Document yy6jnMNjpLE2JgwNx42rg0ZV

Detection of Asbestos in Bulk Insulation Materials An Evaluation of the NIOSH 'Test for Screening Asbestos" Technical Progress Report WRC 210-80 Project No. 39123 Asbestos Printed: December 1980 Author: Reviewer: Approval: References: R. E. Evans M. A. Muhs M. J. O'Neal LR-14138, pp. 48-49, 78-79, 84-85,93, 114 Based on work through May 1980 SHARED -- Under the Research Agreement between SIRM and Shell Oil Company dated January 1, 1960, as amended. lam 026494 ABS-056625 X TABLE OF CONTENTS Abstract...................... Page ii Introduction......................................................................................................................... 1 Experimental.................................................. 3 Discussion.................................. 7 References.............................................................................................................................................................. Appendix............................................................................................................................*....................................... 3.1 WRC 210-80 LAM 026495 ABS-056626 11 ABSTRACT A simple spot test(developed by NIOSH) for the presence of asbestos, a known carcinogen in Insulating material, has been evaluated.- It is based on the colorimetric determinations of magnesium (II) and iron (II) which serve as indicators for the likely presence of asbestos. The method was found to be reliable and suitable for field use. The necessary safety factors in performance of the test were also established. WRC 210-80 LAM 026496 ABS-056627 * 1 Technical Progress Report WRC 210-80 DETECTION OF ASBESTOS IN BULK INSULATION MATERIALS An Evaluation of the NIOSH "Test for Screening Asbestos" by R. E. Evans INTRODUCTION "Asbestos" is a generic term for groups of naturally-occuring, hydrated mineral silicates. They are economically important for their high tensile strength, flexibility, and resistance to heat and chemical attack^. The primary use of asbestos in the petroleum and petrochemical industries is a3 an insulating material on process units and piping. Although no longer used in new work, asbestos is regularly encountered in the removal of old insulation from many units. The removal or "rip-out" processes are of qreat concern as these actions provide the fibrous asbestos 2) . greatest potential for exposure to Exposure to asbestos has been determined to be a serious health hazard responsible for benign and sometimes malignant diseases. Short-term exposures can lead to asbestosis, a chronic respiratory disease characterized by fibrosis in the lungs. Long-term exposures have been related to upper respiratory, pulmonary and gastro-intestinal cancer. The Occupational Safety and Health Administration and the Environ mental Protection Agency emphasized the health hazard potential of asbestos exposure by listing fibrous asbestos as a carcinogen in Title 29 of the "Code of Federal Regulations" and by establishing emission standards for asbestos operations in Title 40 of the "Code of Federal Regulations". These references contain a permissible exposure limit for asbestos as well as detailed informa tion concerning handling of asbestos materials, personal protection and monitoring, environmental monitoring, warning labels, disposal, employee 3 4) exposure records, and medical examinations ' . The monitoring, handling, and disposal of asbestos materials as discussed in these regulations can be quite expensive. It is important, therefore, that the presence or absence of asbestos in bulk insulations be determined quickly and efficiently. LAM 026497 WRC 210-80 ABS-056628 2 Many analytical procedures have been developed for determining asbestos content in insulation materials. They include techniques involving optical microscopy, phase-contrast microscopy, electron microscopy, polarized-light microscopy with dispersion staining. X-ray diffraction, and differential thermal analysis^K These techniques require special equipment and trained personnel for their performance in addition to being costly and time consuming. The National Institute for Occupational Safety & Health (NIOSH) Screening Test for Asbestos reported by Kim, Kupel, and Carter in October of 1979 is a quick, single, inexpensive method which may be used for detecting the possible presence of asbestos in bulk insulation materials^. It is easy to perform and suitable for field use by someone trained in the safe handling of chemicals. The test provides a sensitive detection of magnesium and iron compounds which may indicate the presence of chrysotile, amosite, and crocidolite (Table 1). These are the three most common forms of asbestos found in thermal insulation materials. Samples containing as little as 1-3% asbestos can be reliably detected with a minimum of facilities and apparatus7^. Table 1. ELEMENTAL COMPOSITION OF ASBESTOS TYPES Asbestos Type Formulae *^ Chrysotile Amos. ite1*'\ Mg3 Si2 05 (OH)4 (Fe Mg)6 Si8 022 (OH)2 Crocidolite Na2 Fe5 SiQ 022 (0H)2 1) "Control Techniques for Asbestos Air Pollutants", U.S. Environmental Protection Agency, Pub. No. AP-117, 1973, P. 2-2. 2) Although amosite contains both iron and magnesium, the magnesium does not produce a positive test. See Reference 7. WRC 210-80 LAM 026498 ABS-056629 3 EXPERIMENTAL The procedures used in this evaluation followed those outlined in the NIOSH Screening Test for Asbestos6^. A diagram of the test is shown in Figure 1. It can be divided into four basic parts, namely the interference determinations, the wash and filtration steps, the magnesium test, and the iron test. The detailed method (SRC 11A15/80) is included in the Appendix. The presence of interfering substances is determimed by placing a drop of the magnesium color reagent and the iron color reagent onto fresh portions of insulation samples. Any samples developing blue or red color complexes at this point are washed and filtered which promotes the removal of interfering substances. Samples containing plaster, mineral wool, or glass fiber materials are also washed and filtered as instructed by the method. The wash and filtration steps are accomplished prior to the magne sium and iron tests to remove soluble, interfering compounds. Pea-sized portions of each sample are washed in a disposable beaker with glycerin before the magnesium test to eliminate interferences such as calcium and soluble magnesium compounds found in plasters and mineral wools. The washed sample is then filtered through a 0.8 um mixed cellulose ester filter held in a Swinnex filtering apparatus and rinsed five times with double de-ionized water. An acid-wash is performed on separate portions of samples before the iron test to remove soluble iron compounds. After washing with concentrated glacial acetic acid and sulfuric acid in a disposable beaker, the samples are filtered through a 5 um polyvinyl chloride filter held in a Swinnex filtering appara tus. PVC filters are used for this step as they do not dissolve in acid solutions as will mixed cellulose ester filters. It should be mentioned that all of the samples tested at Westhollow Research Center (WRC) were carried through the wash-filtration steps since the majority contained cement or plaster-like binders and others appeared to be composed of glass fiber or mineral wool materials. After the wash and filtration steps are completed, the samples are tested for iron and magnesium. The filters are removed from their holders and placed on Teflon watch glasses. Drop-wise additions of phosphoric acid, sodium hydroxide, and magnesium color reagent are made to the glycerin-washed filters. The resulting solutions are mixed with glass stirring rods. The formation of a deep blue color complex is considered to be a positive test for WRC 210-80 LAM 026499 ABS-056630 Magnesium Test: A Iron Test: Figure 1. NIOSH Screening Test WRC 210-80 04553 LAM 026500 ABS-056631 5 magnesium. For the iron test, hydrofluoric acid and iron color reagent are added to the acid-washed filter by drop-wise addition. Plastic dropping pipettes are used to add the hydrofluoric acid and stir the solutions as hydrofluoric acid is corrosive to glass materials. The formation of a red or orange color complex is considered to be a positive test for iron. If either the magnesium test or the iron test gives a positive result, then it is assumed the sample contains asbestos. The sample must then be submitted for an instrumental analysis to determine the nature and content of the asbestos in the sample. A number of the samples used in the evaluation had been analyzed by optical and scanning electrom microscopy prior to the development of the Screening 'Pest. These results were not revealed until after perform ance of the Screening Tfest, however. See Table 2. WRC 210-80 LAM 026501 ABS-056632 b Table 2 COMPARISON OF ASBESTOS TEST RESULTS Sample No. IHL 1126 IHL 131-144 IHL 6163 WRC 49695 (a) WRC 49695 (b) IHL 10470 IHL 11091 IHL 12723 IHL 12735 IHL 12736 IHL 12737 IHL 12738 IHL 12739 IHL 12740 IHL 12741 IHL 13045 IHL 13053 IHL 13400 IHL 13401 IHL 13558 IHL 13559 IHL 13560 IHL 13561 IHL 13562 IHL 13563 IHL 13888 IHL 13889 IHL 13902 Description Screening Test Mq+2 Fe+2 Bellaire Analysis Hangar Insulation (6-29-76) Flasher Insulation (9-76) Steampiping Insulation (2-3-78) Old Insulation (3-20-79) New Cloth Insulation (3-20-79) Fire proofing material (6-11-79) Insulation material (8-7-79) Compressor insulation (1-11-80) Process unit insulation (1-18-80) Process unit insulation (1-18-80) Process unit insulation (1-18-80) Piping insulation (1-18-80) Piping insulation (1-18-80) Process unit insulation (1-18-80) Piping insulation (1-18-80) Bulk insulation (2-9-80) - + + + + -- Bulk insulation (2-19-80) Transite board (3-13-80) Brake drum lining (3-13-80) Process unit insulation (3-20-80) Process unit insulation (3-20-80) Process unit insulation (3-20-80) Piping insulation (3-20-80) Piping insulation (3-20-80) Piping insulation (3-20-80) Process unit insulation (4-29-80) Process unit insulation (4-29-80) Pipe shields (3-5-80) + + - - No asbestos + Small amount + 5-10% asbestos Mostly amosite + Mostly chrysotile + 50% asbestos Amosite^ + 10% asbestos + 10% asbestos - No asbestos + 10% asbestos + 10% asbestos + 20% asbestos + 20% asbestos + 20% asbestos + 10% crocidolite or anthophyllite - No asbestos + 50% asbestos + About 1% .asbestos + 60% asbestos 30% asbestos + No asbestos 60% asbestos 5% asbestos + 50% asbestos + 30-50% asbestos + No asbestos + 80% asbestos 1) This sample identified as amosite by Hager Laboratories of Denver, Colorado using polarized-light microscopy with dispersion staining. WRC 210-80 LAM 026502 I ABS-056633 7 DISCUSSION A total of 28 samples have been analyzed by the Screening Test at WRC. Confirmatory analyses were performed at the Bellaire Research Center by optical and electron microscopic and X-ray methods. The results are summa rized below: No. of Samples % of Total True Positive False Positive True Negative 23 2 3 False Negative 0 83 7 10 0 The NIOSH results involving 198 field samples were as follows: No. of Samples % of Total True Positive 79 False Positive 50 True Negative 69 40 25 35 False Negative n o These results were obtained without using the acid wash step in the iron test. Thirteen samples were later analyzed with the acid wash steps imple mented and the results were: LAM 026503 WRC 210-80 ABS-056634 8 True Positive False Positive True Negative False Negative No. of samples 508 0 % of total 38 0 62 0 Tie Screening Test method is stated to be sensitive to samples containing 1% or greater asbestos. In our evaluation of the method, the majority of the samples contained 5% or greater asbestos and positive results were obtained for these samples. One sample was estimated to contain about 1% asbestos and a positive result was achieved for the iron test. This positive result is questionable however as the sample contained a metallic powder which may have interfered with the test. Our results and those of NIOSH showed no false negatives, ttius one can have a high degree of confidence in judging a material to be asbestos free if negative iron and magnesium results are obtained. In addition, there are relatively few false positives, so little time will be wasted on unnecessary confirmatory tests. The iron test is more reliable for detecting the presence of asbestos than the magnesium test for the samples tested. Familiarity and confidence should be developed by performing the tests on samples of known composition prior to any actual determinations. Ihere are several safety factors which should be noted when dealing with the reagents in the Screening Test. Several types of acids are used in the wash steps and care must be taken as splattering may occur when these acids react with the samples under test. In the magnesium test, care should be exercised in the addition of phosphoric acid and 10 N sodium hydroxide as these can react vigorously to produce fuming and splattering. Extreme caution should be used in the handling of hydrofluoric acid. Tie hazards of this acid cannot be overemphasized. It is an extreme irritant and can cause severe burns which occur as.a delayed reaction when the acid comes in contact with the skin. Anyone performing the Screening Test should be trained in the safe handling of chemicals and be aware of the hazards involved in this test. WRC 210-80 LAM 026504 ABS-056635 9 The NIOSH Screening Test is a useful method for in-plant determina tions of asbestos presence in bulk insulation. It would permit the separation of materials containing asbestos from those not containing asbestos and lead to a cost reduction in the handling and disposal of non-asbestos materials. Test kits are currently being marketed commercially with apparatus. reagents, and instructions for performing the Screening Test. They are available from: SMC, Inc. R.D. 1 #395 Valley View Rd. Eighty-Four, PA 15330 (412) 941-9701 Anatole J. Sipin Co., 505 Eighth Avenue New York, NY 10018 (212) 695-5706 Inc. Both kits are available for about $100.00 each and will screen about 25 samples. There are minor differences in the test instructions and in the apparatus. The SIC instructions are more straightforward and its procedure appears easier to perform. The Sipin kit contained no warnings as to the hazards of the reagents either on the reagent bottle labels or in the test instructions. Anyone using the Sipin kit should possess a thorough knowledge of the test procedures and the chemicals involved. One additional difference concerned the shelf life of the reagents. Sipin claimed a shelf life of one month while SMC claimed a shelf life of three months. The Sipin claim is the same as that noted by the developers of the Screening Test. The SIC claim does not appear to be unreasonable, however. The test reagents have been used at WRC for periods of up to three months with no apparent loss in sensitivity. It is advisable to include samples which are known to give positive results as a reagent check during each set of analyses. If a large number of samples are to be screened over a long period of time and laboratory facilities are available, it is recommended that reagents and supplies be ordered separately from scientific supply companies. Reagents could then be prepared as needed and the total cost of supplies would be reduced. WRC 210-80 ABS-056636 10 REFERENCES 1. "Asbestos: An Information Resource," U. S. Department of Health, Educa tion and Welfare Publication Number (NIH) 79-1681, 1979, p. 1. 2. Ibid., p. 48. 3. "Code of Federal Regulations," Office of the Federal Register, National Archives and Records Service, General Services Administration, 1979, 29CFR 1910.1001 pp. 580-585. 4. "Code of Federal Regulations," Office of the Federal Register, National Archives and Record Service, General Services Administration, 1979, 40CFR 61, Subpart B. 5. Labbauf, A., "Update on Asbestos," Penn Environmental Health, Pittsburgh, Pennsylvania, 1980, pp. 12-16. 6. Kim, Walter S., Kupel, Richard E., and Carter, James W. "Test for Screening Asbestos," National Institute for Occupational Safety and Health, Division of Physical Sciences and Engineering. October, 1979. 7. "Asbestos Identification and Measurement - Proceedings of a Topical Symposium, April 9, 1979, Des Plaines, Illinois," American Conference of Governmental Industrial Hygienists, 1979, pp. 18-20. WRC 210-80 LAM 026506 ABS-056637 APPENDIX LAM 026507 ABS-056638 11 $ 1 I i -I *1 i 4 ( { j I i . ' SHELL RESEARCH COMPLEX METHOD SERIES SRC 11A15/80 SHELL DEVELOPMENT COMPANY ANALYTICAL DEPARTMENT Determination of THE PRESENCE OF ASBESTOS IN BULK INSULATION MATERIALS1* Hazardous materials used In this method are designated "(CAUTION*)" in the REAGENTS and PROCEDURE Sections. A Material Safety Data Sheet for each material so desig nated may be found in the PRECAUTIONARY INFORMATION at the end of the method. Operations which may present a hazard are given in the UNUSUAL OPERATIONAL HAZARDS section. SCOPE 1. This method describes a colorimetric spot-test for determination of Magnesium (II) and Iron (II) in bulk insulation materials which may indicate the possible presence of asbestos in the chrysotlle, amoslte, and crocldolite forms. The method does not determine asbestos itself. NOTE li Magnesium (II) is a principle component of chrysotlle asbestos; Iron (II) is a principle component of amoslte asbestos and crocldolite asbestos. METHOD SUMMARY 2. Small portions of bulk insulation material are complexed with p-- nitrophenylazo-a-naphthol for Magnesium (II) and 1,10-phenanthrollne for Iron (II). A positive reaction for Magnesium (II) is indicated by a bluecolor complex formation. A positive reaction for Iron (II) is indicated by a red-color complex formation. INTERFERENCES 3. Soluble magnesium or iron compounds not associated with asbestos may give false-positive results. Calcium found in plaster as CaSO^ is a positive interference in the Magnesium (II) test. Details for washing sample portions prior to testing are provided in the method to aid in the removal of interfering substances. Positive results should be confirmed by other analytical techniques. No false-negative results have been noted. ^Based on NIOSH Screening Test for Asbestos developed by Kupel, Kira and Carter in October, 1979. 2 HAZARDOUS TEST CONDITIONS 4. Asbestos has been determined to be a human carcinogen. All bulk insulation samples under test should be handled as if they contained asbestos. They should be handled in a manner to avoid creation of dust in the air. Analysis should be performed in a hood with sufficient face velocity to eliminate the possibility of Inhalation of fibrous asbestos material. Samples should be stored in sealed containers or air tight plastic bags. Extreme caution should be exercised in the handling of hydrofluoric acid. It is an extremely toxic irritant and may cause serious bums upon contact with skin. Fumes are also hazardous to eyes, throat, and lungs. APPARATUS 5. (a) Teflon* watchglass: Scientific Products. 3 in. diameter. Cat. No. W2510-2. (b) Teflon* stirring rods: Horizon Ecology Company. 6 in. length. Cat. No. 6368-10. (c) Plastic dropping pipettes; Scientific Products. Unitary dropper. Cat. No. P5218. (d) 30ml Teflon* beakers: Nalge Company. Griffin Beaker. Cat. No. 1500-0030. (e) 10ml Plastic disposable syringe w/Luer fitting; VWR Scientific, Inc. B-D Plastlpak. Cat. No. BD5604. (f) 25mm Swlnnex filter holder and gasket; Milllpore Corporation. 25mm. Cat. No. SXOO 025 01. (g) 25am 0.8um Mixed cellulose ester filters: Milllpore Corporation. Cat. No. AAUP 025 00. (h) 25mm 5um Polyvinyl chloride filter; Gelman Instrument Co. VM-1 membrane filter. Product No. 60692. (1) Assorted glassware for preparing reagents. NOTE 2: Kits containing reagents and apparatus for performing about 25 determinations are available from the following suppliers: SKC-Wese, Ine. P.O. Box 2805 Fullerton, California 92633 Anatole J. Slpln Co., Inc 505 Eighth Avenue New York, New York 10018 WRC 210-80 LAM 026509 3 NOTE 3: Teflon or plastic apparatus should be used In perfomance of the magnesium and iron tests because of their Inertness and resistance to corrosive chemicals. REAGENTS 6. (a) Purity of chemicals. All chemicals should be of analytical reagent quality or better. Double deionized water should be used In prepara tion of reagents and throughout test procedures. (b) Phosphoric acid, concentrated (*CAUTION*). (c) 10 N Sodium hydroxide (`CAUTION*). Dissolve 40g of NaOH (`CAUTION*) In 10ml of double deionized water. (d) Magnesium reagent. Dissolve lmg of p-nltrophenylazo-a-naphthol (`CAUTION*) In 100ml of 2N NaOH (`CAUTION*). Age at least one day. Reagent Is stable approximately one month. (e) Hydrochloric acid, concentrated (`CAUTION*). (f) Hydrofluoric acid (`CAUTION*). Dilute 20ml of 48Z HP with 20ml of water. Add 0.6ml of concentrated HC1 (`CAUTION*). (g) Ethanol. 95Z (`CAUTION*). (h) Iron reagent. Dissolve 2g of 1,10-phenanthrollne (`CAUTION*) in 50ml of 95Z ethanol (`CAUTION*). Reagent is stable approximately one month. (1) Glycerin, reagent grade. (j) Acetic acid, concentrated glacial (`CAUTION*). (k) Sulfuric acid, concentrated (`CAUTION*). PROCEDURE 7. (a) Collection of samples. Several samples of bulk material should be obtained for a given area. They should be properly labeled and their color, l*xture, and general physical appearance should be noted. Each sample should be stored In Its own sealed container or air-tight plastic bag. MOTE 4; Due to the presence of non-asbestos insulations In repair work, patch work, and new construction. It is recommended several samples be taken to obtain a representative view of the type or types of materials being handled. (h) Cleaning of apparatus. All apparatus should be rinsed thoroughly with double deionized water to remove any substances which might Interfere with the tests. LAM 026510 WRC 210-80 ABS-056641 14 4 (c) Magnesium Interferences cheek. Obtain a fresh,representative portion of the sample about the size of a large pea and place It on a Teflon vatchglass. Add a few drops of the magnesium color reagent to the sample. A blue color development Indicates an Interference Is present and the sample must be washed with glycerin and filtered with water prior to the magnesium test (7e). If a color Is not observed, the wash-filtration step may be eliminated. NOTE 5: Samples containing plaster must be washed prior to the magnesium test. (d) Glycerin Wash. Place a fresh, pea-sized portion of sample In a 30ml beaker. Add 5 drops of glycerin and mix well with a stirring rod. Rinse stirring rod with approximately 10ml of water. Draw up the resulting solution with a 10ml plastic syringe and attach the syringe to a 25na Swlnnex filtering apparatus containing a 0.8pm mixed cellulose ester filter and gasket. Filter the sample and then wash by Injecting a minimum of 50ml of water Into the Swlnnex apparatus using the 10ml syringe. Five 10ml washes are the minimum number of washes to be performed. Remove the filter and v place on a clean Teflon vatchglass for the magnesium test (7e). . (e) Magnesium Test. Place a fresh portion of the sample (or the filter from the wash step)on a clean Teflon vatchglass. Add a drop of concentrated H.PO4 (`CAUTION*) and mix by grinding the sample with a plastic stirring rod. JAdd 2 drops of 10N NaOH (`CAUTION*) and mix well. Add 5 drops of magnesium color reagent and stir briefly noting any color change. Add 5 more drops of the color Teagent and note final coloT. (f) Observations. A blue color formation indicates chrysotlle may be present. The sample should be submitted for analysis by other techniques for a confirming determination. If a blue color does not appear the sample must be tested for Iron. (g) Iron Interference Test. Place a fresh portion of sample on a Teflon vatchglass and add several drops of the Iron color reagent directly to the sample. A red color Indicates an Interference Is present. The sample must be add washed and filtered prior to the iron test procedure. If a red color Is not observed, the Iron test may be performed without the wash step. NOTE 6: Samples containing plaster, mineral wool or fiberglass should be washed prior to the Iron test. (h) Acid Wash. Place a fresh, pea-sized portion of the sample In a 30ml beaker. Add 5 drops of concentrated acetic acid (`CAUTION*) and 5 drops of concentrated sulfuric acid (`CAUTION*). NOTE 7: Caution should be exercised In the above steps as addition of acids with some samples will result In bubbling and spattering. 1. i * WRC 210-80 LAM 026511 ABS-056642 15 Mix well and ultrasonicate for 5 minutes If available. Rinse stirring rod into beaker with approximately 10ml of water. Using a 10ml syringe draw up sample solution and filter through a Swinnex filter holder containing a 5pm polyvinyl chloride filter and gasket. Wash with a minimum of 5 washings or about 50ml of water. Remove the filter and place in a clean TeflonS watchglass for iron test (71). (i) Iron Test. To a fresh portion of sample (or washed filter sample) add a drop of hydrofluoric acid (*CAUTI0N*). Mix well. Add 5 drops of the iron color reagent. NOTE 8: Exercise caution as the addition of hydrofluoric acid to some samples may result in bubbling and spattering of materials. (j) Observations. A red color Indicates either amoslte asbestos or crocldollte asbestos may be present. The sample should be submitted for analysis by other techniques for a confirmative identification. If no color development was noted in either the magnesium test or the iron test, the probability of asbestos being present is very low. PRECISION AND ACCURACY 8. (a) This method may indicate the presence of as little as IX - 3Z asbestos material. (b) NIOSH results using the Screening Test on 198 building material samples were as follows: Without Acid Wash Step No. of Samples True Positive False Positive True Negative False Negative 79 50 69 With Acid Wash Step (13 Samples) 0 No. of Samples 5 0 8 0 WKC 210-flO lam 026512 ABS-056643 16 PRECAUTIONARY INFORMATION 1 1 f t i The precautionary Information presented in the MSDS's in this section represents the best information available at the time of publication. The MSDS file is continually updated. If a significant time period has elapsed since publication of the method, the user is urged to check for changes in or additions to the information presented here. Current information may be obtained by contacting: Manager, Analytical Chemical/011 Shell Development Co. Westhollow Research Center P.0. Box 1380 Houston, TX 770C1 ?! ij Precautionary Statements Materials For Which No MSDS Is Available MSDS's are in preparation for the following materials. Contact Manager, Analytical Chemical/Oil at the address given on the title page of this section for completed MSDS's. t WRC 210-80 p-nitrophenylaio-o-napthol LAM 026513 ABS-056644 WRC 17 ;:*m w ui40H*Mr 1H) Hn* U * Mf #?* ** Ull h>m r>Mi *** mii* SMELL OIL CO*?AHT SHELL CHEUtCAL CCaPANY SHELL DEVELOPMENT COMPANY SHELL PIPE LIHE CORPORATION rating MSQS 30F,980-78 material safety data sheet HT?A *#** ** W* * #* ' |A. 0(twSM"i< $** * < *U * I>J l* fa# |*r # W nw<t a KM * |T(M SECTION 1 Hooker Cie-icals 4 Plastics Coro. J*w. C'f. !***. Zip CW*i Kiazar-* Ptlis. I.ev York 1UT03 *.< Ml )# ;* T16-2T8-TTTT ! Phosphoric Acid SECTION II HAZARDOUS INGREDIENTS* THIS PRODUCT IS A PURCHASED MATERIAL. SEE ATTACHED MATERIAL SAFETY DATA SHEET FROM THE MANUFACTURER. 0*0*1 & eT 1 9% Vi*0* *ntg*(|MKl| V408 Ot+**Tl 4PM4*C| 43C33* SECTION III PHYSICAL DATA secmc c**virv ihjObm n | C"Ct*r goc*TK( f VOkUMf C.l i **fe --------------------- ___________ L________________ :_________________________________ ________ __________________ SECTION IV FIRE AND EXPLOSION HAZARD DATA fiil* **! (m<AW *Wi Ll V* SMdti fl(| ftMfiM lettt(0 Mt Ml UniltM MW.AW Ip 0*1 C^-p^-y LAM 026514 WRC 210-80 ABS-056645 18 Si floo&sr Industrial chemicals *94*7X3 MOMUIOI. no. k MATERIAL SAFETY DATA SHEET NFPA Designation ChCkiCal NAMC; k*n f COOS MAfCAtak C3CS *eO Phosohoric Acid Manvr*cruci* hamc. Hooker ChenlcAls L Plastics Coro. (716) - 273-7777 Niagara Falls. New York 14302 (iMlCAb hiM| AMO ITnQnmS CHMiC*k Orthoohosahoric Acid **Ok. T. h3p4 98.00 r40l m**e Phosohoric Acid Kf* of u,t` ehenieals, food additives; aistal-treat Physical Properties etc SOU.INC POINT ( (757. Soln) VAPOR PRESSURE (.. (3 25C VAPOR DENSITY lAIRAI) 275 5.0 $pCi^iC gravity im.O ;i> PSHC2NT VOLATiLC Y VOLUVIM CVAPOPATIONS PAT fl SOLU3JLITY IN were* APPEARANCE AnO COOR verv sol. Odorless, viscous liauld 1.574 r^AlM *omr none e f moo Fire and Explasicn Hazard Data CIMt?S UCL---- LL -- AUTOIONITION TENP.' oon# Op EXTINGUISHING MEOIA special, nee pick ting procedures . As appropriate far surrounding fire. UNUSUAL PIPE ANO XPLOSION HAZAflOS Will liberate hvdrogen uoon contact with -inv n.r.1. Protect personnel against aist. vaoor or solashes. Reactivity - incompatibility Reacts vtiorouslv with alkalies, producing heat: oraducini heat and fl--St. hvdrozen gas. with stanv cetals. HAZAPOOU3 OffCOMPCSlTlCN PRODUCTS phosphorus pentoxide. Heating to decor.oositicn vields furces of toxic_________ Conditions TO Avoio Avoid contact with skin and eves. Avoid contact with strong alkalies or with cetals except certain stainless steels. i si t Mlt. 11-1910 WRC 210-80 WRC ABS-056646 19 threshold limit value * <r-n-i-iFTa:3 Pe* cuoic ~eter,_______________________ ______ ______-- effectsof overexposure isxiN.SYE.iNMalaticn.stc.i Contact wtth skin End eves causes( irtitatlcn and can product bums. Ingestion can cause irritation and tumin; of the mucous membranes of the gastro-intestinal tract. Inhalation of mist cav causa v irritation of the respiratory tract.___________________ emergency anq pipit aio paorgmipxx EYES & SiilM; Flush w-th large amounts of water. 1MCESTI0M: Dilute bv drinking large amounts of water, induce vomiting. ISHALA.TIOM: Removal to clean air is usually sufficient; pay be administered. for severe Exposure, ot/?m special medical procedures Get medical attention for all is symptomatic and no specific antidotes are known.~ Tyii^anr ______________________ VENTILATION . Sprciol Protection Information General Toon ventilation.__ ___________ RESPIRATORY (TYPE! . Mist protection where appropriate. CLOVES (TYPE! ______ Rubber, neoorege. eye irvtfgi Chemical safety goggles, plus face shield where appropriate. Other Rubber over leather shoes or rubber shoes. Rub**.-, nii> i x impervious, clothing to protect against splashes.__________________________________ _________ _____ sp^ciaL precautions TOR HANDLING ano storage Store away from heat and separately ;roa alkalies. Neutralizing areata or absorbents and a ready supn'.v nf uji->- iHn.u v,. available, for eeergescy use. _____________________________________________________ __ __________ steps to take in event op spill or release Get personnel protective, eouionent. targe soills. contain by dikes of sand, etc. If spill caters sewer, dilute with u-ater. trill n-'jtri't?; careful tv wl th limestone m soda h -- avnM ;i:iric rd -- then rinse area wi.tn water. , . . .. WASTE DISPOSAL Fi'H- th ri'iilw >T-t nmrr.l.T* '.nth Iif< I""* HY cfufMlIf,' d'Ti'te caustic soda befora discharge to stream or sewer/ Burv acid-soaked clay as land fill. REMARKS. REFERENCES MCA Chemical Safety Data Sheet SD-70: Phosphoric Acid fl95o1. TV* Ki|(meHR iiRfaj hs<a#a JhU * 0ey*e*J b <Vtc*llr m !** lf ! wf le*Ja^ tms o4 C(UU'P. 11 l| * ,*tm4+4 a* lea <IUii(lt(fe r4 fit* (M* *f ta s4iihi<l ursiJhsmsrIa efeM *"4 kw^lief nam LCC. 0*T C. W. Darling Niagara_____________ February 197? Revised Dec. i.976 C c LAM 026516 WRC 210-80 ABS-056647 20 r94M mo ' SHELL OIL C0M?AHY SHELL CHEMICAL COMPAKY shell pevilopme.it coupamy SHELL PIPE LIKE CORPORATION ^QO/b^0 J-3DS VO. 3C00!i-78 MATERIAL SAFETY DATA SHEET IhI<ifv#4I|'-Th * tAt|*.uUImi('P*i*A ** *!#*'*** *"r ' * *(<* **<% *1A 1** GIj:it * NT?A *" **i*Al *(l # 19*0 "'#* <m1 ft* SECTION 1 Dit=.o-d ShanrocV. Cha-ica! Co.. Electro Chp-. CF. ^00 t/n<rn Cn--*''* C*** ^ . fn vM *n<. <m*n (*(w.C>. **( #0*** ((*<*; r-.k* Division |m(A*C(E SiliTI < *>0C>{ Flake Caiistic Soda RJ, SECTION II HAZAROOUS INGRSOIENTS* THIS PRODUCT IS A PURCHASED MATERIAL. SEE ATTACHED MATERIAL SAFETY DATA SHEET FROM THE MANUFACTURER. OM.I*C 3*T | ft vam31 rLiyj*i {--HjJ va*o sirSi't IOLUlli>T* 1* *TJ SECTION III PHYSICAL DATA 1 | HICHiC CAAViTT IHjOsM I _______ !_______ 1 1 ^CCI*tT VOwATltt f VOlU*( i-. 1 |V*9iflOR *TJ ( # m It | * j SECTION IV FIRE AND EXPLOSION HAZARO DATA *vvwK( miuh **mt **?* #>y;(e*Ri) W*-4 ft* Afc >f to) (% <) 'HM.M r 0.1 C.- WRC 210-80 t W*> 1 U* 1 LAM 026517 .i ABS-056648 21 bia.mond Shamrock Chemical Company S:JWAf fcHiAL SM-ki'i V ELECTRO CHEMICALS DIVISION CHEMICAL MAM* tin lulll FORMULA SODIUM HYDROXIDE NaOH FROOUCT NAME Flake Caustic Soda GENERAL INFORMATION Caustic soda is one of the work-horses or the chemical industry, sharing this position onty svith soda ash and sulfuric acid. There is scarcely a single chemical which does nut require one or more of these three basic chemicals for its production, and furthermore, there is hardly an industrial product which does not depend . upon caustic soda. Caustic soda is normally marketed as a S0% (by weight) liquid solution in tank'trucks. tank cars, and barges. When a dry form of caustic soda is required, it normally Is alripped in bags, drums, bulk trucks, or rail cars. Flake caustic soda has been ctearcd for use under the "Food Additives Amendment of 19SS." HAZARD CLASSIFICATION Flake caustic soda is classified by the Department of Transportation as a CORROSIVE. I. IMPORTANT PHYSICAL AMO CHEMICAL PROPERTIES PHYSICAL STATE Solid FLAMMABLE LIMITS .. n NOfl'IlJitiRlSbid VAPOR PRESSURE ICOCT'C. - <2 ran COLOR ' White LIGHT SENSITIVITY No v . 1050C - G9 min 1 OCOR \ ' *LASM POIMT ;oowd co) None *o eBOoI.LnINnGr.PnO,-v.VTT H3f 3P8mCju.free760mm AUTOlGraiTiON . a, temperature Non-flammable SOLUBILITY 130*0 Completely soluble SPECIFIC CSAVITY (h2o-i.o) 2.130@20C. THRcSHOtO LIMIT value Iair sornE) VAPOR DENSITY AJR-1.0 0/3 zmym ^ .. Does not apply 1!00C. - 109 mm 12003C-232rC Not volatile E,E^Tr,*AT6 Does not app. critical temp. Does not apply density at eo? Approx. 60 Ib./eu.ft. heat of CO.U3USTI0N _ .. Duet not apply II,CHEMICAL REACTIVITY DATA STABLE [ X |Y re HAZARDOUS 0=CO*4?CSITlON PRODUCTS VISCOSITY J3C 4.0 cent!poise S 350C. MINIMAL LETHAL OOSc LOSO TEST reactivity Considerable heat is { when water ifadded to caustic soJ- . Caustic can react viol explosively with strong acids an organic chemicals. n- SCLFPOLYMcRlZS Qv None 0N* AVOID CONTACTS WITH THESE MATERIALS When handling llake caustic, avoid contact with such material; as aluminum, leather, wool, tin. and aiuc and alloys containing these metals. CONDITIONS TO AYOlO Avoid handling conditions which may allow fur leaks and spills of caustic soda. Do not permit personnel 10 bandit caustic soda without proper training or work without protective equipment. `D.t a not available; Electro Chemical* Division / Diamond Snarnroc* Chemical Company / 300 Union Commerce 6v*TCinj. C'eaelJcJ. Ohis a a * '/if** HfFu' % t*f v* I'tteti re *m-4 .. t*E rf .* It It tfoOe. He'.v. < I; f* >w> I ixVIV > ft Ai l > it * .> r* !I rafAtt fttMt* f*t \ l*ta f* *.+ m It * > !tr*f m t.-i'J rfttd m ./ rl * #*W >t Ri'pf Jt-p* Ci-f- res * tart |Ph V >ati ,ier',t in * s : :* y **" ('fu'tf >> 7 Pe* u*F Hp; If f"* i* S'ef ft V.-Mhtrot r..r t -*R*t' *t 'P* M* .*4 0% i*st%Vf'iVt't btN ttr.ut *W4'.t >( h --T* It *t^# It fPl^lft^t Hfr J-ti It Its |!,..o<rt^s.>t .FMftotM^ ItH pmr.H ; ' -----^AfftiV : 0-AV0V5 H*v*9ts CO**0*AX' Mm 026518 WRC 210-80 ABS-05664y Caustic JOOJ .is a strung aixan 3nu i> car.gcrous wiicn iinpiupeily lijnCiMJ. I lie toliii caustic rdconcentrated o!ticnj are destructive to tissues which they may contact. producing severe burns. Contact with the eyes, cither in solid form or in solution, causes severe damage to (tie eye. Intulslioa of ll>(J.jsi*or " ` mist of this compound is capable of causing injury to tlie entire respiratory tuel. Swallowing usually results In severe Injury. f C a. ftasT aio raocsounEs Injtsistion IrhaUcon Jr.jestion of caustic causes severe burns of mucous membranes of the mouth, throat, esophagus and Stomach. Dilution of the chemical by drinking hrje quantities of svatcr Or mil!: may be atlcmplej. After this, dilute vinegar or fruit juice may be given to accomplish neutralization. Vomiting may occur spontaneously, but should not be induced nor should stomach tube be used except on advice of physVian. If discomfort is experienced from exposure to caustic mist or dust, the employee should leave the contaminated atmosphere until proper ventilation is restored and report for medical evaluation. SinCwun Wash skin area with large quantities of water. Continue washing far as long at 1-2 hours or until medic.-l help arrives. No satves/ointments should be used on chemical bums for at least 24 hours. Clotkinz/shoes - welted with caustic should not be worn until after they have been thoroughly washed and dcconttr^inal.-d. A physician should see all cases other than minor exposures. Conner win Eyes if even mtnutc quantities of caustic, solid or solution, enter the eyes, they should be irrigated immediately with cophlt water for a minimum of 15 minutes. Eyelids should be held apart while patient rolls eyes in circular motion during Irrigation to Insure contact with all tissues of rye ar.d lid. A physician should be ________________ called in attendance at the first possible moment._______________________________________ S. VZXSQVAL PROTECTIVE EOunpAtEMT__________________________________________________ . ______ ' Chemical safety goggles: Plastic or rubber frames equipped with resistant glass or plastic lens. Face shields: Plastic shields may be worn in addition to goggles. Eye wash fountains and safety showers must be immediately available. Hard hats should be worn where there is danger from falling objects. Safety shoes or rubber bouts should be warn when handling caustic soda. tv, fins >nu explosion_______________________ c Caustic soda is non-combustible. F>n VlmCv'X teaCeueE Caustic soda is non-cotnbutlible. However, fire extinguishing equipment and adequate water for fire fighting should be available to workmen in alt process or storage areas for welding jobs and where combustible material of any kind is present. Workmen should be trained to prevent wcIJing tires by thoroughly wetting down w-uodrn scaffolds and Carps. ' WHC 210-80 lam 026519 phi ABS-056650 wrc 23 SAMPLE WARNING LABEL This is 3 copy of the label which apptari on all containers of this chemical. It should be noted that the information shown Is for a general class of chemicals end should not be used in place of the more detailed Information presented in this boohleL te.-jo-trwtnsviis ^l --tt; n.-^iTiTrrr.y;~-;p. THIS PACKAGE CONTAINS SODJUAA HYD2PXJD2 (CA'JSTiC SODA) Dangar! Sums Skin and Eyas. Do not get in eyes, on skin, or on clothing. Do not tak internally. Whan handling, waar goggles or face shield. While mak; ing solutions, add Sodium Hydroxide slowly to surface of solution to avoid violent spattering. In case of contact, immediately flush skin with plenty of water and wash with vinegar; for eyes, flush wi.'h planty of wafer for at least 15 minutes and get medical attention. > esco uss.u BOSTON 31 Milk Street Boston. Massachusetts 02IC9 (517) 5-12-0534 CHICAGO 20 North Wacker Drive Chicago. Illinois 63505 (312) 641-3000 CINCINNATI 4701 Paddock Road Cincinnati, Ohio 45223 (513) 242-2300 CLEVELAND 631 Hanna Building 1422 Euclid Avenue Cleveland. Ohio 44115 (216) 781-eoeO Sales Offices HOUSTON 1701 C and I Life Building 1005 Main Street Houston. Texas 77002 (713) 224-5351 MEMPHIS P. O. Box 4350 Crosstown Station Memphis, Tennessee 33104 (901) 273-5550 NEW YORK 99 Park Avenue Ngw York. New York 10015 (212) 637-0440 PHILADELPHIA 320 Walnut Street Philadelphia. Pennsylvania I9IC5 (215) 923-7250 1 PITTSBURGH 93C0 McKnight Rood Pittsburgh. Pennsylvania 1S237 (412) 931-4530 REDWOOD CITY P. O. Box 829 Redwood City. California 9405-4 (415) 369-0071 ST. LOUIS 7701 Forsyth Boulevard SL Louis. Missouri 63103 P14) 721-7900 LOS ANGELES 4814 Loma Vista Los Ar.; ores. California S0C53 (213) 533-9521 rni.-.-r-:o u.s a. WRC 210-80 Diamond Shamrock Chemical Company Electro Chemicals Division 300 Union Commerce Building Cleveland. Ohio <4115 AVAtlof OiamdPd Shgm/Mb Co'pd'a.on 2IGG21GI00 fC 1 LAM 026520 ABS-056651 - *: 24 f ( (\. C. ) tliooM be yvaiUbl* for eiMCfgicy'ue \n dissolving or minims ana ituJtii);* av/jy spmeo cau>ctc. opmey *ofi<I form* of caustic may be shoveled up, followed by Ruddn*; with water. Dilute acid, preferably acetic aci-J, may be ujed to neutralize the final traces of caustic immediately after flushing. V/asbinj or mopping / sintljr leaks may be fallowed by a liberal covering of sodium bicarbonate for remo**in^ the bst traces of caustic. WASTE DISPOSAL Waite disposal of caustic soda depends to a {real extent upon tool requirements. Be sure tint all federal, state, and local regulations regarding health and pollution ere followed. Waste caustic soda solution should not be discharged directly into sewers or streams. The caustic sods should first be converted to a neutral salt, as by neutralization with acid, and then well diluted with water. Strong alkali tends to diminish bacterial activity needed for proper sewage disposal by Increasing lire ilkatinity to unfavorable levels. In tire event of accidental spillage, advise the municipal sewage plant if (he discharge wilt enter a municipal system or the state water pollution control board if the chemical will be discharged into slate waters. >DISPOSAL and RETURN PROCEDURES (Returnable Containers) Returnable containers should be shipped in accordance with die supplier's recommendations. Return shipment should comply with all federal, state, and Department of Transportation regulations. NON-RETURNABLE CONTAINERS^*- Alt residua! caustic soda should be removed from the container prior to disposal. \ SPECIAL HANDLING end STORAGE PROCEDURES The Department of Transportation has proposed an amendment to their regulations which wilt classify flake caustic icda as corrosive. Personal protective clothing and handling equipment should be used when handling (lake caustic. 5torage should be provided in an area which will rot allow pick up of moisture. wrc 210-80 lam 026521 ABS-056652 25 vili tki ! H !'** vH| # (ay t|ktl UM -- ll'lhlt f'OA0l l* f$* MliM SHfLL oil COMPANY SHELL CHEMICAL COMPANY SHELL DEVELOPMENT COMPANY SHELL PIPE LINE CORPORATION MSOS 326,320-78 SSDS 32632-78 MAZaBD BaT'NC MATERIAL SAFETY DATA SHEET * * III * *r < 1* *** *# *' Aet t 0 <* ** *I|I |N*MM *** %'* M | '<* pI| ** SECTION I ntyrt(N*{* I klMt Jfelllnciirott.. Inc Kalllnckrodt t Second Streets. St. Louis 631R7 3i.li-231-8980 Hydrochloric Acid SECTION II HAZAROOUS INGREDIENTS' THIS PRODUCT IS A PURCHASED MATERIAL. SEE ATTACHED MATERIAL SAFETY DATA SHEET FROM THE MANUFACTURER. I9IUN6 AO**T 1 r V40* MCDuRf v*OA 0(||7T Ililan SECTION III PHYSICAL DATA IIIC1I1C 6MV1TV iMjOatu NNNfVOilTai V VOkU(M 1 !',* ____________ 1__________________________________________________ f*4- *<t (UsA^vst^l SECTION IV FIRE AND EXPLOSION HAZARD OATA lvssilsf l **.* ttt.Rtw't*.** *(* MiH fiMfnl vnWit Ml Ml UMim uimt >Wi/W If &>U 0*1 Cm* WRC 210-80 LAM 026522 ABS-056653 26 r **< ! Nt. 44RI3R? : ' ui) iloiS) F> Mr. OIHA-M , mi OCCUPATIONAL SAFETY .-J HEALTH ADMINISTRATION MATERIAL SAFETY DATA SHEET SECTION 1 09MSS KALLIMCKRODT. INC. |U|CtCr IUOmOM NO. sum-mo St*0*t. C*f>. SlU, ..izinu.i UALLINCKROOT a SECOND STREETS. ST. LOUIS. HO. SUSP CMtMtCAl NAMf AMO SYNONYMS Hydrochloric Acid Chemical family ____Inorganic acid_______ | INAOC NAUC AMO SVHONtWS j loauuL CHlfequeous tolnl SECTION II HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES. A SOLVENTS nct**rs TLV ALLOTS AMO METALLIC COATlMCS *M U(T*l i s TLV (OAtf) WtTAUlC COATINGS 9IU(A UllAl nut CQATinC OR COf fiu OTHER} HAZARDOUS MIXTURES OF OTHER LIQUID}. SOLIDS. OR CASES TLV KMn! :,i. B,nw ?, .gir r .r a r .- ~ , Jgm ggs= a ^ t x 7 StCTION 111 PHYSICAL DATA ouimg *o*nt fm s**cmc c*vir iNao*u V4RA rtlSSUH MW h*j URGENT VOLATILE >t ypium \i -4,xa. 100 VAOA DENSITY tAtA A$) SOVUS'UTV IN AT|I Infinitely -li Ei VAPwOaRAtTeIOrN SATE olsclble boot t >N|ilUCI AND OCO ,, , , . . ... .. M--------------------------------- Cler, colorltpt solution. pungent odor of bvdrpen chloride. rS :* . feCTION TV FIRE AND EIPIOSIOK HAZARD DATA lUSaSAMI |U>PMNI (LAUUARLE LIMITS 1 UIIN6UISNIN0 MEDIA paoCeoSiiss*1* I SPECIAL Ml MCnllNC PAOitOuMS I Wear full pretggMvg elnt-Mny Rnd fpr the supporting flre- rpT f rnntmiivd brrafMry RpparRMiN. UNUSUAL MM AND EE'lOSION HAIA.OS C/mUff tilph rrW prruSiypR bydrnfpn uMrb fnrrs pvpTnufv -IvPiirrR tl>S tr. WRC 210-80 lam 026523 ABS-056654 wrc iMtl VMUt ..5-Pgff iMicrs * ovimt^osuM ... Concentrated solution* causes severe burnt* pertaMpLyliutl damage oa* occur. l i rSalaHon! Couth. choVlrg. lnflaraetoo of respiratory tract. Inaeitton! eorroif i !n*itttacinHoci 4*noa m>u*it a*>ido nocctoowuss A0; njcous ceefcran**, nnaa.u..iaea,. viaoo7l7tl7r^g. , diarrhea I- 1 Hr ? vash veil f Trr*clHon *r>d Inhalation? , >#S ** ' , . st.su, nr s *: e UNJTASLt for !. ml rate. vlrti vitfr. see physician.__________________ - *'~ f ' .... . M . 'V .* -- .f SECTION VI REACTIVITY OATA V%. COAOiTiON}tOAVO:D - * --------------- ---------- * - w 4* 4>*. a &((&&&}!:*$ SUHI _x____ - INC0M4TAHvnv It Acldt-and cKt.alt. t NAJA*C0U1 OlCC>dOSiTlO MOOVCTS -u=e* ot hydrogen chloride and hvdrogetL In contact vlth re tala, NAfAAOOUS FOlYUtMXATlO* VAT occu *hi not occva COMQITlQNS tO AVOtO __ z___ chlorine t'f frog oxidizes V~ secnon vii cntoV^ssbtris^ .. Z= tu1 to l MI> IN C* M*T(t*l it MU AMO 0 tfiutO ... :I Cover contaminated surface vith sodlua bicarbonate or a soda ash, staked line nix -4j " tureCs3l~S0l. Hlx and add vater if necessary to form a slurry. Scoop up silifrrrrrrr aanndi-^* >vash down drain vlth excess uater. Wash site vlth soda ash solutions Mill DitKiUKItHOO Aid slc*->l* to larze volusa of agitated aolutlon of toda ash or slaVa lie. Add (* r< M neutralized aolueton to excess running uatcr to sever. Aa an added precaution, theH 0 jJ.g^djVlfh^protfctlve rertljif and f l^ed wjrh r _______________________SECtlOU VIII S?CLf.L reOTECTlOa trCrO-U'-ATIQ.V v. ^ . " .imutonHmcimfWM m.v with aeld vapor canister or self breathlr^ apparatus 7VC3NTttLAIZTtOZH ilOoCeA*iitliMiHA.UuSsTr : SAICIAL UlCM.NIC.i./f'X.U OTKIA ' MOT(C1lv( OiOviS K u.b.ber 1I trt Mortcno* othia motic rtvi (OoiniMr Xubber suit or lab cot* l'w . . . iw- * Cogg.lea 1 v?*-* ^tecTfciTa ``s&^bsuurKKt' ^^c*v,T^.;oM.,W.4>.^at.N6.>.o.o...4roteee phytleal | * C^vrTr./.V-^ lilci-J Store tV a jj t^coot, veil ventilated place, separate from all oxidizing agents* i ornia *mc*utioss &mm PKAr>ti-A] SrV-^Q(>CA) zizzznizz A- LAM 026524 WRC 210-80 ABS-05665 T l' 28 SHELL OIL COMPANY SHELL CHEMICAL COMPANY SMELL DEVELOPMENT COMPANY SHELL PIPE LINE CORPORATION MATERIAL SAFETY DATA SHEET MSDS 313,740-78 !* |*T * ,* UM * IIIIWIMW t1 M Kf ,l * l>| lim.ll rM<1 <M **M HVM f# f ! K'MM # # * SECTION 1 011a Corporation 1 lvCH((t T(v(.oe| | 1 (203) 777-7911, Ext. IU30 orl781 `''"`SeseaxclnfeaterT'Vf*? tyfncfester Avenue, New Haven, CT 0650b tM| H| *** hydxo'ftuoric acid ro*ww* SECTION II HAZARDOUS INGREOIENTS * THIS PRODUCT IS A PURCHASED MATERIAL. SEE ATTACHED MATERIAL SAFETY DATA SHEET FROM THE MANUFACTURER. OiimS 9if 1 ft (mN|| OKrr Ml tiT|l SECTION lit PHYSICAL DATA 1*CC*>C ClAViTT iM^aH I HIC'taf VOLATaC ! vociiMf <-.i i 1t to* ***( Ml* 1 ____________ 1_________________________________________________ SECTION IV FIRE AND EXPLOSION HAZARD DATA l|*M ** (MsiM mNI Mill* tLS 7u pT M**W lr Ml| 0*1 Cm WRC 210-80 LAM 026525 ABS-056656 WRC 29 CMfiim USCAKCH CENTEX m WINCHESTER AVENUE. NEW HAVEN. CONNECTICUT 0SS04 Telephone: (203):777-7511, Extensions 11x30, 1731i MATERIAL SAFETY DATA SHEET SECTION II KftESCftVATfVtS. 1 SOLVENTS ft HAZARDOUS INGREDIENTS TLV ALLOYS AMO METALLIC COATWCS trju*rs IASI UITAL ATAiTST Aitovs VtMILlI SOl*t*TS Aoomvis OtHCHJ UITAVUC COATINGS HUI* MITAl FU'SCOaTIMO 0tsA* fill* OTHfAS H&ZAJtOOOS MIXTUKSS 0* OTHER LtOUIOS, SOMOl, OK GASES ft TLV (VeiUl ft TLV SECTION 111 PHYSICAL DATA - loaiNC roiNT *;j 19.AC SafCIEH. C.aVITV IN,0=11 VA^oartiuuM >--x^ 400 nn Hg at 2.5C VAAOS OiNSITT lAllt II N.A. lOtw.ir, IN wall* complete MVAVCOIMtUTMV<OOTltf tVAOft*TtO 1 . 1 -I:- liquid <^taANctv..ooim colorless, fuming liquid ............ 1i 1 -11 1 .................... SECTION IV - FIRE AND EXPLOSION HAZARD DATA fUlH ,OIHI aaMMI N.A HAUVASIk UMll> . *. tl '*" C02, foam, water WlML TM( NiOClOUAII W.. A. 0.98 N.A. N.A. ? * Vtl _u_x_v_u__wi fill MO IIHOfKM VW HuPn attack. s g,lass or st.oneware in ptascic, wax, paramn or lea a containers. Store only LAM 026526 wrc 210-80 ABS-056657 30 lMatSMOiO HMII v*n. 2 pp-n SECTION V HEALTH HAZARD DATA uncioi ovirnow Vapors and liquid are corrosive to tissues. Chronic exposure may cause fluorosis. iifv t*oriuctoui($ xi spilled on SKin or In eyes, flush with flowing water for 15 oln. Ingestion - give magnesia, chalk, milk or egg white. DO MOT INDUCE VOHITII.'C. Inhalation - remove to fresh air. For all above, see a physician ir-.edlHoly.---------------------------------------------- SECTION VI REACTIVITY DATA UNS1AKI STAtll t tViOtU0:4$ TO 4V00 X * tNCOM'ArASHirv oxidl sing materials r vA A, ',h o <. majaauch** orroMosmm *oo*jcts toxic fumes of fluorides HA/AKO^US r<hV Vl/AliOl WAT OCCVJ* WILL NOT occu CONDITIONS TO AvOlO X - IM>TON I-.,- t.Ji SECTION VII SPILL OR LEAK PROCEDURES I>*itiiMf o-Wearing protective equipment, slowly neutralize with alkalies and/or flood area with copious quantities of water.______________________________________________________________________ *sri r>.\aoji^ i-itwoo Neutralize with alkalies - bury in sanitary land-fill. ~ SECTION VIII SPECIAL PROTECTION INTGR.Y.ATtOfJ HVi*a'e3eemr'i'aHl*dter o f soda lime and activated carbon. VfNrilATIO* LOCAL f&HAUSt ^ STICIAL OTH( noucTiv& clovis neoprene 1 l^oggj.ce,3,*(splesh shields) aar*'s suits m areas of larre soills. Aorons (neoarenel SECTION IX SPECIAL PRECAUTIONS rlt Auliorck IO M UMN m mamouhG ano womw. Store In cool, dry, well ventilated place. OlM|j PiiCAUfiOM Information furnished byt Dr. John H. Wedlg Title: Toxicologist Company: Olin Corporation Address: 275 Winchester Avenue, New Haven, Connecticut 'Date:. 2/9/72 oS5c'd l_AM 026527 WRC 210-80 ABS-056658 WRC 31 ao<iMar>t f** -n 1111 SHELL OIL COMPANY SHELL CHEMICAL COMPANY SHELL DEVELOPMENT COMPANY SHELL PIPE LINE CORPORATION MATERIAL SAFETY DATA SHEET C ifcO Ratihg InloimtiiM #n 1M1 fwm la Lmlihia uMl laf tho arrpaia of toaalinKfolm PfOmpitiaail Safaty too HoallP Act o11970 tup utct nft' So triad Iff Iff trwf ayaau. UM O' alaiMilaffM of aM or any part of pit information for any otfiar pyrpoao may raw1! In a aloration of lam orcom r atlfyta iravaat for lafat Milan SECTION 1 MAV*ACt\|AC** MAMS Shell Chemical Cornrtnv Srw9t, Ci*r S*9f*0 W ZIP.Ca/*) One Shell Piets. P. 0. So* 2ko3. CnEM.OL *>AMS.AMa S^JaPMS Ethyl AlcoKOl/Sthsaol Houston. Texes 77001 IWtlCthCV tClC'0"C *. 713-h73-9U6l 1AD& HAMf Alcohol | CH^CHgOH PiCMSNTS COMPOSITION catalyst VEHICLE SOLVENTS AOOiTiVCJ otmeas SECTION II HAZARDOUS INGREDIENTS* \ species 0*l LO 100 Ret Ret 13.6 gn/kg LCjj *ecr.*fio I20.000 23.000 ??V. >0 SECTION III PHYSICAL DATA IOIUN8 POINT (.yj 172 SPECIFIC CNAVlTY VAPOR Mlllfll imoHj) VAPOR OCnSITT Nltoll SOLUBILITY IN VATCN APPXARntaCC to9 3=34 g ggop Colorless, tohlle At 1.6 200S liquid, <-,peacent volatile BY VOLUME EVAPORATION NATE <-J3UAC------ pleasant o3or 0.70 0 1.6 Mad-f.ad Ay Shaft Off Company WRC 210-80 LAM 026528 ABS-056659 32 tctiit '< j'lnumx Anesthesia, causes, headaches, end dltainess. Mar cause sor.e dehydration of the skin. r.tsr 4.a >eg><u Rccore vtctia to fresh air, give artificial respiration If breathing has stopped. STABILITY VfirtKi T*lvC A2>a:cu o<C*4^oat o mcowCTs SECTION VI REACTIVITY DATA C49.7l0l T0 ATCIO , . Sharks end octn fleze. X strong oxidiring egant* haxamcous ^OUYMC^lZATlOH way occuji viu o* oceui COROiftO*) T9 IVQi X s:<?i to ic taxci i* Ciit SECTION VII SPILL OR LEAK PHOCEDUP.ES is iiLima o i;iu!3 flush vlth water, avoid contact vjth soarks cr open flcce. iir[ a*ssi4L Mtr,9s flush vlth vater or controlled burning. Do not flush Into a confined SECTION VIII SPECIAL PROTECTION INFORMATION afif>T:T *7?*i *n*rV nr nT-r-fr VE*7lUATtO* LOCAL tSMMItf r^rtcriet cs,ot _ . . Rubber tmca AKortcrivf (NifMcrn ^ Desirable As required to calntain TLV. IfCCML or*** . 1 erf aosTKTiea 1 Goccles ett T9 If Ti<h la SECTION IX SPECIAL PRECAUTIONS Ml ivoU #1 - r.~ r"i-- attack alualnun at elevated tengerature. Handle as flemeble liculd. 0. M. Sheets Shell Chesleal, Ccr.^&nv nc.irjc &WZ,gr .?t October 1971_____________ r.sa ..> ie*<*t* (!. * t t* -r* i:t* i i* ill : <*a ale| *nM>ti4iimiM*nitTtlirf on(**.tlil%(si.rI**v.>* ?r**a| a*r.fa*oIfti**(s!am>*'.*($*I*i*:la*<.: a.if, !%* m^Mlt All^afilA-TT >l l*f t *M*U f! s i*ah Mtiwtrr.i * ? r ti * T4***l (1 if aOMstKI atT* f)CI*ll C fHMl^ * W|, LAM 026529 WRC 210-80 ABS-056660 wrc : 33 RATING Shell Material Safety Data Sheet ft'U'M.J |9*79) Information w* tfiH form fty for the pwrpOM of complimi with tHa Occupational Safety and Haaflh Act of <970 Kid th|N not be vied for any otHor purpoaa. Um or dtuominotion of atl or any port of (hit information for any othK purpoaa may rttdl in a violation of taw or eon* itituta o^oundi lor toga* action. SECTION 1 MANUFACTURER'S NAME Eastman Kodak ADORES* INUMfttn. STRICT, CITY, STATE, AND ZIP COOC) EMERGENCY TELEPHONE NO. CHEMICAL NAMK AND SYNONYMS CHEMICAL FAMILY TRAQC NAME ... 1 *iO-phenanthronne MANUFACTURER'S DATE OF ISSUE: 10/9/73 SECTION II INGREOIENTS co5# LC*> ORAL I OCRMAL CONCENTRATION HOURS 11 THIS PRODUCT IS A PURCHASED MATERIAL. SEE ATTACHED MATERIAL SAFETY DATA SHEET FROM THE MANUFACTURER. / / i SECTION III OILING POINT <*r> VAPOR PRESSURE (nmhtt VAPOR OCNSITY (AIR k) SOLUOILITY IN WATER appearance AND OOOA PHYSICAL DATA SPECIFIC GRAVITY (HyO )| PERCENT VOLATILE Y VOLUME (*) EVAPORATION RATE 1 II SECTION IV FLASH POINT (METmOO USCOI FIRE AND EXPLOSION HAZARD DATA FLAMMASLC LIMITS EXTINGUISHING MtOIA special fire fighting procedures unusual n*e ano explosion hazards LEL UCL WRC 210-80 026530 ABS-056661 34 * 903289 EASTMAN KODAK L.OMKAW APPROVED BY U.S. DEPARTMENT OF LABOR "ESSENTIALLY SIMILAR" TO FORM OSHA-20 MATERIAL SAFETY DATA SHEET SECTION I PRODUCT NAME: chemical namEi 1,10-Phenanthroline FORMULA. CH:CHCH:NC;CCH:CHC:fel:CHCH;CH- HpO S***1 1 g. and 5 e- manufacturer. Eastman Kodak Company ADDRESS. -3U3' State Street Rochester, New York IU65O FOR INFORMATION ON HEALTH HAZARDS CALL. (716) U58-1000 ext. 65556 FOR OTHER INFORMATION CALL, ^72277 | INFORMATION EFFECTIVE AS OF: October 9, 1973 SECTION II HAZARDOUS INGREDIENTS OF MIXTURES PRINCIPAL HAZARDOUS COMPONENT (S) % TLV (Units) * is R V SECTION III PHYSICAL DATA BOILING POINT PFJ VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR-1) SOLUBILITY IN WATER SPECIFIC GRAVITY (H,0-l) PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE (. .... -T) soluble in about 300 parts water appearance ano ODOR white crystalline powder SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (M*nd *4) FLAMMABLE LIMITS extinguishing MEDIA ------------------------------ SPECIAL FIRE FIGHTING PROCEDURES CO , dry chemical 9' *____________ UNUSUAL FIRE AND EXPLOSION HAZARDS 1*1 WRC 210-80 R! JS VI PR "o' EO PRI IN U*l OTI lam 026531 ABS-056662 WRC 35 SECTION V HEALTH HAZARD DATA THRESHOLD LIMIT VALUE None assigned by A.C.G. I.H. EFFECTS OF OVEREXPOSURE Appears to be of low hazard to health. emergency and first aid PROCEDURES None appear Indicated. SECTION VI REACTIVITY DATA stability INCOMPATIBILITY (Moterioh to ow'd) UNSTABLE STABLE X CONDITIONS TO AVOID HAZARDOUS DECOMPOSITION PROOUCTS toxic fumes HAZARDOUS POLYMERIZATION Moy Occur Will Not Occur X CONDITIONS TO AVOID SECTION VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of Ignition. Nearing suitable protective clothing, sweep material onto paper. Place in fiber carton. Incinerate. Wash spill area veil with soap and water. WASTE DISPOSAL METHOD Make up small packages in paper or other flaraiable raterial. Bum In incinerator. State and local lavs take precedence. SECTION VIII SPECIAL PROTECTION INFORFAATION RESPIRATORY PROTECTION (Spicily typt) VENTILATION LOCAL EXHAUST MECHANICAL (gfffurrol) PROTECTIVE GLOVES rubber OTHER PROTECTIVE EQUIPMENT X SPECIAL OTHER EYE PROTECTION safety goggles PRECAUTIONS TO BE TAKEN IN HANDING AND STORING SECTION IX SPECIAL PRECAUTIONS OTHER PRECAUTIONS tP* iDiti WRC 210-80 LAM 026532 ABS-056663 s 36 SMELL OIL COMPANY SHELL CHEMICAL COMPANY Smell development company 13 DS NO. 30221-78 SHILL PIPS LINE CORPORATION 3<>t, 2/0 MATERIAL SAFETY DATA SHEET mazaro RaTIhC KF?A t*fft**>#ftft * ** H* IN * **** wM MI Sllf u1Ig ff, ^ ft* Ul ft# <iWiMI#R ftf ft* ft# |Af ft#1 ftf |A>| fft# *y fttftft* K.h.11 *# *#* MftM. Nl ft* tv TO " iil p( ft# **wN m* ft *ft*fttftft ft# l* **<* SECTION 1 Union Carbide ioniiwP>k#. C**r. 270 Pari Avenue* nev Zf* York. Sfew York 10017 iiw( mV |vvvm| (ImiCH | 3oU-fiiA-3l;87 1 10( M( [ Aetlc Acid*. Clidal________ SECTION II HAZARDOUS INGREDIENTS* THIS PRODUCT IS A PURCHASED MATERIAL. SEE ATTACHED MATERIAL SAFETY DATA SHEET FROM THE MANUFACTURER. I I A IOilnC P&ml 1 #1 v**e Ht> VA9M 9KtfYT (ftiftarll SOCWVik'^V ft * T t A##t4*cc <-o e:s SECTION III PHYSICAL DATA MIClFlC 6MAVITT IMjOwtl MCImT vOkAVilC VOlUMf I'.l Cvm^OAATioh matc 1 all SECTION IV FIRE AND EXPLOSION HAZARD DATA K*m sft*i |MmM **Ni ri*gyft( !#*! ItliRMilMaft Mtfti* iMim '*( ti(#rwi meiMMi *t Mi umiio# Minn MW./.W ft, 1**4/ ai Cm~0*~T k# INI LAM 026533 f Is FI E. M S? PP WRC 210-80 ABS-056664 WRC 37 miEflJjJL SAfreiry \ii\U\ U.S. Owifimw! Libor **Ct*nt>oHy Slmtlir'* 10 Form L$l-OOS4) PRODUCT NAME: ACETIC ACID. GLACIAL CHEMICAL NAME: Acetie Add FORMULA: CH,COOH SYNONYMS: Ethanoic Add; Methane Carboxylic Add CHEMICAL FAMILY: Adds MOLECULAR WEIGHT: 60.05 BOILING POINT, 760 mm. Hg SPECIFIC GRAVITY (H,0 - 1) VAPOR DENSITY (air - 1) PER CENT VOLATILES BY VOLUME APPEARANCE ANO ODOR 117.9*C. (244.2*FJ 1.0512 at 20/20 *C 2.1 100 Water-white liquid; sharp odor. FREEZING POINT VAPOR PRESSURE AT 20*C. SOLUBILITY IN WATER. % by wt. EVAPORATION RATE (Butyl Acetate* 1) - ^ - e^tj^--e. W. W ^ 41,_W A H-WJWf V I. |w* MATERIAL Acetic Acid (See Sections III through VIII) -100 16.7 *C. 11 mm. Hg Complete 0.97 TLV (Unitsl 10 ppm.. gi..iia,3j'V .. J JLL^uyjwJL--ITJJJi:':>Tr.ir^'W.. * i FLASH POINT (test mathod!s)J 106 *F. Tag closed cup ASTM 0 55 FLAMMABLE LIMITS IN AIR, * by volume LOWER 5.4 EXTINGUISHING MEDIA. Us* carbon dioxide or dry chemical for small fires. Use alcohol foam or water spray for large fires. \ '..'.'JV/M UPPER 16.0 SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE ANO EXPLOSION HAZARDS Fire fighting personnel should be cautious of irritating vapors that may be evolved from an acetic acid fire. Personnel should be protected by self-contained breathing apparatus ar.d complete protective clothing li needed. Non* 304/744-3487 THty oymbif r* *v*loN# d*vt. nr^hi*. tw**k#di. and hoftdjv*. *r*4* umoo Ciiwi Ca>aaraMw iHnw ** r cm emUAol **** aro laciu4 *r* e* oa-Mo^o *iytu*o >0 ow 0/ ..*'* oeorn kri r*o ww ciRawiw. N --a whhin o piwvir o nyimaw *o> co C w Co*j rttsor;w Tr.t r# *w mn !t>r Kti :rpv;d,i<i.'R. oma^tiQR *+ 11 n urn orn Any woo an# na ih A'ymw am v* chowk >y r0 wr taww ietort>mi. ;io`r 'tir-M. Sau UNION CARBIDE CORPORATION . CHEMICALS AND PLASTICS 270 PARK AVENUE. NEW YORK. N.Y. 10017 wrc 210-80 LAM 026534 ABS-056665 r 38 i ,-s THRESHOLD LIMIT VALUE EFFECTS OF OVEREXPOSURE 10 ppm. ACGIH (1977) OSHA CFR 29 1 1000 Table G1 Contact with skin and y causal burns. Breathing of vapors cauias coughing. chest pain, and irritation of nose and throat. May cause nausea and vomiting. ^ ( EMERGENCY AND FIRST AID PROCEDURES Immediately flush skin and eye contact with plenty of water for at least 15 minutes. Get medical care for eyes. If inhaled, remove to fresh air. Give oxygen if breathing is . difficult. Call a physician. , STABILITY UNSTABLE STABLE --V CONDITIONS TO AVOID None INCOMPATIBILITY (materials to avoid) Avoid contamination with alkalies, amines, and nitric acid. HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION May Occur Will not Occur -- V Burning can product carbon monoxide tnd/or carbon dioxide. CONDITIONS TO AVOID None f ' STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED' WASTE DISPOSAL METHOD Wear suitable protective equipment. Collect for disposal. See Section VIII. Toxic to fishl Avoid discharge to natural waters. Incinerate fat a furnace vdtere permitted under appropriate Federal. State, end local regulations. Some supplementary foet may be required for burning. WRC 210-80 LAM 026535 WRC ABS-056666 39 respiratory PROTECTION (specify typel Frtsh-eir mask in confined areas VENTILATION LOCAL EXHAUST MECHANICAL (general) Preferable May not be sufficient SPECIAL OTHER PROTECTIVE GLOVES OTHER PROTECTIVE EQUIPMENT Rubber gloves PROTECTION Full face mask. Impervious apron, eye bath, and safety shower ___ Vapor-proof goggles PRECAUTIONARY LABELING ACETIC ACID, GLACIAL OANGERI CAUSES BURNS HARMFUL IF INHALED COMBUSTIBLE Do not get In eyes, on skin, on dothing. Avoid breathing vapor. Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Wash thoroughly after handing. FIRST AID: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash dothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. FOR INDUSTRY USE ONLY OTHER HANDLING ANO STORAGE CONDITIONS Waste streams containing acetic add coutd be diluted and neutralized with caustic. The neutralized solutions containing sodium acetate salt should be amenable to biological degradation. Aqueous solutions containing 500 ppm. of sodium acetate have been degraded in aedimated laboratory bioiogieal systems. WRC 210-80 LAM 026536 ABS-056667 r*o# fO+M k) IIXC1 * *>ULt OIL COs?AHY SXSLL CHZNICAL COXFAHT SHZLL t>*V5L0>*JXT COMVAHT K5D8 KO. 30052-78 SXZLL tt?Z LIXE COKZOZATIOM o OoaJ5* MA2AX3 ft AT I* S MATERIAL SAFETY DATA SHEET K??A ' Int^<r4l>f f* A4 I#.-- I* I***. *3* * *'* c' (--'P'.t'KI ->t>* IN Oil vfrll-*>< Slfm iN ll*H|li All * l*> 1*1 **' nl N L , - f ||f #T t;|f |||NI Vw I* Awi*|l|H* l*| N*l ' U*| Mln/NklR l|l I* f IM* Iv'fIM INI rM> *** 13-- *(** IMa |/*v*A f* IISX A<'*^ ' SECTION 1 ` Olio Chsnicals h>W^'K!#*. C9r. J'***. 2t* Cft^i 120 Lons fcidse Bo-d- St-ford. Connecticut OoOnli (2m:*; *A*f M> |ftftTi> 1 I 203-777-7Q11 * *Of kN( Buifur ic Acid >. SECTION II HAZARDOUS INGREDIENTS* THIS PRODUCT IS A PURCHASED MATERIAL. SEE ATTACHED MATERIAL SAFETY DATA SHEET FROM THE MANUFACTURER. IO*ilMC 9tftT | ft VA9* hpM|| VSPO* OfftSiVf iSIOati MkWlUYT IM **? SECTION III PHTSICAL DATA Specific CHAVITV IN^Oail IMCC*T VOWATU l VOVMMI IM |V9Q^STlOl *tf Nil 9t* F#*at 4 SECTION IV FIRE AND EXPLOSION HAZARD DATA **** *< MliH #*C r*9<IN*n )> m1a)|i WRC 210-80 LAM 026537 ABS-056668 41 c section i * >TrtO-R" VIL1 fr-C 1 Ar<f wi . ro*^w* .. >so, [ A3) ui V*i., Ad **' U*l in ui i^r *-4 k-fw. | tB*aa m \Ht SECTION 11 HAZARDOUS INGREDIENTS 0 nv K mm fc&uAL nr*" 17 11 HW* | iMiicintv riamwMi COMro^tnt % lb* no>twi>Mnauo* or*iA uo**.Jou9-o t**i coicti Mrm o*Mki(it4U|*r^n SECTION III PHYSICAL DATA HKTX ^**1 \mf} *OA-Cr9***r (*rj virotmuvif t--J Q 20C 1 r*iKvotutvvMoi iuimt.u.nk, nown 550 ooi-rtrK*ij.ii Unknown lnrM4Tiot*u 1 *1 kicpx c**wn OD LA P* Coaolete 6fN(l trrlilAKi oA OM* Colorless to cloudv liouid and no odor. f SECTION |V fIR* AND EXPLOSION HAZARD DATA I fUMAIHI IIMT) T=*=F \ ^C^Tt<10Ci9w0 Coci tank with vater if exposed to fire. bHUUM mi a>d uneven niu5i 'Explosive coaiir.tr>>- 'nn of hydrogen oa* f.-m p.r rnovtar g naf-pT >nV confaVp- ina acid. 1 gg/a-> JECTlOH V health haiatd data iMiaiwoii!>iM Rapid destruction qt tissue on.contp.ct, severe burns, corrosive to siu.n, eyes ana nucous peaSranes. Respiratory irritant. lM<Taj9^4>7AlONeC19wU .. t*y Flush with tloving water at least 15 ednutes. . .. , ,. . . Call a physician imeqlately* ** Flush with flovir.g vater at least 15 eimites. Call a tihvsician icniediatelv, r,ft out"ooutn wicn water and give plenty ot water to orinit 1 ollovtc ny wilk of r-aar.esla:DO SOT INDUCE veaitir.r/ Call a Physician.___________________ *.''*ura*' Reaove to fresh air. Call a physician !OtO'.6Cf minmuw 2140 pg/ktt CH.SO.) irt iniurm Causes severe burns um mini laurrf UWAir sum mimTW^ Corrosive AM M<MUnon TOUITt (*0>18ini CHEMICALS Ot*A Corporation, 120 Ion; fedge Xo*d. Stamford. Connecticut 06904 WRC 210-80 LAM 026538 ABS-056669 42 JTAVITT UHITAJAI TAlt SECTION VI REACTIVITY DATA COnOsYtOn) to AVIOO " X Violent reaction If water spills In acid r.sta^vn _________ hA1A bOVS PKOXMlIIIOn MOMCU iloce N^OAilTAXtOllOttAJlTlOn *IUMTOCCti< COffOlTJOtS TO AVOIO ^ SCCTIOH VII SPILL OR LEAK PROCEDURES jttM tom rAKiTHncuittAmuk itiusoonyiuio Keep people frog area and flush are* vltH a plentiful quantity of water of actd. can be nautraliied vlch line or soda ash. traces wiWI 3'J>0V.lTOO Neutralize with soda ash or line and dispose of in accordance with local, state and federal regulations. SECTION VIII SPECIAL PROTECTION INFORMATION iu'iiaioi mo.-tCTKX UriA nl Self-contained breathing apparatus foxvgen) or cannlster tvoe gas mask. iocai. uhauit Adequate co keep TLV in VIMM.ATIOH SAfflAn V AT"!. IfftphaMt Faa^tnsLde^tuildlns ..it.iL. iti::iIcu>u Gauntlet type rubber or plasticor-;> >AeiiCTi*i iowmim Rubber apron. h*t~. lore 1 mv l<rr ivt rr.o;ccTu> Chemical safety cop.ales and face shield. nr-d Knff; or re-->1pfe safety siilr SECTION IX SPECIAL PRECAUTIONS >asc*v rio^i to ec taxi* i* **>oo*c ajo stos**c Do not add water to sulfuric acid storage tank as large aiaount of heat will be produced. ofp-ta ?fCAur:o*> Do not pet In eves, on skin. on clothing. Tn case of contact. itcfdlnrely fluah vtth plantv of -?**" for IS i.lni-.r and tr r^dlnal aTentfon SECTIONX REMARKS ia>aai>ca namwit in OiyAt>ni rf EmlrwMiiial Ki^m ini TniiJilnfr (20J) 777-7*11 [nl 1JS4.4H, 14)0] Steven J. Barbee, Ph.D. Toxicologist CMllHil CHEMICALS OIn Co'^o/siiOA| Kid| Road, Sumford, Connecticut C69C4 WRC 210-R0 at.: 5/16/77 t Printed " U.5 A. LAM 026539 ABS-056670