Document pp6NGZG1JqORzBvnnokK6aJ1E

CMA. 045980 Manufacturing Chemists Association Safety and Fire Protection Committee 1969 W. S. Wood, Sun Oil Company, Chairman R. H, Albisser, Merck & Co , Inc C H Barboni, CIBA Coroo'at'On G E Cain, Hercules Incorporated A, H, Christian, FMC Corporation A L, Cobb, Eastman Kodak Company G, G, Fleming, Ceianese Corporation G L Gorbe/I, Monsanto Company J F Hayes. Thiokol Chemical Corporation J Jorgensen, Rohm and Haas Company F 0 Kubias, Malhnckrodt Chemical Works R Y Le Vine, Olin Mathieson Chemical Corporation F. E. Macaulay, Wyandotte Chemicals Corporation S. M. MacCutcheon, The Dow Chemical Company R L. Payne, Ohio Ferro-Alloys Corporation J. S. Queener, E. I. du Pont de Nemours & Company S. Schreiber, Allied Chemical Corporation E. C. Sommer, Esso Research & Engineering Company S. F. Spence, American Cyanamid Company J. J Walker, Union Carbide Corporation FOREWORD This April 1970 printing of the Laboratory Waste Disposal Manual contains some modifications of waste disposal procedures recom mended in the September 1969 edition. These are essentially as follows: 1 Disposal Proccdtoe 6 now >ecommends against burning as a means or destroying nitroaromaties, such as trinitroben. zene. unless the bunting area is capable of containing the effects or the possible detonation at these substances 7 Recommendations to flush aside salts to the drains or to 'dispose of them by burning has been deleted tram Disposal Procedure 8. 5 The iccovery of halogenated solvents is now ccnercd In Disposal P/ocedine 27]. Development of the manual is. of course, a continuing pioiect and inroimation on alternative or improved methods of laboiatoiv chemi cal waste disposal i.s requested. Please address communications to F G Stephenson. Editoi. Laboratory Waste Disposal Manual. Manntactunng Chemists Association, 1825 Connecticut Avenue. V.W', Washington, D. C. 20009. CMA 045981 r * LABORATORY WASTE DISPOSAL MANUAL Revised and Reprinted -- May 1970 MANUFACTURING CHEMISTS ASSOCIATION 1825 CONNECTICUT AVENUE N W WASHINGTON 0 C 20009 k CMA 045982 The information and recommendations contained in this Laboratory Waste Disposal Manual have been compiled from sources believed to be reliable and to represent the best opinion on the subject as of 1969. However, no warranty, guarantee, or representation is made by the Manufacturing Chemists Association as to the correctness or sufficiency of any infor mation or recommendation herein, and the Association assumes no responsibility in connection therewith; nor can it be assumed that all necessary hazard warnings and precautionary measures are contained in this manual, or that other or additional information or measures may not be required or desirable because of particular or exceptional conditions or circumstances, or because of applicable federal, state, or local law. PAGE 2 Copyright 1969 by Manufacturing Chemists' Association, Inc, Library of Congress Catalog Card No. 72-87285 Printed in the USA FIRST EDITION, JUNE 1969--3,000 SECOND EDITION SEPTEMBER 1969--6,000 REVISED AND REPRINTED, MAY 1970--5 000 1 k CMA 045983 Page Section I. INTRODUCTION.................. 4 Section II. HOW TO USE THE MANUAL ..................... 5 Section III. CHART HEADINGS DEFINED.................. 6 Section IV. ABBREVIATIONS ................. 8 Section V. REFERENCE CHARTS (alphabetical listing of chemical substances) ........... 9 Section VI. WASTE DISPOSAL PROCEDURES ... . . 121 No. la Organic Acid Halides .............................. 123 No. 1b Inorganic Halides ........... 124 No. 2 Aldehydes ...................................................... 125 No. 3 Alkali and Alkaline Earth Metals, Metal Alkyls, and Alkoxides ....................................... 126 No. 4a Chlorohydrins and Nitroparaffins .................. 127 No. 4b Organic Halogen and Related Compounds ................................... 128,129 No. 4c Substituted Organic Acids............................. 130 No, 5 Aromatic Amines ........................................... 131 No. 6 Aromatic Halogenated Amines and Nitro Compounds ................................... 132,133 No. 7a Aliphatic Amines .......................................... 134 No, 7b Organic Phosphates and Related Compounds 135 No. 8 Azides and Azo Compounds......................... 136 No. 9 Carbon Disulfide ......................................... 137 No. 10 Caustic Alkali and Ammonia ... .................... 138 No. 11 Inorganic Salts ..--..... 139 No. 12a Oxidizing Agents ......... 140 No. 12b Reducing Substances................................ 141 No. 13 Mercaptans and Organic Sulfides................ 142 No. 14 Cyanides and Nitriles --.......................... 143,144 No. 15 Ethers ......... ...............-................. ............... 145 No. 16 Hydrazines ......................... 146 No. 17 Hydrides ...... ............ .......................... .......- 147 TABLE OF CONTENTS Waste Disposal Procedures (continued) Page No. 18 Hydrocarbons, Alcohols, Ketones and Esters................................... 148,149 No. 19 Inorganic Amides andDerivatives ........ 150 No. 20 Organic Amides.......................................... 151 No. 21 Inter-Nonmetallic Compounds ...................... 152 No. 22a Peroxides, Inorganic..................................... 153 No. 22b Peroxides, Organic ...................................... 154 No, 23 Sulfides, Inorganic . ..................................... 155 No. 24a Acids, Organic (Limited to C, H and O Compositions) . 156 No. 24b Acids, Inorganic........................................... 157 No, 25 Carbides ... ................................................... 158 No. 26 Wastes to be dumped into land-fill or released to the air............................... 159 No. 27a Recovery - Scrap Metals..... ..................... 160 No. 27b Recovery - Mercury ..................................... 161 No. 27c Recovery - Phosphorus (Yellow and Red)... 162 No, 27d Recovery - Arsenic, Antimony, Bismuth ....... 163 No, 27e Recovery - Selenium and Tellurium ........ 164 No. 27f Recovery - Lead and Cadmium Compounds 165 No. 27g Recovery - Beryllium Compounds ................ 166 No. 27h Recovery - Strontium and Barium Compounds 167 No. 27i Recovery - Vanadium Compounds .............. 168 No. 27j Recovery - Halogenated Solvents...... 169 No. 27k Recovery - Miscellaneous ......... 170 No. 28 Cellulose Nitrate, Collodion, Celluloid 171 No, 29 Direct Burning ...................... 172 SECTION VII. DISPOSAL MATERIALS--MINIMUM REQUIREMENTS ...................... 173 SECTION VIII. BIBLIOGRAPHY ..................................... 175 PAGE 3 CMA 045984 SECTION I. Introduction This manual is published as a service of the Safety and Fire Protection Committee of the Manufacturing Chemists Association. Its purpose is to assist laboratory personnel in developing an awareness of chemical hazards and in fulfilling their responsibilities to dispose of chemical wastes without personal injury, without hazardous adul teration of drams, and without excessive contamination of ground, air or water. Some 1200 chemicals are specifically listed in the manual. Therefore, because of the vast number not in cluded, this publication should be considered preliminary in nature. However, categorization of disposal procedures by chemical classes (See VI) offers a means by which information can be obtained on the disposal of chemicals not specifically listed. In addition to the normal fire and explosion hazards of flammable liquids and their vapors and the expected hazards of toxic materials, certain other hazards must be anticipated in waste disposal handling. Some materials are corrosive to drainage piping. Some react violently with water or with other chemicals. And others, though possibly relatively nonhazardous in themselves, adversely affect sewage disposal systems. Chemicals poured down the drain should be non-toxic or in concentrations below the threshold limit. The con centrations which may be transferred to the drain in any given location are controlled by water pollution standards. Copies of such standards can be obtained from the water pollution control agency in the state or interstate region. In this manual recommendations for treatment of hazard ous chemical wastes, prior to disposal, are presented in basic outline. Detail is neither possible nor desirable, but all recommendations are directed towards the elimination or adequate reduction of the hazard potential. Some organic wastes can be converted to the non-toxic naturallyoccurring forms. For example, a high valence chromium compound (chromate) can be reduced to a harmless trivalent hydroxide. Certain other inorganic elements and their compounds are highly toxic in any soluble form. Therefore, it is recommended that these be recovered for re-use. Contaminated mercury is an example of this class of material. Recovered material can be shipped to the supplier for reprocessing. Toxic cyanides can be converted to less toxic cyanates or into complex iron cyanides. Very active chemicals, such as SnCI4 can be made less active by mixing with inert materials such as sand, kaolin or vermiculite, and then converted to less harmful forms which can be safely dis charged to the drain. Certain materials can be safely destroyed by burning. The burning process for slow-burning compounds may be speeded up by dissolving in flammable solvents. Some incinerators are equipped to reduce carbon and carbon monoxide by means of afterburners, and to remove by products such as SO, and NO with scrubbers. The manual stresses safe procedures for on-site waste disposal from small laboratories, especially those in small communities not possessing sophisticated equipment. PAGE 4 CMA. 045985 % SECTION II.------------------------------------------------------------------------------1 How to Use the Manual To obtain information on the hazards of a specific chemical substance and recommendations for its disposal as a laboratory waste, proceed as follows: (a) Find the chemical substance in the alphabetical listing in Section V. (If the substance is not listed, refer to the chemical class listings under Section VI in the TABLE OF CONTENTS. The substance will fall into one of these categories and the associated disposal procedure can be used.) (b) Note the information given in Section V on the health, fire and reac tivity hazards of the substance. Note other pertinent physical prop erties and consult the recommended references for more detailed information. (c) A waste disposal procedure number is given in Section V. Refer to this procedure in Section VI and proceed accordingly. NOTE: For emergency handling ol spills and as a matter of good operational policy it is recommended that disposal equipment and materials be readily available and that all who may have to use them know where they are stored. Section VII lists essential equipment and materials and suggests minimum quantities required. PAGE 5 CMA 045986 SECTION III < CHART HEADINGS DEFINED Substance/Formula Substances are listed alphabetically by "common" names. Substances which are crossreferenced (e.g. Acetal, see 1,1-Diethoxyethane) are not included in the sequence numbering. Waste Disposal Procedure (See VI) The number con tained in this column indicates the recommended waste disposal procedure as correspondingly numbered in Section VI. TLV (ACGIH) PPM (mg/M) This column lists Threshold Limit Values as recommended by the American Confer ence of Governmental Industrial Hygienists. TLV's are given in parts of vapor or gas per million parts of air by volume at 25' C, and 760 mm. Hg pressure or (in paren theses) in milligrams of particulate per cubic meter of air. A threshold limit value refers to air-borne concentrations of substances and represents conditions under which it is believed that nearly all workers may be repeatedly exposed, day after day, without adverse effect. The ACGIH advises that threshold limits should be used as guides in the control of health hazards and should not be regarded as fine lines between safe and dangerous concentrations. For further information contact ACGIH at 1014 Broadway, Cincinnati, Ohio 45202. NFPA, 704M System: A numerical system for the Identifi cation of the Fire Hazards of Materials developed by the National Fire Protection Association. The numbers given m the th.ree columns have been taken from NFPA publi cations and other sources, For full definitions of the various degrees of hazard (0 to 4 in each category), see NFPA No. 704M-1969. Abbreviated definitions are as follows: Health 4 Can cause death or major injury despite medical treatment. 3 Can cause serious injury despite medical treatment 2 Can cause iniury Requires prompt treatment. 1 Can cause irritation if not treated 0 No hazard. Fire 4 Very flammable gases or very volatile flammable liquids 3 Can be ignited at all normal temperatures 2 Ignites if moderately heated. 1 Ignites after considerable preheating. 0 Will not burn. Reactivity (Stability) 4 Readily detonates or explodes. 3 Can detonate or explode but requires strong initiating force or heating under confinement 2 Normally unstable but will not detonate 1 Normally stable Unstable at high temp, and pressure Reacts with water. 0 Normally stable. Not reactive with water. Sp. Gr, (Specific Gravity), Specific gravity is expressed in grams per milliliter, or density relative to water. PAGE 6 1 3 1 1 1 * 1 I 1 4 1 1 1 1 CMA 045987 I CHART HEADINGS DEFINED--Continued Vap. Dens. (Vapor density). Vapor density is the relative density of a vapor or gas compared with air expressed as 1.0. FI. Pt- (Flash Point), The flash point of a liquid is the tem perature at which it gives off vapor sufficient to form an ignitible mixture with the air near the surface of the liquid. The flash point figures m the chart represent closed cup tests except where the open cup flash point is designated by the initials "oc" following the figure. Ignit. Temp. (Ignition Temperature). The ignition tempera ture of a substance, whether solid, liquid, or gaseous, is the minimum temperature required to initiate or cause self-sustained combustion independent of the source of heat. Flam. Limits % (Flammable or Explosive Limits in air). In the case of gases or vapors from flammable mixtures f with air or oxygen, there is a minimum concentration of vapor in air or oxygen below which propagation of flame does not occur on contact with a source of ignition, and tu also a maximum concentration above which propagation of flame does not occur. The concentrations (expressed in % by volume) between which propagation can occur are known as the lower and upper flammable (or explo sive) limits. B.P. (Boiling Point), The boiling point of a liquid is the temperature of the liquid at which its vapor pressure equals the atmospheric pressure. M.P, (Melting Point). Expressed as C and ( F). Sol. in H:0 g/IOOg (Solubility of the substance in grams when dissolved in 100 grams water at room tempera ture). The statement "insol." is used for zero solubility, e.g. cuprous cyanide and calcium carbide. "si. sol," means less than 5 grams soluble in 100 grams water, e.g., bromine and benzoic acid. "sol" means 5 to 50 grams soluble m 100 grams water, e.g., barium nitrate. "v. sol." means over 50 grams soluble m 100 grams water, e.g., potassium carbonate. "x" means soluble m all proportions, e.g. sulfuric acid and acetone. Superscripts indicate the centigrade temperature at which the amount stated (in grams) is soluble in 100 grams of water. For example. 52'" indicates that .52 grams of this substance will dissolve in 100 grams of water at 15 C. Misc. Ref. See bibliography (Section VIII). PAGE 7 CMA 045988 SECTION IV A bbre via tions Note: The "Misc. Ref." columns in the charts (see Section V) list sources of information. For explanations of these abbreviations and names of publications, see Section VIII. Other abbreviations used in charts ace. ale. atm. bz. C CCI4 CAR chi. CS< -- acetone -- ethyl alcohol -- atmospheres of pressure -- benzene -- Ceiling limit (not to be exceeded) -- carbon tetrachloride -- carcinogenic--Only chemicals listed in 1968 as carcinogenic by the Department of Health of the State of Pennsylvania are marked CAR. -- chloroform -- carbon disulfide dec. exp. h insol. -- decomposes -- explodes -- hot -- insoluble ISO. -- isomeric m. -- meta MeOH -- methyl alcohol Misc. Ref. -- Miscellaneous References mm -- millimeters of mercury n -- normal 0 -- ortho org, sol. -- organic solvents P -- para sec. -- secondary Skin -- includes skin absorption (avoid skin contact) si. sol. -- slightly soluble sol. -- soluble subl. -- sublimes tert. -- tertiary v. sol. -- very soluble soluble in all proportions < -- less than > -- greater than a -- alpha p -- beta i gamma PAGE 8 CMA 045989 SECTION V. CHARTS 1! II #! Alphabetical Index of Chemical Substances b PAGE 9 f CMA 045990 NOTE: Absence of an entry in any column does not necessarily imply that no information exists. CMA 045991 SUBSTANCE/FORMULA Waste Dis posal PrO` cedure (See VI) TLV (ACGl M> PPM (mg/M3) , NFPA 704M System Health Fire React. 1 Acenaphthene CijHiq 18 1 Acetal, see l, 1-Diethoxyethane ] Igmt. Vap. FI Pt Temp. Sp, Dens. 5C Gr. (Air=1| (F> C Limits (F) % 1 02 J B.P. 4C (F) 278 (532) MP aC (F) , h2o ; g/t00g 96 (205) 1 msol Other Solvents bz. chi Mise. Ret 2 Acetaldehyde CH'jCHO 2a Acetamide CH3CONH2 3 Acetic Acid CH3CQOH 4, Acetic Anhydride 'CH3CO)20 5 Acetone CH3COCH3 6 Acetone Cyanohydrin (CH3)2C(OHICN 7 Acetonitrile CH3CN Acetyl Acetone. see 2,4-Pentanedione 8 Acetyl 8romide CH3COBr 9 Acetyl Chloride CH3COCI 10 Acetylene CjHj Acetylene Dichlortde, see 1,2 Dichloroethylene 2 200 , 2 4 ! 20 24a 1 24a 10 2 2 5 !2 2 18 1000 1 3 14 14 40 i la la 41 33 _L 33 33 1 18 14 jI | 2 1 l 0 2 3 2 2 3 ! j 78 1 154 1 52 -38 (-36) 185 (365) 4-57 21 (69) 221 124 (-191) r 31 sol, ale , bz, 1 05 21 43 (109) 426 (800) 4-16 118 (244) 17 JO (61) org aolv 1 08 79 35 20 54 (129) -18 (0) 380 (716) 538 (10001 3-10 3-13 140 (234) -73 1 (-99) 56 -94 (133) (-137) -JCJ 00 ale , chi ale , bz 93 2,9 74 688 (165) (1270) 82 (180) 19 (-2,2) v sol, ale 79 1 4 6 524 (43) (975) 4-16 80 (176) -41 (-42) ale , chl 11 i' ' 16 __________ 1 1,1 2.7 4 (40) 390 (734) . 77 -96 (170) (-141) dec 51 -112 1 dec. (124) (-170) D2 Chl ace,, bz chl 91 9 335 (635) 3-82 -83 (-118) subl si sol, 1 ace , b/ } j| i! !I BDH,MCA MCA, AIA, NSC,NTTC, BDH MCA,BDH MCA, AIA, NSC, BDH, NTTC BDH, MCB, MCA BDH, MCB. MCA BDH,MCB BDH,MCB CGA, MGB NSC PAGE 11 CMA 045992 t SUBSTANCE/FORMULA Acetylene Tetrabromide, see Tetrgbromoethene Acetylene Tetrachloride, see Tetrachloroethane Acetylene Trichloride, see Tnch loroetny lene 1 1 Acetyl Peroxide (CH3CO)202 Acid Chromate Solution, see Cleaning Solution Ip, Acridine Ci 3H9N 1 3 Acrolein CH2=CHCHO 14 Acrolein Dimer (CH2=CHCHO)2 15 Acrylic Acid CH2='CHCOOH 16, Acrylonitrile CH2=CHCN 1 7 Adipic Acid CQQH (CH2)4COOH 18 Adipomtrile CN(CH2)4CN Aerozme 50, see Hydrazine PAGE 12 Maste Dis posal Pro cedure (See VI) TLV lACGIH) PPM img,M 1 NFPA 7Q4M System Health Fire React Igmt. Vap FI Pt. Temp. Flam, B P Sp. Dens, :C Gr (Air-11 ("FI Limits '0 (=F) 7* ("FI MP 5C (2F) Sol in h20 g/1 GOg Other Solvents Wise, Ref 22b 2 4 12 4 07 1 13oc 63 exo. 30 (145) (86) si. sol CCI4, ale MCB 52 1 005 345 (653) 110 (230) si, sol die , nz , CS2 2 3 3 3 84 19 -26 273 53 -87 'CA BOH (-15) 1532) 3-31 (127) (-125) 1 v sol A I A NSC 2 1 2 1 l.l 48 (118) 151 (304} sOl 24a 3 2 2 1 05 2,5 52oc 429 142 12 (126) (504) (288) (54) ale BDH 14 20 4 3 2 81 1.8 Ooc 481 3-17 77 -83 sol die (32) (898) (171) (-117) 24a 11 1,4 191 1 422 1 (376) (792) . 267 (513) 153 (307) si sol 1 ate MCA MCB, NTTC AIA 14 32 97 93 ! 295- 2 3 (199) 1 (563) (36) si sol ale,, ch|, CMA 045993 SUBSTANCE/FORMULA 19 Aldrin Cl2HSCl6 20 Alizarin Cl4H804 21 Allene ch2 = c = ch2 22 Ally 1 Acetate CH3CO2CH2CHCH2 23 Ally1 Alcohol CH2=CHCH2OH 24 Allyt Amine CH2CHCH2NH2 25, Ally 1 Bromide CH2CHCH2Br 26 Aliyl Chloride CH2CHCH2CI 27 Aliyl Chloroformate CH2CHCH2C02CI Allylene, see propyne 28 Aliyl Glycidyl Ether c6h102 29 Ally! Iodide CH2CHCH2l Waste Dis posal Pro cedure (See VI) TLV (ACQIH) PPM (mg/M"1) NFPA 704M System Health Fire React, 4b ( 25) 3 1 0 Skin 13 1 13 4 18 3 18 2 Skin 3 1 31 Vap. FI. Pt. Sp. Dene. C Or. (Air=1) <aF) i - 66 (150) . 1 8 1,4 Igmt. Temp. C (aF) . Flam. Limits %j 8.P, aC lR j M.P. C (F) Sol. <n H2O g/IOOg Other Solvents Misc, Ref l 1r --------------- r 104 insol. ale , bz , (219) ace. 1 i 430 j 289 (806) (552) sl sol bz., CS2. ale. 1i 1 -34 : -136 (-30) j (-213) j. ' | ' MGB 93 3.4 21oc (70) 374 (705) 1 103 (2171 sl, sol. ale. BDH ,35 2.0 21 378 3-18 (70) (713) 97 "129 (207) (-200) 00 ale. 8DH, MCA 7a 3,3 1 76 2 0 -29 374 2-22 58 *> ale,, chi MCB (--20) (70S) (136) 4b 3' 3 1 1 4 4 2 -1 295 70 -119 insol ale , chi (30) (563) 4.7 (158) (-182) CS2. CCI4 0DH, Vice 4b 1 3 31 ;! 94 2 6 -32 (-26) 4b i ' 3i3 1 1.1 4 2 l ; 1 i : ... |' _____ i________L_______ __ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ 15 10c 3 1 1 97 34 1 1l 4b 3 2 - 1.8 5.S 31 (88) 57 (135) 392 (738) 3-11 45 (113) -136 msol (-213) ale , ace, bz, ' 110 ! (230) ' 1 insol |:l' !ii ' 154 -100 sol (309) ; (-148) aee 102 1 -99 mSOl (216) j (-146) ale,, chi BDH, AIA MCB, MCA MC3 MCB PAGE 13 CMA 045994  30 Allyl Propyl Disulfide C3H5S2C3H7 31 Alum KAI(S04)2 12H20 Dis posal , Pro1 cedure (See VI) TLV (ACGIH) PPM (mg/M3) 704M System Health fire leact. 13 2 3 2 ignit. Vap. FI Pt. Temp. B.P, Sp. Dens, i 5C ' aC Limits 3C Gr. (Air=1) ; (F) , <5F) % (F) 1 1 1 ! M.P =C (F) 1 HzO ! g/IOOq Other Solvents Misc. Ref . j MCS 11 1 7 200 (392) 92.5 i 11,420 (198)j iNTTC 32 Aluminum Al 33 Aluminum Alkyls RALX ' 27a 3 0 1 27 * I 3 4 2; 3, 1 <0 1 (< 32) 1 2056 (3733) 660 , mSdl. (1220) 1 Al A 34 Aluminum Borohydride AI(BH4)3 35 Aluminum Bromide Al Br3 17 3 4 2 ........ . .. ib 1 30 ; 45 -65 j (113) { -85) AIA NSC 1 263 98 dec ale, ace BOH,MC8 (505) (208) CS2 36 Aluminum Carbide A!4C3 37 Aluminum Chloride aici3 35 1 1b 37a Aluminum Chloride, hydrate ! 3 1 ! 0` 2 24 24 ! 1 dec. 1400 ; dec, (2552) , 183 (361) 194 69.915 (381) at 5 atm. ale, CCI4 MCA,BOH NSC 38 Aluminum Ethoxide (c2h5>3Al03 3 1 205 134 dec, si sol i (401) (273) Aluminum Lithium Hydride, see LtThium Aluminum Hydride 39, Aluminum Nitrate A1(NO3)3'9H20 40, 2-Amino-DipHenylene Oxide C12HgNO 11 ISOdec. 70 | 63,7^5 I CS2 (3021 (158) I Glc , jce 94 (201) PAGE 14 CMA 045995 SUBSTANCE/FORMULA 2-Aminoethanol, see Ethanoiamine Waste Dis posal Pro cedure ISee VI) TLV (ACGIH) PPM Img/M') NFPA 704M System Health Fire React Igmt. Vap FI. Pt. Temp Flam, B P, Sp Oens, C Gr, (Air-1) |F) 5C Limits 3C (F) (gF) M,P, C (F) Sol in H2O g/1Q0g Other Solvents Misc, Ret 41 Ammoethyiethanol Amine NH2lCH2)2|SiM(CH2)20H 7a 2 1 0 1 03 36 129 368 (265) 695) 244 (4711 V, sol, , ale NTTC 42 2-Aminopyridine c5h6n2 43 Ammonia, Anhydrous nh3 44 Ammonia, Aqua MM4OH 5 53 10 50 3 1 0 77 59 10 50 2 1 22 1 7 204 (399) 58 sol (136) , org solv 651 (1204) 16-25 -33 -78 (-28' (-1081 89 9 org solv -72 sol (-98) ; MCA, CGA NSC, A1A NTTC MG3 MCA BDH 45, Ammonium Oichromate (MH4)2Cr207 46 Ammonium Fluoride nh4f 12a 11 32 3 l3 ISOdee ! 15 (356) 31 subi, 100 alC ale MCA Ammonium Hydroxide, see Ammonia, Aqua ; 1 47, Ammonium Nitrate NH4NO3 11 2 1 31 exp, 210dec, 169 (410) (336) 118 ale ace VsOH NSC NTTC 43 Ammonium Perchlorate NH4CIO4 , 12a 2 1 4 1.9 49, Ammonium Persulfate (NH4)2S20s 50 Ammonium Sulfamate NH4OSO2NH2 12= 19 (15) 1 1 2 1 j 19 1 __________ L . ,j : 1 is ;I dec 10 7 ace 120deci 58,20 (248) dec iGOdec1 125 1S610 (320) (257) : MCB PAGE 15 CMA 045996 SUBSTANCE/FORMULA 51 Ammonium Sulfide (NH4)2S 52 Ammonium Thiocyanate nh4cns 53. Ammonium Vanadate NH4vQ3 54 n-Amy! Acetate CH3COCXCH2UCH3 55. iso-Amyl Acetate CH3COO<CH2)2CH(CH3)2 56 sec-Amyl Acetate CH3C02CH2CHCH3C2H5 57 n-Amyl Alcohol CH3(CH2)4OH 53 iso*Amy| Alcohol (CH3)2CH(CH2]2OH 59, tert Amyl Alcohol CH 3CH2C(CH3)OHCH3 60 Amylamme CsHnNH2 61 Amyl Bromide CsH^iBr 62 Amylene 05H10 PAGE 16 Waste Dis posal Pro cedure iSee VI) TL V IACGIM) PPM (mg;M^ \ NFPA 7Q4M System Health Fire React. 23 2 11 1 Vap. F|. Pt Sp. Dens. Gr (Air=1| laF) _________ 4 Igmt. Temp, ;C (F| Flam. Limas % B.P. SC (5F) M.P. 5C (*F) Sol in 9/1009 Other Solvents 12 dec. vl. ale,, dec. H2O100 ____ ______1 13 170dec 150 1280 ale., ace (338) (302) WlSC, Rtf BDH 27i 18 TOO l 3 18 18 1 18 1 18 i 18 100 1 1 125 , 1 1 1; ;1 ! i 1 3 3 3 i i2 ; !3 7a 3 1 3 ; 4b 1 3 1 -------4.-------------- 1 , is ; - 1 1 4 23 200dee 5215 dec (392) HjO100 --| -- 0 38 4 5 25 379 1-7,5 148 -79 si sol ale (771 (714) (298) (-110) BDH 0 88 4 5 23 380 1-7,5 142 (73) 1715) @212 F <288) - ale -- Q 86 4,5 32 (89) 1-7 5 -| 121 (250) ale 0 ,82 3.0 33 300 1-10 137 -79 si sol ale (91) (572) <2791 (-110) MSC ---- --. SDH, ^SC 10 31 3,0 43 347 1-9, 132 (109) (657) @212 F (270) Si sol ale SDh !0 .81 30 !0 J__________ '0 8 1 22 3,0 52 1--------------- -- i0 ! 66 1 i _____1 2.4 19 437 (66) 1819) __________ 1 7oc, (45) 1-9 32 (90) i -2 j (23) ---- I 273 j (523) 1 5-9 102 (216) -12 (10) si sol ale 103 (217) -54 (130) 30 (86) -55 (-67) _________ _ 00 -95 (-139) __________ -16S (-265) insol nsoi ale ale 1 aic i SDH ` BDH CMA 045997 SUBSTANCE FORMULA 3 n-Amyl Ether I Cl0H22 qJ tso-Amyl Formate HCOOCsHt , 65 Amyl Mercaptan CHjlCHn^SH @6, iso-Amyl Nitrate c5h11iN10J 67 Amyl Nitrite CH3{CH2)4N02 68 Aniline CSH5-NH2 ------ Q9 o-Amsaldehyde CSH82 70 o-Am$idine CH3QC5H4NH2 --- 71 p-Anisidme CH3OC6H4NH2 72 Anisole c6h5och3 73 Anthracene C6H4(CH)2C6H4 74 2-Anthramme Ci4HiiN Waste Dis posal Pro cedure (See VI) TLV (ACGlHI PPM 1 mg/M ) NFPA 704M System Health fire React 15 1 2 0 Igmt. V/ap FI Ft. Temp, Flam 8 F. sp. Dens. 'c -c Limits C Gr (Ar-1) (3F) % tF) M.P. 5C (SF) Sol m HjO 1 9/1009 ; Other Solvents 74 5 46 5? 171 (135) (340) 190 (374) -70 (-94) 1 insol, 1 ale Misc, Ret 18 1 3 0 39 4 0 26 (791 213 20 3 0 ,84 11 18 (65) 131 (267) -74 (-101) sl sol. 127 , (261) -76 (-105) insol, ale. ale. BDH 4a 1 2 2 99 52 (125) , 152-7 (306-15) sl sol | ale, BDH 1 4a 1 2 2 85 10 209 104 sl sol ale. BDH (50) (408) ' (220) 1 ^ '5 5 3 2 0 1 02 3 22 7Qoc 770 184 -6 sol, ale,, bz NTTC, Skin (158) (1418) 13 (363) (21) MCA 8DH 1 2 ( 2 1 0 1 12 118 (244)oc 250 (482) 2 5 inSOl j (36) ale !5 1 ( 5) Skm 2 ' 224 (435) sl sol ale. BDH 5 ( 51 Skm 2 243 (469) sl. sol ale SDH 15 ' IB 5 1 1 CAR 2 0 , 995 3 72 52oc. . ! (126) 2 125 i 6 15 121 540 (250) (1004) i. 154 (309) -37 (-35) insol 340 217 insol. 6- (644) (423) 236 (457) insol. ale. DZ ale. l 1 j PAGE 17 045998 ! t SUBSTANCe/FORMULA 75 Anthraquinone CqM4(CQ)2CqH4 76 Antimony Sb 77 Antimony Hydride. see Stibine 77 Antimony Pentachloride SbClj 78 Antimony Pentasulfide Sb2Ss 79 Antimony Trtchloride SbCIs 80 Antimony Trioxide Sb203 81 Argon Ar 82 Arsenic A54 83. 7-Arsenic Acid H3As041/:H20 34, Arsenic Trichloride ASCI3 85 Arsenic Tnoxtde As23 PAGE 18 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M 1) 18 NFPA 704M System Health Fire React 11 Sp Gr, 1,44 Vap Dens. (Air=1) FI. Pt. C (F) 1 gn it. Temp. (5F) _ 7 16 1 185 (365) ! Flam. Limits tfl oo__ 380 (716) M.P. C (5F) Sol. in HjO ; 9/100g | Other Solvents j! 286 1 msol, 1 ale (547) (sl sol ) 27d ( 5) 3 2 27d ' 5) 3 6.68 2 34 1380 (2516) 630 (1166) insol 1 i: __________ I__________ 1__________ i ! 140 2.8 dec (284) (37) CHCI3 BDH 27d ( 5) I 27d ( 5) 27d ( 5) ! 26 3 3 3 27d (.5) 3 27d (,5) 3 27d ( 5) 3 1 2 1 3 14 52 j ! - 75dec (167) msol 1 223 (433) 73 (163) 1550 (2822) 656 (12131 602 sl. sol ale bz , ace , chi SDH mcA __ 15 -186 -189 (-303) (-308) 4 -- 5.7 . 615subl msol (1139) __________ ^2 ISOdec 35.5 16 7 ale (320) (95 7) __________ 2 16 6.25 63 (145) -9 (15 8) dec. ale. MG8 CQa NSC BDH BOH. NSC 27d 1 ( 5) 3 I 3 74 i I 193subl 1,22 (379) ale BDH, MCA, NSC CMA 046000 substance/formula t 96 Batteries, Dry Cells 99 Batteries, Wet Cells 100 Bengal Chloride C6H5CHCI2 101, Benzaldehvde c6h5cho 102 1,2-Benzanthracene Cl8H14 103 Benzene C6h6 Benzene Monochloride. see Chlorobenzene 104 Benzene Sulfonic Acid C6H5503H 105 Benzene Sulfonyl Chloride C6H5SO2C! 106 Benzidine ICqH4)2(MH2>2 107. Benzoic Acid C6H5COOH 108. Benzomtrile C6H5CN 2,3-Benzophenanthrene, see 1,2-0enzanthracene PAGE 20 % Waste OispoMl Pro cedure (See VI) TLV (ACGIH) PPM NPPA 704M System Health Fire React 26 27a 4b 2 220 IS CAR Igmt, Vap. Fl. Pt. , Temp. Flam, Dens. Gr, (Air=l) (CF| <H % <FI L-- ...... -J___________ 1 26 1 04 3,7 64 1 (147) 192 (378) 205 (401) 178 (352) 435 (815) M.P. , Sol C g/lOOg Solvents Misc. Ret F I ! i ; -16 (3 2) --------------- ,-------------------- '----------------------- - 1 : nsc 1 1 msoi, 1 ale BDH i -56 (-69) si. sol. ( ale. 1 1 9DH 162 (324) msol, bz. 1 9 9 ' t 1 18 25C 2 30 66 2.8 -1 1 (12) 562 (1044) 1,4-8 80 (176) 5 4 si sol. die,, ace. (41) A1 A, BOH \TTC, V1C4 I ,j , 1 |- !,1________________ 1,,:____________________ ;1_______________________ 4c * 3 525dec sol (977) ale. SDH 1 P la 5 1 24a CAR 3 1 1 1 25 , ,1 32 ' 4'2 121 574 (250) (1065) 252 (485) 14 5 (58) insol hot ale 402 (756) 128 (262) sl sol, 3'c. 249 (480) 122 1252) si sol, ale dz 3DH 1 a p j 1 i 14 1 j !( 1 3 1 01 1 - j !1 ! 1! j exp (376) -13 (8 6) al so) d.C BDH 1 ) CMA 046001 1~ p-B*nzoqumone, see Quinone 109 Benzotnehlonde C6H5CC13 110 Benzotnfluoride C6H5CF3 ill Benzoyl Chloride CgHgCOCI 112 Benzoyl Peroxide II 1C6H5C0)202 i 3.4'Benzophenenthrene A see 1,2-Benzanthracene 1,3 Benzyl Aeetaie CH3CO2CH2C0H5 1 114 Benzyl Alcohol C6H5CH2OH A MS Benzyl Armne C6H5CH2NH2 I 116: Benzyl Benzoate C6H5C02CH2C6HS 117 Benzyl Bromide C6H5CH2Sr 118, Benzyl Chloride C6H5CH2C! Waste Dis posal Pro cedure (See Vfl TIV IACGIH) PPM (mg/M3) fYFPA 704M System Health Fire React 4b 4b la 22b 15) 2 4 3 1 30 21 44 18 1 : 18 5 IS 4b 1 4b 1 10 2 10 3 -'l 1 1|0 3 ,i 1 p-- 12 2 11 l Vap FI. Pt. Sp. Dens, 3C Gr. <Air=1) (F) __________ l Igmt. Temp. -c l3F) Flam. Limits B.P, (F) M P, aC (CF) Sol. in h20 g/IOGg Other Solvents Misc. Ret, ;' 1 38 6a 1 19 5 04 12 154) 214 (417) -5 insol (23) ale., bz 101 1214) -29 i~20) insol, ale BOH BOH 1.22 4 es 72 (162) 197 (387) -5 (31) dec, bz, CS; BOM 1 33 80 (176) ex 106 si sol nz , ace BOH (223) MCA \FPA 1i !! 1 06 51 1,04 3,7 102 (216) 461 (862) 101 (213) 436 (817) 214 (417) -51,5 $l sol (-61) ale _______ 4206 -15 3 ' (403) 14) ale., ace , chi 93 63 (145) 1 11 7 3 148 481 (298) (898) 1 44 5.8 185 (365) 323 (614) 198 (388) CO alb BDH 21 msoi 170) -4 (25) insoi ale . ace . bz,, chi aic, BDH 1 10 4.36 67 (1531 585 (1085) 1 1- 179 (354) -39 (-38) msoi -31C chi BDH, MCA PAGE 21 CMA 046002 SUBSTANCE, FORMULA 119 Benzyl Chloroformate CiC02CH2c6H5 20 Benzyl Cyanide CbH5CH2CN Waite 0>S posal Pro cedure 1 See VI! TLV iACGIH) PPM 1 mq M ' NFPA 704M System Health Fire React 4b 2 14 3 l gn it. Vap FI Pt. Temp. Flam, B P, Sp, Dens 5C -c Limits C Gr, (Air=1) l = F) ( = F) (3F) 103 (217) Mp aC (CF) SoL in h2o g/1OOg Other Solvents Misc. Rf dec dec , ale, SDH 1 02 234 '453) -24 (-31) insol ale SDH Benzyhdene Chloride >ee Benzai Chloride T?1 Benzyl Mercaptan CgHijCH'vSH 13 1:2 Beryllium 3e 27g 123 Beryllium Salts 27g 124 Biphenyl ic6h5i2 18 125 N`4-Biphenylacetohydroxamic Acid 5 1 002) ( 002) 2 4 4 2 2 1 1 1 1 ,\ 1 06 43 70 (158) 194 (381) m$ol ale, CS2 1,86 2970 (5378) 1278 (2332) insol 0 12 53 113 540 6-5,8 256 70 msot ale <235) (1004) 232 F (493) (158) 171 (340) AIA, NSC , A1A. SDH i* i i i 126 2-Biphenylamme CgHgCgH^IMHj Biphenyl, 4,4'Diammo, see Benzidine 127 Bismuth Chloride B1CI3 128 Borax, Anhydrous M32B4O7 129 Boric Acid H3BO3 PAGE 22 5 2 1 0 1 16 5S 452 (846) 1 : ' 27d 11 24b ' '! _______________ :__________ !__________ .__________ :__________ 1__________ 2 23 4 75 j__________ ! 1 72 -l 1.1 j 2 ! 2 46 | -j - 1 299 (570) 49 (120) msol ale , 02 441 (826) 230 (446) dec die,, ace, 1 1575 741 (2867) It 1366) ! 06 AIA 1860 ' 169 (3380) ! (336) 6.33 ale,, MeOHj AIA i* ji i l i CMA 046003 SU6STANCE/FORMULA -- C]0h17OH Waste D ispoSal Pro cedure ISM VI) (ACGIHI PPM j (mg/M") ; IS 1 ' MFPA 704M System Health 2 Fire 2 React. ! 0 ,31, Boron B ,32 Boron Fluoride-Ethyl Ether Complex C4H10BF30 Boron Hydrides, see Di-.Penta-, or Deca-Boranes 26 21 22 320 133 Boron Oxide B2O3 134 Boron Tribromide BBr3 24b 15 21 2 2 135 Boron Trichloride BC13 21 2 136 Boron Trifluoride 8F3 21 1C 3 0 137 Boron Trifluonde Complexes with Acetic Acid end Mentanol 21 3 137a. Brass 27a 138 Bromic Acid H0rO3 139 Bromine Brj 12a 3 12a 01 ! 4 1 2 0, 140 Bromine Pentafluoride BrF^ 21 3 j4 Sp. Gr 1 01 3 33 11 Vap, FI. Pt. Dens. 1 3C (Air=1| 1 (F) Temp. C <F) Flam. Limits B,P. C i5F) M.P. c <3FI Sol. m h2o , g/IOOg I 5 31 66 1151) _____ _____ 212subl( insol. (413) 2550 2300 (4622) (4172) msol. 64oc. j (147) 1 -110 -128 sol, (-166) ( -198) Other Solvents Misc. Ret ale , ace, j Al A At A 2 46 2 65 1,35 4.03 2.99 1860 (3380) 460 (860) sol 92 (196) 45 (-49) dec 12 5 -107 (54) (-161) dec, 99 -127 (-146) (-197) 106 die , CCI4 ale, ale, Al A Al A Al A 3DH VlGB A 1 A VCB Al A, BDH i 3 19 1 lOOdeci v sol (212) BOH 3,1 2 48 5,5 i 6,05 | ,| 1 1- 59 - (138) 40 ,1 (104) -7 4,2 ale C$2 (19) chi -61 (-78) dec Al A, BDH, \TTC, MCA, \J5C MGS PAGE 23 CMA 046004 CMA 046005 SUBSTANCE/FORMULA 3-Bromopyne, see Propargyl Bromide 143 O'Bromotoluene CH3CeH48r -- 149 Bromotrifluoromethane CBrF 3 -- 150 Bronze Alloy 151 Brucine c23h26|SJ204 152 1.3-Butadiene CH2(CH)2 = CH2 153 n-Butane C4H10 154 iso-Butane CH(CH3)3 n-Butanol, see n-Butyl Alcohol Butanone, see Methyl Ethyl Ketone 155 1-Butene CH3CH2CH=CH2 156 2-Butene CH3CH=CHCH3 2-Butoxyethanol. see Butyl Cellosolve Waste Dis posal Pro cedure (See VI) TLV (ACGlH) PPM (mg/M") NFP A 7Q4M System _____ . ___________ Health Fir# React. Ignit. Vap, Fl Pt. Temp Flam. B.P M.P. Sol m Sp, Dens. 3C i SC Limits , SC , 3C HjO Other Gr (Air=1) (^F) (F> % \ (F) j (F) j g/lOQg p Solvents . Wise. Ret 4b 2 2 0 1 42 59 79 1174) 26 1 181 1358) 1 -59 (-74) -27 (-17) insol. __________ L ale . oz -168 (-2701 si. sol chi 27a 0 0 63 178 (352) Si SOI ale , ch| 18 1000 2 4 2 1 88 1.97 <--7 429 2-11 5 -4 7 -109 msol org sol MCA (< 20) (804) (23) (-164) 18 , j 18 1 40 60 2 04 -60 405 1 9-8,5 ! - 5 -138 v sol. ale, chi inttc (-76) (761) (31) (-216) i 1 4 0 56 2,01 462 (864) 18-8.41 -12 (10 4) : -160 (-256) sol sic. ________________ i 18 1 4 0 118 '! 40 >j 1 9 -12 384 16-9 31 -6.1 (-24) (723) (21) 1,9 . 324 1 8-9,7 ! 1,1 (615) (34) S; insol, ale msol sic PAGE 25 ao^ 046006 t t SUBSTANCE, FORMULA 157 n-Butyl Acetate CH ^COOCijHg 158 iso-Butyl Acetate CH3COOCH2CH(CH3)CH3 159 sec-Butyl Acetate CH3COOCH (CH3>Ch2CH3 1 u0 ten Butyl Acetate CH3COOC(CH3l3 161 n-Butyl Alcohol CH3CH2CH2CH2OH 162 iso-Qutyl Alcohol CH3CHICH3*CH20H 163, sec-Butyl Alcohol CH3CH2CHIOH1CH3 164 tert-Butvl Alcohol (CHj^COH 1 65 Butylamme 24H9NH2 166. ten-Butylairune (CH3>3CNH2 167 iso-Butylamme (CH3)2CHCH2!MH2 163 n-Butyl 8romide CHj(CH2)3Br PAGE 26 Waste Dispow! Pro- cedure iSee VII TLV (ACGIH), PPM (mg/M*) NFPA 704M System Health Fire React 18 150 1 30 18 150 1 > 0 18 200 1 30 18 200 18 100 1 30 18 100 1 18 150 1 18 100 1 30 30 30 7a 5C 3 3 0 7a 5C 3 4 0 7a 3 3 0 4b 2 3 0 Igmt Vap FI Ft. Temp. Flam, B P, M.,P, Sol. m Sp. Dens. 1 5C C Limits 1 5C 7C H2O Other Gr (Air=1) <F) : (3f) % (F) ;1 (5FF>| i g/lOOg ; Solvents Misc Ref --------------- 1-------------- 41 38 4 Q 27 ' 399 (8D (750) 1 4J 6 125 (257) sl, sgI, (-105) ale | BOH 87 4 0 IS 423 1 1,3-7 5 ' 117 (64) (793) (243) -99 si. sol (146) ale, 1 BDh -->- 86 4 Q 31 (88)oc ' 17- !, 112 (234) msol =>)c, 87 95 msol ale MCA (203) 81 2 55 29 365 1 4-11 118 -89 sol (84) (689) (244) (-128) ale 31 2.55 28 ' 427 1 7-10.9; 107 -108 10'S ale (82) , (800) @212 F (225) (-162) 81 2 55 24 406 ! 17-9$ ' 99 5 -115 12 5 elk (75) (763) @212 F (211) (-175) ,78 2 55 10 478 2 4-8 83 25 X ale (50) (892) (181) (77) BOH,MCA 1 , BOH ; i BOH J MCA BOH, MCA 76 2 5 -12 312 1,7-9 8 ! 73 -50 X sic (10) (594) (172) (-58) ! BDH 70 2 5 .73 2 5 1 7-H3 ` 45 @212 F (113) -67 (-89) X -9 ! 378 (16) ' (712) 66 M5D -86 (-123) 1 ale ale 8DH BDH 1 28 4.7 18 ' 265 164) ; (509) i 2-6 6 101 @212 F (214) j -112 ,06 (-170) ' ale ' BOH % CMA 046007 SUBSTANCE/FORMULA 169 Butyl Callosolve C4HgOCH2CH20H Wasts Dis posal Pro* cedure (See VI) TLV (ACGIH), PPM ! <mg/M3) NFPA 704M System Health Fire React. 18 50 Skin 2 2,- Ignit. Vap, FI. Pt. Temp. Flam. 8.P. Sp. Dens. 5C Gr. (Air=1) (aF) aC Limits 5C (F) % (F) M.P. C <F) Sol. m H2O g/IOOg Other Solvents 91 4,1 61 (142) 1 M2 7 171 (340) -40 (-40) * ale. 170. n-Butyl Chloride CH3(CH2}3Cl 4b 2 31 a 38 3 2 7 471 1,9-10.1 78 -123 07 ale (45) (880) 0 72) (-189) 171 tert-Butyl Chloride (Ch3)3cci 172. tert-Butyl Chromate CgHigCr04 Butyl Ether. see Dibutyl Ether 173, n-Butyl Formate HCOOC4H9 174 iso-Butyl Formate HCOOCH2CH(CH3)2 175, n-Butyl Glycidyl Ether C4H9*0-CH2`CH-0-CH2 176, Butyl Hydroperoxide (CH3)3COOH 4b 12a ( DC 18 13 15 50 22b 2,3 ! 3i , 1 0 85 : 3,2 i i 2 3I 0 91 i 3 5 1|1 1 - : ,39 !!! | 91 1 4 4 86 2 1 ; <21 (< 70) ! 51 (124) . -27 (-17) si sol ale 18 ! 322 (64) (612) 1 7-8 1 107 -90 i (225) (-130) si sol ! ale. t <21 (< 70) 98 (208) -95 (-139) 164 ! (327) 1 122 ale 27 dec, 6 Sol ale chi (80) (43) 177, n-Butyllithium in Hydrocarbon solvents 177a,b,c, CH3(CH2)3Li 3 solvent 177a. In Heptane 3 500 68 -4 223 1 2*6 7 98 (25) (433) (209) org solv 177b In Hexane 3 500 69 -22 234 V2-7.5 69 (-7) (453) (156) org solv Misc. Ret. BOH SDH 9DH MCA MCA MCA PAGE 27 CMA 046008 SUBSTANCE/FORMULA 177c In Pentane 1 78, Butyl Mercaptan CH jICH2I3SH 17C Butyl Methacrylate CH2C'CH3)COOC4H9 180. Isobutyl Methyl Ketone CH3CQC4Hg Waste , OiSr TLV (A^H) NIFPA 704M System ! i cadur# (mg/MJ) Health , (See vl) Fire React. 1 ; Sp ' Gr. <Air=l) i Fl. Pt. C (F) Ignit, Temp, 5C <F) 3 ' 1000 1 i- 70 i _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ 1__ __ _ ___ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ _ _ 11 13 10 I 2i 3 0 1 84 1 3,1 .; 1! L.:_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ i: -40 (-40) 2 (36) 309 (588) 18 ;2 21 0 89 | 4 8 52 (126)oc Flam. Limits % 1 5-7 8 B.P. C lF) 36 (97) 98 (208) 163 (325) M.P. C <F) -116 (-117) Sol. in H 2O g/IOOg Other Solvents org, solv, $1. sol. ale, insol. ale. 18 100 j 2' 3' 0, ,35 17 460 (63) (860) 1,2-8 126 (259) -57 (-71) ale. Mise, Ret, MCA NTTC BOH 181 tert-Butyl Peracetate CH3C03C(CH3)3 182 tert-Butyl Perbenzoate C6H5C03C'CH3)3 183, Butyl Peroxypivalate (in 75% sol. of Mineral Spirits) 'CH3)3C02C0C(CH3)3 Butyl Peroxytrimethyi Acetate, see Butyl Peroxypioalate 22b 25 ! 2 3' 1 93 j1 34 10 ; 22b ,.1 ; 27 (80) 107 i '225) 22b j 0 3 4, ,, >68 ;! ! 1 (>iss) _ _ _ _ _ _ _ _ _ !_ _ _ _ _ _ _ _ _ :_ _ _ _ _ _ _ _ _ !_ _ _ _ _ _ _ _ _ !_ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ r . 113dec. (235) -19 (-2) 184 di-Butyl Phosphate 'C4HgOl2PO(OH) 7b ale , ace 185. tri-Butyl Phosphate See 1054 186 p-tert'Butyl Toluene CM3C6H4C4Hg 187 Butyl Vinyl Ether C4H9QCH*CH2 18 10 3 2 15 2 3 85 2 ,77 3,4 -9 (l6)oc 193 (379) -52 (-62) in5oi, ace,, or., cnl 94 (201) -92 (-134) insol, org, sol PAGE 28 1 s 1 J 1 i 1 J 1 4 1 1 4 1 CMA 046009 SUBSTANCG/FORMULA 188, 1-Butyne chcch2ch3 189 n-Butyraldehyde ch2ch2ch2cho 190, iso-Buryraldehyde (CH3)2CHCHO 191 n-Butyric Acid CH3(CH2)2COOH 192, iso-Butyric Acid (CH3)2CHCOOH 193 O'Butync Anhydride (CH3{CH2)2CO)20 194, 2 Butyrolactone Ch2ch2Ch2COQ 195 n-Buryronitrile CH3{CH2)3CN 196 Butyryl Chloride C3H7COCI 197, Cadmium Cd 198 Cadmium Chloride CdCt2 199. Cadmium Oxide CdO Waste Dis posal Pro cedure (See VI) TLV (ACGIHI PPM (rtig/M'') NFPA 704M Sye m Health Fire React. 18 2 2 23 1 2 231 224a 2 0 Vap FI. Pt. Sp. Dens 5C Or. IAir=i) !SF> 67 __________ | 32 2,5 -6,7 (20) 79 2 5 - 40 (-40) __________ I 96 30 66 (151) Ignit. Temp. 1 5C 1 F) j Flam. Limits i % B.P SC (F) 1| 81 , (46) 230 (446) 254 (490) 2 5- | 76 (169) i 1 6-10 6i 64 (147) 452 (846) 2-10 i 164 (327) c lp) H2O gytOOg Other Solvents _____________ 1 -127 insol f-197) ale Misc. Ref. -89 4 (-146) ale. BOH VlCA -66 (-87) 4 ale. BDH, MCA -7 9 (17 5) X sic BDW 24a 24a 18 1 i3 1 2 2 2 95 30 62 502 (144) (935) 1 97 5 4 88 307 (190) (585) 1 05 3,0 98 (209) 154 (309) -47 (-53) 2020 ale cni BDH 198 (388) -73 (-99) dec, dec., ale, 206 -44 X ale (403) (-47) 14 - i3 la ,8 1 03 26 (79) 3.7 <21 i< 70) 117 (243) -1 12 si sol (-170) ale or 107 (225) -39 (-128) dec die BDH BDH 27a 0 2 3 2 8.6 767 11413) 321 (610) msot 27f (.2) 27f 1.1) 3 3 40 1 8.2 1 960 (1054) 568 (760) 14020 51, sol ale ; i 1559 900 in 50I (2338) (1652) PAGE 29 CMA 046010 SUBSTANCE/FORMULA t 200 Calcium Ca 201 Calcium Arsanate CalAsQ4)2 Waste Ois: posai ; Pro- 1 (See Vi) ---- 1 TLV lACGIH) PPM (mg/M3)! < NFPA 704M System Health Fire React. 3 (5) 1 1 2 j; i! 1 27d (1) 3 1 ! I gn it, j Vap. 1 FI. Pt. j Temp. Sp. 1 Oens. i QC ! Gr. (Air=1l I ("FI I (F) Flam. Limits % 6.P. C (F> M.P. C (5F| 1 15 1240 842 _____ (1548) (2264) 36 1 45 (34.5) Sot. in H2O Other g/lOOg | Solvents dec 01326 sl so! . ale, Misc. Ret 8DH 202 Calcium Carbide CaC2 203, Calcium Carbonate CaCQ3 204 Calcium Chlorate Ca(C103) 2H20 205 Calcium Chloride CaCI2 206 Calcium Cyanide CatCN)2 207 Calcium Hydride CaH2 25 26 12a 11 14 ! 10 17 1 4 2 22 ;1 1 22 27 2 71 . i[ __________ L__ .______ J__________ _ | ! ; 2 15 .1.1.11 i 1 2300 14172) 447 (837) dec, 899 325 (1650) 11517) si. sol ! BOH,MCA 1 100 (212) 178 ale , ace AIA <1600 772 (<29121 (1422) 7520 ale., ace. \JTTC 20 -- 3 0 13 1 350dec '(662) __________ 1.......... ......... ; 816 (1501) dec dec dec,, ale, BOH, MCA,MCB BDH 208 Calcium Hydroxide Ca(QH)2 209 Calcium Hypochlorite Ca(Cl0l2 ; 10 '* i 2 25 ' ! 2 1 2 2 35 210 Calcium Oxide CaO 210e Calcium Sulfide CaS 26 Of 101 (5) ]1 1 o! 1 3 25 ! ---- '--------------23 i dec. 580 (1076) 18 ' lOOdec dec, (212) 2850 (5162) 2580 (4676) 1310 .......... i i BDH 211 Camphor Cioh160 is (2) 2 2 0 .99 5 24 66 466 .6-3.5 209 175 5l, SOI. ace , ale , (151) (871) (408) (347) bz , chi PAGE 30 t r * 1 1 1 1 l ;* ,1 1 ? 1 1 CMA 046011 SUBSTANCE/FORMULA H2. Caproic Acid C5H11COOH Capryl Alcohol, see 2-Octanol 213, Caprylaldehyde CH3(CH2>6CHO Capryfic Acid, see Octanoic Acid Caprylic Alcohol, see 1 -Octenol 7id. Carbazole CQH4NHC5H4 Carbitol, see Diethylene Glycol Monoethyl Ether Carbolic Acid, see Phenol 215. Carbon, Black C 216. Carbon Disulfide cs3 217, Carbon Monoxide CO Carbon Oxysulfide, see Carbonyl Sulfide Waste 0is- l P, " TLV MFPA 7* 04M Sy' stem " 1 csdure ,m ;m3, Hejlth (See VI) ! 24a | ;2 I1 Flre 1 Rsact. 0 lyn't, Sp ^ F|,CP, ! TS^P' G, |Air=i) (F) 1 (F) II 93 | 4.0 1 102 - | (215)oei Flam. Limits % |! 11 : . . . . 11 1: ; ________________________________ | _ _ _ 1_________ 2 22 0 ,8 4.5 ' 52 : (125) B.P. C (F) 205 (401) 168 (335) MP C (F) Sol. in H?0 g/ 1 QOg Other Solvents -5,4 (22) i.i*> die. grg. 50W. Mtsc. Ref !, ! 1S .............. i____ _____ 6 1 11 : i.io 1 ! j 355 245 msol. , ale., _ _ _ _ L_ _ ________ ; 1_ _ _ _ j-- (671) (473) 1! hot bz. '1 1 1 26 (3.5) 1 - ~-4200 3680 insol. (-7592) (-"6656) 9 20 2 3 0 1.26 2,6 -30 100 144 46 -112 2 ale,, ehl. AIA, BOH, Skin (-22) (212) (115) (-169) MCA, NSC 18 50 2 4 0 .81 .97 609 (1128) 12.5-74 -192 (-314) -- 207 (-341) 004 ale., bz. PAGE 31 CMA 046012 SUBSTANCE/FORMULA 218. Carbon Tetrabromide C8r4 219. Carbon Tetrachloride CCI4 220. Carbon Tetrafluoride CF4 Carbonyl Chloride see Phosgene 221. Carbonyl Fluoride cof2 222. Carbonyl Sulfide COS Carvena, see Dlpantana 223. Caustic Potash KOH 224. Caustic Soda NaOH 225. Callosolve CH2OHCH2OC2HQ 226. Callosolve Acetate CH3CQOCH2CH2OC2H5 227. Cellulose Nitrate C-|2H17(N02)307 PAGE 32 Waste Dis posal Pro cedure (See VI) TLV IACGIHI; PPM ! j NFPA 704M System Health Fire React. 27j 3 0 1 27J 10 3 0 0 Skin 21 2 Ignit. Vap. FI, Pt. Temp. Flam. B.P. Sp. Dens. 'C C Limits C Gr. (Airsl) (aF! (FI % <F) M.P. C (aF| Sol. m HzO g/IOGg Other Solvents 3.4 190 90 Insol. ale., chi. (374) (194) Misc. Ref, 1.58 5.3 none 3.42 none 77 (171) -23 insol. (-9.4) ale., bz., chi. -127 -184 si. sol. (-197) (-299) A!A, BDH, MCA, NTTC, NSC 1 1 21 12 3 13 3 4 1.14 1.07 2.1 -83 (-117) -114 dec. 1-173) 12-29 -50 (--58) -138 so14 (-216) dec., ale. ale. MGS MGB 1 3 1 1 10 3 0 1 2.04 none none 1320 360 107'S ale. BDH, 1(2408) (680) MCA 10 m 3 0 1 2.13 none none 1390 (2534) 31S (599) r*ale. SDH, NTTC, MCA i 18 2 2 .93 3.10 94 (202) 1.7-15.6 135 (275) ace., ale., chJ. BDH P 18 100 2 5km 2 .97 4.7 55 (131) 382 (720) 1.2-12.7 156 (313) -62 (-80) v. sol. org.solv. P 28 2 3 3 1.66 13 (55) insol. ace., MeOH s* -1 CMA 046013 SUBSTANCE/FORMULA 228. Celluloid, Lower Nitrate* of Ceiluloce and Camphor 229, Chloral CCI3CHO 230. Chloral Hydrata CCl3CH(OH\2 231. Chlordtn* CioHgCIs 232. Chloric Acid hC!03-7m20 233. Chlorma Cl2 234. Chlorine Dioxide Cl02 235. Chlorine Trifluoride CIF3 236. Chloroacetaldehyde ch2cicho 237 Chloroacatamide CH2CICONH2 238. Chloroacetic Acid CH2CICOOH 239. Chloroacetonitrila CHjCICN Waste D.t- TLV posai .(ACGlHl Pro PPM cedure (mg/M3) (See VI) NFPA 704M System Health Fire React. 38 2 ' Ignit. Vap. FI. Pt. Temp, Flam. B.P. Sp, Dans. C C Limits c Gr. (Air=1) (F) (F> % (F> M.P. C (F) Sol. in H9O g/IOOg Other Solvents Mite. Ref. 33 1,51 5.1 none 2 21 1.64 98 (208) -58 (-72) v. sol. hot ale. 96 1205) 52 1126) 47417 ale., chi., CS2 4b (.5) 3 - 1.6 56 (133) 175 (347) 12a 33 3 1,28 113a 1C 3 0 2 48 2.49 12a 1 33 3.09 2.3 100 (2121 __________ | 21 .1C 3 3 3 1 77 3.1 j 2 1C 3 2 1,19 __________ __________ 2.7 88 (190) 40dec. (104) -20 v. sol 1-4) BDH -34 (-29) -101 (-150) 1.4 Cl 9.9 -59 dec. (50) 1-74) expl with compounds of carbon. 12 -83 dec. (54) (-117) MCA, MGB. NASA 85 (185) -16 (3.2) 20 225 120 10=" ale. (437) (248) 4c 4 2 1,40 33 189 (372) 63 (145) v. sol ale., bz,, chi., CS2 SDH 14 3 1,19 123 (253) PAGE 33 CMA 046014 SUBSTANCE/FORMULA |k240. Chloracetophenone CsH5COCH2CI 241, Chloroacetyl Chloride cm2cicoci 242 m-Chloroamline C5H4NH2CI 242 o-Chloroaniline C5H4NH2CI 244 p-Chloroanilme C5H4NH2CI Chlorobenzaldehyde, see Benzoyl Chloride 245 Chlorobenzene c6h5ci 246 0-Chlorobenzoyl Chloride CIC6H4COCI 247, Chlorobromomethene CH2CIBr Chlorobutadiene, see Chioroprene 248, p-Chloro-m-cre$ol C0H3CH3OHCI 249, Chlorodiethyleluminum CI-AI-<C2H5)2 Waste Oispoul TUV (ACGIHI Pro- PPM ?fdgw.i (mg/M'V (See VI) ' 1 Health 4b 06 3 NFPA 704MSystem Fire React, ! [ Vap. Sp. 1 Den$. Gr, j IAir=1) FI. Pt. C (F) 1,9 ** Ignit. Temp, C (5F) Flam, Limits % B.P. C (F) 247 (477) M.P. C (F) 59 (138) Sol. m HoO 9/1fog Other Solvents 10501. ace., ale., bz., CS2 Misc. Ref la 3 ; - I 15 1 5 !3 ! ! i 22 ' ' 108 (226) -23 (-9) dec. dec , ale SDH 229 (444) -10 (14) jnsol, org,sOlv, BDH 53 ^ 1 21 !1 ' 209 (408) -14 (6.3) insol org, solv SDH 5 3 i ] 1 43 ;1 231 1448) 70 SOt. (hot) org, solv, (158) BDH i 4b 75 2 3 0 1,11 3.9 ; 29 638 1,3-7,1 132 -56 msoi. ale., bz, A1A (34) (1180) (270) (-69) chi, CS2 BDH NTTC ri la 22 1: l ' 225 1437) -10 (14) dec. dec. ale 26 200 2 1 93 45 68 (154) -88 (-126) msoi. org,solv, 4b 3 3 330 <-1 (< 30) 235 (455) 66 (1511 si sol ale 208 (406) -50 (-53) BDH CMA. 046015 CMA 046016 7^ Chloronaphthylamme C,oH8CIN 258. Chloronitroanihnes NO2CIC6H3NH2 259 Chloronitrobenzenes CsH4C!N02 260 1*Chloro*1*Nitropropene C2H5CHCINO2 261 Chlorapentafluoroethane C2CIF5 262 m-Chlorophenol CgH^ClOH 263. o-Chlorophenol C6H4CIOH 264 p-Chlorophenol C6H4CIOH 265 O'Chiorophenyl Diphenyl Phosphate ClC6H40(C6H50)2PO 266. Chloropicrin CCI3NO2 267. Chloroprene CH2CHCCICH2 Chloropropane, see n-Propyl Chloride ' 36 O'* posal TLV (ACGIH! Pro- | PPM ; cediire (mg/M3>] (See VI} 1 | 704M System Health Fire React. 1 Ignit. Vap. FI. Pt, ; Temp, Sp. Dens, =C 1 C Gr, IAir=ll , (FI \ (F) __________ !__________ 1__________ i__________ i 6 1! , CAR 1 1 - 1|| *;!' _ '! 1 ... .J__________ :__________ ;__________ __________ i__________ 1__________ :---------------- 6!- 3, 1 ' -j -' - 1' !' Flam. Limits % - B.P C (F) M P. C <F) Sol. in HjO g/IOOg Other Solvents 60 (140) ale 108-16 (226*41) ale ace 63 __________ ._________ 1 4a 20 3 26 1000 63 1 1 j 1 37 1 _____ !__________ i__________ 127 i (261) 2 i 3 1.21 ! 4 3 ' 62 (144) 0 1 0 i 1.26 1 1 i : T ! 1 1 2 1 24 242 (466) 32-46 insol. (90-115) ale , bz 142 (288) si. sol. ale -39 (-38) -106 (-159) insol, ale. 214 (417) 32,5 sol,(hot) (90.5) ale , bz. 6 32 1.24 85 1185) 175 (347) 7 (45) v. sol bz 6 32 1 24 121 (250) 220 (428) 43 1109) sol ale bz 7b 12 5 215 240*55 <0 (419) (464-91) (< 32) Misc. Ret. BDH BDH BDH BDH BDH 4a 4 0 1 1.66 57 4b 25 3 ,95 3.0 -20 (-4) 4-20 112 (234) --64 (-83) si sol. ale. bz. 59 (138) sJ, sol org sol BDH CMA 046017 substance/formula 3-Chloro-Propionly Chloride CICH2CH2C0CI Waste Dis posal Pro cedure (See VI) TLV i IACGIH); PPM j (mg/M'3)j ISlFPA 704M System Health Fire React. la Sp. Gr. 1 33 2^9 Chlorosulfonic Acid HOSO2CI 270 ChlOrotnfluoroethylene fcci=cf2 1b 26 3 0 2 1.79 3 <1 2 1 31 271, Chromates (CrOn = ) and Dichrijmates (Cr207') 12a ! 1) 272. Chromic Salts (soluble) Cr+++ n (.5) 273 Chromium Cr 26 ( 5) 0 2 7.2 274 Chromium Trioxide (Chromic Acid) Cr03 12a (,1! 1 0 1 2 70 275 Chromous Salts (soluble! Cr++ 12b < 5) 3 276, Chromyl Chloride (Chromium Oxydoride) CrQ2CI2 12a 3 1 91 277. Cinnamaldehyde c6h5ch=chcho 2 1.05 278 Citraconic Anhydride C5H4O3 24a 1.25 Citrene, see Dipentene Citric Acid C3H4(OH)(COOH)3 24a 11 1 54 i>l lo?< FI. PL eC (F) Igmt. Temp. 6C (F) Flam, Limits % B.P, C <F) 143 (289) M P, C (F) Sol. in HjO 9/100* Other Solvents si sol ale., chi. Misc. Ref. BDH 40 none none 152 (306) -80 dec. (-112) dec. ale BDH, MCA, NSC 8.4-39 -28 -158 1-18) (-252) 49 (120) sol. 2480 (4496) 1890 (3434) insol. dec 196 62 (385) sol. ale. BDH,MCA 116 -96 (241) 1-141) dec org sol 253 (487) -7,5 (18) si sol ale , chi 213 7-8 (416) (45-6) dec. ale. BDH dec. 153 (307) v. sol ale PAGE 37 CMA 046018 SUBSTANCE/FORMULA 280 Cleaning Solution Waste Dit posai Pro cedure I Sea VI} 4 IACGIHI PPM (mg/M3) [ NFPA 704M System Health Fire React I Vap Sp. | Dens, Gr. ! <Air=1> FI. Pt. C (F> Ignit. Temp. C (F) Flam, Limits % B.P, C (6F) M.P. C lF> h4o fl/IOOg Other Solvents Wise. Rf 281 Cobalt Co 2900 IS252) 1495 (27231 282, Cobaltous Nitrate CoiN03)2'6M20 55dec (131) 283 Collodion C-]jH1gOglNC^^ c13h1707^03>3 284, Copper Cu 285 Copper Nitrate Cu(N03)2`6H20 ! 8.9 i 1 2.07 <-18 <<01 2595 (4703) 1083 (1981) l98dec (388) 26 (79) 286 Crag 974 C5H10N2S2 106 (223) 287 m-Cresol CH3CQH4OH 94 ; 559 106-1.351 203 (202) I M038) @302 F (397) 12 (54) org sol 288 O'Cresoi CH3CgH4QH 1 05 3.7 , 81 j 599 , (178) ! (1110) 35- | 191 ! 31 ! sol (hot) org sol 1376) 1 I8S) 289 P'Cresoi CH3C6H4OH 94 559 (202) (1038) 1 06-1.4 @302 F 202 (396) 35 sol (hot) org sol (95) BDH,VGA 290 Creosote (Mixed Phenols) 1.07 1 74 82 1 336 ,(165 180)1 (637) 200-250] (392-482)| Cresylic Acid, see 0-Cresol I.GE 38 CMA 046019 CMA. 046020 1 SUBSTANCE/FORMULA | p03 Cyanogen (CN)2 304. Cyanogen Chloride CNCI 305. Cydoheptanone c6h12cO 306 Cyclohexane c6h12 307 Cyclohexanol C5H10CHOH 308. Cyclohexanone C5H,ciCO 309, Cydohexen* c6h10 310. Cydohexylamme c6h11nh2 311. Cydohexylbenzene 312. Cydomte-ROX c3h6n66 313. Cyclopentadiene c5h6 314, Cydopentane C5H1CI Waite Dis posal Pro cedure (See VII TLV (ACGIH) PPM Imfl/M3) 14 10 NFPA 704M Syvtem Health 4 Fire React. r 42 14 5 3 18 2 18 300 1 30 18 50 1 2 0 Ignit. Vap FI, Pt. Tamp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F| ("FI % (F) M.P, 4C (F) Sol. in H2O g/100g Other Solvents 9 Misc. Ref J 95 1,8 6-32 -21 (-5 8) -34 (-29) 450:0 ale MGB J 12 19 13 (55) -6.5 (20) si. sol. ale. 4 ~1 95 178 insol, ale. (3521 77 2.91 -20 1-4) 260 (500) 1.3-8.4 80 (176) BDH, MCA 41 insol. ale , ace . (39) bz 96 3 45 68 300 (154) (572) 161 25 3.6 CS2.bz (322) (77) ^ I1 18 50 1 2 0 .99 3 4 44 420 1.1*8.1 156 -16 sl. sol. ale MID (788) (313) (3,2) BDH 18 300 1 3 0 81 2.8 -6 (21) 83 (181) -104 msot (-155) ale., ace., bz BDH 7a 2 3 0 87 3.4 32 293 135 -18 sol. org, sol BDH (90) (560) (275) (-.4) 1 1 18 2 1 0 95 99 104 (210) oc (220) 4a 2 3 4 1.B 18 75 2 .80 18 1 3 0 .75 2 42 -7 (< 20) 238 (460) 7.5 insol. (45) ale. 204 (399) ace. 42 -97 (108) (-143) in$ol. ale . bz 49 (120) -94 (-137) msol. ale -* h n 11 11 CMA 046021 SU6STANCE/F0RMULA Cyclopentanone C4H8C0 ......... ......................................................... Waste Dis posel Pro- cedure (See VI) TLV (ACGIH) PPM (mg'M1) NFPA 704M System Health Fire React. Ignit. Vap. FI. Pt. Temp Sp Dens. 6C C Gr (Air=1) : l5F) (FI __________ 1 18 2 30 95 2 3 ' ; (79) 1 y.................................... :....................... -........... _________________ 1--.............. j.____ ,,____ j__________ j Flam. Limits % B P. C <F) 131 1268) M.P. aC <F) -58 (-72) 316 Cyclopropane 18 C3H6 : --------------- --------------- ----------- 1---------- --------------- 1 4 0 72 1 45 ! - 1 498 '2.4-10 4 -33 -127 ; (928) > (-27) (-197) ----------------1__________ ;__________ i__________ 317 p-cymene CH3C6H4CH(CH3)2 18 , 2 2 0 86 4 62 4`, 436 1 7-5 6 177 -68 , 1 (117) ' (817) (351) (-90) Sol. in H2O g/IOOg msol, sl sol insol, Other Solvents ale , MeOH ale. ale , ch| BDH 318 Decaborane B10H14 j 17 05 3 2 1 ,9-4 j i Skin 1 80 149 (176) j (300) 213 (415) 100 (212) sl, sol. ale , bz , CS2 AlA, NFPA, NSC 319 Deeahydronaphthalene C10H1S 320. iso-Decaldehyde C9H19CHO Decalin, see Deeahydronaphthalene 321 n-Decane ch3(ch2)8ch3 322. m-Decyl Alcohol CH3(CH2)gCH20H Dematon, see Systo* 18 2 18 18 2 2 ^ 1 .87 4,76 1 57 ' 250 7-4 9 186 -45 insol. ale , chi, j (135) ! (482) (367) (-49) ,8 ' 5 4 ; 85 1i (186) 1 _ _ _ _ _ _ _ _ _ :_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ,_ _ _ _ _ _ _ _ _ !_ _ _ _ _ _ _ _ _ 197 (387) BDH .. . . . . . . . . . . . 0 2 < 0 ' 73 4 90 46 (115) _ _ _ _ _ _ _ _ _ !_ _ _ _ _ _ _ _ _ 1_ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ _ _ ......... 1, 1 208 1 1 (406) 1 .8-5,4 174 (345) -30 (-22) msol 2 ! ,83 53 82oe 11 (180) 229 7 insol __(4_4_4)_ __(4_5_) _ , ale ale . ace . bz , ehl 323 Deuterium d2 27k 0 4 0 .18 5-75 -250 (-418) -255 (-427) @121 mm sl sol 324 Diacetone Alcohol 18 50 1 2 0 CHjCOCH2C(OH)(CH3>2 4 0 64 603 1.8-6.9 168 -50 (147) (1117) (334) (-58) ale _ Diaminoethane, see Ethylene Diamine BDH PAGE 41 CMA 046022 t| ) SUBSTANCE/FORMULA Diatomaceous Earth, see Silica Waste Djs! p""' [ cedure (See VI) (ACGIH) PPM 1 (mg/M3) NFPA 704M System Health Fire React. Ignit. Vap, FI, Pt, Temp. Flam, B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F) (F| % (F) M.P, C (F) Sot. in H2O g/IOOg Other Solvents 325 Diazomethane CH2^2 326 1.2,5,6-Dibenzacndme C21H15 N 8 ,2 3 5 1 45 lOOexp (212) -23 (-9,4) -145 dec. (-229) hot ale. 327, 1,2,7.8-Dibenzaeridine C2lH15N 5 328 1,2,5,6-Dibenzanthracene CjjH]4 329 1,2.5,6`Dibenzcarbazole C2QH17N 18 5 268 (514) insol ace., bz., CS2 330 3,4,5,6-DibenzcarbBZole C20h17N 33l 1,2,5,6'Dtbenzof luorpne C21HI8 332 1.2,3,4-Dibenzophenanthrene C22h1S Dibenzopyrrole, see Carbazole 5 18 18 280 (536) @ .3mm 174 (345) bz 333, 3,4,8,9'Oibenzpyrene C24H17 18 334, Dibenzylamme HN(CH2C0H5i2 i-- PAGE 42 5 31 1.03 300dec, -26 sol (572) (-15) ale. 1 Miac. Ref CMA 046023 SUBSTANCE/FORMULA A W' ^335, Diborane B2H6 Waste Dis posal Pro cedure (See VI) 17 TlV (ACGIH) PPM (mg/M1)1 01 ; NFPA 704M System Health Fire 3eact. i 31 ! *! 3 !i Dibrom, see Dimethyl-1,2- 1 Dibromo-2,2-Dichioroethylphos : ! 1 So. Gr. 46 336 2, 6-Dibromo-N-Chloro* p-Benzo-Quinonimtne C6H2Br;CINO 6 1,2-Oibromoethane see Ethylene Dibromide ' -- 337 1,2,-Dibromotetrafluoromethane (Freon-114B2) C2Br2F4 i 26 '0 2,72 Vap. Dens. <Air=1l FI. Pt. C (F) Igmt cC (0 F) Limits % B.P, c i6f) ; 1 M,P. C (F) HjO g/IOOg Other Solvents Misc. Ret. .96 -90 145 9-98 1-1301 (293) j| >1 1 -93 I (-135) 1 1 -165 dec (-265) Pec., ale. __________ ______________ !I i| A! A, MCA,NSC 11 85 (185) u_________ in$0l 1 i !1 '! 24 5 (76) 1 -142 1 (-224) - 338 Dibutylemme (C4Hg)2NH 339 Dibutyidichlorotin <C4Hg)2 SnCi2 7a 32 0 50 4.46 52 ; (126)oc 4b 3 1.36 10 5 355 (671) 159 1 -51 sol (318) (-60) 135 (275) @ 1 0mm 1 43 (109) dec ale ale , bz 340 Di n-Butyi Ether !CH3(CH2>3] 20 341 Dibutyl Oxalate (C4H9)2C204 342. Oibutyl Peroxide (CH3)3COOC{CH3)3 15 18 22b 1000 2 3 2 30 0 31 4 77 4 5 1 01 7 0 79 i 5 0 25 194 1,5-7,6 141 -98 insol (77) (381) (286) (-144) 104 (220) 246 (475) -30 (-22) msol 18 (65) ill 12321 -40 insol (-40) dlC ale ace, BDH NFPA 343, Dibutyl Phosphite (C4H90)2FOH m 7b 1 3: 2 i 11 0 ,97 6.7 49 (120) 115 (239) @ 1 0mm PAGE 43 CMA 046024 SUBSTANCE/FORMULA i ^44 D<butyl Phthalate C6H4(COO)2<CaH9)2 345 Dibutyl Tin Dilaurate ;cH3(CH2)10coot 2 Waste Dis posal Pro cedure (See VI) TLV IACGIH) PPM (mg/M ) NFPA 704M System Health Fire React. 18 (5i 0 1 0 18 1 Ignit. Vap FI. Pt. Temp. Flam B.P sp Dens. 6C C 1 Limits C Gr (Air=1) (F| <F> 1 % (F> 1 04 96 157 1315) 403 (757) 340 (644) 1.05 21 8 235 -- (455) M,P, C (F) Sol. in h20 g/IOOg Other Solvents -35 (-31) msol 62 , ace , ale 27 msol (81) ace , b2 Mi$c Ref 346 Oichloroacetic Acid CHCI2COOH 347 Diehloroaeetyl Chloride CHCI2COCI 348 2,5-Dichloroamltne CI2C5H3NH2 349 o-D?chlorobenzene C6H4CI2 350 3,3'-Dchlorobenztdme CINH2C5H3C6H3fSiH2CI 351 1,4-Dichlorobutane CH2CUCH2)3Cl 353 l,3-Dichloro-2-Butene CH2CICHCCICH3 353 Diehlorodifluoromethane cci2f2 354. 1,3-Dchioro-5,5-Difnethylhydantoin C5H5CI2N2O2 355 1,1-DichlQroethane CH3CHCI2 IGE 44 4c la 6 6 50C 6 CAR 4b 4b 26 1000 6 ( 2) 4b 100 3 3 3 2 2 2 1 3 2 1 56 4 45 192 (378) 97 (50) sc ale, SDH 2 1 1 53 51 66 (151) 107 (225) dec dec , ale BDH 10 5 6 166 (331) i 251 (484) 50 (122) si. sol, ale , bii BDH 2 0 1 30 5 07 66 648 ' 2 9 180 -18 msol, ale. (151) (1198) (356) (-.4) A)A, BDH, NTTC.MCA 8,7 dec 132 msol. bz., ace,, (270) ale 2 0 1 1 4 4 52 (126) 162 (324) -39 (-38) inso) chi 30 4 3 27 (81) 123 (253) msol org, sol 1.30 4,2 -29 -158 (-20) (- 252) sot. ale 1 5 68 132 (270) 3 0 1,18 3.4 - 6 458 5 6-11 4 +57 -97 -;0 ale, (21) (856) (+135) '-143) BDH CMA 046025 SUBSTANCE/FORMULA 1,2'Oichloroethane, see Ethylene Dichlonde . Waste i Dis- i PQMl Pro- ! NFPA TLV 704M Syriam MACGIH) ________ PPM 1 HM,th Fire React. T" 1,1-Dichloroethylene, see Vinylidene Chloride 356 1,2-Dichloroethyiene CICH=CHCI 357, 2,2' DichlOroethyl Ether (Cl C2H4)20 15C Skin 358 Dichloromethane CH2CI2 359 Dichloromonofluoromethane CH ChF 360 1,1-Oichloro-l-Nitroethane H3C(N02)CCl2 361 2.4-Dichlorophenol C6H3OHCI2 362 Oichlorophenylphosphine C6H5PCI2 363 1,2-DiChloropropane H2CCICHCICH3 364, 1,3-Dichloropropene C3H4O2 365 Dichlorotetrafluoroethane CCI2F-CF3 i VepSp. i Dens. Gr. ! (Air^l) FI. Pt. C <F) (gnit. Temp, C ("FI Flam, Limits % B.P 6C <aF) M.P. C lF) SHolz.Oin g/IOOg Other Solvents Miic. Ref. 1.3 I 33 2-4 <36--9) 55 (131) 369 (696) (14188---6400) -SO [-112) 178 (352) -24 (-11) 1 34 1 2.93 m O662 15.5-66 (1224) 2 40 (104) -97 (-143) org. sol, 220 1,48 : 3 B 552 (1026) 1,42 ! 4 97 76 1 (168) 114 (237) 9 (48) 124 (255) 210 (410) -135 (-211) .520 45 (113) elc . bz , chi. Al A, BDH, MCB Al A, BDH MCB BDH. NTTC, AJA. MCA 225 (437) bz., CS2 16 (61) 557 (1035) 97 (207) -100 (-148) Al A. NTTC 1.23 35 (95) 104 (219) 3.6 -94 (38) (-137) PAGE 45 CMA 046026 SUBSTANCE/FORMULA j t 366 Dicyc!ohjtylamine (C6Hn>2NH 367 Dieyciopentadiene c 10H12 Dls p"' TLV NFPA 704M Syxtam IARP|V1HI-------------------------------------- - eedure < mg/M1) (See VI) 7a ; Health j Fir# 2 React. 1 Vap. Sp Dens. Gr. i (Air=1) FI. Pt. 5C (SF) Ignit. Temp, c lF) Flam, Limns % 93 6,3 99oc (210) B.P, aC (F) 256 (493) ^ 18 | j 1 : 3 ; 1 ' ,93 4.55 35 I | ' i (95) 170 (338) M P, C (F) -1 (32) Sol. m H2O g/IOOg 16^8 Other Solvents ak., bz. 33 ale. (91) 368 Dieldrin C12H10CI6 369. Diethanolamine (HQCH2CH2)2NH 370 1,1-Di#thoxy#than CH3CH{OC2H5)2 371, Diethyladipate C2H5OOC(CH2)4COOC2H5 372 Diethylaluminum Chloride (C2H5)2AICI 4b (,25) J 1.75 132 175 (347) insol, 7a j ! 15 _ 1 i 1 1 0 ! 1,09 ' 3,6 I __________ j__________ ___________ r 152 662 (306)oc (1224) 270 28 v. sol. (518) (82) 2 3 0 | .83 , 4.08 -20 230 1.7-10.4 102 -100 2120 (*"5) (446) (216) (-148) 18 1,01 - 240-5 -- 21 ,4330 !: (464-73) (-5.8) i 4b 3 3 3 Ignites in air 208 (406) -50 (-58) ace., bz. ale. ak. ale 373 Diethylamjne (C2H5)2NH 7a 25 3 3 0 71 2,5 <-26 312 1.8-10 1 56 -48 V sol ale --15) (594) (133) ( -- 54) 374 2'Diethyl'Ammo--Ethanol {C2H5)2NCH2CH2OH 7a 10 3 2 0 .88 4.03 60 Skin (140)oc 163 (325) 00 ace., ale , bz 375 N. N-Diethylamline CgHglsMCjHg^ 5 3 2 0 .94 5.15 85 332 (185) (630) 216 (421) -38 (-36) 1412 ale 376 Diethylcarbonate IC2HS)2C03 377 Diethylene Glycol ch2ohch2och2Cm2oh 18 18 23 .98 4.07 25 (77) 1 0 1,12 3.66 124 229 2' (255) (444) 126 (259) -43 (-45) insOl. 245 (473) -8 (+18) sol ale. ale Misc, R*t, NTTC BDH NFPA BDH, MCA BDH. NTTC BDH BDH PAGE 46 CMA 046027 SUBSTANCE/FORMULA 78 Diethylene Glycol Monoethyl Ether C2H50(CH2}20^h2,20H 379 Diethylenetnamine (NH2C2H4)2NH Waste Disposal ; Pro* cedure i (See VI) TLV (ACG)H) PPM (mg/M-*). NfPA 704M System Health Fire React, Vap. Sp. Dens. (Air=1) 0 l 111 I 46 i -1.23 FI. Pt. SC (F) 96 (205) Igrnt Temp. 6C (F) Flam, Limits % 204 (400) 1,2- B.P C (F) 202 (396) 95 3 5 ; i 102 399 I (216)oc (750) 207 (405) M.P, C (F) Sol. in i H2O ! g/IQOg j Other Solvents -10 (-14) org sol, Misc. Ret, -39 (-38) NTTC, MCA Diethyl Ether, see Ethyl Ether 360 Oiethyl Ethyl Phosphate (C2H5)2PO(OC2H5) 1,03 ' 5 7 ! 105 (221) 83 (181) @11 mm 381, D<Cie2tHh5y)l2KCeOtone 382. Diethyl Malonete 01^2(00202^5)2 383 O'Diethyl Phthalate (C6H4)(COOC2H5)2 384. p-Diethyl Phthalate (C6H4)(COOC2H5)2 385. Diethyl Sulfate (C2H50)2S02 386 Diethyl Zinc ZnfC2H5)2 82 2,96 i 13 j 452 (55)oe | (846) 1.06 5,5 l 93 I200)oc I 23 7,7 , 117 I (243) 1 23 7.7 i - 163 1 (325) !1.18 5.3 ;i (210i94) 436 (817) 1.18 Ignites in air 101 (214) -42 (-44) 199 ! -50 (390) (-58) 4 720 ale. 2.120 ! aic. 302 (576) --40 (-40) insol. ale., b7, 296 (565) ' --5 1 insol. j ale., bz (23) | 208 j --25 ! insol. (406) ! (-13) 124 (255) 28 (82) 337 DigiyCtdyl Ether ;(ch2-chch2)Oi 2o 1,25 260 (500) Diglycol. see Diethylene Glycol PAGE 47 CMA 046028 substance 'Formula I 1,2'Dihydroxyanthraquinone, see Ali2ann Dyes WDiasste po$al Pro cedure (See vi! tlv (ACGIH) PPM <mg/M` I j NFPA 704M System Health Fire React. 388, 3,4-Dihydro'2H*Pyran csHgQ 18 - 30 Vap Sp. 1 Dens. Gr. ; (Arr=1> Ff. Pt. C (F) Ignit Temp. SC Flam, Limits %! B.P, C (6F> 92 2.9 -18 (0) 86 (187) M.P, C <F1 HjO I Other g/700g So/vents Mrsc Ref 389, Dnsobutyl Ketone {(CF^IjCHCHj! jCO 18 50 1 2 0 60 (140) . ,8-6 2 I 168 ;@212F' (334) 390. Dnsopropyl Amine ((CH3)2CH]2NH 7a 5 Skin 3,3 0 35 -1 (30)OC ! 83 i --61 1 si. soL -84 1 (181) (-78) , 391 Dnsopropyl Ether (CH3)2CHOCH(CH3)2 15 392 Dnsopropyl Fluorophosphate C6H14Fp03 | 7b 500 2 3 3 393 Diisopropyiperoxydicarbonate 22b (C H3 )2 H C*OQ<DC-0-0-C H (C 143)3 i _______________ 9________________ L 394 3,3-Dimethoxybeniidvne [NH2(OCH3)C6H3| 2 l5 395 Dimethoxyethane (CH30)2C2H4 1 15 : 0 CAR 396 Dimethoxymethane (CH30)2CH2 15 j 1000 2 397 Dimethoxypropane ich30)2c3h6 398 N,N-Dimethyl Acetamide CH3CON(CH3)2 j 15 j 20 1 10 Skin 2 ,GE 48 4 2 3 2 1 1 72 3,5 -28 443 1,4-7.9 69 -86 sL sol ale. (-18) (829) (155) , (-123) -1 5,2 , 46 -82 (115) (-116) @5mrn ' 4 12exp. (531 : BDH N F PA 8 5 , 206 (403) 137 (279) msol. bi , ; ace. ale 1 0 .85 3 1 40 _____ , (104) " 2 .86 2.63 | -18 237 | (Oloc (459) 65 (149) -113 (-171) -- 46 (115) -105 (-157) sol. 33 1 ale, chi ale, .35 3 6 I - 7 j (19) 95 , 1203) -! ; - -- 77 -2094 30 354 1.8-13 8 165 oc ale , b2 (1711 (669) (329) (-4) BDH CMA 046029 SUBSTANCE/FORMULA 9 Dimethylamine C2H7N Waste Dis posal Pro cedure (See Vi) NFPA TLV 704M Systam (ACGJH) _______ PPM , Health Fire 400, Dimethylaminoazobenzene-2Naphthalene C-] gH 19N3 401 2-Dimethylammofluorene G15H15M 402 N,N-Dimethylanilme C6H5N(CH3)2 403, 2.3-Dimethylazobenzene (CH3)2C6H3N2C6H5 404, 9.10' Dimethyl-1,20en2anthracene (Ch^'sClS^IO 5 Skin Dimethylbenzylhydroperoxide. I see Cumene Hydroperoxide I 405 N,N-Dimethyl-4-Biphenylamme | (CH3)2(C6H4)2NH I 6 406, 2(C,2H-D3)i3mCeCthHy2l CBHut3ane 407 Dimethyl Carbonate OC(OCH3)2 408 1.2-Dimethyl Chrysene (CH3)2Cl8H10 409 Dimethyl-1,2-Dibromo'2.2Dichloroethyl Phosphate (CH2Br)2C2H3Cl2P04 | 18 ; I Vap. Sp. Dens. Gr. IAir=l) FI. Pt. 9C ISF1 Igmt. Temp, c ("FI Flam, Limits % B.P, C l6F) M.P. aC <F) SHol2. Oin g/IQOg Other Solvents Misc. Ret. -50 (-58) 402 (755) 74 (45) -92 (-134) BDH, MCA, MGB 174 (345) 63 (145) 371 (700) 193 (379) 25 (36) AIA, 0DH 122 (252) --------------1----------------inso) I CS2- hr 65 1 3 00 -48 425 1,2-7.0 I 50 1 -98 ` insol (-54) , 1797) ! (122) I (-144) ale (6196)oc 90 (194) 5 1 insol, , ale (32) t 8DH 448 (838) 250 (482) insol I si, sol, bz ; 200 ('*' 392) PAGE 49 CMA 046030 I # SUBSTANCE/FORMULA Dimethyl Ether, see Methyl Ether Waste Dis posal Pro cedure (See VI) [ TLV ! IACGIHI, PPM |mg/M3)j NFPA 704MSystm Health Fire React. Ignit. Vap. FI. Pt. Temp. Flam, B.P, Sp. Dens. flC C Limits C Gr. (Airssl) <F) <F) % <F) M.P, c <F) Sol. m H2O g/IOOg Othei Solvents 410 Dimethylformamide (CH3)2l\lCHO -- 411 Dimethyl Fumarate (CHCQOCH3)2 2,6-Dimethyl-4-Haptanone, see Diisobutyl Ketone 20 10 Skm 18 , j ---------------- 2 1 0 ; .94 ! 2.51 i 58 (136) 445 22-152 (833) 153 (307) -61 (-78) 192 (378) 102 (216) oe ale., bz. chi. i Misc. Rf BDH c l.l-Dimethylhydrazme, see Unsymmetrical DimethylHydrazine 412. 1,4-Di methylnaphthalene c10h6<ch3>2 Dimethylmtrosoamine, see h-Nitrosodimethylamine 18 ; 1.02 I 1 262 (504) -18 (0) insol. ale. 413 Dimethyl Phthalate C6H4(C02CH3)2 18 (5) 0 0 1.19 i 6.7 146 556 | (295) (1032) 288 (550) insol. ale., bz. 414 2,2-Dimethyl Propane ich3)4c 18 4 0 .61 2.48 <--7 450 1,4-7,5 9.5 -18 insol ale. 20) (842) (49) (0) 415. Dimethyl Sulfate (CH3)2S04 416 Dimethyl Sulfide (ch3)2s 4b 4 2 0 1 33 4 35 83 188 Skm (181) (370) 189dec. -31 (372) (-24) sot, | ale., bz l AIA, BDH, NTTC, MCA 13 4 4 0 8 21 <-18 206 2.2-19.7 37 -83 msol ale . (<0I (403) (99) (-117) MeOH 417 Dimethyl Sulfoxide (ch3}2so 4b 1 0 1 01 95 215 2.6-28.5 !203)oc (419) 189 (372) 18 (65) sol. ale , ace PAGE 50 CMA 046031 SUBSTANCE/FORMULA # 4-Dinitroamhne (!Si02l2^6H3fNjM2 419 nvDmitrobenzene CgH4(N02)2 420 O-Dinitrobenaene C6M4(NC>2)2 421. p-Dinitrobenzene C5H4(N02>2 422, 4.6-Dmitro-O-Cresol IN02)2C6H2CH30H 423 2.7`Dimtrofiuorene Ci3H7(N02)2 424 2,4`Dinitrophenol (NQj^Cq^Oh 425 1,4'Dimtroiopiperazino C4MgN2(N02)2 426 2,4`Dinitrotoluene C6H3CH3IN02)2 427 Di-m-Octyl Phthalate C26H4202 428 Di*eee>Octyl Phthalate Cq^ICQQCqH 17)2 429. 1,4-Dioxane C4Hg02 * Waste Di* ' pOl Pro cedure (See VI) TLV (ACGlH)_ NFPA 704M System PPM : [mg/M3)! Health Fire React. Ignit. Vap. FI. Pt, Temp. Flam B.P, Sp. Dens. &C C Limits *C Or, (A.r=1) ("FI <F) % (F) 244 (471) M.P. C (F) HjO g/IOOg Other Solvents 188 (370) Mic. Ref. (D Skin 150 (302) 5.8 | ISO ; (302) 291 (556) 90 (194) 319 (606) 118 (244) .399 (1) Skm 150 (302) 299 (570) 172 (342) ( 2) Skin 85 (185) si. sol. 1 ale., ace. 160 (320) 1,68 1 6.4 j 114 (237) CAR (1.5) Skin 4.97 1.28 1 6.3 207 (404) 219 (426)OC 218 410 (425)oc (770) 158 (316) 300 (572) 70 (158) .0320 385 (726) -30 -22) 358 (676) Al A, MCA 3,0 12 180 (54) (356) 101 (214) 10 (50) PAGE 51 CMA 046032 SUBSTANCE/FORMULA West# | Dis- ! pTM` ; TLV ! IAppMMI NFPA 704M System Health Fire React. Ignit. Vap. FI. Ft, Temp, Flam, Sp* Dens. C Gr. (Air=1) <F) 5C (F) Limits % ^^^Foipentene 18 2 2 0 0ioH16 i! __________ __________ Dipentene Dioxide, |> see p-Mentha-1,8-Diene | ______ ____________1___________;_________ .............. 431 Dipentene Monoxide ;: 18 i | i 1j ;............ -J___________ Cl0H14 j; 65 .93 4.66 45 (113) 4.45 67 (152) 237 .7-6.10 (458) @302 F ' 432 Diphenylamme (C6H5>2NH 15j |j 3 1 0 1.16 5.8 153 634 (307) (1173) 433, Diphenytmethane IC6H5)2CH2 18 1 1 0 1.01 5.8 130 436 (266) (907) 434 Diphenylsuifide ICgHs^S 43B Dipropylene Glycol Methyl Ether CH30C3H6OC3He0H 436 m-Dodecane Cl2H26 437 Dodecyl Sodium Sulfate cl2H25NaS04 13 15 100 18 4b 2 0 1 1.12 2 L.. 20 95 5 1 85 (185)oc 75 5,96 I 74 | (165) 204 (399) .6- r B.P, C <F) M.P, C !F) Sol. in HjO a/100$ Other Solvents Misc. Ref 178 -97 (352) (-143) msot ale BDH 1 1 13 75 (167) <-6 (21) 302 (576) 53 (127) insol. ale., bz., CS2 266 (511) 26 (79) insol. ale,, ch|, 296 (565) <-40 n$ol. --40) bz., CS2 189 (372) 216 (4211 -12 (10) insol. ale., ace., CS2 ______________ ! 3 1 1 t3 1 1 1 J 438 Elon (H0C6H4NHCH3)2H2S04 6 260dee, 425 ale. 1 (500) 439 Endrin CuHgOCIe 6 ,1 3 1 0 Skin 27 (80) 200 (392) J 44Q, EpichlOfOhydrin C3H5C10 4b 5 3 3 2 1,18 3.29 41 Skin (106)oc m___________________________________ I 52 117 -48 <5 ale,, bz. (243) (-54) BDH, MCA CMA 046033 SUBSTANCE/FORMULA K41 EPN C-| 4H14O5NPS --------442. 1,2-Epoxy3-Phenoxypropane H2COCHCH2OC6H5 .-- 443. 1,2-Epoxy-Propane H3C-CHOCH2 ---- 444 Epoxy Resm Systems Waste Dis posal Pro cedure ' (See VI) TLV (ACGIH) PPM Img/M3) NFPA 704M System Health Fire React 4a ( 51 Skin 3 15 10 15 100 2 4 2 26 445, Erbium Er 27k 2 446 Ethane C2h6 18 1 4 0 Ethanediol, see Ethylene Glycol 447, Ethanethtol c2h5sh 13 IOC 2 4 0 Ethanoic Acid, see Acetic Acid 443. Ethanol ch3ch20h 18 1000 0 3 0 449 Ethanolaminq NH2CH2CH2OH 7a 3 2 2 0 450 Ethoxy Acetylene c?h5qcch 15 2-Ethoxy Ethanol, see Cellosolve Sp. Gr. 1 27 Vap. Dens. (Air=1| FI. Pt. C lF) __________ [ Ignit, Temp, C lF) Limits % B.P, C (F) 1 11 44 245 (473) M.P, "C <FI h2o g/lOOg Other Solvents 36 (97) 3.5 (38) msol. ale., bz. _________ ) . Misc, Ret B3 2 0 -37 (-35) 2.1-21,5 34 -104 v. sol (93) (-155) ale SDH 9 05 2900 (5252) 1497 (2727) insol A1A,NSC 57 1 04 515 (959) 3-12,5 -89 (-128) -183 msol, (-297) ale. 34 2.14 <27 299 2 8-18 ' 37 -144 1,5 ale, (<81) (570) ' (99) (-227) , BDH 79 1 02 ,79 1.59 12 (54) 423 , 3.3-19 i 79 (793! ' (174) 1 2 11 , 85 ! (185) i i I - 170 (338) ! <-- 7 lOOexp j !< 19) (212) I - ! 50 | (122) -114 (-173) ace, 11 (52) , ale ........... \------------------------ I insol, ale BDH,NTTC MCA NTTC, MCB PAGE 53 CMA 046034 SUBSTANCE/FORMULA 2-Ethoxy Ethylacetate, see Cellosolve Acetate 451. 4-Ethoxy-2-Nitro-Aniline C2H5OC6H3NO2NH2 452, Ethyl Acetanilide CH3CONiC2HsMCeH5) Waste NFPA Dl*-, TLV 704M System p" ^PPM^"1--------------------------------------------- Vap. Ft. Pt. 1 f*dur* , Img/MV Health : 1^** VI) Fire React. Sp. Dans. C Gr. (A.r=1> (F) | I 16 ! | __________ i__________ j __________ 20 1 0 1 i__________ i__________ ___________ 1 2 ; 0 __________ 94 5 62 52 (126) 453 Ethyl Acetate 18 400 : 1 3 0 .90 ' 3.04 -4.4 CH3COOC2H5 1i; 1|| (24) __________________________________________i--------------- U-----------J__________ 1__________ 1__________ 1__________ I_________ 454 Ethyl Acetoacetate ' 18 1 !i 2! 2 0 1.03 4 48 ! 84 CH3COCH2COOC2H5 .i L _ _ _ _ _ _ _ _ _ _ _ _ _ _ ___________________________________________ i__________ ....... . 1. 1 1 (183)oc 455 Ethyl Acrylate CH2CHCOOC2H5 18 25 Skin 2 3| 2 1 .92 3.5 16 (60) ____ L____ ___ Ethyl Alcohol, see Ethanol Igmt, Tamp. C <F) 427 (800) 273 (524) Flam. Limits % 2 1S-9 1.8- B.P, 5C (F) M.P. C <F) Sol. in H2O g/IOOg 113 (235) 258 (496) 54 (129) insol 77 (171) -84 (-119) 7.520 181 (358) <-80 (<-112) 1312 100 (212) <-72 (<-98) sol Other Solvents ch|. ale ale. ale., bz ale. Ethyl Aldehyde, see Acetaldehyde 456. Ethylamme C2H5NH2 7a 457 Ethyl sec-Amyl Ketone CH3CH2CHCH3CH2COCH2CH3 18 10 25 3i 4 __________ 1__________ 0 .80 1 56 __________ 1 <-18 (0) 384 (723) 85 57 (135)oc 3.5-14 17 (63) -81 (-114) 161 (322) w insol. ale. ale. r Misc. Rf i i -3 1 BDH, NTTC MCA BDH BDH, NTTC. MCA 1 1 rl 1 1 i BDH, NTTC. MGB 3 3 458 N-Ethyl Aniline C2HsNH(C6H5) 459 Ethyl Benzene C6H5C2H5 5 3 2 0 .96 4.18 85 (185)oc 205 (401) -64 (-83) insol. flic. 18 100 2 3 0 .9 3.7 15 432 1-6.7 136 -95 .01 '5 ale (59) (810) (277) (-139) BDH BDH 3 3 3 IE 54 CMA 046035 SUBSTANCE/FORMULA 460. Ethyl Benzoate C6H5COOC2H5 Ethyl Bromide, see Bromoethene 461 Ethyl Bromoacetate CH2BrC02C2H5 462. Ethyl Butyl Ketone C2H5COC4H9 463 Ethyl Butyrate C3H7CO2C2H5 464 Ethyl Chloride CH3CH2CI 465, Ethyl Chloroacetate CICH2COOC2H5 466 Ethyl Chtoroformate CJCO2C2H5 467. Ethyl Crotonate CH3CHCHCO2C2H5 468. Ethyl Cyanoecetate CNCH2CO2C2H5 I Ethyl Cyanide, see Proptomtrile 469 Ethylene H2C=CH2 Waste | Dis- TLV posat Pro- (ACGIMI I PPM rv,,!^3> NFPA 704M System Health Fire React. 18 I Ignit, Vap. FI. Pt. * Temp. Flam. B.P, Sp. Dens. C C Limits C Gr. (Air=1) (F) F) % lF) M.P *C (F) Sol. m H2O g/l00g Other Solvents 5 17 96 (205) 213 (415) -35 (-31) ale. 1,51 ; 58 48 (118) 159 (318) <-20 (<-41 46 (115)oc 148 (298) -37 1-35) 18 26 463 121 -97 6825 ! ale (79) (865) (250) (-143) \4b ,92 I 2 2 -50 519 12 -139 45 ale. (-58) (966) (54) (-218) 4b 1.26 ! 4,3 66 144 -27 (150) (291) (-17) 4b 1.36 3.74 16 95 --81 dec. be., ! (61) (203) (-114) dec. ale. 18 .92 3.93 I 2 143-7 j 45 insol (36) (289-96)! (113) j 1.06 3.9 110 (230) 206 : -23 (403) (-9.4) 2^5 18 450 -104 26 si, sol,, ale (842) (-155) (-272) PAGE 55 4T .Sg CMA 04603S SUBSTANCE/FORMULA A ^^^thylene Chlorohydnn Waste Dis posal Pro cedure (See VII TLV IACGIH) PPM (mg,M ) NFPA 704M System Health Fire React, 4a 5 3 2 0 Skin 471 Ethylene Diamine NH2CH2CH2NH2 7a 10 3 2 0 472 Ethylene Dibrgmjde BrCH2CH2Br 4b 25C 3 473 Ethylene Oichloride CICH2CH2C! 4b 50 2 3 0 474 Ethylenedmitnle Tetradetic Acid DipotasStum Salt (EDTA) K2^-'10,^9^2h19 4c 475 Ethylene Glycol CH2OHCH2OH 18 1 1 0 ----------------^ Ethylene Glycol Monobutyl Ether, see Butyl Cellosolve Ethylene Glycol Monoethyl Ether, see Cellosolve Ethylene Glycol Monomethyl Ether, see Methyl Cellosolve J ---------------------------------------------------- h Ethylenimme, see Aziridme 476 Ethylene Nitrate C2H4IONO2J2 ; 4a ' r ----1------------- 2j 3 477 Ethylene Oxide (CH^O 15 I 50 2 2 4 3 Sp Gr, 1 21 Vap Dens. <Ar1) 2 78 FI, Pt. SC <F> ; ignit Temp. C (5F) i 60 425 (1 40)oe ] (797) Flam, Limits 49-15.9 B.P aC <F) 128 (262) M,P C <FI Sol, in h2o g/IOOg Othet Solvents -69 (-92) ac ale ,90 2.18 2 07 43 (110) 6 48 117 8,5 V. sol. alc- (243) (47) __________ !" 131 9,3 sl, sol. ale. (268) (48) 1,26 34 73 (55) 473 6 2-75,9 83 (775) (182) . -36 1 -32) . si. sol. ale 1 1 11 2.14 111 (232) 1 413 3.2(775) 1 198 (388) -13 (8.6) 1-- w '-- alc., ace Misc. Ref -- Al A SDH,Mce --BDH, NTTC BDH BDH, ' Al A, NTTC MCA CED BDH, NTTC 1 1 ! 1 1 1 A I 1 1 f 1 1 1.49 5,25 114exp. -20 (237) (-4) insol .87 1 49 \ <-18 429 3-100 11 -111 sol. i l< 0) (804) (5D (-168) alc. ale I A!A, MCA I A I 47$ 481 48* 48: 484S- 486 4 CMA 046037 SUBSTANCE/FORMULA Waste , Dl*- p" NFPA TLV 704M System (App,J, ^ - ^ --- -------------------- P478 Ethyl Ether C2H5OC2H5 cedure {mg/M'^) | 1 (See VI) , ------------------- -----------: ! 15 400 ;1 Health 2\ ' Fire 4 React. 1 Vep. $p Dens. Gr. | (Air^l) FI. Pt. *C (F) Iflnit. Temp. C (F) Flam Limits % 71 j 2 55 -45 (-49) 180 1.85-48 (356) B.P. *C (F) 34 (94) Ethyl Ethynyl Ether, see Ethoxyacetylene 479 Ethyl Fluoride ch3ch2f i ! i .. __________ ,________ ____________ ! ' 4b ' l 1 - i 82 1.66 j 11 I __________ L_ j -38 1 (-36) iSO Ethyl Fluoroacetate FCM2C00C2H5 J 4b - 4 i1'j -j - i 3,7 ! jii! - 116 (241) M.P. C <F) Sol in h2o g/IOOg Other Solvents -123 7,520 (-189) b2 -143 19814 (-225) ale Misc. Ref. A! A, BDH,MCA 481 Ethyl Formate HCOOC2M5 482 2-Ethyl Hexanol C4M9CHfC2H5)CH20H 483, Ethyl Iodide c2h5i 464 Ethyl Lactate CH3CHOHCO2C2H5 Ethyl Malonate, see Diethyl Malonate 18 100 1 2! 3 !1 i ........ ................... i .... ___ 1 18 1 '2 2: j!| 0 .95 2.55 -20 455 2 7-13.5 54 -79 111S ! ak I (--4) ! (851) (129) (-110) i 1 0 ! .83 1 4,49 84 j ; j (184) 180-5 <-76 insol. (356-65) 1-105) ale 4b { - ! i 18 - 1 i __________ L_ ;2 1 i 2 | ! L 2j - ; 1 95 54 __________ i__________ i__________ ;__________ i__________ 2 0 1 04 ' 4 07 46 400 1.5-30 i (115) ' 1752) @212 F 72 (162) 154 (309) __________ i__________ i__________ 1__________ -105 420 (-157) ale. ale j SDH BDH BDH BDH Ethyl Mercaptan, see Ethanethiol 485 M-Ethylmorpholme C6h13NO 486. Ethyl Nitrite C2H5ONO !..... 5 20 Skm 2 4a 2 3 4 ' 0 92 4 00 32 (90)oc 138 I2S0) . ale. 4 90 2.59 -35 90 4.1-50 17 (-30) (194) (63) dec, ale PAGE 57 CMA 046038 Waste Dis posal Pro ft___________________________________ cedure j (See VI) PP7 N-Ethyl-N-Nitroso-N-Butylamine c6h4n2o 7a TLV (ACGIH! PPM (mg/M'M 1 NFPA 704M System Health Fire l CAR React. 488 N-Ethyl-N-Nitrosovinylamine C4HSN20 7a CAR 489, Ethyl Oxalate 'CQOC2H5J2 18 3 2 0 Vap. Sp Dens. Or. ; (Air=1) FI Pt. C taF) Ignit, Temp. C in Flam. Limits % B.P. C 1F) M.P, C lF) Sol. in H2O g/lOOg Other Solvents 1 08 , 5 04 L___ _____, 76 (168) - 186 (367) -41 (-42) si sol ale. r Misc. Ref n i 490 p'Ethyl Phenol CH3CH2C6H4OH 18 491 2-Ethyl-3-Propyl Acrolein CH3(CH2)2CHCX2H5)CHO 2 492 Ethyl Silicate (C2H5US1O4 IS 493 Ethyl Vinyl Ether CH2CHOC2H5 494 Excelsior 495, Fatty Acids 15 l. 1 24b 496, Ferbam FeiCH3)2NC52! 3 13 497 Ferric Chloride i60',l FeCI3 1b 498 Ferrosihcon Fe - Si f 26 499, Ferrous Ammomum Sulfate FeN2HgS20g 6H2O it 58 1 11 1 22 100 ! 2: 2 24 ! (15) 2 1 !2 ( J 0 10 104 (219) 1 85 4.35 68 (155) 219 (426) 45 (113) si sol ________ _ 163 (325) <100 msol 212) a(c , bz , CS2 ale, 0 .93 7 22 52 (125) IIQsubl dec, 1(230) si sol . bz BDH 2 75 2.46 <-46 202 1.7-28 36 -115 si sol ale. l<-50> (395) 197) (-175) --------------- 1-------------------- i i NTTC _________ 1. ____________ 1 dec, 2.80 __________ l J !i ii - 306dec , (583) 74 ale , MeOH 5.4 msol. NSC ! 1 86 ' : - .1 100-10 dec. (212-3Q) J26.920 1 1 1 1 1 I 3 3 3 3 3 3 3 r* CMA 046039 r UBSTANCE/FORMULA Ferrous Chloride FeCl2 tQl Ferrous Sulfate FeS04 H20 Waste D*s> posel ; Pro- ; endure NFPA TLV 704M System ! (ACGIH):______________________________ i PPM I |mg/M3l j Health F.re React --------- --1----- ' ~ ~T 1 | I I Ignit. , Vap FI. Pt, | T$mp. Flam. Sp. Dens. C Limits Gr. I (Air=1) ! (F) (F> % 3.16 B P. 4C <5F) 1026 (1879) M.P, cC (F) Sol. in | HtO Other g/IOOg Solvents 670 64,4^0 (1238) Mise. Ref. 502. Ferrovinsdium Dust FeV 503 N*2'Fluorenylacetemide Ci5H13NO 504, Fluorine p2 506. Fluoroacetic Acid CH2FC00H 192 (378` -188 , -218 (-307) ' (-360) 165 (329) 33 (9D sol h . ale AI A MCA, MGB, NASA 506. Fluoro-Borie Acid HBF4 507. 4-Fluoro-4-Biphenylamine Ci2HiqNF Fluoroethane, see Ethyl Fluoride 508. Fluoroethyiene c2h3f 2 6-21 7 -51 ' -160 1 msol (-60) (-256) Fluorohydnc Acid, see Hydrofluoric Acid 509 2'-FluorO'4-Phenylacetanilide C^H^NOF PAGE 59 CMA 046040 SUBSTANCE/FORMULA Waste D,s' NFPA TLV 704M System fA^HI: - ij ! 1 ^ j^ , |dur* i (mg/M3) j Health i (See VI) Fire RlO 2' F|uor0-4F`Phenyl*cetanilide 6 - CAR Ci4H12NOF ( _________________________________!__________ j__________ !__________ ____ React, \ Gr, j (Air^l) j -1 11 i____ ________________i__________ FI. Pt. C (*F) Iflnu. Temp. C <F) Flam. Limits % 511, 4"'-Fluoro-4`*Phenylacetamlide , C14H12NOF 61 ! < < CAR j -i | 512 Fluoro-Silicic Acid HjSiFg 513, Fluorotnchloromethane CCI3F 24b 1!1 ] 26 1000 : 3 1: |i 1 1,49 1 fir __________ B.P. C (F) 24 (75) M.P. C (FI Sol. in H2O g/IOOg Other Solvents dec. sol. -Ill insol, (-168) ale. 514 Formaldehyde hcho 515 Formalin (39% Formaldehyde Methanol Free) 516 Formalin (37% Formaldehyde15% Methanol) 2 5C 2 4 0 , ,82 f 1.08 1 430 (806) 7 0-73 -19 (--3) -92 (-134) ;ii!___________________________________________________________________________________i L. . .______ . j!: !!! ;2 5 2 t'j 2 ' 0 .82 i ' ' 85 (185) j - 101 (214) ;1r :!:1 ..................j......................................................................... ! sol. j2 ' | 5 21 -, - 1 50 ! !; (122) [ I :j 101 (214) ale. Misc, Ref, BDH BDH, NTTC, MCA, NSC 517 Formamide HCONH2 Form-Dimethylamide, see Dimethylformamide 1 20 ; 22 1 M3 ' i! !1 155 i : (310) i |i 21 Idee. (412) l_.......... 2.6 (36) <w ale 518. Formic Acid HCOQH j 24a 5 3 2 0 1.22 1.59 69 601 18-57 101 8.2 00 ale. j (156) (1114) (213) (47) BDH 519 Fumarie Acid hoocch-chcooh \ 24a j __________________________________________1__________ _ 520. Furan ^ C4H4O 1 18 | 1 >GE 60 1 1.64 1 4 1 .94 2 35 <0 (< 32) 290subl si sol. (554) ale. 32 -86 tnsol (90) (-123) sic [ 1 j CMA 046041 SUBSTANCE/FORMULA ' Wa5t | D,sj I I 521 Furfural j cedure ; ; (See VI); 2i C4H3OCHO 1 __________________________________________,,____ . .) TLV NFPA j ' 704M System | 1 ----------------------| Sp j * | FI* n#ajt^ Ftre 5 1i 2 React. 1 Gr. 1 16 {Air*!) 'I ! 3 31 (aF) 60 Skirt :1 11401 ........... J__________ |__________ |__________ j__________ ___________ |__________ lgnn. Temp, C ("FI 316 1600) Flam, Limits % 2.1- 522 Furfuryl Alcohol 18 1 50 1 2' 1 i 1 13 1 3 37 75 C4H3OCH7OH | ! , : H67)oc _ ____________________________,1; .....................................-..(_______________________________ __________ ji 491 (916) 1 8-16 3 S.P. C <F) 162 (324) 171 (340) M.P. C (F) -37 (-35) -31 (-24) 523 Gadolinium Gd 27k ! -.79! 1 s ~3000 1312 <" 5432) (2394) Sol. m H2O g/lQOg 9 113 insol Other Solvents ale ale 524 Gallic Acid C5H2(OH)3COOH | 24a j ' ! 1 6s f ! ,; . 253dec. (487) ,13 ale,, ace. Misc. Ref. SDH, NTTC CED 525 Gallium Ga 526 Garments, Contaminated 527 Gasoline c5h12 10 C9H2O 528 Germane Ge H4 529 Germanium Ge 530 Germanium Dioxide GeQ2 531 Germanium Hydride Ge2Hg 532 Germanium Tetrachloride GeCl4 27k 1 . [ 5 90 ! i ! !1 2403 (4357) 30 (86) L............ msol, r-- 29 __________ ,__________ ;_____ _____ _j_____ _____________________ ____ ...........r 18 1 3 0 8 ' 3.0-4 0 -43 280-456 1 4-7 5 38-204 | (-45) (536-853 (ioo-4oo)| i NTTC 26 |2 31 j 3 43 __________ !_____________________;__________ !__________ i__________ '' 27k | j j 27k | 17 | 2. 2i i 5 35 , ! -' 1 2 -j 6 24 - ! ! i i 1__________ __________ __________ __________ __________ __________ !1 6.74 | 1,5 1 11b 3 1 88 ! ! I 1 i 1 1 ' - . -90 (-130) -165 (-265) 2700 958 insol 1 - | AlA 14892) i (1756) ' ! ----------------1----------------1--------------- ---------------------;-------------------------- ! 1100 i msol 1 ; (2012) j 1 Al A 1 29 (84) 86 (187) -109 (--164) -50 (-57) dec, dec !--------------------- 1-------------------------- | j AIA 1 1 ! ale i AIA PAGE 61 CMA 046042 JBSTANCE/FORMULA Glutaraldehyde OCH(CH2l3CHO Waste , Dij ' posal , Pro- ! eedure MSmVI) TLV (ACGlH) PPM 1 (mg/M`)! * NFPA 7Q4M System ___ Health Fire 12 534 Glutanc Anhydride C5H63 535 Glycerol CH2QHCHOHCH2OH 536 Glycidol C3H602 24a ' IS 15 11 -- 50 3 1 0 537 Glycolic Acid HOCH2COOH 24a 2 ' 538 Glyoxal OCHCHO 2 7\ 538a Gold 27a 539 Grain Fumigants (Agricultural Insecticides! 7b -- 540 Greases 18 \ 1 1 o41 Guaiacol H0CgH40CH2 15 2 2 542 Hafnium Hf 543 Helium He 27k ( 51 i 26 ! 544 Heptachlor c10ri5cl7 4b ( 5) Skin 3 r Ignit, VP- I FI. Pt. Temp, Flam, B.P. Sp. Dens, C C Limits "C <Air=1} , (F) ("FI % lF) M.P aC lF) Sol, in : H2O 1 g/IOOg ' Other Solvents Misc. Pet 72 3 4 , 1 26 ! 3 17 160 ; (320) 1 12 2 15 393 (739) 1,14 i , 188dec (370) i* ale 303 (577) 290dec (554) 18 (64) 00 ale , CS2 INTTC IBOdec, (320) dec 79 (174) Tfl ale , bz | _______________L______________ ___ sol ale 50 (122) 15 (59) V sol ale BDH 1 J 5 J I l M 3 1 13 13,31 13 1 58 122 140 (50 60} oc 82 (180) 1 20 (68) 1: J ii i_ . 205 (401) 28 (82) 1 715 | O O 1 in cn 2150 (3902) msol <N 269 (-452) -212 (-458) @263tm 9 95 (203) msol ale die. NTTC NT7C CG A 3E 62 CMA 046043 SUBSTANCE/FORMULA Heptane CH3(CH2)5CH3 2-Heptanone, see Methyl Amyl Ketone 3-Heptenone, see thyl But'/I Ketone 546. n-Heptylamme C7hi5NH2 547. Hexachlorobenzene C6CI6 Hexachlorocydohexane. see Lindane 548. Hexaehloroethane CI3CCCI3 549 Hauchioronaphthalene ClOH2cl6 550- Hexafluoroethane C2F6 551. Hexamethylenetetramine (CH2)6n4 552, Hexene ch3(Ch2uch3 553. 1,6`Hex*nedtamme NH2(CH2)6NH2 w.,te D'*' , j pr0. I|-v , | ,ApmM' NFPA 704M Syxtflm j j (SmVD i (n,/MJ| [ H,`l,h Flre R**c'- j Sp Gr' Vap. Dens, (Air=1| FI. Ft. C leF) Iflnit. Temp. aC (F) Flam. Limits % B.P. C (F> 18 | 500 1 3 0 .68 3.45 __________ i__________ __________ -4 (25) 223 1.2-6 7 (433) 98 (208) M.P. C lFI Sot. in HjO fl/IOOfl Other Solvents -91 insol. (-132) ale. Mi*. Ref. BDH __________ 1__________ 7a 2 2 0 .77 4.0 54 (129)oc 4b 1 1 1.57 9.8 242 (468) 158 (316) -23 (-7,6) si sol. ale 322 (612) 230 (446) msoi. bi. 26 1 2 2.09 186 (367) insol. ale. 4b (.2) 5km 3 26 0 1.59 -79 -94 (-110) (-137) insol, $1, sol., ale. 7a 2 1.33 250 (482) 280subl, v. sol. (536) ale., ace. 18 500 3 0 .66 2.97 -22 261 1.1-7.5 68 -96 insol. ale. (-7) (502) (154) (-141) BDH, NTTC 7a 2 204 (399) 42 (108) v. sol ale , b2 PAGE 63 CMA 046044 ^ SUBSTANCE/FORMULA Hexanedioic Acid, see Adipic Acid Dis posal Pro cedure (See VI) TLV IACGIHI PPM Img/M3) | NFPA 704M System Health Fire React. |! Ignit. Vap. FI. Pt, Temp. Flam. B.P. Sp. Dens. SC C Limits C Gr. (Air=1) lF> <F] % (f) M.P. C TO Sol. m H2O g/100g Other Solvents Misc. Ret, Hexinoic Acid, see Caproic Acid | 554 m-Hexenol CH3(CH2)4CH20H 2-Hexanone, see Methyl Butyl Ketone 18 - j 1 i 555. 1-Hexene H2C=CH(CH2l3CH3 IS 1 556 2-Hexene CH3CHCHCH2CH2CH3 18 1 Hexone, see iso-Butyi Methyl Ketone 2 0 81 1 3.52 ! 60 293 ; ! (140) (559) 158 (316) -45 (-49) sl sol ale , bz. BDH 3 0 7 2.97 <-7 20) 3 0 68 2 92 i <--7 20) __________ 1.2-6.9 63 (145) -139 msol. (-218) ale 69 (156) -146 msol (-231) ale 557, sec-Hexyl Acetate (CH3)2CHCH2CH2CH2OOCCH3 18 50 2 0 ,86 4 97 1 45 ; (113) ; Hexyl Alcohol, see m-Hexano! 558 Hexyl Amine CgH13NH; 7a 2 3 0 76 3 49 29 (84)oc 141 (286) -64 (-83) msol. ale. _________________ 129 (264) -19 (-2 2) __________ !____ ________ _ 1 5l. SOI. ale, 1 ; 559 Holmium Ho 27k 560 Hydracrylic Acid-(3-Laetone C3H402 1________________________________________________ c!GE 64 24a CAR 4 2 8 80 1 15 25 74 (165) 2600 (4712) 1461 insol. (2662) 2,9- 155 (311) -33 dec, (-27) Ch|, SUBSTANCE/FORMULA 561- Hydrazine H2NNH2 Waste O'* posal Pro* ! TLV ! f(ACGJH); PPM I {mg/M3)! (See VI) l NFPA 704M System Health Fire React. I Skin 562. Hydrazoic Acid hn3 563 Hydrazine Salts and Solutions 564. Hydriodic Acid HI 665 Hydrobromic Acid HBr 566. Hydrochloric Acid HCI 567, Hydrocyanic Acid HCN 568. Hydrofluoric Acid HF 569 Hydrogen H2 Hydrogen Bromide, see Hydrobromic Acid Hydrogen Chloride, see Hydrochloric Acid Hydrogen Cyanide, see Hydrocyanic Acid 24b I 5C 10 Skin Vap FI. Pt. Igmt. Tamp. Flam. B.P Sp. Dans. C Gr. (Air=1> (F) %C <F) Limits *C (F) 38 (100) Varies with Surface <74- 518 F) 4,7-100 113 (236) exp. 37 (99) M.P. C (F) Sol. in H7O fl/IOOg Othar Solvents 1A (34) Misc. Raf AI A BOH, MCA, MCB, NASA -80 -112) -35 (-31) @4 atm -51 42.5 (-60) -67 -87 I--89) (-125) 1.3 none -85 (-121) -115 83 (-175) (0) ; (1000) 26 (79) -14 (6.8) 20 -83 (68) (-117) 585 1 4*75 11085) ` -253 -259 2 1 (-423) <-4341; aia, boh, ISITTC MCA, MGB AIA, BOH, MCA, SOS. MGB, NSC ,CGA, MAS* PAGE 65 CMA 046046 SUBSTANCE/FORMULA Wastt Dls?TM` i TLV !IA$,H'' NFPA 704M System | ! Sp ; j (S vi) ^ i health Fire React. j Gr. (Air^l) V....... ........ ~~ ~ r i ' : r1 nTM ~ Hydrogen Fluoride, see Hydrofluoric Acid _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ !_ _ _ _ _ _ _ _ _ _ _ _ _ 1.. .. .. .. .. .. . . . . . . . . . . . 11 | -_ _ _ _ _ _ _ _ _ _ _ _ _ ;_ _ _ _ _ _ _____ i_ _ _ _ _ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ _ _ _ _ _ _ Hydrogen Iodide, see Hydnodic Acid !jj j11 1 j FI. Pt. C <n Igmt. Temp. C (F) Flam. Limits % B.P. C (F> M.P aC (F) Sol. in H^O g/IOOg Other Solvents Misc. Ref 570 Hydrogen Peroxide H2C>2 (90%) 22a [| 1 20 3 ! 1.39 ! 140 (284) MCA 571. Hydrogen Peroxide (27-52%) I 572. Hydrogen Selemde H^S | 573 Hydrogen Sulfide h2S 574 p-Hydroqumone C6H4(OH)2 575. Hydroqumone Monomethyl Ether CH3OC6H4QH 576 Hydroxydimethylarsme Oxide ECH3)2AsOOH 577 Hydroxylamme nh2oh 22a 1 2 O' 1 ' 1,39 ij 107 (225) for 35% -11 (12) :' i 27e 05 1 3! 31 - : 2.00 2.8 I -j j 1: -42 (-44) -64 (-83) i1; 23 io S 3; 4; o 1 i,i9 i2 i 260 (500) 4.3-46 -60 -83 (-76) (-117) i1 18 (2) '2 | 1: 1 1.33 3.8 165 . 285 171 1'; j ! (329) (545) (340) !1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _________ _, .; I i ------------------- -------------------- 1 15 i 21 1! : 1.55 | - 131 421 | 246 54 'll!, (268) 1 (790) (475) (129) :i1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ii_ _ _ _ _ _ _ _ _ _ _ _ _ 7b 3, -; - _ _ _ _ _ _ _ _ _ _ _ _ _ i__________ i__________ i__________ 200 (392) 7a 1 3 3 1 20 129e*o. (264) 56 (133) 34 (93) oo BOH, MCA 3774 j CS2 1 437 ale , CS2 AIA, MCA MC8, NSC sol. 1 ale i sol. ale., bz. v sol ale. sol. ale , MeOH 578 Hydroxylamine Hydrochloride NHjOH.HCI 7a Hypo, see Sodium Thiosulfate ft____________________________________ i 23 1 67 dec. 153 (307) 8317 ale,, MeOH ---------------------1- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - i E 66 CMA 046047 SUBSTANCE/FORMULA k | j 2.2'-lmnodethanol, see Diethanolamine WaiW D,s?r0. NFPA 1 TLV i 704M System <ApM ':--------- | 1 , cdur .img/M3): Hsilth { (See VI) , Fir Rmt ! | ' i`i 1' Sp. q. Gr. | (Air=1l 1 l FI. Ft. *C (6F) Ignit. Temp. C <F) Flam. Limits % B.P. C (F) M.P, C (F> Sol. m H2O fl/lOOg Other Solvents Misc. Ref. 579 5-lndanol cgHio ; IS -1 -1 1 - ! 255 (491) 55 (131) sl. sol ale 580 Indium in 27k , ;. 581 Industrial Gas 1 18 (Liquefied Hydrocarbon Gas) 582. Iodic Acid HIO3 1 24b j 32 J 7.3 :,! _____ l1_1:___________________________________________ _______ _ <. 1 i > -108 1 (-162) i 32 463 _ _ _ _ _ _ _ _ _ _ 1_ _ _ _ _ _ _ J_ _ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ _ _ _ 2000 (3632) 155 (311) insol. IIQdec, 286'S (230) ale NTTC 583 Iodine '2 584, Iodine Chloride ICI 585. iodine Pentsfluoride "=5 12a 1C 21 3 I' ! 493 ! ; j ' ! '1 1 184 (363) 113 (235) .0320 1 alc,,b2,, , cs2 ,_______________________________ !:1________ _ 1.1 32 3 18 1 1 1 97 14-27 dec. ale i ,; (207) (57-81) __________ i_ _ _ _ _ _ _ _ _ _ _____________________ __________ 3i ' 3 3,75 'j ` ' 1 98 (208) 9.6 dec. (49) BDH,NSC BDh mgb 586, Iodine Trichloride 1CI3 587 lodoacetic Acid C2H3I05 21 ; 1 j 1 1 4c 31 1 3.12 77dec. 101 dec. alc.,b2, BDH (171) (214) @16 atm, __________i______________ dec 82 sol. (180) ale lodoethane, see Ethyl iodide iodomethane, see Methyl iodide i i PAGE 67 i CMA 046048 SUBSTANCE FORMULA 3-lodopropene, Ally I Iodide 588 Isoprene CH2C(CH3)CHCH2 Isothiocyamc Acid, see Methyl Isothiocyanate 589a Jet Fuel JP-1 589b Jet Fuel JP-4 589c Jet Fuel JP-5 539c Jet Fuel JP-6 590 Kerosene Waste Dis posal Pro cedure (See VI) TLV (com> PPM (mg/M^), NFPA 704MSy,,,nl Health Fire f 591, Ketene ch2co 592. Lectonitrile CH3CH(OH)CN 593. Lamps, Fluorescent 594 Lanthanum La t 68 Ignit. Vap FI Pt Temp. Flam, B.P, Sp. Dens. C Gr. (Air=1) (F) %C (F> Limits C (DF) M.P C (CF) Sol. in h2o g/IOOg Other Solvents Misc. Ref, r -54 -65) 220 ! (428) ! 34 -147 (93) (-233) 35-63 228 (95-145) (442) <-46 (<-5Q) -23-1 I (-10-30) 242 (468) <-46 (<--50) 35-63 1 246 I <95-145)1 (475) <-46 - 50) .8 I <1 38 (100) 224 (435) 121 ! <-46 (250) i -50) 81 ; 45 1 ! 38-66 229 1(100-150) (444) 7-5 170-300 <-46 (338-572) (<---50) -56 -151 (-69) (-240) dec. 77 (171) 182dec. -40 (360) (-40) 3470 (6278) 920 (1688) V =5 CMA 046049 SUBSTANCE/FORMULA , Lacquer Diluent Latex 597 Laurie Acid CH3(CH2hoCOOH 598 Lauroyl Peroxide (Ci iH23CQ)202 599. Lead Pb 500. Lead Acetate Pb(C2H3O2)2'2H20 601. Lead Arsenate PbHAsCU 602 Lead Carbonate <PbC03)2 Pb(OH)2 603 Lead Nitrate Pt>(NQ3)2 604 Lead Oxide PbO 605 Lead Thiocyanate Pb(SCN)2 506. Ligroin 1 Waste Dis* j TLV posal (ACGIH) Pro- j PPM ; fpdUw.\ i <ftig/M3} (See VI), NFPA 704M System Health Fire React. ; Vap. [ FI. Pt. Sp, Dens, i SC Gr. (Air=1) | (F) Igrnt, Temp. C (F) Flam, %Limits B.P, C (F) M P. *C (F) -11 232-88 1,2-6 (12) (450-5501 88*107 (190-2251 Sol. m H2O g/IOOg Other Solvents Misc. Ref. (.2) 27d ( 15) 3 25 <22 72) 299 (570) 48 (118) ale,, b*. 49 (120) insol. 1744 (3171) 327 (621) 75 (167) 4420 720dec. (1328) 400dec. (752) 470dec.! 38u (878) ' (1630) ! BDH, MCA 190dec, 1374) PAGE 69 CMA 046050 SUBSTANCE/FORMULA Limonene, see Dipentene see p-Moutha-1,8-Diene 607, Lindane C6H6a6 608. Liquefied Petroleum Gas (LPG) 609 Lithium 610, Lithium Aluminum Hydride LiAIH4 611, Lithium Borcihydride UBh4 612 Lithium Carbonate L12CO3 613, Lithium Hydride L'H Waste NFPA Dls\ ,AIhyu. 704M System tgmt. ; AppM !---------------------------------------------- Vap. FI. Pt, Temp, Flam. B.P. , cadura i (mg/M3) Health j (See VI) Fire React, Sp Dans. C Gr. (Air=1) (F) aC (F) Limits % C (F) M.P. C lFI Sol. in HjO g/IOOg Other Solvents Misc. Ref 4b (.5) 18 1000 3 ! 17 - 1 | 17 ; ;: : 11 ; i; ; 1| i 17 (.025) ', __________ l________ ,, 3 ! 1 87 - 3 !, - .1 . '`; 288 (550) . 157 insol, (315) <-46 <<-501 1 3 2 , 1 ! 1 I 2 1 53 1 -| j -1 j1 ! I_________ [___________ __________ 1_________ | !1 1! 2 1 92 -, 66 - 2 11 4,2 , ,82 - 1 ; ... , ! innL Spontar,-; eously ! 1337 (2437) 179 dec, (354) I25dec dec. (257) __________ __________ _ 284 1543) 1 1 I310deei 723 !(2390) | (1333) dec, sl. sol 1 680 dec. ,12S6> ace., bz. NTTC BOH, NSC BDH,NSC BDH, NSC BDH 614 Lutecium Lu ' 27k 2 9,84 ! ____________ :_____________________ ______________________!__________ :_____________________ :__________ 1____ ' - ' 3327 1 1652 - ! (6020) 1 (3006) .J........ .................. ...............................1.......... j ,. 615 2,6-Lutidine (CH3)2C5H3N 616 Magnesium Mg 617 Magnesium Chlorate Mg(Cl03)2 6H2Q 7a j| -; - ,92 3,7 38-46 ! j (100-15)1 1 27a 1 - 1 0 !; :j1 1 i 1 12a j - ; 2 ' 3 1 1 [| 2 i 1,74 |' - 1.80 |, i -| ; '1 - ; - 14a ! -6.6 00 si sol , ale. ! BDH (291) : 120) ; | __________ :__________ ;_________ 1______________i______________ 1107 651 (2025) (1204) dec ^ 12CkJec. 35 (248) (95) 12910 ale j 1 1 \ AIA t - * I >/ !! (! * 4 * CMA 046051 SUBSTANCE/FORMULA 0618 Magnesium Chloride MgCl2 619 Megnesium Nitrate Mg(NC>3)2 2H2)0 620 Magnesium Oxide MgO 621 Magnesium Perchlorate Mg(Cl04)2 622 MalathiOn CiOHl9^6pS2 623 Maleic Acid HOOC(CH|2COOH 624 Maleic Anhydride (C0CHI20 625 Manganese Mn 626 Manganese Sulfete MnS04 627 p-Mentha-1, 8-Diene ClOHl6 Mercaptoacetic Acid, see Thioglycolic Acid 628 2-Mercaptoethanol HSCH2CH2OH Waste , D.S-- pose! Procudurs (See VI) 11 tlv (ACGIH) PPM (mg/M'l1 NFPA 704M System Health 1 Fire React. 1 : Vap, Sp Dens. | | Gr. (Air=1l ; ii, 2,32 ! FI. Pt. C (FI Ignit, | Temp. , C I (FI Flam Limits % : | B.P. C (F) ! M,P. C (FI i Sol. *n H20 ' I 9/IOO9 I Other Solvents 1412 (2574) 708 (13061 5420 ^------------ -- 11 1 0 1 2,03 :i 330dec 129 sot ale (626) (264) i 26 (15) 2 3 65 3600 -v2600 (6512) (4712) si.sol 12a 7b ! 24a 24a ' 27a 1 11 f 1 18 13 1 (15) ` Skin 3 2 1 25) : 3 (5)C 2 2 i , i 1 2 ;0 1 26 1 1 23 1 ; 1 59 | 4 0 -i 1 1 ,9 34 21 ] 7,20 i 3 25 ;2 |0 j........... 1 1 3,84 i 7,4 i1 1| ! 102 | (216) 477 (890) 1, 45 (113) 237 (458) 251dec (4841 __________ 156 (313) (3>,7mm 29 (37) SO25 si sol I35dec (275) v sol ale ale bz ale ace. ether 1.4-7.1 202 (396) 58 (127) dec ace 2030 (36861 ~1 1260 dec (2300) S50dec (1562) 700 (1292) 525 ale AIA MCA 1 | 7-6 1 170 (338) <60 l<140) insol ;1 :2 i 1 i 1 | 1 14 I 2 69 74oc (1651 157 (315) sol ale PAGE 71 CMA 046052 SUBSTANCE/FORMULA F Mercuric Chloride HgCI2 630. Mercury Hg Waste , Dis- gTM' . TLV ! NFPA 704M System <A^,HI------ -- ------------ ------------------ i fsmVI) 1 | Hmlth Flr' RMCt- Sp. Gr. r in 27b 3 1- i - 5.44 __________ i__________ !................- 27b l 1) 5km 3 ; i- : 13.6 - >o< FI. Pt. C <F) Ignit, Temp. C lF> Flam. Limits % B.P, C (F) M.P. C (F) Sol. m HzO g/IOOg __________ 304 (579) 277 (531) 357 (674) -39 (-38) 69^0 inSol, 631 Mercury Compounds (organic) 27b ' (01) Skin 631a Mercury Compounds (inorganic)j 27b ------------------------ ----i--------------- 1-- 632 Mercury Fulminate 27b i HgC2N202 | 633 Mesityl Oxide C6H10O 18 25 3 t ,____________________ __________ 1 1 i i 33 4 4,42 . 3 !3 ! 0 .86 3.5 31 344 (88) (652) exp. si. sol. 130 (266) -59 (-74) sol, 633$ Metal Scraps 26 i 634 a-Methacrylic Acid CH2C(CH3)COOH 635 Methane Ch4 636 Methanesulfonic Acid CH4Q3S Methanethiol, see Methyl Mercaptan 637. Methoxychlor (DMDT) (CH30CeH4)2CHCCI3 24a r 18 i 4c ; ' j ! 4b 322 1 40 __________ __________ (15) 1 1,02 1 ; 77oc ! 0711 42 . 6 1 48 1 ; : r- - i ; 1 1 | 537 (999) 158 16 sol. (316) (61) 5-15 -161 -183 si. sol. (-258) (-297) 167 (333) 20 468) v sol. 12 78 insol. (172) 2`Methoxyphenol, see Guaiacol i ! 4-Methoxy Phenol, see Hydroquinone Monomethyl Ether Other Solvents ale Misc, Ref AIA.BDH NSC 8DH ale. NSC ale. BDH ale bz. ale. | | org. sol, l r Sfl u 6 n (i fl r a n n n 4 3 IE 72 1 CMA 046053 SUBSTANCE/FORMULA W 3-13-MethoxypfopojiyM Propanol, see Dipropylene Glycol Methyl Ether g"" 704M Syvtem ---------------------------------------------- ?duL 1 (mg/M ') Health (See VI) , Fira React 'I , ! | Vap. Sp. Dens. Gr. j IAir=1) 1 1 1 FI. Pt, C (F> Igmt. Temp. SC ' lF) [ ________ Flam, Limits % i i B.P 6C (F) M.P. C (F> Sol. m H2O g/IOOg Other Solvents 638 Methyl Acetate > IB 200 ,1 3 0 97 2 55 -9 502 CH3CO2CH3 ; ; 05) (935) ______________________________________,__________ ______________________!__________ ___________ i__________ i________--__________ 1___________ 3 1 16 57 ! -99 j (135) , 1-146) V sol, Methyl Acetylene, see Propyne . !1 i! ] :ii 1 639 Methyl Acrylate CH2CHCOOCH3 Methylal, see Dimet ho xy methane j 18 : ,10 j Skm !; 2 ;3 1 :2 1 ; 95 3 0 j r| -3oc I ! (271 ! ;1 2 8-25 80 (176) -75 (-103) si sol ----------- 1 : ; j j ji ale ale, 640 Methyl Alcohol CH3OH p-Methylarmnophenol Sulfate, see Elon 641 Methyl Amyl Alcohol <CH3)2CHCH2CHOHCH3 642 Methyl-n-Amyl Ketone CH3(CH2)4COCH3 N-Methylamlme, see 0 Toluidme 2-Methylaiindme, see Propytemmine 643 6-Methyl-l, 2-Benianthracene ^ C IgH 1 1 CH3 IS j 200 | 1 1 '1 3 I 0 1 79 ' 1 11 12 ' 464 6-36 5 65 -98 1 i (54) | (867) (149) (-144) * i;;! " 1------------------ ale ace ------------------ 1 1 18 25 2 2 0 80 ; 3 5 41 Skm j (106) j _________ ,, 1-5 5 130 <-90 1266) : K-130) si sol 1 ! ale. 18 100 1 0 81 3 9 49oc 533 (120) (991) ___________ ___________ 151 1 -35 (304) j (-31) si sol ; 1 etc 18 Car 1 ! i 1 I 150 j (302) _ _ _ _ _ _ _ _ _ L_ 1 i tnsol 1 1 CS2 Misc. Ref SDH CED, MCA AIA SDH, MCA.NSC PAGE 73 CMA 046054 SUBSTANCE/FORMULA Waste NFPA D|S' pTM' TLV 704M System !------------------------------------- Vap- F|. Pt. Igmt. Temp. Flam. B.P. cedgre <mg/M5); Mealth (See VIJ Fire React. Sp. Dens. C Gr. (Air=1) (F) 6C <F) Limits % C (F) ^^644 lO-Methyl-1, 2-Bennthracene w c18h,,ch3 18 CAR M.P. C (F) Sol. in HjO g/IOOg Other Solvents Misc. Rf 141 insol (286) ale ace , CS2 645 Methyl Benzoate C6H5CO2CH3 18 ; 0 2 0 1,09 4,69 83 (181) 200 (392) -13 (8.6) insol, ale , MeOH 646 a Methylbenzyl Alcohol CgHgCH (CH3)OH ... ...... 647 Methyl Bromide CH3Br 648 2 Methyl-1-Butene fsHio 18 11 1 . ' .............. ......... ... ............... i i; ; , 4b 20C 3 ' Skin . ' ;i1:1 ; 'IS 1 514 0 | 102 ! 4 21 ; . .....................1. ... . . i......... |ii 0 | 1 73 3 27 j'; 96 (205) 1 0166124 1: <--7 <<-'20) 537 (999) 10-16 203 1397) 21 (70) si. sol. 4 -95 (40) (-139) insol, ale,, CS2 39 (102) - 134 (-209) rnsol Al A, BDH MCA, MG6 649 2-Methyl-2-Butene C5H10 650 3-Methyi-1-Butene c5h10 651 I'J-Methylbutylamine CH3(CH2)3NHCH3 652 Methyl Butyl Ketone CH3OC(CH2)3CH3 653 Methyl Butyrate CH3COOC3H7 18 | - 2 3 0 67 | 2 4 <--7 K20) 38 (100) -123 (-189) si. sol 18 2 4 0 67 ' 2 42 <"7 365 1 5*9 1 20 (< 20) (689) (68) __________ __________ __________ __________ 1 i1: 1 7a 1 3 3 0 74 . 30 ' 13oc 1 ' <55> | 91 (196) __________ __________ L................. ..................... 1 IS 100 2 3 0 , 81 1 345 35oc 533 1.2-8 126 __________ __________ (95) (991) i (259) -68 (-90) - 57 (-71) insol sol. 18 2 3 0 ,90 3 53 14 (57) 102 (216) <-97 si sol (<--143) ale ale ak ale 654 Methyl Celiosolve H3C-0-CH3-CH20H 655 Methyl Cellosolve Acetate CH3COOCH?CH20CH3 18 25 2 2 0 97 2 62 46 288 2 5-14 125 -87 Skin (115) (551) 1257) (-125) bz BDH j 18 25 3 Skm 2 1,01 4.07 56 394 1 7-8.2 145 -70 sol (132) (740) (293) (-94) j E 74 --J W 656 Methyl Chloride Ch3CI Methyl Chloroform, see 1 1 1-Tnchioroethane 657 Methyl Chloroformate CICOOCH3 655 3-Methyl Cholanthrene C21 H16 Methyl Cyanide, see Acetonitrile 659 Methyl Cyclohexane C6H11CH3 Waste Dis posal Pro cedure (See VI) TLV IACGIH) PPM Img/M*)! NFPA 704M System Health Fire React. 4b 100C [ 2 1 4 i 0 1 Sp. Gr. 0 98 Vap. Dens. (Air=1) FI. Pt. C <F) Ignit. Temp. c 1 lF] j Limits s 0.P. c (F) M.P, C (F) 1.8 632 jio 7 17 4 -24 -98 (1170) 1-11) ( -144) H20 g/IOOg $1 sol Other Solvents ale. !j 4b 3 18 CAR 1 1 j! 18 500 2 ' , 30 1 24 3 26 1 28 77 3 39 12 154) 504 (940) 71 (160) r" dec ale , b2 T...... ... j 280 (536) @8Qmm 180 ! (356) ! ; 1 1 1 1 1' i 1 !i 4 (25) 285 ' 1 2-- (545) 100 (212) -126 (-195) I "' TM 1 n so 1, ale Misc. Ref. MCA, MGB BDH BDH 660 (J.Methyl Cyclohexanol ch3c6h,0oh 18 100 3 2 0 92 3 93 68 296 (154) (565) 165 (329) -20 1-4) si sol ale, BDH 661 2-Methyl Cyclohexanone CH3C5H9CO 18 100 3 2 0 92 3 86 48 Skin (118) 165 (329) insol, aic BDH 662 4-Methyl Cyclohexene C6H9CH3 18 3 0 80 3 34 -1 oc (30) 103 1217) -116 (-177) insol ale 663 3 Methyl-4-Dimethylaminoazo- Benzene C15H17N3 8 CAR 664 Methylene-Bi Phenylisoeyenate OCNC5H4CH2C6H4NCO 6 1 __________ __________ L 1 1 19 Methylene Chloride: see Dichioromexhane 1 ':1' 1 !' 1 i1 1! 1! i 1 - : 194 9 ;(3813-?90) ! f ' @ 5mm (99) 1 1-------------------- ! !: | ; PAGE 75 CMA 046056 M .......................... Dis posal Pro eedure (See VI) tlv (ACGIH) PPM 1 mg/M ) | 704M System Health Fire React. Vbp Sp. Dens. Gr. [ |Air=1l FI. Pt. C <F) --' Methylene Chlorobromide, i j see Bromochiorornethane i .. ________ 1________________________________!__________ i_____________________:__________ ___________ _ Ignit. Temp. C (F) Methylene Di-p-Phenylene Isocyanate, see Methylene Biphenyl isocyanate ;, ;1 :,, Limits 665 Methyl Ether CH3OCH3 15 3 4 0 66 1 56 -41 350 3,4-18 ( -42) (662) S.P. C laF) M.P. C (6F) -24 (-11) -139 (-218) HjO fl/IOOg sol Other Solvents ale 666 Methyl Ethyl Ether CH3OC2H5 15 2 4 1 73 2 07 -37 190 2-10 1 11 ( 35) (374) (52) sol ale 667 Methyl Ethyl Ketone CH3COCH2CH3 18 200 1 3 0 81 2 5 7 515 2-10 80 -87 V sol ale b? (20) (960) (175) ( 124) 668 Methyl Ethyl Ketone Peroxide CH3CO2C2H5 22b 669 Methyl Ethylmtrosoearbamate C4H3W2O3 4a 670 Methyl Formate HCOOCH3 18 2 1 CAB 100 2 2 4 4 52-93 (125-200)1 1lOexp (230) sol ale . 1 0 ,99 2,1 -19 456 5 9-20 32 - 100 V SOI ale (-2) (8S3) (90) (-148) 671 2-Methyl Furan c5h6o 5-Methyl 3-Heptangne, see Ethyl Amyl Ketone 18 . ; 2 3 1 92 1 2,8 -30 (- 22) J___________ ! 1: i) i 67? Methyl Hydrazine CH3NHNH2 , 673 Methyl Iodide CH3l BE 76 16 20 Skm i 9 | 16 \ .................J___________ i___________ 1___________ 4b 5 Skin i 1 ! 1 1 ! 2 28 | 4 89 l <27 (< 301 63 1145) -89 ( 128) inSOl ale :! 11 ; 87 <-80 (189) << 112) sot ale 43 009) -67 si sol (-89) aic Misc, Rtf MCA A1A BDH NTTC, MCA NFPA BDH MCA BDH ! CMA 046057 SUBSTANCE/FORMULA P r 674 Methyl Isobutyl Ketone CH3COCH2CH(CH3)2 Dis. TLV ` 7MM Syitam 1 ............ | Sp. i D^ns. i V`` cedurs , (See Vl) " 18 , (mg/MJl ^ 100 Health ; 21 Fite 3 Reect. 1 1" 0 1 | Gr. 1 (Air=tl ' | "I I 80 , 3 5 i lF) 23 (73) Igmt. Temp. *C (R 1 , Flam. Limits ' % B.P. aC (F) MP cC (F) 460 I860) 1,4-7 5 117 (243) -85 (-*121) i Sol. m 1 H2O 1 g/lOOg Other Solvents si sol ale , bz Misc. Ref MCA 675 Methyl Isobutyrate (CH3J2CHCO2CH3 1 18 i 1 1 86 , 3 5 13oc 482 (55) (900) 92 (198) -84 (-119) si sol ale 676 Methyl Isocyanate CM3N=C-0 ____ ! 677 Methyl isothiocyanete CH3NCS 2 M EthyllaCtomtnle, see Acetone Cyanohydrin , 18 16 : 02 Skin . ,^ ;............... J1;| 3 1 97 1 67 ' 1 ' 1 ; 44 (111) 119 (246) 36 (97) __________ si sol ale ! : 678 Methyl Metcaptan CH3SH 13 ! 10C 2 4 0 87 . 1 66 ' <- 18 ,|, ; (<01 | 3 9*21 8 76 (45) -*123 (-189) $1 sol ale MGB 679 Methyl Methacrylate CH2C(CH3)COOCH3 18 100 2 3 2 94 3 6 10 I 421 2 1-12 5 100 -50 si sol sic I 1 (SO) I (790) (212) (-58) BDH, MCA 680 1 Methylnaphthaiene C10H7CH3 681 l-Methyl-2-Naphthylamine CH3CioH6^H2 18 1 5' 2 2 0 ! 1 03 ' CAR 1 - !- '528 ' (982) 240-3 1 -22 msol a(c (464-9) , (-7 6) | ! ! j ( 1 1 51 - org solv ! (124) j J 682 N-Methyl-N-Nitrosoacetamide C3HQN2O2 683 NMethylN Nitrosoallylamme C4H3N2O 684 N Methyl N Nitrosoanilme C6H5N(NO)Ch3 255dec (4911 15 (59) PAGE 77 CMA 046058 SUBSTANCE/FORMULA Waste Ois- ro TLV ^ppaT, NFPA 704M System I cedufe (m9/iw'l Haallh (See VI) 1 Fir* Raact. 1 Sp ; Gr. IAi,= 1) 1 FI. Pt. C (F) Igntt Temp. C lF) Flam. Limits % B.P. SC <F) M.P aC m Sol. m h2o g/IOOg ^R>85 N Methyl-N-Nitrosobenzyla W mtne CgHio^O ---------------------------------------------------------------- 1 686 1 Methyl-1-Nitrosourea H2NCON(NO)CH3 6 6 CAR ^ .......... _ : ^ CAR 1 687 N-Methyl N-Nitrosovinylamine C3H0N2O 6 CAR ' j; i1 jj 1| 1, ! 123dec (253) inSol 688 Methyl Parathion iXylene solution) /C"'ioiHiA10ifN'-0't5oPcS 2-Methyl-2-Propanethiol, see t Butyl Mercaptan 11) ' Skin 1 4 ;,, 3 , & 1 1 \ Aa ; 1 1 11 lb) 1 1 __________ !! Other Solvents ale,, bz Misc. 689 Methyl-n- Propyl Ketone CH3CO(Ch2J2CH3 7 505 (45) (941) 102 (216) -78 (-108) si sol 1 a'c 690 1 Methylpyrrole CH3C4H4N 16 115 insol ale (61) (239) 691 Methyl Salicylate ; 18 i !1 1 HOC6H4COOCH3 III1 ________________________ !__________ __________ 1__________ !__________ 692 a-Methyl Styrene C8H7CH3 ------------........... 693 m,-p-Methvl Styrene CH2CHC6H4CH3 18 i 11 ! 18 j 10QC 100 1 2 2 2 Methyl Sulfate, see Dimethyl Sulfate i j j 0 1 18 j 5 24 ' 101 (214) 454 (850) 92 1 4 08 54 , (129) 574 (1065) 0 89 4,08 57 494 (134) (921) 223 (433) -8 3 (18) Sl 50t 19-6 1 1 167-70 -23 (333-8) , (-9 4) 9 ! 170 (338) -83 (-117) insol ale. ale Methyl Sulfide, see Dimethyl Sulfide 1 1 iGE 78 1 j NTTC i 1 i SUBSTANCE/FORMULA Methyl Sulfoxide, see Dimethyl Sulfoxide Waste I Dispetal TLV IACGIH! Pro- PPM : cedure j (mg/M3) j (See Vl) 1 : Health NFPA 704MSystem Fire React. !! ignit. Vap. FI. Pt. Temp, Flam, B,P, Sp. Dens. PC C Limits C Gr. (Air=l| (F) (F) % <F) M,P, m Sol. in HjO g/IOOg Other Solvents Mi*C. Ref 694 N-Methy! N-2.4.6*Tetrenitroaniline C7H5N5O8 695 Methyl-p-Toluenesulfonate CH3C6H4SO3CH3 696 Methyl Vinyl Ether h2C=Ch-0-CH3 697 Mixed Acids (HNQ3+H2SQ4) 696 Molybdenum Mo 699 Molybdenum Compounds 11 n soluble) 700 Molybdenum Compounds (Soluble) 70l Monochloroamine nh2ci 61 I IS j [2 3 j 1! 1 57 i 1 23 6 45 15 J 1 1 24b 1! i 2 14 2! 1! ! 1 77 ' 2,0 ! __________ S__________ i_____________________i__________ -51 (-60) 41 , None 11 1 27a 26 (15) 2! j 102 1! [ __________ 1_________ 1___________ ___________ !______ .... ,; 1 1 _________ L_i.' 1' i' 11 (5) 1 19 1 __________ !__________ i__________ 1S7exp (369) 130 (266) msol sl sol None 27 (81) insol b* , ale __ .___________. 8 -122 sl, sol ! org, solv (46) (-188) __ _______ i_____________ Vanes Vanes ] - ; __________ I__________ i . MCA 5560 2622 (10040) (4751) 1 l""--.-- -66 (-87) sol ale Monochlorobenzene, see Chlorobenzene 702 Monomethylamine CH3NH2 7a 10 3 4 0 11 -10 430 4 9-20 8 -6 3 -94 v sol ale (14) (806) (211 ( 137) BDH MCA, MGB 703 Morpholine C4H9NO 5 20 2 3 0 99 3,00 38oc 310 Skin (100) 1590) 128 (262) -4 9 (23) c* org solv 1 PAGE 79 CMA 046060 SUBSTANCE/FORMULA Waste i DisI posal J PrO- , cedure ! (See Vi) TLV NFPA 704M System (ACGiH): PPM ! (mg/M3)| Health Fire React. Motor Fuel Antiknock Com pounds, see Tetraethyl Lead Vsp. ; FI. Pt. Sp, 1 Dens. 1 C Gr. | (Air=1> | (F> Igmt, Temp, C <F) Flam, j Limits J %j B.P. bC <F) M.P. C (F) Sol. in h2o g/IOOg Other Solvents Muriatic Acid, see Hydrochloric Acid Mylone, see Crag 974 704 Naphtha (Coal Tar) ___ L ! _ _ _ _ !:i,!:ii!j 18 100 2 2 0 1 87 42 277 (107) ' (531) 149-216 , (300-421 )i NTTC Naphtha (Petroleum), see Petroleum Ether 705 Naphtha, Varnish Makers and Painters, 50Flash 18 ' 3 0 <1 4 1 10 232 ,9-6 7 116*43 i (50) 1450) ; (241-89) 706 Naphtha, Varnish Makers and Painters, High Flash 18 30 43 29 232 1-6 139-77 (85) (450) ,(282-351) 70? Naphtha, Varnish Makers and Painters, Regular 706 Naphthalene Ci0H8 18 ! 3 0 <1 -2 232 (28) (450) 9-6 100-60 (212-320): .............. 18 10 2 2 0 1 15 ' 4 42 79 i 526 9-5 9 ' 210 80 inspl CS2 MCA (174) (979) (410) (176) b2 Naphthalene Ethylene, see J l 1 j' Acenaphthene t'' !, j 709 1 Naphthol C,qH7OH 710 2-Naphtho! C10H7OH i PAGE BO 18 ! 18 2 1,10 i 288 ! 96 m$ol 3l C h? , (550) (205) 11 i 1 22 4 97 1 153 1 295 (563) 123 (253) insol. aic. , hz CMA 046061 SUBSTANCE/FORMULA ^^1 1-Naphthylemine ^ C10H7NH2 Wjste Du- TLV posal (ACGIH) Pro- , PPM ! fedUw. 1 ' Img/M3) [ (See Vi; 1 NFPA 704M System Health Fire React. 5 21 0 l^nit. Vap. FI. Pt. Temp. Flam, B.P. Sp. Dens. C C Limits C Gr. {Air=1) (F) ("FI % (F) 112 j 4 93 157 1315) 301 (574) M,P. C (F) Sol. in N2O g/IOOg Other Solvents 50 (122) si sol. ale Miic. Ref BDH 712 2-Naphthylemine C10H7NH2 5 CAR 713 1 Naphthylisothiocyanate C10H7NCS 7b __________ __________ 714 Natural Gas (S5/oCH4, 10'oC2Hg, n2, c3h8, c4h,o) 18 1 715 Neon Me 28 2 1.06 '' 306 (5831 112 (234) $01 ale. BGH, MCA ------ nr 1.81 i1 !1 ;I 58 (136) insol. bz r ale., ace. 40 482-632 3.8-17 00-1170 69 -246 -249 1.522 (-411) ! (--416) Neopentane, see 2, 2-Dimethylpropane 716 Nickel Ni 717 Ntckel Carbonyl NiICQU 718 Nickel Nitrate Ni(N03)2 6H20 719 Nickel Sulfate N1SO4 720 Nicotine C10H14N3 721 Niobium Nb 27a (1) 18 001 4 2 3 i ; 8.90 ' - 1 1 1 ! 1 32 ^6 . . 2900 1452 insol. (6252) (2646) 60exp, (140) 2- 43 (109) -25 si. sol (-13) ale , bz. MGB 11 (11 1 0 1 2,06 137 (279) 58 (136) 238 ale 11 (1) 1 0 368 848dec 840 (1558) (1544) 29 5 { 5) 4 1 0 1 01 5.61 244 <4711 7-4 0 247 1477) <-80 (<-1121 OO ale 27k 2 8 57 4930 (8906) 2468 (4474) msol PAGE 81 a CMA 046062 SUBSTANCE/FORMULA Wests Di$poul Pro- TlV iACGIH) PPM 1 dur,, 1 tmg/M3) (See VI) Health imFPA 704MSystem Fire React. Vap Sp. Oen$. Gr. (Air=1) Nitrate^Nurite Salt Baths (53% 11 ! W KN03,40%NaN02.7%NaN03) j ; ! __________________________________________ |__________ |__________ |__________ !i 722b Nitrate-Nitrite Salt Baths ' 11 ... i ' (50^KN03,50%NbN02) 1 __________ - 1 ! -i__________ i__________ ;. ;1 ______ s__________i__________ FI. Pt. C iF) Nitrating Ac<d, see Mixed Acids 723 Nitric Acid HNO3 724 Nitric Oxide NO i j1 24b : 2 2 21 25 3 01 ! ; j 1 1 ! 1 50 -; 11 1 ; .! 1 l1 1 3 j 1 34 ! 1 04 ; ) 2,2',2" Nitntotnethanol, see Triethanolamine !1 Ignit. Temp. C laF) Flam. Limits % B.P. C PF) M P, 6C (4F) Sol. in HjO g/IOOg Other Solvents 140 (285) 220 (428) 86 (187) -42 (-44) > dec ale -153 -164 (-243) (-263) 7,3 ale Mite, Ret NSC NSC A| A, BDH, NTTC, MCA AIA, MG8 725 3-Nitroacetgphenone NO7C6H4COCH3 726 m Nitroaniline NO2C5H4NH2 6 i3 6 1 18 ' 202 (396) 81 (178) v sol ale 306 (583) 114 (237) si sol ale , bz MeOH BDH 727 0- Nitroaniline N02CgH4NH2 63 1 44 168oc 521 (3351 (970) 284 (543) 71 (160) si, sol, ale , bz BDH 72 8 p-Nitroamline NO2C5H4NH2 61 Skin 3 1 1,44 199 (390) 336 (637) 146 (295) insol air , MeOH BDH, MCA 729 Nitrobenzene C6H5NO2 6 32 0 1,20 4.24 88 482 1,8- 211 5 si, 501, ale , bi AIA, Skin (190) (900) 2000F, (412) (41) BDH, MCA 730 o- Nitrobiphenyl CeH5c6H4N02 6 CAR 2 0 1 44 6.9S 143 180 (290) (356) 330 (626) 35 (95) Insol ale :E 82 CMA 046063 SUBSTANCE/FORMULA fc. ^ W Nitrochlorobenzene. see W Chloronitrobenzene 731 Nitroethane CH3CH2NO2 732 2-Nitrofiuorene C^HgNOj Waste 1 Disj TLV .^pp^' NFPA 704M System i c`6"re i Ima/M3) | (See VI1 | i J1 Health 1 i Fire React. 1 ! j Vap, Sp. Dens Gr, (Air=l) j 4a | 100 ! 1 i 3 ! 3 1 1 05 1 2 58 1 6 __________ i__________ car ; FI. Ft. C (F) 28 (82) Ignit. Temp, C (SF| Flam Limits % 415 (779) 3.4- B.P. C lF> M.P. aC (*F) Sol, in HjO g/IOOg 114 -90 (237) (-130) sol 160 (320) msol. Other Solvents sic. hot bz Misc. Ref AlA, 6DH 733 Nitrogen N2 734 Nitrogen Dioxide no3 735 Nitrogen Fertilizer Solutions 26 21 26 0 1.25 | ____________________ ------------ 1 ': 5C 3 0 i 1 1 1,49 1 59 ;!: -196 -210 (-321) (-346) 2 3 si. sol ale. CGA 20 (68) -11 (12) dec chi , CSj Al A. MCA, MGS, NASA . j <-73 K-1001 NTTC Nitrogen Tetroxide, see Nitrogen Dioxide 736 Nitrogen Trifluoride nf3 12a 10 3 3 __________ __________ 1 59 -129 -209 (-200) (-344) si sol 737 Nitrogen Trioxide NO3 26 3 1.45 3.5 (38) -102 (-152) eth MGS 738 Nitromethane CH3NO2 4# 100 1 3 4 1.14 2,11 35 418 7 3- 101 -28 sol. ale. (95) (785) (214) (-18) A! A 739, a-Nitronaphthalene C10H7NO2 6 1 i 0 1.14 5.96 164 (327) 304 (579) 60 (140) insol. ale., CS2 740 m-Nitrophenol NO2C6H4OH 6 fe----------------------------------------------------------- 3 1.28 194 (381) (s>70mm 97 (207) si sol. ale. BDH PAGE 83 CMA 04606^ LS SUeSTANCE/FORMULA ^^^>-Nitrophenol NOjCe^QH 742 p'Nitrophenol NO2C6H4OH 743 1-Nitropropane CH3CH2CH2NO2 744, 2-Nitropropane CH3(N02>CHCH3 745 4-Nitroqumohne-N-Oxide NO2C9H6NO 746 N-Nitrosodiethylamine C4H10^2^ 747 N-Nitrosodimethylamine C2H6N2O 748 N-Nitroso-N-Methylenihne CeH5N(NO)CH3 749 4-Nitrosomorpholine C4H9N2O2 750 1-Nitrosopiperazine C4H9N2O 751, N-Nitrosopipendine C5h10N2Q 752 Nitrosyi Chloride NOCI Waste Dis posal Pro cedure (See VI) | TLV t (ACGlHl! PPM j (mg/M3) j NFPA 704M System Health Fire React. 63 Igmt. Vap. FI, Pt- Temp. Flam. B.P. Sp. Dons. 5C C Limits aC Gr. (Airssl) (SF) lF) % (F) 1 48 215 (419) M.P. aC (F) Sol. in h2 g/IOOg Other Solvents 45 (113) S>. sol ale 63 1.48 279 (534) 113 (235) si sol ale 4a 25 1 2 3 99 3 06 49oc 421 2 6- 131 -108 si. sol. ale. (120) (789) (268) (-162) 4 25 1 2 3 ,99 3 06 39oc 428 2.6- 120 -93 si. sol (103) (802) (248) (-135) 6 153 " (307) 7a Misc, Ref, BDH BDH ri ts 7a CAR 6 6 6 6 12a 3 1.01 1 13 1.06 3.0 2.3 152 (306) sol. 255dec (491) 15 (59) mSOl ale. ale 217 (423) -5.8 (21) -64 (-83) sol dec. f f` MGB I- - CMA 046065 SUBSTANCE/FORMULA f 753 m-Nitrotpluene CH3C6H4NO2 Waste Dis posal Pro cedure (Saa VI) TLV (ACGIH) PPM j Img/M3) NFFA 704M System Health Fire React, Sp. Vap, i FI. Pt. ! Dens, j flC Gr. j (Air=1) 1 (F) ,_ _ _ _ _ _ _ _ _ _ _ J____ _ _j_ _ _ _ _ _ _ _ _ _ _ _ _ Ignit. Tamp. aC (F) 6 5)212 Skin 1 15 47 ! 1 106 (223) Flam. %Limits B.P, C (FI 232 (450) M P, C <F) 15 (59) Sol. in H2O g/IOOg 1 insol Other Solvents ale , bz Miic. Ret, 754 o*Nitrotoluene CH3CeH4^02 755 p'NitrOtoiuana CH3C6H4N02 16 ; 5 ' 2 ' 2 1 - i 1,16 ' 4,72 ' 106 ! : ! (223) l1 ! 6 ! 5 ! 2 1 3 i 1 29 , 4.72 i 106 ; 1 ; (223) 220 (428) -4 1 (24) 238 (460) 52 (126) msol ale, msoi, ale,, bz., ' CS2 BDH 756 Nonyl Phenol C9H19CeH40H 757 Octachloronaphthalene C10CI8 18 4b 2 ; (1, j 1 1 : 1 1 1 0I 1 :- ) j 1 95 7 6 .. 1 141 ! (285) i ! i 290-301 (554*74) ' ; 44Qdec 197 ! 1 IS24) (387) 1 ; b2 758 OctafluOrO-2-Butene F3CFC=CFCF3 759 Octafluorocydobutane C4F8 (Freon C318) 4b 26 L. . . . . i , i i 1 53 : 1 i: , !1i! i !- i- | 1 65 1 iiI!!................................................ _................. . 760 Oetafluoropropane 1 4b - C3f8 ! ______________________________________________________ _____________ _____________ _____________ '! 1 29 ) !i - 76' Octane CH31CH2I6CH3 18 500 0 3 0 70 3 86 1 13 ! 220 (56) (428) 12 (34) -136 (-213) -------------------- -4 (25) --41 (-42) ! ; -37 (-35) 1 J -160 ! , (-256) , ;| - 1 gth ; I1 1.0-4,66 125 (257) i --57 msoi (-71) 1 si igi ale, 1 762 Octanoic Ac>d Ch3(Ch2)6COOH 763 1-Octanol CH3(CH2'70H 24a i 1 18 i . 91 5 0 132oc j (270) ; .... :1 !| 2 0 83 | 45 1 81 j , (178) 220 (428) 194 (381) III lb 1 si sol ! ait (61) 1 j ' 1 1 -------------------------- 1------------------------------- - 17 iOl 51 c (1 4) [ 764 2-Octanol , 18 1 i j1 2 0 .82 i 4 48 ! 88 j : (190) 178 (352) -39 ( 38) si. sol ) ale 1 ( 1 PAGE 85 CMA 046066 SUBSTANCF/FORMULA Waste NFPA Dis- TLV 704M System Ignit. IAp^H)------------------------------------------ Vp FI. Pt. Temp. Flam, B.P. Sp. Dens. C C Limits C > lmg/MJ): Health (See VI) Fire React. Gr (Airssl) <F) (F) % <F) M.P. aC (F) SqL m HjO g/lOOg Other Solvents Cocoanut IS 0 1 1 0 --______________ :.............Jiil--________________ 9 766a Oil. Fuel -- 1 . 18 1 0j 2 0 \ <1 | 216 (420) 38oc (100) 229 (444) 7-5 766b Oil. Fuel =2 766c Oil. Fuel -4 IS 0i 2 0 j <1 [ _____ ' ' 'r 1j ; 18 1 !1it 10 2 01 ___________________________________ ______ i!iii: <1 - 38oc 257 (100) (494) 54oc (130) 263 (505) 766d Oil Fuel --5 766e Oil, Fuel - 6 767 Oil, Lubricating 768 Oil, Mineral Oil Mist 18 i 0J 2 0 __________ i__________ !__________ i__________ _____ 10 18 2 0 <1 ! ! I 54oc ! : (i30) . 1__________ ]__________ i.......... ..... i. <1 I 1 71 oc 1 407 1 , (1601 1 (765) ^1! 18 0 1 ! 0 ' >149oc| 260-371 (>3001 1(500-700 __________ i____... i 18 (5) 0 10 81 __________ I_________ 193oc (380) 769 Oil, Olive 770 Oil, Peanut 18 __________ __________ 18 0 0 10 10 9 ,9 225 (437) 282 (540) 343 (650) 445 1833) 771 Oil, Soybean IS 0 1 0 ,9 282 445 (540) (833) Oil of Vitroil, see Sulfuric Acid ^ ! j i 23 (72) <-46 (<--SOI <-46 K-50) <-46 K-50) <-46 (<--50) <-46 K--50) 360 (680) 360 (680) -6 (21) 3 (37) 22 (72) o1C in \W ; Misc. Ref. NTTC NTTC NTTC NTTC NTTC NTTC fcj ri 15 U n to r f r A i- 4 ( CMA 046067 SUBSTANCE/FOR MU LA m Oil, Vegetable 773 Oleic Acid C17H33CGOH Oleum, see Sulfuric Acid 774 Osmium Os Onion Oil, see Allyl Propyl Disulfide 775 Osmium Tetroxide OsO<j 776 Oxahc Acid 'COOH)22H2Q 111 Qxalyl Chloride ICOCI)2 Qxirsne, see Ethylene Oxide 778 Oxygen 02 779 Oxygen Difluonde of2 780 Ozone 3 Waste Dis posal Pro cedure (See VI) TLV IACGIH) PPM 1 mg/M ^) NFPA 704M System Health Fire React, 18 0 1 0 24a 0 10 tgnit. Vap FI Pt Temp Flam, B P. So. Dens 5C gC Limits 5C Gr. (Air=1) (F) <F) % (F> M,P. C (* F) Sol. in m2o g/IOOg Other Solvents <1 321 (610) l 1 -9-1 ; (15 30) 39 189 363 360 14 msol ale , t); (372) (685) (680) (57) Misc, Ref NTTC NTTC ; 1 27k 1 i ' ; 12 1 27k 1002) 1 31 22 5 ! 4,91 None ,i '1i >6300 2700 (>96721 (4892) in Sol i; 130 (266) 41 (106) 5.710 ale 1 1 j ------------------------ { 24a ID 1 3 1 65 ! la ;, i J 11 ; 26 3 ; , ,i 3! 0 1 49 1 0 j 1 43 21 05 | | 190 1 26 1 3i3 17 157 102 (315) , (215) 63 : -16 (145) (3 2) sol dec ale NSC aec , ale 1 -183 -218 (-297) (-360) sol ale j 145 ! -224 (-229) 1 (-371) dec 1 T------- 1-------1 -- 112 1 -193 (-170) |(-315) i sol CG A Al A MGB NASA PAGE 87 CMA 046068 c bstance/formula Waste Dii PQWl Pro cedure < (See VI' TLV (ACGIH) PPM (rflg/M') NFPA 704M Systerr Health 26 7Sla Paladium 7S2 Paraffin 7SJ Paraformaldehyde IHCHO)x 784 Paraldehyde (CH3CHO)3 785 Parathion Ciqhi4NO5PS 786 Pentaborane B5H9 787 Pentachloroethane CHCI2CCI3 788 Pentachloronaphthalene C1QH3CI5 789 Pentachlorophenol CgCisOH ( 1) Skin ( 6) Skin (.5) Skin 19 Ignit, Vap, FI, Pt. Temp. , Flam B.P. Sp Dens, C ;C Limits : C Gr, (Air=1) lF) <f: (F) <27 ' Km M,P, Cc lF) Sol in h2o , g/10Og Other Solvents -36 < -32) , NTTC (I u 4,55 199 245 , (390) . (473) ! ; >370 | 42-60 I t>698) i (108-40) 70 1 300 , (158) , (572) j 120-170 | (248-338)! 36oc 1 238 [ 1 3(96) , (460) 128 (262) 12 (54) 375 (707) 6 1 1 insol. (43) 30 (86) 58 (136) -47 dec, (-53) 162 : (324) -29 (-20) insol. 1 98 , 310 i59Q) 190 (374) BDH,MCA t , AIA, MCA, NA5A,NSC AIA, BDH f f * * 9 CMA 046069 SUeSTANCE/FORMULA 93 2, 4-Pentanedione CH3C(0)CH2C(0ICH3 n-Pentanol, see n-Amyl Alcohol 794 2-Pentenol C5HnOH 2-Pentanone, see Methyl n-Propyi Ketone 3-Pentenone, see Diethyl Ketone Pentene, see Amyiene Waste , Dis posal , Pro, cedure (See Vt) 18 TLV (ACGIH) PPM (mg/M3) ' NFPA 704M System Health 2 Fire React. : 2! 0 1 j Igmt - Vap FI. Pt, Temp, Sp. Oen$. 1 cC Gr. j (Air=1) 1 !F) C lF] 3 45 l __________1 98 1 41oc (106) ' _________ Flam. Limits % B.P. C (F) 136-40 (277-84) M.P. aC (F) -23 (-9 4) Sol. in HjO [ Other | g/10Og Solvents | v sol ale. 1 Misc. Ref BDH 39 no3) 347 ; 1 2-9 0 i 119 (657) j I (246) n-Pentyl Acetate, see n-Amyl Acetate sec-Pentyl Acetate, see Sec-Amyl Acetate Pentyl Alcohol, see n Amyl Alcohol Pentyl Amine, see n-Amylaminti iso-Pentyl Nitrite, see Amy) Nitrite 795 Peracetic Acid (600/o Acetic 12a Acid Solution) CH3COQQH i 41 1 lOexp, (105) (230) 105 ! - 30 (221) I (-22) PAGE 89 CMA 046070 SUBSTANCE/FORMULA 096 Perchloric Acid Solution HClQ4'2h2Q Waste Dis* posel TLV (ACGIH) 1 (SeeVI) NFPA 704M System Fire React. Igntt. I Vap. FI, Pt. Temp | Flam Sp. Dens. 5C C I Limits Gr. < Ar=1 > <F) (F) % B.P. flC <F) 203 (397) M,P, C (F> t Sol m MjO a/1009 Other Solvents "18 (0) v, sol Misc. Ref, AIA, BDH, MCA, NSC Perchioroethyiene. see Tetrachloroethylene 797 Perchloromethyl Mercaptan , 13 CISCCI3 j 1,70 1 6.4 ; 149 (300) 798 Perchloryi Fluoride C1O3F 799 Petroleum Ethers 800 Phenanthrene (C6H4CH)2 --47 ! -146 (-53) (-231) .6 | 2 50 , -57 -70) 118 6 14 288 | (550) 1-6 ; 30-60 ! <-73 1 ] (86-140) i (<-101)1 340 (644) 101 | (214) -H insol. ale., CS2 801 2-Phenanthreneacetamide Ct6Hl3NO 802 3`Phenenthreneacetamide Ci6Wt3NO 803 Phenol C6H5OH 304 Phenyl Acetate CH3CO2C6H5 5I Skin | 3 0 I 1.07 79 (175) 715 (1319) 80 (176) 181 (358) 40 I sol, (104) 196 (385) ale,, CS2 BDH, NTTC, MCA Phenyl Acetonitrile, see Benzyl Cyanide 805, 1-Phenylazo-2-Naphtho! Cl6H12N2Q 102*4 (216*19) CMA 046071 SUBSTANCE/FORMULA Phenyleyelohexane, see Cyciohexylbenzene 806 p-Phenylenediamme H^ry(CgH4)NH2 807 Phenylethanolamme C6H5NHCH2CH2OH 808 Phenyl Ether C6H5OC6H5 809, Phenyl Ether - Biphenyl Mixture . Wests i Dis1 dosal 1 p,T~ cedure I (Sss VI) 1 j 5 | TLV 1 IACGIH1 PPM ! (mg/M5)1, 1 I ( 1) NFFA 704M Syltsirt Health Fire React. r !1 1 1 21 - , - 1 1 ! i 1 ! Sp. Gr. 5 2 1 0 | 1,09 15 1 1 1 ____ L__________ 15 1 1 09 1 06 Vap, Dens. (Air=1) PI. Pt. C (F) Ignit. Temp, C (aF) 37 5 86 156 (3121 152 (305) 960c 12051 646 (1195) 124oe 610 (255) (1130) Flam. Limits % B.P. C lF) 267 (5131 285 (545) 258 (496) 257 (494) M.P. C <F) Soi. m H2O g/lOOg Other Solvents 140 (284) sol. ale 35 4 6=0 ale, (95) 27 insol (81) ale., bz. 12 (54) Phenyl Glyctdyl Ether, see 1,2- Epoxy*3-Phenoxy propane SlO Phenylhydrasine CgHgNHNl-^ 16 5 3 Skin 2 0 j 1 09 37 89 174 (192) (345) 243dec (469) 20 (68) sol ale , b2 Misc. Ret, SDH 811 Phenyl Isocyanate 18 11 165 -30 dec, dee., ale. C6H5NCO (329) (""22) 812 Phenyl'2-Naphthylamine CiQH7NHCgH5 5 81 3 o-Phenyl Phenol C6H5C6H4OH 18 014 Phorone CH3<CH3)C=CHC(0)CH= C(CH3)CH3 18 815 iso-Phorone C9H -j 4O ft--------------------------------------------------------- 18 2 1 20 2 0 1.21 124 (255) 400 (752) 108 (226) insol 286 (547) 57 (135) msoi hot ale ale . ace, ! bz j 2 2 0 .88 48 85 (185) 197 (387) 28 (82) si. sol ale 1 -------------------- f---------------------------- 2 0 93 4 77 96oc 462 ,8-3.8 215 -8 si sol, BDH (205) (864) (419) (16) PAGE 91 CMA 046072 SUBSTANCE/FORMULA ^ 816, Phosdnn C7Hi306P 817 818 Phosgene COCI2 819 Phosgene Solutions in Benzene 820 Phosphoric Acid H3PO4 821 Phosphoric Anhydride P205 822 Phosphorus (White & Veiiow) P4 823 Phosphorus (Red) P4 Wests Oisposel Pro- TLV (ACGIMI PPM --"1 NFPA 704M System Health Fire React. 7b | (.1) Skin 3 ! 1| ---------------21 1 1 -- 3 3! 18 2I 24b (1) 24b 32 27c M) 3 3 27c 01 1 ' 824 Phosphorus Oxychloride POC13 21 3 Phosphorus Pentoxide, see Phosphoric Anhydride 825 Phosphorus Pentichionde PCI5 21 1_______________________________________ m; __________ 1 ii |i 3 2 Ignit. Yep. FI. Pt. Temp. Flam. 8.P, Sp. Dens. C C Limits C Or. (Air=1) (F) lF) % (F) M.P C (F) Sol. in HjO g/IOOg Other Solvents Misc. Ref 1.23 79oc (175) 107 (225) @1 mm I n i* 9 1.39 1.69 2.38 1 82 2 34 1 69 4 65 3.4 <22 72) 8 -128 (46) (-198) dec. dec , ale. MCA MCB, MGB BDH f f ' 260 (500) 42 (108) v sol. ale BHD, NTTC i3 4 42 4.77 5 30 300 sub!. (572) dec. dec.. a>c BDH,MCA 30 (86) spontaneous ignition in dry air 280 (535) 44 (111) si sol bz BDH, MCA,NSC . 260 (500) 280 590 (1094) V 50) @43atm ale BDH f 107 (225) 2 dec (341 dec , a*c BDH, MCA 1 ^ 1 1 1 __________ 1 162 subl. dec (324) CS2 ! BDH f CMA 046073 sSUuBbSs-tance/formula 826, Phosphorus Pentasulfide P2S5 827 Phosphorus Tribromide P4S3 828 Phosphorus Sesquisulfide PBr3 829 Phosphorus Trichloride PCI3 830 Phthalic Anhydride C6H4(CO)20 831 2-Picohne CH3C5H4N 832. 4-Picoline CH3C5H4N 833, Picric Acid (NO2)3C6H20H 334 Pimelic Acid HOOC(CM2)5COOH 835 Pindone (Rival) C14H14O3 836 2-Pinene CiQwi6 E837 Piperidine CgHtQNH Waste 1 Di* I TLV posal | (ACGIH) Pro- PPM "r',,,m9/M NFPA 704M System Health Fire React. Ignit. Vap, FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits 6C Gr. (Air-11 (F) (F) % (F) M.P. C (F) Sol. in H2O fl/1 OOg Other Solvents Miic. Ret. 31 21 2 1 142 (287! 100 (212) (.1) Skin 1.59 4 75 5.10 151 1 (304) 584 (1083) 39oc 538 (102) (1000) 57 (134) 150 1302) 300 (572) 33 (91) 16 (61) 514 (957) 276 (529) $!, SOl. CS2 407 (765! 173' (343) bz. CS2 173 (343) -40 (-40) 75 (167) -112 (-169) dec bz. CS2 BDH, MCA 284 (544) 131 (268) si sol. sic. 129 (264) --70 (-94) 143 (289) 4 (39) >300exp. I>672) 272 (622) @10Qmm 106 (223) 109 (228) 156 (313) -55 (-67) 106 (223) -7 (19) PAGE 93 CMA 046074 SUBSTANCE/FORMULA Waste | Div : TIV posal 1 (ACGIH) Pro- PPM "dur*J<mg/M3) (See VI) ; NFPA 704M System Health Fire React. Igmt. Vap- FI. Pt. Temp. Flam, B.P. Sp- Dens. C C Limits C Gr. (Airsl) (F) ("FI % (F) M.P, flC (F) Sol. in H2O 9/100, Other Solvents Misc. Ref ' 838 Piperylene CH3CH=CHCH=CH2 18 Pival, see Pmdone ----------- -------------------------------------- "----------839 Platinum Pi 27a ! 840 Polytetrafluoroethylene (F2C CF2)n 26 841 Polyvinyl Acetate Emulsion 18 1 13 1 .68 1i !i 1!0 0 :| 1 10 !0 ii __________ ,___ _]___________ ) 21 5 2.2 2 4 -43 <-4S> 2-8.3 42 (108) -141 (-222) insol. ale. 3827 (6920) 1774 (3225) mSol, aq. reg. subl >260 (>5001 in$ol -36 (-32) acet NTTC 842 Potassium K 843 Potassium Acetate CH3COOK 3 11 31 2 .86 1.4 1 1 0 1.8 3,4 774 (1425) 64 (147) dec. dec., ale. 8HD 292 (558) 25320 ale , MeOH 844 Potassium Borohydride kbh4 17 3 3 2 1.18 19 500dec (932) 1920 si sol . ale BDH 845 Potassium Carbonate K2CQ3 846 Potassium Chlorate KCIO3 11 12a 3 0 0 2.43 1 0 2 2.32 dec. 891 (1636) 11220 40Qdee (752) 368 (694) 7 120 ale AlA,BDH 84? Potassium Cyanide KCN 14 5 3 0 0 1.52 635 (11751 50 si sol , ale BDH 848 Potassium Dichromate K2Cr207 12a ( 5) 3 0 0 2.68 <500dec 398 (032) (748) 4,90 PAGE 94 * I i I I CMA 046075 T 1 849 Potassium Ftrrocyanide K4Fe(CN>6 3H2O 850 Potassium Fluoride KF 850a. Potassium Hydride KH 851, Potassium Hydrogen Difluoride KHF2 Potassium Hydroxide, see Caustic Potash 852 Potassium Nitrate KNO3 653 Potassium Perchlorate KCIQ4 854 Potassium Permanganate KMnOd 855 Potassium Persulfate K2S2O8 856 Potassium Peroxide k2o2 857 Potassium Sulfide k2s 858. Praseodymium Pr 859. Propane CH3CH2CH3 i Waste Di* Pro cedure (See VI) TIV (ACGIH) PPM (mg/M3) NFPA 7D4M System Health Fire React, 11 1 0 0 11 1-- 17 j 11 (2 5) 30 i 3 (2 5) 3j 0 0 3 0 11 12a . 101 1 02 12a ! 12a ! 22a ! 23 00 1 1 01 302 210 27k 1 20 18 1000 40 Ignit. Vip. FI. Ft. Temp. Flam. B.P. Sp, Dens. C C Limits C Gr, (Air*1) (F) (F) % (FJ M.P. C (F| Sol, m H2O g/IOOg Other Solvents Misc. Ref. 1 85 2 48 1 43 dec. 70 (158) 27.8'2 1505 880 (2741) (1616) v. sol. dec. sol. ace. 2 37 225dec. (437) 4121 BDH ---------------------,------------------------- 2,11 2.52 2,70 2.48 1.81 3.8 6.64 4.9 58 1.56 (-104) (-156) <A00dec 334 (752) (633) 13 i 610 (1130) <240dc! 464) <1 OOdecj K212) .75 6,420 1 70 j dec , ale ! sol,, MeOH j ---------------------j------------------------- 1 i dec. 490 (914) ! dec,, ale 1 :j dust explosive 840 (1544) sol. ale 3127 (5661) 935 (1715) dec. 468 2.2-0.5 (874) -45 (-49) -187 insol (-305) ale., bz NTTC PAGE 95 CMA 046076 ^ SUBSTANCE/FORMULA r 860 1,3 Propanediamme NH2<CH3)3NM2 861 1,2' Propanediol CH3CHOHCH2OH Waste Dis posal Pro cedure (See VI) TLV (ACGIHI PPM (mg/M3) 7s NFPA 704M System Health Fire React. rj 21 1 31 0 18 0 1 0 Vap. Sp. [ Dens. Gr. j (Air=t) ! ,86 2.86 FI. Pt. C (F) Igmt. Temp. C tFI Flam. Limits % 24qc (75) B.P. C ("FI 136 (276) M.P, C <F) Sol. in HjO g/700g Other Solvents -24 (-10) v. Sol. ale 1,04 2 62 99 (210) 371 2 612 5 (700) 189 (372) -59 (-74) ale n-Propanol. see n-PrOpyl Alcohol 862, Propergyl Alcohol HC=CCH20H 863 Propargyl Bromide HC^CCHjBr 18 | 1! . J_ _ _ _ _ _ L . . \_ _ _ _ _ _ , 1 1;1 31 3 ; 3 .96 1 93 4b 434 1.56 j 4 1 36 B7' 10 (50) 324 (615) 3,43Q- 115 (239) -- 17 (1,4) sol. 90 (194) -61 (-78) ale Propene, see Propylene 864 iso-Propenyt Acetate CH3COOC(CH3),CH2 /3-PropoU>ctone, see Hydracrylic Acid-i3-Laetone 865 Propionaldehyde CjHsCHO 866 Propionic Acid CH3CH2COOH IS 2 24a ji 3 0 .91 3 45 16 (60) 1.9- 93 -93 $1 sol (199) (-135) 23 0 81 2,0 -9*7oe 207 2,9-17 48 -81 sol, ale (15-19) (405) (120) (-114) 2 2 0 99 2.56 54 513 2 9- 141 -22 00 ale. (130) (955) (286) (-8) 867 Propionitnle CH3CH2CN 868 Propionyl Chloride CH3CH2COCI 14 Is i 4 3 1 ,77 1 9 2 (36) 3 3 1 1 06 3,2 12 (54) 3 1- 97 -93 v SOI ale (207) (-134) 80 -94 (176) (-137) dec. ale M/sc. Ret. NTTC BDH BHD BDH PAGE 96 CMA 046077 SUBSTANCE/FORMULA | ^^869 iso-Propyl Acetate CH3COOCH(CH3)2 870 n-Propy! Acetate CH3COOCH2CH2CH3 871 ivPropyl Alcohol CH3CH2CH2OH 872 iso-Propyl Alcohol CH3CHOHCH3 873 Propylamine CH3CH2CH2NH2 Waste Dis posal Pro cedure (See VI) TLV lACGIH) ppm ; (mg/M3) NFPA 704M System Health Fire React. 1; | Vap. PI. Pt. Sp. 1 Dens. ''C Gr. (Air=1) f (F) Igmt. Temp, C (F) Flam, Limits % B.P, C (F) M P, C (F) Sol. in H2O g/IQQg 250 18 1 | 3 ' 0 1 .87 3 52 - 4 460 1.8-7,8 I1: i 1 (40) (860) _________ ................ '__________ !__________ ;__________ :__________ !__________ , i 18 200 ! 1 ! 30 89 , 3,5 i 1 i 14 1 (58) ) 450 (842) 2-8 93 (199) -73 ("99) 102 (216) -95 (-139) sol. si sol 18 200 ! 1 1 3 0 1 1 !! _____________________ 1__________1_________ J___________ i1 1 18 400 1 ; 31 0I !i ' 1 7a 5 3 3 0 ; 78 2 07 1: ;: 79 : 2.07 , ; . 25 433 2 M3,5 (812) ! 12 (53) , 399 (750) 2.3-12 7 .72 1 2,0 ! -37 318 ! 2 000.4 (-35) : (604) ; 97 -127 (207) (-197) 82 -89 (180) (-128) 49 (120) -83 (-116) V sol 00 sol, Other Solvents ale, ale, ale , bz ale. ale. Mi. Ref BDH SDH BDH BDH, MCA BDH 874, tso-Propylamine (CH3)2CHNH2 875 Propyl Benzene C3H7C6H5 7a 5 3 4 0 1 .69 ' 2 03 ' --37oc i 402 2,3-10,4 32 -101 w ale ! - : (-35) (756) (90) (-150) 111 BDH, NTTC. MCA 18 2 3 0| ,86 4 14 30 450 0.8-6 159 -100 insol ale , b2 1 (86) (842) (318) (-14S) iso-Propyl Benzene, see Cumene 876 iso-Propyl Benzoate C6H5COOCH(CH3)2 877 Propyl Bromide CH3CH2CH2Br 18 1 4b . - !2 3 878 Propyl Chloride CH3CH2CH2CI 4b 1 2 __________ 1__________ n-Propyl Cyanide, see ,! Butyronitrile j! 1----------------------------------------------------------- i--i--!-- 3 ; 0 1,01 j I 5 67 1 99 (210) 218 (424) (-15) insol ! ale 1 0 1 1,35 1 43 490 (9141 __________ __________ 71 (160) -110 (-166) 0 ,89 2 71 <-18 520 2.6-11,1 47 123 0 (968) (117) (-189) si sol si sol ale, ale. ! , BDH ! 1 BDH 1 L_ __________ PAGE 97 CMA 046078 SUBSTANCE/FORMULA m ^ Propylene C3H6 Waste Dis posal Pro cedure (See VI) { TLV | IACGIH) ` PPM j (mg/M3) NFPA 704M System Health Fire React. 18 4000 1 4 1 880. Propylene Carbonate C3H6CO3 18 1 10 Propylene Dichloride, see 1,2-Dichloropropane 881 Propylene Disulfate C3HgS208 i 4b CAR i Propylene Glycol, see 1,2-PropanediOl 882 Propylene Imine c3h6nh ' 7a 2 2 2 2 Skin Propylene Oxide, see 1, 2-Epoxv-Propane 883 isO'Propyl Ether f(CH3)2CH!30 IS 500 2 3 1 884 n-Propyl Formate C3H7OOCH 18 2 30 885 iso-propyl formate <CH3}2CHOOCH 18 2 30 886 iso-propyl glycidyl ether 15 50 3 H3C0CH2CH2*0*KC{CH3)2 887 propyl nitrate CH3CH2CH2NO3 4. 25 2 3 3 Igrnt. Vap. FI. Ft. Temp. Flam. B.P. Sp- Dens. C C Limits C Gr. (Air=1) (F) (F) % (F) M,P, C (F) Sol, in HpO fl/IOOg Other Solvents 51 1,5 -108 460 2-11 1 -48 -185 v sol. ale. (-162) (860) ( -- 54) (-301) 1 21 35 135oc (275) 242 (468) -49 (-56) v. sol. bz * 2.0 63 (145) 72 .91 88 .92 1 06 3.5 -28 443 1 4-7 9 69 -60 si. sol ale (-18) (830) (155) (-76) 3 03 -3 455 2.3- 81 -93 si sol ale. (27) (851) (178) (-135) 30 -6 485 (22) (905) 68 (154) si. sol. ale 4.15 137 (279) 20 (68) 177 (350) 2-100 111 (232) <-100 si. sol. (<--148) ale. Misc. Ref MCA MCA CMA 046079 ^SUBSTANCE/FORMULA iso-propyl toluene, see cymene 398 Propyne HC=CCH3 889. Propyne-allene mixture (MAPP) 890. Pyrethrum 891. Pyridine C5H5N 392 Pyrogeihc add CgH3(OH)3 893 Pyrrolidine C4H9N 894. Pyruvic acid ch3cocooh Quicklime, see Calcium oxide 895 Quinaldine CH3C6H3NCHCHCH 896 Quinoline CeH4NCHCHCH 897. 8-Qumolinol HOCgH3NCHCMCH m Waste Dupoial Pro cedure (See VI) TIV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. 1 I Sp. Gr. > < FI. Pt. aC (F) Ignit. Temp. 6C lF) Flam. Limits % B.P. C <F) M.P. C (F) Sol. in h2 g/IOOg Other Solvents Mik. Ref, 18 1000 2 18 1000 2 26 (5) 2 55 24a 2 3 7a 2 24 4| 2 0 68 1 38 42 1 0! ! >1 1I 1 . \.................. 3 0| 99 j 2.7 _ _ _ _ _ _ !_ _ _ _ _ _ J_ _ _ _ _ _ 1 0 1 45 44 ................ . ... 3 1 85 2,45 20 (68) 3 (37) 17 --23 -105 sl. sol. (-9) (-157) forms expl. witH Cu & Ag 482 (90Q) 1.8-12.4 115 (240) -42 (-43) 00 309 (588) 133 (271) v. sol. 89 (192) -63 (-81) 00 ale. aic. aic. aic 1.23 30 165 (329) 14 (57) ale. BDH. NSC BDH 5 3 1 0 1.06 4.9 247 (477) -2 msol (28) ether 6 2 1 0 1.09 4.45 480 1 2- 238 -20 sol ale , CS2 BDH (896) (460) (-4) 6 210 267 (513) 76 (169) msol ale PAGE 99 CMA 046080 SUBSTANCE/FOBMULA ^ 898, Qumone W oc6H4o , Dis- TLV <ApPM ' cedure |mg/M3) (See VI) v 704M System Health Fire React. 18 .13 Vap. Sp, 1 Dens. Gr. (Air=1) FI. Pt. C (F) Ignit. Temp, C (F) Flam. Limits % i B.P i M.P C 1 C (fi : i"Fi Sot. in j HjO 1 Other g/IOOg Solvents 1.32 293 (560) 116subl. (241) si. sol. ale. Misc, Ref. Red fuming nitric acid, see nitric acid, anhydrous , 't[jj ! |j| 899 Refrigerant gases 900, Resins 901 Resorcinol C6hU<QH)2 902, Rhodium Rh 903 Ronnel C8H8CI3O3PS 904 Rotenone ^23^22^6 905 Rubber (tubing, etc.) 906, Rubidium Rb 26 - '' i;1 j 26 I , i , 1! ;i' i 1 18 ;i 12 1 ,j 37 | (.1) ' !7! 1 ........4 i 1 ill 7b | (15) 1 - -1 1.27 i 3,79 ; 127 ! (261) 4 j - : 18 (5) \ 7 ,:. 1,37 i__________ __________ 26 ' 227k 3 1.53 1 <38 j 100) NTTC i _______ 608 14(1126) @392F 281 1(538) ! 110 | (230) _ i 3707 ! 1985 1 (67051 1 (3605) Ii sol i insol. [ ale 1 41 : (1061 . org solv 1 310-30 ! 1410-38)! @5mm 163 (32S, . insol org solv Ignites in air 700 (1292) 38 (102) ---------------------,----------------- ------- dec. dec, ale, ' 907 Ruthenium Ru 27k 2 12.30 4150 (7502) 2450 (4442) m$ol 908. Saiicylaldehyde HOC6H4CHO 2 2 0 1.15 78 (172) 197 (387) -10 (14) si. sol. ale. CMA 046081 -- SUBSTANCE/FORMULA ^Bo9. Salicylic acid HOC6H4COOH 910 Samarium Sm 911 Selenic acid H2SeC>4 912 Selenium Se 913 Selenium dioxide Se03 914 Selenium Hexafluoride SeFg 91S Selenium oxychloride SeOCl2 Setenous acid, see selenium dioxide 916 Sevin ci2HnN02 917 Silane SiH4 918 Silica (cristobalite) SiOZ 919, Silica {free) S1O2 ! Waste , Dis- j |! j TLV ; , ^PPm"'j NFPA 704M System 1 dufe (ma/M3) ! 1 (Sat VI) ; 24a j Haalth 1 i ! Fire 1 Raact. ! 1 1 27k , 1 1> i !2 i .- 27e j 3.2'- Vap. Sp. Dens. G r. (Air^l) 1.44 < , 4,8 7.54 l 3.0 1: 27e I (.2) 1 3 i! 27a (.2) j 3 jj 1 j2 : j- ; i ]- 1 i -4.5 __________ 1 3.95 1 FI. Pt. C lF) 157 (315) * Ignit. Tamp. SC (F) 545 (1013) -150 (302) Flam. Limits % B.P. C (F) J1 M.P. aC (F) Sol. <n ! | HjO I Other g/IOOg Solvents | Misc, Ref. 211 (412) 159 (318) si sol. ale . ace. 1900 (3452) 1072 (1962) msol. 260dec. (500) 58 (136) CjO dec. ale AIA, BDH 688 (1270) 217 (423) msol. 315$ubl (599) 38'^ ch|. ale., bJ AIA, NSC AIA. BDH 27a 05 3 1 i 27a (2) ! 3 j 3,25 - 11 1i | 2.42 : 1i __________ !__________ __________ __________ -46$ubl. (-51) dec. NSC - 176 9 dec. bz., CS2 AIA,NSC (349) (48) 14 (5) 17 3 26 250 2 (%Si02+5) 26 2 3 68 2 32 Sponta neously -- 112 -185 flammal le in air (-170) (-301) insol. ___________________ j MG8 2230 (4046) 1715 (3119) insol. ! _____________ i__________________ PAGE 101 CMA 046082 SUBSTANCE/FORMULA A ^^^BSilica (quartz) ^^TSi02 921 Silica (amorphous) S1O2 922. Silica gel H2S.O3 Silicic acid, sea silica gel 923 Silicon tetrachloride S1CI4 924. Silicon tetrefluonde S1F4 925. Silver Ag 926 Silver Nitrate AgN03 927 Sodium Na 928 Sodium acetate NaOOCCM3 929 Sodium amide NaNH2 930 Sodium azide NBN3 Waste Dis* potal Pro* cedure (See VI) TLV (ACCIH) PPM (mg/M3) IMFPA 7Q4M System Health Fire React, 26 250 2 [%Si02+5 ' 26 20 2 Ignit "cVap, FI. Pt. Temp. Flam, B.P. Sp. Pens. C C Limits Gr. (Air=1) (F| (F) % (FI M.P. Sol. in (F) X9C Othet Solvents 2.64 2230 (4046) 1610 (2930) insol. 2.19 2230 (4046) insol. 26 1 150dec. (302) insol. Miac. Ref. r J 1 -- If k_ 1b 3 21 3 27a (01) 1 27k (01) 1 33 11 19 3 63 2 0 1 2 2 1.48 97 4.67 10.5 1 4.35 2 97 1.53 2 2.85 58 (136) -70 (-94) dec. dec. ale. --65 -90 (-85) (-130) piSlQmm S>1318rrm dec. 2212 (4014) 961 (1762) insol. ate. BOH MGB 444dec. (831) 212 (414) >1 IS (238) spontaneous ignition in dry air 892 (1638) 98 (208) 607 (1125) 324 (615) 1220 dec. ns ath. dec. ale. si. sol ale, 400 (752) 210 (410) dec. 8DH, MCA, NSC BDH dac. 4217 si. sol. ale. BDH 1_ r 3_ -- f- \_ ) _ J ^ a9 --- 3 % CMA 046083 CMA 046084 SUBSTANCE FORMULA Sodium ethoxide NdQC2H5 2C2H5OH 944 Sodium fluoride NaF 945 Sodium fluoroacetate CH2FCOONa 94G Sodium formate NaOOCH Ois posal Pro cedure (See VI) TUV (ACGIH PPM (mg/M` ) 704M System Health Fire React. 3 33 11 3 4b ,05) Skin 11 3 3 1 1 1 gn it, Vap. FI. Pt Temp. Flam B P. Sp. Dens ! *(- Limits SC Gr. |Ar=1) lFI ! |F) % <F) r" "' dec M.P, C (5F) Sol. in h2o g/IOOg Othei Solvents 200 (392) dec ale Mi$c. Ref, BDH 2.56 1.92 1700 (3092) 980-97 (1796- 1827) 4.218 200 (392) 11125 253 (487) 9720 ' si sol ale , i I 1 si sot ale 947 Sodium hydride NaH 948 Sodium hydrogen difluoride NaF-HF 17 11 32 ,92 2 08 Explodes with water 800dec (1472) dec. NSC i 6DH Sodium hydroxide, see CduSTlC sodd ' 1i, I ._ _ _ _ _ _ _ __ ___ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _5!L ....................................................................................................................................................... : 949 Sodium hypochlorite NaOCl 12a 2 dec. j 950 Sodium iodide Nal 11 2 3 67 ;l 1304 (2379) 651 (1204) 18425 1 j ale ace BOH 951 Sodium methoxide NaOCH3.2CH3OH 952 Sodium nitrate [\idNO3 953 Sodium nitrite NaN02 104 3 11 ' 12b 1 '0 2 1| 3 12 j 1 1 2.26 2 17 | |i i :r 1 538exp 1 | (10001 dec. dec. MeOH BDH 380dec. (716) 307 (585) 9225 ale. MeOH 320dec, (608) 271 (520) 8115 si sol ale ' CMA 046085 SUBSTAMCE FORMULA i f 954 Sodium pentaehlorophenate CgClsONa Waste D.s pose) Pro cedyre (See VI) TL V IACGIH, PPM img'M ) NFPA 704M System Health Fire React. 4b < 5) 3 Ignit Vap. FI. Pt. T emp, Flam BP Sp. Dens. Limits "C Gr (Air=1l (=T) <5F) n0 (F) H n T Sol, >n h2o g/100g Other Solvents Misc. Ref, 955 Sodium perchlorate MSCIO4 956 Sodium peroxide Nc!2 O2 957 Sodium 0 phosphate Na2*P04 7H20 95S Sodium-potassium alloy; NaK 959 Sodium propionate NaOOCC2H5 12a 22a 11 3 11 2 0 2 2 02 3 0 2 2,81 1.68 332 Ignite in air 482dec (900) sol ale 460dec (860) sol dec, ale 48 (118) 104^0 BDH sol ale 960 Sodium silicate (water glass) Nd2<0 *Si02 11 1 sol NTTC 961 Sodium sulfide Na2$ 962 Sodium sulfite Na2S03 23 2 1 0 1 86 12b 2 2 63 1180 (2156) 1510 si sol ale dec 12 si, sol ale BOH 963 Sodium tetraborate N02B407 964 Sodium thiocyanate NaSCN 965 Sodium thiosulfate 11 11 12b 3 3 1 2 37 ; 157dec 741 (2867) (1366) 1 Q6 287 (549) 13921 a'c,, ace 1,67 1 ! 48 50 1|1; j i (118) PAGE 105 CMA 046086 STANCE/FORMULA 1| VStannic Chloride W SnCU Wa$te , Oiv : posal PrOi cedure i (See VI) t TLV (ACGIH) PPM : (mg/M3) I NFPA 704M System Health Fire React. ` lb 3 1 j Stannic Chloride hydrate 11 Vep. Sp. 1 Dens, Gr. j (Air=1) 2 23 1 FI. Pt. *C lF) Ignit. Temp. aC (F) Limits % B.P, aC (F) 114 (237) M P, aC <F) h2o g/IOOg -33 (-27) sol Other Solvents eth i ! j i i Misc. Ret BOH 967 Stearic acid C17H35C00H 968 Stibine SbHg 969 4-stibenamine Cl4Hl4 970 Stoddard solvent 971 Strontium Sr 972 Strontium carbonate SrC03 973 Strontium nitrate Sr(NQ3)2 24a 1 27d 3 5 CAR 18 500 1 ............. 27h 2 27h 27h 1 1 0 95 | 9 8 196 395 (385) (743) J__________ | 2 ! 5 30 j___________ |.................. 1 |. .............. ! 358-83 69 (676-721) (156) msol cs2 -17 (1 4) -88 ,40 (-126) ___________ 90 i (194) ! cs2 NTTC 1 2 2 1 10 1 1 26 3.7 0 1 2 99 38-43 227-60 (100-110)|(441-500> 8 5 220-300 (428-572) ;" : 1384 752 (2523) (1386) dec ale 1340 (2444) 1497 (2727) @69atm si. sol. 645 (1193) 570 (1058) 7118 sl. sol ale. < 974 Strontium peroxide Sr02 975 Strychnine C?1 H22M2O2 976 Styrene (CGH5CHCH2ln 27h 5 1 151 1 3 18 2 01 i 3 4.56 1 36 909 3.6 31 (88) 490 (914) 11-61 270 (518) @5mm 146 (295) 215dec, sl sol (419) 268 (514) sf. sol. ale chi --------------- 1 33 msol ale , CS2 (-27) ! ^ Al A, BOH,NTTC 977 Styrene monomer C6H5CHCH2 t IS 100C , 2 i 3; 2 905 ; j 31 (88) 490 (914) 11-61 145 (293) -31 msol, ( 23) ale , CS2 BDH, NTTC, MCA CMA 046087  978 Succmte Actd COOH{CH2)2COOH 979 Succinic Anhydride C4H4O3 980, Succmomtrile NCCH2CH2CN 980a Sulfamic Acid S02(NH2)OH 981 Sulfemide S02IMH2)2 9S2 Sulfur SB 983 Sulfur Oecafiuonde s2FlO 984 Sulfur Dtehlonde sci2 985 Sulfur Dioxide so2 986 Sulfur Hexafluoride SFg 987 Sulfuric Acid H2S04 988 Sulfur Monochloride S2CI2 989 Sulfur Trioxide S03 Ii-- Wast Dis posal Proi cedure (See VI) TLV (ACGIH) PPM ; (mg/M*) | 704M System Health Fire React, 1 i 1! 24a 2 Sp. Or. 1,57 Vap. Dens (Air=1) FI, Pt. C <F) Igmt, Temp. *C lFI Limits % B,P. C (F> 235dec (455) M.P, c r=F) h2o g/IOOg Othet Solvents Misc Ret 185 (365) si sol ale , MeOH j 24a 21 1 10 261 120 insol, ale (502) (248) 14 .... \ 19 19 26 21 31 98 1 2 3 2 03 1 61 1 2 i 0 2 07 3; ! 2 08 2 76 132 1270) ' .! 1 1 1 1 __________i__ _______ 207 <405) 232 (450) 266 1511) 58 (136) V sol ale. bz dec 200 dec, 250dec, 92 (4821 (198) sol 444 (832) 119 (246) insol, 29 (84) -92 (-134) ale. cs2 NTTC. MCA,NSC 21 12b 5 3! 2! 3' 0 0 1 62 3.6 1 4 23 59dec, -78 :|138) (-108) 10 (14) -76 (-105) 230 bz ale BDH, MCA AIA MCA CG A 21 24b ; 1 21 24b ! 1000 I ' ; 1 67 !i im , 3 0 ! 1 1 1 84 1 1 *c 1| 1 ! 1 1 69 1 ! 1 ! 2 2 75 ;t j 62 ! 64sub sl, sol (-83) 28 None j _____ _J 118 (245) 234 (453) None . 338 (640) 136 (277! ------- * [ 1 45 1113) 1 10 (50) -80 (-112) 17 (63) dec. dec ale nee , ale ^ DZ ,CSp AIA BOH NTTC, MCA BDH MCA MCA PAGE i07 CMA 046088 SUBSTANCE, FORMULA ^ ^B)90 Sulfuryl Chlpnde W SO2CI2 991 Sulfuryl Fluoride SO2F? 992 Svstox (C2H5O) 2PSOC2H4SC2H5 993 Tall Oil (Liquid Rosm) 994 Tallow 995 Tannic Acid C76h526 996 Tantalum Ta 997 Tar, Liquid Waste Dis- ^ TLV IA^H' , csdure |m9/MJ) (See vl' 21 NFPA 704M System - - ' Health Fire React. ^ Gr. 3 - 1- 1 67 ! 1 : (Air=i) ' FI, Pt. j C 1 (FI ; Igmt, | Temp. C 1 lFI ; Flam, Limits % B.P *C (F( :I i j ! 69 (156) M P, QC (F| 1 , Sol. in : H20 j ; 9/1009 j Othei Solvents 1 i1 -54 , dec bz (-65) j ! 21 5 \ 3 ! 7b ' 111 i, 3 3.72 t < ! --55 (-67) !r -137 ; 10 ! ale (-215) i 1 __________ l_________ i______________ j 1 134 !1 12731 | 18 1 1; - |, : | [: - 182 ! . (360) , i ;' . 18 01 !!!!;:; 0 395 , 265 ! ' 32 (509) ; (90) ::,i 1 24a j | I2 |,| 1 1* 1i | 199oc 1 527 1 i , 210dec 1 (390) i (980) i : (410) __________ __________ __________ __________ 1:!_______________________________ __________ :; 27a j (5) ,i ! 2 1 16 7 1 ! 1 1 5425 . 2997 ,, 1 | (9797) (5300) ! !!,;! | sol ale , ace insol | 26 ' |3 2 1; 1' --............,--4--.-- 1 ' >93 ! (>2001 1- ! 49 , (120) --------___l--------------------------------!----------------1---------------- --------------- i--------------- 1--------------- ! Mile, Ret, BDH NTTC NTTC NTTC Duhiunopvrophosphate CMA 046089 SUBSTANCE/FORMULA 00. Terbium Tb Waste j Disj posal | Pro- estlu.e (See VI) TLV (ACGlH! PPM (mo/M3l! NFPA 704M System Health Fire React. ! [ l ' Igmt. I Vap. j FI, Pt. j Temp. Sp. I Dens. ] 6C \ C Gr. I (Air=l) I (F) I [FI Ii Flam, Limits % B.P. C (F) M.P. C (5F) Sol. in j H20 I Other g/IOOg Solvents | Mi$c. Ref. : 2800 [ (5072) 1356 (*473) 1001 m-Terphenyl C13H14 135oc, ! (275) ; 365 (689) 87 (189) 1002 o-Terphenyl Cl8h \4 7,9 : 163oc : (325) 332 (630) 57 (135) insol, I bz , MbQH 1003 p-Terphenyl Cl8H14 1004 Tetrabromoethane BrjCHCH 8r2 405 (761) 213 (415) 239dec, (374) -1 (30) insol ! ale. 1005 1,2,4,5-Tetrachlorobenzene CeH2Cl4 1006 1,1,1,2`Tetrachloro*2.2Difluoro Ethane F2CCI CCI3 0 I 1,86 . ! 155 (311) 1,64 ; 7,03 243 (469) 139 (282) insol b2 . CS2 92 (198) 41 (106) irt$ol, ! ale 1007 1,1,2,2-Tetrachloro-1,2. Drfluoro Ethane C2FCCFC)2 93 (199) 25 (77) 1008 1.1,2.2-Tetrachloroethene CI2HCCHCI2 1009 Tetrachloroethylene CI2OCCl2 1010 Tetrachloronaphthalene CioH8Cl4 1011 Tetradecane C14H3O 5 Skin 27j 100 (2) Skin 1.59 5,8 1 None 1 62 5,8 None 68 100 202 (212) (396) 146 (295) 121 (250) -43 (-45) sl sol j ale I | AlA | BDH, MCA -24 (-11) Jmsol ale , bz, | AlA BDH, | I NTTC, MCA 182 (3601 254 (489) 6 (43) PAGE 109 CMA 046090 CMA 046091 i - SUBSTANCE FORMULA Tetramethy! Succmomtnle W NCCfCM3)3C(CH3)2CN Dis posal , Pro. cedure (See VII TL V (acgih; ppm (mg/M'1) 704M System Health Fire React. 14 5 3 Vap Sp. Dens 1Gr, ' (Air=D 1 30 fi, Pt. C (F) ( ; 1 ; igmt. Temp, eC (CF> 'I Flam, Limits % B P, ''C (CFI M.P. C (F) Sol. in h2o g/IQOg Other Solvents 190subl si sol (374) si sol , ale Mi$c. Ref. 21024 Tetramethylthiuram Disulfide 13 (5) (Thirgm) (H2NCSCH 3)482 13 70 (158) I 1025 Tetrenitromethane C(N02)4 4a 33 Tetryl, see N'Merhyi-N-2, 4,6-Tetranitroaniline ______,__________________________________ 1026 Thallium Tl 27k f 1) Skin 3 1 64 .... 11 9 ' '| 1 ...1 126 13 insol (259) 155) J_________ . ' . 1460 (2660) ... 304 (579) msol ale. 1 1 j \ 1 1 : 1027 Thallium, soluble compounds 27k < 1) Skin 3 1028 Thallous Sulfate ti2S04 27k 3 6,77 dec 632 20 (1170) 4,9 1 1029 Thioacetamide CH3CSNH2 13 2 115 (239) v sol ale 1030 2,2' Thiodiethanol (CH2CH2OH)2S 1031 Thiogiycollic Acid HSCH2-COOH 1032 Thionyl Chloride SOCI2 1033 Thionyl Fluoride sof2 13 13 21 21 11 3 3 3 0 1 18 4.2 160oc, (320) 1.35 1 1 64 ! 2 93 ' 1 ; 28 (82) 11 (12) <x> 105 (221) ; @1 1 mm -17 (1) 00 76 -105 (169) (-157) dec. -44 ( -47) -110 (-166) dec ale ale BDH b2 BDH bz,ace : PAGE 111 CMA 046092 SUBSTANCE FORMULA 1034 Thiophene C4H4S 1035 Thiourea NH2CSNH2 Thiram, see Teri'jmerhyi Thiurom Disu Ifitie l036 Thonum Th 1037 Thorium Nitrate T h<NC>3)4 1038 T in 5n 1039 Tm, Inorganic compounds 1040 Tin, Organic compounds 1041 T itanium T1 1042 Titanium Dioxide (rutile) T1O2 1043 Titanium Tetrachloride T1CI4 1044 Toluene C5H5CH3 PAGE 112 A'aSte Dis posal Pro Cpdure 'See VII TLV iACGIH, PPM 1 mq M ') NFPA 704M System Health Fire React. 13 3 Sp Gr 1 06 Vap Dens |Air = l> FI Pt -c t'F) 29 1 <30) 1 qm t T emp, ("Ft Flam Limits BP 3C ( F) 84 (133) M.P SC fF) Sol, <n h2o g/100g Other Solvents 38 1 - 36). org , sol 13 1 1 41 dec 181 sol ilc (358) Misc. Ref, 3DH --- 27k 2 27k 10 1 27a 0 1 11 (2) variable, oxides toxic 26 ( D J 27a 115) 0 26 (15) 1 1b 5 3 0 ,1 18 200 2 13 :0 i 11 7 5 75 4500 (8100) 1327 (332H 1 rviol 500dec (932) V sol 3(C 2260 (4100) 23 2 (450) irlSOl most soluble 45 4 26 l 73 87 700 800 <12921472) 3262 (5432) 1800 (3146) nsol -2 700 14890) 1840 (3344) nsol 136 (277) -30 (- 22) 'Ol 3 1 44 636 14-6 7 1 1 11 -95 nsn' ! (40) 1 ^97 ; (231) (-139) ,,r 1J . ). 052 Al A V\ NSC 41 A 3 Dm NTC MCA CMA 046093 SUBSTANCE/FORMULA 1045 Toluene-2,4-diisoeyanate CH3C6H3lNCO)2 Dis1 posal , ProI cedure 1 (See VI) 1 ,6 TLV (ACG1H) PPM (mg/M3), 1 02C 704M System Health Fire React. 212 ! j Vap. Sp. 1 Dens. Gr. (Air=1) FI. Pt, aC (F) Igmt. Temp, *C (F) Flam. Limits % 1 2 6,0 132 (270)oc 9-9,5 a-Toluenethiol, see Senzyl Mercaptan 1046 1 o-Tolylazo-2-Naphthol 1 a Ci7H14N20 CAR __________ Tglylene Onsocyanate, see ;i! Toluene-2,4-Du50cyanate 'i ________________________________________i__________ ,__________ ___________ ,__________ ,__________ |__________ ;__________ ;__________ _ o-Tolyl Phosphate, see Tntolyl Phosphate '1 :1| 1047 m-Toluidme CH3CSH4-NH2 5 1 3 21 0 99 39 86 482 (187) (900) - B.P. C (F) 251 (4841 203 (398) M.P. C (F) 20 (68) Sol. in HjO g/1OOg Other Solvents I . 1 Mi$c Ret AIA, MCA : -31 si sol (-24) die SDH,MCA 1048 o-Toluidine CH^-CgH^-NHj 1049 p-Toluidine CH3C@H4-NH2 5 53 Skin 2: 0 ! 1 004 > 3 7 85 (185) 482 (900) ' 200 (392) -16 (3) si, sol, ale. 1 5 3 21 0 1,046 3,9 87 482 - 200 44 Sl Spl ale (189) (900) (392) (111) BDH,MCA BDH,MCA 1049a Transits 1049b, Toxaphene, C10H10C|8 1050 Tremolite Ca2Mg5Sig024H2 1051 Triamylamine (C5H t ] >3N Tribromomethgne, see 8romoform 26 1 1 ^ , (0 5) : ^ 1 Skm : 26 | ` i 1 7a 1 - \ ] ;2 \ 1 11 1 )i 11 [ 11 0 1 66 j 1 i *0 | .............. 8 7.8 102 (215) , -- j- ! ! j 1 65-90 insol org. sol. | 232 (450) ale , ace -- --------- 1 PAGE 113 CMA 046094 SUBSTANCE/FORMULA 1052. Tri-n-Butvl Amme (C4H9I3N 1053, Tributylchlorgtin f"12^27^n^l 1054, Tnbutvl Phosphate (C4H9O) 3 PO 1055 Trichloroacetic Acid C CI3COOH Trichloroacetaldehyde, see Chloral 1056 Trichloroacetomtrile CCI3 CM Waste Ois* proos.al tLV (acgih; p^,"'------- NFPA 7G4M System -- -------------- , f*dgr* (mg/M3) Health tse vi- Frre React, 1 7a 2 2 0 : 1 4b 1 Vap, F|. Pt Igmt, Temp. 1 Flam. Dens. ! SC 1 aC 1 Limits G t. (A,r=1) lF) (F) ! % 3, j1 6,38 1 86 1 (i87) ; ! 1.13 ' j 1 B P. lF> M.P. Op (FI Sol. in H2O g/IOOg Other Solvents 216 1 --70 (421) j (-94) si. sol. ale 174 (345) 30 (86) 7b (5) 2 1 4c , 31 - r 1 14 1 ! -j 0 ,97 9.2 1,63 , 1 44 , i' - 146 , (295) 1 t1 ! ,| 1 , 1 ; 292 <-80 (558) (<-1121 sol. ale., bz., cs2 198 (388) 58 (136) v. sol. 1 ale. ; !i ____ :_____________________ L. __________ 1........................... ... -^ 'i 85 (185) -44 (-47) Misc, Ref, 8DH SDH 1057, Tnchloroacetyl Chloride CCI3COCI la ] |, ] 3' 1 1058, 1,2,4-Triehlorobenzene C6H3a3 1059. 1,1,1-Trichloroethane CH3CCI3 1060, Trichloroethylene C1CHCC12 4b , 2 ; 1 r1 27j 350 2 , . j; j ' 27) 100 ; iii 2 1 1,0 \ | ' : 1 1j 1 - Tnchlorofluoromethane, see Fluorotnchloromethane 1 63 1.45 1.34 1.46 ,! 1 63 99 (210) 118 (244) 214 (417) dec. dec , ale, 17 (63) insol. si sol,, etc. 46 4.54 none 32 (90) 74 (165) -38 (-36) insol. ale. 410 12.5-90 (770) 87 (188) -73 (-99) si. sol. ale. Al A, NTTC, MCA Al A, BDH, NTTC. MCA, NSC ! Trichioromethanethiol, see Perchloromethyl Mercaptan PAGE 114 ! 046095 CMA SUBSTANCE/FORMULA SUBSTANCE/FORMULA k 1061. Trichloronaphthalene ^ Ciqh5ci3 " Tnchloronitromethane, see Chloropicrtn | Ops- TLV Pro- (ACGIH, PPM "',ur' Img/M3) 1 (See VI- | 7Q4M System ,J1 ; Hi.lth Em Rst. 1 ; ` 4b (51 2 1 Skm ^ l?niti ] Vap. FI Ft. Temp. Flam. Sp. : Dsns, 1 aC 1 c Lim.ti Gr, , (Air=1) ! (F) ' (F) i|jj % | ' :1 5-pc (FI M.P. aC (F) Sol. m HjO 9/IOO9 Other Solvents 133 (271) alc.h Misc. Ret. 1062. 2,4,5-Tnchlorophenoxy Acetic Acid CI3C2H2OCH2COOH 4c >10) j| - -i * ! j . 157 (315) sl sol 1063 1,2,3-Trichloropropane C3H5CI3 4h , 50 3 2: 0 1.39 5.0 32 ' 304 j 32-126 156 i 1 ; (10O)oc! (579) 1 (313) ' _____________i_____________1_____________i__________ ;_______________________________ !____ _1______________ L. . -------------------------------- 1064, 1,1,2-Tnchloro-1,2,2-Tnf|uoro Ethane CI2FCC Cl F2 Tncresyl Phosphate, see Tritolyl Phosphate 2S 1000 , !1 i! !j 1j j 1 56 j 680 (1256) (118) i _________ 1065 Tridecanoi CH3(CH2IhCH2QH is 1 j -! ' . .82 i 6 9 ; 121 I ) 1 12501 ! !! 274 (525) -15 (5) -36 (-33) 31 (88) si sol. insot in$ol. 1066, Triethyl Aluminum (C2h5)3ai 3 3 .84 <-53 <-53 194 -53 exp.^Q (<--631 (<--63) (381) (-631 ale ale , bz ale. A1A 1067, Tnethyl Amine (C2H5)3N 7a 25 2 3 0 .73 3.48 <-7 K-20)oc 1.2-8.0 89 (192) -115 (-175) sol. ale. BDH 106S Triethanolamine (CH2OHCh2)3N 7a 1 1 1 1 13 179 (355) 360 (680) 20 (68) 00 ale. 1069. TrietHylene Glycol Triethy {CH2OCH2CH20M)2 1070 Tnethyleoe-Tetramine H2NCH2(CH2NHCH2)2CH2 nh2 18 7a 1 1 0 1.13 5,17 177 371 9-9 2 276 -4 QO ale (350) (700) (529) (25) -- 3 1 0 ,98 135 (275) 338 (640) 267 (513) 12 (54) sol. ale. BOH PAGE 115 CMA 046096 SUBSTANCE/FORMULA | P' Triethyl o-Formate (C2H50l3CH Trifluoroaeetic Acid CF3COOH 1073. Trifluoromethene chf3 Waste Ois- TLV posal (ACGIHI Pro- PPM cedure lmg/M3) Health (See VI; 18 3 NFPA 704MSystem Fire R 2 4c 3 26 = Ignit, Vap. FI Pt. ' Temp. , Flam. B.P. Sp Dens. 3C i =C 1 Limits ^ 'C Gr. (A,r=ll (F) 1 <n vg ' (aF) nr ,39 5 1 '86) 146 (295) 1,54 3 92 72 1162) M.P C (aF) Sol, in H2O j Other , g/IOOg j Solvents dec 1 ale -15 ! sol. '51 1 j1 1 1 52 -84 (-119) -163 | si. sol (-261) ale Misc, Ret BDH BDH 1074 Triisobutyl Aluminum (C4Hgt3AI 3 33 79 <0 <4 32) (< 391 114 '237) 4 '39) Al A 1075, Trimethyl Amine Ich3)3m 1076 5,9,1Q-Tnmethyi-1,2-8en?anthracene (CH 3)30-1 gH 13 7a ................... 18 .... 1077 6,9.10`TrimeihyM,2-Ben2anthracene (CH3)3Ci gH-] 3 1078 Tnmethyl Borate SIOCh3)3 18 ! __________ 1 13 3F5,5'Tnmethy)-2'Cvelohexe' none, see tso-Phorone 1079. 2,2,4-Trimethyl Pentane <CH3)3C CH2 CH(CH3)2 is ; 1080 2,4,4-Tnmethyl-2-Pentane (CH3)2C=CH C(CH3)3 18 1081, 1,3,5-T rmitrobenzene C6H3(N02)3 6 3 CAR 4 0 66 20 -13- -8 190 2-11 6 4 -117 1 V, sol, ale , bz BDH, (8-18) (374) (39) (-1791- MCA MGB CAR 2 1 2 2 3 1 92 3 6 <27 f< SOI 67 (153) -29 | dec, ( -20) MeOH ii : __________ __________ ^1L_____________________________ . -------- i ! __________L : t --------------------- !--------------------------! 1 3 0 69 3.9 -12 418 1 1-6.0 99 -107 i insol. | si sol , 3DH (10) (784) (210) (-1611 ale, i 3 0 72 3.9 2 (35) 112 (234) -i07 ! msol (-161) | 4 4 1 69 exp, 121 1 si. sol. ; ace b2 (250) | i CMA 046097 SUBSTANCE FORMULA Trinitrophenol, see Picric Acid Waste Dis posal Pro. cedure (See Mil Tl V iacgih: PPM i mg M ) NFPA 704M System Health Fire React. ignit Vap. FI Pt. Temp 0.P, M P. Sol. in Sp, Dens ;C c Limit* 2C i 5C HjO Other Gr. (A.r=J) (5F1 lcF) (FI laF) g/100g Solvents Misc, Ref 1082, 2,4,6-Trinitrotoluene ^H3cbH21 1 083 1,3,5 TriQxane OCH2OC^2^CH2 1084 Triphenyl Phosphate iC6H50)3 po 6 ii 5) - 4 4 1 65 Skm 18 2 2 0 1 17 7b 131 2 1 0 1 21 exp 240expj 81 |4@4) (178) 45 11 13loc 414 (777) 3 6-29 115 (239) 62 1144) 220 (4281 245 ,473) $>1 1mm 49 (120) msol v sol msol ace , bz, ale , bz cs2 | ; ale., be, 1085 Triphenyl Phosphine ic6hS'3 p 1086 Tnpropylamme <c3h7)3 n 7b 7a 32 1 19 180 i356)oc 2 2 0 75 4.9 41 1106'oc >360 80 (680) (176) msol ale , bz 156 -94 (313) ' (-137) si, sol ale 108?, Trisodiurn Phosphate Na3P04 12H20 1 11 2 1 62 74dec, si. sol (165) i Triton, see Trinitrotoluene 1 i |1 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ _ _ _ I_ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ L__ _ _ _ l_ _ _ _ _ _ _ _ _ _ i_ _ _ _ _ _ _ _ _ _ ._ _ _ _ _ _ _ _ _ _ : .. . . . . . . . . . . . . . . . . . . . 1088 Tntotyl Phosphate <CH3C6H4)3P04 1089 Turpentine c10h16 ! 7, s 2 1 0 1 17 12,7 225 385 (437) j (725) i 410 , 1 1 (770) ; (52) 18 ioo : i 3 0 87 4 6 35-39 253 8 153-75 (95-102)1 (487) 1307-47)1 1 A: A S Dm A' A 1090 Uneymmetrical Dimethyl ! 16 53 3 1 79 1 94 ^ -15 i 249 2-95 63 1 -58 v sol die M*Ok4 MCA Hydrazine (CH3)2NNH2 ! 5) | (480) (145) 1 (-72) 1 1091 Uranium U 27k | ( 25) | 3 3 19,05 3813 | 1130 16905) | (2066) msol, a; A 1 i PAGE 117 CMA 046098 SUBSTANCE/FORMULA Dis TLV posal (ACGIHI Pro PPM cedure , (mg/M'3) (See VI) 7Q4M System Health Fire React. W092 Uranium, Insoluble Compounds 27k 25 3 093 Uranium, Soluble Compounds Z7k ( 05) 1 3 1094 Uranium, Nitrate UQ2<NQ3)2 6H2O 27k ( 05) 1 0 1 1095 Urea H2NCONH2 26 0 Igmt. \ Vap. FI. Pt. Temp, Sp. Dens. ; *c 5C Limits Gr. ; (A.r=1> ! (QF) 1 (F) ! % |i I B.P, *C (F) ! 2 81 1 32 ! 11 118 (2441 dec M.P 5C (F) H2O , Other g/100g j Solvents ,i ! msol 1 ! j Mi sc. Rt 59 (138) sol .......... i.................... , ale ace. " V, sol 1 133 ale 1 NTTC 1096 Valeratdehyde CH3CH2CH2CH2CHO 2 81 3 0 12 1 154) ' 102 -92 si, sol, ale NTTC (217) ( 134) 1097 Valeric Acid C4H9COOH 1098 Vanadium Dichloride VCI2 1099 Vanadium Qxyrnchloride VOCI3 MOO Vanadium Pentoxide v305 1100d Vanadyl Sulfate VOSO4 1 101 Varnish 1 102 Vinyl Acetate CH3COOCHCH2 Vinyl Bromide, see Bromoethylene Vinyl Butyl Ether see Butyl Vinyl Ether 24a 1 27 i 3 27i ( 1) 27i ' ( 1) 2 2 27i IS 3 18 2 1 3 94 3 23 3 5 96 (205)oc i 1 83 3 36 186 (367) -35 1- 31) so! dec =ilc ale 127 (261) -77 (-107) dec I750dec 690 (3182) (1274) si sol ale 0 176-248 1 nttc 1 2 94 30 -8 , 427 2 6-13,4 73 100 msol org, sol, NTTC,MCA (18) i (800) (163) (-148) II PAGE 118 % T, i li 1 1 i U J ) CMA 046099 ) SUBSTANCE FORMULA 1 1 Q3 Vinyl Chloride ch2chci Vinyl Cyanide, see Acr-ylonitnte 1 104 Vinyl Ether CH2CHOCHCH2 1105 Vmyhdene Chloride CH2CCl2 Vinyl Toluene, see Methyl Styrene 1106 Warfarin C t9H16O4 1107 Xenon Xe Xenylamme, see 4.8iphenylamine 1108 m-Xylene C6H4(CH3)2 1109. 0-Xylene CgH4(CH3)2 1110, p-Xyiene C6H4(CH3)2 1111, Xylenol C6H3(CH3I2 OH 1 % Waste Ois po&al Pro. cedure (See VP TLV IACGIH' PPM img,M ) N FPA 704M System Health Fire React. 4b 50QC 2 4 2 or -OOCO Igmt. Vap. FI Pt Temp. Flam B.P. Sp. Dens, 3C =C Limits aC Gr (Airwl) (aF) <F) % (3FI 91 2 15 472 (8821 4-22 -14 (71 M P Sol, m C h2o Other (3F) g/lOOg Solvents 154 si. sol (-245) die, Misc, Ret, MCA -----------------------1 15 3 2 77 24 <-30 360 1 7 27 39 ale. ace i< 22) (680) 1102) 4b 5 - 4 2 13 34 - 5oe 458 5 6-11,4 37 -122 insol (5) (856) (99) (-188) MCA 18 ( 1) 26 3 0 5 89 161 (322) msol ale , ace -108 ( -162) -112 (-170) 240 18 100 2 3 0 87 29 (84) 528 1982) 1 1 1-7 0 139 (282) -48 (-. 54) msol org sol BOH NTTC MCA 18 100 2 3 0! 90 11 32 464 1 0-6 0 144 -26 insol org sol Al A, (90) (867) (291) (-15) BDH, NTTC MCA 18 100 2 3 0i 36 ""j 18 3 1 : ! 27 (SI) 529 (984) 11-70 138 (280) 13 (55) msol org sol 218 (424) 75 (1671 si sol ale A1A BDH, NTTC, MCA SOH PAGE 119 CMA 046100 SUBSTANCE FORMULA ^112 Xyhdine C6H3'CH3)2NH2 m-i 13 Yttrium Y Waste Dis patal Pro cedure (See VIi TL V iACGIH. PPM img/M ) nfpa 704M System Health Fire React, 55 31 0 Skin Sp Gr 99 26 d / 2 4 34 n 14 Zmc Zn 27a M5) 0 1 l 7 14 1115 Zmc Acetate Zn(C2H302>2 1116 Zmc Chlorate Z0(C103)2 4H20 1117 Zmc Chloride Zn Cl2 11 0 1 34 012a 2 2 2,15 011 M) 2 2 2,91 1 1 IS Zmc Oxide ZnO l 119 Zirconium Zr 1120, Zirconium Compounds 26 (5) 3 5 47 126 (5) 4 1 65 11 (5) 1 1121 Zirconium Hafnium Powder ! 26 (5) 1 4 1 Vap Dens. (Air=1| FI. Pt -c (5F) Igmt T emp, 'C fsF) Flam Limits B.P, 'c ( F) M P, 'C (4F) Sol m h2o g/1 OOg Other Solvents 4 2 97 (2061 224 (435) ^ - 15 K5> si sol ale 2927 15300) 1500 '2732) si, dec.i 905 (1661) 419 (787) msol 200dec, (3921 30^0 ale. 60<Jec '140) 2S220 ale , ace 732 (1350 283 (541) 4322i5 ale, 1975 (3587) si SOI 1 260 (500) 3578 <5252) 1S50 (3362) msol 20 i insol, , Misc, Rat, BOH Al A AlA, NSC MC A, NSC r ii i i J i vi 1 J PAGE 120 3 * L CMA 046101 SECTION VI. WASTE DISPOSAL PROCEDURES PAGE 121 CMA 046102 -------------------------------------DISPOSAL PROCEDURE ORGANIC ACID HALIDES Rubber gloves, self-contained breathing apparatus (or work in an effective fume hood with full face shield), laboratory coat. Cover with sodium bicarbonate. If a small quantity is involved, scoop the mixture into a large beaker of water and let stand for a few minutes. Slowly pour into the drain with copious amounts of water. If a large quantity is involved, scoop the resulting bi carbonate mixture into a plastic bag, cardboard box or small fiber drum. This material can then be burned in an incinerator or spread on the ground and flooded with water. The site of the spill should be washed with soapy water. Slowly sift or pour into a large glass or plastic vessel containing a layer of sodium bicarbonate. Mix thoroughly and add slowly to a large container of water with stirring. Slowly pour this mix down the drain with copious amounts of water. Acetyl bromide Acetyl chloride Benzene sulfonyl chloride Benzoyl chloride Butyryl chloride Chloroacetyl chloride 3-Chloropropiony! chloride o-Chlorobenzoyl chloride Crotonyl chloride Dichloroacetyl chloride Oxalyi chloride Propionyl chloride Trichloroacetyl chloride f CMA 046103 DISPOSAL PROCEDURE INORGANIC HALIDES Wear: Rubber gloves, self-contained breath ing apparatus (or work in fume hood), laboratory coat. For the more active compounds work from behind a body shield. Spins: Cover with excess sodium bicarbonate. If a small quantity is involved, scoop the mixture into a large beaker of water and let stand for a few minutes. Slowly pour into the drain with copious amounts of water. If a large quantity is involved, scoop the resulting bi carbonate mixture into a plastic bag, cardboard box or small fiber drum. This material can then be burned in an incinerator or spread on the ground and flooded with water. The site of the spill should be washed with soapy water. Package lots: Sift or pour onto a dry layer of sodium bicarbonate in a large evaporating dish. After mixing thoroughly spray with 6M-NH,0H while stirring. Cover with a layer of crushed ice and stir. Con tinue spraying with 6M-NH.OH. When the smoke of NH,CI has partly sub sided add iced water and stir. Dump this slurry into a large container, Re peat until all has been treated. Neu tralize* and slowly siphon the sus pension into the drain with excess running water. * If excess of 6M-NH1OH has been used, neutralize with 6M-HCI (use litmus pacer indicator). If acidic, neutralize with 6M-NHOH. ^^^PAGE 124--DISPOSAL PROCEDURE lb Examples: Aluminum bromide, anhydrous Aluminum chloride, anhydrous Chlorosulfonic acid Ferric chloride, hexahydrate Germanium tetrachloride Silicon tetrachloride Stannic chloride Tin tetrachloride Titanium tetrachloride _INORGANIC HALiDES CMA 046I04 ALDEHYDES DISPOSAL PROCEDURE Wear: Rubber gloves, self-contained breathing apparatus, laboratory coat. Spills : Eliminate all sources of ignition and flammables. Small--Absorb on paper towel. Evapo rate in fume hood and burn the paper. Large--Cover with sodium bisulfite (NaHSOi). Add small amount of water and mix. Scoop into large beaker. After one hour wash down the dram with a large excess of water. Wash site with soap solution. Package lots: (CHOICE OF PROCEDURES) 1 Absorb on vermiculite. Burn in an open pit or open incinerator. 2 Dissolve in a flammable solvent (such as acetone or benzene). Spray into the fire-box of an incinerator equipped with an afterburner, Examples: Acetaldehyde Acrolein Acrolein dimer o-Anisaldehyde Benzaldehyde Butyraldehyde Caprylaldehyde Chloral Chiora Ihydrate Chloroacetaldehyde Cinnamaldehyde Crotonaldehyde iso-Decaldehyde 2-Ethyl-3-propylacrolein Formaldehyde Formalin (MeOH free) Formalin (15% MeOH) Furfural Glutaraldehyde Glyoxal Paraformaldehyde Paraldehyde Propionaldehyde Salicylaldehyde Valeraldehyde % ALDEHYDES DISPOSAL PROCEDURE 2-PAGE 125 CMA 046X05 3 disposal procedure____ ALKALI AND ALKALINE EARTH METALS, METAL ALKYLS, AND ALKOXIDES Package lots: Examples: arge face shield, labo ratory coat. (Class D fire extinguisher should be available) Spills : Small--Cover with excess dry soda ash or sodium bicarbonate. Mix and add slowly to butyl alcohol. After 24 hours dilute and add to drain with large excess of water, OR Large spill--Mix with dry soda ash or sodium bicarbonate. Scoop into a dry bucket. In a remote area spread onto a large iron pan, Cover with scrap wood, paper and ignite with an excelsior tram. OR--Bum in an open pit incinerator. OR--Direct "dry" steam onto the waste, spread on an iron pan. Beware of splatter. Aluminum alkyls Aluminum ethoxide n-Butyllithium Calcium Chlorodiethylalummum Diethyl zinc Lithium Potassium Sodium Sodium ethoxide Sodium methoxide Sodium-potassium alloys Triethyl aluminum Triisobutyl aluminum !l WARNING: Possible Violent Reaction with Water ;1 3 ^^AGE 126--DISPOSAL PROCEDURE 3 ALKALI AND ALKALINE EARTH METALS, METAL ALKYLS, AND ALKOXIDES ----------------------------------------------------------------------------------- ----- ---------------------------------------------------------------- CMA 046106 ----------------------------------DISPOSAL PROCEDURE CHLOROHYDRINS, NITROPARAFFINS Wear: Neoprene gloves, plastic laboratory coat, self-contained breathing appara tus. Provide good ventilation, Spills: Eliminate all sources of ignition. On skin--Wash immediately with soap solution. Rinse thoroughly. On clothing--Remove clothing immedi ately and place m a fume hood. Wash clothing before wearing again. Shoes are difficult to decontaminate and may have to be discarded and burned. On bench and floor--Cover with soda ash. Mix and spray with water. Scoop into a bucket of water. Let stand two hours. Neutralize* and wash into sewer with large excess of water. Wash site with soap solution. * Neutralize With 6M-HCI. Package lots: (CHOICE OF PROCEDURES) 1 Pour or sift over soda ash. Mix and wash slowly into large tank. Neu tralize and pass to sewer with excess water. 2 Absorb on vermiculite. Mix and shovel into paper boxes. Drop into incinerator with afterburner and scrubber. CyClonite-ROX: Burning not recommended except m an area equipped to contain a detonation. Decompose cyclomte-RDX by adding slowly to 25 times its weight of boiling 5% sodium hydroxide. Boil for 1/2 hour, CHLOROHYDRINS, NITROPARAFFINS Examples: 150-Amyl nitrate iso-Amyl nitrite 1-Chloro-l-nitropropane Chloropicrin Cyclomte-RDX** 1,1-Dichloro-l-nitroethane EPN Ethylene chlorohydrin Ethylene nitrate Ethyl nitrite Methyl ethylmtrosocarbamate Nitroethane Nitromethane Nitropropanes Propyl nitrate Tetramtromethane DISPOSAL PROCEDURE 4a--PAGE 127 CMA 046107 DISPOSAL PROCEDURE______________________ ORGANIC HALOGEN AND RELATED COMPOUNDS Wear: Rubber gloves, self-contained breath ing apparatus, laboratory coat. Spills : Eliminate all sources of ignition Ab sorb on paper towels or with vermicu lite. Place on an iron, glass or plastic dish in a hood. Allow to evaporate. Burn the paper or vermiculite. Wash site with soap solution. Package lots: (CHOICE OF PROCEDURES) 1 Pour onto vermiculite, sodium bicarbonate or a sand-soda ash mixture (90-10). (If a fluoride is present, add slaked lime to the mixture.) Mix and shovel into paper boxes. Place in an open incinerator. Cover with scrap wood and paper. Ignite with an excelsior train; stay on upwind side. Or dump into a closed incinerator with afterburner. 2 Dissolve in a flammable solvent. Spray into the fire box of an inciner ator equipped with afterburner and scrubber (alkali). Examples Aldrm Ally! bromide Aliyl chloride Allyl chloroformate Aliyl iodide Amyl bromide Benzal chloride Benzotrichloride Benzotrifluoride Benzyl bromide Benzyl chloride Benzyl chloroformate Bromobenzene Bromoethane Bromoethylene o-Bromotoluene n-Butyl bromide n-Butyl chloride t-Butyl chloride Chlordane Chloroacetophenone Chlorobenzene Chlorocresols Chlorodiphenyl 2-Chloro-2-methyl propene Chloronaphthalene CMA 046108 EXAMPLES--Continued Chloroprene Ch lorotrif luoroethy 1 ene Dibutyl dichlorotm 1, 4-Dichlorobutane 1, 3-Dichloro-2-butene 1, 1-Dichloroethane 1, 2-Dichlorcethylene 1, 2-Dichlorcpropane 1, 3-Dichloropropene Dieldrln Diethyl aluminum chloride Diethyl sulfate Dimethyl sulfate Dimethyl sulfoxide Dodecyl sodium sulfate Epichlorohydrin Ethyl bromoacetate Ethyl chloride Ethyl chloroacetate DISPOSAL PROCEDURE Ethyl chloroformate Ethylene dibromide Ethylene dichloride Ethyl fluoride Ethyl fluoroacetate Ethyl iodide Eiuorcethylene Heptachlor Hexachlorobenzene Hexachloronaphthalene Lindane Methoxychlor Methyl bromide Methyl chloride Methyl chloroformate Methyl iodide Octachloronaphthalene Octafluoro-2-butene Octafluoropropane Pentachloroethane Pentachloronaphthalene Pentachlorophenol Propargyl bromide Propyl bromide Propyl chloride Propylene disulfate Sodium fluoroacetate Sodium pentachlorophenate 1, 2, 4, 5-Tetrachlorobenzene Tetrachloroethane Tetraethyl lead Tetramethyl lead Tributyl chlorotin 1, 2, 4-Trichlorobenzene Trichloronaphthalene 1, 2, 3-Trlchloropropane Vinyl chloride Vinylidene chloride ORGANIC HALOGEN AND RELATED COMPOUNDS DISPOSAL PROCEDURE 4b--PAGE 129 CMA 046109 DISPOSAL PROCEDURE SUBSTITUTED ORGANIC ACIDS M r self-contained breath ing apparatus or all-purpose canister respirator, laboratory coat. SpiHS : Eliminate all sources of ignition. Turn on the fume hood if acid is volatile. Cover the spill on bench and floor with excess sodium bicarbonate and vermiculite. Mix and scoop into a large beaker of water. When reaction is com plete, pour down the drain with a large excess of water. Wash site with soap solution. Package lots: (CHOICE OF PROCEDURES) 1 Pour onto excess sodium bicarbo nate, Mix and scoop into a bucket. Dump into a 55-gal. drum and fill with water. After 24 hours slowly pour into drain with large excess of water. 2 Pour onto vermiculite in an open incinerator, Cover with scrap wood and paper. Pour waste alcohol over all and ignite with an excelsior tram. Stay on upwind side. 3 Dissolve in a flammable solvent such as waste alcohol. Spray into an incinerator with an afterburner and scrubber. Examples Benzene sulfonic acid Bromoacetlc acid Chloroacetic acid Dichloroacetic acid Ethylenediamine tetracetic acid (EDTA) Fluoroacetic acid lodoacetic acid Methanesulfonic acid Trichloroacetic acid 2, 4, 5-trichlorophenoxy acetic acid Trifluoroacetic acid J ] t 1 i PAGE 130--DISPOSAL PROCEDURE 4c SUBSTITUTED ORGANIC ACIDS I CMA 046110 DISPOSAL PROCEDURE AROMATIC AMINES Wear.- Butyl rubber gloves, plastic laboratory coat, self-contained breathing appara tus. SpHlS : On skin and clothing--Wash skin with strong soap solution immediately. Rinse thoroughly. Contaminated cloth ing should be removed, dried, and washed with strong soap solution--or destroyed. It may be necessary to de stroy shoes by burning. Small spills--Absorb liquids on paper towels, Brush solids onto paper. Place in an iron pan and allow evaporation in the fume hood. Add crumpled paper and burn. Wash site with strong soap solution. Large spills--Cover large spills with sand and soda ash mixture (90-10). Mix and shovel into a cardboard box. Pack with much excess crumpled paper. Burn in an open pit or m an incinerator with afterburners and scrubber. Package lots: (CHOICE OF PROCEDURES) 1 Pour or sift onto a thick layer of sand and soda ash mixture (90-10). Mix and shovel into a heavy paper box with much paper packing. Burn in incinerator, Fire may be augmented by adding excelsior and scrap wood. Stay on upwind side. 2 Waste may be dissolved in flam mable solvent (alcohols, benzene, etc.) and sprayed into fire box of an inciner ator with afterburner and scrubber. Examples Acridine 2-aminodiphenylene oxide 2-aminopyridine Aniline Anisidines 2-anthramine Auramine Aziridine Benzidine* Benzyl amine N-4-biphenyl acetohydroxamic acid 2-biphenyl amine Chloroamlmes 1,2,5, 6- Dibenzacndine 1,2, 7, 8- Dibenzacridme 1,2, 5,6- Dibenzcarbazoie 3,4, 5,6- Dibenzcarbazole Dibenzyl amine N, N-diethyl aniline 3,3'-dimethoxy benzidine " N, N-dimethyl aniline Diphenyl amine N-ethyl aniline Ethyl morpholine 1-methyl- 2-naphthylamine Morpholine 1-naphthylamine 2-naphthylamine' Nicotine p-phenylenediamme Phenylethanolamme Phenyl- 2-napththylamme Pico 11 nes Pyridine Qumaldine Quinoline 8-Qu i no 11 no I 4-Stilbenamme Strychnine Toluidines Xy I id i nes * Carcinogenic t AROMATIC AMINES DISPOSAL PROCEDURE 5--PAGE 131 CMA 046111 DISPOSAL PROCEDURE AROMATIC HALOGENATED AMINES and NITRO COMPOUNDS jutyl rubber gloves, protective labora tory coat, self-contained breathing apparatus, protective shoes. SpillS: On skin--Wash with strong soap solu tion immediately. Rinse well. Contaminated gloves, clothing, shoes-- Remove and dean at once or destroy by burning. Small spills on tables or floor--Absorb liquid spills on paper towels or vermiculite; sweep solid spills onto paper, Put on an iron pan in the fume hood and allow to evaporate. Burn the paper or vermiculite in the absence of other flammables. Wash the site thoroughly with strong soap solution. Large spills--Absorb or mix with ver miculite, sodium bicarbonate or sand. Package this in a paper carton and burn in an open pit. Use fuel such as crumpled paper and wood splinters. Wash site thoroughly as above. Package lots: (CHOICE OF PROCEDURES)*** 1 Pour or sift onto sodium bicarbo nate or a sand-soda ash mixture (90-10). Mix and package in heavy paper cartons with plenty of paper packing to serve as fuel. Burn in an incinerator. Fire may be augmented with scrap wood. 2 The packages of =-1 may be burned more effectively in an incinerator with afterburner and scrubber (alkaline). 3 The waste may be mixed with a flammable solvent (alcohol, benzene, etc.) and sprayed into the fire cham ber of an incinerator with afterburners and scrubber. "** See page U3 Examples Brucine Carbazole 1- Chloro-2, 4-dimtrobenzene Chloro-2-naphthylamine Chloro-nitroamlines Chloro-nitrobenzene Chlorophenals 2, 6-Dibromo-N-chloro-p-benzoquinonimine 2, 5-Dichloroan i I me Dichlorobenzene 3, 3'-Dichlorobenzidine' 1, 3-Dichloro 5, 5-dimethylhydantoin 2, 4-Dichlorophenol 2- Dnmethylaminofluorene 9,10-Dimethy 1-1. 2-benzanthracene N, N-Dimethyl-4-blphenylamlne Din i troan Mine m-Dimtrobenzene" o-Dimtro benzene** p-Dmitrobenzene** 4, 6-Dinitro-o-cresol 2. 7-Dimtrofluorene 2. 4-Dmitrophenol** * Carcinogenic * Explosive Other nitro compounds may also be unstable ^^PAAGGE 132--DISPOSAL PROCEDURE 6 \ AROMATIC HALOGENATED AMINES and NITRO COMPOUNDS CMA 046112 EXAMPLES--Continued 1.4-Dimtropiperazine .2,4-Dimtrotoluene** jElon Endrin 4-Ethoxy-2-nitroanihne N-2-Fluorenylacetamide 4-Fluoro-4-biphenylamine 2'-Fluoro-4'-phenylacetanilide 4'"-Fiuoro-4'-phenylacetamlide Methylene bis-phenylisocyanate Methyl isothiocyanate N-methyl-N-nitrosoacetamide N-methyl-N-nitrosoallylamine N-methyl-N-nitrosoaniline N-methyl-N-nitrosobenzylamine DISPOSAL PROCEDURE 1-Methyl-l-nitrosourea N-Methyl-N-nitrosovinylamine 1- Methyl pyrole N-Methyl-N-2, 4, 6-tetranitroaniline 3- Nitroacetophenone m, o-, p-Nitroanilmes Nitrobenzene Nitrobiphenyl 2- Nitrofluorene ^-Nitronaphthalene Nitrophenols 4- Nitroquinoline-N-oxide N-Nitroso-N-methylaniline 4-Nitrosomorpholine l-Nitro$opiperazine N-Nitrosopiperidine m-, o-, p-Nitrotoluenes Picric acid** Piperidine Tetrachloronaphthalene N, N, N', N'-tetramethyl-3, 3'-dimethoxybenzidine N, N, N', N'-tetramethylenediamine Toluene-2,4-diisocyanate Trinitrobenzene** Trinitrotoluene** *+ Destruction by chemical decomposition is rec ommended for dmitro, tnmtro and other com pounds with explosive potential. Add the material slowly, while stirring, to 30 times its weight of a solution prepared by dis solving 1 part sodium sulfide (Na,,S.9H,0) in 6 parts of water. For unstable acidic materials (e.g. Picnc acid), dissolve m 25 times its weight of a solution made from 1 part sodium hydroxide and 21 parts sodium sulfide in 20o parts of water. Some H;S and NH is evolved VAROMATIC HALOGENATED AMINES and NITRO COMPOUNDS ** Explosive. Other mtro compounds may also be unstable. DISPOSAL PROCEDURE 6--PAGE 133 CMA 046113 I 7a DISPOSAL PROCEDURE. l. ALIPHATIC AMINES Butyl rubber gloves, face shield or all purpose canister respirator, laboratory coat. Spills.- Liquid or solid--Cover with sodium bisulfate, Spray with water and wash into drain with large excess of water. Package lots: (CHOICE OF PROCEDURES) 1 Add the contaminated amine to a layer of sodium bisulfate in a large evaporating dish, Spray with water. Make neutral and wash into the dram with large excess of water. 2 Dissolve in a flammable solvent (e.g., waste alcohols). Burn in an open pit by means of an excelsior train. Stay on the upwind side. 3 Solution of -2 may be sprayed into the fire box of an incinerator with afterburner and scrubber. Examples: Allyl amine Amyl amine Aminoethylethanola- mme Butyl amine uo-Butyl amine Tert-Butyi amine Cyclohexylamine Dibutyl amine Dicyclohexylamine Diethanolamine Diethylamine 2-Diethyl aminoethanol Diethylenetriamine Dii5opropy!amine Dimethylamine Ethanolamine Ethylamine Ethylene diamine N-Ethyl-N-mtroso- N-butylamine N-Ethyl-N-N nitrosovinylamme n-Heptylamine Hexamethylenetetra mine 1-6-Hexanediamine Hydroxylamme Hydroxylamine hydrochloride Lutidine N-Methyibutylamme Monomethylamme N-Nitrosodiethanoia- mine N-Nitrosodimethyla- mine* 1 3-Propanediamine Propyl amines Propylene imme Pyrrolidine Tetraethylenepenta- mine Triamylamine Tri-n-butylamine Tri-ethylamine Triethanolamine Triethylene tetramine Tnmethylamine Tripropylamine * Carcinogenic. PAGE 134--DISPOSAL PROCEDURE 7a \ ALIPHATIC AMINES 'it CMA 046114 ----------------------------------DISPOSAL PROCEDURE ORGANIC PHOSPHATES AND RELATED COMPOUNDS Wear: Rubber gloves, self-contained breath ing apparatus, laboratory coat. Spills: Absorb with vermiculite or paper towels. Scoop the mixture into a plastic bag. Take bag outside to incinerator or pad and burn, If an incinerator is not avail able, set the bag in a pan of waste flammable solvent and burn. Package lots: (CHOICE OF PROCEDURES) 1 * Take packages to an open incin erator. Stay on upwind side and mix with equal parts of sand and pulverized limestone, Wet down with a flammable solvent (benzene or alcohol). Ignite from a safe distance with an excelsior train. 2 Shovel mixture of =1 into a paper box and drop into an incinerator with an efficient afterburner. Alkaline scrub bing will prevent escape of any oxides of phosphorous and arsenic, Examples: 0-Chlorophenyl diphenyl phosphate Dibutyl phosphate Dtbutyl phosphite Dichlorophenyl phosphine Diethyl ethyl phosphate Diisopropyl fluorophosphate Dimethyl-1, 2-dibromo-Z, 2-dichloro-ethyl phosphate Grain fumigants Hydroxy dimethyl arsine oxide Malathion Methyl parathion 1-Naphthylisothiocyanate Parathion Phosdrin Ronnel Systox Tetra ethyl dithlono pyrophosphate Tetra ethyl pyrophosphate Tributyl phosphate Triphenyl phosphate Triphenyl phosphine Tritolyl phosphate ORGANIC PHOSPHATES AND RELATED COMPOUNDS % DISPOSAL PROCEDURE 7b--PAGE 135 CMA 046115 DISPOSAL PROCEDURE 8The organic azides and heavy metal AZIDES and AZO-COMPOUNDS azides are explosive. Alkali and alka line earth azides are not considered ex plosive under normal laboratory con ditions. contamination with a 10% ceric am monium nitrate solution. Large spills or Examples: 2, 2'-Azonaphthalene Azoxybenzene Diazo methane Dimethyl amino azo benzene-2-naphthalene Keep stock of all azides very low. Stamp date and receipt on package. Package lots: (CHOICE OF PROCEDURES) 2, 3-Dimethyl-azo benzene Hydra2oic acid 3-Methyl-4-dimethyl amino-azobenzene Wear: Leather gloves, heavy face shield, labo ratory coat. Work from behind a barri cade (body shield or wall). Avoid un necessary heat, friction or impact. "Kill" by adding to a greater-thanstoichiometric amount of ceric am monium nitrate solution with agitation sufficient to provide suspension of all solids. Cool the reaction. l-Phenylazo-2-naphthol l-Ortho-tolylazo-2-naphthol Sodium azide Small spills: Absorb the liquid on paper or with vermiculite. If it is a solid, dampen and brush onto paper with great care. Place m plastic bag and take outside for burning. OR Sponge up with water, followed by de- PAGE 136--DISPOSAL PROCEDURE 8 AZIDES and AZO-COMPOUNDS CMA 046116 -----------------------------------------DISPOSAL PROCEDURE CARBON DISULFIDE Wear.- Rubber gloves, safety glasses, labora tory coat. If hood is not available wear self-contained breathing apparatus. Carbon dioxide fire extinguisher should be available. Spills : Eliminate flammables and all sources of ignition. Allow to evaporate or ab sorb with paper towels and evaporate in hood on an iron pan or glass dish. Burn the paper. Package lots: All equipment or contact surfaces should be grounded to avoid ignition by static charge. Absorb on vermiculite, sand, or ashes and cover with water. Transfer under water in buckets to an open area. Ignite from a distance with an excelsior train, If quantity is large, carbon disulfide may be recovered by distillation and repackaged for use. CARBON DISULFIDE DISPOSAL PROCEDURE 9--PAGE 137 CMA 046117 DISPOSAL PROCEDURE CAUSTIC ALKALI AND AMMONIA Rubber gloves, large face shield (wear al'-purpcse or special canister respira tor for NH;*), Laboratory coat. Package lots: Pour into large tank of water and neu tralize. Transfer to sewer with large excess of water. SpiHS: Solid--Sweep up, dilute and neutralize with 6M-HCI in a large bucket. Wash down drain with large excess of water. Solution--Neutralize and mop up--or use water-vac. Discharge to sewer with large excess of water. Examples: Ammonia, anhydrous Ammonia, aqua Calcium hydroxide (slaked lime) Calcium oxide (quick lime) Potassium hydroxide (caust-c potash) Sodium hydroxide (caustic soda) ^^PAPCAGE 138--DISPOSAL PROCEDURE 10 CAUSTIC ALKALI AND AMMONIA CMA 046118 DISPOSAL PROCEDURE INORGANIC SALTS Wear: Package lots.- Examples .* Rubber gloves, safety glasses, labora Add slowly to a large container of water. Alums Potassium acetate tory coat. Stir in slight excess of soda ash. If Aluminum chloride, Potassium carbonate fluoride is present add slaked lime also. hydrate Aluminum nitrate, Potassium ferrocyanide Spills: Let stand 24 hours. Decant or siphon into another container and neutralize hydrate Aluminum sulfate, Potassium fluoride Potassium hydrogen 1 Solutions---Cover with soda ash, mix and scoop into a beaker of water. with 6M-HCI before washing down drain with large excess of water. The sludge hydrate Ammonium fluoride Ammonium nitrate d i fluoride Potassium nitrate Sodium acetate Neutralize with 6M-HCI and wash down may be added to land fill. Ammonium Sodium benzoate thiocyanate * drain with excess water. Chromic (III) salts, Sodium fluoride 2 Solids--Collect in a beaker. Dis hydrates Cobaltous nitrate Sodium formate Sodium hydrogen solve in large amount of water. Add soda ash, mix and treat as above. Copper nitrate Cuprous chloride Ferrous Ammonium difluoride Sodium iodide Sodium nitrate If spill contains a fluoride, add slaked sulfate Sodium propionate * lime in addition to the above treatment. Ferrous chloride Sodium silicate Ferrous sulfate Sodium tetraborate Lithium carbonate Magnesium nitrate Stannic chloride, hydrate Zinc acetate Manganese sulfate Zinc chloride Molybdenum compounds (sol. Nickel nitrate Nickel sulfate INORGANIC SALTS DISPOSAL PROCEDURE U-PAGE 139 CMA 046119 DISPOSAL PROCEDURE OXIDIZING AGENTS face shield, laboratory coat. Body shield should be available for the more active agents. Replace face shield with self-contained breath ing apparatus for such agents as chlo rine and bromine. Spills : 1 Gas leak: If the valve is leaking because it cannot be closed (a common cccurrence), the gas can be bubbled through a reducer (sodium sulfite) and excess sodium bicarbonate solution. Be sure to include a trap in the line to prevent the solution being sucked back into the cylinder. If this cannot be done, the cylinder should be placed in or adjacent to a fume hood and left to bleed off. If the leak is in the valve assembly, a plastic bag can be fastened over the head of the cylinder which can then be taken outside or to a fume hood. page 140--DISPOSAL PROCEDURE 12a 2 If the oxidizer is a liquid or a solid--Cover with a reducer (hypo, a bisulfite, or a ferrous salt but not car bon, sulfur or strong reducing agents), Mix well and spray with water. A sulfite or a ferrous salt will require addition of some 3M-HjS04 to promote rapid reduction. Scoop slurry into a con tainer of water and neutralize with soda ash. Wash down the drain with excess water. Wash site thoroughly with a soap solution containing some reducer. Package lots.- Add to a large volume of concentrated solution of reducer (hypo, a bisulfite or a ferrous salt and acidify with 3M-H_.SOi). When reduction is com plete add soda ash or dilute hydro chloric acid to neutralize the solution. Wash into dram with large excess of water. Examples Ammonium dichromate Ammonium perchlorate Ammonium persulfate Barium chlorate Bromic acid Bromine tert.-Butyl chromate Bromic acid Bromine Calcium chlorate Calcium hypochlorite Chloric acid Chlorine Chlorine dioxide Cleaning solution (acid dichromate) Chromium oxide Chromium oxychloride Cleaning solution (acid dichromate) Fluorine Iodine Magnesium chlorate Magnesium perchlorate Nitrogen trifluoride Nitrosyl chloride Peracetic acid Perchloric acid Potassium and sodium perchlorates, chlorates, chlorites, dichromates, hypochlorites, per manganates, persulfates Zinc chlorate OXIDIZING AGENTS U r i* v llrl i i CMA 046X20 DISPOSAL PROCEDURE REDUCING SUBSTANCES Wear: Rubber gloves, safety glasses, labora tory coat. Work in hood or wear a respirator. Spills: Gas leak: Eliminate all sources of igni tion. If the valve is leaking because it cannot be closed, the gas can be bubbled through a calcium hypo chlorite solution. Be sure to include a trap in the line to prevent the solution being sucked back into the cylinder. Solid: Cover spill with soda ash or sodium bicarbonate. Mix and spray with water. If effervescent wait until reaction is complete. Scoop into a large beaker and cautiously add equal volume of calcium hypochlorite (reac tion may be vigorous). Add more water, stir, and allow to stand for one hour. Dilute and neutralize* the oxidized so lution and transfer to the drain with excess of water. Package lots.- If a gas,** bubble into soda ash solu tion. If a solid, mix with equal volume of soda ash and add water to form a slurry in a large container. In either case add calcium hypochlorite. Add more water if necessary and let stand two hours. Neutralize* the oxidized solution. Wash down drain with large excess of water. Examples Chromous salts Sodium bisulfite Sodium nitrite Sodium sulfite Sodium thiosulfate Stannous chloride Sulfur dioxide * Test with litmus. Neutralize with GM-HCI or 6M*NaQH a$ required. ** If a tank of reducing gas has developed a perma nent leak lower it upside down into a drum filled with water. Add a mixture of soda ash and cal cium hypochlorite. Continue the treatment until the tank i$ empty and the drum contains a solu tion of stable element or compound. REDUCING SUBSTANCES DISPOSAL PROCEDURE 12b--PAGE 141 CMA 046121 DISPOSAL PROCEDURE MERCAPTANS-and organic sulfides Rubber gloves, self-contained breath ing apparatus, laboratory coat. Spills : Eliminate all sources of ignition. Cover with calcium hypochlorite and mix. Scoop into a large beaker. After 12 hours, neutralize* if necessary. Wash to sewer with excess water, Wash site of spill with strong soap solution to which has been added some hypochlo rite. Package lots.- 1 As for spills. 2 Dissolve in waste alcohol or other flammable solvent. Burn in an inciner ator with an afterburner and scrubber to neutralize the SCL. Examples Ally I propyl disulfide Amyl mercaptan Benzyl mercaptan Butyl mercaptan Carbonyl sulfide** Crag 974 Dimethyl sulfide Diphenyl sulfide Ethanethiol Ferbam 2-Mercaptoethanol Methyl mercaptan'* Perchloromethyl mercaptan Thioacetamide 2, 2-Thiodiethanol Thioglycolic acid Thiophene Thiourea Tetramethylthiuram disulfide (Thiram) * Test with litmus. Neutralize with 6M-HCI or 6M*NH*OH as required. if quantity Is large, seal and return container to the supplier, if small, allow it to dissipate in a fume hood. %PAGE 142-DISPOSAL PROCEDURE 13 MERCAPTANS--and ORGANIC SULFIDES CMA 046X22 DISPOSAL CYANIDES AND NITRILES Wear: Long rubber gloves, self-contained breathing apparatus, laboratory apron or coat. Evacuate the laboratory and isolate the area during decontamination, Spills : Eliminate all sources of ignition and flammables. 1 General treatment: (a) Absorb liquid with vermiculite or on paper towel (sweep solid onto paper). Place on an iron or glass dish in a hood. Evaporate and burn paper. (b) On skin--Wash away immediately with much soap and water. 2 Hydrocyanic acid (HCN) leak:* Turn on fume hood. Allow gas to leak into a container of sodium hydroxide solution while stopping leak.** Add ex cess calcium hypochlorite to the alkali cyanide. Discharge the cyanate into the drain with excess water. 3 Cyanides: (a) Scoop into a larger beaker and make alkaline with sodium hydrox ide solution. Add to the slurry an excess of ferrous sulfate solution. After one hour, flush down the drain with excess water. OR (b) Add excess sulfur to the alkaline slurry of the cyanide. Heat to con vert to thiocyanate. Flush down drain with excess water. 4 Nitriles: Add excess of strong calcium hypochlo rite solution to produce a cyanate. Scoop slurry into a large beaker. After one hour flush down the drain with excess water. Wash site with soap solu tion containing some hypochlorite. * * Avoid possibility of suck back of alkaline material into liquid HCN * If the leak cannot be stopped set the tank upside down in a drum filled with a strong solution of sodium hydroxide and calcium hypochlorite. Con tinue the treatment until the tank is empty. CYANIDES AND NITRILES (Continued on next page) DISPOSAL PROCEDURE 14-- PAGE 143 CMA 046123 DISPOSAL PROCEDURE Package lots: ^IhuICL UF PROCEDURES) 1 Add with stirring to strong alkaline solution of calcium hypochlorite. Let stand 24 hours. Flush the cyanate down drain with large excess of water. 2 Liquid nitrile can be mixed with a flamable solvent and sprayed into an incinerator equipped with an after burner and scrubber. Examples: Acetone cyanohydrin Acetonitrile Adiporntrile Benzonttrile Benzyl cyanide Butyl nitrile n-Butyronitrile Calcium cyanide Chloroacetonitrile Crotonomtrile Cuprous cyanide Cyanamide Cyanoacetamide Cyanogen Cyanogen chloride Ethyl cyanoacetate Hydrocyanic acid Lactonitrile Potassium cyanide Propionitrile Sevin Sodium cyanide Succinonitrile Tetramethyl-succinomtrile Trich loroaceton i t r i 1 e CYANIDES AND NITRILES \i i* rl' ii: nt ^^PApCage 144--DISPOSAL PROCEDURE 14 % CYANIDES AND NITRILES CMA 046124 DISPOSAL PROCEDURE Wear: Rubber gloves, large heavy face shield (if in doubt use body shield also). Selfcontained breathing apparatus. Spills: Eliminate all sources of ignition and flammables. Absorb on paper towel. Evaporate from an iron pan in a hood. Allow time for vapors to completely escape the hood vents, then burn the paper. If large spill, absorb on much more paper or vermiculite and allow com plete evaporation from all surfaces. Use same precaution before burning paper. Package lots.- 1 Pour on ground in open area. Allow evaporation or ignite from a dis tance by means of a long fuse or excel sior train. 2 Dissolve waste in higher alcohol (e,g,, butyl), benzene, or petroleum ether. Incinerate. 3 PEROXIDE FORMATION. (See MCA Data Sheet SD-29 ethyl ether.) Ether of long standing in contact with air and exposed to light may contain peroxides, especially if stored in clear glass. Explosions have occurred when caps or stoppers were turned. (See MCA Accident Case History No, 603.) Transport cans or bottles to an isolated area (e.g., deserted quarry). Each con tainer should be wrapped in padding material or packed in sawdust. At site uncover containers and arrange an ex celsior train. From a safe distance puncture the cans near bottom with rifle fire. Ignite excelsior train. Local regulations must be observed. Examples Allyl glycidyl ether n-Amyl ether Anisole n-Butyl glycidyl ether Butyl vinyl ether Di-n-butyl ether Chloromethyl ether 2,2-Dichloroethyl ether 1,1-Diethoxyethane Diethylene glycol monoethyl ether Diglycidyl ether Diisopropyl ether Dimethoxy ethane Dimethoxy methane Dimethoxy propane Dipropylene glycol methyl ether 1, 2-Epoxy-3-phenoxy- propane 1, 2-Epoxy-propane Ethoxy acetylene Ethyl ether Ethyl vinyl ether Ethylene oxide Glycidol Guaiacol Hydroquinone monomethyl ether Methyl ether Methyl ethyl ether Methyl vinyl ether Phenyl ether Phenyl ether- biphenyl mixture iso-Propyl ether iso- Propyl glycidyl ether Vinyl ether ETHERS DISPOSAL PROCEDURE 15--PAGE 145 CMA 046125 DISPOSAL PROCEDURE "ubber gloves, self-contained breath ing apparatus. Impervious clothing recommended. Body shield should be available. Spills: Eliminate all sources of ignition and flammables. 1 On skin or clothing--Wash skin immediately. Remove contaminated clothing at once. 2 Absorb liquid with vermiculite or paper towels. Scoop mixture, paper or solids into a plastic bag and take to a burning pit or incinerator for burning. 3 Large spills--Collect the liquid with an aspirator such as used for re covering spilled mercury. Empty into a large beaker and neutralize with dilute sulfuric acid. Wash to drain with excess water. Wash site with soap and water. Package lots: (CHOICE OF PROCEDURES) 1 Dilute to at least 40% and neu tralize with dilute sulfuric acid. Flush to sewer with excess water, OR 2 Dissolve in large volume of waste alcohol or other flammable solvent and burn in an open pit. Ignite from a dis tance with an excelsior train. PAGE 146--DISPOSAL PROCEDURE 16 % tii HYDRAZINES Examples 1, 1-Dimethyl hydrazine (UDMH) Hydrazine Hydrazine salts Methyl hydrazine Phenyl hydrazine i' r- f HYDRAZINES - I CMA 046126 HYDRIDES DISPOSAL PROCEDURE Wear-. Package lots: Rubber gloves, fire proof clothing, face (CHOICE OF PROCEDURES) shield. Work from behind body shield 1 Mix with dry sand to avoid or stop where possible. Keep available pulver fire. Scoop into bucket and remove to ized dolomite or dry graphite for fire open area. Slowly spray with dry butyl fighting. alcohol. Later add water by fogging until last of hydride is destroyed. t Spills : Scoop the solid into a large container. Neutralize* with 6M-HCI. Let settle. * Eliminate all sources of ignition. Scoop Decant and flush to sewer with excess of water. Send sand residue to land fill. in dry plastic bag which has first been If the hydride is a gas (e.g. diborane, purged to inert gas. Remove to the silane, germanium hydride), dispose of * outside for burning. Flood the burned it by controlled burning. residues with water to ensure complete K destruction of hydrides. 2 Burn in iron pan or in open pit. I * Test with litmus-- neutralize with 6M HCI if necessary. I HYDRIDES Examples.- Aluminum borohydride Calcium cyanide Decaborane Diborane Germanium hydride Lithium aluminum hydride Lithium borohydride Lithium hydride Penta borane Potassium borohydride Potassium hydride Silane Sodium amide Sodium borohydride Sodium hydride DISPOSAL PROCEDURE 17-PAGE 147 CMA 046127 DISPOSAL PROCEDURE HYDROCARBONS, ALCOHOLS, KETONES, and ESTERS ^Wubber gloves, face shield, laboratory coat. Have all-purpose canister mask available. Spills : Eliminate all sources of ignition and flammables, 1 A gas leak from a faulty tank-- Keep concentration of gas below the explosive mixture range by forced ven tilation. Remove tank to an open area and allow dissipation to the atmos phere. Attempt to cap the valve outlet and return tank to the supplier, 2 A liquid--Absorb on paper. Evapo rate on an iron pan in a hood. Burn the paper. 3 A solid--Sweep onto paper and place in an iron pan in the hood. Burn the paper and compound. Package lots.- 1 A gas--Pipe the gas into the incin erator. Or lower into a pit and allow it to burn away. 2 A liquid--Atomize into an incinera tor. Combustion may be improved by mixing with a more flammable solvent. 3 A solid--Make up packages in paper or other flammable material. Burn in the incinerator. Or the solid may be dissolved in a flammable sol vent and sprayed into the fire chamber. 1 Examples Acenaphthene Acetone Acetylene Alizarin dye Allene Allyl acetate Allyl alcohol n-Amyl acetate 150-Amyl acetate sec-Amyl-acetate n-Amyl-alcohol iso-Amyl alcohol tert-Amyl alcohol Amylene iso-Amyl formate Anthracene Anthraquinone 1, 2-Benzanthracene Benzene Benzyl acetate Benzyl alcohol Benzyl benzoate Biphenyl Borneol Butadiene n-Butane iso-Butane 1-Butene 2-Butene n-Butyl acetate Iso-Butyl acetate sec-8utyl acetate tert-Butyl acetate n-Butyl alcohol iso-Butyl alcohol sec-Butyl alcohol tert-Butyl alcohol Butyl cellosolve n-Butyl formate iso-Butyl formate Butyl methacrylate iso-Butyl methyl ketone p-tert-Butyl toluene 1-Butyne 2-Butyrolactone Camphor Carbon monoxide Cellosolve Cellosolve acetate Cresols Creosote Croton oil Crude oil Cumene Cycloheptanone Cyclohexane Cyclohexanol Cyclohexanone Cyclohexene Cyclohexyl benzene Cyclopentadiene Cyclopentane Cyclopentanone Cyclopropane p-Cymene PAGE 148-DISPOSAL PROCEDURE 18 \ HYDROCARBONS, ALCOHOLS, KETONES, and ESTERS CMA 046128 EXAMPLES--Continued DISPOSAL Decahydronaphthalene n-Decane n-Decyl alcohol Diacetone alcohol 1, 2, 5, 6-Dibenzanthracene 1, 2, 5, 6-Dibenzofluorene 1, 2. 3, 4-Dibenzophenanthrene 3, 4, 8, 9-Dibenzpyrene Dibutyl tin diluarate Dibutyl oxalate Dibutyl phthalate Dicyclopentadiene Diethyl adipate Diethyl carbonate Diethylene glycol Diethyl ketone Diethyl malonate Diethyl phthalate 3, 4-Dihydropyran Diisobutyl ketone 2, 2-Dimethyl butane Dimethyl carbonate 1, 2 Dimethyl chrysene Dimethyl fumarate Dimethyl naphthalene Dimethyl propane Dimethyl phthalate Di-n-octyl phthalate Di-sec-octyl phthalate 1, 4-Dioxane Dipentene Dipentene monoxide Diphenyl methane Dodecane Ethane Ethanol Ethyl acetate Ethyl acetoacetate ^th^acr^lat^ Ethyl alcohol Ethyl-sec-amyl ketone Ethyl benzene Ethyl benzoate Ethyl butyl ketone Ethyl butyrate Ethyl crotonate Ethylene Ethylene glycol Ethyl formate 2-Ethyl hexanol Ethyl lactate Ethyl oxalate p-Ethyl phenol Ethyl silicate Furan Furfuryl alcohol Gasoline Glycerol Greases Heptane Hexane n-Hexanol 1- Hexene 2- Hexene sec-Hexyl acetate p-Hydroquinone 5-indanol Industrial gases (LHG) Isoprene Jet fuels Kerosene Ketene Lacquer diluent Ligroin Liquefied petroleum gas p-Mentha-1, 8-diene Mesityl oxide Methane Methyl acetate Methyl acrylate HYDROCARBONS, ALCOHOLS, KETONES, and ESTERS Methyl alcohol Methyl amyl alcohol Methyl-m-amyl ketone 6 Methyl-1, 2-benzanthra- cene 10 Methyl, 1, 2-benzanthra cene Methyl benzoate Methyl benzyl alcohol 2-Methyl-l-butene 2- Methy!-2-butene 3- Methyl-l-butene Methyl butyl ketone Methyl butyrate Methyl cellosolve Methyl cellosolve acetate 3- Methyl cholanthrene Methyl cyclohexane 2-Methyl cyclohexanol 2-Methyl cyclohexanone 4- Methyl cyclohexene Methyl ethyl ketone Methyl formate 2-Methyl furan Methyl isobutyI ketone Methyl isobutyrate Methyl isocyanate Methyl methacrylate 1-Methyl naphthalene Methyl-n-propyl ketone Methyl salicylate Methyl styrenes Methyl-toluene sulfonate Naphthas Naphthalene 1- Naphthol 2- Naohthol Natural gas Nickel carbonyl Nonyl phenol Octane 1-Octanoi 2-Octanol Oil, cocoanut Oil, fuel Oil, lubricating Oil, mineral mist Oil, olive Oil, peanut Oil, soybean Oil, vegetable Paraffin n-Pentane iso-Pentane 1, 5-Pentanediol 2, 4-Pentanedione 2-Pentanol Petroleum ether Phenanthrene Phenol Phenyl acetate Phenyl isocyanate o-Phenyl phenol Phorone iso-Phorone Phosgene solutions in benzene 2-Pinene Piperylene Pival Polyvinyl acetate emulsion Propane 1, 2-Propanediol Propargyl alcohol iso-Propenyl acetate iso-Propyl acetate n-Propyl acetate n-Propyl alcohol iso-Propyl alcohol Propyl benzene iso-Propyl benzoate Propylene Propylene carbonate 18 Propyl formate iso-Propyl formate Propyne Propyne-allene mixture Quinone Resorcinol Rotenone Stoddard solvent Styrene Tall oil Tallow Terphenyls Tetradecane Tetrahydrofuran Tetrahydronaphthalene 1-Tetralone Toluene Tridecanol Triethylene glycol Triethylortho-formate 5, 9,10-Trimethyl-l, 2-benzanthracene 6, 9, 10-Trimethyl-l, 2-benzanthracene Trimethyl borate 2, 2, 4-Trimethyl pentane 2, 4, 4-Trimethyl-2-pentane 1, 3, 5-Trioxane Turpentine Varnish Vinyl acetate Warfarin Xylenes Xylenols DISPOSAL PROCEDURE 18-- PAGE 149 CMA 046129 DISPOSAL PROCEDURE INORGANIC AMIDES and Derivatives TObber gloves, large face shield, pro tective laboratory coat. A large body shield should be available. Sift slowly into a large container of cold water, with agitation. When all has reacted, neutralize* and pour into drain with large excess of water. Eliminate all sources of ignition. Sweep up solid amide onto dry paper. Cau tiously add to cold water in small por tions with agitation. Neutralize* and discharge into drain with large excess of water. Ammonium sulfamate Monochloroamme Sulfamic acid Sulfamide Test with litmus. Neutralize with 3M-HCI or 6M'NHiOH as required. \PAGE 150--DISPOSAL PROCEDURE 19 INORGANIC AMIn(rS and DERIVATIVES DISPOSAL PROCEDURE ORGANIC AMIDES Wear: Package lots: Rubber gloves, safety glasses, labora Add to a flammable solvent (alcohol or tory coat. benzene). Pour into an iron pan in an r< Spills : open pit. Ignite. OR Spray into an incinerator. Oxides of Scoop into a plastic bag or onto a nitrogen may be scrubbed out with * paper towel. Remove to the outside, alkaline solution, add alcohol and burn in a safe place. r v i t 1 Examples: Acetamide Chlcroacetamide INI. N-Dimethylacetamiae Dimethylformamide Ethyl Acetanilide Formamide 2-Phenanthreneacetamiae 3-Phenanthreneacetamide ORGANIC AMIDES DISPOSAL PROCEDURE 20--PAGE 151 CMA 046131 21 DISPOSAL PROCEDUREINTER NON-METALLIC COMPOUNDS ^WTirgig rruubbbbeerr gglloo\ves, safety glasses or goggles, self-contained breathing ap paratus, laboratory coat. Recommended that work be done in an effective hood from behind a body shield or in an open barricaded area out of doors. NOTE--Some suppliers will collect unwanted cylinders of com pressed gases on request. SpHlS : Eliminate all sources of ignition. Gas leak (e.g., boron trichloride, chlo rine trifluoride). Allow gas to flow into a mixed solution of caustic soda and slaked lime. If possible, keep in a hood until cylinder is emptied. Liquid or solid--Cover with vermiculite, sodium bicarbonate or a mixture of soda ash and slaked lime (50-50). Mix and spray water cautiously from an \PAGE 152-DISPOSAL PROCEDURE 21 atomizer. Scoop up and add slowly to a large container of water (if too active continue spraying). When reaction is complete neutralize' and wash down the dram with a large excess of water. Wash site with soap solution. Package lots. Sprinkle or sift onto a thick layer of mixed dry soda ash and slaked lime (50-50) from behind a body shield. Mix and spray water cautiously with an atomizer. Scoop up and sift cautiously into a large volume of water, Neutral ize* and wash down the drain with large excess of water. Examples Boron fluoride-ethyl ether complex Boron tribromide Boron trichloride * Make litmus test Neutralize with 6M-NH,OH or 6M-HCI as required. Boron trifluoride Boron trifluoride complexes with acetic acid and methanol Bromine pentafluoride Bromine trifluoride Carbon tetrafluoride Carbonyl fluoride Chlorine trifluoride Iodine chloride Iodine pentafluoride Iodine trichloride Nitric oxide Nitrogen dioxide Oxygen difluoride Perchloryl fluoride Phosgene Phosphorus oxychloride Phosphorus pentachloride Phosphorus pentasulfide Phosphorus sesquisulfide Phosphorus tribromide Phophorus trichloride Silicon tetrafluoride Sulfur decafluoride Sulfur dichloride Sulfur hexafluoride Sulfur monochloride Sulfuryl chloride Sulfuryl fluoride Thionyl chloride Thienyl fluoride INTER NON-METALLIC COMPOUNDS IM CMA 046132 DISPOSAL PROCEDURE PEROXIDES, INORGANIC Wear: Package lots: Rubber gloves, large face shield, labo Use the above method for the encrusted tj ratory coat A body shield should be impure peroxide. Repackage any recov available. ft ered pure granular peroxide in glass containers with rubber stoppers. ft Spills: w Cover with at least double volume of sand-soda ash mixture (90%-10%). Mix e thoroughly and break up any lumps of peroxide. With a plastic scoop add slowly to a large beaker of sodium sul fite solution (3 or 4 liters) with stirring. Neutralize with dilute sulfuric acid. When settled decant the sulfate solu tion into drain with excess water. The sand can be sent to the landfill. Hydrogen Peroxide (spill or package lots); Dilute and wash down drain with excess of water. Examples: Hydrogen peroxide (3% to 90%) Potassium peroxide Sodium peroxide PEROXIDES, INORGANIC DISPOSAL PROCEDURE 22a--PAGE 153 I CMA 046133 22b DISPOSAL PROCEDURE. PEROXIDES, ORGANIC UTION: Keep stock low and date NaOH. Burn the original cartons and t:h container as received. Never bags. nsfer to glass stoppered containers 2 Solid peroxide spills should be or screw cap bottles which can cause mixed with a large volume of vermicu- dangerous friction. See Procedure 15. hte or sand. Cautiously transfer as above and burn. Wear: Rubber gloves, large heavy face shield, laboratory coat. Work from behind heavy body shield in hood. 3 A very small quantity of #1 or *2 may be destroyed by adding 10 vol umes of 20% NaOH, After 24 hours, neutralize* and pass into drain with large excess of water. Examples Acetyl peroxide Benzoyl peroxide Butyl hydroperoxide tert.-Butyl peracetate tert.-Butyl perbenzoate Butyl peroxy pivalate Cumene hydro peroxide 3, 4-dichlorobenzoyl peroxide Dibutyl peroxide Diisopropyl peroxy dicarbonate Lauroyl peroxide Methyl ethyl ketone peroxide Spills : Eliminate all sources of ignition. 1 Liquid peroxide spills may be ab sorbed in large quantity of vermiculite or sand. Using a soft plastic scoop, carefully place the mixture in a plastic container. Spread on a steel pan or in a deep pit. Ignite from a distance with an excelsior train or a long torch. Wash the scoop and container with 20% Package tots: Absorb or mix in small portions on ver miculite or sand. Wet down with 10% NaOH, Scoop up with plastic scoops and take to open-incinerator pit. When dry, ignite from a distance with an ex celsior train. * Neutralize with 6M-HCI. | ^ ,i f. ' .t s| l'l 1' \PAGE 154--DISPOSAL PROCEDURE 22b ------------------------------------ PEROXIDES, ORGANIC i CMA 046134 DISPOSAL PROCEDURE SULFIDES, INORGANIC Wear: Rubber gloves, safety glasses. Work in hood or wear self-contained breathing apparatus, laboratory coat. Spills : Eliminate all sources of ignition. Add FeCI:t solution. Stir until FeS formation is complete. Add slight excess of soda ash. Scoop up and wash into drain with excess water. Wash site with soap solution. OR Absorb with vermiculite or sodium bi carbonate and scoop into plastic bag or wide-mouthed glass jar. Close tightly, remove to safe place outside and add FeClj solution. Stir until reaction is complete. Add slight excess sodium bicarbonate and wash into drain with excess water. Package lots: Add to a large volume of FeCI:i solution with stirring. Add more FeCI:t if neces sary. Add soda ash with stirring until neutral. Scoop up and wash down the drain with excess water. Note: If a gas (e.g., H4S), seal the cylin der and return to supplier. If the valve is leaking the gas can be bubbled through a FeCI, solution. Be sure to include a trap in the line to prevent the solution being sucked back into the cylinder. If this cannot be done, the cylinder should be placed in or ad jacent to a fume hood and left to bleed off. Examples: Ammonium polysulfide Ammonium sulfide Calcium sulfide Hydrogen sulfide Potassium sulfide Sodium sulfide SULFIDES, INORGANIC DISPOSAL PROCEDURE 23--PAGE 155 CMA 046135 DISPOSAL PROCEDURE_________________ ACIDS, ORGANIC (Limited to C, H, and 0 Compositions) ^Rubber gloves, face shield, laboratory coat. Body shield and self-contained breathing apparatus should be avail able. Spills : Eliminate all sources of ignition, 1 Cover contaminated surfaces with soda ash or sodium bicarbonate. Mix and add water if necessary, Scoop up slurry and wash neutral* waste down drain with excess water. Wash site with soda ash solution. Package lots: (CHOICE OF PROCEDURES) 1 * Liquid acid may be injected at base of incinerator or after mixing with a flammable solvent. Afterburner is suggested for complete combustion, 2 A solid acid may be dissolved in a flammable solvent and burned as above. 3 Solid acid may be packaged in paper or other flammable material and burned in an incinerator. Examples Acetic acid Acetic anhydride Acrylic acid Adipic acid Benzoic acid n-Butyric acid iso-Butyric acid n-Butyric anhydride Caproic acid Citraconic anhydride Citric acid Formic acid Fumaric acid Gallic acid Glutaric anhydride Glycolic acid Hydracrylic acid-B-lactone* Laurie acid Maleic acid Maleic anhydride Methacrylie acid Octanoic acid Oleic acid Oxalic acid Phthalic anhydride Pimelic acid Propionic acid Pyrogallic acid Pyruvic acid Salicylic acid Stearic acid Succinic acid Succinic anhydride Tannic acid Valeric Acid wi ft t f - * Make litmus test. Neutralize with 6M*NHiOH or 6M-HCI as required. PAGE 15&--DISPOSAL PROCEDURE 24a * Carcinogenic. 'I 7 ACIDS, ORGANIC CMA 046136 DISPOSAL PROCEDURE ACIDS, INORGANIC Wear: Rubber gloves, self contained breath ing apparatus, laboratory coat, Have body shield available. Spills : 1 Cover the contaminated surface with sodium bicarbonate or a soda ash--slaked lime mixture (50-50). Mix and add water if necessary to form a slurry. Scoop up slurry and wash down the drain with excess water. Wash site with soda ash solution. Package lots: Add slowly to large volume of agitated solution of soda ash and slaked lime. Add neutralized solution to excess run ning water. As an added precaution, the sink can be lined with protective matting and filled with coarse chipped marble. Examples: Boric acid Boron oxide Fluoroboric acid FluorosiIioic acid Hydriodic acid Hydrobromic acid Hydrochloric acid Hydrofluoric acid Iodic acid Mixed acids Nitric acid Phosphoric acid Phosphoric anhydride Sulfuric acid Sulfur trioxide ACIDS, INORGANIC DISPOSAL PROCEDURE 24b--PAGE 157 CMA 046137 DISPOSAL PROCEDURE. Rubber gloves, safety glasses, labora tory coat, Spills: Cover with dry vermiculite, scoop into a dry bucket or plastic bag and trans fer to a safe open area. Dispose of the material cautiously by adding it slowly to a large volume of water. Burn the hydrocarbon gas using a pilot burner. Allow to stand for 24 hours and run to sewer with excess water, Package lots: Take to a safe open area and add slowly to a large container of water. Burn off the hydrocarbon gas with a pilot flame. Allow to stand for 24 hours. Siphon off the liquid and transfer the precipitate to a landfill. Examples Aluminum carbide Calcium carbide * .1 'I 'i 'i 'i PAGE 158--DISPOSAL PROCEDURE 25 'j CARBIDES 11 CMA 046138 DISPOSAL PROCEDURE WASTES TO BE DUMPED INTO LANDFILLS OR RELEASED TO AIR Wear.- Heavy work gloves, safety glasses. Properly assembled waste ready for pick-up trucks may be used as fill in reclaiming low areas or may be dumped into a landfill. Examples .* Argon Asphalt Batteries, dry cell Boron Bromochloromethane Bromoform Bromotrifluoromethane Calcium carbonate Calcium oxide Carbon black Chlorobromomethane 1-Chloro-l, 1-difluoroethane Chloroform Chloropentafluoroethane Chlorotrifluoroethylene Chromium Crude lime 1,2-Dibromotetrafluoromethane Dichlorodifluoromethane Dichloromethane Dichloromonofluoromethane Dichlorotetrafluoroethane Epoxy resin systems Ferrosilicon Ferrovanadium dust FI uorotrichlorome thane Helium Hexachloroethane Hexafluoroethane Hydrogen Lamp bulbs Latex Magnesium oxide Metal scrap Molybdenum, insoluble compounds Neon Nitrogen Nitrogen fertilizers Nitrogen trioxide Octafluorocyclobutane Osmium tetroxide Oxygen Ozone Paint Pyrethrum Resins Rubber Scrap glass Scrap stoneware Silica Sludges Stone, alberine Sulfur Tar Tetrabromoethane WASTES TO BE DUMPED INTO LANDFILLS OR RELEASED TO AIR 1,1, 1, 2-Tetrachloro-2, 2-difluoroethane 1. 1, 2. 2-Tetrachloro-l. 2-difluoroethane Tetramethyl silane Transite Tin, organic compounds Titanium oxide Tremolite 1, 1. 1-T nchloroethane 1. 1. 2-Trich loro-1. 2, 2-trifluoroethane Trifluoromethane Urea Xenon Yttrium Zinc oxide *Zircomum `Zirconium-hafnium powders Clean, dry material may ::e burned on steei date Igmte from distance To dispose of 2 lbs of moist or contaminated ma terial, add, with water, to 10 'ns. cement mix Allow to set for 2 days and dump into 'a^dfi'i DISPOSAL PROCEDURE 26-PAGE 159 CMA 046139 27a DISPOS RECOVERY Scrap metal in the form of sheets, rods, wire, tubes Heavy gloves, safety glasses, laboratory coat. 1 Larger pieces of less expensive metals can be salvaged profitably for use in local shops, or can be sold as scrap metal--e.g., aluminum, copper, brass. 2 The more expensive metals are worth salvaging, even in small pieces-- e.g., platinum wire, silver foil. Metal should be sorted, classified, and placed in boxes, properly labelled. Turnings, shot, cuttings of the cheaper metals may be assigned to landfill, (See 26.) PAGE 160--DISPOSAL PROCEDURE 27a Examples Sheet, rods, wire, tubes, foil, etc. Aluminum Antimony Batteries, wet cells Beryllium Bismuth Bronze Cadmium Cobalt Copper Gold Lead Magnesium Manganese Molybdenum Nickel Paladium Platinum Rhodium Silver Steel, carbon Steel, stainless Tantalum Tin Titanium Zinc RECOVERY--SCRAP METAL & !\ *I >*' *I *I ' .1 'i ) * 'I 'I 'I h rI *'! r 'I T CMA 046140 --------------------------DISPOSAL PROCEDURE RECOVERY*--MERCURY Wear: Rubber gloves, self-contained breath ing apparatus, laboratory coat. CAUTION: The toxicity of mercury is such that the element and its com pounds should not be allowed to con taminate air or water. * In procedures 27b to 27m, recovery is essential because of high toxicity of all elements and com* pounds--.g. the American Conference of Govern mental Industrial Hygienists' threshold limit values (1968) expressed as mg/MJ (milligrams per meter cubed) for mercury = 0.1, for arsenic = 0,5, anti mony = 0.5, selenium = 0.2, beryllium 0.002, lead 0.2, cadmium 0.2, barium 0.5, uranium 0.05, vanadium 0.1--as opposed to hydrogen cyanide 11, and hydrogen sulfide 15. Spills and package lots: Metal--Collect all droplets and pools at once by means of suction pump and aspirator bottle with a long capillary tube. Cover fine droplets in nonaccessible cracks with calcium poly sulfide and excess sulfur. Combine all contaminated mercury in a tightly stoppered bottle. Hold it for purifica tion or sale. Compounds--Dissolve all water soluble contaminated compounds. Convert other contaminated compounds to the soluble nitrates. Adjust the acidity and precipitate as mercuric sulfide. Wash and dry the precipitate. Ship to the supplier. ** Readily destroyed by reaction with 20% sodium thiosulfate. Ventilate process to avoid cyanogen exposure. Examples Mercuric nitrate, chloride and thiocyanate Mercurous nitrate and chloride Mercury Mercury fulminate** Organic mercury compounds RECOVERY*--MERCURY DISPOSAL PROCEDURE 27b--PAGE 161 CMA 046141 27c DISPOSAL PROCEDURE. T PHOSPHORUS YELLOW AND RED Wear: Rubber gloves, large face shield. YELLOW PHOSPHORUS SpillS: Cover with wet sand. Spray with water to keep sand wet. Scoop into a bucket of water. After standing overnight, re cover and repackage. OR If quantity is very small (e.g., frag ments of sticks of yellow phosphorus), cover with water and remove to an open area. Pour onto the ground or a steel pan. The water will evaporate and dry yellow phosphorus will ignite spontane ously in air and burn away. RED PHOSPHORUS Spills: Sweep up and burn on an iron pan in the hood. Defective package: Repackage and return to the shelf--or to the supplier. 91 PAGE 162--DISPOSAL PROCEDURE 27c Defective package Submerge defective package in a large container of water. Repackage under water and return to the suppliers. RECOVERY-PHOSPHORUS CMA 046142 DISPOSAL PROCEDURE RECOVERY--ARSENIC, ANTIMONY and bismuth* Wear: Rubber gloves, safety glasses, respira tor, laboratory coat. Work in fume hood. Waste: Dissolve in minimum hydrochloric acid (concentrated, reagent). Filter if neces sary, Dilute with water until white pre cipitates form (SbOCI and BiOCI). Add just enough 6M-MCI to redissolve. Saturate with hydrogen sulfide. Filter, wash the precipitate, dry, package and ship to the supplier. OR If the waste is of very little value, use Procedure 11, Examples Antimony pentasulfide Antimony trioxide Arsenic acid Arsenic trichloride Arsenic trioxide Arsenous acid Calcium arsenate Lead arsenate Metals (arsenic, antimony and bismuth) Nitrates and chlorides of arsenic, antimony and bismuth Stibine * Although bismuth is much less toxic than arsenic or antimony it is included here because the recov* ery procedure is similar. RECOVERY-ARSENIC, ANTIMONY AND BISMUTH DISPOSAL PROCEDURE 27d-PAGE 153 CMA 046143 DISPOSAL PROCEDURE. --SELENIUM AND TELLURIUM Rubber gloves, safety glasses, respira tor (or work in hood), laboratory coat. Spills : Absorb on paper and place in wide mouth stoppered bottle for later recov ery, Wash site with soap solution. Package lots and recovered spills Liquid or solid --Make a solution strongly acidic with hydrochloric acid. Slowly add sodium sulfite to the cold solution with stirring, thus producing sulfur dioxide, the reducer. Upon heating dark grey selenium and black tellurium form. Let stand over night. Filter and dry. Ship to supplier. Examples: Hydrogen selenide Selenium hexafluoride Selenium oxides Selenium oxychloride Selenium tetrachloride Tellurium hexafluoride Tellurium oxides 3 PAGE 164--DISPOSAL PROCEDURE 27e RECOVERY--SELENIUM AND TELLURIUM CMA 046144 DISPOSAL PROCEDURE RECOVERYLEAD AND CADMIUM COMPOUNDS Wear: Rubber gloves, safety glasses, respira tor (or work in hood). Package lots and recovered spills: Convert to nitrates with a minimum of nitric acid (concentrated, reagent). Evaporate in a fume hood to a thin paste. Add about 500 ml. water and saturate with hydrogen sulfide. Filter, wash, and dry the precipitate. Package and ship to the supplier, OR If the waste is of small volume, use Procedure 11. Examples: Cadmium oxide Cadmium salts Lead oxides Lead salts RECOVERY--LEAD AND CADMIUM COMPOUNDS DISPOSAL PROCEDURE 27f--PAGE 165 CMA 046145 DISPOSAL PROCEDURE RECOVERYBERYLLIUM COMPOUNDS P Wear: Rubber gloves, self-contained respira tor, laboratory coat (wash after each job). Spills: Absorb on paper towels and place in large stoppered wide-mouth bottle. Save for recovery. Wash site with soap solution. Package lots and recovered spills: Dissolve in minimum of 6M-HCI. Filter and treat filtrate with slight excess of 6M-NH,0H (use litmus). Boil and allow coagulated precipitate to settle for about 12 hours, Filter and dry. Pack age and ship to the supplier. Examples: Beryllium salts CMA 046146 DISPOSAL PROCEDURE RECOVERY-STRONTIUM AND BARIUM COMPOUNDS Wear: Rubber gloves, safety glasses, labora tory coat. Package lots and recovered spills: Dissolve waste in 6M-HCI and filter. Neutralize the filtrate with 6M-NH,0H (use litmus) and precipitate with ex cess sodium carbonate. Filter, wash, and dry the precipitate. Package and ship to the supplier. OR If the waste is of small volume, use Procedure 11. Examples: Oxides and salts of strontium and barium RECOVERY-STRONTIUM AND BARIUM COMPOUNDS DISPOSAL PROCEDURE 27h--PAGE 167 CMA 046147 DISPOSAL PROCEDURE. RECOVERY--VANADIUM COMPOUNDS W Wear: aer gloves, large face shield, labo ratory coat. (Wear self-contained respi* rator if spill is large.) Spins : 'over with powdered ammonium car bonate. Add a layer of crushed ice and ipray with 6M-NH4OH while stirring. Scoop slurry into a wide mouth bottle, -ave for salvage. Wash site with soap vater. Package lots: (Work in a fume hood). Add (e.g., VOCl.t) slowly to a thick layer of powdered ammonium carbo nate in a large evaporating dish. Spray with 6M-NH4OH while stirring. Add a layer of crushed ice and continue stir ring and spraying. Add more 6M-NH4OH if necessary. May add more waste va nadium compound with stirring. Pour into large beaker and let stand over night. Filter off the crude ammonium vanadate, dry and package for shipment to supplier for reprocessing. Examples Ammonium vanadate Sodium vanadate Vanadium chlorides Vanadium oxychlorides Vanadyl sulfate I I ft t I II / If e f J I 5 AGE 168--DISPOSAL PROCEDURE 27i RECOVERY--VANADIUM COMPOUNDS R i CMA 046148 DISPOSAL PROCEDURE RECOVERY--HALOGENATED SOLVENTS Wear: Rubber gloves, self-contained respira tor (or work in hood), laboratory coat. Spills : Absorb on paper towels and allow to evaporate in the fume hood. Burn the paper. Wash site with soap solution. Package lots: The toxic liquid compounds concerned here are insoluble in water and cannot be burned. Purify the contaminated liquids by distillation and place the pure distillate back on the shelf. OR Return to the supplier. Examples .* Bromoform Carbon tetrabromide Carbon tetrachloride Chloroform Tetrachloroethylene 1,1,1-Trichloroethane Trichloroethylene RECOVERY-HALOGENATED SOLVENTS DISPOSAL PROCEDURE 27j--PAGE 169 CMA 046149 27k DISPOSAL PROCEDURE. RECOVERY-MISCELLANEOUS The elements and their compounds sted below should be dealt with sepaItely, If the quantity justifies recovery get in touch with the supplier for spe cial instructions. These materials as well as all other naturally radioactive materials, elements or substances must be disposed of >n accordance with regulations of the U.S. Atomic Energy Commission or those of the local or state departments of health. This may usually be done by turning them over to the radiation safety officer or a commercial disposal agency handling radioactive materials. Examples: Deuterium Erbium Gadolinium Gallium Germanium Germanium dioxide Hafnium Holmium Indium Lanthanum Lutecium Niobium Osmium Osmium oxide Praseodymium Rubidium Ruthenium Samarium Silver nitrate Terbium Thallium Thallous sulfate Thorium* U ra n i u m * <!< ii a' U li U fli !I f< L* H J r CMA 046150 DISPOSAL PROCEDURE CELLULOSE NITRATE, COLLODION, CELLULOID Wear: Rubber gloves and face shield. Note: Outside disposal is preferred but can be done in the hood, Spills : CELLULOSE NITRATE Eliminate all sources of ignition, Gather up the nitrocellulose and dampen with an alcohol. Spread out in a thin layer (2 inches deep max.) in an outside open area on top of papers or other combustible material. Ignite from a distance with an excelsior train or a long torch. When disposal by burn ing must be done in a hood, the quan tity of nitrocellulose burned at any one time should be limited to 250 ml or less. This small quantity of nitrocellu lose can be placed in a shallow pyrex dish and ignited after it has been dampened with an alcohol. OR Eliminate all sources of ignition. Gather up the nitrocellulose and dampen with water. Squeeze out ex cess water and place nitrocellulose (250 ml or less) in a large stainless steel beaker (2500 ml or larger), and place beaker in a large pyrex dish. Add an equal amount of 10% caustic (no stronger) to the beaker. Most of the nitrocellulose should be consumed in 20 minutes. Remove beaker (Cau tion: beaker will be hot from the heat of reaction) and pour remaining con tents into drain with large excess of water, Spills : COLLODION (Nitrocellulose Lacquer) Eliminate sources of ignition. Wipe up spilled material with paper towels or rags. Remove to an outside open area, spread on the ground and ignite with an excelsior train or a long torch. Package lots: Small quantities of collodion (250 ml or less) may be disposed of in a hood by igniting it in a pyrex dish. Larger quantities should be disposed of in an outside open area by pouring into a steel pan and igniting with an excelsior train or a long torch. CELLULOID (Nitrocellulose Plastic) Celluloid disposal should be done out side in an open area. Eliminate sources of ignition. Spread the waste celluloid on top of paper or other combustible material. Ignite from a distance with an excelsior train or a long torch. WARNING: Whenever cellulose nitrate, collodion or celluloid is burned or decomposed, oxides of nitrogen are released. Avoid direct breathing of vapors. CELLULOSE NITRATE, COLLODION. CELLULOID DISPOSAL PROCEDURE 28--PAGE 171 CMA 046151 DISPOSAL PROCEDURE DIRECT BURNING vy leather gloves, safety glasses. Disposal: Materials should be properly packed for safe handling, and placed in a pre scribed site for daily pick-up. Burning can be done m an open or closed incin erator with afterburners. Examples: Materials: Bags, paper and cloth Biological wastes--animal remains, bedding, feed wastes Clothing, discarded or contaminated Excelsior Paper wastes, packing boxes, etc. Wood scraps, packing boxes, etc. Bags, paper and cloth M i V K t; n Pi* r tit PAGE 172--DISPOSAL PROCEDURE 29 DIRECT BURNING rit i CMA 046152 SECTION VII Disposal Ma teria/s--Minimum Requiremen ts (a) CHEMICALS Acetone, waste (2 gal.) Alcohol, butyl (2 gal.) Alcohol, denatured (waste) (2 gal.) 'Ammonium hydroxide (concentrated, Reagent) (2 liters) Ammonium hydroxide (6M) (4 liters) Ammonium carbonate (2 x 1 lb.) Benzene, waste (2 gal.) Calcium hypochlorite (2 x lb.) "Calcium polysulfide (2 x 1 liter) Excelsior (box) Fuels -- scrap wood paper organic flammable solvents Ferrous sulfate (2 x 1 lb.) Ferrous sulfate, 30% (4 x 1 liter) Ferric chloride (2 x 1 lb.) Graphite powder (5 lb.) Hydrochloric acid (concentrated, Reagent) (2 liters) "'Hydrochloric acid, (6M) (4 liters) Hydrogen sulfide (small cylinder) Ice, chipped Kaolin (2x5 lb.) Kaolin -- Soda ash (50-50) (2x5 lb.) Limestone, pulverized (2x5 lb.) Litmus paper, red and blue (1 doz. vials each) Marble chips (2x5 lb.) Nitric acid (centrated, Reagent) (2 liters) Paper boxes, waste Potassium iodide, 10% (peroxide test) Sand, dry (2x10 lb.) Sand-Soda ash (90-10) (2x10 lb.) Slaked lime (calcium hydroxide) (2 x 5 lb.) Soap power (6 x 1 lb.) Soda ash (sodium carbonate) (2x5 lb.) Soda ash-Slaked lime (50-50) (2 x 10 lb.) Sodium bicarbonate (2x5 lb.) Sodium hydroxide, 10% (4 liters) Sodium hydroxide, 20% (4 liters) Sodium bisulfite (5 lb.) Sodium sulfite (5 lb.) Sodium thiosulfate (hypo) (2x5 lb.) Sulfur, sublimed (2 x 1 lb.) Sulfuric acid (concentrated, Reagent) (2 liters) ""Sulfuric acid (3M) (4 liters) Towels, paper (1 doz. rolls) Vermiculite (or Oil-Dn, Sol-Speedi-Dri, etc.) (10 lb.) Requires approximately 400 ml of concentrated 'eagent grade per liter of solution. Saturate one liter of concentrated lime water with hydrogen Add excess sublimed sulfur. Shake. Requires 516 ml, of concentrated HCI per liter of solution. ***336 ml. of concentrated reagent H.SOi per liter of solution NMiQH suif.de, _______________________ (See over for EQUIPMENT listing) PAGE 173 CMA 046153 SECTION VII. continued Disposal Materials --Minimum Requirements t EQUIPMENT Laboratory coat, plastic Aspirator bottle (mercury collector) (2) Atomizer spray bottle (2) Beakers, 3 or 4 liter size (2) Matting, open mesh, rubber, to fit sink Mop and bucket Pipettes 10 ml. (peroxide test) (4) Brush, hand (6) Respirator, canisters (1 of each) Brush, small paint Respirator (self-contained breathing apparatus) Bucket, plastic (3 gal.) Safety glasses or goggles (2 prs.) Burners, Bunsen Condenser. Liebig Dish, evaporating, 12" (2) Extinguisher (Class D fires) (30 lb, size) Scoop, plastic Shield, body Shield, face, large and heavy, 0.050", to cover ears and neck Extinguisher (COJ (10 lb. size) Flask, Distilling -- 1 liter (2) Gloves, heavy work Gloves, leather Gloves, neoprene Gloves, butyl rubber Iron pan (for fume hood) (approx. 18" x 24") Spray jar (insecticide type), stainless steel Suction pump (mercury collector) Tank (oil drum, 55 gal.) Tools -- hammer pliers wrench, crescent screwdrivers Laboratory coat, cloth Water-vac PAGE 174 CMA 046154 SECTION VIII BIBLIOGRAPHY ACGIH--"Threshold Limit Values,'' American Conference of Govern mental Industrial Hygienists, 1014 Broadway, Cincinnati. Ohio 45202 AIA--"Nitroparaffms and their hazards," Report =-12. and "Chemical Hazards Bulletin," American Insurance Association, 85 John St . New York, N.Y. 10038 ASTM--"Fire and Explosion Hazards of Peroxy Compounds," Tech. Bui. -- 394 American Society for Testing and Materials. 1916 Race St , Philadelphia, Pa, 19103 Audrieth, L. F. & Ogg, B.A,--"The Chemistry of Hydrazine," John Wiley &. Sons Inc . 605 3rd Ave.. New York, N.Y, 10016 BDH--"Sp///ages of Hazardous Chemicals," British Drug Houses Ltd., Poole, Dorset, England. Also available from Gallard-Schlesinger Chemical Mfg. Corp , 584 Mineola Ave.. Carle Place, Long Island, New York, N.Y. 11514 or from British Drug Houses (Canada) Ltd.. Barclay Ave , Toronto 18, Ontario, Canada Brookes and Alyea--"Poisons," Van Nostrand Reinhold Company, 430 Park Avenue, New Yorn, N Y, 10022 Campbell, Neil--"Schmidts Organic Chemistry," Oliver and Boyd Ltd , Edinburgh, Scotland CGA--"Safe Handling of Compressed Gases" Pamphlet P-1, Com pressed Gas Association Inc , 500 5th Ave., New York, N.Y. 10036 Cloyd, D. R. & Murphy, W, J --"Handling Hazardous Materials--N.A.S.A. SP-5032," National Aeronautics and Space Administration, Washing ton, D. C. 20546 Elkins, H. B.--"Chemistry of Industrial Toxicology," 1963, John Wiley & Sons. 605 3rd Ave., New York, N.Y. 10016 Fairhall, L, T,--"Industrial Toxicology," Williams and Wilkins. Balti more, Md. Gaston, P. J,--`The care, handling and disposal of dangerous chem icals," 1965. Institute of Science Technology, Northern Publishers (Aberdeen Ltd.), Aberdeen, Scotland Gonzales, Vance, Helpern--"Legal Medicine and Toxicology," 1940, Appleton-Century Trade Books, 250 Park Ave,, New York, N.Y 10017 Hurd--"Chemistry of Hydrides," 1952, John Wiley & Sons, Inc., 605 3rd Ave.. New York, N.Y. 10016 IBM--"Freon" solvent data book, IBM Corp,, Yorktown Heights, New York 10598 Kirk & Othmer--"Encyclopedia of Chemical Technology," Vol. 8. p 489 2nd Ed., Wiley-lnterscience, 605 3rd Ave , New York, N.Y. 10016 Los Angeles Fire Dept.--"Dangerous Chemicals Code," 1951, Parker & Son, Inc., Los Angeles, Calif, McElroy, F, E---"Accident Prevention Manual tor Industrial Operations," 5th Ed., National Safety Council, 425 No, Michigan Ave,, Chicago. III. 60611 MCA--"Chemical Safety Data Sheets," "Safety Guides" and "ChemCard Manual," Manufacturing Chemists Association, 1825 Connecti cut Ave., Washington, D. C, 20009 PAGE 175 CMA 046155 MCB-- Safety Procedures- Laboratory Chemical Catalog," pp, 9-31, Matheson, Coleman & Bell, 2909 Highland Ave Norwood Ohio 45212 MGB-- Gas Data Book. ' The Matheson Co Inc P 0 Box 85, East Rutherford N J 07073 ,F P A --No, 49, "Hazardous Chemicals Data", No 325, "Fire Hazard Properties of Flammable Liquids, Gases and Volatile Solids No 491, "Manual of Hazardous Chemical Reactions , No 704M, ' Fire Hazards of Materials, ' National Fire Protection Association 60 Batterymarch St , Boston, Mass, 02110 Nat I Research Council--"Evaluation of the Hazard of Bulk Water Transportation of Industrial Chemicals," 1966, National Academy of Science. 2101 Constitution Ave, N W_ Washington. D C, 20418 Nicholson. H, Page--"Pesticide Pollution ControlScience 758, 871 (Nov 17, 1967) Noller, D C & Bolton, D F--"Sate Handling and Storage of Organic Peroxides in the Laboratory," Anal. Chem 35, 887 (June 1963) NSC--"Chemical Safety ReferencesNational Safety News 97, 47 (Apr 1968), and "Industrial Safety Data Sheets," National . Safety Council, 425 No. Michigan Avenue, Chicago, III 60611 NTTC--"Commodity and Equipment Data Sheets," National Tank Truck Carriers, Inc , 1616 P St , N.W., Washington, D. C 20006 O'Brien, Richard D,--"Toxic Phosphorous Esters," 1960, Academic Press Inc, 111 5th Ave., New York, N.Y, 10003 Patty, Frank A.--"Industrial Hygiene and Toxicology," Vol II, 1963. Wiley-lnterscience, 605 3rd Ave., New York, N.Y. 10016 Pennsylvania Department of Health--"Short Term Limits tor Exposure to Airborne Contaminants." "Hygienic Information Guides," "Indus trial Waste Manual," Division of Sanitary Engineering, Harrisburg, Pa, Pennsylvania Department of Revenue---"Highway Transportation of Hazardous Substances," 1968, Hazardous Substances Transportation Board, Harrisburg, Pa, 17127 Remy, H,--1"Treatise on Inorganic Chemistry," Vot. I & II, 1956, Ameri can Elsevier Publishing Co , 52 Vanderbilt Ave , New York, N.Y. 10017 Ross, R, D --"Industrial Waste Disposal." Van Nostrand Reinhold Com pany, 430 Park Avenue, New York, N.Y. 10022 Sax, N l--"Dangerous Properties of Industrial Materials," 1968. Van Nostrand Reinhold Company, 430 Park Avenue, New York. N Y 10022 Sidgwick--"Chemical Elements and their Compounds," Vol I & II, 1950, Oxford University Press, Inc,, 200 Madison Ave., New York, N.Y, 10016 Sittig, Marshall--1"Sodium, its manufacture, properties and uses," 1956, Van Nostrand Reinhold Company, 430 Park Avenue, New York, N.Y. 10022 Steere, N V.--"Handbook of Laboratory Safety," Waste disposal pp, 34-40, 1967, Chemical Rubber Co,, 18901 Cranwood Parkway, Cleve land, Ohio 44128 Voeglem, Joseph F --"Storage and Disposal of Dangerous Chemicals," J. Chem. Educ. 43, A151 (Feb, 1966) Walsh, John--"Pollution--The Wake of the Torrey Canyon" (news comment), Science 160, 167 (April 12, 1968) Weast. R, C, & Selby, S. M.--"Handbook of Chemistry and Physics," 1967, Chemical Rubber Co., 18901 Cranwood Parkway, Cleveland, Ohio 44128 World Health Organization--'"Treatment and Disposal ot Wastes," WHO Tech, Report Series No 367 (1967) PAGE 176 CMA 046156 Order from Publications Department MANUFACTURING CHEMISTS ASSOCIATION 1825 Connecticut Ave,, Washington, D. C. 20009 CMA 046157