Document 0JkJM1z0RaLbYJD8zzQ9GerGn

AR 226-0359 BEHR-00699-313 CompgNY SaNniit.izey fg A355 _ 2=z o= m z2e5 s FLUOROCHEMICAL USE,DISTRIBUTION AND RELEASE OVERVIEW QE4P - Bo - 373 Dupps BAcode 06 20780 Prepared by 3M Company May 26,1999 000003 2 a TABLE OF CONTENTS Page TE 3M Production of Sulfonyl-based FIUOFOCHEMICAIS.oovcvrersssnrssnseossmsonnd 3M Sulfonyl-based FIUOFOChemical PrOUCtS vovvuvresomnsmsssonmsesmssessmssnons Profile of Major Product Categories...mmursmmmenssssssommsmsesmssmssons] 1 Paper and Packaging PrOIECIONS.cuvvarsvssmssssamsssssmssssssssseseesons PerfOMANCE CHEMICALS varanasi10 Ongoing and Proposed Exposure Assessment and Stewardship Initiatives.....o.......1] Chart 1: POSF Fluorochemical Reaction Tree cou... Table 1: FIUOrochemical GOSSAry.cuavsmonsamsmmesssasmsssssnssmssnssm1s4 Chart 2: Product BUilding BOCK... 15 Table 2: Estimated Fluorochemical (FC) Usage by APPICation cvc..nmrmsnsnee16 Table 3: Features of FIuorochemical SUrfactants....mesmmommmmmomsssenl] ApPpCePnCdiAxP1E Appendix 2 BUSINESS......ooc.cvvervnvoronoesssssenssessssonsnoes soos es 10 2049 APpCpePnHdioxm3eTextile BUSINESS.........o...o..ooccovseereersersoens oes er seen 0-100 ApPpCenPdAipxpa4rel andLeather BUSINESS.........v...o.coeeerserrserrsonsoe sesso 01152 3M Aftermarket Appendix 5 Application and Retail ConsumerBUSIRESS..................... 153-194 ApPpEernfdOiMxA6NCE CHMICAIS......ocecovevrerveroeros esses 195-326 PaanpdPaeckagring BUSINESS............o...ovv..ooceerserreessosnsrensoos sees 327-347 000004 2 LJ} IntroductionFLUOROCHEMICAL USE, DISTRIBUTION AN] RELEASE OVERVIEW This paper and accompanying appendices provide an overview of the use, distribution and environmental triheneltseeeansdmeeadotfetrosiuapllrfseosnleyenlatv-aebaptshreeedlcfiolmnuitonrraoorlcyohrfeem3viMiceawltshorf(oFFuCgCsh)ptaphterihorwdeauncydes-dfuosbreyha3unMmd/aConromadpinsdapnoeysna.vli.rTohTnehmiePsnatapaselsreeasxnspdmoesanuptrpeeisnfdprirocimemstaahreryetime qualitative and is based marketing and technical osnupapvoaritlapbelresoinnnfelo.rmation within 3M and the experience and judgmentof 3M's FC g3rMeatuensdtesritgonoikfitchainscreeavnidewseftorprtiowroitpiuerspfoosresi:n-d(ei)pttho squuapnptoirttatiinviteiaelvjaluudagtmieonntosfatbhoeuutstehaenedxpdoisspuorsealscpernoafriiloesooff asenldecottehderFpCropdruocdutcsttse;waanrdds(hiii)ptaoctgiuviitdieesa.ndAlstethopruigohritthieesrfeovriperwoidsucptrerleifmoirnmaurlyatainodn,qucaulsittaotmiever,`ciot mmmauynbiecautsieofnul in providing EPA and other agencieswithan introduction to FC exposure issues. mpe3lanManvnuihfrwaaohscnimtaceulhnrrtievanaildglysltitocnaeackwtleaiunroddnaess.hrfiauIpnrntgiheanoedirdftiimtaaoitcdoitevnie,lositn3nsogMr,beaimdssoueindcniettohonFerCtiphnriegosxcappeonrsesdsluopirfrmedoisendaauvrnceytdlorurpesevileienseagiwsme.auslTcahoattemispo3enrMse.ihnaecnnPldsruidedevloempwirnenosxidptsuorycsetuwaramoenrdakstsoessment support this assessment assessment workplan is i already presented underway. in the final A summary of sectionofthis 3M's stewardship paper. initiatives and expose Because the information in this paper and appendices is preliminary and qualitative, it contains some worst. case estimatesofpotential exposureandrelease levels. For this reason, the information in the paper should be used with caution. 3M expects that more realistic estimatesof human exposure and environmental release levels will be available once its exposure assessment plan is implemented. The 3M ECF Process FCs are components of several important 3M product lines due to their unique and useful properties. As `sucrofmapcotnanetnst,soacftparsodcautcatlsy,sttshefoyrroelpieglobmoetrhizwaattieornaannddopiol,lyrmeedruiczeatsiuornf,acaentdenfsuinocntimouncwhhelroeweorthtehrapnrootdhuecrts would rapidly degrade. organofluorine molecules, In this process, organic feedstocks are dispersed in Hiquid, anhydrous hydrogen 3M Company utilizes a processknownas Simons Electro-Chemical Fluorination (ECF) to synthesize bfeluorreipdlea,caedndwiatnheflleucotrriincec.urTrhenetpirsepdaosmsiendatnhtrcooumghpotnheenstoslouftitohn,ecparuosdiuncgttshcerheaytderdogbeynthaitsopmrsocoenssthheamvoeltehceulseamteo carbon skeletal arrangement as the feedstock used, but with allofthe hydrogen atoms replaced by fluorine. However, fragmentation and rearrangementofthe carbon skeleton can also occur and significant amounts of cleaved, branched and cyclic structures may be formed. The degreeoffluorinationofthe organic feedstock is aalsseoledcetpreicnadlecnutrruepnotanntdhe tshpeecliefnigctchoafrtbionmechtahien length ofthe process is run. feIetdisstopcokssainbdleptaorasmynettheerssoizfe tfhuellEy CflFuoprrioncaetsesd such. or perfluorooganic molecules where allofthe hydrogen atoms ofthe hydrocarbon feedstock have beenreplaced cbryeaftleudorbinyefautrotmhse.r reUascitniogntshweistehpefrufnlctuioornoaolgiazneidc hmyodlreoccualrebsoansmboalseicculbeusi.lding blocks, unique chemistries can be 3 000005 -- st3ihtMeesSbiiunimlotthnteshUeEnfCiitrFsetdpmrSaotncauetfseasscfutosurirntighnegthpperiolEdoCtucFstciapolrneocoEefCssfFl(upCrooortcotecashgseeiiGcnrao1l9vp4er9o(dpaiunlcdottsh.parsCoucdrourncettniitnoluyne,od3nltMyo)d,heaMvseNtl,horpCeoearnmddaonviumfparcotvuering ADnectawteurrp,,ABLe)l.giFuCm.production using the ECF process occurs outside the United States at 3M's a, facility in IL, and IM Production ofSulfony-basedFluorochemicsls pb3eaMrsficlhuabosuripolrodcoitdnaugncebeslduolcsfukoolnffyolnsyfullcubhoarpsiredoded(ufcPltOusoSrFao)nc.dhetPmhiOecShaiFlgshicesosptmrmoperdroucdciueacdltliiynontfhoverooUlvnueimtree4df0lSuytoearatorecsshpuersmiiimncagarlithl3eyMaEtCm3aFMnup'rfoaccetsusr.esAis ifsac1i-liotcytainneqsuualnftointyi!esfolufoarriodeu.nd + The starting feedstock for s Decatur producing POSF Reaction I CaHSOSF + 34HF 1-Octanesulfonyl Fluoride "> ECF CyFiSOF + 17H, Perfluorooctanesulfonyl fluoride (POSF) o`fTbheyperloedcturcotcsheamnidcawlasfltueoorifnavtairoinabplreocceosmspoysiietlidsona.boBuetc3a4us%e-o4f0sl%igsthrtaidgihftfecrheanicnes(nionrpmraolc)ePssOScFon,diatnidonas,mirxatwure fmartoemrilaolts-,toa-nlodteaqnudipfmreonmt,platnhte-tmoi-xptluanrte.prTohdeucperdodbuyctthtehaetlerecsturlotcshfemriocmalelfelcutorroicnhaetmioincaplrofcleuosrsivnaartiieosn issotmheuwshnaott a pure chemical but rather a mix of isomers and homologues. pDeurrfilnugorpormoedutchtainocn,,abreypvreondtuecdtstoatnhde wasteproductsare atmosphere, but a formed. program The volatile is underway waste products, such as to capture and destroy these irneclienaesreastobry. tThehremablyporxoidduacttiosn,.maTnhye otfarwshfiocrhmeardeiinntchoempprloecteeslsy afrleuoirnicnianteerdatweidthath3ydMrocgoernpoartaotemshaszilalrdporeussenwta,ste dciasncbhearrgeecdyctloecdonbtarcoklliendt,oitnh-ehoEuCseF,pwraoscteeswsaotrerarterepaarttmieanltlysydsetgermasd.edTihnesttarbeialtimzeanttiosnlpurdogceesisseesi,thaenrdlaenvdefnitlulaeldloyr land-incorporated. Someofthe non-POSF byproducts are recovered and sold for secondary uses. fPoOrSuFseisasitasneilanfducsotmrimaelrrciaawlmlaytveiraiballe(pmraoidnulcyt,ouatnsdidien t1h9e9U7S)w.asHoswoeldveirn,qutahnetiptriiemsoarfy approximately use of POSF is within 3M, fwlhueorreocithefmuinccatilopnrsoadsucatns.imTphoretmaanjtoriintteyromfediinatteemianllthye-csoynntshuemseidsoPfOsSuFbsitsaunsceeds tuosepdroidnumceanfyunoctthieorna3llMy fdelruiovraotcihzeemdicfalluso,rotchehiermiaccarlosnyamnsd,hcihgehmimoclaelcnualmaersw,eaignhdtfpoormluylmaesr.icTporoadulcetsss.er Texatbelnet,1siodmeentihfoimesolPoOgSuFe-sbaosfed iPnOtSeFr,med[iCaatFeasnien1)tSheO:fForwmhaetrieonno=footthhererth3aMn 8], principally products. perfluorohexanesulfonyl fluoride, are also FPCesr.fluUonrdooecrtaapnpersouplrfioantieccaocniddit(iPoFnsO,S)thweipllerrfelsuuolrtoforcotmantehseuclhfeomnaitcealanoiromnectaanbofloircmhsyadlrtoslywsiitsh omfonPoOvSaFl-ednetrived metallic cations. Current information indicates that PFOS or its salts cannot be broken down further 4 000006 pcrhoedmuicctalflryoumnPdeOrSnFordmearlivleydocfcluurorrioncgheemnivciarlosnamnedntwailllcognednietriaolnlsy. Therefore PFOS is persist in that form. the ultimate degradation PFOS is also a acdodmimteivrecsi)a.l3izMedseplrlsodaupcptrouxsiemdatfoerlya variety ofsurfactant applications (mainly fire-fighting foams and coating gsUeusnliefnrognaylP!cOlfSalsuFsoerasisodfeafmbloauisoeirctiybnouafittlehddienmgamtobellroeiccaklu,sleumnauisdqieunegbcycho3enmMvi.esnttrTiihoeensamclaahjnyobdreriocncrtaeerarbtmoeedndibraeytaecdsteiraoirnvsea.triezpCirhneagsretPnsOte1SdFabntydht2rhooeuugthlitnheethe etthehy"ltpreeref"liunorCohoacrttan1.esPulOfSonFamisidreea(cFtOeSdAw)i.thFmOeSthAylisosruebtsheyqluaemntilnye to produce either N-methyl or Nreacted with ethylene carbonate to trunk form of aeriethtehreNp-rmientcihpyall obruiNl-deitnhgylbpleorcfklsuoofro3oMc'tsanpersoudlufcotnalmiinedso.etBhyanpoolu(nFdOaSgEe),.meTthhyel-FfOoSseAbaansdedFiOnSteErmiendtieartmeesdiaantdes products slightly predominate over ethyl-fose-based materials; nTehceessseacroinlydaprryodreuaccetipounrsepprroodduucctisn.g aTlhleorfetmheasye bdeerviavartyiivnegsaamroeusnitngsleoforflsueoqruoecnhtieamlicbaaltcrhespirdoucalesss(eusnrtehaatctdeodnoort spaurcthiarlelsyirdeuaacltseidnsctlaurdteinPgFmOaSte,rina-lmsetohryilntaenrdmend-ieattheysl)FtOhaStaAreacnadrNri-eMd efFoOrwSaErdatnodtNh-eEftinFalOpSrEoduacltc,ohoElsx.amples of iTnyptihcealalgyg,rewghaeter,erperperseesnetn,ttrhoesueghrleysid1u-a2l%socfantobtealfFouCnpdraotduacctoinocnevntorlautmieo.n (oFfC1-re2s%idourallsesisni3n Mfinparlopdruocdtuschtasvaend, ftlheuoprootcehnetimailcatlo dmeoigertaideesoardmdeetdabtooltihzeestuolfPoOnySl.f)luoIrnidaeddgirtoiounp,odfurPiOnSgFprcoadnucatlsuosebeorredimsopvoesadl,thtrhoeungohna-variety osfpedceigersawdhaiticohnipsruolcteismsaetsel(ychpermoidcuacle,deansviarroensmuelntotaflsaunchd mdeetgarbaodlaitci)o.nIwnilslucghenienrsatlalnycebse, PthFeOfSluaosroweclhle.mical IM Sulfonyl-based Fluorochemical Products 3ThMem3aMnufCahcetmuirceasltphreofdiuncatl clionmemsetrhcaitaulsiezePdOSpFro-dbuacste.dIfnloutohreorchceasmeisc,al3sMarseelslusmamfalruiozreodchbeemliocwa.l Iwnhiscohmeancoatshees,r `company incorporates `groups are not listed). into its final product. (Product lines using fluorochemicals which contain no sulfonyl PcOoSmEpodneernitve(odr fFlCuosroolcihdes)mirceaplrses(epnotliynmgers andpemrocneontmeorfst)hearfeorfmourlmautliaotne.dTwoittahlwaU.tSe.r porrosdoulcvteinto,nowfiFthCthseolFiCds parcordosusct3iMo'nosfspruoldfuocntyllibneasseisdafblouuotrochemicals in the U3.SM. pTrhoedubcreedaFkdCoswonloidfs3rMeprFesCenptrodupcltuisonofitnhteo tdoitfaflerent product categories is shown in Table 2. CSaurrpfeatcePrTorteecattomrents (`HwiitghhlMoowlepcerucleanrtaWgeeisghotf n(oMnI-Wp)olpyomleyrmiecrsFCorsfoolirdmsu)lated products Fabric/Upholstery Protector Apparel and Leather Protector Protective Products for After Markets and Consumer Application Paper and Packaging Protectors (Phosphate esters Food Packaging or high MW polymers) 5 000007 LJ Paper Products FPierrefEoxrtmiangnucieshCihnegmFicoaalmsC(oLncoewntMraWteschemical Mining and Oil Surfactants Electroplating and Etching Bath Surfactants Household Additives Chemical Intermediates Coatings and Coating Carpet Spot Cleaners Additives Insecticides Raw Materials substances) Surface treatment products tradename; 3M markets its for carpets, textiles and apparel paper and packaging protective are typically sold under theScotchgard products under the Scotchban tradename; and `some performance chemicals are sold under the Fluorad tradename. sStuarifn,acaendTrweaattemrernetsPirsotdanuccetst.o3peMrsfolnuaolroacpphaermeilcaalnsdphroodmuecefdurfnoirshsiunrgfsa.ceTthreeagtrmeeanttbauplpkolifctathieosnes pprroodvuicdtessaorie, manufactured as high-molecular aftermarket and consumer spray weight polymers alt application contain a hough some significant surface fraction treatment products of unpolymerized used for FC components. Polymeric surface treatment products are primarily N-MeFOSEA-based; the fluorochemical ispolymerized with urethane, acrylate `moiety on the polymer laonwde/roirnagditphaetseurrefaaccteanetns.ergSyuocfth hpreotmeactteirviealprtoodwuhctischfutnhcetyioanretahprpoluigedh. the fluorocarbon Paper Protectors. The 3M paper protectors are used in food packaging and commercial applications. They can `be divided into two general classesofchemistries. One class consists`ofmixtures of mono-, di- and triphosphate esters of N-EtFOSE alcohol, roughly in the proportions of 10%, 85% and 5% percent,respectively. cTlhaessoetshoefrprcloadsuscitssN-haMseFtOheSEefAf-eacctorfyllaotweercionpgoltyhemesru.rfaAcpepelnieerdgtyoo fpatpheer,intdhievpiedrufallupoarpoecrarfbiobenrs`.moiTehtiysilnotwheerseed surface energy greatly contributes to the holdoutoflow surface energy liquids such as greases and oils. Performance Chemicals. POSF derived chemistries used as performance chemicalsarerelatively low 3moMl,ecourlianrcowrepiogrhatte(d<b5y003dMaltcounsst)osmuerrfsacientaocftiovremumlaatetreidalpsroadnucdtsm,onfoormeusres.asSsoumrfeaocftatnhtessiencahermaingceaolfs airnedussotlrdiably or consumer applications. Other performance chemicals are used as intermediates from which 3Morits vcaursiteotmyoefrpsomlaykmeeroithcehryfdirnoicsaherdbopnrobduacctksb.onSeusctho fmlaukoreochhiegmhiercamlolientceurlmaerdoialtiegsomcearnicbeorcopvoallyemnetrliycbporuondducttosawith unique performance characteristics. POSF-derived performance chemicals with fluorochemical surfactant properties differ greatly from scuornfvaecnetitoennasliohnytdorolcevaerlbsotnhaatnadrseiulnicroenaechsuarbflaectwaintths.otIhnermotsyptessoyfsstuermfsactthaenytasr.e far In more some efficient aqueous in reducing systems, surface tensions as low as 15 extremely low values to at 16 dynes/cm can concentrations as be attained. low as 100 The parts fluorochemical per million, o surfactants normally produce less. Equally important is the these fact that certainofthese fluorochemical surface active agents are stable and effective in many extremely hostile 6 000008 --- `esnuvmimraornimzeenstst,heinfcelautduriensgosftfrlonugolryocahciedmiicc,asltrsounrfgalcytaanltksa.line and even strongly oxidizing systems. Table 3 PtAonFuoOgtShh,)eyraentudnriehqsaiuvleieepnbhteyesfniocafamlso.rchmaSaruatccethedrfitosoatrimecssoifuscstuetarhltelayaicnctoiPnoOtnaSioFnfh-ilboagwshemdtoelpmeepcreufrloaatrrumrwaeenicogerhcathgfeglmrueioscrsaiolvcsehiecsmhitehcmeaiilrcs(aailbnisclilatunyddtiovnafgpoorrms. f`iTrheessoerftoorxmiuclaatnidonosbnhoaxvieofuosuvnadpcoormsmaenrdcioadolrsa.pplication in suppressing flammable liquid, chemical andorganic Lrofile ofMajorProduct Categories TFChse.AFpoprenedacihceussetocathtiesgoprayp,etrhperAopvpiedenddiectaeislperdespernotfi:les ofeach ofthe major use categories for sulfonyl-based * Chemical composition information for 3M products. * Adescriptionofthe relevant business, including the scope of FC usage and distribution and locationof key customers. * A synopsisofuse and distribution patterns, including potential exposure pathways during the and initial application opportunities for of FCs by 3M's exposure during customers, potential end-useofproducts environm to which enta FCs l release scenarios are applied. Key information about each use category is highlighted below. Surface Trestment Products * These products provide soil resistance and repellency (fluorochemical products). Industrial, `non-retail customers for products in this class consist of(i) carpet manufacturers and fiber producers who serve the markets for residential, commercial and transportation flooring; (ii) textile mills and commission finishers who produce upholstery fabric for residential furniture, home decor items such as slipcovers, mattress pads and shower curtains, and automotive, truck and van interiors or produce non-woven fabrics for use in medical or industrial applications; and (iii) textile mills, leather tanneries, finishers and chemical gfaorrmmuelnattofrusncwthioonatlrefaatbrfiacbsr.ic and leather used for garments, footwear, accessories and non- may occur. These products consist ofpolymeric FCs with `high molecular weights. Industrial, commercial and consumer exposure is primarily to `pmoolnyommereircicsuFbCstraensciedsu,alaslt(htyopuigcha mostof lly at | the 3M percent products or lower contain low amounts levels) to which some of ex pos ur e * Upon distribution to mills, fiber manufacturers or other customers, the 3M surface treatment product is typically mixed with other additives and diluted. It is then applied to uncut fiber, textile or leather or co-application. Depending raw materials. on the market Application methods include spray, foam, pad segment, the application process oceurs in an enclosed or open operation. In the latter case, mill production workers could have inhalation 7 000009 --_-- paonldylomrerdse.rmSaolmeexapdodsiutrieontaol FeCxspoaslutrheoumgahysouccchuerxdpuorsiunrgepwrooucelsdsbinegporpeedroamtiinoannstsluycthoas drying, shearing, cutting and shipping although exposure levels should be low. * TLohsesseesloosfsFesCcpooullydmienrvsoltovethdeisecnhavrigresoonfmpearnorcteesesxpweacstteedwadtuerirnagn3d Maircureslteoamseesr doupreriantgioinnist.ial aApdpdliitciaotniaolnowfasstuersfa(tcyepitcraelaltymesonltifdsorcmoualtaetdiownisthtoFuCncpuotlycamreprest), afribeerc,refaatberdicdourrilnegatchuetrt,ing, slohsesaersindgurainndg odtohwernsptaeckaamgoipnegroapteiroantsiwoinlsl avnadryarbeytaypppilciaclaltyiloanndbfuillitedisoersrteicmyactleedd.thTaottatlheByC could range between The end-useofconsumer example, vacuuming and articles is another source of FC cleaningof carpets is estimated losses to to result the environment, For in substantial removal of tdihsepFosCalt.reSiamtimleanrtlyo,veFrCtilmoes;secsatropetthecoenntvaiirnoinngmeFnCt caroeatailnsgoseixspaelcstoedlanindfwiallsetdewuaptoenrefnrd-oomf-dlrifye: tchleesaeniintgemasndafltaeurntdheeryinagroefdgisacramrdeendt.s, upholstery and leather goods and from landfilling of * t3hMrosuugrhfarecteaitlreaantdmecnotmmpreordcuicatlschhaavneneelxstefnosridviereacfttetrrmeaartkmeetntaopfpulpihcoatlisotnesray,ndcaarrpeetd,isaturtiobuted interiors, apparel and leatherby individual consumers or professional applicators. + uRseet.aiTlhpersoedupcrtosduicnttshiasrecamtaenguofraycatruereaderbosyoilncdaenpesnpdreanytclneoann-er3sMafnadciplirtoiteescutonrdserfocronrtesriadcetntwiiatlh o3uMtleatsn.d Aarevadriisettryibouftfedortmhurloautgihongsroacreermya,nhuafradcwtaurreedanfdoratuhtiospamratrskestt.orTeyspaicnadlloyt,hetrhereytaiinlclude hnaovn-eptohleypmoetreinctifallutoorodcehgermaidcealtosaPlFtOsSa.ndTrheessieduparlosdautctlsevealrse oifntbeentdwedeefnor occasional. hTohmeeseuse only. * Cseormvmiecersciaanld (3iiM) csoumrmfaecrecitarleaftimlemntprporcoedsuscitnsgarfaecimlairtekse.tePdrotdou(cit)scionmtmheercfiirastlccalteeagnoirnygare ulpiqhuoilds,tewrayt,erc-abrapestedanmadtoetrhiearlssuarpfpalcieesditnhrhooumgehs,locwo-mpmreesrscuiraelobfuipladiinntg-styoprerseptraialyfeuqmuiitpumreent to beouttwleetes.nThese products c- oTnhteaisnencoonn-dpcollaysmsoefrpicroFdCucstolsidisncalnuddersesliidquuiadl,s pihnoctoonccuernatbrlaeticoonastionfg for film negatives facilities. which is typically machine-applied at commercial film processing Paanp dPacekagr ing Protectors * `3pMrodmuacrtkseitmspafrltuogrroecahseem,iociallasnidziwnagteargernetssisttoantchee tpoacpkaapgeirnagnadnpdappearpberoairnddussutbrsitersa.teTsh.esTehey afroeodusaepdplfiocratfiooonds c(ofnotladcitngapcparltiocnast,iocnosnt(aplianteerss, afnododcacrobntoanilneesrss,fobramgss aanndd mwarsapksi)nganpdapenrosn)-. 3 LJ 000010 * bFylupoarpoecrhemmiillcsalwhsiizcihngtraegaetnptaspaerrefaipbperlsieadndt,o tpoapaemruacnhd pleaspseerrbeoxatrednt,subbsytcroatnevserptreerdsowmihnoantly tAprpalniscfaotrimopnampeerthaondds/ovrapraypbeurtboaaprpdroixnitmoawtrealpys,75bapgesrcoerntcaorftopnaspefrormidlelsiurseedoefntdh-uessees.products toycpciucrasllvyiaditlhuetesdizien paresstsa.rchTyhweaftleurosroolcuhteimoincaanldparpopdluicetdrienceaived byc3onMcecnutsrtaotmieonrstoitthe sphaippemrewnet.b,Mwihxipcrhepiasrtahteinond,riterdeattomeevnatpoofratthee the water and converted into rolls paper web, and conversion are all for carried out ilnimoipteednbseycsatuesmesofatlthheoudgihluftleufoorrocmohfemtihcealseizxipnogsumriexttuorweoarnkderpsreisdogemnienraanlcleyocfonhsiigdhered to be meonlveicruolnamrenwteiogchcturFsCasesaterressuolrtopfoslpyimlelrasg.e,Scolmeeanluopssaonfd the fluorochemicals to the releases during the opening, rinsing awansdtreewcaotveerryanodfaFirC(tfootresloosrsedsrudumrsi.ngEnpvaipreornmmaeknitnagl)maenddialafnodrfiFllCs r(feolreadsiesspoisnaclluodfeend-use paper products). * 3usMi'nsg Nfo-oEdtpFaOcSkEagainndg apnroadcurcytlsatienccloupdoelaymheirghbamsoeldecounlaNr-wMeeiFghOtSEphAo.spBhoattheofesttheersperoduced uprnoddeurct2s1aCreERr.egu1l7a6t.e1d70b.y tThheeFfoiorsdtparnodduDcrtuhgaAsdbmieneinssturbajteicotnt(oFcDoAns)ifdoerradbilreecdtifaoloogduceontact abpeptlwieceatniFonDsAfialenddb3yM3Ma.s aInreaisusltokfaasspeestsimtieonntfroerceanptplryovsaulbmfiotrtmeidctrooFwaDvAe ipnocpocnonemction awirtehsutlhtiosftpehtietihoynd,ro3lMyspirsoesfencteertdaainnaplryozdeusctincdiocmaptoinngentthastaPnFdOtShecmoeutladbboleifcocromnevderisnivoinvoofas FC residuals. * 3coMm'psosgiretaisoen,tooilitasnfdoowdatceorntraecptelplraondtupctrso.ducCtosnfsourmneorne-xFpDoAsuarpepltioctahteioFnCsarreesisdiumaillsarisin etxhpeemctiendvotlovebevemriyniomccaalsiboencaalusdeerumsaelsccoenntaarcito.s for paper and packaging products containing I"nEdnivriercotnFCooordpoArdadtiitoinv,esR,eJvainsueadrIynt2e5r,im19S9a9f.ety Assessmentof FC-807 and 8074: Two Fluorochemical-based 9 000011 -- Performance Chemicals Products in this category are distributed and consumer applications, often where foar varietyofspecialized industrial, commercial the surfactant propertiesoffluorochemicals offer cshiegmniifsitcrainets;besnoefmiets.arMeafnluyoroofcthheemsiecaplroidnutcetrsmeadriealteoswcmoovlaelceunltalry wbeoingdhetdPtOoSaF-vdareireitvyeodf polymeric hydrocarbon backbones. volumes are generally small. Since these products tend to serve niche markets, Fire Fighting Foams. aqueous film forming Light foams Water (AFFF) and and AalTcoChol-arreesitsrtaadntemcaornkcsenftorra3teM(pArRo-dAucFtFsFt)hautsaerde to stouxpipcrecshsemaincda/lorveaxptorisn.guTihshefglreaamtmabubllkeolfiqtuhiedsefiprersodauncdtssuaprperseoslsdftloa"mfmiareblfeiglhitqeurisd" awnhdo mix teihtehceronmcaennutaraltleywoirtthhwraotuegrhtaonfaourtmomaaftoeadmsyasntdema.ppUlsyeirtctaottehgeorfiierse ofrorftlhaemmfaobalmes liinqculiudde `cmhielmitiacray,laannddepnevtirroolnemuemntpalalnrtse,mefdirieatdieopanrctommepnatnsi,esv.essTelhse, 3ofMf-fshooarmepdrrioldluicntgspcloantftoarimnsl,otwhe concentrations wfhoiacmhisisdtiysppiocsaeldlyopf,retsyepnitcaaltlyletvherlosuogfh wastewaintetrhetrfeoaatmmenast,apbpultieudn.coAnfttreorllaepdplrieclaetaisoens, ttohe surface water or land are known to occur. M`wientitinnggoafntdheOilsuSlufrufraicctaacniids.or3cMyasneilldsestuhraftaclteaancthsestothceopopree,reannhdangcolidngmithneesamtoouinntcorefamseetal rsetciomvuelrayt.ioOni"lfwoerlmlulsaetrivoincethfaitrmiss iannjdecotieldcionmtpoawneilelss taolseonuhsaencteheosiel sourrfgaacstarnetcsovienrya."wTehlelse products contain low molecular weight FCs present at low levels in the range of MienctlauldePlcahtriongmeanadndElpelcatstriocnipcreEptlcahteinegtcBhaatnhts.plUasteerrsssoefe3kiMngsutrofsaucptapnrtesssinoxthiidsizciantgegmoirsyt for pasurlpioqsuiedssodfirweocrtlkyertoprploatteecrtsi.onE.le3ctMrosnuircfsacmtaannutfsaacrteurseolrds eailtshoeradads p3oMwesurrsfatcotafnotrsmauslasttorrosngor acids in order to etch precise patterns ian silicon wafer or a printed circuit board. The 3M products are formulators, these products typically contain FC solids at levels of + As distributed to or higher but are editlcuhtiendgdbaotwhsn. tBoeccoanucseenotfrtathieonpsroefsenceofst`rwohnegnaacdiddesdantodmoetthaelr pcloartrionsgivoermealteecrtiraolnsi,c Dwiosrpkoesraslowfhtohperesppaernet abantdhsaippleyitthheerbtaothwsasntoerwmaatlelryturseeatpmeernstonfaalcilpirtoiteescotrivteoehqauziaprmdeonuts. waste landfills RCRA. or incinerators when the baths qualify as hazardous waste for purposes of 10 000012 a-- * Household Additives. 3M offormulators to improve surfactants are the wettingof now (or previously have been) water-based products marketed sold to a variety as alkaline ctlheeasneeprsr,odfulcotosr (paollkiaslhiense, cplheoatnoegrrsa,pfhliocorfiploml,isdheenst,usrheacmlpeoanosse)rsaraen(dosrhparmepviooouss.lySewveerrea)l of msearrvkiceetse.dStoomceoonfstumheersa;lksaolimnee pcrloeadnuecrtssaarreesaplrsaoys-oalpdpltioejdanaintdorcioaluladndrecsuolmtmienrcinihaallactlieoannionrg ingestion exposure. surfactants are: The primary exposure route for other products is dermal. The 3M the 3M products contain in the range of As supplied to formulators, FC solids but are then heavily diluted and are present in final products at extremely low levels . * I`nctoemrbmiendeidatweist.h3otMhesrelmlsonliommietredsqtuoanptriotdiuecsoefpfolluyomreorcsh.emTihcealinitnetremremdeidaitaetsessowlhdibcyh 3arMe in `tphreoUd.uSc.edinbcylu3dMe,cfulsutoroimneartsedaraelkbyellaicervyeldatteo ahnadveflturoarceinlaetveedlsaolkfylFaClcroehsoild.ualPso.lymers Coatings additives and Coating Additives. 3M sells fluorochemical polymer coatings and coating which are used as received or dpirliuntteedd wciirtchuiwtabtoearrodrsbourtyplhoatcoegtartaephtiocimfiplamr)t. sTohielsoerpwoaltyermerrespeclolnetnaciyntFoCsurrefsaicdeusal(sinicnlludoiwng ltehvielcske(tnytepirocaalqluye4o%usocrolaetsisn).gsOtuhseerd ftoorpmruoltaetcotrtslea,dmda3rbMleflaunodroccohnecmrietcea.l Pprooldyumcetrssianstahis class have some distribution to commercial and consumer channels. CacrarppeettsSppototclCelaenaenresr.in3wMhisucphplthieesfalunoorno-cphoelmyimcaelripcrofvliudoersocshteaminicaanldtsoofilorrmeusilsattaonrces.ofThese `caprrpoedtusc.tsTahree mFaCrkceotmepdontoenctoonfstuhmeesres ipnropduumctpsaisndpraeesreonstolatclaenvselfsorofspray applicatio: n to * Insecticides Raw Materials. The 3M products aprhearporaohceasnstes,d cboymf3iMelcdusanttosmearnsdiantvoaraicettiyveofinhgoruesdeiheontlsd ainntsb.aitThsteasteiopnrsofdourctlesafacruetutseerdants, `mTahienfllyuionroccohmemmeirccailaslaraendpriensdeunsttriinalthaepppleisctaitciiodnes.formulation at levels of OngoingandProposedExposure Assessmentand Stewardship Initiatives pBlaasnendinognathvearrieestuylotfsostfetwsaridnisthiailpparnodduecxtpuosseu,rdeisatsrsiebsutsimoenn,tainnditriealtievaesseionvteernvdieedw,to3bMetthearscuhnardaecrttearkiezne otrheis haingdhersetleparsieorlietvyelhsufmoarnpraondducetnsvicornotnamiennitnaglPeFxpOoSsuorrePpFaOthSwparyescuwrhsiolrestaking initial steps to minimize exposure n 000013 ----- 3M has undertaken extensive research and development programs to reengineer POSF-based products to reduce PFOS and precursor residuals and ultimately to transition to chemistries with loweraccumulation potential. 3M has updated aimed at helping ftlouoprroocmhoetmeiciamlprboavseedduMsSeDaSn'dshaannddlhiansg begun an industrial of fluorochemicals hygiene program with customers and reductionofoccupational exposures where appropriate. As partofthis program, 3M has volunteered to make available its industrial shiymguileanteiopnrosfteusdsiieosnatlosdfeotrerqumailnietaptoitveentwioarlkcpolnasceumaesrseesxspmoesnutrsealtecvuelsstofomrerFCfascirleitlieeass.ed3dMuriisnaglssoprcaoyndapupcltiicnagtiuosne ofsurface treatment products marketed to consumers. Exposure Assessment Plan Overview Building on 3M's initial assessmenat plan also has been developed to assess potential environmental exposure pathways associated with detailed descriptionofall the the manufacture, use exposure/product asntdewdairsdpsohsiitpioinnitoifatmiavjesoris3bMeyfolnudortohcehsecmoipceaolfptrhoiduscptas.perAbut the four principle components are as follows: I) `The characterizationoffate and transport properties is being addressed in multiple steps. The specific projects planned and/or initiated to characterize fate and transport propertiesoffluorochemicals are: @ Physical/chemical properties testingofpersistent fluorochemical degradation products paosiwnet,llboaislisenlgepcotiendt,flvuaoproorchperemsiscuarle,prdoidsuacstss.ociTahtiiosnicnocnlsutdaenst,(whyhderroelyaspipsl,icwaabtlee)r:somleublitliintyg, air/water partition coefficient, octanol/water partition coefficient, soil/water partition coefficient, bioconcentration in fish. b) Photodegradation studies ) Atmospheric chemistry evaluation d) ) DSteuvdeileosptmoeanstsoefsaspaperroopbriicaatnedmaondaeelrsobfiocrbitohedepgrreaddiacbtiiloinotfyphysical/chemical properties of fluorochemicals not tested. 2) Using the initial estimates `manufacturing, the supply in the chain, attached use and assessment and sales data from 1997, releases disposal at all steps are being estimated for the from products identified as important. Release data is also being determined by sampling and analysesof 3M `manufacturing plant processwastes and effluents. In addition to providing the information necessary to assess distribution and exposure, substantiate results from sampling. release estimates will aid in determining It is anticipated that this effort may also sampling sites identify those and fluorochemicals which require further analysis of fate, transport and exposure. 3) Modeling and sampling is being undertaken to estimate fluorochemical concentrations andbetter characterize the distribution of FCs in the environment. These activities are to be conducted in an iterative fashion and will become refined and focused as more data become available. Thespecific projects planned and/or initiated to characterize environmental distribution are: 12 000014 i a 4) pErxipooristuirzeedlpevreoldsucftosr awlilllpobsesiebslteimpaattehdw.ayWshtehnatrceoluelasdelaenadd tdoishturimbautnioencodlaotgaicbaelceoxmpeosauvarielafbrloem, tthhee most ithmepsoerthaynptotphaetshewsayasndwdielltebremhiynpeotthheesiimzpeodr.taenrtaptaitvhewsaaymsptloinbge aunsdedmoinderlisiknagswsielslsmbeente.mpTlhoyeesdpetcoiftiesct projects planned and/or initiated to estimate exposure are: SUMMARY eEnffvoirrtosnamreentu.ndTeorwaauygmaten3tM3tMo'asssienistsiatlrheevriisekwoafnPOexSpFosbuarseedas3sMessfmleunotropclhaenmifcoarlPsOtSo Fbobtahshedumfalunorhoeaclhtehmaincadlsthies being EPA. iAmpPlOeSmeFntbeads.edAfslunoerowchinefmoircmaalteinovnibreocnmoemnetsalav"awihliabtleepiatpweirl"l be summarized and communicated is currently being prepared and will to the be submitted upon completion. 13 000015 Chart 1 POSF Fluorochemical Reaction Tree Alcohols FFaattyy Acid Phosphate Esters Adpates [TT Urethanes Cepsymers. Roryiates ---- ani Sines ides Carboxyites Oxazoldinones, Akoryates (N-AkyerudicSiEhesufonamide) Amines Quatemary Ammonium Salts Amphoterics (PerfuoroocPtOanSeFsafonyl fluoride) Sulonates (PFOS) 14 000016 ---- ET fp Ee C Cr o h-- em ---- C le e e C e n ] : rf ee, oe fe 5 [Feros EhINeEee e ent e] Ee eo et de SS . 1` 000018 --_---- Table 3 Featuresof Fluorochemical Surfactants SURFACE ACTIVITY AQUEOUS SYS i. `mSomseosf thaeesdesfurifamctoantsclaonw cloownecrnsrurtfoancset.enTshioenytwoelecssithnane1i6 dramaticallyreducingsurfacetensionin awidevaroifaequteoyus Nmeodwi,AiQnUclEudOiUngSaSciYdiScTaEndMbSasic systems. Flsorochenical Sura ave be devclpe which wisuly ssnredlduiscnceisnuryifanecceustiennd:sioinlsvnoefgmaasncyihoergc anficlmyee s rtd okabaiodnus ta t2e0nds Ere ScRehtdiuencgsedopfsurafvaaicreitseesnonsfidotnoseyreismulletilni.tnhectaobinthigohilmpirovvtoeetyhse TSiBLeoEwcTssTiEpcRpoeSnoPsreRcnnEoiAuoaDsnIeNiI hnGiaconmdgbitsoibfolnisv,idtchroouvewenadtoicpw} rcsnoinng comings spe oles wes REDUCED WATER 8 i iBeocnaiuzseeodfwretducnedidnropgletpfeorrsmiaotinon,thebneeecdfioradtiset,illoerd TSMhAsLmLaERleGAgSsSbUbBBcLEprSoduced he sho al dig Scheenicapleccrheinigownilsl hve es tendfeo andhcerye, granodcawse SMALLER DROP FORMATION Sole tops ve dest nn rs miss, BETTER LiQUI PENETRATION Tphceercearberdso ecaulse,its mon trough sll pore IMPROVED FIL UNIFORMITY dSmeosotshi, nms cen fins re produced omplshes, shes ELmetsvieonnceosings pple 0ic owe sures ca show greatly improved leveling with the additionofsmall quantities of Bommaiacits, PorMING a `6Sdtarblae foams ms cayn ibedprso,ducwedhitn hSosotilme maednia ssuchh as nchreomigc s -- rsnrIrATltIoONt tive ss-- ellin-- werri `phieccilyopimsooshi,dwnhpetegTpsroermeirsncoampscder CSher miey Soofmteees civ ss sable fn such rigors ceonncveinrtosaisnhlmoatechinro,tmishcorascid,roaonmhyderouts hoydroaznine, hdotnd Whe lof these marr have vr good suits moder temperatures, afew can withstandtemperaturesinexcess of 300F N fair E Tphe0ersSemate2arreinaoarnmlalwsyeeiflfeatccexttorienmvelecy nlowof 00 pars 7 000019 -- 18 L 000020 SANITIZED COPY l Protective Chemical Products Carpet Business Fluorochemical Use, Distribution, and Release Overview 000022 20 ----- Foreword Thbuisisnreesps.ortItiasttaecmopmtpsrteobaenasswiveerltohoekfaoltleoxwpionsgurqueetsoti3onMs. fluorochemicalsintheFloorcoverings ++ WWhhearteprdoodeuscetxsaporseucreuhaspptenoe?xmposeedr1s0? + Whattypeofexposiusriet? siTenhgvomele3vniMtnfsgamnuldltuisupeldefo3oMrrpmurblouotdsiiupnccletessesthnhiasdtpcearoromdepmualcpetpixsl.iaencddtgoalmoubllatli.pMlaersukbesttsrasteersv,esdoalrdiehnitgohmluyltfirpalgemmeanrtkedet Sources Informationforthisreportwasdevelopedsolelyfrominternal 3Msources.Theseinclude: + + BKensotwelsetdimgaetoesfporfoednudc-tuhsaenadplpilnigcaatnidounssferpormakctnicoewsnfcruosmtfioemledrsaaclteisvaintidetse.chnicalpersonnel + Internalsalesreports Knowledge ofworldwideactivities (whereapplicable)byStPaul-based personnel How ToRead ThisReport SitPuraotviiodneAsnbalyasis:ckon bgusirnesosanudpronducdts. Dis`tFOrboijlbelucottwiisvotenihCehptaaoitihndeaoanftdaif3yPaMolilfnpltousioonfrtoCscoohneftmcaioccntatl:atchtrwoiutghhoouurttchheedmiisctarlisbu--tfiornocmhaarirnitvoalfoinnacluesntdoumseerr'.s loading dockthroughproductusageanddisposal. Exp`ocAstutreh mepItnste fwooirqtmum haaitnntitioihfneyCdthiycasptrertiasabn:udtill oenncghtashionf.exposure and numberofworkersexposedtoour S`uCmommabriyneTsa3blMep:roductdetailwiththe expboypsroduucrttyepe. exposure routestoprovide asummary oftotal business 000023 2 -__-- Table of Contents I Chemical Names IL Situation Analysis A. Business Definition B. Market Segments C. Fluorochemical Usage D. Customer Location Map IO. Exposure Assessment A. Distribution Chain / PointsofContact B. C. AEpxpploiscuarteioRnoMuteetshods and Disposal D. End User Information E. Summary Table 000024 22 i ----- Chemical Names 000025 oo 23 { Chemical Names iTnhdievfiodlulaolwpirnogdiusctasl.isTthoeffCohlelmoiwcianlgAibnsftorramcattiSoenrviiscperses(eCnAtSed):namesandmumbersfor GenericCode:Indicatesanintemal3Mdesignationoftheproduct(s). CAS Number:IndicatestheChemicalAbstractsServices number(s)offluorochemicals ICnhdeicmaitceaslthNeaCmheem(iccomapllAebtsetCraAcStsnSaemreviocresTnUamPeA(Csn)oamfefsluiofrCocAhSenmiacmalesdcooenstanionteedxwiistt)h:in each product. ChemicalClass:Indicates ashortened,genericchemicalname. 000026 2 > a RE E e Chemical Names re e---------------- P cpsi.ecas| om [onfE ii SFE --7 0 mre Pes -------- EE E _--t--t ------ a S Situation Analysis 000028 LC 26 Situation Analysis -- Flooring Business Segment Business Definition ``Twhhisosmewgmeesnutpipslcyofmlpuroirsoecdhoemficcaarlpaentdmasntuafinabcltoucrkeerrsparnotdefcitbievreptrroedautcmeenrtss tfoor (cfarlpueotr.ocThhemeisceaplrpordoudcutcstpsr)oavniddestsaoiinl rreessiissttaannccee (asntdairnebpleolclkeernsc)y. TheFRleosoirdinegntBiuaslinCeasrspUentit defines its markebyt the following segments: Commercial Carpet Transportation Carpet * Arca Rugs (minimal activity) Touhrebfuoslilnoewsisnignttwhoospeagseegsmfeunrttsh:erdepictthe Flooring Market Segment and 000029 -_---- 27 1998 U.S. Flooring Market Segments / oe Residential Carpet | Feta *Replacement DIY +YovCooottn . f< Market Size - MMSq. Yds. 912 ow Commercial Carpet + =iposyd Specifier TE Tienszenigion arpet + AutSRoomeooetpiveesnt SE + RaCaannttrarrsvencs eeMarine Fe Area Rugs +ceatue r *Tufted Rugs 363 108 181 Fluorochemical Usage `Thistableissimply abreakdownoffluorochemicalproductsbyvolume. Thesevolumes arethenfurtherdivided by applicationmethod.Thesenum areb base edor nsas les volumesand 3Msourcesincludingsales,technicalservice,andmarketing. 000031 29 -_---- 000032 LJ 30 ProductVolanu dUsme Paettesrns c`hTehimsissturmym,aursyepiasbtatseemd,eoxnpionsduirveidaunadleparovdiucrtos.nImteinsftaatadel.escrofithpe aptpliicaotionn, Product Code:Generic product description. TAphpelircoauttieoonf,ePxrpoocseusrseo,rtEhencdoUnsceen:tTrahteiopneorsfpeflcutoirvoefchreommiwcahli,tchheeuxspeopsautrteewranasnadstsehsesed. feonrvimroornemtehnatnalofnaetaepmpaliycvatairoynw.ithapplicationprocessorenduse --productscanbeused PGreonceersasl:lyustehoe ffofllowlingduefioniticroonnstaoapipnliycn:gphrode uctimnaniothcerpa rodulct. EAnppdliUcsaet:iouns:euosfetorfefatedlsubustraote rcono taincingphrodeuctmtotrieatc a suabstl rate VolumeFCSolidsSoldin 1997: Poundsof fluoroscolhidessomldiinc1a99l7. (M=1000) liCshteemdiasttrtyh:ebGeegnienrniicndgeoscfrtihpitsiosnecotfiofn.luorochemical ingredients. Full chemicalnamesare un%rReeascitdeudalosr:parStuiamltloytraelaocftecdosntcaernttirnagtimaotnoerfitalhseomriixnttuerremoedfifaltueosr.ochemicalsthatare UcseoPamttmeren:arInnddciccioantaseusltmeh,re.majorsector whereproductisused;food,industrial, MdosetLirakenmldyinRahoaullatteio,onf.ExMpaorskurset:heIdmeontsitfileiskterleyreopuotteeontfiaelxrpooustuerseowfietxhpaonsu"rXeTM;.ingestion, iEnncviinreornatmieonnt,awlaFsatteew:atIdeernttirfeiaetsmtehnet,maonsdtdliirkeecltyldyitsopwoastaelrr.outefortheproduct;lands, Comments: Providesadditionaldescriptiveinformation. ``Tchuisstionmfeorrsmhaatnidolneis3bMafsleudoornoc3hMemiinctaelmpraoldkuncotwsl.edIge nandfbesowteassr ticmoammtpeislaoend hftroowmiavaoilanble 3M sourcesincluding sales,technicalservice, marketing and regulatory expertise a 000033 LZ WREN EE [[aee]s| Len lz [Leiena mramn] onliz) gblnes im {Tem| Product Volumes and Use Patterns LNoP P | LT ALA N e YPn POIe of LITT LTT wl F TTL TT T el LLLa] Ie LIT] [ e Leee] ELE] CustomerLocation Map TFlhoeorfionlglsomwianrgkUe.tSs.emgamepnitd.enTthifeigersatyhseclaolcaetkieoynionfdicchaetmeiscwahlepruercaphpalsiicnagtciounstoofm3erMsin the fluorochfoercmaripectoacclurss.Treatedgoodsarefoundthroughoutthe UnitedStates. , 000035 a [CarpetTreatment Breakdown 1. ig co | 1 LLe o < :N EA Ty . Exposure Information 000037 --- 35 DistriChbauint/iPoointnsof Contact `uThlistdiiagmernaadmturseeep.reIsternetpsrtehseenptastahntohveer3vMiperwoodfubcotttahktehsefdrisotmrtibhuettiionmcehiatilneaavnedst3hMetoits sdiigsutirfiibcutainotnpocihanitnsorefpcroensteancttswthheetryeptihceal3uMseporofdtuhectpmroadyubcetlhianned;lneodteavnedruysperdo.duTchtiwsill go thmroaughreakchbesatseetpd.oTphni3sliMnftaoercmhcantiiceoanl wsaersviccoem/psaillees dvfriomasn3dMigientnteerrsanlaliknnofwloerdgmeafortfotimhtoehne `customer interactions. 000038 36 -- : ContectComper Distribution Chain/Points [nim] [am] [FiberManfachesGvenioy] Se Baer [i][0][min] [a[] oe] E-- : (teem [Retsump] I | lean [ir] = [ek a] [Rs [emia] ir, 3M Fluorochemical Exposure Information `FAlrlomitnfhoerPmoatiinotnsoisfbCaosnetdaocnttfhleouwscheaarntd,eahcanhsdltienpgionfth3eMcuflsutoormoecrhuesmiecparlosc,emsastiesriiasloslated. `containing 3Mfluorochemicalsandarticles followinginformationispresented: treated with 3M fluorochemicals. The PoofiConntatct: Describesindividualstepsintheusepattern. ModsetLirakenmldyiRnahoaulltaetio,ofn.ExMpaorskurset:heImdeonstitfliiesktehlyrreoeuptoetoenfteixaplroosuutreeswoiftehxapnos"uXr"e.;ingestion, EfsotriemxaptoesudrNeudmubrienrgoufsWeodr.kers: Indicatesthenumberofworkerswhomayhavepoteatial eEsxtpiomsaetdedduErxipnogsuusre.eTime: Indicatestheamountoftimethatworkerspotentiallymaybe `Physical Form:Indicatesthe praottidmeoufexcposutre. physicalstate (liquid,solid, aerosol,orvapor)of the Openor ClosedSystem: Opensystem:is fluorochemical. definedas onethatallows workerstocomeindirectcontact with 3M. Ctolocsoemdesiynsdtierme:citcsodnetfaicnetdwaitshon3eMthfaltu,ournodcheermnicoarlm.al conditions,doesnotallow workers Comments: Providesadditional descriptiveinformation. `cTuhsistionmfeorrsmhaatnidolneis3bMasfelduoornoc3hMemiinctaelrnparlodkuncotwsl.eIdngfeoramnadtbieosnwteassticmoamtpeisloendhforwom available 3Msourcesincludingsales, technical service, marketingand regulatoryexpertise. 000040 8 LLLLESma E TTT em a EE ap NS TS == I=i PE EE mm ee eo = re a hee Emme PP ttt rrr amet LeDLLF TLTPT now| Donor elLL Lo LL TTT [ome| |[r T rrT r TT t T homme ol Tu[0To | mn] F3 e aSure ttalo] a1 urS TSrBr s rSy | ge r I I HPr Sr PI r I r YIr I py 4 Ff cH E------------ -- --P-- S --P-- O ---- -- --I-- --I-- --I-- [3SemmT ston [5 Tw 0p To | [x[e Je--m--ma] |pfoE medeerg[--T I P xT7TWT A 1 w P X TT P x Too Commgg | ee Dl To a ela |] pp [ee] ------ CF ow TT1 1 r 1 r r 1t rr T r `PrFolodwDiuagcratms Thesediagramsshowthe places that 3Mfluorochemicalsare introducedandlost in the lifecyoc f al carpe et. Eachapplicationmethodisbrokenout separatelyinorderto show greaterdetail.Thisinformation is basedon 3M internalknowledgeandbest estimateson howcustomershandle 3Mfluorochepmroidcucatsl. Inforwamscaomt piliedofrn om available 3Msourcesincludingsales,technicalservice,marketingandregulatory expertise. a 000043 a CP-3, CP-5, CP6 Product Flow Diagram cp-1,CP2, CP-3, CP4 Other Fiber "Fiber with T3reMatFmiebnetrs CP-3, CP-6, CP-7 Tufting and Dyeing @ cpr El * More detail on the p`poluincdaotniotnhebofxoellsocwainngbpeages. Shearing and. Trimming =| N 42 000044 CEE. Fiber Treatments ' CP-3, CP4 . -[ F Dilution Ratio: Non-FC Chemicals InBath: Amountof Use: Exposure Routes: Spin Finish Oil Dermal FC fiber treatments for carpet a 000085 oy Spray Application ' CP-3, CPs, CP-6 re - Dilution Ratio: Non-FC Chemicals In Bath: Amount of Use: Exposure Routes: Product : None carpet treatments Ingestion, Dermal, Inhalation 0004 Foam Application CP-7 - -{ J Dilution Ratio: Non-FC In Bath: Chemicals Amount ofUse: Exposure Routes: Product : Bath Foaming Agent Dermal FC carpet treatments #000047 : Co-Application } LF Dilution Ratio: Non-FC Chemicals In Bath: Product : Bath Product : Bath Amount of Use: Exposure Routes: Dermal FC carpet treatments w 000043 uumm-- Waste Disposal* or Total carpet mil solid waste is approximately 60,000,000Ibs year. This waste includes Thisequalsabout 1 shearing, selvedges, and backed to 1.5 MM ofwasteper year. seamcuts. AA 10010 115 8] per side LV Unbackedseameuts are typically recycledintocarpet underlayment. Sroemcoeveshreeadirfianguwsaestisefiosubnedinfgorlaitn.dfilledseparately sothatitcanbe * TheFifbleurorTorcehaetmmiecnatlsp(oCrPt-i3on/oCfPs-h4e)aring waste is as follows: TopiAcpaplroTxriemaattmeelntys (mainIlbys.CoPfs-o6l)ids in shearing waste * ASwpiptrcohxiinmgatferloym sp.rayinIgbsa.nodfsfoolaimdisnigntsohceoa-raipnpgliwcaasttieon would reduce this amount by up to. distributed on the fiber. because the treatment isevenly When carpetiscleaned,thewastewaterwill contain OEM fluorochemical. The majority utilities. ofthewastewater treatment burden lies on the local Whena typical residential carpet is thrown away, it contains * These numbers were generated internally based on customer tihnefoyrcmaatniboen.coTnhfeisremendumbbyetrhse airneduisntrtye.nded to be used as estimates until 47 000049 ~C-- End User Information ' Typical Use Theaverageresidecanrpteitsaeels 15,000foottrafpferiyecasr. . Carpetsarevacuumedevery 1to 2weekson average. Carpets are professionally cleaned ever3y years. Durability Factors contributing to removal: TTehmepperHoaftutrheeofctlheaenicnlgeasnoilnugtisoonlution The typeofsurfactantsthatareused Lifetime of ResidentialCarpet . Residentialcarpetisin a home for an average of 12years. A graph representing next page. the - removal of OEM treatments can be found on the @ 000050 GEE 000051 49 QE-- Protective Chemical Products Home Textiles Business Fluorochemical Use, Distribution, and Release Overview Home Furnishings, Home Fashions, Automotive Nonwovens 000052 ` 50 Foreword `This report is a comprehensive look at exposure to 3M's fluorochemicals in the Home `Textiles and Nonwoven business. It attempts to answer the following questions. + What products are customers exposed to? + Where does exposure happen? + What typeofexposure is it? `The 3M fluorochemical business is complex and global. Markets served are highly fragmented involving multiple 3M products that are. applied to multiple substrates, sold into multiple market segments and used for multiple end products. Sources of Information For This Report Informationforthis report was developed solely from internal 3M sources. These include: * Knowledgeofproduct handling and use practices from field sales and technical personnel. * Best estimates of end-use applications from known customer activities. * Internal sales reports * Knowledge of worldwide activities (where applicable) by St. Paul based personnel. How To Read This Report `The following typesofinformation are available in this report: Situation Analysis: Provides background on business and products. Distribution Chain and Points of Contact: Follows the pathof a 3M fluorochemical throughout the distribution chain to final end user. Objective is to identify all pointsof contact with our chemicals -- fromarrivalon customer's loading dock through product usage and disposal Exposure Information Charts: Attempts to quantify type and length ofexposure and number ofworkers exposed to our chemicals within the distribution chain. Product Volumes and Use Patterns: Combines 3M product detail with the exposure routes to provide a summaryoftotal `business exposure by product type. 898053 aa Home Textiles Fluorochemical Use, Distribution and Release Overview Table of Contents I Chemical Names IL Situation Analysis A. Home Furnishings, Home Fashions, Automotive 1. Business Definition 2. Products and Markets 3. Application Methods 4. Customer Location Maps B. Nonwovens A. Business Definition B. Products, Markets, and Application C. Customer Location Map II. Exposure Assessment A. Home Furnishings, Home Fashions, Automotive 1. Distribution Chain 2. Points of Contact 3. Exposure Routes 4. Waste Stream/Recycle Characterization 5. Product Volumes & Use Patterns B. Nonwovens 1. Distribution Chain 2. Points of Contact 3. Exposure Routes 4. Product Volumes & Use Patterns 2 0000s -_---- Chemical Names i`Tnhdeivfiodlulaolwpirnogduicsatls.istThofeChfeolmliocwainlgAibnsftorramcattiSoernviiscperse(seCnAtSed):names and numbers for Generic Code: Indicates an internal 3M designationofthe product(s). (CAS Number: Indicates the Chemical contained within each product Abstracts Services number(s) of fluorochemicals Chemical Name (complete CAS name or IUPAC names if CAS`namedoesnot exist): Indicates the Chemical Abstracts Services name(s) of fluorochemicals contained within each product. Chemical Class: Indicates a shortened, generic chemical name. 53 000055 - 3 LJ cnn [oa [ose] omar imomr Teenseremem: i sE yE ---- hPEEoe HeSSmy1 7 * gg:z m[aJem or ores] PB Et yr --t-- Pp Er] be t-- pp | g [=Tova]mreerrsrroomcalmNanes--ocran] Em = EE ---- ---- ---------- -- EE -------- -- 2 IL Situation Analysis A. Home Furnishings, Home Fashions, Automotive Business Definition aHnodmceomFmuirsnsiisohninfgisni--shTehrsi)sssheagrmienngta ics ocmommpornisneededoffOorEpMrotceucsttivoemetrrsea(ttmeexntitlseswhmiilclhs ainmpdaortthseorilteaxntidlestsauibnsrtreastiesstaunsceedapnrdi/moarrcilleyainanbrielsiitdyepnrtioaplerftuimeistutroeu.ph3olMstperroytefcatbirviec chemicals are sold direct to the customer. tHeoxtmilee mFialslhs)iosnhsar-ingThaiscosemgmmoenntneisecdofmoprrpirsoetedcotfivOeEtrMeactumesnttosmewrhsic(phriimmaprairltysoil and stain resistance `window treatments, ofrabsrtiacinwarlellceoavseertiongfsa,brdieccsoursaetdivien home dcor items such pillows, slipcovers, as ofbetdhsepsreeaidtsemasndcacnombfeorltaeurnsd,ermeadt;troetshserpsadrse,qusihroewperrofceusrstiaoinnas,l aclnedantianblge. linens. Some Specification by US manufacturing companies drives OUS sales in this category. mAiultlos)mowthiovepr--ovTihdiespmraortekcettivise ctormeaptrmiesnetds oofnOupEhMolsctuesrtyomfaebrrsic(st,exctairlpeeatnadncdaortpehter textiles (headliners) used in automobile, truck, and van interiors. - 4 -_-- 0000s U.S. Product Portfo--Tloitaol FC Volumes `This chart outlines the products used in the Home Furnishings, Home Fashions, and Automotive markets in the U.S. The following information is provided for eachproduct: ``cThoemptootnaelnftlsutohraotcmheamkiecaulpptohuenpdrsoodfuecatch sold inthe U.S. in 1997, and the chemical fi 3 5 000060 HoUmSe.FPurrondisuhcitnPgosr,tHfoolmioe--FTaosthailonFsC, AVuotloummoetsive 1997 || o= = A = e I[ TTTT mo Product Pounds (000) Chemistry roscvns |] .a -_-- 5 000061 US. Product Portfolio by Market F`Tuhrinsicshhairntgsg,roHuopmsethFeapsrhoidouncst,saunsdeAduitnomtohetibvues,inaensdsbpyromvairdkeestflsueogrmoecnhte,miHcoalmevolumes sold both by product and market segment. 6 000062 U.S. Product Portfolio by Market 1997 FC Lbs. on [ [m m 1 s e -- ms-- --1] [Total Home Furnishings | --a 1 -- -- -- mas m [To[ talHomeFa ash--ions | m | -- cs-- wom -- -- mrmo-- -- [-- TonlAut1om-- otive --|] ey 61 000063 Home FurnishinAgpsp,lHicoamtieonFaMsehitohnosd,sand Automotive sTehgemefnotlsl.owTihngechpaerrtcpernetasgeenstsretphreemseentthothdesmoifxoapfptlhyiensgefmleutohroodcshebmaisceadl ionntfhleusoermoacrhekmeitcal volumes used. ! 4 -_--_-- 62 000064 Home Furnishings, Home Fashions, Automotive Application Methods Key Customers 1997/1998 Customer Location Map TthheeHfoomleloFwuiminsghiU.S.ngmsa,pHiodmenetiFfaiesshitohnesl,oacantdioAnuotfoamlolticvheemmiacrakleptusrecghmaesnitnsg.cuIsnteoamcehrscaisne, the chemical is applied in the city indicated. -- 64 000066 ah A 4 Tl. a= i Be { SH BB ) A i i 4, iCoareFCuE HoGmegFash io Distribution Chain `uTlhtiismadtieagernadmursee.preIsternetpsretsheenptastahntoheve3rMviperwoofdtuchtetasikgensiffircoamnttphoeitnitmsewihtelreeavtehse33MMto its tphreodpurcotdmucatylbiene;hnaontdleevedraynpdruosdeudc.t wTihlilsgdoistthrriobuutgihoneacchhaisnterp.eprTehsiesntisntfhoermtaytpiicoanliussbeasoefd on 3M internal knowledgeofthe marketplace. 000068 66 ------- Distribution Chain Home Furnishings, Home Fashions and Automotive `Textile Mill/ Finisher Fabric Retailer ce Seating `Manufacturer (assembly Cut and Sew Automobile [oe] - 5 `Consumer --_------ 67 000069 Points of Contact `cThhaeinPositnatrstoinfgCwointthatchte dairraigvraalomfde3tMailpsrtohdeupcattaht tthheep3rModuccutsttoamkeers.wiTthhiisn itnhfeodrimsattriiobnutwioans cseormvpiicel/esdalfersovmis3itMs ainndtegmeanlerkanloiwnlfeodrgmeaotifotnhefrmoamrktehetpcluascteobmaesreidntoenra3ctMiontse.chnical - 3 000070 68 -- Points of Contact at Textile Mill Home Furnishings, Home Fashions and Automotive QCLab DeFvoremluolpamteinotn and Work Hr om Empty J [Fotting real of Returned Spray [w=] Face Finishing, Tggering, Shearing QCLab (Fabric) Inspection/Piece Wrap (50 yards) Inventory (Fabric) Loading Dock (Fabric) 69 000071 Rework (5%) - a -_-- 3M Fluorochemical Exposure Information AFlrloimnftohremPaotiinotnsoifsCboanstedacotn ftlheowuscehaartn,dehaacnhdlsitnepg ionft3hMe cfulsutoormoecrheumsiecaplrso,cemsatseirsiaisloslated. fcoonltlaoiwniinnggi3nfMorfmlautoiroonchisempirceaselnstaend:d articles treated with 3M fluorochemicals. The PointofContact: Describes individual steps in the use pattern. Most Likely dermal, and iRnohaultaetoifoEn.xpMoasrurkes:theIdmeonstitfileisketlhyrereouptoetoefntieaxlporsouutreesowfietxhaponsu"Xr"e.; ingestion, Estimated NumberofWorkers: for exposure during used. Indicates the numberofworkers who may have potential Estimated Exposure Time: exposed during use. Indicates the amountof time that workers potentially may be pPrhoysdiuccatlatFotrimm:eofInedxipcoastuesret.he physical state (liquid, solid, aerosol, or vapor)of the Open or Closed System: fOlpueonroscyhsetmeimc:al.is defined as one that allows workers to come in direct contact with 3M tColocsoemdesiynsdtierme:ctiscodnetfaicntedwiatsho3neMtfhaltu,oruoncdheemrincaolr.mal conditions, does not allow workers Comments: Provides additional descriptive information. ``cThuisstoimnefrosrmhaatnidolnei3sbMafslueoordnoc3heMmiicnatlerpnraoldkunctosw.leIdngfeoramnadtiboenstweassticmoamtpeisloend hfroowm available 3M sources including sales, technical service, marketing and regulatory expertise. 70 000072 " eneEA TE H iECOE r SC=Er E EOT I Hry C5 e TT wlwo TT [ oFIo = Ec | 8 II E RC C8 ICy ToCw |IIE E EE EY1 Ser hofw eT Emer ww -- rr miata = e--r HA TrTZ HTE IC ete CE CN oe IE all Te] 3 Jeotmewn| Foes|I TolTos[wom CE I [| [||em] I IE OE =~ er ECIC EI EI I IE RC IE ial ial ame Toa wa P90 I HE CENIC [|| oe II rl enS ConE an pEr me SE Tr eE e n EE|memLm] ; EE Er yer |UE Vapor, Pr JJ KCoRiEi EmBe e]IA C = yIEB ea a e+afabrimc.il .2::i III. Exposure Assessment -- Home Furnishings, Home Fashions, Automotive 6. Waste Stream/Recycle Information An approximation of the actual disposition of the chemical after it arrives at a customer site is given below. No exact values are known. Chemis . - HishR E As shipped As shipped Dilute mix Dilute mix Dilute mix Dried on fabric Dried on fabric Dried on fabric Dried on fabric Residual in shipping drums Spills Unused pad/foam mix Non-recovered spray CoOavteirnspgroayn equipment Vented material Startupandshut downexcess Shearing and face finishing Unrecoverable, off-quality fabric Seam cut-outs Quality/SQC samples 5 oorg CED . ,5 000077 LJ Product Volumes and Use Patterns `This summary is based on individual products. It is a descriptionofthe application, chemistry,usepattern, exposure and environmental fate. Product Code: Generic product description. `ATphpelircoauttieoonf,ePxrpoocseusrse,ortEhendcoUnscee:ntrTahteiopnoerfspfelcutoirvoechfermoimcawlh,icthheeuxspeospuatrteerwnaasnadsstehsesed. environmental fate may vary with application process or end use -- products can be used for more than one application. Generally the following definitions apply: Process: useoffluorochemical containing product in another product. Application: use of fluorochemical containing product to treat a substrate End Use: useoftreated substrate Volume FC Solids Sold in 1997: Poundsoffluorochemical solids sold in 1997. (M=1000) Chemistry: Generic description of fluorochemical ingredients. Full chemical names are listed at the beginningofthis section. u`sAem.ountof Fluorochemical Present: The fluorochemical concentration inprocessor end % Residuals: Sum totalofconcentrationofthe mixtureoffluorochemicals that are unreacted or partially reacted starting materials or intermediates. cUosmemePratctiearln,: aInnddiccoantessumtehre.major sector where product is used; food,industrial, Most Likely RouteofE dermal,andinhalation. xposure: Id Marks the entifies most li three potential routesof exposure; kely routeofexposure with an "X". ingestion, Environmental Fate: Identifies the most likely disposal routefortheproduct; landfill, incineration, waste water treatment, and directly to water. `Comments: Provides additional descriptive information. 7% 000078 a mtg o C EEL EaReET bEee ee1d ] mie EH : 3 -- --] 2i: [[1] = HTT rrecauisne|] pen| con fry ProduGcltoVbalPoroduuacntdPmosreoPolao tss ost kgao yReusosfEnvtonmenta Fate] comments Foaappmpolrepd.ed : | B | | ramen ProdetVelumosand Usa Putin lef ELE] CT ee Peed EE afl EEE E1 21 =EN ECE E[EFomor| A itr L EL eoloefT mem eE d E| EE | 3 7 - ProducGloVboalluPmroosduacnPdUosretPaotioAs goFy 0 o Envtoamentt Fae] comments -- -- -- H Ehe ie| ----F --FT T* o w t r s g2 IL Situation Analysis B. Nonwovens Business Definition Nonwovens -- This finishers) sharing a market is comprised common need for oil of OEM customers (nonwoven plants, and water resistance. Additionally, rmeaasdtielry bhaatncdhlepdrobdyuceexrtsrupsrioocnespsroocuersspeoslaytmseerlemcetletdpnroondwucotveinntomiallfso.rmThtheatfaibsrmicosre produced industrial are used as medical materials, primarily ffaibltreircsme(dsiuarg.ic3alMgporwontse,ctdirvaepcehseamincdawlrsaaprse)saosldwedlilreacst to the customer. CL] @ 000084 Key Products ~ Nonwovens tThheischcahratrotfotuhtleinteotsalthfeluporroodcuhcetmsiucsaeldvionltuhmeeNsosnowldovtoeneascmhaorfkneitnienktehye cU.uSs.tomIenrcsl,udtehde in application method the treated goods. these customersused to apply the chemical, and intended end use of 8 000085 Key Products Nonwovens Product] Total "97 | Estimate 98| Application [E e [ MS e orT rJ e c e oJJeewJe e Joewowommwer moaennsrs]| (000 FC Ibs.)|(000 FC Ibs.) End Use se 000086 Cum----- Customer Location Map `The following U.S. map identifies the locationofall chemical purchasing customers in the Nonwovens market segment. Ineach case, the chemical is applied inthecity indicated. 000087 --- 85 < ' ee 000058 Distribution Chain `Thisdiagram ultimate end repr use. ese It nrtesptrehseepnatsthanthoeve3rMviperowodfuctthetsaikgesniffriocamntthpeotiinmtes it wh leaves ere the 3M toits 3M opthrneo3dpurMcotdiunmctateymlaiblnee;khnnaoontwdlleeevddegraeynopdfrtuoshdeeudc.mtawrTikhleiltspgdloiascttehr.riobuutgihoncacchhaisnterpe.prTehsiesntisntfhoermtaytpiicoanliussbeasoefd o 000089 ' Nonwovens Distribution Chain A(sFsieltmebrlsy Filter User Air Vests Topical Nonwovens: Mill/Finisher CFuotr&tiSneew --N PrS od o P: Cut & Sew Packaging Sterilization Waste/ Incineration J Waste/ Incineration 88 000090 CHEE Points of Contact cThhaeinPositnatrtsionfg wCiotnhtatchtedairaigvarlaomfd3etMailpsrtohdeupcatathttthheep3roMduccutsttoamkeers.wiTthhiisnitnhfeodrimsattriiobnutwioans cseormvpiicel/esdalfersovmis3itMs ainndtegmeanlerkanloiwnlfeodrgmeaotfiotnhefrmoamrktehetpcluascteobmaesreidntoenra3ctMiontse.chnical 89 000091 -_----_-- ; Points of Contact - Mill Topical Nonwovens QC Lab "ormulation Development Wor Empty Drums [HoldingAre: Cleaning Returned 03M [oe] Mictex, Softening Inventory (Fabric) Loa(dFianbgriDc)ock % 000092 ' -- Points of Contact - Masterbatch Producer Nonwovens PMA LinteoFHeoepdp/eDrrum Ship to Nonwovens Producer , 5 0 000093 ~~ CENEED Points of Contact - Extruder Nonwovens PMA (RFoalbrliucp) Quality Control Lab (Fabric) Inventory (Fabric) Loading Dock (Fabric) 2 000094 | --_-- 3M Fluorochemical Exposure Information From the Pointsof Contact flow chart, each step in the custusoepmroecerss is isolated. All informationisbased ontheuse and handlingof 3M fluorochemicals, materials cfoonltlaoiwniinnggi3nfMorfmlautoirooncihsempirecsaelnstaedn:d articles treated with 3M fluorochemicals. The Point ofContact: Describes individual steps in the use pattern. Most Likely Route of Exposure: Identifies three potential routesofexposure; ingestion, dermal, and inhalation. Marksthe most likely route ofexposure with an "X". EfosrtiemxaptoesdurNeudmubreinrgoufsWeod.rkers: Indicates the number of workers who `may have potential Estimated Exposure Time: Indicates the amount oftime that workers potentially may be exposed during use. `PphryosdiuccatlaFt otrimm:eofIenxdpicoastuerset.he physical state (liquid, solid, aerosol, or vapor) ofthe Open or Closed System: fOlpueonroscyhsetmeicma:l.is defined as one that allows workers to come in direct contact with 3M. tColocsoemdesiynstdeimr:ectiscodnetfaicntedwiatsho3neMtfhaltu,ournodcheermniocarlm.al conditions, does not allow workers Comments: Provides additional descriptive information. `This information is based on 3M internal knowledge and best estimates on how customers handle 3M 3M sources including fluorochemical sales, technical products. Information service, marketing and was compiled regulatory exp from ertise available . . ' 000095 = --- FEE we fea | Sonenemoein | HHA roe [re] [2[we [=a CE= L TT T Fao TT Tse song wp Tx 11%1---- FEE I IE IE ESI BE [ee] sidI CC I EOBill Fs I CEI CE il Exponso aman mw [TT Potof Cont [a r-- [ENuinrbaeroodf Ertan Emenre | oan| our Te Frys Form po close Syst rSinse orpan rarn r [cise] irlHEI Wastorbatch Producer CE I NE I EY be| freer E Frad [TTXoTe 2s3[TweWe oaodn|[ [xx| yor | Pre oedie foe: FR S NS0 a ean S i S : S St 2s rer s HHS=r Tn eg a cd EC or BI E 0 iC = C e E Y |251 Medom | x 1 : EoNnsemvaoton HERE i: teose ET I EE CT I 3I [EeT r| [ EEeeC TC o Em]e TRe ee Lee]LTTTT TE IF Product Volumes and Use Patterns `This summaryisbased chemistry,use pattern, on individual products. It is exposure and environmental a descriptionofthe fate. application, `Product Code: Generic product description. `ATphpelircoauttieoonf, ePxrpoocseusrseo,rtEhnedcoUnscee:ntrTahteiopneorfsfpleucotriovechfermoimcawlh,icthheeuxspeopsautrteerwnaasnadsstehsesed. feonrvimroornemetnhtaanlofnaeteapmpaliycavtairoyn.with application process or end use -- products can be used PGreonceersasl:lyutsheeoffofllluoowrioncghdeemfiicnailticoonnstaapipnliyn:g product in anotherproduct. EApnpdliUcsaet:ionu:seoufsteroefatfelduosruobcshtermaitceal containing product to treat a substrate Volume FC (M=1000) Solids Sold in 1997: Poundsoffluorochemical solids sold in 1997. lCihsetmeidsattrtyh:e bGeegnienrniicndgoesfctrhiipstisoencotfifolnu.orochemical ingredients. Full chemical names are AmountofFluorochemical use. Present: The fluorochemical concentration in process or end u%nrReeascitdeudalosr:paSrtuimalltyotraeloafccteodncsetanrttriantgimoantoerfitahlseomrixitnuterremoefdfilauteosr.ochemicals that are cUosmemePratctiearln,: aInnddiccoatnessumtehre.major sector where product is used; food, industrial, dMeorsmtalL,ikaenldyiRnohaultaetoiofn.ExMpoasrukrse:thIedemnotsiftielsiktelryereopuotteeonfteixalporosuutreesowfitehxpaons"urXe.; ingestion, iEnncviinreroantmieonnt,awlasFtatee:watIdeernttirfeiaetsmetnhte,maonsdtdliirkeecltylyditsopwoastaelrr.oute for the product; land, Comments: Provides additional descriptive information. 000100 -.---- . 9% a S--emm--es le ELLE EERE ooEPeE edET. T] CeI [1] EY I wsTeawel111T Vx |posumien_| xT1x11-- .3 : ESCEE T thm m mirans reER--T]) FeTe] len] TTTDETTE g Protective Chemical Products Apparel and Leather Business Fluorochemical Use, Distribution, and Release Overview . > 101 000103 [J Foreword Confidential Business Laormation `LTehaitshreerpobrutsiinseassc.omIptraethteenmpstisvetolaonokswaetretxhpeosfuorlelotwoi3ngM'qsuesftliuoonrso.chemicals in the Apparel and + What proadreucucstotmesrs exposed to? + Where does exposure happen? + What typeofexposure is it? `The 3M fluorochemical business is complex and global. Markets served are highly fragmented involving `segments multiple and used 3M for products that are applied multiple end products. to multiple substrates, sold into `multiple market `This report includes global information based largely on the knowledge ofworldwide activities by St. Paul-based personnel. Sources of Information For This Report Information for thisreport was developed solely from internal 3M sources. These include: + Knowledge of personnel producthandlinganduse practices from field sales and technical + Best estimates ofend-use applications from known customer activities. + Internal salesreports showing regional sales breakdowns for apparel and leather products. How To Read This Report `The following typesofinformation are available in this report: Situation Analysis: Provides background on business and products. Helpful to understand Apparel and Leather customer base, global scope and diversityofmarkets. Distribution Chain and Pointsof Contact: Follows the path ofa 3M fluorochemical throughout the distribution chain to final end user. Objective is to identify all points ofcontact with our chemicals -- from arrival on customer's loading dock Exposure Information Charts: Attempts to quantify type and lengthof exposure andnumofbworekerrs exposed to our chemicals within the distribution chain. Product Volumes and Use Patterns: `Ceoxmpbosiunreesb3y Mpropdroudcutcttypdee.tail with the exposure routes to provide a. . summaryoftotal business 000104 CHEEED 102 Apparel and Leather Fluorochemical Use, Distribution And Release Overview Table of Contents I. Chemical Names IL Situation Analysis A. Business Definition B. Global Polymers C. Key Markets and End Uses D. Application Methods E. Customer Location Maps IL Exposure Information - Apparel A.. Distribution Chain B. Points of Contact C. 3M Fluorochemical Exposure Information D. Waste Stream/Recycle Characterization E. Product Volumes and Use Patterns IV. Exposure Information -- Leather A. Distribution Chain B. Pointsof Contact C. 3M Fluorochemical Exposure Information D. Waste Stream/Recycle Characterization E. Product Volumes and Use Patterns 000105 . 103 Chemical Names `iTnhdeivfiodlulaolwpirnogduicstas.lstTohfeCfhoelmliocwianlgAibnsftorramcattSieornviiscperse(seCnAtSe)d:names and numbers for Generic Code: Indicates an intemal 3M designationofthe product(s). cCoAnStaiNnuemdbweirt:hinInedaiccahtpersotdhuectC.hemical Abstracts Services number(s)offluorochemicals ICnhdeimciatceasltNheamCheem(ciocmapllAebtsetCraAcStsnSaemrveicoers[nUaPmeA(Cs)noafmfelsuiofrCocAhSemincaamles dcooenstariontedexwisitt):hin each product. Chemical Class: Indicates a shortened, generic chemical name. 108 000106 -_---- ] orci [EETomo ] reees m aw] Pes ---- 17 Pe ---- | a i J Perr er e 2 Bee w pees -- 1---------- rr Er =r [Efrem] orm ee [owen] e e t r Per |-- 8 Fluorochemical Apparel and Leather Use, Distribution, and Release Overview II. Situation Analysis A. Business Definition `Smaalneuoffacftluuroerogcahremmeinctasl,sffooortwaepaprl,icaactcieosnsoorniefasbarincds oatnhderlenaotnh-egraursmeedntto functional fabrics. Direct Customers: * TeprxotviildeeMoiilllayn/dCowmamtiesrsrieopnelFliennicsyhetrosenthhaatnucseetfhleufournoccthieomniaclals to performanceofthe fabric produced. * LfeuantcthieornTaalnpneerrifeosr/mFainncieshaesrsabtohvate use fluorochemicals to enhance and/or serve as a processing aid in the conversionofraw leather. * CtheextmiilecaanldFloeramtuhleartcoarrse,thdartyucsleeafnluaonrdocfahtelmiiqcuaolrsiandsuisntrgireesd.ients for the * CqhueamliitcyatlesDtiisntgrirbeuptaocrksatghiantgreasnedl/loprrloadbuctteschtoseernvdicuesweorsrka.ndmay do Global Business Size: 108 000110 EEEED ww Global Polymers `pTohritsfcohlairotwhouitclhinfeesattuhreensin1e9pdioffleryenmt epursroedsducitns.thTehAepppoalryemlearnsdLareeatdihveirdeMdariknettosmapjroorduct product categories: Repellent, Stain Release, Leather and Formulators. The following informatiiosn `make up the polymer,and the providedforeach polymer: the chemical total fluorochemical poundssoldin 1997 components for each. that Volume information is provided relative to the other polymers in the product category, and relative to the total pounds soilntdhe Apparel and Leather Markets. The geographic `breakout, US vs. outsidetheUS is also provided. we 00011 cm =m | z 5 pm gg ow - Git Poymer (000) CpS H x ---- -- i rt LES FO4,FO7 2=thFO-1 = 1 if1 yI 1 -- 1 -- m 000113 CHEE C. Major Markets and End Uses p`Trhoidsucchtarltinpersogvoiedsestod.etTaihlisabionuctlutdheesmtayjpoicramlaernkdetussetshaant deatchheofmtahjoerfsouubrstArpaptaerteylpeasndwhLeeraeth3erM fluorochemicals are used. Information about relative sizeofthe 3M product lines is also shown. t`hTheisseipnrfoodrumctast.ion was developed using the market knowledge of 3M employees involved with nz 000114 ----- Fluorochemical Apparel and Leather Use, Distribution, and Release Overview Major Markets and End Uses Line [T|%b ofTos tal | aocuttievrewweeaarr Tsakiinvceoairt,sgolfwear ppoollyyesctaetr,ionnylon urneisfsorcmlsothing, jsauictkse,tss,halcakcsks Wwooooll,, ppoollyy//wwooooll otthecehrnical textiles | aprwontiencgtsi,vebcolaottchoivnegrs, ||oactrhyelrics, poly/cottons, = = uniforms workwear sthenitess,,bpaacnktpsa,cjkasc,keettsc. _|| ncoytltoonn,,ppoollyye/sctoetrt,oonther shits, pants cotton, poly/cotton 2 s dcraessuaslclcoltohtihnigng Tootwear shsihrirtts, pants shoes, boots ccoottttoonn,, ppoollyy//ccoottttoonn pigskin, bovine garment accessories Teather jackets, gloves, handbags, etc. | pbiogvsiknien,,dbeoevrinseh,eespheep, goat upholstery Textile & lather | acheariorsso,lss,ofsahso,eccer.eams, - care dry cleaners polishes' rainwear/outerwear fatliquor supplies_|waterproof eather D. Application Methods - Apparel Fabrics s`Tehgemefnotl.lowTihneg pcehrarctenptraegseesntrseptrheesmeenttthhoedmsoifxoafptphlyeisnegmfeltuhoorodcshebmaisceadloinnftlhuisormoacrhkeemtical volumes used. na 000116 + Apparel Mill FC Application Methods = Exhaust on Yarn - <1% 2 Foam -2% E 8 PCoaadt-in9g6-%1% Apparel and Leather Team Estimates D. Application Method-s Leather Tanneries `The following chart presents the methodsofapplying fluorochemical in this market segment. The percentages represent the mixofthese methods based on fluorochemical `volumes used. ` 000118 oy ne ro---- nw 000119 Lr , 11s 000120 -_---- MS ggoppy EEE _--_-- pm" 000122 III. Exposure Information - Apparel 000123 HEED 121 A. Distribution Chain Tuhlitsidmaitaegreanmd ursee.preIsternetpsrtehseenptastahntohvee3rvMieprwoofdtuchtetaskiegnsiffircoamntthpeoitnitmsewihtelreeavtehse33MMto its tphreopdruocdtumcatylibnee;hnaontdleevdearnydpruosdeudc.t wTihlilsgdoistthrribouutgihoneacchhaisnterpe.prTehsienstisntfhoertmypaitciailosnusbeasoefd on 3M internal knowledgeofthe marketplace. 122 000124 Distribution Chain B. Pointsof Contact `cThhaeinPositnatrstoinfgCwointthatchte dariraigvraalmofde3taMilpsrtohdeupcattahttthheep3roMduccutsttoamkeers.wiTthhiisnitnhfeordimsattriiobnutwiaons cseormvpiicellesdalfersovmis3itMs ainndtegmeanlerkanloiwnlfeodrgmeaotifotnhfermoamrktehtepcluascteobmaesreidntoenrac3tMiontse.chnical -_--_-- ' 120 000126 Points of Contact at Textile Mill Apparel | Lab . Empty |, [Holding Area] | Returned [ee [] [=] [==" ] `Exhaustion [on] Mechanical Processing Napping, Calendering etc. Re (FaRborlilcSSiczrianpgs) (Fabric) I(nFvaebnrtiocr)y Loading Dock i" --_ 000127 Points of Contact at Manufacture Apparel and Shipped. -_-- 000128 - : 126 Points of Contact at Dry Cleaner Apparel in Closed System Dry Clothing Pressed or Steamed 127 000120 CHEE ----- 000130 ' 128 C. 3M Fluorochemical Exposure Information AFlrloimnftohremPaotiinotnsoisfbCaosnetdaoctnftlheowuscheaartn,dehaacnhdlsitnepg ionft3heMcfulsutoormoecrheumsiecaplrso,cemsatsieriiasloslated. containing 3M fluorochemicals and articles treated with 3M fluorochemicals. The following information is presented: Pointof Contact: Describes individual steps in theusepattern. Most Likely RouteofExposure: Identifies three potential routes ofexposure; ingestion, dermal, and inhalation. Marks the most likely routeof exposure with an "X. Estimated Number ofWorkers: Indicates the number of workers who may have potential for exposure during used. Estimated Exposure Time: Indicates the amountoftime that workers potentially may be exposed during use. Physical Form: Indicates the physical state (liquid, solid, acrosol, or vapor) ofthe product at time of exposure. OOppeenn soyrsCtleoms:edisSdyesftienme:d as one that allows workers to come in direct contact with 3M fluorochemical. Closed system: is defined as one that, under normal conditions, does not allow workers to come in direct contact with 3M fluorochemical. Comments: Provides additional descriptive information. This information is based on 3M intemal knowleanddbgeset estimates on how customers handle 3M fluorochemical products. Information was compiled from available 3M sources including sales, technical service, marketing and regulatory expertise. 000131 129 F|EH E TE==]ol m=eE n fee] --| EE Tewemw [Fee [xlTf wo [xTTT Io][orreomen] = = ee EE lem TTDT ee [ibnvgRoom | TXT 1331 Fgh |xI1111 1 gspmea]r] leffe)l=we I ITT T] Rem [I Te[ee [TI] |x romani) a ee|[x] ToeTome TT TTx] Jromsemsomnn] 15| (Oyighore| |X[x| 3 |wh 1 |x| [xx]J] compan HTr E =EE|H reeoLoE rme] e] Sm=Es= |] =2 we fl= TF TET J llA I GCE) i I EE i I 3 [Create Garment| [wT] CI I J AS SS I I 0I [581 wgh J xT [1 --1 aSosapfrEe= SeE rngatori Poofnontt| Mestely Routeof|CEC ExposureTime. oa] Openor con" vr =Ror=op eenyea] = re r------ opt X | expos-culorseed TOTTT eae g D. Waste Stream/Recycle Information -- Apparel An approximation of the actual disposition ofthe chemical customer site is given below. No exact values are known. after it arrives at a `Waste chemical in liquid form tahserseceewievre:d that ends up in Apparel Pcrg.oduct adhering to inside ofdrum Spills MUinsucseeldlaanpepoluiscation mix ePnedrsceunptoofnchweamsitceaylarpdoaugnedoafgfeasborilcd/tlheaatther: eg CSoelcoorndsaqmupalleitsy fabric/leather Lab samples. Cutting scraps that are recycled or landfilled eTontdaslupperacsewnatsotfecohreomincwaalsptoeugnodoadgs:e sold that . 3 is 000135 --- E. Product Volumes and Use Patterns c`Thheimsissturmym,uasreypiasttbearsne,deoxnpoisnudirveiadnuadlenpvroidruocntmse.ntItails faatdee.scriptionofthe application, Product Code: Generic product description. `ATphpelircoauttieoonf,ePxrpoocseusrseo,rtEhendcoUnscee:ntrTahteiopneorfsfpleucotriovcehfermoimcawlh,icthheexupsoespuartetewrnasanadsstehsesed. feonrvimroornemetnhtaanlofnaeteapmpaliycavtaiorny.with application processorend use --products can be used PGreonceersasl:lyutsheeoffofllluoowrioncghedemfiicnailticoonnstaapipnliyn:g product in another product. EApnpdliUcsaet:ionu:seoufsteorefaftleudorsoucbhsetrmaitceal containing product to traseubsatratte. Volume FC (M=1000) Solids Sold in 1997: Poundsoffluorochemical solids sold in 1997. lCihsetmeidsattrtyh:e bGeegnienrniicndgoesfctrhiipstisoencotfiofn.luorochemical ingredients. Full chemical names are Amountof use. Fluorochemical Present: The fluorochemical concentration in process or end u%nrReeascitdeudalosr:paSrtuimalltyotraeloacftecdonsctaernttirnagtimoantoerfitahlesomriixnttuerremoefdfilauteosr.ochemicals that are Use Pattem: commercial, Indicates the major and consumer. sector where product is used; food, industrial, dMeorsmtalL,ikaenldyiRnohaultaetoifonE.xpMoasrukrse:thIedemnotsitfileisktehlryereopuotteoenftieaxlproosuutreseowfietxhpaonsu"rXe";, ingestion, iEnncviinreorantmieonnt,awlasFattee:watIdeernttirfeiaetsmetnhte,maonsdtdliirkeecltylyditsopowsaatlerr.oute for the product; landsill, Comments: Provides additional descriptive information. 130 000136 [l= oe ProducloVboalPumroosduatnPd rsaetPaotirns Most ayRouteof Ba or =EE beL d TE O w . . 8Je=m] EH ET --] : SEE=_ PeFa nen=a=epln 1] PEE ET [sled ECer TT Tw xIe ex 3I wx ef rotm ores n ms ptr EH " 1 eee | Comments IV. Exposure Information - Leather 000141 139 --_-- A. Distribution Chain uTlhtiismdaitaegernadmruespe.resItenretpsretsheenptasthanthoeve3rMviperwoodfutchtetaskigensiffircoamnttphoeitnitmsewihtelreeavtehse33MMto its tphreopdruocdtumcatylibnee;hnaontdleevderaynpdruosdeudc.t wTihlilsgdoistthrriobuutgihoneacchhaisnterpe.prTehsiesntisntfhoermtaytpiicoanliussbeasoefd on 3M intemal knowledgeofthe marketplace. -_-- 000142 : 140 Distribution Chain yD T | B. Pointsof Contact `The PointsofContact diagram details the path the product takes within the distribution chain starting withthearrivalof3M productatthe 3M customer. This information was compiled from 3M intemal knowledgeofthe marketplace based on 3M technical service/sales visits and general information from the customer interactions. -_---- 12 000144 Points of Contact at Tannery Leather Formulation&CDeLvelopment Work (Liquid Chemica) Mix RetanningApplication by Drum Empty Drums [HoldingAreal,/ Returned Cleaning to 3M [om] [FC Application by Roller Coat, Spray or Chemical Milling ` . Sorting/Measuring/ 143 -- 000145 Points of Contact at Manufacture Leather Packaging and Shipping 000146 Quy 144 C. 3M Fluorochemical Exposure Information From the PointsofContact flow chart, each step inthe customer use process is isolated. All information is based on the use and handling of 3M fluorochemicals, materials containing 3M fluorochemicals and following information is presented: articlestreatedwith 3M fluorochemicals. The Pointof Contact: Describes individual steps in the use pattern. Most Likely Routeof Exposure: Identifies three potential outesof exposure; ingestion, dermal, and inhalation. Marks the most likely routeof exposure with an "X". fEosrtiemxaptoesdurNeudmubreirnog fusWeodrkers: Indicates the number ofworkers who `may have potential eEsxtpiomsaetdedduErxipngosuusre.e Time: Indicates the amountoftime that workers potentially may be Physical Form: Indicatesthe physical state (liquid, solid, aerosol,orvapor)ofthe product at time ofexposure. Open or Closed System: fOlpueonroscyhsetmeimc:al.is defined as one that allows workersto comeindirect contact with 3M Closed system: is defined as one that, under normal conditions, does not allow workers to come in direct contact with 3M fluorochemical. Comments: Provides additional descriptive information. `This information is based on 3M intemal knowledge and best estimates on how customers 3M source handle 3M s including fluorochemical sales, technical products. Information service, marketing and was compiled regulatory exp from a ertise. v ai lab le a . 000147 CEE 145 Eronms [H EEE E fE ea Fm Fee =on sporamyo ii, [eTTeTLe esherTa[mar TT--[-- x]--J-- oe-- ma-- n] cl Te = & l= Le [ee DT 2 [mort EC 3EY. SR I oy | [77 werrign| rr EE IC I ESI A rE oe fl vepneder Rr a] HH ETm E z=][|[=[T= [[=] ErEinys aBc 1i [---- 8 I =] [IE C] N C[E C =~e][I -]]EE fe] [el - [FosterI [XTX TWemmnor[Tx[xT[xT] Cem DTTo =e D. Waste Stream/Recycle Information -- Leather An approximation of the actual dispositionofthe chemical after it arrives at a customer site is given below. No exact values are known. Waste chemical in liquid form as receivedthat ends up in the sewer: Leather eg Product adhering to insideofdrum Spills Unused application mix Miscellaneous ePnedrcseunpt oofncwhaesmtiecaylarpdoaugnedoafgfeabsroilcd/ltehaatther: eg Second quality fabrie/leather Color samples Lab samples Cutting scraps that are recycloerd landfilled eTnotdaslupperacsewnatostfeocrheomniwcaalstpeougnodoadsg:e sold that 148 000150 -- E. Product Volumes and Use Patterns `This summary chemistry, use is based patter, on individual exposure and products. It is environmental a descriptionofthe fate. application, Product Code: Generic product description. `ATphpelircoauttieoonf,ePxrpoocseusrse,ortEhendcoUnscee:ntrTahteiopneorfsfpleuctoirvoechfermoimcawlh,itchheeuxspeospuartetewmaasnadsstehsesed. feonrvimroornemetnhtaanlofnaeteapmpaliycavtairoyn.with application process or end use -- products can be used. Generally the following definitions apply: PAprpolciecsast:iouns:eoufsfeloufofrloucohreomcihceamliccoanltacionnitnaginpirnogdpurcotdiunctantootthreeratpraosduubcstt.rate End Use: useoftreated substrate Volume FC Solids Sold in (M=1000) 1997: Poundsoffluorochemical solids sold in 1997. lCihsetmeidsattrtyh:e bGeegnienrniicndgoefsctrhiipstisoencotfifonl.uorochemical ingredients. Full chemical names are AmountofFluorochemical use. Present: The fluorochemical concentration in process or end 9u%nrReeascitdeudalosr:paSrtuimalltyortealaocftecdosntcaernttirnagtimoantoefrtiahles omrixitnutrereomefdfilautoesr.ochemicals that are Use Patten: commercial, Indicates the major and consumer. sector where product is used; food, industrial, dMeorsmtalL,ikaenldyiRnohaultaetoiofn.ExMpaosrukrse:thIedemnotsitfileisktehlryereopuotteeonfteixalporosuutreesowfietxhpoasnu"rXeTM;. ingestion, iEnncviinreorantmieonnt,awlasFattee:watIdeernttirfeiaetsmtenhte,maonsdt likely disposal routeforthe directly to water. product; landsill, Comments: Provides additional descriptive information. 148 00 0151 --- Sie ProductVolanduUsme Pettrsns = apy LL else l =F "HTT==5 ele SP PP [eE zfsE eel] TTT1T SwIw x x x x rome PEREase fede TT TrT REYTx TT xfx :8 es] CesT] TTT Ix{wx | {xtx [1] 2 3 Produ`cGtloVbaloProldaucnutdPUsamaiPlaetsersna Leaver Ll lle ee d=lE CfrroesTeeenseT ] T= 11 F Iwtw ww Iw[x[xixre 2 8a2 rwtm5aepe E=E C:e feostmeeensl--1--1 feosema 4 IXT Tx[ Iw x x 1 Tx1--] x xx f[eEoosstEprnodcuessesl1 TT TwT TX TT Ix xIx[x RRTx C[rEooss ePoneueses]|T TTT1 IT Ixx Ix xIT x x X TxTx --] ] 3M Aftermarket Application and Retail Consumer Business eee FLUORAONCDHERMEILCEAASLEUSOEV,EDRIVSITERWIBUTION RETAIL MARKETS PRODUCTS COMMERCIAL MARKETS PRODUCTS 000155 153 ----- Aftermarket Application and Retail Consumer Business Foreword A`TphpilsirceaptoirotniasnadcRoemtapirlehCeonnssiuvmeelroobkusaitneesxsepso.surIet attote3mMp'tss ftlouaonroscwheermitchaelfsolinlotwhienAgfqtueersmtairoknse:t + WWhheartepdroodeuscetxspaorseucrueshtaopmpeerns?exposed to? + What typeofexposure is it? fcUlosumeoporlofechx3eMmaincfdalglulooprbraoloc.dhuecmMtiascratklhseattisnarsteheeruvsAeefddtaearrsemaihnrigkgrehetldyiAefpnrptalsigcmiaentneitnoednd-auansnded3RienMtvaoifllovrCemouanlasntuuimmonbeser.rmaoTrfhk3eeMt3s is ufpohromlusltaetriyo,nsapapraereul.sed by 3M customers to reat various substrates such as carpets, M floors, Sources Information for this report was developed solely from internal 3M sources. These include: + BKensotwlesetdigmeatoefsporfoednudc-tusheanadplpilnigcaatnidonussferpormacktnicoewsnfrcoumstfoiemledrsaaclteisviatnieds.technical personnel + Internal sales reports + Knowledgeofworldwide activities (where applicable) by St Paul-based personnel `How To Read This Report SituPartoivoindAensalybsaicsk:ground on business and products. DistrpFiroboluclteiosowsns,CtwhhhaeienpraeatnhadpopPlofaiicaat3bsolMef,Cfotlnhutroaorcoutcg:hhetmhiecadlisitnriabu3tMionencdh-aiunsetoprfoindaulcetnfdruosmerthaenmdaintusfeancdtuursieng amrordivea.l oOnbjceucsttiovmeeirs'tsoildoeandtiinfgyadlolcksitghnirfoiucgahntpprooidnutcsotfucsoangteaacntdwdiitshpo3sMalfluorochemicals --from Exposure Information: fAltutoermopcthsemtiocaqlusanwtiitfhyitnytpheeadnidstlreibnugttihoonfcehxapionsure and numberofworkers exposed to 3M Pro`dCuocmtbVionleasme3sManpdroUdsuecPtatdteetraaisl:with the exposure routes to provi-de a summaryoftotal business exposure by product type. 000156 154 Aftermarket Application and Retail Consumer Business Retail Market Products TABLE OF CONTENTS Fluorochemical Identities Chart Situation Analysis Distribution Chain& Points of Contact FC Exposure Information Summary FC Exposure Information Charts Product Volumes & Use Patterns Summary : Product Volumes & Use Patterns Chart " 000157 155 CHEE sorocmesome ner E B3AL rwwi e T] oone) Ar2 ------ r -- t F EsB-- Gesmel1 t g &g Aftermarket Application aad Retail Consumer Busines TAIL MA] T PR Situation Analysis BUSINESS DEFINITION Home treatment ofupholstery, carpet, auto interiors and apparel by individual retail consumers. pAKrsEortoYescatPloRrcsOafnDosrUpfCraabTyriSccl,euapnheorlssatenrdy,prcoatrepcetto,rlseaftohrerh.omAellupsroe--duccltesanienrtshifsorcaftabergioc,ryupahroelmsatenruyf,acctarupreetd; by independent, non-3M manufacturing facilities under contract with 3M. KEY MARKETS Grocery, club, hardware, auto parts stores. KEY CUSTOMERS Individual retail consumers. OIcNcaTsEioNnDalEDhoUmSeEuse on carpets, upholstery, apparel, auto interiors, shoes and boots. HEoXmPeEuCseT.EDFabUrSicEprotector -- two cansperyearper product user. less per year per product user. Other products -- one can or 000159 157 :s ----- Aftermarket Application and Retail Consumer Business Retail Markets Products Distribution Chain and Pointsof Contact iTthseulftoilmlaotweienngdinusfeo.rmaIttiroenprdeessecnrtisbeasntohveepravtihewtohef3thMe psirgondiufcictanttakpeosinftrsowmhtehreetithmee 3it Mleparvoesdu3ctM to `may be handled and used. TDthhueeridminasgntudrfiisabtcurttiuibrounetircohnta,oittnhheefoprrertotahdieulecRrtetwiaisitlihnMtsahereaklpeeodtsssaiebPrirlooisdtoyuloctcfasonsni.senoNotrocmsooimrgpneliefwxia.cranetPhroeouxdspuiocnstgurissetestphositpihpneebd3etfMwreoemn. product is anticipated during distribution. No charts are providedforthe distribution chain. fTihveorfooclhleomwiicnagl-cchoanrttsaipnrionvgipdrepoodiuncttsdoufrilinkgemlyancuofancttuarweictathndthceus3tMomfelruoursoechemical and + Tmhairskeitnpfloarcmeatbiaosnedwaosnc3oMmpitelcehdnifcraolmse3rMvicien/tseamlaesl vkinsiotwslaenddggeeonfetrhaleimnafnourfmaacttiounrifnrgopmroccuesstsomaenrd interactions 000160 158 RETAIL MARKETS PRODUCTS AEROSOL MANUFACTURE (HC-1,2,34,5; AA-1,2,3) Receiving Warehouse| SamQpAle QA Testing Retain he Staging Area SWteaitigohn CMhiaxrTgaenk Fill; Pressurize Cap; Package Ship to Customer Drum Disposal Rinsate Disposal Reject . 0001s; CHEEES 159 RETAIL MARKETS PRODUCTS HC-1, HC-4 APPLICATION Purchase product Bor frp use Arrange furniture or clothing for treatment Spray on furniture, carpet or clothing Arrange furniture or clothing for drying Let treated article dry " 0001, 62 CE RETAIL MARKETS PRODUCTS HC-2,HC-3 APPLICATION Purchase product forRefefuitu ohse Arrange furniture or clothing for treatment Spray on furniture, carpet or clothing Wipe onto fabric to loosen soil Let treated article dry remove soi, Vacuum to dried cleaner . 11 000163 -_-- RETAIL MARKETS PRODUCTS HC-5 APPLICATION Purchase product for future use Arrange items for treatment Spray on shoes, other leather items Arrange treated article for drying Let treated article dry 62 900164 - CE RETAIL MARKETS PRODUCTS AA-1, AA-3 APPLICATION Purchase product iid Open car doors, windows Spray onto car interior Let car interior dry CJ 13 000165 RETAIL MARKETS PRODUCTS AA-2 APPLICATION Purchase product Store product for future use Open car doors, windows Spray onto car interior Wipe onto fabric to loosen soil Vacuum to remove soil, dried cleaner. Tes 0001 cS. Aftermarket Application and Retail Consumer Business Retail Markets Products 3M Fluorochemical Exposure Information Summary mBaansuefdaoctnutrheeaDnidstcruisbuttoimoenrCuhsaeinp/rPoocienstssoisfisCoolnatteadc.t fAlllowincfhaorrtm,ateiaocnhipsrbiancsiepdalonsttehpienutseheand handling with 3M of 3M fluorochemicals, materials containing fluorochemicals. The following information 3M fluorochemicals is presented: and articles treated `PmoainnutofafcCtounrteaacntd: enDdesucsreibaepspliincdaitviiodnubayltshteepsreitnaitlhceounsseumpeatrt.ern. Use pattem includes steps in Most Likely Routeof Exposure: contact -- ingestion, dermal, and Identifies inhalation. three potential routesofexposure at each Marks the most likely routeofexposure point of with an "X". eEsxtpiomsautreeddNuruimnbgeurseo.fDWourrkienrgs:endInudsiecaatpepslitchaetinonu,mb"enruomfbweroorfkewrosrkwehros"mraeyprheasveentpsotneunmtbiaelrfoofr + occupantsofresidence present during and after product use. Estimated Exposure Time: be exposed during use Indicates the amountoftime that workers/end users potentially may Physical Form: ofexposure. Indicates the physical state (liquid, solid, aerosol, or vapor)ofthe product at time Open or Closed System: Indicates open/closed statusofproduct at timeofhandling as follows: Ofplueonrsocyhsetmeicmali.s deEfxianmepdlaessoonfeotpheant aslylsotwesmswoarrkeemrisxitongckoemtteleisn, doipreecnt dcronutmasctanwditbhot3tlMes Cdliorescetdcsoynsttaectm wiistdhef3iMnedflausorooncehetmhiact,alu.ndEexranmoprlmeaslofconcdliotsieodnss,ysdtoeemssnaorteaslelaolewdwdorrkuemrssatnodcfoilmleed in aerosol containers. Comments: Provides additional descriptive information Disposal: Indicates most incineration. All end use likely methodofdisposalofthe end use products represented in thesechartsare product landfill, recycling packaged in aerosol cans. or Disposal into the waterways or sewer system is not expected. 3`TMhisfilnufoorromcahteimoincails pbraosdeudctosn.3IMnfionrtmearntailonknwoawslecdogmpeialnedd bfersotmeasvtaiimlaatbelseo3nMhsoowurccuesstoimncelrusdihnagndle sales, technical service, marketing and regulatory expertise. ws 000167 o esSrT oTsunreeee rE --pE n-- E. se FE e TToo i rE armpee r pe rrssnn E EFeE ee e ete e eReEr ree ar FE r B re er T E er r EeseT eeaern EEE re ----a-- E ra e rreaae FBe E eemmse e re a E s rre i r o CEe s T a se peT rree ELee ste rT erTTTT TT p[oommasr x x[=| [eljoe[jeWjWee )TaLf||]E f= m] P Ee r0 ge stee|F | IT T e o e T Ce re T Ie e I F e] maee EDpea oreemoomme enmee| |epe|opeoep[oeoefTj rTr Ta TTp e fe] aesd 000e1m 65 166 ogE reE---- of r ET e --E_Se --t= ee CFPe m oeeEeeteme eEer --e ------------ e e E E SEE ee Ee er E Se -- | E Heee mee H H eeHe EeE Ee -- E SE E s ee e etn e e r e er s t=r n =T SS IIE P. Ae poroammene s | | [aa [fooefl ag lLfel[ LLe E| T EE 4) I e I e Ess P BB--eeE--mo sa--et ,----,-- _,APP---- ,_,-- __e---- eee,---- -- ,--o,o 6 _--_-- 000169 na ogran pa C E r re r E ___ E= = e m M = =r E =SEES| e e EEr r Be e EH EEeEE E ee L hE E re--] mE e = E ee e e e e e ---- [opener | TT a [moos| | I il [=byaperinoma| 1 1"TT[ T | | SS EEL] TLE TeTeILEE E -- S[fB = omoemmomeemen|t | | LTe oaoC[2[LS0T]D[2Ee | |E|Elow=er] -_-------- 168 000170 swrueoarAoR ECxroHesnuEnweMomAuATLOn Commmmon eeT= o TEoeee raoA Rsoe |eep--esrpT eTevfreoTeomee------------| FE a r--T r vs 7 a f t----r f --{--lt m ry Sy CFCe i ooeree se In t r T o rpr E Ea s t t e| Comer a EEm SE r s re r s feomee [TT 7 TT TT mee rrTx tw rr Fe ee ey es eees ELe eemee oes[+ =[oT [oe[+ we [p [ | po + T o prem tee] n r me rp ePee 000171 CHEN 169 SMFLUORROECHTEAMNCAARLKEEXTPSOPSRUORBEOEWTFSRMATION = en = Em] CS | proEpurcirn=tcs [mI mrS ---- Ee -- ypS7a REe eheStB oE dpre hs E oe C [EEGs STAT ETT--%T Eee FCI oammee f 1 Tlh Fstr ore ree sy rr 3h Eo s i e| 3Ht oe BS fE eteso ron e1nmT n n sre atee ee aee [LeomEmSoewos||W[ | seS 1 T T1T T 2 T TiT T TT T T T T 1-- ]| comme ToTTs[0[0[| [oo] | | femme [LoEgromaIX[XHT[T ws T r Te T fom F Bee e F w +p r Pe ef---- o r ver -_-- 000172 s 170 ruoETRALoMARCKEEOTHSSPURBROEOIUGFCToSrAATILON _ smoover sant amr em Fim -- n1 n+ oe cs rem es StB (Joas o | FEoee e -- tr rr e tp FFrlaemgee+ T + e rn r F e r r o fee pe rrr poset [Pwpeimvod|| | |T wre eT T r TT[| Ee ems e E eu e e e ee Fewert--t--+--+--+++--+--+--+--@1-------------- _---- mn 000173 er ooo PE Er F eeey e F et ee Lemt me e e t|r e e fr oe erF e o eeTer Te m eee aon EFeetee et | B B Bt t t EFP oeimge T e+ t m +r e -- ee -- --+--t e+ --e++t ------ PF E e mr er FEeeem +t ee + ee C( es TT rr TT rrF rr T rT r 11 Pbe eete r |taee|ee T setEta T e TT T | E Ee er e r r F r e Tefey w FE eset--tH--F+ F+--+--+--F----t r--+--+--+= --+--+------ Ett tt tttt te ----- 172 000174 arss oy ees [r---- fom Te aTen TeToeat ] Fees C Esoooes eeEe et = ca EE e se e e E S eeS t t o Femmes rcee re eten on e EE t tC aever E Ee E E eee+t m f r m r r r e e e p t rrE+ t Foes ---- + + TTT 1 1 1 CC ee= s|T eeeT 1smsnTc:TT1 1EElL eerespH epH pope IEN Tre | Eomen|f so enr oe mr tEsEte SE | Eomme monme F LL L t TE x I 000175 CEES Aftermarket Application and Retail Consumer Business Retail Markets Products Product Volumes and Use Patterns Summary `This summary is based on individual products. It is a descriptionofthe application, chemistry, use pattem, exposure and environmental fate. Product Code: Generic product description. Application, Process or End Use: The perspective from which information was assessed. The routeofexposure, the concentrationofluorochemical, the use pattern and the environmental fate may vary with application process or end use -- products can be used for more than one application. Generally the following definitions apply: Process: useoffluorochemical-containing product in manufactureofanother product; may include dilution prior to commercial distribution. Application: useoffluorochemical-containing product to treat a substrate; may include product dilution by end user EndUse: useoftreated substrate Volume FC Solids Sold in 1997: Poundsoffluorochemical solids sold per product in 1997 expressed in thousands (000). FC solids less than 1000 Ib are indicated by approximate pounds displayed inside parentheses (-). Chemistry: Generic descriptionof luorochemical ingredients. Full chemical names are listed at the beginningofthis section. AmountofFluorochemical Present: The fluorochemical concentration present in product during process or end use. 9% Residuals: Sum total ofconcentrationofthe mixtureoffluorochemicals that are unreacted or partially reacted starting materials or intermediates. Use Pattern: Indicates the major sector where product is used; food, industrial, commercial, and consumer. ManodstinLhailkaetliyonR.ouMtaerkosf Etxhpeosmuorset:iIkdeelnytirfoiuestetohfreeexppootseuntriealwirtohutaens of exposure; "X"" ingestion, dermal, Environmental Fate: Identifies the most likely disposal route for the product; landfill incineration, wastewatertreatment, anddirectly to water Comments: Provides additional descriptive information. 000176 QE3 D 7 ewne SETTT Ee ECrERE eH f o* E olH e| E e re e e e ee e | :EE er Fee TT betel T TTTT | Ere TT ree AcmeAplcion nd Rel ConsumeBusses Endo Retail Markets Products Section 000178 Qu. 176 Aftermarket Application and Retail Consumer Business Commercial Markets Products TABLE OF CONTENTS Fluorochemical Identities Chart Situation Analysis Distribution Chain & Points of Contact FC Exposure Information Summary FC Exposure Information Charts UsPreoPdautcttemVnoslSuummemsa&ry Product Volume&s Use Patterns Chart 00017; ED 77 CFOLMuMoERROCCIHAEMLCNAALRKDEETNSTIPTREOSDCUHCATRST | FeEd eT |CEgefeI en I Er -- sg2 z Aftermarket Application aad Retail Consumer Business `COMMERCIAL MARKETS PRODUCTS Situation Analysis BUSINESS DEFINITION Commercial Markets Products havetwo distinct productcategories: A) Cleaning and protection of commercial building and residential `uphoanldcsartpeetwrityh 3M products `by professio `commercial nbauliladpipnlgiscabtyorsp.roCfelsesainoinnalgstaanfdf maintenanceof floors, suchas in-house custo walls dians and and other hard surfaces in independent contract cleane rs. B) Treatmentofconsumer and professional film negatives by commercialphotoprocessing facilities. KA)E3YMPprRoOteDctUoCrsTaSnd claaer/protectors orcommercialbuilding and residential carpetsandupholstery manufactured as liquids intended for spray application. (Hard surface cleaning products are not considered inthe following sections because useoffluorochemicalsin the formulationsisataverylow level -- perhap0s.1% of the formulationorless --and because similar productsand usepatternsare considered in othermarketsectionsofthis 3Massessmentreport.) B) Liquid photocurable coating for film negatives. `protection for photographic film negatives, Cured, durable coating provides scratch and solvent AK)EJYaniMtoAriRalKsEupTpSly, profesional supply houses B) Commercial film processing facilies KEY CUSTOMERS A) Fumiture retailers, building maintenance personnel, professional residential `carpet cleaning services B) Individual retail consumers (photo negatives) and commercial/professionalphotographers. AI)NTTreEaNtDmeEnDt UofScaErpetandupholsteryfor ufimat useincommercialbuildingsandresidences B)Machineapplied andcured (closedsystem)in averythincoatingonfilm negativesat commercialfilm processing facilities. EXPECTED USE PATTERN A) Liquid water-based products applied using low preosrpsaiunt-rtyepe spray apparatus. Articles are treaattethde customer residence, in commercial buildinogrsi,r `he furnitureretailers establishment. B) Film protectoris applied by commercial applicators only. Cured, dry, treated filmishandled by commercial and retail consumers. t 000181 CEES 179 Aftermarket Application and Retail Consumer Business Commercial Markets Products Distribution Chain and Pointsof Contact Tiths eulftoilmlaotweienngdinufseo.rmaIttiroenprdeessecnrtisbaensotvheerpvatihewtohef3thMe psrigondiufcitcatntakpeosinftrsowmhtehreettihmee 3itMleparvoesdu3ctM to may be handled and used. Tishsehdiipspterdibfutrioomn cthheaimnanfuofracthteurCeormmtoertchieadlisMtarirbkuettosr wPhroodusceltls tisontohte ceonmdpluesexr.. IOnngeenoerramlo,rep.roduct twwaroeihnosutsanicnegs,st3epMs pmraoydubcetiinsvorlevfeodr.muDlautreidntgodeisntdriubsuteiofno,rmtuhleaptrioonduocrtliest idnoswenalfedrocmonctaoinnceernst,ratIne cthoaienn.d uRseefocromnucleanttriaotniaonnidnletthdeodwinstarribeutcioonnspirdoecreesds.inNthoecphoairnttssoafrceopnrtoavcidtecdhafrotrs.the distribution fTlhueorfooclhleomwiicnagl-cchoanrttsaipnrionvgipdrepoodiuncttsdoufrliinkgemlyacnuofancttuarweictathndthceus3tMomfelruousreo.chemical and Tmhairskeitnpfloarcmeatbiaosnedwaosnc3omMpitelcehdnifcraolmse3rMvicienltsearlneasl vkinsiotws laenddggeoenfertahleimnafnourfmaactitounrifnrgopmroccuesstsomaenrd interactions. 180 000182 COMMERCIAL MARKETS PRODUCTS CC-1,CC-2, HC-6 MANUFACTURE [WaWrareehhoouussee| QA Sample QA Testing SaQmAple Disposal Rn Dock Staging Area Weigh Station Charge Mix Tank Adjust pH, solids Ship to Customer Drum Disposal Rinsate Disposal Broken Disposal 000183 --- wm - COMMERCIAL MARKETS PRODUCTS CC-1 MANUFACTURE (Via Formulator) Receive OC-2 CL Area DDiispoosrala Dilute with water. Add chelator, fragrance. Samppliee [TTesetsftoroprH] ox Fe Adjust batch pH ie {Warehouse Dilute prior to use by applicator --- 2 000154 COMMERCIAL MARKETS PRODUCTS PC-2 Manufacture (Via Formulator) PC-1 3M Qa Sample QA Testing Staging Area Charge Mix Tank Dilute with water Drum Disposal Rinsate Disposal QA Sample Disposal Fill, Package PC-2 Reject Disposal - Ship to Customer :" 000135 EEE 183 COMMERCIAL MARKETS PRODUCTS CC-1 APPLICATION CC-1 diluted in warehouse; truck tanks filled Transport to customer residence Spray on furniture, carpet Arrange furniture for treatment Reposition furniture for drying Let treated article dry Customer uses treated article --- 000186 184 COMMERCIAL MARKETS PRODUCTS PC-2 APPLICATION Retailer warehouse SpPrapyA"booth Enclosed area; no ceiling; ; (on) Designated area; no enclosure Ship to furniture retailers Unpackage furniture; prepare for treatment Spray furni:ture Clean sprayers Move furniture to drying area =---- Customer uses treated article Customer picks up furniture 000187 185 --- COMMERCIAL MARKETS PRODUCTS HC-6 APPLICATION Store in facility HC-6 Rec'd from 3M Pour portion into `machine reservoir (multiple fills from one container) Container disposal Coat, cure onto film (continuous process;[>| Clean equipment closed system) Rinsate, wipes Disposal Coated film sent to customer 000155 186 SE. Aftermarket Application and Retail Consumer Business Commercial Markets Products 3M Fluorochemical Exposure Information Summary handlingof 3M fluorochemicals, materials containing 3M fluorochemicals and artices treated with Based on the Distribution Chain/Pointsof Contact information, each principal step in the `manufacture and customer use processes are isolated. All information is based on the use and 3M fluorochemicals. The following information is presented: Pointof product Contact: Describes individual steps in the use pattem. Use pattern manufacture and end use application by the professional applicator. includes steps in Most Likely RouteofExposure: Identifies three potential routesofexposure at each point of contact -- ingestion, dermal, and inhalation. Marks the most likely routeof exposure with an "X". eEsxtpiomsautreeddNuruimnbgeurse.of DWuorriknegrse:ndInudsiceaatpepsltihcaetinonu,mb"enruomfbwerorokfweorrskwehros"mraeyprheasveentpsotneunmtibaelrfoofr occupantsofresidence present during and aftr product use as well as the professional applicator. Estimated Exposure Time: Indicates the amountoftime that manufacture workers/end users potentially may be exposed during use. oPhfyesxipcoaslurFeo.rm: Indicates the physical state (liquid, solid, aerosol, or vapor)of the product at time Open or Closed System: Indicates open/closed statusofproduct at timeofhandling as follows: Ofpleuonroscyhsetmiecmali.s dEefxianmepdlaessoofneotpheant aslylsotwesmswoarrkeemrisxitnogckoemtteleisn, direct open contact with 3M drums and bottles. Closedsystem is defined as one that, under normal conditions, does not allow workers to come in direct contact with 3M fluorochemical. Examples ofclosed systems are sealed drums and filled sealed containers. `Comments: Provides additional descriptive information. Disposal: Indicates most likely methodofdisposal ofthe end use product ~ sewer, lands, recycling or incineration. "This information is based on 3M internal knowledge and best estimates on how customers handle s3aMlesf,ltueocrhoncihceamliscearlvipcreo,dumcatrsk.etIinnfgoarnmadtrieognulwaatsorcyoemxppielrteidsef.rom available 3M sourcesincluding 000159 ~~ CEEEEND 187 R ET --R ---- -- PFE eo m m =eeeesa ee e e L Bee r [. TpertnT E g E E E E eT mE C T F e e e e[ e T rr5 T e e e e = -- | Eee -- ee LTTT Twtc Te Tree E PEE mEESEEm E he Eeeeee El e E E eel e e aE n 1 e e T!H) CPee ELE E [T eT. eel e L1E E [Te T T-- EEE mF LE etoteiae |la |T e TT eT Te oTT [1 T e o femme] Pe lose]| [To[ TL [| [m=] E F[B e JeSe PN e e I Ee Ee Ee ee] Ls 188 mm rmimeerresspon EEE E PE aee eme peerleoneEE S|E |B Bee F o eeeee rTr e oe eeee) E PeaEsem eH E e e e e ee Bet TE A E or ee e 5-53 I I4 = EmreE l L rea e E l e ||]e = lE ee e | | [[| [LITT] = 000191 --- 189 sapurctoors oman EHEEE ee e EeEr T r= e e E e ee e s ---- E bE EE EmE eEEE EEEEEEEer Te e E=e r = e t =e -- EEE e emEeEe E e e e == e e ee------ EE E ee y pE ee mr Ebmee eeL LT LLL LTLLLE] EE me be Le BEREr bomee |LLLTTTT]loom 000192 Aftermarket Application and Retail Consumer Business Commercial Markets Products Product Volumes and Use Patterns Summary "This summary is based on individual products. It is a descriptionof the application, chemistry, use pattem, exposure and environmental fate. Product Code: Generic product description. `Application, Process or End Use: The perspective from which information was assessed. The routeofexposure, the concentrationoffluorochemical, the use pattem and the environmental fate may vary with application processorend use -- productscanbe used for more than one application. Generally the following definitions apply: Process: useoffluorochemical-containing product in manufaocftanuotrheer product; may include dilution prior to commercial distribution. dAiplpultiicoantiboyn:endusueseorf.fluorochemical-containing product to treata substrate; may include product EndUse: useof treated substrate `Volume FC Solids Sold in 1997: Poundsoffluorochemical solids sold in 1997 expressed in thousands (000); FC solids less than 1000 Ib are indicated by approximate pounds displayed inside parentheses (-). Chemistry: Generic descriptionoffluorochemical ingredients. Full chemical names are listed at the beginning ofthis section. AmountofFluorochemical Present: The fluorochemical concentration present in product during process or end use. % Residuals: Sum totalofconcentrationof the mixtureoffluorochemicals that are unreacted or partially reacted starting materials or intermediates. "ND" indicates residual level not determined. Use Patten: Indicates the major sector where product is used; food, industrial, commercial, and consumer. Most Likely RouteofExposure: Identifies three potential routesofexposure; ingestion, dermal, and inhalation. Marks the most likely routeof exposurewith an "X". Environmental Fate: Identifies the most likely disposal routeforthe product; landfill, incineration, waste water treatment, and directly to water. Comments: Provides additional descriptive information. 000193 191 Mourne" Fes = ee EH TE [HEE Aftermarket Application and Retail Consumer Business End of Commercial Markets Products Section 000195 193 - Aftermarket Application and Retail Consumer Busioess END OF FLUOROCHEMICAL USE, DISTRIBUTION AND RELEASE OVERVIEW 000196 194 Performance Chemicals Fluorochemical Use, Distribution And Release Overview 000197 195 * 1 a Foreword Tbuhsiisnersesp.orIttias atcotmpreteohamennspswievtretlhsoeokfoatlleoxwpionsgurqueetsoti3oMn'ss.. fluorochemicals in Performance Chemicals WWhhearteprdoodeuscetxspaorseucrueshtaopmpeerns?exposed to? * What type of exposure is it? Tishnevgeomle3vnMitnfsglaumnourdltouicspheledemfi3ocMramlpubrluotsdiiupncletessseitnhsdactporamorpdeulaceptpxsl,ainedd gtolombuallt,iMpalerksuebtstsrsaetersv,esdoalrdefhaisgeh`lmyufltriaplgemmeanrtkeedt Sources Information for this eport was developed solely from internal 3M sources. These include: 7IntBKeesrtnnaesltiso maaletosefsw roepfproeorl ndtudsc-tue hsaendad lpipnlgicgaantidoe unssefrpormacktnicoewsnrcoumstfoimeeldrasctivaiatinledsecehuicsal personel * Knowledge ofworldwide activities (where applicable) by St. Paulbased-personnel `HowToReadThisReport SituatiPornoAvniadleyssibsa:ckground on business and products. DistribFuotlilonowCshtahienpaatnhdofPoain3tsM. offluCoornotcahcetm:ical throtuhegdihstroibuutiotn chain o final end user LoObajdeicntigvediosctkothirdeonutgifhyparloldpuocitnutssaogfecaonntdadcitswpiotsahl.ourchemicals fromarivaloneymenrs Exposure Information Charts: Chteemmipctalstowiqtuhaintnitfhyetdyipsetarinbdutiloenngcthhaoinf,exposureandnumberofworkersexposedtoour ProducetCxoVpmoobsliuunrmeeesbsy3aMpnprdrodoUudscuetPcattytdpetete.arinlsw:iththeexposureroutes to provide a summoafrtotyal business 0019s 196 CEE Table of Contents L Chemical Names IL Situation Analysis A. Fire-fighting Foams 1. Business Definition 2. Products and Markets 3. Customer Location B. Mining and Oil 1. Business Definition 2. Products and Markets C. Metal Plating and Electronic Etching Baths 1. Business Definition 2. Products and Markets D. Household Additives 1. Business Definition 2. Products and Markets E. Intermediates 1. Business Definition 2. Products and Markets F. Coatings and Coating Additives 1. Business Definition 2. Products and Market . . J 17 000199 Table of Contents Page Two G. Carpet Spot Cleaners 1. 2. PBruosdiuncetsss aDnefdiMniatrikoents 3. Customer Location H. Insecticides 1. Business Definition 2. Products and Markets IIL. Exposure Assessment A. F1.irDei-sftirgihbtuitnigoFn oChaamin 2. Pointsof Contact 3. 4. Exposure Routes Production Volumes and Use Patterns B. Mining and Oil 1. Distribution Chain 2. 3. Points of Contact Exposure Routes 4. Production Volumes and Use Patterns C. Metal Plating and Electronic Etching Baths L. Distribution Chain 2. Points of Contact 3. 4. Exposure Routes Production Volumes and Use Pattern D. Household Additives 1. 2. Distribution Chain Pointsof Contact 3. 4. Exposure Routes Production Volumes and Use Patterns E. I1.ntDeisrtmreidbiuattieosnChain 2. PointsofContact 000200 198 3. 4. Exposure Routes Production Volumes and Use Patterns F. Coatings and Coating Additives 1. 2. Distribution Chain Pointsof Contact 3. 4. Exposure Routes Production Volumes and Use Patterns G. Carpet Spot Cleaners 1. Distribution Chain (CPoomimnetrsocfiaClonCtaarcet,PrEoxdpuocstusrDeiRvoisuitoens)done by Home and 3. Production Volumes and Use Patterns . H. Insecticides 1. Distribution Chain 2. Points of Contact 3. 4. Exposure Routes Production Volumes and Use Patterns -_-- 000201 199 Chemical Names iTnhdeivfidoulallopwriodnusgctasl.istTohfeCfhoelmliowcianlgAbisntfroarcmtaStieornviisceprse(seCnAtSe)d:names and mumbers for Generic Code: Indicates an internal 3M designationofthe product(s). cCoAntSaiNnuemdbweirt:hinInedaiccahtperstohduecCt.hemical Abstracts Services mumber(s)of fluorochemicals eICnahdceihmciaptrceoasdlutcNhtea.mCheem(iccomapllAebtsetCraAcStsnSaermveicoersInUaPmeA(Cs)noafmefsliuforCocAhSemniacamles dcooentsaniontedexwiistt)h:in ChemicalClass:Indicates ashortened,genericchemicalname. ----- 000202 200 Eee | [Ee] memeTo) | EE-------- | m---- Ee ------ Ee-- fF I -- EE FF ---- -- g =---------- | s = | [Eo]emer em] Eee tr Be 1 rEeV---- | 8 ---------------- | 2g rr1 [em]oreo oman] | --tr we ------ 1 7eer} | gle Ee [aToon] omerrmrosmoe amas] rT e-- Tt | 0 a wor ----------------| eed -- -- g~ p[eBtTe -------- m ---- | | g -- 7 vv. Situation Analysis A. Fire Fighting Foams tT Business Definition Fire Protection Industr--y Description: Light Water and ATC are trademarksfor classB fire foam products manufactured by 3M that are aqueous film forming foams (AFFF) and alcohol resistant concentrate (AR-AFFF) used to suppress and/or extinguish flammableliquid fires and suppress flammable liquid and toxic chemical `vapors. Branded foams are `manufactured as well as commercial, competitively priced AFFF's and AR-AFFF's. a) Fluorochemical Foam Surfactant ConverterSegment `This segment is comprisedof companies who purchase fluorochemicalintermediates and convert them by means ofa chemical reaction to `organic fluorochemical surfactants for use in formulating flammable liquid fire fighting foam. Otherthan 3M, `who convert their own intermediates to surfactants, most surfactant `manufacturers in the United States either convert their own intermediates, or obtain their intermediates from companiesotherthan 3M. 3M intermediates that end up in fire fighting foam are `non-existent in the United States, but couldendup in the United States from sources outside the United States where we do sell intermediates for this`segment. b) Foam Formulator Segment: concentrated agents `This segment is comprisedofcompanies that formulate their own AFFF products from Fluorochemical surfactants, or mixtures ofsurfactants called superconcentrates or ) Fire Extinguisher Concentrate Segment: o`Tnhei-sgsaellgomnenetquiisvcaolmenptripsoretdaobflceoumpptaonitherseewhhuondmraendufoarcmtourree fgiarleleoxntifnigxueidsohrerwsh,eferlom `mounted ready to use fire fighting systems. d) Foam Flammable Liquid Fire Fighting Segment: `This segment is comprised ofall usersof AF andF AR-AF FFF Foam. These are the end users, usually describedat "fire fighters". A fire fighter uses the concentrateby 000207 CHEE. 205 wduactteirnags,aoprrem-imxiixn,goirt wuistihngwfaitreerfiatghtthiengtiemqeuoifpmfeignhtttihnagat prfiorpeo,retiitohnesr bthyemcioxnicnegntirtawtieth `swyistthewma,tecornatsaiint iinsgustehed.coAnnceontthreartef,oirsmoeifthfeirremfainguhatlilnyg woirtahutfoomaatmiicsalwlhyeracetaivfaitxeedd `fcoarucseidngthtrheousgyhstspermintkolfeorrhceeatdhseocronacnenaturtaotmeatiinctomaownaittoerrdisrtercetalmytwohetrhee tfhiree."mTihxteu"rfei"reis ffilgahmtmear"blwiellliaqlusiod uthsaetfios abmurfnrionmg oarfiisxeedmiitntsitnalglfatliaomnmfaobrleap/ptloixciactivoanpdoirrse.ctlyto a 2. Products and Markets: `Faoutaommactoinccalelnytraarteeu(sieddenitniftiheed fionlIlVo.wain3g) muasrekbeyttahreea"sf:ire fighter" either manually or Market Area `OTEChemical Industry Description `stCohreagmeifcaacpillliatnitess,, pteratnrsoploerutmatrieofnin(eerxicesl,udtienrgminal marine) Sprinkler Systems enPdu-rcuhsaesreprrsoodfufcotasm(i.co.n,cfeonatmra/tweastefrorspirnicnlkulseirosn, in fire trucks) Marine `Water transportation vessels Fire Brigades Local government fire protection services Civil Aviation Off-Shore. Military Hazardous Waste Airports (Crashfirerescue) + Total drilling platform protection systems Federalinational government armed forces `Environmental Clean-up Companies 206 000208 3. Product Code FF-1 FF-2 FF-3 FF-3A FFFF-3B FF-5 FF-5A FF-5B FF-5C FF-5D FF-6 FF-6A FF-7 FF-8 Key Product Sales Lbs. PE-1 Solids Per Gallon Gallons Sold 2 G-- a 0002 03 000210 HEED 208 000211 209 -_-- 1. Stuston Ansys -- PTei eeeeeeThsSig Hs sogaamemcn oscttsoibsoocnogeearrnagsgiomiens preroesnvihsL s ttosnchmT ehrrTo Sl 98 oTissn aamsted1o33msn ecmowe r ostreec orretmlenhusd lgcroemrpeasnsies rat si 3 sacanns Pros [So (000) uuenMeoesossT ues MO-5 000212 oun ` 210 . Metal Plating and Electronic Etching Baths wsMiuetrthfaalNcItPaOlnaSttsHinfgro-eTgshuuiipsaptsrieeonsgssm.eonx3itMdiizsniucnrigufdaaeccstiadcnthmsirsoatrmeiensaoonlrdddt peltarostph iarcosptrepe ecoptwltadhtr eeelrresotpctehorafnaottropmrlusaltaheteroaslrtswhhwiohnoucosmmeapn3luiMfaacntcuere. solid pellets that are sold o the platers or as liuids that are sold directly to the piaters SEsultrerfcoatncrgtoaanncitcisdEsatcrinheoirendfge.hreTtrhoisesotlsdcethgompferoenrctmiusilenactploaurtdsteswemhtshoeipneularefcsytiriaocnnoidncwsdaimfateneruoftrahecatsupurrreifrnatscetdwanhctoisrabcdeufdboo3raeMrds,seulrifSnagucttahenrtms ttoo the end user or sold directly to the wafer manufacturer PPrEodTucts --Po_un--ds PE PE3 an 000213 D. Household Additives. PbThahoistseodsgerpgarmpohediunccttfsiimn.tchlaut3deMasrescuhsreofmladicctaaasnltcsfloeararmneuelrsasot,lodrwasasxwelhisoq,uiufdlssoeotr3opMtohlsieusrfhfoearscm,tusaiunarttfsoartscoeipmrporteocvteivteheco`wmepttoiunngodfs.waatnegr- parts per million in their product that is sold to the consumer or contract who dite cleaner. them to abet 20, Products RAT HA2 HAS Pounds -_ : 2 2 000214 --- E Intermediates imrnoiansowsmaeeygrmsseimniintioirrndtcoelrutdhteeoscwcraheyeamt3iaMcapluraomrcaoencsuhsfeeamscit3cuaMrleirpnsotlweyrmhmeerd.rieaatTcethse3tMomamfnaluufkoaercotscuuhrrfeeamrcistcahanatinsfndtolerermS3eMMdiia-nLttiegesnrtmwieVtdohitateess ie protection foe or fuoinated polymers. wih residues simiar 0 -Scolcngerd" carpet protecie Products Pounds LMMoz3 -- Ms i 000215 213 -_-- F. Coatings and Coating Additives raCpeopcaleiticivanetdgiosonTrsiinisncscolemugbdmieenaanpttpiioicnncawliiuotdnhesotffhoserurmcumhlaacttooorrasalwtsht1oo uiNtmoipuzosere3hoMoidfouorrcwrcaootcmehmreermrciepiceallllposonulcfyyam1ec.re8scosaautfcianecgecs.raosTnypriecal or elecron component. Products Pounds TcAaS s -- (iCnfartsahtceitinaogmnsAouocfnttavepofesrh-caSzeoanrm)detoofueosnrsmhoualinvaceonertwsseoatfnidnprgoo.teefclrtoiwv,veovictoeiaeltiG,ngrsaainndezpeceovremfrpoyromulanonwdcsleeraveenqldsurtoaefdp3enMrsstuurrefeascaeteamsnaotesmnss. Products Pounds TcaAazsT -- cas 000216 EEE 21 G. Carpet Spot Cleaners. `sTthaiisnsaengdmseonlltrienscilsutdaenscefotromuclarapteotr.soTfhcearcpoentsusmpoetrcslperaanyesrsthwephrooudsuect3oMnfclauropreotchemicals to provide TPrSodTucts P--ou_nd--s 000217 SEES 215 H. Insecticides aonnidsopsleajgcemdeatcnitntibeivaneiiitnrusgdtraeeetdsiiofenondsrtmsf.uoirlae3taoMfrcsfulotuftoeirnroscaenhctetsm,ciocpnathlrasorlaorbaeahibtalsnettnasdtieaodnndswicwtohhcobkfuaosaetchh3aetMsi.sflauotrorcheartisccfaeliavsseect PTroZducts P-o--unds ict 216 000218 Distribution Chain id{iiscntesrpidrbeiusatcgiaortnasmcahnraeiopnrvereserepvnriteesswetnhotfspttahthehsttiyhgpneiicf3ailMcaupnsrteopdooufitcnhttseawpkhreoesdruefcrttohmet3heMtpirmoeduict teamvaeys b3eMhatnodilsedulatimuatenenTdhuises. step. This information is based on 3M internal knowledgeolfitnheenomtaervkeertyplparcoeduct wil go through each 2; 000219 AFFF Surfactant Converter Segment Distribution Chain Distributor/ Contractor Industry/Gov't Fire Dept AFFF Foam Formulator Segment Distribution Chain ne cco220 --- AFFF Foam Formulator Segment Distribution Chain Distributor/ Contractor Industry/Gov't Fire Dept 29 000221 -_---- AFFF Fire Extinguisher Segment Distribution Chain ' Extinguisher Manufacturer Distributor/ Contractor Industry/Gov't . Fire Dept - 220 000221. -_---- AFFF Flammable Liquid Fire Fighting Segment Distribution Chain Distributor/ Contractor Industry/Gov't Fire Dept --- CL 221 -_-- 000223 Pointsof Contact kiTnhtoehwPltoehiedngtaersoroifvfatlChooenftm3aacMrtkedptirpaoldgaurccaetmbadatesttehaidels3ontMh3ecMupsatttoehmcethhnrei.cparlTohsdeuivciitcntefa/oksreamslaetwsiiotvnhisiwintastshaecnoddimsptirlibeudtifornocmha1iMn sjtaarntiensg the customer interactions. general mirofrom 000224 222 --- oa Points of Contact Fire-Fighting Foam Surfactant Converter Receiving Dock [oJwes [oon Drum Staging Area - Drum 000225 -_-- 223 Points of Contact Formulator Fire-Fighting Foam Receiving Dock Staging Area 3 Package (fill) | Ship to . Customer Drum 224 --- -_---- 000226 Points of Contact Fire-Fighting Foam Fire Extinguisher Staging Area Extinguisher/Tank| Returned or Shipped to Customer : 000227 CEES 228 Points of Contact Fire-Fighting Foam End Use All Products Com) pict| | Direc Land Water 000228 -_-- 226 3M Fluorochemical Exposure Information iaFsrrtbiocamlseetsdhteorePnaottiehndetswuisotefhaC3nondMthafaclntudoflrliooncgwhoecmfhiacr3atMl,se.falcuThohrseotcefhpoelimnlioctwahilenscg,umisanttfoeomrriemaraltusisocenopnirtsoapcirneeissnsegnits3eidMs:olfautoedr.ocAhlelmiinsfaoermsaotsion PointofContact: Describes individual steps in the use pattern, iMnohsaltatLiiokne.lyMRaoruktseothfe Emxopsotsulrikee:lyIrdoeuntteiofifeesxtphorseeuproetewnittihalanro"utXe.sofexposure; ingestion, dermal, and EdusrtiinmgatuesdedN.umberofWorkers: Indicates the number of workers who may have potential for exposure Physical Form: exposure. Indicates the physical state liquid, solid, aerosol, or vapor)ofthe product at ime of OCOlppoeesnnedosryssyCtsletomes:me:disiSsdyesdfteiefnimen:dedasasonoentehathtaatl,luonwdserwonrokremrasl tcooncdoitmieonisn,ddioreecstncootntaalcltowwiwtohr3keMrsftlouocrochemical, direct contact with 3M fluorochemical. ome in Comments: Provides additional descriptive information. ftTeuhciohsrnoiiccnahfleomrsiemrcavtaiilcoepn,roimsdaubreakrsese.tdiInongnfao3nrdMmartienigtouenlrawntaalosrkynceooxwpmelpreitdlisgeeed. afnrdombeasvtaielsatbilmeat3eMssoonuhrcoewsciunsctloumdeinrgs shaalneds,le 3M 000229 227 | |p mE] sess mtn:rss ion tsLT pees | eT pee | TE TT f peee I| E T E = I ] 5 fe eS m ErE E aTST ST T 3Bye vr fee fame fem ee je fe] pores TT pe e ee ee pee eee | [ T T L TE TT T oeeen bee [TT i 2| | romusronee ra m i ee ese {=Ilfron J foifeng i e 1 eem a --- M fE oo es eEE eeeeee Xf F FF F F r r fF rr r f Fr F ttt 000231 elleLo SlI I EP To PO P PE P I Py epain r r r+ r + -- Ft Ft FF FF f -- r r r ee r rr + --+ r + Fr+ " EE---- F-- F em F EE ---- i --|-------- F F F F F--F rr " 000232 = FR Lo Tomos[own| --AEE JoeomrentJe oera|] Hy EE T= e L e TT- T e Le eee r rt r ee F r F rrF t r rt r r + CL] EXTINGUISHERS (fers) tt Ff emme h1 w [fe e e mer fB f f ee o y m m e] em a eeeneeee) Eomes We PO even F F F F -- FF F F -- f+ F FF F F -- FEFfF F e F H----Fr Fr F a ---------- 000234 Product Volumes and Use Patterns pTahtitsersn,umexmpaorsyurisebaansdedenovnirionndmiveindtuaall products. fate. Itis adescriptionofthe application, chemistry, use Product Code: Generic product description. apApppepllriiccsaatt:iioonsnh,perPocrcooencscesesonstrroearntEidonnudsoUefs~lep:urToorhdoueccphteesrmscipacenac,bteitvhueesuefsdreofmpoarwtmhtoeirrcnehtaehnxapnotohsenureeenvawpiaprlsoincamsesnetsaseld.fatTehmearyouvtaeroyfwith ation. APGpreponlceierscasal:tliyounts:heeoufrsoeflollfuoowfrilonucgohrdeoemcfihicneaimltiiccoaonnsltacapoipnnltiyan:ginpirnogdpurcotduinctantootthreeratparosduubcstt.rate. End Use: useoftreated substrate. Volume FC (M-1000) Solids Sold in 1997: Pounds of fluorochemical solids sold in 1997. Chemistry: beginningof tGheinseserctdioens.criptionof luorochemical ingredients. Full chemical names are listed a the AmountofFluorochemical Present: The fluorochemical concentration in processorend use, p%arRtieaslildyuraelasc:teSdusmtarttoitanlg omfacteornicaelnstroartiinotneorfmetdhieatmeisx.ture offluorochemicals that are unreacted or Use Pattern: consumer. Indicates the major sector where the product is used; food, industrial, commercial, and iMnohsatlaLtiiokne.lyMRaoruktsetohfeEmxopsotsulrieke:lyIrdoeuntteioffieesxtphorseeurpoetewnittihalanro"uXt"es.ofexposure; ingestion, derma, and `EwnavstierownamteenrttarleaFtamteen:t,Idaenndtidfiireesctthley most likely to water. disposal route fo the product; landsil, incineration, Comments: Provides additional descriptive information. 000235 LJ 233 | serena HT TE bsnl eesTT TTLT g TE ET Ee eel E EdTE TE T [Cr meme TT [ome mamas [ee emamaenl Lgdmmad| | TILT LTIT TT Bes of1 froma EE TIT re Pr ee Distribution Chain dITtihsritesrpidrbieusateignortnasacmhnraeiopnvrereserepvnriteessweotnhftetstphhaeetthsyitpghineci3afilMcaunpstreoopfdotiunchttestwpahrkeoesdruefcrttohlmeitn3he;eMtnpiortmoeedvuiectrtlyemapavreyosdbu3ecMhtawtniodlllitesgdoualtnthidrmuoasutegehde.neadcuThhs.ios, step. This information is based on 3M internal knowledgeofthe marketplace. 000238 26 aun Mining Distribution Chain Copper or Gold Mine Heap Ore 000239 237 _----_-- Oil Distribution Chain Oil Well Service Company 000240 a" 238 Pointsof Contact TwkinhtoehwPltoheiedngtaersroiofvftalChoeonftma3acMrtkedptripoaldgaurccaetmdbaetatstaehidels3otnMhe3cpMuastttheotcmhhenrei.cparlTohsdieusrcvitinctfeaolkrsemaslaetwsiivotinhsiiwntastsahnecdodimgspetirnlieebrudatliforinnofcmohr3amiMantsiitnoatnretrinnagl the customer interactions. from 000241 239 Points of Contact Mining Loading Dock Shipped to Leach Area Transfer to Storage Tank Drum Disposal Use Soln. Leach Pad System Clean-out Dripped or sprayed onto ore Absorbed onto ore 000242 240 --_-- Points of Contact Oil Well Surfactants em| a 000243 -_-- 3M Fluorochemical Exposure Information iaFsrbrtaiocsmleetsdhteornePaottiehndetswuisotefhaC3nondMthafaclntudollriooncwghoecfmhiac3raMtlse.aflcuhToshrteoecpfhoelimnlicotawhliesnc,gumisanttfoeomrreimaraltusisocenonpitrsaopicrneeissnsegnits3eiMds:olfautoedr.ocAhlelmiicnaflosrmaantdion Point of Contact: Describes individual stepsinthe use pattern. MinohsaltatLiiokne.lyMRaoruktsetohfeEmxopsotsulrikee:lyIrdoeunttiefoiefsetxhproeseuproetewnittihalaonu"tXe"s.ofexposure; ingestion, dermal, and dEusrtiinmgatuesdedNumber ofWorkers: Indicates the numberofworkers who may have potential for exposure Physical Form: exposure. Indicates the physical sate (liquid, solid, aerosol, or vapor) ofthe product at time of Open or Closed System: CdOilproeescnetdscyossnyttseatmce:tm:wiistishdd3eeMffinfieladunsoaoresonodcehneetmhtiahctaatal,l.luonwdserwonrokremrasl tcooncdoimtieonisn,ddioreecstncootntaalcltowwiwtohr3keMrsfltuoocroocmheemimnical. Comments: Provides additional descriptive information. tTfelhcuihosnriiocncafhloersmemiracvtaiilcoepn,riomsdbauracksteest.dionIgnnfa3onrdMrmeaitgniutoelnrantwaolarskynecxoopwmelpreitdligeseed.afnrdombeasvtaielsatbilmeat3eMs osnouhrocewsciunsctloumdeinrgs shaalneds,le 3M 22 000244 [ saan so sos i SmELmeaE, ast LLL TIT] PN[= e IIPP e I I [1]e A [1 0 PP EY -- FS3ef slom uee T eT e1T .ew be eT r I ee] | Bpees . spans: Eomn bEeH een=|sov|oe ress [ ga1 sSEn= t] ET [ T= T] Commans pm C E B= ae Er e footie IX TT v2 te x5 ge Lobe LIT TL )5 Product Volumes and Use Patterns pTaittsersn,umemxaporsyurisebaansdedenovniriondnimveindtuaallfpartoed.ucts. Its descriptionofthe application, chemistry, use Product Code: Generic product description. baAppappllriicceaattsiioonhn,perPocrcooencscesesnsotrroaretnEidonnudosUfesf--el:uporroTodhcuehcetpmseirccsapanelc,bteithvueesuefsdreofmpoarwtmtheoirrcnehaetnhxdapntohsoeunreeenavwpiarsonamsesenstsaeld.fiTehmearyouvtaeryofwith plication. PAGrpeopncleeirscasal:tliyounts:heeoufrsoeflollfuofowlriuonocgrhdoeemcfihicenaimltiiccooannlstacapoipnnltiyan:ignpirnogdpurcotdiuncatnotothtreeratpraosduubcstt,rate. End Use: useoftreated substrate. Volume FC M-1000) Solids Sold in 1997: Poundsoffluorochemical solids sold in 1997. bCehgeimninsitnrgyo:fGtheinsersiecctdieosnc.ription of fluorochemical ingredients. Full chemical names are listed att he Amountof Fluorochemical Present: The fluorochemical concentrationi process orend use, p%artRieaslildyuraelsa:cteSdusmtarttoitanlgomfatceornicaelnstroartiinotneromfetdhieatmeisx.tureoffluorochemicals that are unreacted or UcosnesuPmatetre.r: Indicates the major sector where the product is used; food, industrial, commercial, and MinohsaltatLiiokne.lyMRaoruktstehoef Emxopsotsulrikee:lyIrdoeuntteiofifesetxhproeseuproetewnittihalarno"uXt"e,s ofexposure; ingestion, dermal, and EwansvtierownamteenrttarleaFtatmee:nt,Idaenndtidfiiersectthley most likely to water. disposal route for the product; lands,incineration, Comments: Provides additional descriptive information. 000247 25 anu . EEL EE el LL ST TTT EE T TR CoddTT TT 3 g CC CT HHET TH T : 5Ey Ettvomvrs 3 =e TelTT] EEI]HR Distribution Chain dITihsritesrpidrbeiusateignortnasmcahrnaeiopnrvereserepvnriteesswetnhotfetspthahtehstityghpneiic3failMcaupnsrteopdoofutichntestwparhkoeesdruefcrttohme 3tMh tpirmoeduicttlemaaveysb3eMhatnodiltedulstiumautseede.ndTuhsies. step. This information is based on 3M intemal knowledge loiftnh;enomtarekveetrpylparcoed.uct will 0 through each a ` 00025; 250 CHEE Metal Plating Distribution Chain 000253 ----- 251 Electronic Etchant Distribution Chain Electronic Part OEM 000254 mmm 252 Points of Contact KionteohwoltpehiedngtaesrioovffatlChooenmtSfaaMrckedptirpaoldgaurccaetmbadtaetstheaeidlso3ntMh3ecMpuastttehocmthehnrei.cparlTohsdieusricvntiftcoaerksmeasaltewisiotvnhiswiinatsstahcnoddmigspetirnlieebrduatlfioirnnofcmohraaMn sptaerteinsg the customer interactions, mation pom 253 000255 LJ Points of Contact Metal, Plating Pellet Maker/Formulator PE-1 -L_wHiotphpefirllmerixed Formed Pressure Cut, extruded, stamped (pellet formation) Pail,poly bag disposal Shipped to Customer See "plater" flow chart 3 2s 000256 (CHEE Points of Contact Metal/Plastic Etching, MetalPlating Receiving Dock Etching Bath Filter Disposal [Disposa|l IQnsCpoefctpiaornt,s j Packaging Psat| | Aqui Sl a Sa --|Container Disposal Plating Baths Powder Bath Disposal Hazardous Waste {Disposa|l n Shipped to Customer 000257 255 * End Use Chrome Plated Something uum Points of Contact Electronic Etching Baths - PE-4,PE-3 Receiving Dock Drum ificati Staging Area Pre-Mix Pail Di; Ship to Etcher Receiving Dock Filter Fa4 e i Disposal Hazardous Waste = 2s 000258 3M Fluorochemical Exposure Information From the Points of Contact flow is based on theuseand handling chart, of 3M each step in thecustomeruse process is fluorochemicals, materials containing isolated. All information articles treated with 3M fluorochemicals. The following information is 3M fluorochemicals presented: and Point of Contact: Describes individual stepsinthe use pattern, iMnohsaltatLiionk.elyMRaoruktseothfeEmxopsotsulrieke:lyIrdoeunttiefoifeesxtphoreseurpoetweinttihaalnro"uXt"e.sof exposure; ingestion, dermal, and Estimated Number during used. of Workers: Indicates the numberof workers who may have `potential for exposure ePhxypsoiscuarle.Form: Indicates the physical state (liquid, solid, aerosol, or vapor) ofthe productat time of Open or Closed System: dOCilproeescntedscyossnyttsaetcmet:m:wiistisdhed3feifMnienfdelduaosarsooocnnheeemttihhcaatatla,.lluonwdserwonrokremrasl tcooncdoitmieonisn,ddioreecst ncootntaalcltowwi`twhor3kMerfsltuoorcoocmheemiincal. Comments: Provides additional descriptive information. `This informatiiosn based on 3M internal knowledge andbestestimates ftelcuhonrioccahlesmeircvailcep,rmodaurcktest.inIgnfaonrdmarteigoulnawtoarsyceoxpmepritliesed.from available 3M on how sources customers including handle sales, 3M 257 000259 ---, delTTT HeSe ET Le ee 1 = = ee= 1= TTESELT E LL TT TT IT =p=e 8 2 s pr pre BL Tee E] AErome| cnes|] CTT A el ] a C E a E -- mT eE LoeLew TTTILTTTTEIT Tg Product Volumes and Use Patterns pTahtitsersnu,memxaporsyurisebaansdedenovnirionndmievindtuaallfpartoed.ucts. Its adescription of the application, chemistry, use Product Code: Generic product description. Aeappxppplloiisccuaartteii,oontnh,perPocrcooencsceessnsotrroaretnEidonundsoefUsf~elp:uroorTdohucechtepmseircscapanelc,btteihveuesufesdreofmpoarwtmtheoirrcnehaetnhdaxnthoepneenowavpaiprssloiancsumaseteinrsotsna.eeld.fatTehmearyouvtaeryofwith GPreonceersasl:lyutsheeofrofllluoowrioncghdeemfiicnailticoonnstaapipnliyn:g producitn another product. AEpnpdliUcsaet:ionu:seoufsetorfefaltueodrsoucbhstermaitce.al containing product to treat a substrate. Volume FC (M-1000) Solids Sold in 1997: Pounds of fluorochemical solids sold in 1997. bCehgeimninsitnrygo:ftGheinsersiecctdieosnc.riptionoffluorochemical ingredients. Full chemical names are listed at the Amount of Fluorochemical Present: The fluorochemical concentration in process or end use. p%artRieaslildyuraelasc:teSdusmtartottianlgomfactoenrciealnstroartiinotneormfetdhieatmeisx.tureoffluorochemictahlast are unreacted or Use Pattern: consumer. Indicatesthe majorsector wherethe product s used; food, industrial, commercial, and Most Likely Routeof inhalation. Marks the Emxopsotsulrikee:lIydreonuttiefioefsetxhproeseurpoetweinttihalanou"tXe"s.of exposure; ingestion, dermal, and EwansvtierownamteenrttarleaFtamtee:nt,Idaenndtidfiireesctthley most likely to water. disposal routeforthe product; landSill incineration, Comments: Provides additional descriptive information. Lov; Exposure formaPtatiHoenr (Hos Patin sth) _ S[e re eomotcoms| rpnoreponn | amiort Ea ieEs NOR R IIP IEY IY be] ee| [L T TLTTT R ITT pe|LT aTL me TT eT pase | Tee TT Ce TL he ame | EE A lI g T [ T1 [] [1 we 000264 ee| pen tmmaE-- =ErEsLp sry fomFoe|ct| Foefr om om || E am e i [Powder | fe [ow | e x foes TH 4 e Bee fe Te ST TT a sn] oeTTTT PTT T een [ous we 1 [x TT a] [1] 1 TT Poems a ee foe TT bw Te TT | 3 000265 Exposure Information -MetaPlastc Etching, tat Pat [cm] motae. e| oC[oopEvoeuoE<rstTii1cns I 5 gered foP aeme os|T ToT T T Ty e 7Tww m eee ITtTe en foE fF e owen| oeerm 1 r F FF r F t r F ei F F F FF r 0 t r F F r F r t r F ] 000266 25 [-- i ffpooemrrsas, Fe oem fe ol-- Jot mspo FFaoo fa|] | Em omar me to T peT pee fo-- nd,------] B ee Tom ] tw pbo oepTloTLr 1T1L]E P e SS ) | EE -- CL a 1 Es xx ] 1 ~ I: SS 2 A Ss A E ; E= ee ---- >| Teme 7 wesw I Wes = ET eT -------- x x1-- ---- ---- ---- ] CE ---- fEfmeEer, -- r ty ErE bene | IR LL oT I TTTo] I I ey ee ESS |Le lEePToI TT I hehre be be T [L LlTToo e TTTT LT TL | poses 8 | ol To [ ee iLT P] n fe oom TT eaamn[ [xo[T][| [ ] 1 beers 1TT 1 TT 1 1] . woozen Distribution Chain This diagram representsthe paththe 3Mproducttakes fromthe time it leaves 3M to its ultimate end use. It represents an overviewofthe significant points where the 3M product maybehandled and used. This sdtiespt.ribTuhtiisonincfhoarimnarteipornesisenbtastshedetoynpi3cMaliuntseeronfatlhkeno`wprloeddugcteolfinteh;enomtarekveetrpylparcoed.uct will go through each 267 000269 --- Household Additive Distribution Chain or Households Office Buildings 000270 268 aa Pointsof Contact "TwihtehPotihnetasrorifvaCloonfta3cMtdpiraogdruacmtdaetttahiels3tMhepcuastthomtehre.proThdiusctitnfaokressawatiitohninwtahsedciosmtpriilbeudtifonomch3aiMn sitnatretrinnagl knowledgeofthe marketplace based on 3M technical srvice/sales visits and general information from the customer interactions. 269 000271 Points of Contact Formulator Household Additives (cleaners, polish,) Receiving Dock Staging Area Pre-mix Gi Drum Disposal Cleaner End Use Customer 000272 7, GEE Polish End Use Household Polish End Use Commercial ` am 3M Fluorochemical Exposure Information aiFrsrbtiaocsmleetsdhtoernePaottiehndetswuoisfteChoa3nndtMahfcaltnudoflrliooncwghoecfmhiac3rtaM,lsef.alcuThohrseotcefhpoelimnlioctwahilenscg,usmiatntofeomrreimraalutssieocnopnirtsoapcirneeissnsegnits3eidMs:olfaltueodr.ocAhlelmiicnaflosrmaantdion PointofContact: Describes individual steps in the use pattern. iMnohsaltatLiiokn.elyMRaoruktseothfeEmxopsostulriek:elyIrdoeunttieofifeesxtphoreseurpoetewnittihalanro"uXt"es.of exposure; ingestion, dermal, and dEusrtiinmgatuesdedN.umber ofWorkers: Indicates the numberofworkers who may have potential for exposure Physical Form: exposure. Indicates the physical state (liquid, solid, aerosol, or vapor) ofthe product attime of `OOppeennsoyrstCleoms:edisSdyesftienme:d as one that allows workers to comeindirect contact with 3M fluorochemical. dCilroescetdcosnytsatcetm:witishd3eMfinfelduoarsoochneemithcaatl,.undernormal conditions, does not allow workers to come in Comments: Provides additional descriptive information. f`Tlhuiosrioncfhoermmiactailopnriosdubcatsse.d oInnf3orMmaitnitoenrnwalaskncoowmlpeidlgeed afnrdombeasvtaielsatbilmeat3eMsosnouhrocwesciunsctloumdeinrgs shaalneds,le 3M technical service, marketing and regulatory expertise. --- a mn 000273 " Exposure inforHomuseaholtdAiddiotivnes [E[xpoLs<uo1rheeTw,i<ne50s oJrae,ys51o00dda1y4s | E HN r {oToTmeatrEf e onsopet pan |r iE van a rooep , eesi CT---- pomen | fmm e fe Ee poe foe oe |Et tn TT ee TT ---- Fe ean 000274 Exposure Information -Household Aditves [[Eoxwspoeusu<mrbesrTi<s0 . [JJHria,geh5e0sn1t0ih0eaam1.a0 oto say Opanar loss memf e o |]mT fos fT n en|T pf Ee Spe--cm-- e f e ee e Bn TTRta on te et SE prem EBee em --p -- p eee Bfoewm mmer 7 Wee ee -- f Ep me m r -- ee ae ea Jeena me TF ee ee 000275 an Exposure Information - Household Additives [C-- ExopoasersTsimee: Teer rgJoevheseaa10a0r14 Pion e pe e e [s 1e|e | [ on E 1 [ t | -- Et m e t wwm e x F F tt r r r r F r 1 Hr F ----r -- F ------ f 000276 Product Volumes and Use Patterns pTahtitsesm,umemxpaorsyurisebaansdedenovniriondnimveindtuaallfpartoe.ducts. Itis a descriptionofthe application, chemistry, use Product Code: Generic product description. aeApxpppplolisiccuaartteii,oontnh,perPocrcooencscesesnsotrroaertnEidonnudosfUesf~el:uporroTdohucechtepsmeircscapanelc,btetihvueesuefsdreofmpoarwtmhtoeirrcnehatenhxdapnothsoeunreeenwvapaiprsloiancsmasteienostnsa.eld.fatTehmearyouvtaeryofwith PGreonceersasl:lyutsheeofrofllluoowrioncghdeemfiicnailticoonnstaapipnliyn:g productinanother product, EApnpdliUcsaet:ionu:seoufsetorfefaltueodrsoucbshtermaitec.al containing product to treat a substrate. (VMo-l1u0m0e0)FC Solids Sold in 1997: Poundsoffluorochemical solids sold in 1997. bCheegmiinsntirnygo:ftGheinsersiecctdieosnc.riptionoffluorochemical ingredients. Full chemical names are listedatthe Amountof Fluorochemical Present: The fluorochemical concentration in process or end use. p%arRtieaslildyuarlesa:cteSdusmtartottianlgomfatceornicaelnstroartiinotneorfmtedhieatmeisx.tureoffluorochemicalsthatare unreacted or cUosnesuPamtetre.n: Indicates the major sector where the product is used; food, industrial, commercial, and iMnohsatlatLiiokne.lyMRaoruktseothfeEmxoposstulriek:elyIrdoeunttiefoiefsextphroeseuproetewnittihalarno"utXe"s.of exposure; ingestion, dermal, and `EwnavsitrewoanmteenrttarelaFtamteen:t,Idaenndtidfiireesctthleytmoowsattelrik.ely disposal route for the product; landfill, incineration, Comments: Provides additional descriptive information. 000277 ----- 275 Je bee E = E TieeeR Le l=]TT TL LT Lal Lx E--S Coe TPEr 000275 HS 0 =[= = == 000279 fF sess =FI E | dele NE t= TERTTT L 0=T =A E =~ EPP ey EI F x wens Distribution Chain This diagram reprethseepanthtthse 3M product takes from It represents an overviewofthe significant points where the the 3M time it leaves product may 3Mto its ultimate be handled an end use. dstiespt.riTbuhtiisonincfhoarimnarteipornesisenbtasstehdeotnyp3icMalinutseeronfatlhkenopwrloedducgte loiftneh;neomtaerkveetrpylparcoed.uct will go thdrouusgehd.eTachhis 000282 280 ---- Intermediates Distribution Chain Chemical Manufacturer Formulator of Coatings Fire Foams Carpet or Textile Finishes 000283 281 --- Points of Contact k`TwnhiotehwPltoehiedngatresooriffvatClohoneftma3acrMtkepdtripoaldgaurccaetmbadtaestteahidels3otnhMe3cpMuastttheotcmhhenrei.pcraTlohdsiuescrvtiitncafeko/rseamslaetwsiiotvnhisiwintastshaecnoddimgspetirliebudtfiornomch3aiMn istnatrteimnag the customer interactions. neral information from 000284 --- 282 Points of Contact Reactor Intermediates Receiving Dock Container Disposal Ship to Custome Reactor- residuals in product unknown Customer is a formulator that uses surfactants for end uses similar to 3M, including surface treatment like 000285 283 -- 3M Fluorochemical Exposure Information aiFrsrtbiocamlseetsdhteorePnaottiehndetswuoisftehCao3nndMtahfaclntufdollriooncwghcehomafir3cta,Mlsef.alcuThohrseotcefhpoelminlioctawhliesnc,gumisanttfoeomrreimaraltusisocenopnitrsaopicrneeissnsegnist3eiMds:olfaltueodr.ocAhlelmiicnaflosrmaantdion PointofContact: Describes individual steps in the use pattern. iMnohsaltatLiiokne.lyMRaoruktseothfeEmxopsotsulrieke:lyIrdoeunttieofifesextphroeseuproetewnittihalanro"uXt"e.s ofexposure; ingestion, dermal, and dEusrtiinmgatuesdedN.umber of Workers: Indicates the number ofworkers who may have potential for exposure Physical Form: exposure. Indicates the physical state (liquid, solid, aerosol, or vapor)ofthe product at time of Open or Closed System: COlpoesnedsyssytsetme:m:isisdedfeifniendedaassoonneethtahtata,lulnowdserwnoorkremrasl tcooncdoimtieoinnsd,idroeecstncootntaalcltowwiwtohr3keMrsfltuoocroocmheemiincal. direct contact with 3M fluorochemical. Comments: Provides additional descriptive information. fTlhuiosrioncfhoermmiactailopnriosdubcatsse.d Ionnf3orMmaitnitoenmawlaskncoowmlpeidlgeed fanrdombeasvtaielsatbilmeat3eMs osnouhrocewsciunsctloumdienrgs shaalneds,le 3M technical service, marketing and regulatory expertise. 0cezs6 LC 280 a-- |-- owes| er[beeonss nzts en porinnet [| 0[| on [Dermalinhai|a(pteriplaontn) |] [Aerosol] 1 Open [Closed| | Ll | - (feuresmeso e1 |tLT T n EE ] i TTT[1] | recon ates| fee [| poe Te Ta ee pboree[ m e| e] 11 FT -- ate sot t etsfhsoroT ssi, 7t7e1tt arrse 1 ] TT ens ensttnce a Product Volumes and Use Patterns Tpahtitsesm,umemxpaorsyurise baansdedenovnirionndimveindtuaall fpartoed.ucts. It is a descriptionofthe application, chemistry, use Product Code: Generic productdescription. `Aeapxpppplolisicucaartteii,oontnh,perPcrooocncceeessonstrsroaretnEidonnduosfUesf~el:uporrToohdceu:hcetpmseirccsaapnelc,bteitvhueesfuesdreofmpoarwtmhtoeircrnheaetnxhdpanothsoeunreenvwiarsonamsesnestsaeld.fatTeh`emaryouvtaeoryfwith eapplication. Generally the following definitions apply: Process: use Application: oursefolfufolroucohreomcihceamliccoanltcaoinntianignpirnogdpurcotdiuncatntoothtreeratpraodsuubcstt.rate. End Use: use oftreated substrate. (VMo-l1u0m0e0)FC Solids Sold in 1997: Pounds offluorochemical solids sold in 1997. * Chemistry: Generic description beginningofthis section. of fluorochemical ingredients. Full chemical names are listed at the AmountofFluorochemical Present: The fluorochemical concentratiionn process or end use. `%parRteisalildyuarlesac:teSdusmtarttotianlgomfactoenrcieanlstroartiinotneromftedhieat`emsi.xtureoffluorochemicals that are unreacted or UcosnesuPamtetre.rn: Indicates the major sector wherethe product is used; food, industrial, commercial, and iMnohsaltatLiiokn.elyMRaoruktsetohfeEmxopsotsulrieke:lyIrdoeunttiefoifeesxtphorseeur`peotweinttihalanro"utXe.sofexposure; ingestion, dermal, and Environmental Fate: Identifies the most likely `Waste water treatment, and directly to water. disposal route for the product; landfill, incineration, `Comments: Provides additional descriptive information. .. 000288 286 ams PR CT TTR fs TT =1 eT F En E <=SE NN PO 8 I =A =1-3 Cea tloe 1 FE eEeELL e T]Ee TT] 3C TTL r e Distribution Chain TdIhtisirtesrpdiribeuastgeirnotansmcahrnaeiopnrvereserepvnriteessewtonhftetsphathteehsttiyhgpeniicf3ailMcaunspteroopfdotiunchttestwapkhreoesdruefcrttohlmeitn3he;Metnipormtoeedvuiectrtlyemapavreyosdbu3ecMthwatinoldliltegsudoltatinhmrdaoutusegeehdn.cdaTcuhhsies. step. This information is based on 3M internal knowledgeofthe marketplace. 000292 290 uuu Coating Additives Distribution Chain RR OEM Assembler for Various Uses . 000293 201 --- Coatings Distribution Chain Households tine Coma Commercial Buildings 000294 CJ 292 Points of Contact kvTnihtoehwPltoehiedngatresooriffvatlChooenftm3aacMrtkepdtripoaldgaurccaetmbadtaestteahidels3ontMh3ecMpuastttehocmthehnrei.cparTlohdsieusrcvtiinctfeao/krseamslaetwsiiotvnhisiwintastshecodimsptirliebudtfiornocmh3aiMnstianrtterinneg) the customer interactions. and general information fom * _~ 000295 _ 293 Points of Contact Coating Additives and Inks Receiving Dock Container Disposal | :| Shipping - 000296 P --- Points of Contact Finisher/End Use - Coating Additives and Inks Receiving Dock Application -Dip Spray Electrostatic Roll Transfer `Spread or brush Others uv Heat Air Dry Inherent Catalyst E-Beam Factory/commercially applied Coated material 000297 295 See tw -_-- Points of Contact Powder Additive Formulator Receiving Dock Filling -- Surgical Customer Medical Waste |Application and| Curing of Coating Ship Industrial Grade Thickener to 2nd Formulator 000298 296 ab Points of Contact Powder Additive - 2nd Formulator [oc] Staging Area Weighing : End Use Non-Personal Care Products 07 000299 a Points of Contact Coating QC Co Appliance Sipping Spot 000360 . 298 LJ Points of Contact Coating Application Application wo 000301 =) 3M Fluorochemical Exposure Information From the Pointsof Contact flow chart, each step in the customer use process is isolated. All information is based on the use and handlingof 3M fluorochemicals, materials containing 3M fluorochemicals and articles treated with 3M fluorochemicals. The following information is presented: Pointof Contact: Describes individual steps intheusepattern. iMnohsaltatLiiokne.lyMRaoruktsetohfeExmpoosstulrieke:lyIrdoeunttieofifesextphroeseuproetewnittihalanro"uXte"s.ofexposure; ingestion, dermal, and Estimated during use Number d. of Wo rkers: Indicatesthe number of workers who `may have potential for exposure ePxhpyossiucrael.Form: Indicates the physical state (liquid, solid, `aerosol, or vapor)ofthe product at time of Open or Closed System: Open system: is defined as one that allowsworkersto come in direct contact `with 3M fluorochemical. Closed system: is defined as one that, under normal conditions, does not allow workertso come in direct contact with 3M fluorochemical. Comments: Provides additional descriptive information. f`Tlhuiosrioncfhoermmiactailopnroisdbuactsse.d oInnf3orMmaitnitoenrnwalaskncoowmlpeidlgeed fanrdobmeasvtaeilsabtlei3mMoasntohuerocswesciunsctloumdeinrgs shaalneds,le 3M technical service, marketing and regulatory expertise. 300 000302 EEN see mt cos sn ass - S for s pose | Tol aTo Fomor bbhbbe Beoee eomemT T|TTTT Te ToSa||e TwiT eT [ T a e we e a e e [T T T E aT T T T T T TEo] = T p Teeme eaee fomwuiaror { {oer1 mal_[ihalton[TpF orpiand| T [Ligud SoT ta[AeroT sol JvaT ger[oT penJoX lessaT | ovr] ea] Ee TT Tr rT hess ||e| [wo | ow [| [| [a femme | (SN hese PPP NP |[ol[oo| we I [W[[| | PY | Oy fmm | beMEe m|T|T [To T lw e ]| & I PEIYIS ov0zes I sone torpmotessyn ffem, hema | bee |LT boo | Lo| bowery[| [0| Tw Wl Tlle] [on[Wl[|] bees | | | SII I ee | I i -- be ee |Ce eo ] 1 we| Jed[ --Tans----] bo | ol TT ee|od TT| Jom] I. ep mtn poismn EB= ERoLeE Er been | Lo LT poe[Lo hon [Lo IaTfI ny fe ee een[a TT SR HE EE ]f]o FF rrr rrr eeTe Toe = e - T -- 1 Tr SS A HE E -- -- --. ee LL ToT bype of Ex prey Diss hy LT o [7 | bC eeeeS en ILI T IT ER T [F 7 T 1] Es ee fonegg HT Bast--enTT ee LTFT TT 7 [x 7 I-- 1 I I 1 1i4 . psestenn| | Exponus oormaton__ cont fHo veetr on fist, i ee fE oe reo e Ei ferp w e bbe ee pe e e po LE foe ee be TT TP 000307 Product Volumes and Use Patterns pTahtitsesm,umemxaporsyurisebaansdedenovnirionndmievindtuaallfpartoe.ducts. Itis a description oftheapplication, chemistry, use Product Code: Generic product description. aEAppxppplloiisccuaartteii,oonnt,hperPocrcooencscesesnostorrreatnEidnonduosfeUs~fel:puroTordhoucechtpeesmricscapanelc,bteithvueesufesdreofmpoarwtmhteoirrcnehatenhxdpatonhseouenrneevwaiaprpsolincamasetsnieotsnas.eldf.atTehmearyouvtaeryofwith PGreonceersasl:lyutsheeofrofllluoowirnogchdeemfiicnailticoonnstaapipnliyn:g product in another product. EApnpdliUcsaet:ionu:seousfetorfefaltueodrsoucbhstermaitce.al containing product to treat a substrate (VMo-l1u0m0e0)FC Solids Sold in 1997: Pounds of fluorochemical solids sold in 1997. bCheegmiinsntirnygo:ftGheinsersiecctdieosnc.riptionoffluorochemical ingredients. Full chemical names are listed at the AmountofFluorochemical Present: The fluorochemical concentration in process or end use. `%parRteisailldyuarlesa:cteSdusmtarttotianlgofmactoenrcieanltsroartiinotneorfmtedhieatmeisx.tureof fluorochemicalsthatare unreacted or Use Patter: consumer. Indicates the major sector where the product is used; food, industrial, commercial, and Most Likely Routeof inhalation. Marks the Emxopsotsulrikee;lyIrdoeuntteifoifeesxtphoreseuproetewnittihalanro"uXte"s.ofexposure; ingestion, dermal, and `EwnavsitreownatmeernttraelaFtameen:t,Idaenndtidfiireesctthley most likely to water. disposal route for the product; landfill, incineration, Comments: Provides additional descriptive information. 306 000308 LT Ceo ToeTT -- EE [=] 5 z5 g ETE - rst vt spats eed | | ghee ppp pee 22 2 LLTTT kee EE 22 2 ] | 1] =afr] e = H z 5 ] : I =A LTTTT ee EE= = SeER |== acti LLLLILTTLLLT Distribution Chain `This diagram representsthe path the 3M product takesfromthetime it leaves 3M to its ultimate end use. It represents an overviewofthe distribution chain represents the significant typical use points ofthe where the 3M product may behandledand used. This product line; not every product willgothrough each step. This information is based on 3M internal knowledgeofthe marketplace. ny 000315 -_--_-- Carpet Spot Cleaner Distribution Chain ow 000318 qu Product Volumes and Use Patterns "pTahtistsemu,memxaprosyurisebaansdedenovnirionndmiveindtuaallfpartoed.ucts. It is a description ofthe application, chemistry, use Product Code: Generic product description. aeApxpppplolisicucaartteii,otonnh,perPcoroconeccseessnsotrroaretnEidonundsoeUfsf--elp:uroorTdohucechetpmseirccsaapnle,cbtetihvueesuefsdreofmpoarwtmtheoirrcnehatenhxdapnothsoeunreeenavwpiaprlsoincamasetsineostnsa.eldf.atTehmeayrouvtaeroyfwith PGreonceersasl:lyutsheeofrofllluoowrioncghdeemfiicnailticoonnstaapipnliyn:g product in another product. AEpnpdliUcsaet:ionu:seoufsteorefaftleudosruobcshtermatiec.al containing product to treat a substrate. Volume FC (M-1000) Solids Sold in 1997: Poundsoffluorochemical solids sold in 1997. bCehgeimninsitnrgyo:ftGheinsersiecctdieosnc.riptionoffluorochemical ingredients. Full chemical names are listedatthe Amount of Fluorochemical Present: The fluorochemical concentration in process or end use. p%artRieaslildyuralesa:cteSdusmtarttotianlgomfactoenrcieanltsroartiinotneorfmtehdieatmeisx.tureoffluorochemicals that are unreacted or cUosnesuPmaettre.rn: Indicates the major sector wherethe product is used; food, industrial, commercial, and iMnohsaltatLiiokn.elyMRaoruktseothfeEmxopsotsulrieke:lyIrdoenuttiefoifeesxtphoreseuproetewnittihalarno*utXe"s.ofexposure; ingestion, dermal, and Environmental Fate: Identifies the waste water treatment, and directly most likely to water. disposal route for the product; landfill, incineration, Comments: Provides additional descriptive information. 000317 31s Distribution Chain `ITthrisepdrieasgenrtasmarneporveesernvtisetwohfetphaetshitghneif3icMapnrtopdouicnttstawkheesfrerothmeth3eMtpirmoediutctlmeaavyes b3eMhtaonidtlseudlatnimdautseeedn,duTsheie. sdtiespt.ribTuhtiisonincfhoarimnarteiporneissenbtassethdeotnyp3icMaliuntseeornfatlhkenopwrloedudcgteolfinte;henmoatrekveetrpylapcreod.uct will go through each So 000319 37 CEEEED Insecticide Distribution Chain ---- H I 000320 318 -_-- Pointsof Contact kwTnihtoehwPltoehiedngatersroiofvftalhCoeonftma3acrMtkdepitrapogldrauaccmetbadtaestteahidelso3ntMh3ecMtupeasctthhomnteihrec.aplrTohsdieusrcvtiinctfeao/ksreamslawetisitovhinsiiwntastshaecnoddmigspetirnlieebrudatlfiorinnocmh3aiMn istnatretrimneg the customer interactions. formation from k . 000321 319 Points of Contact Insecticides Receiving Dock -- Mixing Tank : Filling PBaacitkiTnrgap [Rell] HHo,u0sebhaosledds Industrial Use Household Oil Base 000322 320 > . a 3M Fluorochemical Exposure Information aiFsrrtbioacmlseetsdhteorenPaottiehndetswuoistfehCao3nndMtahfcalntudoflrliooncwghoecfmh3iacrMta,lsef.alcuThohrsoetcefhpeomliilncotawhliesnc,gumisanttfoeomrreimaraltusisocenonpitrsaopicrneeissnsegnits3eiMds:oflaltueodr.ocAhlelmiicnaflosrmaantdion PointofContact: Describes individual steps in the use pattern. iMnohsaltatLiiokn.elyMRaoruktseothfeEmxopsotsulrieke:lyIrdoeuntiefoifesetxhproeseuproetewnittihalarno"utXe"sofexposure; ingestion, dermal, and dEusrtiinmgatuesdedN.umberof Workers: Indicates the number ofworkers who may have potential for exposure Physical Form: exposure. Indicates the physical state (liquid, sold, aerosol, or vapor) oftheproduct at ime of Open or Closed System: "CdlOiopreescnetdscyossnyttseatmce:tmi:wistidshed3feiMfnienfdelduaosarsoocnoheneemtihtachtaalta,.lulnowdsewronrokremrasltcooncdoimtieonisnd,idroeecstcnoonttaalcltowwiwtohr3keMrsfltuoocroocmheemiincal, Comments: Provides additional descriptive information. AThuiosroicnhfeomrmiactailonpriosdubcatsse.d oInnf3orMmaitnitoenrnwalaskncoowmlpeidlgeed afnrdombeasvtaielsatbilmeat3eMs osnouhrocewsciunsctloumdeinrgs shaalneds,le 3M technical service, marketing and regulatory expertise. --- 2 000323 Ed ee LT To TTThee] A pFtornbgi,d] . te imer) c. m [fori | berm onataen | (po paonsf iowa]Soa [aerosol Jvapor[open [cio | | fe eT uw TeTw eeeperteen ed a [| fa;ee] hemeT CT I LT TT fae] 9 rhe LL TET mC ee lo 1 Loe ee [oT poe TT ooTIT Ti TTT] Mongton pE e eT e pm TT er Tw ee I Tx Te Efee TT Toor TL TTff=m ] oousae Exposure Inform-aIntsecitiocidnes LLEmoE EE coos I [Dermal[ihatation| (porplant)0 | riquia]soll[Aerosol vapor|[Openlc| iowea| F IE o aThrT P = ep Eee TTTT T TT TT o e T Th e Tr] Ee], ttrr je Product Volumes and Use Patterns `This summary is based on individual products. pattern, exposure and environmental fate, It is a description ofth application, chemist, use Product Code: Generic product description. eaApxpppplolisicucaratetii,oontnh,perPocrcooencscesesnsotrroaretnEidnonudosfUes~ef:uporrToohdcuehceptnsericscapanelc,bteithvueesuefsdreofmporawtmhtoiecrrheaetnxhdapntohsoeunreeenavwpiaprlsoincamasetsineotsnsa.eld.fatTehmearyouvtaeroyfwith PGreonceersasl:lyutsheeofrofllluoowrioncghdeemfiicnaitlicoonsntaapipnliyn:g product in anotherproduct Application: useoffluorochemical containing product to treat a substrate. End Use: useoftreated substrate. Volume FC Solids Sold in 1997: Poundsoffluorochemical solids sold in 1997. (M-1000) bCehgeimninsitnrgyo:ftGheinsersiecctdieosnc.ription offluorochemical ingredients. Full chemical names are listed at the `Amount of Fluorochemical Present: The fluorochemical concentration in process or end use. `%parRteisalildyuraelasc:teSdusmtartottianlg omfactoenrciaelnstroartiinotneorfmtedhieatmeisx.tureoffluorochemicals that are `unreacted or UcosnesuPamtetre.rn: Indicates the major sector where the `product is used; food, industrial, commercial, and Most Likely Route of Exposure: Identifies three potential routesofexposure; ingestion, dermal, and inhalation. Marks the most likely routeof exposure with an "X". Environmental Fate: Identifies the most likely disposal route for the product; landfill, incineration, wastewater treatment, and directly to water. Comments: Provides additional descriptive information. " Ee 000326 -_---- res TTTTHere [Ee oepare Lea feel spessren a==[= omP= 31 TTT CLL 8 ] Paper and Packaging Business Fluorochemical Use, Distribution and Release Overview Fo 2m 000329 --- 527 Foreword e Tssporte i compreotog 30 Barentsa prod actingss. WSS naepesofeo uetcomlers set oTMMbstorhcthepsbrssocmola ssdgool.l Maresseet dseHige y Get vingmitie SIotuorrcmeaston fo is ep vs deplly Gr ra sc. To ci B BdEeaf Frcoonns tiee(swhPeorpS olaey StPser] HowTo Bend hiscs SotiunoAnaaits onssdrs Dotson CaiondFonsofCnt: pErosof Follows the omc Ae Borne Bom path oaf 3M fluorochemical throughout the os op distribution chain to final end user. to `Objective is to identify AepoSnaEeImQtUo,iSpCeukrrfspsssmb fwercps rochewii ` 3 259 2 --- 000350 1. Chemical Names `Table of Contents IL AS.ituBautsiionnesAsnaDleyfsiinsition B. C. MParordkuecttDPeofritnfiotliioon D. E. FCluusotroomcheermDiecfailniatpipolnication Methods F. G. U.S. PaperMill Global Product Locations Volumes (1997) IIL EAx.poSsuupprleyICnhfaoirnmaFtlioownChart BC.. D. PTrootcee/sDsrFulmoRwecChoavretry Cycle Flow Chart Product Volumes and Use Patterns E. 3M Fluorochemical Exposure Information 000331 m9 CE 29 Chemical Names The `The following following isnfaolrimsaotfioCnheismpirceaslenAtbeds:tract Services (CAS) names and numbers for individual products, `Generic Code: Indicates an internal 3M designationofthe product(s). `CAS each Number: product. Indicates the Chemical Abstracts Services number(s) offluorochemicals contained within CChheemmiiccaall NAbasmtreac(tcsomSeprlveitceeCs AnaSmen(asm)eoforfIluUoPrAocChenmaimcealsisfcoCnAtaSinneadmweitdhoienscnaocthepxriosdt)u:ctI.ndicates the Chemical Class: Indicates a shortened, generic chemical name. 000332 330 ----- ome ] [S Ee]onr he e m,[roowe] | He| pr ILE e-1,pra| 070% Aphosloipn,hdiaommonnumsoat ra oe E e E SEe T R er | = Situation Analysis Paper and Packaging Business TianghdeeunstPtsrCiyPmcpPaatareptgeogrrriaeeasn:sdet,Phaoeiclk,PaaagncidknagwgaBitunesgrinIrneedssuisssttUarnnyictaepntrdootvhpeiadpeePsrapfaelnrudoIrpnoadcpuhesertmbyi.ocaarTldhsseiuzbfislntugroaartgeoescn,htewsmhitioccathlwsoizbirnogad used for a numberofend use applications that include: are + + FBloeaxridblmeaodrelifgrhotmweriegchytclpeadpefrisbeprriumsaerdilfyorffoorlbdaignsg,cwarrtaopnss.and micro flute containers. * * MSoolliddebdlepauclhpepdrbodouacrtdsffoorrfpolladtiensgacnardtofnoso.d containers. * cFoonrvmeurltaitnogrsintdhuasttrbyl.end FC'swithotheragents, such as varnishes and lacquers,andsell to the * Business and specialty papers for carbonless forms and masking papers. Product Portfolio The `and nporno-dfuoctodpocrotnftoalcito includes products. products regulated for direct food contact (under CFR 176.170) Food PPI Contact Products (Regulated for direct food contact) Grease and oil repellent Ammonium bis(N-ethyl-2-perfluoroalkylsulfonamido ethyl) phosphates PP2 Grease,PXeo0rif-ll2au-onprrdooawplaektnyeylrl)arc-eropyxelolal}te-en,tccohploorliydmee;ro2-fpreotpheannoaimcianciiudm,,2Nm,eNthNy-lt-r,iomextihryaln-y2m-e[t(h2-ymletehstyelr-;1-2- pocrtoypDesnuolifconayclid],m2e-tehtyhloxaymeitnhoy]l eesttheyrl; easntder.2-propenoic acid, 2[[(heptadecafluoro- PNoPn3-Food Contact Product `Water and solvent repellent ePdsieteresfrtl.euro;raonaldk2yl-parcorpyelnaoteiccoacpiodl,y2m[e[r(hoefp2t-apdreocapfelnuooirco-acoicdt,yl2)smuelftohnyyll] pmoeltyhoyxlyeatmhiynloe]neet(h3y3l50) fe 33; 000334 - Market Definition T~hLeiPgahtpweeriagnhdt Ppaapcekrasging business unit defines it markets by the following segments: ~~BRleecaycchleedd ppaappeerrbbooaarrdd ((SCBCSN)) ~~ UFonrbmluelaacthoerdsp(aCpoeartibnogasr)d (SUS) ~ BMuoslidneedssppualppe(rpsap(ecrarpbloantleess)s forms) Fluorochemicals are sold into eachofthese market segments. Customer Definition TfohremuPlaapteorrsa.nd`TPhaecdkeafginiintgiosnaolfesecahcahnnceulstionmcleurdweistphaipnetrhemiclhlasnceolnviesr:ters, end users, and A. `Pmaapneurfamcitlurlis--ngupsreofcleusosr.ochemicals o treat paper fibers during the paper or paperboard B. Ccaorntvoenrst,eertsc,--, fcoornvdeesritrleudoernodchuesmeically treated paper and/or paperboard into wraps, bags, C. Epanpdeurseorrspa--cskpaegceifryeoqruiurseemfenltuso.rochemicallytreatedpaperorpaperboardforuseintheir 1D. `Fmoarrmkueltactooartsin--gbsltehnadt cfalunobreocahpepmliiceadltsowpiatpheortahnerdapgaepnetsr,bosaurcdhdausrivnargntihsehecsonavnedrtliancgquperrosc,esasn,d Fluorochemical Application Methods PFrloucoersoschoremciocnavlesrtcianngboepearpaptliioend,tuopsianpgedriaffnedrepnatpaeprpbloicaartdiosnubmsettrahtoedss:during the manufacturing PT~ahpWeeeratpMpielnlidclaotfitohneppoainptesrfmoarcthhienfeluorochemical at the paper mill can include: ~~ SCiazleenpdreerssstack ~Clay coating Fluorochemical can be applied using various typesofcoating or printing equipment. AduusprepidrnobgxyithUmeaStpeaplapypeer9rm5am%kiliolnfstghipseraopfcplelusiosaerdovctihhaeemtiphcaeaplsesirzumesipelrdleisnsItthse epsatpiemrataendd tphaactk7a3gi%nogftinhdeusftlruyo,raorechaepmpilciaeld 2129 --- 333 00033$5 000336 33 --- Global Product Volumes uPTsahepede.rtaaVbnloedlouPnmacetkhieangffioonlrglmoabwtuiisnoignnepissasgc(eoimnppri1ol9ve9i7dd)eusasntihdnegtgh1le9oe9bs7atlaivnmnoaultaeuldmebsohrifepam3keMdnotfwslnaubonrydoac3ph0pelmisicacalatelisosnopldroicnctshse personnel best estimatesofapplication methods. and sechgical TTuhoerporcohdeumcctivaolluusmaegseiare reported reported by in Mapp(l0ic0a'tsi)onpmoeutnhdosdo,fpprroodduuccttfsaomliildsy,, and geographic region. ApSplP--icsiazteiporneMsestohnodthe paper machine CCCS ----cclaalyencdoeartsitnagcakpopnlitehdedpuarpienrgmpaacpehrinmeaking process WE FM -- -- wetendofthe formulator paper machine OM - off-machine coating operations Product Family The complete under Product chemical description Portfolio. foreach ofthese products i ised inthe Situation Analysis PP-1 PP-2 GGrreeaassee,aonildaonildrweapteelrlreen~tpeFClla-leiFnphCtaticcopaomlmymoenri.um salt. PP-3 Waterand solvent repell~eFnCt copolymer for business papers. GUenoigtreadpShtiacteRsegion Europe Canada Latin America Asia Pacific (APAC) 21299 000337 335 000333 336 --- Exposure Assessment Paper and Packaging Business exposure. The Exposure information throughout the distribution in Paper and Packaging follows the path chain from product shipment from a 3M ofa 3M fluorochemical tdhiespdoissatlroibfutthioenFcChatirneaatnedd ipdaepnetirfioersp`appoeternbtoiaalrds.ouTrchees"oOfveernavlilroFnlmoewntCa`hlmaarontru"fian`cdpturusotrvriiidnaeglshlyaogcpaiitecitnouenretoof Potential sources ofexposure to the product in concentrated or "Tote/Drum RecoveryCycle"and "Supply Chain Flow Chart" diluted form diagrams. is identifiedin Process Flow Chart" provides additional information in regards to The "Paper Mill potential chemical exposure to `workers in the paper mill. Tkinnhtoeewgirlanelfdotgroemotahtfiispordnoecdvoeunlctotapi`mnheaenndtd.ilnintghiasnsdeuctsieopnrwacatsicdeesvferloopmetdecshonlieclaylfarnodm fiinetledrnsaalle3s Mpesrosuorncneesl. wTahse 21299 ay 000339 cum. Paanp dPace kagr ing SupolyChainFlowChart Te Laees - [=] C=] EH == =e 1 hss == HE TE t= e = th`Tehmeislul,ppulsyeichnatihneflmoiwllcphraorcteisllsusttormataeks etfhleufolruoocrhoecmhiecmailctarleaptreoddupcatpdeliveryto cPaopnevrebrotaerddr,olflosallroewsehdipbpyecdontvoeart"icnognvteorateurs"etfhualtroplrlosdiuzce.esAadudsiteifounlaplaelrcyo,kratgheemill construction end user for (eg. multi-wall bags). The converter filloriunseg. Thefilled bags are s ships empty packages to the (eg. stores) to be sold to consumers. hipped to pointsofdistribution raDeiurc,ryciwlnaetg)te,hrai,tsstcphrreaopceepnsadspu,esrte,hrepp(reoogtd.eunsctctiraaclpof)no,traacrnte)dl,eaatatsttehheoercccooonnnvteartcetro.c(ceugr.ssactrtahpefmoirll (eg. contact). sumer (eg, waste,product k``wTnihloelwsgluoepdptglheyrcoohufagtihhneemaarcrehkpersettseppel.natcTsehti.hse itnypfiocramlatuisoeniofsthbaesperdoodunct3,Mnoitnetevrenrayl product (Full page "SupplyChain Flow Chart" follows on the next page). ------- 000340 oe 338 Paper and Packaging Supply ChainFlow Chart --- --_-- ep rg - TGo r as r ms p[nAFreve [om]E= e == fo | = [lois | Se HE] | a L prom be orgdti| ae 7wl fa Waste ar [er 4 [ro] `EisicandPackaging ---- S ' E]LL 4 =p == == :| I =een sntTeooartreesdtohiefnmdlaeuksoiergdonocawhtneedmaiarcreaealasfp.orrFopdouurmcutpsiaenriginvtetoareaatttaihnnegkp.paIappneersrwmoiemlbelscr,aeseceeasic,vhditinogrtdeiocskmoanvdedare stotyfpatirhcceahlwflalytuaeoprrpolscoihleeudmtiiinocnaa.l0tA.of5tateosri1zteh%ep(rpfealspuseororpowecrhaetmiiocnalocwc/urw.) Tcohnecefnlturoartoicoehncetminipeauamlpjisng trvainasnpuomretredoutso satceoanmvheertaitnegdldirnyee,rwchaenrseatnhedebpcoailrsletenrctetarteeededol,intshsaelrwietaetld.eorTwihnseterova3peorisactteh]den converting size roll for shipment to the converter. iFpsuotlrhpewsepltruoarcyedspsraoipfoprlritecotaatfiionornimsni,gntfghieb(eefrilstuhaeonrrdomcodhrleadmieincdianplguplwrpaotoderurcpttaopifseordrimrmaeccahtliuysnep)u.mpFeodrmtiontghe eb. Followitnheg forming the manufacturing process includeasbplreesarstiincgleaonrd cdornyviengr,tisnigmiolpaerrattotihona.tdescribed above. Molded articles do not have `This how ciunsftoormmeatrisohnainsdblaesfelduoorno3chMemiinctaelrnparlokduncotwsl.edge and best estimates on (Full page "Paper Mill Process Flow Chart" follows on the next page). 300 000342 -_---- Paper and Packaging Paper Mill Process Flow Chart nn J Po } +mAmm i ET EE | rHE5EeEe pe = CalenderStack Mold lp H| feaE7t - Later 0) me = 313 -r ) Hi tee ToPtea Daenup dmPRaee cckoavgr eirnygCoceFlowChart tIhnethTeutoortoec/hdermuimcraelcporvoedruycctycilsues,teodtienstohrednroutmesdaprapdeirsmtirlibluptreodcetsost.heAmfitlerltwhhsere specronoutdludtocctoahnactoasnibtnereaancntvicneocnnhdosofurmrfeeosdriicdnluteeahnaeispnrlgoe.cfteToshvsee,rbtphoretotdtouotcmetoo.frTtdhhreeuemtmoitpsetsroyetrtoudtrrenuoemdrtsdtorh3aaMtmaorre cleanedatthecontract vendor arereturnedtothe 3M forreuse. (Full page "Tote/Drum Recovery Cycle Flow Chart" follows on the next page). 000344 342 Paper andPackaging Tote/Drum Recovery Cycle Flow Chart | I hE--ut soa g -- eeERe -- rpee po 0030s Product Volumes and Use Patterns o`fTthehPeroadpuplcitcaVtioolnu, mceheaminsdtrUys,euPsaettpeartntserins,beaxspeodsuorneainnddievnidvuiarlopnrmoednucttasl. faIttei.s adescription Product Code: Generic productdescription. Application, ProcessorEnd Use:`Theperspective from which exposure was assessed. `eTnhveirroountmeenotfaelxfpaotseumrea,ythvearcyonwcietnhtraaptpiloinc.oatfifolnuporrooccehsesmiocraeln,dthueseus--e`ppartotduecrtnsacnadntbhee used for more than Generally the one application. following definitions apply: Process: use offluorochemical containing product in anotherproduct. Application: use offluorochemical containing product to treat a substrate End Use:use oftreated substrate (VMo=l1u0m0e0F)C SolidsSoldin 1997: Pounds offluorochemical solids sold in 1997. Chemistry: listedatthe bGeneergicidoensfctrnhiipstisieocnnotifogfn.luorochemical ingredients. Full chemicalnamesare % Residuals: Sum totalof concentration.ofthemixture offluorochemicals unreacted or partially reacted starting materials or intermediates. that are UcosmemePartctiearln,: Iannddiccaotnessumteherm.ajorsectors where product is used; food, industrial, Route ofExposure: Identifies three potential routesofexposure; ingestion, inhalation. Marks the most likely route of exposure with an "X". dermal, and Environmental Fate: Identifies the most incineration, waste water treatment, and likely disposal route directly to water. for the product; landfill, Comments: Provides additional descriptive information. `This information customers handle is based on 3M internal knowledge and best estimates on 3M fluorochemical products. Information was compile how 3M sources including sales, technical service, marketingand regulatory d from available expertise. : 000346 ` CEE 24 HH HEE AEdE I fe =TA T I == ITT) IF I=E I I Leff oT LJC e fY eT l T I P r Y = Ie ef =eIT J = 5E HY EE = = mL td blr LITT = TL Celene [os TLL Te 3M Fluorochemical Exposure Information FrPooimnttohfeCoSnutpapcltycChharati.nfAllowicnhfaorrtm,ateiaocnhisstbeapsiendthoenctuhsetuosmeeranudsehapnrdolciensgsoifs 3isMolated in the fflluuoorroocchheemmiiccaallss., mTahteerifaollslocwoinntgaiinnifnogrm3aMtiofnluiosrporcehseemnitceadl:s and articles treated with 3M PointofContact: Describes individual steps in the use pattern. iTnyhpaleaotifEoxn.poMsaurrkes: tIhdeenmtoifsiteslitkherleyerpooutteenotfiealxprooustuerseofwietxhpoasnur"eX;".ingestion, dermal, and fEosrtiemxaptoesdurNeudmubreinrog fusWeodr.kers: Indicates the numberofworkers who may have potential Estimated Exposure exposed during use. Time: Indicates the amountof time that workers potentially may be . Physical Form: Indicates attimeofexposure. the physical state (liquid, solid, aerosol, or vapor)ofthe product Open `Open or Closed System: system: isdefinedas one that allows workers to come in direct contact with 3M fluorochemical. Closed system: come in direct ciosntdacetfwiitahns3oeMndefltuhaotr,oucnhdemeircanlo.rmal conditions, does not allow workers to Comments: Provides additional descriptive information. cThuisstoimnefrosrmhaatnidolnei3s Mbasfleudoornoc3heMmiicnatlerpnraoldkunctosw.leIdngfeoramnadtbieosntwesatsimcaotmepsiloend hforowm available 3M sources including sales, technical service, marketing and regulatory expertise. 000343 . EY - PooifConntatct Cha-rMitl [ir . Fema [--emtmen PE EP I ed | fe) oE e t | Fe Fees ce To 1 ee | o= e TT ee P e ea e Ft e F froe me | reese TwT e e T e fpe Fem] ee - 000348