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Sa/techinc. MATERIAL SAFETY DATA SHEET SECTION 1 - Identification 1 Date February, 1980 Product Name SAYTEX BT-93"" Chemical Name Ethylene - bis - tetrabromophthalimide Chemical FamilyBrominated aromatic Manufacturer's Name Say tech, Inc. Manufacturer's Address 879 Main Street Sayreville, NJ 08872 ^~^ Telephone Number (201) 721-2100________ SECTION 2 Hazard Rating Hazard Classification: HealthFlammability2Reactivity Composition: Component N/A_____________________ Concentration N/A ^ Criterion and Value NM SECTION 3 - Physical Properties Appearance and Odor white to light yellow powder Boiling Point (*F) N/A Specific Gravity (Water=1) 2.67 Solubility in Water nil Vapor Pressure (mm Hg) N/A Vapor Density (Air =1) ^/A Evaporation Rate ( =1) N/A Reacts if Exposed to: Light no Air no Heat >400 C Water no Strong Oxidizer yes SECTION 4 - Fire or Explosion Data Vlash Point ('F) Autoignition Temperature ("F) Extinguishing Media water or fog spray N/A LEL (%) N/A uel (%) N/A Special Firefighting Procedure Hydrogen bromide and other toxic gases may be liberated at elevated temperatures, self contained breathing apparatus may be necessary. Unusual Fire or Explosion Protection none known SECTION 5 - Health Data TLV not establishedCriterion Effects of Overexposure Dust may cause transient eye irritation. Full effects not known. Emergency and First Aid Procedures Inqestionlf large amounts are ingested, induce vomiting and get medical attention. No known antidote. Inhalation Remove person to fresh air. Skin Wash with warm water and mild soap. Contaminated clothing should be laundered before reused. Eye Flush with large amounts of water for at least 15 min.. get medical attention. Irritant: Skin not a primary irri- Eye not an irritantInhalation not determined tant Other Data DLDsn = >2.0 gm/kg; OLD5Q = >7.5 gm/kg. APPROVED AS ESSENTIALLY SIMILAR TO O 5 H A FORM 20 (PREVIOUSLY L5B-00S-4)** DO 086726 CONFTDFNTTAl, SECTION 6 Reacitivity Stable xUnstable Conditions to Avoid temperatures >400eC Incompatibility strong oxidizers Hazardous Decompositon Products Hydrogen bromide Hazardous Polymerization: No X YesConditions to Avoid Corrosive: No X Yes_______ Materials SECTION 7 Spills and Leaks Steps to be Taken in Case Material is Released or Spilled Sweep or shovel sn-m Into su-li-ahlp container for disposal or reclaiming. Wash down area. Do not allow gontam-fnat-pH liquid to enter waterways or sewers. Waste Disposal Precautions Dispose of in accordance with Federal, State and local regulations. If incinerated, system must be equipped with a scrubber designed to effectively handle corrosive off-gases. SECTION 8 - Special Protection Respirators: Ventilation: No Yes X Type 3M #8710 recommended Use the guidelines recommended by the American Conference of Governmental Industrial Hygienists in the current edition of "Industrial Ventilation", considering the TLV, Lower Explosive (Flammable) Limit and conditions under which this product is used. Gloves recommended _______________________Other clean, body covering clothing Lye Protection recommended _____________________________________________ SECTION 9 - Special Precautions Handling and Storage Store in a dry area away from eatables. Practice reasonable care to avoid excessive skin and eye contact. Avoid breathing dust if generated. DOT Hazard Label Required: No x Yes Specify Other Precautions Avoid contamination of food. Perforate or crush containers before disposal* 'APPROVED A$ ESSENTIALLY SIMILAR TO OSH A FORM 20 (PREVIOUSLY L S B QOS - 4) CAS Reg. IMo._ 32588-76-4 LaVerne J. Makfinsky Prepared By DO 086727 CONFIDENTIAL Ethyl Chemicals Group MATERIAL SAFETY DATA SHEET Emergency Phone 504-344-7147 99.0.16 PRODUCT IDENTIFICATION TRADE NAME: ^ayte^ 120 Flame Retardant CHEMICAL NAME: CHEMICAL FAMILY: CHEMICAL FORMULA: CAS NO.: Tetradecabromodiphenoxy Benz Complex Polybrominated Aromatic Compound c18Br142 58965-66-5 THIS MATERIAL IS IN COMPLIANCE WITH THE TOXIC SUBSTANCES CONTROL ACT (15 USC 2601 - 2629). CHEMICAL AND PHYSICAL PROPERTIES APPEARANCE/ODOR: VAPOR PRESSURE: SOLUBILITY IN WATER: PERCENT VOLATILES: White powder/no odor. Less than 0.1 mm Hg (at 25C/77F). Insoluble. Less than 0.1% (at 25C/ 77F). FIRE AND EXPLOSION HAZARDS FLASH POINT (METHOD): Solid - Not applicable. FLAMMABLE LIMITS: Not applicable. EXTINGUISHING MEDIA: Dry chemical# water spray (fog), foam or carbon dioxide. HAZARDOUS THERMAL DECOMPOSITION PRODUCTS: Include hydrogen bromide and oxides of carbon. SPECIAL FIRE FIGHTING PROCEDURES; High temperatures may liberate toxic gases. Do not breathe smoke or vapors. 12/18/85 Continued Ethyl Corporation - Chemicals Group Ethyl Tower 451 Florida Blvd., Baton R uge, LA 70801 REPRESENTING ETHYL FOREIGN SALES CORPORATION FOR EXPORT SALES DO 086728 CONFIDENTIAL 4.. <. Page 2 of 3 TRADE NAMEl Saytex 120 UNUSUAL FIRE AND EXPLOSION HAZARDS: None. REACTIVITY DATA STABILITY: Is stable. CONDITIONS TO AVOID: Temperatures in excess of 350C/662F. MATERIALS TO AVOID: Strong oxidizing agents. HAZARDOUS POLYMERIZATION Will not occur. HEALTH HAZARDS CHRONIC EFFECTS OF OVEREXPOSURE: None known. TOXICITY DATA: ORAL LD50 (rat) = > 5000 mg/kg. DERMAL LD50 (rabbit) = > 2000 mg/kg. EMERGENCY FIRST AID PROCEDURES INHALATION: EYE CONTACT: SKIN CONTACT INGESTION: Remove to fresh air. Begin immediate eye irriga tion with cool water. Wash contaminated area with soap and water. Give two glasses of water. EXPOSURE CONTROL INFORMATION EXPOSURE LIMITS: EYE PROTECTION: PROTECTIVE GLOVES: Not established by OSHA/ACG1H Chemical safety goggles or equivalent eye protection. Resistant to chemical penetration. DO 0867W ccnfidentia' 12/18/85 Continued  Page 3 of '3 TRADE NAME* Savtex 120 RESPIRATORY PROTECTION: NIOSH approved dust respirator. LOCAL VENTILATION: At source of visible dusting. MECHANICAL VENTILATION: Recommended. OTHER: If repeated or prolonged skin contact or contamination of clothing is likely, protec tive clothing should be worn. SPILLS OR LEAKS: ENVIRONMENTAL PROTECTION DISPOSAL METHODS: STORAGE REQUIREMENT: Shovel into container. Retain until receive instructions from Ethyl Corp. represen tative. DO NOT DISPOSE OF MATERIAL. Contact Ethyl Corp. represen tative at 1-800-526-3658 for disposal instructions. None. REVISED: 12/18/85 SUPERCEDES: 08/08/85 T&IH File Code: 02334-HB-2 MSDS prepared by: Toxicology and Industrial Hygiene Department Ethyl Corporation FOR ADDITIONAL NONEMERGENCY MSDS INFORMATION, CONTACT: ETHYL CORPORATION TOXICOLOGY AND INDUSTRIAL HYGIENE DEPARTMENT 451 FLORIDA ST. BATON ROUGE, LA 70801 (504) 388-7717 THIS MATERIAL SAFETY DATA SHEET CONTAINS AT LEAST THE INFORMATION REQUIRED BY THE FEDERAL OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200(g)(2). 0023M 8673o CONfrTOBNTTAi Sa/tech Inc. MATERIAL SAFETY DATA SHEET pate January, 1980 SECTION 1 - Identification Product H,TM Chemical Name Decabromodiphenyl oxide Manufacturer's Name Manufacturer's Address Chemical Family halogenated phenyl etherTelephone Number(201; 7Z1-Z10Q- SAYTECH, IHC. 879 Main Street Sayreville, NJ 08872 SECTION 2 - Hazard Rating 2Hazard Classification: Health1 Flammability Reactivity V Composition: Component Concentration None M/A Criterion and Value N/A SECTION 3 - Physical Properties Appearance and Odor Creamy white Pwder> chemical odor____________________________ Boiling Point (*F) Specific Gravity (Waters'!) 3.0 Solubility in Water ppb Vapor Pressure (mm Hg)Vapor Density (Air=1) Evaporation Rate (= 1) Reacts if Exposed to: Light No Air No Heat >300"C Water No Strong Oxidizer yes SECTION 4 - Fire or Explosion Data Flash Point (*F) ~ Autoignition Temperature (*F) N/A LEL (%) N/A (JEL (%) N/A Extinguishing Media water or fog spray_____________________________________________________ Special Firefighting Procedure High temperatures may liberate toxic gases; self-contained breathing apparatus may be necessary._________________________________ ____________ _____________ Unusual Fire or Explosion Protection ____________________________________________________________ SECTION 5 - Health Data TLV not established Criterion _______________________________ Effecfs of Overexposure Dust may cause transient eye or skin irritation.' effects not know. Full' Emergency and First Aid Procedures Inqestion If large amounts are ingested, attention._____ _______ ____ Inhalation Remove person to fresh air. induce vomiting and get medical Get medical attention.__________________ Skin Wash with warm water and mild soap. Remove contaminated clothing and wash before reuse. Eve Flush with large amounts of water. Get medical attention._________________ Irritant: Skin slight response Eye transient irritant Inhalation not determined Other Data OLD^n = >2000 mg/kg.______________________________________________________ _____ __ APPROVED AS ESSENTIALLY SIMILAR rO OSHA FORM 2C (PREVIOUSLY L 5 6 - 0? 9 41" DO 086731 CONFIDENT! Al SECTION 6 - Reactivity Stable X Unstable Conditions to Avoid temperatures > 300 C Incompatibility strong oxidizing agents___ Hazardous Decompositon Products Hydrogen bromide, bromine r Hazardous Polymerization: No X YesConditions to Avoid Corrosive: No X Yes_______ Materials SECTION 7 - Spills and Leaks Steps to be Taken in Case Material is Released or Spilled Streep or shovel into containers for reclaiming or disposal. Do not allow material to enter waterways. Waste Disposal Precautions Dispose of in accordance with Federal, State and local regulations. If incinerated, system must be equipped with a scrubber designed to effectively handle corrosive off gases.___________________________________________ __________ SECTION 8 - Special Protection Respirators: Ventilation: No Yes X Type 3M #8710 recommended Use the guidelines recommended by the American Conference of Governmental Industrial Hygienists in the current edition of "Industrial Ventilation", considering the TLV, Lower Explosive (Flammable) Limit and conditions under which this product is used. Gloves rubberOther clean, body covering clothing Eye Protection safety glasses w/slde shields ____________________________________ _______ _ SECTION 9 - Special Precautions Handling and Storage Store in a dry area. Practice reasonable care to avoid skin and eye contact. Avoid breathing dust if generated. DOT -Hazard Label Reauired: No X Yes Soecifv Other-Precautions Avoid contamination of food . Perforate or crush containers before disposal. "APPROVED AS ESSENTIALLY SIMILAR TO OSH A. FORM 20 /PREVIOUSLY L SB-30S-4)" CAS Reg. Nn. 1163-19-5 LaVeme J. Makf insky Prepared By DO 086732 CONFIDENTIAL. C