Document qkwXXN3En7yNQx0wvXGRJRvQK

CWA COMPLIANCE EVALUATION INSPECTION REPORT U.S. ENVIRONMENTAL PROTECTION AGENCY, REGION 5 Purpose: Compliance Evaluation Inspection Facility: Hubbell Wiegmann 501 West Apple Street Freeburg, Illinois 62243 NPDES Permit Number: NA Date of Inspection: March 24, 2021 EPA Representatives: Ben Atkinson, Inspector, 312-353-8243 Jessica Stromsdorfer, Environmental Engineer, 312-886-3164 State Representatives: Joe Stitely, Inspector, 618-993-7213 Facility Representatives: Jorge Garcia, EH&S Manager, 618-710-8050 Mori Rand Danielle Sheahan Report Prepared by: Inspector Signature: Ben Atkinson, Inspector Water Enforcement and Compliance Assurance Branch Atkinson.ben@epa.gov Atkinson, Benjamin Digitally signed by Atkinson, Benjamin _______________________D_a_te_: 2_0_21_.0_5_.1_9_1_4:_23_:2_5_-0_5_'0_0'____ Approver Name and Title: Ryan Bahr, Section 2 Chief Water Enforcement and Compliance Assurance Branch Approver Signature and Date: Digitally signed by RYAN RYAN BAHR BAHR Date: 2021.05.19 14:45:50 _______________-_05_'00_' _____________________ I. BACKGROUND The purpose of this report is to describe, evaluate and document Hubbell Wiegmann's ("Hubbell" or "facility") compliance with the Clean Water Act (CWA) as observed during the March 24, 2021 EPA Compliance Evaluation Inspection. Hubbell is a producer of electrical enclosures located in Freeburg, Illinois. The facility opened in 1964 as the E.M. Wiegmann Company and expanded multiple times through 1989. Hubbell Inc. acquired the E.M. Wiegmann Company in 1994. The facility works primarily with carbon steel, stainless steel, galvanized steel, and a small amount of aluminum. Hubbell is a indirect discharger that discharges to the Village of Freeburg West Sewage Treatment Plant (National Pollutant Discharge Elimination System Permit IL0032310). The facility is a Categorical Industrial User and falls under the Metal Finishing Subcategory with the effluent limits listed in Table 1. Table 1: Effluent Limitations under 40 CFR 433 The facility has had multiple Zinc exceedances over the past five years. The facility's zinc effluent exceedances are listed in Table 2. Date 7/22/2020 7/9/2020 Jul-20 Feb-20 12/19/2019 Dec-19 May-19 Table 2: Zinc Effluent Exceedances Sample Value mg/l Limit mg/l Limit Type 3.23 2.61 1-Day Max 6.88 2.61 1-Day Max 5.05 1.48 Monthly Average 2.5 1.48 Monthly Average 7 2.61 1-Day Max 7 1.48 Monthly Average 1.9 1.48 Monthly Average 1 Hubbell Wiegmann March 24, 2021 II. INSPECTION SUMMARY Due to the COVID-19 pandemic, the inspection took place in several parts. On March 18, 2021, EPA held a virtual opening conference. Included on that meeting were Ben Atkinson - EPA, Jessica Stromsdorfer - EPA, Greg Sanders - IEPA, Jorge Garcia - Hubbell Wiegmann's Environmental Health and Safety Manager, Brian Donovan - Hubbell Inc.'s Director of Environmental Health and Safety, Paul Pepler - engineer with Brown and Caldwell, and Mori Rand - engineer with Brown and Caldwell. We discussed the facility's operations, self-reported effluent violations, wastewater production, and stormwater management. I ended the conference by requesting a list of documents from Mr. Garcia. We also discussed the COVID-19 safety protocols that would be implemented during the on-site inspection. On March 24, 2021, Ben Atkinson and Jess Stromsdorfer (EPA) along with Joe Stitely of IEPA toured the Hubbell Wiegmann facility. In addition to the facility tour, we had a brief opening discussion and closing conference with Mr. Jorge Garcia, Mori Rand, and Danielle Shehan. The following topics were discussed during the calls and site inspection. Facility Description During the virtual opening conference, the facility representatives explained that the facility makes electrical enclosures (essentially metal boxes for electrical equipment) with an NAICS code 332119 for fabrication which includes sheering, punching, forming, welding, paint preparation, and powdering coating. The facility works primarily with carbon steel, stainless steel, galvanized steel, and a small amount of aluminum. The facility employs approximately 284 employees working 2 shifts Monday through Friday and a half shift on Saturdays. Normal operating hours are 6:00 AM to 4:30 PM. The facility representatives explained that the facility receives metal in raw sheets which is cut with shears, punched, formed, and welded. The products are then prepared for powder coating by being passed through one of three wash lines. The wash lines are called the JIC, NEMA, and large parts washer. "JIC" and "NEMA" each refer to professional associations which developed technical standards for electrical equipment. They are the Joint Industry Council and National Electrical Manufacturers Association respectively. The primary difference between the lines is the size of the boxes. The JIC line produces boxes 12 inches or less in size. The NEMA line produces boxes 12 inches to 36 inches in size. The large parts washer prepares anything over 36 inches. The JIC and NEMA lines are four stage parts washers. The stages are cleaning chemicals, water rinse, rust inhibitor, and water rinse. The large parts washer is a single stage washer that cleans and seals in one step. The facility representatives stated that the parts washers are the only source of process wastewater at the facility. Following preparation, parts are powder coated and then baked. Once the products have cooled, they are packaged and shipped. The facility representatives stated that there were existing floor drains throughout the facility that 2 Hubbell Wiegmann March 24, 2021 had been sealed. EPA was provided with a piping diagram (Attachment 3). The facility representatives stated that since October 2020, in response to the effluent exceedances, the facility has not discharged process wastewater to the sewer. The facility began operating the parts washers in a closed loop and closed the valve that would allow the wastewater holding tanks to discharge. Once the wash water is no longer viable, the facility has a waste hauler, Illini Environmental Inc., remove the spent wash water for offsite disposal. The facility representatives stated that they are in the process of assessing the causes and possible solutions to the zinc effluent limit exceedances. The facility representatives stated they believed the zinc exceedances were possibly due to sediment at the sampling location and were exploring ways (such as installing baffles in the holding tanks) to increase sediment removal prior to discharge. The facility representatives stated that they hoped to resume discharging as soon as they were certain they could meet their effluent limits but intended to continue to have their wastewater hauled away until that time. Prior to October 2020, the parts washers had a constant flow of fresh water to the rinse stages which resulted in a continuous discharge. The cleaning solution and rust inhibitor solutions were periodically discharged. The facility representatives stated that there was no flow meter on the discharge to the sewer. Stormwater The facility representatives stated that the facility had a no exposure certification for industrial stormwater. IEPA was able to confirm that they had received the no exposure certification on August 5, 2016 and that it needs to be resubmitted every five years. Sanitary Wastewater The facility representatives stated that all sanitary wastewater entered the discharge pipe downstream of the process wastewater sampling point. EPA was provided with a piping diagram (Attachment 3). Sampling Procedure The facility provided a copy of the sampling procedures that had been used prior to October 2020 (Attachment 3). The facility did both a grab and a composite sample. The composite sample was a time-based composite composed of three aliquots collected one hour apart. Effluent Exceedances The facility was aware of their effluent exceedances and stated that they were actively investigating potential solutions. Site Inspection EPA and IEPA arrived at the facility at approximately 8:50 AM. EPA presented credentials and held an opening conference. Following the opening conference, the site inspection began. EPA began at the north end of the facility at the JIC wash line. EPA observed the four-stage parts washer and associated wastewater holding tanks. The facility personnel pointed out newly 3 Hubbell Wiegmann March 24, 2021 installed baffles in the wastewater tank which were intended to increase solids settling to help address the Zinc exceedances. The holding tank was empty and not in use as each stage was being operated in a closed loop. EPA observed the parts exiting the parts washer, excess water being sucked off by an employee with a vacuum, and the parts entering the drying oven (photos 1-12). EPA also observed a floor drain that had been sealed off. EPA then walked to the sampling point for the process wastewater and observed the sampling well (photos 13 and 14). EPA then walked to the NEMA 4 stage washer and associated wastewater holding tank. Again, new baffles had been installed to increase solids settling and the tank was not in use (photos 15 and 16). EPA observed the use of overpack drums around chemical barrels. EPA observed the parts traveling through the washer and into the drying oven. EPA also observed the NEMA powder coating area. EPA then walked south through a packaging area and observed the facility using a two-part foam-in-place packaging system and overpack barrels used for chemical component containment. EPA continued south and observed the two-part seal extruder used to place weather seals on enclosure doors (photo 20 - 22). EPA continued south through the manufacturing area and observed drip pans in place to contain fluid leaks from manufacturing equipment (photos 23, 24, and 34). EPA observed an open door on the west side of the facility and observed a small building located between the main building and the warehouse building. Facility personnel identified the building as the air compressor building. In the air compressor building, EPA observed an air compressor with a leaking condensate collection valve (photos 25 and 26). The floor of the building had an oily layer on it with what appeared to be a flow path to the west side of the building (photos 27 and 28). On the west side of the building there was a hole in the side of the building at floor level. EPA walked outside and observed that the hole was covered by a piece of material on the west side of compressor building. No liquid was observed flowing out of the building at the time of the inspection. EPA also observed multiple plastic tubes connected to a condensate collection manifold. One of the lines was leaking with the leak dripping down to an overflowing5-gallon bucket (photo 29). The collection manifold ran to the east to an oil water seperator. EPA observed liquid trickling down the exhaust pipes of the oil water seperator and flowing off the concrete pad (photos 30-33 and 72). EPA then walked back into the main building. EPA observed a barrel of deionized water that is used for cooling the spot welders (photo 35). EPA walked south to the single stage large parts washer and observed the washer and sump pit which collects the wastewater from the washer. Facility personnel stated that this sump pumps water to the wastewater holding tank at the JIC washer (photos 36-42 and 9). 4 Hubbell Wiegmann March 24, 2021 EPA walked west and observed a former paint booth which is now used for individual parts washing on occasion. The paint booth had a sump pit which, the facility personnel stated, pumped any wastewater to the sump pit of the single stage washer (photos 44, 52, and 43). Along the west wall, EPA observed a metal tank with a pipe running from the bottom of the tank through the west wall. EPA walked outside and saw the pipe terminated, uncapped, outside the wall. The facility personnel identified the metal tank as a holding tank for the deionized water used for the spot welder tip cooling system. EPA also observed what appeared to be a cooling tower along the exterior wall. Facility personnel identified the cooling tower as part of the closed loop spot welder tip cooling system (photos 45-48). EPA also noted several pipes, some cut off, penetrating the west wall. EPA walked outside and noted the pipes entered a small building to the west of the main building. Facility personnel stated the building had previously been used for various purposes but was now only used as a storage space for chemicals (photos 49-51). EPA then walked back north and observed the solvent dispensing booth with containment and grounding (photo 54). EPA continued north and observed the chemical storage rack which held empty used barrels, waste storage barrels, and virgin materials barrels. EPA also observed an emergency spill kit (photos 55-63). EPA then began a walk-around of the exterior of the facility. The exterior walk-around began on the northeast side of the facility and proceeded west around the north end of the main building then around the west side of the warehouse. EPA observed used pallets and a sump pit in a recessed loading dock on the west side of the warehouse (photos 64 and 66). EPA walked east along the south side of the warehouse and observed a pipe protruding out of the east wall of the warehouse. EPA entered the warehouse and observed a sump pit to be source of the pipe (photos 67-68). EPA continued north along the east side of the warehouse then south along the west side of the main building. EPA observed a small building north of the air compressor building which was being used for general storage (photos 70 and 71). EPA also observed multiple pipes protruding from the main building that terminated just outside the wall (photos 69, 73, 74, and 75). EPA walked around the south end of the main building then north along the east side. EPA observed the scrap metal bins with covers to prevent stormwater contact (photo 77). 5 Hubbell Wiegmann March 24, 2021 Closing Conference After touring the facility, we went back to the conference room for a closing conference to discuss observations and areas of concern noted during the walk through. We left the facility around 2:30 p.m. III. 1. 2. 3. 4. 5. 6. 7. DOCUMENTS PROVIDED BY THE FACILITY Process Flow Diagram MSDS sheets Illini Environmental explanation of methods of disposal of hauled waste Wastewater Sampling Procedures Facility Piping Diagram Wastewater Tracking Manifests Water Bills IV. 1. 2. 3. 4. AREAS OF CONCERN The following areas of concern were noted during the inspection: The zinc effluent violations that occurred between May 2019 and July 2020. The sampling protocol used by the facility does not appear to meet the requirement for a 24-hour flow proportional composite sample as required by 403.12 (g)(3) and Appendix E to Part 403--Sampling Procedures. The leaking compressor condensate collection system in the compressor building. The several pipes that left the building and whether they have the potential to discharge. V. LIST OF ATTACHMENTS 1. Inspection Photographs 2. Arial Photo of Hubbell Wiegmann 3. Documents Provided by Hubbell Wiegmann 6 Hubbell Wiegmann March 24, 2021 Inspection Photos Hubbell-Wiegmann EPA Inspection 03/24/2021 All photos taken by Ben Atkinson, Enforcement Officer, U.S. EPA Camera: Ricoh WG-4 GPS 1: RIMG0001 Description: Looking north along the 4 stage JIC wash line and wastewater holding tanks. Location: South of the JIC wash line. Camera Direction: North Date/Time: 03/24/2021 9:36 AM Page 1 Hubbell-Wiegmann 03/24/2021 2: RIMG0002 Description: Stage 1 of the 4 stage JIC wash line. Location: South end of JIC wash line. Camera Direction: East Date/Time: 03/24/2021 9:37 AM 3: RIMG0003 Description: Stage 2 of the 4 stage JIC wash line. Location: South end of JIC wash line. Camera Direction: East Date/Time: 03/24/2021 9:38 AM Page 2 Hubbell-Wiegmann 03/24/2021 4: RIMG0004 Description: Mistake photo. Location: Camera Direction: Date/Time: 03/24/2021 9:39 AM 5: RIMG0005 Description: Stage 3 of the 4 stage JIC wash line. Location: South end of JIC wash line. Camera Direction: East Date/Time: 03/24/2021 9:39 AM Page 3 Hubbell-Wiegmann 03/24/2021 6: RIMG0006 Description: Stage 4 of the 4 stage JIC wash line. Location: South end of JIC wash line. Camera Direction: East Date/Time: 03/24/2021 9:39 AM 7: RIMG0007 Description: Parts after exiting the JIC wash line. To the right (out of frame) is an employee who vacuums exccess water from the parts exiting the JIC wash line. Location: North end of JIC wash line. Camera Direction: East Date/Time: 03/24/2021 9:41 AM Page 4 Hubbell-Wiegmann 03/24/2021 8: RIMG0008 Description: Parts after exiting the JIC wash line. To the right (out of frame) is an employee who vacuums exccess water from the parts exiting the JIC wash line. Location: North end of JIC wash line. Camera Direction: East Date/Time: 03/24/2021 9:42 AM 9: RIMG0009 Description: Wastewater holding tanks on south end of JIC wash line. The holding tanks are not currently in use. Note the recently installed baffles (red arrows) intended to increase solids settling prior to discharge. Location: South end of the JIC wash line. Camera Direction: Southeast Date/Time: 03/24/2021 09:45 AM Page 5 Hubbell-Wiegmann 03/24/2021 10: RIMG0010 Description: Pipe from wastewater storage tank to pipe conveying flow to the facility's sampling point and then to the sewer. Location: South end of the JIC wash line. Camera Direction: North Date/Time: 03/24/2021 09:47 AM 11: RIMG0011 Description: Another view of the pipe from wastewater storage tank to pipe conveying flow to the facility's sampling point and then to the sewer. Location: South end of the JIC wash line Camera Direction:East Date/Time: 03/24/2021 09:47 AM Page 6 Hubbell-Wiegmann 03/24/2021 12: RIMG0012 Description: Piping on the west side of the JIC wash line. Location: North end of the JIC wash line. Camera Direction: East. Date/Time: 03/24/2021 9:50 AM 13: RIMG0013 Description: Sampling manhole. Operator stated that all process wastewater is conveyed to the pipe at the bottom of this sampling manhole. Location: North side of the facility. Camera Direction: Down Date/Time: 03/24/2021 9:51 AM Page 7 Hubbell-Wiegmann 03/24/2021 14: RIMG0014 Sampling manhole. Operator stated that all process wastewater is conveyed to the pipe at the bottom of this sampling manhole. Location: North side of the facility. Camera Direction: Down Date/Time: 03/24/2021 9:52 AM 15: RIMG0015 Description: Entry into NEMA wash line. Location: North end of of NEMA wash line on west side of facility. Camera Direction: Southwest Date/Time: 03/24/2021 9:55 AM Page 8 Hubbell-Wiegmann 03/24/2021 redacted for personal privacy 16: RIMG0016 Description: Wastewater holding tank for the NEMA wash line. Location: North end of the NEMA wash line. Camera Direction: North Date/Time: 03/24/2021 10:06 AM 17: RIMG0017 Description: Part of the NEMA line powder paint area. Location: West of NEMA washing line. Camera Direction: South Date/Time: 03/24/2021 10:16 AM Page 9 Hubbell-Wiegmann 03/24/2021 18: RIMG0018 Description: Doors to NEMA line powder paint area. Location: West of NEMA washing line. Camera Direction: Southwest Date/Time: 03/24/2021 10:16 AM 19: RIMG0019 Description: "Sealed Air" two part packaging foam. Location: Packaging area in central part of the facility. Camera Direction: West Date/Time: 03/24/2021 10:19 AM Page 10 Hubbell-Wiegmann 03/24/2021 20: RIMG0020 Description: Two part sealant applied to enclosure doors. Location: Central part of the facility. Page 11 Hubbell-Wiegmann 03/24/2021 Camera Direction: Soutwest Date/Time: 03/24/2021 10:21 AM 21: RIMG0021 Description: Two part sealant applied to enclosure doors. Location: Central part of the facility. Camera Direction: North Date/Time: 03/24/2021 10:22 AM 22: RIMG0022 Description: Two part sealant applied to enclosure doors. Location: Central part of the facility. Camera Direction: North Date/Time: 03/24/2021 10:22 AM Page 12 Hubbell-Wiegmann 03/24/2021 23: RIMG0023 Description: Collection pan under machinery to collect any leaked fluids. Location: Adjacent to a brake press in the NEMA product line area. Camera Direction: North Date/Time: 03/24/2021 24: RIMG0024 Description: Collection pan collecting leaking fluid. Location: NEMA product line. Camera Direction: North. Date/Time: 03/24/2021 10:31 AM Page 13 Hubbell-Wiegmann 03/24/2021 25: RIMG0025 Description: Oil/water leak from air compressor in compressor building. Location: Compressor building west of the main facility and east of the warehouse. Camera Direction: East Date/Time: 03/24/2021 10:33 26: RIMG0026 Description: Oil/water leak from air compressor in compressor building. Location: Compressor building west of the main facility and east of the warehouse. Camera Direction: East Date/Time: 03/24/2021 10:33 Page 14 Hubbell-Wiegmann 03/24/2021 27: RIMG0027 Description: Oily residue and apparent flow path of oil/water leak from air compressor. Location: Compressor building west of the main facility and east of the warehouse. Note the hole in the wall at ground level (red arrow). Camera Direction: West Date/Time: 03/24/2021 10:34 AM 28: RIMG0028 Description: Oily residue on floor around unused piece of equipment. Location: Compressor building west of the main facility and east of the warehouse. Camera Direction: West Date/Time: 03/24/2021 10:34 AM Page 15 Hubbell-Wiegmann 03/24/2021 29: RIMG0029 Description: Compressor condensate collection pipe conveying oil/water condensate from the compressors to the ThermaPhase oil/water seperator. Note the overflowing bucket collecting liquid leaking from the collection pipe. Location: Compressor building west of the main facility and east of the warehouse. Camera Direction: East Date/Time: 03/24/2021 10:34 AM 30: RIMG0030 Description: ThermaPhase oil/water seperator located on the west side of the main facility building. Location: Between the main facility building and the compressor building. Camera Direction: East. Date/Time: 03/24/2021 10:38 AM Page 16 Hubbell-Wiegmann 03/24/2021 31: RIMG0031 Description: Wet area at base of the oil/water seperator which appeared to be condensate (from the exhaust pipes) flowing down the exhuast pipe. Location: Between the main facility building and the compressor building. Camera Direction: East Date/Time: 03/24/2021 10:38 AM 32: RIMG0032 Description: ThermaPhase oil water seperator. Location: Between the main facility building and the compressor building. Camera Direction: Southwest Date/Time: 03/24/2021 10:38 AM Page 17 Hubbell-Wiegmann 03/24/2021 33: RIMG0033 Description: Exhaust pipes from oil/water seperator. Location: Camera Direction: Date/Time: 03/24/2021 34: RIMG0034 Description: Absorbent pad and catch pan being used to collect leaking hydraulic fluid from metal press. Location: Nema product line. Camera Direction: West Date/Time: 03/24/2021 11:02 AM Page 18 Hubbell-Wiegmann 03/24/2021 35: RIMG0035 Description: Barrel of deionized water used in closed loop system to cool spot welder tips. Location: South end of the main facility building. Camera Direction: Down Date/Time: 03/24/2021 11:07 AM 36: RIMG0036 Description: West end of the single stage washer used for large pieces. Location: South end of the main facility building. Camera Direction: Southeast Date/Time: 03/24/2021 11:12 AM Page 19 Hubbell-Wiegmann 03/24/2021 37: RIMG0037 Description: Barrels of chemicals used in large single stage washer. Location: West end of the single stage washer. Camera Direction: Down Date/Time: 03/24/2021 11:12 AM 38: RIMG0038 Description: Barrels of chemicals used in large single stage washer. Location: West end of the single stage washer. Camera Direction: Down Date/Time: 03/24/2021 11:12 AM Page 20 Hubbell-Wiegmann 03/24/2021 39: RIMG0039 Description: Sump pit on north side of single stage washer. Location: North side of single stage washer. Camera Direction: Down Date/Time: 03/24/2021 11:13 AM Page 21 Hubbell-Wiegmann 03/24/2021 40: RIMG0040 Description: Sump pit on north side of single stage washer. Location: North side of single stage washer. Camera Direction: Down Date/Time: 03/24/2021 11:15 AM 41: RIMG0041 Description: Sump pit on north side of single stage washer. Note discharge pump and pipe. The operator stated that this discharge pipe is routed to the JIC Line wash line holding tank. Location: North side of single stage washer. Camera Direction: Down Date/Time: 03/24/2021 11:18 AM Page 22 Hubbell-Wiegmann 03/24/2021 42: RIMG0042 Description: Looking east from the west end of the single stage wash line. Location: West end of the single stage wash line. Camera Direction: East. Date/Time: 03/24/2021 11:25 AM Page 23 Hubbell-Wiegmann 03/24/2021 43: RIMG0043 Description: Large plastic tank located on south wall of main facility, west of the single stage washer. Location: South wall of main facility, west of the single stage washer. Camera Direction: Southwest Date/Time: 03/24/2021 11:25 AM 44: RIMG0044 Description: Pressure washers located on the north side of the paint booth located in the southwest corner of the facility. Location: Southwest corner of the facility's main building. Camera Direction: East Date/Time: 03/24/2021 11:34 AM Page 24 Hubbell-Wiegmann 03/24/2021 45: RIMG0045 Description: Large tank located along the west wall of the south side of the main building. Location: Southwest side of the facility. Camera Direction: Southwest Date/Time: 03/24/2021 11:36 AM Page 25 Hubbell-Wiegmann 03/24/2021 46: RIMG0046 Description: West side of tank seen in photo 45. Note pipe with valve routed from the bottom of the tank through the west wall. Location: Southwest side of the facility. Camera Direction: North Date/Time: 03/24/2021 11:36 AM Page 26 Hubbell-Wiegmann 03/24/2021 47: RIMG0047 Description: West side exterior of main building. Note pipe seen in photo 46 (red arrow) and spot welder water cooling tower (blue arrow). Location: Southwest corner of main building. Camera Direction: Northeast Date/Time: 03/24/2021 11:38 AM 48: RIMG0048 Description: Additional view of cooling tower. Location: Southwest corner of main building. Camera Direction: Northeast Date/Time: 03/24/2021 11:38 AM Page 27 Hubbell-Wiegmann 03/24/2021 49: RIMG0049 Description: A group of pipes protruding through the west wall of the main building on the south end of the building. Location: Southwest corner of main building. Camera Direction: Southwest Date/Time: 03/24/2021 11:41 AM 50: RIMG0050 Description: Small building west of the southwest corner of the main building. The pipes seen in photo 49 go to this building. The operator stated that this building is no longer used for its original purpose and is now only used for chemical storage. Location: Small building west of southwest corner of main building. Camera Direction: South Date/Time: 03/24/2021 11:47 AM Page 28 Hubbell-Wiegmann 03/24/2021 51: RIMG0051 Description: Close-up of one of the barrels stored in the room seen in photo 50. Location: Small building west of southwest corner of main building. Camera Direction: South Date/Time: 03/24/2021 11:47 AM 52: RIMG0052 Description: Sump in former paint booth now used for washing. The operator stated that the sump is piped over to the sump pit of the single stage washer. Location: Southwest corner of main building. Camera Direction: South Date/Time: 03/24/2021 11:54 AM Page 29 Hubbell-Wiegmann 03/24/2021 53: RIMG0053 Description: Sump in former paint booth now used for washing. The operator stated that the sump is piped over to the sump pit of the single stage washer. Location: Southwest corner of main building. Camera Direction: South Date/Time: 03/24/2021 11:54 AM 54: RIMG0054 Description: Chemical solvent dispenser with containment. Location: West side of main building. Camera Direction: West. Date/Time: 03/24/2021 11:56 AM Page 30 Hubbell-Wiegmann 03/24/2021 55: RIMG0055 Description: Waste storage drums and empty drums. Location: West side of main building. Camera Direction: Northwest. Date/Time: 03/24/2021 11:58 AM 56: RIMG0056 Description: Waste storage drums and empty drums. Location: West side of main building. Camera Direction: North Date/Time: 03/24/2021 12:00 PM Page 31 Hubbell-Wiegmann 03/24/2021 57: RIMG0057 Description: Waste storage drums and empty drums. Location: West side of main building. Camera Direction: North Date/Time: 03/24/2021 12:01 PM 58: RIMG0058 Description: Waste storage drums being filled. Location: West side of main building. Camera Direction: Down Date/Time: 03/24/2021 12:01 PM Page 32 Hubbell-Wiegmann 03/24/2021 59: RIMG0059 Description: Closeup of top of waste oil drum lid. Location: West side of main building. Camera Direction: Down Date/Time: 03/24/2021 12:01 PM 60: RIMG0060 Description: Waste storage drums and empty drums. Location: West side of main building. Camera Direction: South Date/Time: 03/24/2021 12:02 PM Page 33 Hubbell-Wiegmann 03/24/2021 61: RIMG0061 Description: Unopened new chemical storage. Location: West side of main building. Camera Direction: South Date/Time: 03/24/2021 12:02 PM 62: RIMG0062 Description: Emergency spill response kit located adjacent to the chemical storage rack. Location: West side of main building. Camera Direction: Southwest. Date/Time: 03/24/2021 12:03 PM Page 34 Hubbell-Wiegmann 03/24/2021 63: RIMG0063 Description: Interior of emergency spill response kit located adjacent to the chemical storage rack. Location: West side of main building. Camera Direction: Southwest. Date/Time: 03/24/2021 12:04 PM 64: RIMG0064 Description: Pallets stacked outdoors west of the southwest corner of the warehouse. Location: West of the southwest corner of the warehouse. Camera Direction: West Date/Time: 03/24/2021 1:23 PM Page 35 Hubbell-Wiegmann 03/24/2021 65: RIMG0065 Description: Loading dock on west side of southwest corner of the warehouse building. Note sump in corner of loading dock (red arrow). Location: West side of southwest corner of warehouse. Camera Direction: East Date/Time: 03/24/2021 1:24 PM 66: RIMG0066 Description: Outlet of sump seen in photo 65 and roof drains on south side of warehouse. Location: South side of southwest corner of warehouse. Camera Direction: North Date/Time: 03/24/2021 1:25 PM Page 36 Hubbell-Wiegmann 03/24/2021 67: RIMG0067 Description: Sump pump located in the southeast corner of the interior of the warehouse. Location: Interior southeast corner of warehouse. Camera Direction: Down Date/Time: 03/24/2021 1:28 PM Page 37 Hubbell-Wiegmann 03/24/2021 68: RIMG0068 Description: Outlet of sump pump seen in photo 67. Location: East side of southeast corner of the warehouse. Page 38 Hubbell-Wiegmann 03/24/2021 Camera Direction: West Date/Time: 03/24/2021 1:29 PM 69: RIMG0069 Description: Uncapped pipe on west side of the main building. Location: West side of main building. Camera Direction: East Date/Time: 03/24/2021 1:34 PM 70: RIMG0070 Description: Interior of small building north of compressor building. Operator stated that this building was used for general storage and did not have a floor drain. Location: North of compressor building between main building and warehouse. Camera Direction: Northeast Date/Time: 03/24/2021 1:38 PM Page 39 Hubbell-Wiegmann 03/24/2021 71: RIMG0071 Description: Interior of small building north of compressor building. Operator stated that this building was used for general storage and did not have a floor drain. Location: North of compressor building between main building and warehouse. Camera Direction: Northeast Date/Time: 03/24/2021 1:40 PM 72: RIMG0072 Description: Closeup of data plate on oil water seperator located east of compressor building. Location: Between compressor building and main building. Camera Direction: West Date/Time: 03/24/2021 1:46 PM Page 40 Hubbell-Wiegmann 03/24/2021 73: RIMG0073 Description: Uncapped pipe on west side of main building. Location: West side of main building. Camera Direction: East Date/Time: 03/24/2021 1:53 PM 74: RIMG0074 Description: Uncapped pipes protruding from the ground on the west side of the main building. Location: West side of main building Camera Direction: East Date/Time: 03/24/2021 1:55 PM Page 41 Hubbell-Wiegmann 03/24/2021 75: RIMG0075 Description: Uncapped pipe protruding from the east side of the main building. Location: Southeast side of main building. Camera Direction: Northeast Date/Time: 03/24/2021 1:58 PM 76: RIMG0076 Description: Pallets stacked on the east side of main building. Location: Southeast side of main building. Camera Direction: South Date/Time: 03/24/2021 2:00 PM Page 42 Hubbell-Wiegmann 03/24/2021 77: RIMG0077 Description: Scrap metal bins on east side of main building. stormwater contact. Location: East side of main building. Camera Direction: Southwest Date/Time: 03/24/2021 2:02 PM Note covers on bins to prevent Page 43 Hubbell-Wiegmann 03/24/2021 Arial Photo of Hubbell Wiegmann . 1 inch = 100 feet Warehouse Compressor Building Main Building Hubbell Wiegmann 501 W Apple Street Freeburg, Illinois 62243 St. Clair County 38.42268926419547, -89.91523035035878 Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community Documents Provided by Hubbell Wiegman Process Diagram Piping Diagram Sampling Procedure Monthly Water Testing Sampling The samples must be collected and submitted to PDC Labs before the 15th of each month. Step 1: The Contact Person (Supervisor) will obtain the testing kit (cooler) from PDC Labs and verify the contents. 1 Chain of Custody Record (COC) sheet in a resealable plastic bag. 1 bottle SP01-Composite (Nitric Acid on red label CAS# 7697-37-2). 1 bottle SP01-Grab (Sodium Hydroxide on a green label CAS# 1310-73-2). 1 bottle SP01-Grab (Nitric Acid on a red label CAS# 7697-37-2). 1 bottle SP01-Grab (Sulfuric Acid on a yellow label CAS# 7664-93-9). 1 resealable plastic bag for the sample bottles. Step 2: The Contact Person will notify the Sampler (production worker) when testing will be conducted and give the Sampler the cooler. Step 3: The Sampler will proceed to the sampling area (manhole cover between JIC packaging and assembly) and collect the samples, in 1-hour increments, in the following order: a. First sample will be for SP01-Composite. Only fill 1/3 of the bottle on this sample. b. Second sample will be for SP01-Composite. Fill second 1/3 of the bottle on this sample. c. Third sample will be filling the remaining SP01-Composite, along with filling the 3 SP01-Grab bottles. Step 4: Upon collection completion, the Sampler will do the following: a. Place all bottles within the resealable plastic bag, seal it, and place the sealed bag in the cooler. b. Fill out the following sections of the COC sheet: a. "Sampler" (Printed Name). b. "Sampler's Signature". c. "Effluent Composite" - date collected and the 3 times samples were collected. d. "Effluent Grab" - date collected, and time collected. c. Notify the Contact Person that the sampling is completed. Step 5: The Contact Person will obtain the cooler and perform the following: a. Verify COC is correctly filled out. b. Immediately put ice on the samples, and note the start time of the chill process, on the COC sheet. c. Contact PDC Labs for cooler pick up. d. Before handing off the cooler to PDC Labs, sign, date, and time stamp the "Relinquished by" section. Hauled Waste Final Disposition ILLINI Environmental, Inc. P.O. Box 387 8895 California Drive Caseyville, Illinois 62232 Phone: 618-397-1234 Fax: 618-397-3234 Hubbell-Wiegmann 501 West Apple St. Freeburg, IL 62243 Re: Methods of Disposal for the following Waste Streams Hello, Per your request, please see the methods of disposal for each of your waste streams, as listed by their Material Name and Illini Approval Number. 20-275-5 (Wash Sump and Holding Tanks): - Material is transported to Illini via Vac Tanker. The material is blended with a solidification agent until it passes paint filter. Once solidified, the material is transferred to a bulk container to be shipped to WM Milam Landfill. 20-321-8 (Universal Waste): - Universal Waste is transported to Illini via Van Trailer. The Universal Waste is either counted or weighed depending on the material. The Waste is sorted into separate containers depending on the final disposal facility. Ex.) Lamps and Batteries will be sent to two different disposal facilities. 20-328-6 (RCRA Empty Drum): - Poly Drums are transported to Illini via Van Trailer. They are added to a bulk load of RCRA Empty containers that Illini transports to WM Milam Landfill on a semiregular basis. - Steel Drums are transported to Illini via Van Trailer. They are crushed and added to our steel scrap for recycle. Thank you, Tyler Martini EHS Manager Page 1 of 1 Waste Hauling Manifests Water and Sewer Records MSDS Sheets MATERIAL SAFETY DATA SHEET ZINCGRIP Steel DATE OF PREPARATION: August 1, 2002 Revised October 7,2005, Revision 2 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT/CHEMICAL NAME ZINCGRIP Steel MANUFACTURER'S NAME & TELEPHONE # AK STEEL CORPORATION 513 425-5000 (Information) 800 331-5050 (Customer Service) 513 425-3815 (Health & Safety) ADDRESS 703 CURTIS STREET MIDDLETOWN, OHIO 45043-0001 SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS Components Base Metal Iron CASRN1 7439-89-6 as Fe Alloying Metals Aluminum 7429-90-5 as Al Boron 7440-42-8 as B Calcium Carbon 7440-70-2 as Ca 7440-44-0 as C Chromium 7440-47-3 as Cr Columbium (Niobium) Copper 7440-03-1 as Nb 7440-50-8 as Cu Manganese 7439-96-5 as Mn Molybdenum 7439-98-7 as Mo Nickel 7440-02-0 as Ni Phosphorus Silicon 7723-14-0 as P 7440-21-3 as Si Sulfur 7704-34-9 as S Titanium Vanadium 7440-32-6 as Ti 7440-62-2 as V Metallic Coating6 Zinc 7440-66-6 as Zn Coating None % Weight >95.0 <0.10 <0.01 <0.10 <0.30 <0.15 <0.10 <0.20 <2.0 <0.30 <0.20 <0.15 <1.0 <0.05 <0.10 <0.10 100.0 OSHA PEL2 10 mg/m3 - Iron Oxide (Fe2O3) Dust and Fume (as Fe) 15 mg/m3 -Total Dust 5 mg/m3 - Respirable4 as Al 15 mg/m3 -Total Dust as Boron Trioxide (B203) 15 mg/m3 - Calcium Oxide (CaO) 15 mg/m3 -Total Dust 5 mg/m3 - Respirable4,5 1 mg/m3 - Chromium Metal 15 mg/m3 -Total Dust 5 mg/m3 - Respirable4,5 0.1 mg/m3 - Fume as CuO 1 mg/m3 - Cu Dusts & Mists Ceiling 5 mg/m3 - Metal Fume & Mn Compounds 15 mg/m3 -Total Dust 5 mg/m3 - Respirable4,5 1 mg/m3 - Ni & Insoluble Compounds 1 mg/m3 as Phosphoric Acid (H3P04) 15 mg/m3 -Total Dust 5 mg/m3 - Respirable4,5 15 mg/m3 -Total Dust 5 mg/m3 - Respirable4,5 15 mg/m3 -Total Dust as TiO2 0.5 mg/m3 - Respirable as V2O54,5 Ceiling 0.1 mg/m3 - Fume as V2O5 15 mg/m3 -Total Dust as ZnO 5 mg/m3 - Respirable4,5 & Fume, ZnO ACGIH TLV3 5 mg/m3 -Iron Oxide (Fe2O3) Dust & Fume as Fe 10 mg/m3 -Metal Dust 5 mg/m3 -Welding Fume as Al 10 mg/m3 Total Dust as Boron Oxide (B203) 2 mg/m3 - Calcium Oxide (CaO) 10 mg/m3 -Total Dust 3 mg/m3 - Respirable4,5 0.5 mg/m3 - Cr Metal & Cr III Compounds 15 mg/m3 -Total Dust 3 mg/m3 - Respirable4,5 0.2 mg/m3 - Fume 1 mg/m3 - Cu Dusts & Mists 0.2 mg/m3 Metal Fume and Mn Compounds 10 mg/m3 - Dust 2 mg/m3 - Respirable4,5 1.5 mg/m3 - as Ni 0.2 mg/m3 - Insoluble Compounds 1 mg/m3 as Phosphoric Acid 10 mg/m3 -Total Dust 3 mg/m3 - Respirable4,5 10 mg/m3 -Total Dust 3 mg/m3 - Respirable4,5 10 mg/m3 -Total Dust as TiO2 0.05 mg/m3 - Respirable as V2O54,5 2 mg/m3 - Respirable4,5 as ZnO STEL 10 mg/m3 - Respirable4,5 Page 2 of 8 ZINCGRIP Steel AK Steel, Revised October 7,2005, Revision 2 Notes: 1. CASRN: Chemical Abstract Service Registry Number 2. OSHA PEL: OSHA 8-hour Permissible Exposure Limit as listed in 29 CFR 1910.1000 Table Z 3. ACGIH TLV: American Conference of Government Industrial Hygienist 8-hour Threshold Limit Valves as listed in 2005 Threshold Limit Valves for Chemical Substances and Physical Agents. 4. Respirable: Particulates as measured with a cyclone sampling device that collects small particulate matter below a certain cut size, as defined in NIOSH Manual of Analytical Methods. 5. As particles not otherwise regulated. 6. % Weight for individual components are for the Metallic Coating, not the base metal and Coating, 7. ZINCGRIP Steel Quality Extras include the following: Commercial Steel Type B Special Killed Extra Deep Drawing Steel Extra Deep Drawing Steel Plus Dent Resistant Structural Steel High Strength Low Alloy Steel 8. Steel coils may be coated with a light coating oil to prevent corrosion. SECTION 3 - HEALTH HAZARD DATA/EXPOSURE Summary of Health Hazards ZINCGRIP Steel in its natural state does not pose an immediate health or fire hazard. However welding or heating this material will cause inorganic and organic fumes that are irritating, potentially corrosive and can cause respiratory distress. Mechanical operations such as sawing, grinding, drilling or similar physical operations may cause potentially hazardous airborne particulates which can injure the eyes and skin. These particulates when breathed may cause irritating and corrosive effects to the mouth, nose and respiratory tract. If it is necessary to weld, heat, saw, grind, drill or any physical operation that will generate a fume or airborne particulates, an exposure assessment should be performed by a qualified industrial hygienist to determine the required personal protection equipment (PPE). Primary Route(s) of Entry: Inhalation, ingestion, eyes or skin contact. Steel products in the natural state do not present an inhalation, ingestion, eye or skin contact hazard. However operations such as burning, welding, sawing, drilling or grinding may constitute hazards if exposures exceed limits listed in Section 2. ACUTE EFFECTS OF EXPOSURE Inhalation: Exposure to high concentrations of metallic fumes and dusts or organic particulates may result in irritation and/or sensitization of the lungs and other mucous membranes. Excessive inhalation of high concentrations of fumes generated from the heating of metals, e.g. zinc, copper and manganese, can produce an acute reaction known as "metal fume fever" Skin Contact: Exposure to metal dusts may cause irritation or sensitization, possibly leading to dermatitis. Eye Contact: Impact of metal particles on the eye may cause temporary damage to the eye or possible scars to the retina, thus producing long damage. Metal particles may cause rust staining of the eye unless removed. Metallic or organic fumes will cause irritation of the eyes. Page 3 of 8 ZINCGRIP Steel AK Steel, Revised October 7,2005, Revision 2 Ingestion: Ingestion of harmful amounts is highly unlikely due to its solid insoluble form. Ingestion of dusts may cause nausea and/or vomiting. Heart failure. MATERIAL CONDITIONS KNOWN TO BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL: Persons with impaired lungs may be at increased risk from overexposure to fumes generated by heating or welding this product. CHRONIC EFFECTS OF OVEREXPOSURE Excessive and Repeated Exposures to Alloy Fume or Dust May Cause: Allergic sensitization - dermatitis and asthma Lung inflammation and damage - pneumonitis, pneumonia, bronchitis, siderosis (benign lung disease caused by inhaling iron particles) diffuse pulmonary fibrosis. Nasal perforation and nasal cavity damage Eye inflammation, Eye stain from imbedded rust particles Central nervous system damage, possibly permanent (manganese) Kidney damage (copper, manganese, molybdenum) Liver damage (copper, molybdenum) Gout - Inflammation of the joints (molybdenum) See Section 11 for detailed toxicity information on individual components. Carcinogenicity: The carcinogenicity of this product as a whole has not been tested. Individual components nickel, chromium and some compounds of these elemental metals have been associated with carcinogenicity by NTP and IARC. IARC lists welding fumes as 2B ( Possibly carcinogenic to humans) No component greater than 0.1% by weight in this alloy is regulated by OSHA within 29 CFR 1910.1000, Subpart Z, as a carcinogen. Signs and Symptoms of Overexposure: Redness, swelling, itching, and/or irritation of skin and eyes; Respiratory difficulties - coughing, wheezing, shortness of breath, dyspnea, decreased pulmonary function; Metal Fume Fever - symptoms consist of chills and fever (very similar and easily confused with flu symptoms), a metallic taste in the mouth, dryness and irritation of the throat, and tightness of the chest. The symptoms occur a few hours after excessive exposures and usually last from 12 to 48 hours. SECTION 4 - EMERGENCY & FIRST-AID PROCEDURES In case of overexposure to metal fumes and/or dusts Inhalation: Immediately move the people from the contaminated area to fresh air. Give artificial respiration if breathing has stopped; or oxygen if necessary. Seek medical attention. Metal fume fever may be treated by bed rest, and administering a pain and fever reducing medication. Skin: Remove contaminated clothing immediately. Flush contaminated skin with large quantities of water for fifteen minutes. Seek medical attention. Eyes: In case of contact, immediately wash eyes with large amounts of water for fifteen minutes, occasionally lifting the lower and upper lids. Seek medical attention. Ingestion: If conscious, immediately give person large quantities of water. Do not induce vomiting. Seek medical attention. Page 4 of 8 ZINCGRIP Steel AK Steel, Revised October 7,2005, Revision 2 SECTION 5 - FIRE AND EXPLOSION DATA The product is: Non-Flammable solid Auto-ignition Temperature (oF): Not Applicable Flash Point:(oF): Not Applicable Flammability Limits (LEL and UEL): Not Applicable Products of Combustion: Steel is not combustible. Steel might have a light surface coating of oil and this coating may produce carbon decomposition products, which are irritating to eyes and throat. Use water to cool coils. Fire Hazard in the presence of various substances: Oil coated steel will smolder and smoke, but will not burn. Explosion hazard in the presence of various substances: Material will not burn. Not Applicable Fire fighting media and instructions: Use water to cool coils. Use appropriate fire extinguishers for surrounding materials. Do not release run off to sewers or waterways Fire fighting equipment: Wear self-contained breathing apparatus firefighters protective clothing for surrounding fire areas to protect against the generation of metal dust and fumes which are hazardous. SECTION 6 - ACCIDENTAL RELEASE MEASURES Spill / Leak Procedures: Not applicable to steel products in solid state. For spills of finely dived particles, clean-up personnel should be protected against contact with skin and eyes. Avoid inhalation of dust. Finely divided material should be cleaned up by vacuuming or wet sweeping methods to prevent further dispersal of dust. Do not use compressed air. Collect material in appropriate, labeled containers for recovery or disposal in accordance with federal, state, and local regulations. Regulatory Requirements: Release of this material in a solid form does not require notification of U.S EPA. SECTION 7 - HANDLING AND STORAGE Handling Precautions: Avoid the generation of large quantities of metal dusts and airborne particulates. Practice good housekeeping. Avoid breathing metal fumes and dusts. Special Handling: Do not store steel products adjacent to acids, corrosive materials, materials that generate corrosive gases or incompatible materials. SECTION 8- EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Ventilation, as described in the current Industrial Ventilation Manual produced by the American Conference of Governmental Industrial Hygienists, shall be provided in areas where exposures are above the permissible exposure limits or threshold limit values specified by OSHA or other local, state, and federal regulations. Respiratory Protection: A respirator should be worn whenever airborne concentrations exceed the threshold limit value (TLV) or other recommended limits, in accordance with the OSHA Respiratory Protection Standard (29 CFR 1910.134). A qualified industrial hygienist should be consulted to perform exposure assessment. Protective Clothing: Use appropriate protective clothing and safety equipment when handling this product. Although not recommended, if heating or welding is required, welder's aprons and gloves, and eye protection should be worn along with safety equipment. An exposure assessment should be conducted by a qualified industrial hygienist to determine proper respiratory protection. Protective gloves should be worn whenever handling steel scrap or touching the steel coil. An example of such a glove is a Leather Glove with Kevlar Liner. Eye Protection: Safety glasses and/or face shield (8" minimum) should be worn whenever grinding, cutting or drilling this product. Eyewash/Deluge stations should be located within 10 seconds of work place. Page 5 of 8 ZINCGRIP Steel AK Steel, Revised October 7,2005, Revision 2 SECTION 9 - PHYSICAL/CHEMICAL CHARACTERISTICS Evaporation Rate (Ethyl Ether=1) Melting Point (F) pH Information Percent Volatile by Volume Solubility in Water Specific Gravity (H2O=1) Vapor Pressure (mm Hg@25.0oC) Vapor Density ((Air=1) Appearance and Odor Not Applicable 2795 F as Fe, 787F as Zinc Not Applicable Not Applicable Not Applicable > 1.0 Not Applicable Not Applicable Gray Metallic Color with No Odor SECTION 10 - REACTIVITY DATA Stability: ZINCGRIP Steel is stable under normal storage and handling conditions. Polymerization: Hazardous polymerization will not occur. Chemical Incompatibilities: Will react with strong acids to form hydrogen gas. Iron Oxide dusts will in react with strong oxidants. Conditions to Avoid: Storage with strong acids or oxidants. Hazardous Decomposition Products: Thermal oxidative decomposition of steel coatings containing zinc can produce fumes containing oxides of zinc. Breathing zinc oxide fumes may produce respiratory distress and "metal fume fever". SECTION 11 - TOXICOLOGICAL INFORMATION ZINCGRIP Steel is not toxic in the solid form. The toxicity occurs when processes generate dust and fumes of individual components. Iron: Chronic inhalation of excessive concentrations of iron oxide fumes or dusts may result in development of a benign pneumoconiosis, called siderosis, which is observable as an x-ray change. No physical impairment of lung function has been associated with siderosis. Inhalation of excessive concentrations of iron oxide may enhance the risk of lung cancer development in workers exposed to pulmonary carcinogens. LD50 (oral, rat) - 30 gm/kg. Iron Oxide, NIOSH-RTECS: N07400000, fume NIOSH-RTECS: N07525000 Aluminum: Nuisance dust. May cause mild irritation to eyes and mucous membranes. LD50-no data. NIOSH-RTECS: BD0330000 Boron: Boron oxide dusts and fumes may cause upper respiratory tract and eye irritation, dryness of mouth, nose or throat, and sore throat and productive cough. LD50 (oral, mouse) - 3163 mg/kg. Boron Oxide: NIOSH-RTECS: ED7900000 Calcium: Concentration of calcium in steel is low but if converted to dust and prolonged exposure occurs inflammation of respiratory tract can occur. Skin irritant. Avoid eye contact. Eye-rabbit: 10 mg severe: calcium hydroxide. LD50 (oral-rat) - 7340 mg/Kg. Calcium Oxide, NIOSH-RTECS: EW3100000 Carbon: Nuisance dust. May cause mild irritation to eyes and mucous membranes. LD50 - no data Chromium: Chromium metal has low toxicity in alloyed solid steel products. Chromium metal and trivalent chromium are listed by IARC as group 3 (not classifiable as to carcinogenicity in humans). Hexavalent chromium is classified by IARC as a Group 1 (carcinogenic to humans) and by ACIGH as A1 (confirmed human carcinogen). Hexavalent chromium compounds can act as a strong irritant of skin, eyes, and mucous membranes. LDLo (oral-human) - 71 mg/Kg. NIOSHRTECS: GB4200000 Columbium (Niobium): No data on human intoxication. There is no evidence of a human health hazard. Treat as a nuisance dust. LD50 - no data. NIOSH-RTECS: QT9900000 Page 6 of 8 ZINCGRIP Steel AK Steel, Revised October 7,2005, Revision 2 Copper: Copper fumes can lead to "metal fume fever" with symptoms of thirst, cough, headache, sweat, pain in limbs and fever. Complete recovery usually occurs within 1 to 2 days of removal from exposure. Copper fumes can also nausea, gastric pain, and diarrhea. LDLo (oral-human) - 120 g/Kg (nausea or vomiting). NIOSH-RTECS: GL53250000 Manganese: Chronic manganese poisoning may result from prolonged inhalation of manganese dust and fumes. The central nervous system is the chief site of damage from the disease, which may result in permanent disability. Symptoms include languor, sleepiness, weakness, emotional disturbances, spastic gait, recurring leg cramps, and paralysis. A high incidence of pneumonia and other upper respiratory infections have been found in workers exposed to dust or fume of manganese compounds. Manganese compounds are experimental equivocal tumorigenic agents. LD50 (oral, rat) - 30 mg/kg; TCLo - 2300 g/m3 (man). NIOSH-RTECS: OO9275000 Moybdenum: Inhalation of high concentrations can cause "hard metal lung" disease' and pneumoconiosis in workers exposed to high concentrations for extended periods of time. Symptoms of over exposure are anemia and diarrhea. The human body in various metabolic processes uses molybdenum. LD50 - no data. NIOSH-RTECS: QA4680000 Nickel: Can cause allergic dermatitis on contact, pulmonary asthma, and conjunctivitis in high concentrations or chronic exposure to soluble nickel compounds. Metallic nickel is classified by IARC as a Group 2B (possibly carcinogenic to humans) , by NTP (reasonably anticipated to be a human carcinogen), and by ACGIH as group A5 (not suspected as a human carcinogen). Nickel compounds are classified by IARC as Group 1 (carcinogenic to humans), by NTP as (known to be carcinogenic to humans, and by ACGIH as Group A1 (confirmed carcinogen in humans). TDLo (oral-rat) - 200mg/Kg (depressed activity). NIOSH-RTECS: QR5950000 Phosphorus: Dust of the phosphorous oxides and ferrophosphorous may cause respiratory irritation. LD50 - no data Phosphoric Acid, NIOSH-RTECS: TB6300000 Silicon: Nuisance dust. May cause mild irritation to eyes and mucous membranes. LD50 (oral, rat) - 3160 mg/kg. NIOSHRTECS: VW0400000 Titanium: Nuisance dust. May cause mild irritation to eyes and mucous membranes. TDLo (oral-rat) - 60 gm/Kg (hypermotility - diarrhea). NIOSH-RTECS: XR2275000 Vanadium: Vanadium as vanadium pentoxide causes bleeding of the nose, asthma, cough, dyspnea, and conjunctivitis. LD50 - no data. Vanadium Pentoxide, RTECS: YW2450000 Zinc: The primary toxicological effect due is the inhalation of zinc fumes, formed when heating, burning or welding a zinc coated surface, such galvanizing. Overexposure to zinc fumes will cause metal fume fever. Attacks usually begin after 4 to 8 hours after exposure and consist of chills and fever, profuse sweating and weakness. Attacks usually last only 24 to 48 hours. Any person who suspects they are experiencing metal fume fever should seek medical assistance. TCLo (inhalation-human) - 600 mg/m3 (cough-dyspnea). Zinc Oxide, NIOSH-RTECS: ZH4810000 Coating Oils: The oil will cause eye irritation. Repeated or prolonged skin contact will dry the skin and lead to dermatitis. LD50 (oral-mouse) - 22 gm/Kg. NIOSH-RTECS: PY8030000 SECTION 12 - ECOLOGICAL INFORMATION ZINCGRIP Steel is coated with a protective layer and poses no ecological hazard unless the metal is processed to generate dust, fumes, and soluble compounds of the individual components. Aquatic Toxicity 24-hour, Ictalurus punctarus (channel catfish), LC50 >0.5% as Iron 96 hr, Pimpehales promelas, fathead minnow, LC50 10-100 mg/L as Chromium 4 days post hatch, Omcorhynchus mykiss, Rainbow trout, LC50 60-90 g/L as Nickel 3-hour and 9 hour, Bufo bufo japonicus (Toad), LC50 = 3.2 mg/L as Zinc ion Terrestrial Toxicity 8 weeks, Eisenia Fetida,earthworm, NOEC 26,000 mg/Kg as Zn 8-day ,Colinus virginianus (Northern Bobwhite), LC50 > 5000ppm as Zinc Oxide 8.5 weeks, 0-survival Porcellio scaber (woodlice) exposed to soil as Zinc Oxide Page 7 of 8 ZINCGRIP Steel AK Steel, Revised October 7,2005, Revision 2 SECTION 13 - DISPOSAL INFORMATION Disposal: Contact supplier or licensed contractor for detailed recommendations. Follow applicable Federal, state and local regulations SECTION 14 - TRANSPORT INFORMATION DOT Classification: Not listed as hazardous under 49 CFR 172.101 Special Conditions for Transport: Not Listed as hazardous substance under 49 CFR 172.101 Identification Number: Not Required Hazardous Material Proper Shipping Name: Not Listed as hazardous substance under 49 CRF 172.10 SECTION 15 - REGULATORY INFORMATION OSHA Regulations (29 CFR) Air Contaminant (29 CFR 1910.1000, Table Z): Steel products are not listed as air contaminants. However individual components are listed. EPA Regulations (40 CFR) Resource Conservation and Recovery Act (RCRA) - Hazardous Waste: Steel products or scrap are not regulated as a solid waste or hazardous waste under this regulation. Dusts or fumes subject to TCLP toxicity characteristic test may indicate this material is to be classified as a hazardous waste (40CRF261.24). Comprehensive Emergency Response Compensation and Liability Act (CERCLA) - Superfund: Steel products or scrap are not listed as hazardous substances. Metals in solid form greater than 100 micrometers (0.004 Inches) are not required to be reported under CERCLA. [Individual Reportable Quantities, RQ: Chromium (RQ = 5000 lb.), Copper (RQ = 5000 lb.), Nickel (RQ = 100 lb.), Copper (RQ = 5000 lb.), Silver (RQ = 1000 lb.), Zinc (RQ = 1000 lb.)]. SARA (Superfund Amendments and Reauthorization Act) Section 311/312 List the hazard class(es) of material : Steel products are not required to be listed. Metals (i.e. chromium, copper, nickel, silver, and zinc) require no reporting of releases of the solid form if the mean diameter is greater than 100 micrometers (0.004 inches). SARA (Superfund Amendments and Reauthorization Act) Section 313 Toxic Chemicals: Steel products are not subject to reporting requirements. State Regulations Steel Products are not listed in state regulations. However, the individual components are listed in various state regulations. Canada WHMIS (Workplace Hazardous Material Information System) The material upon further processing has a WHMIS Classification of D-2 Page 8 of 8 ZINCGRIP Steel AK Steel, Revised October 7,2005, Revision 2 SECTION 16 - OTHER INFORMATION NFPA 704M RATING: Health = 1, Flammability = 0, Reactivity = 0 NFPA Hazard Rating System: Least = 0, Slight =1, Moderate = 2, High =3, Extreme = 4 Revisions: Ecological Section added Sections rearranged along the ANSI Z400.1-2003 guidelines References: ACIGH TLV's. American Industrial Hygiene Association, 2005 American National Standard for Hazardous Chemicals - MSDS, Z400.1-2003 American National Standard for Hazardous Chemicals - Precautionary Labeling, ATSDR- Agency for Toxic Substances and Disease Registry EPA- IRIS Database for Risk Assessment EPA - ECOTOX- ECOTOXiology database EPA- National Primary Drinking Water Standards IARC- International Agency on Cancer Research NTP- National Toxicology Program NIOSH Pocket Guide to Chemical Hazards (NPG), 2005 OSHA - Occupational Safety and Health Act: RTECS- The Registry of Toxic Effects of Chemical Substances Z129.1-2005 Proposed WHILE THE INFORMATION AND RECOMMENDATIONS SET FORTH ON THIS DATA SHEET ARE BELIEVED TO BE ACCURATE, AS OF THE PRESENT DATA, AK STEEL COMPANY, MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. Safety Data Sheet Argon Section 1: Product and Company Identification Cee Kay Supply, Inc 5835 Manchester Avenue Saint Louis, MO 63110 www.CeeKay.com (314) 644-3500 Product Code: Argon Section 2: Hazards Identification Hazard Classification: Gases Under Pressure Hazard Statements: Contains gas under pressure; may explode if heated Precautionary Statements Storage: Protect from sunlight. Store in well-ventilated place. Warning Section 3: Composition/Information on Ingredients CAS # 7440-37-1 Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 1 of 4 Generated: 10/05/2017 10:16:24 Chemical Substance Chemical Family Trade Names ARGON, COMPRESSED Inorganic gases ARGON; UN 1006; AR Section 4: First Aid Measures Skin Contact Not applicable route of exposure Eye Contact Flush eyes with plenty of water. Ingestion Not applicable route of exposure Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. Note to Physicians For inhalation, consider oxygen. Section 5: Fire Fighting Measures Suitable Extinguishing Media Non-flammable gas Products of Combustion Not applicable Protection of Firefighters N/A N/A Section 6: Accidental Release Measures Personal Precautions Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. Methods for Cleanup Other Information Leaks may be detected by a soapy-water solution. Environmental Precautions None known. Methods for Containment Stop leak if possible without personal risk. Section 7: Handling and Storage Handling Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from incompatible substances. Storage Avoid using in confined spaces. Section 8: Exposure Controls/Personal Protection Exposure Guidelines ARGON, COMPRESSED: ARGON: ACGIH (simple asphyxiant) Engineering Controls Handle only in fully enclosed systems. Eye Protection Eye protection not required, but recommended. Skin Protection Protective clothing is not required. Respiratory Protection N/A General Hygiene considerations Avoid breathing vapor or mist Avoid contact with eyes and skin Wash thoroughly after handling and before eating or drinking Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 2 of 4 Generated: 10/05/2017 10:16:24 Section 9: Physical and Chemical Properties Physical State Gas Appearance Colorless Color Colorless Change in Appearance N/A Physical Form Gas Odor Odorless Taste Tasteless Flash Point Flammability Partition Coefficient Autoignition Temperature Upper Explosive Limits Lower Explosive Limits Not flammable Nonflammable Nonflammable Nonflammable Boiling Point -303 F (-186 C) Freezing Point -308 F (189 C) Vapor Pressure 500 mmHg @ -190 C Vapor Density 1.38 (Air=1) Specific Gravity Not applicable Water Solubility 3.36% @ 20 C pH Not applicable Odor Threshold Not available Evaporation Rate Not applicable Viscosity 0.0225 cP @ 25 C Molecular Weight 39.948 Molecular Formula AR Density 1.784 g/L @ 0 C Weight per Gallon Not available Volatility by Volume 100% Volatility Not applicable Solvent Solubility Soluble: Organic solvents Section 10: Stability and Reactivity Stability Stable at normal temperatures and pressure. Conditions to Avoid Stable at normal temperatures and pressure. Incompatible Materials No data available. Hazardous Decomposition Products No data available. Possibility of Hazardous Reactions Will not polymerize. Section 11: Toxicology Information Acute Effects Oral LD50 Dermal LD50 Not established Not established Inhalation Nausea, vomiting, difficulty breathing, irregular heartbeat, headache, dizziness, disorientation, mood swings, tingling sensation, loss of coordination, suffocation, convulsions, unconsciousness, coma Eye Irritation No information on significant adverse effects Skin Irritation No information on significant adverse effects Sensitization Chronic Effects Carcinogenicity Mutagenicity Not established Not established Reproductive Effects Not established Developmental Effects No data Section 12: Ecological Information Fate and Transport Eco toxicity Fish toxicity: Not available Invertibrate toxicity: Not available Algal toxicity: Not available Phyto toxicity: Not available Other toxicity: Not available Persistence / Degradability Not available Bioaccumulation / Accumulation Not available Mobility in Environment Not available Section 13: Disposal Considerations Dispose in accordance with all applicable regulations. Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 3 of 4 Generated: 10/05/2017 10:16:24 Section 14: Transportation Information U.S. DOT 49 CFR 172.101 Proper Shipping Name Argon, compressed ID Number UN1006 Hazard Class or Division 2.2 Packing Group Not applicable Labeling Requirements 2.2 Passenger Aircraft or Railcar Quantity Limitations 75 kg or L Canadian Transportation of Dangerous Goods Shipping Name UN Number Class Packing Group / Risk Group Argon, compressed UN1006 2.2 Not applicable Cargo Aircraft Only Quantity Limitations 150 kg Section 15: Regulatory Information U.S. Regulations CERCLA Sections SARA 355.30 Not regulated. Not regulated. SARA 355.40 Not regulated. SARA 370.21 Acute Chronic Fire Reactive Sudden Release Yes No No No Yes SARA 372.65 Not regulated. OSHA Process Safety Not regulated. State Regulations CA Proposition 65 Not regulated. Canadian Regulations WHMIS Classification A National Inventory Status US Inventory (TSCA) TSCA 12b Export Notification Listed on inventory. Not listed. Canada Inventory (DSL/NDSL) Listed on inventory. Section 16: Other Information NFPA Rating HEALTH=0 FIRE=0 REACTIVITY=0 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Additional Shipping Description N/A Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 4 of 4 Generated: 10/05/2017 10:16:24 Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com Safety Data Sheet REVISION DATE: 7/26/18 This SDS should be attached or kept with the respective product with which it is associated. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Lead Acid Battery, Wet Synonyms: Industrial Battery, Traction Battery General Information Number: 630-851-5800 Transportation Emergency Number: 800-535-5053 Product Use: Electric Storage Battery Manufacturer/Supplier: Battery Builders, LLC. Address: 31W 238 91ST Street, Naperville, IL 60564 CHEMICAL EMERGENCY NUMBER: INFOTRAC 800-535-5053 SECTION 2: HAZARD(S) IDENTIFICATION Health Acute Toxicity (Oral/Dermal/Inhalation) Skin Corrosion/Irritation Eye Damage Reproductive Carcinogenicity (lead) Carcinogenicity (arsenic) Carcinogenicity (acid mist) Specific Target Organ Toxicity (repeated exposure) Category 4 1A 1 1A 1B 1A 1A 2 Environmental Aquatic Chronic 1 Aquatic Acute 1 Physical Explosive Chemical, Division 1.3 GHS Label: Health Environmental Physical Hazard Statements: DANGER! Causes severe skin burns and eye damage. Causes serious eye damage. May damage fertility or the unborn child if ingested or inhaled. May cause cancer if ingested or inhaled. Precautionary Statements: Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing, eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. REVISION DATE: 7/26/18 Page 1 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com Health Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure. May form explosive air/gas mixture during charging. Extremely flammable gas (hydrogen). Explosive, fire, blast or projection hazard. Environmental Physical Causes skin irritation, serious eye damage. Contact with internal components may cause irritation or severe burns. Avoid contact with internal acid. Irritating to eyes, respiratory system, and skin. SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENTS (Chemical/Common Names): Lead and Lead Compounds (inorganic) Electrolyte (H2SO4/H2O) Antimony Arsenic Calcium Tin Polypropylene *Ingredients listed are representative of a typical industrial battery. CAS No.: 7439-92-1 7664-93-9 7440-36-0 7440-38-2 7440-70-2 7440-31-5 9003-07-0 % by Wt: 67 21 1 <0.01 <0.01 <0.01 <1 SECTION 4: FIRST-AID MEASURES INHALATION: Sulfuric Acid: Remove to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Consult a physician. Lead: Remove from exposure, gargle, wash nose and lips; consult physician. INGESTION: Sulfuric Acid: Give large quantities of water; Do NOT induce vomiting or aspiration into the lungs may occur and can cause permanent injury or death; consult physician. Lead: Consult physician immediately. SKIN: Sulfuric Acid: Flush with large amounts of water for at least 15 minutes; remove contaminated clothing completely, including shoes. If symptoms persist, seek medical attention. Wash contaminated clothing before reuse. Discard contaminated shoes. Lead: Wash immediately with soap and water. EYES: Sulfuric Acid and Lead: Flush immediately with large amounts of water for at least 15 minutes while lifting lids; Seek immediate medical attention if eyes have been exposed directly to acid. REVISION DATE: 7/26/18 Page 2 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com SECTION 5: FIRE FIGHTING MEASURES Flash Point: Not Applicable Flammable Limits: LEL = 4.1% (Hydrogen Gas in air); UEL = 74.2% Extinguishing media: CO2; foam; dry chemical. Do not use carbon dioxide directly on cells. Avoid breathing vapors. Use appropriate media for surrounding fire. Fire Fighting Procedures: Use positive pressure, self-contained breathing apparatus. Beware of acid splatter during water application and wear acid-resistant clothing, gloves, face and eye protection. If batteries are on charge, shut off power to the charging equipment, but note that strings of series connected batteries may still pose risk of electric shock even when charging equipment is shut down. Hazardous Combustion Products: Highly flammable hydrogen gas is generated during charging and operation of batteries. If ignited by burning cigarette, naked flame or spark, may cause battery explosion with dispersion of casing fragments and corrosive liquid electrolyte. Carefully follow manufacturer's instructions for installation and service. Keep away all sources of gas ignition and do not allow metallic articles to simultaneously contact the negative and positive terminals of a battery. Follow manufacturer's instructions for installation and service. SECTION 6: ACCIDENTAL RELEASE MEASURES Stop flow of material, contain/absorb small spills with dry sand, earth or vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc. Wear acid-resistant clothing, boots, gloves, and face shield. Do not allow discharge of un-neutralized acid to sewer. Acid must be managed in accordance with approved local, state, and federal requirements. Consult state environmental agency and/or federal EPA. SECTION 7: HANDLING AND STORAGE Handling: Unless involved in recycling operations, do not breach the casing or empty the contents of the battery. Handle carefully and avoid tipping, which may allow electrolyte leakage. There may be increasing risk of electric shock from strings of connected batteries. Keep containers tightly closed when not in use. If battery case is broken, avoid contact with internal components. Keep vent caps on and cover terminals to prevent short circuits. Place cardboard between layers of stacked automotive batteries to avoid damage and short circuits. Keep away from combustible materials, organic chemicals, reducing substances, metals, strong oxidizers and water. Use banding or stretch wrap to secure items for shipping. Storage: Store batteries under roof in cool, dry, well-ventilated areas separated from incompatible materials and from activities that may create flames, spark, or heat. Store on smooth, impervious surfaces provided with measures REVISION DATE: 7/26/18 Page 3 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com for liquid containment in the event of electrolyte spills. Keep away from metallic objects that could bridge the terminals on a battery and create a dangerous short-circuit. Charging: There is a possible risk of electric shock from charging equipment and from strings of series connected batteries, whether or not being charged. Shut-off power to chargers whenever not in use and before detachment of any circuit connections. Batteries being charged will generate and release flammable hydrogen gas. Charging space should be ventilated. Keep battery vent caps in position. Prohibit smoking and avoid creation of flames and sparks nearby. Wear face and eye protection when near batteries being charged. SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits (mg/m3) INGREDIENTS (Chemical/Common Names): Lead and Lead Compounds (inorganic) Electrolyte (H2SO4/H2O) Antimony Arsenic Cadmium Tin Polypropylene Note: N.E. = Not Established OSHA PEL ACGIH US NIOSH 0.05 0.05 0.05 1 0.5 0.01 0.005 2 N.E. 0.2 0.5 0.01 0.002 (b) 2 N.E. 1 0.5 0.01 0.0025 Ca(d) 2 N.E. Quebec PEV 0.05 1 0.5 0.025 N.E. Ontario OEL 0.05 0.2 0.5 0.01 N.E. EU OEL 0.15 (b) 0.05 (c) 0.5 (b,e) 0.01 (f) N.E. NOTES: *Ingredients listed are representative of a typical industrial battery. Consult individual manufacturer's SDS for information relating to a specific battery. (a)As dusts/mists (b)As inhalable aerosol (c)Thoracic fraction (d)Potential occupational carcinogen (e)Based on OEL's of Austria, Belgium, Denmark, France, Netherlands, Switzerland, & U.K. (f)Based on OEL of Belgium (g)Based on OEL of Netherlands Engineering Controls (Ventilation): Store and handle in well-ventilated area. If mechanical ventilation is used, components must be acid-resistant. Handle batteries cautiously, do not tip to avoid spills. Make certain vent caps are on securely. If battery case is damaged, avoid bodily contact with internal components. Wear protective clothing, eye and face protection, when filling, charging or handling batteries. Do not allow metallic materials to simultaneously contact both the positive and negative terminals of the batteries. Charge batteries in areas with adequate ventilation. General dilution ventilation is acceptable. Respiratory Protection (NIOSH/MSHA approved): None required under normal conditions. When concentrations of sulfuric acid mist are known to exceed PEL, use NIOSH or MSHA-approved respiratory protection. REVISION DATE: 7/26/18 Page 4 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com Skin Protection: If battery case is damaged, use rubber or plastic acid-resistant gloves with elbow-length gauntlet, acid-resistant apron, clothing and boots. Eye Protection: If battery case is damaged, use chemical goggles or face shield. Other Protection: In areas where water and sulfuric acid solutions are handled in concentrations greater than 1%, emergency eyewash stations and showers should be provided, with unlimited water supply. Chemically impervious apron and face shield recommended when adding water or electrolyte to batteries. Wash Hands after handling. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Properties Listed Below are for Electrolyte: Boiling Point: 203 - 240 F Specific Gravity (H2O = 1): 1.215 to 1.350 Melting Point: N/A Vapor Pressure (mm Hg): 10 Solubility in Water: 100% Vapor Density (AIR = 1): Greater than 1 Evaporation Rate: Less than 1 % Volatile by Weight: N/A (Butyl Acetate = 1) pH: ~1 to 2 Flash Point: Below room temperature (as hydrogen gas) LEL (Lower Explosive Limit) 4% (Hydrogen) UEL (Upper Explosive Limit) 74% (Hydrogen) Appearance and Odor: Manufactured article; no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating, pungent odor. SECTION 10: STABILITY AND REACTIVITY Stability: Stable X Unstable __ This product is stable under normal conditions at ambient temperature. Conditions to Avoid: Prolonged overcharge at high current; sources of ignition. Incompatibilities: (materials to avoid) Electrolyte: Contact with combustibles and organic materials may cause fire and explosion. Also reacts violently with strong reducing agents, metals, sulfur trioxide gas, strong oxidizers, and water. Contact with metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas. Lead compounds: Avoid contact with strong acids, bases, halides, halogenates, potassium nitrate, permanganate, peroxides, nascent hydrogen, and reducing agents. Arsenic compounds: strong oxidizers; bromine azide. NOTE: hydrogen gas can react with inorganic arsenic to form the highly toxic gas - arsine REVISION DATE: 7/26/18 Page 5 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com Hazardous Decomposition Products: Electrolyte: Sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide, hydrogen sulfide. Lead compounds: Temperatures above the melting point are likely to produce toxic metal fume, vapor, or dust; contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas. Hazardous Polymerization: Will not occur. SECTION 11: TOXICOLOGY INFORMATION Routes of Entry: Sulfuric Acid: Harmful by all routes of entry. Lead Compounds: Hazardous exposure can occur only when product is heated, oxidized or otherwise processed or damaged to create dust, vapor or fume. The presence of nascent hydrogen may generate highly toxic arsine gas. Inhalation: Sulfuric Acid: Breathing of sulfuric acid vapors or mists may cause severe respiratory irritation. Lead Compounds: Inhalation of lead dust or fumes may cause irritation of upper respiratory tract and lungs. Ingestion: Sulfuric Acid: May cause severe irritation of mouth, throat, esophagus and stomach. Lead Compounds: Acute ingestion may cause abdominal pain, nausea, vomiting, diarrhea and severe cramping. This may lead rapidly to systemic toxicity and must be treated by a physician. Skin Contact: Sulfuric Acid: Severe irritation, burns and ulceration. Lead Compounds: Not absorbed through the skin. Arsenic compounds: Contact may cause dermatitis and skin hyperpigmentation Eye Contact: Sulfuric Acid: Severe irritation, burns, cornea damage, and blindness. Lead Compounds: May cause eye irritation. Effects of Overexposure - Acute: Sulfuric Acid: Severe skin irritation, damage to cornea, upper respiratory irritation. Lead Compounds: Symptoms of toxicity include headache, fatigue, abdominal pain, loss of appetite, muscular aches and weakness, sleep disturbances and irritability. Effects of Overexposure - Chronic: Sulfuric Acid: Possible erosion of tooth enamel, inflammation of nose, throat & bronchial tubes. Lead Compounds: Anemia; neuropathy, particularly of the motor nerves, with wrist drop; kidney damage; reproductive changes in males and females. Repeated exposure to lead and lead compounds in the workplace REVISION DATE: 7/26/18 Page 6 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com may result in nervous system toxicity. Some toxicologists report abnormal conduction velocities in persons with blood lead levels of 50 g/100 ml or higher. Heavy lead exposure may result in central nervous system damage, encephalopathy and damage to the blood-forming (hematopoietic) tissues. Carcinogenicity: Sulfuric Acid: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mist containing sulfuric acid" as a Category I carcinogen, a substance that is carcinogenic to humans. This classification does not apply to liquid forms of sulfuric acid or sulfuric acid solutions contained within a battery. Inorganic acid mist (sulfuric acid mist) is not generated under normal use of this product. Misuse of the product, such as overcharging, may result in the generation of sulfuric acid mist. Lead Compounds: Lead is listed as a 2B carcinogen, likely in animals at extreme doses. Proof of carcinogenicity in humans is lacking at present. Arsenic: Listed by National Toxicology Program (NTP), International Agency for Research on Cancer (IARC), OSHA and NIOSH as a carcinogen only after prolonged exposure at high levels. Medical Conditions Generally Aggravated by Exposure: Overexposure to sulfuric acid mist may cause lung damage and aggravate pulmonary conditions. Contact of sulfuric acid with skin may aggravate diseases such as eczema and contact dermatitis. Lead and its compounds can aggravate some forms of kidney, liver and neurologic diseases. Acute Toxicity: Inhalation LD50: Electrolyte: LC50 rat: 375 mg/m3; LC50: guinea pig: 510 mg/m3 Elemental Lead: Acute Toxicity Point Estimate = 4500 ppmV (based on lead bullion) Elemental arsenic: No data Oral LD50: Electrolyte: rat: 2140 mg/kg Elemental lead: Acute Toxicity Estimate (ATE) = 500 mg/kg body weight (based on lead bullion) Elemental arsenic: LD50 mouse: 145 mg/kg Elemental Antimony: LD50 rat: 100 mg/kg Additional Health Data: All heavy metals, including the hazardous ingredients in this product, are taken into the body primarily by inhalation and ingestion. Most inhalation problems can be avoided by adequate precautions such as ventilation and respiratory protection covered in Section 8. Follow good personal hygiene to avoid inhalation and ingestion: wash hands, face, neck and arms thoroughly before eating, smoking or leaving the work site. Keep contaminated clothing out of non-contaminated areas, or wear cover clothing when in such areas. Restrict the use and presence of food, tobacco and cosmetics to non-contaminated areas. Work clothes and work equipment used in contaminated areas must remain in designated areas and never taken home or laundered with personal non-contaminated clothing. This product is intended for industrial use only and should be isolated from children and their environment. REVISION DATE: 7/26/18 Page 7 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com The 19th Amendment to EC Directive 67/548/EEC classified lead compounds, but not lead in metal form, as possibly toxic to reproduction. Risk phrase 61: May cause harm to the unborn child, applies to lead compounds, especially soluble forms. SECTION 12: ECOLOGICAL INFORMATION Environmental Fate: Lead is very persistent in soil and sediments. No data on environmental degradation. Mobility of metallic lead between ecological compartments is slow. Bioaccumulation of lead occurs in aquatic and terrestrial animals and plants but little bioaccumulation occurs through the food chain. Most studies include lead compounds and not elemental lead. Environmental Toxicity: Aquatic Toxicity: Sulfuric acid: 24-hr LC50, freshwater fish (Brachydanio rerio): 82 mg/L 96 hr- LOEC, freshwater fish (Cyprinus carpio): 22 mg/L Lead: 48 hr LC50 (modeled for aquatic invertebrates): <1 mg/L, based on lead bullion Arsenic: 24 hr LC50, freshwater fish (Carrassisus auratus) >5000 g/L. Additional Information No known effects on stratospheric ozone depletion. Volatile organic compounds: 0% (by Volume) Water Endangering Class (WGK): NA SECTION 13: DISPOSAL CONSIDERATIONS (UNITED STATES) Spent batteries: Send to secondary lead smelter for recycling. Spent lead-acid batteries are not regulated as hazardous waste when the requirements of 40 CFR Section 266.80 are met. Spilled sulfuric acid is a characteristic hazardous waste; EPA hazardous waste number D002 (corrosivity) and D008 (lead). Electrolyte: Place neutralized slurry into sealed acid resistant containers and dispose of as hazardous waste, as applicable. Large water diluted spills, after neutralization and testing, should be managed in accordance with approved local, state, and federal requirements. Consult state environmental agency and/or federal EPA. Following local, State/Provincial, and Federal/National regulations applicable to end-of-life characteristics will be the responsibility of the end-user. SECTION 14: TRANSPORT INFORMATION United States: The U.S. Department of Transportation (DOT) hazardous materials regulations (49 CFR) applicable to lead acid batteries are specified in 49 CFR 173.159. Proper Shipping Name: Hazard Class: Batteries, wet, filled with acid 8 REVISION DATE: 7/26/18 Page 8 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com ID Number: Packing Group: Labels: UN2794 N/A Corrosive 49 CFR 173.159(e) specifies that when transported by highway or rail, electric storage batteries containing electrolyte or corrosive battery fluid are not subject to any other requirements of this subchapter, if all of the following are met: (1) No other hazardous materials may be transported in the same vehicle; (2) The batteries must be loaded or braced so as to prevent damage and short circuits in transit; (3) Any other material loaded in the same vehicle must be blocked, braced, or otherwise secured to prevent contact with or damage to the batteries; and (4) The transport vehicle may not carry material shipped by any person other than the shipper of the batteries. If any of the above-referenced requirements are not met, the batteries must be shipped as fully-regulated Class 8 Corrosive hazardous materials. IATA Dangerous Goods Regulations (DGR): The shipping information is as follows: Proper Shipping Name: Batteries, wet, filled with acid Packing Group: N/A Hazardous Class: 8 Label/Placard Required: Corrosive UN Identification: UN2794 Reference IATA Packing Instruction 870 (IATA DGR 56th Edition) IMDG Code: The shipping information is as follows: Proper Shipping Name: Batteries, wet, filled with acid Packing Group: N/A Hazardous Class: 8 Label/Placard Required: Corrosive UN Identification: UN2794 Reference IMDG Code Packing Instruction P801 SECTION 15: REGULATORY INFORMATION UNITED STATES: EPA SARA Title III: Section 302 EPCRA Extremely Hazardous Substances (EHS): Sulfuric acid is a listed "Extremely Hazardous Substance" under EPCRA, with a Threshold Planning Quantity (TPQ) of 1,000 lbs. EPCRA Section 302 notification is required if 500 lbs or more of sulfuric acid is present at one site (40 CFR 370.10). For more information consult 40 CFR Part 355. REVISION DATE: 7/26/18 Page 9 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com Section 304 CERCLA Hazardous Substances: Reportable Quantity (RQ) for spilled 100% sulfuric acid under CERCLA (Superfund) and EPCRA (Emergency Planning and Community Right to Know Act) is 1,000 lbs. State and local reportable quantities for spilled sulfuric acid may vary. Section 311/312 Hazard Categorization: EPCRA Section 312 Tier Two reporting is required for non-automotive batteries if sulfuric acid is present in quantities of 500 lbs or more and/or if lead is present in quantities of 10,000 lbs or more. For more information consult 40 CFR 370.10 and 40 CFR 370.40 Section 313 EPCRA Toxic Substances: 40 CFR section 372.38 (b) states: If a toxic chemical is present in an article at a covered facility, a person is not required to consider the quantity of the toxic chemical present in such article when determining whether an applicable threshold has been met under 372.25, 372.27, or 372.28 or determining the amount of release to be reported under 372.30. This exemption applies whether the person received the article from another person or the person produced the article. However, this exemption applies only to the quantity of the toxic chemical present in the article. Supplier Notification: This product contains toxic chemicals that may be reportable under EPCRA Section 313 Toxic Chemical Release Inventory (Form R) requirements. For a manufacturing facility under SIC codes 20 through 39, the following information is provided to enable you to complete the required reports: Toxic Chemical Lead Sulfuric Acid/Water Solution Antimony Arsenic Tin CAS Number 7439-92-1 7664-93-9 7440-36-0 7440-38-2 7440-31-5 Approximate % by Weight 67 21 1 <0.01 <0.01 See 40 CFR Part 370 for more details. TSCA: TSCA Section 8b - Inventory Status: All chemicals comprising this product are either exempt or listed on the TSCA Inventory. TSCA Section 12b (40 CFR Part 707.60(b)) No notice of export will be required for articles, except PCB articles, unless the Agency so requires in the context of individual section 5, 6, or 7 actions. TSCA Section 13 (40 CFR Part 707.20): No import certification required (EPA 305-B-99-001, June 1999, Introduction to the Chemical Import Requirements of the Toxic Substances Control Act, Section IV.A) REVISION DATE: 7/26/18 Page 10 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com RCRA: Spent Lead Acid Batteries are subject to streamlined handling requirements when managed in compliance with 40 CFR section 266.80 or 40 CFR part 273. Waste sulfuric acid is a characteristic hazardous waste; EPA hazardous waste number D002 (corrosivity) and D008 (lead). STATE REGULATIONS (US): STATE REGULATIONS (US): *Proposition 65 Warning Battery posts, terminals and related accessories contain lead and lead compounds, chemicals known to the state of California to cause cancer and reproductive harm. Wash hands after handling. *Battery companies not party to the 1999 consent judgment with Mateel Environmental Justice Foundation should include a Proposition 65 Warning that complies with the current version of Proposition 65. INTERNATIONAL REGULATIONS: Distribution into Quebec to follow Canadian Controlled Product Regulations (CPR) 24(1) and 24(2). Distribution into the EU to follow applicable Directives to the Use, Import/Export of the product as-sold. SECTION 16: OTHER INFORMATION NFPA Hazard Rating for sulfuric acid: Flammability (Red) = 0 Health (Blue) = 3 Reactivity (Yellow) = 2 Sulfuric acid is water-reactive if concentrated. SOURCES OF INFORMATION: International Agency for Research on Cancer (1987), IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Overall Evaluations of Carcinogenicity: An updating of IARC Monographs Volumes 1-42, Supplement 7, Lyon, France. Ontario Ministry of Labor Regulation 654/86. Regulations Respecting Exposure to Chemical or Biological Agents. RTECS - Registry of Toxic Effects of Chemical Substances, National institute for Occupational Safety and Health. SDS PREPARATION INFORMATION: DATE OF ISSUE: 7/26/18 SUPERCEDES DATE: 2/26/18 REVISION DATE: 7/26/18 Page 11 of 12 Battery Builders, LLC. Battery Builders, LLC. PO Box 5005 Naperville, IL 60567| 31W238 91st St. Naperville, IL 60564 T: (630) 851-5800 | F: (630) 851-1040 | www.bbibattery.com DISCLAIMER: This Safety Data Sheet is based upon information and sources available at the time of preparation or revision date. Information in the SDS was obtained from sources which we believe are reliable but are beyond our direct supervision or control. We make no Warranty of Merchantability, Fitness for any particular purpose or any other Warranty, Expressed or Implied, with respect to such information and we assume no liability resulting from its use. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. It is the obligation of each user of this product to determine the suitability of this product and comply with the requirements of all applicable laws regarding use and disposal of this product. For additional information concerning Battery Builders, LLC. products or questions concerning the contents of this SDS please contact your Battery Builders representative. REVISION DATE: 7/26/18 Page 12 of 12 Battery Builders, LLC. Safety Data Sheet Revision Number: 006.7 Issue date: 09/10/2018 1. PRODUCT AND COMPANY IDENTIFICATION Product name: BONDERITE M-NT 1 CONVERSION COATING known as BONDERITE NT-1 Product type: Conversion coating Restriction of Use: None identified Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 IDH number: 611359 Region: United States Contact information: Telephone: +1 (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CONTAINS FLUORIDES. MAY CAUSE DELAYED BURNS (NOT IMMEDIATELY PAINFUL OR VISIBLE)! LONG TERM EXPOSURE TO FLUORIDES OVER YEARS MAY CAUSE FLUOROSIS! None Precautionary Statements Prevention: Response: Storage: Disposal: HAZARD CLASS PICTOGRAM(S) None Not prescribed Not prescribed Not prescribed Not prescribed HAZARD CATEGORY None Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) Hexafluorozirconic acid CAS Number 12021-95-3 Percentage* 0.1 - 1 * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. IDH number: 611359 Product name: BONDERITE M-NT 1 CONVERSION COATING known as BONDERITE NT-1 Page 1 of 5 Inhalation: Skin contact: Eye contact: Ingestion: Symptoms: Notes to physician: 4. FIRST AID MEASURES If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. Remove contaminated clothing and footwear. Get medical attention. Rinse with large amounts of running water. GET MEDICAL ATTENTION IMMEDIATELY! If iced 0.13% benzalkonium chloride (Zephiran) solution or 2.5% calcium gluconate gel are available, the rinsing may be limited to 5 minutes, with the soaks or gel applied as soon as the rinsing is stopped. If benzalkonium chloride or calcium gluconate gel is not available, rinsing must continue until medical treatment is provided. In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Get immediate medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. See Section 11. Ocular exposure to corrosive fluoride compounds has been treated with isotonic sodium chloride or magnesium chloride. Dermal exposure to corrosive fluoride compounds has been treated with calcium gluconate or calcium carbonate gel applied topically to the affected areas to relieve pain at the site of exposure. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Water spray (fog), foam, dry chemical or carbon dioxide. Wear full protective clothing. Wear self-contained breathing apparatus. May liberate large quantities of dense, foul-smelling smoke which may contain unidentified toxic gasses. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Oxides of nitrogen. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spillage if safe to do so. Wear appropriate protective equipment and clothing during clean-up. Do not allow product to enter sewer or waterways. Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. IDH number: 611359 Product name: BONDERITE M-NT 1 CONVERSION COATING known as BONDERITE NT-1 Page 2 of 5 7. HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing vapors or mists of this product. Use only with adequate ventilation. Do not take internally. For industrial use only. Storage: For safe storage, store between 40 F (4.4 C) and 110 F (43.3 C) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Protect from freezing. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) Hexafluorozirconic acid ACGIH TLV 5 mg/m3 TWA (as Zr) 10 mg/m3 STEL (as Zr) OSHA PEL 5 mg/m3 PEL (as Zr) AIHA WEEL None OTHER None Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Wear chemical goggles; face shield (if splashing is possible). Chemical resistant, impermeable gloves. Gloves should be tested to determine suitability for prolonged contact. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: pH: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Viscosity: Decomposition temperature: Liquid Clear to slightly hazy Mild Not available. 2.2 - 2.4 Not determined > 98.9 C (> 210F) Not determined 1.00 - 1.01 at 15.6 C Not determined Not applicable Not applicable Not applicable Not applicable Not applicable Not available. Disperses in water as Not determined Not available. Not available. Not available. (60.08 F) a suspension IDH number: 611359 Product name: BONDERITE M-NT 1 CONVERSION COATING known as BONDERITE NT-1 Page 3 of 5 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of storage and use. Hazardous reactions: None under normal processing. Hazardous decomposition products: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Oxides of nitrogen. Hydrogen fluoride Incompatible materials: Avoid contact with organic materials, oils, greases, and any oxidizable materials. This product may react with strong alkalies. Reactivity: Not available. Conditions to avoid: Keep away from heat, ignition sources and incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Mists, vapors or liquid may cause severe irritation or burns. Inhalation of mists or vapors may produce upper airway edema, wheezing, pulmonary edema, pneumonitis and respiratory failure. Contains fluorides. Exposure to fluorides over years may cause fluorosis. May cause mild to severe skin irritation. Liquid or vapor can cause fluoride-type irritation or burns which may not be immediately painful or visible. Following skin exposure to this product, the sensation of irritation or pain may be delayed. This product may be severely irritating to the eyes. Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea. Hazardous Component(s) Hexafluorozirconic acid LD50s and LC50s None Immediate and Delayed Health Effects No Records Hazardous Component(s) Hexafluorozirconic acid NTP Carcinogen No IARC Carcinogen No OSHA Carcinogen (Specifically Regulated) No 12. ECOLOGICAL INFORMATION Ecological information: Do not empty into drains / surface water / ground water. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. Wastes must be tested using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of hazardous wastes. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) IDH number: 611359 Product name: BONDERITE M-NT 1 CONVERSION COATING known as BONDERITE NT-1 Page 4 of 5 Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated None None None International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated None None None Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated None None None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimis None above reporting de minimis. Immediate Health, Delayed Health None above reporting de minimis. No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Regulatory Affairs Issue date: 09/10/2018 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ("Henkel") does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel's products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel's products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: 611359 Product name: BONDERITE M-NT 1 CONVERSION COATING known as BONDERITE NT-1 Page 5 of 5 Safety Data Sheet Carbon Dioxide Section 1: Product and Company Identification Cee Kay Supply, Inc 5835 Manchester Avenue Saint Louis, MO 63110 www.CeeKay.com (314) 644-3500 Product Code: Carbon Dioxide Section 2: Hazards Identification Hazard Classification: Gases Under Pressure Hazard Statements: Contains gas under pressure; may explode if heated Precautionary Statements Storage: Protect from sunlight. Store in well-ventilated place. Warning Section 3: Composition/Information on Ingredients CAS # 124-38-9 Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 1 of 5 Generated: 10/05/2017 10:19:48 Chemical Substance CARBON DIOXIDE, GAS Chemical Family Inorganic gases Trade Names CARBONIC ACID GAS; CARBONIC ANHYDRIDE; CARBON DIOXIDE; CARBON OXIDE; UN 1013; CO2 Section 4: First Aid Measures Skin Contact If frostbite or freezing occur, immediately flush with plenty of lukewarm water (105-115 F; 41-46 C). DO NOT USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical attention. Eye Contact Contact with liquid: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. Ingestion Do not induce vomiting. Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. Note to Physicians For inhalation, consider oxygen. Section 5: Fire Fighting Measures Suitable Extinguishing Media Non-flammable Products of Combustion Non-flammable Protection of Firefighters Any appropriate escape-type, self-contained breathing apparatus. Non-flammable Section 6: Accidental Release Measures Personal Precautions Environmental Precautions Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Do not touch spilled material. Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers. Methods for Cleanup Stop leak, evacuate, remove source of ignition. Other Information None Methods for Containment Stop leak if possible without personal risk. Section 7: Handling and Storage Handling Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from incompatible substances. Storage Store and handle in accordance with all current regulations and standards Section 8: Exposure Controls/Personal Protection Exposure Guidelines CARBON DIOXIDE, GAS: CARBON DIOXIDE: 5000 ppm (9000 mg/m3) OSHA TWA 10000 ppm (18000 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30, 1993) 30000 ppm (54000 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30, 1993) 5000 ppm ACGIH TWA 30000 ppm ACGIH STEL 5000 ppm (9000 mg/m3) NIOSH recommended TWA 10 hour(s) 30000 ppm (54000 mg/m3) NIOSH recommended STEL Engineering Controls Handle only in fully enclosed systems. Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 2 of 5 Generated: 10/05/2017 10:19:48 Eye Protection For the gas: Eye protection not required, but recommended. For the liquid: Wear splash resistant safety goggles. Contact lenses should not be worn. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. General Hygiene considerations Avoid breathing vapor or mist Avoid contact with eyes and skin Wash thoroughly after handling and before eating or drinking Skin Protection For the gas: Protective clothing is not required. For the liquid: Wear appropriate protective, cold insulating clothing. Respiratory Protection Any appropriate escapetype, self-contained breathing apparatus. Section 9: Physical and Chemical Properties Physical State Appearance Color Change in Appearance Physical Form Odor Taste Gas Colorless Colorless N/A Gas Odorless Acid taste Flash Point Not flammable Flammability Not available Partition Coefficient N/A Autoignition Temperature Nonflammable Upper Explosive Limits Nonflammable Lower Explosive Limits Nonflammable Boiling Point Not available Freezing Point -71 F (-57 C) @ 4000 mmHg Vapor Pressure 43700 mmHg @ 21 C Vapor Density 1.5 (Air=1) Specific Gravity 1.522 @ 21 C Water Solubility Soluble pH 3.7 (saturated aqueous solution) @ 101.3 kPa (carbonic acid) Odor Threshold Not available Evaporation Rate Not applicable Viscosity 0.01657 cP @ 0 C Molecular Weight 44.01 Molecular Formula C-O2 Density 0.114 Weight per Gallon Not available Volatility by Volume Not applicable Volatility Not applicable Solvent Solubility Soluble: Alcohol, acetone, hydrocarbons, organic solvents Section 10: Stability and Reactivity Stability Stable at normal temperatures and pressure. Conditions to Avoid Stable at normal temperatures and pressure. Incompatible Materials Combustible materials, oxidizing materials, metal salts, reducing agents, metal carbide, metals, bases Hazardous Decomposition Products Carbon monoxide Possibility of Hazardous Reactions Will not polymerize. Section 11: Toxicology Information Acute Effects Oral LD50 Dermal LD50 Not established Not established Inhalation Ringing in the ears, nausea, irregular heartbeat, headache, drowsiness, dizziness, tingling sensation, visual disturbances, suffocation, convulsions, coma Eye Irritation Irritation, frostbite, blurred vision Skin Irritation Liquid: blisters, frostbite Sensitization Difficulty breathing Chronic Effects Carcinogenicity Mutagenicity Not available Not established Reproductive Effects Available. Developmental Effects No data Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 3 of 5 Generated: 10/05/2017 10:19:48 Section 12: Ecological Information Fate and Transport Eco toxicity Fish toxicity: 150000 ug/L 48 day(s) (Mortality) Brown trout (Salmo trutta) Invertibrate toxicity: Not available Algal toxicity: Not available Phyto toxicity: Not available Other toxicity: Not available Persistence / Degradability Relatively non-persistent in the environment. Moderately volatile from water. Section 13: Disposal Considerations Dispose in accordance with all applicable regulations. Section 14: Transportation Information U.S. DOT 49 CFR 172.101 Bioaccumulation / Accumulation Accumulates very little in the bodies of living organisms. Mobility in Environment Leaches through the soil Proper Shipping Name Carbon dioxide ID Number UN1013 Hazard Class or Division 2.2 Packing Group Not applicable Labeling Requirements 2.2 Canadian Transportation of Dangerous Goods Shipping Name UN Number Class Packing Group / Risk Group Carbon dioxide UN1013 2.2 Not applicable Passenger Aircraft or Railcar Quantity Limitations 75 kg or L Cargo Aircraft Only Quantity Limitations 150kg Section 15: Regulatory Information U.S. Regulations CERCLA Sections SARA 355.30 Not regulated. Not regulated. SARA 355.40 Not regulated. SARA 370.21 Acute Chronic Fire Reactive Sudden Release Yes No No No Yes SARA 372.65 Not regulated. OSHA Process Safety Not regulated. State Regulations CA Proposition 65 Not regulated. Canadian Regulations WHMIS Classification A Additional Shipping Description None Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 4 of 5 Generated: 10/05/2017 10:19:48 National Inventory Status US Inventory (TSCA) TSCA 12b Export Notification Listed on inventory. Not listed. Canada Inventory (DSL/NDSL) Listed on inventory. Section 16: Other Information NFPA Rating HEALTH=2 FIRE=0 REACTIVITY=0 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 5 of 5 Generated: 10/05/2017 10:19:48 COLD ROLLED, HOT ROLLED AND ENAMELING STEEL Safety Data Sheet (SDS) Section 1 - Identification 1(a) Product Identifier used on Label: Cold Rolled, Hot Rolled Steel and Enameling Steel 1(b) Other means of identification: AKS-005, Refer to Section 16 for other synonyms 1(c) Recommended use of the chemical and restrictions on use: None 1(d) Name, address, and telephone number: AK Steel 9227 Centre Point Drive West Chester, Ohio 45069 Phone number : 513 425-5000 (information) 513 425-5104 (Health & Safety) 1(e) Emergency phone number: 800 331-5050 Section 2 - Hazard(s) Identification 2(a) Classification of the chemical: Cold Rolled, Hot Rolled Steel and Enameling Steel is considered an article under Reach regulation (REACH REGULATION (EC) No 1907/2006) and is not subject to classification under CLP regulation (REGULATION (EC) No 1272/2008). However, Cold Rolled, Hot Rolled Steel and Enameling Steel is not exempt as an article under OSHA's Hazard Communication Standard (29 CFR 1910.1200) due to its downstream use, thus this product is considered a mixture and a hazardous material. Therefore, the categories of Health Hazards as defined in "GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS (GHS), Third revised edition ST/SG/AC.10/30/Rev. 3" United Nations, New York and Geneva, 2009 have been evaluated. Refer to Section 3, 8 and 11 for additional information. 2(b) Signal word, hazard statement(s), symbols and precautionary statement(s): Hazard Symbol Hazard Classification Signal Word Hazard Statement(s) Carcinogenicity - 2 Reproductive Toxicity - 2 Single Target Organ Toxicity (STOT) Repeat Exposure -1 Acute Toxicity-Oral - 4 Skin Sensitization - 1 STOT Single Exposure - 3 Danger Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to lungs and central nervous system through prolonged or repeated inhalation exposure. Harmful if swallowed. May cause an allergic skin reaction. May cause respiratory irritation. NA Eye Irritation - 2B Causes eye irritation. Precautionary Statement(s): Prevention Do not breathe dusts / fume / gas / mist / vapor / spray. Wear protective gloves / protective clothing / eye protection / face protection. Contaminated work clothing must not be allowed out of the workplace. Use only outdoors or in well ventilated areas. Wash thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not eat, drink or smoke when using this product. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If exposed, concerned or feel unwell: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue Rinsing. If eye irritation persists: Get medical advice/attention. If on skin: Wash with plenty of water. If irritation or rash occurs: Get medical advice/attention. Take off and wash contaminated clothing before reuse. If swallowed: Call a poison center or doctor/physician if you feel unwell. Rinse mouth. 2(c) Hazards not otherwise classified: None Known 2(d) Unknown acute toxicity statement (mixture): None Known Storage/Disposal Dispose of contents in accordance with federal, state and local regulations. Section 3 - Composition/Information on Ingredients 3(a-c) Chemical name, common name (synonyms), CAS number and other identifiers, and concentration: Chemical Name Iron CAS Number 7439-89-6 EC Number 231-096-4 Chromium 7440-47-3 231-157-5 Manganese 7439-96-5 231-105-1 % by weight >95 1.10 (max) <2.0 Page 1 of 1 Cold Rolled, Hot Rolled and Enameling Steel Safety Data Sheet Date: 3/06/2015 SDS Code #: AKS-005 Section 3 - Composition/Information on Ingredients (continued) 3(a-c) Chemical name, common name (synonyms), CAS number and other identifiers, and concentration (continued): Chemical Name Nickel CAS Number 7440-02-0 EC Number 231-111-4 % by weight 0.6 (max) Silicon 7440-21-3 231-130-8 <1.0 EC - European Community CAS - Chemical Abstract Service Notes: Commercial steel products contain small amounts of various elements in addition to those specified. These small quantities frequently referred to as "trace" or "residual" elements, generally originate in the raw materials used and/or are alloying metals. Individual trace elements vary in concentration by weight, and may include aluminum, boron, calcium, carbon, columbium (niobium), copper, molybdenum, phosphorus, sulfur, titanium, and vanadium. Percentages are expressed as typical ranges or maximum concentrations of trace elements for the purpose of communicating the potential hazards of the finished product. Consult product specifications for specific composition information. The product may have a light coating of oil to prevent corrosion. * Steel products as provided contain chromium metal in the zero valence state. As such, chromium metal does not present any unusual health hazard. Hence, the most applicable exposure limits relative to chromium in these products are those established for the metal, itself. However, welding, torch cutting, brazing or perhaps grinding of the chromium metal in steel products may generate airborne concentrations of hexavalent chromium, (Cr VI), a confirmed human carcinogen. Therefore, should the user perform any of these tasks, the hexavalent chromium exposure limits would apply. Section 4 - First-aid Measures 4(a) Description of necessary measures: Inhalation: Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped is not a likely form of exposure. However during further processing (welding, grinding, burning, etc.), if inhaled: Remove person to fresh air and keep comfortable for breathing. If exposed, concerned or feel unwell: Get medical advice/attention. Eye Contact: Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped is not a likely form of exposure. However during further processing (welding, grinding, burning, etc.), if in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue Rinsing. If eye irritation persists: Get medical advice attention. If exposed, concerned or feel unwell: Get medical advice/attention. Skin Contact: If on skin: Wash thoroughly after handling. Wash with plenty of water. If irritation or rash occurs: Get medical advice/attention. Take off and wash contaminated clothing before reuse. If exposed, concerned or feel unwell: Get medical advice/attention. Ingestion: Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped is not a likely form of exposure. However during further processing (welding, grinding, burning, etc.), if swallowed: Call a poison center or doctor/physician if you feel unwell. Rinse mouth. If exposed, concerned or feel unwell: Get medical advice/attention. 4(b) Most important symptoms/effects, acute and delayed (chronic): Inhalation: Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped is not likely to present an acute or chronic health effect. Eye: Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped is not likely to present an acute or chronic health effect. Skin: Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped is not likely to present an acute or chronic health effect. Ingestion: Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped is not likely to present an acute or chronic health effect. However during further processing (welding, grinding, burning, etc.) individual components may illicit an acute or chronic health effect. Refer to Section 11-Toxicological Information. 4(c) Immediate Medical Attention and Special Treatment: None Known Section 5 - Fire-fighting Measures 5(a) Suitable (and unsuitable) Extinguishing Media: Not Applicable for Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped. Use extinguishers appropriate for surrounding materials. 5(b) Specific Hazards arising from the chemical: Not Applicable for Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped. When burned, toxic smoke, fume and vapor may be emitted. 5(c) Special protective equipment and precautions for fire-fighters: Self-contained NIOSH approved respiratory protection and full protective clothing should be worn when fumes and/or smoke from fire are present. Heat and flames cause emittance of acrid smoke and fumes. Do not release runoff from fire control methods to sewers or waterways. Firefighters should wear full face-piece self-contained breathing apparatus and chemical protective clothing with thermal protection. Direct water stream will scatter and spread flames and, therefore, should not be used. Section 6 - Accidental Release Measures 6(a) Personal Precautions, Protective Equipment and Emergency Procedures: Not Applicable for Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped. For spills involving finely divided particles, clean-up personnel should be protected against contact with eyes and skin. If material is in a dry state, avoid inhalation of dust. 6(b) Methods and materials for containment and clean up: Not Applicable for Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped. Collect material in appropriate, labeled containers for recovery or disposal in accordance with federal, state, and local regulations. Follow applicable OSHA regulations (29 CFR 1910.120) and all other pertinent state and federal requirements. Page 2 of 2 Cold Rolled, Hot Rolled and Enameling Steel Safety Data Sheet Date: 3/06/2015 SDS Code #: AKS-005 Section 7 - Handling and Storage 7(a) Precautions for safe handling: Not Applicable for Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped, however further processing (welding, burning, grinding, etc.) with the potential for generating high concentrations of airborne particulates should be evaluated and controlled as necessary. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only outdoors or in well ventilated areas. Practice good housekeeping. Avoid breathing metal fumes and/or dust. Do not eat, drink or smoke when using this product. Cut resistant gloves and sleeves should be worn when working with steel products. 7(b) Conditions for safe storage, including any incompatibilities: Store away from acids and incompatible materials. Section 8 - Exposure Controls / Personal Protection 8(a) Occupational Exposure Limits (OELs): Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped in its physical form does not present an inhalation, ingestion or contact hazard, nor would any of the following exposure data apply. However, operations such as burning, welding (high temperature), sawing, brazing, machining, grinding, etc. may produce fumes and/or particulates. The following exposure limits are offered as reference for an experienced industrial hygienist to review. Ingredients Iron OSHA PEL 1 10 mg/m (as iron oxide fume) ACGIH TLV 2 5.0 mg/m (as iron oxide dust and fume) NIOSH REL 3 5.0 mg/m (as iron oxide dust and fume) IDLH 4 2,500 mg Fe/m3 Chromium 0.5 mg/m (as Cr II & III, inorganic compounds) 0.5 mg/m (as Cr III, inorganic compounds) 0.5 mg/m (as Cr II & III, inorganic compounds) 250 mg/m (as Cr II & metal) 1.0 mg/m (as Cr, metal) 0.5 mg/m (as Cr, metal) 0.5 mg/m (as Cr, metal) 25 mg/m (as Cr III) Manganese 0.005 mg/m (as Cr VI, inorganic compounds & certain water insoluble) "AL" 0.0025 mg/m (as Cr VI, inorganic compounds & certain water insoluble) (C) 5.0 mg/m (as Fume & Mn compounds) 0.05 mg/m (as Cr VI, inorganic compounds) 0.01 mg/m (as Cr VI, inorganic compounds & certain water insoluble) 0.2 mg/m 0.001 mg/m (as Cr VI, inorganic compounds & certain water insoluble) (C) 5.0 mg/m 1.0 mg/m (as fume) 15 mg/m (as Cr VI) 500 mg Mn/m3 Nickel Silicon 1.0 mg/m (as Ni metal & insoluble compounds) 15 mg/m (total dust, PNOR6) 1.5 mg/m (as inhalable fraction5 Ni metal) 0.2 mg/m (as inhalable fraction Ni inorganic only insoluble and soluble compounds) 10 mg/m (STEL) 3.0 mg/m 0.015 mg/m (as Ni metal & insoluble and soluble compounds) 10 mg/m (as total dust) 10 mg/m (as Ni) NE 5.0 mg/m (as respirable fraction, PNOR) 5.0 mg/m (as respirable dust) NE - None Established 1. OSHA Permissible Exposure Limits (PELs) are 8-hour TWA (time-weighted average) concentrations unless otherwise noted. A (C) designation denotes a ceiling limit, which should not be exceeded during any part of the working exposure unless otherwise noted. A Peak is defined as the acceptable maximum peak for a maximum duration above the ceiling concentration for an eight-hour shift. A skin notation refers to the potential significant contribution to the overall exposure by the cutaneous route, either by contact with vapors or, of probable greater significance, by direct skin contact with the substance. A Short Term Exposure Limit (STEL) is defined as a 15-minute exposure, which should not be exceeded at any time during a workday. An Action level (AL) is used by OSHA and NIOSH to express a health or physical hazard. They indicate the level of a harmful or toxic substance/activity, which requires medical surveillance, increased industrial hygiene monitoring, or biological monitoring. Action Levels are generally set at one half of the PEL but the actual level may vary from standard to standard. The intent is to identify a level at which the vast majority of randomly sampled exposures will be below the PEL. 2. Threshold Limit Values (TLV) established by the American Conference of Governmental Industrial Hygienists (ACGIH) are 8-hour TWA concentrations unless otherwise noted. A Short Term Exposure Limit (STEL) is defined as the maximum concentration to which workers can be exposed for a short period of time (15 minutes) for only four times throughout the day with at least one hour between exposures. A "skin" notation refers to the potential significant contribution to the overall exposure by the cutaneous route, either by contact with vapors or, of probable greater significance, by direct skin contact with the substance. ACGIH-TLVs are only recommended guidelines based upon consensus agreement of the membership of the ACGIH. As such, the ACGIH TLVs are for guideline use purposes and are not legal regulatory standards for compliance purposes. The TLVs are designed for use by individuals trained in the discipline of industrial hygiene relative to the evaluation of exposure to various chemical or biological substances and physical agents that may be found in the workplace. 3. The National Institute for Occupational Safety and Health Recommended Exposure Limits (NIOSH-REL) - Compendium of Policy and Statements. NIOSH, Cincinnati, OH (1992). NIOSH is the federal agency designated to conduct research relative to occupational safety and health. As is the case with ACGIH TLVs, NIOSH RELs are for guideline purposes only and as such are not legal, regulatory limits for compliance purposes. 4. The "immediately dangerous to life or health air concentration values (IDLHs)" are used by NIOSH as part of the respirator selection criteria and were first developed in the mid1970's by NIOSH. The Documentation for Immediately Dangerous to Life or Health Concentrations (IDLHs) is a compilation of the rationale and sources of information used by NIOSH during the original determination of 387 IDLHs and their subsequent review and revision in 1994. 5. Inhalable fraction. The concentration of inhalable particulate for the application of this TLV is to be determined from the fraction passing a size-selector with the characteristics defined in the ACGIH 2014 TLVs and BEIs (Biological Exposure Indices) Appendix D, paragraph A. 6. PNOR (Particulates Not Otherwise Regulated). All inert or nuisance dusts, whether mineral, inorganic, or organic, not listed specifically by substance name are covered by a limit which is the same as the inert or nuisance dust limit of 15 mg/m3 for total dust and 5 mg/m3 for the respirable fraction. 8(b) Appropriate Engineering Controls: Use controls as appropriate to minimize exposure to metal fumes and dusts during handling operations. Provide general or local exhaust ventilation systems to minimize airborne concentrations. Local exhaust is necessary for use in enclosed or confined spaces. Provide sufficient general/local exhaust ventilation in pattern/volume to control inhalation exposures below current exposure limits. 8(c) Individual Protection Measures: Respiratory Protection: Seek professional advice prior to respirator selection and use. Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, use only a NIOSH-approved respirator. Select respirator based on its suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of sufficient oxygen. Concentration in air ... Page 3 of 3 Cold Rolled, Hot Rolled and Enameling Steel Safety Data Sheet Date: 3/06/2015 SDS Code #: AKS-005 Section 8 - Exposure Controls / Personal Protection (continued) 8(c) Individual Protection Measures (continued): Respiratory Protection (continued): ... of the various contaminants determines the extent of respiratory protection needed. Half-face, negative-pressure, air-purifying respirator equipped with P100 filter is acceptable for concentrations up to 10 times the exposure limit. Fullface, negative-pressure, air-purifying respirator equipped with P100 filter is acceptable for concentrations up to 50 times the exposure limit. Protection by air-purifying negative-pressure and powered air respirators is limited. Use a positive-pressure-demand, full-face, supplied air respirator or self-contained breathing apparatus (SCBA) for concentrations above 50 times the exposure limit. If exposure is above the IDLH (Immediately dangerous to life or health) for any of the constituents, or there is a possibility of an uncontrolled release or exposure levels are unknown, then use a positive-demand, full-face, supplied air respirator with escape bottle or SCBA. Warning! Air-purifying respirators both negative-pressure, and powered-air do not protect workers in oxygen-deficient atmospheres. Eyes: Wear appropriate eye protection to prevent eye contact. For operations which result in elevating the temperature of the product to or above its melting point or result in the generation of airborne particulates, use safety glasses to prevent eye contact. Contact lenses should not be worn where industrial exposures to this material are likely. Use safety glasses or goggles as required for welding, burning, sawing, brazing, grinding or machining operations. Skin: Wear appropriate personal protective clothing to prevent skin contact. Cut resistant gloves and sleeves should be worn when working with steel products. For operations which result in elevating the temperature of the product to or above its melting point or result in the generation of airborne particulates, use protective clothing, and gloves to prevent skin contact. Protective gloves should be worn as required for welding, burning or handling operations. Contaminated work clothing must not be allowed out of the workplace. Other protective equipment: An eyewash fountain and deluge shower should be readily available in the work area. Section 9 - Physical and Chemical Properties 9(a) Appearance (physical state, color, etc.): Solid, Metallic Gray 9(b) Odor: Odorless 9(c) Odor Threshold: NA 9(d) pH: NA 9(e) Melting Point/Freezing Point: 2795 F, 1530 C (Approximate) 9(f) Initial Boiling Point and Boiling Range: ND 9(g) Flash Point: NA 9(h) Evaporation Rate: NA 9(i) Flammability (solid, gas): Non-flammable, non-combustible NA - Not Applicable ND - Not Determined for product as a whole 9(j) Upper/lower Flammability or Explosive Limits: NA 9(k) Vapor Pressure: NA 9(l) Vapor Density (Air = 1): NA 9(m) Relative Density: >1.0 SG 9(n) Solubility(ies): Water Insoluble 9(o) Partition Coefficient n-octanol/water: ND 9(p) Auto-ignition Temperature: NA 9(q) Decomposition Temperature: ND 9(r) Viscosity: NA Section 10 - Stability and Reactivity 10(a) Reactivity: Not Determined (ND) for product in a solid form. Do not use water on molten metal. 10(b) Chemical Stability: Steel products are stable under normal storage and handling conditions. 10(c) Possibility of hazardous reaction: None Known 10(d) Conditions to Avoid: Storage with strong acids or calcium hypochlorite. 10(e) Incompatible Materials: Will react with strong acids to form hydrogen. Iron oxide dusts in contact with calcium hypochlorite evolve oxygen and may cause an explosion. 10(f) Hazardous Decomposition Products: Thermal oxidative decomposition of steel products can produce fumes containing oxides of iron and manganese as well as other alloying elements. Section 11 - Toxicological Information 11(a-e) Information on toxicological effects: The following toxicity data has been determined for Cold Rolled, Hot Rolled Steel and Enameling Steel when further processed using the information available for its components applied to the guidance on the preparation of an SDS under the GHS requirements of OSHA and the EU CPL: Hazard Classification Hazard Category EU OSHA Hazard Symbols Signal Word Hazard Statement Acute Toxicity Hazard (covers Categories 1-4) NA* 4a Warning Harmful if swallowed. Eye Damage/ Irritation (covers Categories 1, 2A and 2B) NA* 2Bc No Pictogram Warning Causes eye irritation. Skin/Dermal Sensitization (covers Category 1) NA* 1d Warning May cause an allergic skin reaction. Page 4 of 4 Cold Rolled, Hot Rolled and Enameling Steel Safety Data Sheet Date: 3/06/2015 SDS Code #: AKS-005 Section 11 - Toxicological Information (continued) 11(a-e) Information on toxicological effects (continued): Hazard Classification Hazard Category EU OSHA Hazard Symbols Carcinogenicity (covers Categories 1A, 1B and 2) NA* 2g Signal Word Warning Hazard Statement Suspected of causing cancer. Toxic Reproduction (covers Categories 1A, 1B and 2) NA* 2h Warning Suspected of damaging fertility or the unborn child. Specific Target Organ Toxicity (STOT) Following Single Exposure NA* 3i (covers Categories 1-3) STOT following Repeated Exposure (covers Categories 1 and 2) NA* 1j Warning May cause respiratory irritation. Danger Causes damage to lungs and central nervous system through prolonged or repeated inhalation exposure. * Not Applicable - Semi-formed steel products are considered articles under Reach regulation (REACH REGULATION (EC) No 1907/2006) and are not subject to classification under CLP regulation (REGULATION (EC) No 1272/2008). Toxicological data listed below are presented regardless to classification criteria. Individual hazard classification categories where the toxicological information has met or exceeded a classification criteria threshold are listed above. a. No LC50 or LD50 has been established for Cold Rolled, Hot Rolled Steel and Enameling Steel. The following data has been determined for the components: Iron: Rat LD50 =98.6 g/kg (REACH) Rat LD50 =1060 mg/kg (IUCLID) Rat LD50 =984 mg/kg (IUCLID) Rabbit LD50 =890 mg/kg (IUCLID) Guinea Pig LD50 =20 g/kg (TOXNET) Nickel: LD50 >9000 mg/kg (Oral/Rat) Silicon: LD50 = 3160 mg/kg (Oral/Rat) Manganese: Rat LD50 > 2000 mg/kg (REACH) Rat LD50 > 9000 mg/kg (NLM Toxnet) b. No Skin (Dermal) Irritation data available for Cold Rolled, Hot Rolled Steel and Enameling Steel as a as a mixture or its individual components. c. No Eye Irritation data available for Cold Rolled, Hot Rolled Steel and Enameling Steel as a mixture. The following Eye Irritation information was found for the components: Iron: Causes eye irritation. Silicon: Slight eye irritation in rabbit protocol. Nickel: Slight eye irritation from particulate abrasion only. d. No Skin (Dermal) Sensitization data available for Cold Rolled, Hot Rolled Steel and Enameling Steel as a mixture. The following Skin (Dermal) Sensitization information was found for the components: Nickel: May cause allergic skin sensitization. e. No Respiratory Sensitization data available for Cold Rolled, Hot Rolled Steel and Enameling Steel as a mixture or its components. f. No Germ Cell Mutagenicity data available for Cold Rolled, Hot Rolled Steel and Enameling Steel as a mixture. The following Mutagenicity and Genotoxicity information was found for the components: Iron: IUCLID has found some positive and negative findings in vitro. Nickel: EU RAR has found positive results in vitro and in vivo but insufficient data for classification. g. Carcinogenicity: IARC, NTP, and OSHA do not list Cold Rolled, Hot Rolled Steel and Enameling Steel as carcinogens. The following Carcinogenicity information was found for the components: Welding Fumes - IARC Group 2B carcinogen, a mixture that is possibly carcinogenic to humans. Chromium (as metal and trivalent chromium compounds) - IARC Group 3 carcinogens, not classifiable as to their human carcinogenicity. Nickel and certain nickel compounds - Group 2B - metallic nickel Group 1 - nickel compounds ACGIH confirmed human carcinogen. Nickel - EURAR Insufficient evidence to conclude carcinogenic potential in animals or humans; suspect carcinogen classification Category 2 Suspected of causing cancer. h. No Toxic Reproduction data available for Cold Rolled, Hot Rolled Steel and Enameling Steel as a mixture. The following Toxic Reproductive information was found for the components: Nickel: Effects on fertility. i. No Specific Target Organ Toxicity (STOT) following a Single Exposure data available for Cold Rolled, Hot Rolled Steel and Enameling Steel as a mixture. The following STOT following a Single Exposure data was found for the components: Iron: Irritating to Respiratory tract. j. No Specific Target Organ Toxicity (STOT) following Repeated Exposure data was available for Cold Rolled, Hot Rolled Steel and Enameling Steel as a whole. The following STOT following Repeated Exposure data was found for the components: Nickel: Rat 4 wk inhalation LOEL 4 mg/m3 Lung and Lymph node histopathology. Rat 2 yr inhalation LOEL 0.1 mg/ m3 Pigment in kidney, effects on hematopoiesis spleen and bone marrow and adrenal tumor. Rat 13 Week Inhalation LOAEC 1.0 mg/m3 Lung weights, and Alveolar histopathology. Manganese: Inhalation of metal fumes - Degenerative changes in human Brain; Behavioral: Changes in motor activity and muscle weakness (Whitlock et al., 1966). Page 5 of 5 Cold Rolled, Hot Rolled and Enameling Steel Safety Data Sheet Date: 3/06/2015 SDS Code #: AKS-005 Section 11 - Toxicological Information (continued) The above toxicity information was determined from available scientific sources to illustrate the prevailing posture of the scientific community. The scientific resources includes: The American Conference of Governmental Industrial Hygienist (ACGIH) Documentation of the Threshold Limit Values (TLVs) and Biological Exposure indices (BEIs) with Other Worldwide Occupational Exposure Values 2009, The International Agency for Research on Cancer (IARC), The National Toxicology Program (NTP) updated documentation, the World Health Organization (WHO) and other available resources, the International Uniform Chemical Information Database (IUCLID), European Union Risk Assessment Report (EU-RAR), Concise International Chemical Assessment Documents (CICAD), European Union Scientific Committee for Occupational Exposure Limits (EU-SCOEL), Agency for Toxic Substances and Disease Registry (ATSDR), Hazardous Substance Data Bank (HSDB), and International Programme on Chemical Safety (IPCS). The following health hazard information is provided regardless to classification criteria and is based on the individual component(s) and potential resultant components from further processing: Acute Effects: Inhalation: Excessive exposure to high concentrations of metal dust may cause irritation to the eyes, skin and mucous membranes of the upper respiratory tract. Excessive inhalation of fumes of freshly formed metal oxide particles sized below 1.5 micrometer and usually between 0.02-0.05 micrometers from many metals can produce an acute reaction known as "metal fume fever". Symptoms consist of chills and fever (very similar to and easily confused with flu symptoms), metallic taste in the mouth, dryness and irritation of the throat followed by weakness and muscle pain. The symptoms come on in a few hours after excessive exposures and usually last from 12 to 48 hours. Long-term effects from metal fume fever have not been noted. Freshly formed oxide fumes of manganese and copper have been associated with causing metal fume fever. Eye: Excessive exposure to high concentrations of metal dust may cause irritation to the eyes. Skin: Skin contact with metal dusts may cause irritation or sensitization, possibly leading to dermatitis. Skin contact with metallic fumes and dusts may cause physical abrasion. Ingestion: Ingestion of harmful amounts of this product as distributed is unlikely due to its solid insoluble form. Ingestion of metal dust may cause nausea or vomiting. Acute Effects by component: Iron and iron oxides: Iron is harmful if swallowed, causes skin irritation, and causes eye irritation. Contact with iron oxide has been reported to cause skin irritation and serious eye damage. Particles of iron or iron compounds, which become imbedded in the eye, may cause rust stains unless removed fairly promptly. Chromium, chromium oxides and hexavalent chrome: Hexavalent chrome causes damage to gastrointestinal tract, lung, severe skin burns and eye damage, serious eye damage, skin contact may cause an allergic skin reaction. Inhalation may cause allergic or asthmatic symptoms or breathing difficulties. Manganese and manganese oxides: Manganese and Manganese oxide is harmful if swallowed. Nickel and nickel oxides: Nickel may cause allergic skin sensitization. Nickel oxide may cause an allergic skin reaction. Silicon and silicon oxides: May be harmful if swallowed. Delayed (chronic) Effects by component: Iron and iron oxides: Chronic inhalation of excessive concentrations of iron oxide fumes or dusts may result in the development of a benign pneumoconiosis, called siderosis, which is observable as an X-ray change. No physical impairment of lung function has been associated with siderosis. Inhalation of excessive concentrations of ferric oxide may enhance the risk of lung cancer development in workers exposed to pulmonary carcinogens. Iron oxide is listed as a Group 3 (not classifiable) carcinogen by the International Agency for Research on Cancer (IARC). Chromium, chromium oxides and hexavalent chromium: The health hazards associated with exposure to chromium are dependent upon its oxidation state. The metal form (chromium as it exists in this product) is of very low toxicity. The hexavalent form is very toxic. Repeated or prolonged exposure to hexavalent chromium compounds may cause respiratory irritation, nosebleed, ulceration and perforation of the nasal septum. Industrial exposure to certain forms of hexavalent chromium has been related to an increased incidence of cancer. NTP (The National Toxicology Program) Fourth Annual report on Carcinogens cites "certain Chromium compounds" as human carcinogens. ACGIH has reviewed the toxicity data and concluded that chromium metal is not classifiable as a human carcinogen. Hexavalent chromium may cause genetic defects and is suspected of damaging the unborn child. Developmental toxicity in the mouse, suspected of damaging fertility or the unborn child. Manganese and manganese oxides: Chronic exposure to high concentrations of manganese fumes and dusts may adversely affect the central nervous system with symptoms including languor, sleepiness, weakness, emotional disturbances, spastic gait, mask-like facial expression and paralysis. Animal studies indicate that manganese exposure may increase susceptibility to bacterial and viral infections. Occupational overexposure (Manganese) is a progressive, disabling neurological syndrome that typically begins with relatively mild symptoms and evolves to include altered gait, fine tremor, and sometimes, psychiatric disturbances. May cause damage to lungs with repeated or prolonged exposure. Neurobehavioral alterations in worker populations exposed to manganese oxides include: speed and coordination of motor function are especially impaired. Nickel and nickel oxides: Exposure to nickel dusts and fumes can cause sensitization dermatitis, respiratory irritation, asthma, pulmonary fibrosis, edema, and may cause nasal or lung cancer in humans. Nickel causes damage to lungs through prolonged or repeated inhalation exposure. IARC lists nickel and certain nickel compounds as Group 2B carcinogens (sufficient animal data). ACGIH 2013 TLVs and BEIs lists insoluble nickel compounds as confirmed human carcinogens. Nickel is suspected of damaging the unborn child. Silicon and silicon oxides: Silicon dusts are a low health risk by inhalation and should be treated as a nuisance dust. Eye contact with pure material can cause particulate irritation. Skin contact with silicon dusts may cause physical abrasion. Section 12 - Ecological Information 12(a) Ecotoxicity (aquatic & terrestrial): No Data Available for Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped. However, individual components of the product when processed have been found to be toxic to the environment. Metal dusts may migrate into soil and groundwater and be ingested by wildlife as follows: Iron Oxide: LC50: >1000 mg/L; Fish 48 h-EC50 > 100 mg/L (Currenta, 2008k); 96 h-LC0 50,000 mg/L. Test substance: Bayferrox 130 red (95 - 97% Fe2O3; < 4% SiO2 and Al2O3) (Bayer, 1989a). Hexavalent Chrome: EU RAR listed as category 1, found acute EC50 and LD50 to algae and invertebrates < 1 mg. Nickel Oxide: IUCLID found LC50 in fish, invertebrates and algae > 100 mg/l. Page 6 of 6 Cold Rolled, Hot Rolled and Enameling Steel Safety Data Sheet Date: 3/06/2015 SDS Code #: AKS-005 Section 12 - Ecological Information (continued) 12(b) Persistence & Degradability: No Data Available for Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped or individual components. 12(c) Bioaccumulative Potential: No Data Available for Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped or individual components. 12(d) Mobility (in soil): No data available for Cold Rolled, Hot Rolled Steel and Enameling Steel as sold/shipped. However, individual components of the product have been found to be absorbed by plants from soil. 12(e) Other adverse effects: None Known Additional Information: Hazard Category: Not Reported Hazard Symbol: No Symbol Hazard Statement: No Statement Signal Word: No Signal Word Section 13 - Disposal Considerations Disposal: Steel scrap should be recycled whenever possible. Product dusts and fumes from processing operations should also be recycled, or classified by a competent environmental professional and disposed of in accordance with applicable federal, state or local regulations. Container Cleaning and Disposal: Follow applicable federal, state and local regulations. Observe safe handling precautions. European Waste Catalogue (EWC): 16-01-17 (ferrous metals), 12-01-99 (wastes not otherwise specified), 16-03-04 (off specification batches and unused products), or 15-01-04 (metallic packaging). Please note this information is for Cold Rolled, Hot Rolled Steel and Enameling Steel in its original form. Any alterations can void this information. Section 14 - Transport Information 14 (a-g) Transportation Information: US Department of Transportation (DOT) under 49 CFR 172.101 does not regulate Cold Rolled, Hot Rolled Steel and Enameling Steel as a hazardous material. All federal, state, and local laws and regulations that apply to the transport of this type of material must be adhered to. Shipping Name: Not Applicable (NA) Packaging Authorizations Quantity Limitations Shipping Symbols: NA a) Exceptions: NA a) Passenger, Aircraft, or Railcar: NA Hazard Class: NA b) Group: NA b) Cargo Aircraft Only: NA UN No.: NA c) Authorization: NA Vessel Stowage Requirements Packing Group: NA a) Vessel Stowage: NA DOT/ IMO Label: NA b) Other: NA Special Provisions (172.102): NA DOT Reportable Quantities: NA International Maritime Dangerous Goods (IMDG) and the Regulations Concerning the International Carriage of Dangerous Goods by Rail (RID) classification, packaging and shipping requirements follow the US DOT Hazardous Materials Regulation. Regulations Concerning the International Carriage of Dangerous Goods by Road (ADR) does not regulate Cold Rolled, Hot Rolled Steel and Enameling Steel as a hazardous material. Shipping Name: Not Applicable (NA) Packaging Portable Tanks & Bulk Containers Classification Code: NA a) Packing Instructions: NA a) Instructions: NA UN No.: NA b) Special Packing Provisions: NA b) Special Provisions: NA Packing Group: NA c) Mixed Packing Provisions: NA ADR Label: NA Special Provisions: NA Limited Quantities: NA International Air Transport Association (IATA) does not regulate Cold Rolled, Hot Rolled material. Shipping Name: Not Applicable (NA) Passenger & Cargo Aircraft Class/Division: NA Hazard Label (s): NA Limited Quantity (EQ) Pkg Inst: NA Pkg Inst: NA UN No.: NA Packing Group: NA Excepted Quantities (EQ): NA Max Net Qty/Pkg: Max Net Qty/Pkg: NA NA Pkg Inst - Packing Instructions Max Net Qty/Pkg - Maximum Net Quantity per Package Steel and Enameling Steel as a hazardous Cargo Aircraft Only Pkg Inst: NA Max Net Qty/Pkg: NA Special Provisions: NA ERG Code: NA ERG - Emergency Response Drill Code Transport Dangerous Goods (TDG) Classification: Cold Rolled, Hot Rolled Steel and Enameling Steel does not have a TDG classification. Page 7 of 7 Cold Rolled, Hot Rolled and Enameling Steel Safety Data Sheet Date: 3/06/2015 SDS Code #: AKS-005 Section 15 - Regulatory Information Regulatory Information: The following listing of regulations relating to an AK Steel product may not be complete and should not be solely relied upon for all regulatory compliance responsibilities. This product and/or its constituents are subject to the following regulations: OSHA Regulations: Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-2, Z-3): The product, Cold Rolled, Hot Rolled Steel and Enameling Steel as a whole is not listed. However, individual components of the product are listed: Refer to Section 8, Exposure Controls and Personal Protection EPA Regulations: The product, Cold Rolled, Hot Rolled Steel and Enameling Steel is not listed as a whole. of the product are listed: Components Chromium Manganese Nickel Regulations CERCLA, CWA, SARA 313, RCRA, SDWA CAA, SARA 313, SDWA CAA, CERCLA, CWA, SARA 313 However, individual components SARA 311/312 Potential Hazard Categories: Immediate Acute Health Hazard; Delayed Chronic Health Hazard Regulations Key: CAA Clean Air Act (42 USC Sec. 7412; 40 CFR Part 61 [As of: 8/18/06]) CERCLA Comprehensive Environmental Response, Compensation and Liability Act (42 USC Secs. 9601(14), 9603(a); 40 CFR Sec. 302.4, Table 302.4, Table 302.4 and App. A) CWA Clean Water Act (33 USC Secs. 1311; 1314(b), (c), (e), (g); 136(b), (c); 137(b), (c) [as of 8/2/06]) RCRA Resource Conservation Recovery Act (42 USC Sec. 6921; 40 CFR Part 261 App VIII) SARA Superfund Amendments and Reauthorization Act of 1986 Title III Section 302 Extremely Hazardous Substances (42 USC Secs. 11023, 13106; 40 CFR sec. 372.65) and Section 313 Toxic Chemicals (42 USC Secs. 11023, 13106; 40 CFR Sec. 372.65 [as of 6/30/05]) TSCA Toxic Substance Control Act (15 U.S.C. s/s 2601 et seq. [1976]) SDWA Safe Drinking Water Act (42 U.S.C. s/s 300f et seq. [1974]) Section 313 Supplier Notification: The product, Cold Rolled, Hot Rolled Steel and Enameling Steel contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-to-Know Act and 40 CFR part 372: CAS # 7440-47-3 7439-96-5 7440-02-0 Chemical Name Chromium Manganese Nickel Percent by Weight 0.15 max 2.0 max 0.15 max State Regulations: The product, Cold Rolled, Hot Rolled Steel and Enameling Steel as a whole is not listed in any state regulations. However, individual components of the product are listed in various state regulations: Pennsylvania Right to Know: Contains regulated material in the following categories: Hazardous Substances: Chromium, Manganese, Nickel and Silicon Environmental Hazards: Chromium, Manganese and Nickel Special Hazardous Substance: Chromium and Nickel California Prop. 65: Contains elements known to the State of California to cause cancer or reproductive toxicity. This includes chromium compounds and nickel. New Jersey: Contains regulated material in the following categories: Hazardous Substance: Chromium, Manganese, Nickel and Silicon Special Hazard Substance: Chromium, Manganese and Silicon Environmental Hazard Substance: Chromium, Manganese and Nickel Minnesota: Chromium, Manganese, Nickel and Silicon Massachusetts: Chromium, Manganese, and Nickel Other Regulations: WHMIS Classification (Canadian): The product, Cold Rolled, Hot Rolled Steel and Enameling Steel is not listed as a whole. However individual components are listed. Ingredients Iron Manganese Nickel WHMIS Classification B4, D2B B4, D2A D2A, D2B This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. Prepared By: AM Health and Safety, Inc Original Issue Date: 08/01/2002 Section 16 - Other Information Revised Date: 03/06/2015 Page 8 of 8 Cold Rolled, Hot Rolled and Enameling Steel Safety Data Sheet Date: 3/06/2015 SDS Code #: AKS-005 Section 16 - Other Information (continued) Additional Information: Hazardous Material Identification System (HMIS) Classification National Fire Protection Association (NFPA) Health Hazard 1 Fire Hazard 0 Physical Hazard 0 HEALTH= 1, Denotes possible chronic hazard if airborne dusts or fumes are generated Irritation or minor reversible injury possible. FIRE= 0, Materials that will not burn. PHYSICAL HAZARD= 0, Materials that are normally stable, even under fire conditions, and will not react with water, polymerize, decompose, condense, or self-react. Non-explosives. HEALTH = 1, Exposure could cause irritation but only minor residual injury even if no treatment is given. FLAMMABILITY = 0, Materials that will not burn. INSTABILITY = 0, Normally stable, even under fire exposure conditions, and are not reactive with water. ABBREVIATIONS/ACRONYMS: ACGIH American Conference of Governmental Industrial Hygienists BEIs Biological Exposure Indices CAS Chemical Abstracts Service Comprehensive Environmental Response, Compensation, and CERCLA Liability Act CFR Code of Federal Regulations CNS Central Nervous System GI, GIT Gastro-Intestinal, Gastro-Intestinal Tract HMIS Hazardous Materials Identification System IARC International Agency for Research on Cancer LC50 Median Lethal Concentration LD50 Median Lethal Dose LD Lo Lowest Dose to have killed animals or humans LEL Lower Explosive Limit LOEL Lowest Observed Effect Level LOAEC Lowest Observable Adverse Effect Concentration g/m3 microgram per cubic meter of air mg/m3 milligram per cubic meter of air mppcf million particles per cubic foot MSHA Mine Safety and Health Administration NFPA National Fire Protection Association NIF NIOSH NTP ORC OSHA PEL PNOR PNOC PPE ppm RCRA RTECS SARA SCBA SDS STEL TLV TWA UEL No Information Found National Institute for Occupational Safety and Health National Toxicology Program Organization Resources Counselors Occupational Safety and Health Administration Permissible Exposure Limit Particulate Not Otherwise Regulated Particulate Not Otherwise Classified Personal Protective Equipment parts per million Resource Conservation and Recovery Act Registry of Toxic Effects of Chemical Substances Superfund Amendment and Reauthorization Act Self-contained Breathing Apparatus Safety Data Sheet Short-term Exposure Limit Threshold Limit Value Time-weighted Average Upper Explosive Limit Disclaimer: This information covers AK Steel products as delivered from an AK Steel facility, but does not include chemicals that may be applied by subsequent handlers and/or distributors of the product. This could include a variety of materials including oils, paints, galvanization, etc. that are not included in the Safety Data Sheet (SDS). Additionally, specialty orders may require application of coating materials not listed in this SDS. SDS's for any AK Steel applied specialty coating will be supplied separately. The information in this SDS was obtained from sources or is based upon data which we believe to be reliable; however, the information is provided without any representation or warranty, expressed or implied, regarding the accuracy or correctness of the information or whether other measures may be required under particular conditions. The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be beyond our knowledge. AK Steel expressly disclaims all liability for loss, damage, or expense arising out of or in any way connected with the handling, storage, use or disposal of this product. Hot Rolled Steel includes: Commercial Quality/Commercial Steel Type B Commercial quality with Boron/Commercial Steel Type B with Boron Drawing Quality Special Killed/Drawing Steel Type B Drawing Quality Special Killed with Boron/Drawing Steel Type B with Boron Extra Deep Drawing Quality Special Killed/Drawing Steel Type A Hot Rolled Alloy High Carbon This SDS covers the following AK Steel products: Cold Rolled Steel includes: Commercial Steel Types: A.B.C Special Killed Drawing Steel Type B Extra Deep Drawing Steel Extra Deep Drawing Steel Plus Bake Hardenable Dent Resistant Rephosphorized Steel High Strength Low Alloy Steel Structural Steel Heat Treatable B Grades * Enameling Steel includes: Commercial Quality/Commercial Steel Drawing Quality Special Killed/Drawing Steel * Enameling Steel is a steel product that has been manufactured specifically for the enameling processes, which is applied by clients of AK Steel. AK Steel does not sell an enameled steel product. Enameling Steel is manufactured specifically for UNIVIT, I-F and VITPlusTM porcelain coatings are applied. For more description of this product, see the latest edition of AK Steel Corporation Price Book (800)-331-5050. Page 9 of 9 SAFETY DATA SHEET Page 1 of 7 Issue Date: 09/14/2020 Section 1. Chemical product and company identification Product name: PGL432271 H-GRAY 32271 POL. TGIC Product chemistry: Polyester Material uses Electrostatic coating for use in industrial plants. Manufacturer: Vitracoat Pinturas en Polvo s.a. de c.v. Av. Circuito de la Industria Sur No. 284, Parque Industrial Lerma. In case of Emergency (Health or Spills): Lerma Edo. De Mex. C.P. 52000 Mxico: (52) 722 26 27000 US: 888-778-5994 After hours: Section 2. Hazardous ingredients CHARACTERISTIC CHEMISTRY: Chemical Mixture Mxico: (52) 722 26 27000 US: 888-778-5994 SUBSTANCE Triglycidyl Isocyanurate CAS N 2451-62-9 2-Mercaptobenzothiazole zinc salt 155-04-4 %p/p 3-5 1-3 ACGIH TLV TWA TWA: 0.05 mg/m 8 hours. Not available GLOBALLY HARMONIZED SYSTEM Hazard statement: May cause the following hazards if not properly used (Section 7) and if not the recommended safety equipment (Section 5) is used. H303 May be harmful if swallowed H317 May cause an allergic skin reaction H320 Causes eye irritation H333 May be harmful if inhaled H335 May cause respiratory irritation H340 May cause genetic defects (routes of exposure oral,inhalation) H373 May cause damage to organs (respiratory) (if inhaled) LABEL 2 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Section 3. Hazards identification Emergency overview Physical state: Odor: Signal word: Hazard statements Precautionary measures : OSHA/HCS status: Solid. [Powder.] Odorless. WARNING! HARMFUL IF INHALED OR SWALLOWED. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT AND SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. MAY CAUSE GENETIC DEFECTS. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Do not breathe dust. Do not ingest. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep container tightly closed. Use personal protective equipment as required. Wash thoroughly after handling. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Potential acute health effects Inhalation Toxic by inhalation. Slightly irritating to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Ingestion Toxic if swallowed. Skin Slightly irritating to the skin. May cause sensitization by skin contact. Eyes Severely irritating to eyes. Risk of serious damage to eyes. Potential chronic health effects Chronic effects Contains material that can cause target organ damage. Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Target organs Contains material which causes damage to the following organs: lymphatic system. Contains material which may cause damage to the following organs: lungs, the nervous system, upper respiratory tract, skin, eyes. Over-exposure signs/symptoms Inhalation Adverse symptoms may include the following: SAFETY DATA SHEET Page 2 of 7 Issue Date: 09/14/2020 respiratory tract irritation coughing Ingestion No specific data. Skin Adverse symptoms may include the following: Irritation, redness Eyes Adverse symptoms may include the following: pain or irritation watering redness Medical conditions aggravated by Pre-existing skin disorders and disorders involving any other target organs mentioned in this SDS as being at risk may be aggravated by over-exposure to this product. overexposure See toxicological information (Section 11) Section 4. First aid measures After contact with eyes: Check for and remove any contact lenses. Immediately flush eyes with plenty of clean water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. After skin contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. After inhalation of Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or material: oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. After ingestion: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the Protection of first-aiders: rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 5.-Fire fighting measures Flammability of the product Fine dust clouds may form explosive mixtures with air. Extinguishing media Suitable Not suitable Special exposure hazards Hazardous thermal decomposition products Special protective equipment for fire-fighters Use dry chemical, CO, water spray (fog) or foam. Do not use water jet. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Decomposition products may include the following materials: carbon dioxide, carbon monoxide, nitrogen oxides, sulfur oxides, metal oxide/oxides Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6.-Measures accidental release Personal precautions: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe dust. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Precautions for environmental Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains protection: and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods for cleaning / collecting: Pick up with vacuum equipment. Section 7.-Handling and storage Handling: Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe dust. Do not ingest. Avoid the creation of dust when handling and avoid all possible sources SAFETY DATA SHEET Page 3 of 7 Issue Date: 09/14/2020 Storage: of ignition (spark or flame). Prevent dust accumulation. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with hot surfaces, sparks or other ignition sources. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8.-Exposure limits and personal protective equipment INGREDIENT EXPOSURE LIMITS Triglycidyl Isocyanurate ACGIH TLV (United States, 3/2012). TWA: 0.05 mg/m 8 hours. 2-Mercaptobenzothiazole zinc salt There are no currently occupational exposure limit values established for this substance. Recommended monitoring If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be procedures required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Engineering measures Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Personal protection Respiratory protection: Protection of hands: Eye protection: Skin protection: Environmental exposure controls Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. If operating conditions cause high dust concentrations to be produced, use dust goggles. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Section 9 -. Physical and chemical properties Physical state: Solid. (powder) Flash point: Vapor Pressure (20 C): N/A Closed cup: Not applicable. Auto-ignition temperature: 450 to 600C (842 to 1112F) Flammable limits: 20 - 70 g/m3 Odor: Solubility: Odorless Insoluble in the following materials: cold water and hot water. Relative density: Minimum ignition energy (mJ): 1.2 to 1.9 [ISO 8130-2/-3]N/A 5 to 20 Section 10. Stability and reactivity Chemical Stability: Conditions to avoid: The product is stable. Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during Incompatible materials: Hazardous decomposition products: Possibility of hazardous reactions SAFETY DATA SHEET Page 4 of 7 Issue Date: 09/14/2020 transfer by grounding and bonding containers and equipment before transferring material. Prevent dust accumulation. Reactive or incompatible with the following materials: oxidizing materials Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous reactions will not occur. Section 11. Toxicological information Acute toxicity Product/ingredient name Result Triglycidyl Isocyanurate LC50 Inhalation Dusts and mists LD50 Dermal LD50 Oral 2-Mercaptobenzothiazole zinc salt Not available Chronic toxicity Product/ingredient name Triglycidyl Isocyanurate Irritation/Corrosion Product/ingredient name Triglycidyl Isocyanurate Result Sub-chronic NOAEL Oral Chronic NOAEL OralLD50 Sub-acute NOEL Inhalation Dusts and mists Result Eyes - Severe irritant Sensitizer Product/ingredient name Triglycidyl Isocyanurate Route of exposure Skin Carcinogenicity Product/ingredient name Triglycidyl Isocyanurate Result Negative - Oral - TD Species Rat Rabbit Rat Not available Dose 650 mg/m >2000 mg/kg 188 mg/kg --- Exposure 4 hours ----- Species Rat - Male, Female Dose 7.32 mg/kg Rat - Male 1.3 mg/kg Mouse - Male, Female <100 mg/m Exposure 94 days; 7 days per Hjek 63 weeks 5 days; 6 hours per day Species Rabbit Score Exposure 4 hours 100 milligrams Species Guinea pig Result Sensitizing Species Rat - Male Dose 4.36 mg/kg Exposure 99 weeks; 24 hours per day Mutagenicity Product/ingredient name Triglycidyl Isocyanurate Teratogenicity Test OECD 471 Bacterial Reverse Mutation Test OECD 483 Mammalian Spermatogonial, Chromosome, Aberration Test OECD 478 Genetic Toxicology: Rodent Dominant Lethal Test Experiment Experiment: In vitro Subject: Bacteria Metabolic activation: Metabolic activation +/Experiment: In vivo Subject: Mammalian-Animal Cell: Germ Experiment: In vitro Subject: Mammalian-Human Cell: Somatic Metabolic activation: Metabolic activation+/Experiment: In vivo Subject: Mammalian-Animal Result Positive Positive Negative Negative Conclusion/Summary: Not available. Reproductive toxicity Product/ingredient name Triglycidyl Isocyanurate Maternal toxicity ----- SAFETY DATA SHEET Page 5 of 7 Issue Date: 09/14/2020 Fertility Negative Development toxin Negative Species Rat - Male Dose Oral Exposure 94 days; 7 days per week Section 12. Ecological information Ecotoxicity: No known significant effects or critical hazards. Aquatic ecotoxicity Product/ingredient name Triglycidyl Isocyanurate Result Acute EC50 29 mg/l Fresh water 2-Mercaptobenzothiazole zinc salt Acute IC50 >100 mg/l Fresh water Acute LC50 >100 mg/l Fresh water None know. Species Algae Micro-organism Daphnia Exposure 72 hours 3 hours 24 hours Persistence/degradability Product/ingredient name Triglycidyl Isocyanurate Test OECD 301B Ready Biodegradability - CO Evolution Test Result 1 % - Not readily - 44 days Dose ---- Inoculum Activated sludge Section 13. Disposal considerations Waste disposal: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by- products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 14. Transport information Regulatory information UN number DOT Classification TDG Classification Mexico Classification ADR/RID Class IMDG Class IATA-DGR Class PG*: Packing group Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated Section 15. Regulatory information Proper shipping name Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated Classes Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated PG* Label ------------------- Additional information ------------------- HCS Classification: Toxic material, Irritating material, Sensitizing material, Carcinogen, Target organ effects. U.S. Federal regulations: TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. SAFETY DATA SHEET Page 6 of 7 Issue Date: 09/14/2020 Clean Air Act Section 112 (b): Hazardous Air Pollutants (HAPs) Clean Air Act Section 602: Class I Substances Clean Air Act Section 602: Class II Substances DEA List I Chemicals: (Precursor Chemicals) DEA List II Chemicals: (Essential Chemicals) Not listed Not listed Not listed Not listed Not listed SARA 302/304 Composition/information on ingredients No products were found. SARA 304 RQ: Not applicable. SARA 311/312 Classification: Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Name % Triglycidyl Isocyanurate 3-5 Fire Hazard No Sudden release of Pressure No Reactive No Immediate (acute) health hazard Yes Delayed (chronic) health hazard Yes SARA 313 Product Name CAS Number % Form R - Reporting requirements No SARA (Superfund Amendments & Reauthorization AC) 313 chemicals are present SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations Massachusetts New York New Jersey Pennsylvania Canada inventory International regulations International lists Chemical Weapons: Convention List Schedule I Chemicals Chemical Weapons: Convention List Schedule II Chemicals Chemical Weapons: Convention List Schedule III Chemicals None of the components are listed. None of the components are listed. The following components are listed: TRIGLYCIDYL ISOCYANURATE The following components are listed: TRIGLYCIDYL ISOCYANURATE Not determined Australia inventory (AICS): Not determined. China inventory (IECSC): Not determined. Japan inventory: Not determined. Korea inventory: Not determined. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan inventory (CSNN): Not determined. Not listed Not listed Not listed SAFETY DATA SHEET Page 7 of 7 Issue Date: 09/14/2020 Section 16. Other information Label requirements HARMFUL IF INHALED OR SWALLOWED. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT AND SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. MAY CAUSE GENETIC DEFECTS. Version : 2 Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Safety Data Sheet Liquid Nitrogen Section 1: Product and Company Identification Cee Kay Supply, Inc 5835 Manchester Avenue Saint Louis, MO 63110 www.CeeKay.com (314) 644-3500 Product Code: Liquid Nitrogen Section 2: Hazards Identification Hazard Classification: Gases Under Pressure Hazard Statements: Contains gas under pressure; may explode if heated Precautionary Statements Storage: Protect from sunlight. Store in well-ventilated place. Warning Section 3: Composition/Information on Ingredients CAS # 7727-37-9 Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 1 of 5 Generated: 10/05/2017 10:30:26 Chemical Substance NITROGEN, CRYOGENIC LIQUID Chemical Family Inorganic gases Trade Names NITROGEN, REFRIGERATED LIQUID; NITROGEN, REFRIGERATED LIQUID, CRYOGENIC LIQUID; NITROGEN; NITROGEN (LIQUID); LIQUID NITROGEN; UN 1977 Section 4: First Aid Measures Skin Contact Immediately flush with plenty of lukewarm water (105-115 F; 41-46 C). DO NOT USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical attention. Eye Contact Ingestion Inhalation Flush eyes with plenty of water. Get medical attention. If a large amount is swallowed, get medical attention. If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. Note to Physicians For inhalation, consider oxygen. Section 5: Fire Fighting Measures Suitable Extinguishing Media Non-flammable. Use suitable extinguishing media for surrounding fire. Cylinders may rupture or explode if exposed to heat. Products of Combustion Non-flammable Protection of Firefighters Respiratory protection may be needed for frequent or heavy exposure. Section 6: Accidental Release Measures Personal Precautions Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. Methods for Cleanup N/A Other Information N/A Environmental Precautions No significant effects from contamination expected. Methods for Containment Stop leak if possible without personal risk. Section 7: Handling and Storage Handling Keep separated from incompatible substances. Store and use with adequate ventilation. Store away from heat and flame. Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Storage Protect containers from physical damage; do not drag, roll, slide or drop. Always use personal protective equipment including, cold insulating clothing, and splash resistant goggles. Close the container valve after each use; keep closed even when empty. Always use hand truck to transport cylinders. Section 8: Exposure Controls/Personal Protection Exposure Guidelines ACGIH (simple asphyxiant) Engineering Controls Handle only in fully enclosed systems. Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 2 of 5 Generated: 10/05/2017 10:30:26 Eye Protection Wear splash resistant safety goggles. Contact lenses should not be worn. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. General Hygiene considerations Avoid breathing vapor or mist Avoid contact with eyes and skin Wash thoroughly after handling and before eating or drinking Skin Protection Wear appropriate protective, cold insulating clothing. Respiratory Protection Respiratory protection may be needed for frequent or heavy exposure. Section 9: Physical and Chemical Properties Physical State Appearance Color Change in Appearance Physical Form Odor Taste Gas Clear Colorless N/A Liquefied gas Odorless Tasteless Flash Point Flammability Partition Coefficient Autoignition Temperature Upper Explosive Limits Lower Explosive Limits Not flammable Not available Not available Nonflammable Nonflammable Nonflammable Boiling Point -321 F (-196 C) Freezing Point -346 F (210 C) Vapor Pressure 760 mmHg @ -196 C Vapor Density 0.967 (Air=1) Specific Gravity Not applicable Water Solubility 1.6% @ 20 C pH Not applicable Odor Threshold Not available Evaporation Rate Not applicable Viscosity 0.01787 cP @ 27 C Molecular Weight 28.0134 Molecular Formula N2 Density 1.2506 g/L Weight per Gallon Not available Volatility by Volume 100% Volatility Solvent Solubility 1 Soluble: Soluble: liquid ammonia Slightly Soluble: alcohol Section 10: Stability and Reactivity Stability Stable at normal temperatures and pressure. Conditions to Avoid Stable at normal temperatures and pressure. Incompatible Materials Metals, oxidizing materials Hazardous Decomposition Products Oxides of nitrogen Possibility of Hazardous Reactions Will not polymerize. Section 11: Toxicology Information Acute Effects Oral LD50 Dermal LD50 Not available Not available Inhalation Nausea, vomiting, difficulty breathing, headache, drowsiness, dizziness, tingling sensation, loss of coordination, convulsions, coma Eye Irritation Skin Irritation Sensitization Frostbite, blurred vision Blisters, frostbite Difficulty breathing Chronic Effects Carcinogenicity Mutagenicity Not hazardous Not available Reproductive Effects Not available Developmental Effects No data Section 12: Ecological Information Fate and Transport Eco toxicity Persistence / Degradability Bioaccumulation / Accumulation Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Mobility in Environment page 3 of 5 Generated: 10/05/2017 10:30:26 Fish toxicity: Not available Invertibrate toxicity: Not available Algal toxicity: Not available Phyto toxicity: Not available Other toxicity: Not available Not available Not available Section 13: Disposal Considerations Dispose in accordance with all applicable regulations. Section 14: Transportation Information U.S. DOT 49 CFR 172.101 Not available Proper Shipping Name Nitrogen, refrigerated liquid ID Number UN1977 Hazard Class or Division 2.2 Packing Group Not applicable Labeling Requirements 2.2 Passenger Aircraft or Railcar Quantity Limitations 75 kg or L Canadian Transportation of Dangerous Goods Shipping Name UN Number Class Packing Group / Risk Group Nitrogen, refrigerated liquid UN1977 2.2 Not applicable Cargo Aircraft Only Quantity Limitations 150 kg Section 15: Regulatory Information U.S. Regulations CERCLA Sections SARA 355.30 Not regulated. Not regulated. SARA 355.40 Not regulated. SARA 370.21 Acute Chronic Fire Reactive Sudden Release Yes No No No Yes SARA 372.65 Not regulated. OSHA Process Safety Not regulated. State Regulations CA Proposition 65 Not regulated. Canadian Regulations WHMIS Classification Not determined. National Inventory Status US Inventory (TSCA) TSCA 12b Export Notification Listed on inventory. Not listed. Canada Inventory (DSL/NDSL) Not determined. Additional Shipping Description N/A Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 4 of 5 Generated: 10/05/2017 10:30:26 Section 16: Other Information NFPA Rating HEALTH=3 FIRE=0 REACTIVITY=0 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 5 of 5 Generated: 10/05/2017 10:30:26 Safety Data Sheet Nitrogen Section 1: Product and Company Identification Cee Kay Supply, Inc 5835 Manchester Avenue Saint Louis, MO 63110 www.CeeKay.com (314) 644-3500 Product Code: Nitrogen Section 2: Hazards Identification Hazard Classification: Gases Under Pressure Hazard Statements: Contains gas under pressure; may explode if heated Precautionary Statements Storage: Protect from sunlight. Store in well-ventilated place. Warning Section 3: Composition/Information on Ingredients CAS # 7727-37-9 Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 1 of 4 Generated: 10/05/2017 10:05:25 Chemical Substance NITROGEN, COMPRESSED GAS Chemical Family Inorganic gases Trade Names DIATOMIC NITROGEN; DINITROGEN; NITROGEN; NITROGEN-14; NITROGEN GAS; UN 1066; N2 Section 4: First Aid Measures Skin Contact Wash exposed skin with soap and water. Eye Contact Flush eyes with plenty of water. Ingestion If a large amount is swallowed, get medical attention. Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. Note to Physicians For inhalation, consider oxygen. Section 5: Fire Fighting Measures Suitable Extinguishing Media Non-flammable. Use suitable extinguishing media for surrounding fire. Cylinders may rupture or explode if exposed to heat. Products of Combustion Non-flammable Protection of Firefighters Respiratory protection may be needed for frequent or heavy exposure. Section 6: Accidental Release Measures Personal Precautions Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. Methods for Cleanup N/A Other Information N/A Environmental Precautions No significant effects from contamination expected. Methods for Containment Stop leak if possible without personal risk. Section 7: Handling and Storage Handling Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Storage Keep separated from incompatible substances. Section 8: Exposure Controls/Personal Protection Exposure Guidelines NITROGEN, COMPRESSED GAS: NITROGEN: ACGIH (simple asphyxiant) Engineering Controls Handle only in fully enclosed systems. Eye Protection Eye protection not required, but recommended. Skin Protection Protective clothing is not required. General Hygiene considerations Avoid breathing vapor or mist Avoid contact with eyes and skin Wash thoroughly after handling and before eating or drinking Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Respiratory Protection Respiratory protection may be needed for frequent or heavy exposure. page 2 of 4 Generated: 10/05/2017 10:05:25 Section 9: Physical and Chemical Properties Physical State Gas Appearance Clear Color Colorless Change in Appearance N/A Physical Form Gas Odor Odorless Taste Tasteless Flash Point Flammability Partition Coefficient Autoignition Temperature Upper Explosive Limits Lower Explosive Limits Not flammable Not available Not available Nonflammable Nonflammable Nonflammable Boiling Point -321 F (-196 C) Freezing Point -346 F (210 C) Vapor Pressure 760 mmHg @ -196 C Vapor Density 0.967 (Air=1) Specific Gravity Not applicable Water Solubility 1.6% @ 20 C pH Not applicable Odor Threshold Not available Evaporation Rate Not applicable Viscosity 0.01787 cP @ 27 C Molecular Weight 28.0134 Molecular Formula N2 Density 1.2506 g/L Weight per Gallon Not available Volatility by Volume 100% Volatility 1 Solvent Solubility Soluble: Liquid ammonia Section 10: Stability and Reactivity Stability Stable at normal temperatures and pressure. Conditions to Avoid Stable at normal temperatures and pressure. Incompatible Materials Metals, oxidizing materials Hazardous Decomposition Products Oxides of nitrogen Possibility of Hazardous Reactions Will not polymerize. Section 11: Toxicology Information Acute Effects Oral LD50 Dermal LD50 Not available Not available Inhalation Nausea, vomiting, difficulty breathing, headache, drowsiness, dizziness, tingling sensation, loss of coordination, convulsions, coma Eye Irritation Contact with rapidly expanding gas may cause burns or frostbite Skin Irritation No information on significant adverse effects Sensitization Difficulty breathing Chronic Effects Carcinogenicity Mutagenicity Not hazardous Not available Reproductive Effects Not available Developmental Effects No data Section 12: Ecological Information Fate and Transport Eco toxicity Fish toxicity: Not available Invertibrate toxicity: Not available Algal toxicity: Not available Phyto toxicity: Not available Other toxicity: Not available Persistence / Degradability Not available Bioaccumulation / Accumulation Not available Mobility in Environment Not available Section 13: Disposal Considerations Dispose in accordance with all applicable regulations. Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 3 of 4 Generated: 10/05/2017 10:05:25 Section 14: Transportation Information U.S. DOT 49 CFR 172.101 Proper Shipping Name Nitrogen, compressed ID Number UN1066 Hazard Class or Division 2.2 Packing Group Not applicable Labeling Requirements 2.2 Passenger Aircraft or Railcar Quantity Limitations 75 kg or L Canadian Transportation of Dangerous Goods Shipping Name UN Number Class Packing Group / Risk Group Nitrogen, compressed UN1066 2.2 Not applicable Cargo Aircraft Only Quantity Limitations 150 kg Section 15: Regulatory Information U.S. Regulations CERCLA Sections SARA 355.30 Not regulated. Not regulated. SARA 355.40 Not regulated. SARA 370.21 Acute Chronic Fire Reactive Sudden Release Yes No No No Yes SARA 372.65 Not regulated. OSHA Process Safety Not regulated. State Regulations CA Proposition 65 Not regulated. Canadian Regulations WHMIS Classification A National Inventory Status US Inventory (TSCA) TSCA 12b Export Notification Listed on inventory. Not listed. Canada Inventory (DSL/NDSL) Listed on inventory. Section 16: Other Information NFPA Rating HEALTH=1 FIRE=0 REACTIVITY=0 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Additional Shipping Description N/A Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 4 of 4 Generated: 10/05/2017 10:05:25 Safety Data Sheet Oxygen Section 1: Product and Company Identification Cee Kay Supply, Inc 5835 Manchester Avenue Saint Louis, MO 63110 www.CeeKay.com (314) 644-3500 Product Code: Oxygen Section 2: Hazards Identification Hazard Classification: Gases Under Pressure Oxidizing Gas (Category 1) Danger Hazard Statements: Contains gas under pressure; may explode if heated May cause or intensify fire; oxidizer Precautionary Statements Prevention: Keep reduction valves/valves and fittings free from oil and grease. Keep and store away from clothing and combustible materials. Response: In case of fire: Stop leak if safe to do so. Storage: Protect from sunlight. Store in well-ventilated place. Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 1 of 5 Generated: 10/05/2017 13:40:06 Section 3: Composition/Information on Ingredients CAS # 7782-44-7 Chemical Substance OXYGEN, COMPRESSED GAS Chemical Family Inorganic gases Trade Names OXYGEN; DIOXYGEN; MOLECULAR OXYGEN; OXYGEN MOLECULE; PURE OXYGEN; UN 1072; O2 Section 4: First Aid Measures Skin Contact None expected Eye Contact None expected Ingestion Not likely route of exposure Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. Note to Physicians None Section 5: Fire Fighting Measures Suitable Extinguishing Media Non-flammable. Use extinguishing agent appropriate for the material which is burning. Use water in large quantities for fires involving oxygen. Products of Combustion Oxides of burning material Protection of Firefighters Respiratory protection may be needed for frequent or heavy exposure. None Section 6: Accidental Release Measures Personal Precautions Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Methods for Cleanup Stop leak and ventilate Other Information None Environmental Precautions Avoid contact with combustible materials. Methods for Containment Stop leak if possible without personal risk. Section 7: Handling and Storage Handling Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Storage Keep separated from incompatible substances. Section 8: Exposure Controls/Personal Protection Exposure Guidelines OXYGEN, COMPRESSED GAS: No occupational exposure limits established. Engineering Controls Handle only in fully enclosed systems. Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 2 of 5 Generated: 10/05/2017 13:40:06 Eye Protection Eye protection not required, but recommended. Skin Protection Protective clothing is not required. General Hygiene considerations Avoid breathing vapor or mist Avoid contact with eyes and skin Wash thoroughly after handling and before eating or drinking Respiratory Protection Respiratory protection may be needed for frequent or heavy exposure. Section 9: Physical and Chemical Properties Physical State Appearance Color Change in Appearance Physical Form Odor Taste Gas Clear Colorless N/A Gas Odorless Tasteless Flash Point Not flammable Flammability Not available Partition Coefficient Not available Autoignition Temperature Nonflammable Upper Explosive Limits Nonflammable Lower Explosive Limits Nonflammable Boiling Point -297 F (-183 C) Freezing Point -360 F (218 C) Vapor Pressure 760 mmHg @ -183 C Vapor Density 1.1 (Air=1) Specific Gravity Not applicable Water Solubility 3.2% @ 25 C pH Not applicable Odor Threshold Not available Evaporation Rate Not applicable Viscosity 0.02075 cP @ 25 C Molecular Weight 31.9988 Molecular Formula O2 Density 1.309 g/L @ 25 C Weight per Gallon Not available Volatility by Volume Not applicable Volatility Not applicable Solvent Solubility Soluble: Alcohol Section 10: Stability and Reactivity Stability Stable at normal temperatures and pressure. Conditions to Avoid Stable at normal temperatures and pressure. Incompatible Materials Combustible materials, halo carbons, metals, bases, reducing agents, amines, metal salts, oxidizing materials, alkaline earth and alkali metals Hazardous Decomposition Products Miscellaneous decomposition products Possibility of Hazardous Reactions Will not polymerize. Section 11: Toxicology Information Acute Effects Oral LD50 Dermal LD50 Not established Not established Inhalation Irritation, changes in body temperature, nausea, difficulty breathing, irregular heartbeat, dizziness, disorientation, hallucinations, mood swings, pain in extremities, tremors, lung congestion, convulsions Eye Irritation No information on significant adverse effects Skin Irritation No information on significant adverse effects Sensitization No significant target effects reported. Chronic Effects Carcinogenicity Mutagenicity Not known. Available. Reproductive Effects Available. Developmental Effects No data Section 12: Ecological Information Fate and Transport Eco toxicity Persistence / Degradability Bioaccumulation / Accumulation Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved Mobility in Environment page 3 of 5 Generated: 10/05/2017 13:40:06 Fish toxicity: Not available Invertibrate toxicity: Not available Algal toxicity: Not available Phyto toxicity: Not available Other toxicity: Not available Not available Low bioaccumulation Not available Section 13: Disposal Considerations Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Section 14: Transportation Information U.S. DOT 49 CFR 172.101 Proper Shipping Name Oxygen, compressed ID Number UN1072 Hazard Class or Division 2.2 Packing Group Not available Labeling Requirements 2.2; 5.1 Passenger Aircraft or Railcar Quantity Limitations 75 kg or L Canadian Transportation of Dangerous Goods Shipping Name UN Number Class Packing Group / Risk Group Oxygen, compressed UN1072 2.2; 5.1 Not applicable Cargo Aircraft Only Quantity Limitations 150 kg Section 15: Regulatory Information U.S. Regulations CERCLA Sections SARA 355.30 Not regulated. Not regulated. SARA 355.40 Not regulated. SARA 370.21 Acute Chronic Fire Reactive Sudden Release No No Yes No Yes SARA 372.65 Not regulated. OSHA Process Safety Not regulated. State Regulations CA Proposition 65 Not regulated. Canadian Regulations WHMIS Classification A,C National Inventory Status US Inventory (TSCA) TSCA 12b Export Notification Listed on inventory. Not listed. Canada Inventory (DSL/NDSL) Not determined. Additional Shipping Description N/A Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 4 of 5 Generated: 10/05/2017 13:40:06 Section 16: Other Information NFPA Rating HEALTH=0 FIRE=0 REACTIVITY=0 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Cee Kay Supply, Inc Generated by the SDS Manager from AsteRisk, LLC. All Rights Reserved page 5 of 5 Generated: 10/05/2017 13:40:06 SAFETY DATA SHEET Section 1. Chemical product and company identification Product name: POL. HW ANSI 49 GRAY 5373M Product chemistry: Polyester Material uses Electrostatic coating for use in industrial plants. Manufacturer: Vitracoat America 2807 Marina Drive Elkhart Indiana 46514 In case of Emergency (Health or Mxico: (52) 722 26 27000 Spills): US: 888-778-5994 Section 2. Hazardous ingredients CHARACTERISTIC CHEMISTRY: Chemical Mixture Page 1 of 7 Issue Date: 1/3/2019 After hours: Mxico: (52) 722 26 27000 US: 888-778-5994 SUBSTANCE CAS N %p/p ACGIH TLV TWA GLOBALLY HARMONIZED SYSTEM Hazard statement: May cause the following hazards if not properly used (Section 7) and if not the recommended safety equipment (Section 5) is used. Triglicidil Isocianurate 2451-62-9 H303 May be harmful if swallowed H317 May cause an allergic skin reaction 3-5 TWA: 0.05 mg/m 8 hours. H320 Causes eye irritation H333 May be harmful if inhaled H335 May cause respiratory irritation H351 Suspected of causing cancer (if inhaled) H373 May cause damage to organs (respiratory) (if inhaled) LABEL 2 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Section 3. Hazards identification Emergency overview Physical state: Odor: Signal word: Hazard statements Precautionary measures : OSHA/HCS status: Solid. [Powder.] Odorless. WARNING! HARMFUL IF INHALED OR SWALLOWED. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT AND SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. POSSIBLE CANCER HAZARD CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Do not breathe dust. Do not ingest. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep container tightly closed. Use personal protective equipment as required. Wash thoroughly after handling. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Potential acute health effects Inhalation Toxic by inhalation. Slightly irritating to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Ingestion Toxic if swallowed. Skin Slightly irritating to the skin. May cause sensitization by skin contact. Eyes Severely irritating to eyes. Risk of serious damage to eyes. Potential chronic health effects Chronic effects Contains material that can cause target organ damage. Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Target organs Contains material which causes damage to the following organs: lymphatic system. Contains material which may cause damage to the following organs: lungs, the nervous system, upper respiratory tract, skin, eyes. Over-exposure signs/symptoms Inhalation Adverse symptoms may include the following: SAFETY DATA SHEET Page 2 of 7 Issue Date: 1/3/2019 respiratory tract irritation coughing Ingestion No specific data. Skin AIrrditvaetirosne,sryemdnpetosms s may include the following: Eyes Apadivneorsreirrsityamtipotnomwastemrianyginrecdlundeessthe following: Medical conditions aggravated by Pre-existing skin disorders and disorders involving any other target organs mentioned in this SDS as being at risk may be aggravated by over-exposure to this product. overexposure See toxicological information (Section 11) Section 4. First aid measures After contact with eyes: Check for and remove any contact lenses. Immediately flush eyes with plenty of clean water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. After skin contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. After inhalation of Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or material: oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. After ingestion: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the Protection of first-aiders: rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 5.-Fire fighting measures Flammability of the product Fine dust clouds may form explosive mixtures with air. Extinguishing media Suitable Not suitable Special exposure hazards Hazardous thermal decomposition products Special protective equipment for fire-fighters Use dry chemical, CO, water spray (fog) or foam. Do not use water jet. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Decomposition products may include the following materials: carbon dioxide, carbon monoxide, nitrogen oxides, sulfur oxides, metal oxide/oxides Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6.-Measures accidental release Personal precautions: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe dust. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Precautions for environmental Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains protection: and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods for cleaning / collecting: Pick up with vacuum equipment. Section 7.-Handling and storage Handling: Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe dust. Do not ingest. Avoid the creation of dust when handling and avoid all possible sources SAFETY DATA SHEET Page 3 of 7 Issue Date: 1/3/2019 Storage: of ignition (spark or flame). Prevent dust accumulation. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with hot surfaces, sparks or other ignition sources. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8.-Exposure limits and personal protective equipment INGREDIENT Triglicidil Isocianurate Matting agent Jietonda EXPOSURE LIMITS ACGIH TLV (United States, 3/2012). TWA: 0.05 mg/m 8 hours. No data available Recommended monitoring procedures Engineering measures Hygiene measures If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Personal protection Respiratory protection: Protection of hands: Eye protection: Skin protection: Environmental exposure controls Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. If operating conditions cause high dust concentrations to be produced, use dust goggles. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Section 9 -. Physical and chemical properties Physical state: Solid. (powder) Flash point: Vapor Pressure (20 C): N/A Closed cup: Not applicable. Auto-ignition temperature: Odor: Solubility: 450 to 600C (842 to 1112F) Odorless Insoluble in the following materials: cold water and hot water. Flammable limits: Relative density: Minimum ignition energy (mJ): 20 - 70 g/m3 1.2 to 1.9 [ISO 8130-2/-3]N/A 5 to 20 Section 10. Stability and reactivity Chemical Stability: Conditions to avoid: The product is stable. Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during Incompatible materials: Hazardous decomposition products: Possibility of hazardous reactions SAFETY DATA SHEET Page 4 of 7 Issue Date: 1/3/2019 transfer by grounding and bonding containers and equipment before transferring material. Prevent dust accumulation. Reactive or incompatible with the following materials: oxidizing materials Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous reactions will not occur. Section 11. Toxicological information Acute toxicity Product/ingredient name Result Triglicidil Isocianurate LC50 Inhalation Dusts and mists LD50 Dermal LD50 Oral Matting agent Jietonda Oral: LD50 Species Rat Rabbit Rat Rat Dose 650 mg/m >2000 mg/kg 188 mg/kg >1500 mg/kg Exposure 4 hours --- Chronic toxicity Product/ingredient name Triglicidil Isocianurate Irritation/Corrosion Product/ingredient name Triglicidil Isocianurate Matting agent Jietonda Sensitizer Product/ingredient name Triglicidil Isocianurate Matting agent Jietonda Carcinogenicity Product/ingredient name Triglicidil Isocianurate Matting agent Jietonda Mutagenicity Product/ingredient name Triglicidil Isocianurate Result Sub-chronic NOAEL Oral Chronic NOAEL OralLD50 Sub-acute NOEL Inhalation Dusts and mists Species Rat - Male, Female Dose 7.32 mg/kg Rat - Male 1.3 mg/kg Mouse - Male, Female <100 mg/m Exposure 94 days; 7 days per Hjek 63 weeks 5 days; 6 hours per day Result Eyes - Severe irritant Eye: It may irritate to the eyes [rabbit] Skin: It may irritate slightly to the skin[rabbit] Species Rabbit Score Exposure 4 hours 100 milligrams Route of exposure Skin Skin Species Guinea pig Guinea pig, Corium Result Sensitizing It may irritate slightly to respiratory or skin. Result Negative - Oral - TD Species Rat - Male Dose 4.36 mg/kg Exposure 99 weeks; 24 hours per day IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Test OECD 471 Bacterial Reverse Mutation Test OECD 483 Mammalian Spermatogonial, Chromosome, Aberration Test Experiment Experiment: In vitro Subject: Bacteria Metabolic activation: Metabolic activation +/Experiment: In vivo Subject: Mammalian-Animal Cell: Germ Experiment: In vitro Result Positive Positive Negative SAFETY DATA SHEET Page 5 of 7 Issue Date: 1/3/2019 Matting agent Jietonda OECD 478 Genetic Toxicology: Rodent Dominant Lethal Test No data available Subject: Mammalian-Human Cell: Somatic Metabolic activation: Metabolic activation+/- Experiment: In vivo Subject: Mammalian-Animal Negative No data available No data available Teratogenicity Conclusion/Summary: Not available. Reproductive toxicity Product/ingredient name Triglicidil Isocianurate Maternal toxicity ----- Fertility Negative Development toxin Negative Species Rat - Male Dose Oral Exposure 94 days; 7 days per week Section 12. Ecological information Ecotoxicity: No known significant effects or critical hazards. Aquatic ecotoxicity Product/ingredient name Triglicidil Isocianurate Result Acute EC50 29 mg/l Fresh water Acute IC50 >100 mg/l Fresh water Acute LC50 >100 mg/l Fresh water Persistence/degradability Product/ingredient name Triglicidil Isocianurate Test OECD 301B Ready Biodegradability - CO Evolution Test Species Algae Micro-organism Daphnia Result 1 % - Not readily - 44 days Dose ---- Exposure 72 hours 3 hours 24 hours Inoculum Activated sludge Section 13. Disposal considerations Waste disposal: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by- products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 14. Transport information Regulatory information DOT Classification TDG Classification Mexico Classification ADR/RID Class UN number Not regulated Not regulated Not regulated Not regulated Proper shipping name Not regulated Not regulated Not regulated Not regulated Classes Not regulated Not regulated Not regulated Not regulated PG* Label ------------- Additional information ------------- SAFETY DATA SHEET IMDG Class IATA-DGR Class PG*: Packing group Not regulated Not regulated Not regulated Not regulated Not regulated ---- Not regulated ---- Section 15. Regulatory information HCS Classification: Toxic material, Irritating material, Sensitizing material, Carcinogen, Target organ effects. Page 6 of 7 Issue Date: 1/3/2019 ------- U.S. Federal regulations: Clean Air Act Section 112 (b): Hazardous Air Pollutants (HAPs) Clean Air Act Section 602: Class I Substances Clean Air Act Section 602: Class II Substances DEA List I Chemicals: (Precursor Chemicals) DEA List II Chemicals: (Essential Chemicals) TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. Not listed Not listed Not listed Not listed Not listed SARA 302/304 Composition/information on ingredients No products were found. SARA 304 RQ: Not applicable. SARA 311/312 Classification: Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Name % Triglicidil Isocianurate 3-5 Fire Hazard No Sudden release of Pressure No Reactive No Immediate (acute) health hazard Yes Delayed (chronic) health hazard Yes SARA 313 Product Name CAS Number % Form R - Reporting requirements No SARA (Superfund Amendments & Reauthorization AC) 313 chemicals are present SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations Massachusetts New York New Jersey Pennsylvania Canada inventory International regulations International lists Chemical Weapons: None of the components are listed. None of the components are listed. The following components are listed: TRIGLICIDIL ISOCIANURATE The following components are listed: TRIGLICIDIL ISOCIANURATE Not determined Australia inventory (AICS): Not determined. China inventory (IECSC): Not determined. Japan inventory: Not determined. Korea inventory: Not determined. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan inventory (CSNN): Not determined. Not listed SAFETY DATA SHEET Page 7 of 7 Issue Date: 1/3/2019 Convention List Schedule I Chemicals Chemical Weapons: Convention List Schedule II Chemicals Chemical Weapons: Convention List Schedule III Chemicals Not listed Not listed Section 16. Other information Label requirements HARMFUL IF INHALED OR SWALLOWED. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT AND SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Version : 2 Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Safety Data Sheet Revision Number: 004.0 Issue date: 07/21/2014 1. PRODUCT AND COMPANY IDENTIFICATION Product name: BONDERITE C-IC 2520 ACID DEOXIDIZER known as DEOXIDINE 2520 Product type: Cleaner Restriction of Use: None identified Company address: Henkel AG & Co. KGaA Henkelstr. 67 Dsseldorf 40589 IDH number: 693244 Region: United States Contact information: Telephone: +49 (211) 797 0 2. HAZARDS IDENTIFICATION DANGER: EMERGENCY OVERVIEW CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. SKIN CORROSION SERIOUS EYE DAMAGE HAZARD CLASS PICTOGRAM(S) HAZARD CATEGORY 1B 1 Precautionary Statements Prevention: Response: Storage: Disposal: Do not breathe vapors, mist, or spray. Wash thoroughly after handling. Wear protective gloves, eye protection, and face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. Immediately call a poison control center or physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) Nitric acid CAS Number 7697-37-2 Percentage* 5 - 10 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. IDH number: 693244 Product name: BONDERITE C-IC 2520 ACID DEOXIDIZER known as DEOXIDINE 2520 Page 1 of 6 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Symptoms: Notes to physician: If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. Remove contaminated clothing and footwear. For skin contact, flush with large amounts of water. Seek immediate medical attention. In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Immediate medical treatment necessary. DO NOT induce vomiting unless directed to do so by medical personnel. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions. See Section 11. If cyanosis is severe, intravenous injection of methylene blue, 1 mg/kg body weight, may be of value. Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: 5. FIRE FIGHTING MEASURES Use media appropriate for surrounding material. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. This product is an aqueous mixture which will not burn. Irritating and toxic gases or fumes may be released during a fire. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate personal protective equipment. Do not allow product to enter sewer or waterways. Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Do not take internally. Wash thoroughly after handling. Do not breathe gas/fumes/vapor/spray. Storage: Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Do not freeze. For information on product shelf life, please review labels on container or check the Technical Data Sheet. IDH number: 693244 Product name: BONDERITE C-IC 2520 ACID DEOXIDIZER known as DEOXIDINE 2520 Page 2 of 6 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) Nitric acid ACGIH TLV 2 ppm TWA 4 ppm STEL OSHA PEL 2 ppm (5 mg/m3) PEL AIHA WEEL None OTHER None Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Respirators should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR 1901.134) and ANSI's standard for respiratory protection (Z88.2-1992). A written respiratory protection program, including provisions for medical certification, training, fit-testing, exposure assessments, maintenance, inspection, cleaning, and convenient, sanitary storage, must be implemented. If concentrations are below the TLV and/or PEL, a NIOSH approved disposable dust/mist respirator may be used for personal comfort. For concentrations above the TLV and/or PEL but less than 10 times these limits, a NIOSH approved half-face piece respirator equipped with dust-mist cartridges may be used. For concentrations greater than 10 times the TLV and/or PEL, consult the NIOSH respirator decision logic found in Publication No.87-116 or ANSI Z88.2-1992. Note: ANSI Z88.2-1992 requires the use of a HEPA filter if the particle size distribution of the contaminant is unknown. WARNING! Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Wear chemical goggles; face shield (if splashing is possible). Chemical resistant, impermeable gloves. The use of butyl rubber gloves is recommended. The use of polyvinyl chloride gloves is recommended. The use of neoprene gloves is recommended. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: pH: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Viscosity: Decomposition temperature: Liquid Colorless, light brown Acrid Not available. < 2 Not applicable > 200 F (> 93.3 C) calculated Not determined 1.03 - 1.06 Not applicable Not applicable Not applicable Not applicable Not applicable Not determined Complete Not determined 0 % (calculated) Not available. Not available. IDH number: 693244 Product name: BONDERITE C-IC 2520 ACID DEOXIDIZER known as DEOXIDINE 2520 Page 3 of 6 Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Relevant routes of exposure: 10. STABILITY AND REACTIVITY Stable at normal conditions. Will not occur. Decomposes with heat to produce oxides of nitrogen. Oxidizers. May react with acrolein, acrylaldehyde, hydrogen peroxide, nitric acid, and oxidizing agents. This product may react with strong alkalies. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Skin, Inhalation, Eyes Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Mists, vapors or liquid may cause severe irritation or burns. Inhalation of vapors may cause moderate to severe respiratory tract irritation. This product may be harmful by inhalation. Contact with liquid may produce severe skin irritation including redness, inflammation and chemical burns. This product is severely irritating to the eyes and may cause irreversible damage including burns and blindness. This product may produce corrosive damage to the gastrointestinal tract if it is swallowed. Ingestion of corrosive acids may result in moderately severe burns to mouth and esophagus with more severe burns and damage to the stomach. This product may cause methemoglobinemia characterized by a reduction in oxygen carrying capacity of the blood with symptoms including headache, dizziness, flushed face, fatigue, nausea, vomiting, drowsiness, stupor, tremors, uneven heart action, coma and rarely death. Hazardous Component(s) Nitric acid Hazardous Component(s) Nitric acid Ecological information: LD50s and LC50s Inhalation LC50 (RAT, 30 min) = 334 mg/l Inhalation LC50 (RAT, 30 min) = 244 mg/l Inhalation LC50 (RAT, 30 min) = 138 mg/l Inhalation LC50 (RAT, 4 h) = 65 mg/l Immediate and Delayed Health Effects Irritant, Corrosive, Lung, Teeth NTP Carcinogen No IARC Carcinogen No OSHA Carcinogen (Specifically Regulated) No 12. ECOLOGICAL INFORMATION Because of the low pH of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. IDH number: 693244 Product name: BONDERITE C-IC 2520 ACID DEOXIDIZER known as DEOXIDINE 2520 Page 4 of 6 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: This product, if discarded directly, would be a characteristic RCRA corrosive waste (D002). 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Nitric acid Hazard class or division: 8 Identification number: UN 2031 Packing group: II DOT Hazardous Substance(s): Nitric acid International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Nitric acid 8 UN 2031 II Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: NITRIC ACID 8 UN 2031 II 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimis Nitric acid (CAS# 7697-37-2). Immediate Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Nitric acid (CAS# 7697-37-2). Nitric acid (CAS# 7697-37-2) 1,000 lbs. (454 kg) No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Jennifer Mckay, Regulatory Affairs Specialist Issue date: 07/21/2014 IDH number: 693244 Product name: BONDERITE C-IC 2520 ACID DEOXIDIZER known as DEOXIDINE 2520 Page 5 of 6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ("Henkel") does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel's products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel's products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: 693244 Product name: BONDERITE C-IC 2520 ACID DEOXIDIZER known as DEOXIDINE 2520 Page 6 of 6 SDS ID No.: AM USA - 001 Safety Data Sheet (SDS) Section 1 - Identification 1(a) Product Identifier used on Label: Hot Rolled or Cold Rolled Steel 1(b) Other means of identification: Refer to Section 16 for product synonyms. 1(c) Recommended use of the chemical and restrictions on use: These products are sold to all steel-consuming industries including automotive, heavy machinery, pipes and tubes, construction, packaging and appliances. The main markets for these products are construction and mechanical engineering, as well as energy and automotive applications. 1(d) Name, address, and telephone number: ArcelorMittal USA LLC 1 South Dearborn Street Chicago, IL 60603-9888 Phone number : 219-787-4901 or email at: msdssupport@arcelormittal.com 1(e) Emergency phone number: 1-760-476-3962 (3E Company Code: 333211) or CHEMTREC (Day or Night): 1-800-424-9300 Section 2 - Hazard(s) Identification 2(a) Classification of the chemical: Hot Rolled or Cold Rolled Steel is considered an article under Reach regulation (REACH REGULATION (EC) No 1907/2006) and is not subject to classification under CLP regulation (REGULATION (EC) No 1272/2008). However, Hot Rolled or Cold Rolled Steel is not exempt as an article under OSHA's Hazard Communication Standard (29 CFR 1910.1200) due to its downstream use, thus this product is considered a mixture and a hazardous material. Therefore, the categories of Health Hazards as defined in "GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS (GHS), Third revised edition ST/SG/AC.10/30/Rev. 3" United Nations, New York and Geneva, 2009 have been evaluated. Refer to Section 3, 8 and 11 for additional information. 2(b) Signal word, hazard statement(s), symbols and precautionary statement(s): Hazard Symbol NA Hazard Classification Carcinogenicity - 2 Reproductive Toxicity - 2 Single Target Organ Toxicity (STOT) Repeat Exposure - 1 Skin Sensitization - 1 STOT Single Exposure - 3 Eye Irritation - 2B Signal Word Danger Hazard Statement(s) Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to lungs and central nervous system through prolonged or repeated inhalation exposure. May cause an allergic skin reaction. May cause respiratory irritation. Causes eye irritation. Precautionary Statement(s): Prevention Response Do not breathe dusts / fume / gas / mist / vapor / spray. Wear protective gloves / protective clothing / eye protection / face protection. Contaminated work clothing must not be allowed out of the workplace. Use only outdoors or in well ventilated areas. Wash thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not eat, drink or smoke when using this product. If inhaled: Remove person to fresh air and keep comfortable for breathing. If exposed, concerned or feel unwell: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If on skin: Wash with plenty of water. If irritation or rash occurs: Get medical advice/attention. Take off and wash contaminated clothing before reuse. Call a poison center/doctor if you feel unwell. 2(c) Hazards not otherwise classified: None Known 2(d) Unknown acute toxicity statement (mixture): None Known Storage/Disposal Dispose of contents in accordance with federal, state and local regulations. Section 3 - Composition/Information on Ingredients 3(a-c) Chemical name, common name (synonyms), CAS number and other identifiers, and concentration: Chemical Name Iron CAS Number 7439-89-6 EC Number 231-096-4 Manganese 7439-96-5 231-105-1 % weight 95-99.9 0.05-2.45 Page 1 of 9 Hot Rolled or Cold Rolled Steel SDS ID No.: AM USA - 001 Revision: 01/01/2016 Section 3 - Composition/Information on Ingredients (continued) 3(a-c) Chemical name, common name (synonyms), CAS number and other identifiers, and concentration (continued): Chemical Name Nickel CAS Number 7440-02-0 EC Number 231-111-4 % weight 0.01-0.42 Silicon 7440-21-3 231-130-8 0.01-3.04 Aluminum 7429-90-5 231-072-3 0.01-1.60 EC - European Community CAS - Chemical Abstract Service Product surfaces may be treated with small amounts of corrosion-inhibiting oil that may contain mineral oil or petroleum distillates, or paints, epoxies, laminates, etc., generally applied at the customer's request. Refer to the coating manufacturer's SDS for hazards associated with coatings. Section 4 - First-aid Measures 4(a) Description of necessary measures: Inhalation: Hot Rolled or Cold Rolled Steel as sold/shipped is not a likely form of exposure. However during further processing (welding, grinding, burning, etc.), if inhaled: Remove person to fresh air and keep comfortable for breathing. If exposed, concerned or feel unwell: Get medical advice/attention. Eye Contact: Hot Rolled or Cold Rolled Steel as sold/shipped is not a likely form of exposure. However during further processing (welding, grinding, burning, etc.), if in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue Rinsing. If eye irritation persists: Get medical advice attention. If exposed, concerned or feel unwell: Get medical advice/attention. Skin Contact: If on skin: Wash thoroughly after handling. Wash with plenty of water. If irritation or rash occurs: Get medical advice/attention. Take off and wash contaminated clothing before reuse. If exposed, concerned or feel unwell: Get medical advice/attention. Ingestion: Hot Rolled or Cold Rolled Steel as sold/shipped is not a likely form of exposure. However during further processing (welding, grinding, burning, etc.), if exposed, concerned or feel unwell: Get medical advice/attention. 4(b) Most important symptoms/effects, acute and delayed (chronic): Inhalation: Hot Rolled or Cold Rolled Steel as sold/shipped is not likely to present an acute or chronic health effect. Eye: Hot Rolled or Cold Rolled Steel as sold/shipped is not likely to present an acute or chronic health effect. Skin: Hot Rolled or Cold Rolled Steel as sold/shipped is not likely to present an acute or chronic health effect. Ingestion: Hot Rolled or Cold Rolled Steel as sold/shipped is not likely to present an acute or chronic health effect. However during further processing (welding, grinding, burning, etc.), individual components may illicit an acute or chronic health effect. Refer to Section 11-Toxicological Information. 4(c) Immediate Medical Attention and Special Treatment: None Known Section 5 - Fire-fighting Measures 5(a) Suitable (and unsuitable) Extinguishing Media: Not Applicable for Hot Rolled or Cold Rolled Steel as sold/shipped. Use extinguishers appropriate for surrounding materials. 5(b) Specific Hazards arising from the chemical: Not Applicable for Hot Rolled or Cold Rolled Steel as sold/shipped. When burned, toxic smoke, fume and vapor may be emitted. 5(c) Special protective equipment and precautions for fire-fighters: Self-contained NIOSH approved respiratory protection and full protective clothing should be worn when fumes and/or smoke from fire are present. Heat and flames cause emittance of acrid smoke and fumes. Do not release runoff from fire control methods to sewers or waterways. Firefighters should wear full face-piece self-contained breathing apparatus and chemical protective clothing with thermal protection. Direct water stream will scatter and spread flames and, therefore, should not be used. Section 6 - Accidental Release Measures 6(a) Personal Precautions, Protective Equipment and Emergency Procedures: Not Applicable for Hot Rolled or Cold Rolled Steel as sold/shipped. For spills involving finely divided particles, clean-up personnel should be protected against contact with eyes and skin. If material is in a dry state, avoid inhalation of dust. 6(b) Methods and materials for containment and clean up: Not Applicable for Hot Rolled or Cold Rolled Steel as sold/shipped. Collect material in appropriate, labeled containers for recovery or disposal in accordance with federal, state, and local regulations. Follow applicable OSHA regulations (29 CFR 1910.120) and all other pertinent state and federal requirements. Page 2 of 9 Hot Rolled or Cold Rolled Steel SDS ID No.: AM USA - 001 Revision: 01/01/2016 Section 7 - Handling and Storage 7(a) Precautions for safe handling: Not Applicable for Hot Rolled or Cold Rolled Steel as sold/shipped, however further processing (welding, burning, grinding, etc.) with the potential for generating high concentrations of airborne particulates should be evaluated and controlled as necessary. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only outdoors or in well ventilated areas. Practice good housekeeping. Avoid breathing metal fumes and/or dust. Do not eat, drink or smoke when using this product. Cut resistant gloves and sleeves should be worn when working with steel products. 7(b) Conditions for safe storage, including any incompatibilities: Store away from acids and incompatible materials. Section 8 - Exposure Controls / Personal Protection 8(a) Occupational Exposure Limits (OELs): Hot Rolled or Cold Rolled Steel as sold/shipped in its physical form does not present an inhalation, ingestion or contact hazard, nor would any of the following exposure data apply. However, operations such as burning, welding (high temperature), sawing, brazing, machining, grinding, etc. may produce fumes and/or particulates. The following exposure limits are offered as reference for an experienced industrial hygienist to review. Ingredients Iron OSHA PEL 1 10 mg/m (as iron oxide fume) ACGIH TLV 2 5.0 mg/m (as iron oxide dust and fume) NIOSH REL 3 5.0 mg/m (as iron oxide dust and fume) IDLH 4 2,500 mg Fe/m3 Manganese (C) 5.0 mg/m (as Fume & Mn compounds) 0.2 mg/m (C) 5.0 mg/m 1.0 mg/m (as fume) 500 mg Mn/m3 (STEL) 3.0 mg/m Nickel 1.0 mg/m (as Ni metal & insoluble compounds) 1.5 mg/m (as inhalable fraction5 Ni metal) 0.2 mg/m (as inhalable fraction Ni inorganic only insoluble and soluble compounds) 0.015 mg/m (as Ni metal & insoluble and soluble compounds) 10 mg/m (as Ni) Silicon 15 mg/m (total dust, PNOR6) 10 mg/m 10 mg/m (as total dust) NE 5.0 mg/m (as respirable fraction, PNOR) 5.0 mg/m (as respirable dust) Aluminum 15 mg/m (total dust, PNOR) 1.0 mg/m3 10 mg/m (as total dust) NE 5.0 mg/m (as respirable fraction, PNOR) 5.0 mg/m (as respirable dust) NE - None Established 1. OSHA Permissible Exposure Limits (PELs) are 8-hour TWA (time-weighted average) concentrations unless otherwise noted. A (C) designation denotes a ceiling limit, which should not be exceeded during any part of the working exposure unless otherwise noted. A Peak is defined as the acceptable maximum peak for a maximum duration above the ceiling concentration for an eight-hour shift. A skin notation refers to the potential significant contribution to the overall exposure by the cutaneous route, either by contact with vapors or, of probable greater significance, by direct skin contact with the substance. A Short Term Exposure Limit (STEL) is defined as a 15-minute exposure, which should not be exceeded at any time during a workday. An Action level (AL) is used by OSHA and NIOSH to express a health or physical hazard. They indicate the level of a harmful or toxic substance/activity, which requires medical surveillance, increased industrial hygiene monitoring, or biological monitoring. Action Levels are generally set at one half of the PEL but the actual level may vary from standard to standard. The intent is to identify a level at which the vast majority of randomly sampled exposures will be below the PEL. 2. Threshold Limit Values (TLV) established by the American Conference of Governmental Industrial Hygienists (ACGIH) are 8-hour TWA concentrations unless otherwise noted. A Short Term Exposure Limit (STEL) is defined as the maximum concentration to which workers can be exposed for a short period of time (15 minutes) for only four times throughout the day with at least one hour between exposures. A "skin" notation refers to the potential significant contribution to the overall exposure by the cutaneous route, either by contact with vapors or, of probable greater significance, by direct skin contact with the substance. ACGIH-TLVs are only recommended guidelines based upon consensus agreement of the membership of the ACGIH. As such, the ACGIH TLVs are for guideline use purposes and are not legal regulatory standards for compliance purposes. The TLVs are designed for use by individuals trained in the discipline of industrial hygiene relative to the evaluation of exposure to various chemical or biological substances and physical agents that may be found in the workplace. 3. The National Institute for Occupational Safety and Health Recommended Exposure Limits (NIOSH-REL) - Compendium of Policy and Statements. NIOSH, Cincinnati, OH (1992). NIOSH is the federal agency designated to conduct research relative to occupational safety and health. As is the case with ACGIH TLVs, NIOSH RELs are for guideline purposes only and as such are not legal, regulatory limits for compliance purposes. 4. The "immediately dangerous to life or health air concentration values (IDLHs)" are used by NIOSH as part of the respirator selection criteria and were first developed in the mid-1970's by NIOSH. The Documentation for Immediately Dangerous to Life or Health Concentrations (IDLHs) is a compilation of the rationale and sources of information used by NIOSH during the original determination of 387 IDLHs and their subsequent review and revision in 1994. 5. Inhalable fraction. The concentration of inhalable particulate for the application of this TLV is to be determined from the fraction passing a size-selector with the characteristics defined in the ACGIH 2014 TLVs and BEIs (Biological Exposure Indices) Appendix D, paragraph A. 6. PNOR (Particulates Not Otherwise Regulated). All inert or nuisance dusts, whether mineral, inorganic, or organic, not listed specifically by substance name are covered by a limit which is the same as the inert or nuisance dust limit of 15 mg/m3 for total dust and 5 mg/m3 for the respirable fraction. 8(b) Appropriate Engineering Controls: Use controls as appropriate to minimize exposure to metal fumes and dusts during handling operations. Provide general or local exhaust ventilation systems to minimize airborne concentrations. Local exhaust is necessary for use in enclosed or confined spaces. Provide sufficient general/local exhaust ventilation in pattern/volume to control inhalation exposures below current exposure limits. 8(c) Individual Protection Measures: Respiratory Protection: Seek professional advice prior to respirator selection and use. Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, use only a NIOSH-approved respirator. Select respirator based on its suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of sufficient oxygen. Concentration in air of the various contaminants determines the extent of respiratory protection needed. Half-face, negative-pressure, air-purifying respirator equipped with P100 filter is acceptable for concentrations up to 10 times the exposure limit. Full-face, negative-pressure, air-purifying respirator equipped with P100 filter is acceptable for concentrations up to 50 times the exposure limit. Protection by air-purifying negativepressure and powered air respirators is limited. Use a positive-pressure-demand, full-face, supplied air respirator or self-contained .... Page 3 of 9 Hot Rolled or Cold Rolled Steel SDS ID No.: AM USA - 001 Revision: 01/01/2016 Section 8 - Exposure Controls / Personal Protection (continued) 8(c) Individual Protection Measures (continued): Respiratory Protection (continued): ...breathing apparatus (SCBA) for concentrations above 50 times the exposure limit. If exposure is above the IDLH (Immediately dangerous to life or health) for any of the constituents, or there is a possibility of an uncontrolled release or exposure levels are unknown, then use a positive-demand, full-face, supplied air respirator with escape bottle or SCBA. Warning! Air-purifying respirators both negative-pressure, and powered-air do not protect workers in oxygen-deficient atmospheres. Eyes: Wear appropriate eye protection to prevent eye contact. For operations which result in elevating the temperature of the product to or above its melting point or result in the generation of airborne particulates, use safety glasses to prevent eye contact. Contact lenses should not be worn where industrial exposures to this material are likely. Use safety glasses or goggles as required for welding, burning, sawing, brazing, grinding or machining operations. Skin: Wear appropriate personal protective clothing to prevent skin contact. Cut resistant gloves and sleeves should be worn when working with steel products. For operations which result in elevating the temperature of the product to or above its melting point or result in the generation of airborne particulates, use protective clothing, and gloves to prevent skin contact. Protective gloves should be worn as required for welding, burning or handling operations. Contaminated work clothing must not be allowed out of the workplace. Other protective equipment: An eyewash fountain and deluge shower should be readily available in the work area. Section 9 - Physical and Chemical Properties 9(a) Appearance (physical state, color, etc.): Solid, Metallic Gray 9(b) Odor: Odorless 9(c) Odor Threshold: NA 9(d) pH: NA 9(e) Melting Point/Freezing Point: ~2750 F (~1510 C) 9(f) Initial Boiling Point and Boiling Range: ND 9(g) Flash Point: NA 9(h) Evaporation Rate: NA 9(i) Flammability (solid, gas): Non-flammable, non-combustible NA - Not Applicable ND - Not Determined for product as a whole 9(j) Upper/lower Flammability or Explosive Limits: NA 9(k) Vapor Pressure: NA 9(l) Vapor Density (Air = 1): NA 9(m) Relative Density: 7.85 9(n) Solubility(ies): Water Insoluble 9(o) Partition Coefficient n-octanol/water: ND 9(p) Auto-ignition Temperature: NA 9(q) Decomposition Temperature: ND 9(r) Viscosity: NA Section 10 - Stability and Reactivity 10(a) Reactivity: Not Determined (ND) for product in a solid form. Do not use water on molten metal. 10(b) Chemical Stability: Steel products are stable under normal storage and handling conditions. 10(c) Possibility of hazardous reaction: None Known 10(d) Conditions to Avoid: Storage with strong acids or calcium hypochlorite 10(e) Incompatible Materials: Will react with strong acids to form hydrogen. Iron oxide dusts in contact with calcium hypochlorite evolve oxygen and may cause an explosion. 10(f) Hazardous Decomposition Products: Thermal oxidative decomposition of steel products can produce fumes containing oxides of iron and manganese as well as other alloying elements. Section 11 - Toxicological Information 11 Information on toxicological effects: The following toxicity data has been determined for Hot or Cold Rolled Steel when further processed using the information available for its components applied to the guidance on the preparation of an SDS under the GHS requirements of OSHA and the EU CPL. Hazard Classification Eye Damage/ Irritation (covers Categories 1, 2A and 2B) Hazard Category EU OSHA NA* 2Bc Hazard Symbols No Pictogram Signal Word Warning Hazard Statement Causes eye irritation - Rating due to iron particulate generated from further processing (welding, grinding, burning, etc.). Skin/Dermal Sensitization (covers Category 1) NA* 1d Warning May cause an allergic skin reaction. - Nickel is a skin sensitizer. C1Aar, c1iBnoagnedn2ic)ity (covers Categories NA* 2g Toxic Reproduction (covers Categories 1A, 1B and 2) NA* 2h Warning Warning Page 4 of 9 Suspected of causing cancer. - Rating due to nickel particulate or fume that can enter the body generated when further processed (welding, grinding, burning, etc.). Suspected of damaging fertility or the unborn child. - Rating due to nickel particulate or fume that can enter the body generated when further processed (welding, grinding, burning, etc.). Hot Rolled or Cold Rolled Steel SDS ID No.: AM USA - 001 Revision: 01/01/2016 Section 11 - Toxicological Information (continued) 11 Information on toxicological effects (continued): Hazard Classification Hazard Category EU OSHA Hazard Symbols Signal Word Hazard Statement Specific Target Organ Toxicity (STOT) Following Single Exposure NA* 3i (covers Categories 1-3) Warning May cause respiratory irritation. - Rating due to iron particulate or fume that can enter the body generated when further processed (welding, grinding, burning, etc.). STOT following Repeated Exposure (covers Categories 1 and 2) NA* 1j Danger Causes damage to lungs and central nervous system through prolonged or repeated inhalation exposure. - Rating due to nickel or manganese particulate or fume that can enter the body generated when further processed (welding, grinding, burning, etc.). * Not Applicable - Semi-formed steel products are considered articles under Reach regulation (REACH REGULATION (EC) No 1907/2006) and are not subject to classification under CLP regulation (REGULATION (EC) No 1272/2008). Toxicological data listed below are presented regardless to classification criteria. Individual hazard classification categories where the toxicological information has met or exceeded a classification criteria threshold are listed above. a. No LC50 or LD50 has been established for Hot Rolled or Cold Rolled Steel. The following data has been determined for the components: Iron: Rat LD50 =98.6 g/kg (REACH) Aluminum: Rat LD50 > 15.9 g/kg (REACH) Rat LD50 =1060 mg/kg (IUCLID) Rat LD50 =984 mg/kg (IUCLID) Rabbit LD50 =890 mg/kg (IUCLID) Guinea Pig LD50 =20 g/kg (TOXNET) Nickel: LD50 >9000 mg/kg (Oral/Rat) Manganese: Rat LD50 > 2000 mg/kg (REACH) Rat LD50 > 9000 mg/kg (NLM Toxnet) Silicon: LD50 = 3160 mg/kg (Oral/Rat) b. No Skin (Dermal) Irritation data available for Hot Rolled or Cold Rolled Steel as a mixture or its individual components. c. No Eye Irritation data available for Hot Rolled or Cold Rolled Steel as a mixture. The following Eye Irritation information was found for the components: Iron: Causes eye irritation. Silicon: Slight eye irritation in rabbit protocol. Nickel: Slight eye irritation from particulate abrasion only. d. No Skin (Dermal) Sensitization data available for Hot Rolled or Cold Rolled Steel as a mixture. The following Skin (Dermal) Sensitization information was found for the components: Nickel: May cause allergic skin sensitization. e. No Respiratory Sensitization data available for Hot Rolled or Cold Rolled Steel as a mixture or its components. f. No Germ Cell Mutagenicity data available for Hot Rolled or Cold Rolled Steel as a mixture. The following Mutagenicity and Genotoxicity information was found for the components: Iron: IUCLID has found some positive and negative findings in vitro. Nickel: EU RAR has found positive results in vitro and in vivo but insufficient data for classification. Aluminum: IUCLID; ATSDR have found this ingredient is not mutagenic in vitro; but has marginal effects in vivo. g. Carcinogenicity: IARC, NTP, and OSHA do not list Hot Rolled or Cold Rolled Steel as carcinogens. The following Carcinogenicity information was found for the components: Welding Fumes - IARC Group 2B carcinogen, a mixture that is possibly carcinogenic to humans. Nickel and certain nickel compounds - Group 2B - metallic nickel Group 1 - nickel compounds ACGIH confirmed human carcinogen. Nickel - EURAR Insufficient evidence to conclude carcinogenic potential in animals or humans; suspect carcinogen classification Category 2 Suspected of causing cancer. h. No Toxic Reproduction data available for Hot Rolled or Cold Rolled Steel as a mixture. The following Toxic Reproductive information was found for the components: Nickel: Effects on fertility. i. No Specific Target Organ Toxicity (STOT) following a Single Exposure data available for Hot Rolled or Cold Rolled Steel as a mixture. The following STOT following a Single Exposure data was found for the components: Iron: Irritating to Respiratory tract. j. No Specific Target Organ Toxicity (STOT) following Repeated Exposure data was available for Hot Rolled or Cold Rolled Steel as a whole. The following STOT following Repeated Exposure data was found for the components: Nickel: Rat 4 wk inhalation LOEL 4 mg/m3 Lung and Lymph node histopathology. Rat 2 yr inhalation LOEL 0.1 mg/ m3 Pigment in kidney, effects on hematopoiesis spleen and bone marrow and adrenal tumor. Rat 13 Week Inhalation LOAEC 1.0 mg/m3 Lung weights, and Alveolar histopathology. Manganese: Inhalation of metal fumes - Degenerative changes in human Brain; Behavioral: Changes in motor activity and muscle weakness (Whitlock et al., 1966). Aluminum: Repeated exposure associated with Asthma, fibrosis in lungs and encephalopathy in humans. Reviews have found chronic exposure to aluminum flake has been reported to cause pneumoconiosis in workers. Repeat oral exposure to aluminum results in decrements in neurobehavioral function and development. Page 5 of 9 Hot Rolled or Cold Rolled Steel SDS ID No.: AM USA - 001 Revision: 01/01/2016 Section 11 - Toxicological Information (continued) 11 Information on toxicological effects (continued): The above toxicity information was determined from available scientific sources to illustrate the prevailing posture of the scientific community. The scientific resources includes: The American Conference of Governmental Industrial Hygienist (ACGIH) Documentation of the Threshold Limit Values (TLVs) and Biological Exposure indices (BEIs) with Other Worldwide Occupational Exposure Values 2009, The International Agency for Research on Cancer (IARC), The National Toxicology Program (NTP) updated documentation, the World Health Organization (WHO) and other available resources, the International Uniform Chemical Information Database (IUCLID), European Union Risk Assessment Report (EU-RAR), Concise International Chemical Assessment Documents (CICAD), European Union Scientific Committee for Occupational Exposure Limits (EU-SCOEL), Agency for Toxic Substances and Disease Registry (ATSDR), Hazardous Substance Data Bank (HSDB), and International Programme on Chemical Safety (IPCS), European Union Classification, Labeling and Packaging. (EU CPL), Regulation on Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), International Uniform Chemical Information Database (IUCLID), TOXicology Data NETwork (TOXNET), European Risk Assessment Reports (EU RAR). The following health hazard information is provided regardless to classification criteria and is based on the individual component(s) and potential resultant components from further processing: Acute Effects: Inhalation: Excessive exposure to high concentrations of metal dust may cause irritation to the eyes, skin and mucous membranes of the upper respiratory tract. Excessive inhalation of fumes of freshly formed metal oxide particles sized below 1.5 micrometer and usually between 0.02-0.05 micrometers from many metals can produce an acute reaction known as "metal fume fever". Symptoms consist of chills and fever (very similar to and easily confused with flu symptoms), metallic taste in the mouth, dryness and irritation of the throat followed by weakness and muscle pain. The symptoms come on in a few hours after excessive exposures and usually last from 12 to 48 hours. Long-term effects from metal fume fever have not been noted. Freshly formed oxide fumes of manganese have been associated with causing metal fume fever. Eye: Excessive exposure to high concentrations of metal dust may cause irritation to the eyes. Skin: Skin contact with metal dusts may cause irritation or sensitization, possibly leading to dermatitis. Skin contact with metallic fumes and dusts may cause physical abrasion. Ingestion: Ingestion of harmful amounts of this product as distributed is unlikely due to its solid insoluble form. Ingestion of metal dust may cause nausea or vomiting. Acute Effects by component: Iron and iron oxides: Iron is harmful if swallowed, causes skin irritation, and causes eye irritation. Contact with iron oxide has been reported to cause skin irritation and serious eye damage. Particles of iron or iron compounds, which become imbedded in the eye, may cause rust stains unless removed fairly promptly. Manganese and manganese oxides: Manganese and Manganese oxide are harmful if swallowed. Nickel and nickel oxides: Nickel may cause allergic skin sensitization. Nickel oxide may cause an allergic skin. Silicon and silicon oxides: May be harmful if swallowed. Aluminum and aluminum oxides : Not Reported/ Not Classified Delayed (chronic) Effects by component: Iron and iron oxides: Chronic inhalation of excessive concentrations of iron oxide fumes or dusts may result in the development of a benign pneumoconiosis, called siderosis, which is observable as an X-ray change. No physical impairment of lung function has been associated with siderosis. Inhalation of excessive concentrations of ferric oxide may enhance the risk of lung cancer development in workers exposed to pulmonary carcinogens. Iron oxide is listed as a Group 3 (not classifiable) carcinogen by the International Agency for Research on Cancer (IARC). Manganese and manganese oxides: Chronic exposure to high concentrations of manganese fumes and dusts may adversely affect the central nervous system with symptoms including languor, sleepiness, weakness, emotional disturbances, spastic gait, mask-like facial expression and paralysis. Animal studies indicate that manganese exposure may increase susceptibility to bacterial and viral infections. Occupational overexposure (Manganese) is a progressive, disabling neurological syndrome that typically begins with relatively mild symptoms and evolves to include altered gait, fine tremor, and sometimes, psychiatric disturbances. May cause damage to lungs with repeated or prolonged exposure. Neurobehavioral alterations in worker populations exposed to manganese oxides include: speed and coordination of motor function are especially impaired. Nickel and nickel oxides: Exposure to nickel dusts and fumes can cause sensitization dermatitis, respiratory irritation, asthma, pulmonary fibrosis, edema, and may cause nasal or lung cancer in humans. Nickel causes damage to lungs through prolonged or repeated inhalation exposure. IARC lists nickel and certain nickel compounds as Group 2B carcinogens (sufficient animal data). ACGIH 2014 TLVs and BEIs lists insoluble nickel compounds as confirmed human carcinogens. Nickel is suspected of damaging the unborn child. Silicon and silicon oxides: Silicon dusts are a low health risk by inhalation and should be treated as a nuisance dust. Eye contact with pure material can cause particulate irritation. Skin contact with silicon dusts may cause physical abrasion. Aluminum and Aluminum oxides: Chronic inhalation of finely divided powder has been reported to cause pulmonary fibrosis and emphysema. Repeated skin contact has been associated with bleeding into the tissue, delayed hypersensitivity and granulomas. Chronic exposure to aluminum flake has been reported to cause pneumoconiosis in workers. Repeat oral exposure to aluminum results in decrements in neurobehavioral function and development. Section 12 - Ecological Information 12(a) Ecotoxicity (aquatic & terrestrial): No Data Available for Hot Rolled or Cold Rolled Steel as sold/shipped. However, individual components of the product when processed have been found to be toxic to the environment. Metal dusts may migrate into soil and groundwater and be ingested by wildlife as follows: Iron Oxide: LC50: >1000 mg/L; Fish 48 h-EC50 > 100 mg/L (Currenta, 2008k); 96 h-LC0 50,000 mg/L Test substance: Bayferrox 130 red (95 - 97% Fe2O3; < 4% SiO2 and Al2O3) (Bayer, 1989a). Nickel Oxide: IUCLID found LC50 in fish, invertebrates and algae > 100 mg/l. 12(b) Persistence & Degradability: No Data Available for Hot Rolled or Cold Rolled Steel as sold/shipped or individual components. Page 6 of 9 Hot Rolled or Cold Rolled Steel SDS ID No.: AM USA - 001 Revision: 01/01/2016 Section 12 - Ecological Information (continued) 12(c) Bioaccumulative Potential: No Data Available for Hot Rolled or Cold Rolled Steel as sold/shipped or individual components. 12(d) Mobility (in soil): No data available for Hot Rolled or Cold Rolled Steel as sold/shipped. However, individual components of the product have been found to be absorbed by plants from soil. 12(e) Other adverse effects: None Known Additional Information: Hazard Category: Not Reported Hazard Symbol: No Symbol Hazard Statement: No Statement Signal Word: No Signal Word Section 13 - Disposal Considerations Disposal: Steel scrap should be recycled whenever possible. Product dusts and fumes from processing operations should also be recycled, or classified by a competent environmental professional and disposed of in accordance with applicable federal, state or local regulations. Container Cleaning and Disposal: Follow applicable federal, state and local regulations. Observe safe handling precautions. European Waste Catalogue (EWC): 16-01-17 (ferrous metals), 12-01-99 (wastes not otherwise specified), 16-03-04 (off specification batches and unused products), or 15-01-04 (metallic packaging). Please note this information is for Hot Rolled or Cold Rolled Steel in its original form. Any alterations can void this information. Section 14 - Transport Information 14 (a-g) Transportation Information: US Department of Transportation (DOT) under 49 CFR 172.101 does not regulate Hot Rolled or Cold Rolled Steel as a hazardous material. All federal, state, and local laws and regulations that apply to the transport of this type of material must be adhered to. Shipping Name: Not Applicable (NA) Packaging Authorizations Quantity Limitations Shipping Symbols: NA a) Exceptions: NA a) Passenger, Aircraft, or Railcar: NA Hazard Class: NA b) Group: NA b) Cargo Aircraft Only: NA UN No.: NA c) Authorization: NA Vessel Stowage Requirements Packing Group: NA a) Vessel Stowage: NA DOT/ IMO Label: NA b) Other: NA Special Provisions (172.102): NA DOT Reportable Quantities: NA International Maritime Dangerous Goods (IMDG) and the Regulations Concerning the International Carriage of Dangerous Goods by Rail (RID) classification, packaging and shipping requirements follow the US DOT Hazardous Materials Regulation. Regulations Concerning the International Carriage of Dangerous Goods by Road (ADR) does not regulate Hot Rolled or Cold Rolled Steel as a hazardous material. Shipping Name: Not Applicable (NA) Packaging Portable Tanks & Bulk Containers Classification Code: NA a) Packing Instructions: NA a) Instructions: NA UN No.: NA b) Special Packing Provisions: NA b) Special Provisions: NA Packing Group: NA c) Mixed Packing Provisions: NA ADR Label: NA Special Provisions: NA Limited Quantities: NA International Air Transport Association (IATA) does not regulate Hot Rolled or Cold Rolled Steel as a hazardous material. Shipping Name: Not Applicable (NA) Class/Division: NA Passenger & Cargo Aircraft Limited Quantity (EQ) Cargo Aircraft Only Special Provisions: Pkg Inst: NA NA Hazard Label (s): NA UN No.: NA Packing Group: NA Excepted Quantities (EQ): NA Pkg Inst: NA Max Net Qty/Pkg: NA Pkg Inst: NA Max Net Qty/Pkg: NA Max Net Qty/Pkg: NA ERG Code: NA Pkg Inst - Packing Instructions Max Net Qty/Pkg - Maximum Net Quantity per Package ERG - Emergency Response Drill Code Transport Dangerous Goods (TDG) Classification: Hot Rolled or Cold Rolled Steel does not have a TDG classification. Page 7 of 9 Hot Rolled or Cold Rolled Steel SDS ID No.: AM USA - 001 Revision: 01/01/2016 Section 15 - Regulatory Information Regulatory Information: The following listing of regulations relating to an ArcelorMittal product may not be complete and should not be solely relied upon for all regulatory compliance responsibilities. This product and/or its constituents are subject to the following regulations: OSHA Regulations: Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-2, Z-3): The product, Hot Rolled or Cold Rolled Steel as a whole is not listed. However, individual components of the product are listed: Refer to Section 8, Exposure Controls and Personal Protection. EPA Regulations: listed: Components Manganese Nickel Aluminum The product, Hot Rolled or Cold Rolled Steel is not listed as a whole. Regulations CAA, SARA 313, SDWA CAA, CERCLA, CWA, SARA 313 SARA 313 However, individual components of the product are SARA Potential Hazard Categories: Immediate Acute Health Hazard; Delayed Chronic Health Hazard. Section 313 Supplier Notification: The product, Hot Rolled or Cold Rolled Steel contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-to-Know Act and 40 CFR part 372: CAS # 7439-96-5 7440-02-0 7429-90-5 Chemical Name Manganese Nickel Aluminum Percent by Weight 2.5 max 1.8 max 1.60 Regulations Key: CAA Clean Air Act (42 USC Sec. 7412; 40 CFR Part 61 [As of: 8/18/06]) CERCLA Comprehensive Environmental Response, Compensation and Liability Act (42 USC Secs. 9601(14), 9603(a); 40 CFR Sec. 302.4, Table 302.4, Table 302.4 and App. A) CWA Clean Water Act (33 USC Secs. 1311; 1314(b), (c), (e), (g); 136(b), (c); 137(b), (c) [as of 8/2/06]) RCRA Resource Conservation Recovery Act (42 USC Sec. 6921; 40 CFR Part 261 App VIII) SARA Superfund Amendments and Reauthorization Act of 1986 Title III Section 302 Extremely Hazardous Substances (42 USC Secs. 11023, 13106; 40 CFR sec. 372.65) and Section 313 Toxic Chemicals (42 USC secs. 11023, 13106; 40 CFR Sec. 372.65 [as of 6/30/05]) TSCA Toxic Substance Control Act (15 U.S.C. s/s 2601 et seq. [1976]) SDWA Safe Drinking Water Act (42 U.S.C. s/s 300f et seq. [1974]) State Regulations: The product, Hot Rolled or Cold Rolled Steel as a whole is not listed in any state regulations. However, components of the product are listed in various state regulations: Pennsylvania Right to Know: Contains regulated material in the following categories: Hazardous Substances: Aluminum, Manganese, Nickel and Silicon Environmental Hazards: Aluminum, Manganese and Nickel Special Hazardous Substance: Nickel California Prop. 65: Contains elements known to the State of California to cause cancer or reproductive toxicity. This includes Nickel. New Jersey: Contains regulated material in the following categories: Hazardous Substance: Aluminum, Manganese, Molybdenum, Silicon, and Nickel Environmental Hazards: Manganese and Nickel Special Hazardous Substance: Aluminum. Manganese and Silicon Minnesota: Manganese, and Nickel Massachusetts: Aluminum, Manganese, Silicon and Nickel individual Other Regulations: WHMIS Classification (Canadian): The product, Hot Rolled or Cold Rolled Steel is not listed as a whole. However individual components are listed. Ingredients Manganese Nickel Silicon WHMIS Classification Reproductive toxicity - Category 2, Specific target organ toxicity - repeated exposure - Category 1, Combustible dusts Skin sensitization - Category 1, Carcinogenicity - Category 2, Specific target organ toxicity - repeated exposure - Category 1 Flammable solids - Category 2, Combustible dusts This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. Prepared By: ArcelorMittal USA LLC Original Issue Date: 8/26/2002 Section 16 - Other Information Revised Date: 01/01/2016 Page 8 of 9 Hot Rolled or Cold Rolled Steel SDS ID No.: AM USA - 001 Revision: 01/01/2016 Section 16 - Other Information (continued) Additional Information: Hazardous Material Identification System (HMIS) Classification National Fire Protection Association (NFPA) Health Hazard 1 Fire Hazard 0 Physical Hazard 0 HEALTH= 1, Denotes possible chronic hazard if airborne dusts or fumes are generated Irritation or minor reversible injury possible. FIRE= 0, Materials that will not burn. PHYSICAL HAZARD= 0, Materials that are normally stable, even under fire conditions, and will not react with water, polymerize, decompose, condense, or self-react. Non-explosives. HEALTH = 1, Exposure could cause irritation but only minor residual injury even if no treatment is given. FLAMMABILITY = 0, Materials that will not burn. INSTABILITY = 0, Normally stable, even under fire exposure conditions, and are not reactive with water. ABBREVIATIONS/ACRONYMS: ACGIH American Conference of Governmental Industrial Hygienists BEIs Biological Exposure Indices CAS Chemical Abstracts Service Comprehensive Environmental Response, Compensation, and CERCLA Liability Act CLP Classification, Labelling and Packaging CFR Code of Federal Regulations CNS Central Nervous System GI, GIT Gastro-Intestinal, Gastro-Intestinal Tract HMIS Hazardous Materials Identification System IARC International Agency for Research on Cancer LC50 Median Lethal Concentration LD50 Median Lethal Dose LD Lo LEL LOEL LOAEC g/m3 mg/m3 mppcf MSHA NFPA Lowest Dose to have killed animals or humans Lower Explosive Limit Lowest Observed Effect Level Lowest Observable Adverse Effect Concentration microgram per cubic meter of air milligram per cubic meter of air million particles per cubic foot Mine Safety and Health Administration National Fire Protection Association NIF NIOSH NTP ORC OSHA PEL PNOR PNOC PPE ppm RCRA REACH RTECS SARA SCBA SDS STEL TLV TWA UEL No Information Found National Institute for Occupational Safety and Health National Toxicology Program Organization Resources Counselors Occupational Safety and Health Administration Permissible Exposure Limit Particulate Not Otherwise Regulated Particulate Not Otherwise Classified Personal Protective Equipment parts per million Resource Conservation and Recovery Act Regulation on Registration, Evaluation, Authorization and Restriction of Chemicals Registry of Toxic Effects of Chemical Substances Superfund Amendment and Reauthorization Act Self-contained Breathing Apparatus Safety Data Sheet Short-term Exposure Limit Threshold Limit Value Time-weighted Average Upper Explosive Limit Disclaimer: This information is taken from sources or based upon data believed to be reliable. Our objective in sending this information is to help you protect the health and safety of your personnel and to comply with the OSHA Hazard Communication Standard and Title III of the Emergency Planning and Community Right-to-Know Act. ArcelorMittal USA LLC makes no warranty as to the absolute correctness, completeness, or sufficiency of any of the foregoing, or any additional, or other measures that may not be required under particular conditions. THIS ARCELORMITTAL USA LLC SDS MAKES NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING THE IMPLIED WARRANTY OF MERCHANTABILITY, OR ANY IMPLIED WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE, AND ANY IMPLIED WARRANTIES OTHERWISE ARISING FROM COURSE OF DEALING OR TRADE. Products covered for Hot Rolled or Cold Rolled Steel include: Cold Rolled Steel Cold Rolled Full Hard Steel Cold Rolled Enameling Steel Cold Rolled Carbon Steel Cold Rolled HSLA Steel Cold Rolled Motor Lamination Steel Hot Rolled Carbon Steel Floor Plate Hot Rolled HSLA Steel Advanced High Strength Steel (AHSS)/TRIP Bake Hard High Strength Low Alloy (HSLA) Low Carbon Ultra High Strength (UHSS) Ultra Low Carbon (ULC) Advanced High Strength (AHSS) Structural Page 9 of 9 Hot Rolled or Cold Rolled Steel Signal Word: DANGER Symbols: HAZARD STATEMENTS: Causes eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause respiratory irritation. Causes damage to lungs and central nervous system through prolonged or repeated inhalation exposure. PRECAUTIONARY STATEMENTS Do not breathe dusts / fume / gas / mist / vapor / spray. Wear protective gloves / protective clothing / eye protection / face protection. Contaminated work clothing must not be allowed out of the workplace. Use only outdoors or in well ventilated areas. Wash thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not eat, drink or smoke when using this product. If inhaled: Remove person to fresh air and keep comfortable for breathing. If exposed, concerned or feel unwell: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue Rinsing. If on skin: Wash with plenty of water. If irritation or rash occurs: Get medical advice/attention. Take off and wash contaminated clothing before reuse. Call a poison center/doctor if you feel unwell. Dispose of contents in accordance with federal, state and local regulations. SDS ID No.: AM USA - 001 ArcelorMittal USA LLC 1 South Dearborn Street Chicago, IL 60603-9888 General Information: Phone: 219-787-4901 or email at: msdssupport@arcelormittal.com CHEMTREC (Day or Night): 1-800-424-9300 Emergency Contact: 1-760-476-3962, (3E Company Code: 333211) Original Issue Date: 8/26/2002 Revised: 01/01/2016 Material Safety Data Sheet Revision Number: 002.1 Issue date: 06/24/2011 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Product type: BONDERITE C-IC PURGE 2510 SCALE REMOVER known as PARCO PURGE 2510 Cleaner Company address: Henkel Corporation 32100 Stephenson Highway Madison Heights, MI 48071 IDH number: 593872 Region: United States Contact information: Telephone: 248.583.9300 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: 3 Color: Light yellow FLAMMABILITY: 0 Odor: Sharp PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 DANGER-CORROSIVE!: CAUSES EYE, SKIN, DIGESTIVE TRACT, AND RESPIRATORY TRACT BURNS. Relevant routes of exposure: Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Skin, Inhalation, Eyes Mists, vapors or liquid may cause severe irritation or burns. Inhalation of mists or vapors may produce upper airway edema, wheezing, pulmonary edema, pneumonitis and respiratory failure. Corrosive to the skin. Contact with the skin or mucous membranes may cause severe irritation and burns. This product is severely irritating to the eyes and may cause irreversible damage including burns and blindness. This product may be fatal if it is swallowed. This product may produce corrosive damage to the gastrointestinal tract if it is swallowed. Pre-existing skin, eye and respiratory allergies. This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components Hydrochloric acid CAS NUMBER 7647-01-0 % 30 - 60 4. FIRST AID MEASURES Inhalation: If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. IDH number: 593872 Product name: BONDERITE C-IC PURGE 2510 SCALE REMOVER known as PARCO PURGE 2510 Page 1 of 5 Skin contact: Eye contact: Ingestion: Remove contaminated clothing and footwear. For skin contact, flush with large amounts of water. Seek immediate medical attention. Launder contaminated clothing before reuse. In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Immediate medical treatment necessary. DO NOT induce vomiting unless directed to do so by medical personnel. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions. 5. FIRE FIGHTING MEASURES Flash point: Not applicable Autoignition temperature: Not available Flammable/Explosive limits - lower: Not applicable Flammable/Explosive limits - upper: Not applicable Extinguishing media: Use media appropriate for surrounding material. Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Unusual fire or explosion hazards: This product is an aqueous mixture which will not burn. Hazardous combustion products: Upon combustion, oxides of chlorine may be released. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear suitable protective clothing, gloves and eye/face protection. Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. Ventilate area. 7. HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Do not breathe gas/fumes/vapor/spray. Wash thoroughly after handling. Provide adequate ventilation. Do not take internally. For industrial use only. Storage: Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components Hydrochloric acid ACGIH TLV 2 ppm Ceiling OSHA PEL 5 ppm (7 mg/m3) Ceiling AIHA WEEL None OTHER None IDH number: 593872 Product name: BONDERITE C-IC PURGE 2510 SCALE REMOVER known as PARCO PURGE 2510 Page 2 of 5 Engineering controls: Respiratory protection: Eye/face protection: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Wear chemical goggles; face shield (if splashing is possible). Skin protection: Chemical resistant, impermeable gloves. Gloves should be tested to determine suitability for prolonged contact. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: pH: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Liquid Light yellow Sharp Not available < 1 Not determined > 100 C (> 212F) Not available 1.1 - 1.2 Not determined Not applicable Not applicable Not applicable Not available Not available Complete Not available Not applicable 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Stable at normal conditions. None under normal processing. Upon combustion, oxides of chlorine may be released. Incompatible materials: Conditions to avoid: This product may react with strong alkalies. Do not mix with chlorates. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Hazardous components Hydrochloric acid NTP Carcinogen No IARC Carcinogen No OSHA Carcinogen (Specifically Regulated) No Hazardous components Hydrochloric acid Health Effects/Target Organs Irritant, Corrosive, Kidney 12. ECOLOGICAL INFORMATION Ecological information: No data available. Because of the low pH of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. IDH number: 593872 Product name: BONDERITE C-IC PURGE 2510 SCALE REMOVER known as PARCO PURGE 2510 Page 3 of 5 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations. Hazardous waste number: This product, if discarded directly, would be a characteristic RCRA corrosive waste (D002). 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Hydrochloric acid Hazard class or division: 8 Identification number: UN 1789 Packing group: II DOT Reportable quantity: Hydrochloric acid International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Hydrochloric acid 8 UN 1789 II Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: HYDROCHLORIC ACID 8 UN 1789 II 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimus Hydrochloric acid (CAS# 7647-01-0). Immediate Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Hydrochloric acid (CAS# 7647-01-0). Hydrochloric acid (CAS# 7647-01-0) 5,000 lbs. (2,270 kg) This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. E, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Prepared by: Jennifer Mckay, Regulatory Affairs Specialist IDH number: 593872 Product name: BONDERITE C-IC PURGE 2510 SCALE REMOVER known as PARCO PURGE 2510 Page 4 of 5 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: 593872 Product name: BONDERITE C-IC PURGE 2510 SCALE REMOVER known as PARCO PURGE 2510 Page 5 of 5 Material Safety Data Sheet Revision Number: 001.2 Issue date: 11/30/2010 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Product type: BONDERITE C-NE 5175 NEUTRAL CLEANER known as P3 NEUTRACARE 5175 Cleaner Company address: Henkel Corporation 32100 Stephenson Highway Madison Heights, MI 48071 IDH number: 1265623 Region: United States Contact information: Telephone: 248.583.9300 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION Physical state: Color: Odor: WARNING: EMERGENCY OVERVIEW HMIS: Liquid HEALTH: 2 Yellow FLAMMABILITY: 0 Ammoniacal PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Relevant routes of exposure: Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Skin, Inhalation, Eyes Inhalation of vapors or mists of the product may be irritating to the respiratory system. This product may cause irritation to the skin. This product is severely irritating to the eyes. Ingestion of this product is unlikely. However, ingestion of product may produce gastrointestinal irritation and disturbances. Eye, skin, and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components Inorganic phosphate Amine borate Isononanoic acid, potassium salt CAS NUMBER Proprietary Proprietary 84501-71-3 % 10 - 30 10 - 30 5 - 10 4. FIRST AID MEASURES Inhalation: If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. IDH number: 1265623 Product name: BONDERITE C-NE 5175 NEUTRAL CLEANER known as P3 NEUTRACARE 5175 Page 1 of 5 Skin contact: Eye contact: Ingestion: Notes to physician: For skin contact flush with large amounts of water. Obtain medical attention if irritation persists. In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Get immediate medical attention. Do not induce vomiting. Treat symptomatically and supportively. 5. FIRE FIGHTING MEASURES Flash point: > 100 C (> 212F) Autoignition temperature: Not applicable Flammable/Explosive limits - lower: Not applicable Flammable/Explosive limits - upper: Not applicable Extinguishing media: Use media appropriate for surrounding material. Special firefighting procedures: Wear full protective clothing. Wear self-contained breathing apparatus. Unusual fire or explosion hazards: This product is an aqueous mixture which will not burn. Hazardous combustion products: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear suitable protective clothing, gloves and eye/face protection. Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Do not take internally. Storage: Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Manufacturer recommends storing above 4.4 C (40 F). Thaw and mix thoroughly if frozen. Do not store above 100 F (37.7 C). For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. IDH number: 1265623 Product name: BONDERITE C-NE 5175 NEUTRAL CLEANER known as P3 NEUTRACARE 5175 Page 2 of 5 Hazardous components Inorganic phosphate Amine borate Isononanoic acid, potassium salt ACGIH TLV None 2 mg/m3 TWA Inhalable fraction. 6 mg/m3 STEL Inhalable fraction. None OSHA PEL None None None AIHA WEEL None None None OTHER None None None Engineering controls: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Eye/face protection: Wear safety glasses; chemical goggles (if splashing is possible). Skin protection: Chemical resistant, impermeable gloves. Gloves should be tested to determine suitability for prolonged contact. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: pH: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Liquid Yellow Ammoniacal Not available 10 Not determined > 98.9 C (> 210F) Not determined 1.15 - 1.17 at 15.56 C (60.01 F) Not determined > 100 C (> 212F) Not applicable Not applicable Not applicable Not available Complete Not determined Not applicable 10. STABILITY AND REACTIVITY Stability: Stable at normal conditions. Hazardous reactions: Will not occur. Hazardous decomposition products: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Incompatible materials: This product may react with strong oxidizing agents. This product may react with strong reducing agents. Conditions to avoid: Keep away from heat, ignition sources and incompatible materials. 11. TOXICOLOGICAL INFORMATION Hazardous components Inorganic phosphate Amine borate Isononanoic acid, potassium salt NTP Carcinogen No No No IARC Carcinogen No No No OSHA Carcinogen (Specifically Regulated) No No No IDH number: 1265623 Product name: BONDERITE C-NE 5175 NEUTRAL CLEANER known as P3 NEUTRACARE 5175 Page 3 of 5 Hazardous components Inorganic phosphate Amine borate Isononanoic acid, potassium salt Health Effects/Target Organs No Target Organs Cardiac, Central nervous system, Developmental, Gastrointestinal tract, Irritant, Kidney, Metabolic, Reproductive No Records 12. ECOLOGICAL INFORMATION Ecological information: Not available 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations. This chemical contains phosphates. Hazardous waste number: Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated None None None Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated None None None 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimus None above reporting de minimus Immediate Health None above reporting de minimus No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.B IDH number: 1265623 Product name: BONDERITE C-NE 5175 NEUTRAL CLEANER known as P3 NEUTRACARE 5175 Page 4 of 5 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: Corrected information in Section(s): 15 Prepared by: Jennifer Mckay, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDH number: 1265623 Product name: BONDERITE C-NE 5175 NEUTRAL CLEANER known as P3 NEUTRACARE 5175 Page 5 of 5 SAFETY DATA SHEET Page 1 of 7 Issue Date: 01/11/2021 Section 1. Chemical product and company identification Product name: ZSR235242 RAL 9006 WHITE ALUMINIUM BONDED RPSD Product chemistry: Polyester Material uses Electrostatic coating for use in industrial plants. Manufacturer: Vitracoat Pinturas en Polvo s.a. de c.v. Av. Circuito de la Industria Sur No. 284, Parque Industrial Lerma. Lerma Edo. De Mex. C.P. 52000 In case of Emergency (Health or Spills): (52) 722 26 27000 U-5994S: 888-778 After hours: (52) 722 26 27000 U-5994S: 888-778 Section 2. Hazardous ingredients CHARACTERISTIC CHEMISTRY: Chemical Mixture SUBSTANCE Triglycidyl Isocyanurate Aluminium powder (stabilised) CAS N 2451-62-9 7429-90-5 231-072-3 %p/p 4-6 0-1 ACGIH TLV TWA TWA: 0.05 mg/m 8 hours. 10 mg/m GLOBALLY HARMONIZED SYSTEM Hazard statement: May cause the following hazards if not properly used (Section 7) and if not the recommended safety equipment (Section 5) is used. H303 May be harmful if swallowed H317 May cause an allergic skin reaction H320 Causes eye irritation H333 May be harmful if inhaled H335 May cause respiratory irritation H340 May cause genetic defects (routes of exposure oral,inhalation) H373 May cause damage to organs (respiratory) (if inhaled) LABEL 2 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Section 3. Hazards identification Emergency overview Physical state: Odor: Signal word: Hazard statements Precautionary measures : OSHA/HCS status: Solid. [Powder.] Odorless. WARNING! HARMFUL IF INHALED OR SWALLOWED. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT AND SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. MAY CAUSE GENETIC DEFECTS. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Do not breathe dust. Do not ingest. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep container tightly closed. Use personal protective equipment as required. Wash thoroughly after handling. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Potential acute health effects Inhalation Toxic by inhalation. Slightly irritating to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Ingestion Toxic if swallowed. Skin Slightly irritating to the skin. May cause sensitization by skin contact. Eyes Severely irritating to eyes. Risk of serious damage to eyes. Potential chronic health effects Chronic effects Contains material that can cause target organ damage. Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Target organs Contains material which causes damage to the following organs: lymphatic system. Contains material which may cause damage to the following organs: lungs, the nervous system, upper respiratory tract, skin, eyes. Over-exposure signs/symptoms Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing Ingestion No specific data. SAFETY DATA SHEET Page 2 of 7 Issue Date: 01/11/2021 Skin Adverse symptoms may include the following: Irritation, redness Eyes Adverse symptoms may include the following: pain or irritation watering redness Medical conditions aggravated by Pre-existing skin disorders and disorders involving any other target organs mentioned in this SDS as being at risk may be aggravated by over-exposure to this product. overexposure See toxicological information (Section 11) Section 4. First aid measures After contact with eyes: Check for and remove any contact lenses. Immediately flush eyes with plenty of clean water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. After skin contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. After inhalation of Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or material: oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. After ingestion: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the Protection of first-aiders: rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 5.-Fire fighting measures Flammability of the product Fine dust clouds may form explosive mixtures with air. Extinguishing media Suitable Not suitable Special exposure hazards Hazardous thermal decomposition products Special protective equipment for fire-fighters Use dry chemical, CO, water spray (fog) or foam. Do not use water jet. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Decomposition products may include the following materials: carbon dioxide, carbon monoxide, nitrogen oxides, sulfur oxides, metal oxide/oxides Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6.-Measures accidental release Personal precautions: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe dust. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Precautions for environmental Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains protection: and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods for cleaning / collecting: Pick up with vacuum equipment. Section 7.-Handling and storage Handling: Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe dust. Do not ingest. Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Prevent dust accumulation. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly SAFETY DATA SHEET Page 3 of 7 Issue Date: 01/11/2021 Storage: closed when not in use. Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with hot surfaces, sparks or other ignition sources. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8.-Exposure limits and personal protective equipment INGREDIENT Triglycidyl Isocyanurate Aluminium powder (stabilised) EXPOSURE LIMITS ACGIH TLV (United States, 3/2012). TWA: 0.05 mg/m 8 hours. AGW (Inhalable fraction) 10 mg/m AGW (Alveolate fraction) 1.35 mg/ m Recommended monitoring procedures Engineering measures Hygiene measures If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Personal protection Respiratory protection: Protection of hands: Eye protection: Skin protection: Environmental exposure controls Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. If operating conditions cause high dust concentrations to be produced, use dust goggles. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Section 9 -. Physical and chemical properties Physical state: Solid. (powder) Flash point: Vapor Pressure (20 C): N/A Closed cup: Not applicable. Auto-ignition temperature: 450 to 600C (842 to 1112F) Flammable limits: 20 - 70 g/m3 Odor: Solubility: Odorless Insoluble in the following materials: cold water and hot water. Relative density: Minimum ignition energy (mJ): 1.2 to 1.9 [ISO 8130-2/-3]N/A 5 to 20 Section 10. Stability and reactivity Chemical Stability: Conditions to avoid: The product is stable. Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Prevent dust Incompatible materials: Hazardous decomposition products: Possibility of hazardous reactions SAFETY DATA SHEET Page 4 of 7 Issue Date: 01/11/2021 accumulation. Reactive or incompatible with the following materials: oxidizing materials Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous reactions will not occur. Section 11. Toxicological information Acute toxicity Product/ingredient name Result Triglycidyl Isocyanurate LC50 Inhalation Dusts and mists LD50 Dermal LD50 Oral Aluminium powder (stabilised) LC50: Inhalation Species Rat Rabbit Rat Rat Dose 650 mg/m >2000 mg/kg 188 mg/kg >5 mg/l 4h Exposure 4 hours --- Chronic toxicity Product/ingredient name Triglycidyl Isocyanurate Irritation/Corrosion Product/ingredient name Triglycidyl Isocyanurate Result Sub-chronic NOAEL Oral Chronic NOAEL OralLD50 Sub-acute NOEL Inhalation Dusts and mists Result Eyes - Severe irritant Species Rat - Male, Female Dose 7.32 mg/kg Rat - Male 1.3 mg/kg Mouse - Male, Female <100 mg/m Exposure 94 days; 7 days per Week 63 weeks 5 days; 6 hours per day Species Rabbit Score Exposure 4 hours 100 milligrams Sensitizer Product/ingredient name Triglycidyl Isocyanurate Route of exposure Skin Species Guinea pig Result Sensitizing Carcinogenicity Product/ingredient name Triglycidyl Isocyanurate Result Negative - Oral - TD Species Rat - Male Dose 4.36 mg/kg Exposure 99 weeks; 24 hours per day Mutagenicity Product/ingredient name Triglycidyl Isocyanurate Test OECD 471 Bacterial Reverse Mutation Test OECD 483 Mammalian Spermatogonial, Chromosome, Aberration Test OECD 478 Genetic Toxicology: Rodent Dominant Lethal Test Teratogenicity Conclusion/Summary: Not available. Experiment Experiment: In vitro Subject: Bacteria Metabolic activation: Metabolic activation +/Experiment: In vivo Subject: Mammalian-Animal Cell: Germ Experiment: In vitro Subject: Mammalian-Human Cell: Somatic Metabolic activation: Metabolic activation+/Experiment: In vivo Subject: Mammalian-Animal Result Positive Positive Negative Negative Reproductive toxicity Product/ingredient name Triglycidyl Isocyanurate SAFETY DATA SHEET Page 5 of 7 Issue Date: 01/11/2021 Maternal toxicity ----- Fertility Negative Development toxin Negative Species Rat - Male Dose Oral Exposure 94 days; 7 days per week Section 12. Ecological information Ecotoxicity: No known significant effects or critical hazards. Aquatic ecotoxicity Product/ingredient name Triglycidyl Isocyanurate Result Acute EC50 29 mg/l Fresh water Aluminium powder (stabilised) Acute IC50 >100 mg/l Fresh water Acute LC50 >100 mg/l Fresh water No data available Species Algae Micro-organism Daphnia Exposure 72 hours 3 hours 24 hours Persistence/degradability Product/ingredient name Triglycidyl Isocyanurate Test OECD 301B Ready Biodegradability - CO Evolution Test Result 1 % - Not readily - 44 days Dose ---- Inoculum Activated sludge Section 13. Disposal considerations Waste disposal: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by- products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 14. Transport information Regulatory information UN number Proper shipping name Classes PG* DOT Classification TDG Classification Mexico Classification ADR/RID Class IMDG Class IATA-DGR Class PG*: Packing group Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated Not regulated ---- Not regulated ---- Not regulated ---- Not regulated ---- Not regulated ---- Not regulated ---- Section 15. Regulatory information HCS Classification: Toxic material, Irritating material, Sensitizing material, Target organ effects. Label Additional information ------------------- U.S. Federal regulations: Clean Air Act Section 112 (b): TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. Not listed SAFETY DATA SHEET Page 6 of 7 Issue Date: 01/11/2021 Hazardous Air Pollutants (HAPs) Clean Air Act Section 602: Class I Substances Clean Air Act Section 602: Class II Substances DEA List I Chemicals: (Precursor Chemicals) DEA List II Chemicals: (Essential Chemicals) Not listed Not listed Not listed Not listed SARA 302/304 Composition/information on ingredients No products were found. SARA 304 RQ: Not applicable. SARA 311/312 Classification: Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients Name % Triglycidyl Isocyanurate 4-6 Fire Hazard No Sudden release of Pressure No Reactive No Immediate (acute) health hazard Yes Delayed (chronic) health hazard Yes SARA 313 Product Name CAS Number % Form R - Reporting requirements No SARA (Superfund Amendments & Reauthorization AC) 313 chemicals are present SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations Massachusetts New York New Jersey Pennsylvania Canada inventory International regulations International lists Chemical Weapons: Convention List Schedule I Chemicals Chemical Weapons: Convention List Schedule II Chemicals Chemical Weapons: Convention List Schedule III Chemicals None of the components are listed. None of the components are listed. The following components are listed: TRIGLYCIDYL ISOCYANURATE The following components are listed: TRIGLYCIDYL ISOCYANURATE Not determined Australia inventory (AICS): Not determined. China inventory (IECSC): Not determined. Japan inventory: Not determined. Korea inventory: Not determined. Malaysia Inventory (EHS Register): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan inventory (CSNN): Not determined. Not listed Not listed Not listed Section 16. Other information SAFETY DATA SHEET Page 7 of 7 Issue Date: 01/11/2021 Label requirements HARMFUL IF INHALED OR SWALLOWED. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT AND SKIN IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. MAY CAUSE GENETIC DEFECTS. Version : 2 Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.