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TOXICITY TO AQUATIC PLANTS TEST SUBSTANCE Identity:A mixturecontainingperfluorooctanesulfonawthei,ch may alsobe referredtoas PFOS, FC-95,oras a component ofFC-203. (1Octanesulfoniaccid)(CAS # 2795-39-3). Remarks: The 3M productiolnotnumber was notnoted.The testsample isFC-203. Currentinformatioinndicateistisa mixtureof1.34% PFOS, 35% diethyleneglycolbutylether,37.85% water,20% ethyleneglycol,2.66 % Sultonefoamer,3% sodium octylsulfate0,.1% sodium laurylsulfatea,nd 0.05% tolyltdazole. The followingsummary appliesto a mixture with incompletely characterizedconcentrationsof impurities.Data may not accurately retlectoxicityof the fluorochemicalcomponent of the testsample. METHOD: Method: NS-EN ISO 10253,1998: Water qualit-y Marine algalgrowth inhibitiotnest Type (testtype): Acute Static GLP: No Year study performed: 2000 Species: Skeletonemacostatum Source: StrainNIVA BAC1, stockculturmeaintainedatRF - Rogaland Research. Element basis:Estimatebiomass by measuring fluorescence. Exposure period: 72 hours StatisticaMlethods: Growth ratesby loglinearregressionon biomass (fluorescencev)s.time,as describedinNS-EN ISO 10253. Calculatioonf NOEC done by singlefactorANOVA followedby Bonferronisprocedure. Analyticalmonitoring: pH Test Conditions: Algal NutrientMedium: Naturalseawater (34pptsalinitfyr)om an unpollutedsiteinByfjordN,orway, enrichedwithnutrientasccordingto ISO 10253 and recommendations from theParisCommission. This nutrient medium providedallmineralnutrientesssentiafloralgalgrowth and also served as thediluenftorallalgaloperations.The pH ofthissynthetiaclgal medium was 8.3. Stock and testsolutionpreparation:A 500.8 mg/L primarystocksolution was preparedby dilutin0g.5008grams oftestsample in1 liteorfgrowth medium. Aliquotswere then added directltyogrowthmedium intestvessels to createtestsolutions. Exposurevessels:100 mlflat-boftomfeldaskcsontainin5g0 mi test solution. Agitation: Shaken continuouslyon an orbitalshaker. Number of replicates: 3 Initiaclellloading: 2.0 x 103 cells/mL Number of concentrations: sixplusa blank control Lighting: Continuous fluorescentlightingat >50 pE/M2 Water Chemistry: pH range (0-96 hours): 8.3 - 8.4 (controlexposure) 8.2- 8.4(100 mg/L exposure) Test temperature range: 20 2 *C RESULTS sek. Nominal concentrations: Bk control,0.32, 1, 3.2,10, 32, and 100 mg/L. Algal Growth Response E,C5o values (based on growth rate) 72-hour ErC50 = 62 (48 - 83) mg/L 72-hour NOEC = 32 mg/L Element values are based on nominal concentrations. Reversibilityof Growth Inhibition:Not conducted. Remarks: Testingwas conducted on the mixture as described inthe Test Substance Remarks field.The values reportedapply to thatmixtureand not the fluorochemicalproportionalone. CONCLUSIONS FC-203 exhibitsa 72-hour ErC50 growth ratevalue of 62 mg/L with a 95% confidence intervaolf 48 -83 mg/L. The 72-hour No Observed EffectConcentration(NOEC) is32 mg/L forgrowth rate. Validitycriterifaulfillecdo;ntrolcelldensityincreased by a factorof more than 16 and the referencesubstance was withinnormal range. Submifter: 3M Company, Environmental Laboratory,P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY Reliability:Klimischranking = 2. This study meets the criterifaorquality testing.However, sample puritywas not properlycharacterizedand the study lacksanalyticaclonfirmatioonftheamount offluorochemicaplroportioninthe solution. REFERENCES Testwas conductedby RF Rogaland Research,ofStavanger,Norway atthe requestof 3M Norge,Lab referencenumber 99312-2,2000. OTHER Lastchanged: 6/27/00 99312-2 no A W. PMS MWJF ROGALAND --SEARCH "FC-203 LightWater Brand AFFF II Toxicitytests Report RF-2000/002 Lab. ref.no.: 99312-2 No. ofpages: 31 ISBN: Author: Elin Horve Client(s): 3M Norge DistdbLdonrestriction: VersionNo. date: Vers. 1106. 012000 Research Program: Open from(date): 7 Summary: The followingtestresultswere obta7inedwith"FC;-203Ught Water Brand AFFF Toxicity:Skeletonema costatum Acartfatonsa Corophium volutator 72 h EC, 48 h LC, 10 d LCM (mgA) : 62 (mgA) : 200 (mg/kgdryweight): >3060 The resultsrelatetothe productas suppliedby Novatech. Key-words: Toxicity,Skeletonema costatum, Acartia tonsa,Corophium volutator. No partof thisdocumerd may be reproduced in any form whhotn permission inwrtlingby RF - Rogaland Research 0. !S-tu r lngerUsa Andersen 142 L . forRF - Rogaland Research Khre Netand 99312-2 VjJ A CONTENTS: I.PREFACE ............................................................................3............. 2. TEST FOR TO)UCrrY WrrH SKELETONEMA COSTAYTJM ..........................................4............... 3.TEST FOR TO)aCrrY WrrH ACARTLI TOArS,.4..............................................1.0............. 4. TE ST FOR To)acrrywrrh COR OPHIUM VOL UTA TOR ........................................1.5.............. 5.DATA SHEET(S) .....................................................................2.0............. 99312-2 PREFACE: Ecotoxicologtiecsatwlsereperformeond'FC-203LightWaterBrandAFFF"in agreementwith ]Vovatech.Thesample isa concentratethatnormallywillbe usedina 3% solution.Testswere conductedinaccordancewiththe "HarmonisedOffshoreChemicalNotificatioFnormat" (OSPAR COM 1995 /SFT 1998). Theprojectwas carriedoutat RF -Rogaland Researchfor3M Norge. Allthetestswere performedby RF- Miljolab.Studydirectorwas SeniorEngineerIngerLisaAndersen. The testresultsarepresentedinseparatesections.The resultrselatetotheproductassupplied byNovatech. Thistestreportisissuedby a laboratoryaccreditedby Norwegian Accreditatio(n7vA). Y7zea.ccreditatiosntatesthatthelaboratorymeetstheNA requirementsconcerningcompetence, equipmentand workingproceduresforallthetestmethodscontainedintheaccreditation. Italsostatesthatthelaboratoryhasa satisfactorqyualityassurancesystem,which includes internaqlualitycontrolschemes,participatioinninterlaboratoc?oymparisons,and theuseof certifierdeferencematerialsand secondaryreferencematerials. 7'hetestpserformedarecoveredby theaccreditation. 7"histestreportmay notbe reproducedinanyform otherthaninfullw,ithoutthepermissionin writingby RF -Miljolab. TEST FOR TOXICITY Marine alga:Skeletonemacostatum 99312-2 A W6@ Uj A TEST REPORT GROWTH INHMITION TEST WITH THE MARINE ALGASkeletonema costatum no 1&.PNI ROGALAND RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: The 72 hoursEC50 was calculatedto 62 mg/l. The testsubstancewas suppliedby Novatech,and thetestresultsrelatetothisproduct. TEST DETAELS: METHOD: NS-EN ISO 10253,1998:Water quality-Marine algalgrowth inhibitiotnest with Skeletonemacostatumand Phaeodactylum tricornutum. TEST ORGANISM: Skeletonemacostatum,straiNnIVA BAC 1. A stockcultureofthetest organism iskeptatRF - Rogaland Research. PF@EPARATIONS: Naturalseawater(salinit3y4: %o)from an unpollutedsiteinBAord was used asbasisforthegrowth medium. The waterwas filteretdhrougha GF/C filter, and brieflyheatedtoabout750C priortouse. The seawaterwas enrichedwith nutrientasccordingtoISO 10253,and recommendations from theParis Commission. Testsolutionwsere preparedfrom a stocksolution.A stocksolutionof500.8 mg/l was preparedby stirrin0g.5008grams oftheproductin1 litroefgrowth medium. Otherconcentrationwsere preparedfrom thisstocksolution. INCUBATION: Testculturesof 50 ml were incubatedin 100 ml flat-bottomedflaskson an orbitaslhaker,3 replicatefsoreach concentrationT.estcultureswere moculatedtoabout2000 cells/mflrom an exponentiallgyrowmg inoculumculture. The testwas runundercontinuouslight(> 50 pve-sek) from fluorescenttubesofuniversalnaturalwhitetype,ata temperatureof 20:t 2*C. The testwas run forabout72 hours,and subswnplesof 5 ml were takenfr6m thetestflaskseach day forgrowth measurements.Algal growth was measured by fluorescencep.H measurements were performed as indicatedon datasheet. Lab-i-cf.110.: 99312-2 Page6of31 I)ATA ANALYSIS: CALCULATIONS: Growth rateswere calculatedby log linearregressionon biomass (fluorescence) versustime,as describedin NS-EN ISO 10253. EC50: The inhibitoryeffecton the growth of Skeletonema costatum isexpressed as the concentrationof a product giving 50% reductionof growth rate(EC5o). This effectconcentrationand the 95% confidence limitwere calculatedby theuse of thecomputer programme TOXEDO developed by VKI (Denmark), assuming a logarithmicnormal distributioonf data.Tte programme alsocalculateconcentmtionsinhibitinggrowth rate 10% and 90% (ErC Io and ]@,Cgo). NOEC: Calculationof NOEC (No Observed EffectConcentration)isdone by singlefactorANOVA followed by Bonferronisprocedure forcomparing each concentrationmean with the controlmean. TEST RESULTS: COMNffiNTS: VALIDATION: Table 1. EC and NOEC valuesobtainedwith Skeletonema costatum. Testsubstance "FC-203 Ught Water Brand AFFF" FClo 13 (8.3-18) FCso 62 (48-83) ErCgo >100 NOEC: 32 Valuesindicatceoncentrationgsiving10*/o5@0*loand 9001ainhibitiofngrowthrate.Unitsinmgl7. Valuesarecalculatebdy thecomputerprogramme TOAEDO (VKI,Denmark),and 95% confidence intervalasreindicatedN.OEC arecalculatebdyusingthecomputerprogramme GraphPad InStat3.0. The resultsare based on growth ratesforthe time span 0 - 72 h, the period duringwhich the growth isconsidered to be exponentialin the controlcultures (seegrowth curves). The validitycriterigaiven in thetestprotocolare fulfilledi,n thatthe control celldensityincreasedby a factorof more than 16 in the testperiod (correspondingto a growth rateof more than 0,9 d7'),the controlpH did not vary by more than 1,0unitsduring thetestand the 72 hours testresultswith 3,5-dichlorophenolwas in the range normally found. Lab. ref.no.: Sample received.: Test period: Report date: 99312-2 20.09.99 04-07.10.99 06.01.2000 ElinHorve Engineer Analyticaltechnician Age Molversmyr Senior Research Scientist Quality Assurance Enclosed: Data sheets ThistesrteporitsissuebdyalaboratoarcycreditbeydNorwegianAccreditat(iNoAn).Therepormtay notbereproduceidnany formothetrhaninfulwli,thoutthepermissioinwritinbgy RF -Miljolab. 99312-2 Page 7 of31 PRIMARY DATA:GrowthinhibititoenstwithSkeletonemcaostatum Testsubstance:"FC-203LighWtaterBrandAFFP' f Lab. ref.:99312-2 Startdate: 04.10.99 Conc. unit:mgA Measurement: The biomass was measured by fluorescencev;alues influorescenceunits Time: 04-10.99 05.10.99 06.10.99 07.10.99 Growth pH pH rate Corre- atstartatend Concentration 14:05 09:25 10:30 10:40 day -1 lation oftest oftest 0 0.11 0.59 9.2 56 2.39 0.998 0 0.15 0.63 7.9 59 2.14 0.997 0 0.13 0.62 9 54 2.29 0.997 8.3 8.4 0 0.14 0.63 6.4 47 2.07 0.999 0 0.14 0.62 6.3 48 2.06 0.999 0 0.12 0.71 7.1 55 -2.20 1.000 0.32 0.13 0.82 9.2 61 0.32 0.13 0.77 9.6 66 0.32 -0.14 0.84 12.5 71 230 1.000 2 32 1.000 8.4 8.4 2'43 0.999 1 0.14 0.77 11 70 2.36 0.999 1 0.14 0.69 12 65 2.41 0.996 8.4 8.5 1 0.16 0.63 8.3 60 2.13 0.995 3.2 0.18 0.58 8 63 2.05 0.990 3.2 0.14 0.59 7.1 52 2.12 0.997 8.4 8.5 3.2 0.12 0.6 6.6- 50 2.17 0.999 10 0.14 0.58 8.5 64 2.22 0.995 10 0.16 0.34 4.4 48 1.79 0.974 8.4 8.5 10 0.16 0.6 7.6 68 2.09 0.994 32 0.14 0.43 4.4 42 1.86 0.992 32 0.12 0.39 5.3 46 2.05 0.990 8.4 8.4 32 0.13 0.3 3.6 30 1.79 0.979 100 0.1 0.04 0.1 0.3 0.00 100 0.09 0.18 0.3 1.35 0.65 0.987 8.4 8.2 100 0.08 , 0.06 0.21 1.3 0.52 . 0.784 Reference substa ce (3,5-dichlorophe1): 1.5mgA 0.14 0.47 1.85 1.5mgA 0.16 0.43 1.45 I 1 0.16 1 0.45 1.45 2 .3E 2.9 .39 0 .999 11.19 1 000 8.3 8.2 1.19 0.!9]99 Mean values: 0 0.32 1 3.2 10 32 100 0.13 0.13 0.15 0.15 0.15 0.13 0.09 Referencseubst. 0.15 0.6 8 53 0.8 10 66 0.7 10 65 0.6 7 55 0.5 7 60 0.4 4 39 0.1 0 1 0.45 1 1.6 1 __3-5-1 2.19 2.35 2.30 2.11 2.03 1.90 0.39 26 0.99i 1.000 0.997 0.996 0.991 0.988 Theresuolft he ().917reference substancies 1 1.000 withitnherange normallfyound Lab.refno.: 99312-2 Page8 of31 GROWTH CURVES: GrowthinhibititoenstwithSkeletonemacostatum Testsubstance:"FC-203LightWaterBrandAFFF' Lab.ref.:99312-2 7. Control 5. 3 co cEo @ 2.4 48 72 testduration(hours) -3 7. 5. (A 3 .2 1 mg/l -1 @24 -3 24 48 72 testduration(hours) 7 10 mgA 75. 3 40 co E @@4 -3 J 0,32 mg/i 48 72 testduration(hours) 71 3,2 mg/i 5 3. .1 24 48 72 testduration(tioum) -3 J 7- 32 mgA 3I Em -3 48 72 testduration(hours) 75. SD 3 -31 100 mg/i -A 24 2 nn@(ah oo (haouumm)) 3 48 72 -3 testduration(houm) Lab.refno.., 99312-2 Page9of31 Inhibition of the growth of Skeletonema costatum with: mg/l (FC-203 Light Water Brand AFFF) ------------------------------------------------------- Experimental data: --------------------------------------------------------------------- concentration in Growth rate FC-203 Light Water Brand AFFF Inhibition in percent ---------------------------------------------------------------------- control 1 control 2 Control 3 Control 4 Control 5 Control 6 2.39 2.14 2.29 2.07 2.06 2.20 - Control mean 2.19 0 0.32 0.32 0.32 2.30 0.0 2.32 0.0 2.43 0.0 1.00 1.00 1.00 2.36 0.0 2.41 0.0 2.13 2.8 3.20 3.20 3.20 2.05 6.5 2.12 3.3 2.17 1.0 10.00 10.00 10.00 2.22 1.79 2.09 0.0 18.3 4.6 32.00 32.00 32.00 1.86 2.05 1.79 15.1 6.5 18.3 100.00 0.00 100.0 100.00 0.65 70.3 100.00 0.52 76.3 ---------------------------------------------------------------------- STATISTICAL PARAMETERS CALCULATED FROM CONTINUOUS RESPONSES 5 doses and 11 responses have been used during calculations. EC 10 : EC 50 : EC 90 : 13.33 61.95 288.00 95 % confidence limits : 95 % confidence limits : 95 % confidence limits : 8.29 48.25 186.95 Coefficient of determination :0.763 18.46) 83.10) 562.40) Lab.refno.: 99312-2 Page10of31 TEST FOR TOXICITY MarineherbivorAec:ayWa'tonsa 99312-2 TEST REPORT ACUTE TO)UCITY TEST WITH THE MARINE COPEPODAcarttioansa naPORSK "KREDrrERNG NEF ROGALAND RESEARCH TEST SUBSTANCE: "FC-203 LightWater Brand AFFF" TEST RESULT: The 48 hours LC50 was calculatetdo 200 mg/l. The'testsubstancewas suppliedby Novatech,and thetestresultrselateto thisproduct. TEST DETAILS: METHOD: ISO/DIS 14669 - 1997: Water quality- Determination of acute lethaltoxicity tomanne copepods (Copepoda,Crustacea). TEST oRGANism: Acartiatonsa(Dana),suppliedby theMarine BiologicalLaboratory, Universityof Copenhagen. CULTIVATION: The testorganismswere suppliedas eggs,and were cultivatedinaccordance withthe"ParisCommission -Ring TestProtocol"(VKI). Large copepodites and adultswere used inthetest. PREPARATIONS: NaturaIseawater(salinit3y4: %o)from anunpollutedsiteinBAord was used asbasisforthedilutiownater.The waterwas filteretdhrougha GF/C filter priortouse. Testsolutionwsere preparedfrom a stocksolution.A stocksolutionof 1003 mg/l was preparedby stirring0.5017 grams of the product in I litreof dilution water. Other concentrationswere prepared from thisstock solution. INCUBATION: The testwas run in glasscontainers(28 ml rolledrim vials)each containing 25 ml of testsolutionand 5 animals, 4 replicatesforeach concentration.'.-Thd vialswere kept under a 16h/8h light/dark-photoperioadta temperature of 20 I "C. pH and oxygen measurements were performed as indicatedon the data sheet. Lab.rej."Io.: 99312-2 rage12oj-11 DATA ANALYSIS: CALCULATIONS: TheeffecotnthesurvivoaflAcartitaonsiasexpresseadstheconcentratoifon a productlethatlo50% ofthetestanimals(LC50).The combined mortality pertestconcentratiownere used forcalculationT.he 24 hours and 48 hours LC5o valuesand the95% confidencelimitwere calculatedby usingthe standardprocedurePROBIT Analysis,NationalSwedish Environmental ProtectioBnoard (Version2.3,1990).Thisprogramme alsocalculatteest concentrationlsethalto 10% and 90% ofthetestanimals. NOEC: CalculatioonfNOEC (No ObservedEffectConcentrationi)sdone by singlefactorANOVA followedby Bonferronisprocedureforcomparingeach concentratiomnean withthecontrolmean. TEST RESULTS: Table 1. LC and NOEC valuesobtainedwith "FC-203 LightWater Brand AFFF". Acartiatonsa 24 hours 48 hours LCIO 160 (84-220) 76 (32-110) LCSO 340 (260-460) 200 (140-270) 740 (530-1400) 510 (350-1100) LC90 NOEC: 100 100 Valuesindicat1e001o5,0Yoand 9001olethaliatfyter24 and 48 hours.Unitsinmgll.Valuesare calculatebdy PROBIT analysisa,nd 95% confideweintervalasreindicatedN.OEC arecalculatebdy thecomputerprogramme GraphPad ]nstat3.0. VALIDANON: The validitcyriterigaiveninthetestprotocolarefulfilleidn,thatthedissolved oxygen concentratioanttheend ofthetestwas greaterthanor equalto4 mg/l, thepercentagemortalityinthecontrolwsas lessflm 10%, and the48 hours LC50 of3,5-dichloropheno(lreferencew)as intherangenormallyfound. Lab. ref.no.: Sample received.: Testperiod: Report date: 99312-2 20.09.99 06-08.10.99 06.01.2000 ElinHorve Engineer Analyticatlechnician Age Molve rsmyr SeniorRese h Sciintist QualityAssurance Enclosed: Data sheets T'histestreportisissuedby a laboratorayccreditebdy NorwegianAccreditafio(nNA). The reportmay notbereproducedinany form otherthaninfullw,ithoutthepermissioinnwritinbgy RF - Miljolab. 99312-2 PRIMARY DATA: AcutetoxiciteystwithAcartitaonsa Testsubstance: "FC-203LightWaterBrandAFFF' Lab. ref.: Startdate: Measurement: 99312-2 06.10.99 Number ofdead Concentration (mgA) Control 10 32 100 320 1003 Total number Specimen pr.conc. 30 20 20 20 20 20 Number of specimen prvessel AC E BDF 5 55 5 55 555 5 5 55 5 555 5 5 55 5 555 5 NUMBER OF DEAD 24 hours 48 hours ACE BDF Total A CE BDF Total 000 000 001 1 101 2 0 00 010 0 0 0 1 0 00 001 1 1 1 2 1 00 201 0 1 1 4 2 12 3 44 2 7 3 14 5 55 555 5 20 5 20 Reference substance (3,5-dichlorophenol): 1.0 mgA 55 020 254 30 5 5 55 100 3 130 15 The resuftwith the referencesubstance is withinthe range nonnallyfound. 99312-2 Testsubstance: "FC-203 LightWater Brand AFFF' Lab. ref.: Startdate: 99312-2 06.10.1999 Aleasurements of oxygen and pH. Start Concentration Oxygen pH (mgA) (mgA) 24 hours 48 hours Oxygen pH Oxygen pH (mgA) (mgA) Control 7.6 8.1 7.2 8.1 10 8.1 8.1 7.3 8.2 32 8.1 8.1 7.1 8.2 100 8.1 8.1 6.7 8.2 320 8.0 8.2 6.1 8.1 1003 7.3 8.2 6.6 8.1 Reference substance (3.5-dichl6rophenol): 1.0mgA 7.7 8.1 7.3 8.2 99312-2 TEST FOR TOXICITY MarineAmphipode:Corophiumvolutator Lab.i-c,j.iio.: 99312-2 Page16of31 TEST IZEPORT ACUTE TO)ACITY SEDIMENT TEST WITH THE MARINE AMPHIPODCorophium volutator an ROGALAND EA RCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: The IOd LC50 was calculated to >3060 mg kg-1 dry weight sediment. The testsubstancewas suppliedby Novatech,and thetestresultrselatetothisproduct. TEST DETAILS: METHOD: ASTM E1367-90, StandardGuide For Conducting 10 day StaticSediment ToxicityTestswith Marine and EstuarineSediments. TEST ORGAMSM: Corophium volutatorf,rom an unpollutesditenearTrondheim. CULTIVATION: The testorganismswere suppliedas adults(4-8mm insize)and were heldin aeratedseawaterat 15*C. A smallamount of naturalseaweed was used for feeding. PREPARATION: Naturalseawater(salinit3y4: %o) from an unpollutedsiteinBAorden outside Stavangerwas used fordilutiownater.Sediment conectedatan unpollutedsite was used forpreparingtestsediments.The sedimentisa muddy sand and was analysedfororganiccontentand proportionsilftoreach test. Each testconcentratiownas preparedby addingtheproductin600 grams of damp sedimentina plastibcucket.200 ml of seawaterwas added and the bucketwas shakenfor3 hours.The sedimentwas dividedintothreebeakers, 400 ml of seawaterwas added to each,and thebeakerswere aeratedover night.10 animalswere thenrandomly selectedforeachbeaker.A sample qf thedamp sedimentwas analysedforwater content,and allconcentrationasre calculateads mg kg-Isedimentdryweight. INCUBATION: The testwas run inglasscontainer(s600ml) each containing200 9 of test sediment,app.400 ml of seawaterand 10 animals,3 replicatefsoreach concentrationT.he beakerswere keptunder continuousaerationata temperatureof IS 1*C. PH and oxygen measurements were performed as indicatedon thedata sheet. 99312-2 DATA ANALYSIS: CALCULATIONS: TheeffecotnthesurvivoaflCorophiumvolutatiosrexpresseadstheconcentratioonfa productlethalto50% ofthetestanixnal(sLCso).The combined mortalitypertestconcentratiownere used forcalculationT.he 10 day LC50 valueand the 95% confidencelimitarecalculatebdy usingthestandard PROBIT Analysis,NationalSwedish EnvironmentalProtectioBnoard (Version 2.3,1990).Thisprogramme alsocalculatteestconcentrationlsethalto 10% and 90% of thetestanimals. NOEC: CalculatioonfNOEC (No Observed EffectConcentrationi)sdone by singlefactorANOVA followedby Bonferronisprocedureforcomparing each concentratiomnean with thecontrolmean. TEST RESULTS: Table 1. LC andNOEC valuesobtainewdith"FC-203LightWaterBrandAFFF" Corophiuvmolutator 10days LCIO LCSO LC90 >3060 >3060 >3060 NOEC: 3060 Valuesindicat1e001o5,001aond 9001loethaliatfyter10days.Unitsinmg kel sedimentdryweight. ValueasrecalculabtyePdROBITanalysiNsO.EC arecalculabtyetdhecomputeprogramme GraphPaIdnSta3t.0. VALIDATION: The validitcyriterigaiven inthetestprotocolarefulfilleidn,thatthedissolved oxygen concentrationattheend of thetestwas greaterthanor equalto60 %, thepercentagemortalityinthecontrolswere lessthan 15% and a testwith Fluorantene(referencew)as intherangenormallyfound. The sedimentused isfound tobe withinacceptedlimitsfororganiccontentand siltfraction. Table2. Characteristoifctshesedimentusedfortesting Organiconten(t*/o) 0.7 Silftraction 0.8 Lab. ref.no.: Sample received.: Test period: Report date: 99312-2 20.09.99 03-13.12.99 06.01.2000 ElinHorve Engineer Analyticatlechnician Age Molversmyr SeniorResearch Scientist QualityAssurance Enclosed: Data sheets ThistesrteporitsissuebdyalaborataocrcyreditbeydNorwegiaAnccreditat(iNoAn).TheTepormtaynotbereproduciendany formothetrhaninfulwli,thoutthepermissiionnwritinbgyRF -Miljolab. 99312-2 PRIMARY DATA: AcutetoxicitteystwithCorophiumvolutator Testsubstance: "FC-203LightWater BrandAFFF' Lab. ref.: Startdate: Measurement: 99312-2 03.12.99 Number ofdead Total number Number of specimen pr.vessel Concentration Specimen A C E (mg/kgdryweight) pr.conc. B D F Control 10 10 10 60 10 10 10 10 10 10 91.1 30 10 10 10 501 30 10 10 10 1030 30 10 10 10 3060 30 NUMBER OF DEAD 5 days ACE BDF Total 10 days AC E BDF Total 000 0 00 0 200 2 1 01 2 100 1 1 02 3 Reference substance (fluoranthene): 20.3 10 10 10 30 322 7 The resultwiththe referencesubstance iswithinthe range normallyfound Lab.refyio.: 99312-2 Page19of3l Testsubstance: "FC-203 LightWater Brand AFFF" Lab. ref.: Startdate: 99312-2 03.12.99 Aleasurements of oxygen and pH. Start Concentration Oxygen pH (mg/kgdryweight) (%) - Control 94 8.1 5 days Oxygen pH (%) - 91 8.1 91.1 96 8.1 93 8.1 501 77 7.8 92 8.1 1030 97 8.1 93 8.1 3060 97 8.1 74 7.7 10 days Oxygen pH (0/.) - 91 8.0 88 8.1 90 8.1 86 7.9 91 8.0 Reference substanc uoranthene): =20-3 95 8-1= 90 8.1 90 8.1 Lab.ref.no.: 99312-2 Page20 of31 DATA SHEETS Lab.ref.no.: 99312-2 Page21of31 EMS-DATABLAD (.tielse-m,iljo- 09 S;-kkerhetsdatablad) Dokumentnr.: Mrstatter 10-3814-0 02/10/97 Utgitt Sk--evet ut : 03/11/98 Versjon : 11/11/98 Side 06. 00 1 av i: HMS-databladet er utarbe;-det av Miljeavdelingen Telelon: 63 84 75 00 / Telefax: 63 84 17 88 ved 3M Norge A/S. ------------------------------------------------------------------------- I ZD7NTIFIKASJON AV Kj'rMIX@-@TIET OG ANSVARLIG FI.RM.A. ------------------------------------------- ,------r----------------------- Imporl@or: 3M Norge A/S gandelsnavn: FC-203 LIGHT WATER B.RAND AQUEOUS FILM FORMING FOAM Deklarasjonsnum-ner, Produktregistere-.:P-nr.: 002614. Telefon, Gi-,-Fti-n!o---nasjonssentralen: 22 59 13 00 ------------------------------------------------------------------------ 2 OP?LYSNT-NG---R OM SXM14ENS---'.rN!NG. ------------------------------------------------------------------------ in@lo--mas)on om enkel-tkomoonenter, faresymbol(er) og risikosetninger ST017FNAV.N------------------------------------- VANN 2-(2-BUTOKSYETOKSY)-ETANOL (Dir-TYL-=NGLYKOLMONOBUTYLET'-rR) Faresymboler/risi-kosetninger: Xi; 1,2-ETANDIOL Faresymboler/risikose- -ninger: SYNTETISKE DET-=RGENTER FLUORALKYL OVERFLATEAKTIVE STOFFER RESTER AV ORGANISKE FLUORKJEMIKALIER Xn; CAS-nr V"ZKT-PROSENT ------------------ ------------- 7732-18-5 112-34-5 36 40 35 R:36 107-21-1 R:22 Trade Secret Trade Secret Trade'Secret 20 I I Ikke -5 -5 kjent ------------------------------------------------------------------------ 3 VIKTIGSTE FAREMOM---NT---R. ------------------------------------------------------------------------- Lab.ref.no.: 99312-2 FC-203 LIGHT W2kTER BRAND Page 22 of31 AQUEOUS FILH FORKING FOAM Viktigste skadevirkn;-nger Helse!are: Kan irritere eynene og huden. Sikkerhat: miljo!are: Soesialav!all. ------------------------------------------------------------------------ 4 FORSTR-HJELPSTILTAK. ---------------------------------------------------------------------- Tiltak eyne: Skyll s-@raks eynene um'ddelbart. med rikelige mengder vann. Kontakt lege T;-ltak hud: SkY!l huden med kontak-@ lege. r4kelige mengder vann. Evis ir?-itasjonen vedvareri Tiltak innhnding: Hvis symp-omer ozostir,-bring eksmoneringskilden. Sorg for kontakt lege. vedko=nende bort fra frisk luft. Hvis symptomene vedvarer, Tiltak svelg;ng: Kontakt lege um;-dde2.bart.'Fremkall b--ekn;-nger kun i sa=id med medi-s,-nskpersonell. Gi aldr4- noe gjennom munnen ti-1 en bevi-sstles person. -----------------------------------------------------------------------5 TILTAK VED B.@LANNSLUKNT-NG. ------------------------------------------------------------------------ Egne'@ brannslukningsm;-ddel: Produkte-. er et brannslukkingsmiddel. Ikke egnet brannslukningsmiddel: Eksponeringsrisiko ved brann: Forbrenningsprodukter ved brann: Prosedyrer ved slukking av brann: Lab.refno.: 99312-2 Page23of31 FC-203 LIGHT WATER BRAND AQUEOUS FILH FORMINC;ROAH -----------------------------------------------------------------------6 TILTAK V---DUTILS ---KT---UTTSLli@P. --------------------------------------------------------Z---------------- Personlige vernetiltak: Se vernetiltak under andre punkter i dette EMS-databladet. Tiltak ved utils4-ktetutslico: Ventiler omrkdet. Spill avgrenses umidde'Lbart.Dekk til med et absorberende ma-.e--iale.S-mill samles o.o-oumiddelba@-t. Rengjor om--kdet med vain. Plasseres i en egne-,beholder med lokk. Fierni-ngav kjem4-kalieavfall: Se punkt 13, rjerni-ng av kjemikal;-eav-@'all. -----------------------------------------------------------------------7 H.4TOTE.RING Or. OPPB7-VA.RT-NG. ------------------------------------------------------------------------ Beti-ngelser for s.4;.kkeorldpbovaring: Mi ikke lagres i om--Ader hvor produk-@et kan komme i kontakt 'med mat eller lagem;-dler. Lagres ved temoera--urunder 49-grader cels4-us. Lagres ved -@enoeraturer over 0 grader cei-sius. Hold behol-deren te-.-6li-,kke-r@ir Droduktet -kke er i bruk. U!orene!4-ge mater4-aler: Vent4-lasjon: Oppbevar embal-l-asjenpi et god-6 ventilert sl@ed. Sikkerhe-6s4--iltak-for A @lorh;-ndrebrann: Sikkerhe-6stiltak for & forh;-ndre eksolosjon: ikkebrennbar, Sikkerhetstiltak for A forh;-ndrestatisk elek,@risitet: Forholdsregler ved b@-uk: Hold emballasjen tett lukket. Royking 4orbudt: Under bruk av produktet kan reyking @orkrsake forurensning av tobakken og/eller -eyken og fa.-I;ge dekomponeringsproduk-er kan dannes. Se punkt 10, stabili-6 et ag reaktivi@6et, skadelige dekomponenter. ---------------------------------7-------------------------------------- 8 EKSPONERINGSKONTROLL OG PERSONLIG VERNEUTSTYR. ------------------------------------------------------------------------ 99312-2 Page24of3l FC-203 LIGHT WATER BRAND AQUV-OUSFILM FORMING FOAM Oyevern: unngi A fi damp, sprav eller t&ke i eynene. Bruk tette vernebrillor med ventil-er. Hindvern: Bruk egnede vernehansker hindtering av produktez. anbe!ales: Bu--ylguirm;-. av hens4;.ktsmessigmate.-iale ved ve--nehanskerav folgende ma-,eriale(r) Annet hudvern enn h&ndvern: Unng& hudkontakt. indedrettsvern: Unngk innind4-ng av lu!tb&ret materiale. Basert*p& konsentrasjonen av luftforurensninger ;-arbeidsatmosfaren velges en av folgende -@ype(r) godkjent &ndedrettsve?--n:halvmaske med fil-6ermot organiske da-.%zerog v2ske!orm;-ge partikier: A/P2SL. Sve-lg4-ng: Det mi ikke sp4-ses, dr4-kkes ell-a-zreykes under arbei-d med produk@@et. Vask utsaz-@e om--Ader grundig med s&pe og vann. hendene et-.er h&ndter4-ng og for spising. Vask Anbe@cait ventil-asjon: Evis utsugni-ngsvent4-lasjoni-kkeer tilstrekkeli-g,m&.egnet godkjent knded--ezzsvernbenyttes. Sorg for t;-lstrekkelig ven@lilasion s!4-k at da@-nDkonsent=asjonene holdes under anbe-4alte adm;-nistra-:;-vneo--merog/eller kontroller spray eller t&ke. Adm. normer for forurensni--g i arbe;-dsatmosfare, Februar 1996z VANN (7732-18-5) A.-merkn4-nger: ingen ad-@i.no=. 2-(2-BUTOKSYETOKSY)-ET.:kNOL / (DIETYLT-NGLYKOLMONOBUTYL7T7R) (112-34-5) 6-timers verdi Diom: 35 Anmerkninger: A@erikansk grenseverdi anbe4-alt av produsen-@en. (Ingen norsk adm. norm). lr2-ETANDIOL (107-21-1) 8-timers verdi ppm: - (stev) $-timers verd;-mg/m3: 10 (stov) Takverdi- ppm: 25 (damp) Takverdi- mg/m3: - (do--no) SYNTETISKE DETERGENT7-R (Trade Secret) Anmerkninger: Ingen adm. norm. FLUORALKYL OvERrLATEAKTIV--- STOFFER (Trade Secret) Anmerkninger: Ingen adm. norm. RESTER AV ORGANISKE FLUORKJEMIKALIER.(Trade Secret) 8-timers verdi mg/m3: 0,1 Grenseverdi anbefalt.av 3M. .Lao.rej.no.: 99312-2 Page25of31 FC-203 LIGHT WATER BRAND AQUEOUS FILH FORKING FOAH ------------------------------------------------------------------------ 9 FYSISKE OG KJ---MISv%EEGENSKA-DER. ------------------------------------------------------------------------ Tilstandsfo--m,!arge, lukt: Klar, rav!arvet vaske. Kokepunkt/-in-.ervall: ca. ca. 100 C (Begynnende) Smalteounkt/-in-@ervall: Flamezunkl@-: Ikke relevant ingen (Setaflash'CC) Selvantennelighet: Ek solosjonsgrenser, nedre: Ikke relevant Ikke relevant Eksplosjonsgranser, ovre: Da.-,iptrykk: Ikke relevant ca. 14.3 mmHg (Kalkulert v/rom-@emoeratur) Loselighet i vann: Blandbar. Spesifi-kkvekt: ca. 1.05 (vann-1) Di,-motet,6.het: ca. 1.21 (luft-1) (Kalkulert v/20C) Flyktige organiske forb4-ndelser (VOC): = 578 g/i SCAQMD Kalkuler"6 v/20C. Fozda.*noningshast4-ghet: < 1 (bu--Ylacetal.-l) V46skosite-6: Ikke kjent -----------------------------------------------------------------------10 STABILITET OG REA.XTIVITET. ------------------------------------------------------------------------ Forhold som skal unng&s: materialer som skal unngis: ikke kjent. Farl;-gespaltningsorodukter: Karbonmonoksi@ og karbondioksid. Hydrogenfluorid. Giftige dampere gasser eller partikler. Dekomponering av bruksferdig blanding forventes ikke i representere n@en risiko. Lab.ref.no.: 99312-2 Page26of31 FC-203 LIGET WATER BRAND AQUEOUs FILM FORMING FOAM Stab4.14-te@@og reakt;-vi-@et: Stabilt. Farlig polymer;-sasjon vil ikke forekomme. ----------------------------------------------------------------- 11 OPPLYSNINGER OM F.'-zy-SEFArt-=. ------------------------------------------------------------------------ Effek4.-ereyne: Mild eyeirritasjon: svmptomer kan vere redhet, hevelse, smerter og t&rer. Effekter hud: mild hudi-rri---asj(oent@.erlangvarig eller gjentatt kontakt): symptomer kan vere redhet, hevelse og klee. Effekter i-nnindi-rg: En enkelt ove-@eksponer;-ngsom overstiger no-@mer, kan fo--e til: anbe'6alte administrative Pivirkni-ng av sen,@-ralnervesystemet: symp','omerkan vere hodet)ine, orhet, sevn;ghe--, manglende koordi-n.asjonsevne,nedsatt reaksjonsevne, si-ore-t-ale, svin=elhet og i.ekstreme tilfeller bev,-ssA-Ileshe@@. irritasjon (ovre luftve4er): symptomer kan vare si--he-i@ nese og svelg, host4.ng og nys;-ng. -7--Fz-ektesrvelg;-ng: Dyreforsek u-,!orr-med organ;-ske fluorkjemikalier, som finnes i det'leproduktet, vi-ser ef!ek-@er som leverfors tyrrelser, vekttap, manglende appe--i-t-.s,lovhet samt effekter som p&virker neurologi, bukspyt-.,binyre og hematologi. De-.foreligger ingen kjente helseeffek@-.erfo.-mennesker fra eksponering overfor organiske '&luorkjemikalier n&r de brukes som fo--Utsatt og tihenhold ti'&. veiledning. Svelging kan-fore til: Pivirkning av nyrene: symptomer kan vare redusert uri=engde, blod i urinen og rvggsmerter. AspirasjonsDneumoni (Lurgebetennelse som skyldes at fremmedlegemer ko=er ned i lungene. En alminnelig irsak til tilstanden er o.opkast.): symp-@omer kan vare hosting, pustevanske@-, gisp4-ng, hoste opp blod og lungebe-.ennelse som kan vare livst--uende. Informasjon om allerg;-,overfelsomhet: Kreftfremkallende egenskaper: Lab.refno.: 99312-2 Page27of31 FC-203 LIGHT WATER BRAND AOU'-POUSFILH FORHING FOAM Arves-@ofl&skadeligeegenskaper: Reproduksjonsskadelige egenskaper: Andre skadevirkninger, helse: Et resyml vedrerende produkte@.sgiftighet er tilgjengelig pi, foresporsel. Dette produk@let innehaider en eller flere organ4-ske fluorkjemikalier, som muligens kan absorberes og lagres i kroppen over lengre tid, enten som utgangsmolekylet eller som nedbrytningssto@Ifer (metabol4-tter),og kan akkiimuleres ved gjentatte eksponeringer. Det foreligger 4-ngenkjente helseeffekter for mennesker fra eksponering overfor organiske fluorkjemikalier. nkr de brukes som .1orutsat-@og i hen*.-,oltdil veiledning. Forakomsten av orga-4-ske fluorkjemikalier i blode%&.til den generelle be!olkn4@-gen og underdopulasjoner som aroe;-dere, har vmrt publ4-sert s;-de,-1,970 &--ene. 3ms epidemiologiske studier av egne arbeidere viser ingen skadelige el-'&ekter. - ------------------------------------------------------------------------ 12 OPPLYS.4!NGER OM MILJO.7.@-R---. ------------------------------------------------------------------------ Pezsis@@eis/Biolog4-sk nedb@--ytbarhet: Del@te produkte-W -i-nneholderen eller flere organ4-ske fluorkjemikalier to-amuligens ikke er nedbrytbare og forblir 4miljoet (persisten-.e). Andre skadevirkn4-nger, m4-ljo: Ned.bry-6barhet: COC (Chemical Oxygen Demand) 1,1 g/g; BOD 20 dagers (Bioc@,enical Oxygen Demand) BOD 20 dagers/COD = 1,00. 1,1 g/g; Akvatisk giftighet: Statisk 96 timers LCSO for fisk (Fathead minnow (Pin@ephales promelas)) - 750 mg/l; Statisk 95 timers LC50 for fisk (Rainbow trout (Oncorhyncus mykiss)) - 1300 mg/l; Statisk 48 timers LCSO for daphnia (Water flea (Daphnia magna)) 1600 mg/l (1300-2100 mg/1); statisk 48 timers LCSO, Amfipode (Scud (Gammarus fasciatus)) 1100 mg/l (840-1300 mg/1); 48 timers EC50, Eastern oyster embro-larvae (Crassostrea virginica)*- 47 mg/l (10-234 mg/1); 48 timers LCSO, Common mummichog (Fundulus heteroclitus) - 2500 mg/l (1700-3600 mg/1); Lab.refn.o.: 99312-2 Page28of3l FC-203 LIGHT WATER BRAND AouEous rilm roRMING FOAM (360-710 mg/1); IC50 Respirasjon, Activated sludge - > 1000 mg/l; TTC (2,5,5-trifenyltetrazoliumklorid)test viste 4ngen ensymhemning for konsentrasjoner opp ti-l-1000 mg/1- Sorg -forav-4a!lshindteringiht. gjeldende forskrifter. -----------------------------------------------------------------------13 FJERNING AV KTR-MIKALIZAVFALL. ------------------------------------------------------------------------ Metoder for fjerni-ngav kjemikalieavfall: Sp esialav-Fall.Lever av4.6 all til en of-'entli?gjodkjent innsamler, mot%'.aks-eller behand!4-ngsanlegg for spesi-alav!all. Anbe@Ialte av-fallsgrupper: HOV-ZDKATEGOR! 07: AVFALL FRA ORGANISKE P.AOSESSER. UNDE.RKATEGOR! 07 06: Avfall fra PBDB av fetts-offer, s&pe, rengjoringsm4-dler, desinfeksjonsmidler og kosme-@ikk. EA:<-kode 07 06 03: Halogenerte organ4-ske losem,-*dler,vaskevesker og moderlu-,. Avfalistof,6nummer: 7151 Organisk av&lal'-med halogen. Spes,-elle ko,-,.ponen--e-i-n:nehoider 9-lour @4orb--ndei-ser. ------------------------------------------------------------------------ 14 OP?LYSNINGER OM TRA6NSPORT-. ------------------------------------------------------------------------ ADR-kiasse: s;-ffer: - bokstav: - margnummer: - CEFIC-kort: - UN-nummer: - ICAO-klasse: - IMDG-klasse: I14DG-s ide: EMS-nr.: MFAG: Lab.ref.no.: 99312-2 Page 29 of31 FC-203 LIGHT WATER BRAND AQUEOUS PILH FORHING roam evrige opplysni-nger: Ikke transport!arlig gods. -----------------------------------------------------------------------15 OPPLYSNINGER OH LOVER OG r.0RSKRIFTER. ------------------------------------------------------------------------ Merkeeti-kett: Symbol(er): H7-LSES.'<ADELIG (Xn) inneholder: 2-(2-butoksyezoksy)-etanol 35% Etylenglykol 20% R-setninger: Farlig ved svelgi-ng. Kan irritere eynene og huden. S-setn4-nger: Unng& inninding av damo/sp-royte-@ike. Unngi kontakt med huden og' oynene. Fir man s@@offez i oynone; skyll s-@raks grundig med A-@ore mengder vann og kontakt lege. Etter hudkon-@akt, vask-med s&ze og vann. Ved svelgi-ng, kon@@akt lege omg&ende og vis denne beholderen eller e'l@;-ket%'.Keunn. til industr4-ell bruk. Ikke beregnet til bruk som medi-si-nsk u-@styr eller legem4-ddel. YL-gruppe: 00 Korr. yrkeshyg. lul-tbehov: Ovrige applysni-nger om merkeetiketten: Ovennevn-@e merk;-ng er basert p& tidligere merkeforskri!ter og v;-l vare A finne p& produktet en tid fremover. Herki-ngen vil imidlertid erstattes av folgende merking, som er basert pi reviderte merkeforskri---Fterav januar 1998. Symbol: Ingen Inneholder: 2-(2-Butoksyetoksy)-etanol, 1,2-etandiol Kan irritere oynene og huden. Unngh inn&nding av damp /sproytetkke. Unng& kontakt med huden og eynene. F&r man s-%.offeti eynene; skyll s-@raks grundig med store mengder vann og kon-.akt lege. Fkr man stoff p& huden, vaskes straks med store mengder s&pe og vann. Ved svelging, drikk to glass vann og kontakt lege umiddelbart. YL-grucce: 00 Lab.ref.no.: 99312-2 Page30of31 rC-203 LIGHT WATER BRAND AQUEOUS pILm FORHING FOAM Spesielle lover og bestemmelse_-: 1. Forskri!t om utarbeidelse og distribusjon av Helse-, Miljo- og Sikkerhetsdatablad for farlige kjemikal4-er. 2. Forskrift om klassi!isering og mark;ng av farl4-gekjerrikalier. 3. Forskri--4otm klassifisering, merk4_ng M.V. av stoff som kan med!ore mi-l-jefare. 4. Forskr4-ft om stofl@karto-@ek. S. Forskri.Itom spes4-alavfall. 6. Etc. ----------------------16 ANDR-7 OP?LYSNT-NGER AV BETYDNING FOR BRUX=-RNES SIXK---I@-tiEOTG HELSE. ------------------------------------------------------------------------ Anvendelsesor=ider: Filmdannende skumkonsen-,ra@.for slukking av brann i hydrokarboner. V;-kl@;-gstkeilde(r) ved utarbeidelsen av HMS-databladet: Datablad fra 3H General offices, St. Paul, Minnesota, USA. irsak til ol.Dodater4-ng: Hele da-.ablade-.er revi-dert. Ti-loasse-.nye me--ke- og HMS-databladlorskrilze=, fasts&-.ti januar 1998. Etc! Egne o.D.zlysn4--.ger: In'@o--masjonenpi dette .=.MS-da-@--ablaedreti henhold til vire niverende opplysninger og bes@@e 'oopfatning angkende rikt;-gbruk og hindteringen av dete produktet under no--maleforhold. Enhver bruk av produktet som k ke er 1 samsvar med dette F.MS-da@@abladet,eller som medforer bruk av produktet i kombinasjon med andre produkter eller enhver annen prosess er brukerens ansvar. Lab.ref.no.: 99312-2 Page31of31 FC-203 LIGHT WATER BRAND AOUEOUS RILM roRMING ROAM FOLGENDE PRODUKTER D7-XKr-S AV DETTE RMS-DATABLADET: 3M ID-nr. X---0008-0217-3 3H A-7FF FC-203 Brannslukningss kam P-oduksjon 3M ID-nr. : XF-0008-0099-5 3H Light water 3% AFFF Fire Fighting Foam, FC-203,1000 L 3M ID-nr. 3H ID-nr. : XF-0008-0070-6 3M Light Water 3% AFFF Fire Fighting Foam, FC-203, 200 L : X'@'-0008-0069-8 - 3M Light Water 3% AFFF Fire Fi-ght4-ng Fo&,n, FC-203, 20 L