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DOW CHEMICAL U.S.A.
LOUISIANA OIV1*ION p. O. SOX 1*0
PlAOUtMINf. LOUISIANA 707S4
W4 Ht.1000
INDUSTRIAL HYGIENE REPORT
SUMMARY
The asbestos in air monitoring for the first half of 1980 has been completed in the Chlor-Alkali II block. Survey results were satisfactory and well below the acceptable threshold limit value of 2 fibers per cubic centimeter greater than five (5) microns in length.
The highest exposure recorded was 0.40 fibers per cc of *ir. Due to the low results obtained in routine time-weighted sampling, it is recommended that short duration excursion sampling be emphasized in future surveys.
Good housekeeping, strict safe operating procedures, and a constant vigil for problem areas are the most important considerations for a successful abatement program. Employees must be informed of the sur vey results and must review the consequences of over-exposure to asbestos fibers. (See Attachment 2.)
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DISTRIBUTION
LOUISIANA
M. F. Currier - 2303
L. W. Raopy - 1803
*F
G. W. Daigre
- 2501
H.
Swank - 1803
*R
E. P. Edwards
- 3701
*S
C. L. Melancon - 4701
*R
V. j. Neely
- 2306
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0i tit WuUari ; Ju 0601
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y,- 2501 OMMTM UNIT 04 YHS OWN CMMMCAL COMPANY
D. Axe - Pittsburg L. Daniel - Freeport A. Goode - 0CD J. McCormick - Strongs D. Olsen - Sarnia
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DOW CHEMICAL U.S.A.
INTRODUCTION
LOUISIAN* OIVKION
a o. sox no ALAOLMMMM. LOUISIANA TOTS
The required asbestos in air monitoring for the flrst*Tiaf*o?
1980 has been completed. The survey serves to protect the employees against over-exposure, pinpoint problem areas and
fulfill the requirements of the Federal Occupational Safety and Health Act.
DISCUSSION
In addition to everyday safety equipment, operators are required to wear disposable paper suits, rubber gloves and proper dust respirators when handling or working with asbestos. The safe procedure for handling asbestos should be discussed with each new employee before entering the work area and reviewed annually with the experienced operators as part of the ongoing Industrial Hygiene Education Program.
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EXPERIMENTAL
Sampling Method
Personnel samples are collected from the operators' breathing zone with a millipore filter (37 mm diameter; 0.8 micron pore size) mounted on an open-face filter holder and attached to the operators' lapels. These cassettes are connected to monitoring pumps calibrated with a soap bubble meter to operate at a rate of 1.5 to 2.0 liters per minute.
Analytical
The asbestos samples are analyzed using the NIOSH Approved Method, P A CAM 239.
RESULTS (See Attachment 1)
Six personnel samples were collected from the operators' breathing zones.
Monitoring results of the six samples indicate all samples were well below the present exposure limit of 2 fibers > 5 microns in length per cubic centimeter. Highest recorded sample was 0.40 fibers per cc.
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RECOMMENDATIONS
Further short-term excursion sampling is recommended in future sampling to better determine if problems exist in some Jobs.
CONCLUSIONS
The monitoring results were satisfactory and well below the established exposure limit of two fibers per cubic centimeter. However, due to the hazardous nature of asbestos, housekeeping and good safe operating procedures remain the most important considerations for a good abatement program. This must be a daily, Job-by-Job program to be successful and to offer the greatest protection to the employee.
The Chlor Alkali II employees must be informed of this survey's results and the consequences of over-exposure reviewed. (See Attachment 2.)
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DATE 5/15/80 3/20/80 4/9/80 5/1/80 5/28/80 5/28/80
SAMPLE # 266 434 443 444 450 451
ATTACHMENT 1
SAMPLE DESCRIPTION
DURATION (MIN.)
OTT - Pulping Celia
85
OTT - Pulping Celia
60
SOT - Pulping Celia
45
OTT -> Pulping Celia
65
OTT - Pulping Celia
105
SOT - Pulping Celia
90
VOLUME (1)
144.5 t02.0
76.5 110.5 178.5 153.0
FIBERS/ >5 MICRON IN LENGTH
< 0.01 < 0.01
0. 10
0.03 0.05
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10/9/80 sb
CONSEQUENCES OF OVEREXPOSURE
COMPOUND: Asbestos
EXPOSURE LIMIT:
2 >5fibers/ml /
microns in length
ODOR:
none
EYcS:
Contact with the dust can cause irritation SIMILAR TO THAT CAUSED BY SIMILAR FOREIGN BODIES.
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TN6ESTI0N:
Some evidence indicates that swallowed ASBESTOS MAY INCREASE CHANCES OF STOMACH
CANCER.
DUST INHALATION:
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Long Term:
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OF THE DUST HAY CAUSE MODERATE
DISCOMFORT. INHALATION OF
MODERATELY HIGH CONCENTRATIONS
MAY CAUSE NO DISCOMFORT.
Inhalation of the asbestos fibers
IN CONJUNCTION WITH SMOKING HAS SEE
SHOWN TO INCREASE CHANCES OF LUNG
90CANCER BY. A50UT
TIMES THAT OF A
PERSON WHO NEITHER SMOKES NOR WORKS WITH ASBESTOS. CAN ALSO CAUSE A
SERIOUS LUNG DISEASE CALLED AS3ESTO Can also cause cancer of the chest
LINING.
COMMENTS:
Proper respirator is required when working with asbestos.
BSHorvath 6/22/76