Document 06Drb2q4zzLMar8MOBNnb25MR

n. *49- l WWJ INTERMAL CORRESPONDENCE CHEMICALS and plastics t.v r i)**r>*-c uOf * ri * 'v. f. L. Johnson 'uildirp ro. "Cxas cm pla::t m. o, max rmxA% city. rti July 26. 1076 <,,. r r. Fis^ur V, c-a.'t; y**-. F. 'jcrti.n-.S 'r. n. V. heeVr - F1A SWCT Frani-: j 't /our request, spot samples of ^SAI.--7 more obtained froi" the Vo. l r^nnino f\\'v sir! amlyzed 'or residual ''Cl*. |A comparison with the 'rioin'l ! in analysis (taien from top of linlafter Mending-) is as ''f* ] ? ci' !',: r; 31 end l!o. 3a te Tine m-- Bag n-T^S r7 -'1f3 1 A#*.I 7*20 7-21 7-22 7-23 3:0n n.n. 1:00 p.r. 1A:0P a.n. 10:0^ a. m. 3 i? n i 10 3 <1 ::n -f. iif or to indicate a trerd of a sliohf reduction in residual 1" rccjry'ric a resin is transferrin from storage bin into haooino o'-.r. 'Ms observation is not unexpected, riev.f let *"e know If additional information is desired. ucc 055082 ANALYSIS OF Vvr.! SAMPLES CCTAINED FRflM PUILDINO U'O ORYERS rr r* * r r * * fate c-:3 .0-7 : '' ` -.r Z Spit " `t * * * b r. . A-30 ' * *I 7/ * */ Time 10:00 ajm. VCM. oom 2293 810 15 1C:00 a.m. 1829 868 23 ' C: 00 a..f. ! : '0:00 a.ri. 3206 228 46 341F *e <Ue: for Total Sol ids.C'lk? SamP,es Adjusted UCC 055085 J'* RF5IDUAL VCM ANALYS15 TEXAS CITY VINYL RCrflS PRODUCTION JUNE, 1C 7)6 Authors: R. *1. Arnold L, D. Morgan : / <!. F. C-unervisor: </ T. F, Tacouard Dote: July 2, 1976 Attached in Table I is a surmary of the residual VCM levels in suspension vinyl resin products produced during the ronth of June. The residual VCM level in QSAlf-7 and QSAL-7 product!)n showed a slight decrease from the May production* A dramatic decrease in residual VCM levels was observed in 1$nF-7 production from the last production run (June, 1075) A decrease in blend analysis from 600 ppm to 60 ppm was observed. VSKK-10 and v<UE-n showed no obvious chance in residual VCM levels from recent production runs. Tables JI-XII summarize individual bin and blend data from suspension vinyl resin production during the month. Also shown in Tables XIII and XIV are residual VCM levels in non-solvent and solvent production, respectively. f*ne ITHI bin, one VYUD bin and one VYNS bin were tlended to achieve < 1 ppm VCM. /kw Attachment RESINS LABORATORIES UNION CARBIDE CORPORATION CHEMICALS AND PLASTICS DIVISION TEXAS CITT PLANT UCC 055086 TACLf r,.!**,^Rv OF VCM ANALYSIS OF A'^rENFLCf! VlftYL JU-'E* 1 f T*tf Q t Rosin Type "CAL-7 o?a:i*7 QSAM-7 QSQF-7 V5KK-10 V50E-1C VC*\ ppr Bin Blend 73 - 1 20 21 106 008 648 603 375 S PI ends < 10 pr*n VCM < 1 pom VCM ! 7 36 88 ! 15 26 - -* - j- ucc 055087 3E5iOl'M. YCM C^MTFriT OF n-;A|L-7 BLTND SA'TIF*1 Jl'NE, 1976 riffid lijrter ftOJ or r r,7 ^09 flO^ 005 90f. ofty OCfl onf) iooo mi 1002 1003 1004 1005 1006 1007 i 'os 1009 1010 ion 1012 1013 1014 1015 1016 1017 1018 1019 VC*11 pfW fl *> O 5 2 2 16 4 2 *1 2 *1 2 1 <1 <1 <1 2 : 1 <1 . 1 3 2 /* 13 1 3 <1 1 2 1 2 2 9 lend Number 1020 1021 1022 1023 102 1025 1026 1027 1028 102? 1030 1031 1032 ; 1033 1034 1035 1036 1037 1038 1039 1040 1041 1042 1043 1044 1045 1046 1047 1048 1057 lose 1059 4 VC 14 23l i V1 <1 1 * <1 1 2 1 3 <' 1 <1 ** 1 7 3 1 1 3 3 4 n 3 < 1o <1 v ucc 055088 TABLE I I re?'dual VC" cnrun of n^n-z blcmo sArPLFr junc. 19 6 T1 enc* Uunber 6099 600 6n01 6902 C903 CpOd 6905 6n06 6907 6908 69no 6910 6911 6912 6913 6914 6915 ___ enie 6917 6918 6919 6920 6921 6^22 6923 C924 6n25 6926 6927 VC", ppm. 11 5 2 1 1 1 1 <1 3 8 5 4 3 10 1 5 2 1 1 *1 2 6 1 3 19 4 ucc *-t - 055069 T*r.LE IV RFf!OU.,'L VCV CONTENT OF P!-4h-7 FIEND SAMPLES JUNE, 1976 Cl end `lumber 1838 1831 1832 1833 1834 1835 1836 1837 1838 1839 1840 1841 1842 18/13 1844 1845 1846 1847 1848 1840 1850 VCf1, ppn 3 34 45 21 39 7 7 24 20 20 36 34 22 13 146 22 n 23 17 10 ucc 055090 TACLf HC'l.'H'AI. VCM COMTCNT OF 0:QF r.LEf'O SAMPLE? ju:ie, 19/6 pi end 'lunl-er 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 VCM, ppn 34 44 44 22 25 41 66 125 83 63 45 OQ 164 62 50 ucc 055091 TADLF V' r.rr.iw.u vcm cwtfht of vm;k-io ntno SArin.r? JIINF, 1076 PI end Number 1063 1064 1066 1068 VCM, ppm 410 029 774 478 t V}CC TAPLE VII rurstruAL vc" content of vsjc-io clemd sampled JUNE, 1076 ,ii NurOcr p,o? 3Q3 895 aof 8n7 3 or, *nn non 901 002 903 on/* n05 0H6 9 07 or\0 0 <vp T* 9)2 C13 015 016 017 '.'CM, ppn 104 93 125 362 180 451 438 234 423 304 37 25 6G8 311 234 182 254 571 722 1012 256 394 1 8 243 226 Cl end Nurher 918 - pio 920 0?1 022 923 924 25 926 927 928 929 930 931 932 933 934 935 936 937 938 939 940 941 VCM, ne 732 3n2 224 454 463 610 n/to 518 798 332 67 022 285 546 327 541 237 ?7n i?i 351 485 OS 65 164 ucc 055093 Gin 60S 415 606 412 r.ni 603 604 405 406 411 408 400 502 607 402 414 ~ 412 ( 606 115 405 406 604 411 40 607 604 408 602 606 609 414 605 602 On te r-i ii n m M 6-2 M n ii M 6-3 ii M it ii u f-4 II II II II II 6-5 H II e-r m ii ii ii ii ii ii T40LE VIII 3EST0UAL vcr1 CnriTEriT OF rSAL-7 PIN 5/V1PLEF vUINC, 1076 VCM, ppm Pin 0<ite VCM, ppm Gin 8 27 a L. 71 403 405 402 6n -7 M 008 ii -1 16 <1 2 f.ni 405 60S /ipn 1? <1 IP e 4 06 6-8 3 604 604 M 3 414 600 II 2 40 408 II 31 *06 5 p 400 II 602 II 23 411 10 41* 4 0 *1 f in 607 F.nf 411 405 414 6-9 II ll ll II 604 II 2 1 12 <1 <1 1 415 *11 *12 408 400 403 7 t 608 6-10 403 601 H II 5 8 3 414 401 406 -i i. 607 II 602 6-11 1 411 3 4*>8 . i <i -i 606 608 ll ll 406 II 4 412 3 *06 2 a no ,* 605 ll - 1 *14 t 604 6-12 2 412 50 606 ii < 1 602 * 1 *06 ii 1 603 <1 4 <1 1 o 414 6-13 4 602 II <1 403 II <1 411 II 2 609 II 2 606 607 60* 60Q 608 Date 6-14 6-15 6-16 6-1 7 6-18 6-1 6-20 H 6-21 II 6-22 6-23 il 6-24 it 6-25 6-26 6-27 6-28 6-2o 6-30 VC*\ ? i <1 4 l '1 '1 2 3 *1 3 1 2 0 5 3 26 30 1 1 4 3 127 12 33 18 3 3 2 5 2 '1 1 ucc 055094 T"aE h nrrinuAL vcm contcht of osak-7 nir: writ-. ouriE, lwr. Pin Date VCM, f 403 402 6-2 f. H 14 a 405 ii S 411 6-27 40 406 II 26 i408 II 414 H 29 4 All 6-23 i 403 it A 402 M 42 412 II 38 408 f-2 23 405 il 13 400 6-30 24 412 II 31 411 l 16 403 II 12 ucc 055095 Tru RESIDUAL VCM CONTENT Or '1506-7 DIN SAMPLES Jllf'.E, 1076 Pin 60n 605 60* fin;? 60'1 601 607 601 C06 604 60? 605 f.0 603 Date 6-20 6-21 M 6-22 it it II 6-23 II 6-24 M II ll 6-25 VCM, ppm 68 63 55 63 55 48 59 128 107 118 147 214 09 254 vjCC 055096 *c.:idi"VL wcM r.ofucrr rp ' Y-i' &.`fi -1"5 ,11'me, n: Cin Date VCM. P 70v 6-24 1588 70C H 642 705 6-25 900 70 ii 991 in 6-26 671 703 H 950 c 704 G-27 829 701 M 1076 702 II 367 705 6-28 647 708 fi-29 336 702 II 1545 707 C-30 1051 704 II 480 ucc 0550fl7 taell XII 9FSIDUAL VCM CONTENT OF V?JE-10 BIN SAMPLFC JIINF. 1976 J*5 -- - - ^ fti 707 76 II M 70* 703 6H -2 704 701 7 P'' 6-3 H II 706 H 707 708 703 fli-4 ll 709 6-5 706 703 704 6M -6 II 701 707 6ll -7 702 r-8 708 6--9 700 6-10 702 707 6II -11 702 6-12 703 6-13 1J 202 220 400 397 348 498 427 605 340 550 387 618 349 594 652 1119 1483 1260 1 OAO 460 250 285 286, 330 512 ------ <r 70J 709 706 707 701 704 703 705 709 702 707 704 705 701 704 707 702 703 705 706 708 702 704 709 701 i* 1 5 6ll -16 6ll -17 ll 1* 6-lfl 6II -19 6-10 6-20 6II -21 II II eII -22 ll II 6II -?3 II II i- - . 1173 109 1000 903 7"7 6^2 27 770 1155 897 305 691 445 531 413 161 535 403 33 563 162 480 ucc 055098 TAPIE XIII CCPIQI'AL VCM CONTENT OF NON-SOLVENT OLEND SAMPLE? VYflW Herd Nur.ber 332 3^33 3934 33G 3930 JUNE, I9Tf '/CT1, ipm 33 iOv/ 10 2 7 2 rvf!L Cl end Number VCM, npn 1*7* c - 1475 3 1476 3 1477 1 1478 2 1479 4 1480 8 ucc 055099 TABLE XIV RES I OHM VC* COI'.TftiT Of SOL''EMT VfflYL Plc!fl OK! SAMPLES JUttf. 1*776 VHCH VMCC VYHO VYH1 Bin VCHt ppm fin VCM, ppm Bin VCM, ppm Fin VCM, ppn Bin VCM, ppm rs J ^ s irO 'o ^ ro ro ro 'J 61 41 64 < .2 < .2 < .2 72 71 < .2 . 82 < .2 72 < .2 84 < .2 83 .2 31 3? 33 34 < .2 P.2 < .2 74 < .2 51 62 < .2 o.fi 71 < .2 74 .2 71 < .2 52 < .2 41 < .2 63 < .2 34 < .2 *3 < .2 44 < .2 Cl < .2 51 < .2 .3 - .2 - .2 11 12 21 22 23 13 14 21 22 - .2 - .2 .2 n.9 - .2 0.2 < .2 < .2 ovi %c oO oO PI FTi'I PUT I Of! TEXAS CITY Mr. m- E- Eisenhcur Mr. R. L. Frantz fir. *1. L. Hockersmith/F. L. Johnson Dr. C. E. Moyer/n. R.Montgomery Mr. F. S. Trcvenzano fir! K. E. Ross BOUND TROOK Dr. R. J. Anderson Mr. T. F. Archer Mr. F. Bell Mr. R. G. Davis flEH YORK OFFICE Mr. A. E. Donaldson /* Mr. J. P. Hoilinosworth ( Mr. S. A. Mortimer Mr. 0. T. Scott Dr. T. T. Szaho SOUTH CHARLESTON PLANT Mr. C, F. Fry Mr. R, N. '.'heeler TAFT Mr. A. S, Amatannelo UCC 055101 V. Author: RESIDUAL VCM ANALYSIS TEXAS CITY VINYL RESINS PRODUCTION May, 1976 R. M. Arnold L. D, Morgan Date: June 9, 1976 Attached in Table I is a suninary of the residual VCM levels in suspension vinyl resin products produced during the month of O May. Essentially all of the QSAN-7 production shown in this data fs resin having the QSAL-7 molecular weight. Thus, a slight increase in residual VCM levels of QSAN-7/QSAL-7 pro duction was observed when compared with actual QSAN-7 produc tion during April. A slight decrease in residual VCM in QSAH-7 production during the month was also observed. Individual bin and blend data for suspension resin produced during the month are shown in Tables Il-VIII. Also shown in Tables IX and X are residual VCM levels in non solvent and solvent production during May. One VMCH bin and one VYHD bin were blended to achieve I ppm VCM. /mf Attachments RESINS LABORATORIES UNION CARBIDE CORPORATION CHEMICALS AND PLASTICS DIVISION TEXAS CITY PLANT UCC 055102 TABLE, i SUMMARY OF VCM ANALYSIS OF SUSPENSION VINYL RESINS May, 197 Resin Type QSAN-7 QSAL-7 QSAH-7 QSAP-7 VCM, Bin --- 13 16 10 42 29 14 20 Pet Blends < 1 f ppm VCM 64 59 16 62 <1 ppm VCM 12 9 46 ucc 055103 ucc 055104 end No. 6800 6806 6809 6810 6811 6812 6813 6814 6815 6816 6817 6818 6819 6820 6821 6822 6823 6824 6825 6826 6827 6828 6829 6830 6831 6832 6833 6834 6835 6836 6837 6838 6839 6840 6841 4842 6843 TAP' ' ' RESlDUAL VCN CONTENT OF QSAN-7 BLENO SAMPLES May, 1976 VCH, ppm 7 17 29 13 7 4 4 24 5 10 3 13 7 17 1 32 30 3 9 13 8 14 .7 103 8 22 1 17 148 10 25 3 12 11 35 24 10 Blend No. 6844 6845 6846 6847 6848 6849 6850 6851 6852 6853 6854 6855 6856 6857 6858 6859 6860 6861 6862 6863 6864 6865 6866 6867 6869 6870 6871 6872 6873 6874 6875 6876 6877 6880 6881 6882 6883 6884 VCM, ppm 11 8 20 4 9 3 10 15 3 5 1 2 <1 9 <1 4 31 34 2 <1 1 3 12 5 3 <1 10 10 73 5 12 19 <1 2 13 13 4 7 f.lcnd No. 6885 6886 6888 6889 6890 6892 6895 6896 6897 6898 VCH, ppm 1 3 22 <1 4 4 2 1 2 1 TABLE III RESIDUAL VCM CONTENT OF QSAH-7 BLENO SAMPLES May, 1976 Blend No. 1820 1821 1822 1823 1824 1825 1826 1827 1828 VCM. ppm 10 22 67 270 111 93 22 72 24 OCC 055105 TABLE IV RESIDUAL VCM CONTENT OF QSAP-7 BLEND SAMPLES May, 1976 Blend No. 714 715 740 741 742 743 744 746 747 748 749 750 751 752 753 754 755 756 757 758 759 760 761 762 763 764 765 766 767 768 769 770 771 772 773 . 774 15 <1 2 16 <1 10 <1 6 1 25 <1 <1 <1 31 <1 14 20 <1 2 <1 34 3 21 <1 190 1 2 <1 173 . 15 <1 <1 65 <1 65 <1 UCC 055106 TABLE V RESIDUAL VCM CONTENT OF QSAL-7 BLEND SAMPLES May, 1976 Blend No.' 969 970 971 972 973 976 977 '979 981 982 983 VCM, 18 11 11 <1 48 <1 5 6 <1 3 2 ucc 055107 TABLE VI RESIDUAL VCM CONTENT OF QSAL-7 BIN SAMPLES May, 1976 Bln No. Date VCM. ppm Bin No. Date VCM. ppm Bin No. Dite VCM, ppm Bin No. Date VCM, ppm i 704 702 5-1 13 705 5-11 39 8 706 II 3 408 5-19 11 405 H 4 412 5-27 406 5-28 15 31 703 If 5 702 II 2 609 II 1 414 II 15 708 II 8 703 II 39 411 5-20 33 409 II 5 706 M 26 707 5-12 20 603 H 12 411 It 46 709 5-2 705 II 701 tt 702 5-3 703 II 27 702 II 4 7 701 M 13 1 <1 705 703 5M -13 17 74 37 701 5-14 40 607 II 608 M 409 H 605 II 606 H <1 12 11 10 7 415 II 405 M 403 5-29 406 606 11 ll 2 2 <1 10 <1 704 H 139 704 II 24 709 5-21 <1 412 5-30 40 702 II 705 II 701 5-4 <1 708 U 71 702 If <1 706 14 3 706 ft 2 12 412 M 22 46 415 15 603 II 409 ll 411 II 2 18 4 703 H <1 707 5-15 27 703 tl 12 609 ii 3 * 701 41 704 H <1 6 703 II <1 406 5-22 5 601 ll '1 701 5-5 704 5-6 706 H 7 605 II 7 706 II 7 702 1 8 . 702 It 3 21 414 409 H U 3 12 4 606 608 5-31 ll 607 II 4 7 2 702 II 24 601 If 7 705 II 2 414 It 6 709 II 229 < 703 5-16 4 708 M <1 603 It 2 708 II 10 607 It 33 702 5-23 14 406 II 22 703 701 M5-7 24 705 It 22 606 14 1 402 H 8 6 709 II 2 705 It 43 603 5-17 5 703 1 7 ucc 055108 706 II 704 708 702 5M -8 N 71 708 II 6 702 II 8 704 M 26 703 II 4 4 <1 6 702 411 5-24 H 2 3 705 41 708 M 15 28 705 701 m5-9 8 701 II 12 609 il 78 24 408 5-25 7 702 N 10 704 N 8 601 II 28 409 U 2 709 M 13 403 5-18 4 703 ft <1 709 ft 26 412 14 5 709 5-26 4 1 708 5-10 12 414 If 6 706 It <1 TABLE VIi RESIDUAL vcm CONTENT OF QSAH-7 bin samples May, 1976 Bin No. Date VCM, 409 5-10 257 403 M 12 412 5-11 2 405 5-12 6 408 II 52 411 H 12 412 5-14 15 414 it 31 405 ii 33 402 II 28 c 408 M 32 406 5-15 27 403 II 10 415 II <1 412 5-16 19 414 II 36 402 H 133 406 5-17 108 408 II 13 405 II 49 415 II 19 409 5-18 23 406 II 46 ucc 05S109 TALiLC VIII RESIDUAL VCM CONTENT OF QSAP-7 Cl.'; Sa/IPLES May, 1076 Uin No. 604 603 605 606 607 609 601 603 602 604 606 608 607 601 602 603 605 609 C08 606 602 607 605 601 603 607 60S 608 609 603 601 602 604 607 Date 5-1 H II 5-2 n il il 5-3 H 5-4 II II 5-5 II l 5-6 II II It M II 0il -7 5-6 II II II 5-9 II II 5-10 II n VCH, ppm -1 12 2 1 2 2 9 23 <1 <1 1 <1 15 3 >5 <1 22 <1 <1 17 <1 8 45 2 93 2 2 143 2 43 1 1<1 1 ucc 055)10 4 c # TABLE IX RESIDUAL VCM CONTENT OF NON-SOLVENT BLENO SAMPLES May, 1976 VYNW QY\J Blend No. VCM, ppm Blend No. VCM, ppn 3926 3927 3928 3929 3930 6 19 15 3 20 3 21 <1 18 21 5 Vjcc 055A" ) t' thut x RESIDUAL VCM CONTENT OF SOLVIffI VINYL RLSIN BIN SAMJ'Lf Hay, 19/6 VYHH I NO. 54 53 52 52 62 63 54 51 41 61 52 62 53 63 ppm. VCtl 0.4 <.2 0.2 0.6 <0.2 0.2 0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 0.2 io VMCII BIN No. 82 71 73 82 64 72 B1 73 74 84 72 83 71 82 72 81 74 84 71 73 74 83 ppm, VCM <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.6 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 , | 1 | ! j VYHD 8111 NO. 31 31 43 32 33 33 34 ppm, VCM 0.6 0.6 .2 0.6 1.0 1.0 0.9 Resample DISTRIBUTION TEXAS CITY Dr. C.Eh Moyer/Dr. D. R Montgomery Mr. M. E. Eisenhour Mr. R. L. Frantz fir. J. L. Hockersnith/F. L. Johnson Mr. K. E. Ross Mr. F. S. Provenzano BOUND BROOK Dr. R. U. Anderson Mr. T. F. Archer Mr. E. Bell Mr. R. G. Davis NEW YORK OFFICE Mr. A. E. Oonaldson Mr. J. B. Hollingsworth Mr. S. A. Mortimer Mr. G. T. Scott Dr. T. T. Szabo SOUTH CHARLESTON PLANT Mr. C. E. Fry Mr. R. N. Wheeler TAFT Mr. A. S. Amatangelo UCC 055113