Document wq3x95rrv90Gve1qpYKqX12oJ

VAPOR PRESSURE TEST SUBSTANCE Identity:N-ethylperfluorooctasnuelfonamidoethanolm;ay alsobe referredto as N-ETFOSE Alcoholor FM-3422. (I-Octanesulfonamide,N-ethyl1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2-hydroxyethyl)-, CAS # 1691-99-2) Remarks: Materialisa whitewaxy solid.Itischaracterizeads beingstableat room temperature.The reportindicatesthe sample was 99% pure. METHOD: Methodfollowed: OECD Guideline104, "Vapor Pressure Curve, Dynamic Method." GLP: Yes Year study was performed: 1998 Remarks: The followinqguotefrom thetestreportdescribestheonlytestdeviation. "Whiletestingtestitem,the aircondenser was used inplaceofwater condenser because of low meltingpointofthe testitem. To the bestofour (ASci Corporation)currentscientifikcnowledge and understanding,thisdeviation should have no effecton the outcome ofthistest.("Quote taken from thetest report). No note was made ofany decomposition. RESULTS- The vapor pressuresat 100C, 200C, 250C, and 300C were 0.194 Pa, 0.504 Pa, 0.792 Pa, and 1.227 Pa, respectivelbyased on the decreasingpressure regressionequation. Remarks: "The estimatedvapor pressuresforthe increasingand decreasing pressure conditionsdiffebry 42-50 percent." CONCLUSIONS The vapor pressuresuggests thismaterialwould existprimariliynthe gas phase inthe atmosphere. DATA QUALITY ReliabilitKyl:imiscrhankin=g 2. Thisstudymeetsaltlhecriterfioarquality testing.However, the 99% puritymay notbe correct.The value was assigned by NMR which isincomplete.Possiblenon-lineaprlot(notenough data points). As describedabove, the vapor pressurescalculatedwhilepressurewas increasedvs.decreased diffebry 42-50 percent.However, thirdpartyconsultant reviewofthe data concluded the study isvalid. REFERENCES Determinationof Vapor Pressure Curve by Dynamic Method forU1463 (ET FOSE), ASci Report # 044-VP.R3M, AScl Study ID #5030-044-01, November 6, 1998.. OTHER Submifter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St.Paul, Minnesota,55133 Last changed: 5/18/00 ASel Report #044-VP.R3M ASc,lStudy ID #5030-044-01 STUDY TRME Page I fc Determinationof Vapor PressureCurve by Dynamic Method forU1463 (ET FOSE) DATASTANDARD OECD Guideline104, "Vapor PressureCurve, Dynamic Method" AUTHORS Mike Signotelli Linda Christensen PhilliMp arquis STUDY COMPLETED November 6, 1998 TESTING FACILrrY AScl Corporation/AScI-Duluth EnvironmentalTestingDivision 4444 AirparkBoulevard Duluth,MN 55811-5712 Tel.No.-(218)722-4040 STUDY IDENTIFICATION NUMBERS ASCI Study ID# 5030-044-Ola 3M Company EnvironmentalTechnology and SafetyServices SponsorStudy ID# U1463 This studyreportcontainsa totalof 26 pages. The raw datapackage (33 pages)supportingthis studyiskepton fileatASCI-DETD. Spomor Study ID# U1463 ASel RVort #044-VP.R3M A&I SuWy ID #503G-04"1 Page 2 CERTMCATION OF GOOD LABORATORY PRACTICE COMPLIANCE To thebestof my knowledge,thisstudywas conductedinaccordancewith OECD Good Laboratory Practiceregulation(s1). ASCI Study Director Name (signed): Date: Lyq Name (qTed):LindaChristensen Sponsor Study IDN U1463 ASCI Report #04,@-VP.R3M ASel StudyID #5030-0"-Ol Page 3 STATEMENT OF OUALITY ASSURANCE The studydatawere reviewedby the ASCI QualityAssurance Unit toassurethatstandardoperating procedur'easnd guidelinesused to conductthisstudywere followed,and thisreportisan accurate reflectioonf theraw data. The typesof auditsperformed forthisstudyarelistedinthefollowing table. Type ofAuditfor ASel Stu_dyED# 5030-04"1 TestProtocol d' Inn-LifePhThSayatse AP&r'otocol RaRIFEaieDwn6atatlDRaaetpaoarsuntpd Dmft Fi-nwUafleRePport Report Audit Date 3/26/98 4/3/98,4nl98 5/22/98,5/27/98 11/4/98 Date Reported to Study Directorand Management 3/27198 4/6/98,4/8/98 5/26/98,5127/98 11/5/98 AScI's QualityAssuranceUnit Auditor Name (signed):. Name (typed):AlanMozol Date: SponsorStudyID# U1463 ASciReport#044-VP.R3M ASelStudyID #5030-044-01 Page4 TABLE OF CONTENTS COVER'PAGE .............................................I...... CERTIFICATION OF GOOD LABORATORY PRACMCE COMPLIANCE ............2.. STATEMENT OF QUALITY ASSURANCE .............................3.... TA13LE OF CONTENTS ........................................4...... STUDY SYNOPSIS ...........................................6...... 1.0 INTRODUCTION .......................................8...... 2.0 TEST METHODS .......................................8...... 3.0 TREATMENT OF RESULTS .................................10... 4.0 RESULTS AND DISCUSSION ................................10... 5.0 CONCLUSIONS ......................: ..................11. 6.0 DEVIATION FROM APPROVED TEST PROTOCOL ............... 12 1.0 REPORT SIGNATURE ....................................12.... .8.0 REFERENCES ........................................1.2.... TABLE1. TABLE 2. TABLE 3. TABLE 4. Toluene(ReferenceItem):BoilingPointsM and CorrespondingVapor Pressures(p) at IncreasingPressure ..................................1.3 .... Toluene(ReferenceItem):BoilingPointsM and CorrespondingVapor Pressures(p) at DecreasingPressure .................................14... Toluene(ReferenceI.tem):EstimatedVapor Pressures(p)atDifferentTemperatures Determinedfrom EquationI ...........................1.5.. Toluene(ReferenceItem):EstimatedVapor Pressures(p)atDifferentTemperatures (T)Determinedfrom Equation2 ...........................1.6.. Sponsor Study ID# U1463 TableofContent(scont.) ASelReport#044-VP.R3M ASclStudyID #5030-0"-ol Page5 TABLE'5- Range Of Vapor PressureValues forToluene by theDynamic Method from OECD and EEC-LaboratoryIntercomparisoTnestingProgram (4)..............1.7. TABLE 6. ET FOSE (TestItem):BoilingPoints(T)and CorrespondingVapor Pressure(sp)at IncreasingPressure ..................................1.8 ... TABLE 7. ET FOSE (TestItem): BoilingPointsM and CorrespondingVapor Pressures(p)at DecreasingPressure ..................................1.9 ... TABLE 8. ET FOSE (TestItem):EstimatedVapor Pressures(p)atDifferenTtemperatures(T) Determined from Equation3 ..............................20.... TABLE 9. ET FOSE (TestItem):EstimatedVapor Pressures(@)atDifferenTtemperatures(T) Determined from Equation4 .............................2.1... TABLE 10. ET FOSE (TestItem): ResponsibilitieSsi,gnaturesa,nd Initialosf Key Personnel Involvedin theStudy .................................2.2 ... FIGURE 1. A RepresentativPelotofLog p (Pa)and I/T (K) TolueneatIncreasinPgressure 23 FIGURE 2. A RepresentativPelotof Log p (Pa)and 1/T (K) TolueneatDecreasingPressure 24 FIGURE 3. A RepresentatiPvleotof Log p (Pa)and I/T (K) ET FOSE atIncreasing, Pressure ........................................2.5 .... FIGURE 4. A RepresentativPelotof Log P (Pa)and 1/T (K) ET FOSE atDecreasingPressure26 RAW DATA PACKAGE APPENDIX A. Approved StudyProtocol#044-VP.P3M and Amendments APPENDIX B. TestItem Information APPENDIX C. TestItem Receiptand Usage APPENDIX D. Raw Data Sheets SponsorStudy ID# U1463 ASelRcport#044-VP.R3M ASCIStudyID #5030-0"-Ol Page6 Title: STUDY SYNOPSIS Determinationof Vapor PressureCurve by Dynamic Method forU1463 (E7 FOSE) Test Method: Dynamic method as describedin ASCI Protocol#044-VP.P3M Key Findings: 1) The estimatedvapor pressuresof thetestitem,ET FOSE, are0.504 Pa at 20*C and 0.792 Pa at 250C. Study SWnsor Company: 3M Environmental Technology & 935 Bush Avenue Building2-3E-09 St.Paul, Minnesota 55133-3331 SafetyServices Study Representative: Dr. Rich Purdy Ecotoxicologist Phone: (612)778-5379 Fax: (612)778-6176 Test Chemical Trade Name: ET FOSE. Lot/BatchNumber: 61691-16 (TechnicalLaboratoryBook, John therlin). Sponsor Study IdentificatioNnumber:' U1463 Molecular Formula: CSF17SO2N(CH2CH3)CH2CH20H Chemical AbstractServiceRegistry#/Code#: TradeSecret PhysicalDescription:White waxy.solid PercentPurity(% activeingredient):99% Based on informationsuppliedby Sponsor's Representative. Sponsor Study ID# U1463 ASci Report #044-VP.R3M ASel Study ID #5030-0"-Ol Page 7 StabilitDyata: Stableatroom temperature. StorageConditions:Room temperaturein darkness. TestingFagft Company: AScl Corporation/AScI-Dulutli EnvironmentalTestingDivision(ASCI) 4444 AirparkBlvd Duluth,Minnesota 55811-5712 AScl Study Direr-tor: Linda Christensen Phone: (218)722-4040 Fax: (218)722-2592 ReferenceItem Trade Name: Toluene. Lot/BatchNumber: 8608KTMH. CAS Registry#/Code#:108-88-3.PercentPurity:99.9%., Source: MalUnckrodt. Date ContainerOpened: 4/3/98. Study InitiatiDoante: 3/30/98. Exp@Lnmental Dates ExpiLnment StartingDate TerminationDate Determinationof Vapor Pressure 4/3/98 4/8/98 LocationRaw Data and Final Certifiecdopieswillbe archivedattestinfgacilitfyorfiveyearsfrom thedatethestudyis completed,afterwhich, the Sponsorwillbe contactedto determinefurtherdispositioonf allrecords. Sponsor Study ID# U1463 ASci Report#044-VP.R3M ASci Study ID #5030-044-01 Page8 1.0 INTRODUCTION Chemical substancesintroducedintotheenvironmentpresentpotentiadlisposaland reentry hdzwds. The assessmentof environmentalfateand effectof thesesubstancesisrequiredby variousgovernmentalagencies.Accordingly,one of-thetestsistodeterminethevapor pressureof a substance.In thisexperiment,the testitem boilingpointisdeterminedata desiredpressureand thenvapor pressureand boilingpointarecorrelated. The vapor pressureof a substanceisan environmentallyrelevantpropertybecause(1)it indicatetsheprobabilitoyfphase transitiovno,ladlizatio(nliquid/gaosr) sublimation (solid/gaso)f,a chemical,(2)ithelpssubstantiatperedictionrsegardingtheenvironmental behaviorofchemicals,(3)chemicalvaporpressureand watersolubilitayllowforthe calculationfchemicalvolatiliftryom an aqueoussolutiona,nd (4)itisusefulin deciding whetherphotochemicauy induceddegradationcan be determined in thehomogenous gas phase orin an absorbedphase (OECD 1993). 2.0 TEST METHODS 2.1 Glass 1) 2) All glasswareemployed were cleanedbeforeuse by performingthefollowing: Washed inhotdetergentwater and rinsedthreetimeswith warm tap water. Immersed in 10% HN03 acidbath and then rinsedwith deionizedwater. 3) Rinsedthreetimeseach with acetonefollowedby hexane. AU glasswareused were labeledwith therelevantinformationrequiredforproper identification. 2.2 TestItem. The testitem,ET FOSE, materialsafetydatasheets,and certificaotfeanalysis were receivedatASCI on March 27, 1998. The testitem was inone glassbottleand was storedatroom temperaturein darknessas received. All relevantinformationabout the"te-st itemisdescribedearlieirnthisreport.In thistest,14.21g of testitem was used. 2.3 ReferenceItem. Reagent-gradetoluenewas used as a referenceitem. All relevant informatioanboutthereferenceitem isdescribedearlierin thisreport.In thistest,35 ml of referenceitem was used. 2.4 TestApparatils.The testsystem consistedof-. 5-L Ballasbtulb tovary pressureindouble-neckdistillatifolnask. Sponsor Study ID# U1463 AScl Report #044-VP.R3M ASci Study ID #5030-0"-Ol Page 9 2) Closed-tubemercury manometer to measure pressure. 3) 100-ml double-neckdistillatifolnask. 4) Centigradethermometer, 0.2*C, withone holerubberstoppertofit in thedistillatifolnask. 5) Refluxcondenser. 6) Heatingelement. 7) Vacuum pump. 8) Aspirator. 9) Boiling stones@. 10) Nitrogencylinder. 2.5 Determinationof VaMr Pressure.The proceduretodeterminethevapor pressuresof test and referenceitemswas as follows: 1) Placedtheitem indouble-neckdistillatifolna.skat a volume aboutone- thirdtheflaskvolume, and added threeto fourboilingstones. lp 2) Flangedtestsystemtogetherand purged itwith nitrogen.The pressure in thesystem was adjustedusingvacuum. 3) Heatedthechemicaglradualulnytitlemperatuerqeuilibriwuams reachedt,haits,whena constabnotilintgemperatuWraes found. 4) At thispoint,recordedtotalpressure(inmm Hg) and boilingpointT (in*C). 5) For atleastfivedifferenptressures,increasedpressureand recorded new totalpressuresand boilingpointswhen equilibriwaere reached. 6) To obtainthesecondsetof data,recordedtotalpressureand boilingpointas the pressurewas lowered. Sponsor StudyID# U1463 A&[ Report#044-VP.R3M ASelStudyID #5030-0"-ol Page10 3.0 TREATMENT OF RESULTS Foreachdatasetwithtesatndreferenicteemst,otaplressuwraesconvertetdoPa unitby multiplyingtheobservedmillimetermercurypressurewith 133.3. Similarlyt,heboiling pointM was convertedto OK by adding273.15 totheobservedOC boilingpoint.The log of totalpressure(Pa)vs.(1/T)from theindividuadlatasetswere regressedtodevelopthe vapor pressurecurvesforeach item. Vapor pressuresforthe test'iteamnd thereference item were determinedat.10*C, 200C, 25*C, and 30*C usingappropriatleinearregression equations. 4.0 RESULTS AND DISCUSSION ReferenceItem: Toluen The observed dataobtainedforincreasingand decreasingthepressureare shown in Table's1 and 2, respectivelfyortoluene.The calculaterdegressiocnurvesfrom theplottedcurves, Figures1 and 2, are: Increasingpressure: logp = 10.27-1994(I/T) r = -0.999,n = 5 (1) Decreasing pressure: logp = 10.35-2023(1/T) r = -0.998,n = 5 (2) The two datasetsaresimilarand have correlatiocnoefficiengtrs"r than0.990. The estimatedvapor pressuresat 10,*20, 25,*and30*C are listeidn Tables3 and 4 forthetwo toluenedata sets.Table 5 listtsherange of vapor pressurevaluesdeterminedby the dynamic method from interlaboratocroymparisons(4). The toluenevapor pressuresdeterminedfrom equation1 are withintherangeslistedforthe interlaboratorcyomparisons.The valuesdeterminedfrom equation2 are slightllyower at 10 a.nd 20*C. The vaporpressurefortolueneat20*C (2.8X 103 Pa) islower thanthe criterion established in the protocol (2.9-3.1 X 103 Pa). The vapor presure for toluene at 10*C (1.6 X 10-3 Pa) is lower than the criterion stated in reference 4 (1.7-1.8 X 10-3 Pa). A problem occurredwith the systemas thepressurewas decreased.To getthetolueneto boil as thepressurewas decreased,more boilingchipswere added totheitem. Itisnot clear whether thiswould have affectedthetemperatureand pressuremeasurements. Sponsor Study ID# U1463 ASciReport#044-vp.R3m A&I StudyID #5030-0"-ol Page11 The experimentdaelsigpnresentehderefordeterminivnagporpressurceurveasppeartso providedatacomparabletothatreportedinreference4. The regressiocnurvesare linearfor both increasingand decreasin*gpressures. TestItem: ET FOSE The observeddataobtainedforincreasingand decreasingthepressureare shown inTables6 and 7, respectivelyT.he calculaterdegressioncurvesfrom theplottedcurvesof logp vs (1/T),Figures3 and 4 are: Increasingpressure: logp = 11.09-3278(1/T) r = -0.988,n = 5 Decreasing pressure: (3) logp 11.42-3435(1/T) r = -0.994,n.= 5 (4) The regressionlinefordecreasingpressureismore linear.thatnheincreasinpgressure regressionline.The estimatedvapor pressuresat 10, 20, 15, and 30*C are listeidnTables 8 and 9 for thetestitem. The estimatedvapor pressuresforthe increasinagnd decreasing pressureconditionsdifferby 42-50 percent. 5.0 CONCLUSIONS The placementof the thermometerin the apparatusproved tobe pivotalinestablishing accurate,steadytemperaturemeasurements. The placement of thethermometerforthe test item was differentthanthatof thereferenceitem. Two previoustrialwsiththetestitem were performedpriortothe testreportedto determinethe correctplacementof the , thermometer. The thermometerwas placedapproximatelyone inchabove thebubblingt,est iteminthecollectiofnlask.The thermometer forthereferenceitemwas placedintheneck of thecollectiofnlask. Based on the decreasingpressureregressionequation,thevapor pressuresat 10*C, 20*C, 250C, and 30*C were 0.194 Pa, 0.504 Pa, 0.792 Pa, and 1.227Pa, respectively. 7 Sponsor Study ]D# U1463 ASelReport#044-VP.R3M ASelStudyID #50304344-01 Page12 6.0 DEVIATION FROM APPROVED TEST PROTOCOL The deviationwhich occurred'whilceonductingthisstudyis: 1) While testintgestitem,theaircondenserwas used inplaceof water condenser becauseof low meltingpointof thetestitem. To thebestof our currentscientifkincowledge and understandingt,hisdeviationshouldhave no effecton the outcome of thistest. 7.0 REPORT SIGNA ASCI Study Director Name 7;Lk (sis!ned): Cf-,- Name (typed):LVdaChristensen Date: illIbqJ" Responsibilitiessi,gnaturesi,nitialasn,d names of key personnelinvolvedinthisstudyare in Table 10. .8.0 REFERENCES 1) OrganizatiofnorEconomic Cooperationand Development (OECD), 143-. OECD GuidelinesforTestingof Chemicals.OECD PublicatioInnformationCenter, Washington,DC. 2) Shoemaker, D.P. and C.W. Garland.1962.ExperimentsinPhysicalchemistry. McGraw-Hill Book Co., pp. 162-163. 3) OrganizationforEconomic Cooperationand Development (OECD), 1997. Environment DirectorateC,hemicalsGroup and Management Committee. OECD Serieson Principleosf Good LaboratoryPracticeand Compliance Monitoring. Number 1. OECD Principleosn Good LaboratoryPractice. SponsorStudy ID# U1463 TABLE 1. mmHg 47 64 77 100 124 ASci Report #044-VP.R3M ASel StudyID #5030-04"1 Page 13 Toluene(ReferenceItem): BoilingPointsM. and CorrespondingVapor Pressures(p)at IncreasingPressure Mumred Prmure p (Pa) 6265 8531 10264 13330 16529 Log p (Pa) 3.797 3.931 4.011 4.125 4.218 T ('*C) 35.0 41.2 45.5 51.2 56.5 Obwved Tempemture T (OK) 308.15 314.35 318.65 324.35 329.65 I/T (OK) 0.003245 0.003181 0.003138 0.003083 0.003034 Sponsor Study ID# U1463 TABLE2. rnm g ISO 128 110 77 52 ASel Report#044-VP.R3M ASci StudyID #5030-0"-ol Page 14 Toluene (ReferenceItem): BoiUmg PointsM and Corresponding Vapor Pressures(p)at Decreasing Pressure Memured Premre P (Pa) 19995 17062 14663 10264 6932 Log P (Pa) 4.301 4.232 4.166 4.011 3.841 T ('C) 61.2 57.7 53.6 45.0 3,8.0 Obsuved Tempemture T (-K) 334.35 330.85 326.75 318.15 311-15 1/T(-K) 0.002991 0.003023 0.003060 0.003143 0.003214 Sponsor Study M# U1463 ASel Rcport #044-VP.R3M ASel StudyID #5030-04"1 Page 15 TABLE 3. Toluene (ReferenceItem):-EstimatedVapor Pressures(p)atDifferent Temperatures (7)Determined from Equation Is T (OC) io 20 25 30 Vapor Pressure(Pa) 1.7 X 103 2.9 X 103 3.9 X 103 4.9 X 103 Vapor Pressure(mmHg) 12.7 22.0 28.6 36.9 EquationI - Log p 10.27-1994(In) lip Sponsor Study ID# U1463 ASci Report #044-VP.R3M AScl Study ID #5030-044-01 Page 16 TABLE 4. Toluene (ReferencIetem): EstimatedVapor Pressures(p)at Different Temperatures(1)Determined from Equation 2a T (*C) 10 20 25 30 Vapor Pressure(pa) 1.6 X 103 2.8 X 103 3.7 X 103 4.8 X 103 vapor Pressure(rrumhg) 12.0 21.1 27.5 35.6 Equation2 - Log p 10.35-2023(lM Sponsor Study ID# U1463 TABLE 5. AScl Report #044-VP.R3M ASci Study ID #5030-044-01 Page 17 Range of Vapor PressureValues forToluene by theDynamic Method from OECD and EEC-Laboratory IntercomparisonTestingProgram (4) Temperature (OC) 10 20 30 Range of Vapor Pmmre (Pa) (1.7-1.8)X 103 (2.9-3.1)X 103 (4.8-5.0)X 103 Sponsor Study ID# U1463 TABLE 6. mmHg 42 55 67 81 96 ASci Report#044-VP.R3M ASci Study ID #5030-044-oi Page 18 ET FOSE (TestItem):BoiUmg pointsM and CorrespondingVapor Pressures (p)at IncreasingPressure Observed Pressure p (Pa) 5599 7332 8931 10797 12797 LDg P (Pa) 3.748 3..865 3.951 4.033 4.107 T (6C) 174.6 179.0 187.2 190.2 197.0 Observed Temperature T (OK) 447.75 452.15 460.35 463.35 470.15 Irr (-K) 0.002233 0.002212 0.002172 0.002158 0.002127 Sponsor Study ID# U1463 TABLE 7. mmHg 93 93 68 8 37 ASel R"rt #044-VP.R3M ASel Study ID #5030-0"-Ol Page 19 ET FOSE (restItem):BoWmg pointsM and.CoxTmponding Vapor Pressures (p)at DecreasingPressure Observed Pre&sm p (Pa) 12397 11064 9064 6398 4932 Log p (Pa) 4.093 4.044 3.957 3.806 3.693 T (OC) 195.8 191.6 188.2 176.4 172.2 Observed Temperature T (-K) 468.95 464.75 461.35 449.55 445.35 I/T('K) 0.002132 0.002152 0.002168 0.002224 0.00224,5 Sponsor Study M# U1463 ASel Report#044-VP.R3M AScl Study ID #5030-0"-Ol Page 20 TABLE S. ET FOSE (TestItem): EstimatedVapor'Pressures(p)at Different Temperatures(1)Determined from Equation3 T (OC) 10 20 25 30 Vapor Pressure(Pa) 0.326 O.SW .1.246 1.892 Vapor Pressure(mmHg) 2." X 10-3 6.07 X I(Y3 9.35 X 10-3 14.2 X 10-3 Equation 3 - Log Pa 11.09-3278(lfT) Example Calculation Log Pa = 11.09-3278 (lrl) 10*C = 283.150K Log Pa = 11.09-3278(1/283.15) Log Pa = 11.09-11.5769 Log Pa = 0.4869 Pa = InvLog (-0.4869) Pa = 0.326 For Hg 0.326 2.44 X 10-3 133.33 Sponsor Study ID# U1463 AScl Report #044-VP.R3M ASci Study ID #5030-044-01 Page 21 TABLE 9. ET FOSE (TestItem): EstimatedVapor Pressures(p)at Different Temperatures (1)Determined from Equation 4 T (OC) 10 20 25 30 Vapor Pressure(Pa) 0.194 0.504 0.792 1.227 Vapor Pressure(mmHg) 1.46 X 10-3 3.78 X 10-3 5.94X I(Y3 9.21 X 10-3 Equation4 - Log Pa 11.42-343(5IM Sponsor Study M# U1463 ASel Report #044-VP.R3M ASci Study ID #5030-0"-oi Page 22 TABLE 10. ET FOSE (TestItem): ResponsibilitiSeisg,natures,and Initialosf Key PersonnelInvolvedinthe Study Pwwnnel Title/Responsibili Linda Christensen Study Director Mike Signortili Alan Mozol LaboratoryAssistance QualityAwumnee Audit6r Joe Amato PhilMarquis Nancy Jordan ProjectManager Report Prepamtion Aschivist Signature V Initials Sponsor StudyID# U 1463 C4) C., f4 cc 40- cu cu C)- Cl) Co)) -J %0+- cu (1) > cu CL Cl) x < (Y) CY) 0 0 LO CN Ce) 0 C:) ci 0 C%4 CY) C:) LO TCY") 0 C:) C:) vcr) C:) C:) LO C:) CY) C:) C:) C:) C:) c%I0nt CY) C:) Do Lr) CD C,4 N Lo a U-) a U-)a U-)0 Lo c@ C:) C:) (3) (3) CO CC) r@-- C:) 14: 14: li cyi C6 CY5 C6 6 Bd 'd Bo-I 0 7E-) FL- Cf) CL a) o 40 .*, 0 > C) co CN CY) C:) C:) (Zi C:) C,4 CY) C:) 9 . C:) LO CY) C:) C:) (Zi CT:-) CY) C:) LO 0 (Y) C:) C:) (Zi CL a) < C-li C:) C:) CY) C:) C:) ci LO cn %0 i7L CN C:) C:) T-T C:) CY) C:) CN C:) C:) C:) C:) 0) C:) OC) C:) 1q: cyi cvi Bd 'd Bo-i Figure3. A RepresentativPelotofLog p (Pa)and 1/T(K)forET FOS IncreasingPressure 4.15 4.104.05 4.00 3.95.3.90 3.85 .3.80 -3.75 3.70 0.00212 0.00214 0.002,16 0.00218 1/T(K) 0.00220 0.00222 SI)onsorStudy [D# U 1463 Figure4. A RepresentativePlotofLog p (Pa)and 1/T(K)forET FOS Decreasing Pressure 4.15- 4.10- 4.05- 4.00- 3.95- cE 3.90 - 0 .j 3.85 - 3.80 - 3.75 - 3.70 - 3.65 0.00212 0.00214 0.002164,v,0.00218 0.00220 1/T(K) 0.00222 0.002 Siw)nsorStudy ID# U 1463 ASel Report #044-VP.R3M ASci Study ID #5030-044-01 r4ixtlxv@ 11\0 RAW DATA PACKAGE APPENDIX A. Approved Study Protoco.1#044-VP.P3M and Amendments APPENDIX B. Test Item Information APPENDIX C. Test Item Receipt and Usage APPENDIX D. Raw Data Sheets CP@@6@i SponsorStudy ID# U140 Page of chow I ASci Corporation November 4444ArparkBoulevardD,uluth,Minnesota55811 4, 1998 (218)722-4040 Fax(218)722-2592 To: Study File.5030-044-01 It Fkom: Alan E. Mozol, QAU Manager RE: Raw data package deficiencies The following deficiencies were noted by the*Sponsor when editing DRAFT report and raw data for this study: .1. The chain of custody provided by the Sponsor was not signed by AScl-Environmental Testing Division (ETD) personnel. Test item ET FOSE (3M Company Lab Request Number U1463) was received at ASCI-ETD on March 27, 1998. The sample was received by Michael Signorelli, whom is no longer employed at ASCI-ETD. The test item was properly logged in following, ASCI-ETD SOP SUB-01-R. The "Test Item Receipt and Shipping Form" was properly completed noting March 27, 1998 as the dated received. The completed form is contained in the raw data on page 28. The Chain-of-Custody was not signed as an oversight by Mr. Signorelli. 2. On page 31 in the raw data, an entry was crossed out and not properly error coded by the technician. The initial value was 3.39101 and the 39 after the decimal were.crossed out and replaced by 93 which provides a correct value. The correct value is a calculated value and not a raw data point. The lack of proper error coding was a technician error. The following explanation is also provided for clarity: On page 33, some entries are blacked-out to make them unreadable. These entries do not pertain to the vapor pressure study, but do apply to other studies conducted on the test item. paq,e of -_lz ASet Report#044-VP.R3M AScl Study ID #5030-044-01 APPENDIX A. Approved Study Protocol#044-VP.P3M and Amendments Sponsor Study ID# U1463 Pa _qo of ASCI Protocol#"044-VP.P3M ASCI Study M# 5030-044-01 Fmal Version Page I of 12 ASCI CORPORATION/ASCI-DULUTH ENVIRONMENTAL TESTING DIVISION Determinationof Vapor PressureCurve by Dynamic Method ASCI Protocol#044-VP.P3M ASCI Study ID# 5030-044-01 'TestItem: ET FOSE Sponsor Study ID# U1463 paqo of AScl Protocol#044-VP.P3M ASel Study [D# 5030-044-01 Final Version Page 2 of 12 The followinginformationand signatureasre necessarytobe in compliancewith Good Laboratory Practiceregulation(sGLP) and/orAScI'sPolicy. To BE CONTLETED BY ASCI BASED ON DQFORMAIJON PROVEDED BY STUDY SPONSOR Study Sl?onso Company: SiteAddress: MailingAddress: Phone: Fax#: 3M Company 3M Center St.Paul,MN 55144--1000 Dr. Rich Purdy 3M Company EnvironmentalTechnology & SafetyServices 935 Bush Avenue Bldg.2-3E-09,P.O. Box 33331 St.Paul,MN 55133-3331 612/778-5379 FAX 612/778-6176 Sponsor Study IdentiricatiNounmber Numbe : U1463. l,ot/BatcNhumber: 61691-16(TechnicaLlaboratoryBook No., John Eberlin). Chemical AbstractServiceRegisia#/Code#: TradeSecret. MolecularFormula: CSF17SO2N (CH2CH3) CH2CH20H. PhysicalDescript@ionW:hite waxy solid. Sponsor @tudy [D# U1463 Page-iol-n-:>5 AScl Pmtoool# 044-VP.P3M ASci Study ID# 5030-044-01 FinalVersion Page 3 of 12 PercentPurily(% activeingredienll9!9% Based on informatiosnuppliedby Sponsor'sRepresentative. StabiliiDy : Stableatroom temperature. MeltingPoin : Not determined. BoilingPoint: Expectedtobe lessthan350*C. Storage,Conditions:Room temperaturein darkness. ReferenceItem: Toluene Note: The sponsorwillprovidetheMaterialSafetyData Sheetsand'otherrelevantinformationfortest chemical. Authorizationto Return Test Chemical and SamRLeUs Sponsor'sauthorizedagent to receivesamples and any remaining testchemical. Name: Dr. Rich Purdy Title: Ecotoxicologist Shipping Address: 3M Company EnvironmentalTechnology& SafetyServices 935 Bush Avenue Building2-3E-09 St. Paul,Minnesota 55133-3331 Phone: 612-778-5379 Fax: 612-778-6176 Sponsor Study ID# U 1463 Page') OF AScl Protocol#044-VP.P3M ASci Study ID# 5030-044-01 FinalVccsion Page 4 of 12 ProtocolApprAval (The followingistobe signedby theappropriatsetudypersonnel.) SpQnsor'sStudy Rcpresentativ Name (signed): (@z. Date: 77 mood 19@e_ Name (typed): Dr. Rich Purdv -@itle: Ecotoxicologist Sponsor Study ID# U1463 Page 6-ofw-35 ASCI Protocol#.044-VP.P3M ASel Study ID# 5030-044-01 FinalVmion Page 5 of 12 TO BE COMPLETED BY ASCI Study Conducted By Address: ASCI Corporation/AScl-Duluth EnvironmentalTestingDivision(AScl) 4444 AirparkBoulevard Duluth,MN 55811 Phone: (218)722-4040 Fax#: (218)722-2592 The studydirectoirslocatedatthisfacility. Data Standard OECD Guideline104, "Vapor PressureCurve,Dynamic Method." Proposed Expgrimental Dates ExpLnment: StartingDate: TerminationDa oil Vapor PressureCurve Determination April3, 1998 April3, 1998 Sponsor Study ID# U1463 Page oo-r AScl Protocol#-044-@FP.P3M AScl Study M# 5030-044-01 FinalVersion Page 6 of 12 ProtocolAiwroval (The followingistobe signedby theappropriatsetudypersonnel.) ASCI gtudy Director: Name (signed): Date: Name (qq)ed): Linda Christensen Title: AnalyticaClhemist ASCI ProjectManage- Name (signed): Name (typed): Joe Amato Title: DgRuiy Director Sponsor Study ID# U1463 Pao* of AScl Protocol#044-VP.P3M ASel Study ID# 5030-044-01 FinalVersion Page 7 of 12 1.0.0 INTRODUCTION Chemical substancesintroducedintothe environmentpresentpotentiadlisposaland reentry hazards. The assessmentof environmentalfateand effectof thesesubstancesisrequiredby variousgovernmentala,gencies. Accordingly,one of the testsis to determinethe vapor pressureof a substance.In thisexperiment,the testitem boilingpointisdeterminedata' desiredpressureand thenvapor pressureand boilingpointarecorrelated. The vapor pressureof a substanceisan environmentallryelevantpropertybecause(1) it indicatetsheprobabilitoyfphasetransitiovno,latilizati(olniquid/gaosr)sublimatio(nsolid/gas), of a chemical,(2)ithelpssubstantiaptreedictionrsegardingtheenvironmentalbehaviorof chemicals,(3) chemicalvapor pressureand water solubilitayllow for the calculatioonf chemicalvolatilitfyrom an aqueoussolutiona,nd (4) it is usefulin decidingwhether photochemicallyinduceddegradationcan be determined'itjhie homogenous gas phase or inan absorbedphase (OECD 1993). 2.0.0 OUALIFYING STATEMENT The dynamic method isrestrictetdo-testitemsthatdo not uodergo chemicalreactionf,or example,autoxidationr,earrangementor degradationa,ttemperaturesbelow theboilingpoints. In thisstudy,ifthetestitemboilingpointisgreaterthan350*C orifthe testitem frothst.h,en thetestsubstancevapor pressurewillbe not be determinedvia theDynamic Method. Sponsor Study ID# U1463 Page of ASclProtocol0#44-VP.P3M ASci StudyID# 5030-044-01 FmalVersion Page8 of12 3.0.0.OBJECTI The objectiveof thepresentstudyisto developifpossiblet,hevapor pressurecurve forthetest item usingtheDynamic Method. With the testobjectivea,nd GLP regulationisn mind, ASCI has preparedthe following' protocol. 4.0.0 TEST METHODS 4.1.0 TestApparatus. The testapparatus(Figure1,Shoemaker and Garland 1962)willconsistof: (1) 5-L Ballastbulb tovary pressureindouble-neckdistillatifolnask; (2) Closed-tubemercury manometer to measure pressure; (3) Double-neck distillatifolnask; (4) Centigradethermometer (accuracy 0.1*C) withone holerubberstopper to fitthedistillatifolnask; (5) Refluxcondenser; (6) Heatingelement; (7) Vacuum pump; (8) Nitrogencylinder;and (9) Boilingstonestoavoidbumping in boilinlgiquid. Sponsor Study ID# U1463 Page of AScl Protocol#044-VP.P3M ASci Study ID# 5030-044-01 Final Version Page 9 of 12 4.2.0 Determinationof VaMr Pressure The proceduretodeterminethe vapor pressurecurvesfor ,testand referencesubstanceswillbe as follows: (1) Place testsubstancein double-neckdistillatifolnaskat a volume not exceedingone-thirtdheflaskvolume,and add two or threeboilingstones; (2) Flange theapparatustogetherand vacuum it; (3) Adjustthepressuirnteheapparattou1s03Pausinngitrogen; (4) Heat the testsubstancegraduallyuntilequilibriumisreached,thatis, when a constantboilingtemperatureisfound; (5) At thispoint,recordthetotalpressure(Pa)and boilingpointM; (6) Increasepressureand recordthe new pressureand boilingpointwhen equilibriumisreached; (7) Contintuheipsrocedufroeratleasat5 differpernetssufroersupto105 Pa pressure; (8) To obtaina second setof data,recordpressuresand boilingpointsas pressureisloweredto 103 Pa. 5.0.0 Treatmentof Results.For each data set,log of totalpressure(Pa) willbe calculateadnd boilinpgoint(T)transformetdoKelvin(K). The logPa and I/T (inK) willbe thenusedto developtwo vapor pressurecurves. From each vapor pressurecurve,thetestsubstancevapor pressureatthreetemperatureisn therangeof 0-50* C, and at25*C willbe determinedby data interpolationr extrapolatioannd reported. Sponsor Study M# U1463 Page ASci Protocol0#44-VP.P3M AScl Study[D# 5030-044-01 FinalVersion Page 10 of 12 6.0.0 REPORT PREPARATION. The finarleportwillbe preparedaccordingto instructiopnrsesenteidn OECD Serieson Principleosf GLP and Compliance Monitoring,Number 1, OECD Principleson GLP 1997. The reportwillinclude(1) Cover and descriptiyteitle(,2) Test and referenceitem identificatio(n3s)Characterizationf testitemincludingpurity,stabilitayn,d homogeneity,(4) Informationdescribingthetestsponsor,testfacilitya,nd contributors(5)duly signedstatements regardingGLP Compliance and QualityAssurance,(6)Study Synopsis,(7)Introductioannd Objectives(,8)Materialsand Methods, (9)Resultsand Discussion,(10)Conclusions,(11)any Deviationsfrom theApproved Study Plan,(12)Study Director'sReport Signature,(13)a list of personnelinvolvedin the Study and theirFunctions,(14)LiteraturReeferences,(15)Raw TestData,includingtheplotof log P versus I/T,and (16)Appendices. 7.0.0 OUALrrY ASSURANCE Test procedures,documentation,recordsand reportswill conform to GLP tandardsas promulgated under the OECD Chemicals Group and Management Committee, Environment Directorate1,997. The ASCI QualityAssurance Unit willperform one in-lifpehase auditduring thetest,and willalsoauditthestudypjan,testdata and report.,Thetestwillbe unacceptable ifvapor pressuresof referenceitem (toluene)arenot in the followingranges:1.7 + 0.1 x 103 at 10-C; 3.0 0.1 x 103 at 20*C; and 4.9 0.1 x 103 at 30*C. During the study,ifASCI realizeas need toamend the approved studyplan,we willdocument reasonsfor such changes and contactthe Sponsor for approval. The changes willalsobe signedand datedby theStudy Directorand maintainedwith the studyplan. Afteracceptance of thefinalreportby theSponsor, ASCI willreturnthe a portionof the remaining testsubstance to theSponsor,and a portionwillbe retainedforarchiving. Sponsor Study IDN U]463 ASci Protocol0#44-VP.P3M ASci StudyID# 5030-044-01 FinaVlcrsion Page11of12 Raw datafromthisstudys,tudpyrotocople,rtinewnrtitteandtelephocnoemmunicatioannsd, ,finarleportwillbe archivedforfiveyearsatAScl.D6ring thefifthyear,ASCI willcontactthe Sponsor regardingfurtherstorageof allrecords. 8.0.0 REFERENCES OrganizationforEconomic Cooperationand Development (OECD), 1993.OECD Guidelines forTestingof Chemicals.OECD PublicatioInnformationCenter,Washington,Dc. Shoemaker, D.P. and C.W. Garland.1962-.ExperimentsinPhysicalchemistry.McGraw-Hill Book Co., pp. 162-163. Organizationfor Economic Cooperationand Development (OECD), 1997. Environment DirectorateC,hemicals Group and Management Committee. OECD Serieson Principleosf Good LaboratoryPracticeand ComplianceMonitoring.Number 1. OECD Principleosn Good LaboratoryPractice. Sponsor Study ID# U1463 Page of ASci Protocol#044-VP.PRO ASci Study ID# 5030-044-01 FinalVersion Page 12 of 12 FIGURE 1. APPARATUS FOR VAPOR PRESSURE DETERMINATION Refluxconicenset C10S.ed-lubmeetcury mSnOmete( 2 -neckClaissen nask F 8alLastbulb To va@xmm Stopeor-sk st@ x Sponsor Study ID# U1463 ',7 Page (L@of ASCI Protocol# 044-VP.P3H AscI Study XD# 5030-044-01 AmLandiment - 4/2/98 AMENDNW.NRS (AScl Protocol#044-VP.P3M efonowilngamendtmen tshave been institutefdorProtocol# 044-VP.P3M, Sponsor Study ID# U1463. 1. The centigradethermometer used forthe study willhave gradationsof 0.2*C and not O.I*C. 'This isdue to the commercial availabilitoyf thermometers in theexpectedtestrange of OOC-2000C. 2. The distillatifolnaskwillbe 100 ml insteadof 500 ml to accommodate thesmallersample size. 3. The distillatifolnaskwillbe insulatedwith f6ilduring the experimentsto minimize heatloss. Amendment Approval Spgnsor's Studv ReRrgs::eative: Name (signed).L-I-Y- Name (typed): Dr. Rich r y Title: Ecotoxicologist Date: ASCI Study Director: Name (signed): Name (typed): Title: Linda Christensen AnalyticalChemist Date: AScl ProjectManag Name (signed): Name (typed). Title: Joe Amato Dgputy Director Sponsor Study ID# U1463 Page @5@-o@135 AScl Report #044-VP.R3M ASel Study ID #5030-044-01 APPENDIX B. Test Item Information 41 Sponsor Study ID# U1463 Pagoi_c of 3> .KATERM,SAFETY DATA SHEET (intermediate) 3H 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (612) 737-6501 (24 hours) U 14&3 Copyright, 1997, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: SPECIALTY MATERIALS DIVISION MATERIAL: FLUOROCHEMICAL ALCOHOL FM-3923 FM-3924'FM-4084 FM-4120 FM-4121 F-8904 F-8905 F-8960 ID NUMBER: 41-2600-8904-4 41-2600-8905-1 41-2600-8960-6 41-2700-3923-7 41-2700-3924-5 41-2700-4084-7 41-2700-4120-9 41-2700-4121-7 ISSUED: October 30, 1997 SUPERSEDES: May 03, 1996 DOCUMENT: 04-1162-9 --1-.--I-NG-R-E-DI-E-N-T-------------------------C-.-A-.S-.--N-O-.---------P-ER-C-EN-T----------------------------------------------------------------------------------------------- N-ETHYLPERFLUOROOCTANESULFONAMIDOETHYL ALCOHOL ............................1.69.1.-99-2 100 ----------------------------------------------------------------------------- 2. PHYSICAL DATA -------------------------------------------------------------------------------- BOILING POINT: ...............N./A. VAPOR PRESSURE: ..............<..27 psia @131F VAPOR DENSITY: ...............N./D. EVAPORATION RATE: ............N./.D SOLUBILITY IN WATER: ..........n.eglig. SPECIFIC GRAVITY: ............c.a.. 1.6 Water=l PERCENT VOLATILE: .............0 .% pH: ........................N/.A... VISCOSITY: ..................N./.A . MELTING POINT: ...............N/.D. APPEARANCE AND ODOR: Amber, waxy solid. ASci Study ID# 5030-044-01 ----------------------------------------------------------------------------Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: FLUOROCHEMICAL F-8905 F-8960 octhber 30, 1997 ALCOHOL FM-3923 FM-3924 FM-4084 FM-4120 FM-4121 F-8904 PAGE 2 - - - - -- - - - - - ---- - -- - - - - - - - -- - - - - - - - - -- - - - - - 7 - -- - - - - -- - - - - - - - - - - - -- - - - - - - -- - - - - - 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT: .................> .3.00 FLAMMABLE LIMITS LEL: ........N/A FLAMMABLE LIMITS UEL: ........N/A AUTOIGNITION,TEMPERATURE: ......N/D F PMCC ASci Study [D# 5030-044-01 EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Foam 'SPECIAL FIRE FIGHTING PROCEDURTS: Wear full protective clothing, includi6g helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. NFPA HAZARD CODES: HEALTH: 2 FIRE: 1 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY None-known. - MATERIALS/CONDITIONS TO AVOID: HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Hydrogen Fluoride. ----------------------------------------------------------------------------5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Observe precautions from other sections. Collect spilled material. Place in a closed container. RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility. Combustion products will include HF. Disposal alternative: Dispose of waste product in a facility permitted to accept chemical waste. ----------------------------------------------------------------------------Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately Page A oZf)3 TSDS: FLUOROCHEMICAL F-8905 F-8960 )ctober 30, 1997 ALCOHOL FM-3923 FM-3924 FM-4084 FM-4120 FM-4121 F-8904 PAGE 3 ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION (continued). ----------------------------------------------------------------------------- =-NVIRONMENTAL DATA: Not determined. IEGULATORY-INFORMATION: Volatile Organic Compounds: N/D. VOC Less H20 & Exempt Solvents: N/D. ASCI Study ID# 5030-044-01 Since regulations vary, consult applicable regulations or authorities before disposal. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: No CHRONIC: No ----------------------------------------------------------------------------6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: No need for first aid is anticipated. SKIN CONTACT: Wash affected area with soap and water. IN14ALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: No need for first aid is anticipated. ----------------------------------------------------------------------------7. PRECAUTIONARY INFORMATION ---------------------------------------------------------z------------------- EYE PROTECTION: Avoid eye contact. Wear safety glasses with side shields. Wear.full faceshield when handling molten material. SKIN PROTECTION: Avoid skin contact. Wear appropriate gloves when handling'this material. Wear appropriate gloves, such as Nomex, when handling this. material to prevent thermal burns. RECOMMENDED VENTILATION: Provide appropriate local exhaust when product is heated. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is.not adequate, use ----------------------------------------------------------------------------Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately Pageki of .Sod: FLUOROCHEMICAL F-8905 F-8960 )cibber 30, 1997 ALCOHOL FM-3923 FM-3924 FM-4084 FM-4120 FM-4121 F-8904 PAGE 4 ---------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ---------------------------------7 --------------------------------------- appropriate respiratory protection. IESPIRATORY PROTECTION: Avoid breathing of vapors. Avoid breathingof airborne material. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: haif-mask organic vapor respirator,f*ull-face organic vapor respirator,full-face suppliedair respirator. PREVENTION OF ACCIDENTAL INGESTION: Wash hands after handling and before eating. Do not ingest.. RECOMMENDED STORAGE: .Keepcontainer closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Not applicable. ASci Study ID# 5030-044-01 EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- N-ETHYLPERFLUOROOCTANESULFONAMIDOETHY L ALCOHOL .......................0...1. MG/M3 TWA 3M y SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contributionto the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - 3M: 3M Recommended Exposure Guidelines ----------------------------------------------------------------------------8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: No adverse health effects are expected from eye contact. SKIN CONTACT: Product is not expected to be irritatingto the skin. May be absorbed through the skin and persist in the body for an extended time. ----------------------------------------------------------------------------Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately of M%S: FLUOROCHEMICAL F-8905 F-8960 octhber 30, 1997 ALCOHOL FM-3923 FM-3924 FM-4084 FM-4120 FM-4121 F-8904 PAGE 5 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- INHALATION: may be absorbed by inhalation and persist in the body for an extended time. IF SWALLOWED: ingestion is -nota likely route of exposure to this product. illness may occur after a single swallowing of relatively large quantities of this material. OTHER HEALTH HAZARD INFOR14ATION: This product is not known to contain any substances regulated under California Proposition 65. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEALTH HAZARD DATA SECTION CHANGED SINCE May 03, 1996 ISSUE ASCI Study ID# 5030-044-01 ----------------------------------------------------------------------------Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately ----------------------------------------------------------------------------- The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. Page of 4 MATERIAL INFORMATION TRANSPORTATION DOCUMENT DIViSion: BE - SPECIALTY MATERIALS DIVISION Issued: 07/22/97 Supersedes: 05/03/96 MITS Document: 04-3216-1 Status: Complete Material: FLUOROCHEMICAL AMIDE FM-4220 F-7604 F-7605 F-8005 F-8903 F-8929 F-8947F-8961 F-9391 ---------------------------------------------------------------------------- AUTHOR SECTION Status: Complete Date: 03/16/95 --------------------------------------------------------------------------- Div. Author: COOPER WIGGINTON Div. Contact: TAMMY JOHNSON Requester: KELLY BOELKE Phone: 520-6108 Phone: 737-4152 Phone: 736-4830 Comment: FX-12 (41-2600-8903-6) will be charged to the tank truck at elevated temperature (e.g.-,95-105C) and will be maintained at this temperature to keep it molten and facilitate easy drainage. FX-12 essentially has no flashpoint (e.g., it is >>>>250F). Specific Use: FX-12 MATERIAL TYPE: .....................S.O.LI.D. Type of Solid: .....................W.AX.Y.. Specific Gravity:..................1...7. pH: ..............................N/.A.... Tested for Flammable Solid: ..........N.o PROTECTIVE SERVICE REQUIREMENTS: Protect from Freezing: ..............N.o. Protect from Heat: .................N.o.. Requires Dry Ice:..................N.o.. STORAGE REQUIREMENTS: Store: ...........................I.n.s.id.e.; Outside Water Reactive: ....................No... Light Sensitive:...................N.o .. CHEMICAL COMPATIBILITY WITH PACKAGING MATERIALS: Polyethylene: ......................N.o-... Plain Steel: ......................Y.e.s .. Glass: ...........................Y.e.s ... Epon Lined Steel: ..................Y.e.s . Stainless Steel: ...................Y.es.. REPORTABLE QUANTITY OF HAZARDOUS SUBSTANCE: Reportable: .......................N.o... MARINE POLLUTANT HAZARDOUS SUBSTANCE: Pollutant:......................*....N.o. HAZARD DEFINITIONS: ASci Study ID# 5030-044-01 ---------------------------------------------------------------------------Abbreviations: N/D - Not Determined N/A - Not Applicable - 3H INTERNAL USE ONLY - Page 2@76f 2@@ 04'-3216-1 MATERIAL INFORMATION TRANSPORTATION DOCUMENT Page 2 ------------------------------------------------------------------------- AUTHOR SECTION (continued) ---------------------------------------------------------------------------- DOT HAZARD CLASSES (SOLID) * MEETS NONE OF THE HAZARD DEFINITIONS HAZARDOUS MATERIAL: ingredienis No Ingredients Selected ... C.A.S. No. Percent ---------------------------------------------------------------------------- TOXICOLOGY SECTION Status: Complete Date: 03124195 ---------------------------------------------------------------------------- Name: LARA ANDERSEN Phone: 612-737-0 KAZARD DEFINITIONS: TOXICOLOGY * MEETS NONE OF THE HAZARD DEFINITIONS ---------------------------------------------------------------------------- TRANSPORTATION SECTION Status: Complete ---------------------------------------------------------------------------- ID/Sample Package Description 41-2600-8961-4 55 GAL/220 LITER METAL DRUM Classifier: RAYMOND DUZYNSKI FCS A[C.FCC PSC Flash Pt 05/03/96 4 A53 A 41-2600-9391-3 55 GAL/220 LITER METAL DRUM Classifier: RAYMOND DUZYNSKI 07/22/97 4 A53 A 41-2600-8947-3 55 GAL/220 LITER METAL DRUM Classifier: RAYMOND DUZYNSKI 04/24/96 4 A53 A 41-2700-4220-7 55 GAL/220 LITER METAL DRUM Classifier: RAYMOND DUZYNSKI 03/29/95 4 A53 A 41-2600-8903-6 CARGO TANK TRUCK Classifier: RAYMOND DUZYNSKI 04/09/96 3 A53 A 41-2600-8929-1 55 GAL/220 LITER METAL DRUM Classifier: RAYMOND DUZYNSKI 09/18/95 4 A53 A AScl Study ID# 5030-044-01 ---------------------------------------------------------------------------Abbreviations: N/D - Not Determined N/A - Not Applicable - 3M INTERNAL USE ONLY - of 63/26/1998 3M EWIRONMEN CONTRACT LABORATORY LABORATORY WORK ORDER BY SAMPLE LAB REGLEST NO. U1463 REAUESTOR NAME: RE PURDY DEPARTMENT: 0211 FROJECT NO: 06 DATE RECEIVED: 03/26/1998 DESC: ET-FOSE BP and VP Determinations CONTR4CT LAB(S): ASCI E)(PCtM DATE: 05/3#/19?8 DATE COWLETED: FROJECT LEAD: RE PURDY PHONE NO: 3k FAX NO: 612-778-61-76 Bottle labeled: REX N.R. ETFOSE Alcohol See FM-3923 MSDS Tare - 97g J. Eberlin 53-6S-02 61691-16 Do vapor pressure under GLP, detervnineboiling point as part of VP study. ------------------------------------------ ------------------------------------ SAMPLE DATE CODE . DESCRIPTION RESULT MDL or (95% C.I.) ------------------------------------------------------------------------------- 1 03/12/98 EL*-FOSE ASCI BDII--PT-E *EOCUILIBRIUM ECOILTNG F,OI!4T ASCI VAF*-PRESS *VAPOR PRESSURE CONTRACT LAB DATA UPDATED DATA _2@.f e33 Page ASci Study ID# 5030-044-01 21 '4 DATE: 03/26/1998 3M ENVIRONMENTAL LABORATORY CONTRACT LABORATORY WORK ORDER BY PARAMETER LAEC REGUEST NO. U1463 CONTRACT LAB : Asci, PROJECT NUMBER : 06 SHIP'DATE : Computer Code Test Name--------- PROJECT LEAD: RE PURDY TELEPH(1%4E FAX 612-7-/(3-6176 Sample Numbei-s ------------- Sample Available Date -------- Result Due Date --------- BOIL-PT-E EQUILIBRIUil r(DILINGPOIMTI VAF,-PRESS VAFOR F'RESC-URE 03/2'Xlfl-9?8 s!512711998 03/27/1998 05/27/19S9 Page ASci Studv ID# 5030-044-01 ChainofCustodyRecord 3M Environmental Laboratory Form 35176-PWO 3M Facft Er)\Ljob Add ss 9'e- -3E0-9 13L5-BL)s@i i4\/ LIx 1 6751ilq ,5v4-ayA). Samm" BV (PIW) cor4mclor 12jecLCl-I S@ r ture 07041 3M ProledTklo FT-r-ost- 4. bT-?6sA- V.SPtL).rAx ciftContect 3M T*Woiom NLirnber '778- 5-3 ZI - Number Containers e ofeach so vas ithm L) 2 3 Sample@ Description Date Time m latrix oz I 3 4 5 6 7 8 3M R"U*SW -3V,-rA 13P VP Le IL Samples SplitS Con 10 11 12 13 Item ASCI St @elinquishedBy/Affiliation Time Date Shipped Via ReceivedBy/Affiliation t a-.tI-bfj,,(,)t.gn;otfjr See ASel Report#044-VP.R3M ASci Study ID #5030-044-01 APPENDIX C. Test Item Receipt and Usage Sponsor Study [D# U1463 et Page d@l of ASCI COrPOmtiOnIASci-Duluth EnvironmentalTesting Diviion SOP No.: 'SUB.01-R Reviewer. -V TEST SUBSTANCE RECEIPT AND SHIPPING FORM jnsftuctioFnisk.c*opyofcomplaedform (bothPans I & ii)in thestudyfik. PART.1- Test Substance Receipt Substance: Study IID#: (Write forour study Tea SubstanceReceived: -2>12'V and Number of ContainersRomived: Weight of Containerand Test Substance: WeightofTestSubstanc(eifprovided): Transportatio(ncheckone): Datod Initialosf Receiver 57ti W lY-f- amp on of Labeland Other InformationThat Came With Test Substance: L@ IL4LL3f Substance Lot No., Bat,@hNo., etc.: q ty/purity: (checkone): .......... Solubilitiyn Water. e Locationand Temperature: ginalMSDS and MailingReceiptsFiledin Notebook: Yes iesOf MSDS and MailingReceiptsFiledintheStud File: Yes 4- Color lq7Q ffectiv1e/:1998 Paged:@LO, T jc iv ASCI Study ID# 5030-044-01 ai2. Page -)q Page of 4 of 5 AScl Corpomtion/ASci-Duiuth Fnviran@meaW TcstingD-tyLsion t SOP No.: SUB-@2-U Raviewer. t4 q A =T SUBGTANCE USAGE FX)RM lashvctioris:A copy of thisform must be filedin theStudY File- ASCIStudyID# 5030-044-01 OART I-Test Substance @ate TestSubstanceReceived: ype and Number of s Opened : I & t Sponsor. IVA AScl Study ID#: 5'0 SO C)( -01 Dated Initialosf Person opening Container(s): V-VV w f TPA..' )Sticae q S/I0 ]@. "p - /f TestSubstanceLot No., Batch No., etc.: kRT ]I-TestSubstanceUsage Ug .......... ....... 157@ t+oIts"f5v FCV4- 4.q L 13.1410 5. 6. 7. Effmive: 1/lggg So Pag of-Zi" Pagg@L O(Il Nge 4 of 5 ASci Report #044-VP.R3M AScl Study ID #5030-044-01 APPENDIX D. Raw Data Sheets Sponsor Study ID# U1463 Page@3 I OL Date: A vst: VAPOR PRESSURE DATA SHEET StudyID#: ASO, Corporation/Asel-Duluth F.n,im,m,ntalTcstingDivision ci --- TestItem: .. ........ 0 'zU Lt 13-3 3 C> -01 I-z 4ik3 3o irl(s7 k 513 -2 191 671 0 0 3cl9'3 . -303 ot Notes: qq, o t Y04 -L- 0 cisq i4w3 1024"f, 6?31 I LA bi 13,7 t 3 18'Lio-k'33 iA5-1 -3-3Li,3S7 -@-5o,gs- @3 i?,tiy- 0 -7-1 c/-3o-z3 C9 o v 3oto oo 0, -SOW a ppa 133.3(Pm,,) b TeMp. (-K)= 273.15+ Temp. (*C) 7:@ -Z /,,ti -0, 4clq -O,Clqv o c- 2@l Ir o,oos-i-t- 3,57-3-3 3 -As,- 0 i-Iurl Page ]@ of DateAnalyst: at t A-celCorponaion/A&I-Duluth F-nv'ronmcGtATial4ing Diiio. VAPOR PRESSURIE DATA SHEET Study ID#: S77-,>4 -to 14Lt-0 Testitern: A 14J@(O 7 row 7@7q7,3 -7',Zr22 q,013,3i3 q- q-5-ItT q(tq. q 44t1iq I ;T 0 10 o -z/:F-Z- 0 100 Z/3 ------3-- qq 9 1S3- qLi 160 -Z-zz, otoo 19,ft331 Notes: Pp.,= 133.3(Pn.) b TeMp_ (*K) = 273.15 + Temp. C) Page@@,f Item P(mm) P(Pa) L.o0(P(Pa) Toluene 47 64 77 100 124 6265.1 8531.2 10264.1 13330 16529.2 3.796928 3.93101 4.011321 4.12483 4.218252 12.6 1685 32266 ,-2.2:04:)<@@;,/ 3*.468 3817.8 3.582 36.88 4915.6&/ 3.692 150 19995 4.300921 128 17062.4 4.23204 110 14663 4.166223 77 10264.1 4.011321 52 6931.6 3.840@33 1607.2 121@,2- e@282@8l.1 35.8 (@447777@11.3 3.206 3.4515 3.567 3.679 U1463 42 5598.8 3.748079 55 7331.5 3.865193 67 8931.1 3.950905 81 10797.3 4.033315 96 12796.8 4.107101 0.00188 0.000479 0.00745 0.0114 0.2506 0.6392 0.9936 1.521 -0.6009 -0.1943 -0.0028 0.182 93 12396.9 4.093313 83 11063.9 4.043908 68 9064.4 3.957339 48 6398.4 3.806071 37 4932.1 3.693032 0.00127 0.00335 0.00528 0.00821 0.1692 0.4461 0.7043 1.094 -0.7717 -0.3506 -0.1522 0.0392 woommoNWASCI T(C) 35 41.2 45.5 51.2 56.5 10 20 25 30 61.2 57.7 53.6 45 38 10 20 25 30 T(K) Irr(K) 308.15 314.35 318.65 324.35 329.65 0.003245 0.003181 0.003138 0.003083 0.003034 283.15 293.15 298.15 303.15 0.003532 0.003411 d.-Ci6 -3-3& -4 0.003299 334.35 330.85 326.75 318.15 311.15 0.002991 0.003023 6.00306 0.003143 0,003214 283.15* 293.15 298.15 303.15 0.003532 0.003411 0.003354 0.003299 r--0.999 a=0.00515 b=-0.000501 r--0.998 a=0.00512 b=-0.000496 174.6 179 187.2 190.2 197 10 20 25 30 195.8 191.6 188.2 176.4 172.2 10 20 25 30 447.75 452.15 460.35 463.35 470.15 0.002233 0.002212 0.002172 0.002158 0.002127 283.15 293.15 298.15 303.15 0.003532 0.003411 0.003354 0.003299 468.95 464.75 461.35 449.55 445.35 0.002132 0.002152 0.002168 0.002224 0.002245 283.15 293.15 298.15 303.15 0.003532 0.003411 0.003354 0.003299 r--0.988 a=0.00335 b=-0.000298 r-0.994 a=0.00331 b=-0.000287 Study ID# 5030-044-01 Page 3@ of