Document 06Y88qMQ4vXG16Bm8Rzqvakwm

fig w u rv flle M a te r friP o a a s ANALYTICAL REPORT PFOA/PFOS A nalysis Lot#: D7L140421 Nicki Smith Q C L a b o ra to rie s , In c . 1205 Industrial Highway Southampton, PA 18966 TestAmerica Denver G ailD eR u Project M anager January 7, 2008 4955Yarrow Street Arvada, CO 80002 tel303.736.0100 fax303.431.7171 www.te5tamericainc.com DEP2-SDWB-000460 Case Narrative D7L140421 TestAmerica Denver utilizes USEPA approved methods in all analytical work. The samples presented in this report were analyzed for the parameters listed on the methods summary page in accordance with the methods indicated. Dilution factors and footnotes are provided on each datasheet to assist in the interpretation of the results. The results relate only to the samples in tnis report and m eet all requirements of NELAC. All data have been reviewed for compliance with the laboratory QA/QC plan and have found to be compliant with laboratory protocols with any exceptions noted below. Please note that Non-Detect (N D ) results have been evaluated down to die Method Detection Limit (MOL) and should be considered ND at the MDL. Unless otherwise noted, results for solids have been dry weight corrected. This report shall not be reproduced except in full, without the written approval of the laboratory. Sam ple A rrival and Receipt The following report contains the analytical results for three samples received 12/14/07, according to documented sample acceptance procedures. The samples w ere received in good condition at a temperature of 1.2C. No anomalies were encountered during sample receipt. Standards Analytical standards were prepared using the add form of the compound perfluorooctanoic acid (PFOA). PFOS is a commercial prepared and certified solution. Perfiuoro-n-[1,2,3,4-13C4]octanoic acid was introduced at the extraction step and was used as an internal standard for quantitation of PFOA. PerfIuoro-1-[1,2,3,4-13C4]octanatesulfonate was introduced at the extraction step and was used as an internal standard for quantitation of PFOS. Sam ple Extraction and Analysis The sample presented in this report was analyzed for the target analyte by TestAmerica Denver's SOP DEN-LC-0012A. For water samples a 250 mL aliquot of each sample is acidified with 1 mL o f 6N HCI solution and it is extracted using solid phase extraction technique with methanol conditioned C18 cartridges. Each sample is spiked with the internal standard, prior to extraction. After the sample is passed through the cartridge, the analytes are eluted with 4 mL of methanol. The final volume is brought to 5 mL using methanol and the extract is analyzed by LC/M S/M S. Method QC Sam ples The Method Blank is processed reagent water spiked with surrogate and prepared with each batch of 20 samples of the same matrix. The method blank was non-detect at the reporting limit in both batches. Each batch Is prepared with a Laboratory Control Sample (LCS). The recoveries of two concentration levels of Laboratory Control Samples were within control limits for both batches. DEP2-SDWB-000461 Analytical Com m ents The method required M S/M SD could not be performed for QC batch 7353153, due to insufficient sample volume submitted. The acceptable LCS analyte recoveries for two levels provide evidence that the laboratory is peTorming the method within acceptable guidelines. No other anomalies were observed. DEP2-SDWB-000462 EXECUTIVE SUMMARY - Detection Highlights D7L140421 PARAMETER L2517314-2 12/12/07 09:30 002 PFOA L2517314-3 12/12/07 10:00 003 PFOA RESULT REPORTING LIMIT UNITS ANALYTICAL METHOD 0.0058 J 0.010 ug/L DEN -LC-0012 0.0069 J 0.010 ug/L DEN -LC-0012 DEP2-SDWB-000463 METHODS SUMMARY D7L140421 PARAMETER ANALYTICAL METHOD LC/MS/MS, PFOA DEN -LC-0012 References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. PREPARATION METHOD DEP2-SDWB-000464 METHOD / ANALYST SUMMARY D7L140421 ANALYTICAL METHOD________________________ ANALYST_______________________ DEN -LC-0012 Jaqueline Bonnett References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. ANALYST ID_____ 003601 DEP2-SDWB-000465 SAMPLE SUMMARY D 7L 140421 wo # SAMPLE# CLIENT SAMPLE ID KD8MK 001 L2517314-1 KD8ML 002 L2517314-2 KD8MM 003 L2517314-3 NOTE (S) : - The analytical results of the samples listed above are presented od the following pages. - All calculations are performed before rounding to avoid round-off errors in calculated results. - Results noted as bND* were not detected at or above die stated limit. - This report must not be reproduced, except in lull, without the written approval of the laboratory. - Results for the following parameters are never reported on a dry weight basis: color, corrosivity, deitsty, flashpoint, igniability, layers, odor, paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight. SAMPLED SAMP DATE TIME 12/12/07 09:00 12/12/07 09:30 12/12/Q7 Oh* O O DEP2-SDWB-000466 QC Laboratories Client Sample ID: L2517314-1 1DPLC Lot-Sample #...: D7L140421-001 Work Order #...: KD8MK1AA Date Sampled...: 12/12/07 09:00 Date Received..: 12/14/07 Prep Date..... : 12/19/07 Analysis Date..: 12/21/07 Prep Batch #...: 7353153 Analysis Time..: 21:10 Dilution Factor: 1 Method........ : DEN -LC-0012 Matrix PARAMETER_____________________ RESULT_________ PFOA ND PFOS ND REPORTING LIMIT UNITS 0.010 ug/L 0.010 ug/L SURROGATE_____________________ 13C4 PFOA 13C4 PFOS PERCENT RECOVERY_______ 78 57 RECOVERY LIMITS (50 - 200) (50 - 200) : WATER DEP2-SDWB-000467 QC Laboratories Client Sample ID: L2517314-2 EPIC Lot-Sample # __ : D7L140421-002 Work Order # __ : KD8ML1AA Date Sanpled...: 12/12/07 09:30 Date Received..: 12/14/07 Prep Date..... : 12/19/07 Analysis Date..: 12/21/07 Prep Batch #...: 7353153 Analysis Time..: 21:42 Dilution Factor: 1 Method........ : DEN -LC-0012 Matrix.... ....: WATER PARAMETER PFOA PFOS RESULT 0.0058 J ND REPORTING LIMIT 0.010 0.010 UNITS ug/L ug/L SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 84 65 RECOVERY LIMITS (50 - 200) (50 - 200) NOTE (S) :_____________ i Estimateli remit. Result is less than RL. DEP2-SDWB-000468 QC Laboratories Client Sample ID: L2517314-3 HPLC Lot-Sample #...: D7L140421-003 Work Order # __ : KD8MM1AA Date Sampled-- : 12/12/07 10:00 Date Received-.: 12/14/07 Prep Date..... : 12/19/07 Analysis Date..: 12/21/07 Prep Batch #...: 7353153 Analysis Time..: 21:59 Dilution Factor: 1 Method... DEN -LC-0012 Matrix. PARAMETER PFOA PFOS RESULT 0.0069 J REPORTING LIMIT 0.010 0.010 UNITS ug/L ug/L SURROGATE 13C4 PFOR 13C4 PFOS PERCENT RECOVERY 81 57 RECOVERY LIMITS (50 2 0 0 ) (50 2 0 0 ) HOTE(S) :_____________ J E stasiai result. Result is less than RL. : WATER DEP2-SDWB-000469 QC DATA ASSOCIATION SUMMARY D7L140421 Sample Preparation and Analysis Control Numbers SAMPLE# 001 002 003 MATRIX WATER WATER WATER ANALYTICAL METHOD DEN -LC-0012 DEN -LC-0012 DEN -LC-0012 LEACH BATCH # PREP BATCH ft 73S3153 7353153 7353153 DEP2-SDWB-000470 METHOD BLANK REPORT HELC Client Lot #...: D7L140421 MB Lot-Sample #t R7L190000-153 Analysis D a t e : 12/21/07 Dilution Factor: 1 Work Order : KEE591AA Prep Date- 12/19/07 Prep Batch #...: 7353153 Matrix........ : WATER Analysis Time.-: 20:06 PARAMETER EFOA PFOS RESULT ND ND REPORTING LIMIT UNITS 0.010 ug/L 0.010 ug/L METHOD______ DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 83 62 RECOVERY LIMITS (SO - 200) (50 - 200) ROTE (S) :__________________________________ __ Calculations are performed before rounding to avoid round-off errors in calculated results. DEP2-SDWB-000471 LABORATORY CONTROL SAMPLE EVALUATION REPORT HPLC Client Lot # -- : D7L140421 Work Order #...; KEE591AC LCS Lot-Sample#; R7L190000-153 Prep Bate..... : 12/19/07 Analysis Date..: 12/21/07 Prep Batch # -- ; 7353153 Analysis Time..: 20:22 Dilution. Factor: 1 Matrix.... PARAMETER PFOA PFOS PERCENT RECOVERY 94 98 RECOVERY LIMITS (70 - 130) (39 - 120) METHOD DEN -LC-- 00X2 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 85 69 RECOVERY LIMITS (50 - 200) (50 - 200) NOTE (S) i____________________________________ Calculations are performed before rounding to avoid round-offerrors In calculated results. Bold print denotes oontFol parameters . : WATER DEP2-SDWB-000472 LABORATORY CONTROL SAMPLE DATA REPORT HPLC Client lot # -- : D7L140421 Work Order : KEE591AC LCS Lot-Sample#: R7L190000-153 Prep Date..... : 12/19/07 Analysis Date..: 12/21/07 Prep Batch. #. ..: 7353153 Analysis Time..: 20:22 Dilution Factor: 1 Matrix....... PARAMETER PFOA PFOS SPIKE AMOUNT 0.200 0.200 MEASURED AMOUNT 0.189 0.196 UNITS ug/L ug/L PERCENT RECOVERY 94 98 METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 85 69 RECOVERY LIMITS (50 - 200) (50 - 200) NOTE(S) t____________________________________ Calculations are performed before rounding to avoid round-offerrors in calculated results. Bold print denotes control parameters DEP2-SDWB-000473 LABORATORY CONTROL SAMPLE EVALUATION REPORT HPLC Client Lot #...: D7L140421 Work Order # __ : KEE591AD LCS Lot-Sample#: R7L190000-153 Prep Date..... : 12/19/07 Analysis Date..: 12/21/07 Prep Batch 7353153 Analysis Time..: 20:38 Dilution Factor: 1 Matrix:.... PARAMETER PFOA PFOS PERCENT RECOVERY 92 93 RECOVERY LIMITS (70 - 130} (39 - 120) METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 84 68 RECOVERY LIMITS (50 - 200) (50 - 200) NOTE(S) :____________________________________ Calculations arc performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters : WATER DEP2-SDWB-000474 LABORATORY CONTROL SAMPLE DATA REPORT HPLC Client Lot D7L140421 Work Order : KEE591AD LCS Lot-Sample#: R7L190000-153 Prep Date-..... : 12/19/07 Analysis Date..: 12/21/07 Prep Batch 7353153 Analysis Time.- : 20:38 Dilution Factor: 1 Matrix....... .: WATER PARAMETER PFQA PFOS SPIKE AMOUNT 0.0200 0.0200 MEASURED AMOUNT 0.0185 0.0186 UNITS ug/L ug/L PERCENT RECOVERY 92 93 METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 84 58 RECOVERY LIMITS {50 - 200) {50 - 200) NOTE(S) :_______________ _____________________ Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters DEP2-SDWB-000475 D EP 2-SD W B -000476 O QCLaboratories CHAIN OF CUSTODY 1205 Industrial Blvd. Southampton, PA 181996666--00514 PFhaox:ne. 221155--335555--73253010 Bill to/Report to; (Hdifferent) Cllent/Acct. No. &cMJrf\tdhCt^ Address jm a ^ Sampling Sile Address: (If different City/State/ZIp Phona/Fax Client Contact PROJECT F IE L D ID P.O. No. XS8CeO QC Contact Collection MiriaryTime Number of Containers Matrix 0338 rubi -a -* r ii f L MS- M '----'-----------------f--t---- n -- . LabLIM S No: to i _______________ _________________ M ATRIX CO DES LAB US ONLY: # ^ 2 ^ Ascprblcmci Vfals # ___HCI Vials .NfijiSnOg , '# L Na OH/Zn acetate oH # HNO, pH DW: DRINKING WATER GW: GROUND WATER . WW: WASTEWATER SO: SOIL SL: SLUDGE # :';vfesbeoH : .-.:rvfNsOH-dH'.--- ; # l_ L _ 'nprs'snred ` . Hl.pH: ... :Temb control ' ID# M ANA LYSIS.R EQ U ESTED OIL: OIL SOL: NON SOIL SOLID, Ml: MISCELLANEOUS X: OTHER Reid pH Tamp (C or F), DO, CI& S. Cond. etc. ir cc <Z EC 1 S A M P L E D B Y : (N a m e /C o m p a n y ) t_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 1_ _ _ _ _ _ _ J _ _ _ _ _ _ _ _ _ 1 i l i < i i i . r i i i i_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ V e r b a l/f a x d a t a d u a : 1 R e p o rt F o rm a t S ta n d a rd F o rm a I H a rd c o D V d u e : / / S ta n d a rd + Q C Q N J R e d u c e d O D is k s ta r- Plddso califorpricingandavatfabttyon rush (<14-21day)lomaroundandonallbui standardformai. F ie ld P a r a m e te r s A n a ly z e d B y : j D a t*u rn m & : rraR1/ fIcTA i ffln ." " W s a j ^ p TSwk-SAMPLE CUSTODY EXCHANGES MUST BE DOCUMENTED BELOW. USE FULL LEGAL SIGNATURE, DATE AND MILITARY.TIME (24 HOUR-CLOCK,. I.E. 8AM IS 08QQ.4 PWI IS 1600) R E L IN Q U IS H E D S fA S A M P L E R DA TE j ______ / ) ______ ____ / T IM E j ...... 1 F R E L IN Q U IS H E D B Y Ay DA TE T IM E I R E C E IV E D B Y 11 R E C E iv p ^ r y f _c _ _ _ _ f-- DA TE DA TE O&DBXT I M E D E U y e n r M E J M D : Q Q C C O U R IE R 0C L IE N T Cuatodjr Seal Number S 5p 3 O THER______________ T IM E COMMENTS: . . / " (i j. . / T IM E R E U N Q U IS H E D B Y lJ DA TE T IM E R E C E i v r o | iy M 3 ^ D A T E T IM E 4^ t.R E L > I N- Q U I S H E D B Y 5 D A T E T IM E R E C E IV E D B Y S D A T E T IM E Hazardous: yes/no For example to aid completion, see reverse aide. T JACK LYNCH PENNSVILLE HATER DEPARTMENT 2 SANDERLIN ROAD PENNSVILLE, NJ 08070 Regarding: JACK LYNCH PENNSVILLE HATER DEPARTMENT TUFTS ROAD PENNSVILLE, NJ 08070 Account No: AP0223, PENNSVILLE HATER DEPARTMENT Project No: AP0223, PENNSVILLE WATER DEPARTMENT Sample Number L2517314-1 Sample Description TP005010 TUFT RD POE Received Temp: 38 F Iced (Y/N): Y Parameter PFQA Method Sample Number L2517314-2 Sample Description TP003003 WATER ST POE Received Temp: 38 F Iced (Y/N): Y Parameter PFOA Method Result ATTACHED Result ATTACHED P.O. No: Voucher PWSID No: 1708001 Samp. Date/Time/Temp 12/12/07 09:00am NA F Inv. No: 940417 Sampled by Customer Sampled RLs Test Date, Time, Analyst Samp. Date/Time/Temp 12/12/07 09:30am NA F Sampled by Customer Sampled RLs Test Date, Time, Analyst - A result of "ND" indicates the concentration of the analyte tested was either not detected or below the RLs. - Definitions: ND=not detected; NEG=negative; POS=positive; COL=co]onies; RLs=laboratory reporting limits; 17A=laboratory accident; TNTC=too numerous to count - A result marked with "DRY" indicates that the result was calculated and reported on a dry weight basis. - All analysis, except field tests are conducted in Southampton, PA unless otherwise identified. - The test"pH lab"is analyzed upon receipt at the laboratory, the result will not be suitable for regulatory purposes. - Actual times of analysis for parameters reported <24 hrs are available upon request. All testing is completed within the required holding time unless otherwise noted.. - QC NELAP ID's:PA 09-00131,NJ PA166.FL E87954.NY 11223,CT PH-0768,DE PA-018.KY 90228,MD 206,EPA PA00018.Bioassay:PA 09-03574,NJ PA034 FL E87953 KS E10373 SC 89020001 - QC STATE ID'S-Hind Gap.NJ PA001.PA 48-01334;E RUTHERFORD NJ02015;Vineland NJ06005; Reading PA 06-03543. - All samples are collected as "grab" samples unless otherwise identified. - MCL= is the EPA recommended "maximum contaminant level" for a parameter. PLs=custaner specific permit limits. Regulatory authorities are assessing substantial fines for testing omissions. Please track your sample collections and results on a weekly, monthly, or quarterly basis to ensure compliance. QC's internet program 'LIVE ACCESS' will provide you with real-time access to collection dates and results. Please contact Customer Service for further information on acquiring LIVE ACCESS. Page l of 2 Serial Number: 924903 T h o m a s J. H in e s, P re s id e n t 1205 Industriai BlvdP.O. Box514, Southampton, PA I8966-C514 Phone: 235-355-3900Fax: 215-355-7231 www.qclaboratories.com DEP2-SDWB-000477 QC Laboratories Analytical Report Account No: AP0Z23, PENNSVILLE WATER DEPARTMENT P.0. No: Voucher Inv. No: 940417 Project NO: AP0223, PENNSVILLE WATER DEPARTMENT_____________________________ PWSID NO: 1708001_______________________________ Sample Number L2517314-3 Sample Description TP004006 HERON AVE POE Received Temp: 38 F Iced (Y/N): Y Samp. Date/Time/Temp 12/12/07 10:00am NA F Sampled by Customer Sanpled Parameter PFOA Method Result ATTACHED RLs Test Date, Time, Analyst - A result of "ND" indicates the concentration of the analyte tested was either not detected or below the RLs. - Definitions: ND=not detected; NEG=negative; PQS=positive; COL=-colonies; RLs=laboratory reporting limits; L/A=laboratory accident; TNfC=too numerous to count - A result Barked with "DRY" indicates that the result was calculated and reported on a dry weight basis. - All analysis, except field tests are conducted in Southampton, PA unless otherwise identified. - The tesr'pH lab"is analyzed upon receipt at the laboratory, the result will not be suitable for regulatory purposes. - Actual times of analysis for parameters reported <24 hrs are available upon request. All testing is completed within the required holding time unless otherwise noted.. - QC NEtAP ID'S:PA 09-00131,NJ PA166,FL E87954.NY 11223,CT PH-0768,DE PA-018,KY 90228,MD 206,EPA PA00018.Bioassay:PA 09-03574,NJ PA034 FL E87953 KS E10373 SC 89020001 - QC STATE ID'sIwind Gap.NJ PA001.PA 48-01334;E RUTHERFORD NJ02015;Vineland NJ06005; Reading PA 06-03543. - All samples are collected as "grab" samples unless otherwise identified. - MCL= is the EPA recommended "maximum contaminant level" for a parameter. PLs=customer specific permit limits. Regulatory authorities are assessing substantial fines for testing omissions. Please track your sample collections and results on a weekly, monthly, or quarterly basis to ensure compliance. QC's Internet program 'LIVE ACCESS' will provide you with real-time access to collection dates and results. Please contact Customer Service for further information on acquiring LIVE ACCESS. Page 2 of 2 Serial Number: 924903 T ho m as J. H in e s, P re s id e n t DEP2-SDWB-000478 D EP 2-SD W B -000479 ^ QCLaboratories' 1205 Industrial Blvd. Phone: 215-355-3900 Southampton, PA 18966-0514 Pax: 215-355-7231 CHAIN OF CUSTODY /P aae of Bill tofReport to: (if different} Cllent/Acct. No. Address s u u h q W < lk < '*? V V t 'Q . ' / (*1'* fVj Sampiinq Site Address; (1 different) AS$C lty /S tate /Z ip f e . 4 W > ls < iLe - ' P h o n e /F a x C C ) L u j t y (s>^ C lie n t C o n ta c t -- " LFIELD ID T u f't ?*> . 6UHe/* $ 1 -- f t e 'Q * P.O. No. Q C Contact i ! iDate MilitaryTime \ jJ M P Coda 1 Total; 1^!>1n1i1fisi,_>sHmnT1i: 1> O u J J _ x IT -o---H-----s--l----S--3- ;--" 1 L j 1 :j 1P faP r P fir MATRIX CODES DW DRINKING WATER GW: GROUND WATER W W WASTEWATER SO: SOIL SL: SLUDGE OIL: OIL SOL NON SOIL SOLID, M l: MISCELLANEOUS X: OTHER OO.C2.S. ~ ~jr---f-^----(-W- r ---- il-r . ----------------- S A M P LED BY: (Nam e/Com pany) Verbalrtax data due; Hardcopy due; / lo D Y& A , 1 _ P / / T 1 Li Report Form al; P Standard O Forma Standard + Q C NJ Reduced Disk /9 - Sig: Field Parameters Analyzed By: Please call for pricing and availability on rush (<14-21 day) turnaround and on all but standard format. SAMPLE CUSTODY EXCHANGES MUST BE DOCUMENTED BELOW. USF. L-ULL LEGAL SIGNATURE, DATE AND MILITARY TIM E (24 HOUR CLOCK, I.E. 8AM IS 0800,4 PMIS 1BOO)