages. *A-10"____________ Specifications: Condensation product of aniline and formaldehyde. It is neither meihvlene dianilide nor formaldehyde aniline, but probably a mixture in which the latter product predominates. White or yellowish tinted powder; 95 per cent through 200 mesh and 99 per cent through 100 mesh; loss on beating less than 5.0 per cent when heated for two hours at 105'C.; m.p., begins to soften at 120CC.: *p. g. 1.17; unrombined reagents, no excess of free aniline and not more than truces of formaldehyde. _____________________________ Specifications: Formaldehyde derivative of a condensation product of aniline and acetaldehyde, of complex chemical composition. Brown resinous powder; m.p. between 75'C. and 85C.; sp. g 1.17. Specifications: Reaction product af butyraldehyde and butylidene aniline. The chemical structure of such products is necessarily complex. Red yellow to orange brown oily liquid, slightly turbid when cold; sp. g. 0.98; flash point 80C.; soluble in benzene, chloroform, acetone and solvent naphtha. Specifications: Light tan powder; constant composition blend of Santocure and HI Sixty. ! 6 T H B n I TIO > Page 17 0683757 TOWOLDMONOQ41841 ACCELERATORS "A-77" Specifications: Condensation product of acetaldehyde and aniline by a special Monsanto process. Such produos, known as aldehyde derivatives of SehifTs |,j>cs, are of complex chemical rmnpo'dijon. Free flowing reddish brown liquid; p. g. I.iil: Ha.*U point 5.VC.: soluble in benzene. chloroform and acetone; partly oliiMe in alcohol and gasoline. \-imr Specifications: Aldehyde derivative of a SrhifTs base made with the use of both hutyraldehyde and ureialdei yde. Dark reddish brown oily liquid; sp. g. MU: flash point 85*C.; soluble ii benzene, chloroform, acetone and solvent naphtha. `BL'TASAX" (Zinc Salt of Dibutyl Dithiocarbamic Acid)____ Specifications: Cream colored powder; sp.g., 1.21: melting point, 106C.; cur at temperatures below I00C. General Information: 0.5% to 1 % on rubber weight used in latex, cements, for dipped goods, adhesives, coatings, etc. DPG (Diphenylguanidine) Specifications: White powder, not darker than the approved color standard: no residue on 100 mesh screen; m. p. not less than 146C.; sp. g. 1.19; strength, 90.0% min. of DPG by acidimetric titration; soluble in alcohol, benzene, chloro form and ether; very slightly soluble in water. "EL SIXTY" (Dibenzothiaeyldimethylthiol urea) Specifications: A light cream colored powder; 99.5% min. through 200 mesh, no coarse particles; m.p. 220C. min.; sp. g. 1.29; very slightly soluble in acetone, alcohol and chloroform; alightly soluble in hot pyridine or orthodichlorbenzene. "ETHASAN" (Zinc Salt of Diethyl Dithiocarbamic Acid) ____ Specifications: White powder; sp.g , 1.5; melting point, 173C. General Information: 0.5% to \% on rubber weight used in latex. Page 18 HONS A NTO CHEMICALS 0683758 TOWOLDMONOQ41842 "Gl'ANTAL" Specifications: Ester formed by reacting two molecules of diphenylguanidine and one molecule of pluhalic acid: contains one-half mole of water of crystallizalion. White powder ranging from blue white to faint gray; 99.5% min. through 200 mesh, no coarse particles; m. p 178C. min.; sp. g. 1.20; soluble in alcohol; insoluble in benzene and gasoline. "METHASAN" (Zinc Salt of Dimethyl Dithiocarbamic Acid) Specifications) White powder; sj.g.. 2.00; melting point, 249C.; cures at temperatures below 100C. General Information) 0.5 to 1% on rubber weight used id latex and cements. PIP-PIP (Piperidine-pentamethylene Dithiocarbamate)_____ V) Specifications) FlufTy, cream colored powder; 98.0% min. through 200 mesh SC and 99.5 per cent through 100 mesh; m.p. over 160C. at time of shipment. s Decomposes slowly in the presence of water and during storage with a corre p* sponding drop in melting point. Sp. g. 1.13; soluble in alcohol and solvents con* taining water. I "R-2" CRYSTALS Specifications) Reaction product of carbon bisulfide with methylenedipiperi* dine. Light brown coarae crystalline solid; sp. g. 1.11; m. p. between 50C. and 60C. "SAXTOCURE"__________ ____________________________________ Specifications) Condensation product of mercaptobenzothiazole with cyclo* hexylamine. Light tan or buff colored powder; 99.5% min. through 200 mesh; m.p. 90C. min.; sp. g. 1.27. Available Literature) 52-page booklet, "Santocure--An Accelerator for Rubber Vulcanization.** "TACKOL" Specifications) Standardized, uniform blend of resins and oils. Viscous brown liquid. Odor is distinctive coumarone*like; sp. g. 1.05; flash point 160C. 26TH EDITION Page 19 0683759 TOWOLDMONOQ41843 ACC F I F.RATORS General Information: Used a* a softener or tack producer in rubber. Available Literature: 42-page booklet: "Monsanto Chemicals for the Rubber Industry." THIOCARBAN1L1DE Specifications: White powder, not darker than the approved color standard; min. through |()0 mesh, no course particles: ni. p. not less than sp. g. 1.32: insoluble in water and many other common *o| vents soluble in alcohol. THILRAD" (Tetramethyl Thiuram Disulfide). Specifications: Sp.g., 1.29: melting point, 116-1 18C.: color, white: odor, none: soluble in carbon bisulfide, benzene a^d chloroform; insoluble in water, dilute caustic and gasoline. "UREKA" Specifications: Constant composition blend of diphenylguanidine and 2, tdinilropbenyl thiobenzolhiazole. Uniform light yellow powder; 99.5% min. through 200 mesh, no coarse particles; m. p. between 117C. and 127C.; sp. g. 1,25; soluble in alcohol and chloroform. `TREKA BLEND B"_________ Specifications: A blend similar to "l reka" with a portion of the "DPG" re placed by "Guantal." Yellow to brownish powder; 99.5% min. through 200 mesh, no coarse particles; tn.p. 130C. min.; sp. g. 1.33. "UREKA C" (Benzothiazylthfobenzoate) Specifications: An acyl-thiazole powder in which (he acidic hydrogen atom of mercaptobenzothiazole has been replaced by a benzoyl group. A pale ivory or yellowish powder; 100 per cent through 30 mesh: m.p. not less than 1159C.; - sp. g. 1.43; soluble in chloroform and benzene; slightly soluble in alcohol. ACETANILID, U.S.P. NHCOCH* 0 Page 20 Mol. Wt. 135.16 Standard Forms: Crystals, powder. (Continued) w CHEMICALS 0683760 TOWOLDMONOQ41844 Specifications! White crystals or powder; ash 0.05% max.; conforms to I'.S.P. tests for carbonizable impurities ami heavy metals; solubility in ethvl alcohol 95%, complete; m.p. LI L0eC. tuia.; no crystals retained on 11 mcah; 3.0% max. ponder retained on 80 mesh. K.K. Classification: Vrt-lanilid. Generul Information: I'hartnai eutical product. ACETIC ACID ............. . ............................................................. CHjCOOH Grades: 56% CjHtOj: sp.g. 1.06?; freezing point --8.0F. 70% CjFIiOj: sp.g. 1.074; freezing point +0.6F. 80% C}HtO}: sp.g. 1.076; freezing point + IT. 1F. 81% CjlljOj: sp.g. 1.075; freezing point +27.3F. Glacial: 09% CjHjOj: sp g. 1.0576; freezing point +58.3F. K.K. Classification! Acetic Acid. General Information! Used in dyeing where a weak acid is required in the dye bath; in the manufacture uf acetate solvents; manufacture of cellulose acetate: and in the formation of oi her acetates, such as aluminum, lead, sodium, and ammonium acetate. Also used in manufacture of fish glue; as an antichlor: coagulation of rubber latex; destrurlion of fungi; disinfectant in gelatine; pickling foodstuffs; giving added detergency and firmness to soap; stabilizing olive oil; protecting seedlings from injury due to root rot and damping ofT; hardening and developing solutions for photographic films. (See table in general data section) ACETONE C. P. Typical Analysis! Water white liquid; non-volatile matter, not more than 0.001 gram when 100 cc. are evaporated and heated to constant weight at 100C. to 110C.; water solubility, miscible with distilled water in ail proportions; drvness, no turbidity when one volume is mixed with 19 volumes of 60B6. gasoline at 20C.; sp. g., 0.791 to 0.793 at 20C./20C.; rcidity, less than 0.002%, calculated as COj.; purity, 99-100% dimethyl ketone; potassium permanganate test, color of added potassium permanganate retained at least two hours when 1 cc. of a 0.1% solution is added to 100 cc. of Acetone; chlorides, none; iron, none; odor, mild--non-residual; flash point, -- 18C. (--0.4F.); wt, per U.S. gal., 6.59 lbs. at 68F. K.K. Classificationi Acetone. General Information! Acetone w faster drying than ethyl acetate and a more active solvent. It is an important constituent of quick-drying water proof ce ments; an active solvent for celluhwe acetate: a good dye solvent; resin solvent used extensively in paint removers and cleaners and for various extraction, processes. 26T H RDITtON Page 21 0683761 ACETOPHENETIDIN, U.S.P NHCOCHj Mol. Wi. 179.11 Standard Forms: Crystals: powder. Spccifications:White crystals or crystalline powder; Solubility in ethvl alcohol ''i'o (1:15), complete: m.p. 135.0C. min.; ash .05% max. No crystals retained <>n 11 mesh screen; 5% powder retained on 100 mesb. K.R. Classfication: Chemicals NOIIiN. General Information: Phariuaceutical product. paro-ACETYL-AMINO-BENZENESULFONECHLOR IDE_____ NHCOCH, 0 so,a Mol. Wt. 233.59 Standard Forms Crystals. Characteristics: Light tan to browi-ish powder or fine crystals; assay, 97.5% K.R. Classification: Chemicals NOI8N. General Informations Used as an intermediate in the manufacture of sulfa drugs. ACETYL SALICYLIC ACID, U.S.P. (Also known as Aspirin) COOH 0OCOCHi Mol. Wt. 180.06 Standard Formas Crystals, 20 mesh Crystals, 40 mesh Powder, 80 mesh Specifications s White crystals or poyder; assay 99.5% min.; solubility in ethyl alcohol 95% (1:5), complete; solubility in 10% NajCOj(l:20), complete; ash, 0.05% max.; conforms to U.S.P. test for heavy metals, carbooizable impurities, resinous products, chloride, sulfate. apd free salicylic acid. (Continued) Page 22 MONSANTO CHEMICALS 0683762 TOWOLDMONOQ41846 Retained on-- 20 mesh screen 80 mesh screen 10 mesh screen IS mesh screen 50 mesh screen 60 mesh screen 80 mesh screen Thru-- 100 mesh screen 140 mesh screen 20-mesh K)-mesh Trace max. 5.0% mtn. 10.0% min. 45.0% min. 60.0% max. 70.0% min. 85.0% max. Trace max. 10.0% min. 20.0% max. 20.0% max. 15.0% min. 60.0% max. 10.0% max. 25.0% max. 80-mesh none 2.0% max. R.R. Classification! Acetyl Salicylic Acid. General Information! Pharmaceutical product. ACETYL SALICYLIC ACID, Starch Granulations Standard Forms: 10%, 12*50 mesh, white 16%, 12*50 mesh, white 20%, 12*50 mesh, white 10%, 12*50 mesh, pink 10%, 20 mesh, pink 10%, 12*50 mesh, green 10%, 20 mesh, green Specifications! (Made with Acetyl Salicylic Acid U.S.P.) White, pink or green granules. Assay: starch granulation 10%, 90.0% min. 91.0% max.; starch granulation 16%, 84.0% min. 85.0% max.; starch granulation 20%, 80.0% min. 81.0% max. Free salicylic acid conforms to U.S.P. test on Acetyl Salicylic \oid. UF.SH: Retained on-- 12 mesh screen 14 mesh screen 16 raesh screen 20 mesh screen Thru-- 40 mesh screen tH EDITION 12-50 mesh Trace, max. 5.0% min. 15.0% max. 20.0% min. H5.0% max. 60.0% min. 5.0% max. k0.0% max. (Continued) 20-mesh Trace, max 0683763 TOWOLDMONOQ41847 It.It. Classification: Acetyl Salicy I ic Acid. General Information: Pharmaceutical product. ACID CALCIIM PHOSPHATE (See CaMum Phosphate. Mono). VIRCRAFT FINISHES _ Commercial Finishes: \ircraft finishes include proiertive and decorative coatings for every part of the aircraft structure, such as fabric dopes (clear and colors) for Mings, control snr. faces and fusilage; primers, surfacers and lacquers for aluminum and dural sheet; llume-proof dopes for interiors, thinners, cleaning solvents. Properties of the com mercial finishes in application conform to the best modern plant practice, and properties in service meet the severe requirements of resistance to stress, sea water corrosion, weather, gas and oil. .Monsanto finishes have for years been accepted as standard by manufacturers and airlines. CMDK NO. TYPE OF PRODUCT For Fabric--Dopes 1,-3901 L-1031 L-2194 L-760 L-3193 L-3195 I.-2391 Clear Nitrate Dope (high solids) Clear Nitrate Dope (medium solids) Cleur Nitrate Dope (comm, grade) Fully Pigmented Dopes--all colors; non-bleeding reds: matt, resist ance to fading and chalking. Interior Fire-Resistant Clear Dope Interior Fire-Resistant Pigmented Dopes--all colors. Finish Reclaimer (Rejuvent tor) for Nitrate Dope For Metal--Primers, Surfacers, and f.uc^uers R-4017 Yellow 728 Zinc Chromate--Fa*t Drying. R-4063 Gray 578 Synthetic Primer Surfaces--Slow Drying. R-3552 Gray 423 Lacquer and Dope Surfacer. L-2939 Clear Aluminum Vehicle. R-3785 Fully Pigmented Lacquers--all colors (except light shades); non. bleeding reds; max. resistance to fading. I,-1518 L-1087 L-2680 L-3196 L-1034 Page 24 Thinners (Reducers)--AU Types Standard lacquer and dope thinner. Retarder (anti-blush) Brush wash for general cleaning. For fire-resistant (acetate). Wax-free remover (dope and lacquer). (Continued) MONSANTO CHEMICALS 068376A TOWOLDMONOQ41848 I . S. Irmy and Navy Specification Finishes. ........... tlage finishes for ......that aircraft were added m the Monsanto line earh in the Defense Program. These finishes are in addition to the original L. S. Arniv and l. $. Navy specification materials of which Monsanto has long been an approved supplier. Finishes under the new combined Ar. / and Navy specifica tions (VN-TT) are now available. \\.| |.|,.<,>6 w.rr-i .',i \ \ -TT-D-oo I I I Ill's M |K' \ Mvtal Surfaces Zinc Chromate Primer. (/loss Lanpicr Color*. (dear Aluminum Uron/.e \ chicle. Army < .amniilliigc Colored Lacquers. Navy Camoiillage (adored Lacquers. Fabric Surfaces AN-TT-D-511 \ N TT-I)..Y>6 \N-TT-D-554 I 1106 M -m (.tear Dope. Semi-Pigmented Colored Dopes. Fnlly-I'igmecited Colored Dopes. Army Camnullege Colored Dopes. Navy Camouflifge Colored Dopes. Thinners AN-TT-T-256 For use with above lacquers. ANTT-T-2S8 Blush Retarder for above lacquers. ILK. Classification: Lacquer. ALCOHOL (See Ethyl Alcohol). ALKYL PHOSPHORIC ACIDS Properties: Amvl Phosphoric Acid (from Pentasol): fluorescent reddish amber liquid: sp.g., 1.33 at 25e'C.; alky l acid content, approx. 99%.* n-Butyl Phosphoric Acidt fluorescent reddish amber liquid; sp.g., 1.24 at 253C.: alkyl acid content, approx. 99%.* Ethyl Phosphoric Acid: pale straw colored liquid; sp.g., 1.33 at 25C.; alkyl acid content, appvox. 97%.* Methyl Phosphoric Acid: pale straw colored liquid; sp.g., 1.439 at 259C.; alkyl acid content, approx. 97%.* n-Propyl Phosphoric Acid: reddish amber liquid; sp.g., 1,30 at 259C.s alkyl acid content, approx. 97%.* * Balance of assay is ortho-phospboric acid and unconverted alcohoL R.K. Classification: Phosphoric Acid. (Continued) 26TH EDITION Page 23 0683765 TOWOLDMONOQ41849 General Information: The Alky! Phosphoric Acid are mobile liquids which can be neutralized with alkalis and amines with resultant water-soluble salts. The methyl, ethvl and propyl phosphoric acids are water-soluble, but the butyl and amyl acids are not. The salts of all are water-soluble. The methyl and ctlnl phosphoric acids and their salts a^e very hygroscopic (amine, sodium and poijssiiuii sails) whereas the propyl, bi lyl and arnyl acids are not hygroscopic .nid their sails only slightly so. Alkyl I'lmsphorit- Acids are used in textile and paper processing compounds: .1- aiaK -is in urea re>in formation: as polymerizing agents for resins and oils. ALUM (See Aluminum Sulfate). ALUMINUM CHLORIDE AljCl Mol. Wi. 266.7 Standard Forms: Liquid. 32a B., 56% ALCU+12 H,0 approx.; crystals,* 97% Al.Clj +12H:0 approx. Typical Analysis: Neutral salt, low in nron content. Solutions have an acid re action but contain no free acid. Typical analysis as follows: Crvstal Liquid ALCI* 12 H-O 97.2% 30.3% ALOi 20.5 10.6 Cl 42.7 22.1 Fe .003-.005 .005 K.R. Classifications! Aluminum Chloride Dry or Aluminum Chloride Liquid. General Information: Used in carbonizing fine wool such as piece goods, raw slock or shoddy, resulting in an exceptionally white, lofty wool. Also in car bonizing colored goods where it has vety little stripping action. Used in soap manufacture for treatment of glycerin lyes where chloride of alumina is more desirable than sulphate. (See table in gentral data section) Crystals: Resale product. ALUMINUM OXIDE ABRASIVE GRAIN (Also know n as fused aluminum oxide; artificial corundum.) Specifications: Fused aluminum oxide containing 95-99% AljOj; hardness 9.6, Moh's scale. K.R. Classifications: Abrasive flour or grain. General Information: Coarse to flour grades are available for grinding wheels, polishing, refractory purposes, and for ariti-slip or tread use. Page 26 Monsanto chemicals 0663766 ALUMINUM SULFATE, COMMERCIAL A1,(S04),. 14.5 HjO Standard Form: Fine to lump. Typical Analysis: AljOj, 17.2%; FeO, 0.35%; FejOj, 0.01%. K.R. Classification: Aluminum Sulfate. General Information: Used in paper sizing and water treatment. Monsanto also provides a slab form (6'x6'*18') for stork solutions; this form contains 15.5 16.0% AljOj. (See faWe in general data section) ALUMINUM SULFATE, IRON FREE. Alj<S04),. 14.5 HjO Standard Form: Fine to lump. Typical Analysiai AljOj, 17.2%; FejOj, 0.01%. R.R. Classification: Aluminum Sulfate. General Information! Used in sizing fine papers; manufacture of satin white and dry colors; tanning white leathers; dyeing operations. ort/io-AMINODIPHENYL, TECHNICAL (Also known as 2<aminobipbenyl.) NH, Mol. Wt. 169.10 Standard Foma: Fused solid. ' Specifications: Purplish crystalline mass; crystallizing point 47.0C. min.; assay 94.5% min. Distillation range: first drop, 29S.0eC. min.; 95% (1-96 ml), 8.0C. max.; dry point, 310.0C. mu. R.K. Classification! Dye Intermediate. General Information: Used as in intermediate in dyestuff synthesis; in the production of resins; in the production of varnishes; in the synthesis of rubber products; as a solvent. CAUTION: This product is toxic. Avoid breathing its vapors and avoid contact with the skin, 26TH EDITION Page 27 0683767 TOWOLDMONOQ41851 para-AMINODIPHENYL, TECHNICAL (Alto known as 4-aminnbipbenyl.) O-OTM Mol. Wt. 169.10 Standard Forms Fused solid. Specifications: Yellowish brown crystalline mass; crystallizing point 50.5*C. min. Distillation range: First drop, 325.0C. min.; 95% (1 -96 ml), 8.0C. max.; dry point, 340C. max. K.K. Classifications Dye Intermediate. General Informations Used as an intermediate in dyestuff synthesis; in the production of resins; in the production of varnishes; as a solvent. CAUTION: This product it toxic. Avoid breathing its vapors and avoid contact with the skin. 2-AMINOTHIAZOLE. Mol. Wt. 100.14 Standard Forms Crystals Characteristics! Light brown crystals. R.R. Classificationt Chemicals NOIBN. General Informations Used as an intermediate in organic synthesis. AMMONIA, ANHYDROUS _ Properties! At normal temperatures and pressures Ammonia Anhydrous is a colorless gas, 0.597 times as heavy as air. It is readily condensed by the ap plication of pressure below 268F. to a colorless liquid weighing 5.33 lbs. per gal.* and having a boiling point of -- 28F. R.R. Classifications Anhydrous Ammonia. General Information t Ammonia Anhydrous is used in refrigeration; aa a con densing agent in the formation of pbeoolformaldebyde resins; in water treatment in connection with chlorine; partial neutralisation of phosphate fertiliser; in vulcanization of rubber; nitriding of steel; as a neutralizing agent after carbon izing; neutralizing excess carbon dioxide in water supplies; neutralizing and deodorizing rubber goods which have been cured with sulfur chloride; neutral izing petroleum stocks before crackling; as a relatively inexpensive source of hydrogen or nitrogen; and as a solvent. (See table in general data section) Available Literatures Leaflet: "Monsanto Ammonia for Refrigeration." Page 28 Monsanto chemicals 0683766 TOWOLDMONOQ41852 AMMONIA, AQL'A NHiOH Mol. Wt. 3S.0S Standard Forms: Commercial Aqua Ammonia 16, 18% 20% 26 BA Properties: Pungent, water white liquid; wt. per gal. 7.48 lbs. (26s). K.R. Classification! Ammonia Aqoa. General Information t Uses--1. Partial neutralization of phosphate fertilizers. 2. General household cleaning purposes. 3. As a condensing agent in the forma* tion of phenol-formaldehyde resins. 4. As an antichlor. 5. After carbonizing, as a neutralizing agent. 6. Neutralization of excess carbon dioxide in water supplies. 7. Neutralizing and deodorizing rubber goods which have been cured with sulphur chloride. 8. Neutralizing goods wl>ich have been dyed with aniline black. 9. Pre serving rubber latex. 10. Neutralizing oil before cracking. 11. Silk degumming. 12. Manufacture of cuprammoniqm silk. 13. As a solvent. 14. As a debarring agent for bides. 15. For reeling silk* 16. As a penetrant in wetting back crusted tanned leather. 17. As a penetrant for driving in fat liquor in leather making. (See table in general data faction) AMMONIUM BENZOATE Mol. Wt. 139.1S Standard Form i Powder. Specificationsi Fine white crystalline powder; assay 98.0% min.; solution in water (1:10) clear. R.R. Classification! Chemicals NOIBN. General Information! Used as *> preservative. AMMONIUM ETHYL PHOSPHATE (Mixture of mono* and diethyl ammonium phosphates). Standard Formi 75% solution is water. Properties! Water-white to yellow-tinged liquid of ammoniacal odor; sp. g. 1.23 at 25'C.; wt. per gal. 10.37 lbs.; pH 75% sol.; 7.0 - 7.2; viscosity at 25C., 60 centipoises. Chemical constitution: 67% mono ethyl ammonium phoapbate; (Continued) 26TB EDITION Page 29 0683769 TOWOLDMONOQ41853 53% di ethyl ammonium phosphate. In thin film is liquid at relative humidities above 40%; not stable to heat; when subjected to elevated temperatures for any length of time as a solution or while on any article, will liberate ammonia with a reduction in pH; at temperatures below ISC. crystals will form in the solution and will dissolve with a rise in temperature or on dilution. it.lt. Classificationi Ammonium Phosphate. General Informations Used as flame proofing agent for paper, textiles, wood a ml other combustible materials. AMMONIUM HYDROXIDE C, P. NHOH Mol. Wt. 35.06 specifications! Colorless liquid, free from suspended matter; strength (N'Hj) 28.0% min.; nonvolatile matter 0.005% max.; carbon dioxide (CO}) 0.'>2% max.; total sulphur (as SO,) 0.0003% max.; chloride (Cl) 0.00005% max.; pyri. dine, to pass A.C.S. test; substances reducing (KMnOt), to pass A.C-S. test; iron 0.0001% max.; heavy metals (as l<ad) 0.0005%. R.R. Classification! Chemicals, Ammonia. General Information! Laboratory reagent. AMMONIUM PHOSPHATE, Dl (Also known as diammonium hydrogen phosphate, secondary ammonium phos phate, and ammonium phosphate di-basic.) (NH^HPO, Mol. Wt. 132.068 Gradeai Food (meets all U. S. Pure Food Law requirements); special grades supplied on request. Properties! White crystalline material, stable in air and very soluble in water; pH value of 1% solution, 7.75. At temperatures above 70C. aqueous solutions lose ammonis readily. Dissociation Pressure; According to Britgke and Dumajew (Gtnelin't Htndbuch der anorganische Chemie, Ammoniak, p.423) and Warren (JACS 49, 1904,1927): Temp. C. 98 111 125 135 147 pNHjinmm. Hg, 3.2 10.7 26.0 55.2 123.4 R.R. Classification! Phosphate of Ammonia. General Information! Used as a fire retardant in fire-proofing and as s yeast food by yeast producers and breweries. Page 30 MONSANTO CHEMICALS 0683770 TOWOLDMONOQ41854 5 oh/hHty of Diammtniym Phot4*4h inWgttr 7= 15 iH - ni l .<1 p/VrfMittvr $ of O'ommot M mm PAotpA9H u s' / < Q_2 sl > 3 * 't I 41 4 3 H- 43 l \, s s s' -7 7f Ptntnt OAP`(HHtiKHPQt 100 90 tO 70 60 SO 40 SO 10 !0 0 Amii* MAP'NHiUPQ, AMMONIUM PHOSPHATE, MONO (Also known as ammonium aciti phosphate, primary ammonium phosphate, ammonium dihydrogen phosphate, ammonium phosphate mono-basic, am monium biphosphate). NH4HjP04 Mol. Wt. 115.04 Cradeai Food grade meets all U.S. Pure Food Law requirements. Special grades will be supplied on request. Properties! A white crystalline material, stable in air and soluble in hot and cold water; pH of 1% solution, 4 7. R.R. Classification! Phosphate of Ammonia. General Information! Used as a retardant in fireproofing and paper special ties, for special medicinal purposes, in the production of woven belting, and as a yeast food. AMMONIUM SALICYLATE N.F. (See Salicylates). AMYL ACETATE_______ _____________________________________ Typical Analysis! Water white liquid; odor, no residual; sp. g. 0.865 0.870 at 15.5C.; shipping wt. per gal., 7.?0 lbs.; acidity, less than 0.01% as free acetic acid; dryness, mixes with petroleum benzine in all proportions without turbidity. Boiling range: below 110C., none above 130C., less than 50%; above 150C., none. Ester content, 85-90%. (Continued) 16TH EDITION Page 31 0683771 TOWOLDMONOQ41855 R.R. Classification: Amyl Acetate General Information! Used as a idtrocellulose solvent. It is less active than ethyl or butyl acetate and more resistant to moisture. Blends of all three with appropriate diluents such as alcohols (ethyl, but)!, and amyl) yield thinners and solvent mixtures of excellent cutting power, moisture resistance, good Bow ar.d leveling, and compatability with various resins and oils. Used in the artificial leather industry and in formulating lacquer finishes for wood, metals, textiles, and paper. A!\n L PHOSPHORIC ACID (See Alkyl Phosphoric Acids). ANILINE OIL__________ ( Man known as aminobenzene). NH* Mol. Wt. 93.13 Specifications) Slightly yellowish liquid; purity, 99.5% min.; distillation range, 95% within 0.5C.; distillation limits, 182.0 to 185.0C. (dry point); crystallizing point, --6.2C. min.; moisture, 0.10% max.; solution in HCI, complete; nitro benzene, none. R.lt. Classification) Aniline. "Poison" label required. General Information: A basic intermediate in the dyestuff industry. It also finds application in the production of rubber accelerators, as a constituent of resina and in the manufacture of explosives. CAUTION: This product is toxic. Avoid breathing Us vapors. Avoid contact wUh the akin. ortho-ANISIDINE__________ ___________________________________ (Also known as ortho*metboxyantliae, ortho-amtnoanisole, and l-amino-2-me- ihnxvbenzene.) OCH, Mot. Wt. 123.15 Standard Formt Liquid Specifications! Reddish brown to amber liquid; crystallizing point 5.3C. min. Distillation range: first drop 223.0aC. min.; 95%, 1.2C. max.; dry point, 226.0C. max. Solution in HCI, clear. R.R. Classification! Dye Intermediate. General Information i Used aa a component of azo dyes and in the manufacture (Continued) Page 32 Monsanto chemicals 0663772 TOWOLDMONOQ41856 of dyestuff intermediates. CAUTION: This product is toxic. Avoid breathing its vapors and avoid contact uith the skin. para-ANISIDINE----------------------------------------------------------------------(Also known as pora-metboxyanilioe, pora-aminoanisole, and 1-amino-4.meth- oiy benzene.) OCH, Mol. Wt. 123.15 MI. Standard Form: Fused solid Specifications: Fused, crystalline mass; crystallizing point 5?.2C. min. Distilla tion range: first drop 240.0C. min.; 95% 2.0C. max.: dry point 243.09C. max. Solution in HCI clear, darkens on ageing. K.R. Classification: Dye Intermediate. General Information: Used as a component of various azo dyestuffs and as an intermediate in chemical synthesis. CAUTION: This product is toxic. Avoid breathing its vapors. Avoid contact uith the skin. ANTI-OXIDANTS, OIL (S<-e Santolube). i-- ANTIOXIDANTS, RUBBER See individual antioxidants below for specifications. R.R. Classification: Chemicals MOIBN. Available Literature: "Monsanto Chemicals for the Rubber Industry," 42 pages. "Latex Compounding," 36 pages. "Rubber Compounding for the Wire Industry," 48 pages. "FLECTOL H" Specifications: Condensation product of acetone and aniline. Light colored powder: 99.5% min. through 200 mesh, no coarse particles: m. p. 120C. min.; sp. g. 1.08; antioxidant value equal to that of the accepted standard in vulcan ized rubber, both in oxygen bomb and standard flexing tests; solubility approx. 10% in benzene, alcohol and gasoline: insoluble in water. "FLECTOL WHITE"____ Specifications: Light colored powder, not darker than the approved color (Continued) 26TH edition Page 33 ANTIO XIDANTS 0663773 TOWOLDMONOQ41857 standard; 99.5% min. through 200 ttrsh, no coarse particles; m. p. 145C. nun.-, sp. g. 1.25; antioxidant value equ I io that of the accepted standard in ultra violet light tests; soluble in alcohoi. very slightly soluble in water and benzene, insoluble in gasoline. "OXYNONE" (2, 4-Diamino Diphenylamine) Specifications: Brown crystalline powder; 99.5 per cent through 100 mesh and 95 per cent throush 200 mesh, no coarte particles; m. p. not less than 123C.; sp. g. 1.25; soluble in alcohol, chloroform and benzol; very slightly soluble in cold water and gasoline. ANTIO XIDANTS "SANTOFLEX B" Specifications: Reaction product of acetone and para-aminodipbenyl. Waxy, dark gray, lumpy solid; crystallizing point about 80C.; sp. g. 1.045. SANTOFLEX BX" Specifications! Constant composition blend of Santoflex B and dipbenyl-para. phenylene diamine. Waxy, dark gray, lumpy solid; sp. g. 1.11. "SANTOVAR A". Specifications: Alkylated polybydroxy phenol. Nearly white crystalline powder, no darker than the accepted standard; m. p. not less than 165C.; sp. g. 1.049; completely soluble in twice its weight of acetone. General Information! Used as a varnish snti>skinning agent; as an antioxidant in oils, paints, and rubber. ANTISEPTICS AND GERMICIDES Chloramine-T U.S.P. (See under C). para~Chloro-meto>Cre*ol (See under C). para-Chloro-meta-Xylenol (See under C). Dichloramine-7 N.F. (See under D). Phenol U.S.P. (See under P). "Santamine" (See under S). "Santophen" (See under S). ARESKAP (Monobutyl Phenylphenol Sodium Monosulfonate) Standard Format Liquid and dry powder. (Continued) Page34 Monsanto chbmicals 0683774 TOWOLDMONOQ41858 K.R. Classification! Washing Compound NOIBN General Information: Wetting, penetrating and spreading agent; used as spreading agent in insecticidal compositions, in embalming fluids and in metal pickling. AHESKET (Monobutyl Diphenyl Sodium Monosulfonate)___ Standard Forms: l.icpiid and dry powder. It.It. Classification: Washing Compound NOIBN. General Information: Wetting, penetrating and spreading ageot. AKESKLENE (Dibutyl Phenylphenol Sodium Disulfonate)__ Standard Forms: Crystals and g>auboids. Typical Analysis: 43% NajSO* available. Dry AreBklene-400: Tan hygroscopic powder, slightly aromatic; sulfates, trace; chlorides, trace; m. p. about 1600C.; pH, approx. 7.5 for 1% solution of dry material at 25C.; soluble (10 parts to 90 parts solvent) in alcohol, acetone, dibutyl tartrate, ethylene glycol, ethyl acetate and butyl cellosolve. Aresklene-375: Light brown paste, slightly aromatic; sulfates, trace; chlorides, (Continued) A laboratory In the new rubber chemicals research building at Nitro, W. Va, 0683775 TOWOLDMONOQ41859 trace; m. p., decomposes at about 175 C.; not soluble in solvents which are immiscible will) water. R.H. Classification: Washing Compound, NOIBX. (General Information: Wetting, penetrating and spreading agent used in kicrhoiling, scouring and dying textiles, in industrial cleaners, in deodorant preparations, in insecticidal formulations, in metal cleaning and as a stabilizer .md welting agent in latex used to treat tord or other fabrics. "AROCLORS" Specifications: The Aroclors are chlorinated hydrocarbons which varv from water-white mobile liquids and pale yellow viscous oils to light amber resins and opaque crystalline solids. Non-flammability: The viscous Aroclor oils and resins do not support combustion when heated alone even at their boiling points-- temperatures above 360C. Most of the Aroclors flux readily with resinous and pitch-like materials to give a product ha\ ing a decreased fire hazard. Electrical properties: The Aroclors have excellent electrical characteristics, high dielectric strength and resistivity, low power factor. Certain of the liquid Aroclors have a high dielectric constant as compared with that of mineral oils. Solubility: The Aroclor oils and resins are easily soluble in most of the common organic solvents and drying oils. The hard crystalline materials are in general less soluble than the oils of resins. All Aroclors are insoluble in water. Adhesiveness: The more viscous Aroclor and Aroclor resins have excellent adhesive properties. Thermoplasticitv: The Aroclors are thermoplastic, and apparently undergo no further condensation or hardening upon repeated melting and cooling. Non-drying properties: The Aroclors are non-drying, and when they are exposed to the air no noticeable oxidation or hardening takes place. Vaporisation loss: The clear resins have rather low vaporization losses. At 65.8`C. (150F.) these losges are less than 0.04 g. per square inch of surface per month. Odor and taste: The Aroclor viscous oils and resins are almost without odor and taste at ordinary temper atures. Refractive indices: The refractne indices of these materials are above 1.6125. Stability: The Aroclors in general are stable on long heating at 150C. and are not affected by boiling with sodium hydroxide solution. Tbe light oils can be distilled at atmospheric pressure without appreciable decomposition and the viscous oils and resins distill readily under vacuum. Corrosiveness: The Aroclors have practically no corrosive action when applied to metallic surfaces. General Information: Uses: Lacquer, paint and varnish: Aroclors impart resistance to moisture, gas, acids, alkalies, and ultra violet light and improve electrical insulating properties and durability. They function as both plasticizers and resins in nitrocellulose and ethyl cellulose lacquers. Sealing Waxes: Where a moisture proof, non-flammable wax or one with good electrical insulating properties is desired. Adhesives: Aroclors in adhesive application have the desirable qualities of being non-crystallitie, insoluble in water, thermoplastic, light in color, practically odorless, non-drying, and soluble in most organic sol vents. They provide excellent adhesion even to lacquered or varnished surfaces. Impregnation: Aroclors are used in impregnation of materials and articles to give them resistance to moisture, flamet alkalies and acids, and to improve electrical insulating properties. Corresponding to each clear Aroclor there is also a black Aroclor of similar properties. Flameproo/ing; Aroclors are used in combination with many other materials to reduce tbe flammability of those materials. Rubber and rubber substitutes: The liquid Aroclors have a solvent (Continued) Page 36 Monsanto chemicals 0683776 TOWOLDMONOQ41860 action on rubber and act as plasticizer. The solid Aroclors impart flame resist ance. Plastics: The Aroclors are compatible with nitrocellulose, ethyl cellulose and vinyl resins. In ground powder form is an excellent organic pigment. Available Literature: 20-page Utoklet "The Aroclors--Physical Pro|>orties and Suggested Applications." ASPIRIN (See Acetyl Salicylic Acid). BATTERY ACID (Electrolyte) Typical Analysis: Practically colorless liquid; HjSOt, 93.2% min.; iron, 0.005% max.; nitrogen compounds (as HNOj), 0.001% max; sp. g. 1.210-1.835. (Acids of tower strengths should be calculated in proportion to above specification on H}SO| content.) R.R. Classification: Sulfuric Aci<>. Ceneral Information: Electrolyte is sulfuric acid, especially adapted to the needs of the storage battery trade Various strengths can be furnished to meet the needs of the individual purchaser. BELT CEMENT Ceneral Information: Nitrocellulose base cements for cementing ply belting and taps. Characterized by strength, flexibility, rapid drying properties, and resistance to water. Specially adapted to power belting. More flexible types are ofTered for wool combing aprons and paper machine dryer felts. R.R. Classification! Lacquers. BENZENE SULFONAMIDE, TECHNICAL O Mol. Wt. 157.18 O Characteristics: A brownish crystalline solid, crystallizing at 150 I52C. R.K. Classificationt Lacquer Solvents, NOIBN. Ceneral Informations This product is the techincal form of Santicizer 129. It may be used in organic syothes<s, production of dyestuffs or as a plasticizer in resinous compositions where col is not a factor; is analogous to Monsanto's para-Toluencsulionamide and can probably be used as a substitute in most applications. 26TH EDITION Page 37 066377? TOWOLDMONOQ41861 BENZENE SULFONIC ACID, TECHNICAL Mol. Wt. 158.17 SOjH Characteristics! Greenish black viscous liquid or crystalline mass; crystallizing point, 25.8C. (approx.); HjSO,, 24.0 25.0%; benzene sulfonic acid, 70.6 71.0%; ap.g. 25a/I5.5C., 1.45 (approx.). K.R. Ossification: Chemicals, NOIBN. General Information! Used as an intermediate in organic synthesis and as a catalyst in certain condensation reactions. BENZOATE OF SODA (See Sodium Benzoate). BENZOIC ACID Mol.Wt. 122.12 Grades! U.S.P. and Technical. Specifications of U.S.P. Grades White crystalline needles or fine powder; assay 99.S min. (dry basis); m.p. 122.50C. min.; solution in alcohol (1:2.5) and in 10% sodium carbonate (1:6), clear and colorless; meets U.S.P. test for carboaisable impurities; 5% max. powder retained on 100 mesh screen. Specifications of Technical Grade t White to yellowish white granules or powder; assay, 99.25% min.; odor, characteristic; solution in 10% NajCOj (1:6), slightly turbid or opalescent and practically colorless; approx. 10*20% retained on 20 mesh; approx. 100% retained on 100 mesh. R.R. Classification! Of U.S.P. Grade--Food Preserving Compound; of Tech* nical Grade--Chemicals, NOIBN. General Information! U.S.P. Grade used in medicinal preparation# and as a preservative in foodstuff#. Technical Grade used in the manufacture of ben* zoatea and benzoyl compound#; aa an intermediate in the manufacture of dyea; as a mordant in calico printing; as a n-odifying agent in alkyd resins; as a color stabiliser in baking varnisbes; as a dispersing agent in the grinding of pigments. Page 38 MONSANTO CHEMICALS 0683778 TOWOLDMONOQ41862 BENZOTRICHLORIDE _ CCI. 0 Mol. Wt. 195.46 Standard Form: Liquid. Specifications: Colorless to light green or yellow liquid: crystallising point 0.0C. min. Distillation range: fkst drop, 218.0C. min.; 95% (1-96 ml), 2.0C. max.: dry point, 223.0C. max. K.R. Classification: Chemicals N'OIBN. General Information: Used as an intermediate in dyestuff synthesis. (.4 t T10.\: Irritating to the skin, f apars are highly irritating to the eves, .-livid breathing vapor*. Avoid contact with the skin. BENZYL CHLORIDE CHjCl Mol. Wt. 126.59 Standard Forms: Liqguid, anhydt rous; liquid with 10% NajCOj solution. Specifications! For anhydrous liquid and material recovered from 10% solution below: Colorless to light green to brown liquid; sp. g. at 15.5/15.5'C.. I. 104 > 1.108. Distillation raoge: first drop, 177.59C. min.; 95% (1-96), 3.0C. max.; dry point, 185.0C. max. Liquid with 10% NajCOj: NajCO# in water solution, 9.0 11.0%. Note: 23 lbs. of 10% NajCOj solution are add'd to 450 lbs. of benzyl chloride contained in 55 gal. black iron drums. The wet material is a milky white emulsion, from which water may separate into a definite layer at either the bottom or top de> pending on the temperature and the concentration of NajCOj. The concentration of VajCOj s\owly decreases on standing. II. II. Classification: Chemicals ISOIBN. General Information: Used in the production of the following: Dyestuffs; perfume bases such as benzyl alcohol, acetates, benzoate and phenyl ethyl at* cohol; plasticizers; resins; wetting agents; rubber accelerators; gasoline gum inhibitors; benzyl cellulose; various pharmaceuticals. CAUTION: This product is irritating to the skin. Sapors are highly irritating to the eyes. Avoid contact with the skin. Avoid breathing vapors. BISULFATE OF SODA (See Nitre Cake) BISULFITE OF SODA (Set Sodium Bisulfite). 26TH EDITION Page 39 0683779 TOWOLDMONOQ41863 BLEACH (See Merrlor). BONE ASH General Informations Mold wash grade for coating molds used in casting copj>er wire bars, ingots and slabs. A suptrior mold coating far certain. Steel casting operations. This product is also ustd in producing opal and other translucent glasses. it.it. < las-ificulions Hone Ash. BONE BLACK Grades: Twelve grades are available which vary in fineness, top tone, undertone, tinting strength, and color in oil. Specifications: In general, bone blacks when compared with lampblack or carbon black have greater hardness and lower oil absorption. They mix easily with water, shellacs and lacquer, and are relativ able to sunlight. Specifics* lions for the various standard grades are as foil Grade No. 45 % Moisture 4.10 % PA 33.50 150 4.10 33.50 250 4.94 33.05 350 4.07 30. IS 439 4.78 32.05 439 Spec. 4.78 31.73 450 & 450-CT. 4.86 34.50 650 4.28 34.00 841 4.02 32.95 850 3.82 34.60 Ceco 4.95 32.30 *Lbs. oil per 100 lbs. pigment. **No. 450, 99.90; No. 450-CT., 99.67 % Cari;".: 9.20 9.20 9.75 13.84 14.57 15.12 9.30 8.75 8.90 8.37 9.70 Oil Absorption* 46.2 46.2 43.9 43.9 50.2 50.5 42.7 43.9 46.2 43.9 46.3 % thru 325 Screen 99.89 99.90 99.40 99.85 99.95 99.90 ** 99.73 99.90 99.90 99.95 R.R. Classification: Animal Charcot l. Other Than Spent. General Information: Chief use is as a pigment in leather finishes, artificial leather, paints, lacquers, japans, inks and wall paper. Bone black has good jetness and is easy to wet, whereas lampblack wets only with difficulty and has much less jetness. BRONZING LIQUIDS General Information: Clear lacque: base mediums for aluminum and bronze powders. Several types offered for metal, wood, fabric, and paper. Applied by spray or machine coating. Many are inhibited to retard gelling. R.R. Classifications Bronzing Liquids. Page 40 MONSANTO CHEMICALS 0683780 lU-TASA-N" (See Accelerators, Kubber). BUTYL ACETATE Typical Analysis! Water white liquid: sp. g. 0.872 0.877 at 29'205C.: 7.3 lb*, per gal.: ester content, 88-90%. Boiling range: below 1 l.VC., none: below 122C.. n..t over 10%; below 125C., a.: least 90%; below 130 C., 100%. Drvnes*. mixes with ]0 vols. 60* Be. gasoline. Less than 0.01% as free acetic acid. It.lt. Classification: Butyl Acetate. General Information: Lsed as a nitrocellulose solvent. Is intermediate in activity between ethyl acetate and amyl aeetate. Blends of all three with ap propriate diluents such as alcohols (ethyl, butyl, and amyl) yield thinners and advent mixtures of excellent cutting power and moisture resistance, good flow and leveling, and compatability with various resins and oils. Lsed in the artificial leather industry and in formulat-ng lacquer finishes for wood, metals, textiles, and paper. BLTYL BENZENE SULFONAMIDE (See Santicirer 127). H-BUTYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). BUTYL PHTHALATE (Se< Dibutyl Phthalate). BUTYL PHTHALYL BUTYL GLYCOLLATE (See Samicixer B-16) CABLE LACQUERS General Information* Manufactured in clear, black and colora for application by gasket, for high tension autoo^otive cables and primary wires. Special types are available that are flameproof, resiatant to hot oil, and have high beat test ratings: also non-inflammable type sleeving lacquer of high dielectric strength. All types build well, giving a tough, glossy, flexible finish. R.R. Classification! Lacquers. 26TH bd'tion Page 41 0683781 CAFFEINE, U.S.P. CH, I_ l-?"0 'CH, 0 = C C-nC 1 iCH N--C--N I . RiO Mol. W,. 212.21 ,,, Standard Format Powder, anhydrous pi>wder, hydrated. Specifications: White powder. Loss on drying at 80C: anhvdrous powdrr 0.25% max.; hydrated flakes 5.75 6.50%. M.p. 235C. min.; meets U.S.P. test for rarbonizable impurities. MESH Retained on-- 20 mesh screen 35 mesh screen 45 mesh screen 100 mesh screen 200 mesh screen Hydrated Trace max. 12 0% max. 18 0% max. R.R. Classfication: Chemicals NOIBN. Anhydrous None 2.5% max. General Information: Pharmaceutical product. CAFFEINE, CITRATED, U.S.P.____ CHt II ,,CH, 0= C C -- N 'CH H.C --COOH + HO --C-COOH I HtC-COOH (Caffeine) (Citric Acid) Equal quantities by weight Standard Form t Powder. Specifications: White powder; assay 48.0-52.0% anhydrous caffeine; loss on dry ing at 80C., 0.2% max.; solubility in watet (1*4). complete; conforms to U.S.P. tests for sulfate and heavy metals; 15.0% max. retained oo 100 mesh screen. R.R. Classification: Chemicals NOIBN. General Information: Pharmaceutical product. Page 42 MONSANTO CHEMICALS 0683782 TOWOLDMONOQ41866 CALCIUM GLYCEROPHOSPHATE N.F. (See Glycerophosphates). CALCIUM NITRATE Ca(N03)2.3 II20 Standard Forms: White crystals; 7>% water solution. Typical Analysis: Ca(.\Oj)2 3 IIjO Heavy Metals Iron RA Water White Crystals Solution 98.95% 71.21% none none none none none none 25% Balance to make up 100 is probably magnesium nitrate. R.R. Classification: Calcium Nitrate. General Information: Used as a coagulant in latex dipping processes. CALCIUM PHOSPHATE, MONO (\lso known as primary calcium phosphate, calcium di-hydrogen phosphate, mono-basic calcium phosphate, calcium acid phosphate, and acid phosphate of Grades: Regular for phosphated and self-rising flour and baking powder. Granular for baking powder. All grades meet U.S. Pure Food Law requirements. Special grades will be supplied on request. The following mixtures are carried in stock: Xeut. Strength 52 50 50 45 45 45 Constituents Regular, Starch and 15% Calcium Sulfate. Regular and Starch Granular a(id Starch Regular, Starch and 18% Calcium Sulfate. Regular, Starch and 30% Calcium Sulfate. Regular and Starch. Properties: A white stable material, soluble in water, giving an acid reaction. R.R. Classification: Calcium Phosphate. General Information: Used in baktries for leavening purposes and to prevent the formation of "rope'' in bread; as a leavening agent in biscuits and crackers and as an acid leavening agent in pancakes; as sole acid agent or mixed with sodium aluminum sulfate or sodium acid pyrophosphate in baking powders: in making self-rising, phosphated plain flour and prepared flours; to control pH of solution in malt. 76TH EDITION 0663783 TOWOLDMONOQ41867 CALCIUM PHOSPHATE, DL (Also known as phosphate of lime, precipitated bone, secondary phosphate of lime, dicalcium ort/io>phosphate and bibasic calcium phosphate.) Anhydrous CuHP04 Dihydrate CaHP04.2Hj0 Mol. Wt. 136.068 Mol. Wt. 172.0B4 Standard Format Anhydrous; dihydrate. Properties: Insoluble in alcohol; soluble in dilute citric acid solution. Solubility in CO} free water in grams per liter: Anhydrous: CaO PA Dihydrate; CaO PA 30C. .0414 .0866 .0954 .2066 Gradeai Medicinal; food; dentifrice. 50C. .667 .1630 .2617 .6182 68C. .0985 .2234 .3409 .3245 100. rc. .1046 .2461 .3109 .7591 ' R.R. Classification! Calcium Phosphate. General Information! Used as a mineral supplement in diets that are deficient in calcium and phosphorus; as polishing agent in tooth pastes and powders. Anniston, Alabama, plant of the Phosphate Division. 068378V TOWOLDMONOQ41868 CALCIUM PHOSPHATE, TRI____________________________ _ (Also known as tri-basic calcium phosphate, normal calcium phosphate, neutral calcium phosphate, tertiary calcium pnospbate.). Standard Forms White powder. Grades) Dentifrice, conditioner (salt, sugar, etc.), and medicinal. All material conforms to requirements of the I .S. Pure Food Laws. Properties! White amorphous p.jwder, odorless and tasteless; practically in soluble in water. K.R. Classification! Calcium Phosphate. General Information! Used as a mineral supplement to supply calcium and phosphorus; as a tooth paste base or polishing agent in tooth powder; as an in gredient in making milk glasses; as an antacid: aa a conditioner to prevent caking in salt, sugar, talc and other powdered material. CALCIUM PHOSPHATE, X-C Generallnformation: Extra rich in calcium. Used as a mineral supplement to supply calcium and phosphorus, especially in enriched flours; to control pH of baked products in order to reduce lose of Tbiamin (B|) in baking process; in phosphating plain floure. CALCIUM PYROPHOSPHATE Ca2P2Q7 Mol. Wt 254.12 Properties! A finely subdivided powder; contains 43.8% CaO and 55.5% P205. General Information! Used in food fortification as a mineral supplement. CALCIUM SALICYLATE (See Salicylates). CALCIUM SULFATE (See Crysalba). CARBOLIC ACID (See Phenol). CARBON DIOXIDE GAS______________________________________ CO, Typical Analysis! 100% CO, appiox.; sp. g. of liquefied gas, 1.057. [Continued) 26TH EDITION Page 45 0683785 TOWOLDMONOQ41869 K.R. Classification: Liquefied Carbon Dioxide. General Information: Monsanto carbon dioxide is liberated from pure soda ash. It is purified, dried and compressed to 400 lbs. per sq. in. in a multi-stage compressor, then condensed or liquefied and placed in steel cylinders. Thus pre pared, it is entirely free from odors and tastes and is widely used in carbonating beverages. It is also used as a non-oxidizing atmosphere, in rubber vulcanizing, in dry cleaning, in preserving foods, or wherever an inert oxygen-free medium is required. Liquefied Carbon Dioxide is the cheapest source of high pressure which is portable and without fire hazard. CARBON DIOXIDE, SOLID (Dry Ice) Standard Formt Blocks, 10'xl0'x)0', weighing 50 to 55 lbs. K.R. Classification: Dry Ice. General Information: A product of molasses fermentation in tbe manufacture of alcohol. Carbon dioxide thus produced as compared with the gas from other sources permits higher yield and a purer product, requiring less processing for purification prior to liquefying and solidifying. Used for low temperature refrig eration. CAST PHENOLIC (See Plastics, Opaion). CATECHOL (See Pyrocatecbol). CAUSTIC SODA (Also known as sodium hydroxide) Na OH Mol. Wt. 40.00 Standard Form: Solution 50%. Specifications: Practically clear, colorless or slight yellowish or greenish tinge; sodium hydroxide 48.5% min., 50.$% max.; sodium carbonate 0.20% max.; sodium chloride 1.25% max.; sodiuni chlorate 0.04% max.; iron 0.007% max.; sodium sulfate 0.04% max.; copper 0.0005% max. R.R. Classification! Caustic Soda. General Information! Used in petroleum refining, vegetable oil refining, tanning, soap making, textile manufacture (rayon), rubber reclaiming. CELLULOSE ACETATE (See Plastics, Fibestos). CELLULOSE NITRATE (See Plastics, Nitron). Page 46 IONSANTO CRIMtCALS 0683786 TOWOLDMONOQ41870 CEMENTS General Information: Rapid-drying waterproof cement in various soluble cellulose and resin bases: also heat sealing cements. A complete line of cements is offered for adhering wood, metalK paper and fabric to various plastic materials; also cements for packaging in collapsible metal tubes, such as household cement, model airplane cement, and libraty cement. K.R. Classification: Lacquer. CHLORAL HYDRATE, U.S.P. CCIjCH(OH)j Standard Form: Crystals. Mol. Wt. 165.39 Specifications: Colorless, dry transparent crystals; assay 99.5% min.; solubility in water (1:1), complete; water solution neutral to litmus; comforms to U.S.P. test for carbonizable impurities and chlorides. R.R. Classification: Chemicals NOIBN. General Information: Used in pbarmacentica] preparations and veterinary medicines. CHLORAMINE-B (Also known as N.N-eodium chlorobenzene sulfonamide) 1H HiO Mol. Wt. 240.63 I N./N'vci Standard Form: Crystalline powder. Specification*: Nearly white crystals or crystalline powder; soluble in water; active chlorine 14.45% min. General Information: Chloramine-B is a water-soluble, chlorine-bearing pow der used as a germicide, disinfectant and deodorant. CHLORAMINE-T, U.S.P__________________________ H`c^ oM II Na ^>S -- N^- . SHtO Mol. Wt. 281.70 O Cl Standard Form: Crystalline powder. Specification*i White or faintly yellow powder or granules; sotubility in water (2:15), complete; free alkali (as N*OH), 0.07 0.15%; loaa on drying (3 hr*, at !Continued) 26tb aotTtON Page 47 0683787 TOWOLDMONOQ41871 97UC.), 18.0 . 20.0%; active chlorine 12.25 - 12.60%; assay 97.3% min. MESH Retained on 10 mesb screen--Trace max. Retained on 35 mesb screen--1.0% min. R.R. Classification! Disinfectant other than medicinal. General Information! Chloraraine-T is a water-soluble, chlorine-bearing pow der used as a germicide, disinfectant and deodorant. CHLORCOSANE (Chlorinated Paraffin, N.F.)__ Specifications! Light yellow oil; odorless and tasteless; sp. g. 1.00 to 1.07 at 25'C.; combined chlorine content 27% to 30%; reaction of water extract to lit mus. neutral; chlorides (as HCI) 0.004% max.; free chlorine, none; unchlorinated paraffin, negative (N.F. test). K.R. Classification! Chemicals NOIRN. General Information: A solvent for dichloramine-T. For uses where a product with fire-resistant, insulating and solvtnt properties are indicated. CHLORINATED DIPHENYL (See Aroclors). CHLORINATED PARAFFIN, N.F. (See Chlorcosane). CHLORINE Specifications! Ctear, amber colored bquid; about \Yi times as heavy as water; conforms with American Water Works Association specifications. R.R. Classification! Chlorine. General Information! Used for municipal water purification, sewage treatment and swimming pool sterilization, for slime control, in pulp and textile bleaching, metallurgy, bleaching and processing of flour, organic synthesis, and in the manufacture of metallic chlorides and hypochlorites. CAUTION: Chlorine it toxic and highly irritating. Avoid contact with the skin and breathing the vaport. Available Literature! 20-page booklet "Monsanto Chlorine" paro-CHLORO-mefa-CRESOL, white transparent crystals; used as a disinfectant intensifier; made by Monsanto Chemicals Limited. ortho-CHLORO-poro-TOLUENE-SODIUM SULFONATE (See Monsanto Salt). paro-CHLORO-meta-XYLENOL, white crystals; used as a disinfect. (Continued) Page 48 Monsanto chemicals 0683736 TOWOLDMONOQ41872 ant intensifier and aa a preservative and preventive against mold and mildew; made by Monsanto Chemicals Limited. ortho-CHLOROAMLINE___________________________ (Also known as orf/kj-aminochlor.jbenzene and l-amino-2-cblorobenzene.) NH, Mol. Wt. 127.58 'v Standard Formt Liquid Specifications! Discolors readily on exposure to air: crystallizing point --2.3C. min. Distillation range: first drop, 208.0C. min.: 95% (1-96 ml), 1.0C. max.; dry point, 210.0C. max: Solution in HCI, very slightly opalescent max. R.R. Classification! Dye Intermediate. General Information! Used as an intermediate in the production of dyestuffs. CAUTION: This product is toxic Avoid breathing its vapors and avoid contact uith the skin. meto-CHLOROANILINE _______________________________ (Also known as meta*aminocblorobenzene and l-amino*3*chlorobenzene.) Mol. Wt. 127.58 Standard Fonni Fused solid Specifications i Clear, fight yellow liquid; crystallizing point approx. --10.0CC. Distillation range: first drop, 228.0. min.; 95% (1*96 ml), 1.0C. max.; dry point, 231. 0C. max. R.R. Classification! Dye Intermediate. General Information! Used as an intermediate in the mano/actore of azo dyestuffs. CAUTION: This product is toxic. Avoid breathing Us vapors. Avoid contact with the skin. para-CHLOROANILINE _________________________________ [Also known as Para-aminochlorobenzene and l-amino-4-chlorobenzene.) NH, Mol. Wt. 127.58 Cl 36TB XDITION Standard Formi Fused solid. (Continued) Page 49 0683769 TOWOLDMONOQ41873 .Specifications: Yellowish, white solid; crystallizing point 69.5*C. min. Distilla tion range: first drop, 229.0JO. min.: 05% (1*96 ml), 1.5C. max.; dry point, 233.0C. max. Solution in HCI. slight opalescence max. It.R. Classification: Dye Intermediate. General Information: I'sed as an intermediate in the production of dyestuffs. C.tUTfO.X: This product is toxic. Avoid breathing its vapors and avoid contact u ith the skin. CHLOROBENZENE Cl Mol. Vi. 112.56 Standard Forms Liquid. Specification*! Clear, almost colorless liquid. Distillation range: first drop, 131.5C. min.; 95% (1*96 ml), 0.5*C. max.; dry point. 133.5C. max. R.R. Classifications Monochlorobenzene. General Informations Major use is as an intermediate in the preparation of the various substituted chlorobenzenes which are in turn intermediates for the preparation of dyestuffs, explosives, and various other organic chemicals. Also used as an organic solvent. ortho-CHLOROPHENOL, TECHNICAL (Also known as o/tAo*bydroxycblorobeizeoe and l-chloro-2-hydroxybenzene. OH Mol. Vt. 128.56 lyyl Standard Forms Liquid. Specifications! Clear yellow to brown liquid; monochloropbenol (from Cl con. tent), 95.0% min. Distillation range: fiiet drop, 173.0C. min.; 95% (1-96 ml.), 2.0C. max.; dry point, 178.0C. max. R.R. Classifications Dye Intermediate. General Informations Used as an intermediate in the production of dyestuffs and various other organic product*. CAUTION: This product is toxic, /iwoid breathing its vapors. Avoid contact with the skin. pora-CHLOROPHENOL_ (Also known as poro-bydroxychlorobeiuene and l*chloro4>bydroxybetizene.) (Continued) Page 50 MONSANTO CHEMICALS 0683790 TOWOLDMONOQ41874 OH Mol. Wt. 128.56 Standard Forms Fused solid. Cl Specifications) Yellow to brown crystalline mass; crystallizing point 42.5C. min.; sp.g. at 45.0/15.59C., 1.256-1.262. 11.11. Classifications Dye Intermediate. Ceneral Informations Used as an intermediate in the production of dyestuffs, as a germicide and in the synthesis of pharmaceuticals. C.4 VTION: Care should In- exercised in handling this product, /livid contact with the skin. CHLOROSULFONIC ACID (Also known as sulfuric cblorohydrin.) CISOjOH Mol. Wt. 116.53 Standard Forms Liquid. Specifications; Heavy mobile liquid; assay 98.5% min. R.R. Classifications Acid. General Informations Used in chlorosuifonation reactions. CAUTION: Chlo rosulfonic acid reacts violently with water, forming hydrochloric and sulfuric acids. CHROME SULFATE (See Santotan). CITRATED CAFFEINE, U.S.P. (See Caffeine, Citrated). CONTACT MASS (See Vanadium Catalyst). COPPERAS NITRATE OF IRON (See Nitrate of Iron C). COTTON SOLUTIONS General Informations Made from RS (regular soluble) cotton of any desired viscosity. Viscosity, solid content, and solvent composition can be regulated to meet customer requirements. Used in manufacture of lacquers, leather dopes, fabric coatings, artificial leather finishes, etc. Composition of standard base solutions follow: (Continued) 26TB EDITION Page 51 0683791 TOWOLDMONOQ41875 Formula Number R-1202 R-4683 R-2816 R-1205 R1204 L-4692 Standard Nitrocellulose Solutions Viscosity Wt. NC Percent to l gal. .\itrocel. Nitrocellulose Solvents dry Active Solvent* Seconds 64 ox. 33.9 Butyl Acetate Y% " 64 " 6 " 45 " 36.5 28.1 Ethyl Acetate Butyl Acetate 15-20 " 28 " 19.5 Butyl Acetate 15-20 " 28 " 19.5 Ethyl Acetate 250-400 " 16 " 13.0 Ethyl Acetate Weight one gallon 8.71 lbs 8.54 " 8.53 " 7.99 " 8.1 " 7.24 " * Usual added diluents: Toluol, xylol, lapbthas (varying aromaticity), alcohols (ethyl, butyl, amyl). K.K. Classification i Lacquers, "COUMARIN MONSANTO" 'Coumarin N. F.) --0 -- C ** 0 Mol. Wt. 146.14 Standard Format Crystals, fine: crystals, large--I mesh. Specificationsi Fine or large white crystals: melt (liquid), clear and colorless: m.p. 68.8C. min.; solubility in ethyl alcohol (1:10), complete; loss on drying 0.03% max.: ash 0.05% max.; conforms to N.F. test for acetanilid; 5.0% max. retained on 4 mesh screen; 95.0% min. retained on 8 mesh screen. R.R. Classification i Coumarin. General Information! Coumarin is a flavor and odor principle used separately and in conjunction with vanillin. It is used in perfumes, soaps, tobacco, inks, foods and other products where flavoring or aromatic ingredients are required. Available Literature! Folder, "Coumarin Monsanto". CREAMERY ACID (See Sulfuric Acid). meta-CRESOL, colorless liquid, assay 98*100%, crystallizes at 10.5 12C.; used in the manufacture of synthetic perfumes and nitro-derivatives; made by Monsanto Chemicals Limited. ort/lO-CRESOL* white crystalline mass, crystallizes 30 31C.; used in the manufacture of and as a dye intermediate; made by Monsanto Chem icals Limited. Page 52 MONSANTO CHEMICALS 0683792 TOWOLDMONOQ41876 para-CRESOL, loose white crystals, crystallizes 34.5C.; dye imermediate; made by Monsanto Chemicals Limited. CRESOL-CRESYLIC ACID, duty-free grades; used as a flotation agent and gasoline antioxidant and in tb< manufacture of soaps, disinfectants, paint removers, textile chemicals, resins and dyestuffs; made by Monsanto Chemicals Limited. CRESYLIC ACID (See Cretol), "CRYSALBA" CaSO Mol. Wt. 136.14 Properties! Extremely fine, white powder composed of minute particles of crystalline-shaped anhydrous calcium sulfate, standardized and specially pre pared for use as a dentifrice base (paste or powder). R.R. Classification! Calcium Sulfaie. Principal Uses! Used as a tooth paste base or polishing agent. Suitable for preparation of neutral, acid, basic, soap, or magnesia type dentifrice. "CURODEX" A complete line of reodorants for the rubber trade; not manufactured by us but furnished for the convenience of our customers. "CYCLINE" OIL Specifications! Blend of mineral and vegetable oils. Clear, yellow oil with pale blue-green fluorescence; sp. g. 0.89; Bash point, 185C.; viscosity, between 105 and 115 Saybolt viscosimeter at 37.5C.; soluble in benzene, gasoline, dry al cohols, ethers and acetone. R.R. Classifications Petroleum Oil, NOIBN. General Informations Used as a rubber softener. Available Literatures 42-page booklet "Monosanto Chemicala for the Rubber Industry." 26TH EDITION Page 53 0663793 TOWOLDMONOQ41877 O.YCLOHEXYLA.MI.NE____ (Also known as hexahydroaniline.) NH. CH HC CH, Mol. Wt. 99.17 Standard Forms Liquid. Specifications) Clear, practically colorless; sp. g. at 15.5/15.5C., 0.870.0.874. Distillation range: first drop, 132.0'C. min.; 95% (1-96 ml.), 4.0C. max.; dry point, 137.5C. max. R.R. Classification) Chemicals NOIBN. General Information) Used as a dyestuff intermediate; as an intermediate or ingredient for insecticidal compositions; as a component of conosion inhibitors; in organic synthesis. CA UTION: Thie product ia toxic. Avoid breathing its vaport and avoid contact with the skin. DETERGENTS (See Areskap, Aresket, Aresklene, Santomerae). DIACETONE, TECHNICAL ____ _ Typical Analysis) Nearly water white liquid; acidity, neutral; odor, no residual; sp. g. 0.918 at 15.5C.; shipping wt. per gal., 7.60 lbs.; diacetone content, 85%; boiling range, theoretical b.p. 164C. (decomposes at 130* 140C.); dryness, mixes with 5 vols. of petroleum naptha without turbidity. R.R. Classification) Diacetone. General Information, Diacetone is one of the most active high boiling solvents for nitrocellulose. It is a good solvent for cellulose acetate and many resins, waxes and dyes. Diacetone is miscible and has a high tolerance for nearly all lacquer diluents. Higher percentages of water are tolerated than with most solvents. DIAMMONIUM PHOSPHATE (See Ammonium Phosphate, Di). "D.P. SOLUTION 4519"_____________________________ Standard Form, 40% sol. in ethyl alcohol. {Continued) Page 54 MONSANTO CHEMICALS 0663794 TOWOLDMONOQ41878 Properties! Pale straw colored liifuid; 8.2 lbs. per gal. R.K. Classification: Chemicals NOIBN. General Information: Ised as an anti-corrosion agent in lacquers and cotton solutions, and as an agent to prevent tbe settling of Santocel in fiat lacquer formulations. IMHLTYL PUTHALATE . 0 -C -0-C<H, 0~C -0-C,H, o Mol. Wt. 278.17 Specifications: Clear, oily, liquid, color (APHA) 10 max.; odor, slight; aciditv (as phtbalic acid) 0.01% max.; ep. g. at 20/20C., 1.0480.00l; refrac. index at 25C., 1.-19050.001; assay (ester content) 99% min.: sulfur (copper strip test), negative. K.K. Classification: Dibutyl Phthalate. General Information: Dibutyl Phthalate is one of the most widely used plasticizers for nitrocellulose. It is miscible with all the common organic solvents and with oils but is soluble in water only to the extent of 0.001% at 30C. It has excellent light stability which permits its use in colorless, white or delicately tinted produets. Tbe stability of Dibutyl Phthalate and its high solvent power for most plastic materials make it one of tbe most acceptable plasticizers for general use. Available Literaturei 40 Page booklet ''Plasticizers and Resins". DICALCIUM PHOSPHATE (See Calcium Phosphate, Di). DICHLORAMINE-T, N.F O -------- , || H,C _____y S --NCI* O Mol. Wt. 240.11 Standard Form: Crystalline powder. Specification*: Yellowish white crystalline powder; crystallizing point 80.5*C. min.; assay (available chlorine) 29.SS%. R.R. Ciaaaificationi Chemicals NOIBN. {Continued) J6TH BDITION Page 55 0683795 TOWOLDMONOQ41879 General Information: Dich!ormine*T 19 a Mater soluble, active chlorine bearing product. It rnuat be stored away from light and in a cool place. > 2,5-DICHLOROANILINE_________ (Alao known as i-aroino.2,5*dichloiobenzene) NH* Mol. Wt. 162.03 Standard Form: Fused crystalline mass. Characteristic*: Light brown crystalline mass; crystallizing point, 48,6C. min. Distillation range: start, 24TC. min.: 95%, within l.S#C. R.R. Classificationt Dye Intermediate. General Information: Used as an intermediate in the preparation of azo dye* Bluffs. CA L TION: This product is toxic. Avoid breathing Us vapors. Avoid contact with the skin. "Poison*' label requited. DICHLOROBENZENE (See Santochlor and ortho.Dichlorobeozene) para-DICHLOROBENZENE (See Santochlor), orfho-DICHLOROBENZENE, TECHNICAL. (Also known as 1, 2*dichlorobenzene) Cl Mol. Wt. 147.00 Standard Forint Liquid. Characteristics! Colorless to slightly yellow liquid; crystallizing point, 7.0C. max.; 100% (1st drop, dry point), l<i.0oC. max. Sp.g, 15.5/15.5, 1.305.1.313: composition, 75 85% ortho-dicblorobenzene, 15 25% para-dichlorobenzene. R.R. CUaeifications Ortho-dicblorobenzene. General Informations Used as a dyestuff intermediate; solvent; ingredient in cleaning preparations; and as an insecticide and fungicide. Page 56 MONSANTO CHEMICALS 0663796 2, 4-DICHLOROPHENOL (Also known as l,3-dicbloro-4-hydj oxybenzene.) Mol. Wt. 163.00 Standard Formt Fused solid. Specification*! Yellow to brown crystalline mass: crystallizing point 42.0C. min. Distillation range: first drop, 211.5C. min.; 95% (1-96 ml.), 2.0C. mat. R.R. Classification! Dye Intermediate. General Information! Used as an intermediate in tbe production of dyestuffs and as a germicide. CA UT10,V: Core should be exercised in handling this material. Avoid contact with the skin. Avoid breathing its vapors. DICYCLOHEXYLAMINE <V> \ N-H / Mol. Wt. 181.32 Standard Formt Liquid. Characteristics! Clear, practically colorless liquid: sp.g. 15.5V1S.5C., 0.916 0.920. Distilling range: first drop, i!52.0C. min. Flash point ("Tag'* open cup), above 200F. R.R. Classification! Chemicals NOIBN. General Information! Used as an intermediate in the manufacture of oil additives and insecticides. CA UTfON: This product is toxic. Avoid breathing its vapors. Avoid contact with the skin. DIETHYL PHTHALATE o II -C "0 --CiH* - C - 0 - C,H* II o Mol. Wt. 222.11 Specifications! Clear, water-wbitt oily liquid; color (APHA), not darker than 10; odor, very slightly aromatic; acidity (as pbthalic acid) 0.01% max.; sp. g. at 20o/20C., 1.1230.005; refrwe. index at 2QC., 1.5030 0.001, sulfur (copper-strip test), negative. (Continued) 26TB bdition Page 57 0663797 TOWOLDMONOQ41881 R.R. Classification! Diethyl Pbthalate. General Informations Diethyl Phtbalate is a colorles* liquid plasticizer gen* erally used in mixture with dimethyl pbtha ate aa a plasticizer for cellulose acetate. It is miscible with all the common organic solvents and diluents. Evap. oration rate of Diethyl Pbthalate is too high for successful use as a regular nitro cellulose plasticizer and it is not a solvent for cellulose acetate. Thus its range of usefulness is somewhat restricted. Mixtures of Diethyl and Dimethyl Pbthaiates usually give better results than can be obtained by either one alone. Boiling point is 295C.; weight per gal., 9.35 lbs. Available Literature! 40 Page booklet "Plasticizers and Resins". 2, 3-DIMETHOXY BENZALDEHYDE, TECHNICAL (Also known as ort/io-veratraldehyde). /,, OCH* Mol. Wt. 166.0 0OCH, Characteristics! Yellowish brown fused crystalline mass; solubility in sodium bisulfite, nearly complete; crystallizing point, 4?.5C. min.; sp.g. at 60C., 1.117; wt. per gal., 9.3 lbs. approx. R.R. Classification! Chemicals NOIBN. General Information! Used aa a perfume fixative and as an intermediate in chemical synthesis. DIMETHYL PHTHALATE . O /X 11 | j -- C ---0 -- CHi l J-c --O -- CH V II Mol. Wt. 194.08 Specifications! Clear, water-white oily liquid; color (APHA), not darker than 10; odor, not more than slightly aromatic; acidity (as phthalic acid) 0.01% max.; p. g. at 15.6/1S.6*C., 1.196ab0.001; refrac. index at 20C., l.S1550.001; sulfur (copper strip test), negative. R.R. Classification! Dimethyl Pbthalate. General Information! Dimethyl Phtbalate is a solvent plasticiser for cellulose acetate. It is miscible with all common organic solvents and with oils (except (Continued) Page 58 Monsanto chbmicals 0683790 TOWOLDMONOQ41882 petroleum oils) and has a solubility io water of 0.4% at 32C. It has excellent light stability. Dimethyl Phthalate is much used but cannot be said to meet very rigid plasticizer requirements. Its use is restricted almost entirely to the cellulose acetate field, and there, as a general rule, it is used in combination with diethyl phthalate or some other plasticizer. Dimethyl Phthalate has a boiling point of 282C., a crystallizing point of 0JC., and weighs 10 lbs. per gallon. Available Literature! 40 Page booklet ''Plasticizers and Resina." 2, 4-D1MTROAMLINE____________ (Also known as l*dmino>2, 4-dutUrobenzene.) NHi Mol. Wt. 183.12 NO, Standard Form: Powder. Specifications! Bright yellow powder; m. p. 177.5C. min.; chlorides (total) 0.15% max. R.R. Classification: Dye Intermediate. General Information: Used as an intermediate in the preparation of dyestuffs. CAUTION: This product is toxic. Avoid breathing its dust. Avoid contact with the skin. 2, 4-DIMTROCHLOROBKNZENE, TECHNICAL (Also known as l*chloro-2,4-dinitTobenieBe.) Cl NO, Standard Form: Fused crystalline solid. Grades: 3 grades of fused crystalline solids with crystallizing points of 48.0C., 46.5C., and 44.0aC. Approximate Analysis: 2:4 dinitto* chlorobenzene 48.0C. 4b.5*C. Vu7o 44.0C. 85% isomeric dinitxo* chlorobenzenes 5% Approi. 10% " 15% " P.J* 59 0663799 General Information! Used in the production of explosives, photographic chemicals, and dinitrophenol, and as an intermediate in the preparation of dyestuffs. CAUTION: This product if toxic. Aioid breathing Us vapors. Avoid contact with the skin. DIPHENYL______________________ (Also known as biphenyl; phenyl benzene). o-o Mol. Wt. 154.2 Properties! Technical diphenyl is a light yellow crystalline solid. Boiling point 254.98C, freezing point 68.5C. to 68.91' C. R.R. Classification! Diphenyl. General Information! Used as a high temperature, low pressure heat transfer medium. It is also the starting point for many derivatives such as Aroclors (chlorinated diphenyl) and the suifonio acid, nitro, amino and hydroxy com* pounds. DIPHENYL PHTHALATE Mol. Wt. 318.31 Specification#! Essentially white fused solid; melt, clear and light yellow color: free acid (as phthalic) 0.20% max., free phenol 0.25% max. R.R. Classification! Lacquer Solvent. General Information! Diphenyl Phthalate has a crystallizing point of about 69C. and is readily soluble in ketones, esters and chlorinated hydrocarbons. Its solubility in alcohols, turpentine afcd linseed oil is rather low, approx. 5.0 grams per 100 c.c. of solvent at 25SC. Diphenyl Phthalate is compatible with nitrocellulose and with the sulfonamide, phenolic, polystyrene and vinyl types of synthetic resins. In nitrocellulose lacquers it produces hard coatings that have excellent gloss retention and weather resistance. Mixtures of Diphenyl Phthalate with either Santolite MS or Santolite MHP are excellent plasticizers for nitro* cellulose in odorless, flexible, adhesive coatings. Diphenyl Phthalate is completely insoluble in water and gives increased water resistance to all compositions in which it is used. It is especially recommended for vinyl resins, polystyrene, ethyl cellulose, and some of the natural resins such as Damar. Available Literature! 40 Page booklet "Plasticizers and Resins'*. Page 60 MONSANTO CHIMICALS 0683800 TOWOLDMONOQ41884 DIPHENYLGUANIDINE (See DPG under Accelerator*, Rubber). DIPPING LACQUERS (Se< Lacquer*). DISINFECTANT INTENSIFIERS (See Santophen, Are*kap). DISODIUM PHOSPHATE (See Sodium Phosphate, Di). DISPERSING AGENTS (See Areskap, Aresket, Aresklene, Saotomerte). DRY ICE (See Carbon Dioxidt Solid). "EL SIXTY** (See Accelerator*, Rubber). ELECTROLYTE (See Battery Acid). EMULSIFYING AGENTS (See Araakap, Aresket, Aresklene, Santomene). ENAMELS (See Lacquers and Resin*). "ETHASAN** (See Acceleratois, Rubber). "ETHAVAN" (Ethyl Vanillin)--------------------------------------------------OH Mol. Wt. 166.17 C=0 Standard Formt Needles. Specifications! Fine white crystalline needles; completely soluble in ethyl alco hol 95% (1:2); ash 0.05% max.; n..p. 76.5C. min. R.R. Classification! Chemicals NOIBN. (Continued) 26TB BDITION Page 61 0683S01 TOWOLDMONOQ41885 General Information! Etbavan is us<d as a flavoring and aromatic, and has a flavor similar to that of Vanillin but not identical with it. Tbe relative flavoring strength of Etbavan approximates three times that of Vanillin. Available Literature! Leaflet, ''Etbavan." ETHYL ACETATE Typical Analysis: Water white liquid; sp. g., 0.895 at 15.5C.; 7.40 lbs. per gal.; ester content, 85-90%. Boiling range: 7(>C. 80C. Dryness, mixes with not less than 10 vols. of petroleum benzine without turbidity. Less than 0.02% as free acetic acid. K.lt. Classification! Ethyl Acetate. General Information! Used as a nitrocellulose solvent. It is a more active solvent than either butyl or amyl acetate, evaporating the fastest, and having the least resistance to moisture blush. Blends of all three with appropriate diluents such as alcohols (ethyl, butyl, and amyl) yield thinners and solvent mixtures of excellent cutting power and moisture resistance, good flow and leveling, and com patibility with various resins and oils. 1'sed in the artificial leather industry and in formulating lacquers and finishes foi wood, metals, textiles, and paper. ETHYL ALCOHOL--190 Proof CjHjOH (Also see Mersol, a proprietary solvent type alcohol, and Nealco Anti-Freeze.) Grades i 1. Tax Free: 190 proof pure Ethyl Alcohol (95% by volume). May be withdrawn Under Regulations and Provisions by the U. S. or any governmental agency thereof, or by tbe several states and territories, or any municipal subdivision thereof, or by the District of Columbia, or for the use of any scientific university or college of learning, any laboratory foi use exclusively in scientific research, or use in any hospital, or sanitarium, or for the use of any clinic operated for charity and not for profit, including use in tbe compounding of bona 6de medicines for treatment outside of such clinics of patients thereof, but not for sale. 2. Tax Paid: 190 proof pure Ethyl Alcohol (95% by volume), (a) May be pur chased by manufacturers and others for non-beverage use without Federal Permit or bond, but such users must sign affidavit that the alcohol so purchased is for industrial use only, as defined by Federal Alcohol Administration Regula tion 2. (b) May be purchased by blenders and rectifier*, (c) Subject to Federal Government Tax. Individual state regulations apply on tbe purchase and use of pure Tax Paid Alcohol. 3. Specially Denatured Alcohol: May lie withdrawn for use in a great number of specialised art* and industries. The character of the denaturant or denaturanta employed ia such that Specially Denatured Alcohol may be aold, possesaed and used only pursuant to permit and bond approved by Internal Revenue Depart ment, Alcohol Tax Diviaion. All application forms covering tbe withdrawal of (Continued) Page 62 Monsanto chimical* 0683802 TOWOLDMONOQ41886 Molasnes storage tanka of the New England Alcohol Company. Specially Denatured Alcohol may be obtained from the office of the District Supervisor, Internal Revenue Department, Alcohol Tax Division of the district in which the purchaser's plant is located. 4. Completely Denatured Alcohol: 188 proof. May be withdrawn without permit or (ax, but buyer must comply with certain Federal and State regulations govern* ing records and storage. R.R. Classification! Alcohol NOll*N or Denatured Alcohol. General Informationi Nealco ethyl alcohol is manufactured by the fermenta tion of molasses. It is offered in its pure state and in all formulas of Specially Denatured and Completely Denatured Alcohol as authorized by Federal Law under the provisions of Title III of the National Prohibition Act. It is of high uniform quality complying with the exacting specifications of the National Formulary VI and U.S.P. XI. Available Literature! 68-page booklet "Nealco Industrial Alcohol." ETHYL BENZENE SULFONAMIDE (See Santiciser 128). ETHYL PHOSPHATE (See Triethyl Phosphate). 26TH KIMTION Page 63 0683803 TOWOLDMONOQ41887 ETHYL PHOSPHORIC ACID (Se Alkyl Phosphoric Acids). ETHYL PHTHALYL ETHYL GLYCOLLATE (See Santicizer E-15). ETHYL TRIETHANOLAMINE PHOSPHATE______________ Properties* Medium siraw colored liquid of slightly alcoholic odor; sp. g. 1,19 at 25 C.; ut. per gal. 9.9 tbs,; liquid at all ranges of relative humidity but very viscous when anhydrous; pH 7.0 7.4; strength, 60% solution in water. R.R. Classifications* Chemicals NOIBN. General Information* Used as a plasticizer for water soluble materials and as a humectant. ETHYL VANILLIN (See Ethavan). FERRIC CHLORIDE SOLUTION (Iron Perchloride)_____ FeCI, Standard Form* Liquid. Grades* 37aB.; 40B6.; 426B*. Typical Analysis* Ferric Chloride 42Bf: total FejOs. 20.3%; FeO, 1.0%; combined Fe^Oj, 19.2%; FeClj, 39.0%. R.R. Classification* Iron Chloride Liquid. General Information* Used as an acid oxidizing agent in etching, photoengrav> ing, and in the manufacture of textile printing rolls and brass signs. It is used in water and sewage treatment for its iron content. FERRIC GLYCEROPHOSPHATE (See Glycerophosphates). FERRIC NITRATE, LIQUID (Trot Nitrate of Iron) Fe(NOj)j Grades* 47BB,, 16.0% FejOj R.R. Classification* Iron Nitrate. General Information* A source of ferric hydroxide for mineral tan and buff colors on cotton; brown papers; logwood blacks on silk; shoe stains and inks. FERRIC PHOSPHATE- Sodium Ferric Pyrophosphate NagFe,|(Pj07)j.XHi0 (Continuet') Page 64 Monsanto chemicals 0663804 Ferric Orthophosphate Ferric Pyrophosphate Ferric Acid Pyrophosphate General Information: Used in food aod pharmaceutical fortification as a mineral supplement. FERRIC SULFATE {See Feirisul). FERRIC SULFATE, LIQUID (Copperas Nitrate of Iron) ___ FerfSO* Grades: 40B., 13.6% FejOj 47B6., 15.7% Fe,0* Containers: Carboys; barrels. General Information: A strong solution of ferric sulfate, containing no nitric acid. Used as a source of ferric hydroxide for mineral tan and buff colors on cotton, brown papers, logwood blacks on silk, shoe stains and inks. "FERRISUL"(Anhydrous Ferric Sulfate) FejfSOO* Standard Form: Pellets 4*40 meehu Typical Analysis: 90% min. FejfSO*)*. R.R. Classification: Dry Ferric Sulfate. General Information: An effective coagulant for the treatment of water supplies, sewage, and industrial waste. In solution, it is a mild oxidising sgeot snd can be used for pickling certain alloys such as the stainless steels, brass aod other copper alloys. It is also used in various organic reactions. Available Literature: Booklets, "Ferrisul for Treatment of Water, Sewage and Industrial Wastes'* snd "Ferrisul for Metal Treating." FERROPHOSPHORUS (Iron Phosphide) Standard Forma: Chill cast lumps, egg sise; powder. Contains 23 26% pbos* phorua. R.R. Classification: Ferropboephorus. General Information: An alloy of iron snd phosphorus. Used in iron and steel castings to increase fluidity; in sheet steel to prevent sticking of sheets in final rolling; in wire to give stiffness and better surface for drawing. Available Literature: Phosphoms-Iron Alloys Bulletin No. 1. A report of (Continued) 26TB EDITION Page 65 0663605 TOWOLDMONOQ41889 ueneral exploratory research upon the influence of phosphorus in low carbon, low alloy sleds, 36 pages. Bulletin No. 2. A report of experimental research investigation upon corrosion jnd mechanical influences of alloying elements in low alloy steels. 62 pages plus harts. Bulletin No. 3. Abstracts of U.S. patents relating to phosphorus as an alloying lenient in steel and list of iron and steel patents, 5-1 pages. Bulletin No. 4. Rcporu of experimental research investigation upon influence >f phosphorus in steels in elevated temperature service and in Cr-Mo steels, 20 pages. "FIBESTOS" (See Plastics). ''FLECTOL" H and WHITE (See under Antioxidants). I* LOTATION AGENTS (See Xanthates). FUNGICIDES (See Santobrite and Santophen 20). GERMICIDES (See Antiseptics and Germicides). GLAUBER'S SALT (Sodium Sulfate) Na*S04+ 10 HjO Standard Formsi Crystals and Glauboids. Typical Analysisi 43% NajS04 available. R.R. Classification! Glauber's Salt. General Information! Used principally as a leveler in dyeing wool and silk; for the precipitation of barium aulfate or blanc fixe; neutralising of sulfonated oils; treating softened boiler feed water to prevent caustic embrittlement; salting skint. GLYCEROPHOSPHATES___ Specifications! See individual glycerophosphates below. General Information! The Glycerophosphates are a group ofproducts contain* (Continued) Page 66 MONSANTO CHBMICALS 0663606 TOWOLDMONOQ41890 ing the glycerophosphate radical and may be used advantageously to carry such important elements as calcium, iron, magnesium, manganese, potassium, and sodium in the formulation of pharmaceutical preparations. In the case of the less soluble salts, such as calcium, iron, magnesium, and manganese, the solubility of these products may be materially increased if they are formulated with Glycerophosphoric Acid or certain accepted food acids, such as lactic, citric and tartaric. GLYCEROPHOSPHATE, CALCIUM, N.F. CaCiH(OH)jPO, Mol. Wt. 210.15 Standard Form i Powder, 80 t-iesh. Specifications! Fine white powder; assay (dry basis) 98.0% min.; sp. g. 0.42 0.50; loss on drying at 130C., 12.0% max.; solubility in water (1:50),complete; chloride (aa CaCI.) 0.1% max.} sulfate (as CaSO,) 0.50% max.; free phosphate (aa P]0) 0.02% max.; conforms to N.F. test for heavy metals; 3.0% max. re tained on 80 mesh screen; 5.0%, max. on 100 mesh screen. R.R. Classification: Chemicals NOIBN. GLYCEROPHOSPHATE, FERRIC, N.F. Fet(CjH(OH)iPO<]j Mol. Wt. 621.90 Standard Form; Powder. Specifications! Buff or yellowish green powder; assay (dry basis), 17.0% Fe min.; moisture, 10.0% max.; chloride (as FeCIi), 0.10% max.; sulfate (as Fe;(SO<)t), 0.10% max.; free phosphate (as PjO), 0.20% max.; 2.0% max. re tained on 60 mesh screen, 10.0% max. on 150 mesh screen, 30.0% max. on 250 mesh screen. R.R. Classifications Chemical! NOIBN. GLYCEROPHOSPHATE, MAGNESIUM MgCHi(OH)jPO, Mol. Wt. 194.39 Standard Forms Powder, 80-mesh. Specifications White powder: assay, 97.0% mb.; moisture, 12.5% max.; calcium (as CaO), negative; chlotide (aa MgCI-), 0.10% max.; sulfate (as MgSO), 0.10% max.; free phosphate (as PjO*), 0.20% max.; conforms to N.F. test for heavy metals; 2.0% max. retabed on 60 mesh screen, 4.0% max. on 80 mesh screen, 10.0% max. on 100 mesh screen. R.R. Classifications Chemicals NOIBN. 26TB COITION Page 67 068380? TOWOLDMONOQ41891 GLYCEROPHOSPHATE, MANGANESE, N.F. MoCjHj(OH)jPO Mol. Wt. 225.00 Standard Formt Powder, 80-mesh. Specifications) Pinkish white powder; assay (dry basis), 98.0% min.; solubility in 25% citric acid solution (1:5), complete; moisture, 10.0% max.; chloride (as MnCI:), 0.15% max.; sulfate (as MnSO,), 0.03% max.; free phosphate (as P.Oj), 0.20% max.; conforms to N.F. test for heavy metals; 2.0% max. retained on 60 mesh screen, 4.0% max on 80 mesh screen, 10.0% max. on 150 mesb screen. R.R. Classification) Chemicals NOIBN. GLYCEROPHOSPHATE, POTASSIUM (Solution) KjCjH*(OH)jPO, Standard Forint Solution 75%. Specifications! Clear, colorless or slightly yellowish solution; assay, 61.6 63.2% anhydrous salt; carbonate (as K jCOj). 0.50 % max.; chloride (as KCI), 0.10% max.; sulfate (as K?SO), 0.10% max.; free phosphate (as PjO*), 0.20% max.; conforms to N.F. test for heavy metals. R.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, SODIUM, N.F NatCtH,(OH)}PO. 5V$HiO Mol. Wt. 315.15 Standard Formal Crystals, 10-80 mefcb; powder. Specifications! White crystals; assay, 68.0 72.0% anhydrous salt (equivalent to 96.35 104.9% hydrated salt); solubility in water (1:10), complete; chloride (as NaCI), 0.05% max.; free phosphate (as PtOi), 0.02% max.; cooforms to N.F. test for heavy metals and sulfate (as NaiSO,); no crystals retained on 10 mesh screen, 40.0% min. crystals on 80 mesb screen. R.R. Classificationi Chemicals NOIBN. GLYCEROPHOSPHATE, SODIUM (Solution) NatCiHi(OH)tP04 Standard Forms Solution 75%. Specifications! Clear, colorless or slightly yellow solution; assay 50.0 52.0% {Continued) Page 68 Monsanto chemicals 0663806 TOWOLDMONOQ41892 anhydrous salt; carbonate (as NajCOj) 0.5% max.; chloride (as NaCI) 0.10% max.; sulfate (as NatSO<) 0.10% max.; free phosphate (as PjO) 0.15% max.; conforms to N.F. test for heavy metals. R.R. Classification] Chemicals NOIBN. GLYCEROPHOSPHORIC ACID (Solution) HiCH(OH):PO Mol. Wt. 172 Standard Formt Solution 35%. Specifications] Clear, colorless liquid, APHA 20 max.; assay 35.0 36.0%; chloride (as CaClj), 0.10% max.; sulfate (as CaSO<), 0.20% max.; calcium (aa CaO), 0.25% max.; free phosphate (as PjOj), 0.35% max.; conforms to N.F. test for heavy metals. R.R. Classification! Chemicals NOIBN. ``GUANTAL" (See Accelerators, Rubber). H ACID (Mono8odium-l-Amino-8-Naphthol-3,6-Disulfonate) OH NH* NaSOj SOsH Mol. Wt. 341.29 Typical Analysist White powdet; 86-88% monoeodium salt; trace of NaCI and NajSOi; solubility in water, complete. R.R. Claaaificationt Dye Intermediate NOIBN. General Information! Used as so intermediate in the manufacture of dyestuffs. "HIBITITE"_______________________________________________ Standard Format Hibitite; Hibitite A, a commercial blend having half the strength of regular Hibitite. Properties! Derivative of an organic base; reddish brown powder; soluble in concentrated sulfuric and muriatic acids. R.R. Claaaificationt Iron or Steel Cleaning NOIBN. (Continued) 26TB BDtTION Page 69 0683809 TOWOLDMONOQ41893 General Information: Hibitite is widely employed in acids used for pickling and cleaning ferrous metals. It protects the metal by inhibiting the attack of the acid and by reducing the possibility of embrittlement caused by hvdrogen peoe(ration. Hibitite A is similar in act>on to Hibitite with the exception that it is more readily dispersed than Hibitite in making up the acid solutions. Sulfuric acid containing Hibitite is used for pickling tin plate, wire, alloy steels, sheets for galvanizing; for cleaning steel drums and sand filters: for pre* paring articles for vitreous enameling; for removing metal coatings. Muriatic acid containing Hibitite is used for cleaning boilers, economizers, heat exchangers, pipe lines, condensers, tanks, tuixs, coils, screens, pans, drums and similar equipment. For steel pickling acid containing Hibitite, see Inhibited Add. Available Literature! 4-page raimtographed leaflet, "Hibitite and Its Uses." HYDROCHLORIC ACID, C. P HCI Mol. Wt. 36.46 Specifications! Colorless liquid free from suspended matter; strength 37.0 to 38.5%; non-volatile matter 0.0005% max.; sulphate 0.0002% max.; free chlorine 0.0002% max.; sulphite 0.003% max.; arsenic 0.00001% max.; iron 0.0001% max.; heavy metals (as lead) 0.0005% max. R.R. Classifications Muriatic Acid General Informations Laboratory reagent. HYDROCHLORIC ACID (See Muriatic Acid). 2-HYDROXY-3-METHOXY BENZALDEHYDE, TECHNICAL (Also known ss ortho-vanillin.) /0 C--H OH 0OCH, Mol. Wt. 152.1 Characteristics! Yellowish crystalline solid; crystallising point, 40.0C. min.; density, 1.20 at 60C.; wt. per gal., 10.0 lbs. R.R. Classifications Chemicals NO) BN. General Informations Used ss sn antioxidant and at an intermediate in chem ical synthesis. Page 70 MONSANTO CHEMICALS 0683610 TOWOLDMONOQ41894 INHIBITED ACIDS Grades: These acids are solutions of Hibitite in Monsanto's commercial grades of 60CB. sulfuric acid, 66B. sulfuric acid. 18B#. muriatic acid and 20B. muriatic acid. General Information: Addition of Hibitite to sulfuric and muriatic acids results in a decreased rate of attack of the acid on metal hut does not retard the action of the acid on surface scale on the metal. Inhibited sulfuric acid is used for pickling tin plate stock, pickling sheets for galvanizing, preparing articles fov vitreous enamel, pickling Hire, pickling high carbon steel, removing metal coatings, cleaning steel drums and cleaning sand lilters. Inhibited muriatic acid is ui-ed for pickling alloy wire and cleaning boiler tubes, condensers, pipes, beater coils and drums. INHIBITORS (See Hibitite). INKS, LACQUER BASE General Information: Lacquer inks are rapid drying, waterproof, greaseproof, adherent, flexible, and resistant to abrasion. Colors are light, fast and opaque, glossy or dull. Adapted for printing or coating cellophane, glassine, foil and other wrapper stock. Application is by intaglio photo engraved roll printing only, print roll being cleared by doctor blade. R.R. Classification! Lacquers. INSECTICIDES ortho-Dichiorobenzene (See under D). "Santochlor" (See under S). IRON CHLORIDE (See Fenic Chloride). IRON GLYCEROPHOSPH AT E (See Glycerophosphate, Ferric). IRON NITRATE (Sen Ferric Nitrate). IRON PHOSPHATE (See F*ric Phosphate). IRON PHOSPHIDE (See FetTopboapborus). IRON GLYCEROPHOSPHATE N.F. (See Glycerophosphates). IRON SULFATE (See Ferric Sulfate and Ferriaul). 26TB edition Pace 71 0683811 TOWOLDMONOQ41895 IACQUERS----------------------------------------------------------------- For information on special lacquers and related products offered by Monsanto see tbe following listings elsewhere in this catalog: Acetone: Aircraft Finishes; Amyl Acetate; Belt Cement; Bronzing Liquids; Butyl Acetate; Butyl Alcohol; Cable Lacquers: Cements; Cotton Solutions; Diacetone; Ethyl Acetate; Inks. Lacquer Base; Leather Dopes; Manicure Lacquers; Mersol (Solvent Alcohol); Mertec; Textile Lacquers; Textile Printing Lacquers; Thinners. General Information i Tbe Lacquer and Solvent Department of Monsanto has been engaged for twenty years in th< development and manufacture of a wide variety of nitrocellulose base coalings for industrial use. At tbe present time Monsanto finishes for textiles, leathei. paper, rubber, wood and metal are being used in practically all classes of industry. Specific information available on re quest. K.R. Classification > Lacquers. LACQUER COTTON (See Cotton Solutions). LACQUER EMULSIFYING AGENTS (See AreekJene and Santomerse). LAMPBLACK Grades! Ten grades are available which vary in free carbon, density, and oil absorption. Specifications! Grad* Ordinary Black Lampblack Bear Germantown Commercial Black Lampblack No. 10 Lampblack B-5 Lampblack B-16 Lampblack BTA Lampblack S-100 Lampblack No. 8 Lampblack AA Fret Carbon 88.0% 9;\20% 88.05% 99.11% 97.20% 98.38% 98.23% 97.70% 97.03% 9(-.34% Apparent Density Lb. per Cu. Ft. 25.4 7.76 25.4 12.11 7.76 6.75 6.30 5.72 5.15 4.77 Benzol Extract % -- 1.65 -- .20 1.65 .7 .6 .6 .65 .85 R.R. Classification! Lampblack NOIBN. General Information! Used as pigment in paints, varnishes, enamels, inks, leather finishes, stencils, crayons, polishes; in pressed forms as electrical conduc tors and electrodes. Available Literature! Booklet, "Monsanto Lampblack." LATEX PENETRANTS (See Aresklene and Santomerse). LATEX STABILIZERS (See Aresklene and Santomerse). Page 72 tONSANTO CBBMICALS 0663812 TOWOLDMONOQ41896 LEATHER DOPES_______________________________________ General Information! Nitrocellulose solutions specially formulated for the incorporation of plasticizer and pigment for use in finishing split, patent, and artificial leathers. R.R. Classification! Lacquers. LITHIUM SALICYLATE N.F. (See Sa)icylatX "LUSTRON" (See Plastics). MAGNESIUM AMMONIUM PHOSPHATE____ _ (Also known as magnesium ammonium ortho phosphate.) MgNH4P0.6H,0. Mol. Wt. 245.44 Standard Form! White powder. Properties! Insoluble in water and soluble in acids. Decomposes on beating. Grade! Technical. R.R. Classification! Chemicals NOIBN. Principal L'sest As an ingredient in fire retarding paints for theatre scenery and curtains. General Information! A hexahydrate and a monohydrate form exist. At ordinary temperatures dieaesociajion of the hexabydrate to the monohydrate takes place without appreciable loss of ammonia. Above 60C. the monobydrate loses NHj forming MgHPO4.Ha0. MAGNESIUM GLYCEROPHOSPHATE (See Glycerophosphates). MAGNESIUM PHOSPHATE, MONO------------------------------------- (Also known as magnesium phosphate, monobasic; acid magnesium phosphate; magnesium tetrahydrogen phosphate; magnesium hiphosphate.) MgH4(POt)i Mol. Wt. 218.31 Standard Form! White crystals. Gradei Technical. 26TB EDITION (Continued) Page 73 0663813 TOWOLDMONOQ41897 Rotary kiln at Camden, New Jeraey, plant. R.R. Classifications Chemicals NOIBN. Principal I'wst Used in pharmaceutical preparations. MAGNESIUM PHOSPHATE, TRI_____________ (Also known as neutral magnesium phosphate.) Mg(PQi)i Mol. Wt. 262.88 Standard Form > White crystalline powder. Grades Technical R.R. Classificationt Chemicals NOIBN. General Informations Used in pharmaceutical products as an antacid. Page 74 MONSANTO CHEMICALS 068381* TOWOLDMONOQ41898 MAGNESIUM SALICYLATES (Se.Salicyl.tc), MALEIC ANHYDRIDE Mol. Wt. 98.06 Standard Form! Fused solid. Specifications! While crystalline mass; crystallizing point 52.09C. min.; water solution (4 grams in 10 nil.), clear and colorless; glyceromaleate resin, clear with slight amber color; iron 0.0005% m*K. H.R. Classification) Chemicals NOIBN. General Information) Used alone or in combination with other acids in the manufacture of alk>d type resins. MANGANESE GLYCEROPHOSPHATE (See Glycerophosphates). MANICURE LACQUERS (See Lacquers). MANICURE LACQUERS and REMOVERS_______________ General Information) Manicure lacquers are offered in two types -- trans parent and creme. The dye* used in the transparent type are selected for stability to light, soapy water and ag*ng. The bottle appearance of the creme type lacquers is unusually good. There is no objectionable separation due to settling, and the lacquer applies without streaking. The bottle color matches the applied lacquer very closely. Colors and shades are provided according to the suggestions and specifications of the customer, and the opportunity to assist in development of new shades is welcomed. For those who prefer to select from standard shades, the following are offered in Manicure Lacquer R~4040 Creme and Transparent: Reddish Creme Shades Natural Robin Red Rose Sunrose Tulip Burgundy Old Roee Garnet Brotmish Creme Shades Thistle Suntan Rust Chestnut BUtish Creme Shades Lilac Windsor Grape Heather (Continued) Transparent Natural Rose Garnet 26TR EDITION Page 75 0683815 TOWOLDMONOQ41899 Manicure Lacquer Remover R-2522 is an active solvent and has an agreeable odor. Containers: Cans, 5 gal.; drums, 55 gal. Available Literature: Color chip folder, ''Monsanto Manicure Lacquers." "MERCLOR" (Sodium Hypochlorite)________________ NaOCl Standard Form: Liquid. Typical Analysis: 22B6.; 12% available chlorine by volume R.R. Classification: Sodium Hypochlorite Solution. General Information: Merclor is i>sed as an oxidizing agent for bleaching cf vegetable fibers and as a chlorinating agent for water, organic compounds and wool. (See table in general data section ' "MERSOL" Typical Analysis: Water white liquid: sp. g. 0.80 0.82 at 15.6*C.; odor, mild, non-residual; distillation range, 74s 80s C.; acidity, less than 0.005% as acetic acid. Composition: Alcohol, Special Denatured No. 1 Methyl isobutyl ketone Ethyl acetate, denatured withmethyl isobutyl ketone Gasoline 100 gals. 1 gaL 1 gat. 1 gal. R.R. Classification: Denatured Alcohol Solvent Containing Not Less Than 90% Denatured Alcohol. General Information: Meraol, a proprietary solvent alcohol, is formulated to have the advantages of Special Denatured Alcohol No. 1 without the necessity and burden of purchasing and operating under a government permit. It has the mild odor of alcohol and no residual; Meraol may be used for most industrial purposes where SDA No. 1 is indicated, as a solvent for shellac and soft manila gums, in lacquer thinners, cleaners, removers, polishes, dressings, inks, adhesives, celluloid, softeners, brighteners, and s a fuel and dye and stain solvent. Available Literature: 68 page booklet "Nealco Industrial Alcohol." "MERTANOL" Grades: Mertanol SS; Mertanol L; Mertanol 7L; Mertanol D; Mertanol 7D. (Gmtinued) Page 76 MONSANTO CHEMICALS 0683816 TOWOLDMONOQ41900 Typical Analyses: Mertanol SS Mertanol L Mertanol 7L Tannin Acidity equivalent to Sp. Gr. Inorganic Salts 12% 19-20% 19 - 20% .64 >66 normal 1.22 1.26 normal neutral 2.66 2.74% HjSOi approx. 4.74% HjSO* pH 6> 8 1.176.1.178 1.205.1.212 1.214 1.225 8.2% Na,S04 11.4% (NH,),SO 18.8% (NH^O, Tannin Acidity equivalent to Sp. Gr. Inorganic Salta Mertanol D 19 20% 1.22 1.26 normal approx. 4.74% H^SO* I.22 1.23 II.4% (NH^SO, Mertanol 7D 19 . 20% neutral pH 6-8 1.23 1.24 18.8%(NH4),SO Inorganic salt crystallizes out at temperatures below 40 F. K.K. Classification! Liquid Tanning Extract NOIBN. General Information! Mertanol is a synthetic tanning agent consisting of a naptbalene sulfonic acid condensation product in liquid form. The free sulfuric acid acidity has been completely neutralized and the sulfonic acidity neutralized to a definite acidity. I'sed in the manufacture of leather for bleaching of chrome tanned leather, bleaching base stock for making pastel leathers, for preplanning pickled stock before regular tan in order to maintain a lighter colored leather throughout the tannage, in vegetable tanning as sn aid to penetration of the extracts and solubil* ization of non.tans, in dyeing to give even dyeing and increased penetrstion of (he dye, and as a mordant to hasten dyeing of chrome tanned and untanned leathers. "MERTEC" (Corrosion-Resistant Paint) __ _________________ Mertec is a corrosion-resistant paint designed for use as a protective finish under severe acid and alkaline conditions. It is formulated on a chemically inert base and gives remarkable protection against acid fumes and caustic alkali attack. Mertec is primarily for use on metal, but tbe inert base makes it a practical finish for concrete. It may also be used on wood surfaces. It gives a tough, glossy, oil and water resistant finish. Fire resistance is excellent; tbe paint does not support flame travel. Heat resistance in continuous service is good up to about 200F. Mertec is supplied in gray, rust, black, white and clear. Coverage is about 300 sq. ft. per gal. Pigmented Mertec R-3311 Gray 859 has the most desirable general properties. It is flexible and adhere* well to almost any reasonably clean surface. It should cover satisfactorily in one coat, particularly the gray color which is recom mended for general mill use on exposed metal. Clear Mertec R-3300 is inferior to tbe pigmented type in weather resistance, (t is also slightly less effective as a protective coating, and is recommended only where a pigmented finish is impractical. In using Clear Mertec R-3300 as a vehicle for aluminum, use about 1% pounds Aluminum Powder per gal. A (Continued) 26TR edition Page 77 06B3817 TOWOLDMONOQ41901 ready mixed product, Aluminum Met tec R-3457, can be supplied. For outside exposure a prime coat of R-3137 Gray 326 is recommended. Clear Mertec Topcoat R-3311 is a special type for application over ordinary painted surfaces to give resistance to corrosion. Clear Mertec Topcoat also im> parts greater resistance to corrosion when used over the Pigmented Mertec, and is especially recommended for use over Clear Mertec R-3300. Pigmented Mertec R-3799 is a special type for concrete floors. No priming coats or special preparation of the surface is necessary other than cleaning off loose grit and dirt and any accumulation of oil and grease. The surface should preferably be dry but damp surface* can be successfully finished. From the standpoint of durability under traffic the concrete surface should be smooth. K.R. Classification! Lacquers. Available Literaturei Leaflet, "Maintenance Paints." META-CHLOROANILINE (See meta*Chloroaniline under C). META-CRESOL (See metaCreso! under C.) META-NITROCHLOROBEN/ENE (See meta*Nitrocblorobenzene under N). "METHASAN" (See Accelerators, Rubber). METHYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). METHYL PHTHALYL ETHYI, GLYCOLATE(SeeSanticizerM.17). METHYL SALICYLATE U.S.P. (See Salicylate*). MIXED ACID (See Nitrating Acid). MOLDING COMPOUNDS (Seo plastics). MOLD PASTE _____________ Specifications! Several materials blended to give a satisfactory combination of the properties necessary for use on molds for vulcanizing rubber. Light brown colored paste; sp. gr., 1.54. (Continued) Page 78 Monsanto chemicals 0663816 TOWOLDMONOQ41902 R.R. Classification: Chemicals NOIBN. Available Literature: 42-page booklet "Monsanto Chemicals for the Rubber Industry". MONOAMMONIUM PHOSPHATE(5ee Ammonium Phosphate, Mono). MONOCALCIUM PHOSPHATE (See Calcium Phosphate, Mono). MONOCHLOROBENZENE (See Chlorobenzene). MONOMAGNESIUM PHOSPHATE (See Magnesium Phosphate, Mono). MONSANTO PLASTICS (S,<e Plastics). "MONSANTO SALT" (orlho-Chloro-para-Toluene Sodium Sulfonate) ,______________________ (Also known as 3<hloro-4*njethyI benzene sodiumsulfonste). CH, Mol. Wt. 228.63 Characteristics: Light gray to light tan powder; aaaay (from Cl content), 97.0 100.5%; NaCI, 0.5% max.; n,<oiature (HjO), 1.0% max. R.R. Classification: Dye Intermediate. General Information: Used in dyestuff synthesis. MURIATIC ACID (Hydroch(oric)______________ HC1 Grades: 18 B<; 20* B; 22* BL Typical Analysis: 18* B*.. 27.9% HC1.; 20* B5., 31.5% HCI.; 22" B*., 35.2% HCI. R.R. Classification: Muriatic Acid General Information: Used extensively in the starch, glucose, steel, galvaniz ing, paper, leather and glass industries. (See table in general data section) 26th bdition Page 19 0683819 TOWOLDMONOQ41903 'NEALCO" ANTI-FREEZE General Information! A completely denatured ethyl alcohol type anti-freeze fluid for automobile, airplane and oiher gasoline engine cooling systems. Will not corrode the radiator, form rust, sludge or sediment; will not cause leaks nor attack hose connections. K.R. Classification i Anti-freeze Alcohol. NITRATE OF IRON, COPPERAS <S,,,, F.mc Sulf.t,). NITRATE OF IRON* TRUE (See Ferric Nitrate). NI ATING ACID (Mix ` Acid) -- Typ- <1 Analysis: Nitric Acid (HNOj) Sulphuric Acid (H*SO) Oxides of Nitrogen (NjOj) 80.15 80.0% 15.0% 0.25% 85-12 85.0% 12.0% 0.25% i8 60.0% 38.0% 0.25% 45*53 45.0% 53.0% 0.25% R.R. Classification: Nitrating Acid General Information: Mixed acid is used for nitrating in the chemical industry, particularly in the manufacture of explosives and dyestuffs. Special mixtures can be furnished to meet individual requirements. (See table in genera/ data section) NITRE CAKE (Sodium Bisulfate) Standard Format Bulk; ground; globular. Typical Analysisi 35% HjSOj available. R.R. Classification! Nitric Cake. General Informations Used to replace either sulfuric acid or combination of sulfuric acid and Glauber's salt. One hundred lbs. of Nitre Cake is approximately equivalent to 35 lbs. of o6 sulfuric acid and 141 Iba. of Glauber's salt. Used principally in viscose rayon spinning batbs; dyeing woolen goods; re fining nickel ores; manufacture of sulfate pulp; in tanneries for pickling, deliming and making one bath tan solutions; as an acid scour for household use; in agri culture for disinfecting soil; as a bowl cleaner in sanitary trade. Page 80 MONSANTO CHEMICALS 0683820 T NITRIC ACID HNOj Standard Forms! 36 B6., 38 Bt*., 40 Be., and 12 Bi. Typical Analysis! %HNOj: 36Btf.. 52.3: 388B.. 56.5: 408B#,, 61.4: 428B., 67.2. Sp. g. will not vary mors than 0.,5* terms of B. HjSO* 0.1% max.; HCI 0.1% max. For higher strengths refer to Merrimac Division Sales Office. R.R. Classification! Nitric Acid. General Information! Used in the manufacture of insecticides, dyestuffs, drugs, pharmaceuticals, explosive^, photo engravings, nitrates and other nitro products. (See table in general data section) NITRIC ACID C. P. UNO* Mol. Wt. 63.01 Typical Analysis! Colorless Iquid, free from suspended matter; strengthtHNOs), 70.0 to 71.5%; non-volatile matter, 0.0005% max.; sulphate (S04) 0.0002% max.; chloride (Cl), 0.00007% piax.: arsenic (As), 0.000003% max.; heavy metals (as lead), 0.0005% max.; heavy metals (as iron), 0.0001% max. R.R. Classification! Nitric Acid. General Information! Laboratoi-y reagent. l-NITRO-2, 5-DICHLOROBENZENE (Also known as 2, 5-dichloroQitrobenzene.) Mol. Wt. 192.01 Cl Standard Formi Fused solid. Specifications! Light yellow to light brown crystalline solid; crystallising point, 52.5eC. min. R.R. Classification! Dye Intermediate. General Information! Used as at> intermediate in the preparation of dyestuffs. CAUTION: This produet it toxic. Amid breathing its vapors and avoid contact with the skin. 2ATH EDITION Page 81 0683821 TOWOLDMONOQ41905 oreho-NITROANlLINE _ (Also known us ortAu.aminonitrobensene and I-aminn'2>nitrobenzene.) NH, Mol. Wt. 138.12 Standard Forms) Powder; powder with 0.5% triealrium phosphate. Specifications) Yellow to nrangt powder; m. p. 70.0C. min. Assay: powder, 98.70% min.; powder with triraMum phosphate, 98.50% min. Ash: powder, 0.25% max.; powder with trioalcium phosphate, 0.75% max. K.K. Classification: I)\e Intermediate. General Information) ortho.Nitroaniline powder has a tendency to "set up" in lumps on standing. It is recommended that it be milled to proper fineness just before using. The addition of 0.5% tricalcium phosphate reduces the caking tendency, ortho.Nitroaniline is used as an intermediate in the preparation of dyestuffs. CAUTION: This product is toxic. Avoid breathing its dust and avoid contact with the skin. para-NlTROANILINE NH, Mol. Wt. 138.12 NO, Standard'Form) Powder. Characteristics) Bright yellow crystalline powder; soluble in HC1; m. p. 148C. min.; assay 99% min. R.H. Classification) Dye Intermediate. "Poison" label required. General Information) Intermediate in dyestuff syntheses. CAUTION: ThU product is toxic. Avoid contact with tdcin. Avoid inhaling vapors. ortho- NITROANISOLE (Also known as ortha-aminoaniaole, ortAo-nitrophenylmetbylether and l*me thoxy ^.nitrobenzene. OCH, Mol. Wt. 153.14 Page 82 Standard Forms Liquid (Continued) MONSANTO CBS MIC A LS 0683822 Specifications! Light reddish or light amber liquid; crystallizing point, 9.6C. min., dry basis. Distillation range: first drop 270.0C. min.; 95% 2.08C. max.; dry point 273.0C. max. Nitropbeiiol 0.05% max. R.R. Classification! Dye Intermediate. General Information i ortAo-NitroanisoIe is used in the production of such dye intermediates as oriho-anisidine apd dianisidine. It is also used in various or ganic syntheses. CAUTION: This product it toxic. Avoid breathing its vapors and avoid contact with the skin. NITROCELLULOSE SOLUTIONS (See Cotton Solutions). meta-NITROGHLOROBENZENE ___________________ (Also known as meta-chloronitrobeneene and 1 cbloro-3-nitrobenzene.) NO Mol. Wt. 157.50 Standard Form i Fused solid Specifications! Greenish yellow crystalline mass; clear when melted; crystalliz ing point 43.9'C. min. R.R. Claaaificatiom Dye Intermediate. General Information! Used for tonversion into various dyestuff intermediates, cbloroanilinea and chlorobenzidines. CAUTION: This product is toxic. Avoid breathing its vapors. Avoid contact with the skin. ort/io-NITROCHLOROBENZENE ____________________ (Also known as ortAo-chlorooitrobenzene and 1-chioro-2-nitrobenzene.) Cl MoL Wt. 157.50 Standard Formi Fused solid Specifications! Greenish yellow crystalline mass; crystallizing point 31.7C. (on sample as received). R.R. Classificationi Dye InteruMtdiate. General Information! Used in the preparation of dyestuff intermediates. CAUTION} This material is toxic Avoid breathing its vapors. Avoid contact uziA the skin. 26TB EDITION Page 83 0683823 TOWOLDMONOQ41907 poro-NITROCHLOROBENZE-NE (Also known as ptfra-chloronitrobenzene and !-chloro>4-nitrobenzeDe.) NO* Mol. Wt. 157.56 Cl Standard Form: Fused solid Specifications: Light greenish yellow solid; crystallizing point 82.5C. min. R.R. Classification: Dye Intermediate. General Information: /wjra-Nitrotxnzene is used ia the preparation of dyestuff intermediates. CALT10S: This ptoduct is toxic. Avoid breathing Us vapors and avoid contact with the skin. ort/io-NITRODIPHENYU TECHNICAL NO* Mol. Wt. 199 Characteristics: Light yellow to reddish crystalline solid; crystallising point 34.5C. min. R.R. Classification: Dye Intermediate NOIBN. General Information: Used as an intermediate in chemical synthesis where it is useful in some applications as an alternate for substituted nitrobenzenea. May be partially reduced and rearranged to give 2,2'*dipbenyl benzidine (NHj-=l). "NITRON" (See Plastics). paro-NITROPHENOL (Also known as pora>hydroxynitrobenaene and 1-hydroxy*4-nttrobeniene.) OH Mol. Wt. 139.11 NO, Standard Form t Granules Specifications: Brown granular mass; m. p. (dry basis) 1I2.0C. min.; assay, 96.5% min.; water insoluble material 0.20% mas.; alcohol insoluble material 0.20% mas. (Cwirinnerf) Page 84 MONSANTO CHEMICALS 068382A R.R. Classification: Dye Intermediate. General Information: /wo*Nitrophenol has the following uses: as an inter* mediate in the production of dyestuffs and photographic chemicals such as para aminophenol and methyl para-aminophenol; as a fungicide to prevent mold growth on chrome tanned leather. C.4VT10N: This product is toxic. Avoid brrathinfi its dust or vapors and avoid contact with the skin. OIL ANTIOXIDANTS (See Stntolube). OIL OF VITRIOL (See Sulfuric Acid). OLEUM (See Sulfuric Acid). "OPALON" (See Plastics). ORTHO-AMINODIPHENYL (See ortho-Aminodipbenyl under A). ORTHO-ANISIDINE (See ortho-Anisidine under A). ORTHO-CHLOROANILINE (See ortho-Chloroaniline under C). ORTHO-CHLORO-PARA-TOtUENE-SODIUM-SULFONATE (See Monsanto Salt.). ORTHO-CHLOROPHENOL (See ortho-CUorophenol under C). ORTHO-CRESOL (See ortbo-Cw*ol under C). ORTHO-DICHLOROBENZENE TECHNICAL (See ortho-Dichlom. benteoe Technical under D). ORTHO-NITROANILINE (See ortho>Nitroawline under N). ORTHO-NITROANISOLE (See ortbo-Nitroanieole under N). 26TB bditio* Page BS 068362$ TOWOLDMONOQ41909 ORTHO-NITROCHLOROBENZENE (See ortbo-Nitrochloiobenxene under N). ORTHO-NITRODIPHENYL (See ortbo-N'itrodiphenyl under N). ORTHO-PHENETIDIN (See ortboPbenetidin under P). "OXYNONE" (See Antioxidants Rubber). PAINT, acid and alkali resistant (or plant maintenance; (See Mertec). PAINT ANTISKINNING MATERIALS, available to fit varied trade requirements; (See Santovar A). PAPER LACQUERS (See Lacquers). PARA-AMINODIPHENYL (See para-Aminodiphenyl under A). PARA-ANISIDINE (See para*Aniidine under A). PARA-CHLOROANILINE (See para-Chloroaniline under C). PARA-CHLORO-META-CRIESOL (See para-Cbloro-meta-Cresol under C). PARA-CHLORO-META-XY LENOL (See para-Chloro-meta-Xylenol under C). PARA-CHLOROPHENOL (See para-Cbloropbenol under C). PARA-CRESOL (See para-Cres>1 under C). PARA-NITROANILINE (See para-Nitroaniline under N) Page86 Monsanto chemicals 0603626 TOWOLDMONOQ41910 PARA-XITROCHLOROBEXZKXE (See para*i\itrochlorobenzene under N). PARA-XITROPHEXOL (See para>Nitrophenol under N). PARA-PHEXETIDIX (See para-Phenetidin under P). PARA-TOLLEXESLLFOXAMIDE (See pura-Tnluenesulfonamide under PARA-TOLL EXESULFOXCHLORIDE (See para-Toluenesulforw chloride under T). PEXETRATIXG AGEXTS (See Areskap, Aresket, Aresklene, Santoraeese). PEXTACHLOROPHEXOL (Se< Santophen 20 and PermasanJ. PERCHLORIDE OF IRON (S<e Ferric Chloride Solution). PERMAXOL" Gradeet Pertnanol; Permanol 7. Propertieei Viacoua liquid. Inorganic fait crystallize* out at temperatures below 40 F. R.R. Classification! Liquid Tanning Extract NOIBN. General Information! Permanol is *. synthetic tanning agent in liquid form. It has the special property of being extremely ligbtfast. Information on uses for Mertanol applies. See Mertanol. "PERMASAN" Characteristics! Consists of S% p<ntachlorophenol, min., 5% non-volatile solvent and 90% petroleum distillate; light amber color, less than 4.5 NPAS; characteristic petroleum odor; flash point, 140F. min. by Tagliabue closed cup method; ap.g. approx. 0.8785 at 1S.5C.; wt. per gal., 7.2 lbs. (Continued) 26TB COITION Page 87 0663827 TOWOLDMONOQ41911 R.R. Classification: Liquid Wood Preservative NOIBN. General Information: Used for preservation of wood against termites, Lyttus (powder-post) beetles, decay, and a wide range of other wood-attacking insects and organisms. Does not adversely affect the feel and appearance of wood, and surfaces properly treated may be satisfactorily glazed, painted or otherwise fin ished. Permasan conforms with th specifications of the Western Pine Associa tion's Bulletin No. 6 (revised) and is accepted by the National Door Manufact urers Association. Permasan is irritating to the skit! and mucous membranes if sufficient contact is permilled. The precautions for handling given in literature listed below should be observed. Available Literature: 6-page Monsanto Technical Bulletin 0-20, "Permasan for the Preservation of Seasoned Wood." 5-page Monsanto Technical Bulletin 0-14, "Permasan for Lyctus (Powdec-Post) Beetle Control." "PERMASAN 116" Characteristics: Consists of 5% pentachlorophenol, min., and 95% mixture of water repellents, organic solvents and diluents; light amber color, less than 4.5 NPAS; mild, not unpleasant odor; flash point, 1009F. min, by Tagliabue closed cup method; sp. g. approx. 0,855 at 15.5C.; wt. per gal., 7.13 lbs. R.R. Classification: Liquid Wood Preservative NOIBN. General Information: Used same as ordinary Permasan (see above) except gives added advantages of water repellency. Conforms with specifications of Western Pine Association's Bulleti:- No. 6 (revised). Permasan is irritating to the skip and mucous membranes if sufficient contact is permitted. The precautions for handling given in literature listed below should be observed. Available Literature: 8-page Monsanto Technical Bulletin 0-21, "Permasan 116 A Water-Repelleot Preservative for Wood." PETROLEUM CHEMICALS* (See Santolene, Santolubes, Santopoid, Santopour). PHENACETIN (See Acetopheuetidin). orf/io-PHENETIDIN _____ (Also known as ortfio-aminophenyktbylether, ort/io-aminophenetole, and 1-ami no-2-ethoxybenzene. (Continued) Page 88 Monsanto chimicals 0663828 TOWOLDMONOQ41912 OCjH, 0 NH* Mol. Wt. 137.18 Standard Form! Liquid Specifications! Dark red liquid: crystallizing point (as received) --4.09C. min. Distillation range: first drop 231.0'C. min.; 95% (1-96 ml.), 2.0C. max.; dry point. 234.0C. min. Solubility in I1CI, complete. K.K. Glassification: Dye Internudiate. General Information! ort/io>Phnetidin is used as an intermediate in the production of dyestuffs. CAUTION: This product is toxic. Avoid breathing its tupors and contact with the skin. pora-PHENETIDIN (Also knoton as para<aminophenylethylether.para-aminophenetole, and l>amino>4 etboxybenzene.) OCH Mol. Wt. 137.18 NHi Standard Form: Liquid Specifications! Dark red liquid; crystallizing point (as received) 4.09C. min. Distillation range: first drop 248.0C. min.; 95% (1*96 ml.), 2.0C. max.; dry point 251.0C. max. Solution in HO, opalescent. R.R. Classification; Dye Intermediate. General Information! poro-Phepetidin is used as an intermediate in the pro* duelion of dyestuffs and pharmaceuticals. CAUTION: This product it toxic. Avoid breathing its vapors and contact with the skin. PHENOL-FORMALDEHYDE RESIN (See Plastics. Resinox). PHENOLIC RESIN, CAST (See Plastics, Opalon). PHENOL________________ ___________________________ 26TH EDITION (Continued) Page 89 0683829 TOWOLDMONOQ41913 Standard Forms! Crystalline solid, U.S.P.; l:quid 85%; liquid 88%. Specifications of Crystalline Solid, U.S.P.! White crystalline solid; melt, colorless mobile liquid: solution in water (1:15), clear and colorless; non-volatile residue (lOC'C.). 0.04% max.; crystallizing point 40.0C. min. Distilling range: first drop, 180.0C. min.; 100% (first drop to dry point), 2.0C. max.; 50% to dry jvoint, 0.2C. max. Specifications of Liquids: Colorless mobile liquids. Assav: liquid 85%, 85.0. 80.0%; liquid 88%. 88.0 - 80.0%. ' R.R. Classification: Phenol. General Information: Used as an intermediate for the production of dyestuffs; in production of resins for molding and in the preparation of varnishes, enamels, lacquers and paints; as a selective solvent in the manufacture of lubricating oils; as a disinfectant; in textile printing; in the production of explosives, synthetic tanning materials, pharmaceuticals and medicinals, antiseptics, germicides and preservatives, deodorants, soaps, embalming fluid, vermin exterminators, rubber compounds, and photographic chemicals. PHENOLPHTHALEIN, U.S.P. OH OH Mol. Wt. 318.31 Standard Form: Powder. O Specification*: White powder; m.p. 259.0C. min.; solubility in alcohol (1:15), complete; acidity (cc's N/1000 NsOU/2 g. sample), 3.0 cc. max.; ash 0.05% max.; arsenic 0.001% max.; conforms to U.S.P. test for fluorine and heavy metals; trace max. retained on 100 mesh screen; 21.0% max. on 325 mesh screen. R.R. Classification: Chemicals NOIBN. General Information: Used in pharmaceutical preparations. PHENOLPHTHALEIN, YEI.LOW, Not U.S.P Standard Form! Powder. Specifications! Yellow powder; m.p. 257.0C. min.; loss on drying, 0.50% max.; ash, 0.10% max.; acidity (cc*s N/1000 sodium hydroxide per 2 gm. sample), 5.0 cc max.; solution in ethyl alcohol 95% (1:15), clear; sp. g. (apparent) 0.500 0.600; none retained on 20 mesh screen. (Continued) Page 90 MONSANTO chbmicals 0663630 TOWOLDMONOQ41914 K.K. Classification: Chemicals NOIBN. (General Information: Used in pharmaceutical preparations. PHENOL-FORMALDEHYDE (See Plastics, Resino* Molding Com* I.....mis). PHENYL SALICYLATE (See Salicylates). PHOSPHATES (See Ammonium Phosphate, Calcium Phosphate, Magnesium Phosphate, Potassium Phosphate, Sodium Phosphate) PHOSPHOLEUM (See Tetraphoephoric Acid). PHOSPHORIC ACID (Ortfcophosphoric Acid) HPO Mol. Wt. 98.004 Standard Forms: 50%, 75% and 85% HjPO^ Other concentrations supplied <m request. Specifications: Clear, water-white liquid miscible with water in all proportions. Grades: U.S.P.; food, meets all U.S. Pure Food Law requirements; commercial, clear water white liquid; Phoailage, meets ail U.S. Food Law requirements; special. U.H. Classification: Phosphoric Acid. General Information: Principal uses -- Ceramics; To increase translucency and improve the color of porcelain*; as a vitrifying agent and flux. Chemicals and Intermediates: In manufacture of sodium phosphates, calcium phos phates, and other phosphates; in manufacture of ethylene gas; in making albumen derivatives. As a drying agent in the synthesis of various intermediate chemicals. Dyes: As a drying agent in the synthesis of various dyes. Engraving: In pro cess engraving and litho trades. Envelopes: As a penetrant to aid in the ab sorption of the gum. Fertilizers: In manufacture of double and triple super phosphates; in manufacture of ammonium phosphate. Gelatin: Iq manufacture of gelatin. Glass: Aa opacifier. Jelly and Preserves: As a substitute for tar taric and citric acids. Metals: For pickling and cleaning. Pharmaceuticals: In manufacture of certain pharmaceutical chemicals; in making dental cements; in manufacture and purification of hydrogen peroxide; in manufacture of glycero phosphates. Rope and Ttvine: For brightening the finish. Rubber; As a coagulant of rubber latex. Rust Proofing: In the manufacture of rust proofing compounds. Silage: For silage pteservation. Soft drinks: As a substitute for (Continued) 16TB COITION Page 91 0683831 TOWOLDMONOQ41915 tartaric and citric acids. Sugar: As a defecating and clarifying agent. Textiles: In brightening the color of silk; in the dyeing of cotton; in calico printing. Water treatment: In water softening and correction of alkalinity. 15C. Density and Composition of water solutions of Orthophosphoric Acid (S' ~o -- Density Decrease g./cc. per 19C. %HjPO %PA %P MOO 0.00030 17.52 12.69 5.54 1.150 0.00035 25.25 18.29 7.98 1.200 1.250 1.300 1.339 1.350 1.400 1.450 0.00045 0.00050 0.00055 0.000S5 0.00060 0.00060 0.00060 32.52 39.22 45.51 50.00 51.22 56.85 62.27 23.55 28.41 32.96 36.21 37.10 41.17 45.10 10.28 12.40 14.39 15.81 16.19 17.97 19.68 1.500 0.00065 67.35 48.78 21.29 1.550 1.581 1.600 1.650 0.00070 0.00077 0.00075 0.00075 72.11 75.00 76.75 81.30 52.23 54.32 55.59 58.88 22,79 23.71 2 4.26 25.70 1.693 0.00080 85.00 61.56 26.87 1.700 0.00080 85.63 62.02 27.07 1.750 0.00080 89.88 65.10 28.41 1.800 0.00080 94.15 68.19 29.76 1.850 0.00080 98.13 71.07 31.02 1.874 0.00080 100.00 72.43 31.61 The density of more concentrated acic^s increases approximately linearly (within the range 72.44% to 85% PjOj) with the excess PjOj over 72.44% according to the equation: Dtosityi^-- 1.874 + 0.0171 <%P,0I -- 72.43). PHOSPHORIC ANHYDRIDE (See Phosphorus Pentoxide). PHOSPHORUS, ELEMENTA1 (Also known as yellow phosphorus and white phosphorus) Gradest Monsanto process of manufacture provides over 99.9% purity. Properties! Light yellow, waxdike, semi-transparent solid; burns spontaneously in air to form PtOi; m.p. 44.1C.; insoluble in water but very soluble in carbon bisulphide. K.R. Classification! Phosphorus, Yellow. General Information! Used in manufacture of phosphorus alloys, phosphoric anhydride, phosphorus compounds, phosphoric acid, rodent poisons, flares, smokescreens, etc. PHOSPHORUS OXYCHLORIDE _________ (Also known as phosphoryl chloride). POCU Mol. Wt. 153.35 (Continued) Page 92 MONSANTO CHEMICALS 0683832 TOWOLDMONOQ41916 Standard Forms Liquid. Specifications: Water-white to yeilow liquid; crystallizing point 0.8C. min.; assay 99.0% min. Distillation range: first drop, 106.0C. min,; 95% (1-96 ml.), l.5C. max.; dry point, 108.5C. max. PCIj, 0.20% max.; PClj, trace max.; HjPCV 0.30% max.; HCI, 0.50% max.; free chlorine, trace max.; iron, 0.0005% max. R.R. Classification: Phosphorus Oxychloride. General Information: Used as a chlorinating agent and catalyst in the prep aration of various intermediates end dyestuffs and as a reagent in the prepara tion of acetic anhydride and organic phosphates. CACTIOS: Care must be ex ercised in handling this product. Avoid breathing its vapors; avoid contort with the skin. It reacts tvith water with explosive violence. PHOSPHORUS PENTOXIDE.._____________ (Also known as phosphoric anhydride; phosphoric oxide; solid P,0,.) P,0, Mol. Wt. 141.96 Standard Formt White amorphous powder. Characteristics: Vapor Pressures: (after J. C. Southard and R. A. Nelson--J.A.C.S. 59. 911 (1937) p = vapor pressure in cm. of mercury. T absolute Temperature). A (low temperature form) Logiof = 9.792--(5000/T) B (high temperature form) Logtop ** 11.113--(7930/7') L (liquid) Logiop = 6.809--(4320/7") Atmospheric sublimation temperat ure: 358.9C. Heat of vaporization: A--22,800 calories per gm. molecule. B--36,200 calories per gm. molecule. L--19,700 calories per gm. molecule. Heat of fusion: 16,500 calories pet gm. molecule. Probable molecular formula of va]or: P4O10. R.R. Classification: Phosphoric Anhydride. General Information: Used in the manufacture of organic and phosphorus compounds and as a cayalyst. It Is a vigorous drying and dehydrating agent. PHOSPHORUS TRICHLORIDE PCI, Mol. Wt. 137.35 Standard Form: Liquid. Specification#1 Water white liquid: sp. g. at 15.5/15.59C., 1.582-1.587. Dis> (Continued) 26TB EDITION Page 93 0663833 TOWOLDMONOQ41917 tilling range: first drop ,71.5'C. min.; d*y point. 79.0C. max.; total range. 3.0C. K.K. Classification] Phosphorous Trichloride. General Information! Used as a chlorinating agent and catalyst in the prep* aration of various intermediates and dvesluffs; as a reagent in the preparation <>f acetic anhydride and organic phosphates; in the manufacture of phosphorus oxychloride and phosphorus pentachlotide; and in producing iridescent metallic deposits. C. 4 {.'770 V: Care must be exercised in handling this product. Rearts ti ith tuner. .4mid breathing its vapors; avoid contact with the skin. PHTHALIC ANHYDRIDE Cradesi Three grades with crystallizing points of 131.2C,, 131.0C., and 130.7C respectively. Specifications: White flakes; solution in benzene (1:20) clear; ash 0.03% max. Maleic acid: 131.2C., 0.10% max.; 131.0C., 0.15% max.; 130.7C.* 0.15% max. R.R. Classification! Phthaiic Anhydride. Genera) Information: Uses; As an intermediate in the production of dyestuffs, perfume bases, alcohol denaturants, pharmaceutical products, plasticizers--such as dibutyl phthalate, dimethyl pbthalate, diethyl pbthalate, phtbalyl glycollates --and alkyd resins. PHTHALYL CHLORIDE Mol. Wt. 203.03 Standard Form! Liquid, Characteristics> Yellowish liquid; assay, 95.0% min.; crystallizing point, 7.5C. R.R. Classificationt Chemicals NOIBN. Corrosive liquid (white label required). General Information! Used in the manufacture of plasticizers sod resins. PICKLER'S ACID (See Inhibited Acid). Page 94 MONSANTO CHEMICALS 0683634 TOWOLDMONOQ41918 PIPERIDINE ________________ ;____ (Also known as hexahydropyridine). Mol. Wt. 85.14 Standard Form: Liquid Specifications! Clear, water-whits liquid of characteristic odor; assay, 98% min.; p\ridine, 1.0% max.; sp. g. 25/25'C., 0.860 0.003. Distillation range; 104.0CC. min. start; 107.0C. max. dry point. It.It. Classification: Chemicals NOIBN. General Information: Used as an intermediate in the manufacture of phar maceuticals, wetting agents, and getmicides. "PIP-PIP" (See Accelerators, Rubber). PLASTICIZERS (See Santicizrrs, Dibutyl Pbthalate, Diethyl Phtbalate, Dimethyl Pbthalate, Diphenyl Phtbalate, Tricreeyl Phosphate, Triphenyl Phosphate). PLASTICS (See individual materials below.) p-- CAST PHENOLIC (See Plastic*, Opalon). CELLULOSE ACETATE (See Plastics, Fibestoa). CELLULOSE NITRATE (See Plastics, Nitron). "FIBESTOS"* (Cellulose Acetate) The most widely-used thermoplastic, cellulose acetate, is distinguished by a flexible range of properties and formulations. In the form of molding compounds, Fibestos is adapted to either compression or injection molding. Sheets, rods, tubes and continuous length roils ate other forms in which it is produced by Monsanto. Mechanical Properties > Specific gravity....................................................................... 1.27 1.37 Specific volume, cubic inches per pound..................... 20.2 21.8 (Continued) 26th edition Page 95 PLASTICS 0683835 J TOWOLDMONOQ41919 PLASTICS Kefraetive index .......................................................... 1.17 1.50 Tensile strength, Ib.-*., sq.in...................... . 5.500 11.000 Klongation, percent .............................................. . .5-55 llursiing strength (rupture) lbs. q.in., mil.. . . 13 35 Modulus of elasticity, -q.in x 105......................... I -3.5 Impart strength, 1/n.l, fi. lbs., in. of note! (VS.T.M.) ............................................................... 0.7 - \:1 Itrini-ll hardness, 2.5 nun. ball 10 kg. load . . . .0 . 15 Porkwell hardness .............................. ................................ M25 M55 M aeli in in;: qualities................................................................<h>d Molding Properties: 1 vpe............................................................................................ Thermoplastic Molding qualities.................................................................. I'Arellent Molding 1 emperatnre F. ( aiilipressinii............................................................... 210 - 350 Injection.......................................................................300 I 10 Molding Pressure lbs. sip in. Compression............................................................... 500 - 5000 Injection............................................... . . .3000 - 30000 Preformin'!........................................................... . Very good Tendency to cold Don .......................................... .Slight Processing cellulose at Springfield plant for manufacture of Monsanto plastics. 0683836 TOWOLDMONOQ41920 Molding methods applicable............................................. Compression, injection, trillion, sh aging Mold shrinkage, inches/nch: Povtive........................... 002 .003 Sepii-positive............... 005 .007 Flash............................... 008 .009 Extruding quality.................................................................. Excellent ei* Thermal Properties: Horning rate, in. min. (.060') ....................................... 1.5 2.0 Slow burning Thermal conductivity, 10--* calo'ies/sec,/sq.cm./ C. cm.........................................................................4.5 7.8 Specific heat, calories/C. 'gram...................................... 0.3 0.4 Thermal expansion, 10--5 C............................................10 16 Resistance to heat, F. (continuous).............................140 250 Softening point. F.................................................................140 260 Effect of heat, dry ............................................................. Little or none moist.............................................................Slight swelling Heat distortion, F. (A.S.T.M.)......................................122-212 Electrical Properties: \ nlume resistivitv, ohms-cms. (59%R.H. and 25C.). . ..................................................................(0.7 1.4)xl0> Breakdown voltage, 60 eyries volts mil.......................600 1.800 Dielectric constant, 60 cycles........................................... 3.5 - 7.5 10* cycles......................................... 2.0 5.0 Power factor, 60 cvcles ..................................................... 0.007 0.07 10 cycles......................................................0.007 - 0.03 Chemical and Physical Propet ties: Odor.............................................................. .... Taste.................................................................. Effect of age.................................................... Effect of sunlight ........................................ Effect of ultraviolet light.......................... Effect of metal inserts................................ Effect of weak mineral acids................... Effect of strong acids.................................. Effect of weak alkalis ............................... Effect of strong alkalis ............................. Water absorption 24 hours....................... Solubility: Softens in-- ........................ Swells in-- .......................... Insoluble in--.......................... None to mild aromatic None Slight Gradually become brittle-- some colors fade Gradually become brittle-- some colors fade. None Fair resistance Decomposes Slight Decomposes 1.5-3% Alcohols, esters Chlorinated hydrocarbons Aromatic and aliphatic hy drocarbons, animal, mineral, and vegetable oils, ethers Colon Available in an extremely wide variety of transparent, translucent, pastel and opaque colors, at well as in many mottles, pearls and decorative configurations. Forme: Sheets, rods, tubes and molding compounds. Trade Mark Reg. U. S. Pat. Ofl. 26TH EDITION Page 97 0663837 TOWOLDMONOQ41921 PLASTICS- T "LL'STRO.N"* (Polystyrene Molding Compounds) Lustron is Monsanto's formulation of polystyrene molding compound. Tbe rapid expansion of uses for Lustron since its introduction in 1939 is excellent proof of its versatility and broad range of useful properties. It is unexcelled among thermoplastics for electrical characteristics, chemical resistance, low moisture absorption and dimensional stability as the following table of properties indicates. Molding quality .................................................................... Excellent Coniprosion molding temperature, F...................... 275 350 Compression molding pressure, Ibs./sq.in.................... 1000 5000 Injection molding temperature, F.................................300 500 Injection molding pressure, Ibs./sq.in........................... 10.000 and up Compression ratio................................................................ 2.0 2.3 Mold shrinkage....................................................................... Compression 0.002 0.005 in. per in. Injection 0.002 0.008 in. per in. Specific gravity ................................................................ 1.054 1.070 Specific volume, cu.in./lb.................................................. 26.3 25.9 Refractive index ................................................................1.59 Tensile strength, lbs., sq. in................................................5000 9000 Elongation, %.................................................................. . . . 2 5 Modulus of elasticity, in tension, lbs./sq in.............. 1.7 2-6 x 10s Compressive strength, lbs. sq. in.................................... 11.500 13.500 Flexural strength, lbs./sq. in............................................. 14.000 19,000 Impact strength, Izod, ft. Ibs./in. of not< h (A.S.T. M.)..................................................................0.35 0.50 ft.Ibs./in. of notch Brinell hardness (2.5mm bail, 25kg. load)................. 20 30 Rockwell hardness.................................................................M87 M90 Light transmission, % ..................................................88 90 Thermal conductivity, cal./sec./sq.cm./C./cm. 1.9 x 10--4 Specific heat, cal./"C./gram ........................................ 0.32 Thermal expansion, C........................................................(6 8) x 10-* Softening point, F................................................................ 190 230 Distortion under beat, F. (A.S.T.M.) ................... 170 180 Tendency to cold flow .................................................... Slight Volume resistivity, ohm*cins. (50% R. H. and 25C.)................................................................................ 10*t . iot Dieletric strength, short time, V3 in. thickness volts/mil.......................................................................500 700 Dielectric constant, 60 cycles.................................... .. 2.5 2.6 Dielectric constant, 10s cycles.........................................2.5- 2.6 Dielectric constant, 10* cycles.........................................2.5 2.6 Power factor 60 cycles......................................................... 0.0001 0.0002 Power factor 10* cycles.......................................................0.0001 0.0002 Power factor 10* cycles.......................................................0.0001 0.0004 Water absorption, immersion 24 brs..............................0.00 Burning rate............................................................................. Moderate Effect of age..............................................................................Very slight Effect of sunlight.................................................................. Yellows slightly Effect of weak acida and strong acids...........................None Effect of weak alkalis and strong alkalis.................... None Effect of organic solvents....................................................Soluble in aromatic and chlorinated hydrocarbons Machining qualities............................................................... Fair to good (Continued) Page 98 MONSANTO CHE MIC A I r 0663638 TOWOLDMONOQ41922 P L A S T IC S Color possibilities Effect od metal inserts Unlimited .None Available Literature: 16-page booklet "Lustron--A Monsanto Plastic." Trade Mark Reg. U. S. Pat. Off. "NITRON"* (Cellulose Nitrate Sheets, Rods, Tubes)______ Nitron is a cellulose nitrate plas;:ic which continues as the most suitable material for many exacting uses such as drawing instruments, fountain pens, tool bandies, tooth brush handles, heel coverings, watch and instrument crystals. The raoge of colors and special effects obtainable in Nitron plastics is unlimited. It is easy to fabricate and can be molded, drawn, or blown. Mechanical Properties: Specific gravity........................................................................1.35 1.40 Specific volume, cu.in./lb.................................................... 19.8 20.5 Refractive index No ............................................................ 1.50 Ultimate tensile strength, Ibs./sq. in..............................5,000 10,000 Elongation, %..........................................................................10 > 40 Modulus of elasticity, intension Ibs./sq. in.................. 200,000- 400,000 Impact strength, Charpy, ft. lbs /in. of notch (A.S.T.M.)...................................................................3-12 Brinell hardness, 2.5 m.m. ball, 10 kg. load.................8 11 Rockwell hardness................................................................ M25 M60 Machining qualities............................................................... Very good Molding Properties: Typ............................................................................ Molding quality..................................................... Compression molding temperature................ Compression molding pressure, Ibs./sq. in. Preforming.............................................................. Tendency to cold flow......................................... Molding methods applicable............................. . Thermoplastic . Good . 185 250F. .100-500 .Very good . Slight . Swaging, shearing, blowing-- All very good Thermal Properties: Burning rate................................................... ....................... Rapid Thermal conductivity, B.T.U./br./sq. ft./F. temp. diff./in. thickness..................................................... 0.90-1.48 Specific beat, calories/C./gram............ ....................... 0.34 - 0.38 Thermal expansion, 10--*/F................... ....................... 6.5-8.9 Resistance to heat, F. (continuous).. ........................Approximately 140 Softening point, (A.S.T.M.) .............. ....................... 160 195F. Decomposes at 272F. in 30 minute* Effect of best, dry ..................................... ....................... Discolors on continued heat ing at 212F. Electrical Properties! Volume resistivity obms-cms. (50% R. H. and 25C.) ............................................................. (2-30) xl0* Dielectric strength, 60 cycles, volu/mil...................... 600 1,200 (Continued) 26TH EDITION Page 99 0663639 TOWOLDMONOQ41923 -P L A S T IC S Dielectric constant, 60 cycles.................. Dielectric constant, 10 cycles............... Power factor, 60 cycles.............................. Power factor, 10 cycles............................ Chemical and Physical Propertiesi <)dor................................................................... Taste.................................................................. Dffect of age................................................. . PfTcct of sunlight............................................ effect of ultraviolet tight........................ effect of weak mineral acids..................... effect of strong acids.................................... Effect of weak alkalis.................................... effect of strong alkalis................................. Water absorption 24 hours immersion . Effect of hot water......................................... effect of cold water........................................ Effect on metal inserts................................. Solubility! Soluble in................................. Insoluble in 6.T 7.3 6.2 0.06 0.15 .0.07-0.10 None or ramphorous Tasteless to slight .Slight hardening . Discolors and becomes brittle . \eiiows and decomposes on extended exposure .Good resistance . Poor resistance, decomposes . Very slowly decomposes . Decomposes .0.6 -2.0% Softens, slight shrinkage . None . N one . Alcohols, ketones, esters Aromatic and aliphatic hydrocarbons, mineral, animal and vegetable oils. Colon Available in an extremely wid< variety of transparent, crystal, translu. cent, pastel and opaque colors,, as well as in many mottles, pearls and ornamental configurations. Format Available in sheets, rods, tubs and special shapes. Trade Mark Reg. U. S. Pat. Off. "OPALONM* (Cast Phenol-Formaldehyde) A cast phenol.formaldehyde resin. Option is noted for its beauty and the ease with which it can be fabricated, together with the ability to take a high and lasting polish. Special shapes and castings can be produced with low investment in molds. The size of casting ranges fropi handles for brushes and razors to large parts for coin machine housings, and complete radio cabinets. Restrictions on raw materials now limit the use of Opalon to essential civilian needa and to military applications. Mechanical Properties! Specific gravity....................................................................... 1.27 1.32 Specific volume, cu. in./lb.................................................. 20.0 21.8 Refractive Index Np............................................................1.5 1.7 Tensile strength, lbe./sq.in................................................. 5,000 12.000 Elongation.................................................................................Very Slight Modulus of elasticity, lbs./sq.in.xl0........................... 5*15 Compressive strength, Ibs./sq.in..................................... 15,000 30,000 Impact strength, Izod ft. Ibs./in. of notch (A.S.T.M.) ....................................................................0.1 -0.4 Brineil hardness, 2.5 mm. ball, 25 kg. lead.............. 30 > 4S (Continued) Page 100 MONSANTO chemicals 0683840 Rockwell hardness............................................................... M80 M130 Machining qualities...............................................................Excellent Shrinkage, % ..........................................................................0*1 Molding Properties: Tvpe............................................................................................Thermosetting, non-moldable Thermal Properties: Burning rate........................................................................... Will not support combustion Thermal conductivity, 10""4 calorie^t/second/sq.cm C. cm........................................................................ 3*5 Specific heat, calories/C./gram......................................0.3 0.4 Thermal expansion, 10-5/C............................................2.8 Resistance to heat, F. (continous)............................... 160 Effect of heat, dry ............................................................... Hardens slowly moist............................................................. Whitens Heat distortion....................................................................... Above normal temperatures Electrical Properties: \ olume resistivity, obms-ctns. ($0% R.H. and 25C).............................................................................10 - 10H Dielectric constant, 60 cycles...........................................5-10 10 cycles.........................................5.0 7.0 Power factor, 60 cycles...................................................... 0.025 0.20 10 cycles.................................................... 0.005 0.08 10 cycles.................................................... 0.01 -0.045 Chemical and Physical Properties: Odor................................................................... Taste.................................................................. EfTect of age.................................................... Effect of sunlight......................................... Effect of ultraviolet light.......................... Effect of weak acids.................................... Effect of strong acids.................................. Effect of weak alkalis.................................. Effect of strong alkalis............................... Water absorption, 24 hours immersion Effect of hot water....................................... Effect of cold water..................................... Effect on metal inserts............................... Solubility: Insoluble in-- .......... .. . None None . Hardens slightly . Yellows slightly on exposure Some colored materials fade .Yellows slightly on exposure Some colored materials fade . None or slight . Decomposed by oxidizing acids. Reducing and organic acids have less effect .Slight to marked, depending on alkalinity . Decomposes .0.01 -0.5 . Softens and whitens . None .Inert . Most organic solvents, alco* hols, ketones, esters, aro matic and aliphatic hydro carbons, mineral, animal and vegetable oils Color: Available in an extremely wide variety of transparent, crystal, trans* lucent, pastel and opaque colors, as well as in many mottles and orna mental configurations. Form: Available in sheets, rods, tubes and a very extensive variety of cut shapes and objects. Trade Mark Reg. VS. Pat. Off 26TB EDITION Page 101 0663841 TOWOLDMONOQ41925 P L A S T IC S "RESINOX"* (Phenol Formaldehyde Molding Compounds). Over a period of years the range of Resinox molding materials has grown to encompass almost every important industrial demand. Shortages of metals and the extremely exacting requirements of the natioo's armed forces have stimulated the development of new types of Resinox materials having particularly high impact strengths. Since fillers vary I be properties of Resinox, the following table gives the range attained by the most common fillers of wood flour, cut fabric, cotton flock, mica and asbestos. Molding quality....................................... .............................. Fair-excellent Compression molding temperature, "F..........................290 400 Compression molding pressure, Ibs./sq.in.......... 2000 4500 Compression ratio (bulk factor)...................................... 2.02 10.0 Mold shrinkage. Inches per inch........................................004 .010 Specific gravity........................................................................ 1.34 1.75 Specific volume, cu. in./lb................................................... 13.3 22.2 Tensile strength, Ibs./sq. in................................................ 4200 9500 Modulus of elasticity, Ibs./sq. in x 10*........................8-45 Compressive strength, Ibs./sq.in...................................... 20,000 35,000 Flexural strength Ibs./sq. in...............................................8,000 - 15,000 Impact strength, ft. lbs./in. of notch, Izod (A.S.T.M.).................................................................. 0.26-4.00 Rockwell hardness.................................................................. M85 M125 Thermal conductivity, 10--* cal./sec./sq.cm./C./ cm................................................................................... 3 * 20 Specific heat, cal/C./gram............................................... 0.25 0.36 Thermal expansion, 10-- */8C......................................... 2.0 7.5 Resistance to heat 8F. (continuous).............................. 225 450 Softening point, F.................................................................None Distortion under heat F..................................................... 240 285 Tendency to cold flow..........................................................None Volume resistivitv, ohm-cma. (50% R. H. and 258C.)......................................... 10 - 10> * Dielectric strength, short time, volts/mil, Y% in. thickness..........................................................250 500 Dielectric strength, atep-hy-atep, volts/mil, Vi in. thickness..........................................................200 - 400 Dielectric constant, 60 cycle*........................................... 5-20 Dielectric constant, 10* cycles.........................................4-20 Dielectric constant, 10* cycles......................................... 4.5 20 Power factor 60 cycles......................................................... 0. 04- 0.30 Power factor 10* cycle*....................................................... 0.04 0.20 Power factor 10* cycles....................................................... 0.005 0.10 Water absorption, immersion 48 hours (%).............. 0. 01 1.5 Burning rate............................................................................. Very low Effect of age..............................................................................None Effect of sunlight....................................................................Light shades discolor Effect of weak acids.............................................................. None to slight Effect of strong acids............................................................Decomposed by oxidising acids Effect of weak alkalis ......................................................... Slight to marked Effect of strong alkalis.......................................................Decomposes Effect of organic solvents................................................... None on bleed-proof materials (Continued) Page 102 MON3. NTO CHEMICALS 06B3B`i2 TOWOLDMONOQ41926 P L A S T IC S Machining qualities.......... ................................................... Fair Color range...................................................................... Limited Available Literature: 12-page booklet "Resinox--A Monsanto Plastic." Trade Mark Reg. U. S. Pat. Off. "SAFLEX"* (Laminating Plastic)______________________ _ Saflex is a polyvinyl acetal sheet plastic used as the interlayer in making "HiTest" laminated safety glass. The Saflex plastic 6heet, .01$ gauge, acts as the bonding agent holding the two sheets of glass firmly together and prevents scattering of the glass in case one or both surfaces of the glass are broken. The tough, elastic Saflex interlayer gives full protection at all temperature ranges encountered in winter or summer driv ing. For military vehicles and aircraft, multiple-layer laminations of Saflex and glass give protection against small-caliber bullets, bomb or shell fragments and flying debris. Trade Mark Reg. U. S. Pat. Off "VUELITE"* (Embossed Fluorescent Lighting Shields)_____ Vuelite is the trade name for embossed cellulose acetate, developed by Monsanto to serve as diffusing panels for fluorescent lighting fixtures. Glare and brightness are eliminated by a suitable design that spreads the light evenly. The excellent light transmission factor of the material assures highly efficient light distribution. Although s fluorescent fixture m*y be Urge in site, the addition of a Vuelite diffusing panel adds very little to its weight thereby allowing the design of a lowweight fixture. The danger of breakage of Vuelite as compared with glass of the same size is very small. Vuelite is easily formed to shape Fixtures that require more than a six-inch radius are fitted with diffusing panels by slipping flat sheets into position. Smaller sizes and intricate shapes are formed without expensive molds or tools while punching, drilling aod cutting opeiations are carried out with ordinary tools. Vuelite sheets are 20'x SO' in size, available in the following designs: Number 4B 6B 8B 9B 20B 27B 42B 44B Name "H'* Line Whipcord Silk Cobra Large Cube Mesh Axtee Glow Worm Limiting Gauge Not Under .050* .040' .030' .050' .030' .030' .040' .040' (Continued) Direction of Size Design 20x47 Lengthwise 20x47 Lengthwise 20x49 Lengthwise 20x47 Lengthwise 20x47 Both ways 20x49 Lengthwise 20x49 Crosswise 20x49 Lengthwise 26TB BDITION Page 103 0683843 TOWOLDMONOQ41927 PLASTICS 54B 55B 65B Sahara No. 5174 Large Crackle .050' .050' .040' Trade Mark Reg. L\ S. Pat. Off. 20*47 20*47 20*49 Both nays Both ways Both ways "VUEPAK"* (Rigid Transparent Packaging Material) ______ Vuepak is produced as a clear transparent sheet plastic in continuous length rolls HI'o inches wide. It is extensively used in the manufacture of durable rigid transparent containers, packages and displays for all types of consumer goods products. Originally used chiefly for luxury items. Vuepak containers have now become a successful packaging medium for food products, candies, household appliances, beverages and dry bulk products of all types. An im* portant contributing factor to the broader use of Vuepak containers has been the improved efficiency of fabricating equipment and techniques in the plants of the more than two hundred firms oiw established as Vuepak fabricators. The properties of Vuepak are covered by the properties of Fibestos cellulose acetate materials in the preceding table. Standard gauges of Vuepak are .005', .0075', .010', .0125'. .015' and .020'. In addition to continuous length rolls, Vuepak is sold in standard size sheets or in pieces cut to order. Vuepak can be drawn, scored, beaded, folded or stitched. With suitable Inlca the surface of Vuepak can be readily piinted in one or more colors. For special requirements Vuepak containers can be made with metal bottoms and lids or in combinations with box-board, paper, wire frames or wood. J-- `Trade Mark Reg. U. S. Pat. Off. POLYSTYRENE (See Plastica, Lustron). POLYVINYL ACETAL SHllET (See Plastics, Salfex). POTASSIUM AMMONIUM PHOSPHATE (Also known as potassium ammonium phosphate; ammonium potassium phos phate.) KNH4H4(P04), Mol. Wt. 251.128 Standard Forms White crystals. Grade i Technical crystals. Page 104 (Continued) MONSANTO CHEMICALS 06838't't TOWOLDMONOQ41928 R.R. Classification: Potassium Salts NOIBN. General Information: Used in pharmaceutical products for special medicinal purposes, and in the fermentatioi of *ines. POTASSIUM AMYL XANTHATE It.It. Classifiestion: Potassium \amhate. General Information: Flotation agent used principally in the mining industry. POTASSIUM ETHYL XANTHATE R.R. Classification: Potassium Xantbate. General Information: Flotation agent used principally in the mining industry. POTASSIUM GLYCEROPHOSPHATE (75% SOLUTION) (See Glycerophosphates). POTASSIUM PHOSPHATE, DI _ KiHPO, Mol. Wt. 171.18 Standard Form: 60% solution in water. Typical Analysis: Bluish, odorless liquid: sp.g. 1.7 at 25C.; 14.6 lbs. per gal.; pH 9.9 10.3: viscosity 33 centipoises at 25C.; water solubility 71 grams per 100 gms. solution. R.R. Classification: Chemicals, NOIBN. General Information: Used as a.a antistatic agent for wool and in fermentation and nutrient solutions. POTASSIUM PHOSPHATE, MONO (Also known as potassium diphosphate and potassium biphosphate). KH,P04 Mol. Wt. 136.09 Standard Form: White crystals. Grades: Technical containing about 0.50% SOj; sulfate*free containing about 0.01% SO,. (Continued) 26TB EDITION Page 105 0663645 TOWOLDMONOQ41929 T R.R. Classificationt Potassium Salts. General Information: Used to control pH of culture media and for special medicinal purposes. POTASSIUM PYROPHOSPHATE, TETRA K4P20, Mol. Wi. 330.34 Properties: White powder, hygroscopic in air: pH value in 1% solution at 25 '( 10.6: solubility. 190 grams in 100 grrms water at 25C. R.R. Classification: Cleaning Com|<ound. General Information: Used for incorporation in textile oils and soaps to increase emulsifying values and to prevent formation of insoluble bard water soaps; ss clarifying agent and to improve cleansing action of soaps. POTASSIUM SALICYLATE (See Salicylates). n-PROPYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). PYRIDINE, pure waterwhite liquid; used as a solvent and chemical reagent,as a denaturant for alcohol, and in special medicinals; made by Monsanto Chem* irals Limited. PYROXYLIN CEMENTS (Set Celluloid Cements and Belt Cements). PYROCATECHOL ________ ________ _______________ (Also known as brenzcatechin, catechol or 1, 2*dihydroxy benzene). OH r >H Mol. Wt. 114.1 Specifications: Fine white needles (may contain a few dark specks); assay, 99.5% min.: odor, practically none; crystallizing point, 104.0C. min. Solution in cold water, (1:10): color, APHA 40,, max.; turbidity, essentially clear. Solution in alcohol (1:10): color, APHA 40, mac. K.R. Classification: Chemicals NOIBN. General Information: Used aa a developer in fur dyes, antioxidant in printing inks, and as intermediate in chemical synthesis. Page 106 MONSANTO CHBMICALS 06838*6 TOWOLDMONOQ41930 "R-2" CRYSTALS (See Accelerators, Rubber). REODORANTS, RUBBER Monsanto provides, but does not manufacture, the following types of rubber reodorants for the convenience of its customers. Curodex No. 19-- Pale yellow liquid; deodorizes: percent used in 100 lbs. of rubber, 0.15 - 0.20; standard package, 5 lb. bottle. Curodex No. 188--Pale yellow liquid: odor, lily; percent used in 100 lbs. of rubber, 0.20 0.50; standard package, 5 lb. bottle. (.urodex No. 198--Pale yellow liquid; odor, musk; percent used in 100 lbs. of rubber, 0.20 0.50; standard package, 5 lb. bottle. RESIN'S (See Santolites and Plastics). "RESINOX" (See under Plastics). RUBBER LACQUERS (See Lacquers). "SACCHARIN MONSANTO" Saccharin Monsanto is available in the so-called insoluble form (complies with L.S.P. requirements for Saccharin) and in the soluble or sodium form (complies with L.S.P. requirements for Saccharin, Sodium). Descriptions of both forms are given below. SACCHARIN, U.S.P_____ __________________________________ (Also known as saccharin insoluble; ortho-sulfobenzimide). O-L NH V 0, Standard Form t Powder Mol. Wt. 183.11 Specification*! White crystalline powder: assay 98% min.; m.p. 227.0C. min.; loss of drying 0.50% max., solubility in 10% NajCOj(l:5) complete. R.R. Classification t Chemicals NOIBN. General Information! Saccharin has approximately 500 times the sweetening power of sugar. Used as a sweetener in tooth pastes, mouth washes, and phar maceutical preparations, and in beverages and foodstuffs in place of sugar for diabetics. 2ATR EDITION Page 107 0683847 TOWOLDMONOQ41931 SACCHARIN. SODIl'M, U.S.P. (Also known as soluble saccharin; sodium ortho-sulfobenzimide). [ '_C^NN,2H,0 v-f,r Mol. Wt. 211.13 Standard Format Crystals; powde-r. Specifications! %hite crystals or j-owder; solubility in water (1:8), complete. Loss on drying at I25C.: crystals U.0% rain. --14.35% max.; powder. 5.3% min. --S.8% max. H.K. Classification! Chemicals NOIBN. General Information! See under Saccharin, U.S.P. "SAFLEX" (See Plastics). SALICYLATE, AMMONIUM _ COONH* 0OH Mol. Wt. 155.08 Standard Formt Powder, 80 mesh. Specifications) White crystalline powder; assay, 98.0% min.; solubility in water (1:5), complete, colorless; solubility in ethyl alcohol 95% (1:15), complete; con* forms to N. F. test for heavy metals. No powder retained on 80 mesh screen. R.R. Classification! Chemicals NOIBN. General Information! Pharmaceutical product. SALICYLATE, CALCIUM _______________________________ Mol. Wt. 314.16 Standard Formi Powder. Specifications! Fine white powder; solubility in water (1:50), complete, colorless; free salicylic acid. 0.25% max.; conforms to U.S.P. test for heavy metala. R.R. Classification! Chemicals NOIBN. General Information! Pharmaceutical product. Page 108 Monsanto chemicals 0683848 TOWOLDMONOQ41932 Pilot plant operation at St. Louis plant. SALICYLATE, LITHIUM, N.F. ( \ COOLi U" Mol. Wt. 143.98 Standard Forms Powder. Specifications! White or slightly grayish powder; assay 98.5% min.; solubility in water (1:20), complete, colorless; conforms to N.F. test for heavy metals. R.R. Classifications Chemicals NOI6N. General Informations Phannaceutital product. SALICYLATE, MAGNESIUM coo O Mg OH I ------ 12 Mol. Wt. 298.54 Standard Form i Powder. Specifications! Fine white powder; solubility in water (1:10), complete; con forms to L'.S.P. test for heavy metals. R.R. Classifications Chemicals NOIBN. General Informations Pharmaceutical product. 26TR EDITION Page 109 06838<i9 TOWOLDMONOQ41933 SALICYLATE, METHYL, U.S.P. COOCH, OH Mol. Wt. 152.14 Standard Form: Liquid. Specifications: Clear, colorless liquid, assay 98.0% min.; solubility in 70% ethyl alrohol (1:7), complete; solubility in N KOH (1:10), complete; sp. g. 25/2S9C., 1.180 1.185; free phenols, 0.010% max.; conforms to U.S.P. test for heavy metals. II.R. Classification: Oil of Wintergreen. General Information: Used as a pharmaceutical product, as a flavoring agent in foodstuffs and beverages, and as an odorant in printing inks and insecticides SALICYLATE, PHENYL, U.S.P. (Salol) Mol. Wt. 214.21 Standard Forms: Crystals; powder, 80-mesh. Specifications: White crystals or powder; solubility in ethyl alcohol 95% (1:6), complete; m.p. 41.0C. min.; conform^ to U.S.P. tests for chloride, sulfate, free acid, free phenol, and free salicylic acid . 1.0% max. retained on 80 mesh screen. H.R. Classification: Chemicals NOWN. General Information: Pharmaceutical product. SALICYLATE, POTASSIUM. f \ COOK JoH Mol. Wt. 176.21 Standard Form: Powder. Specifications: White or very slightly pinkish powder; assay (dry basis), 99.0% min.; solubility in water (1:10), complete; conforms to U.S.P. test for heavy metals; free alkali, negative. K.R. Classification: Chemicals NOIRN. General Information: Pharmaceutical product. Page 110 MONSANTO CHEMICALS 0683850 TOWOLDMONOQ41934 SALICYLATE, SODIUM, U.S.P. COONa OOH Mol. Wt. 160.11 Standard Forms: Powder, crystals. Specifications: White powder or crystals; assay (as received) 90.S% min.: solubility in \ater (10:100), complete, APHA 15 max.: solubility in ethyl alcohol 05% (1:10), complete, colorless; conforms to U.S.P. tests for heavy metals and rarbonizable impurities: trace msx. ponder retained on 60 mesh screen, 1.0% on 80 mesh screen, 2.0% on 100 tnesb screen. R.R. Classification: Sodium Salts. General Information: Pharmaceutical product. SALICYLATE STRONTIUM, N.F.-_______________ Sr . 2H.0 M"l- 7.74 Standard Form: Powder. Specificationai White crystalline powder; assay (as dihydrate), 99.0% min.; solution in water (1:20), complete; conforms to N.F. test for heavy metals and barium. R.R. Claaaificatlon: Chemicals NOIBN. SALICYLIC ACID, (OrthoHydroxybenzoic Acid). COOH OH Mol. Wt. 138.05 Grades: U.S.P. and "B" Grade. Specificationa of U.S.P. Grade: White needle* or powder, 100-mesh; assay 99.5% min.; m.p. 158.0eC. min.; conforms to U.S.P. test for carbonizable sub stances; asb 0.05% max.; powder trace, max. retained on 100-mesb screen. Specifications of "Bf* Grade: White needles; assay 98.75% min.; m.p. 158.0C. at start. (Continued) 26TB EDITION Page 111 0683051 R.R. Classification: Salicylic Acid. General Information: Used in the manufacture of medicinal* and dyestuffs, as an industrial preservative and as an intermediate in many organic syntheses. SALOL (See Salicylate, Phenyl). SALT CAKE (Sodium Sulfate, Technical) Na,SO Typical Analysis! 94 - 95% NajSO* available. R.R. Classification! Salt Cake. General Information: Used in (he manufacture of sulfate pulp, glass, sodium sulfide, and for treatment of boilei feedwaters. "SANTAMINE"_____ Characteristics: White powder, readily soluble in water, will not decompose on standing if kept in clean dry place. R.R. Classification: Disinfectant Other Than Medicinal NOIBN. General Information: Santamme ia a sterilizing and deodorizing agent de veloped especially for the dairy industry, where it ia used in water solution for washing utensils, equipment and bottles as well as the udders and teats of the cows. It also finds use in other industries where ao efficient chemical sterilizing agent ia required. It contains no poison or acid and will not barm rubber or metal. "SANTICIZER 8" ______ ______________________________ ___ (Mixture of ortho and poro*toluene ethyl sulfonamides). OH y-------\ II I CH,-< >-S-N- -------- / II O CH, Mol. Wt.199.26 Specifications: Light yellow, visxms liquid; odor, slight, characteristic; free amide, 9% to 13%; acidity (at acetic acid) 0.1% max. R.R. Clasaificatlom Lacquer Solvents NOIBN. General Information! This plasticizer is readily miscible with all common organic solvents except the petroleum hydrocarbons in whirb it is only very 'Continued) Page 112 MONSANTO CHEMICALS 0663652 TOWOLDMONOQ41936 slightly soluble. It is soluble in castor oil. sligbtlv soluble in china wood oil and insoluble in linseed oil. In water it is soluble to the extent of about 0.13% at 23C. and 0.21% at 430C. Its Bolubility in water is decreased by the presence of ammonia but is increased by other alkalies. Its retentivity in acetyl cellulose is about 90 parts by weight to 100 of acetate, and it imparts a high degree of plasticity. It is a solvent for both nitrocellulose and acetyl cellulose. Santirizer 8 is an excellent plasticizer for cellulose acetate, giving a brilliance and polish not obtainable with other plasticizers. This product, being practically insoluble in petroleum hydrocarbons, is a valuable plasticiser for coatings designed to withstand gasoline and related products. Santicizer 8 has some plasticizing action on such protein compounds as casein, glue, soybean protein and corn protein. It may be used alone or in conjunction with other materials such as glycerine or similar compounds. Santicizer 8 greatly increases the flexibility of ishellac, having at the same time a considerable softening effect. Available Literatures 40-page b\>oklet, "Plasticizers and Resins'*. "SANTICIZER 9" _____ ________ . (Mixture of ortho and para-tolueaesulfonamides) OH HI O-- S-N--H O Mol. Wt. 171.16 Specifications: Fine granular particles; m. p. 105C. min.; melt, clear and light vellow; acidity, pti 4.6 min. in dilute acetone (2 gram sample in IS cc A. R. Acetone and 35 cc of COj free diptiUed water). R.R. Classification: Lacquer Solvent NOIBN. General Information: Solubility of this plasticizer is quite low in coal-tar hydrocarbons and negligible in p<troleum hydrocarbons. It is readily soluble in most other solvents, and in bot linseed, china wood, and caster oils. It is soluble in water to the extent of only about 1.0% at 3-lC., but this is increased by the presence of alkali. It is the least soluble of the Monsanto plasticizers in ethylene dichloride and in benzene, its solubility in ethylene dicbloride being about 4% at 30C. and in benzene about 1.5% at 30C. Santicizer 9 differs greatly from other plasticizers in its action. Relatively small amounts impart a gloss to polished articles and give smooth working and uniform curing of molded products. It blends readily with most synthetic resins and does not impart the softening action of liquid plasticizers. It is particularly valuable to the makers of molding compositions. In some phenol-aldehyde resins it appears to act not only as a lubricant but also as a promoter, giving more uniform and thorough curing. In amounts of about 20 parts per 100, it has a temporary plasticizing action on protein compounds such as com protein and soybean protein. Available Literature: 40-page booklet, "Plasticizers and Resins'*. 26TH EDITION Page 113 0683053 TOWOLDMONOQ41937 "SANTICIZER E-15'1 (Ethyl Phthalyl Ethyl GlycoIIate)_____ 00 II II 0 -- C --0---CH* -- C --0--CH ----O --CjH* II U Mol. Wt. 280.13 Specifications: Color, (APHA), 20 max.; sp. g. at 25'725'C., 1.1800.005; refrac. index at 25C., 1.498 0,002; acidity (as acetic acid) 0.02% max.; odor, slight; sulfur (copper strip test), negative. It.lt. Classificationi Lacquer Solvent NOIBN. General Information; This plasticizer is miscible with the common organic solvents except the petroleum hydrocarbons. It is miscible with vegetable oils when heated but partially separates oih cooling. Its solubility in water is 0.0175% at 30C. Santicizer E-15 is a solvent for both nitrocellulose and acetyl cellulose mil for most resins. It is light-fast, and does not evaporate even from the thin nest films. With both acetyl and nitrocellulose it gives clear, tougb, flexible films which have greatly increased (esistance to moisture penetration. It is highly recommended for use with cellulose acetate and vinyl resins. Available Literature; 40-page booklet, "Plasticizers and Resins". "SANTICIZER B-16" (Butyl Phthalyl Butyl GlycoIIate)_____ OO -- C-O-CH; -- C-O-C.H, II O Mol. Wt. 336.19 Specifications; Color (APHA), 45 max.; sp. g. at 25*/25C., 1.0970.005; refrac. index at 25C., 1.490 0.002; acidity (as acetic acid) 0.02% max.; odor, essentially odorless; sulfur (copper strip test), negative. R.R. Classification i Lacquer Solved NOIBN. General Information; Santicizer B-16 is a practically colorless liquid plastic izer which boils at 219C. at S mm. a(td does not crystallize at temperatures as low as --35C. Its water solubility i(> 0.0012% at 30eC. It is extremely lightstable. It darkens upon heating abov< 290C. Sancticizer B-16 is a solvent for nitrocellulose and is compatible with most resin*, imparting good flexibility. It probably embodies more desirable properties {Continued) Page 114 MONSANTO CHEMICALS 068385A TOWOLDMONOQ41938 than any other single nitrocellulose plasticizers, lire retarding action being about the only property it does Dot have. Santicizer B-16 is a solvent for and imparts plasticity to many resins both synthetic and natural. It has especially interesting properties when used with resins of the glycerol-pbthalate and pheDol-aldcbyde types in which is may be incorporated at various stages of resin formation. It is miscible with castor, linseed and china wood oils and somewhat retards gel formation in the latter on heating, it swells crepe rubber but appears to have no effect on vulcanized rubber. It is an excellent plasticizer for chlorinated rubber, from 10 to 25 parts per 100 usually being required. It is an exceptionally good plasticizer for polystyrene. Mixtures of Santicizer B-16 and Santoilte resins may he used to plasticize casein and coi'n protein. Vtailahle Literature: 40-page booklet, "Plasticizers and Resins". "SANTICIZER M-17" (Methyl Phthalyi Ethyl Glycollate) _ OO o Specifications: Color, (APHA) JO max.; sp. g. at 25/25C., 1.220^0.005; refrac. index at 25C., 1.5040.00jj; acidity (as acetic acid) 0.02% max.; odor, slight characteristic; sulfur (coppet strip test), negative. K.R. Classification; Lacquer Sohent NOIBN. General Information: Santicizer M-17 is a solvent for both nitrocellulose and aretyl cellulose. It imparts a high degree of plasticity which is maintained undinmhed even in extremely thin films exposed to air currents for a long time. It is very light stable and may be used in transparent or tinted articles without danger of yellowing. This product is not miscible with castor, linseed, or china wood oils or with petroleum hydrocarbons but is readily miscible with other organic solvents. Its solubility in water is 0.09% at 30C. but it imparts a con siderable degree of resistance to moisture penetration to both nitrocellulose and acetyl cellulose films. Santicizer M-17 is probably th<: best cellulose acetate plasticizer available. It dissolves Santolite resins, and as both are very resistant to petroleum products and compatible with so many film-forming materials, they make an excellent combination for producing gasoline resistant coatings. Available Literature: 40 page booklet, ''Plasticizers and Resina". "SANTICIZER 127" (Butyl Benzene Sulfonamide). OH II I O Mol. Wt. 213.29 Continued) 26TB EDITION Page 115 0683855 TOWOLDMONOQ41939 Characteristics: Essentially colorless, oily liquid: crystallizing point --20C. (approx.): sp. g. 1.146 at 25V25C ; refrac. index 1.522 at 2SeC. R.R. Classification: Lacquer Solvents NOIBN. Ceneral Information! This plasticizer is almost identical in characteristics with Santicizer 8 for which it may be substituted in most formulations. It has slightly less solvent action, lower compatibility, and is less soluble in water (0.005% at 3lC.). When used with small amounts of active solvent plasticizers it produces hard but flexible and tough compositions. ``SANTICIZER 128" (Ethyl Benzene Sulfonamide). Mol. Wt. 185.25 O Characteristics: White crystalline solid; m. p. 51.9C.; sp.g., 1.208 at 60C. R.R. Classification*: Lacquer Solvents NOIBN. General Information: The plastici^iog properties of this product are of the same general character as Sancticizer It has less compatibility and should not be used in amounts greater than 50 parts by weight to 100 parts of base plastic. Its chief value is as an auxiliary plasticizer to be used with others in order to extend the supplies of less available materials and at the same time impart the properties of gloss, workability, etc., < haracteristic of the sulfonamide plasticizers. "SANTICIZER 129" (Benzene Sulfonamide) O Mol. Wt. 1S7.18 O Characteristics: White crystalline solid; crystallizing point 152C. R.R. Classification! Lacquer Solvents NOIBN. General Informations Santicizer 129 is similar in properties to its toluene analog, Santicizer 9. The principal difference U a slightly lower compatibility with most plastic materials. See Benzene Sulfonamide Technical for use where color ia not a factor. "SANTOBRITE" (Sodium Pentachlorophenate Technical)__ Standard Format Powder; 1-oz. briquettes. {Continued) Page 116 MONSANTO CHEMICALS 0683856 Characteristics: Brownish gray powder; non-volatile at ordinary temperatures; practically odorless; noa-hygros<opic under ordinary atmospheric conditions. Solubilities in water are: 4C. (395F.) 20.8% by weight; 25C. (77F.) 26.1% by weight; 35'C. (95F.) 28.0% by weight. Santobrite is a stable, relatively un. reactive chemical and is not spent on organic matter. Its water solutions do not attack metals and under ordinary conditions do not decompose to form acid materials. It can be supplied as substantially neutral material containing from <1.2 to 0.6% free alkali or as a more alkaline product containing 3 4% alkali. Conversion to pentachlorphenol o.'cure at pH's below 6.8. ICIC Classification: Agricultura Insecticide or Fungicide NOIBN. General Information: A water-soluble industrial preservative and fungicide. I sed for manufacture of termite-resistant cellulose insulating board and for control of microbiological activity m paper, paperboard, leather, adhesives, latex and cold water paints; for control of sap stain in green lumber; and for control of slime and algae in water systems where the water is not used for drinking or bathing. Santobrite and its solutions are irritating to the skins and mucous membranes of many individuals and are somtwbat toxic to man and the higher animals. For detailed information on usea and methods of handling, write for literature listed below. Available Literature: Technical Bulletin No. 0-1, "Santobrite for the Preservation of Adhesives." Technical Bulletin No. 0-2, "Santobrite and Santophen 20 for Paint Preser vation." Technical Bulletin No. 0-5, "Santobrite for Microorganism Control in the Pulp and Paper Industry". Technical Bulletin No. 0-15, "Santobrite for the Control of Slime and Algae." Technical Bulletin No. 0-17, "Santobrite for the Preservation of Rubber Latex." Technical Bulletin No. 0-19, "Santobrite in the Tanning Industry." Technical Bulletin No. 0-22, "Santobrite--Methods of Handling and Applica tion," "Sap Stain Control by Monsanto" (24 page booklet). "Preservation of Cellulose Insulating Materials by Monsanto" (24 page booklet). "Instructions for Handling Santobrite." "SANTOCEL" Standard Form: Light weight portus solid. Properties: Santocel is silica gel from which the water has been removed by a process which does not destroy the original gel structure. Apparent density 7.5 lbs. per cubic foot; bulking value in liquid 17.1 lbs. per gal. Typical Analysis: 16TB EDITION SiO, Volatile Sodium Sulfate FejOj and AljOj 90% 5.5% 3.5 1. (Continued) Page 117 06836$? Types: (1) Santocel 45, high oil ah&ttrbmg. (2) Santocel 58, low oil absorbing. (3) Santocel "O", designed lor use as a thermal insulator. All but Santocel "O'* are white and translucent. Grades: The three types are each available in two grades. Fine and All Sire. Thru 20 40 60 80 100 200 APPROXIMATE MESH Fine On Thru 20 mesh 7% 40 6% 3 60 12% 6 80 H% 10 100 9% 20 200 28% 40 27% 60 100 All Size On 3 : nesh 20.7% 6 20.7% 10 17.2% 20 H.7% 40 13.0% 60 4.2% 80 2.5% 7.0% R.R. Classificationt Insulating Ma erial NOIBN. General Information: Santocel 45 and Santocel 58 are used principally as (I) Flatting agents for paints, varnishes and lacquers. (2) Thickening :ents for volatile and nonvolatile liquids; particularly useful in printing ink' >) Anti* caking agents. (4) Dry dispersing agent for pigments and dyestuffs. (5 >urce of highly reactive silica. (6) Stiffening itgent in crepe rubber. Santocel "O" is designed for use as a thermal insulation material. "SANTOCHLOR" (para-Diohlorobenzene) (Also known as 1, 4-dichlorobenzene) Cl Mol. Wt. 147.00 Cl Characteristics: White crystals; crystallizing point, 52.8C. min. Standard Crystal Sices: No. 2. (large)--For shaker top cans. No. 5 (small)--For peach tree borers and for insecticide and miscellaneous uses. No. 34 (medium)--A combination of two uniformly sized crystals. For shaker top cans and for compressing into cakes. R.R. Classification: Paradichlorobetizene. General Information: Para-dichlorobenzene is used as an intermediate in (he production of dyestuffs; as a deodorant; mothicide, larvacide, and in control of peach tree borers. (Continued) Page 118 MONSANTO CHEMICALS 06838S8 Available Literature: 3 page Technical Bulletin No. 0*18, "Santochlor for the Control of Peach Tree and Stone Fruit Borers." 'SANTOCURE" (See under Accelerators) 'SANTOFLEX B*' (See under Antioxidants, Rubber), "SANTOFLEX BX" (See under Antioxidants. Rubber). "SANTOLITE BA" almost identical in properties with Santolite MS. of hich it is the benzene analog. SANTOLITE BH," almost identical in properties with Santolite MHP, of which it is the benzene analog. "SANTOLITE BK," almost identical in properties with Santolite K, of which it is the benzene analog. "SANTOLITE BK5" almost identical in properties with Santolite K3, of which it is the benzene analog. "SANTOLITE K" Specifications! Clear, light yellow sticky resin; color, not more than No. 2.5 by Monsanto Santolite K Standard (comparable in depth of color but not in shade to No. 5 of the Gardner 1933 standard); acid number, 10 max.; refractive index at 50C., 1.5330 to 1.5390. R.R. Classification! Synthetic Resin. General Information! Santolite K is a resinooa condensation product of toluene sulfonamide, formaldehyde , and alkyd resins. It is a soft aticky resin with the qualities of both the sulfonamide and alkyd types. It is compatible with cellulose esters and ethers. Santolite K hss plasticizing properties itself but for most purposes additional plasticiser is desirable and Santiciser M-17 is recom mended, although others may be ysed advantageously. Santolite & is soluble in practically all common organic solvents except the petroleum hydrocarbons. It is not compatible with drying oils so cannot be used in oil Tarnishes. Santolite K has s better light stability thin the other Santolites and is of special value for increasing the resistance to moisture penetration of cellulose ester compositions. Available Literature! 40-page b;xklet, "Plasticizers and Resina." 26TB EDITION Page 119 0663859 TOWOLDMONOQ41943 "SANTOLITE K5"___ General Information: A modification of Santolite K having the same general characteristics except that it is harder. "SANTOLITE MHP". Specifications! Hard, practically colorless resin: refractive index (25 grams in "> grams normal Hntyl Acetate), (.4280 to 1.4310; penetration, (200 gram load for 5 seconds at 25C.) 2.0 mm. max. K.K, Classification: Synthetic hesin. General Information: Santolite MHP is an aryl sulfonamide-formaldehyde resin and is similar to Saotolite VIS in characteristics, except that it is much harder, softening at about 62C. snd being brittle at normal temperatures. It is nearly colorless and is well adapted to specialty lacquers, fabric coatings, molding compositions and the like. Being incompatible with drying oils it cannot be used as a varnish material. Exceptional features of this resin are the ease with which it may be worked into practically any formula using a cellulose ester and the wide variation of properties obtained by its use. Its high degree of solubility makes very concen(rated solutions possible, and its extreme compatibility with plasticizers and cellulose esters removes much of the danger of blushing, sweating and separation. Santolite MHP can be used in spraying, dipping or brushing lacquers to make clear, colorless, odorless coatings of good gloss and adhesion. It doea not material ly increase the viscosity of the solution and permits the building up of a high solids content in the lacquer. It is compatible with all the common plasticizer*. Available Literature* 40-page booklet, "Plasticizers and Resins'*. "SANTOLITE MS" Standard Format Viscous Resin: Solution T.B. Specifications of Viscous Resin i Pale yellow viscous resin: solution in benzene (1:5), clear; solution in benzene (4:6), no crystalline deposit in 24 brs.; refractive index at 50SC., 1.5690 - 1.5720; color of benzene solution (25 gms. in 50 cc.). APHA 70 maximum. Specifications of Solution TBi Light colored, viscous liquid, free flowing at temperatures above 20C. Composition: 85% Santolite MS; 15% solvent (95% toluene and 5% butyl acetate), tolerance from 14 to 16% solvents; refractive index at 2SC., 1.563 0.002. R.R. Classification! Synthetic Resin. General Information! Santolite MS is a soft, practically colorless resin made (Continued) Page 120 S4VTO CHZMIC^L* 0683860 Looking down an aisle in one of the Monsanto warehouses. by the condensation of formaldehyde with aromatic sulfonamides. Like all the Santolites it is compatible with both nitrocellulose and acetyl cellulose and, being a solvent for both, it can b< used in any proportion. It forms brittle com* positions with both these esters but the addition of a plasticizer makes such combinations permanently flexible. It is readily miscible with all the common organic solvents and thinners except petroleum hydrocarbons. It is not miscible with varnish and paint oils. Santolite MS is excellent for water-white lacquers which will not be exposed to extreme weather conditions, its high gloss and lack of color being unusual in tbe resit: field. Available Literature! 40-page b>oklet, "Plasticizers and Resins." "SANTOMASK" Specifications! Clear, light yellow liquid; faint vanilla-like odor; sp. g. at 2572SC., 1.04- 1.06. Additional Properties! Flash point, 210F. (by Cleveland open cup method); flow point, below 0C.; lbs. per gal., 8.7. (Continued) 2 6TH EDITION Page 121 0683661 TOWOLDMONOQ41945 K.R. Classification: Chemicals NOIIiN. General Information! Odor-masking ingredient for interior paints, printing nks and similar products having objectionable natural odors. In addition to masking odors, may reduce or eliminate irritation to eyes, nose and throat caused by volatile components of some interior paints. Will not affect drying time, color durability and other characteristics of paints and inks. "SANTOMERSE" Standard Format The Santomerses are highly efficient surface active wetting agents and detergents. The Santoraerse series consists of six products. Each is distinctive in character and has been developed to meet a certain industrial need. Suntomerse D--neutral powder. SantomerseS--30% aqueous solution of Santomerse D. Santomerse No. 1--neutral flakes. Santomerse No. 2--alkaline flakes. Santomerse No. 3--neutral powder. Santomerse No. 3--paste (75% Santomerse No. 3 in water). R.R. Classificationt Washing Compound NOIBN. General Information! The Santomerses are the salts of a homologous series of substituted aromatic sulfonic acids. They are used as wetting, spreading, pene trating, emulsifying agents and detergents in the following industries: textile, paper, leather, adhesive, rubber, insecticide, dust collection, soap, cosmetic, ceramic, detergent, metal cleaning, plating, emulsions, dyes, pharmaceutical, embalming fluid, laundry, steel, paint, cement, glue, felt and color, etc. Available Literature: 32 page booklet 'Santomerse". . "SANTOPHEN 7" (ortho and pora-Bcnzyl Phenol.)________ Standard Forint Fused solid. Specifications! Light yellow, semi-crystalline mass: faint phenolic odor; sp. g., 1.088 - 1.098 (55ftC./$5*C.); refrac. index, 1.579 1.589 (55C.); crystallizing point, 40C. min, R.R. Classification! Agricultural Insecticides. General Information! Santophen 7 is used as the active ingredient in disin fectants and antiseptic formulations; as an industrial preservative and as an enhancing agent for coal tar and cresylic acid disinfectants. It is highly toxic to bacteria. CAUTION: This product is toxic. Avoid contact with the skin. Available Literatures Monsanto Technical Bulletin 0-3, "Santophen 7--A Germicide and Industrial Preservative." Page 122 MONSANTO CHEMICALS 0683862 TOWOLDMONOQ41946 "SANTOPHEN' 20" (Petitachlorophenol) Characteristics: Dark grayith brown flakes; chlorphenolic odor: crystallizing point, I75M80C.; bulking value, 45.45 lbs. per cu. ft.; dispersible in soaps and sulfonated oils. R.R. Classification: Agricultural Insecticides Other Than Liquid NOIBN. General Information: Santophen 20 is highly toxic to fungi and many bac teria and is used industrially where such growths must be prevented or con trolled. Frequently used in oil solution (See Permasan) or as the sodium salt (see Santobrite). SOLUBILITY DATA Solub; iities expressed as per cent Santophen on weight of solution Water Pine Oil 95% Ethyl Alcohol (Ethanol) 100% Ethyl Alcohol Methyl Alcohol (Methanol) Orthodicblorbenzene Stoddard Solvent No. 9 Refined Oil Gas Oil Diesel Oil Carbitol Ethylene Glycol Diethylene Glycol Benzol Cellosolve Butyl Carbitol Dioxan Diethyl Ether U.S.P. Acetone U.S.P. Linseed Oil (Raw) Tung Oil Dipentene Turpentine Carbon Disulfide Carbon Tetrachloride Glycerin 0 c. 0.00049 24.5 39.0 46.0 40.5 20 C. 0.0014 32.0 47.5 53.0 57.0 5.5 8.5 1.5 6.4 1.1 0.3 2.4 1.9 3.1 30.0 6.0 27.5 11.0 8.0 27.0 34.5 48.0 11.5 52.9 21.5 13.9 11.2 8.4 3.0 3.0 2.0 0.1 at 35C. 40 C. 0.0025 39.0 56.5 60.0 72.0 15.5 3.5 2.5 5.2 5.7 51.0 21.0 62.0 19.5 50.0 62.0 22.0 60 0.00 46.5 65.5 67.0 77.5 26.0 7.5 5.6 9.3 21.3 38.5 ii.s 65.0 37.5 Santophen 20 and its solutions and formulations are irritating to the skin and mucous membranes and are somewhat toxic to man and tbe higher animals. Precautions suggested in "Instructions for Handling Santophen 20" should be observed. Available Literature: 3-page mimeographed bulletin "Santophen 20." Mimeographed bulletin "Instructions for Handling Santophen 20." 26TK EDITION Page 123 0663663 TOWOLDMONOQ41947 "SANTOPOID S''. Standard Forms Oily, homogeneous liquid Specifications: Dark brown liquid; sp. g. 1.20 1.30; flash, (open cup method), 250T. min.; fire, (open cup method), 290 * 300F. min.; pour, below --35F, viacoaitv, S.U. at lUOT.. 134.5 - 14?.5 3cconda. R.R. Classification: Chemicals NOIBN. General Informations Used up to 10% mixed with mineral oil to form extreme pressure lubricants for hypoid and other gears. "SANTOPOLR" Specifications: Gravity, 26.7A.P.l.; flash, 485T.; pour, 10F.: viscosity, S.U. at 210F., 156.4; carbon residue, 1.4; color, NPA (85 and 15), 6; neutralization number, 1.20. R.R. Classifications Petroleum Lubricating Oil. General Information! An improved pour point depressant for lubricating oils. Lowers tbe pour point of wax-bearing oils as much as SOT. Stable under extreme service conditions. Available Literatures Application Data Bulletin No. 120, "Santopour." "SANTOSITE** (Sodium Sulphite Anhydrous, Technical)___ Specifications! Tan to slightly pink crystalline powder; assay (NajSOj) 93.0% min.; foreign odor, very faint, max.; solution, filtrate from a 10% solution in water is not darker than APHA ISO max. R.R. Classifications Sodium Sulphite Anhydrous. Technical. General Informations Used as a depressant in ore flotation and rubber, paper and cordage manufacture, and as a reducing agent for removing oxygen from boiler feed water. "SANTOTAN-KR" (Basic Chrome Sulfate) Contains approx. 50% of Crj(SO<)j(OH)i Standard Form: Crystals. Specifications: Dark green crystal^; solution in water (5:500), clear; basicity (CrjQj/SOj), 101-105; basicity (Schorlemmer), 37.3%-39.7%; chromium as CrjOj, 23.9% min. (Continued) Page 124 MONSANTO CHEMICALS 0683864 TOWOLDMONOQ41948 R.R. Classification: Dry Tanning Extract NOIBN. General Information: Used in chrome tanning of calf, cow, and horse bides and sheepskins. Available Literature: 16 page b-x>klet "Chemicals for the Tanning Industry." "SANTOVAR A" (See under Antioxidants, Rubber). SANTOWAX, REGULAR_______________ _____________ ____ Standard Form: Yellow waxy solid. Properties: Boiling range: first drop, 365eC.; 80%, 402C. Freezing point: primary hold point, 140C.; secondary bold point, 56C. Apparent sp.g., 1.10 (approx.) at 2SC. Slightly soluble in alcohol and more soluble in benzene. R.R. Classification: Coal Tar Re-sin. General Information: Used in compounding polishes and waxes when a high melting wax is desirable. Also a plasticizer and resin. "SANTOWAX M" Standard Form: Yellow waxy solid. Properties! Micro-crystalline hydrocarbon wax of unsual stability toward heat: melting point, 83 85C.; flash point, 207C.; hardness (ASTM D-5-25) 250 gm. load, 0.23 mm. R.R. Classification! Coal Tar Resin. General Information i Used as att opactfier for paraffin candles and as a partial substitute for Carnauba wax. "SANTOWAX O" Properties! Oily, crystalline hydrocarbon; hold point, less than 50C.; flash point, 171C.; flame point, 193C. Hardness (ASTM D-5-25): 50 gm. load, 0.13 mm.; 150 gm. load, 0.40 mm.; 250 gm. load, 1.07 mm. R.R. Classification! Coal Tar Resin. General Information! Semisolid plasticizer for soft wax or resin compositions. 26TB EDITION Page 125 0683865 TOWOLDMONOQ41949 T "SANTOWAX P" Standard Forms Flaky crystals. Properties: Nearly white, crystalline high-melting hydrocarbon: first crystals, 209 213C.; flash point, 207C.: flame point. 238C.: hardness (ASTM D-5-25) 230 gm. load, 0.33 mm. It.K. Classifications Coal Tar Res ns. General Information t Used to raise softening point and hardness of other w axes and resins. SODIUM ACETATE CHjCOONa CHjCOONa. 3HjO Mol. Wt. 82.02 Mol. Wt. 136.07 Standard Formas Crystals, 60%, >. F.: anhydrous (not N.F.) Specifications of N.F. Grades White crystals or granules: assay (as trihy drate), 99.5 104.0% solubility in w^ter (1:2), complete: alkalinity (as NajCOj), 0.025% max., conforms to N.F. te*t for heavy metals; no crystals retained on 10 mesh. Specifications of Anhydrous (not N.F.): White or grayish crystalline ma terial: assay, 99.0% min.: solubility in water (1:2), complete; carbonate (as NajCOj), 0.5% max. R.R. Classification! Sodium Acetate. General Informations Used in tbt manufacture of dyestuffs as a condensing component and buffing agent in coupling reactions; in dyeing operations as a mordant: in the manufacture of pharmaceuticals; in the soap and tanning indus tries; and as a photographic chemical. SODIUM ACID PYROPHOSPHATE (Also known as disodium dihydrogtn pyrophosphate and acid sodium pyro phosphate). NajHjPjOj Mol. Wt. 221.97 Gradeat Food and commercial. Fot>d grade meets all U. S. Pure Food Law requirements. Properties: White powder, soluble in water and having min. neutralizing value of 74; pH of 1% solution, 4.2. (Continued) Page 126 Monsanto chemicals 0663666 TOWOLDMONOQ41950 R.R. Classification: Sodium Phosphate. General Information: Used in oil well drilling muds and as a leavening agent in baking powder and flour. SODIUM ALUMINATE Na AUO, Mol. Wt. 164.2 Standard Form: White soluble powder; contains 90% soluble sodium aluminate. Properties: Readily soluble in water and extremely low in iron and insoluble material. Stable for at least 24 hours in 10% solutions although comains a max. of only 5% free caustic soda. R.R. Classification: Sodium Aluminate. General Information: Used iu papermaking: With aluminum sulfate for sizing at higher pH's. Also to help se| color and filler and to improve paper formation. In treatment of municipal and industrial water: With aluminum sulfate as a coagulant. In the lime-soda soft<ning process for silica removal and floe formation. Miscellaneous: As an alkaline source of alumina in the manufacture of certain pigments, catalysts and casein paints; in processing glycerin lyes; in chrome tanning; in cleaning solutiona; to aid set of the frit in vitreous enameling. SODIUM AMMONIUM PHOSPHATE (Also known as microcoamic salt; sodium ammonium hydrogen phosphate; salt of phosphorus; phosphorous salt; fusible salt of urine.) NaNH4HP04.4H,0 Mol. Wt. 209.09 Standard Formi Crystals. Properties! Transparent, white, efflorescent, monoclinic crystals. Gives off water and ammonia on beating, leaving NaPOs; contains above 32% PjOj, 7.5% NH) and 14% NajO. Grades Commercial. R.R. Classification: Disodium Phosphate. Principal Uses: Used principally in analytical laboratories for staodardizing uranium solution; determination of Mg and Mn; as reagent in blow pipe analysis. SODIUM BENZOATE. rv Mol. Wt. 144.11 J6TH EDITION .Continued) Page 127 06S386? TOWOLDMONOQ41951 Grades) U.S.P. and Technical. Specifications of U.S.P. Grade: Thin white flakes or white powder; solubility in water (1.0:1.8 at 25C.), complete solubility in 90% etbvi alcohol (1:50), com plete; N/10 alkali or acid per 2 grain sample, 0.2 cc max.; pH 6.8 - 10.4; loss on drying at 110C., 0.50% max.; assay, 99.0% min.: chlorides (as NaCI), 0.05% max.; organic chlorine, none; sulfates (as N'ajSCh), 0.05% max.; nitro compounds, none. Specifications of Technical Grade: White or slightly tinted powder; assav, 99.0% min. (dry basis); solution in v, a ter (1:1.8), essentially complete but slightiv inferior to U.S.P. quality; chlorides (as NaCI), 0.6% max.; sulfates (as Na,S04j, 0.6% max.: phthaiic acid, 0.1% max.; heavy metals, none. R.R. Classification: Food Preserving Compound. General Information: Used for preserving foods, tobacco and medicinal pre parations. SODIUM BISULFATE (s,, Mitr. Ck<0. SODIUM BISULFITE Standard Forma: Liquid--33 B$. containing approx. 21% SO,; wt. per gal., 10.78 lbs. Anhydrous (Sodium Metabisulfite)--66% SO] (approx.) Typical Analyaia: SO, Na*S04 Fe Liquid 21.5% 3.00 .006 Anhydrous 66% 1.5 .002 R.R. Classification: Sodium Bisulfite Dry or Sodium Bisulfite Liquid. General Information! Used in dy< manufacture,as source of SO, for reducing sodium bichromate to basic chrome ^ulphate in tanning, bleaching of vegetable tan extracts, production of hydrosulfite for vat dyeing, antichlor in bleaching of groundwool, bleaching dyes out of wo:>den coloring drums used for dyeing leather, antichlor in pulp bleaching, antichlor in laundries, bleaching of straw, rabbit fur, sugar syrups, glue, glucose. (See toblf in general data section) SODIUM FERRIC PYROPHOSPHATE NagFe4(P,Oi)* . XH,0 Properties: A finely subdivided powder, insoluble in water, soluble in hydro chloric acid; contains min. of 15.5% iron. General Information! Used in foot! fortification as a mineral supplement. Page 128 Monsanto chbmicals 0683868 TOWOLDMONOQ41952 SODIUM GLYCEROPHOSPHATE (See Glycerophosphates). SODIUM HYDROXIDE (See Caustic Soda). SODIUM HYPOCHLORITE (See Merclor). SODIUM PENTACHLOUOPHENATE (See Santobrite). SODIUM PHOSPHATE, DI (Also known as phosphate of so<?a; sodium phosphate di-bastc; secondary sodium phosphate; exsiccated sodium phosphate). NajHPO Mol. Wt. 141.982 Properties! Soluble in water, insoluble in alcohol. On exposure to air will absorb 2 to 7 mols HjO depending on humidity and temperature. Loses molecular water at 2408C. forming tetrasodium pyrophosphate. pH of 1% solution at 258C., 8.8. One lb. anhydrous productisequivalent to 2.5 lbs. of crystalline (dodecabydrate)* Gradest Technical, Food (Regi-lar, Granular, Powdered), Medicinal, U.S.P. R.R. Classification: Disodium Phosphate. General Information t Used in making glazes for potteries, porcelains and china ware; as an emulsifier in leaking process cheese; in various chemical pro. cesses; in manufacture of dyestuffs such as Schnitzler's green; in the preparation of enamels; in tinning and soldering; in leather tanning; as a bath ingredient in galvanoplastic work; in the manufacture of pigments such as cobalt phosphate; in the weighting of silk and impregnating of textiles in dyeing and calico printing; in the adjustment of condensed milk; conditioning boiler water; medicinal. DINS/Tr OF Stluk'I'N 0/ Pinhtn UONOSODtUM PHOSPHATF SOLUTIONS ,/ / K z: f / Ha AtFCfM 7 1 f rmati&t a! n Va/.4FtiS7-l9aa / Na / 21\ jy--i I I -1--1 I 1-1- -I t I I I I 0 to 10 3040i00100t0w &t*c Page 129 0683669 SODIUM PHOSPHATE, MONO ___ (Also known as sodium phosphate, monobasic; sodium dihydrogen phosphate; sodium biphosphate; monosodium ortho phosphate; acid sodium phosphate.) NaH,PO< Mol. Wt. 119.993 Standard Form: White powder. Properties: Contains not less than 1)8% PjOj; pH value of 1% solution, 4.5. tirades: Food: commercial. IOC Classification: Sodium Phosphate. General Information: Used for conditioning boiler water and in electroplating. 0663670 TOWOLDMONOQ41954 SODIUM PHOSPHATE, TRI (Vlso known as normal sodium phosphate; sodium phosphate, tri-basic; tertiary sodium phosphate: T.S.P.) NajPOj. 12H}0 Mol. Wt. 380.16 Specifications! White crystalline material, uniformly sized: quickly soluble in water giving an alkaline reaction: pII value of 1% solution, 11.8. R.R. Classification: Trisodium Pnosphate. General Information: Used principally in cleaners and detergents for both household and industrial use. Fruit Cleaning: To remove insecticide sprays and inhibit grow th of fruit mold. Watet Treatment: For softening and conditioning water. SODIUM PHOSPHATE, TRI, MONOHYDRATE Na3PCVH20 Mol. Wt. 181.99 Standard Form: White powder. Properties- Soluble in water: one Kb. is equivalent in NajPC>4 content to 2.10 lbs. of tris<- iin phosphate crystalline. Grade: Commercial. R.R. Classification: Trisodium Phosphate. Principal Uses: Used for the same purposes as crystalline T.S.P.: in the manu* facture of compounds containing caustic soda it permits the production of dry mixtures. SODIUM POTASSIUM AMYL PHOSPHATE (Mixture of sodium and potassium salts of the amyl phosphoric acids). Standard Form: 60% solution in water. Properties: Straw colored liquid with slight Pentasol odor; sp. g. 1.339; wt. per gal. 11.2 lbs.; pH 7.0 7.3; slightly hygroscopic; anhydrous form gelatinous. K.K. Classification: Chemicals NOIBN. General Information: Used as ingredient in vat printing pastes and as a spin ning agent for wool. SODIUM PYROPHOSPHATE, TETRA (Also known as sodium pyrophosphate, pyrophosphate of soda, normal pyro- sodium phosphate, alkaline sodium pyrophosphate and TSPP.). Grades: Crystalline and Anhydrout. Properties: White crystalline material and white granular or powder; pH value of 1% solution, 10.2. R.R. Classification: Sodium Phosphate. (Confirmed) 26TH EDITION Page 131 0683871 TOWOLDMONOQ41955 Entrance to office and laboratory building at Trenton, Michigan, plant. General Information! Used in bleaching, especially for straw, and aa an ink eradicator; in manufacture of iron pyrophosphate and other pyrophosphates; household and industrial cleaner and detergent: in dye bath for putting certain types of dye in complete solution; electroplating; metal cleaning; electrolytic separation of various metals; oil drilling muds; as emulsifier in process cheese manufacture; soap builder; degummin^ textiles. SODIUM SALICYLATE (See Salicylates). SODIUM SULFATE, ANHYDROUS NtSO Mol. Wt. 142.05 Typical Analysis! White granular crystals; 99% NajSOj available. For crude Sodium Sulfate, see Salt Cake. R.R. Classifications Sodium Sulfate. General Information! Differs from dauber's salt only in sodium sulfate con tent. Glauber's salt contains 43% sodium sulfate and 56% water of crystalliza tion. Anhydrous sodium sulfate contains 99% sodium sulfate and no water of (Continued) Page 132 Monsanto chemicals 0663872 TOWOLDMONOQ41956 rrystallizaiion. spi! for diluting; dry dyestuffs and io tanning. Other uses same as for Glauber's salt. For crude Sodium Sulfate, see Salt Cake. SODIUM SULFHYDRATE* NaHS Mol. Wt. 56.06 Standard Form: 33!2% NaHS, liquid. It.lt. Classification: Sodium Su fhydrate. General Information! Sodium Sulfbydrate is chemically simitar to sodium sulfide. Where a sulfide with a lower caustic content is desirable Sodium Sulfhv. drate may be used. The main application for Sodium Sulfbydrate is in dehairing leather where its tower caustic alkalinity makes it more desirable than sodium sulfide for certain leathers. A lower caustic alkalinity causes less swelling of the hides or skins, thus producing leather with a finer, smoother grain. It can be said that Sodium Sulfbydrate affords a means of controlling plumping (swelling). I nlike sodium sulfide. Sodium Sulfbydrate will not dehair by itself. Lime must be used with it to give a sufficiently high pH for debairiog. * Not manufactured by us, but furnished for the convenience of our customers. SODIUM SULFIDE Standard Forms: Crystals (\ajS.9HjO): concentrated--flakes.* (NajS.nHjO); liquid (20% N'ajS solution). Typical Analysis: Crystals. 31% NajS; concentrated, 60-62% NajS; liquid, 20% Na,S. H.R. Classification: Sodium Sulfide. General Information: Sodium Sulfide is a salt of the weak acid, hydrogen sulfide, and the strong alkali, caustic soda, and consequently its solutions are strongly alkaline. Reacts with m<tal salts to form metal sulfides, nearly all of which are colored. Reacts with aci<ts, precipitating sulfur and liberating hydrogen sulfide. Is a reducing agent, and solutions are ready solvents of sulfur to form polysulfides. Principal use is in tanning, to remove hair from calfskins and cowhides, and from sheepskins from which the v, ool has already been removed. Other uses are in the manufacture and application of sulfur dyes, degumming of silk, denitrat ing of nitrocellulose rayon, sodium polysulfide solutions, leaching gold ore tailings, dissolving cresols from coal tar oils, boiling out linen, and depositing mineral pigments on cotton. * Not manufactured by us but furnished for the convenience of our customers. SODIUM SULFITE (See Saitoeite) SOLVENTS (See Etbyl, Butyl and Amyl Acetates, Diacetone Alcohol). 26TB EDITION Page 133 0683873 "SOPANOX" General Information: Sopanox is an amino compound, effective in minute quantities in restraining the oxidation of soap and the resulting rancidity, tli. coloration and other adverse qualities, all of which must be avoided in pro* during a product of highest grade. Our experience shows that Sopanox satisfies the exacting demands of manufacturers of soaps produced from animal or vege* (able oils, filled or unfilled. It is particularly valuable in preventing discoloration of refined toilet soaps. IMI. Classification: Chemicals !\OIBX. Available Literature: Technical bulletin "Sopanox.*' "SOPET" (Sodium Potassium Ethyl Phosphate Solution)____ Mixture of sodium and potassium salts of the ethyl phosphoric acids. Standard Form: 60% solution in water. Properties: Water white liquid with slight ester odor; 11.4 lb. per gal.; sp. g. 1.37 at 25C.; pH 7.0 7.4 in 60% solution; viscosity, 128 centipoiaes at 25C. R.R. Classification: Chemicals NOIBN. General Information: Used as fiber lubricant in spinning of wool. Being water soluble* is easily removed from yarn or cloth without soap scouring. SPRAY LACQUERS (See Lacquers). SPREADING AGENTS (See Areskap, Aresket, Aresklene, Stntomerse). STEEL PICKLING INHIBITORS (See Hibitite). STRONTIUM SALICYLATE N.F. (See Salicylate.). SULFANILAMIDE, U.S.P. (para-Aminobenzene Sulfonamide) NH, Mol. Wt. 172.20 SO NHi Page 134 Standard Forms: Crystals, 30-mesh; powder, 100-meah. (Continued) MONSANTO CHEMICALS 066387'* TOWOLDMONOQ41958 General Informations L'sed in pharmaceutical preparations and veterinary medicines. CA L T/O.V: SutfanUar^ide should be administered only under super vision of a competent physician. SULFATE OF IRON (See Ferric Sulfate and Ferrisul). SULFUR 99.5% pure sulfur. Gradess Commercial rubbermaker*, commercial flour, 90% through 80 mesh; dueling, 93*95% through 325 mesh. R.B. Classification! Sulfur. General Information! Sulfur is a brilliant yellow crystalline substance, ap proximately twice as heavy as water and melting at about 248 F. This ready fusibility permits casting into various shapes. It is highly acid resisting and is a jK>or conductor of heat and electricity. It combines with rubber to form polysullides. Sulfur is used as a source of sulfur vapor for manufacture of carbon bisulfide and sublimed sulfur; as a source of sulfur dioxide for fumigation, bleaching and manufacture of sulfuric acich sulfite, and bisulfite for paper manufacturing; in formation of sulfides and polysulfides for oil refining, vulcanization of rubber, smelting, and manufacture of calcium sulfide and sodium polysulfide; as an acid-resistant bonding material for brick-lined acid tanks; as a water-resistant material for water pipe joints; as a non-conductor for the manufacture of insu lators; as a fungicide; in manufacture of fireworks and railway signals; in grain mixtures for poultry; as a soil disinfectant. 16TH EDITION Page 135 0683875 TOWOLDMON0041 Converters used in manufacture of sulfuric acid at Everett. Mass, plant. Sl'LFl'RIC ACID II2S04 Standard Strengths! 58 B; 60 B6.; 66 Be.; 98% H2S0j; Oleum. Typical Analysisi 58 B: 74.36% HjSOi; freezing point, below --40F. 60 B4.: 77.67% min. HjS04; freezing point, +12.6 F. approx. 66 Be.: 93.2% min. HjSO*; freezing point. --29 F. approx. 98%: 98.0% min. H2SO4; freezing poiM, 38 F. approx. Oleum--20% SOj: 104.50% min. HjSO<; freezing point, 22.8F. 25% SO3: 105.6% min. H2S04; freezing point, 48.7F. 35% SOj: 107.88% min. HjSO,; freezing point, 83.5F. 40% SOj: 109.00% min. HjSOi; freezing point, 91.5F. 65% SO-: 114.6% H2SO4; freezing point, 38.0 F. Oleum freezing point data based on Manufacturing Chemists Association curve, 1M1 R.R. Classification! Sulfuric Acid. General Information! Used extensively in steel mills, enameling works, oil refineries, pigment works, by*product ghs plants, fertilizer plants, tanneries, and many other industries. (See tables in general data section) Page 136 MONSANTO CHEMICALS 0683876 TOWOLDMONOQ41960 SULFURIC ACID C.P___ HjSOt Mol. Wi. 98.07 Specifications! Colorless liquid; assay, 95.5 97.0%; non-volatile material. 0.0005% mat.; chloride (Cl), 0.(K)OO6% max.: nitrate (NOj), 0.0002% max.; ammonium (NH4), 0.0003% mat.; SOj, 0.0005% max.; arsenic, 0.000003% max.; heavy metals (as Pb), 0.0005% max.; heavy metals (as Fe), 0.0001% max. R.R. Classification! Sulfuric Ac>d. Corrosive liquid (white label required). Central Informations Lsed as a laboratory reagent and where an extremely pure material is required. SULFURIC COISTACT CATALYST (See Vanadium Catalyst). SU'LFURYL CHLORIDE SOjCJj Standard Form; Liquid. Mol. Wt. 134.97 Characteristics! Light yellow liquid (may deposit precipitate on standing); sp.g. 15.5/15.5C., 1.67 1.71. Pistilling range: first drop, 50.0X. min.; dry point, 70.0X.; 20% 100% range, 2.0X. max.; total condensation, 95% min. R.R. Classification: Chemicals NOIBN. Corrosive liquid (white label required). General Information: Used as a chlorinating and condensing agent. SYNTANS (See Mertanol). TETRAPHOSPHORIC ACID (Phospholeum) Properties: Clear, water white viscous liquid; PjOj content 83 84%; does not crystallize at --SOX. Sp. g.: 2.060 at 20C.; 1.983 at 100X.; 1.960 at 125X. R.R. Classification: Phosphoric Acid. General Information: Used for industrial applications where a high strength phosphoric acid is desired and as t drying agent. TETRAPOTASSIUM PYROPHOSPHATE (See Potassium Pyrophos phate, Tetra). (Continued) 26TB EDITION Page 137 0663622 TOWOLDMONOQ41961 TETRASODIl.M PYROPHOSPHATE (See Sodium Pyrophosphate, Tesra). TEXTILE LACQUERS General Information t Clear and pigmented for waterproofing garment fabrics, raincoats, shower curtains, duck and balloon cloth. Can be supplied in cellulose nitrate, acetate, aceto butyrate, ethyl cellulose, and chlorinated rubber base. Applied by machine coating. R.R. Classification: Lacquers. TEXTILE PRINTING LACQLERS _ General Information: Pigmented lacquers for engraved roll and stencil print* ing on finished fabrics, cotton, silk, crlanese, rayon taffetas, crepes, and voiles. R.R. Classification: Lacquers. THINNERS General Information: Thinners are supplied for reducing all lacquer producta to required viscosity for spraying, dipping, and machine coating. Can be adjusted to meet special requirements for flow out, drying time, moisture resistance, and solvent power. Retarding thinners, cleaning thinners, stripping thinners, re movers, resins and dye solvents are also available. R.R. Classification* Lacquer Thinmng Compound. THIOCARBANILIDE (See und<* Accelerators). THIOUREA________________ _______________________________ (Also known as tbiocarbamide, sul/ocarbamide, and sulfourea.) NHj.CS.NH, Mol. Wt. 76.12 Standard Formt Crystals. Specifications: White, free-flowing crystals; moisture 0.50% max.; ash 0.05% max.; solution (10% water at 25C.) turbid. R.R. Classification: Chemcials NOIBN. General Information: Used as an intermediate in the production of dyestuffs #*'1and pharmaceuticals; in the manufacture of vulcanisation accelerators; as an (Contuui Page 138 Monsanto cbrmicals 0683878 TOWOLDMONOQ41962 ingredient of insecticidal compositions; moth-proofing agent in treating furs, feathers, skins and fabrics; and as an intermediate in the production of resins and waxes. 'THILRAD" (See Accelerators) TOLUENE ETHYL SULFONAMIDE (See Santicizer 8). para-TOLUENESULFONAMIDE (Also known as poro-ioluenesulfonic acid amide, para-sulfonamidotoluene, and 4-sulfonamidotoluene.) CH* Mol. Wt. 171.21 SOiNH* Standard Formi Crystalline powder Specifications! Light brownish, crystalline powder; crystallizing point (dried material) 135.0C. min.; ash 0.60% max.; alcohol insoluble material, 0.60% max.; loss on drying, 0.50% max. R.R. Classification! Chemicals NOIBN. General Information! Used as an intermediate in the production of active chlorine bearing compounds, as an intermediate in the production of dyestuffs, as a plasticizer, and as a base ip the production of plasticizers and resins. Also see Santicizer 9, a mixture of ortho and para-toluenetulfonatnidea. para-TOLUENESULFONCHLORIDE CHi Standard Form) Crystals Characteristics! White or yellowish crystals; assay, 95% min.; crystallizing point, 65.5C. min. R.R. Classifications Chemicals NOIBN. General Informations Used at a condensing agent and an intermediate in dyestuff tynthesia. 26TH EDITION Page 139 0683679 TOWOLDMONOQ41963 TOLLENESLLFONIC ACID, TECHNICAL CH, 0 Mol. Wt. 172.19 SOjH Standard Form: Fused crystalline mass. Characteristics! Brown to black crystalline solid: toluenesulfonic acid. 85.0% min.: IIjSO,, 8.0% max. Composition: approx. 85.0% para and 15.0% ortho; contains up to 14.0% water; may contain 1.0 2.0% toluene. R.R. Classification} Chemicals NOIBN. General Information: Used in ti e manufacture of dyestuff intermediates and as a catalyst in certain organic reactions. TRICALCIUM PHOSPHATE (See Calcium Phosphate. Tri). TRICHLOROBENZENE, TECHNICAL _____________ C*H,C1, Mixture of 1. 2. 3* and 1, 2, 4-tricblorobentene Standard Formi Liquid. Mol. Wt. 181.45 Characteristics} Practically cle*r, colorless to light yellow liquid; sp.g. 15.5<>/15.5'JC., 1.460 1.477; acidity as HC1, 0.01% max.; crystallizing point, 10.0C. max. Distilling range; first drop, 205.0C. min.; 50%, 213.09C. min.; 90%, 216.0C. min.; dry point, 250.0*C. max. R.R. Classification! Trichlorobemene. General Information! Used in organic synthesis, as a solvent, and as an insect icide. TRICRESYL PHOSPHATE. Page 140 Mol. Wt. 368.18 (Continued) MONSANTO CHKMICALS- 0683800 TOWOLDMONOQ41964 Specification#; Clear practically colorless liquid; sp. g. at20/20C., 1.1620.005; acidity (as HsPO*) 0.01% max.i free phenols (permanganate test), a distinct purple color to be present after 3>) minutes. R.R, Classificationt Lacquer Solvents NOIBN. General Information! Tricresyl Phosphate is used principally as a plasticizer, (t has a high boiling point and is relatively non-volatile, the evaporation loss in 100 hours at 100C. being less than 0.10%. The refractive index is abo\it 1.556 at 20aC. Viscosity increases rapidly at temperatures below normal until at about --35'C. the product is a solid transparent mass without crystalline structure. It is miscible with all the common solvents and thinners, and with linseed, china wood, and castor oils. Its solubility in water is less than 0.002% at 85C. and it imparts good moisture resistance to nitrocellulose films. Being a solvent for nitrocellulose, it has a high retentivity and can be used in large proportions without danger of sweating or separation. Tricresyl Phosphate is the standard fire retarding plasticizer for nitrocellulose. It is compatible with most lacquer resins and gives firm, tougb, flexible films of excellent weathering qualities. The ortho isomer, which is reputed to be the toxic element in normal Tricresyl Pbos* pbate, has been virtually eliminated from Tricresyl Phosphate Monsanto, there by reducing toxicity dangers to a minimum and making the product morn suit able for many applications. Elimination of the ortho isomer causes no impairment in plasticizing qualities. Available Literatures 40-page booklet, "Plasticizers and Resins". TRIETHYL PHOSPHATE (CjHj^OjPO Mol. Wt. 182.2 Standard Forms Liquid. Characteristics! Water white liquid; acidity (cc. a/100 NaOH per 5 cc.), 3.0 cc. max.; moisture, 0.20% max. Distilling range: first drop, 2009C. min.; dry point, 220C. max. R.R, Classifications Chemicals NOIBN. General Information: Used as a solvent plasticizer and as a catalyst in chem ical syntheses. Available Literatures 40-page booklet: "Plasticizers and Resins." TRIMAGNESIUM PHOSPHATE (See Magnesium Phosphate, Tri). JOTB COITION Page 141 0683661 TRIPHENYL PHOSPHATE. Mol. Wt. 326.31 Specifications! White flakes, faintly aromatic; m. p. 48.5C. min. start; solution in alcohol (10 gins. in 50 cc), not more than faintly opalescent; permanganate test, distinct purple color to be present after 30 minutes; acidity (as HjPOj) 0.003% max. II.R. Classification! Lacquer Solvents NOIBN. General Information! The chief uses of Tripbenyl Phosphate are as a plastic izer and fire retarder. It is miscible with the common solvents and thinners and with vegetable oils. Its solubility it. water is 0.001% at 34C. and 0.002% at 54C. and it imparts some moisture resistance to cellulose acetate films. Its retentivity in cast cellulose acetate films is nearly 80%; that is, it can be incorporated in the proportion of 8 parts to 10 of acetate without causing separation and blooming. It imparts good flexibility and gives clear, tough compositions without tendency toward tackiness. Triphenyl Phosphatfe is toxic and should not be used in articles such as foil, which are to come in oontact with foodstuffs. One of the most valu able properties of Triphenyl Phosphate is that of fire retarding. When used alone in cellulose Acetate films an amount of Tripbenyl Phosphate equal to 20% of the cellulose acetate weight produces films which will not support combustion. Available Literature? 40-page booklet "Plasticizers and Resins" TRIPHENYL PHOSPHITE Mol. Wt. 310.31 Specifications! A crystalline soli<$ at slightly below room temperature; at higher temperatures is an oily liquid weighing 9.85 lbs. per gal. R.R. Classificationi Chemicals NOIBN. General Information! Used as s plasticizer and aa a fire retarder for nitro cellulose. Page 142 Monsanto chemicals 0663882 TOWOLDMONOQ41966 TRISODIUM PHOSPHATE (See Sodium Phosphate, Tri). "I'REKA". "UREKA BLEND B'\ "UREKA C" (See under Accele rators, Rubber). VANADIUM SULFURIC ACID CATALYST General Information : Used in manufacture of sulfuric acid by contact process. (Not suitable for other purposes). VANILLIN, ETHYL (See Eth<,van). OH Standard Form: Fine Crystals. Specifications! Fine, white crystalline needles: m.p. 81.5C. min.: no foreign flavor (in sugar solution): loss on dr) mg, 0.03% max.; solubility in alcohol (1:2), complete. R.K. Classification! Chemicals NOIBN. General Information! Used as a flavoring agent in foodstuffs and beverages. Available Literature: Leaflet "Vanillin Monsanto." VARNISH ANTISKINNING AGENTS (See Santovar A). "VUELITE" (See Plastics). "VUEPAK** (See Plastics). WATER-TREATING CHEMICALS (See Aluminum Sulfate. Ammonia, Chlorine, Ferrisul, Hypochlorite of Soda, Santobrite, Santosite, Sodium Alum- inate, Sodium Sulfate). 26TH EDITION Page 143 0663683 TOWOLDMONOQ41967 WETTING AGENTS (See Areskap, Aresket, Aresklene, Santomerse). XANTHATES, (See Potassium Amyl Xanthate and Potassium Ethyl Xan* (hate). ZINC CHLORIDE Crudest 25s Be. and 52 B6. solutions. K.K. Classification t Zinc Chloride Liquid. General Information > l aed as a flux in galvanizing and soldering since it has (he acid properties of muriatic acid without being volatile at the temperature used. The following products are made by Monsanto Chemicals Limited, London, England, find are not at present available for sale bv Monsanto in the United States: "ACROSYL" ANTHRACENE OIL AIRINE BENZENE BENZENE ABSORBING OIL COL'MARQNE RESIN CREOSOTE NAPHTHA, HIGH FLASH NAPHTHA, SOLVENT NAPHTHALENE PITCH PYRIDINE BASES TAR ACID OIL TOLUENE Page 144 MONSANTO CHEMICALS 068388-. TOWOLDMON0041968 MONSANTO LITERATURE Accelerators, Rubber. "Santecure." 52-page file size booklet giving proper ties, uses and comparative data. Alcohol. "Nealco Industrial Alcohol." 70-page booklet giving chemical and physical data on ethyl alcohol, completely denatured alcohol, anti-freeze, and specially denatured alcohols. Abo includes government regulations pertaining to alcohols. Ammonia. "Monsanto Ammoiiia for Refrigeration." 12-page reference book let for operators of refrigerating machines. Contains property tables for an hydrous ammonia and calcium chloride and instructions for handling ammonia and ammonia cylinders. Aroclors. "The Aroclors." 20-page file size booklet covering physical and chemical properties, uses, and applications. Chlorine. "Monsanto Chlorine. ' 20-page file size, illustrated booklet, giving properties of chlorine and information on containers, care of equipment and safe handling. Coumarin. "Coumarin Monsanto." 4-page pocket size folder, giving proper ties and uses. Ethavan. "Ethavan (Pure Ethyl Vanillin)." 4-page pocket size folder, giving properties and uses. Ferrisul. "Ferrisul for Metal Treatment." 12-page file size booklet, giving properties and directions for use of Ferrisul for pickling stainless steel and copper and for etching metal articles preparatory to galvanizing. Ferrisul. "Ferrisul for Treatment of Water, Sewage and Industrial Wastes." 16-page file size booklet, giving properties and directions for use of Ferrisul for treatment of municipal water supplies, sewage and industrial wastes and for other industrial uses. Ferropbosphorua. "Phosphorus-Iron Alloys, Bulletin No. 1." 36-page file size booklet, containing a report of general exploratory research upon influence of phosphorus in low carbon, low lloy steel. Based on work done at Bsttelle Memorial Institute. Ferrophosphorus. "Phosphorus-Iron Alloys, Bulletin No. 2." 64-page file size booklet. A report of experimental research investigation on corrosion and mechanical influences on alloying elements in low alloy steel. Ferrophosphorus. Phosphorus-Iron Alloys, Bulletin No. 3." 56-page file size booklet in two parts. Part one-. Digest of U.S. Patents relating to phosphorus as an alloying element. Part two-: Lisl of U.S. Patents relating to steel production and treatment. Ferrophosphorus- "Phosphorus-Iron Alloys, Bulletin No. 4." 20-page file size booklet containing reports of experimental investigation on the influence of phosphorous in Cr.-Mo steels and sttels in high temperature service. IlibiUte. "Hibitite and Its Uses." 4-page mimeographed bulletin. Lacquers. "Safiex Lacquers." 4-pa$e mimeographed bulletin on Saflex fabric coatings. 26TR EDITION Page 145 0683665 TOWOLDMONOQ41 MONSANTO LITERATURE_Continued Lampblack. "Monsanto Bear Lampblack. Properties and Principal Uses." 12-page pocket size booklet, giving description and analyses of the various grades of Monsanto Lampblack. Latex. "Latex Compounding." 36-page file size illustrated booklet containing comprehensive discussion of latex compounding methods and technique, com pounding materials and various test data. Manicure Lacquers. "Monsanto Manicure Lacquer." Pocket size color card folder, containing sample chips of the standard creme shades of Monsanto man icure lacquers. Mertec. "Maintenance Paints." Mimeographed bulletin. Metbyl Salicylate. "Methyl Salrylate Monsanto." 4-page pocket size folder giving specifications and uses. Permasan. "Chemicals for Termite Control." Monsanto Technical Bulletin No. 0-13, August 22, 1940. 4-page file size bulletin describing recommended chemicals for treatment of soil and wivod. Permasan 116. "Permasan 116, A Water Repellent Preservative for Wood." Monsanto Technical Bulletin No. 0-21. February 1.3. 1911. 8-page file size bullet in giving properties and application dat<<. Phosilage. "Grass Silage for Mor<< Profitable Livestock Farming--How to Make It and How to Feed It." 32-page pocket size booklet, describing procedure for making and feeding grass silage in which Phosilage is used as the preser vative. Plasticizer* and Resina. "Plasticisers and Resina, Specifications and Applica tion Data." Revised May, 1940. 40-page file size booklet, giving comprehensive data on properties and applications of Monsanto plasticizers and resins, which include the Samicixers, phthalatea. phosphates, Santolitea, and Aroclora. I'laatica. "Resinox, A Monaanto Plastic." 12-page illustrated booklet describ ing properties, manufacture, molding, and uses of Resinox phenol-formaldehyde plastic. Plastics. "Lustron. A Monsanto Plastic." 16-page illustrated booklet describ ing properties, manufacture, molding, ana uses of Lustron, Monsanto poly styrene. Plastics- "A Wartime Guide to Monsanto Plastics." 15-page file size booklet describing the main groups of Monsanto Plastics and some of their wartime applications. Potassium Pyrophosphate, Tetra. "Tetrapotissium Pyrophosphate." Mon santo Technical Bulletin No. P-23. January 1, 1941. 4-page file size bulletin. Rubber Chemicals. "Monsanto Chemicals for the Rubber Industry." 44-page file site booklet giving properties and general characteristics and uses of Mon santo accelerators, antioxidants, softeners and miscellaneous materials for the rubber industry. Page 116 MONSANTO CHEMICALS 0683866 TOWOLDMONOQ41970 MONSANTO LITERATURE_Continued Rubber Compounding. "Rubber Compounding for ihe Wire Industry." 17-page file size booklet giving specification* and testing and compounding data on rubber w ire coatings. Santobrite. "Sanlobrite for the Preservation of Adhesives." Monsanto Tech nical Bulletin No, 0-1. June I. 1940. 6-page tile size bulletin. Santobrite. "Santobrite and Santophen 20 for Paint Preservation," Mon santo Technical bulletin 0-2. 2-paee tile size bulletin. Santobrite. "Santobrite for Microorganism Control in the Pulp and Paper Industry," Monsanto Technical Bulletin No. 0-5. April 1, 1940. 8-page file size bulletin. Santobrite. "Santobrite for the Control of Slime and Algae," Monsanto Technical bulletin No. 0-15, March 25, 1940. 6-page file size bulletin, describ ing Santobrite for the control of shine and algae in industrial cooling water systems. Santobrite. "Santobrite for the Preservation of Rubber Late*," Monsanto Technical Bulletin No. 0-17. September 29, 1939. 8-page file size bulletin des cribing the use of Santobrite for preventing biological deterioration of raw latex and latex products. Santobrite. "Santobrite in the Tanning Industry," Monsanto Technical Bulletin No. 0-19, June 20, 1940. 6-page file size bulletin describing the use of Santobrite for preserving hides, tanned leather, and tanning materials from mold and biological deterioration. Santobrite. "Santobrite--Methods of Handling and Application," Monsanto Technical Bulletin No. 0-22. 8-page file size bulletin. Santobrite. "Preservation of Cellulose Insulating Materials by Monsanto." 24-page file size booklet describing the use of Santobrite for protecting cellulose insulating materials and fibre boards from attack by decay and termites. Contains much investigational and field data. Illustrated. Santobrite. "Sap Stain Control by Monsanto." Revised August, 1940. 24page illustrated file size booklet, describing the use of Santobrite for controlling sap stain and mold in green lumber. Santoehlor. "Santocblor for the Control of Peach Tree and Stone Fruit Borers," Monsanto Technical Bulletin No. 0-18, December 1. 1939. 3-page file size bulletin. Santolube. "Santolubea--Corrosion Inhibitors for Lubricating Oils." 20-page file size booklet giving properties and results of operating and laboratory tests. Santomask. "Santomask for After-Odor Control of Interior Paint, Printing Inks and Some Other Odoriferous Formulations." Monsanto Technical Buelltin No. 0-16, July 26, 1940. 2-page file sfce bulletin, giving properties and directions for use. 2 6TH EDITION Page 147 0683887 TOWOLDMONOQ41971 MONSANTO LITERATURE--Continued Sanlomerse. "Sanlomerse."' 32-page file size booklet, giving physical ami chemirul properties and applications of Sanlomerse as a detergent and wetting, spreading, penetrating, cleaning and dispersing agent. Santophcn T. "Sanlophen 7, A Germicide and Industrial Preservative." Monsanto Technical bulletin No. 0-3. August 15, 1941. 7-page file size bulletin giv ing properties and application dat<>. Suntopour. "Santopour. A Pour-Point Depressant for Lubricating Oils." 10-pagc file size booklet describing properties, method of application, and test and field service results. Sopanox. "Sopanox--An Antioxidant for Soaps." Monsanto Technical Bulle tin No. P-100, May 1, 1939. 3-page file size bulletin giving properties and direc tions for use of Sopanox, also methods of testing soap for oxidation and rancidity. Vanillin. "Vanillin Monsanto." -1-page pocket size leaflet giving properties and uses. Vuepak. "How Vuepak Helped 21) Manufacturers to Package for Greater Sales." 30-page file size booklet, giving case studies of sales gains resulting from use of Vuepak. Intermediates are made at the Norfolk, Virginia, plant. Page 148 MONSANTO CHEMICALS 0683888 TOWOLDMONOQ41972 GENERAL DATA TESTING LIQUIDS WITH THE BALME HYDROMETER Monsanto products, when madt? to a Baume specification, may vary 0.2 Be. above but never below the speeded strength. The hydrometer used should be of limited range. not more than 10 B., and should be at least 10' in length. Its accuracy should be certified by the manufacturer. Our own hydrometers are tested against standard glasses certified by the U. S. Bureau of Standards, METHOD OF READING THE HYDROMETER* The correct method of reading tlie hydrometer is illustrated in Figs. 1 and 2. 1 he sample of li<|uid is placed in a clear glass jar or cylinder and (lie hydrometer carefully immersed in it to a point slightly below that to which it naturally sinks, and is then allowed to float freely. The reading should not be taken until the liquid and the hydrometer are free from air bubbles and are at rest. Method of Reading Baume Hydrometer In taking the reading the eye should be placed slightly below the plane of the surface of the liquid (Fig. 1) and then raised slowly until this surface, seen as an ellipse, become* a straight line (Fig. 2). The point at which this line cuts the hydrometer scale should be taken a* the reading of the instrument (Fig. 2). In case the liquid is not sufficiently clear to allow the reading to be made as above described, it will be necessary to read from above the liquid surface and to estimate as accurately as possible the point to which the liquid rises on the hydro* meter stem. It should be remembered, however, that the instrument is calibrated * U. S. lurseu of Stondordi, Clrc. No. 57 26TH edition Page U9 0683869 TOWOLDMONOQ41973 to give correct indications when lead at the principal surface of the liquid. It will be necessary, therefore, to coirrct the reading at the upper meoiscus by an amount equal to the height to which the liquid creeps up on the atem of the hydrometer. The amount of this correction may be determined with sufficient accuracv for most purposes by taking a few readings on the upper and the lower meniscus in a sample of the clear liquid And noting the difference. The magnitude of the correction will obviously depend upon the length and value of the subdivisions of the hydrometer scale and must be determined in each case for the particular hydrometer in question. CORRECTING FOR TEMPERATURE The Thermometer must be used along with the hydrometer in testing any liquid. Hydrometers do not indicate the correct strength of a liquid unless read at the exact temperature indicated on the spindle, that is, at 60F. Accurate readings may be obtained by bringing the liquid to this temperature by cooling or warming, but in most instance* a correction can be applied with sufficient accuracy by reference to the following tables. For all liquids listed in this booklet, except Ammonia, the correction is added when the test is made above 60F. and subtracted when made below 60F. For Ammonia the reverse is true. CONVERSION FORMULAE FOR DENSITY SCALES Heavy Liquids Degrees Twaddell *=* (Sp. Gr. --1)200 Sp. Gr. Deg. Tw. +200 200 US Degrees Bauml -- HS Sp. Gr. Sp. Gr. :* 145--Deg. B4. Light Liquids Degrees Bauml ----------------------- 130 Sp. Gr. Sp. Gr. - 130 +Deg. Bi. Page 150 MONSANTO CHBMICALS 0663890 THE DILUTION AND CONCENTRATION OF LIQU IDS AND MIXTURES RECTANGLE METHOD Tbe figures expressing (he percentage concentration of two solutions (or those of one solution, and the figure 0 jor troter, where dilution with water is desired) are written in the two left hand corners of a rectangle, and tbe figure expressing the desired concentration is placed on the intersection of the two diagonals of this rectangle. ubirart the figures on the diagonals, the smaller from the larger, and write the result at the other end of the respective diago* nal. These figpres then indicate what quantities of the solutions whoe< concentration is given on the other end <>f the respective horizontal line, must be taken to obtain a solution of the desired concentration. For ex* ample, to make a 12% solution, by mixing an 8% and a 15% solution we prepare Fig. 1, which indicates that we have to take 3 parts by weight of the 8% solution, and 4 parts by weight of the 15% solution to obtain (7 parts by weight of) the 12% solution. Again, if we wish to dilute a 25% solution so as to obtain a 9% solution, we place the figure 25 in, for example, the upper left corner of a rectangle and place figure 0 (concentration of ...................... the solution in pure water) in the lover left corner, and then place tbe figure 9 (desired concentration) at the point of intersection of the diagonals, and subtracting across the diagonals, we obtain Fig. 2: 9 parts by weight of the 25% solution, if mixed with 16 parts by weight of water, will give 25 parts by weight of a 9% solution. In diluting to a given Baum strength or Specific Gravity, the percentage composition, corresponding to the Baum or Specific Gravity, must be taken _ from the following tables. For instance, supposing a 32 .......................^^0Baum6 Chloride of Alumina solution is to be diluted to 8 Bauro6 with vater. By reference to table on page 163 6.50 a 32 Baum6 solution contains 27.88% AlfCU, and an 8 Baumi solution contains 6.50% AljCl*. These percentages q....... A/s '^t........must be used in finding the weights of Chloride of Alumina ' and water to b< mixed by the above method. According to the scheme as outlined above, the percentages are arranged as in Fig. 3 and the subtractiona made along the diagonals, the lower from the higher. Thus when 32 Baum6 Chloride of Alumina is mixed with water in the proportion 6.50 pounds to 21.38 pounds, 27.88 pounds of solution will be obtained at 8 Baum. 26TH EDITION Page 151 0683691 TOWOLDMONOQ41975 SULFURIC ACID* By W. C. Ferguson and H. P. Talbot De grees He Specific Gravity 60760* F. Per Cent H,SO Freezing (Melting) Point Dg. F. De. grees B*. Specific Gravity 60760 F. Per Cent h*so4 Freezing (Melting) Point Deg. F. 0 1.0000 0.00 +32.0 36 1.3303 42 63 --70.0 1 1.0069 1.02 2 1.0140 2.08 3 1.0211 3.13 4 1.0284 4.21 +31.2 +30.5 +29.8 +28.9 37 1 3426 43.99 --60.0 38 1.3551 45 35 --53.0 39 1.3679 46 72 --47.0 40 1.3810 48.10 --no 5 1.0357 5.28 +28.1 41 1.3942 49.47 --35.0 42 1.4078 50.87 --31.0 6 1.0432 6 37 +27.2 43 1.1216 52.26 --27.0 7 1.0507 7 45 8 1.0584 8 55 +26.3 +25.1 44 1 6 53.66 --23.0 45 1 55.07 --20.0 9 1.0662 9.66 +24.0 10 1.0741 10.77 +22.8 46 1. 56 48 --14.0 47 1. 57.90 -- 15.0 11 1.0821 11.89 +21.5 48 1. 59.32 --18.0 12 1.0902 13.01 13 1.0985 14 13 +20.0 49 1.5: +18.3 50 1.52. 60.75 62.18 --22.0 --27.0 14 1.1069 IS. 25 +16 6 15 1.1154 16.38 +14.7 SI 1.5426 63.36 --33.0 52 1.5591 65 13 --39.0 16 1.1240 17.53 +12.6 S3 1.5761 66.63 --49 0 17 1.1328 18.71 +10.2 54 1.5934 68.13 --59.0 18 1.1417 19.89 19 1.1508 21.07 +7.7 5S 1.1611 69.65 +4.8 t 20 1.1600 22.25 +1.6 56 1.6292 71.17 57 1.6477 72.75 t t 21 1.1694 23.43 --1.8 58 1 6667 74.36 22 1.1789 24 61 --6.0 59 1.6860 75.99 --7.0 23 1.1885 25.81 --11.0 60 1.7059 77.67 +12.6 24 1.1983 27.03 --16 0 25 1.2083 28.28 --23.0 61 1.7262 79.43 +27.3 62 1.7470 81.30 +39.1 26 1.2185 29 53 --30.0 63 1.7683 83 34 +46.1 27 1.2288 30.79 --39.0 64 1.7901 85.66 +46.4 28 1.2393 32.05 --19.0 64 M 1.7957 86.33 +43.6 29 1,2500 33 33 --61.0 64H 1.8012 87.04 +41 1 30 1 2609 34.63 --74 0 64K 1.8068 87.81 +37 9 65 1.8125 88.65 +33 1 31 1.2719 35 93 --82.0 65 1.8182 89.55 +24 6 32 1.2832 37 26 --96 0 65 H 1.8239 90.60 +13 4 33 1.2946 38.58 --97.0 655* 1.8297 91 80 -- 1.0 34 1.3063 39 92 --91.0 35 1.3182 41.27 --81.0 66 1.8354 93.19 --29.0 *Thia table has been approved and adopted as a Standard by the Manufact uring Chemists' Association of tbe United States. fBelow--40. Specific Gravity determinations wen made at 60* F., compared with water at 60F. (Continued) Page 152 Monsanto chbmicals 0683892 TOWOLDMONOQ41976 SULPHURIC ACID_Continued From the Specific Gravities, the corresponding degrees Bauml were cal culated hy the following formula: llaume= 145--145/Sp. Gr. ALLOWANCE FOR TEMPERATURE At 10 Be.correction of .029 B6. or .00023 Sp. G. for every 1F. At 20 B.correction of .036 Be. or .00034 Sp. G. for every 1F. At 30 Be.correction of .035 06. or .00039 Sp. G. for every 1'F. At 10 Be.correction of .031 Be. or .00041 Sp. G. for every 1F. At 50 B6.correction of .028 Be. or .00045 Sp. G. for every I'F. At 60 B6.correction of .026 Be. or .00053 Sp. G. for every 1 F. At 63 B6.correction of .026 B. or .00057 Sp. G. for every 1F. At 66 Be. correction of .0235' B6. or .00054 Sp. G. for every 1F. For temperatures above 60F.. the correction is added to the observed in dication: below 60F. subtracted. % Oleum OLEUM % Free SO, Equiv. % H:SO, Freezing Point F. 0 0 100.00 50.5 10 10 102.25 32.0 20 20 104.49 22.0 25 25 105.62 47.0 30 30 106.75 66.0 40 40 109.0 91 9 50 50 111.25 91 9 60 60 113.5 62 0 65 65 114.62 38.0 70 70 115.75 56.0 80 80 118 0 78.0 26TB BDITION Page 153 0663893 TOWOLDMONOQ41977 Degrees Baun>6 1.00 2.00 3.00 4()0 5 00 5 25 5.50 5.75 6.00 6.25 6 50 6.75 7.00 7.25 7.50 7.75 8.00 8.25 8.50 8.75 9.00 9.25 9.50 9.75 10.00 10.25 10.50 10.75 11.00 11.25 11.50 11.75 12.00 12.25 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 Page 154 hydrochioric acid* (Muriatic Acid) By W. C Ferguson Specific 60760 F. Gravity 1 0069 1.0140 1.0211 1.0284 1.0357 1.0375 1.0394 1.0413 1.0432 1 0450 1 0469 1.0488 1.0507 1.0526 1.0545 1 0564 1.0584 1.0603 1.0623 1.0642 1.0662 1.0681 1.0701 1.0721 1.0741 1.0761 1.0781 1.0801 1.0821 1.0841 1.0861 1 0881 1.0902 1.0922 1.0943 1.0964 1.0985 1.1006 1.1027 1.1048 1.1069 1.1090 1.1111 1.1132 1 1154 Per Cent HCl. Degrees Baumt 1 40 2.82 4.25 5 69 7.15 1S.2S 15.50 15.75 16.0 16.1 7.52 7.89 8.26 8.64 9.02 16.2 16.3 16 4 16 5 16.6 9.40 9.78 10.17 10 55 10.94 17 : \ 1 17.1 11.32 11.71 12.09 12.48 12.87 17.2 17.3 17 4 17.5 17.6 13.26 13.65 14.04 14.43 14.83 17.7 17.8 17.9 18.0 18.1 15.22 15.62 16.01 16.41 16.81 18.2 18.3 18.4 18.5 18.6 17.21 17.61 18.01 18.41 18.82 18.7 18.8 18.9 19.0 19.1 19.22 19.63 20.04 20.45 20.86 19,2 19.3 19.4 19.5 19.6 21.27 21.68 22.09 22.50 22.92 19.7 19.8 19.9 20.0 20.1 {Continued) Specific Gravity 60760 F. 1.1176 1.1197 1.1219 1.1240 1.1248 1.1256 1.1265 1 1274 1.1283 1.1292 1.1301 1.1310 1.1319 1.1328 1.1336 1.1345 1.1354 1.1363 1.1372 1.1381 1.1390 1.1399 1.1408 1.1417 1.1426 1.1435 1.1444 1.1453 1.1462 1.1471 1.1480 1.1489 1.1498 1.1508 1.1517 1.1526 1.1535 1 1544 1.1554 1.1563 1.1572 1.1581 1.1590 1.1600 1.1609 Per Cent HCl. 23.33 23.75 24.16 24.57 24.73 24.90 25.06 25.23 25.39 25.56 25 ' 25 26 26 26.,, 26.56 26.73 26.90 27.07 27.24 27.41 27.58 27.75 27.92 28.09 28.26 28.44 28.61 28.78 28.95 29.13 29 30 29.48 29.65 29.83 30.00 30.18 30.35 30.53 30.71 30.90 31.08 31.27 31.45 31.64 MONSANTO CHEMICALS 068369*1 TOWOLDMONOQ41978 HYDROCHLORIC ACID_Continued Degrees Baum6 20.2 20.3 20.4 20.5 20.6 20.7 20.8 20.9 21.0 21.1 21.2 21.3 21.4 21.5 21.6 21.7 21.8 21.9 22.0 22.1 22.2 22.3 22.4 22.5 22.6 22.7 22.8 22.9 23.0 23.1 Specific 60 .60 F. Gravity 1 1619 I 1628 1.1637 1.1647 1.1656 1.1666 1.1675 1.1684 1.1694 1.1703 1.1713 1.1722 1.1732 1.1741 1.1751 1.1760 1.1770 1.1779 1.1789 1.1798 1.1808 1.1817 1.1827 1.1836 1.1846 1.1856 1.1866 1.1875 1.1885 1.1895 Per Cent HCI. 31.82 32.01 32.19 32,38 32.56 32.7> 32.9,1 33. 1:2 33 31 33.59 33.69 33.88 34.07 34.26 34.45 34.61 34.81 35.02 35.21 35.4) 35.59 35.78 35.97 36.16 36.3> 36.54 36.78 36.9) 37.14 37.36 Degrees Baume 23.2 23.3 23.4 23.5 23.6 23.7 23.8 23.9 24.0 24.1 24.2 24.3 24.4 24.5 24.6 25.7 24.8 24.9 25,0 25.1 25.2 25.3 25.4 25.5 Specific Gravity 60,60 F. 1.1904 1 1914 1.1924 1.1934 1.1944 1.1953 1.1963 1.1973 1.1983 1.1993 1.2003 1.2013 1.2023 1.2033 1.2043 1.2053 1.2063 1.2073 1.2083 1.2093 1.2103 1.2114 1.2124 1.2134 Per Cent HCI. 37.58 37.80 38 03 38.26 38.49 38.72 38 95 39 18 39.41 39.64 39.86 40.09 40.32 40.55 40.78 41.01 41.24 41.43 41.72 41.99 42.30 42.64 43.01 43.40 This table baa been approved and adopted as a Standard by the Manufact uring Chemists' Association of the tailed States. Specific Gravity determinations were made at 60F., compared with water at 60F. From the Specific Gravities, tbo corresponding degrees Baum6 were calcul ated by the following formula: 145 Bauml *=145 ----------------- Sp. G. allowance: for temperature At 10 to 15 B4. correction of 1/40 B.or .0002 Sp. G. for every 1F. At 15 to 22 B6. correction of )/30 B6.or .0003 Sp. G. for every 1 F. At 22 to 25 B6. correction of ] /28 B6.or .00035 Sp. G. for every 1F. 26TH EDITION Page 155 0683895 TOWOLDMONOQ41979 Degrees Baume 10 00 10 :s 10 '.0 10.75 11.00 11.25 11.50 11.75 12.00 12.25 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17.00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19.50 19.75 20.00 20.35 20.50 20.75 21 00 Page 156 NITRIC ACID* By W. 0. Ferguson Specific Gravitv 60 60s'F. l.OTU 1 0761 1.0781 l .0801 1.0821 1.0841 1.0861 1.0881 1.0902 1.0922 1.0943 1.0964 1.0985 1.1006 1.1027 1.1048 1.1069 1.1090 1.1111 1.1132 1.1154 1.1176 1.1197 1.1219 1.1240 1.1262 1.1284 1.1306 1.1328 1.1350 1.1373 1.139S 1.1417 1.1410 1.1462 1.1485 1.1508 1.1531 1.1554 1.1577 1.1600 1.1624 1.1647 1.1671 1 1694 Per Cent HNOj Degrees | Baume 12.86 13.18 13.49 13.81 14,13 1 i j l 21.25 21.50 21.75 22.00 22.25 14.44 14.76 15.07 15.41 15,72 22 50 22.75 23.00 23.25 23.50 16.05 16.39 16.72 17.05 17.38 23.75 24.00 24.25 24.50 24.75 17.71 18.04 18.37 18.70 19.02 25.00 25.25 25.50 25.75 26.00 19.36 19.70 20.02 20.36 20.69 26.25 26.50 26.75 27.00 27.25 21.03 21.36 21.70 22.04 22.38 27.50 27.75 28.00 28.25 28.50 22.74 23.08 23.42 23.77 24.11 28.75 29.00 29.25 29.50 29.75 24.47 24.82 25.18 25.53 25.88 30.00 30.25 30.50 30.75 31.00 26.24 26.61 26.96 27.33 27.67 31.25 31.50 31.75 32.00 32 25 (Continued) Specific Gravitv 60760 'F. 1.1718 1.1741 1.1765 1.1789 1.1813 1.1837 1.1861 1.1885 1.1910 1.1934 1.1959 1.1983 1.2008 1.2033 1.2058 1.2083 1.2109 1.2134 1.2160 1.2185 1.2211 1.2236 1.2262 1.2288 1.2314 1.2340 1.2367 1.2393 1.2420 1.2446 1.2473 1.2500 1.2527 1.2554 1.2582 1.2609 1.2637 1.2664 1.2692 1.2719 1.2747 1.2775 1.2804 1.2832 1 2861 Per Cert HNOj 28.02 28.36 28.72 29.07 29.43 29.78 30 14 30.49 30.86 31.21 31.58 31.94 32.31 32.68 33.05 33.42 33.80 34.17 34.56 34.94 35.33 35-70 36.09 36.48 36.87 37.26 37,67 38.06 38.46 38.85 39.25 39.66 40.06 40.47 40.89 41.30 41.72 42.14 42.58 43.00 43.44 43.89 44 34 44.78 45 24 MONSANTO CHEMICALS 0663696 TOWOLDMONOQ41980 NITRIC ACID--Continued Degree* Baum6 32 SO 32.75 33.00 33 25 33.50 33.75 34.00 34.25 34.50 34.75 35.00 35 25 35.50 35.75 36.00 36.25 36.50 36.75 37.00 37.25 37.50 37.75 38.00 38.25 38.50 38.75 39.00 39.25 39.50 39.75 40.00 40.25 40.50 40.75 41.00 Specific Gravity 60 60 F. 1.2889 1.2918 1.2946 l 2975 1 3004 1.3034 1 3063 1.3093 1.3122 1.3152 1.3182 1.3212 1.3242 1.3273 1.3303 1.3334 1.3364 l.3395 1.3426 1.3457 1.3488 1.3520 1.3551 1.3583 1.3615 1.3647 1.3679 1.3712 1.3744 1.3777 1.3810 1.3843 1.3876 1.3909 1.3942 Per Cent HNOj Degrees Baume 45 68 46 14 46 58 47 04 47.49 41.25 41 50 41 75 42 00 42.25 47.95 43.42 43 90 49 35 49.83 42.50 42.75 43 00 43 25 43.50 50.32 50 81 51.30 51.80 52.30 43.75 44.00 44.25 44.50 44.75 52.81 53.32 53,84 54.36 54.89 45 00 45.25 45.50 45 75 46 00 55.43 55.97 56.52 57.08 57.65 46.25 46.50 46.75 47 00 47.25 58.23 58.82 59.43 60.06 60.71 , 47.50 47.75 48.00 43.25 48.50 61.38 62.07 62.77 63.48 64.20 Specific Gravity 60 60'F. 1.3976 1.4010 1.4044 1.4078 1.4112 1.4146 1 4181 1. 4216 1 4251 1.4286 1.4321 1.4356 1 4392 1.4428 1 4464 1 4500 1 4536 1.4573 l. 4610 1.4646 1 4684 1.4721 1.4758 1.4796 1.4834 1.4872 1.4910 1.4948 1.4987 1.5026 Per Cent HNOj 64 93 65 67 66.42 67 18 67.95 68 73 69 52 70 33 71 IS 71 98 72.82 73.67 74.53 75.40 76.28 77 17 78.07 79.03 80 04 81.08 82.18 83.33 84.48 85.70 86.98 88.32 89.76 91.35 93.13 95.11 This table baa been approved and adopted aa a Standard by the Manufac turing Cbemiata* Aaaociation of tbe United State*. Specific Gravity determination* were made at 60s F. compared with water at 60F. From tbe Specific Gravities, the corresponding degree* Baumfi were calcu lated by tbe following formula: -- Baumfc *= 145 -- 145 ------------------Sp. G. (Continued) 26TB EDITION Page 157 0683697 TOWOLDMONOQ41981 .NITRIC ACID_Continued ALLOWANCE FOR TEMPERATURE At from 10 to 20 B. correction of 1/30 B4. or .00029 Sp. G. for every 1F. At from 20 to 30 B6. correction of 1/23 B. or .00044 Sp. G. for every 1F. At from 30 to 40 B6. correction of 1/20 B6. or .00060 Sp. G. for every 1F. At from 40 to 43.5 B6. correction ofl/17 B. or .00084 Sp. G. for every 1F. ACETIC ACID 60,60 F. Oudemanns Specific Gravity 1.0000 1.0016 1.0032 1.004? 1.0062 1.0077 1.0093 1.0108 1.0123 1.0137 1.0152 1.0167 1.0181 1.0195 1.0210 1.0224 1.0238 1,0252 1.0266 1.0280 1.0294 1.0308 1.0321 1.0334 1.0347 1.0360 1.0373 1.0385 1.0398 1.0410 1.0422 1.0434 1.0446 1.0457 Per Cent CjHA 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 Specific Gravity 1.0469 1.0480 1.0491 1.050? 1.0512 1.0523 1.0533 1.0543 1.0553 1.0562 1.0572 1.0581 1.0590 1.0599 1.060? 1.0617 1.0625 1.0633 1.0641 1.0648 1.0656 1.0663 1.0670 1.0676 1.0683 1.0689 1.0695 1.0701 1.0707 1,0712 1.0717 1.0722 1.0727 1.0731 Per Cent CjHA 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 ! 61 62 , 63 64 65 66 67 : Specific Gravity 1.0735 1.0739 1.0743 1.0747 1.0750 1.0752 1.0754 1.0756 1.0757 1.0758 1.0758 1.0758 1.0758 1.0757 1.0756 1.0754 1.0752 1.0749 1.0746 1.0741 1.736 1.0730 1.0723 1.0715 1.0706 1.0696 1.0684 1.0670 1.0654 1.0635 1.0614 1.0590 1.0563 Per Cent c,h4o, 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 Page 158 MONSANTO CBSMICALS 0683896 TOWOLDMONOQ41982 AQUA AMMONIA* By W ('. Ferguson I, 1 _________ ; Degrees Baum 10.00 10.25 10.50 10,75 n.oo 11.25 11.50 11.75 12.00 12,25 12.50 12.75 13.00 13.25 13,50 13.75 14.00 14.25 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17,00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19.50 19.75 Specific Gravity 607604'. 1.0000 .9982 .9964 .9947 .9929 .9912 .9894 .9876 .9859 .9842 .9825 .9807 .9790 .9773 .9756 .9739 .9722 .9705 .9689 .9672 .9655 .9639 .9622 .9605 .9589 .9573 .9556 .9540 .9524 .9508 .9492 .9475 .9459 .9444 .9428 .9412 .9396 .9380 .9365 .9349 Per Cent NHj j Degrees | Baum6 .oo .40 .80 1.21 1.6}i 20.00 20.25 20.50 20.75 21.00 2.0'? 2.40 2.81: 3.30 3.73 21.25 21.50 21.75 22.00 22.25 4.10 4.5V S.Oi 5.45 5.81 22.50 22.75 23.00 23.25 23.50 6.3] 6.74 7.17 7.61 8.05 23.75 24.00 24.25 24.50 24.75 8.49 8.93 9.35 9.83 10.28 25.00 25.25 25.50 25.75 26.00 10.73 11.18 11.64 12.10 12.56 26.25 26.50 26.75 27.00 13.02 13.49 13.96 14.43 14.90 27.25 27.50 27.75 28.00 28.25 15.37 15.84 16.32 16.80 17 28 28.50 28.75 29.00 Specific Gravity 60760^. .9333 .9318 .9302 .9287 .9272 .9256 .9241 .9226 .9211 .9195 .9180 .9165 .9150 .9135 .9121 .9106 .9091 .9076 .9061 .9047 .9032 .9018 .9003 .8989 .8974 .8960 .8946 .8931 .8917 .8903 .8889 .8875 .8861 .8847 .8833 .8819 .8805 1 17.76 18.24 18.72 19.20 19.6H 20.16 20.64 21.12 21.60 22.08 22.56 23.04 23.52 24.01 24.50 24.99 25.48 25.97 26.46 26.95 27.44 27.93 28.42 28.91 29.40 29.89 30.38 30.87 31.36 31.85 32.34 32.83 33.32 33.81 34.30 34.79 35.28 '"This table has been approved am? adopted as a Standard by the Manufac* luring Chemist#' Association of the l nited States. Specific Gravity determinations wi re made at 60F, compared with water at 60F. (Continued) 26TH EDITION Page 159 0663899 TOWOLDMONOQ41983 AQl A AMMONIA__ Continued ] to Ratinie ------------------------ -- 130. SP. G. ALLOWANCE FOR TEMPERATURE The coefficient of expansion for ai Jinonia solutions varving with the temper* attire, eorreetion must he applied acording to the following table: -- Degrees i itamne I I Corrections to be Added for Each Degree Below 60F. 40JF. 50eF. OI5Be. .021 " .027 " .033 " .039 " .053 " .017*86. . (J23 " .029 " .036* " .042 " .057 '* Corrections to be Subtracted for Each Degree Above 6<)F. 7):F. 80F. 90'F. o::oHe. | .0E6* " .0s<i ' " !; .043 " i i. (C7 ' .022*86. | .028 " .033 - ! .038 " ! .043 " 1 .059 " . l)24Be. .030 " .035 ' .040 " 017 " ]00F. . 026*B6. .032 " .037 " .042 " Central Hesearcb Department Laboratories. Dayton, Ohio Page 160 MONSANTO CHEMICALS 0683900 TOWOLDMONOQ41984 Temp. U.g. -- U> -35 - 30 -J5 --20 -15 -- 10 --5 0 5 10 15 20 25 30 3S 40 45 50 55 60 65 TO 75 80 85 00 95 100 105 110 115 120 125 ANHYDROUS AMMONIA Pressure Lbs. per Sq. In. Abs. Specific V olume <>:' Liquid C;i Ft. per Lb. of Sat. Vapor, Cu. Ft. per Lb. 10.12 11.74 13.56 15.61 0.0234 0.0235 9.0236 9.0238 25.45 22.14 19,35 16.95 17.91 20.46 23.30 26.46 29.95 33.79 38.02 42.67 47.75 53.50 59.39 65.91 73.03 80.75 89.09 98.03 107.7 118.1 129.2 141.1 153.9 167.4 181.8 197.3 213.8 231.2 249.6 269.2 289.9 311.6 0.0239 0.0240 0.0241 0.0242 0.0244 0.0245 0.0246 0.0248 0.0249 0.0250 0.0252 0.0253 0,0255 0.0256 0.0258 0.0259 0.0261 0.0263 0.0264 0.0266 0.0268 0.0270 0.0271 0.0273 0.0275 0.0277 0.0280 0.0282 0.0284 0.0286 14.89 13.15 11.63 10.32 9.19 8.20 7.34 6.583 5,920 5 336 4.820 4.364 3.959 3.599 3.278 2.992 2.734 2.503 2.296 2.109 1.940 1.788 1.650 1.524 1.408 1.305 1.210 1.122 1.042 0.970 Meat of \ aporization, B.T.l. 601.9 598.3 594.7 591.1 587.4 583.6 579.9 576.1 572.2 568.3 564.4 560.4 556.3 552.2 548.1 543.9 539.7 535.3 531.0 526.5 522.0 517.5 512.8 508.1 503.4 498.5 493.5 488.5 483.4 478.2 472.9 467.4 461.9 456.3 Sp. G. Liquid 0.6364 at 32F. 26TH EDITION Page 161 0683901 TOWOLDMONOQ41985 ALUMINUM CHLORIDE 60 60 F. Bii-choff _.L S p e c ific G ra vity ti }g to a a.< .00 SO 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17,00 1.0000 1.0035 1.0069 1.0105 1.0140 1.0175 1.0211 1.0247 1.0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0584 1.0623 1.0662 1.0701 1.0741 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1.1111 1.1154 1.1197 1.1240 1.1284 1.1328 .00 .35 .75 1.17 1.58 2.00 2.40 2.78 3.16 3.58 4-00 4.38 4.81 5.20 5.63 6.05 6.50 6 92 7.32 7.75 8.13 8.57 9.00 9.46 9.90 10.28 10.70 11 IS 11.60 12,05 12.50 12.95 13.37 13.83 14.30 Li h jt t| 5 ty t _* XV a.< 00 .038 .113 .178 .242 17.50 18.00 18.50 19 00 19.50 .307 .370 .430 .490 .557 20.00 20.50 21.00 21.50 22.00 .625 .686 .756 .820 .890 22.50 23.00 23.50 24.00 24.50 .962 1.04 1.11 1.18 1.25 25.00 25 50 26 00 26.50 27.00 1.32 1.39 1.47 1.55 1.63 27.50 1 28.00 28.50 29.00 29.50 1.70 1.77 1.85 1 93 2.02 30.00 30.50 31.00 31.50 32.00 2.10 2.19 2.27 2.35 2.44 ! 32.50 ! 33.00 ! 33.50 1 34.00 1 34 50 1 1.1373 1.1417 1.1462 1.1508 1.1554 1.1600 1.1647 1.1694 1.1741 1.1789 1.1837 1.1885 1.1934 1.1983 1.2033 1.2083 1.2134 1.2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3100 14 73 15.16 15.60 16.OS 16.53 16.94 17.43 17.88 18.33 18.78 19.22 19 68 20.13 20.57 21.03 21.50 21.98 22.38 22.82 23.20 23.70 24 13 24.58 25.02 25.53 25.99 26 45 26.92 27.38 27.88 28.33 28.78 29.24 29.68 30.00 L+ < 2 53 2 60 2 69 2.78 2.88 2.96 3.06 3.15 3.25 3 34 3.43 3 53 3.62 3.72 3.81 3.90 4.02 4.12 4.21 4.30 4 41 4.50 4 61 4.72 4.83 4.94 5 04 5 16 5.27 5.40 5 50 5.62 5 73 5.85 5.92 * AljCU +12HjO, Chloride of Alumina For Chloride of Alumina 32B. twice the above pounda per gallon of aohttion. Page 162 MONSANTO CHBMICALS 0683902 TOWOLDMONOQ41986 a JtS i A? 00 50 1.00 1.50 2.0 2.5 3.0 35 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 14.0 14.5 ISO 15.5 16.0 16.5 17.0 17.5 18,0 18.5 19.0 19,5 1 000 1.0035 1.0069 1.0105 1.0140 1.0175 1.0211 1.0247 1.0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0584 1.0623 1.0662 1.0701 1.0741 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1.1111 1.1154 1.1197 1.1240 1.1284 1.1328 1.1373 1.1417 1.1462 1.1S08 1.IS54 26TB EDITION ALUMINUM SULFATE ftO 60 F. Beveridge hi M 4*= .00 .53 1.07 1.64 2.16 .00 .044 .090 .138 .181 2.70 3.28 3.79 4.40 4.97 .228 .279 .323 .376 .427 5.52 6.10 6.73 7.33 7.98 .476 .528 .585 .638 .700 8.56 9.18 9.82 10.43 11.OS .751 .808 .860 .925 .980 11.65 12.26 12.90 13.53 14.13 1.04 1.10 1.16 1.22 1.28 14.71 15.32 15.98 16.60 17.25 1.34 1.40 1.47 1.53 1.59 17,90 18.48 19.13 19.80 20.40 1.66 1.72 1.79 1.86 1.92 21.06 21.73 22.43 23.10 23.78 1.99 2.06 2.14 2.21 2.28 (Continued) = ,, 5I tl4*i-'-J*<53i .00 0,6 1.1 1.7 2.3 2.9 3.5 4.1 4.7 5.3 6.0 6.7 7.3 7.9 8.5 9.2 9.8 10.5 11.1 11.8 12.4 13.1 13.8 14.4 15.1 15.7 16.4 17.1 17.7 18.4 19.1 19.9 20.4 21.1 21.8 22.4 23.1 23.7 24.4 25.1 .00 .050 .092 1.50 1.95 .246 .298 .350 .403 .456 .518 .581 .635 .690 .745 .809 .865 .931 .988 1.05 1.11 1.18 1.2s 1.30 1.37 1.43 1.50 1.57 1.63 1.70 1.77 1.86 1.91 1.99 2.06 2.12 2.20 2.26 2.34 2.42 Ptge 163 0683903 TOWOLDMONOQ41987 ALUMINUM SULFATE_Continued tl U>3 i -2 20.0 20.5 21.0 21.5 22.0 22 5 23.0 23.5 24.0 24.5 25 0 25.5 26.0 26.5 27.0 27.5 28 0 28.5 29.0 29.5 30.0 30.5 31.0 31.5 32.0 32.5 33.0 33 5 34.0 34.5 35.0 35.5 36 0 36 5 1.1600 1.1647 1.1694 . 1741 1.1789 1.1837 1.1885 1.1934 1.1983 1.2033 1.2083 1.2134 1.2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3122 1.3182 1.3242 1.3303 1 3364 S jW c ifK ! G ra vity I 2 so* 24.38 24.99 25.60 26.22 26.87 27.50 28.16 28.85 29.50 30.18 30.85 31.54 32.24 32.95 33.63 3 4.35 35.03 35.75 36.46 37.20 37.90 38.58 39.30 40.02 40.73 41.49 42.20 42.96 43.71 44.48 45.20 46.00 46.80 47.58 til< 2.35 2.42 2.49 2.36 2.64 2.71 2 78 2.86 2.94 3.02 3.10 3.18 3.27 3.35 3.44 3.52 3.61 3.70 3.79 3.88 3 98 4.06 4.16 4.25 4.35 4.45 4.54 4.64 4.75 4.86 4.95 5.07 5.18 5.29 s . v 2 2- i ^ t-2^ -~ * *" r-* 25.7 26.4 27.1 27.7 28.4 29.1 29.8 30.3 31.1 31.7 32.4 33.1 33.8 34,5 35.2 35.9 36.7 37.3 38.1 38.8 39.7 40.3 41.0 41.8 42.5 43.3 44.1 44.9 45.7 46.5 47.4 48.3 49 2 50 1 2. 49 2.56 2.64 2.71 2.79 3 11 3.18 3.35 3.44 3.52 3.61 3.70 3.79 3.87 3.97 4.06 4.18 4.26 4.35 4.46 4.55 4.66 4.76 4.87 4.98 5.09 5.21 5.34 5.46 5 59 FREEZING POINTS OF 0.6% "BASIC ALUM SOLUTIONS Baumj at 60F. 5 10 15 20 25 30 35 Freezing Points, degrees F. 31 30 29 27 24 21 38 Page 164 MONSANTO CHEMICALS 0683904 TOWOLDMONOQ41988 SODIUM BISULFITE 6(1 60 F. H. B. Bischoff * ) Xc7 s ^ y= 3 ii L 2 <23 If <&c 5 '? 2 A4 =3 1. .00 . 50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15 00 15.50 16.00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 1 0000 1 0034 l 0069 1 0104 1.0140 1.0175 1.0211 1.0247 1 0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0584 1.0623 1.0662 1.0701 1.0741 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1 1111 1.1154 1.1197 1.1240 1.1284 1.1328 1.1372 1.1417 1.1462 1.1508 1.1554 .00 51 1 02 1.53 2.04 2.55 3 06 3.57 4.08 4.59 5.11 5 63 6.15 6 67 7.19 7.71 8.24 8.77 9 30 9.83 10 36 10.89 11.42 11.95 12.48 13.02 13.56 1.410 14.65 15.20 15.75 16.30 16.85 17.40 17.96 18.52 19.08 19.64 20.20 20.76 .00 . 3i. .63 .94 1.26 2.2o1.5" 1.88 2.8^2.5) 3 . IS 3.41 3.79 in 4.43 4.75 5.01 5.4^ 5.7? 6.06 6.36 6.70 7.03 7.36 7.66 8.02 8.35 8 66 9.02 9.36 9.70 10. oa 10.37 10.71 11.05 11.39 11.74 12.08 12.43 12.77 20.00 20.50 21.00 21.50 22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00 30.50 31.00 31.50 32.00 32.50 33.00 33.50 34.00 34.50 35.00 35.50 36.00 36.50 37.00 37.50 38.00 38.50 39.00 39.25 1 1600 1.1647 1.1694 1.1741 1.1789 1.1837 1 1885 1.1934 1.1983 1.2033 1.2083 1.2134 1.2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3122 1.3182 1.3242 1.3303 1.3364 1.3426 1.3488 1.3551 1.3615 1.3680 1.3712 21.32 21 88 22.44 23.00 23.57 24.14 24.71 25.28 25.85 26.42 26.99 27.56 28 13 28.70 29.27 29 85 30 43 31.00 31.57 32.14 32.71 33.28 33.86 34.43 35.01 35 62 36.25 36.88 37.51 38.14 38.78 39.42 40.06 40 69 41.30 41.91 42.52 43.12 43.72 44.02 13 13 13.46 13 81 14. 15 14.50 14.85 15.20 15.55 15.91 16.23 16 60 16.96 17.32 17.66 18.01 18.37 18.73 19.08 19 33 19.78 20.13 20.46 20.83 21.19 21.55 21.92 22.30 22.70 23 08 23.47 23.87 24.27 24.65 25.03 25.41 25.79 26.17 26.54 26.91 27 10 26TB EDITION Page 165 068390$ TOWOLDMONOQ41989 B6. .25 .50 .75 1,00 1.25 1.50 1 75 2.00 2.25 2.50 2.75 3 on 3 25 3.50 3.75 4.00 4.25 4.50 4.75 5.00 5.25 5.50 5.75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 8.25 8 50 8.75 Tw.8 .34 .70 1.04 1.38 1.74 2.10 2.44 2.80 3.14 3.50 3.86 4.22 4.58 4.94 5.30 5.68 6.04 6.40 6.76 7.14 7.50 7,88 8.26 8.64 9,00 9.38 9.76 10.14 10.52 10.90 11.30 11.68 12.06 12.46 12.84 MKRCLOR Per Cent Available Cl by Volume .11 .21 .32 .43 .54 .65 .76 .87 .98 1.10 1.21 1.32 1.43 1.55 1.66 1.78 1.90 2.01 2.13 2.26 2.38 2.51 2.63 2.75 2.88 3.01 3.13 3.26 3.39 3.52 3.64 3.77 3.90 4.05 4. 18 B*. 9.00 9.25 9.50 9.75 10.00 10.50 11.00 n so 12.00 12.50 13.00 13.50 14.00 14.50 15.00 15.50 16 00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 20.00 20.50 21.00 21.50 22.00 22.50 23.00 23.50 24.00 24.50 25.00 Tw.9 13.24 13.62 14.02 14.42 14.82 15.62 16. 42 17.22 18.04 18 86 19.70 20.54 21.38 22.22 23.08 23.94 24.80 25.66 26.56 27.44 28.34 29.24 30.16 31.08 32.00 32.94 33.88 34.82 35.78 36.72 37.70 38.68 39.66 40.66 41.66 Per Cent Available Cl by Volume 4.30 4.43 4.57 4.71 4.84 5.09 5.38 5 65 5.94 6.24 6 52 6.83 7.12 7.41 7.71 8.01 8.31 8.60 8.92 9.23 9.54 9.87 10.19 10.51 10.84 11.18 11.52 11.89 12.23 12.60 12.95 13.33 13.71 14.11 14.50 P*l< 166 MONSANTO CHSMICALS 0683906 TOWOLDMONOQ41990 WEIGHTS PEK GALLON AT 60 F. Arctic Acid 28% ............................................... Arctic Acid 56% . ....................... Acetic Acid Glacial . . ................................................... Aluminum Chloride 32 B6 ................................................. Amyl Acetate........................................................................ Aqua Ammonia 18 B............................................................. Aqua Ammonia 20 B#............................................................. Aqua Ammonia 26 B4.............................................................. Battery Acid 1.400...................................................... Butyl Acetate................................................................................ Diacetone Alcohol........................................................................ Ethyl Acetate.................................................................................. Iron, True Nitrate 47 B6........................................................... Iron, Copperas Nitrate 47 B................................................ Iron, Perchloride 40 B6......................................................... Merclor.............................................................................................. Muriatic Acid 18 B4.................................................................... Muriatic Acid 20 Be.................................................................... Muriatic Acid 22 B4.. ........................................................... Nitric Acid 36" B6.......................................................................... Nitric Acid 38 B6. ....................................................................... Nitric Acid 40s B6.......................................................................... Nitric Acid 42 B6.......................................................................... Oleum 25% (at 15 C.)............................................... Oleum 60% (at 15 C.) ............................................................. Phosphoric Acid 75%.................................................................. Sodium Bisulfite 33 B............................................................... Sulfuric Acid 66 B<.................................................................... Sulfuric Acid 98%........................................................................ Sulfuric Acid 100% (Monohydrate)...................................... Zinc, Cholride 52 B4.................................................................... Zinc, Cholride 72 B<.................................................................... Weight per gallon *= Sp. Gr. x 8.337 1 Cubic Foot r= 7.480 gallons 1 Gallon := 3.785 liters Pounds 8 66 8.90 8.81 10.70 7.2 7 89 7.78 7 48 11.67 7.3 7.6 7.4 12.30 12 30 11.51 97 9.67 9.83 11.09 11.30 11.51 11.74 16 12 16 84 13.2 10.78 15.30 15.36 15. 41 13.00 16 56 26th edition Page 167 068390V TOWOLDMONOQ41991 IIVTERCONVERSION TABLES FOR TO CO WERT FROM - ML'LTIPLYBY To Cu. In. To Cu. Ft. To Cu. Yd. To FI. Oz. To Pint To Quart T-< Gallon Cu. In. Cu. Ft. Cu. Yd. FI. Oz. 1.00000 1728.00 46656.0 1.80469 .0,5787 1.00000 27.0000 .001044 .0,2143 .037037 1.00000 .0,3868 .554112 957.505 25852.6 1.00000 .034632 59.8442 1615.79 .062500 .017316 29.9221 807.896 .031250 .004329 7 48052 201 974 .007813 Pint Quart Gallon Orain Oz. Troy Lb. Iroy Oz. Av. I.b. Av. 28.8750 57.7500 231.000 .003954 1.89805 22.7766 1.72999 27.6799 .016710 .033420 .133681 .0,2288 .001098 .013181 .001001 .016018 .0,61*19 .001238 . 0049,51 . 0,8475 .0,4068 .0,4882 .0,3708 .0,5933 16.0000 32.0000 128.000 .002191 1.05173 12.6208 .958608 15.3378 1.00000 2.00000 8 00000 .0*1369 065733 .788800 .059913 .958611 .500000 1.00000 4 00000 . 0,6850 .032867 . 394400 .029957 .479306 .125000 250000 1 00000 .0,1712 .008217 .098600 .007489 .119826 CC or Cram Liter or Kg. Cu. M. .061024 61.0237 61023 7 .0,3531 .035315 35 3146 0jl3Q8 .00131)8 1.3079S .033814 33.8140 33814.0 002113 2.11337 2113.37 .001057 1 05669 1056.69 .0,2642 .264172 264.172 NOTE:--The small subnumeral following a zero indicates that the zero ia to be taken that number of times, thus .0jl428 is equivalent <o .0001428. Values used in constructing table: 1 inch 2.540001 cm. 1 cu. in. -- 16.387083 cc. = 16.387083 g. H,0 at 48C.(39F.) 1 lb. av. -- 453.S926 g. Page 168 MONSANTO CBBMICAL9 0663908 TOWOLDMONOQ41992 UNITS OF VOLUME AN1) WEIGHT MULTIPLY BY To Crain To Oz. Troy To Lb. Troy To Oz. Av. To To To Lb. Av. CC. or G. Liter Or Kg 252 891 436996 117990, 456.390 7302.23 1460.45 58417.9 1.00000 480.000 5760.00 437.500 7000.00 .526857 910.408 24581.0 .950813 15.2130 30.4260 121.704 .002083 1.00000 12.0000 .911457 14.5833 ,043905 75.8674 2048.42 .079234 1.26775 2.53550 10.1420 .0,1736 .083333 1.00000 .075955 1.21528 . 5780117 998.848 26968 9 1.043)8 16.6908 33.38(6 133.527 .0022^6 1.09714 13.1657 1.000Q0 16.0000 .036127 62.4280 1685.56 .065199 1.04318 2.08635 8.34541 .0,1428 ,068571 .822857 .062500 1.00000 16.3871 28316.9 764556 29.5736 473.177 946.354 3785.42 064799 31.1035 373.342 28.3495 453.593 016387 28.3169 764.556 .029573 .473177 .946354 3.78542 .0,6479 .031104 373242 .028350 .453593 15.4523 15432.3 154320' .032151 32.1507 32150.7 .002679 2.67923 2679.23 .035274 3S.2739 35273.9 .002205 2.20462 2204.62 1.00000 1000.00 1000000 .001000 1.00000 1000.00 1 lb. av. = 27.679886 cu. in H,0 at 4C. (39F.). 1 lb. av. * 7000 grains 1 gal. = 8.34541 lb. 1 gallon = 58417.87 grains. 231 cu. in. = 1 gal. -- 3785.4162 g. To Cu. M. .0,1639 .0,2957 .0:6479 .0,4536 t 00000 26TB EDITION Pag* 169 PRINTED IN U. S. A. 0683909 TOWOLDMONOQ41993 0683910 TOWOLDMONOQ41994 f Monsanto Chemical Company wu one of the Brat to be awarded the INavy "E" and Bureau of Ordnance flag and the All-Nary "E" burgee 'in recognition of production of ordnance materiel vital to our national defenae." It waa alao one of the Brat to be awarded the joint Army-Navy **E" burgee "repreaenting recognition by both the Army and Navy of erpecially meritorioua production of war materials." 0683911 TOWOLDMONOQ41995 0683912 TOWOLDMONOQ41996