Document 09jp8vKz7bg51OM9dBzzbmgx

BULLETIN NO. IC/FF-38R (Revised March, 1975) Inspection & Maintenance Guide Monsanto TOWOLDMONOQ34774 SECTION A TRANSFORMER ASKARELS..........................................1 I. Introduction......................................................... 1 II. History of Trade Name Types............................. 1 Table I - The Composition of Transformer Askarels ............... .2 III. Interchangeability ...............................................2 IV. Tabled - Official Transformer Askarel Shipping Specifications.......................................3 V. Ordering Instructions ......................................... 2 VI. Stability................................................................ 2 VII. Precautions When Handling Drums, Tank Cars and When Opening Transformers........................2 A. Keep Dry During Handling .......................... 2 Table III -- Handling and Pumping Temperatures..................................4 B. Use Ordinary Personal Precautions ............. 4 C. Precautions on Opening an Askarel Transformer....................................... 5 VIII. Avoid Environmental Pollution.......................... 5 1. Labeling Askarel Transformers..................... 6 2. Disposal of Liquid and Solid Wastes ...........6 3. Conditioning of New or Recycled Askarel .6 4. Teardown of Transformers for Repair or Scrap .......................................7 6. Transformer Disposal.....................................7 IX. Expected Service Life..........................................7 X. General Characteristics of Transformer Askarel Fluid.........................................................7 XI. Sampling Transformer Askarel Fluid ................ 8 XII. Evaluation of Askaret R eceived in New Equipment.............................................. 8 XIII. Dielectric Breakdown Voltage - Moisture Relationship......................................... 9 Table IV - Relation of Dielectric Breakdown Voltage to Amount of Dissolved Water in Askarel and Mineral Oil.......................................9 Table V - Approximate Solubility of Water in Transformer Askarel and Mineral Oil .... 10 XIV. Turbidity ............................................................10 XV. Check Points for Maintaining Askaret I nsutation .............................................10 A. General Considerations................................ 10 B. Modern Sealing Procedures ........................11 C. The Older Sealing Arrangements.................12 XVI. Periodic Fluid Inspection and What Checkpoints Mean ...................................12 A. Visual Inspection.......................................... 13 B. Dielectric Breakdown Voltage ................... 13 XVII. Inspection Checklist.......................................... 13 XVIII. Contamination in Transformers......................... 14 Table VI - Eilect of Common Insulation Materials on Power Factor and Dielectric Strength.............................................14 Table VII - Effect of Common Insulation Materials on Volume Resistivity of Askarel............................................................14 XIX. ASTM Method for Investigatingthe Compatibility of Transformer Insulation and Construction Materials in Askarels............15 XX. Refining Askarel for Re-Use............................. 15 A. Filtering Through Dry Blotter Paper to Remove Moisture and Extraneous Particles..................................... 15 XXI. XXII. Table VIII - Water Removal by Filtering Askarel Through a Paper Press ............... B. Disposal of Solid Wastes.................... C. Solid Insulation Requiring Drying . . D. Earth Treatment for Maximum Improvement of Power Factor and Volume Resistivity ......................... Table IX - Effect of Power Factor end Volume Resistivity............. Cleaning Arced Transformers............... Sampling Askarel.................................... 15 16 16 17 17 17 SECTION B ASKAREL FILLED SWITCHES AND TERMINAL CHAMBERS ................................... 19 I. Introduction...................................................... 19 II. Sources of Contamination ............................... 19 III. Seating Switches and Terminal Chambers ...20 IV. Askarel Used Under Mild Arcing Conditions . 20 V. Maintenance for Askarel Filled Switches .... 20 VI. Askarel Under Excessive Temperature or Fault Conditions ......................................... 21 SECTION C TOXICITY AND SAFE HANDLING............................. 21 I. Inhalation..........................................................21 II. Skin Contact.....................................................21 SECTION D ANALYTICAL SERVICES ON TRANSFORMER ASKAREL AVAILABLE FROM MONSANTO ............................... 22 Types of Analyses Available: ......................................... 22 1) Routine Maintenance Check.................................... 22 2) Complete Analysis................................................... 2^ 3) Analysis After Earth Refinement .......................... 2^ SECTION E APPENDICES................................................................... 23 Appendix A -- Askarel Stability and Composition of Arc Formed Gas..................................23 Appendix B - Solubility of Gas in Transformer Askarels ................................................... 23 Appendix C -- Effect of Temperature on Dielectric Breakdown Voltage of Askarel ...................23 Appendix D - Comparison of the Approximate Viscosity in Saybolt Universal Seconds of Transformer Askarels and Mineral Oil.......................... 24 Appendix E - The Density of Inerteen 54201 KA 7336-9 and Transformer Pyranol A13B3B-3........................................................ 24 Appendix F - Thermal Conductivity Values of Transformer Pyranol A13B3B-3............................... 24 Appendix G - Heat Capacity......................................... 24 Appendix H - Coefficient of Expansion........................24 Appendix I -- Fire Resistance......................................... 24 Appendix J -- Seals, Properties and Procurement ........................................................... 25 Appendix K - Caution Label......................................... 25 I NOTICE: "Nothing contained herein is to be construed as a recommendation to use any product in conflict with any patent. MONSANTO MAKES NO WARRANTIES AS TO THE FITNESS FOR A PARTICULAR PURPOSE OR MERCHANTABILITY OF ANY PRODUCT REFERRED 3TO, no guarantee of satisfactory results from reliance upj^ on contained information or recommendations, and dis claims all liability for any resulting loss or damage. 0t>04<i43 TOWOLDMONOQ34775 : ' - .'1 , * ' f M- .. -A - ".. ....................................................................ky^4r,!-'.- V' Transformer Askarel I. Introduction . The term "askarel" as defined by IEEE, ASTM and the National Electrical Code generally describes a broad class of fire-resistant* synthetic chlorinated hydrocarbon insulating liquids widely used in transformers, reactors and accessory equipment operated at power frequencies. Askarels of various compositional types are in use. (For the general properties and types see ASTM D-2283.) Under arcing conditions the gases produced, while consisting of predominantly non-combustible hydrogen chloride, can contain varying amounts of combustible gases depending upon the askarel type. This manual describes the operating characteristics of transformer askarel liquid insulation as manufactured by Monsanto and how it differs from mineral oil. Appropriate handling and disposal procedures for both Scrap askarel liquid and impregnated solid materials are given in accordance with the guidelines recommended by the American National Standards Institute. The information is based on facts gathered by Monsanto over 40 years as a producer of askarel, plus knowledge gained from the experience of transformer manufacturers and users. This guide outlines the maintenance required for askarel fluid in "modern" transformers and offers suggestions for sealing and maintaining askarel in old units. By following this guide, we believe users will obtain maximum service from askarel insulation with a reasonable minimum of maintenance. If questions arise relating to the designing and building of transformers, these should be referred to regular transformer suppliers. Monsanto gratefully acknowledges the assistance, guidance and the contributions of certain data by the following: Edward L Raab - General Electric . Dr. T.K. Sloat -- Westinghouse Electric II. History of Trade Name Types "Askarel" is the generic name for the fire-resistant liquid insulation and coolant first used by General Electric Company in 1932 for their Pyranol1 brand name fire-resistant transformers, Westinghouse Electric Corporation uses their brand name, Inerteen.2 Whatever the trademarked brand, the askarel contains chlorinated biphenyl -- one of the best liquid insulations developed by science. This inert material is chemically stable, fire-resistant, heat stable, non-corrosive, and has high dielectric strength under the operating conditions encountered in transformers. In addition to manufacturing Aroclor (chlorinated biphenyl), Monsanto also mixes this dielectric fluid with chlorobenzenes to produce the presently used Inerteen and Pyranol blends described in Table I, "NOTE: Materials designated 'fire resistant* generally are more difficult to ignite, or once Ignited, burn at a slower rate than corresponding conventional materials. This term does not mean that fire resistant materials will not burn. However, when properly used, Monsanto's fire resistent ASKAREL FLUIDS are useful in helping customers meet their fire safety requirements." ^Trademark of General Electric Company ^Trademark of Westinghouse Electric Corporation Registered trademark of Monsanto Company . 0309494 1 TOWOLDMONOQ34776 Table I The Composition of Typical Transformer Askarelt Method ASTM 02283 Type D Type E , Type G Trade Names Inerteen 70-30 . Inerteen 100-42 Pyranol A13B383 Ingredients (% by wt.) Aroclor 1254, ^ chlorinated biphenyl . {54% chlorine by weight! 70 Aroclor 1242, chlorinated biphenyl ; {42% chlorine by weight) ' Trlchlorobenzene 30 Phenoxypropene oxide ' scavenger . 0.18 to 0.22 100 .. 0.18 to 0.22 60 40 0.115 to 0.135 ASTM Method D-2283, titled "Chlorinated Aromatic Hydrocarbons (Askarels) For Transformers", also lists the composition of all transformer askarels used at various times since 1932. . Monsanto manufactures similar transformer askarel fluids in England ' Where the trade name Pyroclor is used. ' III. Interchangeability :, In general all transformer askarels are interchangeable. However, it is suggested that the transformer manufacturer be consulted prior to mixing in significant proportions or total substitution. , IV. Transformer Askarel Specifications - Specifications for the three modern transformer askarel fluids are shown in Table II. V. Ordering Instructions , Monsanto's current policy is to sell askarel transformer fluids only to transformer manufacturers. Others interested in these fluids should contact the manufacturers of askarel transformers and hot Monsanto. The transformer name plate Indicates die transformer maker and usually gives sufficient date to identify the specific askarel fluids used. VI. Contamination r Askarel insulation must never be mixed with mineral oil. Over two percent of mineral oil by volume in askarel begins to lower its fire resistance. , In modern transformers, the principal "enemy" of askarel is contamination by water. Keeping askarel water-free will insure long-time service. - Askarel is heavier than water. If water gets into askarel insulation, only a tiny amount (approximately 126 ppm) dissolves -- the rest floats on top. Askarel Is very insoluble in water, only about 200 parts per billion of askarel dissolve in water, at normal temperatures, VII. Precautions When Handling Drums, Tank Cars, and When Oponing Transformers . ". The following are significant precautions: ; . A. Keep Dry During Handling: . ,. In handling, storing, sampling and inspecting askarel and in TOWOLDMONOQ34777 9 . - Traiisformer Askarel Specifications (New Fluid) : Specification Properties1 Color. APHA Condition - >y Water content, ppm (ASTM D1533-60) : - r - Acidity, mg KOH/g (ASTM D974-55) . . v- Dielectric Strength, 25C, 0.1 in. gap y * (ASTM D877-49) ,- Dielectric Constant, 100C, 60 Hz ;..y (ASTM 0924-49) .- , Volume Resistivity, lOO'C, : 500 volts DC 0.1 inch gap, 10s ohm-cm ; (ASTM D1169) . . . Inorganic chlorides, pom (ASTM 01821 and G.E, Method E4C41B). .. Refractive index, 25C {ASTM D1807) Viscosity at 37.8*C (ASTM D88-56) : . ; Saybolt Universal Seconds - Pour Point C (ASTM D-97-57) v: Specific gravity 25/15.5C (ASTM D1810) Burn point (ASTM D92) Distillation range (ASTM 020*56) corrected . for stem and barometric pressure , General Electric Co. Transformer Pyranol A13838*3 ASTM D2283 Type 0 Westinghouse Transformer Inerteen 70*30* ASTM D2283Type D. . Westinghouse - Transformer Inerteen 100^2* ASTM 02283 Type E 160 max. Clear , . 30max,V." - 0.014 max. :' ' -35 KVr min. - 150 max. Clear - - 30 max. - 0.014 max.: . y ... 35 KV, min. ... . 60 max, r- . Cleer 35 max. . 0.01 max.. 35 KV, min. 4.2 to 4.6,. A2 to 4.5 . : 4.7 to 4.9 : 100. :y - 100 - .: O.IOmaxiV ' . 0.10 max. . 1.6110 to 1.6120 44 to 48 ; 1.6153 to 1.6173 i ' 56 to 61 - -38 or lower5 'ie 1.495 to 1.510 V None to boiling 1st drop 200C min. 40% max. below 270*0 90% 379 to 394 .t - . .. *30 or tower c , - 1.518 to 1.528 v. ' ; None to boiling 1st drop 200"C min. 35% below 270-C . 90% 379 to 394 . : 100 0.05 max. v 1.6240 to 1.6260 82 to 92 , v -17 or lower 1.381 to 1.392 None to boiling 10% 325C mitt; ; 90% 360 max;.; I Fixed chlorine . ; 56.4 + 0.5% 55.6% min. . ' 43 t 0.5% I Corrosion test , After heating with aluminum for 6 hrs. at 200 to 220"C, the aluminum must not be corroded on either visual or weight inspection and the askarel should meet the following specifications;, . Color. APHA . . .* Acidity, mg KOH/g Inorganic chlorides ppm Condition Scavenger content . . 200 max. 0.014 max. . 0.15 max. Clear 0.115 to 0.135% - Diepoxide 200 max. 0.014 max. .. . 2.0 max. - Clear . 0:18 to 0.22% phenoxypropene oxide 200 max. , 0.01 max. . - ' 0.15 max. ' Clear - 0.18to0.22% phenoxypropene oxide Typical Properties2 Coefficient of Thermal Expansion 0.0007 0.0007 0.00068 (ASTM D1903),cm2/cm2/c Arc formed gases Askarels of various compositional types are used. Under arcing conditions the gases produced, while consisting predominantly of non-combustibte hydrogen chloride, can include varying amounts of combustible gases depending upon the askarel type. Insulation systems incorporating these askarels and ceilulosic or other organic materials may. when arced, produce gaseous mixtures which are moderately ffammable. As a precaution, such gases should be Westinghouse ues their private number Inerteen 54201KA lor Inerteen 70-30 and their private number Inerteen 54201 CM for Inerteen 100-42. removed from the askarel by bubbling dry nitrogen through the askarel and flushing the gas space with dry nitrogen before any work is performed on the apparatus. 1These ouantitlas are firtel aales wwcifjeations only to tha extant that they coincide with Monsanto's published specifications. JThit data is bassd upon samplas tasted in the laboratory and is not guaranteed for all swnptes. Write us for complete sales specifications for Askarel fluids. TOWOLDMONOQ34778 operating askaret transformers -- take every precaution to guard the askarel insulation from exposure to high humidity and moisture contamination. Keep 5 or 65 gallon drums of askarel dry; lay stored drums on their sides with the bung at the highest point from floor to "keep water off die drum head (which can be sucked into the askarel by the drum "breathing"). This precaution is not necessary when drums are stored indoors, which is the preferred place for storage. To avoid leakage the drums used for askarel are of heavy construction. Sixteen gauge metal is used, with special rim seal and bung construction. The drums should be drained as completely s possible and then flushed twice with kerosene type solvent to remove all of the askarel. Accumulated liquids and washings should be collected and should be incinerated at high temperatures, e.g., about 2000P, to destroy the polychlorinated biphenyls (PCBs). See Section A, VIII. Tank cars used to transport askarets are in exclusive service and not used interchangeably for other products. All cars must be unloaded through the top (dome fitting) either by pumping or with controlled pressure using dry air or dry nitrogen. If nitrogen has been used for unloading it Is necessary to advise the shipper so that when the car returns the nitrogen can be replaced with dry air before any one may enter the car. If the car is to be unloaded by pumping it will be necessary to use a dryer on the air intake line to remove moisture. ; All tank cars are fitted with steam coits, which are available for unloading under extreme low temperature conditions. Convenient handling and pumping temperatures are given in Table 111. .. 6. Use Ordinary Personal Precautions: Transformer askaret has boon made, handled, and used for over 40 years. It can be handled safety with recommended precautions. If ' accidentally spilled on hands, no serious skin irritation will occur. However, liquid askarel has a solvent action (similar to paint Table III Handling and Pumping Temperatures . . Product , Unloading,. Handling and Pumping . Tomperature*C . ^ . ,. Pyranot A13B3B-3 Inerteen 70*30 Inerteen 100-42 20-55 20-66 35-75 thinner) on the fats and oils of the skin and prolonged contact may lead to drying and chapping of the skin. In case of contact, wash the skin with soap and water; remove and dry clean saturated clothing. Clean up spills with rags,sawdust and absorbent clay. Eye contact may result in painful irritation but no permanent damage to tissues. If askaret gets in the eyes, flush with large amounts of water. As with all eye first aid, refer to a physician. To relieve irritation, physicians have used an opthaimic anesthetic solution as well as opthaimic cortisone acetate solution, or castor oil. r Infrequent exposure to askarel vapors will not cause ill effects. However, prolonged exposure to high vapor concentrations should be avoided. If hot asksret must be handled in a closed or confined area, provide tho area with mechanical exhaust ventilation - or wear an organic cartridge respirator approved by the U.S. Bureau . of Mines. . C. Precautions On Opening an Askarel Transformer! Askarels of various compositional types are used. Under arcing . conditions the gases produced,`while consisting of predominantly non-combustible hydrogen chloride, can yield varying amounts of ' - combustible gases depending upon the askarel type. Insulation systems incorporating these askarels and cellulosic or other organic materials may, when arced, produce gaseous mixtures which are moderately flammable. As a precaution, such ; gases should be removed from the askarel by bubbling dry. nitrogen through the askarel snd flushing the gas space with dry nitrogen before any work is performed on the apparatus. The American Institute of Electrical and Electronic Engineers Guide No. 76, March, 1974 gives more detailed instructions and guidance "For Acceptance and Maintenance of Transformer Askarel in Equip ment". This guide is published by the Institute of Electrical & Elec tronics Engineers, Inc., 345 East 47th Street, New York, New York 10017. We recommend that users of askarel transformers refer to this IEEE document. VIII. Avoid Environmental Pollution Transformer askarels contain polychlorinated biphenyls (PCBs) which have been used in the United States and elsewhere over the past 40 years for many industrial and consumer applications. During the past several years evidence has accumulated to indicate that PCBs are widely dispersed throughout the environment and that they can have adverse ecological and toxicological effects. . The United States Government's Interdepartmental Task Force on PCBs, Com-72-10419, jn their March 20, 1972 report titled, "Polychlorinated Biphenyls and die Environment", recommended restricting PCBs to use in capacitors and transformers. This report is distributed by the National Technical Information Service, U.S. Department of Commerce, Springfield, Virginia 22151. A document titled, "Guidelines for Handling and Disposal of Capacitor and Transformer Grade Askarels, Containing Polychlorinated Biphenyls", has been prepared and is available from the American National Standards Institute, Committee Cl 07, 1430 Broadway, New York, New York 10018. The scope, objectives and the composition of this committee are: > ANSI Committee C107 Scope: , Procedures and guides for safe use, maintenance and disposal of askarel and askarel-soaked materials used in electrical equipment. Objectives: , 1. Source of technical information and advice for Federal, State, local authorities and all others concerned. 2. Encourage development of suitable disposal facilities and keep all concerned informed. 3. Serve as the advisory group for United States participation in international organizations: CEE, IEC,CIGRE. Composition: . Organizations active in or represented by this ANSI committee include: National Electrical Manufacturers Association, Electronic Industries Association, Institute of Electrical and Electronic Engineers, American Society for Testing and Materials; Electric Light and Power Association; Certified Ballast Manufacturers Association; Environmental Protection Agency; Office of Environmental Affairs; General Services Administration; National j I I i TOWOLDMON0034780 r' Bureau of Standards; Department of the Army; Rural Electrification Administration; Division of Environmental Research, TVA; American Public Power Association, Water Pollution Control Federation; Food and Drug Administration; . National Fire Protection Association; Underwriters Laboratories; . end several sections of the US. Department of Interior. , , . - /" . . : ! The following are pertinent excerpts taken from the ANSI Guidelines for askarel transformers: .. 1. ; ., LABELING ASKAREL TRANSFORMERS (Pg. 16) ` 4.2.2.1 New Transformers. AH new transformers that contain PCBs Shall have a label of adequate durability, permanently and prominently attached to tf)e tank by the manufacturer, given adequate warning and instructions. A suggested label includes the following: , CAUTION: The insulating liquid in this transformer contains polychlorinated biphenyls (PCBs). Care should be taken to prevent entry into die environment. In case of malfunction or leaks, consult the instruction manual or the manufacturer. *. - 4.2.2.2 In-Service Transformers. The transformer manu- facturer should make available suitable labels with a simitar warning as shown in 4.2.2.1 for use on existing transformers. 2 ... . : : DISPOSAL OF LIQUID AND SOLID WASTES {Pg. 15) 4.1.6.5.1 General. Disposal of askarels andaskarel-soaked materials should be accomplished by means In which there is no significant release of askarel to the environment. At present, disposal is accomplished by carefully controlled incineration of liquids and soaked software, and by con trolled landfill burial of apparatus and other hardware from which askarel has been previously drained and washed. ' Present knowledge indicates that proper incineration must involve a suitable balance between dwell time and temperature in die incineration plus oxygen availability and, finally, suitable scrubbers to remove the HCi that will be formed; for example, 2-second dwell time a'i 200CPF and 3% excess oxygen in stack gas, or 1.5-second dwell time at 270CPF and 2% oxygen in stack gas. These facilities should meet the applicable requirements of the state in v/iich they are located and should control effluents widiin the limits set forth in this standard. Controlled landfill or deep-well disposal can be used where permitted by federal, state, and local regulations. ' - The ANSI Guide lists the locations of facilities that conform ,., . . with tire above requirements. Monsanto has such an incin/ erator at the W. G. Krummrich Plant, Department 831, , ' Sauget, Illinois 62201, where arrangements can be made for scrap askarel liquid disposal for a modest fee. For disposal of solid scrap a controlled dry land-fill can be used where permitted by Federal, State and local regulations. 3. . CONDITIONING OF NEW OR RECYCLED ASKAREL (Pg. 16) 4.2.I.3.I. Askarel Conditioning equipment. The condi tioning unit should be located either in the storage tank area or in die main transformer manufacturing area for filling with askarel. ' 4.2.1.3.2 Fuller's Earth. Conditioning of new askarel or recycled askarel requires fuller's earth treatment. The spent fuller's earth in cartridges or bags, when replaced, should be allowed to drain thoroughly over drip pans to remove as much liquid askarel as possible. The cartridge units of steel mesh construction should be placed in the "STEEL CON- TAMINA TED WITH ASKAREL" container for disposition, doth bags filled with fuller's earth should be pieced in the "SCRAP BURNABLE ASKAREL WASTE" container for disposition. (o) TOWOLDMON0034781 4. TEARDOWN OF TRANSFORMERS FOR REPAIR OR SCRAP (Pg. 16) 4.2.1.4.1 Drain all askaref from the unit either into a holding tank or reuse or into the drum labeled "SCRAP ASKAREL" for disposition, and then allow sufficient time for all of the askare! to drain from the core and coils. 4.2.1.4.2 Remove die core and coil assembly from die transformer. Sufficient absorbent material should be placed on the floor to absorb any askaref fluid that still drips from the transformer, r. 4.2.1.4.3 Place all materials in the appropriate salvage containers during the dismantling for later disposition. 4.2.1.4.4 All used materials, including rags, sawdust, tape, etc, regardless of quantity, shall be put into the appropriate containers for disposition, 5. t' ; ' TRANSFORMER DISPOSAL (Pg. 17) 4.2.3. The ultimate disposal of an askarel-fiiled trans former may be accomplished in either of two ways: (1) Complete drainage and dismantling with the proper disposal of the askarel and askarel-soaked components as described in 4.1.6. {21 Disposition of askarel transformers by means of junk or scrap dealers. This should be avoided unless a transformer is first drained, followed by soaking the interior with a suitable solvent. Accumulated liquids and washings are to be disposed of as described in 4.1.6. iX, Expected Service Life Manufacturers indicate that properly designed and installed askarel transformers ere expected to give trouble-free service for at least 30 years. Since their introduction in 1332, the manufacturers report finding the overall failure rate to be less than 0.5% for all units under test end service conditions. The Edison Electric Institute's report (1956-1958) on their member utilities publishes the failure rate for askarel transformers as 0.13 per hundred banks per year. .Mr. Frank M. Clark, who invented transformer askarels at the General Electric Company in the early 1930s, made the highly pertinent comment based on his many years of experience with G.E. Pyranol (askarel type) transformers that -- ; "The important thing is to keep them dry -- otherwise leave them alone". . : These words pf wisdom became especially applicable in more recent years when welding shut rather than gasketing became the main method of sealing askarel transformers. These units are sold with the understanding that the liquid is in a normally hermetically closed system. X. General Characteristics of Transformer Askarel Fluid Appreciation of the following characteristics, as given in the IEEE Guide, leads to understanding the reasons for selecting dielectric breakdown voltage and moisture as the prime practical tests to judge the quality of transformer askarel fluid. Also, due to these characteristics the power factor of transformer askarel will be normally much higher than the corresponding values for mineral oil. In comparison to mineral insulating oil, askarel is a relatively polar material; i.e., its molecules are dipoles, free to rotate around their axes and responsive to orientation by electrical forces: Askarel also exhibits a much higher dielectric constant and capacitance than insulating oil, and these differences must be kept in mind when interpreting electrical test data. " : ... ... '-v 't Because it is relatively polar, and possesses high solvency power, askarel is much more electrically sensitive than mineral oil to traces of extraneous soluble polar materials, and consequently the choice of obemoo I a I jj 'i , | 3 ,! > * ji jj I j !> .. : ; : i 'f constructional materials destined for use in askarel it very critical. This sensitivity is reflected in the pow6r factor and resistivity {specific resistance) of the askarel. ' It is important to note that, with the exception of water, the dielectric breakdown voltage of askarel Is not generally adversely affected by many of the soluble polar materials to which its power factor and resistivity {specific resistance) are to sensitive. In fact, the dielectric breakdown voltage of askarel is somewhat greater than that of insulating oil. Therefore, the values assigned these dielectric fluids in newly supplied transformers are 30 KV mm. and 20 KV min., respectively. . .. .^ As with insulating oil, askarel must be kept dry. It can pick up moisture from exposure to humid atmosphere. Under similar conditions of exposure, askarel can pick up nearly twice as much moisture when measured on a parts per million weight basis. XI. Sampling Transformer Askarel Fluid - The following precautions about sampling are quoted from the IEEE Guide. . : . , . "Representative samples, whether of the complete contents or only parts thereof, are extremely important from the standpoint of evaluation of the quality of the product sampled. Obviously careless sampling procedure or contamination in the sampling equipment will result in a sample that is not truly representative. This generally leads to erroneous conclusions concerning quality and incurs loss of time, effort, and expense involved in securing, transporting, and testing the sample. It is strongly recommended that all of the procedures and precautions outlined in the latest revision of ASTM D923 (Sampling Electrical Insulating Liquids) be followed. ;.v v "Because of the high specific gravity (relative density) of askarel (greater than 1), water and some other impurities are most likely to be found at or near the surface. The top sample, therefore, is considered to represent the worst condition." '-vy,-.-. v XII. Evaluation of Askarel Received in New Equipment. Some users of askarel equipment find it desirable to make "as received tests" on all equipment. It is quite common to use the dietectiic breakdown voltage test and visual appearance as the most significant tests, (f suitable equipment and trained personnel are available additional information may be obtained from the power factor, color, and moisture content tests. , In sampling askarel contained in apparatus extreme care must be exercised in order to obtain a representative sample. ASTM Method 0 923 should be followed. New equipment with askarel exhibiting the following characteristics is considered acceptable: - ;, - ; Dielectric Breakdown Voltage Color Condition - Visual Water Content Power Factor at 25* C - ASTM Methods ` *~ 30KVmin. D877 300 max. (Straw color) D 2129 Clear 0 1702 35 ppm max. D 1533 * D 924, D 150 *The power factor of askarel taken from new transformers, reactors and accessory equipment can reflect the presenoe of moisture, dissolved polar compounds, or other contaminants and may vary with the type of equipment from which the sample was taken due to (he different ratios of liquid-to-solid insulation and to the high solvency power of the askarel. Given an acceptable water content and dielectric breakdown voltage of the askarel as indicated above, a high power factor seldom impairs the serviceability of the askarel within rather broad limits and is b0 .> indicative of the degree of extraneous soluble polar materials present, ,, . > > Recognizing the possibility of a wide range of power factors being , - recorded for askarel in new equipment, it is difficult to establish a 1. single limit which would be acceptable to both suppliers and users for all applications. However, as a broad guide, power factors up v.-to about 10% at25'Cand 60 cycles per second (hertz) do not in ^ general indicate any abnormal contamination providing that the other criteria (water content, dielectric breakdown voltage, etc.) - are met. Much higher power factors may indicate excessive contamination or the misapplication of the solid materials used in manufacture In contact with the askarel and should be investigated. XIII. Dielectric Breakdown Voltage -- Moisture Relationship The dielectric breakdown voltage of askarel is highly sensitive to excess moisture; not sensitive to ordinary dissolved polar materials. While the dielectric breakdown voltage can also be lowered by severe arcing, askarel turns noticeably black or has particles of sooty carbon floating in it if arcing has occurred. Then the transformer should be repaired and the askeret replaced. , , M . If the dielectric, breakdown voltage is checked periodically and decreases significantly -- this indicates moisture pick-up, arcing, or both. When the dielectric breakdown voltage has dropped to 26 KV or less, an analysis for water is necessary. If water is found in excess of 40 ppm at room temperature, its source should be located and corrections made. 1 >v ^ , When the moisture content approaches 126 ppm (saturation level at room temperature), the dielectric breakdown voltage of askarel drops below the value required for-efficient insulating. The moisture content should not be allowed to rise over 70 ppm, sampled at operating temperature. If the moisture content is found to be in a satisfactory range and the dielectric breakdown voltage is low, the transformer manufacturer should be consulted. ., Table IV shows the relationship of dielectric breakdown voltage vs. moisture and Table V indicates the approximate water solubility limits in askarel and mineral oil. ' v , Table IV Relation of Dielectric Breakdown Voltage to Amount of Dissolved > . ! Water in Askarel and Mineral Oil Water Content (PPM) Breakdown Voltage (ASTM D677) Askarel Mineral Oil 'O' - . : 20 . 40 60...... \ 80 110 ' ' - 70 KV 55 47 40 38 10 50 KV 39 30 26 22 5 TTlj . I0b09bO2 TOWOLDMONOQ34784 -~ Approximate Solubility of ytfater in Transformer . . Askarel and Mineral Oil , . S. ' ' Amount of Water (PPM) Dissolved Askarel , - -v, Mineral Oil -30 -22 . 20 A , -10 . 14 0 32 10 00 20 68 30 86 / 40 104 ' 8 16 28 41 65 94 128 ' 170 ' ' > '8 10 <3 20 33 68 85 130 XIV. Turbidity ' ^ v.: . ... may be the visual sign of undissolved water, or may indicate dirt. Cloudiness may also result from cold precipitation of tin tetraphenyl "scavenger" that was used in the earlier Pyranol transformers. This scavenger begins to come out of solution around 15F above zero. To redissolve ft requires heating to 16Q-200F and agitation. High dielectric breakdown voltage will quickly indicate that any turbidity present is not moisture; that the insulating efficiency of the askarel is still excellent. However, if the dielectric strength is below 26 KV, moisture should be determined, using the Karl Fischer method (ASTlOl 01633-60). The dielectric breakdown voltage test for askarel serves primarily as an indicator for moisture. U is by far tfte most important maintenanpe test -t for transformer askarel. XV. Check Points for Maintaining Askarel Insulation ; A. General Considerations: \\ , Modern askarel transformers with welded construction or silicone . \ *v or Viton* gaskets {hand hole-cover, switch and terminal . compartment covers) and with properly constructed bushings require little maintenance. With properly constructed trans formers, annual or semi annual visual inspection and dielectric breakdown voltage test of the askarel fluid should suffice for routine maintenance chocking over many years of service. However, many askarel units were installed in the early 1930s --> before the development of some of the better modern gasketing i materials and before improved designs were developed for sealing I out moisture. Such early units should be, arid can be, modernized. * leaky or deteriorated gaskets should be replaced. If the askarel has become contaminated, it should be reconditioned. At the same time, a general clean-up of the unit and possible refinishing may be *. desirable. . ., If it Is not convenient to take an old transformer out of service for general repairs, leaky gaskets can be sealed temporarily by painting over the leaky area with epoxy cement. ! A survey of users Indicates a good number of earty-buift askarel transformers {over 20 years old) are kept in continuous servloe in critical installations by the following steps (instead of modernization). _ ..... ( . The operating units are equipped with compound pressure gauges for reading pressure above and below atmospheric. Positive `Trademark of E.l.DuPont DeNemouri & Company,Inc, yd fl pressure is maintained on the shell by introducing nitrogen at 2 to 3 pounds above atmospheric. Regular workmen in the area daily record the temperature and pressure. If a sudden pressure drop is noted more nitrogen is introduced and the gaskets are checked for leaks with soap solution, teaks are sealed by applying epoxy cement. ,< B. Modern Sealing Procedures: Transformer purchasers should specify the following modern ' techniques for sealing: . 3. Welding Construction: Covers, radiator connections, switch ' and terminal housings, instrument connections, etc. should be welded. 2. Bushing Connections: A number of bushings have been J developed to obtain a proper seal for the electrical connection through the tank wall. They are classified as follows: 1) Welded Type - (Bushing flange welded to tank wall) a. Cast resin bushing with a molded seal to the . bushing stud and external stainless steel or copper flanges. b. Roiled flange bushing with the metal to porcelain ................... seat at the cap and flange made by being rolled into . * grooves in the porcelain over silicone rubber rings. . The seal between the cap and stud is made by welding. c. Porcelain or glass bushings with metal to glass or - metal to porcelain seals. 2) Bolted Type-(Bolted to tank wall) a. Cast resin bushings with either cast or metal flanges ' containing recessed gasket grooves. : 1 b. Porcelain or glass bushings with flanges containing : . ' recessed grooves or gasket stop. . The gaskets may be either of rectangular or circular cross-section, usually % inch thick. Bushings with recessed grooves are suitable to use with cork, cork-nitrile rubber combinations or nitrile rubber as well as gasket materials such as silicone or Viton. 3. Small Size Connections: When not possible to weld, small size connection seals should be made with Flexitallic* stainless steel rings. The surfaces must be machined and parallel. The filler between the steel laminations of the Flexitallic ring should be either silicone or Viton. 4. Gaskets for Hand-Hole Covers: Modern design specified silicone gaskets. Such gaskets must be retained in a groove. , The groove preferably is machined into the flange or cover. However, it can also be formed by welding concentric steel strips to the flange or the cover. Generally the gaskets should be 5/16 to 1/2 in. thick for covers, depending on the depth of the groove or stop. A rectangular cross-section is usually used. The silicone material should be Dow Corning No. 50 Silastic** or equivalent. This is a low compression set material. For best sealing 20-25% compression is recommended, with ample clearance in the groove or stop to allow for this compression. No cement is required. With reasonable care the gasket is removable without damage and is reuseable. Silastic 50 is slightly swelled by askarel which contributes to the tightness of the seal. It is not deteriorated by askarel fluid or vapors. It resists weathering and it is thermally stable and "Trademark of FlexitaHic Gasket Company * "Trademark of Dow Corni(\g f: ]: i. i. [; f.i s i i! i i j i YtmOh09b04 i TOWOLDMONOQ34786 \ flexible at all operating temperatures. It is an excellent . . . moisture barrier. - * NOTE: Dow Corning. Midland, Michigan will supply a fist of a;>^ Silastic 60 gasket fabricators to all transformer >............. manufacturers or users. They will also furnish technical ........ data. See Appendix J Seals, Properties and procurements. C. The Older Sealing Arrangements; > .' ; ; The older type gaskets consist of either cork or cork-nitrile rubber combinations or straight nitrile rubber. .; : 1. Cork-Nitrile Combinations; Covers for the main tank, v hand-holes, switch and terminal chambers, relief diaphrams, etc., are held in place by studs welded , to the flange or by bolts. The gaskets are cut with openings and placed over the bolts. Often Shellac (Westinghouse Style No, 1160419, or General Electric Company** Glyptal* 12761 is used to , cement the cork to the flanges. > ^, The following is recommended for sealing with the cork nitrile rubber combinations: _ Use Armstrong NC-757 cork-nitrile material or equivalent. The gasket can be cut from a single sheet or by scarfing strips of the material. A convenient method for joining strips is to make a Keystone Type joint. For this purpose, Westinghouse, . , , Sharon, Pennsylvania, offers their gasket cutter Style No. 328 6614 601, tabout $161. 1' . The joints - and also the gasket - should be cemented to the flange, using one of the above cements. Excess cement should not be allowed to reach the interior of the transformer. After installation and bolting, the outside edge of the gasket should be coated thoroughly with epoxy cement to increase weather resistance. . This epoxy cement is a paste to which a curing catalyst is added immediately before use. Typical are: v . , ,- - . Epoxy Fetch Kit #1-C . . Hysol Corporation, Olean, New York. ' b. Sootchcast* * Resin #4 . Minnesota Mining & Manufacturing Company St. Paul,Minnesota ,. , c. Adhesive A-1 and Activator Type B 1 Armstrong Products Company i Argonne Road, Warsaw, Indiana d. Adhesive 9860-1, Synthetics Organic Company, Cleveland, Ohio, used with activator diethylene triamine (Carbide and Carbon Chemical Company) , , 2. - Straight Nitrile Rubber: When straight nitrile rubber was originally used, invariably the gasket was recessed in a groove. This was to prevent gasket flow and to protect the material against excessive compression. Although this type seal was not cemented, the nitrite rubber gasket is not reuseable. Since grooves or stops have already been provided for the u nitrile rubber seal, Silastic 50 can be easily substituted and is recommended. This conforms with modern practice. XVI. Periodic Fluid Inspection and What Checkpoints Mean On a regular schedule - at six, nine, or twelve-month intervals -- make a simple visual inspection of your askarel insulation and run a dielectric breakdown voltage check. . . >. Trademark ol General Electric Company ! , , /Trademark of Minnesota Mining & Manufacturing Company // , ,v v > ObO^bOb TOWOLDMONOI A. Visual Inspection: ' . Askarel is a dear, faint-yellow liquid. After long-term use this ; ^ color may gradually intensify to light brown. The fluid should ^ ' remain clear and free from turbidity or cloudiness. . , > ; Any color change - such as to a green, red or blue cast - indicates extraction of impurities {colormaterials) from the solid insulation. If a distinct foreign color pick-up is noted, cherfc the complete range of electrical characteristics and notify the transformer maker. Blackening of the askarel may indicate an arcing condition. Other color changes alone are not danger signals since the dielectric breakdown voltage is not likely to be impaired. . B. Dielectric Breakdown Voltage ' If the dielectric breakdown voltage has decreased significantly from the last inspection, or if it has gradually decreased below 26 KV range (at 25*C) - RUN A CHECK FOR MOISTURE. Use ASTM D1533 (Karl Fischer Method), f: ! jjr til! ) j! 'I, j I'! j! ILj [: j; j!;l j| `l-,! j|,( ; ji1 jjij The dielectric breakdown voltage of askarel is the major indicator to the operating efficiency of your liquid insulation. Besides the visual inspection tests, dielectric breakdown voltage is the only - test necessary to run on a routine basis. Well-scaled askarel transformers have service records of 25 to 30 years on the original . askarel. jj 1 || ! j!, | ' j;i XVII. Inspection Checklist 1. If askarel is clear -- even though darkened to light brown, has no sediment or turbidity, has dielectric breakdown voltage over 26 KV-give it the inspection "OK". . . ' . 2. If askarel is clear, but has foreign color of blue, green, red ... it is "extracting color" from internal materials. This is not, of itself, an operating hazard when the dielectric breakdown voltage stays over 26 KV and moisture remains low. However, this rare occurrence calls for checking into the condition of the interior construction and consulting the transformer maker. However, when sampling the fluid care should be taken to avoid getting color into the askarel from paint that may be inside or outside of the sample valve. : . :. 11 *. 1 i !<j j'. i; ' ;j i i i: !j: 1 jj j!; | 3. If the moisture content is found to be above 70 ppm at operating temperature, then sampling should be done at more frequent intervals to establish a possible trend, particularly on outdoor installations, v .. 4. If askarel is clear, but dielectric breakdown voltage drops to 22 or lower KV, and moisture rises over 80 ppm when sampled at operating temperature ... the askarel ts ready for simple "refining". If the moisture is near the saturation level labout 125 ppm at room temperature) a thorough inspection should be made for water droplets in the transformer tank, and even for "globules" of water floating on the askarel surface. If found, the transformer manufacturer should be consulted for reconditioning both the transformer and the fluid. j; : :' jj' j ;;j j ('j j; j j r;l !; j ! j f{ ;j !' |: !. ; 5. If askarel is dark brown to black, if black particles of carbon are seen, and dielectric strength is low ... the askarel has been broken down by arcing. It cannot be refined and should be removed and incinerated under proper conditions. (See ANSI Committee C107 report on Use and Disposal of Askarel and Askarel-Soaked ' Materials. 1430 Broadway, New York, New York 10018. ;! j j'j i i ) 1i I; i If any of these five simple inspection tests appear out of the ordinary or the relationship between appearance and test values is abnormal, contact your transformer supplier for a complete analysis. . . . ; , ' ' | ' .j Whenever a sample is to be shipped to Monsanto, please follow the directions shown under. "SAMPttNG ASKARE^V :, ! TOWOLDMONOQ34788 r XVIII. Contamination in "transformer* Moisture, particulate matter and arced decomposition products are known to be serious contaminating influences on transformer askarel. ` The power factor test normally used for the detection of contamination In mineral oil filled transformers is of little use for this purpose in askarel filled transformers, due to the extreme effect of extraneous v soluble polar materials. This increase in power factor as illustrated in Table VI has no adverse effect on dielectric breakdown voltage. rabte VI Effect of Common Insulation Materials on Power Factor and Dielectric Strength (Heat Aged 96 Hours in Askarel at 100C.I Material Immersed __ Askarel After Exposure_ Power Factor, Percent at 60 eye., lOCTC Dielectric Strength _ 25C, None (control) Black varnished cloth . Copper : Pressboard Manilapaper Phenol formaldehyde resins Shellac . Iron , Synthetic rubber . 1.0 85.0 1.6 2.0 1.6 1.6 6.0 6.0 70.0 35 KV 42 40 37 39 41 36 39 39 Similarly, trace contaminants from commonly used construction materials can lower the volume-resistivity of askarel, without affecting its dielectric breakdown voltage. This is shown in Table VII. Table VII Effect of Common Insulation Materials . . . on Volume Resistivity of Askarel Sample .. Volume Resistivity . ^ x 10 ohm-cm (at . .. fOOC.. 500 Volts PC., 0.1" gap) 1. New askarel before heat aging 2. New askarel after heat aging 96 hours at 100C 3. After heat aging with 1 sq. inch specimens of: ; a. Phenolic resin tap changer materiel . b. Paper c. Grade A pressboard (ten) 0 d. Grade A pressboard (gray) . e. Grade A pressboard, laminated strip f. Cotton wrapping . " g. Glyptal 1276 cement, cured 48 hrs. at 110C 2.000 1,900 1,200 750 500 500 400 300 190 While trace contamination easily lowers volume resistivity from high levels, It is important to note that heavy contamination (as when arced) does not lower the resistivity below the order of 10 ohm-cm. at 10p*C. The different behavior of askarel vs. mineral oil in these respects can be summarized as follows: High power factor and low volume resistivity In transformer mineral oils 8re commonly regarded as "danger signals*' that the oil has deteriorated and broken down chemically or excessive moisture is present. . This is NOT TRUE of askarel liquid insulation unless the dielectric breakdown voltage Is low or the moisture content is high. m mssm r`V' N^F v ` , V, , ` ' ' > ' '>.,> t..>-( Manufacturers of askarel type transformers point out that h is quite . welt known that askarel transformers with initial power factor of the askarel fluid In excess of 50% at room temperature and 50 Hz are giving satisfactory service life. However, there needs to be assurance that both dielectric breakdown voltage and moisture are at satisfactory levels and do not show adverse trends. - ^ , XIX. ASTM 03255 Method for Investigating The Compat ibility of Transformer Insulation and Construction Materials in Askarels ' This method uses the change of electrical and/or chemical characteristics of transformer askaret resulting from its controlled exposure to insulation and construction materials, in order to evaluate their immediate major "contamination" effect on the askarel fluid. Delayed or long time contamination effects may not be detected. The method also utilizes various physical tests on the insulation and construction materials after controlled exposure to the askarel to determine the compatibility of these materials with transformer askarel. Properly proportioned specimens of the insulation or structural materials are immersed in refined askarel for 168 hours at 100 1C in a forced draft oven. Changes in electrical and chemical properties of the transformer askarel are comparod against a control sample of the askarel treated in the same manner, in absence of the test specimens. Dissipation factor (ASTM D 924) change is one of the criteria used. The askarel fluid is refined by absorptive treatment to a dissipation factor level of 0.05 max. at 100*0 and 60 Hz and 0.01 max. at 25C and 60 Hz. Corresponding values of the askarel fluid after heating 168 hours at 100% in absence of a test Specimen are 0.075 and 0.02 respectively* The maximum dissipation factor levels suggested for the askarel after heating In presence of the test specimen are 0.20 at 100% and 60 Hz and 0.04 at 25% and 60 Hz., XX. Refining Askarel for Reuse > , A. Filtering Through Dry Blotter Paper to Remove Moisture and Extraneous Particles: - Most operators prefer portable refining apparatus, such as a plate press fitted with a dolly, available from Sparkler, Mundelein, Illinois or General Electric Company, Pittsfield. Massachusetts; or ; the earthen cartridge filter type available from Industrial Filter Corporation, Lebanon. Indiana. Filter paper liners for the plate . press are available from Carl Schleicher and Scbuelt Company. Keane, New Hampshire and manufacturers of filter presses listed above, . . , . ; . The filter paper must be dried Immediately before use. For best results, spread the paper for maximum surface exposure in a hot air circulating oven and heat It for 4 to 6 hours at 110%. Circulate the askarel hot (but not over 40*0 through the filter fitted with the dry paper liners. , After filtration the dielectric breakdown voltage of the askarel should be 35 KV minimum* PRECAUTIONS: 1. Filtering should not be done when the relative humidity exceeds 75%. : 2. Any flexible hoses and gaskets on the refining equipment should be lined with or made of materials that will not be softened by contact with askarel fluid. (Materials lined with Silicone, Viton or Teflon* or flexible metal > materials are suitable.) ^Trademark of . 1. DuPont DeNemour*& Company, 3 0^09508 TOWOLDMON0034790 TABLE VIII Guide to Bate of Dissolved Water Removal By filtering Askare! Through a Paper Press Passes Through Paper West v Water in Askare) PPM - 0 J, 2 3 Yv 4 ''' '5 6 115 35 ' 22 18 . 12 10 10 Disposal of Solid Wastes: ; v^ ^ The ANSI guide C107.1-1874, Section 4.1.6 gives detailed recommendations. , : .^ : Solid Insulation Requiring Drying:. . . ` If the solid insulation of the transformer requires drying, consult the transformer manufacturer or an apparatus service shop, as in such case oven drying is preferred. ,; Earth Treatment for Maximum Improvement of Power Factor and Volume Resistivity We question whether pumping and filtering the fluid solely to achieve a change in power factor or volume resistivity alone is Justified in today's ecological climate regarding PCBs. We recom mend that In these situations the original transformer manufac turer be contacted. v 1. Procedure: ....... . / . The askarel liquid should be relatively dry pjior to the following earth filtration. , j ; : As a coating on the filter paper surface use finely divided : i ; Attapulgus* clay or Fuller's earth dried and activated by heating for 12 hours at 300-350F immediately prior to use. ,' The amount of earth used should be 0.1 to 0.2 percent by . weight on the weight of the askarel to be treated. Askarel weighs about 12.5 pounds per gallon. v To deposit the earth evenly, stir one-third of the earth with a - . small portion of askarel in e clean container. Pump the ' mixture through the filter and follow with two more one-third portions. Then circulate askarel taken from near the top of tho transformer, pass it warm inot over 65C) ' through the earth-coated filter and feed back through the bottom transformer outlet. Continue circulation until the fluid is dear and test shows that the electrical properties are . ' fully restored. .V' . -. 2. Effect of Earth on Removal of Scavengers ` Only slight and insignificant (oss by selective absorption of ' . tin tetraphenyl and epoxides occurs when askarel is refined by treatment with 0.1 to 0.2 percent by weight of earth. To remove significant amounts of the scavengers requires rape ' tilious treatment with much larger amounts of earth. "Trademark of Engelhard Minerals and Chemicals Carp. li- TOWOLDMON003^ Table IX Approximate Relationship Showing the Insignificant Effect of Power Factor and Volume-Resistivity on Dielectric Breakdown Voltage of Transformer Askarel , ; Power Factor , <60 cyc.l lO&C : W5 Volume Resistivity x 109 ohm-cm (at Breakdown 1000,500 Volts Voltage PC, 0.1" gap)__. 25*0.0.1" gap 2% 65% 15% 20-26% 40-50% ' 0.05% 0.1% ' 0.7% 2.0% - . 1500 500 100 60 70 25 35 KV 35 35 35 35 XXI. Cleaning Arced Transformers If a unit has arced so that the askarel is no longer fit for use. a thorough cleaning of the unit is necessary before refilling with new askarel insulation and returning it to service*. Follow this procedure insuring care is taken to prevent any loss of liquid askarel to effluent streams. A, Drain out all dark, carbon-contaminated askarel. Arrange to have the scrap fluid incinerated under proper conditions. (See ANSI Committee C107 report.) ;i , |! ;! j :i > ; :l ;| | 6. Carefully brush carbon deposits from internal parts and insulation, ' using a Soft bristle brush making sure that insulation is not damaged. , .. . v .. C. Flush thoroughly using new askarel -- oof an oil. not a cleaning solvent. *' ; D. Flush a second time with fresh askarel; dram; then fill to the proper level with new askarel. ; ; ;j 11 ;| 'j | E. Energi?e transformer to warm the fluid for 24 to 48 hours; then circulate the askarel through a filter, returning it to the unit filtered and ready for use. XXII. Sampling Askarel Take a sample as close to the top of the liquid surface as possible. Many large askarel transformers have a built-in sampling tube near the surface for convenient sampling. Then, to make sure that your sample truly represents your askarel insulation, take another sample from the bottom. If additional sampling tube connections are contrived on the valves for easier sampling, make the tubes of clean glass, stainless steel, aluminum or tin for rigid types; and silicone, or Viton or Teflon tubing for flexible types. ^ | \ n '| j i; i! j | j Use NEW containers for the askarel sample. A new and thoroughly pre-dned, small-mouth quart glass bottle fitted with a Bakelite** screw cap with aluminum or tin cap liner is recommended for quick, on-site testing. (If complete analysis is to be made, a 5-pint size sample is required.) ; , j ! ... 11 ,! Be sure that the new bottle does not stand open to collect dust or moisture. Rinse the sample bottle and cap lining two or three times with askarel from the transformer, then fill it. If the sample will be tested promptly, a clear glass bottle can be used. If sample is to be stored indefinitely, use an amber glass bottle or wrap clear glass with aluminum foil. . 1 ; ! J l| j | A. Select a dry day. Do not sample insulation on a warm, moist day when humidity exceeds 75%, and ... ) > This assumes that the cause of arcing has been established and corrections made. When severe arcing occurs, major repairs are usually necessary and the unit rebuilt. This procedure can be applied for flushing out the repaired units. Trademark of Union Carbide Corporation > ' > .................Bln,I>,il ; j jj :!! i | TOWOLDMON0034792 B. Make sure that the askarel is at least as warm as the surrounding . ' air. {Cold liquids can condense moisture from humid air.) . C, When sampling askarel from transformers, it it best to take the sample when the unit is warm and operating at average or maximum toad, especially for a check on moisture as reflected by a dielectric breakdown voltage test. Sampling the warm askarel more truly represents its condition during operation. . Experience shows that water will migrate from a transformer's solid insulation to the askarel liquid and vice versa, depending on temperature. Therefore, when the transformer is hot, the moisture )s most likely to be found in the liquid. This acoounts largely for periodic variations In dielectric breakdown voltage. For example, a , relatively high dielectric breakdown voltage may be found during winter months and a relatively low dielectric breakdown voltage 1 during the Summer months on samples taken from the same unit. When testing has been completed, the remainder of the fluid sample should be destroyed by high temperature incineration described in Section VIII. Askarel Filled Switches and Terminal Chambers / I. Introduction High voltage leads are usually connected to askarel or mineral oil-tilled network transformers and power centers through terminal chambers and switches. In some cases terminal chambers are not used, and the high voltage leads are connected directly to the switch terminals. They may be filled with either askarel or mineral oil. Switches are usually rotary or drum type fitted with a revolving block and porcelain unit as the principal element arranged for three-phase service. Askarel transformers with attached switches have been in use for about 30 years. When they were first introduced, the availability of insulating and gasketing materials was rather limited and even the best materials at the time had no service history. As a result, inadequate gasketing materials such as cork, nitrite rubber, and nitrile rubber-and-cork particles were used. While satisfactory for a limited period of time, these materials cannot be depended upon for the expected long life of the equipment. ; ,, The terminal chamber is usually above or below the switch compartment and separated by a steel wall through which the bushings are inserted. When bushings are property selected and correctly installed, there is no leakage from one compartment to the other. With poor bushing seats, and the terminal chamber above the switch, potting compounds or cable oil can seep into the askarel. When the terminal chamber Is below the switch, askarel can drain into the terminal chamber. .; II. Sources of Contamination There are three possible sources of contamination for askarel in switches and terminal chambers; they rank in this order of frequency: (1) water entering through poor gaskets; (2) decomposition products from arcing when switch Is used to break magnetizing current; 13} entrance of pothead or cable compounds through leaky bushing seals. Unlike an askarel transformer where the amount of contaminant is likely to be very small (probably only trace amounts) in relation to the volume of askarel fluid -- in switches or terminal chambers with faulty seals, the amount of contamination can be relatively large. Experience has shown that, based on the number of installed askarel-switch units, the percentage of failures is extremely small. When investigated, it has been found that most failures originate in the switch chamber. Water is the chief source of contamination. However, heavy contamination of askarel with petrolatum and asphalt material, due to leakage, have caused a few failures. Petrolatum is used frequently for filling terminal chambers. When either cable oil or petrolatum seeps into askarel, no great harm results. The fire resistance will be somewhat decreased and power factor of the askarel will increase with an accompanying drop in resistivity. While highly undesirable, it Is doubtful that failure of the unit results. Where asphaltic compounds are used in place of petrolatum, the danger Is increased somewhat because asphaltic contamination may cause excessively high dielectric losses in the askarel. When the terminal chamber Is betow the switch chamber, the potting compound can be contaminated by askarel if the bushing seals are leaky. This is undesirable because the askarel will increase the power factor and conductivity of the potting compound or cable oil and develop heat from dielectric loss, if this mixture is drawn into the cable ObOJ612 m TOWOLDMONOQ34794 insulation, a cable failure Is likely. This ayain emphasizes the Importance of tight bushing assemblies < ' III. Sealing Switches and Terminal Chambers - ' Proper bushing construction, use of Silastic seals and welding wherever possible is highly desirable (as covered in Section A). Where an elastomeric seat is to be used In contact with both askarel and petroleum oil, DuPont's Viton is suggested. , , For new equipment the user should specify these modern sealing arrangements to keep out contaminants and minimize maintenance. IV. Askaret Used Under Mild Arcing Conditions The IEEE Guide for Transformer Askarel calls attention to the following: , .. . . .; , "Askarel is used, to some extent, in apparatus where it is subjected to light intermittent arcing, such as In self-contained induction regulators, where operating switches are continually producing slight arcs, in transformer de-energizing switches, etc., Under normal conditions, deterioration of the askarel is very slight. However, improperly adjusted or defective switches in this type of apparatus can produce excessive and prolonged arcing and accelerated deterioration of the askarel. It is recommended that :/ when askarel is used under these conditions, checks of the liquid, especially for moisture and dielectric breakdown voltage made more frequently than when it is used only as a cooling and , insulating fluid. Deterioration of this type is indicated by a ' blackening of the liquid. It can usually be reconditioned as . previously described. Special attention should be given to maintaining the Scavenger at the appropriate concentration." V. Maintenance for Askarel Filled Switches A. Switches used for grounding after power source has been ' deenergized will not undergo arcing. 0. Switches interrupting magnetizing current will be subject to arcing; the amount of decomposition will depend on power interrupted, time and frequency of operation. As a general rule, the liquid should be checked after 6 to 10 operations. 1. On newly Installed switches, check the askarel at 3,6 end 12 . month Intervals; if found satisfactory, check once annually ' thereafter. With proper attention to the gasketing of covers and bushings, experience will probably indicate that less frequent Inspection is warranted. ,,. 2. Check askarel for: . ; ... a. Dielectric breakdown voltage (ASTM D877): It should be 26 KV minimum. If dielectric breakdown voltage is low, confirm presence of water by Karl Fischer method ASTM D-1533. Filter to remove moisture. Dielectric strength should then be 30 KV minimum, b. Presence of carbon from arcing: Fluid should be relatively free of carbon. If badly arced and very blade, replace fluid. If only minute amounts of carbon are present, filtration is recommended. Check power factor ; of liquid (should not be over 5% at 25C and 60 cycles). Flush out switch chamber with several gallons of fresh ' ' askarel before refilling. ,. 3. If there is discoloration, high power factor, detectable change In specific gravity or refractive index, or if fluid flashes below 250F, there is a possibility of seepage of potting compound into the switch compartment. In this case, correct any leaky bushing seals with proper replacements and fill with new askarel. 4. If terminal chamber is below switch, check potting compound for presence of askarel (can usually be detected by odor or by an increase in specific gravity). If askarel is present, correct any leaky bushing seals with proper replacements, and renew compounds. 5. Examine cover gaskets visually. Deterioration can be detected by swelling and Cracking of the exposed edge. In cases of yf severe deterioration, liquid seepage is usually present. 6, Check for leakage at packing gland of switching shaft. If 0 . ' leaking, repack with a Silastic ring type gasket. VI. Askarel Under Excessive temperature or Fault Conditions The IEEE Guide also points out that, 'Chlorobenzenes used In transformer askarels begin to boil at temperatures of about 205C, under atmospheric conditions. If the material is heated to such high temperature in a sealed system, pressure develops. Pressure will also develop In the system if the askaret is arced sufficiently to generate copious hydrogen chloride . gas. 'Therefore, It is recommended that wherever possible, scaled .......askarel*ffiled equipment be provided with pressure relief devices. These devices must be large enough to provide immediate relief at a definite pressure, and to prevent further buitd up of pressure if decomposition continues. It must be remembered that the presence of devices of this sort docs not necessarily preclude the rupturing of containing vessels, since pressure build up can be .....extremely rapid under violent arcing conditions." Toxicity* Safe Handling I. Inhalation At ordinary temperatures the chlorinated biphenyls in Askarel have not presented industrial toxicological problems. The hazard of potential toxic exposure varies with their volatility: the lower-chlorinated, morevolatile ones present more of a potential problem from the standpoint of both inhalation and skin contact. When Askarel fluids are used at elevated temperatures, engineering controls must be applied, either by the use of closed systems or by effective local-exhaust ventilation together with general workroom exhaust. Vapors of Askarel at room temperature should not be breathed in a confined space, and no vapor of any fluid evolved at elevated temperatures should be allowed to be dispersed into the general workroom. ,^ Inhalation tests on animals indicate that the maximum safe concentra tion of Vapor is in the range of from 0.5 to 1.0 milligram per cubic meter of air. The threshold limit value (maximum allowable concen tration of an 8-hour working day) set by the American Conference of Government Hygienists are 1.0 milligram of the lower-chlorinated biphenyl compounds per cubic meter of air and 0.5 milligram of the more-highty-chlorinated compounds, per cubic meter of air. II. Skin Contact . Prolonged or repeated skin contact with the Askarel fluids must be avoided by the use of gloves and protective garments, because of the possible occurrence of a condition called chloracne. Although reports of this condition caused by Askaret are rare, it can be produced by excessive skin contact. If the fluid is spilled on the skin the skin should be washed in the usual manner with a soap solution. . A burn caused by contact with a hot Askarel should be treated like any ordinary burn. For disposal instructions of Askarel fluids, see Section A - VIII, page 6. _ ...0,0^1, jr 2fi TOWOLDMONOQ34796 Analytical Services on Transformer Askarcl <3 Available From Monsanto Transformer users not wishing to make their own fluid analyses can obtain the service from Monsanto. Simply contact Monsanto and specify what analyses are wanted. You will be sent the proper-sized, Clean sample container, fitted with a proper label. When you receive this, carefully take your sample (following the procedure for sampling in this guide). Send the container to Monsanto's laboratory. Charges listed include sample container and laboratory costs. The charges are those in effect March 1, . 1976, and are subject to change. , Types of Analyses Available Analysis 1) . ROUTINE MAINTENANCE CHECK , . Total Charge: $30.00 ' To determine the general condition of the fluid and find whether further analysis is necessary, (one-quart sample required) ; ; Properties Tested <' Dielectric Breakdown Voltage 1 Color and Condition * - Moisture . . You wilt be notified of the results of this test. If further testing is Indicated, and you want a complete analysis, you wilt be sent a five-pint sample container. This sample will be used for the following series of tests: Analysis 2) COMPLETE ANALYSIS , : Total Charge: $76.00 . , . (1) To determine the extent of fluid contamination, (2) earth refinement to determine what degree of restoration of electrical and insulating properties is possible, (3) check test to see how the fluid responded to earth treatment. a) Complete Analysis: to determine the extent of contamination < .. . Properties Tested . Free Chlorides . v Color end Condition . . Acidity Specific Gravity Oieleetric Breakdown Voltage . ... . .Refractive Index Water ; b) Earth Refinement Response: . .v..... . . ' Power Factor, Dielectric Constant, and Resistivity > -v:. .' . '. m Consists of treatment for 2.6 hours at 50-60C. with 0.1 to 0.2 percent by weight of properly conditioned Attapulgus clay and then filtration through dry filter paper. c) Analysis After Laboratory Earth Refinement: .^ r . . . . ; Properties Tested Acidity Refractive Index . Dielectric Breakdown Voltage Water : , Power Factor, Dielectric Constant, and Resistivity Free Chlorides * Yog will be notified of the results of this test series on your sample. Then after refining your entire transformer fluid fill you can check on the results by requesting the following analysts: .. Analysis3) .-. v . y. - '' ANALYSIS AFTER EARTH REFINEMENT Total Charge: $50.00 .r . , - .. (Thischarge will not apply when . . : . analyses 1 and 2 have already been made.) * '. ^ , '` To determine whether the entire lot of the askaret fill responded to the same extant as the laboratory sample, (five-pint sample required) . Properties Tested Free Chlorides . . v Color and Condition # Acidity Refractive Index . Dielectric Breakdown Voltage Water - Power Factor, Dielectric Constant, and Resistivity To arrango for the tests described above write to the following address: David Wood Monsanto industrial Chemicals Company , ' 800 North Lindbergh Blvd. ` St. Louis, Missouri 63166 '^ ; '- , ' . . Samples to be tested should be clearly marked for Identification and sent directly to; Monsanto Company ;. ' W. G. Krummrich Laboratory Sauget, Illinois 62201 :- . . *, 1 Attention: R. Kuster - H . . 0!>(mi5 TOWOLDMONOQ34797 , 1 < '* (t ' ^ +(" * * , < \ />,'!, t >V ( E Appendices r '% ) APPENDIX A Askarel Stability and Composition of Arc Formed Gas: Askarel insulation is one of the most inert, chemically-stable heat resistant, non-corrosive liquids known. It will not break down, oxidize or sludge when exposed to air and high temperatures, 150C. or even somewhat higher. Arcing, however, will break down the compound to liberate some hydrogen chloride and smalt amounts of carbon. APPROXIMATE COMPOSITION ARC-FORMED GAS FROM TRANSFORMER ASKAREL BLENDS ASTM TYPES D AND ti (INERTEEN 70-30 AND PYRANOL A13B3B-3, RESPECTIVELY) Gas * carbon monoxide . ; carbon dioxide oxygen inert gases hydrogen chloride (note the absence of phosgene) . ^ < - , . ./ " ; Amount 0.3% 0.3% 0.6% 1.5% 97.3% This arc-formed gas from ASTM Type D and Type F transformer askarels Is non-flammable and non-combustible. Cl For all practical purposes, the amount of gas liberated from askarel under a given set of arcing conditions Is about 100 cubic centimeters per kilowatt-second. . .^ . APPENDIX B SOLUBILITY OF GAS IN TRANSFORMER ASKARELS ........ ASTM TYPES D AND G . < /: : Vs , . J, , V Carbon dioxide Air Nitrogen Hydrogen chloride1 ;! *tn absence of scavenger Percent ot Gas By Volume Corrected to: 25-C 760 mm 255. 100-C 71% ` 6.7 6.0 , 37.8 47% 4.9 4jB 50.6 ., ,, 0"C. 760 mm 2PC 10QaC . 6.8 5.0 6.6 4.4 APPENDIX C EFFECT OF TEMPERATURE ON DIELECTRIC BREAKDOWN VOLTAGE OF ASKAREL o . . .' ,, ......... . ... Temperature *C . , -60 -40 ` -20 t) ' ''I - ' 20 40 60 4 80 . -. ; Dielectric Breakdown Voltage ASTMD877 67 KV 63 . .. 67 : 55 60 60 ' 48 ' 45 - ' `. ' ' TOWOLDMONOQ34798 APPENDIX O COMPARISON OF THE APPROXIMATE VISCOSITY IN SAYBOLT UNIVERSAL SECONDS OF TRANSFORMER ASKARELS AND MINERAL OIL ........ ^ ^ ," Temp.X5 * ,* , -20 o 20 40 60 60 100 . , ryrmol 11 A13B3B-3 1,000 100 70 46 39 34 30 ,- 10 Mineral Oil 1,000 150 65 49 40 34 30 - Inerteen 70-30 2,800 195 85 60 40 36 33 APPENDIX E ` * THE DENSITY OF INERTEEN 70-30 ' AND TRANSFORMER PYRANOL A13838-3 .- Approx, Density flm/cc. Temp.*C O 20 40 60 80 ' . Inerteen 70-30 Pyranol A13B3B-3 1.574 1.652 1.529 1.607 1.485 * 1.677 1.655 1.632 1.610 1.488 APPENDIX F The thermal conductivity values of transformer Pyranol AI383B-3 at 27C and 68C are 26.2 and 26& x 10'5 calories centimeters*1, degrees centigrade-*, second-*, respectively. Or, approximately 0.06 BTU per (hr.) (sq. ft.) (*F.) per foot. This same approximation applies to Inerteen 70*30. APPENDIX 0 Heat Capacity , v >. . Over the temperature range of 26* to 125*0 the specific heat of transformer askarel is close to 0.30 calories per gram per degree.' * ' ' APPENDIX H_______________________________________________ ,' ' '_________ Coefficient of Expansion '*5 . The average coefficient of expansion of transformer askarel over the temperature range 20 to 100*C is 0.0007 cc/oc/O. One gallon would increase to 1.056 gallons on heating from 20 to 100T2. APPENDIX I Fire Resistance . Askarels of various compositional types are used. Under arcing conditions the gases produced, while consisting of predominantly non-combustible hydrogen chloride can yield varying amounts of combustible gases depending upon the askarel type. ' . . Insulation systems Incorporating these askarels and cellulosic or other organic materials may, when arced, produce gaseous mixtures which are moderately flammable. As a precaution, such gases should be removed from the askarel by bubbling dry nitrogen through the askarel and flushing the gas space with dry nitrogen before any work is performed on the apparatus. , ,f 'vlf t iV 0b04^7 TOWOLDMONOQ34799 APPENDIX J Seals, Properties and Procurement * Dow Corning Corporation, Midland, Michigan with Districts at Atlanta, Boston, Chicago, Cleveland, Dallas, Los Angeles, New York City, Washington, D.C. and Toronto has available Bulletin 09-019, August 1962 entitled "Silastic Design Data", This lists the gasket fabricators throughout the country from whom the "Silastic 50" gasketing can be purchased in sheet, extrusions or molded shapes. Generally, Silastic 50 sheet goods are stocked by local die cutters, hence, could be generally purchased locally. Usually small quantities of gaskets ere die cut. If larger quantities are needed, tools are made of the same type used to cut other elastomers. Where the gasket is extruded for fitting into a machined groove or between gasket stops, Dow Corning advises use of a scarved joint. This joint is then cemented using Dow Coming's Silastic 140 (clear) or their RTV 731 (white) materials, which air cure. Dow Corning points out that the local "rubber" fabricators purchase the Silastic 50 in billet form. This is worked on a roll mill in preparation for sheeting or extrusion. Then to obtain the desired physical properties the fabricator must oven cure the Silastic 60 for 24 hours at 480F. SPECIFICATIONS* ASTM D676 ASTM D412 ASTM D412 ASTM D395 Color Specific Gravity at 77F Hardness, Shore A. Scale Tensile Strength, psi, min Elongation, percent, min Compression Set after 22 hrs at 300F, percent, max White 1.20+0.02 45 to 60 800 250 30 *AN physical properties measured on 0.075 inch thick samples molded 5 minutes at 240C,F, and oven cured 24 hours at 480F. APPENDIX K____________________________________________________________________________________ Caution Label CThe following or equivalent caution statements should be fixed on all containers of transformer askarels and the transformers themselves: This product contains Polychlorinated Biphenyls (PCBs). Care should be taken to prevent entry into the environment through spills, leakage, use, vaporization, or disposal of liquid or containers. Avoid prolonged breathing of vapors or mists. Avoid contact with eyes or prolonged contact with skin. If skin contact occurs, remove by washing with soap and water. Following eye contact, flush with water. In case of spillage onto clothing, the clothing should be removed as soon as practical, skin washed, and clothing laundered. Monsanto MONSANTO INDUSTRIAL CHEMICALS COMPANY SPECIALTY PRODUCTS GROUP 800 N. LINDBERGH BLVD. ST. LOUIS, MISSOURI 63166 The information herein regarding obtaining optimum results from askarel fluids in your transformer has been accumulated by Monsanto for over 40 years from the experience of makers and users of askarel transformers and it is believed will be helpful. Nothing herein shall be construed as applying to other than askarel insulation. Data and maintenance suggestions herein do not apply to the other components of the transformer. All operating and maintenance suggestions recommended by the manufac |turer of the transformer should also be carefully followed. ^Because these maintenance directions apply only to the askarel Insulation, Monsanto disclaims any liability for damage to property or injury to persons arising from transformer operation. 0b09t>X8 TOWOLDMON00348QO U SCUSTOMER SERVICE CENTERS AKRON, OHIO 44319 -' 260 Springtide Drive Montrose Oenloprmnt Park ft/. 1275/55547 7 7 i-' . ATLANTA, GEORGIA 30339 ' 320 Interstate North Parkway Suit* 600 ft?. 7404/ 454 4949 , . BOSTON, MASSACHUSETTS 02149 Everett Stttion TN. {6W 367*010 wci/sro/v, tfxas 22022 750/SosrOaA Tower 5057 IVasfha/mar Aaatf Tel. (713} 621-9560 tOS ANGEL E$. CAL IFORNIA 7407 Dova Stoaat Newport Beech, California 92660 Tat. (714) 6339160 A/ftV YORK, NEW YORK 10036 77774Aranyao/fft#Anr/oai Taf. (212) 764*000 52. LOI//S, MISSOURI 63106 BOON. Lindbergh Blvd. TV. tf W 694 1000 SAN FRANCISCO BAY AREA 27iOLefeytta Santa C/ara, California 95052 ft/. f40 2430414 WILMINGTON. DELAWARE 19810 Su/fe 204, Bancroft Bldg. , 3411 Silvertide Road ft/, 7502/ 478-4600 INTERNATIONAL OFFICES ARGENTINA Montanto Argentina S.A.I.C. Avda Madero 1020, Floort 17th 6 18th Buenos Aires, Argentine AlttlTMLM Montanto Australia Limited East Tower, Princes Gate Bldg. ` 151 Flinders Street Melbourne, Victoria 3001 AustraMa ' Monsanto Auttralla Limited 35 Tarry $fraaf Roselle, Sydney, NSW Ai/irr#//* 2019 Monsanto Australia Limited Aort CW/c* 9ox 1111K, Adelaida Sooth Ac/ftr*//# 5017 A#c*nM^ro Aosfra//a Limited 0r/s6ana A O. Sox 55, Hamilton Central Queensland, Auttralla 4007 Monsanto Ai/stra/Z* Limited Perth A O. Sox 22 Doubleview - IVasf Austro//# 5079 A(/S777A Monsanto G/nh/ZAuftr/a Rudolfsplatt 12 A-IOIOWIen 1, Austria . BELGIUM Monsanto furcpaStA. 7, A/m* Madou 7050 Brussels, Belgium ' Monsanto ft/ropa A/VA . 755 Macho/sasfeantraj , . ' 2000 Antwerp, Belgium . BRAZIL Industrial Monsanto Ltd*. Aua Arao/o 275, 6Ander 540 Awfe, 5nar// 07220 r. < CAVAftA 1..1 MonM/im CWjkJo Ltd. : TTSRexdateBied. ' Aaxtfa/a, Ontario, Canada ' f Monsanto C4na<7a Lr<7. '' 100 Park Royafe, Suite 701 *ft#rttinooutwr,5.C.,Canada . CW/L5 . Monsanto ChWa Comarc/a/a Industrial Lknltada Edifklo Espena Ofklna 602 Celle Estedo 337 Sanf/a^ji/aC/jfla . COLOMBIA Monsanto Cotomblana Inc. Carrara 74, Wo 22 59 Bogota, Colombia _ DENMARK Monsanto A/S 5 ffysanstoan^atfa D/C 7554 Ccpan/upari Danmark ; EL SALVADOR Monsanto Centroamerlca (ElSalvador) S.A Edifklo Platt 52Aron/</0 5i/ryC4/fo*Ssnfe ftc/a San Salvador, El Salvador FINLAND Monsen to (Scandinavia) AB Arkadiankatu BC 20 00100Helsinki 10. Finland ' FRANCE Socfete Montanto SA. 9 rue d'Argenaon 75 Paris (8) Franca . ,. GUATEMALA Monsanto Guatemala Inc. Edifklo Casa 7a Avenkda 7-11 Zona 9 Guatemala City, Guatemala HONG KONG Monsanto Far East Ltd. Management House, 2nd Floor 26 Canal Road Watt Hong Kong, B.C.C. INDIA Mlndia Chemicals Ltd. Monsanto Chemical of India Pvt. Ltd. (Ag Products) Wakefield Houee 11 Sprott Rd., Ballard Estate Bombay 400 001. India Mindia Chemicals Ltd. 19 Rajendranath Mukherjee Rd. Calcutta 700 001. India Mindia Chemicals Ltd. Monsanto Chemicals of India. Pvt. Ltd. (Ag Productsf 570-57 7 Llnghl Chatty Street Madras 600 001, Indie Mindia Chemicals Ltd. 3/8 Asaf AH Road New Delhi 110 001, India INDONESIA A. T. Monsanto Pan Electronics 191 DJ. Dr Saherdjo Jakarta, Indonesia . ITALY Montanto Itatlane S.p.A. Via Melchlorra Gloia 8 . Milano 20124, Italy JAPAN Monsanto Japan Ltd. Room 217, Shin KokusaiBldg., 4-I.MarunouchlS-choma Chiyoda-ku, Tokyo, Japan ' ' MALAYSIA Monsanto Far East Ltd. . (Malaysia Branch) \ 116,JalanSemangat . Petallng Jaya, Selangor, Malaysia MEXICO Montanto ComercletS.A da C.V. Thkn No. 248 Mexico 8, D.Fu Mexico NETHERLANDS Monsanto B.V. . Jan ran Nasseustraat 83*6 Dan Hate 77>a Netherlands, Holland NEW ZEALAND Monsanto New Zealand Ltd. 19 Great South Road Remuera Auckland 6, New Zealand NICARAGUA Monsanto (Nicaragua) S.A A O. Box 288 Managua. Nicaragua NORWAY Monsanto Norge A.S. Fred Olsentgate 11 Oslo 1, Norway PHILIPPINES Monsanto Philippines Inc. Suite 1101 Security Bank 8 Trust 6788 Ayala Ava. Makati RitaID-706, Philippines PUERTO RICO Montanto Puerto Rko Company Munoz Rivera Ava. Borniquan St. Rio Piedras, Puerto Rico SINGAPORE Monsanto Singapore Company (Pta.) Ltd. Suite 706 Cathay Bldg., 2th Floor Mount Sophia, Singapore 9 SOUTH AFRICA Monsanto South Africa (Pty.) Ltd. 11th Floor, Sandton City Bldg. Sandton, Transvaal, South Africa SFA1N Monsanto Iborko SA. Lapanto 350* Barcelona 13. Spain SWEDEN Monsanto (Scandinavia) AB Utvsundavagen 106 Bromma, Sweden SWITZERLAND Montanto (Suisse) SA Tiafenhofa 10, CH8022 Zurich, Switzerland TAIWAN Montanto Far East Ltd. - (Taiwan Branch) 36 Chang An East Road, 6th Floor Section t, Taipei Taiwan THAILAND Montanto Thailand Ltd. 6th Floor, Kasamki) Bldg. 120Siiom Road Bangkok, Thailand UNITED KINGDOM Monsanto Ltd. 70-79 Vktorla Street Monsanto House London SWIH ONQ England - VENEZUELA Monsanto (Venezuela) CA Torre Phelps A/so 24 Plaza Venezuela Caracas 101, Venezuela WEST GERMANY Monsanto (Deutschland) GmbH /mmarmannsfrassa 3 0-4000 Dusseldorf, West Germany .4 / i *1; | 'a. K Monsanto0 Montanto Industrial Chamicali Oo. / A Unit of Montanto Company / 800 N. iJndbrdh Blvd., St. Louis, Mo- 63166 . ,, 0^/09^19 * Utho I* U.S.A. TOWOLDMONOQ34801