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,-2-S REV. ?t V 3 to: subject: INTEROFFICE COMMUNICATION Westlake, Louisiana December 3, 1970 M. J. Thomaes, Saddle Brook Standard Heel Allowances -- Procedure Please refer to your letter of November 20, 1970, which requested the details of the procedure used at the VCM Plant in granting heel allowances to customers. The procedure is as.follows: 1. As each car is loaded, the total volume in the car is determined by calcula tion. The calculated weight is used on the Bill of Lading as the shipping weight. Freight costs are based on this weight. 2. When invoicing a customer, the Bill of Lading weight, less a standard heel allowance (net weight) is used as the "invoicing11 weight. (See Invoice No. 387-701 attached.) Our standard heel allowances are based on 12 pounds pressure at 60 and are as follows: 1470 lbs for 38,000 gal cars 1190 lbs for 30,000 gal cars 800 lbs for 20,000 gal cars and 22,000 gal cars. t 3. The heel on all empty cars coming Into the plant is calculated, [f the car was last loaded at our plant, we determine who the customer was and then compare the returning heel against the standard heel to determine if the customer left a heel greater or less than the one they were allowed. If they left a greater heel, they are credited for the volume above the heel allowance. If they left, a lesser heel, they are charged. All charges or credits are made at the contract price. (See Invoice No. 387-707 attached.) We are aware of some of the other methods used to grant a heel allow ance and could switch to any one of them; however, no method is as accurate and fair to both the shipper and customer as the method we employ. We can see why a customer who receives heel allowances by two systems would raise a question, but do not understand why the different methods create internal accounting problems. Other than the pumper/loaders who lake the pressure and temperature off the incoming cars. Bill HoWel! prepares all the documents involved in the product and heel calculations and the invoices. CUH 000005441 M. J . Thomaes Page 2 advise. Should any other information on this matter be required, please JJW-MC Att . ^ cc; LNV^ WCB JFP WRH J. J. Weidner CU1H 000005442 D-UN-S 00-49<l-8 196 ^ Conoco Poire chomicaik REMIT TO Continental Oil Company P, 0. Box 52C2 Church Street Station No,7 York, IJo.v York 10003 VWW'Mi..,.. invoice no. tumm 337-701 INVOICE DATE 11/30 770 SMlf*. rat From Continental VCM Plant Westlake, Louisiana SNIPPER'S NO. SOLD lO Diamond Shamrock Corporation Accounts Payable 300 Union Commerce Cleveland, Ohio 44115 route. Shipped to; Deer Park Plant; Houston, Texas ______ ~[> ORIGIN F.P.S. ^DEST. ^ n ] COUECI PREPAID ] j . [> MFA. CUSTOMER ORDER NO. GB5552-11DP TERMS 15 Days Net FREIGHT EQUALIZED WITH s UJO r ROD. CODE PRODUCT NAME AND DESCRIPTION i 5 T/C Vinyl Chloride 2 Less Permanent Vapor Heel PRICE/UNIT u U 1 I BILLING QUANTITY 1,111,231 3 Allowance of 1190 lbs ./car 5,950 Invoicing Lbs. 4.2#Ab. ' 1,105,251 3 T/C Freight Prepaid $35.96 Per Car. AMOUNT OF CHARCES $ 49,737.65 179.SO PLEASE REMIT THfS AMOUNT TO Tilts ABOVE ADDRESS . ^(?X?XiH ;AV/?.djO'. ijy. mnc- ikmyhhi: vi'Jjrrn :hhhiL'xcmf-ii 'it <V.f9t :sf- f/hi- u-'usr? triicbiftyt 65V ? (tSV. is .i'l'i'iR'IihiV. CAR NUMP-EP RELEASE NO. OS l/l NO. Jhip.-iMG DATS DA T, -- CSOSS AS/IS G NET ICO^i D5 ACIIVi OAllONS/llS. P GAllCNS/lBS. 1 -1 1 T -J i 1 TEMP. COA\A\ENTS See attached summary for dates chipped. s 49,917.45 DIRCCT CITOTNP'TOIir-IKilMr-TMAirL,'iO\ ilh. rC;iOaMpPi ANY cuh ooooo: >443 I IWI V r. T *T <r _ <r uT __ o o 3-- a YJp 'O'd -' JGUJO-tSrQ *" -*-'j cFTZTJ -- wsi#. j.'fcTjj v&VTeQ o 9 669 +/ '/ * / / / *9 o^y7o ./ St ts // W/rfV* `*H0*'Mwjr3)bt 4unoLuy 84oy 4q6;sj j 4q6ij j 7wrrri --7W . C64 '(CO y (ic-' 'iSC'CCC _<;rc:tc TZ5?^ .44619/^ 43N * 6/'C/e JTSt'CVf /s/t'e't css e/t uy//c 4H6!M SSOJ0 v~61 'Vyt'WOf/ > saivsT do ainaaTos INVld WOA 1VIN3NUNOD K^`4 " eeog 77 / // " C/&6 / &oo6 uoijduosQQ ^^/'//. t/ ^oW7T paddiqg JOD . >4dq SF.OC csc?c. 7sol /COC C CO6. !$?0 " z''7 VOA ZSZ DQ1 .. 98S o REMIT TO r V ' I: P-ll-N-5 UU-'ivn-ft I VO Continental Oil Company P, 0. Box 5232 Church Street Station New York, hew York 10003 Conoco chsmicak mvosce iio.Mmsm . 337-707 INVOICE DATfll / 30 / 70 $mr From Continental VCM Plant Westlake. louisiana SHIPPER'S KO. _____ 1 nnJ'_ * SOLD * 10 . - Diamond Shamrock Corporation Accounts Payable 300 Union Commerce Cleveland, Ohio 44115 - o o ' routes Shipped to; . Reybold} Delaware origin f.o.6. w t>SL { .) [> COUECI CUSTOMER ORDER MO. TERMS PREPAID ^ l A'.FA. fftEIGKI EQUALIZED WITH < U/O PROD. \~Z CODE 15 Days Net PRODUCT NAME AND DESCRIPTION' \ To Charge your account for heels-* 2 removed In excess of allowance U PRlCE/UNIT N 1 x -- 4.5c!/rb. 3 BILLING QUANTITY 2,709 AMOUNT OF CHARGES $ 121.91 Or- O O I .i o. o o o.. u. . ".y -. * fiJ * ui 0 K < Xu 1L O z 0 H c. cc Wu) fcj O ' Ar-' f. jr.y. 'JE'jJl'i: iVsVis PLEASE REMIT THIS AMOUNT* TO Tth AD0VE ADDRESS Ov iV-!'jC->?'><h\l5 'vV.-Vl/lh.ViO'Jj'D /l.cr 0': CAR NUMBER IEIEASE NO. OR t/l NO. lMi>hsO DATC MO. C>*. T, CROSS A5/5S 0 NET 100?S , ,CAllONS/lES. 0* r ACTIVE OAUO'IS/U*- TEMP. ,,1 1 -- 11 -- 1J i1 , COMMENTS See attached summary for dates shipped. *. % * 121.91 t ( < { < ( ( l i ( ( ( ( ( < 1 0 r. DIRECT INQUIRIES TO: CONTINENTAL OIL COMPANY PETROCHEMICAL DEPARTMENT PARK - SO TLAXA EAST ^Minir r.r-rvi'V' nm1.' ir-rcu-v n v f. r. 0 CUH 000005445 ORIGINAL INVOICE UNIT; C - CAL LONS f v POUIIOS T = tons Dote Shipped c)-JV-7o It {/ /O'//' /O'S- 70 /0/7-70 /D-/t/-?o // /0'/S~ 70 /0 '/C/-70 /0-ZO-? O /O-J/- 70 /0-^^-73 /0-P/-7O /0-?r>~ ?o CONTINENTAL VCM PLANT RETURNING HEEL STATEMENT 19 'po Gar Numbs r v C/J*r- ' //c/s(' V7/.s7> GtffX- fr 9?/7 /( 9*>2oJ /r /( 9?)33 / /r 9/3/c/ A q$?6r /s 9fu.-z //CfixT-- / 7^0 // /7 </9/ &>0*7 // ' st // ff /?c/r- '/TVS.* \ i i * CUSTOMER I/lCsfhP'^ (/?) Date Returned //-/. ?o //-2-yo // //- <~;>o ft /r - /s //-/{?-?i> //-23-70 V/-/-7-70 */ //-/3~7 //~/9-?o //-/& - 7 /A AT- 7 o /s-2-?~?0 Returning Heel /&3?S! //</S /?/o /3SO /?JTA /SO/ ///> /</& ! //?9 1 /</*? II /J>Jl* ' ` /3?7 /o3o /7/c/ //99 //9? /739 /cost /3*S TVh / l/eef Tot*> A t* 1' / Qpr*OV ttJ Ox (MS PC /)//,*C*"4 C 3.QA / 37 9,30 -P/7ft9 Chcrc/ CUH 000005446 < k / \ ~i '! O c\.*_ No U CO 6-0 J V.C. 1 ' . L- - A ecnr-orous cnr^o consiCerei to involve prrtieuirr hr:-::irA, v;hcn turns-* port eel in bull. ceentieios on. boorcl vessels, or vi'.on hrnrlec. in be i R cur.:/: itios cn vr.terircnc facilities, '-is ony ccrsr.ocity vhich by virtue- of its proportion v.-rvlf. creese on. v.r.ucu:;! hr.uc.rc. if relcescb. The ccrercdsties subject to trie section arc: ACETALDHHY Dll HVLROCRrOPIC ACYL ACETONE ' CYAN OHYDAY N Lr.`iY..' [i\.e acetonitrile METHYL ACRYLATE iiCAi liO.'i j. Tr\l 1/3 ALLvr A~rrvy-sv/.--.vv.-v1 . METHYL HROMYDE MSTrj YL CALCIC DE .ALLYL CHLORIDE METHYL METE:'CRY LATE (Mv'NCM^A} AMMON1A / AM:iYD301;S '- NON YD PHENOL ANILINE OLEUM BUTADIENE PHENOL CARLOLIC OIL CARBON DISULFIDE . PHOSPHORUS, ELEMENTAL . tnvnPr.Vr*. CHLORINE PROPYLENE CHLOEOHYDRINS/ CRUDE PROPYLENE OXIDE CROLONALDHYDE SULFURIC ACID 1,2 - DICKLORORAOPANE SULFURIC ACID, SPENT DICHLOFOPROPENE TETRAETHYL I/EAD KFICHLOROHYDAIN TSTAAETHYYLHAD MIXTURES ETHYLENE ETHYL ETHER VINYL ACETATE 4/VINYLVINYL CHLORIDE (F.ONOl-rER) ETHYLENE OXIDE VINYLIDENE CHLORIDE . '` * CUJH 000005447 c (j. Vc.cz cz::$o on hoc: vii 1 bo 115 o-:*. r~ i : VI' i^c-UO o v.:v/'.c. o vie;. ::o s.-rtvo c icuiir n r.r.c : Ic, 5. Failure to comply v;il the above safety precautions r.ay rose contc.ticr. boir.e; c-.OoOb c'o until ccmnlinrco is mot. A. B. BOS?: Coir-t'.v.ru.ox* / U. . Coosu Guc.re Captain or the Port, Houston 3- - CWH 000005448 ) ?.c. O i'j%> c*o ; t-- w*. oj *_''**^ ** v* subject cargo- will .be coz-.pletcly be. 1 tad. i.*'wv -L4a Li.t**^.o ^v.!*, t. r h. The tank. ship's fire rdr.n will bo. rated to the facility fire- 'fieht-N Vv ^c ''^ ,w ^ ' . '"' ...........-"' :-.v nro wu:;vos ore srnporaurve. bn is process will coacraj.ly require too utilisation of a foreign vessel ` s Intel.Sitienal Shore Connection. gho bo:;C.Hoic shell never be eh recce, unless in use during a fire. t .J j y/ .- . i. Vessels bonded V w' V. , Conner tier: c and any spi] Clc'-V.pS are : transferring- the subject cargoes should bo electrically Cj,.1 .<i.%2 jeon r. ! :0< i- O^. (?11Sq- 3. In suuv'.wurrr.ery, we torfro.ot facilities handling- products; of unusual ho cere as lis coo :.:- re tfisj! a Hose properly gu.: b. Pro-' c. Vape would ctiberr a. 7, doc nature cf th e. 7.doc. f. A do t/,;: `V (j- 'GC'enoir.g upon tee C* Shor the vessel f .shut.dov;n acuten h. Carg ^osc-s are tested annually according to rnarudcctuadr' s .-recca-- ttende.tiens. i. Care, :oses ere clearly Berkos with ranufacturor' s guaranteed ri\a:-:ir;Uu'i or go Dj. Ncottiify CCC? 24 hours before arrival of vessel beading or dichcarging co-c.ronoodoi.,itti0ic5.sJ iof particular ha sard. (2a) k. Insu lined i n par, 4. In surtuC' Bnclosu ro (l[ 24 hr b Bunkc loam no or cl. c^. ^Dj. iscii;wii y ;tk.#-uii ,;.ou - _ etc, t.c- -ui .*. c%*-/u c-^-. * cl. l.ll piping used for subject caregos shall conto-in all bolts in flanges and' a functional casket. 7i.Il connections shall be without a leak. 2(c) CUH 000005449 X WoveliCl cgti'* ptygic :w'.^c 6-ot Subj: C;.nc.-u:. n o'- uho Tout ?olic:y concerning Vessels Loading or Discharging "Cargoes of fi> * (a) COIV Public Wotioo *>-<*'0 j , hefeior.'.'- r s fier-ovy Ciurc^lj.o . . . * \ 2. Duo to the particular end severe hazards v*hich exist during the trar.c of cargoes listed in 33 CFK 134.14(b) (!) , (See enclosure (1)) , it will be :,-.y eolicv to order safety precautions listed in the for loving paragraphs v;hcn arc' tank ship or barge is transferring or has aboard such cargoes in the Port of Houston: a. At least 24- nours m advance, tno v.'c; vorvront mcr.lii-y v,.. e _ o L.r.e cargo'of particular hr. rare is to be transferred /' will notify the CCT? of the. anticipated date, .ir.e, vessel, cargo one err.ount -c-: be transferroe.. This notification rriev be acce.tolishee bv letter cr telephoi'.e, (672-2143). Acry_-.cn:.i_r;.le , rei_nvx acrylate, butacrcno, r..ei--.y 1 *,.tir: c. c _ y 1 ao, ethylene oxide, vinyl chloride, vinylidene chloride and vir.yl acetate Trust be inhibited or stc.bilir.ee. The waster of a. venae! cr tno tnr.korv/.r.a of a barge into v.'hich these cocr.'.odities .ere loaded \;L 11 be province vein i state:.*,one as to the type of inhibitor used, the entire:.roc tar.e tr.a rnna;::r of the inhibitor.' c. Veesssseellss: shall not bunker_oorr.Jhlo.oaadd_^st~ovres~ fro--m- g hope see a 'b cl. While discharging or lording any of the subject cargoes to or frcr\ r. facility, a vessel shall not transfer any cf the subject cargoes or any other cargo to cr from any vessel alongside. e. Tank vessels nay transfer any of the subject cargoes to cr free* a vessel alongside only if transfer operations to cr free-, the :?.cur:y are n conducted at the sane tire. While engaged in such operations, sufficient personnel shell be on v.-ntch in such positions that they can a:v,o.Goia'corv secure the operation if a hazardous situation develops. f While discharging cr loading any of the subject ccwvoiities, v;aterfront facilities shall provide adequate physical security, i;;c1 udir.g_jy guard force to alien' on'v those rsrsens v.*ho have an o i f 5 c 1 a j. n e s e nor presev.ee cn the faciiiuv durir.e v.he coernuion. CUJH 000005450 -`'I'--c-.: t.r.o iio Uir.C-:'. U. S. Coast Gear: P. O. ? e:: ill Galena Par!-:, Ge ; r; 77 i 7 Fro-.: TO: CC p l r. .17s 0 I All Marine OrN-'-r h OV;5.. eon 1 JJovcnlcr 1553 su: c. Po. jee 1. Bncicseo a? COT? Pudac Mctrce 6-C9 are effective be.:;;'r.nine: 1 KcyGirher ISoO crovisi c o c n i s 2. Public Kccico rose. Tnc re v.'itb certain erro 0 was released in early Oct so has been favorable, arid n tha original release cerr er, 19-39, to (j a notice is he ted. :o w7 Mjn< A B c> Correia r, U. S. Coast Guam 0SO v.cl oi the Pert, Houston f-`WH 000005451 GOOD SA72TY T'aACj. * VIXYi ol% I.Ua. kAUlIX< -- .j ^ 1 i C.c is cl !`.2ur^OU3 r.SteriS.l whose J.'UWC;3 Can ~ 3 <C C tUC Ci'cV/ dj.c-.Zy c.'.\C. causor unconsciousness . xt ns very 1 lar.vwsoie ana c an cite j on fire by static c_.cctviej.cy v.'r.en ^c..sing r.ron a tan*c. Tne v cl j. low m g "i rs. o V i. cos iTti r ecorr.TTi enc o c v.'n ev. cancer .ps are carrying vinyl chloric. lOADIXG: . Devore leading vinyl chloride, the tanks must be free of oxygen to prevent a explosive winter a being present or a reaction or the oxygen with the vir.yl cnlorrce. Tr.e snap s nome r.ava it1 s own wethed or anaxymng ew.pty tanas i or oxygen. The tanks must also be clear of the previous cargo to proven o v . * of the vinyl chloric e di.u t.n possibility of a reaction betv.'een th< `ar.e the vinyl chloride. M1XIX0 vJlTH CTcuP CAPGOIS: m loading and transferring vir.yl chloride, all piping must be clean of previous cargoes, otherwise a reaction wight start in the pipe. PhACTlOXS: Vinyl chloride v:ill react with the. oxygen in the air. Care should be taken that no air enters tne tanas through xecay peeling on compressors or a l1ea -..v O V. V, - - l_` .. on c orao re s s o r Phenol or hydrocuinor.e is added to the. vinyl chloride at the tine of loading. iC*s ourjoae is to orevem sni*.. swoun*-s oair fio... rcacv.o.ng \%j.u.h -..e cn_g\j. As. long as no air enters the tanks, this inhibitor will be aval lab le. Kcv.-ove if wore air enters the tanks than can be handled by the inhibitor, you will s a sxcw build-up in toe te.i.perature and pressu re of the car o J.J- L..1S happens, a reac <_ on is it-nr, u o lace within the tank. In this case, t h e cargo sn cult. Zie vented to waintain a safe pressure and a lew ter,-.per a Cure . Vfnen venting tne vaoors are w.ucn heavier than air and'will settle frow the v ent st a e .". arc can burn -if they cowe in contact with dry heat of approxiwately 9001 or open fInwe. The attached graphs car. : e used to determine if changes in pressure are due to changes m u-ewnerat-lire cr no- ino i.ewperalu.re and/or pressure o_ tr.e tanas SCOUl^ b.-s or d s= o chi t you can be -aware, of any change in the condition of the cargo. CUH 000005^52 -0_ Sm.sll leaks car. usually ba found by the odor of escaping vinyl chloride. The r.ay also be round vi.ch an exp...osion r..eher. ra fittcs* are twice as r.er.vv as sir era will collect m ra; bi-^ge or ary j-Ct' parr or mo 5r.1p arc. ioiv. or. explosive condition. The insulation or. the tanks will usually allov; leaking vinyl or lorre a t 0 r j.or.7 covu the outsic.e or tne t ar.k r. ad into me 01 _ g e is a vary c.argarous conn tter. In' the avert: of a lech or. a ship> all sources of ignltion r.rast be eliminated ur.nl w.-.e ^.cr<i( 13 stoipec are the sir is clv^aa 01 any Vu'. vapors} Gtp'iv.....r.-i...y below each. Voter fog car be used to absorb sore vapor. rwr rURr w? TASKS: V, . If the tanks cor. v1 1 eh1 o r i c e s ahoouuildc ruoture. or develop a la.rp the v..i-r.myl which tt.ay chloride v.'ill escape. As 1t escapes, it ignite tr.a vinyl cr.ronoa. every eCffort vr.- uilc. static be made to stgo _ea.aa i' ana or piping wit r.out wiiic: Xf tae lea.k can.-.ot be stoppeCj in a cargi will be cooled as it boils off. This will '.take the vir.yl chlor s^cw are will e:-:tano possioixity cl lire or explosxon- M. l- V> Ti' W Bull MIXG: urr.irg vir.yl chloride gives off carbon monoxide which is a deadly poiscr. end ydrogen chloride which is ar. acid ar.d will burr. the. lur.gs. The crew should toy upwind of the fire. The hydrogen chloride will destroy ary wet ratal. erge stream, of water should be used on the gases corning off of the fire. Th. ire shone not be out out cue to the possibility of ussr'.b&OiC, ?HR/r;.r ft CWH 000005453 VAVOJ! ,0 r.Vt' ; \ i *' . .V' L.". 4 ^ ,.v i V C i V i ' \; `v \X' v_> . i ; *.*> <, . ,\ //nanwP VVuo\iVL /^f^rniiLnnOL-t, -.i-avLu. !l; a^, i ^V.73 i Li U11_. . i vj C' Oi 'A C. O iC v/vii^i i Cwt; C. < i . i Oi V ; ^>. { *.*;*,*. f ? _ , , ..J ___ i _,,,{ _.,, * ^A ^ .\Z*" v^--O o'vi o`. . i.. u.iry( viv vv;i,y >J, v. v--..- ji rvnem Arp:;[7A@ s U J g--c A-_i:. V. I Rt? 5l _____ ; . f_ . _i r _ , _ ___ t_ ___ ^ /?_ iTrt/.`c,..,'.'c.'.iy i;... i. i. ~i .3/ U. cA; ;Sj 7. 0\-1, ^ 7<\o 07 Op o' A i`;v.77iG. 6 077X7...? 70X;C.!-.c.`3 7 /. 7,0,7. .' ' CW. 7;/3 77O''' C C 0 V w1 / e,. J * j\ ** ' ' r-- ' r ' < ***. r;, . -i " ' * 1 : .- >*,- 07 i CV;Vv7 X7r. V.X.`..'vX W* w.\. w, -7.X 7. o',; 0. 7 V. O -1 oX t 7*_i'_.'.'U/0 , f:V:^X7 :-7;'-r use: I_____ Vcmor h ,, i ,> ^ 67 6*/6 :7:J7V :r7;;6:7 VO rrc-?;j.76. j- Lib\LS lv*^S>^55^- ,, r [S>i T;V-v ltV.v;Atifo:'t/T^-'..'\C0 li E; i;wuA'U'jar to Shut off si! ignition sources. Shut off leak if without risk. 'Wear self-contained breathing apparatus and protective clothing. F:ush area with'water spray. In case of nn spill into waterway, notify fire, health and. State w pollution agencies. Do net out out tire unless lack can be shut off Insroedietoiy. On small fire use cry ehemieei or carbon dioxide. On large fire use water spray or foam. Wear self-contained breath ing apparatus. CgoI tank with water if exposed to fire. Remove to fresh air. If unconscious, cai! a physician. If not breathing, apply artificial respiration, oxygen. In case of contact with liquid or cold gas, thaw frosted parts with water. In case of exposure to gas from fire, administer oxygen if breathing is difficult. 6 s;^' A,'.jCi-i;.; ., '..'-j C trj;.Mi fL'.il.t, ".j rj j-cr..i;> :1.^: ir., ..t r0. C. "TVi 7'.S. ti.-.-ja c-r pt j ;.j: P:i;.;.i j.-, LIa CWH 0000054