Document zdz1yBL7J1JEDN5OzEDB1y9BB

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY, REGION 2 CARIBBEAN ENVIRONMENTAL PROTECTION DIVISION MULTIMEDIA PERMITS AND COMPLIANCE BRANCH NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM COMPLIANCE EVALUATION AND SAMPLING INSPECTION INDUSTRIAL FACILITY FACILITY OWNER / OPERATOR PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP 1 Estate Hope, Christiansted, Virgin Islands 00820-5652 Telephone Number: (340) 643-2265 FACILITY PETROLEUM REFINING & BULK FUELS STORAGE TERMINAL 1 Estate Hope, Christiansted, St. Croix, Virgin Islands Virgin Islands 00820 Coordinates: Latitude 1742'53.24" N; Longitude 6445'26.30" W Statute: Sections 301(a) and 308(b) of the Clean Water Act NPDES Regulations: 40 C.F.R. Parts 122, 124 and 419 TPDES ID Number: VIU005563 Inspection Dates: June 10 to 14, 2024 Key Participating Personnel: Environmental Protection Agency: Jim C. Casey, Senior Environmental Engineer Clean Water Act Team Molly Hillenbrand, Life Scientist Monitoring Operations Section Robert Morrell, Senior Geologist Monitoring Operations Section Jos A. Rivera, Lead Environmental Engineer Clean Water Act Team Thuan Tran, Senior Physical Scientist Monitoring Operations Section Department of Planning and Natural Resources: Courtney Dickenson Environmental Engineer Tel.: (340) 773-1082 courtney.dickenson@dpnr.vi.gov George Patrick Deputy Director Tel.: (340) 773-1082 george.partick@donr.vi.gov Port Hamilton Refinery and Transportation, LLLP: Fermn Rodrguez Vice President & Refinery Manager Tel.: (340) 643.2265 fermin.rodriguez@phrt.com Catherine Elizee Environmental Manager Tels.: (340) 692-3389 / (340) 244-9171 catherine.elizee@phrt.com Curtis Green Consultant, Pinnacle Tel.: (340) 474-4235 curtis.green@phrt.com Shay Glasgow Consultant, Pinnacle Tels.: (340) 513-0498 shay.glasgow@phrt.com Phillip Mead Consultant, Pinnacle Tel.: (340) 690-8097 philip.mead@phrt.com PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 2 of 11 Inspection Report Prepared by: Inspection Report Approving Officer: Inspection Report Approving Officer: __________________________ __________ Jim C. Casey Date Senior Environmental Engineer Clean Water Act Team Email: casey.jim@epa.gov; Tel.: (202) 655-1137 __________________________ __________ Jos A. Rivera, BSCE Date Enforcement Officer / Lead Environmental Engineer Clean Water Act Team Email: rivera.jose@epa.gov; Tel.: (787) 977-5842 ROBERT Digitally signed by ROBERT MORRELL MORRELL Date: 2024.08.13 ___________________1_3_:3_0_:2_2_-_04'00' __________ Robert Morrell Date Senior Geologist Monitoring Operations Section Email: morrell.robert@epa.gov; Tel.: (848) 229-5054 __________________________ __________ Nancy Rodrguez, P.E. Date Supervisor Multimedia Permits and Compliance Branch Email: rodriguez.nancy@epa.gov; Tel.: (787) 977-5887 PHILIP Digitally signed by PHILIP COCUZZA COCUZZA Date: 2024.08.13 ___________________1_3_:3_5_:3_1_-_04'00' __________ Phil Cocuzza Date Supervisor Monitoring Operations Section Email: Cocuzza.phil@epa.gov; Tel.: (732) 321-4478 PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 3 of 11 TABLE OF CONTENT Page A. Executive Summary B. Pre-Inspection Activities a. Announcement of Inspection (to PHRT) b. Post-Announcement Discussions (EPA with PHRT) Monday, June 10, 2024 C. Pre-Field Activities a. Entry Meeting & Escort Coordination (afternoon) D. On-Site and Off-Site Field Activities Tuesday, June 11, 2024 a. Reconnaissance on the Influent Waste Streams flow path 1. Tank#7418, Bundle Wash Bay, DGF Unit 2. Track waste stream into WWTP (Jim, Bob in morning) b. Walkthrough of Sections/Industrial Activities (Industrial Process) (Jim) 1. Coke Domes, PWS, and Coker 2. Walkthrough of Industrial Stormwater areas: (Jose) PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 4 of 11 Coke Domes, All- American Channel, Ice plant, Stormwater Outfalls along eastern boundary (Outfall 011, 012, 006, 007) c. Sampling Activities (Bob) Wednesday, June 12, 2024 On-Site and Off-Site Field Activities (cont'd) d. Review of Records (morning) (Jim, Jose) e. Sampling Activities (Bob) f. Walkthrough of Sections/Industrial Activities: (Jim) 1. Sandblasting Operations, Spent Waste storage, Scrap Metal Opers 2. Rail-Con staging and storage area 3. Waste Management Area (Haz & Non-Haz Wastes) 4. Machine & Maintenance Shop Thursday, June 13, 2024 g. Sampling Activities (morning): Intake h. Walkthrough of Sections/Industrial Activities: 1. FCC/Sulfur pellets (bagged) storage 2. OWS (API#3) 3. Amine rinsate (Sourer-water tanks) Storage 4. Equipment Maintenance (Contracted) 5. OWS (API#1) E. Exit Meeting (Morning) a. General Brief of Inspection Activities b. Areas of Concern and Observations c. Action Items d. Inspection Report (Bob) (Jim) (Jim, Jose, Bob) PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 5 of 11 F. Post-Inspection Activities a. Electronic Mails receipt and review b. Post-Inspection Discussions c. Review of Sample Results and presentation d. Development Sections of Inspection Report e. Request for additional information G. Others a. Equipment (cameras) b. Photo Log (Jim) (Jim, Jose, Bob) (Bob) (Jim, Jose, Bob) (Jim, Jose, Bob) PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 6 of 11 LIST OF ATTACHMENTS Attachment 1 - Aerial Imagery of Facility Attachment 1A - Aerial Imagery of Watershed Attachment 2 - TPDES Permit issued to Hovensa Attachment 3 - Attendance List Attachment 4 - Wastewater Treatment Plant Diagram Attachment 5 - Discharge Points at PHRT's Premises Attachment 6 - Sampling Points Attachment 7 - Waste Streams Flow Diagram Attachment 8 - Stormwater Runoff Flow Diagram Attachment 9 - Rain Data Attachment 10(a) - Photo Album (JCC) Attachment 10(b) - Photo Album (JAR) Attachment 10(C) - Photo Album (RM) Attachment 11 - Inspection Announcement Attachment 12 - Post Inspection Records Receipt (emails) Attachment 13(a) - Entry Meeting Attendance List Attachment 13(b) - Exit Meeting Attendance List Attachment 14 - Sampling Results for Influent, Outfall 401, Outfall 001, and Seawater Intake Attachment 15 - EPA Region 2 Laboratory Final Report Attachment 17 - Chain of Custody Documentation Attachment 18 - List of Documents Provided during the Inspection PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 7 of 11 1. EXECUTIVE SUMMARY 2. PRE-INSPECTION ACTIVITIES a. Announcement of Inspection (to PHRT) b. Post-Announcement Discussions (EPA with PHRT) 3. PRE-FIELD ACTIVITIES a. Credentials and Access Clearance (for site) b. Safety Briefing (morning on Monday by OPT) c. Entry Meeting & Escort Coordination (afternoon on Monday) 4. FIELD ACTIVITIES a. Monday, June 10, 2024 1) Wastewater Treatment Plant 2) Sampling Points 3) Other Observations b. Tuesday, June 11, 2024 (Sampling Team Activities) 1) Description of Areas Visited (afternoon) 2) Sampling Activities The EPA Sampling Team began sampling operations on the morning of June11, 2024. An automatic composite sampler was set up at Outfall 401. The sampler was programmed to collect an aliquot of the wastewater every 15 minutes for 24 hours. The composite sample container was packed in ice. Temperature, total residual chlorine, pH, and conductivity were analyzed in the field and recorded in the field notebook. Three grab samples (Grab #1 through Grab #3) were collected from a tap on the discharge line for the analysis of Skinner List volatile organics. An additional grab sample (Grab #5) was collected for oil and grease. A manual grab composite sample for total phenolics and Skinner List nonvolatile organics was also collected at Outfall 401 by collecting four aliquots during the 24-hour sampling period (three aliquots were collected on June 11). PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 8 of 11 At the Influent to the dissolved gas floatation (DGF) unit, a manual grab composite sample was collected by collecting four aliquots from a sample tap during the 24-hour sampling period (three aliquots were collected on June 11). The Influent DGF Grab Composite sample was analyzed for 5day biochemical oxygen demand (BOD5), total suspended solids (TSS), total organic carbon (TOC), ammonia, chemical oxygen demand (COD), total phosphorus, sulfide (with undissociated hydrogen sulfide), Skinner List metals, total phenolics, Skinner List non-volatile organics, and MBAS (surfactants). Temperature, total residual chlorine, pH, and conductivity were analyzed in the field and recorded in the field notebook. Three grab samples (Grab #1 through Grab #3) were collected from the sample tap for the analysis of Skinner List volatile organics. An additional grab sample (Grab #5) was collected for oil and grease. At Outfall 001, temperature, total residual chlorine, conductivity, pH, and dissolved oxygen were analyzed in the field and recorded in the field notebook. 3) Other Observations c. Wednesday, June 12, 2024 1) Review of Records (morning) 2) Sampling Activities The EPA sampling team continued sampling activities on the morning of June 12, 2024. Using a rod and bottle clamp, a grab sample was collected at Outfall 001. This sample was analyzed for oil and grease, sulfide (with undissociated hydrogen sulfide), Skinner List volatile organics, Skinner List non-volatile organics, Skinner List metals, total phosphorus, COD, total kjeldahl nitrogen (TKN), ammonia, TOC, MBAS (surfactants), BOD5, TSS, and total phenolics. At Outfall 401, the 24-hour composite sample was collected from the composite sample container. This sample was analyzed for BOD5, TSS, TOC, ammonia, COD, total phosphorus, sulfide (with undissociated hydrogen sulfide), Skinner List metals, and MBAS (surfactants). Grab #4 was collected from a tap on the discharge line for the analysis of Skinner List volatile organics. The fourth aliquot for the manual grab composite was also collected at the tap on the discharge line for Outfall 401. The 24-hour flow reading was provided by a representative of Ocean Point Terminals. At the Influent DGF location, the fourth aliquot for the manual grab composite sample was collected from the sample tap. Grab #4 was collected from the sample tap for the analysis of Skinner List volatile organics. PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 9 of 11 The four grab samples for volatile organics that were collected at each location were composited at the EPA Region 2 Laboratory. All sample containers, preservatives, and holding times were in accordance with U.S. EPA requirements specified in 40 CFR Part 136. All samples were placed in coolers with wet ice and shipped overnight to the U.S. EPA Region 2 Laboratory in Edison, New Jersey. Split samples were given to representatives of Ocean Point Terminals. 3) Description of Areas Visited (afternoon) d. Thursday, June 13, 2024 1) Description of Areas Visited 2) Sampling Activities The EPA sampling team continued sampling activities on the morning of June 13, 2024. Using a rod and bottle clamp, a grab sample was collected at the seawater intake for the reverse osmosis unit and fire water system. The intake sample was analyzed for BOD5, TSS, TOC, ammonia, COD, total phosphorus, TKN, Skinner List metals, oil and grease, and MBAS (surfactants). All sample containers, preservatives, and holding times were in accordance with U.S. EPA requirements specified in 40 CFR Part 136. All sample containers were placed in a cooler with wet ice and shipped overnight to the U.S. EPA Region 2 Laboratory in Edison, New Jersey. Split samples were given to representatives of Ocean Point Terminals and Port Hamilton Refining and Transportation. 5. EXIT MEETING (MORNING) a. General Brief of Inspection Activities b. Areas of Concern and Observations c. Action Items d. Inspection Report 6. POST-INSPECTION ACTIVITIES a. Electronic Mails b. Post-Inspection Discussions PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 10 of 11 c. Review of Sample Results and Findings Analytical results indicate that there were no exceedances of parameters for the expired TPDES permit with respect to Outfall 401 and Outfall 001 during the 24hour sampling survey. Skinner List constituents (benzene, toluene, and ethylbenzene) were detected in the effluent for Outfall 401. 7. OTHERS a. Equipment (cameras) b. Photo Log End of Report PORT HAMILTON REFINERY AND TRANSPORTATION, LLLP NPDES Compliance Evaluation and Sampling Inspection Report TPDES ID Number: VIU005563 Page 11 of 11 Attachment 10(C) - Photo Album (RM) Photo #1: Sample location for Outfall 401 where 24-hour composite sample was collected. Photo #2: Sample tap for Outfall 401 where grab samples were collected. Photo #3: Sample location for Influent DGF. Photo #4: Outfall 001. Photo #5: Seawater Intake. Attachment 14 - Sampling Results for Influent, Outfall 401, Outfall 001, and Seawater Intake Parameter Oil & Grease (mg/l) Benzene (ug/l) Toluene (ug/l) Ethylbenzene (ug/l) Fluorene (ug/l) Napthalene (ug/l) Phenanthrene (ug/l) 2,4-Dimethylphenol (ug/l) Phenol (ug/l) Pyrene (ug/l) Antimony (ug/l) Arsenic (ug/l) Barium (ug/l) Beryllium (ug/l) Cadmium (ug/l) Chromium (ug/l) Lead (ug/l) Cobalt (ug/l) Nickel (ug/l) Selenium (ug/l) Silver (ug/l) Vanadium (ug/l) Zinc (ug/l) Mercury (ug/l) Ammonia (mg/l) TKN (mg/l) BOD5 (mg/l) COD (mg/l) TOC (mg/l) Total Phenolics (ug/l) Phosphorus (mg/l) Sulfide (mg/l) Hydrogen Sulfide, Unionized (mg/l) MBAS (mg/l) TSS (mg/l) Flow (g/day) Temperature (oC) Total Residual Chlorine (mg/l) Conductivity (us/cm) pH (su) Dissolved Oxygen (mg/l) Influent - DGF 12.2 ND ND ND 8.31 95.5 L 16.6 L 31.7 J 163 L ND ND ND ND ND ND 5.38 ND ND 22.5 ND ND 52.7 74.5 0.349 7.16 -69.3 J 172 22.1 1760 0.306 70.3 3.16 0.659 J 55.0 -34 0.0 4548 6.96 -- Outfall 401 ND 2890 3340 1480 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 24.9 50.9 0.151 ND -12.2 J,L (15 lbs/day) 74 11.9 (14 lbs/day) 24.3 (0.03 lbs/day) 0.167 0.0206 (0.02 lbs/day) 0.00189 ND J 19 (23 lbs/day) 144,000 33 0.06 10009 8.37 -- Permit Limit Daily Max. 2130.7 lbs/day -------- -------64.52 lbs/day --------5582 lbs/day -7091 lbs/day -15601 lbs/day 52.59 lbs/day -46.22 lbs/day -- -4929 lbs/day Monitor only --- -6.0 - 9.0 -- Outfall 001 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 29.7 ND ND 0.154 ND 2.08 J ND K 4.37 24.1 ND 0.0102 L 0.000936 ND J 16 -36 0.0 54705 8.34 7.9 Permit Limit Daily Max NISP -------- -------------------- ---- --- -- --Monitor only 38.83 -- -6.7 - 8.5 5.0 min. Intake ND -------- --ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND J ND J ND J ND J 2.05 J -- ND J -- -- ND J ND J ---- ---- NISP - No indication of substance present. ND - Not detected. K - The reported value may be biased high. L - The reported value may be biased low. J - Estimated value. *Only those analytes which were detected at or above the reporting limit are listed in the above table. A complete list of analytes can be found in the attached laboratory report. **Permit limits were obtained from expired TPDES Permit No. VI0000019. Attachment 15 - EPA Region 2 Laboratory Final Report UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory 2890 Woodbridge Avenue Edison , New Jersey 08837 732-906-6886 Phone 732-906-6165 Fax July 08, 2024 Philip Cocuzza Monitoring & Assessment Branch LSASD/MAB Edison, NJ 08837 RE: Port Hamilton Refining-Ocean Point Tml - 2406018 Enclosed are the results of analyses for samples received by the laboratory between 6/14/2024 and 6/19/2024. The signature below reflects the laboratory's approval of the reported results. If you have any questions concerning this report, please refer to Project Number 2406018 and contact the laboratory. Sincerely, John R. Bourbon Chief, LSASD/LB Project Narrative: UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 The National Environmental Laboratory Accreditation Conference Institute (TNI) is a voluntary environmental laboratory accreditation association of State and Federal agencies. TNI established and promoted a National Environmental Laboratory Accreditation Program (NELAP) that provides a uniform set of standards for the generation of environmental data that are of known and defensible quality. The EPA Region 2 Laboratory is NELAP accredited. The Laboratory tests that are accredited have met all the requirements established under the TNI Standards. Condition Comments Biochemical Oxygen Demand (BOD) Analysis:- All samples were received past holding time. Samples were qualified with a "J" as an estimated value. Biochemical Oxygen Demand (BOD) Analysis: Sample 2406018-15 exhibited toxicity toward the seed organisms used for BOD. This is demonstrated by increasing BOD values as sample dilution increases. Only the result for the largest sample dilution is being reported instead of the average of all acceptable dilutions; the average is used when the sample does not exhibit toxicity. Since an even higher sample dilution may have produced a higher BOD result, this sample was qualified with an "L" to indicate the result is biased low. MBAS- All samples were received past holding times. All samples were qualified with a J" as an estimated value. Samples showed high chloride values which is a known interference. As per method requirement, samples were diluted prior to extraction and reporting limits were raised to reflect the dilutions. Total Suspended Solids (TSS) Analysis: Sample 2406025-01 temperature upon receipt was outside acceptable range (18.4C); sample was qualified with "J" as an estimated value. Ammonia, Total Phosphorous, TKN, COD and TOC- Sample 2406025-01 was received outside the acceptable temperature range. The sample was qualified with a "J" as an estimated value. Chemical Oxygen Demand- All samples showed high chloride values which is a known interference. As per method requirement, samples were diluted prior to digestion and reporting limits were raised to reflect the dilutions. Comment(s): The "Sample Analysis Date and Time" is included in the results section for any analyte with a prescribed holding time of 72 hours or less. U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 1 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Data Qualifier(s): U- The analyte was not detected at or above the Reporting Limit. J- The identification of the analyte is acceptable; the reported value is an estimate. K- The identification of the analyte is acceptable; the reported value may be biased high. L- The identification of the analyte is acceptable; the reported value may be biased low. NJ- There is presumptive evidence that the analyte is present; the analyte is reported as a tentative identification. The reported value is an estimate. Reporting Limit(s): The Laboratory was able to achieve the appropriate limit for each analyte requested. U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 2 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 SUMMARY REPORT FOR SAMPLES Field ID Laboratory ID Trip Blank 2406018-01 Outfall 401- Grab#5 2406018-06 Outfall 401-Grab#1-4(Lab Composite) 2406018-07 Influent-DGF-Grab#5 2406018-12 Influent-DGF-Grab Comp.DL 2406018-13 Outfall 401-Grab Comp. 2406018-14 Outfall 401-24Hr. Comp. 2406018-15 Outfall 001-Grab 2406018-16 Influent-DGF-Grab#1-4(Lab Composite) 2406018-17 Intake 2406025-01 Matrix Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Date Sampled 06/11/2024 11:05 06/11/2024 11:56 06/14/2024 00:01 06/11/2024 13:02 06/12/2024 11:42 06/12/2024 11:29 06/12/2024 10:40 06/12/2024 10:12 06/14/2024 00:01 06/13/2024 11:20 Date Received 06/14/2024 13:00 06/14/2024 13:00 06/14/2024 13:00 06/14/2024 13:00 06/14/2024 13:00 06/14/2024 13:00 06/14/2024 13:00 06/14/2024 13:00 06/14/2024 13:00 06/19/2024 10:15 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 3 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analysis 624.1 VOA EPA-NPDES 625.1 SVOA NPDES Ammonia [As N] Biochemical Oxygen Demand Chemical Oxygen Demand Mercury Metals ICP TAL NPDES/DW Nitrogen, Total Kjeldahl Oil & Grease Organic Carbon Phenolics, Total Phosphorus Hydrogen Sulfide, Unionized MBAS, calculated as LAS, mol wt 320 Residue, Non-Filterable SUMMARY REPORT FOR METHODS Method EPA 624.1 SOP C-89 Rev 3.7 EPA 625.1 SOP C-90 Rev 3.9 EPA 350.1 SOP C-80 Rev 2.8 SM 5210B SOP C-21 Rev 2.8 EPA 410.4 SOP C-53 Rev 2.8 EPA 245.1 SOP C-110 Rev 2.8 EPA 200.7 SOP C-109 Rev 3.7 EPA 351.2 SOP C-40 Rev2.8 EPA 1664A SOP C-126 Rev 1.7 SM 5310 B SOP C-83 Rev 2.9 EPA 420.4 SOP C-29 Rev 2.8 EPA 365.1 SOP C-68 Rev 2.8 SM 4500 S2 D SOP C-115 Rev 2.8 SM 5540C SOP C-61 Rev 2.8 SM 2540D SOP C-33 Rev 3.8 Certification NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP NELAP Matrix Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous Aqueous U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 4 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Trip Blank VOA GCMS Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-01 Date and Time of Analysis* --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U L 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 5 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Trip Blank VOA GCMS 1,4-Dichlorobenzene 1,2-Dichlorobenzene Field ID: Outfall 401- Grab#5 GC Oil & Grease Field ID: Outfall 401-Grab#1-4(Lab Composite) VOA GCMS Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-01 Date and Time of Analysis* --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 Sample ID: 2406018-06 --- U 5.68 mg/L B407009 Sample ID: 2406018-07 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U L 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 2890 500 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 3340 500 ug/L B406075 --- U 5.00 ug/L B406075 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 6 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Outfall 401-Grab#1-4(Lab Composite) VOA GCMS 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene Field ID: Influent-DGF-Grab#5 GC Oil & Grease Field ID: Influent-DGF-Grab Comp. NVOA GCMS Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-07 Date and Time of Analysis* --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 1480 500 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 Sample ID: 2406018-12 12.2 5.81 mg/L B407009 Sample ID: 2406018-13 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U 4.95 ug/L B406074 8.31 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 7 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Influent-DGF-Grab Comp.DL NVOA GCMS Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-13 Date and Time of Analysis* 95.5 L 3.96 ug/L B406074 16.6 L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 31.7 J 4.95 ug/L B406074 --- U 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 29.7 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 29.7 ug/L B406074 --- U J 4.95 ug/L B406074 --- U L 29.7 ug/L B406074 --- U 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U 4.95 ug/L B406074 --- U L 29.7 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U 4.95 ug/L B406074 --- U 4.95 ug/L B406074 --- U 4.95 ug/L B406074 --- U L 1.98 ug/L B406074 --- U 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U 4.95 ug/L B406074 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 8 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Influent-DGF-Grab Comp. NVOA GCMS Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene Metals ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Lead Nickel Selenium Silver Vanadium Zinc Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-13 Date and Time of Analysis* --- U L 1.98 ug/L B406074 --- U L 29.7 ug/L B406074 --- U L 1.98 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U L 4.95 ug/L B406074 --- U J 4.95 ug/L B406074 --- U L 29.7 ug/L B406074 163 L 59.4 ug/L B406074 --- U 4.95 ug/L B406074 --- U 20.0 ug/L B406102 --- U 8.00 ug/L B406102 --- U 100 ug/L B406102 --- U 3.00 ug/L B406102 --- U 3.00 ug/L B406102 5.38 5.00 ug/L B406102 --- U 20.0 ug/L B406102 --- U 8.00 ug/L B406102 22.5 20.0 ug/L B406102 --- U 20.0 ug/L B406102 --- U 5.00 ug/L B406102 52.7 20.0 ug/L B406102 74.5 20.0 ug/L B406102 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 9 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Result Qualifier Reporting Limit Units Batch Date and Time of Analysis* Field ID: Influent-DGF-Grab Comp. Mercury CVAA Mercury Sanitary Ammonia [As N] Biochemical Oxygen Demand Chemical Oxygen Demand Total Organic Carbon Phenolics, Total Phosphorus Sulfide Hydrogen Sulfide, Unionized MBAS, calculated as LAS, mol wt 320 Total Suspended Solids Field ID: Outfall 401-Grab Comp. NVOA GCMS Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 0.349 7.16 69.3 172 22.1 1760 0.306 70.3 3.16 0.659 55.0 ------------------------------- Sample ID: 2406018-13 0.050 ug/L B406124 0.100 mg/L B406103 J 2.00 mg/L B406071 06/19/2024 11:19 40.0 mg/L B407001 2.00 mg/L B406080 200 ug/L B406072 0.0500 mg/L B406104 1.00 mg/L B406073 mg/L B406073 J 0.500 mg/L B406070 06/14/2024 15:41 10.0 mg/L B406093 Sample ID: 2406018-14 U L 5.00 ug/L B406074 U L 5.00 ug/L B406074 U 5.00 ug/L B406074 U L 5.00 ug/L B406074 U L 5.00 ug/L B406074 U L 5.00 ug/L B406074 U L 5.00 ug/L B406074 U L 5.00 ug/L B406074 U L 5.00 ug/L B406074 U L 5.00 ug/L B406074 U 5.00 ug/L B406074 U 5.00 ug/L B406074 U L 5.00 ug/L B406074 U L 2.00 ug/L B406074 U L 5.00 ug/L B406074 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 10 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Outfall 401-Grab Comp. NVOA GCMS 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-14 Date and Time of Analysis* --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U J 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 30.0 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 30.0 ug/L B406074 --- U J 5.00 ug/L B406074 --- U L 30.0 ug/L B406074 --- U 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U L 30.0 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U L 2.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U L 2.00 ug/L B406074 --- U L 30.0 ug/L B406074 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 11 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Outfall 401-Grab Comp. NVOA GCMS Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene Sanitary Phenolics, Total Field ID: Outfall 401-24Hr. Comp. Metals ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Lead Nickel Selenium Silver Vanadium Zinc Mercury CVAA Mercury Sanitary Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-14 Date and Time of Analysis* --- U L 2.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U J 5.00 ug/L B406074 --- U L 30.0 ug/L B406074 --- U L 30.0 ug/L B406074 --- U 5.00 ug/L B406074 24.3 20.0 ug/L B406072 Sample ID: 2406018-15 --- U 20.0 ug/L B406102 --- U 8.00 ug/L B406102 --- U 100 ug/L B406102 --- U 3.00 ug/L B406102 --- U 3.00 ug/L B406102 --- U 5.00 ug/L B406102 --- U 20.0 ug/L B406102 --- U 8.00 ug/L B406102 --- U 20.0 ug/L B406102 --- U 20.0 ug/L B406102 --- U 5.00 ug/L B406102 24.9 20.0 ug/L B406102 50.9 20.0 ug/L B406102 0.151 0.050 ug/L B406124 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 12 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Result Qualifier Reporting Limit Units Batch Date and Time of Analysis* Field ID: Outfall 401-24Hr. Comp. Sanitary Ammonia [As N] Biochemical Oxygen Demand Chemical Oxygen Demand Total Organic Carbon Phosphorus Sulfide Hydrogen Sulfide, Unionized MBAS, calculated as LAS, mol wt 320 Total Suspended Solids Field ID: Outfall 001-Grab VOA GCMS Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane --- U 12.2 J, L 74.0 11.9 0.167 0.0206 0.00189 --- U J 19.0 --- U --- U --- U L --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U Sample ID: 2406018-15 0.100 2.00 40.0 1.00 0.0500 0.0100 0.500 10.0 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L B406103 B406071 B407001 B406080 B406104 B406073 B406073 06/19/2024 11:19 B406070 06/14/2024 15:41 B406093 Sample ID: 2406018-16 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 5.00 ug/L B406075 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 13 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Outfall 001-Grab VOA GCMS cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene NVOA GCMS Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-16 Date and Time of Analysis* --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 2.00 ug/L B406074 --- U 5.00 ug/L B406074 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 14 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Outfall 001-Grab NVOA GCMS 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-16 Date and Time of Analysis* --- U 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U J 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U J 30.0 ug/L B406074 --- U 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U L 30.0 ug/L B406074 --- U J 5.00 ug/L B406074 --- U L 30.0 ug/L B406074 --- U 5.00 ug/L B406074 --- U L 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U L 30.0 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 2.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 2.00 ug/L B406074 --- U 30.0 ug/L B406074 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 15 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Outfall 001-Grab NVOA GCMS Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene GC Oil & Grease Metals ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Lead Nickel Selenium Silver Vanadium Zinc Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-16 Date and Time of Analysis* --- U 2.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.00 ug/L B406074 --- U J 5.00 ug/L B406074 --- U L 30.0 ug/L B406074 --- U L 30.0 ug/L B406074 --- U 5.00 ug/L B406074 --- U 5.81 mg/L B407009 --- U 40.0 ug/L B406102 --- U 16.0 ug/L B406102 --- U 100 ug/L B406102 --- U 3.00 ug/L B406102 --- U 6.00 ug/L B406102 --- U 10.0 ug/L B406102 --- U 40.0 ug/L B406102 --- U 16.0 ug/L B406102 --- U 40.0 ug/L B406102 --- U 40.0 ug/L B406102 --- U J 5.00 ug/L B406102 29.7 20.0 ug/L B406102 --- U 40.0 ug/L B406102 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 16 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Outfall 001-Grab Mercury CVAA Mercury Sanitary Ammonia [As N] Biochemical Oxygen Demand Chemical Oxygen Demand Nitrogen, Total Kjeldahl Total Organic Carbon Phenolics, Total Phosphorus Sulfide Hydrogen Sulfide, Unionized MBAS, calculated as LAS, mol wt 320 Total Suspended Solids Field ID: Influent-DGF-Grab#1-4(Lab Composite) VOA GCMS Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-16 Date and Time of Analysis* --- U 0.154 2.08 J --- U K --- U 4.37 24.1 --- U 0.0102 L 0.000936 --- U J 16.0 0.050 ug/L B406124 0.100 2.00 200 0.100 1.00 20.0 0.0500 0.0100 2.00 10.0 mg/L mg/L mg/L mg/L mg/L ug/L mg/L mg/L mg/L mg/L mg/L B406103 B406071 06/19/2024 11:19 B407001 B406116 B406080 B406072 B406104 B406073 B406073 B406070 06/14/2024 15:41 B406093 Sample ID: 2406018-17 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U L 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 17 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Influent-DGF-Grab#1-4(Lab Composite) VOA GCMS Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene Field ID: Intake GC Oil & Grease Metals ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Lead Result Qualifier Reporting Limit Units Batch Sample ID: 2406018-17 Date and Time of Analysis* --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 --- U 5.00 ug/L B406075 Sample ID: 2406025-01 --- U 5.75 mg/L B407009 --- U 40.0 ug/L B406102 --- U 16.0 ug/L B406102 --- U 100 ug/L B406102 --- U 3.00 ug/L B406102 --- U 6.00 ug/L B406102 --- U 10.0 ug/L B406102 --- U 40.0 ug/L B406102 --- U 16.0 ug/L B406102 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 18 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Analyte Field ID: Intake Metals ICP Nickel Selenium Silver Vanadium Zinc Mercury CVAA Mercury Sanitary Ammonia [As N] Biochemical Oxygen Demand Chemical Oxygen Demand Nitrogen, Total Kjeldahl Total Organic Carbon Phosphorus MBAS, calculated as LAS, mol wt 320 Total Suspended Solids Result Qualifier Reporting Limit Units Batch Sample ID: 2406025-01 Date and Time of Analysis* --- U 40.0 ug/L B406102 --- U 40.0 ug/L B406102 --- U 5.00 ug/L B406102 --- U 20.0 ug/L B406102 --- U 40.0 ug/L B406102 --- U 0.050 ug/L B406124 --- U J 0.100 mg/L B406103 --- U J 2.00 mg/L B406095 06/24/2024 07:15 --- U J 200 mg/L B407001 --- U J 0.100 mg/L B406116 2.05 J 1.00 mg/L B406117 --- U J 0.0500 mg/L B406104 --- U J 2.00 mg/L B406096 06/19/2024 13:55 --- U J 10.0 mg/L B406099 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 19 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 VOA GCMS - Quality Control Analyte Batch B406075 Blank (B406075-BLK1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L 100 ug/L 100.0 97.5 ug/L 100.0 104 ug/L 100.0 100 60-140 97.5 60-140 104 60-140 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 20 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 VOA GCMS - Quality Control Analyte Batch B406075 LCS (B406075-BS1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 60.7 5.00 ug/L 50.00 50.0 5.00 ug/L 50.00 35.1 5.00 ug/L 50.00 50.9 5.00 ug/L 50.00 55.0 5.00 ug/L 50.00 42.6 5.00 ug/L 50.00 51.5 5.00 ug/L 50.00 56.1 5.00 ug/L 50.00 47.0 5.00 ug/L 50.00 50.8 5.00 ug/L 50.00 51.0 5.00 ug/L 50.00 48.4 5.00 ug/L 50.00 46.4 5.00 ug/L 50.00 51.9 5.00 ug/L 50.00 51.9 5.00 ug/L 50.00 50.7 5.00 ug/L 50.00 54.2 5.00 ug/L 50.00 50.0 5.00 ug/L 50.00 50.7 5.00 ug/L 50.00 52.4 5.00 ug/L 50.00 52.8 5.00 ug/L 50.00 55.3 5.00 ug/L 50.00 51.5 5.00 ug/L 50.00 53.4 5.00 ug/L 50.00 53.2 5.00 ug/L 50.00 53.9 5.00 ug/L 50.00 47.1 5.00 ug/L 50.00 58.6 5.00 ug/L 50.00 52.5 5.00 ug/L 50.00 51.2 5.00 ug/L 50.00 52.0 5.00 ug/L 50.00 99.9 ug/L 100.0 100 ug/L 100.0 106 ug/L 100.0 121 19-205 100 5-195 70.1 15-185 102 40-160 110 50-150 85.2 50-150 103 60-140 112 60-140 94.0 70-130 102 70-130 102 70-135 96.9 70-130 92.8 70-130 104 70-130 104 65-135 101 65-135 108 35-165 100 65-135 101 25-175 105 70-130 106 50-150 111 70-130 103 70-130 107 70-135 106 65-135 108 60-140 94.1 70-130 117 60-140 105 70-130 102 65-135 104 65-135 99.9 60-140 100 60-140 106 60-140 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 21 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 VOA GCMS - Quality Control Analyte Batch B406075 LCS Dup (B406075-BSD1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 55.8 5.00 ug/L 50.00 44.5 5.00 ug/L 50.00 35.0 5.00 ug/L 50.00 45.9 5.00 ug/L 50.00 50.2 5.00 ug/L 50.00 39.5 5.00 ug/L 50.00 48.8 5.00 ug/L 50.00 54.0 5.00 ug/L 50.00 43.8 5.00 ug/L 50.00 46.9 5.00 ug/L 50.00 47.8 5.00 ug/L 50.00 45.2 5.00 ug/L 50.00 44.1 5.00 ug/L 50.00 49.7 5.00 ug/L 50.00 49.1 5.00 ug/L 50.00 48.3 5.00 ug/L 50.00 51.3 5.00 ug/L 50.00 48.0 5.00 ug/L 50.00 49.0 5.00 ug/L 50.00 49.5 5.00 ug/L 50.00 50.6 5.00 ug/L 50.00 53.2 5.00 ug/L 50.00 47.9 5.00 ug/L 50.00 51.2 5.00 ug/L 50.00 51.2 5.00 ug/L 50.00 51.1 5.00 ug/L 50.00 46.4 5.00 ug/L 50.00 57.7 5.00 ug/L 50.00 49.9 5.00 ug/L 50.00 49.7 5.00 ug/L 50.00 50.8 5.00 ug/L 50.00 98.4 ug/L 100.0 101 ug/L 100.0 107 ug/L 100.0 112 19-205 8.52 20 89.1 5-195 11.6 20 70.1 15-185 0.0285 20 91.8 40-160 10.4 20 100 50-150 9.24 20 79.0 50-150 7.55 20 97.5 60-140 5.46 20 108 60-140 3.69 20 87.6 70-130 7.05 20 93.7 70-130 8.11 20 95.6 70-135 6.40 20 90.5 70-130 6.81 20 88.2 70-130 5.04 20 99.4 70-130 4.33 20 98.2 65-135 5.45 20 96.7 65-135 4.71 20 103 35-165 5.42 20 95.9 65-135 4.23 20 98.0 25-175 3.51 20 99.0 70-130 5.75 20 101 50-150 4.30 20 106 70-130 3.84 20 95.8 70-130 7.24 20 102 70-135 4.09 20 102 65-135 3.85 20 102 60-140 5.30 20 92.8 70-130 1.37 20 115 60-140 1.51 20 99.8 70-130 5.12 20 99.4 65-135 3.01 20 102 65-135 2.43 20 98.4 60-140 101 60-140 107 60-140 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 22 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 VOA GCMS - Quality Control Analyte Batch B406075 Matrix Spike (B406075-MS1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2406018-16 56.8 5.00 ug/L 48.1 5.00 ug/L 40.8 5.00 ug/L 51.6 5.00 ug/L 48.6 5.00 ug/L 47.5 5.00 ug/L 52.3 5.00 ug/L 63.6 5.00 ug/L 49.3 5.00 ug/L 50.0 5.00 ug/L 49.3 5.00 ug/L 47.4 5.00 ug/L 45.4 5.00 ug/L 50.2 5.00 ug/L 53.8 5.00 ug/L 51.6 5.00 ug/L 53.6 5.00 ug/L 50.8 5.00 ug/L 49.9 5.00 ug/L 51.9 5.00 ug/L 50.0 5.00 ug/L 55.0 5.00 ug/L 50.9 5.00 ug/L 50.8 5.00 ug/L 51.0 5.00 ug/L 52.1 5.00 ug/L 50.0 5.00 ug/L 59.9 5.00 ug/L 49.8 5.00 ug/L 49.8 5.00 ug/L 49.8 5.00 ug/L 100 ug/L 103 ug/L 112 ug/L 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 100.0 100.0 100.0 114 19-273 96.2 49-251 81.6 21-242 103 14-230 97.3 17-181 95.1 52-234 105 69-221 127 40-160 98.7 54-156 100 59-155 98.5 51-138 94.9 52-162 90.8 70-140 100 49-155 108 37-151 103 70-157 107 74-210 102 35-155 99.8 80-227 104 47-150 100 17-183 110 52-150 102 64-148 102 53-149 102 37-160 104 37-162 100 45-169 120 46-157 99.6 59-156 99.6 18-190 99.6 18-190 100 60-140 103 60-140 112 60-140 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 23 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 VOA GCMS - Quality Control Analyte Batch B406075 Matrix Spike Dup (B406075-MSD1) Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene Methylene Chloride Acrylonitrile trans-1,2-Dichloroethene 1,1-Dichloroethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride 1,2-Dichloroethane Benzene Trichloroethene 1,2-Dichloropropane Bromodichloromethane cis-1,3-Dichloropropene Toluene trans-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroethene Dibromochloromethane Chlorobenzene Ethylbenzene Bromoform 1,1,2,2-Tetrachloroethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene Surrogate: 1,4-Difluorobenzene Surrogate: 2-Bromo-1-Chloropropane Surrogate: 1,4-Dichlorobutane Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2406018-16 55.6 5.00 ug/L 46.0 5.00 ug/L 42.8 5.00 ug/L 48.0 5.00 ug/L 49.4 5.00 ug/L 47.4 5.00 ug/L 53.2 5.00 ug/L 65.4 5.00 ug/L 48.8 5.00 ug/L 49.8 5.00 ug/L 49.8 5.00 ug/L 48.4 5.00 ug/L 46.2 5.00 ug/L 51.4 5.00 ug/L 51.4 5.00 ug/L 50.2 5.00 ug/L 51.0 5.00 ug/L 50.3 5.00 ug/L 49.2 5.00 ug/L 49.7 5.00 ug/L 48.9 5.00 ug/L 54.3 5.00 ug/L 50.5 5.00 ug/L 50.4 5.00 ug/L 50.9 5.00 ug/L 50.4 5.00 ug/L 49.8 5.00 ug/L 60.6 5.00 ug/L 49.8 5.00 ug/L 49.7 5.00 ug/L 49.8 5.00 ug/L 99.1 ug/L 100 ug/L 110 ug/L 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 50.00 ND 100.0 100.0 100.0 111 19-273 2.24 28 92.1 49-251 4.42 28 85.6 21-242 4.74 28 96.0 14-230 7.31 28 98.9 17-181 1.59 28 94.9 52-234 0.189 28 106 69-221 1.71 28 131 40-160 2.78 28 97.6 54-156 1.04 28 99.7 59-155 0.280 28 99.5 51-138 1.01 28 96.7 52-162 1.92 28 92.4 70-140 1.68 28 103 49-155 2.22 28 103 37-151 4.54 28 100 70-157 2.75 28 102 74-210 4.99 28 101 35-155 1.03 28 98.3 80-227 1.49 28 99.5 47-150 4.31 28 97.8 17-183 2.26 28 109 52-150 1.26 28 101 64-148 0.868 28 101 53-149 0.909 28 102 37-160 0.294 28 101 37-162 3.34 28 99.6 45-169 0.441 28 121 46-157 1.29 28 99.6 59-156 0.0201 28 99.3 18-190 0.261 28 99.5 18-190 0.0402 28 99.1 60-140 100 60-140 110 60-140 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 24 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 NVOA GCMS - Quality Control Analyte Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD Batch B406074 Blank (B406074-BLK1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 2.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 30.0 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 30.0 ug/L --- U 5.00 ug/L --- U 30.0 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 30.0 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 RPD Limit Page 25 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 NVOA GCMS - Quality Control Analyte Batch B406074 Blank (B406074-BLK1) Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene 1,4-Dioxane Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12 LCS (B406074-BS1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 2.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 2.00 ug/L --- U 30.0 ug/L --- U 2.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 5.00 ug/L --- U 30.0 ug/L --- U 30.0 ug/L --- U 5.00 ug/L --- U 2.00 ug/L 38.8 ug/L 50.00 ND ug/L 50.00 37.1 ug/L 50.00 36.3 ug/L 50.00 34.7 ug/L 50.00 49.2 ug/L 50.00 41.4 ug/L 50.00 46.2 5.00 ug/L 50.00 43.4 5.00 ug/L 50.00 44.3 5.00 ug/L 50.00 48.5 5.00 ug/L 50.00 48.2 5.00 ug/L 50.00 46.1 5.00 ug/L 50.00 46.2 5.00 ug/L 50.00 77.6 60-140 34.3 60-140 74.3 60-140 72.6 60-140 69.3 60-140 98.4 60-140 82.7 60-140 92.4 47-145 86.7 33-145 88.6 27-133 97.1 33-143 96.4 17-163 92.1 24-159 92.4 35-219 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 26 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 NVOA GCMS - Quality Control Analyte Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD Batch B406074 LCS (B406074-BS1) Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene 46.4 5.00 ug/L 50.00 46.3 5.00 ug/L 50.00 49.8 5.00 ug/L 50.00 43.0 5.00 ug/L 50.00 42.2 5.00 ug/L 50.00 49.0 5.00 ug/L 50.00 37.7 2.00 ug/L 50.00 43.7 5.00 ug/L 50.00 33.1 5.00 ug/L 50.00 45.0 5.00 ug/L 50.00 42.4 5.00 ug/L 50.00 20.7 5.00 ug/L 50.00 46.3 5.00 ug/L 50.00 48.5 5.00 ug/L 50.00 31.2 30.0 ug/L 50.00 42.6 5.00 ug/L 50.00 36.8 5.00 ug/L 50.00 45.6 30.0 ug/L 50.00 77.4 5.00 ug/L 50.00 48.0 30.0 ug/L 50.00 44.0 5.00 ug/L 50.00 42.5 5.00 ug/L 50.00 43.5 5.00 ug/L 50.00 20.9 30.0 ug/L 50.00 41.7 5.00 ug/L 50.00 38.3 5.00 ug/L 50.00 39.8 5.00 ug/L 50.00 50.2 5.00 ug/L 50.00 44.9 5.00 ug/L 50.00 44.4 5.00 ug/L 50.00 43.4 5.00 ug/L 50.00 43.8 2.00 ug/L 50.00 45.4 5.00 ug/L 50.00 50.0 5.00 ug/L 50.00 42.3 5.00 ug/L 50.00 92.7 11-162 92.7 17-168 99.6 33-227 86.0 26-137 84.4 59-121 97.9 39-171 75.3 21-133 87.4 54-120 66.2 44-142 90.1 37-144 84.7 39-135 41.3 32-120 92.6 39-139 96.9 50-158 62.4 21-191 85.2 60-120 73.5 23-134 91.2 29-182 155 38-262 96.0 17-181 87.9 53-127 85.0 22-147 86.9 25-158 41.8 9-132 83.3 33-184 76.6 12-158 79.6 36-166 100 8-158 89.8 38-152 88.9 60-115 86.9 31-114 87.5 28-120 90.8 1-120 100 4-146 84.6 35-152 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 RPD Limit Page 27 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 NVOA GCMS - Quality Control Analyte Batch B406074 LCS (B406074-BS1) Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene 1,4-Dioxane Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12 LCS Dup (B406074-BSD1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 31.7 2.00 ug/L 50.00 39.5 30.0 ug/L 50.00 28.4 2.00 ug/L 50.00 49.9 5.00 ug/L 50.00 41.0 5.00 ug/L 50.00 25.0 5.00 ug/L 50.00 41.0 5.00 ug/L 50.00 73.7 5.00 ug/L 50.00 35.6 30.0 ug/L 50.00 16.3 30.0 ug/L 50.00 44.4 5.00 ug/L 50.00 22.0 2.00 ug/L 50.00 41.9 ug/L 50.00 15.7 ug/L 50.00 42.5 ug/L 50.00 41.8 ug/L 50.00 45.8 ug/L 50.00 52.9 ug/L 50.00 46.7 ug/L 50.00 39.7 5.00 ug/L 50.00 37.8 5.00 ug/L 50.00 42.0 5.00 ug/L 50.00 45.2 5.00 ug/L 50.00 45.2 5.00 ug/L 50.00 43.7 5.00 ug/L 50.00 43.5 5.00 ug/L 50.00 43.7 5.00 ug/L 50.00 43.3 5.00 ug/L 50.00 46.3 5.00 ug/L 50.00 40.8 5.00 ug/L 50.00 40.1 5.00 ug/L 50.00 46.0 5.00 ug/L 50.00 34.2 2.00 ug/L 50.00 63.4 24-120 79.0 15-76 56.8 40-120 99.9 21-196 81.9 35-180 49.9 17-127 82.0 43-230 147 79-139 71.3 14-176 32.6 5-120 88.7 52-120 43.9 7-106 83.8 60-140 31.4 60-140 85.0 60-140 83.6 60-140 91.7 60-140 106 60-140 93.4 60-140 79.4 47-145 15.2 30 75.6 33-145 13.7 30 84.1 27-133 5.26 30 90.5 33-143 7.02 30 90.5 17-163 6.36 30 87.3 24-159 5.35 30 87.1 35-219 5.93 30 87.3 11-162 5.98 30 86.6 17-168 6.81 30 92.6 33-227 7.29 30 81.6 26-137 5.27 30 80.2 59-121 5.05 30 92.1 39-171 6.11 30 68.5 21-133 9.54 30 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 28 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 NVOA GCMS - Quality Control Analyte Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD Batch B406074 LCS Dup (B406074-BSD1) Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine 41.3 5.00 ug/L 50.00 29.8 5.00 ug/L 50.00 40.8 5.00 ug/L 50.00 39.3 5.00 ug/L 50.00 13.4 5.00 ug/L 50.00 45.0 5.00 ug/L 50.00 42.5 5.00 ug/L 50.00 29.1 30.0 ug/L 50.00 37.0 5.00 ug/L 50.00 37.4 5.00 ug/L 50.00 44.1 30.0 ug/L 50.00 67.6 5.00 ug/L 50.00 48.8 30.0 ug/L 50.00 41.4 5.00 ug/L 50.00 38.2 5.00 ug/L 50.00 41.0 5.00 ug/L 50.00 17.6 30.0 ug/L 50.00 39.9 5.00 ug/L 50.00 40.0 5.00 ug/L 50.00 37.2 5.00 ug/L 50.00 46.8 5.00 ug/L 50.00 43.0 5.00 ug/L 50.00 41.7 5.00 ug/L 50.00 41.6 5.00 ug/L 50.00 38.4 2.00 ug/L 50.00 43.0 5.00 ug/L 50.00 46.7 5.00 ug/L 50.00 39.8 5.00 ug/L 50.00 26.1 2.00 ug/L 50.00 32.2 30.0 ug/L 50.00 25.0 2.00 ug/L 50.00 46.9 5.00 ug/L 50.00 39.2 5.00 ug/L 50.00 26.2 5.00 ug/L 50.00 39.5 5.00 ug/L 50.00 82.6 54-120 5.63 59.7 44-142 10.3 81.6 37-144 9.83 78.7 39-135 7.39 26.7 32-120 43.0 90.1 39-139 2.74 85.0 50-158 13.1 58.1 21-191 7.07 73.9 60-120 14.1 74.7 23-134 1.59 88.2 29-182 3.32 135 38-262 13.5 97.7 17-181 1.76 82.7 53-127 6.10 76.4 22-147 10.7 82.1 25-158 5.78 35.3 9-132 16.9 79.9 33-184 4.24 80.0 12-158 4.27 74.3 36-166 6.86 93.6 8-158 7.03 86.0 38-152 4.32 83.4 60-115 6.34 83.2 31-114 4.35 76.7 28-120 13.2 86.1 1-120 5.31 93.3 4-146 6.93 79.7 35-152 5.96 52.1 24-120 19.6 64.5 15-76 20.2 50.0 40-120 12.7 93.9 21-196 6.17 78.4 35-180 4.36 52.3 17-127 4.69 79.1 43-230 3.60 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 RPD Limit 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Page 29 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 NVOA GCMS - Quality Control Analyte Batch B406074 LCS Dup (B406074-BSD1) N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene 1,4-Dioxane Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12 Matrix Spike (B406074-MS1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 70.0 5.00 ug/L 50.00 36.4 30.0 ug/L 50.00 17.0 30.0 ug/L 50.00 41.9 5.00 ug/L 50.00 22.5 2.00 ug/L 50.00 41.6 ug/L 50.00 15.9 ug/L 50.00 38.4 ug/L 50.00 37.7 ug/L 50.00 39.1 ug/L 50.00 48.3 ug/L 50.00 42.2 ug/L 50.00 140 79-139 5.23 30 72.8 14-176 2.17 30 34.1 5-120 4.38 30 83.9 52-120 5.61 30 45.0 7-106 2.43 30 83.3 60-140 31.9 60-140 76.8 60-140 75.3 60-140 78.1 60-140 96.6 60-140 84.3 60-140 Source: 2406018-16 35.3 5.05 ug/L 35.8 5.05 ug/L 38.9 5.05 ug/L 41.0 5.05 ug/L 40.5 5.05 ug/L 40.2 5.05 ug/L 42.5 5.05 ug/L 40.2 5.05 ug/L 40.2 5.05 ug/L 45.1 5.05 ug/L 38.6 5.05 ug/L 38.2 5.05 ug/L 48.2 5.05 ug/L 35.4 2.02 ug/L 38.6 5.05 ug/L 35.1 5.05 ug/L 30.8 5.05 ug/L 32.5 5.05 ug/L 31.1 5.05 ug/L 42.5 5.05 ug/L 37.2 5.05 ug/L 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 69.9 47-145 70.9 33-145 77.1 27-133 81.2 33-143 80.3 17-163 79.5 24-159 84.1 35-219 79.7 11-162 79.6 17-168 89.2 33-227 76.4 26-137 75.6 59-121 95.4 39-171 70.1 21-133 76.4 54-120 69.4 44-142 61.0 37-144 64.3 39-135 61.6 32-120 84.1 39-139 73.7 50-158 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 30 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 NVOA GCMS - Quality Control Analyte Batch B406074 Matrix Spike (B406074-MS1) 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene 1,4-Dioxane Surrogate: 2-Fluoroaniline Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2406018-16 19.3 30.3 ug/L 35.4 5.05 ug/L 29.9 5.05 ug/L 35.2 30.3 ug/L 30.4 5.05 ug/L 35.3 30.3 ug/L 38.8 5.05 ug/L 35.5 5.05 ug/L 38.2 5.05 ug/L 13.7 30.3 ug/L 36.7 5.05 ug/L 36.6 5.05 ug/L 36.1 5.05 ug/L 45.6 5.05 ug/L 41.9 5.05 ug/L 40.1 5.05 ug/L 40.5 5.05 ug/L 36.6 2.02 ug/L 41.5 5.05 ug/L 45.6 5.05 ug/L 38.0 5.05 ug/L 34.2 2.02 ug/L 34.7 30.3 ug/L 34.3 2.02 ug/L 35.4 5.05 ug/L 36.8 5.05 ug/L 23.7 5.05 ug/L 37.4 5.05 ug/L 37.9 5.05 ug/L 26.8 30.3 ug/L 17.9 30.3 ug/L 38.7 5.05 ug/L 19.9 2.02 ug/L 41.6 ug/L 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 ND 50.51 38.2 21-191 70.0 60-120 59.3 23-134 69.8 29-182 60.1 38-262 69.9 17-181 76.8 53-127 70.3 22-147 75.5 25-158 27.2 9-132 72.7 33-184 72.5 12-158 71.5 36-166 90.3 8-158 82.9 38-152 79.4 61-106 80.2 31-114 72.4 28-120 82.3 1-120 90.3 4-146 75.2 35-152 67.7 24-120 68.8 15-76 67.8 40-120 70.2 21-196 72.9 35-180 47.0 17-127 74.1 43-230 75.1 79-139 53.0 14-176 35.5 5-120 76.5 52-120 39.3 7-106 82.5 60-140 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 31 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 NVOA GCMS - Quality Control Analyte Batch B406074 Matrix Spike (B406074-MS1) Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12 Matrix Spike Dup (B406074-MSD1) Acenaphthene Acenaphthylene Anthracene Benzo(A)Anthracene Benzo(A)Pyrene Benzo(B)Fluoranthene Benzo(G,H,I)Perylene Benzo(K)Fluoranthene Chrysene Dibenzo(A,H)Anthracene Fluoranthene Fluorene Indeno(1,2,3-Cd)Pyrene Naphthalene Phenanthrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2,4-Dinitrophenol 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'- Dichlorobenzidine 4,6-Dinitro-2-Methylphenol Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2406018-16 18.0 ug/L 37.5 ug/L 36.9 ug/L 34.1 ug/L 49.1 ug/L 36.6 ug/L 50.51 50.51 50.51 50.51 50.51 50.51 35.6 60-140 74.2 60-140 73.1 60-140 67.6 60-140 97.1 60-140 72.4 60-140 Source: 2406018-16 32.5 5.15 ug/L 51.55 ND 63.0 47-145 8.26 24 32.8 5.15 ug/L 51.55 ND 63.7 33-145 8.72 24 36.9 5.15 ug/L 51.55 ND 71.5 27-133 5.42 24 39.0 5.15 ug/L 51.55 ND 75.7 33-143 4.90 24 39.1 5.15 ug/L 51.55 ND 75.8 17-163 3.62 24 39.0 5.15 ug/L 51.55 ND 75.7 24-159 2.91 24 43.5 5.15 ug/L 51.55 ND 84.3 35-219 2.35 24 38.5 5.15 ug/L 51.55 ND 74.6 11-162 4.52 24 38.9 5.15 ug/L 51.55 ND 75.5 17-168 3.14 24 46.1 5.15 ug/L 51.55 ND 89.5 33-227 2.38 24 36.8 5.15 ug/L 51.55 ND 71.5 26-137 4.67 24 37.1 5.15 ug/L 51.55 ND 72.0 59-121 2.78 24 44.2 5.15 ug/L 51.55 ND 85.7 39-171 8.74 24 35.2 2.06 ug/L 51.55 ND 68.4 21-133 0.386 24 37.1 5.15 ug/L 51.55 ND 72.0 54-120 4.00 24 34.5 5.15 ug/L 51.55 ND 67.0 44-142 1.51 24 31.0 5.15 ug/L 51.55 ND 60.1 37-144 0.489 24 33.3 5.15 ug/L 51.55 ND 64.6 39-135 2.38 24 18.9 5.15 ug/L 51.55 ND 36.8 32-120 48.6 24 41.2 5.15 ug/L 51.55 ND 79.9 39-139 3.03 24 34.2 5.15 ug/L 51.55 ND 66.3 50-158 8.57 24 26.6 30.9 ug/L 51.55 ND 51.6 21-191 32.0 24 33.1 5.15 ug/L 51.55 ND 64.2 60-120 6.57 24 31.2 5.15 ug/L 51.55 ND 60.5 23-134 4.01 24 37.2 30.9 ug/L 51.55 ND 72.1 29-182 5.34 24 26.7 5.15 ug/L 51.55 ND 51.8 38-262 12.8 24 40.0 30.9 ug/L 51.55 ND 77.5 17-181 12.4 24 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 32 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 NVOA GCMS - Quality Control Analyte Batch B406074 Matrix Spike Dup (B406074-MSD1) 4-Bromophenyl-Phenylether 4-Chloro-3-Methylphenol 4-Chlorophenyl-Phenylether 4-Nitrophenol Bis(-2-Chloroethoxy)Methane Bis(2-Chloroethyl)Ether Bis(2-Chloroisopropyl)Ether Bis(2-Ethylhexyl)Phthalate Butylbenzylphthalate Azobenzene Diethylphthalate Dimethyl Phthalate Di-N-Butyl Phthalate Di-N-Octyl Phthalate Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Isophorone Nitrobenzene N-Nitrosodimethylamine N-Nitroso-Di-N-Propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenol Pyrene 1,4-Dioxane Surrogate: 2-Fluoroaniline Surrogate: Phenol-D6 Surrogate: Naphthalene-D8 Surrogate: 1-Fluoronaphthalene Surrogate: 2,4-Dibromophenol Surrogate: Anthracene-D10 Surrogate: Chrysene-D12 Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2406018-16 37.2 5.15 ug/L 51.55 ND 72.1 53-127 4.27 24 33.0 5.15 ug/L 51.55 ND 64.1 22-147 7.22 24 37.2 5.15 ug/L 51.55 ND 72.2 25-158 2.54 24 13.0 30.9 ug/L 51.55 ND 25.2 9-132 5.51 24 36.3 5.15 ug/L 51.55 ND 70.3 33-184 1.31 24 36.5 5.15 ug/L 51.55 ND 70.9 12-158 0.247 24 36.4 5.15 ug/L 51.55 ND 70.7 36-166 0.887 24 44.4 5.15 ug/L 51.55 ND 86.2 8-158 2.61 24 40.2 5.15 ug/L 51.55 ND 78.0 38-152 4.08 24 39.0 5.15 ug/L 51.55 ND 75.7 61-106 2.73 24 39.2 5.15 ug/L 51.55 ND 76.1 31-114 3.21 24 33.4 2.06 ug/L 51.55 ND 64.7 28-120 9.22 24 40.5 5.15 ug/L 51.55 ND 78.5 1-120 2.64 24 44.2 5.15 ug/L 51.55 ND 85.7 4-146 3.23 24 36.2 5.15 ug/L 51.55 ND 70.2 35-152 4.81 24 33.6 2.06 ug/L 51.55 ND 65.1 24-120 1.84 24 32.4 30.9 ug/L 51.55 ND 62.9 15-76 6.83 24 34.0 2.06 ug/L 51.55 ND 65.9 40-120 0.831 24 34.1 5.15 ug/L 51.55 ND 66.2 21-196 3.80 24 36.1 5.15 ug/L 51.55 ND 70.1 35-180 1.96 24 24.8 5.15 ug/L 51.55 ND 48.1 17-127 4.48 24 36.1 5.15 ug/L 51.55 ND 70.0 43-230 3.62 24 36.8 5.15 ug/L 51.55 ND 71.5 79-139 2.95 24 29.7 30.9 ug/L 51.55 ND 57.6 14-176 10.4 24 19.4 30.9 ug/L 51.55 ND 37.6 5-120 7.89 24 36.7 5.15 ug/L 51.55 ND 71.2 52-120 5.16 24 20.3 2.06 ug/L 51.55 ND 39.3 7-106 2.09 24 40.6 ug/L 51.55 78.8 60-140 18.0 ug/L 51.55 34.8 60-140 36.1 ug/L 51.55 70.1 60-140 36.2 ug/L 51.55 70.3 60-140 32.4 ug/L 51.55 62.8 60-140 46.6 ug/L 51.55 90.3 60-140 37.2 ug/L 51.55 72.1 60-140 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 33 of 47 Analyte Batch B407009 Blank (B407009-BLK1) Oil & Grease LCS (B407009-BS1) Oil & Grease LCS Dup (B407009-BSD1) Oil & Grease Matrix Spike (B407009-MS1) Oil & Grease UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 GC - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit --- U 5.00 mg/L 35.7 5.00 mg/L 40.00 89.2 78-114 37.6 5.00 mg/L 40.00 94.0 78-114 5.18 20 Source: 2406018-16 42.8 5.68 mg/L 45.45 ND 94.2 78-114 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 34 of 47 Analyte Batch B406102 Blank (B406102-BLK1) Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Lead Nickel Selenium Silver Vanadium Zinc LCS (B406102-BS1) Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Lead Nickel Selenium Silver Vanadium Zinc UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Metals ICP - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit --- U 20.0 ug/L --- U 8.00 ug/L --- U 100 ug/L --- U 3.00 ug/L --- U 3.00 ug/L --- U 5.00 ug/L --- U 20.0 ug/L --- U 8.00 ug/L --- U 20.0 ug/L --- U 20.0 ug/L --- U 5.00 ug/L --- U 20.0 ug/L --- U 20.0 ug/L 198 20.0 ug/L 200.0 198 8.00 ug/L 200.0 205 100 ug/L 200.0 200 3.00 ug/L 200.0 200 3.00 ug/L 200.0 201 5.00 ug/L 200.0 204 20.0 ug/L 200.0 201 8.00 ug/L 200.0 200 20.0 ug/L 200.0 194 20.0 ug/L 200.0 201 5.00 ug/L 200.0 205 20.0 ug/L 200.0 201 20.0 ug/L 200.0 98.8 85-115 99.2 85-115 102 85-115 99.9 85-115 99.8 85-115 101 85-115 102 85-115 100 85-115 100 85-115 97.1 85-115 101 85-115 102 85-115 101 85-115 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 35 of 47 Analyte Batch B406102 LCS Dup (B406102-BSD1) Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Lead Nickel Selenium Silver Vanadium Zinc Matrix Spike (B406102-MS1) Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Lead Nickel Selenium Silver Vanadium Zinc UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Metals ICP - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 206 20.0 ug/L 200.0 203 8.00 ug/L 200.0 210 100 ug/L 200.0 205 3.00 ug/L 200.0 207 3.00 ug/L 200.0 209 5.00 ug/L 200.0 211 20.0 ug/L 200.0 210 8.00 ug/L 200.0 207 20.0 ug/L 200.0 203 20.0 ug/L 200.0 208 5.00 ug/L 200.0 212 20.0 ug/L 200.0 209 20.0 ug/L 200.0 103 85-115 4.20 20 102 85-115 2.34 20 105 85-115 2.56 20 103 85-115 2.73 20 104 85-115 3.81 20 104 85-115 3.63 20 106 85-115 3.52 20 105 85-115 4.23 20 104 85-115 3.48 20 101 85-115 4.19 20 104 85-115 3.58 20 106 85-115 3.55 20 104 85-115 3.77 20 Source: 2406018-16 242 40.0 ug/L 239 16.0 ug/L 253 100 ug/L 186 3.00 ug/L 185 6.00 ug/L 208 10.0 ug/L 199 40.0 ug/L 192 16.0 ug/L 202 40.0 ug/L 232 40.0 ug/L 277 5.00 ug/L 235 20.0 ug/L 187 40.0 ug/L 200.0 ND 200.0 ND 200.0 33.9 200.0 ND 200.0 ND 200.0 ND 200.0 ND 200.0 ND 200.0 11.7 200.0 ND 200.0 1.61 200.0 29.7 200.0 8.38 121 80-120 119 80-120 110 80-120 93.0 80-120 92.6 80-120 104 80-120 99.5 80-120 95.9 80-120 95.2 80-120 116 80-120 138 80-120 102 80-120 89.5 80-120 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 36 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Metals ICP - Quality Control Analyte Batch B406102 Matrix Spike Dup (B406102-MSD1) Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Lead Nickel Selenium Silver Vanadium Zinc Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2406018-16 227 100 ug/L 200.0 ND 114 80-120 6.39 10 234 40.0 ug/L 200.0 ND 117 80-120 1.80 10 243 500 ug/L 200.0 33.9 105 80-120 3.92 10 202 15.0 ug/L 200.0 ND 101 80-120 8.26 10 197 15.0 ug/L 200.0 ND 98.4 80-120 6.01 10 207 25.0 ug/L 200.0 ND 104 80-120 0.472 10 206 100 ug/L 200.0 ND 103 80-120 3.58 10 198 40.0 ug/L 200.0 ND 98.9 80-120 3.08 10 219 100 ug/L 200.0 ND 110 80-120 8.18 10 217 100 ug/L 200.0 ND 108 80-120 6.56 10 237 25.0 ug/L 200.0 ND 119 80-120 15.4 10 251 100 ug/L 200.0 29.7 111 80-120 6.70 10 203 100 ug/L 200.0 ND 102 80-120 8.04 10 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 37 of 47 Analyte Batch B406124 Blank (B406124-BLK1) Mercury LCS (B406124-BS1) Mercury LCS Dup (B406124-BSD1) Mercury Matrix Spike (B406124-MS1) Mercury UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Mercury CVAA - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit --- U 0.050 ug/L 0.940 0.050 ug/L 1.000 94.0 85-115 0.964 0.050 ug/L 1.000 96.4 85-115 2.52 20 Source: 2406018-16 0.960 0.050 ug/L 1.000 0.042 91.8 80-120 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 38 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Sanitary - Quality Control Analyte Batch B406070 Blank (B406070-BLK1) MBAS, calculated as LAS, mol wt 320 Blank (B406070-BLK2) MBAS, calculated as LAS, mol wt 320 LCS (B406070-BS1) MBAS, calculated as LAS, mol wt 320 LCS Dup (B406070-BSD1) MBAS, calculated as LAS, mol wt 320 Matrix Spike (B406070-MS1) MBAS, calculated as LAS, mol wt 320 Reference (B406070-SRM1) MBAS, calculated as LAS, mol wt 320 Batch B406071 Blank (B406071-BLK1) Biochemical Oxygen Demand LCS (B406071-BS1) Biochemical Oxygen Demand LCS (B406071-BS2) Biochemical Oxygen Demand Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit --- U 0.100 mg/L --- U 0.100 mg/L 0.705 0.100 mg/L 0.7080 100 85-115 0.728 0.100 mg/L 0.7080 103 85-115 3 20 Source: 2406018-13 1.14 0.500 mg/L 0.5000 0.659 95 80-120 0.102 0.100 mg/L 0.1000 102 0-200 --- U 2.00 mg/L 175 mg/L 198.0 168 mg/L 198.0 88.4 84.6-115.4 84.9 84.6-115.4 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 39 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Sanitary - Quality Control Analyte Batch B406071 LCS (B406071-BS3) Biochemical Oxygen Demand Duplicate (B406071-DUP1) Biochemical Oxygen Demand Matrix Spike (B406071-MS1) Biochemical Oxygen Demand Matrix Spike Dup (B406071-MSD1) Biochemical Oxygen Demand Batch B406072 Blank (B406072-BLK1) Phenolics, Total LCS (B406072-BS1) Phenolics, Total LCS Dup (B406072-BSD1) Phenolics, Total Matrix Spike (B406072-MS1) Phenolics, Total Matrix Spike (B406072-MS2) Phenolics, Total Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 182 mg/L 198.0 91.7 84.6-115.4 Source: 2406018-16 2.24 2.00 mg/L 2.08 7.41 25 Source: 2406018-16 66.8 2.00 mg/L 79.20 2.08 81.7 75-125 Source: 2406018-16 49.8 2.00 mg/L 59.40 2.08 80.3 75-125 29.3 200 --- U 20.0 ug/L 1700 40.0 ug/L 1670 102 90-110 1600 40.0 ug/L 1670 96 90-110 6 20 Source: 2406018-16 519 20.0 ug/L 500.0 24.1 99 90-110 Source: 2406003-01 475 20.0 ug/L 500.0 29.1 89 90-110 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 40 of 47 Analyte Batch B406073 Blank (B406073-BLK1) Sulfide Hydrogen Sulfide, Unionized Blank (B406073-BLK2) Sulfide Hydrogen Sulfide, Unionized LCS (B406073-BS1) Sulfide LCS Dup (B406073-BSD1) Sulfide Matrix Spike (B406073-MS1) Sulfide Batch B406080 Blank (B406080-BLK1) Organic Carbon Blank (B406080-BLK2) Organic Carbon LCS (B406080-BS1) Organic Carbon UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Sanitary - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit --- U 0.00340 0.0100 mg/L mg/L --- U 0.00400 0.0100 mg/L mg/L 0.426 0.0100 mg/L 0.4610 92 85-115 0.433 0.0100 mg/L 0.4610 94 85-115 2 20 Source: 2406018-16 0.0737 0.0100 mg/L 0.2000 0.0102 32 80-120 --- U 1.00 mg/L --- U 1.00 mg/L 74.6 5.00 mg/L 76.70 97 85-115 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 41 of 47 Analyte Batch B406080 LCS Dup (B406080-BSD1) Organic Carbon Matrix Spike (B406080-MS1) Organic Carbon Batch B406093 Blank (B406093-BLK1) Residue, Non-Filterable LCS (B406093-BS1) Residue, Non-Filterable LCS Dup (B406093-BSD1) Residue, Non-Filterable Duplicate (B406093-DUP1) Residue, Non-Filterable Batch B406095 Blank (B406095-BLK1) Biochemical Oxygen Demand LCS (B406095-BS1) Biochemical Oxygen Demand UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Sanitary - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 74.8 5.00 mg/L 76.70 98 85-115 0.3 20 Source: 2406018-16 24.0 1.00 mg/L 20.00 4.37 98 80-120 --- U 10.0 mg/L 46.0 10.0 mg/L 46.40 99.1 85-115 48.0 10.0 mg/L 46.40 103 85-115 4.26 20 Source: 2406018-16 15.0 10.0 mg/L 16.0 6.45 20 --- U 2.00 mg/L 165 mg/L 198.0 83.2 84.6-115.4 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 42 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Sanitary - Quality Control Analyte Batch B406095 LCS (B406095-BS2) Biochemical Oxygen Demand LCS (B406095-BS3) Biochemical Oxygen Demand Duplicate (B406095-DUP1) Biochemical Oxygen Demand Matrix Spike (B406095-MS1) Biochemical Oxygen Demand Matrix Spike Dup (B406095-MSD1) Biochemical Oxygen Demand Batch B406096 Blank (B406096-BLK1) MBAS, calculated as LAS, mol wt 320 Blank (B406096-BLK2) MBAS, calculated as LAS, mol wt 320 LCS (B406096-BS1) MBAS, calculated as LAS, mol wt 320 LCS Dup (B406096-BSD1) MBAS, calculated as LAS, mol wt 320 Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 171 mg/L 198.0 86.5 84.6-115.4 176 mg/L 198.0 89.0 84.6-115.4 Source: 2406025-01 --- U 2.00 mg/L ND 25 Source: 2406025-01 60.9 2.00 mg/L 79.20 ND 76.9 75-125 Source: 2406025-01 45.7 2.00 mg/L 59.40 ND 76.9 75-125 28.6 200 --- U --- U 0.701 0.711 0.100 mg/L 0.100 mg/L 0.100 mg/L 0.7080 0.100 mg/L 0.7080 99 85-115 100 85-115 1 20 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 43 of 47 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Sanitary - Quality Control Analyte Batch B406096 Matrix Spike (B406096-MS1) MBAS, calculated as LAS, mol wt 320 Reference (B406096-SRM1) MBAS, calculated as LAS, mol wt 320 Batch B406099 Blank (B406099-BLK1) Residue, Non-Filterable LCS (B406099-BS1) Residue, Non-Filterable LCS Dup (B406099-BSD1) Residue, Non-Filterable Duplicate (B406099-DUP1) Residue, Non-Filterable Batch B406103 Blank (B406103-BLK1) Ammonia [As N] LCS (B406103-BS1) Ammonia [As N] Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2406025-01 1.25 2.00 mg/L 0.5000 0.529 145 80-120 0.0989 0.100 mg/L 0.1000 99 0-200 --- U 10.0 mg/L 48.0 10.0 mg/L 46.40 103 85-115 47.0 10.0 mg/L 46.40 101 85-115 2.11 20 Source: 2406025-01 9.00 10.0 mg/L 7.00 25.0 20 --- U 0.100 mg/L 2.08 0.100 mg/L 2.060 101 90-110 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 44 of 47 Analyte Batch B406103 LCS Dup (B406103-BSD1) Ammonia [As N] Matrix Spike (B406103-MS1) Ammonia [As N] Batch B406104 Blank (B406104-BLK1) Phosphorus Blank (B406104-BLK2) Phosphorus LCS (B406104-BS1) Phosphorus LCS (B406104-BS2) Phosphorus LCS Dup (B406104-BSD1) Phosphorus LCS Dup (B406104-BSD2) Phosphorus Matrix Spike (B406104-MS1) Phosphorus UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Sanitary - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit 2.15 0.100 mg/L 2.060 104 90-110 3 20 Source: 2406018-16 5.13 0.100 mg/L 5.000 0.154 100 90-110 --- U 0.0500 mg/L --- U 0.0500 mg/L 9.26 0.250 mg/L 8.450 110 90-110 9.21 0.250 mg/L 8.450 109 90-110 9.11 0.250 mg/L 8.450 108 90-110 2 20 9.14 0.250 mg/L 8.450 108 90-110 0.8 20 Source: 2406018-16 1.04 0.0500 mg/L 1.000 0.0370 101 90-110 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 45 of 47 Analyte Batch B406116 Blank (B406116-BLK1) Nitrogen, Total Kjeldahl Blank (B406116-BLK2) Nitrogen, Total Kjeldahl LCS (B406116-BS1) Nitrogen, Total Kjeldahl LCS Dup (B406116-BSD1) Nitrogen, Total Kjeldahl Matrix Spike (B406116-MS1) Nitrogen, Total Kjeldahl Batch B406117 Blank (B406117-BLK1) Organic Carbon Blank (B406117-BLK2) Organic Carbon LCS (B406117-BS1) Organic Carbon LCS Dup (B406117-BSD1) Organic Carbon UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Sanitary - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit --- U 0.100 mg/L --- U 0.100 mg/L 12.8 0.200 mg/L 12.40 103 90-110 12.8 0.200 mg/L 12.40 103 90-110 0 20 Source: 2406018-16 3.80 0.100 mg/L 4.000 ND 95 90-110 --- U 1.00 mg/L --- U 1.00 mg/L 75.8 5.00 mg/L 76.70 75.5 5.00 mg/L 76.70 99 85-115 98 85-115 0.4 20 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 46 of 47 Analyte Batch B406117 Matrix Spike (B406117-MS1) Organic Carbon Batch B407001 Blank (B407001-BLK1) Chemical Oxygen Demand Blank (B407001-BLK2) Chemical Oxygen Demand LCS (B407001-BS1) Chemical Oxygen Demand LCS (B407001-BS2) Chemical Oxygen Demand LCS Dup (B407001-BSD1) Chemical Oxygen Demand LCS Dup (B407001-BSD2) Chemical Oxygen Demand Matrix Spike (B407001-MS1) Chemical Oxygen Demand UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 2 Laboratory Final Report Project: Port Hamilton Refining-Ocean Point Tml - 2406018 Project Number: 2406018 Sanitary - Quality Control Result Reporting Limit Units Spike Source %REC Level Result %REC Limits RPD RPD Limit Source: 2406025-01 22.4 1.00 mg/L 20.00 2.05 102 80-120 --- U 20.0 mg/L --- U 20.0 mg/L 195 40.0 mg/L 194.0 101 90-110 197 40.0 mg/L 194.0 102 90-110 196 40.0 mg/L 194.0 101 90-110 0.6 20 191 40.0 mg/L 194.0 98 90-110 3 20 Source: 2406018-16 315 200 mg/L 50.00 143 343 90-110 U.S.E.P.A Region 2 Laboratory NOTE: The results recorded in this report relate only to the samples as received on the date and at the time noted Reported: 7/8/2024 Page 47 of 47 Attachment 17 - Chain of Custody Documentation US !'PAR -610 2 LABORATORY CHAIN OF CUSTODY( FlELD DATA f'ORM pages -'lJ'/J'""" ;:t_ ?.I'i.. _j /)J ijI"{