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REPLACEMENT SUGGESTIONS FOR
AROCLOR PLASTICIZERS
The Information contained in this bulletin is, to our best knowledge, true and accurate, but all recommend ations or suggestions are made without guarantee, since the conditions of use are beyond our control. Monsanto Company disclaims any liability Incurred in connection with the use of these data or suggestions. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or ltB use.
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In conjunction with our removal of Aroclor plasticizers from the market, Monsanto has attempted to put together a list of replacement suggestions for this line of pro ducts. Anyone who has had experience with Aroclors will recognize that this is a difficult task. The combination of thermal and chemical stability, good compatibility, low cost, and fire retardance make Aroclors difficult products to replace.
On the following pages, you will find listed products pro duced by Monsanto and by other competitive suppliers which could be used as a starting point in reformulation work. This list has been compiled based upon our understanding of the requirements of the various application areas and not necessarily upon extensive application research. Therefore, the list should not be construed to be a blanket recommendation.
Monsanto would be happy to discuss replacement reformulation questions as they arise. Listed below are several people who have had contact with the various application areas in volved. Please feel free to contact them.
Dr. A. William Coaker (314) 694-2486
Polysulfides Acrylics Adhesives
Dr. Charles P. Parley (3X4) 694-2438
Mr. John H. Orem (314) 694-2489
Polyurethane Foam Rubber
Melamines Phenolics Coatings Carpet-backing
Mr. L. David Press (314) 694-2487
Polyurethane Film
Pigments Film and Sheeting Coated Fabrics
[jd'SUL s.o^JL
Willis S. Clark Product Supervisor Bi/Terphenyl Derivatives (314) 694-2518
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AROCLOR REPLACEMENT SUGGESTIONS
Application Area
Polymer/Binder
Adhesives Delayed Tack
SBR, PVAc, PS
Aroclor Used 6090, 5^60
Emulsion
PVAc, SBR Acrylio-YAc Acrylic-Ethylene
1221-B, 6040, 6050
Pressure Sensitive
Natural Rubber, SBR, Cl Rubber
1221-B, 6062, 5460
Hot Melt
EVAc, FVC, Phenoxies, Polyamides
5460, 5060 Montar 5
3.
Replacement Suggestions
Supplier
Product
Monsanto
DCHP, DPP
Santlcizer 1-H Santollte MHP
2
-s TOr 0
Monsanto FRP
Santicizer 218-A Santlcizer 885 Santlclzers 8, B-16, M-17
Isoester A, B, C
Monsanto FRP
Santicizers 140, 148, 160 Triphenyl Phosphate
Isoester B
Monsanto
Plcco Velsicol Goodyear FRP
Santicizers 9, 1-H
Santowax OM 1'
,
DCHP/Santicizer 160 `
Triphenyl Phosphate
DPP
Piccotex 75
Klyrvels
Wingtac
Isoester D
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AROCLOR REPLACEMENT SUGSESTIONS
Replacement SuRRestlons Application AreaPolymer/BinderAroclor UsedSupplierProduct
Adhesives (Continued) Hot Melt (Continued)
Hercules
Staybelite
1. Potentially available In mid-February. Not available now. 2. Alkali dispersible hot melt systems.
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AROCLOR REPLACEMENT SUGGESTIONS
Application Area
Polymer/Binder
Sealants
Polysulfide, Nitrile, Epoxy, Polyurethane
Aroclor Used
1254, 5432 Santicizer 261/ 5460
Replacement Suggestions
Supplier
Product
SJ a
Monsanto
HB-40 2 3`
Santicizer 26l Santicizer 278 Santicizer 358 Santicizer 898
p
?' ,
Thiokol
ZP-680
ICI Cereclor 4985
Caulking Compounds
Acrylic, Butyl
5060, 6070
Monsanto
Santiclzers 412, Santicizer 8 Santicizer 26l Santicizer 278 DCHP/DPP Santicizer 148
429
Surface Coatings
Paints
FVAc, FVC,
Nitriles Styrene Acrylics Cl Rubber
5460, 6062, 6070, 6090
Monsanto
1. Developmental Item - Refer to P. R. Graham.
FRP ICI
2. Recommended primarily for resin system.
3. Recommended primarily for catalyst dispersion system,
k Several products available under this code name.
Santiclzers 160, 261 278 Santicizer 898 Santiclzers 140, 148 DCHP, Santolite MHP
KMP, Filtrez
Cereclor 42 Cereclor 70
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AROCLOK REPLACEMENT SUGGESTIONS
Replacement Suggestions
Application AreaPolymer/BinderAroclor UsedSupplier
Product
Surface Coatings (Continued)
Lac quers
Alkyd Ethyl Cellulose Nitro Cellulose
5460, 6062, 6070, 6090
Monsanto
FRP Neville
Santiclzers 8, 9, B-16, M-17 DCHP Santolite MHP Santiclzers 261, 278
Isorosin, Filtrez ^
Diamond Shamrock
Varnish Paper Coatings
Polysulfide Other
6070, 5460
Ethyl Cellulose
6040, 6050
Monsanto FRP Monsanto
1. Approximately twenty Filtrez products are available.
Santlcizer 26l Santicizer 278
Filtrez
Santiclzers 8, 9, B-16, M-17 DCHP Diphenyl Phthalate Santolite MHP
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AflOCLOR REPLACEMENT SUGGESTIONS
Application Area____________ Polymer/Binder
Printing Inks
Nitrocellulose
Acrylic Vinyl
Aroclor Used
5460, 6062, 6070, 6090
7.
Replacement Suggestions
Supplier
Product
S n
Monsanto
Santlcizers 160, 26l 278 '
Santlcizers 8, 9
FRP
Filtrez
1. Approximately twenty Filtrez products are available.
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AROCLOR REPLACEMENT SUGGESTIONS , . Replacement Suggestions Application AreaPolymer/BinderAroclor UsedSupplierProduct
Lost Wax Casting: Epoxy Systems
Wax Epoxy
Laminating Resins
Phenolic
5460 6062, 6070
Monsanto Monsanto
5460, 1221, 5432, 6070
Monsanto
Santlcizer 9, 9F DCHP, DPP
Mod-Epox Santlcizer 8 Santlcizer 9 Phosgard C-22-R Other
Santolite MHP Santlcizer 8 Santlcizer 9 Phosgard 2XC-20 Phosgard C-22-R Other -*
1. Monsanto has development products In this area. Contact L. 0. Raether
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LIST OP SUPPLIERS
Monsanto Diamond Shamrock PRP Goodyear Hercules ICI Neville Piooo
Monsanto Industrial Chemicals Company 800 North Lindbergh Boulevard St. Louis, Missouri 63166 w. S. Clark (314) 694-2518
Diamond Shamrock Chemical Company 300 Union Commerce Building Cleveland, Ohio 44115 (216) 621-6100
PRP Company P. 0. Box 349
Baxley, Georgia (912) 367-3616
31513
Goodyear Tire and Rubber Company 1144 East Market Street
Akron, Ohio 44316 (216) 794-4390
Hercules, Inc. 910 Market Street Wilmington, Delaware (302) 656-9811
19899
ICI America, Inc. 151 South Street
Stamford, Connecticut
(203) 327-3200
06904
Neville Chemical Company Neville Island
Pittsburgh, Pennsylvania (412) 331-4200
15225
Pennsylvania Industrial Chemicals Corp. 120 State Street St. Clairton, Pennsylvania 15025 (412) 233-8600
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Thlokol Velsicol
LIST OF SUPPLIERS (Continued)
Thlokol Chemical Corporation 930 Lower Perry Road Trenton, New Jersey 08607 (609) 396-4001
Velslcol Chemical Corporation 341 East Ohio Street Chicago, Illinois 606II (312) 467-5700
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MONSANTO DISTRICT SALES OFFICES
AKRON, OHIO 44313 260 Sprlngslde Drive Montrose Development Tel. (216) 666-4111
Park
ATLANTA, GEORGIA 30339 320 Interstate North Parkway Suite 500 Tel. (404) 432-7111
BOSTON, MASSACHUSETTS 02149 Everett Station Tel. (617) 387-5010
CHICAGO, ILLINOIS 3158 Des Plaines Avenue Des Plaines, Illinois 60018 Tel. (312) 296-6688
CINCINNATI, OHIO 45206 1501 Madison Road Tel. (513) 751-6707
DETROIT, MICHIGAN 500 Northland Towers West Southfield, Michigan 48075 Tel. (313) 357-0910
HOUSTON, TEXAS 77027 1301 Post Oak Tower 5051 Westheimer Road Tel. (713) 621-9550
LOS ANGELES, CALIFORNIA 90022 6670 East Flotilla Street
Tel. (213) 723-2492
NEW YORK, NEW YORK 10036 1114 Avenue of the Americas Tel. (212) 764-5000
ST. LOUIS, MISSOURI 63166 800 North Lindbergh Boulevard Tel. (314) 694-1000
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SAN FRANCISCO BAY AREA 2710 Lafayette Street Santa Clara, California Tel. (408) 243-0414
95052
SEATTLE, WASHINGTON 98121
2112 Third Avenue Tel. (206) 622-4203
WILMINGTON, DELAWARE 19810 Suite 204, Bancroft Building 3411 Sllverside Road Tel. (302) 478-4600
Monsanto Industrial Chemicals Company A Unit of Monsanto Company 800 North Lindbergh Boulevard St. Louis, Missouri 63166
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