Document vyaYKOeDRmM6y0pLaag4yXRpZ

r\ rfjUAJ/STo*) & I'i XOKJJTO CtaOCXL COMP JIT AWirraf, ALABAMA. STA^SAU KAHBTACTUalNQ PROCXSS roa BXPHKSTL Eg Data: Saptaabar 17, 1957 Praparad by: X. L. Hadvortk Suparrlaor; Jack Clacorn Production Supc: J. I. Crouck fTd *4 L"" Cf iUf. jitA /?/. '>/' s.j DEFENDANT'S EXHIBIT Q 7_ f? -'4 J. <4 DSW 048614 MWV 018257 | WATER PCB-SD0000050463 r-'\. *.;> * : . u > J '* *5j i , V-> ` x- .. j-.i sr V> * r. ,. te.3 x-t c.-* pm*-* - :Amr \ t.^^-r5 iv fast. r^- azsiaucrzca List 1. Director of NamrifCurinj - Ortool Chaadcala Blriaioo SU L. kincklor a. s. obuf 2. Annieton Plant tienagar - 0. >. Soar 3. Production Superintendent - J. X. Crouch A. lipfconyl Plant Suparvieor - Jock Cl oxen 5. St. Louie ieeaarch 6. SC. Louie Baaearch 7. Technical Carrico Department - ieni Jton Plant S. Standarda Department - Annietoo Plant 9. Standarda Departueut - Annliton Plant 10. Extra Copy ! v w* .** P^ :-K*S? xr--. m4~ m mzk fF*1& *v#i m v* & DSW 048615 Ss* MWV 018258 WATER PCB-SD0000050464 '4c^ M' '*i gs clibiWtwsi ' ; v jhu1 X-iioexciloo Coocor - 3t. !. (8) tvMftrit? Fiio ?. S. fvti*ur - 6. 0* J. i. L'&lUi i. s. K**fe a. i>. s.woajaoo ?. a, *rsx>'a ra Jtx* (j> )>Utf tu4or4o (Bxtroo) OCKMUff aszsxoi, mwu sa ji a TgfrTTft fcSBfcnSgT S >ggra retro au-aacrasw ?mcto Of 17 Sc? 57 22ZU* "oat AcitCM *o froaotar la Sifhoayl Tubular talc. oajscimi -*>< MiUit ^nrfliM far a six aootb Cut af tbo ooo of Aootsoa M o prwetor la Uo tlpbaayl Tufeolar tait (imiii rastarracncit Layro?ar. a! la praooatly uJ u ta freuttz to holp ooo*rt racsara caiaai Aootooo yjali bo ea5otitut*4 for Iooprwp<moi. laltiol tact a14 bo with lor Q'Hof irtoo oi4 oMtloclool.y iwlptf UoC to >i>in pTMtacloc lorIso ofintao imho Ipfropcnl. bug Un Coot will bo etrrM Mt tai abort ton toot oooilxao pro*loos flofiafa, . WATER_PCB-SD0000050465 k-M'. ; J i *f Xh -- V ' '; . wm wrtstl -.1 'lewnitaant S 7easyi huaufactur in* Procaaa ifo-ila C7 SiT-.t 1. TS9 Proxx^ea 1*',ort 37di298, Bo. 1, yi Jua 4 - Aaalyala of Statistically dealguod taat data tLowa Isepropaaol increases Its effect oa sosraraloa with ictersaaias taaparataro. Pyrolysis mi XPA forms Acotoaa at fsraaca conditions which la a battax promoter thas I?A. 2. Baaaana Tyrol/aia la a laboratory Tubular Baaoter - Bapart Bo. 2772, S Apr 61, by X. 1orach, A. Z. Li^pasa sad W. 9. Koelaaoa. ;1iae promoters triad tfith Acatona bast and Iaaprcpaaol aanoad boat. / 3. hlpbasyl, Tubular Process, deport do. 2491, 23 May 30, b7 J. B. Sauadera aod B. J. Slocoabe. Aaatoea found to ba effective promoter. A. Plpbaayl froe Baaaaaa, 7ia*l Bapert 117-881, 5 Oat 35 by C. Conover aid A. B. Buff. Of 17 promoters triad, Acatoaa baac and Xaopropaaal aaaood boat. itArm 1 Bo additional pracautioaa are aaadad for uiinx Acetone aa tba proaeter. Tha abort taro dnaa taatiag vlll provide tba proper grouadiuj aceaaaarlaa to aaaaxa aafa fcaodllug of tba Aaatooa. 3W ,,# Xsiatiaz apac oa Aeetoae abooa laaa tbaa 0.0031 Aeetls Aaid vhlah abaold oat iarxaaaa aaxroaioa. Water coataat is about 0.21 which should oat appreciably increase Aaatia Aaid foreatlaa. Lcag tana taat vlll ohaak this. Or.M^TT; The eaa of Aaataea abaald have ao affact oa the quality of 1lphenyl-gaatouaa predated. ****** 07 PPQgTBATIOll The taat period will ha six aonths. % -% Of3 \ WATER PCB-SD0000050466 INfe WATER PCB-SD0000050467 m 731R&AVX KSietEM SO. S TO 1SX 3TAgw,in) KiAonciziua r*zu~i*4 rot &XTCT3C. <*?t. 17, iiSIT) Xacoad 9 Joa a Ts> t 7. X. Modulo X. C. Moody _ l. c. rjhaMlatar ' 3. o. muw s5-i2fr.lv. / D. Daaa. - S. 0. r ftr* t;. B. lummr - 0. o. 3&W ^ - L* ***** - >. 2* '*- iE ^Va* w* fc*5TM*!1 - ^ *C*atral Tachalaal Vila - So, Sod Tootiu? oi Soui-Coaclc. jo Siatlllatloa of Cruda llphoayl i iaca^lot*. Sm Cruda llyhoa/1 Dlatlllatioa bfart Xa. 570s2o!V dut^A 1 Jul 6k for oufUoa of Cha coating program. Xu WLtmai.au of tha normal a lx noatha aooaptaaca or rojoctloo parlod fur Xoatatloa laaa froat B la rogoaaead. Should you havo aay ot.joatloa, plaaaa 1*6 IE ho known by 7 dag 6t aa thla it cha ud of tha alx aoath parlod. %Mr miu OSW 048619 i. i) t i 5* ,.t` U xi I J, _,* 'i ** MWV 018262 c. WATER PCB-SD0000050468 ,-]h SUUrlhutioet samr unn cowami Technical, Xaioraetloa Center - It. X* (2) Security File D. B. EoMt - 0. 0. j. X. MeSlala 8/ O.D.C. 2-7-64 I. C. Moody M B. 0. Sereraoe B. C. Sprague 2-7-64 TCB File (J) Plant Standard# (Xxcraa) CONFIDENTIAL MOBSAHTO CHiMXCAl, COtUTt ABVUTOB, ALABAMA 29 Jaa 64 TPUTIVB A1BKPT P i- KA.TAIN IN H Ei To BIPTirart STAXQASn KAHDFACTPBIMC PROCESS n Of 17 Say 37 TITLSl txstibg or SDa-covrmooos distillatiob or cxodc izpbbirl. 9HKIFt= Thin aaandiaat caacela Tentative Aaentaont C aad provide# for a iU month coat of tool-coatlauooa dlitllUtloi of crude Biphenyl to yield peclilcatloQ grade Biphenyl aad Bipheayl "free* Saatoner C. ItZZZXZ PMCTiai *-&3 Crude Bipheayl waa foraerly purIflad By batch dlatlllatloa. Tentative Aaaatoaat C allowed tha teetiag of coatlauoua diatillatioe. Coatlnuoua dlatlllatloa did aot yield Bipheayl "free" Baatomx C and, therefore, a teal-coatlaaooe diatillatioe of Bipheayl la carried oat at preeeat. The at11 la will be fed oe the eighth tray free the top of the coloaa cootlaaoualy oatil the atill pot ftlla. Thee a Celia fraction will be renewed leering llphaayl "free" tint tinea C to be traaefarred for further purification. J05TI7ICATI0H: Seal-coetiawoua diatillatioe iacraaaea prodactloe capacity aad yield# a higher purity Blphaayl thee that of batch diatillatioe. ,r daia; . Sea TSD Prograaa Report 370:26, Bo. 2, aatlelod "Coetiauoua Diatillatioe of Crude Bipheayl" for detaila on aeei-coatlnuoua dlatlllatloa. DSW 048620 MWV 0l8263 ^^p WATER_PCB-SD0000050469 Taatatira Aawtwat D Blpbaapl Haau/aatarlag Procaaa -2- 2) Jm64 Ho s&ditlooal pracautiotu ura uuM for ai-coatlaooua diatillailoa tkN *** ot bate* diatlllatioa. mm: Saai-coatiaooaa dlatillad Blfbanyl ku a bighar cryatalllatag potat mad a lovar color (Cardaor acala). zxTErrt cr ppaotcTTATioti; Ttaa Laat parted will ba ala aoatha. K7?tavja.t Dapartaaat Soparrlaor: - ^ Production Supawlaor: Plaat Maaagor: ^ laaaarch Maaagar: Raaaarch Croup Laadar: Origioatad by_ r. I. Haapt B. 0. Srraraoa R. C. Mdbdp / \J. MeClaia 9/ R. t. Hubbard H. 1. Hubbard 9/ D. B. Hoaaar D. 1. Hoaaar 9/ R. U. Buc'caall R. W. Buckaall -If 7____ ' Data 'Data ' 7/3/^4- Data 2/6/fi* Data 2/U/fi* Data _ ____2^T/fi* Data .... DSW 048621 <A yjs MWV 018264 WATER PCB-SD0000050470 f 'jr ^-i .. t - **:-z*MX'k t >/. - f *V<r -.A - - <_.tf riait!* iHMi'imAi Lj- . t.. . . : m: % *1/!) i'J. MONSANTO CHEMICAL COMPANY i^.#c % /MS L9CAHON t 9 OAT* *\ i Aauiatcn, Alabaaa March 18, 1963 c c. bL.UfCT i Bateauton of Tooting Parted yp, - `."A ~a & jr>V .1 y:^e*-TlV3,Tt|t ` AtPIftKMCC TO 1 nnrcArrfi tx.&Mnx ho. c to tu STAifcARa JUiTUPACr>JRZi* PRUX88 /OR BIPURTL (Scftaubnr 17, 1957) Anaadvent C laaaad 10/12/62 J. X. McClain C. Moody J. C. Larkin E. 0. J. 7. Seieilary - C. 0. 0. S. u^Mir - C. 0. a. L. Hobbard - So. 2td W. b. RobIn*oa - So. Sod Contra! Technical Tilo - So. 2nd -- T' ,3fc4.*" j % V : .**5 m n Delay* la laatallatloa aad production raqulr--anta have canoed a delay la the conflation of the Coatlnnona Blpbaayl Dlatlllatloa Scud/. Thoee taata aada to data have boaa highly aucceaaful, bat bar* boaa htaparad by continued aacbaalcal problana. Aa axteaalon of tba normal alx aontba accaptaaca or rajactloa parlod for Xaatativ* Aaendnant C la raqueatad. Should yon have aay objection, plaaaa let it ba kaovn by April 15th. Thlo data la tba aad of tbia a lx aoath parlod. TRRtfcd R. Haupt^ v-Zt'T* ? 's?j rJ '. r. ^ V il'M 1 rr\ ih io 0SW 048622 MWV 018265 WATER PCB-SD0000050471 -v> \ k 'f* /p. t ^w. *-:^:: v ,ijg.s^y%. -.4 V ^gr- fr` CONFIDENTIAL .s.vrrrr ktitw co*irrxs Master copy signed by hI->ty Ciaaltcee l0/22/62 cc: J. *. HcClai* X. C. Moody J. C. Larki* B. 0. SmrMt T. 1. lUi*t D. >. Ht*r - C. 0. a. L. Hubbard - So. 2ad V. 9. koblasoo - So. 2*4 Caatral Technical 1'lla - So. iad 3. F. Stlekley - G. 0. MDBSJUfTO OUMZCa C09AMT . AJUilSIOM, AlAiAHA %< October 12, 1962 -ZKKTm ammphwi ho. c TO THE STANDARD HANOTACTURIMP FROCESS rot aiPUZHTL Saptsaber 17, 1957 TKST1HG Or CONTINUOUS DISTILLATION OF CRUDE BffHUfifL. This naandwant covers tha Casting of continuous distillation of crude Biphenyl Co /laid apacifleation grade Biphenyl aad Biphenyl "fraa* Santowax C. Crude Biphenyl la presently purIf lad by aaaaa ox a batch dlaclllatloo. Four fraction# ara reaoved; baasana, baada (bensaae aad Biphaayl), Blpbaayl, taila (Biphenyl aad Tarpbanyla), and Santovax C aa raaldua. Tha baada aad tails fractioo* ara racyclad froa batch to batch. Tha tost will bo carrlad oat la tha two axlating dlaclllatloo colxaau. Tha first celaaus will aaparata beniana aa orarhaada aad Blphaayl, Soatowax C aa bottons. Tha aaeond coltma will produca Blphaayl ovarhaad aad Saatooax C as bottaoa. Tha apaclfle goals of this cast ara: 1. To pxova the faaalblllty of producing apaciflcatloo grada Blphaayl on a continuous bail*. *: t * m MWV 018266 sfg; WATER PCB-SD0000050472  * *' 'rjtt ' Ml*# WATER PCB-SD0000050473 Siena k SYSOPSn or P20CZ5S liphacyl la produced by the pyrolysis of Baas*a*. Tho process used la too nsnuf-ccuro of Zipkeayl la rnnncnly known aa tho Lead Pee Proeaaa. The equipment consists of a vaporiser coll, three staialesa ataal lead filled geo fired pots and two fractionating columns, all la aeries. Baasol la continuously vaporised in cha vaporiser coil sad heated to the pyrolysis taparaura ai it la bubbled through the moltan lead in the three pots. The uareacted Benrol and the reaction products. Biphenyl, Terphanyl and Bydruga peas through two orifice plates sad into the stripping col tan. The super heat in the gsa drives the uareacted Bensol up the coluan, with the Bydrogan, where it Is condensed and returned to the feed tank. The Hydrogen, saturated with Bensol, is coolsd and conprassed to renova the raaindsr of the Bansol. This Bensol is recycled through the process with fresh Bensol. The underflow, flows by gravity to a exude Biphenyl storage tank. The units era oparatsd between 10 end 301 converaion by regulating the con- end S10C. The higher tsnpereturee giving The pot pressuree rang.i fron 60 to 100 psig on the No. 1 Preheater, to 30 to 70 paig on the converter. The higher pressures are encountered when the unite are nearly plugged. The crude Biphenyl, which is approximately 75Z Biphenyl, 1SZ Terphaayl, end 10Z Bensol is charged hatch-wise to a fractional distillation unit and the Biphenyl is distilled off. Haet for the distillation is provided by cir culating the charge through a coil In a gas firad furnecs. Pour distillation cuts ere made: (l) s Bensol cut, - Co recover cha Bensol that wee left in the underflow fron the first colunn, (2) s heeds cut which is a mixture ei Bensol and Biphenyl, (3) a Biphenyl cut end, (4) a tells cut which Is a mixture of Biphenyl and Terphenyl. The haada and Calls cut srs recycled to the next distillation charge. The still residue, Santowax C, consists essentially of Ortho, Mete, and Pars Terphenyls and certain higher boiling eoopouade. It Is ptaped to storage for non in tho Saatowax X procase. MWV 013269 WATER PCB-SD0000050475 WATER PCB-SD0000050476 C-.J -f T>. SECTION C EQUIPMENT Thera ara 12 Biphenyl units of approxlnately equal capacity. Each unit conaiaca of a pipa coll vi"orlser locatad in tha flua gas exhaust stack, three stalnLasa scaal pots partially filled vith molten laad and suspandad in a firebrick setting for burning natural gaa, and a fractionating colu vith a condansar and split flow box. Tha pots ara 24" O.D. x 72*' long, with a dishad bottoa. Tha units ara nuabarad 2 through 13, thara having baan a No. I unit at ona tiaa. Tha prasant nuabar of units ware erected in five installments. Nos. 2 and 3 having been erected at different tines, Nos. 4 and 5 together. Nos. 6, 7, 8, 9 and 10 together, and Nos. 11, 12 and 13 together. These groups are all slightly different in some details. There are, however, only two fundamentally different types of units. Nos. 4 and 3 differing froa the rest in that one of the preheater pots is repla-.ed by a shell and tube heat exchanger. Although the hast exchanger effected a gas savings as predicted, it proved impractical due to carbon and tars fouling tha tubas, and the idea was abandoned on tha subsequent units. A larger converter pot (sojourn pot) has been Installed on No. 11 unit to provide additional sojourn ties. This additional ties results in a lower temperature for a given conversion as compared to the other units. Tha heat Input to the unit remains at a maximum and this extra heat is utilised by the addition of more Benrol feed tr the unit. The reduced pyrolysis tas^aracures made possible by the largsr pot result in: 1. A 10*151 production increase, 2. Reduction in gas consumption per pound of Biphenyl produced, 3. Reduction of pot failures and maintenance cost, 4. Reduced carbon formation, thus permitting better operating efficiency of the unit, 5. Reduced lead carry over has been observed on the unit equipped with the sojourn pot. . Drawings which describe the equlpemnc used In this process are listed in Phosphate. Division Engineering Department Report Mo. 117. ' DSW 048628 MWV 018271 WATER PCB-SD0000050477 WATER PCB-SD0000050478 Monsanto Chemical Company OFtGAMlC CHEMICALS OIVSIO* ANNISTON, ALABAMA PLANT RAW MATERIAL SPECIFICATION MATERIAL. BENZENE - NITRATION GRADE C M EMJ CAL FO NUU L A **ooucr coce 14700 MCTHOO IDENTITY (ASTM D-835) Issued Sept. 11, 195? STA_NHMLDS DEPT. Anniston, Ala. Plant *vj ca a App. 1952 lAwauf ron ANA^y^i) 2 x 16 oz. nn Bottles UNCLASSIFIEH $PECIFICATIONS W. B'. Dunlap # MOL. WT. 78.108 GENERAL- TESTS Appearance / ' Acidity Acid wash test Color Crystallizing point Distilling range; 100% over in Range to include Specific gravity; 60/60f 25/25C Copper corrosion sulphur compounds Total sulfur ASTM METHODS Clear liquid with no free water or suspended matter * No free acid Barrett 2 max AFHA 25 max 5.30j?C min. wet basis 5.39C min. dry basis D-847 D-848 D-853 D-852 D-850 80.lc (Using Bunsen Burner) 0.8820 to 0.8860 0.8740 to 0.8780 Negative Free of H2S and S02 0,020% Max. D-849 D-853 D-90 OSW 048630 MWV 018273 WATER PCB-SD0000050479 " Movsakto Chemical Compact ORGANIC CHEMICALS OlVISION ANWSTJN !>[..AN`r RAW MATERIAL SPECIFICATION MATR| AL __________ .Lead. CHEMICAL FORMULA ' L>., |PRODUCT CODE 1 ...- - AA^F1-!... TItV 1-----------------------1 SUPPLIER I ,, . ,, ,_ I National Lead Lo. SUPERS 0 ES SPECS. OP SAMPLE FOR ANALVOS ___ Npw_________________ ____________________ -Sept*. 11; 195? STANDARDS DEPT. Anniston, Ala. Plant By >v. B. Dunlap MOL. fT, 2 0". 21 unclass:;- :r:.- spfc:fk:at;o Lcnctui 1Vn* ; y: - u i A".il . As Ci; (-:} Bi fc) Zn (ft.) Fe {^) As, Sn, Sb (%) ' Cc {-:i) Co, Ni (*/.) ooo C*. 0 0 Nc.*r?p c.cooi 0.0002 0.0002 0.004b Assay (% Pb by d l:fererce)99. 92 I H 1 i H fl Basis of Spec ification: Suppliers typical anaiyrir cf p.-oducf (5 Zii/rib} DSW 048631 1- M ; l i-i- /' ' yfc jf; V .' _ <' \ ' i nl^Lniii.3feh*a..* Jii ~ .Ift. l llS .1 U --V. -fc . JL %fw^' -?. **-j-`>#; . :--.V.-%^V% ^=f'-:v?^Bte33,4g*:9 SKTZOII 1 PiuXZdf m CCT&ZL lLZ^2Slii Bipkoayl h** It* aoaufccCnxed by tka load pot procooo alaca 1913 at daalatoa. The precaa* ta aaeaadaiiy tka *aaa a whaa it vaa Lrat developed. Tka aaly varladoa balag tbo aaa ei' a caavaraiea preaetar cad a kitbag eparadag praeaora. Proto*a lavsaeigadea ha* pcimtad oat aaay of tka Tariabloo vklck affaet tko predoedea of Blphaayl cad tko by-predace Saatawax. 7oc la*toco. It kaa booa docorvlaod tkat a balaaco batvaaa Xlpkoayl aad lutwwr preducdoa caa bo aaiataiaed ovar a tide raaga of roqulroMBta daa to tka raladaaahlp bataaaa tka porcoac coavcrjloo cad tka rolctivo aaeaat of llpkaayl to Saatoaox pradaced. Tkat raladoaitkip balag: 1.053 (x) (Parcaat Caavaraiaa) Percoat Saatawax (Tarpkaayl) 1* tka crude Blpaoayl Tka 1.053 la r oferred to * tko ilpu (!) factor. Tkla algaa factor roaalaa raladvaly ceactaat over.tko eparadag raaga of tka procaaa, caaaagaaatly. . It vaa pooalblo to doralop tka Bipkoayl oparatloa* chart which kaevo tko rolatioaaklp botvoaa Bipkoayl production, Scotevax preducdoa, tka parcaat eeavoraiea, and tka Baaaaaa faad rota. Aaotkar lapertaat davalepocat la tka aaaufactura of Bipkoayl vaa aatabllh*iMt of tko rolatloa botvooa tko parcaat coavoroioa aad tka aejoura daa at differoat eparadag taaperaturaa. Thla ralatloa brMgkt akaat aa evalaadea of epdmaa aejoura tlaa which raaaltad la a largar caavortar pot. caaamly kuna aa tka oojoara pot. (oov balag daaaaotratod) aad a klgkar oparatlag praaaura. Both kava poralttod lacraaaad food rata* aad lavar oparatlag tooporaturaa far a glvca ceavexoica rata. TUa actual ralatloa bataaaa tcaperaturo, coavoroioa aad aajoara r< -- kaa aot boaa datandaad.wkaa a eoavaraioa proaotar la aaod. Tka aojoara daa, taparatara, parsaat caavaralaa chare la praaaatad to pletarally chew tka gaaaral ralatloa of theee faatarc. To aoaaarlaa - tkroa factor* offoce tka aaaaae of Beoutaae tkat la oaavartad par paaa tkroagk tka ault, tkay aro: (1) tauparatara, (2) aajoara daa aad. (3) tka aaaaae atoa praaatar. Tka raladva osouat of llpkaayl pradaadaa ta Saatavas prodactloa caa ba ciasgad 07 ckaaglag tka parcaat eaavaralaa. Tkat la--at kigk caavarnloe rata* uera paaado of Saateoax ara produced par paoad of Bipkoayl tkaa at aaaa lover coavardaa rata. Tka caavaralaa rata la cawtrolled by ckaaglag tka ta^aratura vlckla tko poea. rte V- >h H tXi pi "Vs h MWV 018276 S'fv WATER PCB-SD0000050482 tm- 1-2 7n.su Baasel l* added cooticoolly to Aa food (uk froa Aa Booiol stnijt tank, I**pr3pyl Alcohol la .adod to Aa B mol fa<l la aioouata varvla* Kafir'-* trTM 1 ,T uTil~i-o praaota Aa -ovr< n- ( riiMinri) Baraslly 0.15X la adfravi ca Aa5e**ol aa it ia puaped through automatic eoatrel vulvea to Aa Individual uait*. Aa faed Aa* paasas through a call la Aa botto of tha colam^>vtxara Aa liquid 1* prana* Cad. aad ta a call la Aa flua gaa arh.vjat *cack,vhcra Aa liquid Boaaol ia vaporised. Aa Boaaol vapor 1a bubbled through aeltau load ia U* baa preheater ul caaraartar pata where it la heated ta Aa pyrelyala raaetioa taaperaturo. After leaviag Aa ceuvertar, Aa Beaxs.1 and ceanrersiea prodoc ta paaa through a load trap far fin-lag eatralaad load aad thorn aactt Aa betteu of Aa fractlomati ag coluua. Aa tauparatora la Aa couvurter pat ia usually coatrelled batraaaa 750 - U0*C. Aa topuratura seeded for Aa daulrad ceuverslea Aoagaa aa Aa pota bagla to plug vita carboa dua to Aa klghar praauuraa aad raaoltlag loagar aojoura tlaa ia Aa pota. t tirit 0 4`, t 1 \j Ev*cy 30 to 90 daya Aa carboa ia physically cloaaad froa Aa diatrlbutar aad vapor liaoa. (Sea attaAad tail a for food rataa, reflux, ta^oratnraa.) Aa aupr-hoat la Aa vapor a froa the coavortor la utlllaad ia a fraetloaatiag coluaa to offoct a partial aaparatioa af Ao Baasel froa Ao coavoraloa products. Aa coluaa top la aaiscalaed at a ta^eratura of 100*C (at highar tsapora tor eo a cm Biphonyl bogies ta com over) by rofluxiag tha ceadaaaed Baasol vapora bock to Ao top plata. Aa units ara usually oporatod wlA a 60-701 raflux, wlA 901 boiag aat aa a aaxiaua. If 9CX reflux dooa aot cool Aa vapora, leavlag Aa tap plata of Ao coluaa bale* 100*c, Aoa It la aacaaaary to reduco Ao food. Aa ceavaraiaa product aad iom Baaaol la coadoaaod la Aa coluaa aad allowed to overflow froa a carboa trap oa Aa bettaa of Ao coluaa to a crudo Blphaayl catA taak far atoraga prlar ta bacA dlatlllatioa. Ao ovorhood vapors froa Aa coluaa ara ceolad ty a caadaaaar aad Ao liquid Baaaol dralaod to a rotowalr for aplittlag Ao flow iato raflux aad recycle Baaaol. Ao recycle Boasel flow* to Ao Beaael food taak by gravity. Ao by-product Hydregaa, oacuratod wiA Boaaol vapor flars froa Aa coadeaaer aad rotawolr, ia collected ta a enm hoadar at a prosaura of appraxlaataly 3 palg aad paaaaa through a a arise of coolers where ism of Aa Tv-rtl la coauoaaad. Ala Baaaol ruas by gravity bach ta Aa food taak. Tree Aa coolara tha saturated Bydrogea goo ia paaaod to a collecting taak la whlA ora of Ao Boaaol coadoaaoa out aad dralaa to Aa Baaaol puap task. Ala puap taak la locatod la Aa ceapresaor room, sad poriodlcally Ao Baaaol la puaped to Aa Boaaol faod taak. Ao Bydregoa froa Aa coll<icti<ig t*A Is coaprcssad by throo 2-otago coas-.l praaaora, la par*11*1, to beCwuaa 250-350 prig. Aa eyataa laalados aa latarcoolar aad aftorcool k for c*odoaalag Ao Baaaol vapora. This liquid Baaaol ia cellected la preeaura recalvar a afcar aach stage* Aa Baaaal la poriodlcally blowa by tha Kydrogaa pressure over late Aa pup taak for return to Ao Boaaol fjed taak. Ao ftydrogaa ia uaod la tha aaaufsstaro of 13-40, IB-20 or vsatad Co Ao ataesphoro. DSW 048634 MWV 018277 WATER PCB-SD0000050483 f II** fzi STj. VJJ* m ' -'V-J Pmcaca 1-3 Xa the aacead type unit (.tea. 4 aad 3) the flew at material la oaeaatlally the mm a that described shove (accept the vaporised Baaaal toad anarglag from the vaporiser call phases through the shell side at a haat auhaajar la 11m ef aaa of the preheaters. The conversion products end Tt-r-1 Croat tka converter pot aru passed through the tubaa af tha haat orrhaagar, counter current ta tha Baaaal feed, thus transferring sensible haat fra* tha con verter gases ta preheat tha food. Tha eaTaraiaa products aad vapors fraM tha converter pat thaa paaa aa ta a caliMi,aa la tha eaaa with tha athar salts. Tha underflow fro* tha eelunas la call actad by gravity la twa crada Biphenyl catch taafca. Tha plplag to tha taaka la ataaa Jachatad ta provaat tha crada Biphaayl, which la approximately 731 Biphaayl, 15Z Tarphaayl aad 10X Baaaal, Croat fraaaiag aad haa a liquid trap ta prevent vapors Cram catering tha catch taaka fvww tha caloaa. Tha taaka ara vaatad lata tha lydregaa gas haadar ta equallaa tha praaaura aad pravaat laaa of Baaaal. Tha crude Biphaayl la poped directly to otto af the- twa batch Biphaayl etilla. Tha two watch atilla each caaalat af a horisoatal, cyliadrical tank surmounted by a fracdoaadng coluam, a submerged puap aad a gaa fired call heater. The atilla ara operated at atmospheric praaaura. Tha pop circulator the atill charge fro tha teak, through tha cell heater aad back to tha teak. Tha rata af tfiatlllatleu af the crude Biphaayl la eoutrolled by tha caebuatlae rata af natural gaa la tha gaa flrad heater, which la controlled by aa adjustabla aatoaatic temperature recorder aad controller ta haat tha crude Blpheeyl uffidaatly ta give a taaparature rlaa af 15-25*C between the ialet ad outlet ef the coll. The vapors from the adll are separated la e 20 plate fractioaatlag coluan. The flrat cut from the celuma la Beasaae. Thla cut la takae at a top plata vapor tnaperature of 60*C aad at a reflux rate ef 20X return aad BOX forward flew. The ?e*aae flows by gravity to a~cateh teak lor aubeoqueat recycling through the Biphaayl unite. The next fraction, distilling above 90C, la taken uadi the fraaaiag polat of tho diadllata reachoo 66.6*C. Thle cut la called the head cue and oaaalata af a mixture af Benaal aad Biphenyl. It la node with 30Z *f the notarial being returned ta the celvi aa reflux. Tha Biphaayl cut la taken after the fraaaiag point af tka diadllata ri 6t.6*C and la continued until tha pot teoparatura raachae 330*C. Thla cut ta nada with a 20X reflux. The tali cue, at 13X reflux fallows tha Blphyl eat aad la continued until the diadllata on tha tap plata reaches a teoparatura af 300*C< Thla cue canalate af a Mixture af Biphaayl aad Tarphenyla. Occasionally it la acceeeery ta make s cue af Material balling between Benaal and Biphenyl which sccuaulates la the system. Thla material, usually about 30 ta 30 gall ana, la collected la a dnn end dlecarded. Water la drculatad through tha condenser at the tap af tha frecdaaadag column during tha dlsdliadoa aad la cut heck at the end of a dledlladea la order ta keep tka condenser 1'ren fraaaiag. $ * :k I DSW 048635 UBMJJFI MWV 018278 WATER PCB-SD0000050484 -.T 4fc| A* luCivu C, raaalalag la tha atill u raaldua coaaiadag aaaaatlally i Ortho, Meta, and ?*r* Tarphaayla wad cat tala hi{bar bolllag coaponada, la pf*l t* tha tatowu C utch Cask W thaa ta tha Iitiau a till, lutiwu C a Corago Cask, or imto druaa far ataraga. Blphaayl la atorad for lacaraal aaa or flakad for aala. Ika taaparatara of tha ataraga Cask should aot arcaad 90C aa higher taapcratvxaa uill caaaa dlacoloratloa. A eoavaatloaal vatar cool ad dm flakar la uaad far flaklag Blphaayl. Bo taaparatura coatrala ara macassar/. Ika flakad Blphaayl la la papar kaga or fiber druaa. Charta Tit. 1 - Shava tha tkaoratlcal B 1 practica at varlau parcaat Pig. 2 - Shows tka aomthly Blphaayl aad Jutovn prodoctioa rataa at varlaaa parcaat coavaraleaa hatvaaa 2,000 aad 3,(00 gallaaa par hoar of Baaaaaa food. Tig. 3 - Shava tka pooada of Bydrogaa produced par powad of Blphaayl at varlaaa parcaat coavaral'oaa. * rig. A - Shava tha pouada of iutam "C" producad par pauad of Blphaayl at varlaaa parcaat aaavaralaaa. rig. 3 - Shava tka parcaat coorvaraioa that caa ba azpactad at dlffvMt raactloa ta^oraturaa aad varlaaa sojoura tlaaa. rig. 6 - Show aaathly Blphaayl producdaa at varloaa parcaat aaavoralaaa batvaaa 2,000 aad 3,(00 gallaaa par hour of Baaaaaa food. rig. 7 - Shava tka o**veralaa bdmg ohtalaad aa tka ualta aa ladlcatad by tka apaclfle gravity of tha roadaaaad vapara paaalag ta tka ealMa* DSW 048636 MWV 018279 WATER PCB-SD0000050485 ------------ Vi-irS ^ <vxo\ - w-* iUie-i J5> '. v.. i T^r] /: _:J l/r^ A ------------ / nAH---------- ~ -------- / ^rO- / ff- /> .... . -f. lA^i-xi-J iiu- - ip ii .. iy: : 2g: : 30: '. n ~ * xr /v /p>; . j " .: . > *i * ^ ^ - . ' . ..._L_1dIx-K ;d-f~ .fi . .I ** . __ * !~~+ : ~ " '*%>* r"'* J SSS osw MWV 018280 WATER PCB-SD0000050486 WATER PCB-SD0000050487 V' -- - i \ t f S o-n. h a u i % - * MWV 018283 OSInl 048640 WATER PCB-SD0000050489 WATER PCB-SD0000050490 WATER_PCB-SD0000050491 /o Con ye i '/! TYPICAL BIPHENYL UNIT OPERATIONS . . c->oo** 4- 1 O "dmax ' XSTxrag s<Or soO scCm 3q3fupTH 3 *auod *4 o wa* 3 CO vO CM ^>4 9inSS91^ 2U32 p?3 OcO CCMS oo ----------------------------- ------------------ 2oo | i CnM C<Oo OCM ,M sCOM OCM CCMO cnn Q1 GO GfO4 CO r- <* CO1 sO vO4 CO s*--Ot O CTs CO r- in s*o4 cCOO O*C4M COHM OTC-M ooH CCMO COOs rr^ Oo JI3no IT0 m ;rezpjodA 3 Ul SvN*OT s*4 S4 or* X ovO M o0<*0M <inMr 0o suei bo J33F *! dnms 3 no puoo oOs -- m^4 to * dTHSJ m sriTi X *S3J< *09lS00f) CmM CCMO VroT4c4>4> CU>11L04>. OgO i H -T CcmO *rC>M-r CVMT ` - 3SU?* *M XO 0*C1U4O) cu HS Or- *o>r SOOO cOcmos 0T4* 04MX440 .5o5 a. F3 Do *cluX uxsc'TOD % #:iq/ *T*2 0r-9* <Ninr CCOO CU"Oi O m s0O0 JNO4* Or- 2.x OSf4O CCMO it N rC'Ci Orr- vsTf vCCOMO soO OOus cCMc soo b w oCr"O4 C-o4M COfOO CO CfMO vOO i.--n1 0C13#04 CCIOOrt CU 1 L5 i34eU) Occ ItOo Cr^-O4. mOCMt 5CM0 cCCMoO <c*pr -jsS;' SOO rC*O. sVCOOO Or- <sor oCO or* OCnM sOcOM OCOS C*OoM *oT oSO -Ors*T- SOO ssoOO COO CM 3 scOc scoc CtC--MO4 3CM rCsOj 3O IO Osr*O. sOO svOOO nr-- C004 Tr--^.. COCMO GC>MO4 CCO x oC*v 05 OCp--O c5o siPnoM or-*- OP>MT 05 OOs tCCOMM CM CM CO oicn-*> 4C 0C5O Ocrc oO sssO^f 'oO co 3 r* soO OCCMO n- CM CM CM X2 icCnoM . 3fM srOs PM swOO on rb4O a. op-** Hu4O51 oo ^Mc tM ^ 1 ' -q -^o PsS> "vc4b3<ol wn obN3co ^^><4s -uO0uVt3 .I -- If s1 . ' j| CM r* CCr-MO^ CMC O 413c0Js MaC ,-j^V0uu36a>9u0) --3X2c6o2n-0-v4^-J--nv--oxs4-J &OU-K S4o3J 1 j1 oo Or*M- n TCa*t *6W0 AJ M s~ 1 'O - ^rM i s0o0 oin oVoO iionn .(0u"M>COVi lCHOMO3O.OCNuM0* M*130 U:) Hs n4rVJt O*iJOocSmvcOnvcT^m 1 roo4 oo m rM Or-- OOs oGO --swc, * hi O M* -gJ- , 54d3rJj Hr-i. 2O= B -nN4oSC4)it-O4TU6cO<0----*H0UtV3cn----C-M--c-o- ^ 1 or 3TUH f-4 r~ N ro T o so p*- CO Os HO ^r44 p.--n o MWV 018287 WATER PCB-SD0000050493 section r CCHWOTTS ON THK PROCESS Ic has beea established that a higher conversion caa ba obtained at a given temperature with all fresh Bensene feed thaa with all recycled Beasaas feed. Tha frash Banaaaa has baaa postulated to contaia a coovarsloa promoter which is used up as tha Baeaeae is pastad through tha units, accounting for tha 1 over convarsioa with rscyclad Bsstaaaa. To alinlnata tha fluctuating convarsioa a level control has baaa provided la tha feed tanks to continuously add frash Banaaaa to tha recycle la tha faad tanks. Conversion Promoter Tha actual meehealsm by which isopropyl Alcohol promotes conversion is not known. It is baliavad to sanslciza the Baaaaaa tc tha formation of Blphaayl and Tarphanyl by incraaalng tha rata of frao phanyl radical formation. Isopropyl Alcohol Is only oaa of a aumbar of products which saasltlaa tha Banaaaa. Isopropyl Alcohol was chosam bacausa of aconoad.cs. Otbar saaaitiaars ars 11 scad In Rasaarch Rsport No. 117-681 by Ruff and Conover, datad October 5, 1935. ' Lead Levels Tha land Is adjusted co a 25" outage In tbs No. 1 Preheater, a 30" outage in tha No. 2 Preheater, aad a 35" outaga la the converter whenever these pots are opened for inepeccloa, cleaning or repaira. These outages tucva beam found to ba optlnejm with respect C. lead carryover aad heating of tha Baaaaaa faad. Laad Dross Occasionally laad drosa will contaminate tha laad aad raise tha maltiag tsmperature. When this coataadnatioa occurs tha lead la tha top of tha pot la dipped out aad frash laad added. Water in Baaaaaa Peed Water la draiaed from tha Baaaaaa faad teaks sbout every two hours. If this water is permitted to eater tha units, it will causa a suddma surge is pressure aad rupture the pot flaaga gaskets. Higher thaa aoraal temperature sometimes results from a thermocouple failure. Wham this condition is eacouatared car boa is formed. This carbon plugs tha distributor aad pipe Unas. . DSW 048645 - t t a ? r ) T-2 Benzene, the major raw material handled in tha Biphenyl Dopertmeat, la a flamnable liquid aad ita vapors fora axploelvc mixtures vich air. It praaaata a fire hasard unleaa proper care la taken in storage end handling. It poeaaaaea a high degree of toxicity. Continued Inhalation of low con centration# nay cauaa serious, even fatal blood change*. Tha liquid, after prolonged contact, nay eeuae defatting of tha *kin resulting in denetitla or secondary infection. Benzene can be handled, shipped, and stored aafely, provided the personnel handling the product recognise tha hesarda and are thoroughly familiar with the necessary precaution*. Soma of the principle pre'autlons era: (1) Keep awav from sparks or open flame. j (2) Provide adequate ventilation. (3) Ground all containers and equipment beforn dischargn to reduca danger from atatlc electricity. (4) Avoid inhalation of Benzene vapor. (5) Avoid akin eonca.-t with Benzene. Hydrogen is e highly inflsanable gas which form* expletive mixtures with air. In area* where Hydrogen is handled #r stared, every effert should bn made to prevent sparks or liras of any kind. Biphenyl en^ 'Untovax iTerpheavl) - Both Biphenyl end Sentewex have a vary low order ef toxicity. These products era not Co ba taken internally or maintained in contact with tha skim, eyes or ether body parta. Biphenyl haa a flash aad fire point of 1O60C and 124*C respectively. ;*r St II DSW 048646 MWV 018289 WATER PCB-SD0000050495 SECTION G PROCESS CONTROL PROCEDURE Sample* ar# taken frem Benzol tank car* bafora the cars art unloaded far a freezing point determination. Freezing point a the Benzol nuit be 5.3C minimum. Sample* of rha gaa leaving the Biphenyl coavarcara are takaa daily and the coaveraion rata determined by apacific gravity. The percent caaraaraiaa la regulated to produce the required amount* of both Blpheayl and Santowax. (Sea Chart Fig. 7) The percent coaveraion 1* regulated by changing the converter pat temperature. The converter pot ia uaually operated at a caparature of approximately 780C to give a coaveraion of 15-17X. The temperature required to get thia converaion change* at the pot* begin to plug vith carbon, eauaing lncraaaad aojourn tine due to the increaaed preaaure. No. 1 and No. 2 preheater* are uaually operated at approximately 490C and 670*0 raapactlvaly. When the preaaure on No. 1 preheater pot raachaa 100 lba. the unit la ahut down and cleaned out. At thia point the preaaure on No. 2 preheater will be approximately 80 lba. and on the converter approximately 60 lba. ' The unit* are uaually operated with a 60-701 reflux, with 901 being aet aa a maTlum. The reflux cool a the vapor* leaving the top plate below 100C. If 901 reflux doe* not cool the top plat* vapor* below 100C, then it i* neceaaary to cut Che feed. Biphenyl freeaing point* are u*jd aa a control point for the Biphenyl dietillacirrr cut. The freeaing point la to be 68.bC minima before this cut ia taken. Typical batch data aheeta are attached. DSW 048647 MWV 018290 WATER PCB-SD0000050496 S3T 1 7 3fORM MCC * . M MONSANTO CHEMICAL COMPANY ANNISTON. ALABAMA. PLANT FOR 24 HOURS BEGINNING 7:00 A. M. ' 6-13 Biphenyl Oper ________ _19J2L OPERATOR S.B. B. -- ij rtxD rLOW Il TIME RAT* I =- IBOX 1 COLUMN !SET-& TEMPERATURE. DEGREES CENT. !f!i BUMP ;iCONV'R NO. Z P.H. NO. t P.H LINE LEAD LEAD LEAD i; LINE No. 1 S PRESSURE POUNDS . ! '1 FEED j NO. i NO. 2 : COO**j*| Hi * ? ** : Ij| PR EH. J PREH. co y *cetr ,.2, d ji 215 }j5-t3 II >* 3 l| i 1 78 198 743 690 ! 495 ii 164 ! 95 | 67 1 57 ' 42 i 27 II 68 1 200 743 580 1 493 it || i i J .J 1 |! 11 I -- 12 !1 T 2 3. i ii 11 il 1 1 ii l! 30 Ij 80 j 82 1 84 173 740 678 183 j 742 678 178 | 743 650 1 188 743 j 678 ti 182 j 746 ; 680 111 i 493 I 493 | 493 | 497 1 500 1 1 165 i i i ! 164 i j 94 11 1 j 93 f1 : 162 J_96 !. i i 65 . j 55 i 40 ' 25 !! 71 1 I! 1 i! i 90 - I pr* Zry I 9 9 ] r<+ ao > *a I r ! i : i! 1 ---------------------------1 : 66 57 I 42 26 :! 73 1 : 1 REMARKS:/ enrol tvabeck temp. #2-78, #3-80, #4-64, #5-45, #6-49, iZ=*8f #9-72. #10-44, #12-74. OPERATOR- TrtiJ.tt 4 215 5 9 7 Tl i: I85-15 ! ii "1!|iI ! 1 Ii . ii 90 88 89 80 78 | 205 182 198 193 190 91 i io i Bu] 75 189 740 740 | 740 | 732 ! 730 i | 735 i | 675 1 675 j 672 1 662 '660 668 REMARKS: NO. 2 SI 492 495 m 468 468 1 1 j 475 1 { f 164 MIf ji 164 I ii 164 [1 Ii i 165 1 ! 96 95 j 66 j 1 66 i 58 L. ! 58 i i 1^ |42 j 25 !! 74 j / i I. . ' 1 jj_ _ 1 1 i; 72 l i i; 96 l 1 166 ----------- 1j----5--8------ 1 42 25 Ii II 72 .. 1 !_ j 92J 68 58 42 25 r2 11 i! OPERATOR Horton 12 215 i 85-15 75 I l! M ! 2 j T ' j 77 3 Ii ii i 77 * '! :i i 78 I s 8 ij j ; 76 1 77 7 i| ii REMARKS: j 190 738 665 1! 198 738 662 193 738 660 185 740 668 J 182 740 | 668 186 740 j 668 1! 470 165 94 | 468 | 165 95 468 | 1 165 95 475 ii 478 li 165 95 ii i NO. 3 Sb 68 57 68 57 68 57 68 ; 58 1 42 j 25 i| 70 .1 . =1 ! 42 i 25 ! 70 6 6- 1 ! _ i 43 J 20 70 6< i 43 ;26 ; 70 1 6f 1 ; MWV 018291 WATER PCB-SD0000050497 ny! Operating Record NO. I SHIFT UNIT NO.. CHIEF OPERATOR T--C.-K. 1 COOSC 1 H, IN l Hi OUT l jwATCT i NECK | ... ! 3-4 1 1 ' 2 3 " A ! IN t NfN. i63 : 65 ! 34 43 1 17 32 ! 26 30 if!! ! 11 WATCH OUT i! ! z ! 3 I4 MEASUREMENT < 30 1 30 I 30 |i 3'10" ; 1 * 3** I! COM PR. it !f OK ii 71 ! 70 ! 33 46 22 hr --^ I' 35 1 28 ! 32 !! CO > -**<%. i! 7Tr 40 46 49 36 iI cAyA i 34 ii i I !ii i -ZfiJi 73 | 71 i 40 45 ;26 36 ! 30 I 34 ( 32 32 34 34 ! 34 32 ifeh*.steel l'6"i! GK ;! i L J** ,'!!| A v1 inti Sr* 4m i"in !iiil ! !i ve* 341! 1*0" I 2'i>rt 44. *12-74, #13-68 Water press. 60 lbs. CONVERSION SAMPLE TIME CONVR. TUMP. NO. 2 P.H. TEMP. BP. GRAVITY AT TEMP.. C. CONVERSION 12:QQ.-- 745 ... 680 *05 31 ,, 16.3 ?LUE GAS ! OK No. 2 SHIFT CHIEF OPERATOR McSulHcm 125 ij 74 | 72 41 ir^ ! 47 | 26 j 37 ! 30 j 34 34 34 | 34 jj Mty i III!! 3.6 J OS |j ^5 !! 72 ! 72 I 38 f ii i i i 25 i| 72 | 68 1 35 46 241 36 29 | 34 i 34 1i 44 | 21 | 32 j 26 j 30 | 30 34 | 34ij Mty ' 1 i! 30 j 30:; 1.0 ' j :1 1 j! 1! !i , ! f 25 72 67 34 43 , 20 ; 21 | 25 j 31 30 29 | 29 1.3 j 4.2 ! : | Mty :l CSC '! :i jj -OK i>1 Mty :| OK ' i i II: i N0-3. SHIFT____ CHIEF OPERATOR. Adcock 25 j 70 ! 68 j 34 44 i 18 32 24 30 j i !: : 1 !| i1 25 :i'70 i 66 j 32 44 j 18 30 24 29 ill ! 1 ! ! l i 26 | 70 | 66 | 34 44 i 20 32 24 30 ii i iL 1 ; ! i; !! 26 ii 70 I 68 ! 34 44 | 20 | 32 26 30 1: !! | ! | 23 28 28 j 2-0 II 29 28 28 2-9 i 30 28 23:1 3-5 1. 1: 30 29 29 4-0 ! i' 1-3 OK OK 1 1-3 jj OC j 1-3 ! OK Raised conv. 20750 TIME CONV'R. TEMP. NO. Z P.H. TEMP. BP. GRAVITY AT TEMP.. C. CONVERSION 12:00 738 665 0888 32 14-0 FLUE GAS MWV 018292 DSW 048649 WATER PCB-SD0000050498 Charge: BIPHENYL DISTILLATION RECORD Operator StartedOperator Finish. Started Charging Still at- M- C.UM. C.S. 5:30 ?.K. .Shift- WATER PCB-SD0000050499 SECTION H STANDARD COST SHEET DSW 048651 |lMONSANTO CHEMICAL COMPANY Jpffooucr----------- .Bip.hcnyZ------------ PRODUCTION COST STANDARDS Anniston .fVANT QZWT. NO-- _ 1Julyc^ncTivc dati - 1957 _% capacity___ ?> 1QQJWQ lbs i _INVENTORY STANDARD 2.100.000 lb 3. > YIELD ON -H COST UNIT-Am* 1QQ Iba, INVtMTOHY cost S7.211 g*f*T(TY *15 WAlt r*e *# L* AL iiftiT SS** '! 10QS0 Tcon-ronvl Alcohol ! ii 14700 Benzol' i i! 38400 Lead i> ! 1 ]j ? '650 _ 06231 1331770 ; 200 i. 05250 18100 i 040 7 023 036 i ! ii ii if] i ! 11 . OIWCCT C O N V E R S IO N CO ST MAW MATERIAL WAREHOUSING B MAMDLtNQ [GROSS TOTAL MATERIALS fjj CREDITS Jj 7 099 j !!. 8.28el/HydroRan ii 825 3 SanEovsx G ;i TOTAL CREDITS '{ NET TOTAL MATERIAL* 1510 26!670 110000 i03320 .051 ___________ li_42Z ___________ (523 5:576 !j i! r. :j ' MATERIALS !] STEAM Jj ELECTRICITY !i COMPRESSED AIR T WATER.PURCHASED .[ WATER.PL-ANT sMONTHLY PRODUCTION BRACKETS \1 1J** 050,000 lbs. 5 1,575. 000 lbs. ;l 2.100. 000 lbs. !| unit COST j S 5 5761 AMOUNT ? UNIT COST I 58548 1 5i 576 1 AMOUNT 87822 i| UNIT COST j j 515761 AMOUNT 117096 fi |COST (-- jj 0681 714 t ! 068 1071 1 068! 1428 ^ Q49i ____ 315 ' 049 _______ ZZ2 J____ LCA9i _____ 1029 ____ i} i '! i _____________i____ !____ 1____________l! 2 011} 116 i Oil 173 i '011! 231 1 j{ 0831 872 i : 083 1307 j i 0831 1743 1 j| FUEL-CAS. COAL. OIL jj RETRiaCRATrON a ICE Jj LABOR jj 3281 3439 j 1328 ;| i 1! ' 2251 2365 II i 265 5158 1 i 328! _____ 6878 L________ i 4183 199 4183 -_--_-_--_- 1-------------- 1 ; supervision 9I; S. S. TAX * COMP. INK. PCM . |* ; repair*,equipment 0581 031! 4291 610 327 4500 [039 i 033 i 406 610 527 6400 i02 1021. Laai. ,6m. 527 80QQ- REPAIR*. BUILDING 004| 44 ii _44. lOQ2. _44_ 0341 360 1033 520 L03. 720 LABORATORY 0071 72 1007! JM. 1007 .144.. ; CUJTHlNO a laundry t Tech. Service 001! 041! -10 1 430 100.11 : 027 j .15. 430 001 H2Q _2Q_ ilQ_ TOTAL DIRECT CONY. 11 369!. 14374 H353: -.1314 232]____ 25487 DEPRECIATION I 1781 1869 i 119! 1869 mi 7 869 r*CT*>v inOI*CCT EXPENSE 618: 6488 i 4121 648S 1309! 6488 - AMOUNT . - toti. iMoimcT coNv. j____ ; 796 8357 f TOTAL PRODUCTION COST OPERATING PERIOO 7!741- 81279 :i 30 =** 3 "i 953.0 1050 cHK/Mst^Cr-KJIU " _ `-ii _13'/ 25_ WATER rOMC M M _________ 12L- WATER.PLAN! Up* pXX. H i,*vnniroNv UnitsXW3^ .4.623. 144 8 I531i 8357 !398 8357 j 7:460? 117493 j 7i211 30 3 ...,rr. > 30 151440 ^ SHIFTS 1680.2 1680.2 1575 2100 630 840 L2M2- 26250 JL82. -2QQ2________ 1_________33A5_ L.208________ __________288_ MWV 018295 OSW 048652 - ..V>VS* WATER PCB-SD0000050501 WATER PCB-SD0000050502 A ** Movaatrro CasMicaL Commit | PMWCT eM OMOANIC CHMCALI MV)MO* I 20 Issued Jaly I, 57 1\ I MTHM I04MTITT FINISHED PRODUCT 3 es j iM.ta cooc STANDARDS DIPT, SPEC1FICATJON rmSHCT (TtmJm mmt) J 1313-K0-E-S9 TTP [Aanlstae. All* Tlut wa ^ BIPHENYL sosue r fCuaS** *>) TECHNICAL TTM ____________ qgHBHTL________________________HCffiSSAL____________ *r_M 0*MAC fOMMA m WMMIDI1 IMCI OF fUlLLi2_______ IHiVL smwis ran *M**rai WOJC,Aaaistea, 8*1-- _Plm_ca_jnoUii^ 2-p^ kt W UNCLASSIFIED SPECIFICATIONS Routine Tests Specifics,tic Test Ne. Appearance Colorless to pale yellow crystallised solid ar flakes Freesing Point (C) Coler (Gardner 1953) DistUlatisoi Range (1) (C, Corrected 1st drop - dry; NOTE: (1) Distiller!oas most include 255C wlikia tke range. Gardner 1953 L>1quid Coler Standards Using FIoorescent Lighted Comparator, or using Gardner-Helllgs Comparator, Cat* No. 430 Cat. Ne. 440-405Y Gardner Laboratory, Inc. Betheads 14, Idarylaad . r\\ & MWV 018297 W DSW 048654 WATER PCB-SD0000050503