Document om9E4OeZwevaX9kGD8KaE31O7

PCS AMENDED PETITION - ATTACHMENT A JONES DAY 1420 PEACHTREE STREET, N E SUITE 800 ATLANTA, GEORGIA 30309 3053 TELEPHONE +1404 381 3939 FACSIMILE: +1,404,981,8330 October 16,2015 VIA HAND DELIVERY and ELECTRONIC MAIL The Honorable Gina McCarthy Office of the Administrator U.S. Environmental Protection Agency Room 3000 1200 Pennsylvania Ave., N.W. Washington, DC 20460 Mr. Keith Barnett Group Manager Sector Policies and Program Division U.S. Environmental Protection Agency 109 T.W. Alexander Drive Mail Code: D243-04 Research Triangle Park, NC 27709 B...a..r..n..e. .t.t...K.. .e..i.t.h..@....e..D..a.....g..o..v. Lorie Schmidt, Esq. Air and Radiation Law Office U.S. Environmental Protection Agency Mail Code: 2344A 1200 Pennsylvania Ave., N.W. Washington, DC 20460 Schmidt.Lorie@epa.gov Ms. Tina Ndoh Environmental Protection Agency 109 T.W. Alexander Drive Mail Code: D243-04 Research Triangle Park, NC 27709 ndoh.tina@epa.gov Re: Petition for Reconsideration and Request to Stay "Phosphoric Acid Manufacturing and Phosphate Fertilizer Production RTR and Standards of Performance for Phosphate Processing; Final Rule," 80 Fed. Reg. 50,386 (Aug. 19,2015) (EPA Docket ID No. EPA-HQ-OAR-2012-0522) Dear Administrator McCarthy, PCS Phosphate Company, Inc.; White Springs Agricultural Chemical, Inc., d/b/a PCS Phosphate-White Springs; and PCS Nitrogen Fertilizer, L.P., (collectively "PCS") respectfully submit this Petition for Reconsideration and Request for Administrative Stay of the abovereferenced Final Rule. In this Petition, PCS fully supports and incorporates the grounds for reconsideration and stay presented in the Petition submitted by The Fertilizer Institute ("TFI"). PCS is submitting this Petition to additionally seek reconsideration and stay based on grounds that are unique to PCS facilities. Please contact me with any questions on this Petition. Sincerely, cc: Jonathan Averbach, Esq. (EPA) Susan Fairchild (EPA) (via electronic mail) Casey Femung Bradford Counsel for PCS (404)581-8119 ALKHOBAR ATLANTA BEUING BOSTON BRUSSELS CHICAGO CLEVELAND COLUMBUS DALLAS DUBAI FRANKFURT HONG KONG HOUSTON IRVINE JEDDAH LONDON LOS ANGELES MADRID MEXICO CITY MILAN MOSCOW MUNICH NEW DELHI NEW YORK PARIS PITTSBURGH RIYAOH SAN DIEGO SAN FRANCISCO SAO PAULO SHANGHAI SIUCON VALLEY SINGAPORE SYDNEY TAIPEI TOKYO WASHINGTON NAI-1500590655VI 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00001 BEFORE THE UNITED STATES ENVIRONMENTAL PROTECTION AGENCY PCS PHOSPHATE COMPANY, INC.; WHITE SPRINGS AGRICULTURAL CHEMICALS, INC., d/hfo PCS PHOSPHATE-WHITE SPRINGS; and PCS NITROGEN FERTILIZER, L.P. Petitioners EPA Docket #: EPA-HQ-OAR-20I2-0522 PETITION FOR RECONSIDERATION AND REQUEST FOR ADMINISTRATIVE STAY Charles T. Wehland JONES DAY 77 West Wacker Drive Chicago, IL 60601 Telephone: (312) 782-3939 Facsimile: (312)782-8585 Email: ctwehland@jonesday.com Jessica DeMonte Senior Counsel PCS Administration (USA), Inc. 1101 Skokie Boulevard Suite 400 PO. Box 3320 Northbrook, Illinois 60062 Telephone: (847) 849-4291 Facsimile: (847) 849-4663 Email: Jessica.DeMonte@potashcorp.com Casey F. Bradford JONES DAY 1420 Peachtree Street Atlanta, Georgia 30309 Telephone: (404) 581-8119 Facsimile: (404) 581-8330 Email: cbradford@jonesday.com NAI-1500577867v3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00002 PETITION FOR RECONSIDERATION AND REQUEST FOR ADMINISTRATIVE STAY Pursuant to Clean Air Act Section 307(dX7)(B), 42 U.S.C. 7607(dX7)(B), and the Administrative Procedure Act, 5 U.S.C. 553(e), 705, PCS Phosphate Company, Inc.; White Springs Agricultural Chemicals, Inc. d/b/a PCS Phosphate-White Springs; and PCS Nitrogen Fertilizer, L.P. (together referred to herein as "PCS") respectfully submit this petition (hereinafter "Petition") to the U.S. Environmental Protection Agency ("EPA") for reconsideration and an immediate administrative stay of the "Phosphoric Acid Manufacturing and Phosphate Fertilizer Production RTR and Standards of Performance for Phosphate Processing; Final Rule." 80 Fed. Reg. 50,386 (Aug. 19,2015) ("Final Rule") (Dkt No. EPAHQ-O AR-2012-0522). Reconsideration is warranted because in adopting the Final Rule, EPA made a number of substantial and unforeseeable, substantive changes to the National Emission Standards for Hazardous Air Pollutants ("NESHAPs") for phosphoric acid manufacturing and phosphate fertilizer production under 40 C.F.R. Part 63, Subparts AA and BB, without allowing an opportunity for meaningful public comment before the changes were adopted in the Final Rule. Many of these changes, which became effective immediately upon publication of the Final Rule without any implementation period, are described in the Petition for Reconsideration and Request to Stay submitted by The Fertilizer Institute (the "TFI Petition"). PCS hereby adopts and fully incorporates by reference the grounds for reconsideration and stay presented in the TFI Petition. In this Petition, PCS is also requesting that EPA reconsider the Final Rule based on two grounds that are unique to PCS. First, PCS Phosphate Company, Inc. ("PCS Phosphate") owns and operates the only existing phosphate rock calciners subject to the new total fluoride emission NAI-1500577867v3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00003 limit for calciners in the Final Rule. Emissions data collected by PCS Phosphate demonstrate that the total fluoride limit is not achievable during a representative range of operating conditions which can occur with the PCS Phosphate calciners. Second, the requirement in the Final Rule for liquid-to-gas ratio monitoring of absorbers that operate with a pressure drop of less than five inches of water column ("low-energy absorbers") presents unique technical challenges for PCS facilities. It was simply impossible for PCS to comply with this requirement on August 19,2015 as required by the Final Rule. Section 307(dXTXB) of the Clean Air Act requires EPA to grant reconsideration of these requirements because the grounds for objection arose after the close of the public comment period, were not logical outgrowths of any proposed rulemaking, were impracticable for PCS to raise in comments, and are of central relevance to the Final Rule. PCS will be filing a Petition for Judicial Review of the Final Rule in the United States Court of Appeals for the District of Columbia Circuit to preserve its right to seek judicial review within the time frame specified by Clean Air Act Section 307(dX7XB). PCS hopes that EPA will grant this Petition for administrative reconsideration and then move jointly with PCS to request that the Court hold the litigation in abeyance during the reconsideration process. In addition to seeking reconsideration, PCS is requesting that EPA administratively stay the Final Rule or agree to a judicial stay pending the outcome of reconsideration. A stay is warranted to avoid subjecting PCS and other regulated entities to substantial costs and legal concerns as a result of the technical and legal errors in the Final Rule pending reconsideration or judicial review. INTRODUCTION AND BACKGROUND I. The PCS Facilities PCS owns and operates manufacturing facilities subject to 40 C.F.R Part 63, Subparts AA and BB, in Aurora, North Carolina; White Springs, Florida; and Geismar, Louisiana. These NAI-I500577867v3 -3- 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00004 facilities include wet process phosphoric acid, superphosphoric acid, purified phosphoric acid, and diammonium and monoammonium phosphate process lines. As mentioned, the PCS Phosphate facility in Aurora also includes the only existing phosphate rock calciners subject to the Final Rule. PCS participated in EPA's information collection process for this rulemaking and submitted extensive comments to EPA during the proposed rule stage. All three PCS facilities will face noncompliance and liability risks and will incur substantial costs in the near future unless EPA grants reconsideration and stays the Final Rule. PCS therefore has a substantial interest in the Final Rule and the quality of the public comment process that is the basis for the Final Rule. II* Tjhe^llgPjA^Jftuleinalcinjg^a^^Is^ue Section 112(f) of the Clean Air Act requires EPA to review the NESHAPs every eight years and to revise those standards as necessary to address any risk remaining to human health and the environment. Under Section 112(d)(6) of the Clean Air Act, EPA is also required to revise the Maximum Achievable Control Technology ("MACT") standards in the NESHAPs "as necessary (taking into account developments in practices, processes, and control technologies)." Together, these two processes are commonly known as a "residual risk and technology review." EPA issued two rounds of information requests under Section 114 of the Clean Air Act to inform its review of Subparts AA and BB. In 2010, PCS conducted total fluoride testing concurrent with hydrogen fluoride testing in response to an EPA request. In early 2014, EPA required additional testing of emissions from several process lines at the PCS facilities, including additional testing of hydrogen fluoride emissions from phosphate rock calciners. PCS conducted the required testing of hydrogen fluorides in response to the 2014 request and submitted the resulting data to EPA. PCS also voluntarily conducted concurrent testing of total fluoride NAI-1500577867v3 17cv1906 Sierra Club v. EPA - 6/22 Production -4- ED 001523 00007569-00005 emissions from the calciners in 2014 to address its concerns about tire accuracy and reliability of the methodology for hydrogen fluoride testing. On November 7,2014, EPA issued a proposed rule to revise Subparts AA ami BB based on its residual risk and technology review. 79 Fed. Reg. 66,512 (Nov. 7,2014) ("Proposed Rule"). EPA found that the existing standards in Subparts AA and BB were already amply protective of human health and the environment, and that additional standards were not appropriate based on a review of technology. Id. at 66,538-39,66,549-50; see also 80 Fed. Reg. at 50,390-91,50393 (finalizing EPA's conclusion that no additional requirements were necessary based on risk or changes in technology). Nevertheless, EPA proposed several new requirements under Subparts AA and BB, including a new work practice standard for hydrogen fluoride emissions from phosphate rock calciners.1 79 Fed. Reg. at 66,534-35,66,566 (proposed 40 C.F.R. 63.602(aX2Xiii))> EPA also proposed several options for monitoring and operating requirements at low-energy absorbers. The Proposed Rule would have required low-energy absorbers to monitor either influent liquid flow or liquid-to-gas ratio, and either exit gas temperature and inlet liquid pressure or temperature differential. 79 Fed. Reg. at 66,575 (proposed 40 C.F.R. Part 63, Subpart AA, Table 3). PCS provided EPA with timely comments on the Proposed Rule. See 79 Fed. Reg. 73,872 (Dec. 12,2014) (extending the public comment period to January 21,2015); "Comments on the U.S. Environmental Protection Agency's Proposed Rule Entitled `Phosphoric Acid 1 For some affected facilities, EPA also proposed numeric hydrogen fluoride emissions limits and requested comment on an alternative compliance option whereby those facilities could have demonstrated compliance with their existing numeric limits on total fluoride emissions. 79 Fed. Reg. at 66,546,66,557,66,573-74 (proposed 40 C.F.R. Part 63, Subpart AA, Tables 1 - 2A), 66,586 (proposed 40 C.F.R. Part 63, Subpart BB, Tables 1 - 2). Phosphate rock calciners, however, were not already subject to any numeric limit on total fluoride emissions under existing regulations at the time of the Proposed Rule. Nor did EPA propose or request comment on any numeric limit for either total fluoride or hydrogen fluoride emissions from calciners in the Proposed Rule. NAM500577867v3 -5- 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00006 Manufacturing and Phosphate Fertilizer Production RTR and Standards of Performance for Phosphate Processing'" (Dkt. ID No. EPA -HQ-OAR-2012-0522-0037) ("PCS Comments" submitted January 21,2015). The PCS Comments included a statement of support for the work practice standard that EPA proposed for phosphate rock calciners. PCS Comments at 6 (Dkt ID No. EPA-HQ-OAR-2012-0522-0037). The Final Rule, issued August 19,2015, departs significantly from the Proposed Rule in terms of its requirements for both calciners and low-energy absorbers. Although EPA proposed a work practice standard for calciners and did not propose or request comment on any numeric fluoride emission limit for calciners, the Final Rule sets a MACT floor limit of0.0009 lb of total fluoride per ton of rock feed (lh/ton) for existing calciners such as PCS's. 80 Fed. Reg. at 50,401,50,445 (40 C.F.R. Part 63, Subpart AA, Table 1). EPA promulgated this limit without the benefit of the test data that PCS collected in April 2014, showing that total fluoride emissions from the Aurora calciners exceeded 0.0009 lh/ton during three out of four test runs in 2014. With respect to low-energy absorbers, the Final Rule differs from the Proposed Rule because it establishes liquid-to-gas ratios as the only allowed parameter for monitoring and operating requirements. Id. at 50,336,50,457 (40 C.F.R. Part 63, Subpart AA, Table 3, and Subpart BB, Table 3), These new requirements for calciners and low-energy absorbers became effective immediately upon publication of the Final Rule in the Federal Register on August 19,2015. Id. at 50,386 ("This final action is effective on August 19,2015."). ARGUMENT The Clean Air Act requires the Administrator of EPA to convene a reconsideration proceeding if "it was impracticable to raise [an] objection" to a final EPA action within the time for public comment or if "the grounds for such objection arose after the period for public comment (but within the time specified for judicial review)" and such objection is "of central NAI-1500577867v3 6 - - 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00007 relevance to the outcome of the rule." 42 U.S.C. 7607(dX7)(B). These criteria for granting reconsideration are satisfied here, where EPA promulgated an unachievable numeric limit on total fluoride emissions from the Aurora calciners without proposing or requesting comment on the possibility of any such limit Reconsideration is also necessary because EPA revised the monitoring and operating requirements for low-energy absorbers without explaining its rationale until after the close of the comment period and without addressing various technical challenges to compliance. At the same time, the Administrative Procedure Act and Clean Air Act grant EPA authority to stay the Final Rule. See 5 U.S.C. 705 ("When an agency finds that justice so requires, it may postpone the effective date of action taken by it, pending judicial review-----"); 42 U.S.C. 7607(dX7XB) ("The effectiveness of the rule may be stayed pending such reconsideration___ "). Considering the numerous technical ami legal errors raised in this Petition and the TFI Petition, justice requires that EPA stay the Final Rule and take any other steps that are necessary to defer compliance deadlines or other requirements of the Final Rule pending the outcome of a reconsideration proceeding and/or judicial review. I. EPA Should Reconsider the Total Fluoride Emissions Limits for New and Existing Phosphate Rock Calciners The total fluoride limit for calciners in the Final Rule is based on data collected from just three test runs of Method 13B at a PCS calciner in response to EPA's 2010 information request. 80 Fed. Reg. at 50,400. EPA must reconsider the total fluorides limit because 2014 test data for that same calciner demonstrate that the total fluoride limit in the Final Rule does not meet the definition of a MACT floor limit, does not adequately account for variability in total fluoride emissions from calciners at different points in time, and is not achievable at the PCS Aurora calciners during a representative range of operating conditions for such calciners. NAI-l 500577867v3 -7- 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00008 Section 112(dX3) of the Clean Air Act defines the MACT floor as the average level of emissions achieved by the best performing five sources when there are fewer than 30 sources in the relevant source category. PCS Phosphate owns and operates the only six existing phosphate rock calciners in the Subpart AA source category. Therefore, the MACT floor for existing calciners is defined as the average emissions limitation achieved by the PCS Aurora calciners. EPA has acknowledged that all six calciners in Aurora are identical, such that data from one calciner is representative of emissions from the others during the same test event. 80 Fed. Reg. at 50,400 ("In response to the April 2010 CAA section 114 request, the facility provided EPA Method 13B total fluoride emission testing results for one of their six identical phosphate rock calciners. We conclude that the total fluoride emission rate achieved by this phosphate rock calciner characterizes the emissions from all six calciners and thus this emission rate was used to determine the MACT floor for total F emissions."); see also 67 Fed. Reg. 40,814,40,815 (June 13,2002) (explaining that all six calciners in Aurora are identical). The total fluoride data that PCS collected in April 2014 was taken from the same calciner (EP-203) using the same methodology (Method 13B) as the 2010 data that EPA used to set the limit in the Final Rule. As shown in Table 1 of this Petition, the results of three out of four individual test runs of Method 13B in April 2014 exceeded the total fluoride limit for calciners in the Final Rule. Table 2 in this Petition shows that any three-run average from 2014 also exceeds the total fluoride limit in the Final Rule. See also Attachment A, URS Summary Letter Report for Calciner Emissions Testing, at Table 3 (April 29,2014); Attachment B, URS Report, EPA Information Collection Request Emissions Testing, PCS Phosphate Company, Inc. - Aurora, NC, at Table 3-1, Appendix A-l-6 (Nov. 2010). NAI-1500577867v3 17cv1906 Sierra Club v. EPA - 6/22 Production 8 - - ED 001523 00007569-00009 Table 1: Method 13B Stack Test Results & Feed Rates for Calciner EP-203 PCS Phosphate - Aurora* North Carolina Hun Run Date Number 8/3/2010 1 Phosphate Ore Ma s Flow k^teto nlciner^ton /hr* 89.5 Pound' of Total Fluoride Per on of Phosphate Ore Ft ed (lb/ton) 0.00045 8/3/2010 2 65.5 0.00057 8/3/2010 3 91.0 0.00036 4/4/2014 1 4/4/2014 2 4/4/2014 3 4/4/2014 4 61.1 51.9 36.2 20.4 0.00172 0.00250 0.00083 0.00121 Table 2: Three-Run Average Test Results from Method I3B Stack Testing on April 4,2014 PCS Phosphate - Aurora* North Carolina 2014 (Runs 1,2,4) 2014 (Runs 1,3,4) 2014 (Runs 2,3,4) 44.5 39.2 36.2 0.00181 Yes 0.00125 Yes 0.00151 Yes Variability in total fluoride emissions from the calciners over time is caused by differences in process operating conditions. For example, the average feed rate to Calciner EP- NAI-l 500577867v3 -9- 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00010 203 during the 2014 testing was approximately 42 tons/hour, compared to approximately 80 tons/hour during the 2010 testing. Rock production at the mine during the 2014 testing was constrained by difficult geological conditions, which in turn required a lower rate of feed to the calciners. Because each calciner is a constant-volume piece of equipment, lower feed rates have the effect of increasing the residence time of the feed inside the calciner and, therefore, the potential for total fluoride emissions. Other process operating conditions (for example, moisture content) may contribute to emissions variability. PCS is continuing to collect and evaluate operating data for the periods of total fluoride testing and will supplement this Petition based on the results of its review. To demonstrate compliance with the new total fluorides limit, the Final Rule requires performance testing during "representative" operating conditions, which are defined as a "range" of process and control measure conditions "under which the facility expects to operate (regardless of the frequency of the conditions)" and that are "likely to most challenge the emissions control measures of the facility." 80 Fed. Reg. at 50,453 (40 C.F.R. 63.626(dXl)). The total fluorides emissions testing in April 2014 was conducted during representative operating conditions for the calciners. The 2014 emissions data demonstrate that EPA's total fluoride limit for calciners is not achievable during representative operating conditions and must be revised to account for the 2014 test data. Because EPA failed to propose or request comment on the possibility of a numeric limit on fluoride emissions from calciners, the grounds for this objection arose after the close of the comment period for the Proposed Rule. Furthermore, EPA's promulgation of a numeric limit for total fluorides is not a logical outgrowth of a proposal to establish a work practice standard for hydrogen fluorides. It would have been impracticable for PCS to provide meaningful comments NAI* 1500577867v3 17cv1906 Sierra Club v. EPA - 6/22 Production -10- ED 001523 00007569-00011 on the appropriate level of a total fluoride limit which was never even mentioned by EPA in the Proposed Rule. See Envtl. Integrity Project v. EPA, 425 F.3d 992,996 (D.C. Cir. 2005) (explaining that the logical outgrowth doctrine does not apply "where interested parties would have to `divine [the agency's] unspoken thoughts'") (quoting Arizona Pub. Serv. Co. v. EPA, 211 F.3d 1280,1299 (D.C. Cir. 2000)). EPA is required to grant reconsideration of the total fluorides limit for phosphate rock calciners under these circumstances. II. EPA Should Reconsider the Parametric Monitoring and Operattog Requirements for Low-Energy Absorbers. As explained previously, PCS supports and incorporates the grounds for reconsideration set forth in TFI's Petition, including TFI's concerns with the new liquid-to-gas ratio monitoring and operating requirements for low-energy absorbers. PCS also presents the following grounds for reconsideration that are unique to the PCS facilities. PCS operates at least 11 low-energy absorbers subject to the NESHAPs in Aurora, NC; six in Geismar, Louisiana; and three in White Springs, Florida. For many years now, PCS has monitored and recorded influent liquid flow rate and pressure drop information for low-energy absorbers under Subparts AA and BB. See 40 C.F.R 63.605(c), .625(c) (2002 - 2014). PCS continues to believe that monitoring pressure drop remains appropriate for some low-energy absorbers in order to ensure proper operation of the unit. Nevertheless, in the Final Rule, EPA for the first time asserts that "pressure drop is not integral to the mechanism used in [a low-energy] absorber to mix the scrubbing liquid and inlet gas." 80 Fed. Reg. at 50,418. EPA's support for this statement is found in a Technical Memorandum that was added to the rulemaking docket after the close of the comment period. "Use of Pressure Drop as an Operating Parameter," (Dkt. ID No. EPA-HQ-OAR-2012-05220077) (uploaded to the docket on August 19,2015) ("Technical Memo"). PCS believes, NAI-1500577867v3 -11- 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00012 however, that the Technical Memo fails to account for relevant differences among low-energy absorbers and, instead, focuses on solids particulate loading in low-energy absorbers. See id. at 1 (asserting that pressure drop is not a parameter of interest in low-energy absorbers "because it is not directly related to the effectiveness of particle capture"). The Technical Memo fails to address certain low-energy absorbers at some PCS facilities that have different mechanisms for pollutant capture; for example, crossflow absorbers that utilize a mesh pad to promote contact, or liquid-to-gas absorbers where the gas is also absorbed into a liquid such that the inertial impact portion of the capture mechanism is not as dominant Reconsideration is necessary to allow an opportunity for public comment on technical issues related to EPA's rationale for eliminating pressure drop as an acceptable parameter for low-energy absorbers. EPA also should reconsider the requirement for liquid-to-gas ratio monitoring as the only option for parametric monitoring of low-energy absorbers. 80 Fed. Reg. at 50,446 (40 C.F.R. Part 63, Subpart AA, Table 3), 50,457 (40 C.F.R. Part 63, Subpart BB, Table 3). Unlike the Final Rule, the Proposed Rule would have allowed other options, besides a liquid-to-gas ratio, for low-energy absorbers. See, e g., 79 Fed. Reg. at 66,575 (proposed 40 C.F.R. Part 63, Subpart AA, Table 3). The switch to require liquid-to-gas ratio monitoring only is not a "logical outgrowth" of the Proposed Rule and has a significant negative impact on PCS facilities, especially in light of the immediate effective date of this requirement. None of the low-energy absorbers at PCS facilities are capable of complying with the new requirement for immediate liquid-to-gas ratio monitoring, because none of the absorbers in question have gas influent monitoring equipment. Installing the requisite monitors on the influent side of these absorbers will take time (at a minimum, a year to order and install equipment) and will present technical challenges that EPA has not allowed facilities an NAI-1500577867v3 17cv1906 Sierra Club v. EPA - 6/22 Production -12- ED 001523 00007569-00013 opportunity to evaluate and address in comments. Indeed, at some units, PCS does not know if it is even technically feasible to install such meters. EPA must allow a meaningful opportunity for comment on the technical challenges and cost of gas flow monitoring equipment Although the Final Rule includes an option to utilize design blower capacity "with appropriate adjustments for pressure drop" instead of installing gas flow monitors, it was not possible for PCS to achieve compliance with this option immediately on August 19,201S as required by the Final Rule. 80 Fed. Reg. at 50,446 (40 C.F.R. Part 63, Subpart AA, Table 3), 50,457 (40 C.F.R. Part 63, Subpart BB, Table 3). Achieving compliance on August 19,2015 would have required an impossible, instantaneous change in monitoring procedures at the PCS facilities. Furthermore, determining gas flow based on design blower capacity raises a number of technical questions that are not addressed in the Final Rule and that will require time for PCS to resolve. For example, it is not clear what EPA means by "appropriate adjustments for pressure drop." Nor is it clear how gas flow should be determined in cases where multiple absorbers share a single fan or blower, or where one absorber has multiple fans or blowers. As another example, three low-energy absorbers at the PCS Phosphate facility in Aurora, North Carolina do not have any fans or blowers and therefore cannot comply with the option to utilize design blower capacity. In conversations with PCS after the Final Rule was issued, EPA has suggested that PCS should request EPA's approval of an Alternative Monitoring Plan under 40 C.F.R. 63.8(f) for these three low-energy absorbers. EPA's suggestion does not provide a reasonable path to compliance with the Final Rule. Requesting and obtaining EPA approval of an Alternative Monitoring Plan is a lengthy and complicated process. EPA's suggestion would create an unavoidable compliance problem for PCS facilities between the effective date of the Final Rule and an undetermined, future date of EPA approval of an Alternative Monitoring Plan, NAI-l 500S77867v3 17cv1906 Sierra Club v. EPA - 6/22 Production -13- ED 001523 00007569-00014 which EPA would have discretion to approve or not A rulemaking with notice and public comment is the appropriate mechanism for gathering information on feasible and economical methods of monitoring control device parameters. EPA should grant reconsideration to allow for public comment on both the appropriate methods of determining gas flow and the amount of time required to begin implementing liquid-to-gas ratio monitoring. III. This Petition.. In the Final Rule, EPA introduced new and unprecedented regulatory changes that create substantial costs and legal uncertainties for PCS facilities under Subparts AA and BB. PCS has been working diligently since the Final Rule was issued to achieve compliance to the extent possible. However, the requirements addressed in this Petition present ongoing compliance concerns that must be resolved through reconsideration and then appropriate regulatory amendments. Justice requires that EPA stay the Final Rule so that these issues can be resolved in an organized and fair manner without exposing PCS and other facilities to legal risks when it is impossible to achieve immediate compliance. Although EPA has broad authority to stay the Final Rule because "justice so requires," 5 U.S.C. 705, PCS notes that a stay would also be warranted under the criteria that courts apply when deciding whether to stay agency action. See Affinity Healthcare Servs. v. Sebelius, 720 F. Supp. 2d 12,15 (D.D.C. 2010) ("Motions to stay agency action pursuant to [5 U.S.C. 705] are reviewed under the same standards used to evaluate requests for interim injunctive relief"). "A plaintiff seeking a preliminary injunction must establish that he is likely to succeed on the merits, that he is likely to suffer irreparable harm in the absence of preliminary relief, that the balance of equities tips in his favor, and that an injunction is in the public interest." Winter v. NRDC, 555 U S. 7,20 (2008); see also Mills v. DC., 571 F.3d 1304,1308 (D.C. Cir. 2009) (same). NAI-1500577867v3 -14- 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00015 In this Petition, PCS has demonstrated that the total fluoride limit for calciners exceeds the results of actual emissions testing at the Aurora calciners during representative operating conditions. PCS is therefore likely to succeed on the merits of its claim that the total fluorides limit for the calciners must be revised to be consistent with the definition of an achievable MACT floor limit Similarly, there is no doubt that immediate compliance with liquid-to-gas ratio monitoring, as required by the Final Rule, is impossible for low-energy absorbers at PCS facilities, and that additional time is needed to resolve technical challenges associated with liquid-to-gas ratio determinations. Absent a stay, PCS will continue to suffer irreparable harm in the form of legal risks, substantial costs, and interruption of normal plant operations as it attempts to deal with the errors in the Final Rule. Equity, justice, and the public interest require a stay in these circumstances. CONCLUSION For the foregoing reasons, EPA should grant this Petition for reconsideration, administratively stay the Final Rule, and take any other steps needed to immediately defer or otherwise nullify the requirements of the Final Rule pending the outcome of reconsideration or judicial review. Dated: October 16,2015 Respectfully submitted, . / * ~~T) ----------- w-------------------- ------------------ i NAI-1500577867v3 17cv1906 Sierra Club v. EPA - 6/22 Production -15- ED 001523 00007569-00016 Attachment A, Original Petition ! April 29, 2014 Ms. Suzy Jordan PCS Phosphate Co. Inc. 1530 NC Highway 306 South Aurora, North Carolina 27806 Re: Summary Letter Report to Satisfy Requirements of the EPA 114 Request Conducted on April 1-4, 2014 - Aurora, North Carolina Dear Suzy: The intent of this letter is to provide a summary of the test URS performed on Calciner Nos. 2 and 3 conducted April 1-4, 2014. Background: The objective of the testing was to evaluate the total fluoride (F`), hydrogen fluoride (HF) from Calciner No. 3 and mercury (Hg) emissions levels from the Calciner No. 2 stack for submission to satisfy the EPA's 114 request. In addition to collecting the requested data, URS collected paired speciated mercury tubes for additional information. The test crew completed test runs of EPA Methods 1-4, 13B, 30B, 320 and collected speciated mercury tubes. A total of six 60-minute mns were performed for EPA Method 320 by Fourier Transform Infrared Spectroscopy (FTIR) for hydrogen fluoride, four of which were ran concurrently with EPA Method 13B. A total of six paired tubes for a sampling duration of 60 minutes by EPA Method 3 0B were collected. A total of three speciated paired tubes to differentiate the species of mercury emission were also collected, for internal purposes. Tests Conducted: The emissions testing on the Calciner No. 2 was completed April 1-2, 2014. The test team arrived on Monday March 31, 2014 to set up and start testing, however, high winds caused testing to become unsafe, and resulted in testing delayed until Tuesday when weather conditions improved. Emission testing on the Calciner No. 3 was completed April 3-4, 2014 for EPA Method 13B and EPA Method 320, because Calciner No. 2 went offline. Mercury analysis for the EPA Method 30B and the speciated samples was completed at the URS Laboratory in Morrisville, NC. Test results for all emission sampling tests are summarized in Tables 1-4. Table 5 summarizes the QA/QC performed on the FTIR prior to and during the EPA Method 320 by FTIR sampling runs. Additional test run supporting data are provided in the attachments to this letter report. URS Corporation 1600 Perimeter Park Drive, Suite 400 Morrisville, NC 27560 Tel: 919.461110) Fax: 919.461.1415 www.urs.com 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00017 Table 1 Summary of Speciated Paired Tubes Test Results Calciner No. 2 Nil in pic \ oIn me Axeragc Spccialcd llg Concentrations (ug/dscm) Axeragc llg ( oiicciilration Axeragc Hr Km iss iu. Kim (Id Particulate Oxidized Elemental (Ug/dscm) (IIW hr) 4A 29.74 0.06 4B 26.97 0.18 28.11 28.4 0.0040 6A 31.47 0.13 0.40 29.92 30.5 0.0043 6B 29.44 7A 33.10 0.18 0.51 32.45 33.1 0.0049 7B 33.19 Table 2 Summary of EPA Method 30B Paired Tubes Test Results Calciner No. 2 Sample Hr Axeragc llg Axeragc llg Volume Concentration Concentration E mission Kim (L) (ug/dscm) (ug/dscm) (10/hr) 1A1 75.51 IB 75.33 14.95 23.48 19.2 0.0027 2A 78.69 2B 79.63 25.85 24.02 29.5 0.0041 3A 79.45 3B 78.04 25.87 28.49 24.6 0.0035 5A 49.89 5B 49.08 26.29 29.91 40.5 0.0057 8A 78.09 8B 74.30 40.49 43.27 41.9 0.0062 9A 75.29 9B 74.30 37.24 38.90 38.1 0.0054 1 The spiked tubes for Run 1 A/B resulted in 71.19 ug/dscm, which is outside of the method specified matrix spike recovery criteria. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00018 Table 3 Summary of EPA Method 13B Test Results Calciner No. 3 Run Run I'iiiie 1 09:( 5-10:15 2 11:( 6-12:13 3 13:( 0-14:05 4 14:f 5 - 16:02 Average lotal lluoridc (mg) 0.686 0.843 0.194 0.157 0.470 riuoride Concentration (|)|)m\) 0.905 1.126 0.270 0.218 0.630 Owgen (%) 14.7 15.1 14.2 15.3 14.8 rluoride Concentration (|)|)im 'a 3% ();) 2.61 3.48 0.72 0.70 1.88 Table 4 Summary of HF EPA Method 320 Test Results Calciner No. 3 III Concentration () \\ gen Run Run lime (|)|)iu\) ( /) 1 09:05 - 10:07 0.181 14.7 2 11:07- 12:20 0.156 15.1 3 13:00- 14:05 <0.141 14.2 4 14:55- 16:01 <0.141 15.3 5 16:40- 17:39 <0.141 14.8 6 18:23 - 19:21 <0.141 14.8 III-' Concentration' (ppniN a 3% ():) 0.52 0.48 0.38 0.45 0.42 0.42 1 The method detection limit of 0.141 ppmv was used to calculate the HF concentration of ppmv @ 3% O2. 2 EPA Method 320 was performed concurrently with EPA Method 13B for Runs 1-4. The O2 level for Runs 5 and 6 were determined using an average of Runs 1-4. 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00019 Table 5 Summary of Quality Assurance for HF Method 320; Sulfur Hexafluoride (SF6) Tracer Calciner No. 3 Obserx ed Start rime - Dilution Spike U ' factor Pre-Test Spike 1 0. 071 1.421 Spike (ppim) - Pre-Test Spike 2 0. 068 1.327 - Pre-Test Spike 3 0. 068 1.296 09:05 - 10:07 Post Run 1 0.072 1. 553 11:07- 12:20 Post Run 2 0.073 1. 119 13:00- 14:05 Post Run 3 0.076 1. )27 < 0.035 14:55 - 16:01 Post Run 4 0.076 1. )41 < 0.035 16:40- 17:39 Post Run 5 0.074 1. 105 < 0.035 18:23 - 19:21 Post Run 6 0.072 1. )68 < 0.035 1 HF MDL equals 0.141 ppmv. Native III (ppim) - - 0.250 0.127 Tracer Cone. (ppim) - - - 0.617 0.625 0.644 0.644 0.634 0.616 Expected Spike (ppim) 1.404 1.373 1.372 1.200 1.096 1.048 1.048 1.032 1.005 Percent Recox erx (%) ' 101.2 96.6 94.5 112.7 102.2 98.0 99.4 107.0 106.3 Spike Recox erx Limits (%) 70- 130 70- 130 70- 130 70- 130 70- 130 70- 130 70- 130 70- 130 70- 130 An audit sample through the Source Sampling Audit Sample (SSAS) program was acquired from an Accredited Audit Sample Provider (AASP). The SSAS was analyzed by PCS in conjunction with a field sample in the laboratory. Table 6 summarizes the results from the Calciner No. 3 fluoride audit sample. Table 6 Summary of AASP Audit Results Parameter Fluoride l nits mg/dsem Lahoralorx Result 0.491 Acceptable Range 0.424 - 0.574 Assigned Value 0.499 As documentation of test results from this testing event, the attachments to this letter include detailed EPA Method 13B and 30B emissions test summaries, copies of raw field data sheets, example calculations, equipment calibration records, and analytical results. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00020 If you have any questions regarding the results provided in this test report feel free to contact Bob Jongleux at (919)-461-1242. URS Corporation Enclosure cc: Jimmy Hardy - PSC Randy Taylor - URS Ross Smith - PCS Steve Hall - URS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00021 Attach merit A Data Su m maries and Field Data 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00022 PCS Phosphate Calciner #2 Mercury Emission Calculations o2 Correction Basis 3 Pollutant: Mercury Run 1 2 3 5 8 9 AVERAGE Hg Concentration |jg/dscm 19.2 29.5 24.6 40.5 41.9 38.1 32.3 Hg Concentration ppmV 0.0023 0.0035 0.0030 0.0049 0.0050 0.0046 0.0039 Oxygen % 15.8 15.8 15.8 15.8 13.8 13.6 15.1 Hg Concentration pg/dscm @ 3% 67.4 103.5 86.5 142.1 105.6 93.4 99.7 Flow Rate dscfm 37,723 36.966 38.118 37,803 39.382 38.072 38011 Hg Emissions Ib/hr 0.0027 0.0041 0.0035 0.0057 0.0062 0.0054 0.0046 Hg Emissions oz/year 380.8 572.6 493.5 803.8 866.5 761.5 646.4 Copy of PCS Method 30B 2014 MOD_1 .xls 17cv1906 Sierra Club v. EPA - 6/22 Production Mercury ED 001523 00007569-00023 PCS Phosphate Calciner #2 Mercury - Speiciated Emission Calculations Oo Correction Basis % Pollutant: Run 4 6 7 AVERAGE Hg Concentration pig/dscm 28.4 30.5 33.1 30.6 Hg Concentration ppmV 0.0034 0.0037 0.0040 0.0037 Oxygen 0/ 15.8 15.8 13.8 15.1 Hg Concentration pg/dscm @ 3% 99.5 106.9 83.6 96.7 Flow Rate dscfm 37.352 37.803 39.382 38.179 Hg Emissions Ib/hr 0.0040 0.0043 0.0049 0.0044 Hg Emissions oz/year 556.4 604.8 685.7 633.1 PCS Method speciated 2014_MOD.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Mercury ED 001523 00007569-00024 PCS Phosphate Calciner # 3 Method 13B Emission Calculations Normal Oo Correction Basis % Pollutant: Fluoride Total F- Sample F- F- Catch Volume Concentration Concentration Oxygen Concentration Flow Rate Run mg dscf mg/dscm ppmV % ppmV @ 3% dscfm 0.686 33.885 0.71 0.905 14.7 2.61 39,250 0.843 33.453 0.89 1.126 15.1 3.48 38.934 0.194 32.131 0.21 0.270 14.2 0.72 37.604 38.143 Calciner3 M13B 040414.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Other Pollutant Results ED 001523 00007569-00025 PCS Phosphate Calciner# 3 FTIR EPA Method 320 Emission Calculations 02 Correction Basis 3 Pollutant: HF Run 1 2 3 4 5 6 Field Blank AVERAGE HF ppmV 0.181 0.156 0.141 0.141 0.141 0.141 0.150 Oxygen % 14.7 15.1 14.2 15.3 14.8 14.8 HF ppmV @ 3% 0.52 0.48 0.38 0.45 0.42 0.42 14.8 0.46 Calciner3 M320 Emis Sum.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Other Pollutant Results ED 001523 00007569-00026 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 1 Potash Corp #2 Calciner Normal -0,1 100 30,04 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs, Stack Press, (in, Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5,10 5.1 02 Percent 15,80 N2 Percent 15.8 79.1 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 18.66 18.66 0.813 29.45 27.31 4/1/2014 PAT/WL 0.84 C 72,0 4071.5 29.94 29.93 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AB) (in H20) 0.27 0.26 0.23 0.22 0.23 0.21 0.27 0.23 0.24 0.28 0.26 0.21 0.31 0.32 0.30 0.32 0.32 0.36 0.20 0.23 0.24 0.22 0.21 0.20 Stack Temp Ts (F) 140 142 143 144 142 140 139 138 136 135 135 132 144 143 141 140 140 143 140 133 133 132 132 132 Square Root of AJ> SQRT(AB) 0.520 0.510 0.480 0.469 0.480 0.458 0.520 0.480 0.490 0.529 0.510 0.458 0.557 0.566 0.548 0.566 0.566 0.600 0.447 0.480 0.490 0.469 0.458 0.447 Stack Gas Velocity (fps) 32.0 31.4 29.6 29.0 29.6 28.2 31.9 29.5 30.0 32.4 31.2 28.0 34.4 34.9 33.7 34.8 34.8 37.0 27.5 29.3 30.0 28.7 28.0 27.3 Average Stack Average SORT Temp AP Average Velocity 138.29 0.50 30.96 Act Volumetric Flow Rate (acfm) Std, Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 52530 46378 37723 PCS Method 30B 2014 1.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R1 ED 001523 00007569-00027 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 2 Potash Corp #2 Calciner Normal -0,1 100 30,04 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs, Stack Press, (in, Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5,30 5.3 02 Percent 15,80 N2 Percent 15.8 78.9 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 17.72 17.72 0.823 29.48 27.45 4/1/2014 PAT/WL 0.84 C 72,0 4071.5 29.94 29.93 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (A8) (in H20) 0.24 0.23 0.24 0.22 0.21 0.24 0.24 0.25 0.27 0.26 0.24 0.20 0.26 0.32 0.28 0.29 0.32 0.24 0.23 0.20 0.20 0.19 0.18 0.21 Stack Temp Ts (F) 140 144 144 143 142 141 139 138 137 136 136 134 132 133 133 133 133 133 133 132 132 132 132 132 Square Root of A/P SQRTJAR) 0.490 0.480 0.490 0.469 0.458 0.490 0.490 0.500 0.520 0.510 0.490 0.447 0.510 0.566 0.529 0.539 0.566 0.490 0.480 0.447 0.447 0.436 0.424 0.458 Stack Gas Velocity (fps) 30.1 29.5 30.2 28.9 28.2 30.1 30.0 30.6 31.8 31.2 30.0 27.3 31.1 34.5 32.3 32.9 34.5 29.9 29.3 27.3 27.3 26.6 25.9 27.9 Average Stack Average SdjF^T Temp AP Average Velocity 136.00 0.49 29.88 Act Volumetric Flow Rate (acfm) Std, Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 50690 44925 36966 PCS Method 30B 2014 1.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R2 ED 001523 00007569-00028 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 3 Potash Corp #2 Calciner Normal -0,1 100 30,04 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs, Stack Press, (in, Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5,10 5.1 02 Percent 15.80 N2 Percent 15.8 79.1 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 18.66 18.66 0.813 29.45 27.31 4/1/2014 PAT/WL 0.84 C 72,0 4071.5 29.94 29.93 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (A8) (in H20) 0.29 0.26 0.27 0.26 0.28 0.22 0.24 0.25 0.27 0.24 0.25 0.21 0.28 0.30 0.34 0.32 0.28 0.33 0.24 0.22 0.24 0.25 0.22 0.20 Stack Temp Ts (F) 135 135 138 141 143 144 144 143 141 140 139 136 137 138 139 139 136 139 139 139 138 137 136 134 Square Root of A/P SQRT(AB) 0.539 0.510 0.520 0.510 0.529 0.469 0.490 0.500 0.520 0.490 0.500 0.458 0.529 0.548 0.583 0.566 0.529 0.574 0.490 0.469 0.490 0.500 0.469 0.447 Stack Gas Velocity (fps) 33.0 31.2 31.9 31.4 32.6 29.0 30.2 30.8 32.0 30.1 30.7 28.1 32.5 33.6 35.8 34.8 32.4 35.3 30.1 28.8 30.1 30.7 28.8 27.4 Average Stack Average SdjF^T Temp AP Average Velocity 138.75 0.51 31.31 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 53121 46864 38118 PCS Method 30B 2014 1.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R3 ED 001523 00007569-00029 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 4 Potash Corp #2 Calciner Normal -0,1 100 30,04 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs, Stack Press, (in, Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5,00 5.0 02 Percent 15,80 N2 Percent 15.8 79.2 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 19.29 19.29 0.807 29.43 27.23 4/1/2014 PAT/WL 0.84 C 72,0 4071.5 29.94 29.93 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (A8) (in H20) 0.27 0.25 0.26 0.26 0.27 0.20 0.22 0.24 0.25 0.24 0.23 0.22 0.29 0.31 0.33 0.32 0.26 0.31 0.27 0.21 0.24 0.23 0.22 0.19 Stack Temp Ts (F) 142 144 143 142 141 138 138 138 138 137 137 134 140 142 142 141 140 140 139 138 137 136 136 134 Square Root of A/P SQRT(AB) 0.520 0.500 0.510 0.510 0.520 0.447 0.469 0.490 0.500 0.490 0.480 0.469 0.539 0.557 0.574 0.566 0.510 0.557 0.520 0.458 0.490 0.480 0.469 0.436 Stack Gas Velocity (fps) 32.1 30.9 31.5 31.5 32.0 27.5 28.9 30.1 30.8 30.1 29.5 28.8 33.2 34.4 35.5 34.9 31.4 34.3 32.0 28.2 30.1 29.5 28.8 26.7 Average Stack Average SdjF^T Temp AP Average Velocity 139.04 0.50 30.94 Act Volumetric Flow Rate (acfm) Std, Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 52482 46277 37352 PCS Method 30B 2014 1.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R4 ED 001523 00007569-00030 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 5 Potash Corp #2 Calciner Normal -0,1 100 30,04 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs, Stack Press, (in, Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5,00 5.0 02 Percent 15,80 N2 Percent 15.8 79.2 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 18.18 18.18 0.818 29.43 27.35 4/1/2014 PAT/WL 0.84 C 72,0 4071.5 29.94 29.93 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (A8) (in H20) 0.26 0.24 0.22 0.23 0.21 0.23 0.28 0.29 0.27 0.22 0.21 0.19 0.31 0.33 0.28 0.32 0.35 0.28 0.25 0.23 0.22 0.22 0.25 0.20 Stack Temp Ts (F) 136 137 138 138 138 137 137 137 136 139 137 135 134 136 137 139 139 140 138 137 137 137 136 135 Square Root of A/P SQRT(AR) 0.510 0.490 0.469 0.480 0.458 0.480 0.529 0.539 0.520 0.469 0.458 0.436 0.557 0.574 0.529 0.566 0.592 0.529 0.500 0.480 0.469 0.469 0.500 0.447 Stack Gas Velocity (fps) 31.2 30.0 28.8 29.4 28.1 29.4 32.4 33.0 31.8 28.8 28.1 26.7 34.1 35.2 32.4 34.7 36.3 32.5 30.7 29.4 28.8 28.8 30.6 27.4 Average Stack Average SdjF^T Temp AP Average Velocity 137.08 0.50 30.79 Act Volumetric Flow Rate (acfm) Std, Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 52228 46205 37803 PCS Method 30B 2014 1.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R5 ED 001523 00007569-00031 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 6 Potash Corp #2 Calciner Normal -0,1 100 30,12 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs, Stack Press, (in, Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 6.90 6.9 02 Percent 13,80 N2 Percent 13.8 79.3 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 24.00 24.00 0.760 29.66 26.86 4/2/2014 PAT/WL 0.84 C 72,0 4071.5 30.02 30.01 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (A8) (in H20) 0.33 0.30 0.32 0.31 0.29 0.32 0.29 0.32 0.30 0.32 0.32 0.28 0.38 0.41 0.42 0.38 0.40 0.40 0.32 0.24 0.34 0.22 0.24 0.21 Stack Temp Ts (F) 145 153 155 154 153 151 146 146 148 151 153 150 142 146 148 148 147 146 146 145 144 149 151 152 Square Root of A/P SQRT(AB) 0.574 0.548 0.566 0.557 0.539 0.566 0.539 0.566 0.548 0.566 0.566 0.529 0.616 0.640 0.648 0.616 0.632 0.632 0.566 0.490 0.583 0.469 0.490 0.458 Stack Gas Velocity (fps) 35.7 34.3 35.5 34.9 33.7 35.4 33.5 35.2 34.2 35.4 35.4 33.1 38.3 39.9 40.4 38.4 39.4 39.4 35.2 30.5 36.2 29.3 30.6 28.7 Average Stack Average SdjF^T Temp AP Average Velocity 148.71 0.56 35.11 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 59558 51821 39382 PCS Method 30B 2014 1.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R6 ED 001523 00007569-00032 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 7 Potash Corp #2 Calciner Normal -0,2 100 30,12 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs, Stack Press, (in, Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 7.20 7.2 02 Percent 13.60 N2 Percent 13.6 79.2 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 22.27 22.27 0.777 29.70 27.09 4/2/2014 PAT/WL 0.84 C 72,0 4071.5 30.02 30.01 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (A8) (in H20) 0.28 0.32 0.27 0.26 0.28 0.29 0.30 0.31 0.33 0.29 0.30 0.24 0.30 0.41 0.30 0.31 0.29 0.27 0.26 0.25 0.27 0.23 0.25 0.23 Stack Temp Ts (F) 148 149 150 151 152 152 150 149 147 146 145 145 141 143 143 144 144 143 143 143 143 143 142 142 Square Root of A/P SQRT(AR) 0.529 0.566 0.520 0.510 0.529 0.539 0.548 0.557 0.574 0.539 0.548 0.490 0.548 0.640 0.548 0.557 0.539 0.520 0.510 0.500 0.520 0.480 0.500 0.480 Stack Gas Velocity (fps) 32.9 35.2 32.3 31.7 33.0 33.6 34.1 34.6 35.6 33.4 33.9 30.4 33.8 39.6 33.9 34.5 33.3 32.1 31.5 30.9 32.1 29.7 30.9 29.6 Average Stack Average SdjF^T Temp AP Average Velocity 145.75 0.53 33.03 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 56029 48977 38072 PCS Method 30B 2014 1.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R7 ED 001523 00007569-00033 Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner # 3 Condition Normal Sample Type: Method 13B Run Number: 1 Date: 4-Apr-14 2 4-Apr-14 3 4-Apr-14 Total Sampling Time (min) 60.0 60.0 60.0 Corrected Barometric Pressure (in Hg) Absolute Stack Pressure (in H20) 29.79 29.77 29.79 29.77 29.79 29.77 Stack Static Pressure (in H20) Average Stack Temperature (F Stack Area (sq in) Actual Meter Volume (cu ft) Average Meter Pressure (in H20] Average Meter Temperature (F Moisture Collected (g) Carbon Dioxide Concentration (%V) -0.24 151.0 4072 36.119 1.28 91.3 297.5 6.1 -0.24 152.5 4072 36.257 1.26 100.6 319.6 5.7 -0.24 152.3 4072 34.972 1.18 102.8 299.9 6.5 Oxygen Concentration (%V) Nitrogen Concentration (%V) 14.7 79.3 15.1 79.2 14.2 79.3 Dry Gas Meter Factor (y5) 0.9808 0.9808 0.9808 Nozzle Diameter (in) Pitot Constant 0.276 0.84 0.276 0.84 0.276 0.84 Average Sampling Rate (dscfm) 0.565 0.558 0.536 Standard Metered Volume (dscf) 33.885 33.453 32.131 Standard Metered Volume (dscm) Stack Moisture (%V) Saturated Moisture (%V) Mole Fraction Dry Stack Gas Dry Molecular Weight 0.960 29.3 26.1 0.739 29.56 0.947 31.1 26.7 0.733 29.52 0.910 30.6 26.7 0.733 29.61 Wet Molecular Weight Average SORT of Delta P Stack Gas Velocity (fps) Stack Gas Velocity (mpm) Volumetric Flow Rate (acfm) Volumetric Flow Rate (acmm) Volumetric Flow Rate (dscfm) Volumetric Flow Rate (dscmm) 26.54 0.58 36.4 11.1 61740 1748 39250 1112 26.44 0.58 36.5 11.1 61936 1754 38934 1103 26.51 0.56 35.2 10.7 59795 1693 37604 1065 Percent Isokinetic Post Test Meter QA (yqa) 98.0 1.0253 97.5 1.0220 97.0 1.0268 4 4-Apr-14 60.0 29.79 29.77 -0.24 151.1 4072 35.252 1.20 107.3 277.3 5.6 15.3 79.1 0.9808 0.276 0.84 0.536 32.136 0.910 28.9 26.1 0.739 29.51 26.51 0.56 35.4 10.8 60003 1699 38143 1080 95.6 1.0355 Average 60.0 29.79 29.77 -0.24 151.9 4072 35.783 1.24 98.2 305.7 6.1 14.7 79.3 0.9808 0.276 0.84 0.553 33.156 0.939 30.3 26.5 0.735 29.56 26.50 0.57 36.0 11.0 61157 1732 38596 1093 97.5 1.0247 Calciner3 M13B 040414.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run Summary ED 001523 00007569-00034 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data C02 Percent Replicate 1 6.1 Replicate 2 Replicate 3 Average 6.1 Method 13E PCS Phosphate 31829746 Calciner# 2 Normal N-54 0.9806 2.5 29.89 02 Percent 14.7 14.7 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft) Static Pressure (Ps Stack Geometry (R or C)? Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.3 Nozzle ID (in) 4/4/2014 WL/PA1 1 1.9070 0.84 100 -0.24 c 72.0 0.275 0.277 0.276 0.276 impinger Weights (g) initial Final Net impinger 1 697.9 931.8 233T Impinger2 661.8 673.9 12.1 impinger 3 630.1 656.5 26.4 impinger 4 895.4 920.5 25.1 impinger 5 C impinger 6 0 impinger 7 c impinger 8 c Moisture Collected (g) 297.E Pitot Tube ED Saturated Percent Moisture 26.06 Standard Calculated Percent Moisture 29.28 Volume (dsef) isokinetic % 98.0 33.9 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 2.5 5 7.5 10 12.5 15 17.5 20 22.5 25 27.5 30 30 32.5 35 37.5 40 42.5 45 47.5 50 52.5 55 57.5 60 Clock Time (24 hr) 9:05:00 9:07:30 9:10:00 9:12:30 9:15:00 9:17:30 9:20:00 9:22:30 9:25:00 9:27:30 9:30:00 9:32:30 9:35:00 9:45:00 9:47:30 9:50:00 9:52:30 9:55:00 9:57:30 10:00:00 10:02:30 10:05:00 10:07:30 10:10:00 10:12:30 10:15:00 Dry Gas Meter Reading Vm (ft3) 756.075 757.660 759.320 761.030 762.710 764.340 765.970 767.530 768.840 770.150 771.560 772.850 774.193 774.193 776.010 777.680 779.350 780.810 782.190 783.750 785.180 786.690 788.070 789.430 791.000 792.194 Velocity Head (AP) (in H20) 0.41 0.46 0.48 0.44 0.44 0.43 0.28 0.25 0.27 0.28 0.23 0.24 0.41 0.39 0.32 0.35 0.26 0.38 0.31 0.29 0.31 0.30 0.28 0.26 Orifice Pressure Diff (AH) (in H20) 1.59 1.70 1.86 1.85 1.60 1.56 1.16 0.91 0.98 1.10 0.83 0.87 1.49 1.62 1.16 1.27 1.03 1.38 1.12 1.19 1.12 1.14 1.15 0.94 Stack Temp Ts (F) 149 153 149 143 153 153 144 154 154 148 157 158 155 144 154 155 147 154 154 145 153 150 145 154 Dry Gas Meter Temperature Tm in Tm out (F) (F) 87 87 87 87 88 88 88 88 88 88 89 88 89 88 89 88 91 89 92 89 92 90 92 90 92 92 93 92 93 92 93 93 94 93 94 93 95 93 97 94 95 94 96 94 96 94 96 94 Calciner3_M13B_040414.xisx Run 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00035 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data C02 Percent Replicate 1 5.7 Replicate 2 Replicate 3 Average 5.7 Method 13E PCS Phosphate 31829746 Calciner# 2 Normal N-54 0.9806 2.5 29.89 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.2 Nozzle ID (in) 4/4/2014 WL/PA1 2 1.9070 0.84 100 -0.24 c 72.0 0.275 0.277 0.276 0.276 impinger Weights (g) initial Final Net impinger 1 607.4 861.2 253. Impinger2 797.4 850.1 52.7 impinger 3 662.2 665.1 2.9 impinger 4 919.1 929.3 10.2 impinger 5 0 impinger 6 0 impinger 7 0 impinger 8 c Moisture Collected (g) 319.6 Pitot Tube ED Saturated Percent Moisture 26.72 Standard Calculated Percent Moisture isokinetic % 31.06 97.5 Volume (dsef) 33.5 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 2.5 5 7.5 10 12.5 15 17.5 20 22.5 25 27.5 30 30 32.5 35 37.5 40 42.5 45 47.5 50 52.5 55 57.5 60 Clock Time (24 hr) 11:06:00 11:08:30 11:11:00 11:13:30 11:16:00 11:18:30 11:21:00 11:23:30 11:26:00 11:28:30 11:31:00 11:33:30 11:36:00 11:43:00 11:45:30 11:48:00 11:50:30 11:53:00 11:55:30 11:58:00 12:00:30 12:03:00 12:05:30 12:08:00 12:10:30 12:13:00 Dry Gas Meter Reading Vm (ft3) 792.219 793.840 795.420 797.040 798.640 800.170 801.770 803.240 804.730 806.110 807.480 808.680 810.245 810.245 811.960 813.680 815.400 817.070 818.780 820.510 822.010 823.390 824.680 825.970 827.270 828.476 Velocity Head (AP) (in H20) 0.38 0.36 0.37 0.34 0.35 0.37 0.34 0.30 0.29 0.27 0.32 0.23 0.44 0.48 0.43 0.42 0.45 0.43 0.30 0.28 0.25 0.24 0.24 0.20 Orifice Pressure Diff (AH) (in H20) 1.42 1.31 1.45 1.33 1.27 1.41 1.23 1.09 1.12 0.99 1.16 0.87 1.73 1.74 1.71 1.52 1.63 1.61 1.11 1.01 0.91 0.87 0.87 0.76 Stack Temp Ts (F) 151 156 148 148 156 150 155 154 149 152 154 150 148 157 147 154 156 151 152 156 155 153 158 150 Dry Gas Meter Temperature Tm in Tm out (F) (F) 98 99 98 99 98 99 99 99 99 99 100 99 100 99 100 99 101 100 101 100 102 101 102 101 101 102 101 102 102 102 102 101 102 101 102 101 102 101 102 101 101 101 101 101 102 101 102 101 Calciner3_M13B_040414.xisx Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00036 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data C02 Percent Replicate 1 6.5 Replicate 2 Replicate 3 Average 6.5 Method 13E PCS Phosphate 31829746 Calciner# 2 Normal N-54 0.9806 2.5 29.89 02 Percent 14.2 14.2 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft) Static Pressure (Ps Stack Geometry (R or C)? Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.3 Nozzle ID (in) 4/4/2014 WL/PA1 3 1.9070 0.84 100 -0.24 c 72.0 0.275 0.277 0.276 0.276 impinger Weights (g) initial Final Net impinger 1 731.4 984.4 252 Impinger2 742 775.2 33.2 impinger 3 681.8 684.2 2.4 impinger 4 988.5 999.8 11,3 impinger 5 C impinger 6 0 impinger 7 0 impinger 8 0 Moisture Collected (g) 299. Pitot Tube ED Saturated Percent Moisture 26.72 Standard Calculated Percent Moisture 30.56 Volume (dsef) isokinetic % 97.0 32.1 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 2.5 5 7.5 10 12.5 15 17.5 20 22.5 25 27.5 30 30 32.5 35 37.5 40 42.5 45 47.5 50 52.5 55 57.5 60 Clock Time (24 hr) 13:00:00 13:02:30 13:05:00 13:07:30 13:10:00 13:12:30 13:15:00 13:17:30 13:20:00 13:22:30 13:25:00 13:27:30 13:30:00 13:35:00 13:37:30 13:40:00 13:42:30 13:45:00 13:47:30 13:50:00 13:52:30 13:55:00 13:57:30 14:00:00 14:02:30 14:05:00 Dry Gas Meter Reading Vm (ft3) 828.619 830.080 831.740 833.410 835.080 836.770 838.530 840.020 841.390 842.680 844.030 845.280 846.449 846.449 848.150 849.420 850.900 852.380 853.830 855.240 856.670 858.060 859.480 860.890 862.350 863.591 Velocity Head (AP) (in H20) 0.40 0.43 0.44 0.40 0.43 0.46 0.27 0.28 0.25 0.24 0.22 0.20 0.34 0.33 0.30 0.32 0.31 0.30 0.28 0.29 0.29 0.26 0.27 0.24 Orifice Pressure Diff (AH) (in H20) 1.57 1.56 1.60 1.64 1.56 1.72 1.07 1.01 0.91 0.97 0.80 0.72 1.23 1.20 1.09 1.24 1.12 1.09 1.11 1.05 1.10 1.02 0.98 0.87 Stack Temp Ts (F) 148 156 153 145 153 151 147 156 157 146 155 157 154 154 155 149 156 156 147 154 150 148 154 153 Dry Gas Meter Temperature Tm in Tm out (F) (F) 99 100 99 100 99 100 99 100 100 100 101 101 102 101 102 101 103 101 103 101 104 102 104 102 105 104 105 104 105 104 105 104 105 104 105 104 105 104 105 104 105 104 106 104 106 104 106 105 Calciner3_M13B_040414.xisx Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00037 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data C02 Percent Replicate 1 5.6 Replicate 2 Replicate 3 Average 5.6 Method 13E PCS Phosphate 31829746 Calciner# 2 Normal N-54 0.9802 2.5 29.89 02 Percent 15.3 15.3 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft) Static Pressure (Ps Stack Geometry (R or C)? Stack Diameter (in] Stack Width (If Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.1 Nozzle ID (in) 4/4/2014 WL/PA1 4 1.9070 0.84 100 -0.24 c 72.0 0.275 0.277 0.276 0.276 impinger Weights (g) initial Final Net impinger 1 746.2 983.6 237.4 Impinger2 687.2 715.9 28.7 impinger 3 533.6 534.9 1.3 impinger 4 958.8 968.7 9.9 impinger 5 0 impinger 6 0 impinger 7 0 impinger 8 c Moisture Collected (g) 277.2 Pitot Tube ID Saturated Percent Moisture 26.06 Standard Calculated Percent Moisture 28.92 Volume (dsef) isokinetic % 95.6 32.1 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 2.5 5 7.5 10 12.5 15 17.5 20 22.5 25 27.5 30 30 32.5 35 37.5 40 42.5 45 47.5 50 52.5 55 57.5 60 Clock Time (24 hr) 14:55:00 14:57:30 15:00:00 15:02:30 15:05:00 15:07:30 15:10:00 15:12:30 15:15:00 15:17:30 15:20:00 15:22:30 15:25:00 15:32:00 15:34:30 15:37:00 15:39:30 15:42:00 15:44:30 15:47:00 15:49:30 15:52:00 15:54:30 15:57:00 15:59:30 16:02:00 Dry Gas Meter Reading Vm (ft3) 864.319 866.080 867.560 869.110 870.780 872.310 873.660 875.040 876.480 877.790 879.160 880.680 881.932 881.932 883.810 885.520 887.050 888.520 890.010 891.470 892.910 894.350 895.640 896.980 898.310 899.571 Velocity Head (AP) (in H20) 0.37 0.33 0.35 0.36 0.29 0.32 0.29 0.27 0.24 0.27 0.28 0.24 0.48 0.44 0.34 0.42 0.42 0.38 0.29 0.27 0.25 0.26 0.22 0.23 Orifice Pressure Diff (AH) (in H20) 1.49 1.22 1.27 1.35 1.17 1.16 1.05 1.10 0.87 0.98 1.16 0.87 1.91 1.70 1.23 1.60 1.60 1.38 1.09 1.04 0.91 1.00 0.86 0.83 Stack Temp Ts (F) 146 152 156 151 146 155 155 145 154 155 144 154 147 149 155 150 150 155 151 149 155 149 148 155 Dry Gas Meter Temperature Tm in Tm out (F) (F) 106 107 106 107 106 107 106 107 107 108 108 108 108 108 109 109 109 109 109 109 108 109 107 109 107 108 106 108 107 107 107 107 106 107 107 107 107 107 107 107 107 107 107 107 106 106 106 106 Calciner3_M13B_040414.xisx Run 4 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00038 URS RTP, NC Project Analytical Support Laboratory Ohio Lumex Mercury Analysis URS Slope: 1.15E-02 QC Summary Project Name PCS - SOB URS Project#____________ 31829725.00001 Intercept: R;: 220.77 1.000 Lumex Hg Calibration 12000.00 10000.00 y = 0.012x-t-220.774 R2= 1.000 8000.00 6000.00 4000.00 2000.00 0.00 +00 -- -j'-'--" 1.0E+05 2.0E+05 3.0E+05 .............. +................ 4.0E+05 50E+05 6.0E+05 Peak Area Sampling Analysis Date Date Sample ID Trap# MDL (ng) DCS (ng) DL (ng) Temp. Profile 0.432 # 2 Air Flow (Train) 1 0.432 QC Recovery1 CCV min max 331.2% 331.2% 7.0E+05 8.0E+05 Fraction Known ng Peak Area ng % Recovery Trap Total ng Response Factor 0.03367 % Breakthrough 3/11/2014 3/11/2104 Facility ID Unit/Stack # Samole # lOOng re! 500ng lOOOng 5000ng lOOOOng 100.00 500.00 1000.00 5000.00 10000.00 2,970 24.400 66,100 416,000 846,000 255.1 502.5 984.0 5024.2 9989.3 100.5% `W.4% 100.5% W.9% Spike 0.0% 0.0% 2200 rain 1100 max 3300 Sample Hg Cone Average Hg Crec Spike Pair %D Volume (ua/dsem) Cone Recovery % (StdL) (pg/dsem) 3/11/2014 3/11/2014 3/11/2014 3/11/2014 3/11/2014 3/11/2014 3/11/2014 3/11/2014 3/11/2014 3/11/2014 PCS PCS PCS PCS PCS PCS PCS PCS PCS PCS Analyst: Calciner#2 Calciner#2 Calciner#2 Calciner#2 Calciner#2 Calciner#2 Calciner#2 Calciner#2 Calciner#2 Calciner#2 - ICV CCV Stack 1A Stack IB Stack 2A Stack 2B Stack 3A Stack 3B Stack 5A Stack 5B FB-A FB-B OL172024 OL207693 OL 172017 OL207680 OL172033 OL207655 OL 172029 OL207643 OL211455 OL207686 Section 1 Section 2 Section 1 Section 2 Section 1 Section 2 Section 1 Section 2 Section 1 Section 2 Section 1 Section 2 Section 1 Section 2 Section 1 Section 2 Section 1 Section 2 Section 1 Section 2 Stephanie Chesebro 59,200 59,800 267,000 751 131,000 1,050 345,000 893 146,000 174 344,000 1,860 171,000 837 285,000 0 108,000 0 183,000 0 0 0 63,800 904.3 911.3 3303.7 25.3 1733.4 35.4 4204.4 30.1 1906.6 5.9 4192.8 62.6 2295.3 28.2 3511.6 0.0 2467.8 0.0 2333.8 0.0 220.8 0.0 957.5 Date 4/3/2014 1768.7 4234.5 2912.4 4255.5 2223.4 3512.6 1467.8 2333.8 220.8 2.0% 0.7% 0.3% 1.5% 1.3% 0.0% 0.0% 0.0% 0.0% 75.33 78.69 79.63 79.45 78.04 49.89 49.08 73.93 73.27 23.48 25.85 24.02 25.87 28.49 26.29 29.91 1.81 3.02 27.28 -.p-7] 24.64 -i r 95.94 4.82 URS-RTP Hg Analysis - Analytical Sheet 17cv1906 Sierra Club v. EPA - 6/22 Production Report Generated 4/14/2014 Page 1 of 3 ED 001523 00007569-00039 URS RTP, NC Project Analytical Support Laboratory Ohio Lumex Mercury Analysis I QC Summary Project Name PCS - 30B URS Project #____________ 31829725.00001 Slope: 1.61E-02 Intercept: R2: 24.65 1.000 Lumex Hg Calibration MDL (ng) DCS (ng) DL (ng) Temp. Profile 0.432 # 3 Air Flow (L'min) 1 0.432 QC Recovery min max CCV 178.9% 178.9% Response Factor 0.01304 Spike 0.0% 0.0% 2200 min 1100 max 3300 Sampling Analysis Date Date Sample ID Peak Area Trap # 3/11/2014 3/11/2104 Facility ID Unit/Stack # Samole # lOOng ref 500ng lOOOng 50Q0ng lOOOOng Fraction Known ng Peak Area ng % Recovery Trap Total ng % Breakthrough Sample Hg Cone Average Hg Crec Spike Pair %D Volume (|ig''dscm) Cone Recovery % (Std L) (|ig''dscm) 100.00 500.00 1000.00 5000.00 10000.00 7,670 32,100 62.500 300,000 622,000 148.4 542.5 1033.0 4864.7 10059.7 148.4% 108.5% 103.3% 97.3% 100.6% 5/11/2014 3/11/2014 5/1 1/2014 3/1 1/2014 ICV CCV Stack 8A Stack 8B Stack 9A Stack 9B OL211456 OL207687 OL172053 OL207681 Section ; Section 7 Section ; Section 7 Section i Section * Section ' 61.500 62,600 330.000 1,020 197.000 900 302.000 8.210 174.000 1016.9 1034.6 5348.7 13.3 3203.0 11.7 4897.0 107.0 2831.9 101.7% 103.5% Analyst: Stephanie Chesebro Date 4/4/2014 URS-RTP Hg Analysis - Analytical Sheet 2 17cv1906 Sierra Club v. EPA - 6/22 Production Report Generated 4/14/2014 Page 2 of 3 ED 001523 00007569-00040 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 16 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL172024 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002547 0.9996 0.9996 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) 11:35:0Q 11:40 11:45 11:50 11:55 12:00 12:05 12:10 12:15 12:20 12:25 12:30 12:35 Digital Gas Meter Reading (L) 0.000 6.480 12.310 18.400 24.090 30.340 36.460 42.390 48.940 55.410 61.970 68.350 74.7920 74.7920 Mechanical Gas Meter Reading (m3) 74.7920 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 146 253 64 34 261 146 254 64 34 261 146 286 65 34 263 146 290 65 34 267 146 265 65 34 267 146 251 65 34 264 146 283 65 34 263 146 298 65 34 266 146 272 65 34 266 146 261 65 34 265 146 272 65 34 262 146 298 65 34 265 146 274 65 34 266 146 273.62 64.85 34.00 264.31 Pump Vacuum (" Hg) 2 2 3 3 3 3 3 3 3 3 3 3 3 2.85 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 75510.74482 75.5107448 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 1A ED 001523 00007569-00041 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 22 Final Leak Check (L/min @ "Hg) 0.000 19 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" KfeO) Barometric Pres. (" Hg) OL207693 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002511 0.9884 0.9884 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 11:35:00 11:40 11:45 11:50 11:55 12:00 12:05 12:10 0.000 6.820 13.110 19.120 25.550 31.090 38.280 44.490 12:15 12:20 12:25 12:30 12:35 50.620 56.980 63.330 69.470 75.6390 75.6390 75.6390 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 146 253 66 34 261 146 254 66 34 261 146 286 67 34 263 146 290 67 34 267 146 265 66 34 267 146 251 66 34 264 146 283 66 34 263 146 298 66 34 266 146 272 65 34 266 146 261 66 34 265 146 272 66 34 262 146 298 66 34 265 146 274 66 34 266 146 273.62 66.08 34.00 264.31 Pump Vacuum <" Hg) 5 5 5 5 5 5 5 5 5 5 5 5 5 5.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 75333.4754 75.3334754 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production IB ED 001523 00007569-00042 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 22 Final Leak Check (L/min @ "Hg) 0.000 16 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL172017 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002547 0.9996 0.9996 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 12:50:00 0.000 12:55 6.730 13:00 13:05 13.160 19.740 13:10 26.470 13:15 13:20 32.870 39.160 13:25 13:30 45.670 52.360 13:35 58.590 13:40 65.040 13:45 71.390 13:50 78.0000 78.0000 78.0000 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 146 284 66 34 259 146 284 66 34 260 146 291 66 34 263 146 261 65 34 263 146 271 65 34 264 146 286 65 34 262 146 294 65 34 264 146 288 65 34 265 146 272 65 34 266 146 277 65 34 263 146 269 65 34 264 146 280 65 34 264 146 281 65 34 264 146 279.85 65.23 34.00 263.15 Pump Vacuum <" Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 3.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 78691.87053 78.6918705 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2A ED 001523 00007569-00043 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 24 Final Leak Check (L/min @ "Hg) 0.000 18 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL207680 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002511 0.9884 0.9884 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading <L) Mechanical Gas Meter Reading (m3) 12:50:00 12:55 0.000 6.920 13:00 13:05 13:10 13:15 13:20 13:25 13:30 13:35 13:40 13:45 13:50 13.290 19.830 26.480 32.930 39.320 45.680 52.220 58.390 65.130 71.440 79.9730 79.9730 79.9730 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 146 284 67 34 259 146 284 67 34 260 146 291 67 34 263 146 261 66 34 263 146 271 66 34 264 146 286 66 34 262 146 294 66 34 264 146 288 66 34 265 146 272 66 34 266 146 277 66 34 263 146 269 66 34 264 146 280 66 34 264 146 281 66 34 264 146 279.85 66.23 34.00 263.15 Pump Vacuum <" Hg) 5 5 5 5 5 5 5 5 5 5 5 5 5 5.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 79626.66863 79.6266686 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2B ED 001523 00007569-00044 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 15 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL172033 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002547 0.9996 0.9996 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 14:05:00 14:10 14:15 14:20 14:25 14:30 0.000 6.820 13.300 19.910 26.480 32.940 14:35 14:40 14:45 14:50 39.270 45.910 52.670 59.700 14:55 15:00 15:05 65.850 72.140 78.6240 78.6240 78.6240 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 141 280 64 34 263 141 288 64 34 262 141 288 64 34 262 141 272 65 34 263 141 273 65 34 262 141 264 65 34 263 141 289 65 34 264 141 289 65 34 263 141 264 64 34 263 141 271 64 34 264 141 283 64 34 263 141 291 64 34 263 141 288 64 34 263 141 280.00 64.38 34.00 262.92 Pump Vacuum <" Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 3.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 79449.48015 79.4494801 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3A ED 001523 00007569-00045 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 23 Final Leak Check (L/min @ "Hg) 0.000 18 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL207655 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002511 0.9884 0.9884 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 14:05:00 14:10 14:15 14:20 14:25 14:30 14:35 14:40 14:45 14:50 14:55 15:00 15:05 0.000 6.940 13.620 20.420 27.050 33.550 39.850 46.160 52.560 59.410 65.500 71.740 78.1920 78.1920 78.1920 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 141 280 65 34 263 141 288 65 34 262 141 288 65 34 262 141 272 65 34 263 141 273 65 34 262 141 264 65 34 263 141 289 65 34 264 141 289 65 34 263 141 264 65 34 263 141 271 65 34 264 141 283 65 34 263 141 291 65 34 263 141 288 65 34 263 141 280.00 65.00 34.00 262.92 Pump Vacuum C Hg) 5 5 5 5 5 5 5 5 5 5 5 5 5 5.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 78036.00965 78.0360096 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3B ED 001523 00007569-00046 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 20 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL172029 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002547 0.9996 0.9996 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 16:41:00 0.000 5 16:46 4.270 10 16:51 7.950 15 16:56 12.620 20 17:01 16.090 25 17:06 20.140 30 17:11 24.400 35 17:16 28.480 40 17:21 32.870 45 17:26 37.400 50 17:31 40.620 55 17:36 44.850 60 17:41 48.9910 48.9910 48.9910 Meter Flow Rate (Lpm) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 140 270 62 34 258 140 270 62 34 260 140 261 62 34 258 140 287 61 34 258 140 269 62 34 261 140 274 61 34 261 140 259 61 34 262 140 261 61 34 259 140 258 61 34 262 140 273 61 34 262 140 258 62 34 263 140 254 63 34 262 140 252 63 34 261 140 265.08 61.69 34.00 260.54 Pump Vacuum C Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 49893.52504 49.893525 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 5A ED 001523 00007569-00047 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 23 Final Leak Check (L/min @ "Hg) 0.000 23 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL211456 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002511 0.9884 0.9884 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading <L) Mechanical Gas Meter Reading (m3) 16:41:00 0.000 16:46 4.510 16:51 8.420 16:56 13.610 17:01 16.330 17:06 20.270 17:11 24.450 17:16 17:21 28.400 32.910 17:26 36.890 17:31 17:36 40.250 44.420 17:41 48.8410 48.8410 48.8410 Meter Flow Rate (Lpm) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 140 270 63 34 272 140 270 63 34 273 140 261 63 34 275 140 287 62 34 274 140 269 62 34 276 140 274 62 34 278 140 259 62 34 278 140 261 62 34 279 140 258 62 34 279 140 273 62 34 279 140 258 63 34 279 140 254 65 34 279 140 252 65 34 279 140 265.08 62.77 34.00 276.92 Pump Vacuum <" Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 3.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 49082.05862 49.0820586 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 5B ED 001523 00007569-00048 URS Date 4/2/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 17 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL172053 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002547 0.9996 0.9996 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading <m3) 9:18:00 0.000 9:23 9:28 9:33 9:38 12:43 12:48 12:53 12:58 7.710 14.120 20.600 27.100 33.150 39.910 46.150 52.900 13:03 13:08 13:13 59.640 66.220 72.630 13:18 79.0150 79.0150 79.0150 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 150 261 77 34 274 150 263 76 34 275 150 264 77 34 274 150 264 77 34 274 150 263 78 34 277 150 261 78 34 268 150 262 78 34 271 150 260 78 34 273 150 261 78 34 273 150 265 78 34 273 150 263 78 34 274 150 261 78 34 272 150 260 78 34 273 150 262.15 77.62 34.00 273.15 Pump Vacuum C Hg) 3 3 3 3 3 6 6 5 4 4 4 4 4 4.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 78085.79423 78.0857942 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 8A ED 001523 00007569-00049 URS Date 4/2/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 22 Final Leak Check (L/min @ "Hg) 0.000 19 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" FfeO) Barometric Pres. (" Hg) OL207681 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002511 0.9884 0.9884 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 10:52:00 0.000 10:57 6.320 11:02 11:07 12.480 18.800 11:12 12:43 12:48 24.910 30.990 37.640 12:53 12:58 44.740 52.090 13:03 57.790 13:08 13:13 64.050 70.220 13:18 76.8390 76.8390 76.8390 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 150 261 80 34 274 150 264 80 34 275 150 263 80 34 274 150 267 80 34 274 150 265 80 34 277 150 266 83 34 268 150 266 84 34 271 150 262 86 34 273 150 263 86 34 273 150 265 86 34 273 150 268 86 34 274 150 267 86 34 272 150 268 86 34 273 150 265.00 83.31 34.00 273.15 Pump Vacuum <" Hg) 5 5 5 5 5 6 6 5 5 5 5 5 5 5.15 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 74297.41787 74.2974179 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 8B ED 001523 00007569-00050 URS Date 4/2/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 17 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL172053 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002547 0.9996 0.9996 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) 10:52:00 10:57 11:02 11:07 11:12 12:43 12:48 12:53 12:58 13:03 13:08 13:13 13:18 0.000 6.150 12.260 18.820 24.730 30.830 37.260 44.320 51.780 57.960 64.0700 70.4300 76.8270 76.8270 Mechanical Gas Meter Reading (m3) 0.000 76.827 76.8270 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 150 261 79 34 274 150 264 79 34 275 150 263 79 34 274 150 267 79 34 277 150 265 79 34 277 150 266 81 34 268 150 266 83 34 271 150 262 84 34 273 150 263 85 34 273 150 265 85 34 273 150 268 85 34 274 150 267 85 34 272 150 268 85 34 273 150 265 82.15384615 Pump Vacuum C Hg) 3 3 3 3 3 6 6 5 4 4 4 4 4 Target Volume 0 Spike Amount (ng) 100 Comments: Mechanical Totalizer Total Volume (L) 75287.56905 75.2875691 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 9A ED 001523 00007569-00051 URS Date 4/2/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30B Run Number/Side (A/B) Operator Location Height Initial Leak Check (L/min @ "Hg) WL 0 0.000 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" HfeO) Barometric Pres. (" Hg) OL207681 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002511 0.9884 0.9884 Page 1 of Run No. Diagram of Duct & Travers Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) 10:52:00 10:57 11:02 11:07 11:12 12:43 12:48 12:53 12:58 13:03 13:08 13:13 13:18 0.000 6.320 12.480 18.800 24.910 30.990 37.640 44.740 52.090 57.790 64.0500 70.2200 76.8390 76.8390 Mechanical Gas Meter Reading <m3) 0.000 76.839 76.8390 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 150 261 80 34 274 150 264 80 34 275 150 263 80 34 274 150 267 80 34 277 150 265 80 34 277 150 266 83 34 268 150 266 84 34 271 150 262 86 34 273 150 263 86 34 273 150 265 86 34 273 150 268 86 34 274 150 267 86 34 272 150 268 86 34 273 83.30769231 Pump Vacuum <" Hg) 5 5 5 5 5 6 6 5 5 5 5 5 5 Target Volume o Spike Amount (ng) 0 Comments: Mechanical Totalizer Total Volume (L) 74297.41787 74.2974179 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 9B ED 001523 00007569-00052 URS Date 4/2/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30B Run Number/Side (A/B) FB | A Operator WL Location Height 0 Initial Leak Check (L/min @ "Hg) 0.000 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL211455 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002547 0.9959 0.9959 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point Sampling Time (min) 0 5 10 15 20 25 30 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 12:23:00 12:28 12:33 12:38 12:43 12:48 12:53 0.000 75.000 0.000 75.000 Meter Flow Rate (Lpm) 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 0 0 77 77 77 77 77 77 Pump Vacuum <" Hg) TOTAL 75.0000 75.0000 0 0 77 Target Volume 0 Spike Amount (ng) 100 Comments: Mechanical Totalizer Total Volume (L) 73928.3382 73.9283382 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Field Blank A ED 001523 00007569-00053 URS Date 4/2/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30B Run Number/Side (A/B) FB | B Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL207686 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % 002% 02/C02 Method 8002511 0.9884 0.9884 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point Sampling Time (min) 0 5 10 15 20 25 30 Clock Time (min) Digital Gas Meter Reading (L) 12:23:00 12:28 12:33 12:38 12:43 12:48 12:53 0.000 75.000 Mechanical Gas Meter Reading <m3) 0.000 75.000 Meter Flow Rate (Lpm) 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 0 0 76 0 0 0 0 76 0 0 0 0 77 0 0 0 0 77 0 0 0 0 77 0 0 0 0 77 0 0 Pump Vacuum <" Hg) TOTAL 75.0000 75.0000 76.66666667 Target Volume 0 Spike Amount (ng) 0 Comments: Mechanical Totalizer Total Volume (L) 73417.19346 73.4171935 PCS Method 30B 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production PCS Method 30B 2014.xls ED 001523 00007569-00054 Project Name PCS Aurora Unit Speciated Mercury Summary Calciner #2 Stack Sampling Date Analysis Date 4/1/2014 4/8/2014 Sample ID 4A 4/1/2014 4/8/2014 4B 4/1/2014 4/8/2014 6A 4/1/2014 4/8/2014 6B 4/2/2014 4/8/2014 7A 4/2/2014 4/8/2014 7B Trap # OL213525 OL213590 OL213509 OL213517 OL213506 OL213606 F raction Particulate Oxidized Elemental Particulate Oxidized Elemental Particulate Oxidized Elemental Particulate Oxidized Elemental Particulate Oxidized Elemental Particulate Oxidized Elemental ng 3.5 10.4 1679.6 3.5 10.4 1500.2 3.5 10.4 806.0 3.5 10.4 741.6 3.5 10.4 657.4 4.0 10.4 662.6 Trap Total ng Sample Volume (Std L) 1693.4 56.95 1514.0 56.14 819.9 26.05 755.5 25.67 671.2 20.28 677.1 20.40 Fraction Hg Cone (pg/dsem) 0.06 0.18 29.49 0.06 0.19 26.72 0.13 0.40 30.94 0.13 0.40 28.90 0.17 0.51 32.41 0.20 0.51 32.48 Total Hg Cone (pg/dsem) 29.74 26.97 31.47 29.44 33.10 33.19 Average Particulate Cone (pg/dsem) 0.06 0.13 0.18 Average Oxidized Cone (pg/dsem) 0.18 0.40 0.51 Average Elemental Cone (pg/dsem) Average Hg Cone (pg/dsem) 28.11 28.35 29.92 30.45 32.45 33.14 PCS Method speciated 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Speciated Results ED 001523 00007569-00055 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type Run Number/Side (A/B) Operator Location Height Initial Leak Check (L/min @ "Hg) Speiciated J___ : WL 100 0.000 20 Final Leak Check (L/min (5) "Hg) 0.000 22 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL213525 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002547 0.9996 0.9996 15.7 5.0 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading <L) Mechanical Gas Meter Reading (m3) 0 15:20:00 0.000 5 15:25 5.290 10 15:30 9.950 15 15:35 14.660 20 15:40 19.430 25 15:45 24.120 30 15:50 28.810 35 15:55 33.660 40 16:00 38.220 45 16:05 42.650 50 16:10 47.040 55 16:15 51.650 60 16:20 56.6360 56.6360 56.6360 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 146 256 67 34 262 146 255 67 34 263 146 250 67 34 264 146 255 67 34 278 146 257 67 34 283 146 252 67 34 284 146 249 67 34 284 146 253 67 34 283 146 256 67 34 283 146 254 67 34 282 146 255 67 34 283 146 253 67 34 283 146 251 67 34 284 146 253.54 67.00 34.00 278.15 Pump Vacuum C Hg) 18 18 18 18 18 18 18 18 18 18 18 18 18 18.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 56946.42532 56.9464253 PCS Method speciated 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 4A ED 001523 00007569-00056 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type Speiciated Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 23 Final Leak Check (L/min @ "Hg) 0.000 24 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL213590 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002511 0.9884 0.9884 15.7 5.0 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 15:20:00 0.000 5 15:25 5.170 10 15:30 9.890 15 15:35 14.610 20 15:40 19.390 25 15:45 24.080 30 15:50 28.750 35 15:55 33.600 40 16:00 38.220 45 16:05 42.610 50 16:10 47.000 55 16:15 51.600 60 16:20 56.5710 56.5710 56.5710 Meter Flow Rate (Lpm) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 146 256 68 34 262 146 255 68 34 263 146 250 68 34 264 146 255 68 34 278 146 257 68 34 283 146 252 68 34 284 146 249 68 34 284 146 253 68 34 283 146 256 68 34 283 146 254 68 34 282 146 255 68 34 283 146 253 68 34 283 146 251 68 34 284 146 253.54 68.00 34.00 278.15 Pump Vacuum <" Hg) 20 20 20 20 20 20 20 20 20 20 20 20 20 20.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 56137.15728 56.1371573 PCS Method speciated 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 4B ED 001523 00007569-00057 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type Speiciated Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 20 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL213509 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002547 0.9996 0.9996 13.7 6.9 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 18:06:00 0.000 5 18:11 3.270 10 18:16 6.250 15 18:21 9.340 20 18:26 12.610 25 18:31 15.910 30 18:36 19.270 35 18:41 22.480 40 18:46 25.826 25.8260 25.8260 Meter Flow Rate (Lpm) 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 143 188 65 34 262 143 182 65 34 262 143 179 65 34 262 143 174 65 34 263 143 168 65 34 263 143 164 65 34 262 143 167 65 34 263 143 172 66 34 264 143 178 67 34 265 143 174.67 65.33 34.00 262.89 Pump Vacuum <" Hg) 5 5 5 5 6 6 6 6 6 5.56 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 26049.99001 26.04999 PCS Method speciated 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 6A ED 001523 00007569-00058 URS Date 4/1/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type Speiciated Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 23 Final Leak Check (L/min @ "Hg) 0.000 23 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" KfeO) Barometric Pres. (" Hg) OL213517 30.04 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002511 0.9884 0.9884 13.7 6.9 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading <L) Mechanical Gas Meter Reading (m3) 0 18:06:00 0.000 5 18:11 3.240 10 18:16 6.390 15 18:21 9.620 20 18:26 12.930 25 18:31 16.190 30 18:36 19.450 35 18:41 22.580 40 18:46 25.799 25.7990 25.7990 Meter Flow Rate (Lpm) 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 143 188 66 34 262 143 182 66 34 262 143 179 66 34 262 143 174 66 34 263 143 168 66 34 263 143 164 66 34 262 143 167 66 34 263 143 172 68 34 264 143 178 70 34 265 143 174.67 66.67 34.00 262.89 Pump Vacuum <" Hg) 8 8 8 8 8 8 8 8 8 8.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 25666.00127 25.6660013 PCS Method speciated 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 6B ED 001523 00007569-00059 URS Date 4/2/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type Speiciated Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 15 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL213506 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002547 0.9996 0.9996 13.5 7.1 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading <L) Mechanical Gas Meter Reading (m3) 0 8:25:00 0.000 5 8:30 4.460 10 8:35 7.820 15 8:40 11.280 20 8:45 14.450 25 8:50 17.490 30 8:55 20.259 20.2590 20.2590 Meter Flow Rate (Lpm) 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 154 152 69 35 269 154 156 69 35 269 154 157 70 35 270 154 147 71 35 273 154 148 72 35 273 154 152 72 35 273 154 152 72 35 272 154 152.00 70.71 35.00 271.29 Pump Vacuum (" Hg) 7 7 7 8 8 8 8 7.57 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 20281.25711 20.2812571 PCS Method speciated 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 7A ED 001523 00007569-00060 URS Date 4/2/2014 Plant PCS Phosphate Location Cal #2 Stack Sample Type Speiciated Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 23 Final Leak Check (L/min @ "Hg) 0.000 17 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL213606 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002511 0.9884 0.9884 13.5 7.1 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading <L> Mechanical Gas Meter Reading (m3) 0 8:25:00 0.000 5 8:30 4.590 10 8:35 7.960 15 8:40 11.280 20 8:45 14.420 25 8:50 17.590 30 8:55 20.543 20.5430 20.5430 Meter Flow Rate (Lpm) 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 154 152 68 35 269 154 156 68 35 269 154 157 68 35 270 154 147 69 35 273 154 148 70 35 273 154 152 70 35 273 154 152 70 35 272 154 152.00 69.00 35.00 271.29 Pump Vacuum <" Hg) 9 9 9 9 9 9 9 9.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 20401.08209 20.4010821 PCS Method speciated 2014.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 7B ED 001523 00007569-00061 Run averages corrected for bias Operator: PAT Plant Name: PCSAurora Location: Calciner#3 02 002 Run % % 1 14.7 6.1 2 15.1 5.7 3 14.2 6.5 4 15.3 5.6 RESULIS.xIsm 17cv1906 Sierra Club v. EPA 6/22 Production RESULTS ED 001523 00007569-00062 Test Run 1 Begin. STRATA Version 3.2 Operator: PAT Plant Name PCS Aurora Location: #3Calciner 02 002 % % 4/4/2014 10:30:55 14.647 6.007 4/4/2014 10:31:55 14.621 6.006 4/4/2014 10:32:55 14.601 6.006 4/4/2014 10:33:55 14.588 6.009 Average of Test Run 14.613 6.007 RE5UL.TS.xlsm 17cv1906 Sierra Club v. EPA 6/22 Production 1 ED 001523 00007569-00063 Test Run 2 Begin. STRATA Version 3.2 Operator: PAT Plant Name PCS Aurora Location: #3Calciner 02 002 % % 4/4/2014 10:49:52 15.01 5.637 4/4/2014 10:50:52 14.978 5.635 4/4/2014 10:51:52 14.954 5.637 4/4/2014 10:52:52 14.948 5.636 Average of Test Run 14.968 5.636 RE5UL.TS.xlsm 17cv1906 Sierra Club v. EPA 6/22 Production 2 ED 001523 00007569-00064 Test Run 3 Begin. STRATA Version 3.2 Operator: PAT Plant Name PCS Aurora Location: #3Calciner 02 002 % % 4/4/2014 13:45:53 13.955 6.482 4/4/2014 13:46:53 13.962 6.481 4/4/2014 13:47:53 13.967 6.478 4/4/2014 13:48:53 13.97 6.482 4/4/2014 13:49:53 13.973 6.478 4/4/2014 13:50:53 13.977 6.473 4/4/2014 13:51:53 13.974 6.48 4/4/2014 13:52:53 13.979 6.467 4/4/2014 13:53:53 13.988 6.468 4/4/2014 13:54:53 13.988 6.467 Average of Test Run 13.974 6.475 RESULTS.xIsm 17cv1906 Sierra Club v. EPA - 6/22 Production 3 ED 001523 00007569-00065 Test Run 4 Begin. STRATA Version 3.2 Operator: PAT Plant Name PCS Aurora Location: #3Calciner 02 002 % % 4/4/2014 15:39:26 15.123 5.558 4/4/2014 15:40:26 15.115 5.566 4/4/2014 15:41:26 15.115 5.564 4/4/2014 15:42:26 15.118 5.557 4/4/2014 15:43:26 15.122 5.558 4/4/2014 15:44:26 15.117 5.561 Average of Test Run 15.118 5.561 RESULTS.xIsm 17cv1906 Sierra Club v. EPA - 6/22 Production 4 ED 001523 00007569-00066 Test Run 1 STRATA version 3.2 02 % Begin calculating run averages 04-01-2014 15:04:33 04-01-2014 15:05:33 04-01-2014 15:06:33 04-01-2014 15:07:33 Run Averages 15.750 15.756 15.756 15.760 02 % 04-01-2014 15:07:34 Operator: Plant Name: Location: Test Run 1 End 15.755 PAT PCS Aurora #2 Calciner C02 % 5.101 5.110 5.112 5.102 C02 % 5.106 /?U/Ul 3& Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00067 Final System Bias Check, Run 1 STRATA Version 3.2 Operator: PAT Plant Name: PCS Aurora location: #2 Calciner Reference Cylinder Numbers Zero Span 02 CC44752 SA18330 C02 CC44752 SA18330 Date/Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg Zero Bias% Zero Drift% Span Ref Cyl Span Cal Span Avg Span Bias% Span Drift% 04-01-2014 02 C02 % % 0.000 0.000 0.095 -0,037 0.078 0.034 0.1% 0.4% 0.1% 0.0% 10.470 9.760 10.440 9.646 10.456 9.688 0.1% 0.2% 0.0% 0.0% 15:12:34 Ini Zero Avg 0.058 Ini Span Avg 10.457 Run Avg 15.755 Co 0.068 Cm 10.457 Correct Avg 15.810 System Bias Check End 0.031 9.687 5.106 0.033 9.688 5.128 PASSED ^WfUl Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00068 Test Run 2 STRATA Version 3.2 02 % Begin calculating run averages 04-01-2014 15:15:00 15.701 04-01-2014 15:16:00 04-01-2014 15:17:00 15.699 15.706 04-01-2014 15:18:00 15.702 Run Averages 02 % 04-01-2014 15:18:25 15.702 Operator: PAT Plant Marne: Location: PCS Aurora #2 Calciner Test Run 2 End 02 % 5.223 5,235 5.227 5.228 C02 % 5.229 Hum t 3o8 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00069 Final System Bias Check, Run 2 STRATA Version 3.2 Operator: PAT Plant Name: PCS Aurora Location: #2 Calciner Reference Cylinder Numbers zero Span 02 CC44752 SA18330 C02 CC44752 SA18330 Date/Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg Zero 3ias% Zero Drift% Span Ref Cyl Span Qal Span Avg Span Bias% Span Drift% 04-01-2014 02 C02 % % 0.000 0,000 0.095 -0.037 0.061 0.042 0.2% 0.4% -0.1% 0.0% 10.470 9.760 10.440 9.646 10.449 9.683 0.0% 0.2% 0.0% 0.0% 15:22:34 Ini Zero Avg 0.078 Ini Span Avg 10.456 Run Avg 15.702 Co 0.069 Cm 10.452 Correct Avg 15.763 System Bias Check End 0.034 9.688 5.229 0.038 9.686 5.251 PASSED 2b lh6) Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00070 Test Run 3 STRATA Version 3.2 02 % Begin calculating run averages 04-01-2014 15:26:04 15.760 04-01-2014 15:27:04 15.759 04-01-2014 15:28:04 15.758 04-01-2014 15:29:04 15.758 Run Averages 02 % 04-01-2014 15:29:12 15.758 Operator: PAT Plant Name: PCS Aurora Location: #2 Calciner Test Run 3 End C02 % 5.106 5.124 5.117 5.110 C02 % 5.116 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00071 Final System Bias Check, Run 3 STRATA Version 3.2 Operator: PAT Plant Name: PCS Aurora Location #2 Calciner Reference Cylinder Numbers Zero Span 02 CC44752 SA18330 C02 CC44752 SA18330 Date/Time Analyte Onits Zero Ref Cyl zero Cal zero Avg Zero Bias% Zero Drift! Span Ref Cyl Span Cal Span Avg Span Bias! Span Drift! 04-01-2014 02 C02 % % 0.000 0.000 0-095 -0.037 0.053 0.041 0.2% 0.4% 0.0% 0.0% 10.470 9.760 10.440 9.646 10.451 9.689 0.1% 0.2% 0.0% 0.0% 15:34:06 Ini Zero Avg 0.061 Ini Span Avg 10.449 Run Avg 15.758 Co 0.057 Cm 10.450 Correct Avg 15.817 System Bias Check End 0.042 9.683 5.116 0.041 9.686 5.135 PASSED Hum ? i? Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00072 Test Run 4 STRATA Version 3.2 02 % Begin calculating runi averages 04-01-2014 16:41:08 15.696 04-01-2014 16:42:08 15.700 04-01-2014 16:43:08 15.698 04-01-2014 16:44:08 15.697 Run Averages 02 % 04-01-2014 16:44:12 15.698 Operator: PAT Plant Name: PCS Aurora Location: #2 Calciner Test Run 4 End C02 % 4.960 4.966 4.965 4.970 C02 % 4.965 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00073 Final System Bias Check, Run 4 STRATA Version 3.2 Operator: PAT Plant Name: PCS Aurora Location: #2 Calciner Reference Cylinder Numbers 2ero Span 02 CC44752 SA18330 C02 CC44752 SA18330 Date/Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg Zero Bias% Zero Drift* Span Ref Cyl Span Cal Span Avg Span Bias% Span Drift* 04-01-2014 02 C02 % % 0.000 0.000 0.095 -0.037 0.015 0.028 0.4% 0.3% -0.2% -0.1% 10.470 9.760 10.440 9.646 10.397 9.648 0.2% 0.0% -0.3% -0.2% 16:48:48 PASSED Ini zero Avg 0.053 Ini Span Avg 10.451 Run Avg 15.698 Co 0.034 Cm 10.424 Correct Avg 15.784 System Bias Check End 0.041 9.689 4.965 0.035 9.668 4.995 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00074 Test Run 5 STRATA version 3.2 02 % Begin calculating run averages 04-02-2014 09:04:03 13.713 04-02-2014 09:05:03 13.701 04-02-2014 09:06:04 13.702 04-02-2014 09:07:04 13.695 Run Averages 02 % 04-02-2014 09:07:54 13.702 Operator: PAT Plant Name: PCS Aurora Location: #2 Calciner Test Run 5 End C02 % 6.862 6.867 6.866 6.869 C02 % 6.867 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00075 Test Run 6 STRATA Version 3.2 02 % Begin calculating run averages 04-02-2014 15:50:16 13.496 04-02-2014 15:51:16 13.489 04-02-2014 15:52:16 13.487 04-02-2014 15:53:16 13.485 Run Averages 02 % 04-02-2014 15:54:01 13.489 Operator: PAT Plant Name: PCS Aurora Location: #2 Calciner Test Run 6 End CG2 % 7.095 7.105 7.102 7.106 C02 % 7.103 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00076 Final System Bias Cheek, Run 5 STRATA Version 3.2 Operator: PAT Plant Name: PCS Aurora Location: #2 Calciner Reference Cylinder Numbers Zero Span 02 CC44752 SA18330 C02 CC44752 SA18330 Date /Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg Zero Bias% zero Drift% Span Ref Cyl Span Cal Span Avg Span Bias% Span Drit% 04-02-2014 02 C02 % % 0.000 0.000 0.095 -0.037 0.028 0.024 0.3% 0.3% 0.1% 0.0% 10.470 9.760 10.440 9.646 10.425 9.653 0.1% 0.0% 0.1% 0.0% 09:12:05 Ini zero Avg 0.015 Ini Span Avg 10.397 Run Avg 13.702 Co 0.022 Cm 10.411 Correct Avg 13.787 System Bias Check End 0.028 9.648 6.867 0.026 9.651 6.937 PASSED jlllti S' 30& Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00077 Final System Bias Check, Run 6 STRATA Version 3.2 Operator: PAT Plant Name: PCS Aurora Location: #2 Caleiner Reference Cylinder Numbers Zero Span 02 CC44752 SA18330 C02 CC44752 SA18330 Date/Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg Zero Bias% Zero Drift% Span Ref Cyl Span Cal Span Avg Span Bias% Span Drit% 04-02-2014 02 % 0.000 0.095 0.049 0.2% 0.1% 10.470 10.440 10.409 0.2% -0.1% C02 % 0.000 -0.037 0.007 0.2% -0.1% 9.760 9.646 9.615 0.2% -0.2% 15:59:23 Ini Zero Avg 0.028 Ini Span Avg 10.425 Run Avg 13.489 Co 0.039 Cm 10.417 Correct Avg 13.569 System Bias Check End 0.024 9.653 7.103 0.016 9.634 7.192 PASSED fa A) ^ Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00078 URS SfexMuj 7UAS Plant Name p-S Date V// Z/4^ Page / of / Project Number Location (Source) f^ i Meter ID JrW 4 1) e>7L3/3SJl<r Sorbent Trap IDs 2) c>lj/3^?o Condition Run *Z Operator /JO Bar. Press. (In. H20) Elevation (relative to Barometer) (ft) Trap Clock Time flj E=55:5T`" ... Volume (L, dry) Flow Rate (Lpm) H? (in. H20) Sorbent Initial Leak |i) Rate 2) Final Leak ID Rate |2) Third Bed d Spike Level |2) Temperature (F) Probe Heat-Traced Line & @ J)G "Hg 3 @ A?.*? "Hg _0 @4it. "Hg O @ "Hg zzz// Z7///9 Meter Vacuum (in. Hg) 1) O / 2) O / / 1) f*2 9 / 2) /$H.. 5, / 7 / / 1) .96 / 2) l$3o / / 1) /. / / 2) /az /*/r// 1 1 1) /9.V3 1 2) PS70 79. 3? 1 1 1) &. /a. / 2) /f9s A.0% / 1 1) 38.8' / 2) /Ho 3$, 7S' 1 / 1) 66 1 2) 33 .0 I / 1) 2) 7,8.2 a 3 0.3 2 .1..... ) 1 1) 2) /6of ......... |. _____ J_J ( D 7o 2) Ji/o 7,00 ..t ( 1 1) .57- 6 .. l 2) /(,'f 61,60 .... f . 1 1) SL. 35 J 2) /S </z> 6.57A I / 1) 356 JSS a so $85 $57 J- 5A ot 0/ JS3 "3 a,*) <6 s A60 $8$ $.83 ZZ3 5 9 $7% 8U3 P/> i AS 3 olg/ 3S.9 $ 59 $83 3$ Hi 67 AZ / $93 60 383 557 6 7 6 0> 67 6> ..... 17 6% 6? .<?> 67 6>A 6 7. 6)7 6 % 6? &7 /f 67 69, 6 7 6 %...... 6 /8 cSO /B <30 /$ It > /<3 610 /& ao /8 /f<Qs> 0 78 $o r3 /a / 2) 1) 2) L.j55v:?"':.. .::a Comments: ______________ J6c/<6 77, mf ^/- /%9 ~ /V6 SAMt*^ ...................................................................... T>.i """"<*> ,?y ~ 17cv1906 Sierra Club v. EPA - 6/22 Production l\C-^R> W----t.---* " * t *%,+* ED 001523 00007569-00079 URS 7k $fi-S Plant Name /? (2J> Project Number Location (Source) /"*At $7ae/t. Meter ID $Ot> 4 ......... ....."TliSW i) 010/3597 Sorbent Trap IDs d<dLD\?5/7 Date Y/ / /76 Condition Run Operator 6> /jJ 7 Bar. Press, (in. H20) Elevation (relative to Barometer) (ft) Page / of / Initial Leak 1) Rate 2) Final Leak l) Rate 2) 3 @ "Hg > @ 5)3 "Hg O @ "Hg 53 "Hg Third Bed n____/AM... Spike Level 2) ft///? Trap Clock Time Volume (L, dry) Flow Rate (Lpm) AP (in. HjO) Sorbent Temperature (F) Probe Heat-Traced Line 1) n 2) /$0S 6 * 35 ,5 A /m /&7 1) 2) 78/7 1) 1.3 7 3.0 9 6.3 S A <X 3 .25...... . SIS' / 83 *A5 787 2) 78/&..... 6.39 1) 9.3Y 2) /&?/ 9,60 .2 5 .05 .OS -H ..... .. ls 779 78 / /'/Y .. ... 176 1) siO 3 2) tScL 5> 75.93 .as..... .sis /6% 770 1) /5.9/ 2) 76,/? /6Y 756 1) J977 . <95 2) 1931, ./93/r.... , <95 '35 76 7 779 <3 63 363 02 6a SS3 Si i3 363 1) 2) (gt! 36.88 .... .35 ,35 773 / 75 367 1) 35* $3-6 * aUS 2) ^S76 c *0$ /7B /&o A~75 1) 2) 1881 . OS .3,5 *515 ol 6y 1) 2) /8S1 .3,5 *3S 863 1) 2) ft Of ,35 ,35.. ,35 5163 1) 2) 78o/ ,QS , 3S ck6Y 1) Meter 65.... 6 6 6SL.... 6 6 6-f 6 6 65 66 65 6 6 6S 6 6 69 66 6 6 6ft 6 7 70 7s 9), 70 67 70 69 7S 66 ?A Vacuum (in. Hg) r $a> < 0 CD . <> s 8 O& 6<> O<> A $ 7 8 6.. 6 9 6 % 4 g5 2) 1) 2) Comments: ..... (.&*, y m /u^in&r Ta37 17cv1906 Sierra Club v. EPA - 6/22 Production SDS-35: Mereurv hv Sorbent Trm - MethnH 30R ED 001523 00007569-00080 HRS Plant Name ft (L S 1 Project Number Location (Source) // j si'acft Meter ID i) OL^i 2S*4 Sorbent Trap IDs 2)ol:XlU/>4 Date 'ft /<3. ft /ft Condition Run 7 Operator /J ft Bar. Press. (In. H20) Elevation (relative to Barometer) (ft) Page / of / Initial Leak 1) ft? Rate 2) -o @ JO "Hg @ftl 1 "Hg Final Leak Rate 1) 2) ft/ @ /S' "Hg @ /7 "Hg Third Bed 1) Spike Level 2) Zlft/ft /ft//'? Trap Clock Time Volume (L, dry) Row Rate (Lpm) AP (in. H20) Sorbent 1) 2) 9as 1) 2) ft) e> ft, ft 6 ftftft a <3,9 *39 .39 /fa y's/, 1) 2) Bjft 7, 33 ft, 9/, eft 9 *AS * Aft..... ?S7 1) 2) 8 ft o 1) 2) //,/>.& J/.3S /V.ftS Jft,ftk rM * 9l,S *.SS . ,3 ft / ft? //$ 1) 2) 8So /7.ft9 /7,Sft fils ^ ,39 as /SJ 1) e Aft fts 2) 0.9 ft3 sftS *Sft /SA 1) Temperature (F) Probe Heat-Traced Une Meter /ft6 /ft3 a a? a 9 //V 37 & //A 373 /Si 373 4..7 6%. 99 4 7o ftft> 7/ ftft 7a /ft ft J-73 73 7o /a/ .......... 3/9 70 Vacuum (in. Hg) 9 7 n 7 ft /*? ft g ft 3 ft & ft 2) 1) 2) 1) 2) 1) 2) 1) 2) 1) 2) 1) 2) i) 2) Comments: A/ 7= /sa J*!V y rh'tu^ /eft'if rr 17cv1906 Sierra Club v. EPA - 6/22 Production b-35: Mapf-urv hv Xnrhp.nt Trnn - AA&iknri 3fik ED 001523 00007569-00081 URS Plant Name /? Date 7 // // Project Number Location (Source) dal 5 l^cl Condition Run / Meter ID SOC/ 4 ........ . u/ Sorbent Trap IDs ._______________ 2) 0 6.20 76*3 'Operator , Bar. Press, (in. H20) Elevation (relative to Barometer) (ft) Page / of / Initial Leak Rate Final Leak Rate DO "Hg 2) > @ J?J "Hg 1) > /S "Hg 2) O @ /<? "Hg Third Bed 1) Trap Clock Time Volume (4 dry) 1) o 2) // o 1) 6, 9% 2) /)vs Sfi. 1) 3 / 2) 2 *3 n,// 1) /8'9o 2) no /9< / 1) Mo* 2) t/S s>. 1) 3# ,39 2) /5)6 o 1) </.'// 2) /?6< 3.B,J8 1) 72,39 2) VV.Vf 1) 9.97 2) D/S .<* 62 1) .2$. *9/ 2) 1) 1.97 2) /3,33 1) 39,35' 2) 12 3o % 97 1) 77,795) 2) / 3^ 2$>33$ 1) 2) 1) 2) Comments: Flow Rate (Lpm) HP (in. H20) ..../ / . / ..... / . I / / . 7 ! / / ) f }... 1 / / / 1........ / / / / / / /........... ./ / ...../ ./ } / / } } / / f / 5W 63/t Sorbent AJ3..... ??// 26f 6>S! 7S3 428 272 22/ 272 428 27V -/-~-Lsy$ Temperature (F) Probe Heat-Traced Line 273 J7 2 87 ^ f 56/ 263 JS7 267 jgv 267 382 767 2gS 263 2 $7 6^ 66 2 S3 Jf7 26S 652 <397 293 C$d<6 JY6 Meter Vacuum (in. Hg) 7 7 66 S 67 7 66 62? 3 67 S . 67......... 6 3 6) 6 S <65 3 S 6d J . 6 J 6(5 6S 3 6S..... s ..... S_ 3 26 7 S A.5. 3 5 . 6LZ 1 jf 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00082 URS Plant Name S>SS~ Date >7/7 //7 Project Number Condition Location (Source) Y'sf ^<3 5pc/c. Run P Meter ID----7^5~~~ 'Operator C/76 i) Bar. Press, (in. H20) Sorbent Trap IDs 2)/9^3 0 76 $ & Elevation (relative to Barometer) (ft) Page Initial Leak Rate Final Leak Rate Third Bed Spike Level / of / 1) 60 "Hg 2) :> @72 7 "Hg 1) 7> @ /s "Hg 2) O @ /ft "Hg i) SS oO /Of 2>. ?i7/>f ` Trap ^ Clock Time Volume (L, dry) Flow Rate (Lpm) 1) o / 2) /.> o / 1) P.73 / 2) /H5 p. 93 / 1) J3./6 / 2) /3&<? / 1) /3 7 '/ } 2) Pop /9.S3 / ... i) 36.97 / 2) /j/6) 46. 98 ;..... 1) :?a.87 7 2) /7/x 32,43 / 1) )i a : .....i 2) /&o 3 9.39! f 1) 95. 6 7 ! 2) /]/r 95JP / 1) &.3i ! 2) 6l3o St. i s*o 1 1) S3Sf / 2) S8.B7 / 1) 5. 09 1 2) /j/dj H./3 l 1) m> 3 / 2) nvc 7/, 44 /..... 1) 7ff. oo o i 2) / 3So 77. 9^2 i 1) bS> (in. H20) / ( i 1 / / / / / / 1 1 ) Sorbent 284 704 2 4! (ddf 7.7/ 286 244 A 88 27/ v A 77 AH A 90 ?6! Temperature (F) Probe Heat-Traced Line Heter Vacuum (in. Hg) 7 3 $S7 SlS9 7 7 P 6 6 *5 A 7 S 66 3 2 86 old3 6 (7 P A#*/ 6 P 2 66 S 293 65 AH ...../7 3 jr 4P- 3 a 8-7 d 6 & 6 A <5 AS PBP AH 66 v5 PS *0 JH 6A s ^rns 66 PS 6 A 3 s AS r? 28/ c5? 63 6A 3 65 ? a 85 A64 66 5* 87 a/4 6S.......... 3 66 .5 66 3 29/ 81/ 6 6 s 2) 1) 2) Comments: jT/w r_ 727 /> ^P 694 ChUter Tsj* 2*7 / 17cv1906 Sierra Club v. EPA - 6/22 Production ft~35; Mftmtrv hv Snrh&nf Tr/m - Mt>*hnri 3HQ ED 001523 00007569-00083 URS Plant Name Date ft // ft/d/ Project Number Location (Source) / a/ Meter IDo^c? Condition p. d/ncft/ Run ft " 'Operator fWO V&L/73 033 Sorbent Trap IDs 2) OLHOftSSS Bar. Press, (in. H20) Elevation (relative to Barometer) (ft) Page I Initial Leak 1) Rate 2) Final Leak 1) Rate 2) Third Bed i) Spike Level 2) of / o .................... 'Hg o @ft3 'Hg > @ /S 'Hg & @ //> 'Hg Z2//<4 Trap Clock Time Volume (L, dry) 1) 2) /ft Oft > 1) ft. So 2) /9/d ft tftft Flow Rate (Lpm) / / ... / / tP (in. H20) / / Sorbent 8g Temperature (F) Probe Heat-Traced Line 09 J6S </" ft Meter ^ y 6/ d. 69 Vacuum (in. Hg) 3 S 3 5 1) /3,30> / 2) /9/f ,3.do / / gg /ft 7 fto 5 1) 2) ' /ftdd 79-ft/ 1 8>S ? / / 76? 93 ft 63 SO 5* 1) oft ft ft / 2) /93S' 39o S / / 0 73 ftlfts SS 3 ss S 33?. W / 2) /ftId 33,gft f / a/d 2 ... SS 83 ss 3 X 1) 39,3 7 / 2) /ft/j 3ftJft / / ss 3 S9 J9 6>S s 1) ft5,9/ l 2) /ft ft ft/,/6 l / 3-S? Id 1 <(,3 /ft s 1) 2) 50,67 ... 1... <0,86 / / #9 83 63 Sft Sd 3 S 1) <9,70 / 2) /ftSo 5 7. V/ / / Pi dft 3 69 ss S 1) 6S, P>S / 69 3 2) /YjOf 6 5/ 6 o / / $83 ft8s 63 77 5 1) 2) /ftdo 7$. Id ftl/7 ft / / / 9! 6ft 3 63 6S 5 1) 78, S3 ft / 2) 7$. /?3 / / 289 69 3 d$ sr 1) 2) 1) 2) Comments: /Sft'ac/d T? Mf) & F /ft/ C/-> hf .*'/D*' fr TT*sAo 5JF7- 3nU ft 17cv1906 Sierra Club v. EPA - 6/22 Production SOS-35: Mercurv bv Sorbent Tran - Method 308 ED 001523 00007569-00084 URS Plant Name P C- Project Number Location (Source) Cg / ^D ^/gC/P Meter ID'f1 ..!"=""... srm 1) Sorbent Trap IDs 2) oi 1076V3 Date .V Z///P Condition Run /JP Operator i/U S Bar. Press, (in. H2O) Elevation (relative to Barometer) (ft) Page / Initial Leak 1) Rate 2) Final Leak i) Rate 2) Third Bed i) Spike Level 1 2) of / O @ O "Hg c> @ #3 "Hg 0 @ 3Z> "Hg > @A? "Hg AiSlod 4/9 /&//? ' Trap Clock Time Volume (4 dry) 1) 2} 767/ 1) 2) 4/ Sp O O 00 Vii 1) 7,95 2) //// 8. 3 1) /O* 6S 2) 7/lfS /3.A4 1) /A, of 2) /70/ /6.3 3 1) GO. iV 2) >7o6 1) 2) //// 747 1) 2) /?// 1) %3j7 2) 470) 1) 2) 36.09 1) pa. 7$ 2) /73f 3.04 1) AS 2) )7U 7 2.. 1) 2) I7/ 1) 2) 1) 2) Comments: Flow Rate (Lpm) A *s &p (in. HiO) ,f Sorbent A77 ...* P . A70 , s > .s <3 A 4 .s S J97 * A .< s 3.6? A A . A ,6 A S ,s A A >s . A * f t 7s .5* A .. >5 07V 7^ 3(/ 078 7 73 078 ss.i , A , ..7SG Tempera ture (F) Probe Heat-Traced Line ASV A Si 781 GS8 78? 78b GSQ / 38V 64 A / 77a dPAL JSV <6)6>S Ofo cP AS 08! .. 063 781 0I6Q Sg0 711 SAac/c ShJlfos ...................... &* IPO Tg/y, *S w Meter Vacuum (in. Hg) P-0 S3 ..... A Ol A3 O O .I.. At 6<sz Pa 03 P/ 03 4/ .. A 9~ / 1......... } 3 t............ 3. / J / 3 / I. 7 3 / 3 0/ AO______ 0/ 03 Pa 63 A3 PS & ? AS / 3 i 3 1........... 3 1 3 f 1 .. 17cv1906 Sierra Club v. EPA - 6/22 Production SOS-35: Mercury by Sorbent Trap - Method 30B ED 001523 00007569-00085 UBS Plant Name P cS Date 9/7 f/Y Page / of / Project Number Location (Source) 7/2. pfyo/i Condition Run $ Initial Leak 1) O @ pi <5 "Hg Rate 2) L> @ 2 "Hg Meter ID 8 --.............lA" Sorbent Trap IDs V OLD 1/ YDA 2) 01207607 Operator CtL L- Bar. Press, (in. HjO) Elevation (relative to Barometer) (ft) Trap Clock Time Volume (L, dry) .m. , Flow Rate AP (Lpm) (in. H20) Sorbent Final Leak 1) Rate 2) Third Bed i) Spike Level 2) Temperature (F) Probe Heat-Traced Line @ "Hg @ "Hg dY /i///9 Vacuum Meter (in. Hg) 1) / 2) o / / 1) 7,7/ / 2) W / 1 1) /,/P / 2) Vfi /<& / / 1) 2) 9Td ja/,77 / / ./ 1) 3%M> / 2) 938 / / 1) 33,/5 . / . 2) 9l IS, ol '/ / 1) 39,9/ / / 2) `Z/,3 8 1) "T4--^c=--,*-/-S'J~'f---- - / 2) VS3 97,S / / 1) 52*90 / 2) 15$ .53. VO f / 1) 5^.67 I 2) /o$ 59.5/ f / i) Yj/>> D 3. ! 2) p)&S AS, B^ / / 1) 77,63 / 2) /C/3 *71,88 {..... f 1) 79,o/S 2) /o/f 7 7. 977 I......... I( 1) 2*' 0IS9 67 t?3 25/ a 5?6z> 6 / 66 </4>3 &/ j (>t olf& 55$ 3-So Jk/s 2/t> A$o JlSo 150 ISO 3 7A 3 93 SI 75 7 79 3.?6 7? 3 70) 379 oL.?<? A 79 74 73 7k 93 o7 73 77 7i 7& 75 . 7% 75 78 75 ....... 79, Z# 79 75 79 7S 75 76 rf, 76 7% 75 3 ~S ..3........ S' .. 3 . S r x.... ? X_____ 3 3 5 3 13 X_____ s ..1 .... s 3 $ 3 5 .? S 2) 1) X, 2) Comments: 5VWX ... ................... 7em f / SO TT.iu- zJp > .................................... %30h \ Ond 6 &?mD(g-<; \kk>re xm\sk . cm\e m 3r ftPniWo <2.1omPV t/f- #>.. C*A*.+ T.TM - iJ~4.L---- * 3/-1/5 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00086 URS Trap Clock Time Volume (L, dry) 1) /70> 2) i) 2} /5>S7 6 (6./S A. 'SpZ 1) 2} /a,y& 1} 2) do? /8i So 1) a> 93 2) ma. a %8t 1) 2) m> /3in ~3<0,94 1) 37,36 2) 7% 69 1) 7753 99,37 2) 1) st,7 a 2) l4~3A ,01 1) l6T} 57*96 2) hfW 5*7,7f 1) / w$ 69,07 2) 67,65 1) 1313 70,73 2) hm 76.90. 1) 1JW~ 76,997 2) ih5$r 76. Sll 1) 2) 1) 2) Flow Rate (Lpm) AP (in. H20) / i / t t / l 1 / ! t / ' J ( / / / / / / / / / / / 1 l / t / i 1 / } / / i 1 / Sorbent o2 & f 0 >3 <067 3.60 <&y <6.66 6 6$ 66 S 037 070 Temperature (F) Probe Heat-Traced Line 00V 77 007 <009 30S 67 60 7 3.77 77 668 07 6% ?/ 73 668 6 J7 3 76 70 7Y 70 67 7^ Meter 7? g?<o> 7 9 Be) ,y <~3 && 79 79 36> Si 83 83 BY 99 83 S5 3> 6 8$ & %s 36 8$ <86 8>S m Vacuum (In. Hg) 3 3 S J______ s 3 6 .? _j_______ 6 6 .... .. 6 s s H 6 9 S H.. S ,6 7~J 6 Comments: //.Vf 7Q~r V /So / d/,,:'/itS. s, n7~1\.e <*?s^=sr & ?V J_______________________ _____ , .. /?/ --ran^e. VI5iH^- vlQ.W dfj*3igfe in-klbg-ft P,A SbS-35: Mercurv bv Sorbent Tran - Method308 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00087 Plant Name Project Number Location (Source) a? ^ wrrsjf?? / Meter ID <$&> 'T&Trfflrv ..... """"" ` >7""... Sorbent Trap IDs i) 2) ?L&-*r<s? **___9 /3 f/V Condition Run / > Operator Bar. Press, (in. H2O) Elevation (relative to Barometer) (ft) Trap Clock Time 1) 2) 1) 2) 1) 2) 1) 2) 1) 2) 1) 2) 1) 2) 1) 2) 1) 2) ' 1) 2) 1) 2) 1) 2) 1) 2) 1) 2) 1) 2) Comments: Volume (4 dry) /O > Flow Rate (Lpm) /.. / AP (in. H20) ..be....... --..... Sorbent / ... Page /of / Initial Leak 1) Rate 2) /0 @ "Hg cD @ ^7 .T "Hg Final Leak 1) Rate 2) @ "Hg @ "Hg Third Bed 1) Q. &0 C? Spike Level 2) /l/Z/9 1 Temperaiture (F) Probe Heat-Traced Line Meter Vacuum (in. Hg) 17cv1906 Sierra Club v. EPA - 6/22 Production SOS-35: Mercury bv Sorbent Trao - Method30B ED 001523 00007569-00088 URS FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE / OF / Client/Plant: fcj (jtf Project#: 3t8imL6X>t Date: -- y Operator(s): OS Location: PGM#: /j/^64 CF(Yd): K-Factor: PbarC'Hg): Initial Leak S (<0.02 ft3/min; >10"Hg) J QAlCsUt Run #: 4 Duration (min): 467 AHs 7,444. Height w.r.t. Barometer (ft): Cp: 0.84 Pstatic ("H2O)*. AiL ft /min: Q^ggVac. ("Hg): Source Height (ft): t ot> Duct Diameter ("): 9Z Final Leak (<0.02 fr/min; >max vacuum) ft3/min: > Vac. ("Hg): Jo Duct Width ("): fi/fy Duct Length ("): Askj Pitot Leak (>3"H20) +P ("H20) P ("H20): Nozzle D1 (") 0: 4 Fyrite/Orsat O2 (%/time) fif."J" % (Ctft$ Fyrite/Orsat C02 (%/time) ^,p^% (Cf#{S) Nozzle D2 (") : ^g? S3 Fyrite/Orsat O2 (%/time) % ( ) Fyrite/Orsat CO2 (%/time) % ( Nozzle D3 (") 0: (S>,^2 76 Sample Point Time Clock Run (min) DGM Volume (ft3) AP Ch2o) AH C"H20) Source Probe 24825 Temperature (*F) Rlter 248+25 Impinger Exit S88 9&4 rO 746. 077 4/ /4i / p7 PJfih L 74 74744 44 A70 /3 3ft 4 S 9/0 7433 r7B /M 967 ir 74 7A/,o3 49 4f? /3 966 l S3 v US /o 743,7! .M / 4>S /3 966 \ (r 747 4/1 AS6 .7$3 1 \% 9JlD 76 744 7? 44 4/6 /74 74743 44 l.y/ / 666 / 4SA? I \ If so *) 9/2< ,06> 7/s.m 47 48 /6 SSA f |c. 77047 ,4 <3 A/d /7Z 34/ If n*> 6)4 77/44 43 76? B ^ 376 77345 ,1 ,41 68 ST Ifesf ?3.< ' 3o wv./n / !pr4 4ft > 5% w.m 4/ A 9 /ST' rlSS &e> t7'?.k>t ,3? /, / J<7 g& J 38 77747 i ns 79t,3S .3^ S 9 7A K> 7B0. gf *r/4 % 734 Igist.W 38 1 />( L/i 78i7S , 41 f) 774 41 io& So 73648 31 4/4 767 762 A 38 1.44 /./? a/a 74 3S0 / #4 /77 /X 49 TS6 /S JSf /2 /)8 S3 s7 67 67 S 66 S7 w &4 9B3,o? , 3> )% /Oil 44 7M343 48 ft /A S74 711.00 tOl6 6O m.m A/ //> US' /$ 49 tM 4Sf> 67 SP> Js -- 1----- DGM Inlet DGM Outlet ' Pump Vac. ("Hg) >7 ^g'T y 7 .7 84 4 SB s 03_ m 9 09 S 89 6 J?9 9/ 8 f3 S3 C 6 <?<Q <c> 94 9o S 9& 76 7 9J 93 93 9a 3 83 3 99 93 3 f 3 1 96 13 3 77 99 3 1$ 79 3 ts 9Y 3 96 7 3 96 99 <3. COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00089 UBS Client/Plant: Vbhck tcny Location Impinger# 1 2 3 4 Impinger Contents DI H20 DI H20 Empty Silica Gel FIELD SAMPLING DATA SHEET ___________ (RECOVERY)___________ Project#: 3\.MdO / Condition: Date: Run #: METHOD 13A/B Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD 100 GS -- MOD - MOD n/. t , 1 yz&'f' Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Di H20 Rinse) COMMENTS: 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00090 URS FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE f OF / Client/Plant: f/ Q Project #: Date; Y- Y~~AY Operators); Uj A Location: Ao/ & 3 DGM#: Condition CF (Yd): 9 S&g Run #: ^=~ AH@: A,97 Duration (min): ASS Cp: 0.84 K-Factor. PbarfHg): &, $j Height w.r.t. Barometer (ft): Initial Leak V (<0.02 ft /min; >10"Hg) ft /min: ? Vac. ("Hg): Source Height (ft): / oo Duct Diameter ("); Final Leak V (<0.02 ft /min; >max vacuum) ft3/min: Vac. (-Hg): 9 Duct Width ("): #14 Duct Length ("): fdtf Pitot Leak V(>3"H20) +P("H20): P ("H20): Nozzle D1 (") 0: &,S7S Fyrite/Orsat 02 (%/time) 15", | % (CtUS ) Fyrite/Orsat C02 (%/time) 5% (CE/WS) Nozzle D2 (") Q: Fyrite/Orsat 02 (%/time) % ( ) Fyrite/Orsat C02 (%/time) % ( ) Nozzle D3 (") 0: ^ ^ !/Q Fyrite/Orsat O2 (%/time) % ( Fyrite/Orsat C02 (%/time) % ( ) Average Nozzle D ("): CD, //{ Sample Point Time Clock Run (min) DGM Volume (ft3) OP C'HjO) AH CH2o) Source Probe 24825 Temperature (F) Filter 24825 Impinger Exit s68 DGM Inlet DGM Outlet Pump Vac. ("Hg) ,4 / J J 9 $ A 7 9 7* // /# // 3 V y s 'fi a /O f/ /fo6 e> ,3 J,r& /St J>S 7/3. RV ,34 43) ASS S? //// S 79S.V3 /,V< /Y8 J&l 7,If m,& 433 /Yfi ASS ///A /// /> ?? /A,Y /< 7>/<79 3S *37 ,3V 3.07 99/ /,$ 3 /SS pAS /s& A)S>c2> /SS SS9 /?.S Aefi /AY /1 ,9A S'/ S&YvA /JR /79 ry/S &>,// *99 70S SSR f)3i os fiaZYS .3a /,/A /AY SSS 7`t< *87 /AD <AS% K3S //95 mo^HS R/YOVS .yy A7Z ` /rfi ' La AS? v? ///S, //VfS 7/<3 9//.U 3 7/C 9/> 8/7.6? n,< WZ. 7% M .93 ^Vi .vs *Z A 77 A7f /SSl 4a? A A/ 777 OSS // %S7) /8V ''ass /SC RY7 73/ //jg 9S fiSt^St YfS 1 /2(8> S<s 803J9 SsS '%}</,& 7/7 /Sol J0S8 /.>t /St AS/ ,fl /AS asst 9 /S3 ssr ss &S,?7 .ay ,7 /SR 3S8 3?A . 3 (7 ,7/ /So 3S7 4?/3 fib SXS.f/6 fi/ 9B ?f 5 ss >& 99 3 Si SR 9 99 3 99 79 A 5A ?f 99. 3 ss />/> 99 3 ss />> ff 3 SA />> 99 3 Sf A&V />& Y TV /// />> Y X$r /&& /& 7 A /&C? A& / Y SS /e>t /* s VS />/ /*>Z s YY /&A /&# 5 YY / /> / A YY S&S 4s?/ A Y3 /os /<?/ A VY /&S /<?/ S YS /OS /Of S 99 fej />t s> 16/ 76 1 A 79 /oO //>/ S /DO. /& J S COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00091 URS Client/Plant: Location: sa&f . a/c Impinger# Impinger Contents FIELD SAMPLING DATA SHEET ____________(RECOVERY)____________ Project#: Condition: 6Moj CMCff^rZ, Date: Run #: METHOD 13A/B Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 1 Dl HzO 100 MOD */ n i.*_ 2 Dl H20 100 GS "WY fro\ 3 Empty -- MOD Uf>\ 4 Silica Gel - MOD 9/9.1 Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (D! H20 Rinse) Qoffl. (J^a - Z 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00092 TIDC wlM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE / OF / Client/Plant; Project#: /jft Date; ft// //<?/ Operators): At//-- Location: ^s/ft/- Condition Run#: 3 Duration (min): ^ <3 PGM#: /)/- CF(Yd): AH8: /. for Cp: 0.84 K-Factor: Pbar("Hg): Height w.r.t. Barometer (ft): Pstatic ("H2O): Initial Leak v' (<0.02 ft /min; >10"Hg) ft3/min: // Vac. ("Hg): /ft Source Height (ft): Duct Diameter ("): Final Leak S (<0.02 ft /min; >max vacuum) ft/min; > Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak (>3"H20) +P ("H20); P C'H20): Nozzle D1 (") 0: y*/ Fyrite/Orsat O2 (%/time) fi)t Fyrite/Orsat CO2 (%/time) Qyf % (tG.jtis ) Nozzle D2 (") 0; yg * Q 7"7 Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat CO2 (%/time) % ( Nozzle P3 () 0: Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat C02 (%/time) % ( Average Nozzle D ("): Sample Point Time Clock Run (min) DGM Vo(lfut3m) e aP ('H2O5 aH ("H2Q Temperature (F) Source Probe 24825 Filter 24825 Impinger Exit S68 DGM inlet DGM Outlet Pump Vac. ("Hg) ,4 f /3oO> ft /.S7 /ftS JQS/. PMo.otf 33 /.* 37 S?S T *3AS S3 l>7 ,yy 7 SO /S3 ftS7 O /* 73 9333/ 3d.... lm 3S ASft y 03 /o S3S0R . 3 /$/ /S3 j$9 // Mft ms,77 ms /7ft /s/ <a$ 9 /3/<r / 39 A*7 /ft7 ft63 $ /F,f AO/ /SC ASS 9 /%#/> ffV/.M t9f /Sf fO/ssrk /# M,sr 3, c Cf7 7/A // /33- OS Mm 03 *<79 mo SfS /? 373 97SMS j.9&. 39 ASS /3?6 3> S63ft? rft, /33S Wsftm /<? s M/SJS 33 /Oo /ftft OSS 3 J3Y0 QWM 30 /& /Ss g)37 Y ffso. <io / /3#s */> $SrO,3& 33/ /Aft /Y9 ftssr A/S) 3/ OS8 a ,S 973.33 ,3& / Sf 7S/> ASA 7 77 9S6,3 ft7,7 sssm ,A9 ft ris5 So $S3,Od /> saS eswe /> $S // ftoo SS' 7$7 /A, msms 3ft /ftos S3 96337/ /// /. oS A/& A &S) 39 37 / 3ft /So ///? w /S3 059 ASS OS'? 44 s ftSB 779 So 9 7 SSL S') Sf S3 rY 3S SS S7 Sg 9 ff 99 /oo /30 /&> /oo /oo /o/ /ef />A /Of /o / />% /of MM />/ /oft /oft /oft /Oft 3 3 3 ft A/ ft ft ft ft f... // S3 ss S3 S3 S3 S3 S3 ss S7 S7 MS /o ft 3 /*>< /Oft s S /oS /oft /OS' /oft r /oS /oft s /oS /O ft 6 /oS /oft S /oS /oft s /<oS /></ s /06 /Oft S /06 /oft S />& /&S 3 COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00093 URS Impinger# 1 2 3 4 Impinger Contents Dl H20 Dl HzO Empty Silica Gel FIELD SAMPLING DATA SHEET ___________ (RECOVERY)___________ Project#: J.ibool Condition; Date: Run#: METHOD 13A/B Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD am 100 GS VfHZc) -- MOD QM -- MOD qrCf Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dl H20 Rinse) C&WT CKL COMMENTS: 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00094 COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00095 HRS FIELD SAMPLING DATA SHEET ___________ (RECOVERY)____________ METHOD 13A/B Impinger# 1 2 3 4 Impinger Contents D! HaO Dl H20 Empty Silica Gel Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 100 MOD 100 GS LH-Z- -- MOD -- MOD 90^ Final (g) 9ii. e. Gain (g) Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dl H20 Rinse) ftfjf. ( COMMENTS: Osfft Z Tare (g) GZJ> Final (g) , 1 -_ Gain (g) 5'3f.o - 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00096 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00097 URS FIELD SAMPLING DATA SHEET Sample and Velocity Traverse for Stationary Sources EPA METHOD 1 Client/Plant: Project #: Number of Traverse Points Chosen: Location: Number of Ports: Duct Diameters From Downstream Flow Disturbance {Distance A) 0. 1.0 1.5 2.0 Date: Number of Points per Port: Duct Diameters From Upstream Flow Disturbance (Distance B) Point on a Diameter Lo cation of Traverse Points in Circular Stacks* Number of Traverse Points on a Diameter 4 6 8 . 10 12 1 6.7 4.4 3.2 2.6 2 25.0 14.6 10.5 8.2 3 75.0 29.6 19.4 14.6 4 93.3 70.4 32.3 22.6 5 85.4 67.7 34.2 6 95.6 80.6 65.8 7 89.5 77.4 8 96.8 85.4 9 91.8 10 97.4 11 12 * Percent of Stack Diameter from Inside Wall to Traverse Point 2.1 6.7 11.8 17.7 25.0 35.6 64.4 75.0 82.3 88.2 93.3 97.9 Cross-Sectional Layout for Rectangular Stacks Traverse Points Matrix 9 3x3 12 4x3 16 4x4 20 5x4 25 5x5 Deq = 2LW / (L+W) Diameters Upstream Diameters Downstream Traverse Point Location Distance From Wall Nipple Length Total Distance 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00098 HRS FIELD SAMPLING DATA SHEET EPA METHOD 2 PAGE OF j? Schematic of Trav srse Points . .0 + : Clockwise Pitot Rotation ^4 HlA - : Counterclockwise Pitot Rotation Client: Piant: ^rarVV,Ale, Static P (Pfl): Source Height (ft): %02: Pitot Leak {>3"H20} Project #: Date: 3/jt/tY Operators): f^L- Location: Condition: 1a)>JV^Y ' i Cp: 0.84 "H20 Barometric P (Pbar): "Hg Height w.r.t. Barometer (ft): Pitot Tube#: Duct Diameter ("): 1 Duct Length (" Duct Width ("}: Area (A): fr % CO2: 02/C02 Method: +P ("H20): 3k P ("HzO); %H2Q: JtfTwtfrtfgD Run: Run; Port Sample Point Time AP ("H20) 6.3S o.% Ts (T) + clockwise - counterclockwise Z3 At Time AP "H20) Ts (F) + clockwise - counterclockwise C- 3? 4 xr MX ML JL Id 1 0.31 XI <M]r ML Id HA (Pli f Is 0.ZI M- AH t 0*3? oM 6Jj K o>%f I A 30 f 0.31- 0, % 10 W.lL JL '0l\ \z Koo lit h% LL Zz, M IA (54 11 X^ i.r AVERAGE if d-&o ML AVERAGE 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00099 T UIID lM C FIELD SAMPLING DATA SHEET EPA METHOD 2 PAGE X OF Schematic of Traverse Points 0 + : Clockwise Pitot Rotation - : Counterclockwise Pitot Rotation Cllent: kkl&y ^_____ Project #: Ptent: f A) C Location: 4 ZCaLIS^A- Date: y/| fjtf Condition: Operators): fATfk)t-- Cp: 0.84 StaticP{Pg); -,, / "H20 Barometric P (Pbar): j?<?. * V "Hg Height w.r.t. Barometer (ft): Pitot Tube#: /ffP~~f -^106'' Source Height (ft): Duct Diameter {"): T 2. Duct Length ("): fify | Duct Width ("); Area (A): ft2 %Oz: %COz: 2A 02/C02 Method: %H20; trtitc/ Pitot Leak (>3"H20) i/ | +P ("H20): U' 4, L - P ("H20): ^ - </, t/ Port k X r l RRUurnr' i4' 5.1 to. Run: X $Xt&x_ Sample Point l _____ ____ L > Y......... \ L f 1 b U IL L Time AP ("H20) Ts <F) + clockwise - counterclockwise //7^> .57 /</*> 8 * Q. -130- r .3.3 *4 /yy 3 ,A3 i7j l j A i /4C 9.7 /39 r .J3 /M 9 9 _ 9 -lA.... /Si *sl6 /XT i> *Al n a <r *31 /yy ............. .30 m _^3............ Time /tt AP Ts ("H20) (F) 29 m . 23 /yy i7// t. <2A iy3 iJ2/ /yy ,2V /W n9 ns -27 /3? A y>__ /U , M tU .AD /37 * A 6 * 3H f?3 + clockwise - counterclockwise ) V Sr _4_____ T g , .. .. . 32. .36 _ ,J 3 _ /4f c /VO H /yo _J_______, /V3w 2 / yo r /?3 .J9 .32 __ .A L/ .A3 .2 /3 3 /33 /25 f33 /3A r /33 ,, . AO /?y f) I| 1? ' ;;ry{ AVERAGE na 8 ,3! /3A t .AD /39 < Qil<C ISIS u ny y- _ * /? * /8 <J{ AVERAGE m m /JC> CJ 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00100 HRS FIELD SAMPLING DATA SHEET EPA METHOD 2 PAGE ^ OF Schematic of Traverse Points + : Clockwise Pitot Rotation - 0: Counterclockwise Pitot Rotation o Client: tobsLCw Plant: hirnrA, A/C Project #: Location: Date: cff/jl if Condition: fOOilM Static P(Pn): -o>| "H20 Barometric P (Pbar): 5t>. W "Hg Height w.r.t. Barometer (ft): 2 ^l0>' Source Height (ft): Duct Diameter ("): tj. 2, Duct Length ("): /v&4- Duct Width ("): Operator(s): j^jL Cp: 0.84 Pitot Tube#: ftTP'f-X A/4 Area (A): ^.Z-T^A ft %02: Pitot Leak (>3"H20) % C02: ^ 02/C02 Method: jJA +P ("H20): f. 6 - P ("H20): %H20: - l/,/ Run- , J Cr*i Run: if Port Sample Point Time AP ("H20) Ts (F) + clockwise - counterclockwise Time AP ("H20) Ts (F) * _J______ 1 2 y < r V a 16 II .3? - *3? t <5? * <Pol *<PS . Pi PS ..73/ /3J /jB /*/ f 93 /tf/f /W !c/3 // //> /3<j 35! a? /Y > ol 3> /? ! (9 3 /9 37 /y/ 'JO / 3% rAA /,7S i '39 ,f /3d ,ji /37 '3? /J? 1*- ,7 / /39 A 2 . 38 /37 * 5a / 3% ,J9 /Yd /?/ WA . /?? .31 /y/> _J_____ , JV- 99/ r f ? r i_____ to ii 2. 30 - 33 . ,3/ 33 5 2. .. ................. * 77 , . 2-0 fU /3i /n /if m /$7 /H /iV //Df * AL& 99$ ,3 1 /yo ,37 /3d ,at /3% /37 *7 ? /3S tr Al *2. /*6 r /? /39 AVERAGE 0JCI ni 4 6*2-W nid AVERAGE + clockwise - counterclockwise ^ * ffsvo > o^L m - ft-1 % 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00101 URS FIELD SAMPLING DATA SHEET EPA METHOD 2 PAGE OF > oSchematic of Traverse Points + : Clockwise Pitot Rotation - : Counterclockwise Pitot Rotation Client: fa{teL/'dtf Plant: fttf /lo jt{^, tJ(- Project #: Location: *f Date: 4fl)}<3 Condition: (Jo .M 4L Operator(s): AfT jv/L Cp: 0,84 Static P (Pg): -a > 1 "HzO Barometric P (Pbar): 30. "Hg Height w.r.t. Barometer (ft): 100 ' Pitot Tube#: (ItP-%'% Source Height (ft):^l0>y Duct Diameter ("): If- "L- Duct Length {"): A/lA- Duct Width ("): /Uf' Area (A): ft2 % Oa: % C02: 02/CQ2 Method: J 4 ' %H20: Pitot Leak (>3"H20) ^ +P ("H20): . - P ("H20): i-"" Port A R Rurr. s -A JT ~c CJ L- Run: C S 9 I2-) lLl 6* Sample Point Time AP {"HaO) Ts (F) 0 + clockwise - counterclockwise Time AP ("H20) Ts (F) + 0 + clockwise - counterclockwise / 3? 3> 73 93 7 . 3 ? /S 2 .94 /J7 - 3^> /S3 3 t At? /39 3p\ /SS 3 ,A3 /SB * 37 f . 711 /3 0 . B7 /S2 6 *313 /J7 , 3Si /JJ 7 /S7 .&<k i 7 2 ,,o?9 J3? -3J- 9 736 , 3^ m /0 /n . /,?/ ft <Sl H7 * JS3 A ,11 !*$ i .3 1 729 /&> /YA <2 >33 13 6 .9/ /77 3 /37 !`/9, 9 139 S .IS /3<j 4 / 6 Xo /7g j/# /97 .9o 796 7 .AS n$ % .A3 137 , 3A / 76 .AY ivs 9 n? to .3 a /3 9 U , 2-5 nt .39 /Y9 79* .* /// 5M D o AVERAGE 2^ / 2 m-\ 995 *71 /SA V ~ a.3t<S M.V jAVERAGE Sub ^231 fT-.O ^ Dus--m il* 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00102 URS FIELD SAMPLING DATA SHEET 1 EPA METHOD 2 [page 3 OF oSchematic of Traverse Points + : Clockwise Pitot Rotation - : Counterclockwise Pitot Rotation Client: P^L^rA Project #: Date: *//<!,//1/ Operators): Pat ) W L PI<3nt. Location: l Condition: Cp: 0.84 Static P(Pg): "h2 Barometric P (Pbar): Height w,r,t. Barometer (ft): )ff0 Pitot Tube#: Source Height (ft): J $) Duct Diameter ("): f % Duct Length'("): tW( Duct Width ("): ^ Area (A): ft2 %02: Pitot Leak (>3"H20) % C02: 02/C02 Method: j +P ("H20): \S - P ("HzO): %h2o: smMrtes L-^ Rurc c7'7 Run: ^ Port A Sample Point / J Time AP C`H20) .,20 .,3 A Ts (T) /Kg /? 0 + dockwise - counterclockwise Time 3_____ .77 /& ______ y . ol> ,a& /f/ /&? , 3^ /JA 7 i /fo , 3/ 9 ,33 /Y7 /> *39 9 /y/ n o / ______ ______ y__ .< _A__ 9 9 to 1/ /a ,1 .ay .?> . 9f * . n >99 ,27 9- / ,2S X-7 .23 ,3. ,23 tS tvs _17_ rV3 //3 /yy /9 /V3 /73 /93 /y? J73 jya l7o2 AP ("H20) Ts (F) i + clockwise - counterclockwise AVERAGE $,<?< /t/fj AVERAGE 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00103 Attach ment B QA/QC Documentation 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00104 Project Title Location Project ID Date Technician PCS NC 31829746 4/8/2014 NNL Low-Level Cal Curve Slope 0.0058 Intercept -4.58 r2 0.9900 Ohio =x Analysis Sample Type Mass (ng) , Calibration 50 100 old! iUdl Us 150 200 CO/Post-Cal 100 ICV Post-Cal 100 NCI CO/Post-Cal 100 DCS1 DCS? 10 DCS3 Average DCS 10 Peak Area 93 f\j 19800 27100 33900 18100 18000 19300 1720 2160 2400 2093 High-Level Cal Curve Slope 0.0053 Intercept 53.39 r2 0.9999 Cal Curve Mass (ng) Recovery(%) 19.53 78 49.85 100 110.44 110 152.84 102 192.34 96 100.56 101 99.98 100 107.53 108 5.41 7.97 9.36 7.58 Sample Type Mass (ng) 200 Calibration 500 1000 1500 5000 CO/Post-Cal 1000 ICV Post-Cal 1000 NCI CO/Post-Cal 1000 Peak Area 28300 90700 174000 273000 940000 173000 166000 188000 Cal Curve Mass (ng) Recovery(%) 202.46 101 531.16 106 969.96 97 1491.45 99 5004.96 100 964.69 96 927.82 93 1043.70 104 Low-Level Calibration Curve High-Level Calibration Curve Peak Area 17cv1906 Sierra Club v. EPA - 6/22 Production K and Spec 20140408_MDD.xisx ED 001523 00007569-00105 Ohio Lumex Analysis MDL Study Method Detection Limit (MIX) Daily DCS Average Daily 10 ngRF 3.46 2093 0.0048 Mass of MDL Standard (ng) 10 Sample Type MDL Standard Replicates Average Standard Deviation (SD) 3.14xSD Peak Area 2170 2160 1720 2020 2400 1810 2110 2056 230.86 724.89 MDL Study Performed by NNL Date 4/8/14 Lumex Spreadsheet - App Kand Spec 20140408_MDD.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00106 Sample Run CAL #2 Stack 1 CAL #2 Stack 2 CAL #2 Stack 3 Description of Conditions Traps extremely moist 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00107 Project Title Location Project ID Date Technician PCS NC 31829746 4/8/2014 NNL Ohio Lumex Analysis Sample Run Log Sample Type Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated XV - Post-Sample XV - Post-Sample Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated XV - Pre-Sample CCV - Post-Sample Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated Speciated CCV - Post-Sample XV - Post-Sample ocv Time 17:36 17:45 17:36 17:45 19:52 19:56 Spike Mass (ng) 100 1000 100 1000 100 1000 Sample Run CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 CAL #2 Stack 1 Trap Side 2 2 2 CAL #2 Stack 2 CAL #2 Stack 2 CAL #2 Stack 2 CAL #2 Stack 2 CAL #2 Stack 2 CAL #2 Stack 2 CAL #2 Stack 2 CAL #2 Stack 2 CAL #2 Stack 2 CAL #2 Stack 2 CAL #2 Stack 2 2 CAL #2 Stack 2 CAL #2 Stack 3 CAL #2 Stack 3 CAL #2 Stack 3 CAL #2 Stack 3 CAL #2 Stack 3 CAL #2 Stack 3 CAL #2 Stack 3 2 CAL #2 Stack 3 CAL #2 Stack 3 CAL #2 Stack 3 CAL #2 Stack 3 CAL #2 Stack 3 Sample Trap ID CL213525 CL213525 CL213525 CL213525 CL213525 OL213525 CL213590 CL213590 CL213590 CL213590 CL213590 CL213590 CL213509 CL213509 CL213509 CL213509 CL213509 CL213509 CL213517 CL213517 CL213517 CL213517 CL213517 CL213517 CL213506 CL213506 CL213506 CL213506 CL213506 CL213506 CL213606 OL213606 CL213606 CL213606 CL213606 CL213606 Sample Fraction Peak Area Plug 1 AGS Plug 2 and Bed A Plug 3 and Bed B Plug 4 and BedC Plugs 5&6 and BedD Plug 1 AGS Plug 2 and Bed A Plug 3 and Bed B Plug 4and BedC Plugs 5&6 and Bed D Plug 1 AGS Plug 2 and Bed A Plug 3 and Bed B Plug 4and BedC Plugs 5&6 and BedD Plug 1 AGS Plug 2 and Bed A Plug 3 and Bed E Plug4and BedC Plugs 5&6 and BedD Plug 1 AGS Plug 2 and Bed A Plug 3 and Bed B Plug4and BedC Plugs 5&6 and Bed D Plug 1 AGS Plug 2 and Bed A Plug 3 and Bed E Plug 4and BedC Plugs 5&6 and Bed C 553 101 709 661 307000 1890 580 230 640 11 274000 528 18500 182000 333 -8 288 73 142000 968 721 198 583 380 130000 410 18200 178000 418 273 136 252 114000 -4 845 141 160 115000 444 19600 197000 Calculated Mass (ng) <3.46 <3.46 <3.46 <3.46 1670.55 9.03 <3.46 <3.46 <3.46 <3.46 1496.72 <3.46 102.89 1012.10 <3.46 <3.46 <3.46 <3.46 801.39 4.62 <3.46 <3.46 <3.46 <3.46 738.18 <3.46 101.14 991.03 <3.46 <3.46 <3.46 <3.46 653.90 <3.46 4.04 <3.46 <3.46 <3.46 659.17 <3.46 109.28 1091.11 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 <3.46 Data Flag u u u u F U U U U U U u u u F U U U U U u u u u u F U U U u u u u u u u u u u u u u u u u u u u u u u u Comments Test Passed, no need to re-calibrate Passed, no need to re-calibrate Passed, no need to re-calibrate Passed, no need to re-calibrate Passed, no need to re-calibrate Passed, no need to re-calibrate Lumex Spreadsheet - App K and Spec 20140408_MDD.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00108 Project Title Location Project ID Date Technician PCS NC 31829746 4/8/2014 NNL Ohio Lumex Analysis OCV and IQ/ Recoveries Sample Type Spike Mass CCV Time Peak Area (ng) Low-Level Calibration GCV Post-Cal 100 18100 ICV Post-Cal 100 18000 KCI OCV Post-Cal 100 19300 High-Level Calibration CCV Post-Cal 1000 173000 ICV Post-Cal 1000 166000 HO CCV Post-Cal 1000 188000 Sample Analysis OCV - Post-Sample 17:36 100 18500 OCV - Post-Sample 17:45 1000 182000 OCV - Pre-Sample 17:36 100 18200 OCV - Post-Sample 17:45 1000 178000 OCV - Post-Sample 19:52 100 19600 OCV - Post-Sample 19:56 1000 197000 Calculated Mass (ng) 100.56 99.98 107.53 964.69 927.82 1043.70 102.89 1012.10 101.14 991.03 109.28 1091.11 Percent Recovery (%) 101 100 108 96 93 104 103 101 101 99 109 109 Comments Passed, no need to re-calibrate Passed, no need to re-calibrate Passed, no need to re-calibrate Passed, no need to re-calibrate Passed, no need to re-calibrate Passed, no need to re-calibrate Lumex Spreadsheet - App K and Spec 20140408_MDD.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00109 Project Title Location Project ID Date Technician PCS NC 31829746 4/8/2014 NNL Ohio Lumex Analysis Speciated Trap Results Trap Sample Sample Run Side Trap ID Sample Fraction Peak Area CAL #2 Stack 1 1 CAL #2 Stack 1 1 CAL #2 Stack 1 1 CAL #2 Stack 1 1 CAL #2 Stack 1 1 CAL #2 Stack 1 1 CAL #2 Stack 1 2 CAL #2 Stack 1 2 CAL #2 Stack 1 2 CAL #2 Stack 1 2 CAL #2 Stack 1 2 CAL #2 Stack 1 2 CAL #2 Stack 2 1 CAL #2 Stack 2 1 CAL #2 Stack 2 1 CAL #2 Stack 2 1 CAL #2 Stack 2 1 CAL #2 Stack 2 1 CAL #2 Stack 2 2 CAL #2 Stack 2 2 CAL #2 Stack 2 2 CAL #2 Stack 2 2 CAL #2 Stack 2 2 CAL #2 Stack 2 2 CAL #2 Stack 3 1 CAL #2 Stack 3 1 CAL #2 Stack 3 1 CAL #2 Stack 3 1 CAL #2 Stack 3 1 CAL #2 Stack 3 1 CAL #2 Stack 3 2 CAL #2 Stack 3 2 CAL #2 Stack 3 2 CAL #2 Stack 3 2 CAL #2 Stack 3 2 CAL #2 Stack 3 2 OL213525 OL213525 OL213525 OL213525 OL213525 OL213525 OL213590 OL213590 OL213590 OL213590 OL213590 OL213590 OL213509 OL213509 OL213509 OL213509 OL213509 OL213509 OL213517 OL213517 OL213517 OL213517 OL213517 OL213517 OL213506 OL213506 OL213506 OL213506 OL213506 OL213506 OL213606 OL213606 OL213606 OL213606 OL213606 OL213606 Rug 1 AGS Rug 2 and Bed A Rug 3 and Bed B Rug 4 and Bed C Rugs 5&6 and Bed D Rug 1 AGS Rug 2 and Bed A Rug 3 and Bed B Rug 4 and Bed C Rugs 5&6 and Bed D Rug 1 AGS Rug 2 and Bed A Rug 3 and Bed B Rug 4 and Bed C Rugs 5&6 and Bed D Rug 1 AGS Rug 2 and Bed A Rug 3 and Bed B Rug 4 and Bed C Rugs 5&6 and Bed D Rug 1 AGS Rug 2 and Bed A Rug 3 and Bed B Rug 4 and Bed C Rugs 5&6 and Bed D Rug 1 AGS Rug 2 and Bed A Rug 3 and Bed B Rug 4 and Bed C Rugs 5&6 and Bed D 553 101 709 661 307000 1890 580 230 640 11 274000 528 333 -8 288 73 142000 968 721 198 583 380 130000 410 418 273 136 252 114000 -4 845 141 -44 160 115000 444 Calculated Mass (ng) <3.46 <3.46 <3.46 <3.46 1670.55 9.03 <3.46 <3.46 <3.46 <3.46 1496.72 <3.46 <3.46 <3.46 <3.46 <3.46 801.39 4.62 <3.46 <3.46 <3.46 <3.46 738.18 <3.46 <3.46 <3.46 <3.46 <3.46 653.90 <3.46 4.04 <3.46 <3.46 <3.46 659.17 <3.46 Data Flag KCI Breakthrough (%) U U U U 100.00 F U U u u 100.00 u u u u u 100.00 F u u u u 100.00 u u u u u 100.00 u F u u u 100.00 u Carbon Breakthrough (%) Particulate Mercury Mass (ng) Oxidized Mercury Mass (ng) Elemental Mercury Total Mercury Mass (ng) Mass (ng) 0.54 3.46 10.39 1679.58 1693.43 0.23 3.46 10.39 1500.18 1514.03 0.58 3.46 10.39 806.02 819.87 0.47 3.46 10.39 741.64 755.50 0.53 3.46 10.39 657.36 671.21 0.53 4.04 10.39 662.63 677.06 17cv1906 Sierra Club v. EPA - 6/22 Production Lumex Spreadsheet - App KandSpec 20140408_MDD.xlsx ED 001523 00007569-00110 Dry Gas Meter 5-Point Calibration Meter Box ID: DGM Number: Calibrated By: N-54 12829626 ETR Barometric: Date: 29.96 9-Oct-13 Orifice ID Orifice Coefficient K' Ambient Temperature Run #1 Run #2 11 0.2817 66 68 Run #1 Run #2 16 0.4234 68 67 Run #1 Run #2 19 0.4923 68 69 Run #1 Run #2 23 0.6124 68 68 Run #1 Run #2 30 0.7904 68 68 Vacuum (>14" Hg) Delta H Initial Volume Ft3 Final Volume Ft3 Total (>5 Ft3) Initial DGM TempF Final DGM TempF Average Temp F Time Minutes Time Seconds Delta H@ Calibration Factor (y) Average y 23 23 0.47 0.47 481.900 551.200 487.900 557.200 6.000 6.000 65 72 66 72 65.5 72.0 15 15 44.72 42.66 1.969 1.952 0.9591 0.9670 0.9631 pass 21 21 1.00 1.00 494.900 501.300 500.900 507.300 6.000 6.000 67 68 68 68 67.5 68.0 10 10 45.82 45.34 1.859 1.854 0.9861 0.9872 0.9866 pass 20 20 1.40 1.40 507.900 514.800 513.900 520.800 6.000 6.000 68 69 69 70 68.5 69.5 9 9 14.59 14.00 1.925 1.925 0.9855 0.9853 0.9854 pass 19 19 2.10 2.10 522.100 528.800 528.100 534.800 6.000 6.000 70 71 71 71 70.5 71.0 7 7 26.53 25.56 1.866 1.864 0.9891 0.9878 0.9884 pass 17 17 3.60 3.60 535.800 543.200 541.800 549.200 6.000 6.000 71 72 72 73 71.5 72.5 5 5 43.59 42.94 1.930 1.927 0.9805 0.9805 0.9805 pass Gamma must not deviate by more than + /- 0.02 from average. Delta H@ must not deviate by more than 0.2 inches of water from average. Calibration Factor (y) Delta H@ 0.9808 1.907 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00111 PCS Phosphate 4/4/2014 Calciner # 3 Post Test Meter Calibration Check Meter No. N-54 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 4 Average Initial Meter y Deviation Post Test Meter QA (yjfa) 1.0253 1.0220 1.0268 1.0355 1.0274 0.9808 4.8% Must be less than 5% Calciner3 M13B 040414.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00112 Dry Gas Meter Console Calibration Full Calibration Date: Box # DGM # 27-Jun-13 2 8002547 Technician: Cai. Meter: Cal. Meter #: etr Wet Test 538788 Ref. Pbar: Meter Pbar: Vacuum 29 58 Hg "Hg 0 "Hg Flow Rate L/min 2.5 1.5 0.5 Pressure Gas Volume "H20 Wet Test Meter Initial 7671.476 Final 7697.400 Total 25.924 Initial 7699.342 Final 7714.544 Total 15.202 Initial 7715.192 Final 7721.424 Total 6.232 Gas Volume Mechanical Meter Initial 46027.50 Initial Final 46053.50 Final Total 26.00 Total Initial 46055.00 Initial Final 46070.50 Final Total 15.50 Total Initial 46071.00 Initial Final 46077.00 Final Total 6.00 Total Gas Volume Digital Meter 0.00 25.79 25.79 0.00 ~.:5 5.'5 0.00 6.2: 6.21 Test Meter Temp. (C) Gas Meter Temp (C) In In 22.00 19.44 22.00 20.56 Average 22 Average 20 22.00 20.56 22.00 21.11 Average 22 Average 21 22.00 21.11 22.00 21.67 Average 22 Average 21 Time 10 10 10 iiiiii Average: Yi % Diff Yi Mechanical Mechanical Digital 0.9903 -1.09 0.9984 0.9769 -2.43 0.9993 1.0365 1.0013 3.52 1.0010 0.9996 % Diff Digital -0.12 -0.02 0.14 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00113 Dry Gas Meter Console Calibration Full Calibration Date: Box # DGM # 27-Jun-13 2 8002511 Technician: Cal. Meter: Cal. Meter #: etr Wet Test 538788 Ref. Pbar: Meter Pbar: Vacuum 29.57 Hg "Hg 0 "Hg Flow Rate L/min Pressure Gas Volume "H20 Wet Test Meter Initial 7741.223 Final 7766.567 Total 25.344 Initial 7767.050 Final 7782.578 Total 15.528 Initial 7782.578 Final 7788.894 Total 6.316 Gas Volume Mechanical Meter Initial 44879.00 Initial Final 44905.00 Final Total 26.00 Total Initial 44905.50 Initial Final 44921.50 Final Total 16.00 Total Initial 44921.50 Initial Final 44927.50 Final Total 6.00 Total Gas Volume Digital Meter 0.00 25.64 25.54 0.00 5.7i 5.7' 0.00 6.44 6.44 Test Meter Temp. (C' In 22.00 23.00 Average 23.00 23.00 Average 23.00 23.00 Average Gas Meter Temp (C) In 0.9766 0.9725 1.0558 Average:1.0016 % Diff ^igita^ 0.18 0.23 0.9843 -0.41 0.9884 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00114 Initial System Bias Check Initial System Bias Check Plant: Location: Date: PCS Aurora #3Calciner 4/4/2014 Reference Gas Cyl i nders Parameter Zero 02 0C44752 002 0C44752 Span SA18330 SA18330 System Check Zero Span Analyte Units Ref Cyl Cone. Cal Average Bias Ref Cyl Cone. Cal Average Bias 02 % 0 0.041 0.009 0.2 10.47 10.431 10.419 0.1 002 % 0 0.002 0.019 0.1 9.76 9.69 9.708 0.1 IBIAS_Summary_Table.xlsm 17cv1906 Sierra Club v. EPA - 6/22 Production IBIASJABLE ED 001523 00007569-00115 Plant: Location: Date: PCS Aurora 4/4/2014 Calibration Error Test Parameter 002 02 Reference Gas Cyl i nders Zero Mid Range High Range 0C44752 SA18330 0C119741 0C44752 SA18330 0C119741 System Check Zero Mid High Analyte Units Ref Cyl Cone. Average Error% Ref Cyl Cone. Average Error% Ref Cyl Cone. Average Error% 002 % 0 0.041 0.2 10.47 10.431 0.2 19.21 19.361 0.8 02 % 0 0.002 0 9.76 9.69 0.3 20.24 20.445 1 Cal_Err_Table.xlsm 17cv1906 Sierra Club v. EPA 6/22 Production Cal_Err_Table ED 001523 00007569-00116 Final System Bias Check for Run 1 . STRATA Version 3.2 02 002 02 002 % % Volts Volts 4/4/2014 10:35:51 14.382 0.436 0.5765 0.0208 4/4/2014 10:36:51 0.059 0.009 0.0024 0.0102 4/4/2014 10:37:51 0.792 0.757 0.0317 0.0287 4/4/2014 10:38:51 10.261 9.588 0.4113 0.2469 4/4/2014 10:39:51 10.388 9.634 0.4164 0.248 4/4/2014 10:40:51 10.393 9.647 0.4166 0.2483 Final System Bias Check for Run 1 Operator: PAT Plant Name: FCSAurora Location: #3Calciner Reference Cylinder Numbers Zero Span 02 0C44752 SA18330 002 0C44752 SA18330 Date/Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg Zero BiasP/o Zero Drift% Span Ref Cyl Span Cal Span Avg Span BiasP/c Span Drift% Ini Zero Avg Ini Span Avg Run Avg Co Cm Correct Avg 4/4/2014 10:41:01 02 002 % % 0 0 0.041 0.002 0.037 0.009 0 0 0.1 0 10.47 9.76 10.431 9.69 10.393 9.647 0.2 0.2 -0.1 -0.3 0.009 10.419 14.613 0.023 10.406 14.712 0.019 9.708 6.007 0.014 9.678 6.052 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00117 Final System Bias Check for Run 2 . STRATA Version 3.2 02 002 02 002 % % Volts Volts 4/4/2014 10:55:55 0.048 0.01 0.0019 0.0102 4/4/2014 10:56:55 7.546 7.513 0.3025 0.1956 4/4/2014 10:57:55 10.582 9.642 0.4242 0.2482 4/4/2014 10:58:55 10.906 9.655 0.4372 0.2485 4/4/2014 10:59:55 11.243 9.48 0.4507 0.2442 4/4/2014 11:00:55 10.512 9.704 0.4214 0.2497 Final System Bias Check for Run 2 Operator: PAT Plant Name: FCSAurora Location: #3Calciner Reference Cylinder Numbers Zero Span 02 0C44752 SA18330 002 0C44752 SA18330 Date/Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg Zero BiasP/o Zero Drift% Span Ref Cyl Span Cal Span Avg Span BiasP/c Span Drift% Ini Zero Avg Ini Span Avg Run Avg Co Cm Correct Avg 4/4/2014 11:01:31 02 002 % % 0 0 0.041 0.002 0.048 0.01 0 0 0.1 0 10.47 9.76 10.431 9.69 10.356 9.724 0.4 0.2 -0.2 0.4 0.037 10.393 14.968 0.043 10.374 15.126 0.009 9.647 5.636 0.009 9.685 5.675 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00118 Final System Bias Check for Run 3 . STRATA Version 3.2 02 002 02 002 % % Volts Volts 4/4/2014 14:03:33 -0.011 0.067 -0.0005 0.0116 4/4/2014 14:04:33 8.76 8.91 0.3511 0.2301 4/4/2014 14:05:33 10.321 9.664 0.4137 0.2487 Final System Bias Check for Run 3 Operator: PAT Plant Name: FCS Aurora Location: #3Calciner Reference Cylinder Numbers Zero Span 02 0C44752 SA18330 002 0C44752 SA18330 Date/Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg Zero BiasP/o Zero Drift% Span Ref Cyl Span Cal Span Avg Span BiasP/c Span Drift% Ini Zero Avg Ini Span Avg Run Avg Co Cm Correct Avg 4/4/2014 14:05:47 02 002 % % 0 0 0.041 0.002 -0.009 0.064 0.3 0.3 -0.3 0.3 10.47 9.76 10.431 9.69 10.324 9.666 0.6 0.1 -0.2 -0.3 0.048 10.356 13.974 0.02 10.34 14.157 0.01 9.724 6.475 0.037 9.695 6.506 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00119 Final System Bias Check for Run 4 . STRATA Version 3.2 02 002 02 002 % % Volts Volts 4/4/2014 15:49:27 7.072 6.68 0.2835 0.175 4/4/2014 15:50:27 10.309 9.624 0.4132 0.2477 Final System Bias Check for Run 4 Operator: PAT Plant Name: FCSAurora Location: #3Calciner Reference Cylinder Numbers Zero Span 02 0C44752 SA18330 002 0C44752 SA18330 Date/Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg Zero BiasP/o Zero Drift% Span Ref Cyl Span Cal Span Avg Span BiasP/c Span Drift% Ini Zero Avg Ini Span Avg Run Avg Co Cm Correct Avg 4/4/2014 15:51:16 P/^SSED 02 C02 % % 0 0 0.041 0.002 -0.007 0.046 0.2 0.2 0 -0.1 10.47 9.76 10.431 9.69 10.318 9.633 0.6 0.3 0 -0.2 -0.009 10.324 15.118 -0.008 10.321 15.333 0.064 9.666 5.561 0.055 9.65 5.6 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00120 Facility: Test Site: Test Date: Component: Test Run 1 2 3 4 Facility: Test Site: Test Date: Component: Test Run 1 2 3 4 FCS Aurora #3Calciner 4/4/2014 02 Calibration Gases Zero Gas 0 0 0 0 FCSAurora #3Calciner 4/4/2014 002 Upscale Gas 10.47 10.47 10.47 10.47 System Bias Check Results Final Initial Zero Initial Upscale Final Zero Upscale 0.009 0.037 0.048 -0.009 10.419 10.393 10.356 10.324 0.037 0.048 -0.009 -0.007 10.393 10.356 10.324 10.318 Raw Corrected Result Result (ppm) 14.613 14.712 14.968 15.126 13.974 14.157 15.118 15.333 Calibration Gases Zero Gas 0 0 0 0 Upscale Gas 9.76 9.76 9.76 9.76 System Bias Check Results Final Initial Zero Initial Upscale Final Zero Upscale 0.019 0.009 0.01 0.064 9.708 9.647 9.724 9.666 0.009 0.01 0.064 0.046 9.647 9.724 9.666 9.633 Raw Corrected Result Result (ppm) 6.007 6.052 5.636 5.675 6.475 6.506 5.561 5.6 FBIAS_Results.xlsm 17cv1906 Sierra Club v. EPA - 6/22 Production Summary ED 001523 00007569-00121 Run# Run 1 Run 2 Run 3 Run 4 Run 5 Run 6 HFMDL EPA Method 320 QA/QC Summary Avg. HF (ppm) 0.203 0.192 BDL BDL BDL BDL 0.141 Avg. HF w/ 0 sub for BDL Avg. HFw/ DLsub for BDL EPA Data Designation SiF4 0.129 0.055 0.000 0.000 0.000 0.000 0.181 0.156 0.141 0.141 0.141 0.141 DLL <0.011 DLL <0.011 BDL <0.011 BDL <0.011 BDL <0.011 BDL <0.011 DL=0.011 CO to 7725 ppmm 150C C02 to 34%m 150C CH4 to 39000 ppmm 150C N20 to 2550 ppmm 150C NITRIC OXIDE (FF) 150C NITROGEN DIOXIDE (PF) 150C H20 to 275 %m150Chi 126.177 142.071 134.518 131.660 129.624 123.626 5.328 5.264 5.060 4.988 4.846 4.856 7.051 6.550 6.330 6.659 6.631 6.843 16.555 15.684 15.124 14.494 15.753 15.916 57.162 53.454 59.646 62.991 63.961 63.398 5.872 6.220 4.995 4.793 5.240 4.495 30.319 31.327 29.535 28.261 27.487 28.197 Run Data Report (2).xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Method 320 QA Summary ED 001523 00007569-00122 PCS Phosphates Raw FTIR Data Spectrum Pre TestCTS PRE-TEST DiRECT_0002.LAB PRE-TEST DiRECT_0003.LAB PRE-TEST D!RECT_0004.LAB PRE-TEST DSRECT_0005.LA8 PRE-TEST DIRECT_0006.LAB PRE-TEST D!RECT_0007.LAB PRE-TEST DiRECT_0008.LAB PRE-TEST D(RECT_0009.LAB PRE-TEST D!RECT_0010.LAB HF Direct PRE-TEST DIRECT_0011.LAB PRE-TEST DiRECT_0012.LA8 PRE-TEST DiRECT_0013.LAB PRE-TEST DiRECT_0014.LAB PRE-TEST D!RECT_0015.LAB PRE-TEST DiRECT_0016.LAB PRE-TEST D!RECT_0017.LAB PRE-TEST D!RECT_0018.LAB PRE-TEST DiRECT_0019.LAB PRE-TEST D!RECT_0020.LAB PRE-TEST DiRECT_0021.L4B PRE-TEST DiRECT_0022.LA8 PRE-TEST DiRECT_0023.LAB PRE-TEST DiRECT_0024.LAB PRE-TEST DiRECT_0025.LAB PRE-TEST DiRECT_0026.LAB PRE-TEST DiRECT_0027.LAB PRE-TEST DiRECT_0028.LA8 PRE-TEST DiRECT_0029.LAB PRE-TEST DiRECT_0030.LAB PRE-TEST DIRECTJXBl.LAB PRE-TEST DiRECT_0032.LAB PRE-TEST DiRECT_0033.LAB PRE-TEST DiRECT_0034.LAB PRE-TEST D!RECT_0035.LAB PRE-TEST DiRECT_0036.LAB PRE-TEST D!RECT_0037.LAB PRE-TEST DSRECT_0038.LA8 PRE-TEST DiRECT_0039.LAB PRE-TEST D!RECT_0040.LAB PRE-TEST DiRECT_0041.LA8 PRE-TEST DiRECT_0042.LAB PRE-TEST DiRECT_0043.LAB PRE-TEST DiRECT_0045.LAB PRE-TEST DiRECT_0046.LAB PRE-TEST DiRECT_0047.LAB PRE-TEST DiRECT_0048.LAB PRE-TEST DiRECT_0049.LA8 PRE-TEST DiRECT_0050.LAB PRE-TEST DiRECT_0051.LA8 PRE-TEST DiRECT_0052.LAB PRE-TEST DiRECT_0053.LAB PRE-TEST DiRECT_0054.LAB PRE-TEST DiRECT_0055.LAB PRE-TEST D!RECT_0056.LAB PRE-TEST DiRECT_0057.LAB PRE-TEST D!RECT_0058.LAB PRE-TEST DSRECT_0059.LA8 PRE-TEST DiRECT_0060.LAB PRE-TEST D!RECT_0061.LAB PRE-TEST DiRECT_0062.LAB PRE-TEST DiRECT_0063.LAB PRE-TEST DiRECT_0064.LAB PRE-TEST DiRECT_0065.LAB PRE-TEST DiRECT_0066.LAB PRE-TEST DiRECT_0067.LA8 PRE-TEST DiRECT_0068.LAB PRE-TEST DiRECT_0069.LAB PRE-TEST DiRECT_0070.LAB PRE-TEST DiRECT_0071.LAB PRE-TEST DiRECT_0072.LAB PRE-TEST DiRECT_0073.LAB PRE-TEST DiRECT_0074.LAB PRE-TEST DiRECT_0075.LAB PRE-TEST D!RECT_0076.LAB PRE-TEST DiRECT_0077.LAB PRE-TEST D!RECT_0078.LAB PRE-TEST D!RECT_0079.LAB PRE-TEST DiRECT_0080.LAB PRE-TEST D!RECT_0081.LAB PRE-TEST DiRECT_0082.LAB PRE-TEST DiRECT_0083.LAB PRE-TEST DiRECT_0084.LA8 PRE-TEST DiRECT_0085.LA8 PRE-TEST DiRECT_0086.LAB PRE-TEST DiRECT_0087.LAB PRE-TEST DiRECT_0088.LAB PRE-TEST DiRECT_0089.LAB PRE-TEST DiRECT_0090.LAB PRE-TEST DiRECT_0091.LA8 PRE-TEST DiRECT_0092.LAB PRE-TEST DiRECT_0093.LAB PRE-TEST DiRECT_0094.LAB PRE-TEST DiRECT_0095.LAB PRE-TEST D!RECT_0096.LAB PRE-TEST DiRECT_0097.LAB PRE-TEST D!RECT_0098.LAB PRE-TEST DSRECT_0099.LA8 PRE-TEST DiRECT_0100.LAB PRE-TEST DSRECT_0101.LA8 PRE-TEST DiRECT_0102.LAB PRE-TEST DiRECT_0103.LAB PRE-TEST DiRECT_0104.LAB PRE-TEST DiRECT_0105.LAB PRE-TEST DiRECT_0106.LAB PRE-TEST DiRECT_0107.LA8 PRE-TEST DiRECT_0108.LA8 PRE-TEST DiRECT_0109.LA8 PRE-TEST DiRECT_0110.LA8 PRE-TEST DiRECT_0111.LA8 PRE-TEST DiRECT_0112.LAB PRE-TEST DiRECT_0113.LA8 PRE-TEST DiRECT_0114.LAB PRE-TEST DiRECT_0115.LAB PRE-TEST D!RECT_0116.LAB PRE-TEST DiRECT_0117.LAB PRE-TEST DiRECT_0118.LAB PRE-TEST DiRECT_0119.LA8 PRE-TEST DiRECT_0120.LA8 PRE-TEST DiRECT_0121.LAB PRE-TEST DiRECT_0122.LA8 PRE-TEST DiRECT_0123.LAB 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 11:18:50 11:19:19 11:19:49 11:20:18 11:20:47 11:21:16 11:21:45 11:22:14 11:22:43 11:26:43 11:27:13 11:27:42 11:28:11 11:28:40 11:29:09 11:29:38 11:3007 11:30:36 11:31:05 11:31:34 11:3203 11:32:32 11:3301 11:33:30 11:33:59 11:34:28 11:34:57 11:35:26 11:35:55 11:36:24 11:36:53 11:37:22 11:37:51 11:38:20 11:38:49 11:39:18 11:39:48 11:40:17 11:40:46 11:41:15 11:41:44 11:42:13 11:43:11 11:43:40 11:44 09 11:44:38 11:4507 11:45:36 11:4605 11:46:34 11:4703 11:47:32 11:4801 11:48:30 11:48:59 11:49:28 11:49:57 11:50:26 11:50:55 11:51:24 11:51:53 11:52:22 11:52:52 11:53:21 11:53:50 11:54:19 11:54:48 11:55:17 11:55:46 11:56:15 11:56:44 11:57:13 11:57:42 11:58:11 11:58:40 11:5909 11:59:38 12 00:07 12:00:36 1201:05 1201:34 12:02:03 1202:32 120301 12 03:30 1203:59 1204:28 12 04:57 1205:26 1205:56 1206:26 1206:54 1207:23 1207:52 1208:21 12 08:50 1209:19 12:09:48 12:10:17 12:10:46 12:11:15 12:11:44 12:12:13 12:12:42 12:13:11 12:13:40 12:1409 12:14:38 12:1507 12:15:36 12:1605 12:16:34 12:1703 12:17:32 12:18:01 12:18:30 12:18:59 12:19:29 12:19:58 12:20:27 12:20:56 0.066 0.002 0.009 -0.019 0.009 -0.003 -0.011 0.002 0.005 0.208 0.194 0.174 0.195 0.235 2.339 15.967 20.288 23.808 19.487 19.519 14.792 11.207 9.544 8.792 8.422 8.193 8.184 8.124 8.146 8.200 8.321 11.775 15.951 7.627 7.680 8.032 8.328 8.641 8.844 9.068 9.330 9.486 9.832 9.998 10.204 10.321 10.448 10.709 10.812 10.922 11.072 11.159 11.351 11.462 11.626 11.809 11.878 11.945 12.065 12.277 12.385 12.473 12.612 12.652 12.805 12.790 12.920 13.019 13.090 13.205 13.301 13.449 13.637 13.681 13.738 13.788 13.876 13.981 14.056 14.228 14.267 14.368 14.432 14.486 14.599 14.683 14.717 14.744 14.754 14.916 15.081 15.139 15.137 15.133 15.208 15.381 15.436 15.483 15.551 15.615 15.754 15.815 15.812 15.960 15.883 16.063 16.238 16.244 16.301 16.299 16.429 16.526 16.477 16.466 16.504 16.456 16.536 16.484 16.594 16.665 16.694 SF6 (ppm) 0.010 0.005 0.003 -0.001 0.002 0.003 0.003 0.006 0.003 8.328 8.522 8.520 8.539 8.547 7.895 8.732 8.873 9.662 8.691 8.700 8.617 8.526 8.542 8.546 8.551 8.547 8.549 8.549 8.549 8.556 8.549 8.543 8.516 8.550 8.550 8.543 8.534 8.540 8.534 8.540 8.544 8.535 8.545 8.546 8.553 8.541 8.539 8.553 8.552 8.538 8.550 8.538 8.547 8.542 8.545 8.537 8.543 8.538 8.545 8.545 8.564 8.565 8.558 8.554 8.564 8.564 8.570 8.558 8.558 8.554 8.553 8.565 8.558 8.567 8.563 8.562 8.572 8.558 8.546 8.556 8.553 8.564 8.555 8.547 8.552 8.563 8.555 8.564 8.565 8.571 8.576 8.566 8.569 8.569 8.571 8.570 8.575 8.571 8.572 8.572 8.576 8.574 8.566 8.578 8.573 8.583 8.582 8.568 8.581 8.579 8.578 8.584 8.577 8.578 8.577 8.569 8.579 8.569 8.566 8.568 8.563 SiF4 (ppm) 0.036 0.031 0.041 0.038 0.041 0.039 0.038 0.041 0.037 9.890 14.333 13.956 14.222 14.006 14.020 14.128 14.001 14.059 0.160 0.057 -0.015 0.106 -0.056 -0.086 -0.032 -0.142 0.059 0.192 -0.044 -0.018 -0.167 -0.049 -0.058 0.003 -0.146 0.046 0.029 -0.196 0.026 -0.052 0.014 0.019 0.000 0.148 -0.132 -0.163 -0.143 0.102 -0.009 0.028 -0.179 0.158 -0.053 -0.060 -0.111 0.013 -0.178 0.016 -0.010 -0.028 0.085 0.171 -0.121 0.111 -0.004 -0.121 0.141 0.047 -0.110 -0.165 0.056 0.000 -0.214 -0.061 -0.070 0.007 -0.064 -0.146 -0.006 -0.250 -0.092 0.011 -0.050 -0.084 0.084 -0.060 -0.110 0.106 -0.016 0.041 -0.163 -0.118 -0.167 -0.077 -0.047 -0.160 -0.075 0.057 0.035 0.036 0.070 -0.074 -0.172 0.123 -0.025 -0.341 -0.007 0.029 -0.001 -0.060 -0.084 -0.143 0.176 0.055 0.144 -0.112 -0.197 -0.157 -0.201 -0.118 -0.103 0.157 -0.056 -0.060 -0.215 0.057 -0.074 -0.167 -0.110 -0.135 C02 (%) 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -0.001 0.000 0.000 0.000 0.000 0.000 -0.001 0.000 0.000 -0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CH4 (ppm) NH3 (ppm) HC! (ppm) N20 (ppm) NO (ppm) N02 (ppm) -0.052 -0.108 0.039 -0.013 -0.047 0.146 -0.096 -0.114 -0.022 1.047 -0.005 -0.241 -0.092 -0.049 -0.114 -0.018 -0.052 -0.130 0.085 -0.012 -0.031 -0.001 -0.010 -0.006 -0.035 0.018 -0.018 0.037 -0.023 -0.034 -0.025 -0.023 -0.034 -0.020 -0.027 -0.017 13.202 17.397 17.455 17.382 17.319 17.128 17.091 17.199 0.176 -0.048 0.059 0.228 -0.200 -0.378 -0.136 -0.111 -0.166 0.136 -0.225 -0.278 -0.068 -0.318 -0.322 -0.217 -0.107 -0.078 -0.046 -0.208 -0.315 -0.157 -0.249 0.036 -0.221 -0.204 -0.333 -0.172 -0.016 -0.497 -0.403 -0.222 -0.587 -0.181 -0.507 -0.032 -0.174 -0.264 0.132 -0.091 -0.117 0.144 -0.241 0.050 -0.021 -0.327 -0.062 -0.218 -0.007 -0.010 -0.135 -0.002 -0.101 0.080 -0.087 -0.057 -0.278 -0.474 0.161 -0.031 0.287 0.065 -0.113 0.117 -0.198 -0.055 -0.124 -0.019 0.130 -0.071 -0.068 -0.115 -0.080 -0.140 -0.528 -0.596 0.006 0.007 -0.233 -0.172 -0.101 -0.113 -0.026 -0.331 -0.354 0.039 -0.025 -0.151 -0.038 -0.179 -0.231 -0.108 -0.302 0.006 -0.505 -0.486 -0.347 -0.369 -0.110 -0.170 -0.503 -0.258 -0.272 -0.105 -0.186 -0.374 -0.369 -0.403 -0.393 -0.638 -0.469 -0.243 -1.073 -1.290 -1.345 -1.372 -1.407 -1.499 -1.917 -2.105 -2.297 -1.854 -1.924 -1.645 -1.544 -1.528 -1.565 -1.566 -1.586 -1.571 -1.576 -1.604 -1.607 -1.568 -1.578 -1.519 -1.562 -1.585 -1.566 -1.538 -1.584 -1.574 -1.535 -1.538 -1.556 -1.562 -1.562 -1.568 -1.550 -1.565 -1.596 -1.579 -1.550 -1.584 -1.565 -1.572 -1.546 -1.557 -1.572 -1.561 -1.532 -1.578 -1.607 -1.580 -1.593 -1.572 -1.582 -1.605 -1.585 -1.584 -1.585 -1.593 -1.592 -1.605 -1.581 -1.601 -1.611 -1.579 -1.594 -1.626 -1.622 -1.576 -1.610 -1.593 -1.600 -1.595 -1.573 -1.579 -1.596 -1.602 -1.635 -1.604 -1.625 -1.630 -1.598 -1.606 -1.621 -1.629 -1.611 -1.628 -1.626 -1.609 -1.633 -1.615 -1.631 -1.627 -1.618 -1.603 -1.622 -1.643 -1.630 -1.640 -1.647 -1.614 -1.618 -1.631 -1.605 -1.607 -1.620 -1.596 -1.591 -1.586 -1.573 -1.584 0.019 0.000 0.014 0.010 0.034 0.025 0.060 0.018 0.043 0.022 0.066 0.008 0.031 0.024 -0.006 0.033 -0.003 0.010 0.011 0.019 0.023 0.025 0.039 0.065 0.022 0.027 0.006 -0.017 -0.029 0.037 0.026 0.023 0.078 -0.038 -0.001 0.042 0.000 0.049 0.004 -0.007 0.049 0.029 0.008 0.004 0.029 0.032 -0.015 0.035 0.024 -0.006 0.008 0.007 0.035 0.048 0.008 0.023 0.001 -0.021 0.040 -0.007 0.037 0.014 -0.011 -0.011 0.016 0.007 0.046 -0.041 0.028 0.026 0.014 0.007 0.027 -0.003 0.023 0.038 -0.010 0.027 -0.016 0.040 0.009 -0.010 -0.004 0.023 -0.029 -0.010 -0.012 0.029 -0.014 0.002 0.009 -0.031 -0.035 0.021 -0.014 -0.027 -0.040 0.023 -0.031 -0.010 -0.001 -0.020 -0.021 0.009 0.013 -0.032 0.005 -0.055 0.019 0.011 0.007 0.001 -0.004 0.002 0.006 -0.005 -0.005 -0.006 -0.003 0.006 0.001 -0.001 0.000 0.001 -0.006 -0.012 0.004 0.002 0.002 -0.005 0.001 0.006 0.007 -0.001 0.006 0.000 0.004 0.006 -0.007 -0.009 0.003 0.000 -0.001 0.003 0.002 -0.003 0.012 -0.004 0.005 -0.003 0.003 0.003 -0.004 -0.002 -0.009 -0.007 -0.005 0.002 -0.002 -0.004 0.005 -0.002 -0.010 -0.002 -0.005 0.000 -0.007 0.000 -0.008 -0.001 -0.005 0.006 0.002 -0.004 -0.001 -0.001 0.004 -0.004 -0.004 -0.004 0.000 -0.008 0.000 -0.007 -0.002 0.003 0.004 0.008 -0.003 -0.006 -0.001 -0.006 -0.007 0.000 -0.006 0.004 0.006 -0.002 0.000 0.000 -0.007 -0.005 0.003 -0.010 0.006 -0.003 0.002 0.004 0.000 -0.010 -0.002 -0.001 -0.008 -0.007 -0.001 -0.001 -0.001 -0.003 0.006 0.002 0.004 0.005 -0.002 -0.003 H20 (%) Temp ( C) Pressure (atm) 0.137 -0.004 -0.006 -0.009 -0.008 -0.009 -0.008 -0.009 -0.006 149.430 149.125 149.023 149.125 149.125 149.227 149.125 149.430 149.430 1.013 1.013 1.014 1.013 1.013 1.013 1.013 1.013 1.013 0.053 0.033 0.020 0.018 0.016 0.017 0.002 -0.006 0.000 0.003 -0.008 0.005 -0.005 0.008 -0.002 -0.004 0.004 0.002 0.006 0.000 0.003 0.004 0.012 0.036 0.006 0.006 0.002 0.004 0.004 -0.003 -0.015 -0.007 -0.006 -0.002 0.008 0.000 0.001 0.003 -0.003 -0.006 0.002 0.002 0.004 0.000 0.000 0.000 0.003 0.000 0.004 0.007 -0.002 0.001 -0.001 0.036 -0.001 0.000 0.002 -0.002 0.002 0.009 0.006 0.000 -0.008 0.007 -0.003 0.004 -0.001 0.002 0.004 -0.002 0.002 -0.003 -0.001 0.004 -0.004 0.004 0.001 0.003 0.003 -0.002 -0.002 -0.011 0.004 -0.004 -0.005 -0.006 0.003 -0.004 -0.005 -0.005 -0.001 -0.003 -0.003 0.006 -0.012 -0.012 -0.008 -0.014 -0.015 -0.005 -0.006 -0.005 -0.006 -0.006 -0.003 -0.006 0.000 -0.015 -0.004 -0.011 -0.011 0.003 149.532 149.430 149.328 149.125 149.328 149.328 148.718 148.718 148.616 148.820 149.125 148.921 148.718 149.125 149.532 149.532 149.532 149.634 149.634 149.532 149.532 149.430 149.532 149.430 149.430 149.532 149.532 149.430 149.532 149.532 149.634 149.634 149.532 149.532 149.735 149.735 149.532 149.430 149.735 149.634 149.634 149.634 149.634 149.634 149.532 149.532 149.430 149.430 149.430 149.430 149.430 149.634 149.735 149.532 149.634 149.532 149.532 149.532 149.735 149.634 149.634 149.532 149.532 149.532 149.634 149.634 149.532 149.735 149.532 149.532 149.532 149.634 149.532 149.532 149.532 149.430 149.532 149.532 149.634 149.532 149.532 149.532 149.634 149.532 149.532 149.634 149.532 149.430 149.532 149.634 149.532 149.532 149.532 149.532 149.634 149.735 149.532 149.532 149.430 149.634 149.532 149.634 149.532 149.532 149.532 149.532 149.532 149.634 149.735 149.634 149.634 149.430 1.017 1.017 1.018 1.017 1.017 1.151 1.170 1.175 1.056 1.055 1.055 1.017 1.017 1.017 1.018 1.017 1.018 1.018 1.018 1.018 1.017 1.018 1.016 1.018 1.018 1.017 1.018 1.018 1.017 1.018 1.017 1.017 1.017 1.016 1.017 1.018 1.018 1.017 1.016 1.017 1.017 1.017 1.018 1.017 1.017 1.016 1.017 1.016 1.016 1.017 1.017 1.016 1.017 1.017 1.017 1.017 1.017 1.016 1.017 1.017 1.017 1.017 1.017 1.017 1.017 1.017 1.017 1.016 1.017 1.017 1.016 1.017 1.016 1.016 1.017 1.016 1.016 1.017 1.017 1.017 1.017 1.016 1.017 1.016 1.017 1.017 1.016 1.016 1.016 1.017 1.017 1.017 1.016 1.017 1.016 1.017 1.016 1.016 1.017 1.016 1.016 1.016 1.016 1.016 1.016 1.017 1.017 1.016 1.016 1.017 1.016 1.016 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00123 PCS Phosphates Raw FTIR Data Spectrum PRE-TEST DiRECT_0124.LAB PRE-TEST D!RECT_0125.LAB PRE-TEST DiRECT_0126.LA8 PRE-TEST DiRECT_0127.LAB PRE-TEST D(RECT_0128.LAB PRE-TEST DiRECT_0129.LAB PRE-TEST DiRECT_0130.LAB PRE-TEST DiRECT_0131.LAB PRE-TEST D(RECT_0132.LAB PRE-TEST DiRECT_0133.LAB PRE-TEST D(RECT_0134.LA8 PRE-TEST DiRECT_0135.LAB PRE-TEST DiRECT_0136.LAB PRE-TEST DiRECT_0137.LAB PRE-TEST DiRECT_0138.LAB PRE-TEST DiRECT_0139.LAB PRE-TEST D!RECT_0140.LAB PRE-TEST DiRECT_0141.LAB PRE-TEST D!RECT_0142.LAB PRE-TEST D!RECT_0143.LAB PRE-TEST DiRECT_0144.LAB PRE-TEST D!RECT_0145.LAB PRE-TEST DiRECT_0146.LAB PRE-TEST DiRECT_0147.LAB PRE-TEST D(RECT_0148.LA8 PRE-TEST DiRECT_0149.LAB PRE-TEST D(RECT_0150.LAB PRE-TEST DiRECT_0151.LAB PRE-TEST D(RECT_0152.LAB PRE-TEST DiRECT_0153.LA8 PRE-TEST D(RECT_0154.LA8 PRE-TEST DiRECT_0155.LAB PRE-TEST DiRECT_0156.LAB PRE-TEST DiRECT_0157.LAB PRE-TEST DiRECT_0158.LAB PRE-TEST DiRECT_0159.LAB PRE-TEST D!RECT_0160.LAB PRE-TEST DiRECT_0161.LAB PRE-TEST D!RECT_0162.LA8 PRE-TEST D!RECT_0163.LAB PRE-TEST DiRECT_0164.LA8 PRE-TEST D!RECT_0165.LAB PRE-TEST DiRECT_0166.LAB PRE-TEST DiRECT_0167.LAB PRE-TEST D(RECT_0168.LAB PRE-TEST DiRECT_0183.LAB PRE-TEST D(RECT_0184.LAB PRE-TEST DiRECT_0203.LAB PRE-TEST D(RECT_0204.LAB PRE-TEST DiRECT_0205.LAB PRE-TEST DiRECT_0206.LAB PRE-TEST DiRECT_0207.LAB PRE-TEST D!RECT_0208.LA8 PRE-TEST DiRECT_0209.LA8 PRE-TEST DiRECT_0210.LAB PRE-TEST DiRECT_0211.LAB PRE-TEST D!RECT_0212.LA8 PRE-TEST DiRECT_0213.LA8 PRE-TEST D!RECT_0214.LAB PRE-TEST D!RECT_0215.LAB PRE-TEST DiRECT_0216.LAB PRE-TEST D!RECT_0217.LAB PRE-TEST DiRECT_0218.LA8 PRE-TEST DiRECT_0219.LA8 PRE-TEST DiRECT_0220.LAB PRE-TEST DiRECT_0221.LAB PRE-TEST D(RECT_0222.LA8 PRE-TEST DiRECT_0223.LAB PRE-TEST D(RECT_0224.LAB PRE-TEST DiRECT_0225.LAB PRE-TEST D(RECT_0226.LA8 PRE-TEST DiRECT_0227.LA8 PRE-TEST D(RECT_0228.LAB PRE-TEST DiRECT_0229.LA8 PRE-TEST DiRECT_0230.LAB PRE-TEST DiRECT_0231.LAB PRE-TEST D!RECT_0232.LAB PRE-TEST DiRECT_0233.LAB PRE-TEST D!RECT_0234.LAB PRE-TEST D!RECT_0235.LAB PRE-TEST DiRECT_0236.LAB PRE-TEST D!RECT_0237.LAB PRE-TEST DiRECT_0238.LA8 PRE-TEST DiRECT_0239.LA8 PRE-TEST DiRECT_0240.LAB PRE-TEST DiRECT_0241.LAB PRE-TEST DiRECT_0242.LAB PRE-TEST DiRECT_0243.LA8 PRE-TEST DiRECT_0244.LAB PRE-TEST DiRECT_0245.LAB PRE-TEST DiRECT_0246.LAB PRE-TEST DiRECT_0247.LAB PRE-TEST D(RECT_0248.LAB PRE-TEST DiRECT_0249.LA8 PRE-TEST DiRECT_0250.LAB PRE-TEST DiRECT_0251.LAB PRE-TEST D!RECT_0252.LAB PRE-TEST DiRECT_0253.LAB PRE-TEST D!RECT_0254.LAB PRE-TEST D!RECT_0255.LAB PRE-TEST DiRECT_0256.LA8 PRE-TEST D!RECT_0257.LAB PRE-TEST DiRECT_0258.LAB PRE-TEST DiRECT_0259.LAB PRE-TEST DiRECT_0260.LAB PRE-TEST DiRECT_0261.LAB PRE-TEST D(RECT_0262.LAB PRE-TEST DiRECT_0263.LA8 PRE-TEST DiRECT_0264.LAB PRE-TEST DiRECT_0265.LAB PRE-TEST DiRECT_0266.LAB PRE-TEST DiRECT_0267.LAB PRE-TEST D!RECT_0268.LA8 PRE-TEST DiRECT_0269.LA8 PRE-TEST DiRECT_0270.LAB PRE-TEST DiRECT_0271.LAB PRE-TEST D!RECT_0272.LAB PRE-TEST DiRECT_0273.LAB PRE-TEST DiRECT_0274.LAB PRE-TEST DiRECT_0275.LAB PRE-TEST DiRECT_0276.LA8 PRE-TEST DiRECT_0277.LA8 PRE-TEST DiRECT_0278.LAB PRE-TEST D!RCT_0279.LA8 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 12:21:25 12:21:54 12:22:23 12:22:52 12:23:21 12:23:50 12:24:19 12:24:48 12:25:17 12:25:46 12:26:15 12:26:44 12:27:13 12:27:42 12:28:11 12:28:40 12:29:09 12:29:38 12:30:07 12:30:36 12:31:05 12:31:34 12:32:04 12:32:33 12:3302 12:33:31 12:3400 12:34:29 12:34:58 12:35:27 12:35:56 12:36:25 12:36:54 12:37:23 12:37:52 12:38:21 12:38:50 12:39:19 12:39:48 12:40:17 12:40:46 12:41:15 12:41:44 12:42:13 12:42:42 12:49:58 12:50:27 1301:56 13:02:25 13:02:54 1303:23 1303:52 13:04:21 1304:50 1305:19 1305:48 1306:17 1306:46 1307:15 1307:44 1308:13 1308:42 1309:11 1309:40 13:1009 13:10:38 13:11:08 13:11:37 13:12:06 13:12:35 13:13:04 13:13:33 13:1402 13:14:31 13:1500 13:15:29 13:15:58 13:16:27 13:16:56 13:17:25 13:17:54 13:18:23 13:18:52 13:19:21 13:19:50 13:20:19 13:20:48 13:21:17 13:21:46 13:22:15 13:22:44 13:23:13 13:23:42 13:24:12 13:24:41 13:25:10 13:25:39 13:26/38 13:26:37 13:27:06 13:27:35 13:2804 13:28:33 13:2902 13:29:31 13:30:00 13:30:29 13:30:58 13:31:27 13:31:56 13:32:25 13:32:54 13:33:23 13:33:52 13:34:21 13:34:50 13:35:19 13:35:48 13:36:17 13:36:46 13:37:16 13:37:45 13:38:14 13:38:43 16.679 16.824 16.922 16.900 17.043 17.129 17.161 17.184 17.225 17.390 17.363 17.232 17.247 17.326 17.427 17.445 17.554 17.700 17.701 17.739 17.667 17.830 17.997 17.967 18.076 18.040 18.117 18.136 18.223 18.308 18.375 18.409 18.386 18.428 18.473 18.566 18.670 18.676 18.770 18.784 18.790 18.750 18.728 18.731 18.796 19.420 19.425 10.004 10.418 10.793 11.139 11.436 11.702 11.920 12.091 12.331 12.466 12.494 12.677 12.822 12.984 13.152 13.235 13.354 13.469 13.554 13.612 13.714 13.800 13.939 13.937 14.007 14.093 14.134 14.102 14.238 14.312 14.366 14.431 14.559 14.522 14.653 14.732 14.736 14.764 14.798 14.868 14.901 14.932 14.969 14.989 15.045 15.076 15.055 15.049 15.240 16.364 18.009 20.042 21.214 18.519 13.735 11.044 9.995 8.770 7.749 7.342 7.250 7.373 7.389 7.378 7.458 7.422 7.484 7.534 7.566 7.533 7.520 7.587 7.644 7.625 7.649 7.658 7.614 SF6 (ppm) 8.567 8.565 8.565 8.560 8.566 8.576 8.565 8.568 8.569 8.567 8.569 8.564 8.565 8.561 8.567 8.564 8.563 8.566 8.561 8.572 8.563 8.574 8.572 8.568 8.576 8.567 8.569 8.571 8.576 8.570 8.572 8.562 8.575 8.568 8.574 8.571 8.569 8.572 8.570 8.570 8.567 8.567 8.579 8.580 8.574 8.578 8.584 8.585 8.583 8.583 8.580 8.580 8.586 8.584 8.577 8.588 8.584 8.584 8.587 8.580 8.580 8.579 8.575 8.573 8.574 8.575 8.566 8.562 8.574 8.576 8.567 8.560 8.566 8.562 8.551 8.556 8.554 8.562 8.556 8.562 8.560 8.565 8.576 8.573 8.567 8.568 8.581 8.572 8.568 8.571 8.582 8.578 8.585 8.576 8.572 8.565 8.562 8.557 8.556 8.555 8.541 8.520 8.502 8.489 8.481 8.464 8.404 8.449 8.453 8.454 8.468 8.473 8.480 8.483 8.495 8.496 8.504 8.510 8.517 8.519 8.528 8.531 8.530 8.526 SiF4 (ppm) -0.182 -0.364 -0.066 -0.135 -0.073 -0.046 0.055 0.067 -0.416 0.007 -0.196 -0.253 -0.104 -0.384 0.006 -0.249 -0.190 -0.158 0.009 -0.087 -0.220 -0.076 -0.211 -0.067 -0.165 -0.318 -0.100 -0.194 -0.100 0.018 -0.049 -0.184 -0.217 -0.377 -0.115 -0.225 -0.236 0.089 -0.160 -0.137 -0.149 -0.191 -0.101 -0.336 -0.116 -0.088 -0.042 -0.132 -0.197 -0.371 0.036 -0.183 -0.194 -0.131 -0.041 0.021 -0.275 -0.119 -0.234 -0.118 0.099 -0.270 0.036 -0.187 -0.080 -0.359 -0.005 -0.133 -0.194 -0.215 0.064 -0.166 -0.280 -0.128 -0.066 -0.236 -0.094 -0.143 -0.021 -0.150 -0.313 0.005 -0.117 0.019 -0.074 -0.128 -0.048 -0.057 -0.117 -0.214 -0.188 -0.165 -0.176 -0.024 0.044 -0.188 -0.015 -0.165 0.092 0.170 0.528 3.805 8.106 10.915 13.241 14.441 15.560 15.802 15.811 16.156 15.901 16.066 16.066 16.076 15.801 15.936 15.959 16.180 15.941 15.830 15.983 15.947 16.040 16.134 C02 (%) 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.001 0.000 0.000 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.001 0.001 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.003 0.002 0.002 0.002 0.002 0.003 0.002 0.003 0.003 CH4 (ppm) -0467 -0.232 -0530 -0.161 -0065 -0.202 -0.234 -0.343 -0.257 -0.082 -0.289 -0.288 -0.292 -0.279 -0.312 -0.352 -0.352 -0.269 -0.378 -0.363 -0.441 -0.471 -0.336 -0.460 -0.457 -0.300 -0.290 -0.286 -0.207 -0.432 -0.512 -0.295 -0.470 -0.371 -0.248 -0.359 -0.240 -0.135 -0.548 -0.396 -0.220 -0.312 -0.301 -0.272 -0.272 -0.405 -0.537 -0.245 -0.050 -0.476 -0.229 -0.198 0.025 -0.301 -0.427 -0.356 -0.341 -0.480 -0.195 -0.352 -0.248 -0.289 -0.402 -0.292 -0.358 -0.344 -0.235 -0.447 -0.251 -0.221 -0.124 -0.438 -0.389 -0.318 -0.326 -0.252 -0.426 -0.312 -0.297 -0.279 -0.217 0.108 -0.543 -0.431 -0.351 -0.181 -0.190 -0.161 -0.142 -0.367 -0.330 -0.502 -0.346 -0.466 -0.476 -0.501 -0.419 -0.109 -0.032 0.128 0.091 1.015 1.269 1.336 1.637 1.637 2.096 1.800 1.681 1.874 1.896 1.577 1.757 2.094 1.924 1.725 1.749 1.960 1.850 1.968 2.101 1.482 1.930 1.900 NH3 (ppm) -1.592 -1.583 -1.594 -1.607 -1.600 -1.584 -1.599 -1.584 -1.591 -1.606 -1.597 -1.611 -1.594 -1.612 -1.612 -1.614 -1.649 -1.626 -1.606 -1.620 -1.622 -1.594 -1.644 -1.627 -1.609 -1.606 -1.607 -1.633 -1.643 -1.625 -1.612 -1.597 -1.614 -1.632 -1.611 -1.629 -1.622 -1.639 -1.648 -1.638 -1.626 -1.623 -1.617 -1.639 -1.634 -1.627 -1.631 -1.554 -1.554 -1.528 -1.532 -1.534 -1.536 -1.535 -1.552 -1.548 -1.546 -1.542 -1.553 -1.538 -1.549 -1.562 -1.535 -1.516 -1.523 -1.529 -1.536 -1.489 -1.513 -1.528 -1.517 -1.494 -1.494 -1.492 -1.479 -1.477 -1.488 -1.519 -1.497 -1.480 -1.494 -1.501 -1.488 -1.496 -1.498 -1.499 -1.515 -1.521 -1.476 -1.526 -1.487 -1.481 -1.488 -1.497 -1.489 -1.472 -1.465 -1.459 -1.449 -1.452 -0.523 14.890 52.454 96.459 170.456 284.755 285.229 233.188 192.068 162.109 139.401 121.798 107.783 96.499 87.268 79.543 73.049 67.486 62.769 58.632 55.040 51.857 49.046 46.399 -0.045 -0.009 -0.013 0.051 0.018 0.009 0.020 0.003 -0.010 0.032 -0.058 -0.010 -0.004 -0.005 -0.008 0.002 -0.015 -0.030 -0.007 -0.013 -0.024 -0.039 0.006 0.038 0.010 -0.049 0.014 -0.001 -0.015 0.001 -0.008 -0.006 -0.019 -0.012 -0.022 -0.019 -0.003 -0.023 0.024 -0.010 0.013 -0.008 -0.047 -0.022 -0.020 -0.019 -0.010 0.027 -0.009 0.000 0.031 0.039 0.005 0.004 0.017 0.001 -0.031 0.027 0.008 0.009 0.035 0.031 -0.009 -0.008 -0.014 0.037 -0.021 0.003 -0.010 -0.016 -0.001 0.005 -0.001 0.026 0.028 0.020 0.007 0.008 0.003 -0.003 -0.020 -0.016 0.009 0.042 0.014 -0.002 0.005 0.004 0.017 0.021 0.040 -0.018 0.001 0.038 0.023 0.000 0.011 0.056 0.001 -0.181 -0.328 -0.449 -0.432 -0.502 -0.721 -1.131 -1.166 -1.106 -1.047 -0.956 -0.946 -0.939 -0.900 -0.866 -0.823 -0.801 -0.784 -0.752 -0.749 -0.747 -0.752 -0.697 -0.711 -0.694 N20 (ppm) -0.002 -0.006 0.001 0.000 0.004 0.005 -0.001 0.008 0.003 0.003 -0.006 0.006 -0.004 -0.004 -0.009 0.006 -0.005 -0.005 0.007 0.000 0.015 -0.012 -0.002 -0.003 -0.007 0.001 -0.002 -0.001 -0.010 -0.003 -0.001 0.000 -0.016 -0.008 0.006 0.004 -0.006 -0.015 -0.003 -0.006 -0.004 -0.006 0.002 -0.003 -0.009 0.004 0.002 -0.002 -0.009 0.001 -0.002 -0.009 -0.002 -0.009 -0.013 -0.014 0.000 0.001 -0.010 -0.011 -0.007 0.001 0.001 0.000 -0.002 0.006 0.000 0.002 -0.008 0.005 0.004 0.000 0.002 0.005 0.001 -0.001 -0.011 -0.004 -0.004 -0.003 -0.013 0.000 -0.002 -0.003 -0.005 0.007 -0.007 0.001 -0.004 -0.005 -0.014 -0.001 -0.010 0.000 -0.004 -0.009 -0.011 -0.003 -0.002 -0.006 -0.003 0.009 -0.014 -0.019 -0.024 -0.031 -0.020 -0.032 -0.024 -0.026 -0.037 -0.032 -0.035 -0.027 -0.028 -0.016 -0.037 -0.027 -0.021 -0.025 -0.029 -0.026 -0.018 -0.021 N02 (ppm) H20 (%) -0.007 -0.012 -0.007 -0.009 -0.001 -0.009 -0.007 -0.018 -0.012 -0.012 -0.003 -0.011 -0.004 -0.013 -0.005 -0.009 -0.008 -0.022 -0.012 -0.008 -0.006 -0.012 -0.015 -0.008 -0.010 -0.010 -0.005 -0.003 -0.006 -0.010 -0.007 -0.009 -0.005 -0.008 -0.005 -0.008 -0.016 -0.007 -0.006 -0.009 -0.009 -0.010 -0.009 -0.005 -0.001 -0.014 -0.009 0.032 0.030 0.021 0.026 0.029 0.025 0.023 0.015 0.016 0.017 0.017 0.021 0.021 0.015 0.016 0.004 0.016 0.018 0.018 0.011 0.011 0.019 0.018 0.010 0.016 0.016 0.010 0.012 0.009 0.014 0.006 0.019 0.011 0.016 0.014 0.008 0.010 0.013 0.008 0.005 0.011 0.015 0.009 0.011 0.003 0.010 0.010 0.006 0.009 0.014 0.014 0.026 0.098 0.157 0.242 0.258 0.260 0.289 0.351 0.354 0.335 0.317 0.307 0.297 0.295 0.291 0.277 0.286 0.279 0.282 0.273 0.288 0.275 0.268 0.278 0.273 0.271 Temp r c) 149.532 149.532 149.430 149.430 149.532 149.634 149.532 149.532 149.532 149.532 149.634 149.634 149.532 149.532 149.430 149.430 149.430 149.532 149.532 149.532 149.430 149.532 149.532 149.532 149.532 149.532 149.430 149.532 149.532 149.735 149.532 149.430 149.735 149.532 149.532 149.532 149.532 149.532 149.532 149.532 149.430 149.532 149.634 149.735 149.634 149.532 149.532 149.328 149.328 149.328 149.532 149.532 149.430 149.227 149.328 149.532 149.532 149.430 149.532 149.125 149.430 149.328 149.328 149.328 149.328 149.430 149.430 149.227 149.430 149.430 149.328 149.430 149.430 149.328 149.227 149.227 149.125 149.227 149.125 149.125 149.125 148.921 149.125 149.125 149.125 149.125 149.430 149.125 149.227 149.125 149.430 149.430 149.532 149.328 149.328 149.227 149.227 149.430 149.227 149.532 149.532 149.430 149.430 149.023 149.125 149.328 149.125 149.430 149.735 149.532 149.532 149.328 149.430 149.328 149.328 149.227 149.430 149.328 149.430 149.430 149.532 149.430 149.328 149.125 1.016 1.016 1.016 1.017 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.017 1.016 1.017 1.016 1.016 1.016 1.016 1.017 1.015 1.016 1.016 1.016 1.016 1.015 1.016 1.015 1.016 1.015 1.016 1.016 1.016 1.016 1.016 1.015 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.015 1.016 1.016 1.016 1.015 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.017 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.016 1.015 1.015 1.016 1.016 1.016 1.015 1.016 1.015 1.016 1.016 1.015 1.016 1.016 1.016 1.015 1.015 1.016 1.016 1.015 1.016 1.015 1.015 1.016 1.016 1.016 1.015 1.015 1.016 1.016 1.016 1.016 1.016 1.015 1.015 1.013 1.011 1.011 1.010 1.010 1.010 1.010 1.010 1.010 1.010 1.010 1.010 1.010 1.010 1.010 1.010 1.010 1.010 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00124 PCS Phosphates Raw FTIR Data Spectrum PRE-TEST DiRECT_0280.LAB PRE-TEST D!RECT_0281.LAB PRE-TEST DiRECT_0282.LA8 PRE-TEST DiRECT_028B.LAB PRE-TEST D(RECT_0284.LAB PRE-TEST DiRECT_0285.LAB PRE-TEST D(RECT_0286.LAB PRE-TEST DiRECT_0287.LA8 PRE-TEST DiRECT_0288.LAB PRE-TEST DiRECT_0289.LAB PRE-TEST DiRECT_0290.LAB PRE-TEST DiRECT_0291.LAB PRE-TEST DiRECT_0292.LA8 PRE-TEST DiRECT_029B.LAB PRE-TEST DiRECT_0294.LAB PRE-TEST DiRECT_0295.LA8 PRE-TEST D!RECT_0296.LAB PRE-TEST DiRECT_0297.LAB PRE-TEST D!RECT_0298.LAB PRE-TEST D!RECT_0299.LAB PRE-TEST DiRECT_0300.LA8 PRE-TEST D!RECT_0301.LAB PRE-TEST DiRECT_0302.LA8 PRE-TEST DiRECT_0303.LAB PRE-TEST D(RECT_0B04.LAB PRE-TEST DiRECT_0305.LAB PRE-TEST D(RECT_0306.LAB PRE-TEST DiRECT_0307.LAB PRE-TEST D(RECT_0308.LAB PRE-TEST DiRECT_0309.LAB PRE-TEST DiRECT_0310.LAB PRE-TEST DiRECT_0311.LAB PRE-TEST D(RECT_0312.LAB PRE-TEST DiRECT_0313.LAB PRE-TEST D(RECT_0314.LAB PRE-TEST DiRECT_0315.LAB PRE-TEST DiRECT_0316.LA8 PRE-TEST DiRECT_0317.LA8 PRE-TEST D!RECT_0318.LAB PRE-TEST D!RECT_0319.LAB PRE-TEST DiRECT_0320.LAB PRE-TEST D!RECT_0321.LAB PRE-TEST DiRECT_0322.LA8 PRE-TEST DiRECT_0323.LAB PRE-TEST D(RECT_0324.LAB PRE-TEST DiRECT_0325.LA8 PRE-TEST DiRECT_0326.LAB PRE-TEST DiRECT_0327.LA8 PRE-TEST D(RECT_0328.LAB PRE-TEST DiRECT_0329.LAB PRE-TEST DiRECT_0330.LAB PRE-TEST DiRECT_0331.LAB PRE-TEST D(RECT_0332.LA8 PRE-TEST DiRECT_0333.LAB PRE-TEST D(RECT_0334.LAB PRE-TEST DiRECT_0335.LAB PRE-TEST D!RECT_0336.LAB PRE-TEST DiRECT_0337.LA8 PRE-TEST D!RECT_0338.LAB PRE-TEST D!RECT_0339.LAB PRE-TEST DiRECT_0340.LAB PRE-TEST D!RECT_0341.LAB PRE-TEST DiRECT_0342.LA8 PRE-TEST DiRECT_0343.LAB PRE-TEST D(RECT_0344.LAB PRE-TEST DiRECT_0345.LAB PRE-TEST DiRECT_0346.LAB PRE-TEST DiRECT_0347.LA8 PRE-TEST DiRECT_0348.LAB PRE-TEST DiRECT_0349.LAB PRE-TEST DiRECT_0350.LA8 PRE-TEST DiRECT_0351.LAB PRE-TEST D(RECT_0352.LA8 PRE-TEST DiRECT_0353.LAB PRE-TEST D(RECT_0354.LAB PRE-TEST DiRECT_0355.LAB PRE-TEST D!RECT_0356.LAB PRE-TEST DiRECT_0357.LA8 PRE-TEST D!RECT_0358.LAB PRE-TEST D!RECT_0359.LAB PRE-TEST DiRECT_0360.LAB PRE-TEST D!RECT_0361.LAB PRE-TEST DiRECT_0362.LA8 PRE-TEST DiRECT_0363.LAB PRE-TEST DiRECT_0364.LAB PRE-TEST DiRECT_0365.LAB PRE-TEST DiRECT_0366.LAB PRE-TEST DiRECT_0367.LAB PRE-TEST D(RECT_0368.LAB PRE-TEST DiRECT_0369.LAB PRE-TEST DiRECT_0370.LA8 PRE-TEST DiRECT_0371.LAB PRE-TEST DiRECT_0372.LA8 PRE-TEST DiRECT_0373.LAB PRE-TEST D(RECT_0374.LAB PRE-TEST DiRECT_0375.LAB PRE-TEST D!RECT_0376.LAB PRE-TEST DiRECT_0377.LAB PRE-TEST D!RECT_0378.LAB PRE-TEST D!RECT_0379.LAB PRE-TEST DiRECT_0380.LAB PRE-TEST D!RECT_0381.LAB PRE-TEST DiRECT_0382.LAB PRE-TEST DiRECT_0383.LAB PRE-TEST DiRECT_0384.LAB PRE-TEST DiRECT_0385.LA8 PRE-TEST DiRECT_0386.LA8 PRE-TEST DiRECT_0387.LA8 PRE-TEST DiRECT_0388.LA8 PRE-TEST DiRECT_0389.LAB PRE-TEST DiRECT_0390.LAB PRE-TEST DiRECT_0391.LAB PRE-TEST D(RECT_0392.LA8 PRE-TEST DiRECT_0393.LAB PRE-TEST D(RECT_0394.LA8 PRE-TEST DiRECT_0395.LA8 PRE-TEST D!RECT_0396.LA8 PRE-TEST DiRECT_0397.L48 PRE-TEST DiRECT_0398.LA8 PRE-TEST DiRECT_0399.LA8 PRE-TEST DiRECT_0400.LAB PRE-TEST DiRECT_0401.LAB PRE-TEST DiRCT_0402.LA8 PRE-TEST D!RCT_0403.LA8 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 13:39:12 13:39:41 13:40:10 13:40:39 13:41:08 13:41:37 13:42:06 13:42:35 13:43:04 13:43:33 13:44:02 13:44:31 13:45:00 13:45:29 13:45:58 13:46:27 13:46:56 13:47:25 13:47:54 13:48:23 13:48:52 13:49:21 13:49:50 13:50:19 13:50:49 13:51:18 13:51:47 13:52:16 13:52:45 13:53:14 13:53:43 13:54:12 13:54:41 13:55:10 13:55:39 13:56:08 13:56:37 13:57:06 13:57:35 13:58:04 13:58:33 13:5902 13:59:31 14:00:00 14:00:29 14:00:58 14:01:27 14:01:56 14:02:25 14:02:54 14:03:23 14:03:53 14:04:22 14:04:51 14:05:20 14:05:49 14:06:18 14:06:47 14:07:16 14:07:45 14:08:14 14:08:43 14:09:12 14:09:41 14:10:10 14:10:39 14:11:08 14:11:37 14:12:06 14:12:35 14:13:04 14:13:33 14:14:02 14:14:31 14:1500 14:15:29 14:15:58 14:16:27 14:16:57 14:17:26 14:17:55 14:18:24 14:18:53 14:19:22 14:19:51 14:20:20 14:20:49 14:21:18 14:21:47 14:22:16 14:22:45 14:23:14 14:23:43 14:24:12 14:24:41 14:25:10 14:25:39 14:2608 14:26:37 14:2706 14:27:35 14:28:04 14:28:33 14:2902 14:29:31 14:30:01 14:30:30 14:30:59 14:31:28 14:31:57 14:32:26 14:32:55 14:33:24 14:33:53 14:34:22 14:34:51 14:35:20 14:35:49 14:36:18 14:36:47 14:37:16 14:37:45 14:38:14 14:38:43 7.692 7.630 7.637 7.613 7.627 7.684 7.679 7.707 7.667 7.697 7.703 7.707 7.744 7.720 7.724 7.722 7.693 7.629 7.641 7.634 7.632 7.627 7.638 7.663 7.685 7.653 7.673 7.687 7.709 7.713 7.704 7.712 7.723 7.715 7.706 7.668 7.645 7.619 7.672 7.671 7.652 7.651 7.666 7.633 7.612 7.623 7.629 7.616 7.649 7.633 7.656 7.710 7.692 7.723 7.725 7.711 7.714 7.754 7.711 7.646 7.685 7.683 7.683 7.661 7.631 7.681 7.616 7.618 7.593 7.642 7.644 7.629 7.643 7.625 7.630 7.702 7.719 7.709 7.708 7.694 7.722 7.706 7.684 7.684 7.684 7.679 7.700 7.714 7.718 7.674 7.689 7.710 7.722 7.758 7.731 7.766 7.698 7.730 7.748 7.683 7.672 7.706 7.684 7.692 7.723 7.791 7.768 7.746 7.782 7.770 7.740 7.755 7.713 7.747 7.715 7.737 7.712 7.722 7.695 7.682 7.678 7.662 7.651 SF6 (ppm) 8.540 8.546 8.547 8.549 8.553 8.557 8.555 8.560 8.561 8.564 8.564 8.564 8.570 8.570 8.573 8.575 8.579 8.581 8.576 8.577 8.576 8.578 8.581 8.582 8.585 8.580 8.590 8.584 8.590 8.585 8.589 8.596 8.599 8.598 8.600 8.596 8.601 8.603 8.605 8.605 8.604 8.606 8.605 8.613 8.612 8.610 8.611 8.616 8.622 8.615 8.617 8.617 8.621 8.624 8.631 8.635 8.635 8.640 8.638 8.644 8.646 8.644 8.647 8.643 8.650 8.647 8.649 8.650 8.652 8.656 8.656 8.656 8.657 8.655 8.663 8.665 8.663 8.665 8.665 8.667 8.674 8.672 8.672 8.676 8.681 8.677 8.683 8.676 8.680 8.679 8.679 8.681 8.685 8.684 8.692 8.692 8.697 8.692 8.694 8.697 8.703 8.697 8.700 8.709 8.706 8.709 8.710 8.712 8.717 8.717 8.721 8.717 8.719 8.723 8.728 8.731 8.736 8.737 8.741 8.737 8.741 8.745 8.740 8.742 SiF4 (ppm) 0.089 0.089 0.091 0.090 0.088 0.087 0.086 0.084 0.085 0.083 0.083 0.082 0.082 0.081 0.081 0.080 0.080 0.078 0.077 0.076 0.074 0.075 0.075 0.074 0.074 0.072 0.072 0.071 0.070 0.069 0.070 0.069 0.070 0.069 0.069 0.069 0.066 0.066 0.066 0.065 0.065 0.065 0.065 0.066 0.064 0.064 0.063 0.063 0.062 0.061 0.060 0.060 0.061 0.062 0.059 0.059 0.058 0.059 0.058 0.058 0.058 0.057 0.056 0.057 0.056 0.057 0.055 0.056 0.055 0.054 0.055 0.054 0.053 0.053 0.053 0.052 0.053 0.053 0.052 0.053 0.052 0.052 0.051 0.052 0.051 0.050 0.051 0.052 0.053 0.052 0.051 0.051 0.051 0.049 0.049 0.049 0.049 0.049 0.049 0.048 0.050 0.047 0.048 0.047 0.048 0.046 0.046 0.046 0.047 0.047 0.046 0.047 0.046 0.046 0.045 0.043 0.045 0.044 0.046 0.044 0.044 0.043 0.044 0.044 16.194 16.194 16.215 16.140 16.182 16.221 16.223 16.210 16.059 16.047 16.263 16.332 16.281 16.371 16.367 16.549 16.551 16.484 16.315 16.399 16.336 16.559 16.394 16.332 16.349 16.421 16.376 16.689 16.501 16.430 16.560 16.771 16.713 16.800 16.869 16.738 16.651 16.789 16.872 17.108 16.879 16.956 16.927 17.007 16.944 17.042 17.174 16.832 16.698 16.915 16.985 17.014 16.888 16.699 16.562 17.095 16.877 16.938 17.277 17.041 17.206 16.940 17.039 17.136 17.259 17.231 17.233 17.236 17.363 17.274 17.293 17.225 17.220 17.449 17.474 17.354 17.403 17.349 17.429 17.566 17.388 17.437 17.347 17.545 17.629 17.715 17.570 17.535 17.703 17.640 17.662 17.404 17.823 17.432 17.644 17.587 17.682 17.907 17.890 17.819 17.818 17.774 17.616 17.888 17.750 17.955 17.699 17.807 17.818 17.706 17.705 18.080 18.055 17.946 17.929 18.016 17.847 18.075 17.855 17.796 18.046 18.155 18.015 18.173 C02 (%) 0.002 0.002 0.003 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.003 0.003 0.003 0.002 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.003 0.004 0.004 0.003 0.004 0.004 0.003 0.004 0.004 0.003 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.003 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.005 0.004 0.004 0.004 0.004 0.004 0.004 0.005 0.004 0.004 0.004 0.004 0.005 0.004 0.004 0.005 0.005 0.005 0.004 0.005 0.005 0.004 0.004 0.004 0.005 0.004 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 CH4 (ppm) 2.075 1.530 1.548 1.692 1.760 1.650 1.623 1.715 1.676 1.688 2.026 1.562 1.819 2.210 1.926 2.046 2.054 2.152 1.874 1.527 1.688 1.956 1.577 1.643 1.778 1.722 1.820 1.782 1.847 1.994 2.026 1.899 2.016 2.122 2.282 2.087 2.503 2.207 2.247 2.204 2.286 2.155 2.393 2.141 2.036 1.776 1.817 2.067 1.851 1.525 1.784 1.755 1.748 1.713 1.938 1.940 2.063 1.979 1.957 2.252 2.206 1.947 2.039 2.324 2.397 2.297 1.995 2.208 2.214 2.195 2.299 2.085 2.337 2.122 2.092 2.052 2.166 1.895 2.046 2.153 2.160 2.144 2.377 2.334 2.103 2.114 2.332 2.424 2.252 1.972 2.386 2.369 2.474 2.486 2.211 1.971 2.212 2.379 2.369 2.405 2.451 2.351 2.245 2.526 2.365 2.303 2.293 2.295 2.256 2.282 2.317 2.442 2.480 2.212 2.267 2.075 2.279 2.245 2.319 2.396 2.303 2.436 2.112 2.209 NH3 (ppm) 44.233 42.160 40.348 38.728 37.207 35.825 34.579 33.437 32.377 31.383 30.423 29.489 28.698 27.931 27.232 26.483 25.815 25.164 24.570 24.040 23.562 23.104 22.695 22.299 21.929 21.527 21.184 20.827 20.537 20.168 19.890 19.652 19.366 19.124 18.862 18.619 18.361 18.132 17.889 17.644 17.468 17.277 17.108 16.939 16.782 16.581 16.392 16.269 16.152 16.025 15.875 15.707 15.629 15.494 15.326 15.163 15.017 14.920 14.786 14.681 14.527 14.380 14.300 14.175 14.093 13.972 13.900 13.784 13.692 13.649 13.519 13.440 13.387 13.290 13.232 13.171 13.101 13.057 12.968 12.903 12.849 12.742 12.639 12.607 12.560 12.515 12.450 12.355 12.292 12.270 12.189 12.146 12.116 12.023 11.983 11.912 11.872 11.830 11.733 11.723 11.702 11.605 11.576 11.574 11.479 11.469 11.431 11.409 11.349 11.313 11.286 11.301 11.230 11.212 11.107 11.086 10.998 10.955 10.956 10.892 10.864 10.834 10.805 10.770 -0.704 -0.669 -0.646 -0.647 -0.626 -0.620 -0.627 -0.621 -0.602 -0.577 -0.612 -0.586 -0.576 -0.525 -0.565 -0.562 -0.513 -0.521 -0.495 -0.455 -0.540 -0.478 -0.489 -0.436 -0.426 -0.522 -0.497 -0.420 -0.467 -0.471 -0.462 -0.440 -0.438 -0.479 -0.442 -0.479 -0.436 -0.470 -0.421 -0.410 -0.444 -0.393 -0.393 -0.414 -0.388 -0.350 -0.389 -0.385 -0.380 -0.368 -0.386 -0.374 -0.349 -0.389 -0.349 -0.391 -0.343 -0.391 -0.388 -0.335 -0.335 -0.407 -0.360 -0.317 -0.350 -0.338 -0.293 -0.284 -0.334 -0.305 -0.350 -0.317 -0.304 -0.330 -0.275 -0.302 -0.352 -0.207 -0.291 -0.279 -0.282 -0.298 -0.320 -0.273 -0.290 -0.244 -0.320 -0.317 -0.323 -0.266 -0.320 -0.277 -0.286 -0.250 -0.325 -0.293 -0.286 -0.287 -0.291 -0.245 -0.229 -0.213 -0.276 -0.254 -0.226 -0.257 -0.319 -0.282 -0.289 -0.261 -0.251 -0.266 -0.296 -0.193 -0.272 -0.255 -0.251 -0.231 -0.261 -0.234 -0.207 -0.302 -0.243 -0.253 N20 (ppm) -0.021 -0.022 -0.025 -0.019 -0.038 -0.024 -0.026 -0.038 -0.037 -0.022 -0.028 -0.020 -0.018 -0.022 -0.025 -0.029 -0.023 -0.028 -0.029 -0.027 -0.027 -0.035 -0.024 -0.018 -0.018 -0.021 -0.024 -0.031 -0.015 -0.020 -0.016 -0.013 -0.029 -0.021 -0.015 -0.021 -0.015 -0.022 -0.025 -0.017 -0.026 -0.022 -0.022 -0.026 -0.021 -0.026 -0.017 -0.022 -0.011 -0.015 -0.021 -0.020 -0.005 -0.013 -0.007 -0.008 -0.011 -0.023 -0.012 -0.013 -0.017 -0.019 -0.013 -0.014 -0.014 -0.011 -0.024 -0.017 -0.011 -0.009 -0.014 -0.033 -0.024 -0.028 -0.022 -0.005 -0.021 -0.019 -0.002 -0.010 -0.008 -0.019 -0.012 -0.019 -0.010 -0.019 -0.024 -0.017 -0.015 -0.010 -0.007 -0.005 -0.010 -0.017 -0.014 -0.015 -0.008 -0.008 -0.012 -0.008 -0.015 -0.016 -0.015 -0.010 -0.018 -0.015 -0.006 -0.009 -0.010 -0.017 -0.009 -0.012 -0.012 -0.019 -0.014 -0.003 -0.013 -0.015 -0.021 -0.007 -0.013 -0.012 -0.020 -0.011 N02 (ppm) H20 (%) 0.267 0.269 0.263 0.255 0.265 0.269 0.257 0.264 0.271 0.258 0.272 0.258 0.262 0.263 0.277 0.259 0.258 0.259 0.256 0.266 0.256 0.257 0.256 0.260 0.260 0.263 0.264 0.268 0.264 0.257 0.263 0.263 0.259 0.264 0.264 0.257 0.257 0.264 0.254 0.253 0.254 0.255 0.260 0.269 0.261 0.261 0.258 0.260 0.263 0.270 0.274 0.274 0.273 0.273 0.269 0.268 0.278 0.281 0.271 0.278 0.278 0.271 0.276 0.274 0.277 0.278 0.282 0.270 0.283 0.288 0.275 0.284 0.294 0.275 0.293 0.290 0.286 0.284 0.282 0.286 0.289 0.293 0.302 0.289 0.293 0.290 0.292 0.304 0.297 0.298 0.300 0.299 0.303 0.304 0.309 0.306 0.298 0.293 0.302 0.304 0.316 0.309 0.314 0.311 0.320 0.315 0.319 0.316 0.316 0.323 0.304 0.311 0.314 0.319 0.322 0.325 0.326 0.328 0.332 0.319 0.330 0.333 0.333 0.333 Temp r c) 149.430 149.430 149.430 149.532 149.532 149.532 149.430 149.430 149.532 149.430 149.430 149.328 149.328 149.430 149.430 149.430 149.328 149.430 149.328 149.125 148.921 149.125 149.125 149.023 149.125 149.125 149.430 149.227 149.328 149.125 149.125 149.430 149.532 149.430 149.532 149.430 149.532 149.532 149.430 149.430 149.532 149.430 149.430 149.634 149.532 149.430 149.430 149.430 149.430 149.430 149.430 149.430 149.430 149.430 149.532 149.328 149.532 149.532 149.532 149.430 149.328 149.227 149.430 149.227 149.430 149.328 149.328 149.328 149.430 149.430 149.328 149.227 149.328 149.328 149.328 149.430 149.227 149.430 149.328 149.430 149.328 149.430 149.430 149.430 149.430 149.328 149.430 149.227 149.227 149.227 149.125 149.125 149.328 149.227 149.227 149.125 149.227 149.023 149.125 149.125 149.125 148.921 149.125 149.227 149.125 149.125 149.125 149.227 149.125 149.125 149.328 149.125 149.227 149.023 149.125 149.125 149.125 149.125 149.125 149.023 149.023 149.125 148.820 149.023 t.010 t.010 1.010 t.010 t.010 t.010 t.010 t.010 t.Oll t.010 t.Oll t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.Oll t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.Oll t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.010 t.009 t.010 t.009 t.010 t.010 t.009 t.010 t.010 t.009 t.010 t.009 t.009 t.010 t.009 t.009 t.010 t.010 t.009 t.010 t.009 t.010 t.010 t.009 t.009 t.009 t.009 t.010 t.009 t.009 t.009 t.009 t.009 t.009 t.009 t.009 t.009 t.009 t.009 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00125 PCS Phosphates Raw FTIR Data Spectrum PRE-TEST DiRCT_0404.LAB PRE-TEST DiRECT_0405.LAB PRE-TEST DfRECT_0406.LA8 PRE-TEST D!RECT_0407.LAB PRE-TEST DiRECT_0408.LAB PRE-TEST DiRECT_0409.LAB PRE-TEST DiRECT_0410.LAB PRE-TEST D!RECT_0411.LAB PRE-TEST D!RECT_0412.LAB PRE-TEST D!RECT_041S.LAB PRE-TEST D!RECT_0414.LAB PRE-TEST DiRECT_0415.LAB PRE-TEST D!RECT_0416.LAB PRE-TEST DiRECT_0417.LAB PRE-TEST D!RECT_0418.LAB PRE-TEST DiRECT_0419.LA8 PRE-TEST DiRECT_0420.LAB PRE-TEST D(RECT_0421.LAB PRE-TEST DiRECT_0422.LA8 PRE-TEST DiRECT_042S.LAB PRE-TEST DiRCT_0424.LA8 PRE-TEST DiRECT_0425.LAB PRE-TEST DIRECT_0426.LAB PRE-TEST D!RECT_0427.LAB PRE-TEST DiRECT_0428.LAB PRE-TEST DiRECT_0429.LA8 PRE-TEST DiRECT_0430.LAB PRE-TEST D!RECT_0431.LA8 PRE-TEST D!RECT_0432.LAB PRE-TEST D!RECT_0433.LAB PRE-TEST D!RECT_0434.LA8 PRE-TEST DiRECT_0435.LA8 PRE-TEST D!RECT_0436.LAB PRE-TEST DiRECT_0437.LAB PRE-TEST D!RECT_0438.LAB PRE-TEST DiRECT_0439.LA8 PRE-TEST DiRECT_0440.LAB PRE-TEST DiRECT_0441.LAB PRE-TEST DiRECT_0442.LAB PRE-TEST DiRECT_0443.LAB PRE-TEST DiRCT_0444.LA8 PRE-TEST DiRECT_0445.LAB PRE-TEST DfRECT_0446.LA8 PRE-TEST D!RECT_0447.LAB PRE-TEST DiRECT_0448.LA8 PRE-TEST DiRECT_0449.LA8 PRE-TEST DiRECT_0450.LAB PRE-TEST D!RECT_0451.LA8 PRE-TEST D!RECT_0452.LAB PRE-TEST D!RECT_0453.LAB PRE-TEST DSRECT_0454.LA8 PRE-TEST DiRECT_0455.LAB PRE-TEST D!RECT_0456.LAB PRE-TEST DiRECT_0457.LAB PRE-TEST D!RECT_0458.LA8 PRE-TEST DiRECT_0459.LAB PRE-TEST DiRECT_0460.LAB PRE-TEST D(RECT_0461.LAB PRE-TEST DiRECT_0462.LA8 PRE-TEST D(RECT_0463.LAB PRE-TEST DiRCT_0464.LAB PRE-TEST DiRECT_0465.LAB PRE-TEST DIRECT_0466.LA8 PRE-TEST D!RECT_0467.LAB PRE-TEST DiRECT_0468.LAB PRE-TEST DiRECT_0469.LA8 PRE-TEST D!RECT_0470.LAB PRE-TEST DiRECT_0471.LA8 PRE-TEST DiRECT_0472.LAB PRE-TEST D(RECT_0473.LAB PRE-TEST DiRECT_0474.LAB PRE-TEST D5RECTJ3475.LAB PRE-TEST DiRECT_0476.LA8 PRE-TEST DiRECT_0477.LAB PRE-TEST DiRECT_0478.LAB PRE-TEST DiRECT_0479.LAB PRE-TEST DiRECT_0480.LAB PRE-TEST DiRECT_0481.LAB PRE-TEST D!R#2_0001.LAB PRE-TEST D!R#2_0002.LAB PRE-TEST DiR#2_0003.LAB PRE-TEST DiR#2_0004.LAB PRE-TEST D!R#2_0005.LA8 PRE-TEST DiR#2_0006.LAB PRE-TEST D(R#2_0007.LAB PRE-TEST DiR#2_0008.LAB PRE-TEST D(R#2_0009.LAB PRE-TEST DiR#2_0010.LAB PRE-TEST D(R#2_0011.LAB PRE-TEST DiR#2_0012.LAB PRE-TEST D!R#2_0013.LAB PRE-TEST DiR#2_0014.LA8 PRE-TEST DiR#2_0015.LA8 PRE-TEST DiR#2_0016.LAB PRE-TEST DiR#2_0017.LAB PRE-TEST D!R#2_0018.LAB PRE-TEST D! R#2_0019.LAB PRE-TEST DiR#2_0020.LA8 PRE-TEST DiR#2_0021.LAB PRE-TEST DiR#2_0022.LAB PRE-TEST D!R#2_0023.LA8 PRE-TEST D!R#2_0024.LA8 PRE-TEST DiR#2_0025.LA8 PRE-TEST DiR#2_0026.LA8 PRE-TEST D(R#2_0027.LA8 PRE-TEST DiR#2_0028.LA8 PRE-TEST DiR#2_0029.LA8 PRE-TEST DiR#2_0030.LAB PRE-TEST D(R#2_0031.LAB PRE-TEST DiR#2_0032.LAB PRE-TEST D(R#2_0033.LAB PRE-TEST DiR#2_0034.LAB PRE-TEST D!R#2_0035.LAB PRE-TEST DiR#2_0036.LA8 PRE-TEST DiR#2_0037.LA8 PRE-TEST D!R#2_0038.LA8 PRE-TEST D!R#2_0039.LAB PRE-TEST DiR#2_0040.LA8 PRE-TEST DiR#2_0041.LAB PRE-TEST DiR#2_0042.LA8 PRE-TEST DiR#2_0043.LA8 PRE-TEST DiR#2_0044.LAB PRE-TEST DiR#2_0045.LAB PRE-TEST D! R#2_0046.LA8 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 14:39:12 14:39:41 14:40:10 14:40:39 14:41:08 14:41:37 14:42:06 14:42:36 14:43:05 14:43:34 14:4403 14:44:32 14:45:01 14:45:30 14:45:59 14:46:28 14:46:57 14:47:26 14:47:55 14:48:24 14:48:53 14:49:22 14:49:51 14:50:20 14:50:49 14:51:18 14:51:47 14:52:16 14:52:45 14:53:14 14:53:43 14:54:12 14:54:41 14:55:10 14:55:40 14:5609 14:56:38 14:57:07 14:57:36 14:58:05 14:58:34 14:59:03 14:59:32 150001 15:00:30 1500:59 15:01:28 1501:57 15:02:26 15:50:38 15:51:07 15:51:37 15:52:06 15:52:35 15:53:04 15:53:33 15:54:02 15:54:31 15:55:00 15:55:29 15:55:58 15:56:27 15:56:56 15:57:25 15:57:54 15:58:23 15:58:52 15:59:21 15:59:50 1600:19 1600:48 1601:17 1603:18 1603:47 16:44:23 16:44:52 16:45:21 16:46:29 17:16:40 17:1709 17:17:38 17:18:07 17:18:36 17:19:05 17:2308 17:23:37 17:24:06 17:24:35 17:25:04 17:25:33 17:2602 17:26:31 17:2700 17:27:29 17:27:58 17:28:28 17:28:57 17:29:26 17:29:55 17:30:24 17:30:53 17:31:22 17:31:51 17:32:20 17:32:49 17:33:18 17:33:47 17:34:16 17:34:45 17:35:14 17:35:43 17:36:12 17:36:41 17:37:10 17:37:39 17:38:08 17:38:37 17:39:06 17:39:35 17:40:04 17:40:33 17:41:03 17:41:32 17:42:01 7.661 7.651 7.657 7.668 7.675 7.657 7.674 7.683 7.667 7.606 7.673 7.667 7.667 7.684 7.661 7.646 7.672 7.699 7.689 7.716 7.719 7.708 7.685 7.721 7.768 7.770 7.777 7.787 7.805 7.854 7.901 7.903 7.971 8.016 7.990 8.067 8.039 8.091 8.108 8.136 8.175 8.188 8.222 8.211 8.185 8.256 8.253 8.248 8.248 0.615 0.722 4.252 14.855 12.361 5.562 4.288 3.899 3.848 16.381 19.085 18.196 16.116 16.104 13.634 9.192 7.959 7.432 7.131 6.948 6.773 6.675 6.637 6.659 6.593 -0.017 0.011 0.004 0.007 0.006 0.009 -0.005 0.279 0.969 2.067 16.767 18.243 18.707 19.716 25.124 24.247 21.488 21.653 21.786 20.418 20.171 20.255 20.385 20.563 18.510 17.966 17.845 17.836 17.849 17.921 17.978 18.069 18.183 18.276 17.683 14.019 12.810 12.153 11.792 11.585 11.371 11.269 11.196 11.389 12.127 12.444 12.598 12.634 12.737 12.745 SF6 (ppm) 8.864 8.867 8.808 8.928 9.068 9.240 8.788 8.799 8.896 8.725 8.702 8.718 8.724 8.791 8.643 8.652 8.652 8.656 8.654 8.647 8.655 8.656 8.651 8.650 8.653 8.557 8.558 8.557 8.557 8.560 8.558 8.561 8.561 8.556 8.561 8.566 8.569 8.566 8.571 8.568 SiF4 (ppm) -0.010 -0.010 -0.011 -0.010 0.000 -0.001 0.001 0.001 0.001 0.055 0.241 0.265 0.299 0.303 0.194 0.320 0.327 0.318 0.346 0.444 0.435 0.432 0.431 0.439 0.670 0.669 0.665 0.659 0.654 0.648 0.644 0.642 0.639 0.637 0.754 1.523 1.461 1.441 1.426 1.415 1.400 1.297 1.230 1.285 1.286 1.274 1.264 1.256 18.228 18.262 17.873 17.991 18.311 18.376 18.328 18.384 18.603 18.243 18.197 18.155 18.357 18.171 18.226 18.240 18.403 18.282 18.358 18.459 18.489 18.566 18.234 18.364 18.456 18.611 18.503 18.635 18.500 18.703 18.822 18.442 18.476 18.538 18.756 18.752 18.683 18.642 18.738 18.158 18.776 18.542 18.408 18.564 18.632 18.583 18.731 18.598 18.802 -0.167 -0.086 -0.323 -0.395 -0.207 -0.561 -0.397 -0.155 -0.356 -0.531 -0.707 -0.675 -0.557 -0.280 -0.089 -0.424 -0.372 -0.522 -0.533 -0.240 -0.230 -0.492 -0.166 -0.317 -0.652 -0.193 -0.241 -0.075 -0.236 -0.082 -0.042 -0.029 -0.123 -0.079 -0.681 0.044 0.081 0.191 0.126 0.093 0.315 0.083 0.405 0.050 0.111 -0.146 0.065 -0.113 0.092 0.095 0.058 0.231 0.133 0.009 -0.030 -0.145 0.082 -0.128 -0.104 -0.013 0.143 0.077 0.168 0.063 0.042 0.264 0.109 0.140 0.080 0.091 -0.020 0.024 0.270 0.214 0.211 C02 (%) 0.005 0.005 0.005 0.005 0.005 0.004 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.006 0.006 0.006 0.005 0.005 0.005 0.006 0.006 0.006 0.005 0.005 0.000 0.000 0.000 0.000 0.001 0.000 0.001 0.001 0.001 0.000 0.001 0.001 0.000 0.001 0.001 0.000 0.000 0.000 0.000 0.001 0.000 0.000 0.001 -0.001 0.000 0.002 0.002 0.002 0.002 0.000 0.000 0.000 0.006 0.034 0.072 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -0.001 -0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -0.001 0.000 0.000 -0.001 0.000 -0.001 0.000 -0.001 -0.001 -0.001 -0.001 -0.001 0.000 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 CH4 (ppm) 2.488 2.288 2.500 2.443 2.464 2.502 2.264 2.522 2.504 2.376 2.517 2.718 2.497 2.500 2.369 2.222 2.337 2.458 2.635 2.438 2.591 2.302 2.480 2.652 2.503 2.288 2.343 2.556 2.753 2.605 2.574 2.450 2.353 2.594 2.473 2.456 2.615 2.408 2.415 2.852 2.592 2.706 2.533 2.817 2.696 2.810 2.758 2.745 2.795 -0.113 -0.602 -0.501 -0.847 -1.003 -1.209 -0.812 -0.956 -0.589 -0.709 -0.807 -0.653 -0.785 -0.650 -0.418 -0.508 -0.656 -0.679 -0.930 -0.737 -0.584 -0.871 -0.570 -0.424 -0.518 1.849 1.556 1.607 1.609 0.063 -0.001 0.022 0.219 1.008 1.967 -0.270 -0.348 -0.383 -0.210 -0.305 -0.181 -0.271 -0.333 -0.363 -0.416 -0.384 -0.389 -0.384 -0.466 -0.410 -0.487 -0.622 -0.413 -0.495 -0.494 -0.709 -0.496 -0.614 -0.549 -0.411 -0.581 -0.388 -0.301 -0.285 -0.304 -0.614 -0.515 -0.554 -0.632 -0.521 -0.494 -0.377 -0.419 -0.751 -0.590 NH3 (ppm) 10.783 10.713 10.696 10.690 10.661 10.598 10.619 10.569 10.567 10.533 10.529 10.476 10.477 10.442 10.399 10.400 10.433 10.424 10.426 10.417 10.380 10.372 10.327 10.351 10.365 10.408 10.388 10.384 10.404 10.441 10.460 10.447 10.524 10.535 10.588 10.615 10.606 10.616 10.577 10.634 10.641 10.638 10.622 10.660 10.659 10.618 10.638 10.618 10.603 -0.703 -0.768 -1.474 -2.539 -2.016 -1.126 -1.080 -1.071 -1.159 -2.460 -2.586 -2.315 -2.098 -2.078 -1.600 -1.450 -1.375 -1.399 -1.394 -1.415 -1.467 -1.443 -1.410 -1.520 -1.469 -0.082 -0.078 -0.075 -0.047 0.002 0.003 -0.026 0.037 0.125 0.955 -2.755 -2.600 -2.653 -2.733 -3.191 -3.048 -2.741 -2.743 -2.726 -2.511 -2.504 -2.526 -2.487 -2.525 -2.340 -2.306 -2.303 -2.306 -2.290 -2.307 -2.318 -2.287 -2.301 -2.307 -2.207 -1.998 -1.970 -1.998 -1.998 -2.003 -2.023 -2.004 -1.987 -2.008 -2.013 -1.992 -2.023 -2.021 -2.024 -2.015 -0.276 -0.223 -0.187 -0.174 -0.201 -0.236 -0.214 -0.220 -0.197 -0.228 -0.223 -0.202 -0.166 -0.202 -0.194 -0.190 -0.215 -0.210 -0.201 -0.189 -0.230 -0.166 -0.170 -0.153 -0.194 -0.214 -0.224 -0.172 -0.243 -0.257 -0.216 -0.207 -0.207 -0.188 -0.233 -0.208 -0.209 -0.180 -0.175 -0.170 -0.156 -0.180 -0.235 -0.199 -0.179 -0.182 -0.240 -0.155 -0.168 -0.085 -0.077 -0.058 0.002 0.016 -0.015 -0.048 -0.026 -0.049 -0.048 0.000 -0.032 0.004 -0.125 -0.081 -0.073 -0.023 -0.058 -0.048 -0.083 -0.054 -0.077 -0.027 -0.050 -0.121 0.087 0.088 0.092 0.094 0.016 -0.003 0.000 0.006 0.026 0.187 0.043 -0.008 -0.028 0.032 -0.019 0.044 0.037 0.037 0.013 0.023 -0.003 -0.010 0.049 0.039 0.013 0.038 0.063 0.061 0.015 0.065 0.028 0.021 0.079 0.013 0.050 0.012 -0.001 0.013 0.015 0.001 0.026 0.073 0.027 0.007 0.004 -0.012 0.033 -0.002 0.066 0.005 N20 (ppm) -0.011 -0.015 -0.014 -0.015 -0.006 -0.006 -0.007 -0.005 -0.008 -0.011 -0.012 -0.013 -0.012 -0.006 -0.014 -0.014 -0.004 -0.018 -0.013 -0.017 -0.007 -0.003 0.000 -0.013 -0.002 -0.007 -0.006 -0.005 -0.004 -0.009 -0.002 0.005 -0.002 0.002 0.001 0.000 0.007 0.005 0.002 -0.003 0.001 0.002 0.007 0.006 0.000 0.008 0.006 0.006 0.015 0.002 0.011 0.005 0.015 0.003 0.002 0.024 0.002 0.017 0.010 0.000 -0.006 0.005 0.010 -0.005 -0.012 -0.005 0.009 -0.005 0.019 0.011 0.013 0.001 0.001 -0.004 0.045 0.046 0.046 0.041 -0.004 0.000 -0.008 0.050 0.296 0.630 0.001 -0.009 -0.003 -0.012 -0.015 -0.034 -0.009 -0.017 -0.010 -0.020 -0.009 -0.022 -0.027 -0.020 -0.014 -0.018 -0.011 -0.019 -0.025 -0.016 -0.025 -0.026 -0.019 -0.021 -0.008 -0.018 -0.012 -0.009 -0.023 -0.024 -0.027 -0.017 -0.019 -0.021 -0.020 -0.022 -0.022 -0.017 -0.025 -0.022 -0.053 -0.021 -0.019 0.156 0.057 -0.534 0.157 0.119 0.189 0.441 0.320 0.232 0.103 0190 0.206 0.077 0.154 0.158 0.164 0.314 0.155 0.320 0.222 0.048 0.178 0142 0.067 0.132 0.210 0.213 0.143 0.233 0.291 0.194 0.088 0.168 0.102 0.189 0.151 0.263 0.126 0.118 0.208 0.130 0.205 0.170 N02 (ppm) 0.031 -0.022 -0.002 0.062 0.119 0.761 0.031 0.004 0.012 0.071 0.101 0.068 0.017 0.040 0.049 0.034 0.058 0.037 0.023 0.051 0.054 0.016 0.047 0.067 0.070 0.034 0.037 0.043 0.056 0.065 0.049 0.034 0.044 0.062 0.071 0.087 0.043 0.078 0.044 0.063 0.098 0.081 0.078 0.082 0.090 0.073 H20 (%) 0.324 0.329 0.326 0.331 0.332 0.330 0.328 0.331 0.326 0.335 0.338 0.344 0.337 0.337 0.345 0.346 0.356 0.350 0.355 0.353 0.354 0.349 0.354 0.360 0.357 0.350 0.353 0.371 0.370 0.365 0.365 0.365 0.367 0.374 0.381 0.382 0.388 0.375 0.380 0.399 0.395 0.401 0.397 0.400 0.408 0.403 0.412 0.415 0.409 -0.013 -0.007 -0.012 -0.023 -0.020 -0.024 -0.015 -0.025 -0.025 -0.010 -0.016 -0.022 -0.012 -0.022 -0.020 -0.018 -0.011 -0.014 -0.022 -0.011 -0.019 -0.012 -0.023 -0.029 -0.026 0.194 0.200 0.198 0.237 -0.004 -0.007 0.000 0.193 0.984 2.344 -0.004 -0.015 -0.010 -0.007 -0.018 -0.010 -0.016 -0.017 -0.009 -0.013 -0.017 -0.011 -0.011 -0.015 -0.021 -0.020 -0.023 -0.016 -0.020 -0.012 -0.024 -0.022 -0.021 -0.023 -0.023 -0.021 -0.023 -0.025 -0.025 -0.026 -0.021 -0.022 -0.029 -0.028 -0.032 -0.022 -0.023 -0.023 -0.029 -0.033 Tremc)p 149.023 149.125 149.125 149.125 149.125 149.023 149.125 149.227 149.125 148.921 149.125 149.328 149.328 149.227 149.125 149.125 149.125 149.328 149.430 149.430 149.328 149.430 149.430 149.125 149.328 149.227 149.227 149.430 149.532 149.735 149.837 149.532 149.735 149.735 149.939 149.837 149.634 149.430 149.430 149.227 149.532 149.430 149.430 149.532 149.532 149.532 149.634 149.532 149.532 149.430 149.430 149.125 148.921 149.125 149.125 149.430 149.532 149.532 149.023 148.921 148.921 149.125 149.023 149.227 149.430 149.227 149.532 149.430 149.328 149.430 149.430 149.430 149.634 149.430 98.962 100.285 101.709 104.965 148.107 148.209 148.209 149.023 148.209 148.006 148.820 148.921 148.921 148.820 148.107 148.616 148.311 148.209 148.311 148.616 148.718 148.718 148.820 148.921 148.921 149.125 149.023 149.125 149.125 149.125 149.125 149.227 149.125 149.023 149.227 149.227 149.328 149.328 149.430 149.430 149.430 149.328 149.532 149.328 149.430 149.430 149.532 149.532 149.634 149.532 1.009 1.009 1.010 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.009 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.009 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.008 1.013 1.013 1.061 1.031 1.013 1.013 1.012 1.013 1.013 1.083 1.051 1.025 1.024 1.027 1.013 1.012 1.013 1.012 1.012 1.012 1.012 1.012 1.012 1.012 1.012 0.993 0.993 0.991 0.993 1.006 1.005 1.005 0.984 0.377 1.044 1.044 1.042 1.039 1.329 1.046 1.047 1.047 1.029 1.029 1.031 1.030 1.029 1.019 1.019 1.018 1.018 1.018 1.018 1.019 1.018 1.018 1.018 1.018 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.012 1.011 1.011 1.011 1.011 1.011 1.011 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00126 PCS Phosphates Raw FTIR Data Spectrum PRE-TEST DiR#2_0047.LAB PRE-TEST D!R#2_0048.LAB PRE-TEST DiR#2_0049.LAB PRE-TEST DiR#2_0050.LAB PRE-TEST DiR#2_0051.LAB PRE-TEST DiR#2_0052.LA8 PRE-TEST DiR#2_0053.LA8 PRE-TEST DiR#2_0054.LAB PRE-TEST DiR#2_0055.L4B PRE-TEST DiR#2_0056.LAB PRE-TEST DiR#2_0057.LAB PRE-TEST DiR#2_0058.LAB PRE-TEST DiR#2_0059.LA8 PRE-TEST DiR#2_0060.LA8 PRE-TEST DiR#2_0061.LAB PRE-TEST DiR#2_0062.LA8 PRE-TEST DiR#2_0063.L4B PRE-TEST DiR#2_0064.LA8 PRE-TEST DiR#2_0065.L4B PRE-TEST DiR#2_0066.LA8 PRE-TEST DiR#2_0067.LAB PRE-TEST DSR#2_0068.LA8 PRE-TEST DiR#2_0069.LAB PRE-TEST DiR#2_0070.LAB PRE-TEST DiR#2_0071.LAB PRE-TEST DiR#2_0072.LA8 PRE-TEST DiR#2_0073.LAB PRE-TEST DiR#2_0030.LA8 PRE-TEST DiR#2_0031.LAB PRE-TEST DiR#2_0032.LAB PRE-TEST DiR#2_0033.LAB PRE-TEST DiR#2_0034.LA8 PRE-TEST DiR#2_0035.L4B PRE-TEST DiR#2_0036.L4S PRE-TEST DiR#2_0037.L4B PRE-TEST DiR#2_0038.L4B PRE-TEST DiR#2_0039.LAB PRE-TEST DiR#2_0040.LAB PRE-TEST DiR#2_0041.LAB PRE-TEST DiR#2_0042.LAB PRE-TEST DiR#2_0043.L4B PRE-TEST DSR#2_0044.LAB PRE-TEST DiR#2_0045.LAB PRE-TEST DiR#2_0046.LAB PRE-TEST DiR#2_0047.LAB PRE-TEST DiR#2_0048.LAB PRE-TEST DiR#2_0049.LA8 PRE-TEST DiR#2_0050.LAB PRE-TEST DiR#2_0051.LAB PRE-TEST DiR#2_0052.LA8 PRE-TEST DiR#2_0053.LA8 PRE-TEST DiR#2_0054.LA8 PRE-TEST DiR#2_0055.LAB PRE-TEST DiR#2_0056.LA8 PRE-TEST DiR#2_0057.LAB PRE-TEST DiR#2_0058.LA8 PRE-TEST DiR#2_0059.LAB PRE-TEST DiR#2_0060.LA8 PRE-TEST DiR#2_0061.LAB PRE-TEST DiR#2_0062.LA8 PRE-TEST DiR#2_0063.LAB PRE-TEST DiR#2_0064.LA8 PRE-TEST DiR#2_0065.LAB PRE-TEST DiR#2_0066.LA8 PRE-TEST D!R#2_0067.LAB PRE-TEST DiR#2_0068.LAB PRE-TEST DiR#2_0069.LAB PRE-TEST DiR#2_0070.LAB PRE-TEST DiR#2_0071.LAB PRE-TEST D!R#2_0072.LAB PRE-TEST DiR#2_0073.L4B Pre Test QA Spikes PRE-TEST QAJXH31.LAB PRE-TEST QA_0002.LAS PRE-TEST QA_0003.L4B PRE-TEST QA_0004.LAB PRE-TEST QA_0005.L48 PRE-TEST QA_0006.LAB PRE-TEST QA_0007.LAB PRE-TEST QA_0008.LA8 PRE-TEST QA_0009.LA8 PRE-TEST QA_0010.LAB PRE-TEST QAJDOll.LAB PRE-TEST QAJ3012.L4B PRE-TEST QA_0013.LA8 PRE-TEST QA_0014.LAB PRE-TEST QA_0015.LA8 PRE-TEST QA_0016.LAB PRE-TEST QA_0017.LAB PRE-TEST QA_0018.LAB PRE-TEST QA_0019.LA8 PRE-TEST QA_0020.LAB PRE-TEST QA_0021.LAB PRE-TEST QA_0022.LA8 PRE-TEST QA_0023.LA8 PRE-TEST QA_0024.LAB PRE-TEST QA_0025.LAB PRE-TEST QA_0026.LA8 PRE-TEST QA_0027.LAB PRE-TEST QA_0028.LAB PRE-TEST QA_0029.LAB PRE-TEST QA_0030.LAB PRE-TEST QA_0031.LAB PRE-TEST QAJ3032.L48 PRE-TEST QA_0033.LA8 PRE-TEST QA_0034.LA8 PRE-TEST QA_0035.LA8 PRE-TEST QA_0036.LA8 PRE-TEST QA_0037.LAB PRE-TEST QA_0038.LAB PRE-TEST QA_0039.LA8 PRE-TEST QA_0040.LAB PRE-TEST QA_0041.LA8 PRE-TEST QA_0042.L4B PRE-TEST QA_0043.LA8 PRE-TEST QA_0044.LAB PRE-TEST QA_0045.LA8 PRE-TEST QA_0046.LAB PRE-TEST QA_0047.LAB PRE-TEST QA_0048.LAB PRE-TEST QA_0049.LA8 PRE-TEST QA_0050.LAS PRE-TEST QA_0051.L4B 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 17:42:30 17:42:59 17:43:28 17:43:57 17:44:26 17:44:55 17:45:24 17:45:53 17:46:22 17:46:51 17:47:20 17:47:49 17:48:18 17:48:47 17:49:16 17:49:45 17:50:14 17:50:43 17:51:12 17:51:41 17:52:10 17:52:39 17:5308 17:53:37 17:54:07 17:54:36 17:55:05 17:34:16 17:34:45 17:35:14 17:35:43 17:36:12 17:36:41 17:37:10 17:37:39 17:38:08 17:38:37 17:39:06 17:39:35 17:40:04 17:40:33 17:41:03 17:41:32 17:42:01 17:42:30 17:42:59 17:43:28 17:43:57 17:44:26 17:44:55 17:45:24 17:45:53 17:46:22 17:46:51 17:47:20 17:47:49 17:48:18 17:48:47 17:49:16 17:49:45 17:50:14 17:50:43 17:51:12 17:51:41 17:52:10 17:52:39 17:5308 17:53:37 17:54:07 17:54:36 17:5505 18:00:55 1801:53 18:02:51 18:03:49 18:04:47 18:05:45 1806:43 18:07:41 18:08:40 18:09:38 18:10:36 18:11:34 18:12:32 18:13:30 18:14:28 18:15:26 18:16:24 18:17:22 18:18:20 18:19:18 18:20:16 18:21:14 18:22:13 18:23:11 18:24:09 18:2507 18:26:05 18:27:03 18:28:01 18:28:59 18:29:57 18:30:55 18:31:53 18:32:51 18:33:49 18:34:48 18:35:46 18:36:44 18:37:42 18:38:40 18:4007 18:41:05 18:42:03 18:4301 18:43:59 18:44:57 18:45:55 18:46:53 18:47:52 18:48:50 18:49:48 12.812 12.761 12.808 12.788 12.829 12.937 13.096 13.118 13.183 13.183 13.291 13.324 13.377 13.368 13.363 13.400 13.439 13.478 13.592 13.619 13.610 12.626 11.739 11.530 11.502 11.481 11.443 18.276 17.683 14.019 12.810 12.153 11.792 11.585 11.371 11.269 11.196 11.389 12.127 12.444 12.598 12.634 12.737 12.745 12.812 12.761 12.808 12.788 12.829 12.937 13.096 13.118 13.183 13.183 13.291 13.324 13.377 13.368 13.363 13.400 13.439 13.478 13.592 13.619 13.610 12.626 11.739 11.530 11.502 11.481 11.443 SF6 (ppm) 8.570 8.568 8.573 8.559 8.576 8.566 8.563 8.573 8.569 8.565 8.570 8.571 8.562 8.559 8.553 8.559 8.553 8.544 8.553 8.552 8.546 8.526 8.526 8.528 8.531 8.528 8.535 8.650 8.653 8.557 8.558 8.557 8.557 8.560 8.558 8.561 8.561 8.556 8.561 8.566 8.569 8.566 8.571 8.568 8.570 8.568 8.573 8.559 8.576 8.566 8.563 8.573 8.569 8.565 8.570 8.571 8.562 8.559 8.553 8.559 8.553 8.544 8.553 8.552 8.546 8.526 8.526 8.528 8.531 8.528 8.535 1.812 1.734 1.549 1.355 1.190 1.050 0.904 0.825 0.782 0.832 0.849 0.817 0.755 0.855 0.761 0.709 0.621 0.661 0.672 0.618 0.578 0.564 0.508 0.477 0.446 0.828 1.100 1.145 1.193 1.209 1.321 1.367 1.325 1.307 1.305 1.298 1.310 1.372 1.416 1.446 1.365 1.335 1.296 1.293 1.340 1.399 1.425 1.449 1.354 1.300 1.293 0.044 0.043 0.045 0.045 0.055 0.041 0.046 0.044 0.039 0.047 0.053 0.041 0.050 0.043 0.048 0.049 0.038 0.047 0.041 0.046 0.045 0.044 0.047 0.043 0.049 0.556 0.667 0.659 0.648 0.647 0.664 0.671 0.658 0.657 0.645 0.649 0.648 0.661 0.675 0.677 0.644 0.635 0.633 0.632 0.652 0.669 0.674 0.669 0.645 0.644 0.642 SiF4 (ppm) 1.246 1.232 1.217 1.193 1.181 1.181 1.182 1.178 1.163 1.148 1.141 1.140 1.125 1.099 1.079 1.062 1.048 1.037 1.034 1.023 1.014 1.019 1.046 1.066 1.082 1.092 1.099 0.637 0.754 1.499 1.523 1.488 1.461 1.441 1.426 1.415 1.400 1.297 1.230 1.285 1.286 1.274 1.264 1.256 1.246 1.232 1.217 1.193 1.181 1.181 1.182 1.178 1.163 1.148 1.141 1.140 1.125 1.099 1.079 1.062 1.048 1.037 1.034 1.023 1.014 1.019 1.046 1.066 1.082 1.092 1.099 0.067 -0.082 0.324 0.064 0.064 0.185 -0.165 0.024 0.075 0.226 0.165 -0.094 0.330 -0.011 0.114 0.008 0.024 -0.069 -0.052 0.067 0.157 0.206 0.192 0.376 0.344 0.172 0.433 -0.104 -0.013 0.143 0.077 0.168 0.063 0.042 0.264 0.109 0.140 0.080 0.091 -0.020 0.024 0.270 0.214 0.211 0.067 -0.082 0.324 0.064 0.064 0.185 -0.165 0.024 0.075 0.226 0.165 -0.094 0.330 -0.011 0.114 0.008 0.024 -0.069 -0.052 0.067 0.157 0.206 0.192 0.376 0.344 0.172 0.433 C02 (%) -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 0.000 -0.001 -0.001 -0.001 -0.001 -0.001 0.000 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 0.000 -0.001 0.000 -0.001 -0.001 -0.001 -0.001 -0.001 0.000 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 0.000 -0.001 -0.001 -0.001 -0.001 -0.001 0.000 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 -0.001 0.030 0.022 0.032 0.032 0.031 0.031 0.034 0.030 0.035 0.036 0.030 0.032 0.037 0.031 0.036 0.035 0.034 0.036 0.035 0.035 0.040 0.040 0.034 0.036 0.036 0.036 0.038 0.033 0.035 0.037 0.027 0.035 0.039 0.036 0.032 0.040 0.032 0.035 0.031 0.035 0.032 0.032 0.040 0.035 0.037 0.035 0.037 0.037 0.033 0.035 0.030 138.604 125.911 156.031 119.239 129.076 123.192 154.664 127.574 114.771 125.652 166.035 107.906 131.097 122.485 123.107 120.248 110.469 140.980 107.500 129.897 130.668 126.680 102.075 108.717 129.231 109.389 119.811 116.051 106.459 121.749 114.221 106.622 114.306 153.536 122.232 107.152 113.312 119.599 103.958 126.409 127.200 119.625 132.416 122.561 116.552 90.999 102.358 99.293 90.555 94.368 103.121 4.900 4.695 4.902 4.551 4.652 4.625 5.032 4.869 4.638 4.667 4.930 4.515 4.753 4.642 4.657 4.730 4.467 4.802 4.509 4.741 4.703 4.678 4.708 4.575 4.937 4.374 4.236 4.403 4.294 4.402 4.444 4.133 4.490 4.479 4.167 4.247 4.396 4.387 4.164 4.706 4.338 4.239 4.408 4.425 4.314 4.296 4.573 4.428 4.352 4.281 4.470 CH4 (ppm) -0.417 -0.463 -0.524 -0.664 -0.505 -0.621 -0.259 -0.688 -0.639 -0.740 -0.813 -0.612 -0.662 -0.718 -0.440 -0.536 -0.720 -0.506 -0.539 -0.649 -0.830 -0.759 -0.717 -0.512 -0.198 -0.425 -0.415 -0.549 -0.411 -0.581 -0.388 -0.301 -0.285 -0.304 -0.614 -0.515 -0.554 -0.632 -0.521 -0.494 -0.377 -0.419 -0.751 -0.590 -0.417 -0.463 -0.524 -0.664 -0.505 -0.621 -0.259 -0.688 -0.639 -0.740 -0.813 -0.612 -0.662 -0.718 -0.440 -0.536 -0.720 -0.506 -0.539 -0.649 -0.830 -0.759 -0.717 -0.512 -0.198 -0.425 -0.415 NH3 (ppm) -2.027 -2.024 -2.029 -2.011 -2.024 -2.024 -2.016 -2.000 -2.026 -2.011 -2.022 -2.011 -1.995 -2.027 -2.007 -2.020 -2.015 -2.036 -2.002 -2.032 -1.963 -1.888 -1.791 -1.766 -1.744 -1.689 -1.663 -2.307 -2.207 -1.998 -1.970 -1.998 -1.998 -2.003 -2.023 -2.004 -1.987 -2.008 -2.013 -1.992 -2.023 -2.021 -2.024 -2.015 -2.027 -2.024 -2.029 -2.011 -2.024 -2.024 -2.016 -2.000 -2.026 -2.011 -2.022 -2.011 -1.995 -2.027 -2.007 -2.020 -2.015 -2.036 -2.002 -2.032 -1.963 -1.888 -1.791 -1.766 -1.744 -1.689 -1.663 0.021 0.010 -0.013 0.001 0.041 0.054 -0.004 0.026 0.030 0.004 0.006 0.004 -0.030 0.033 -0.028 0.019 0.003 0.000 -0.013 -0.020 0.026 0.003 0.059 -0.004 0.021 0.013 0.072 0.013 0.050 0.012 -0.001 0.013 0.015 0.001 0.026 0.073 0.027 0.007 0.004 -0.012 0.033 -0.002 0.066 0.005 0.021 0.010 -0.013 0.001 0.041 0.054 -0.004 0.026 0.030 0.004 0.006 0.004 -0.030 0.033 -0.028 0.019 0.003 0.000 -0.013 -0.020 0.026 0.003 0.059 -0.004 0.021 0.013 0.072 8.565 7.941 8.209 8.588 8.968 7.292 8.125 8.129 7.876 8.067 8.182 7.477 7.587 7.593 8.090 8.49 1 6.974 7.788 7.096 7.967 7.895 7.367 8.151 7.592 7.617 6.573 6.991 7.327 6.479 6.662 6.332 7.42 1 6.891 6.675 6.304 6.284 7.006 6.644 6.878 7.193 7.305 6.813 7.668 6.156 6.872 7.537 8.008 9.327 8.110 10.105 8.065 1.029 1.368 1.357 1.267 1.166 0.982 0.824 0.553 0.611 0.677 0.828 0.813 0.996 1.029 0.828 0.600 0.690 0.908 1.008 0.875 0.965 0.779 0.462 0.450 0.528 0.504 0.529 0.346 0.357 0.386 0.210 0.135 0.356 0.238 0.451 0.316 0.355 0.172 0.154 0.108 0.155 0.280 0.201 0.346 0.195 0.068 -0.038 -0.202 0.020 -0.029 0.160 -0.660 -0.641 -0.657 -0.626 -0.673 -0.605 -0.635 -0.638 -0.642 -0.652 -0.657 -0.635 -0.689 -0.665 -0.645 -0.665 -0.650 -0.671 -0.647 -0.678 -0.657 -0.638 -0.636 -0.632 -0.612 -0.592 -0.598 -0.627 -0.586 -0.594 -0.581 -0.606 -0.627 -0.619 -0.590 -0.541 -0.602 -0.583 -0.588 -0.617 -0.580 -0.628 -0.627 -0.573 -0.569 -0.560 -0.585 -0.638 -0.63 1 -0.608 -0.638 N20 (ppm) -0.022 -0.027 -0.021 -0.028 -0.023 -0.021 -0.016 -0.021 -0.017 -0.032 -0.036 -0.022 -0.030 -0.025 -0.022 -0.024 -0.032 -0.030 -0.021 -0.023 -0.027 -0.022 -0.019 -0.026 -0.026 -0.027 -0.032 -0.021 -0.008 -0.018 -0.012 -0.009 -0.023 -0.024 -0.027 -0.017 -0.019 -0.021 -0.020 -0.022 -0.022 -0.017 -0.025 -0.022 -0.022 -0.027 -0.021 -0.028 -0.023 -0.021 -0.016 -0.021 -0.017 -0.032 -0.036 -0.022 -0.030 -0.025 -0.022 -0.024 -0.032 -0.030 -0.021 -0.023 -0.027 -0.022 -0.019 -0.026 -0.026 -0.027 -0.032 8.346 8.257 7.862 7.433 7.596 7.619 8.363 8.642 8.502 7.839 8.350 7.605 7.691 7.781 8.666 8.376 8.546 7.779 7.563 6.950 7.797 7.734 8.004 7.946 8.248 7.602 7.266 7.386 7.176 7.470 7.701 7.704 7.465 7.913 7.582 7.188 7.096 7.649 7.347 7.786 7.643 7.524 7.431 7.395 7.700 8.525 8.198 8.539 8.002 7.542 7.565 0.192 0.230 0.136 0.075 0.177 0.175 0.210 0.200 0.133 0.223 0.163 0.229 0.186 0.254 0.213 0.175 0.239 0.219 0.145 0.085 0.144 0.109 0.291 0.376 0.474 0.589 0.525 0.213 0.143 0.233 0.291 0.194 0.088 0.168 0.102 0.189 0.151 0.263 0.126 0.118 0.208 0.130 0.205 0.170 0.192 0.230 0.136 0.075 0.177 0.175 0.210 0.200 0.133 0.223 0.163 0.229 0.186 0.254 0.213 0.175 0.239 0.219 0.145 0.085 0.144 0.109 0.291 0.376 0.474 0.589 0.525 52.034 51.666 46.048 52.119 50.904 51.127 43.020 46.675 52.156 54.609 48.230 54.169 51.194 49.910 47.816 52.640 54.987 51.945 54.444 50.590 49.493 48.142 53.205 53.426 53.250 49.766 46.765 46.945 50.736 44.496 46.479 51.851 50.340 46.141 46.630 51.554 48.803 46.324 49.930 46.910 48.045 50.013 46.091 46.119 47.037 46.211 46.428 49.310 52.745 54.013 48.961 N02 (ppm) 0.068 0.077 0.044 0.063 0.076 0.038 0.014 0.036 0.084 0.051 0.059 0.080 0.059 0.058 0.044 0.085 0.093 0.086 0.090 0.076 0.073 0.076 0.054 0.090 0.105 0.065 0.063 0.065 0.049 0.034 0.044 0.062 0.071 0.087 0.043 0.078 0.044 0.063 0.098 0.081 0.078 0.082 0.090 0.073 0.068 0.077 0.044 0.063 0.076 0.038 0.014 0.036 0.084 0.051 0.059 0.080 0.059 0.058 0.044 0.085 0.093 0.086 0.090 0.076 0.073 0.076 0.054 0.090 0.105 0.065 0.063 H20 (%) -0.019 -0.028 -0.023 -0.027 -0.025 -0.030 -0.025 -0.033 -0.033 -0.037 -0.030 -0.027 -0.024 -0.026 -0.032 -0.033 -0.036 -0.038 -0.022 -0.032 -0.035 -0.037 -0.034 -0.031 -0.027 -0.031 -0.024 -0.023 -0.023 -0.021 -0.023 -0.025 -0.025 -0.026 -0.021 -0.022 -0.029 -0.028 -0.032 -0.022 -0.023 -0.023 -0.029 -0.033 -0.019 -0.028 -0.023 -0.027 -0.025 -0.030 -0.025 -0.033 -0.033 -0.037 -0.030 -0.027 -0.024 -0.026 -0.032 -0.033 -0.036 -0.038 -0.022 -0.032 -0.035 -0.037 -0.034 -0.031 -0.027 -0.031 -0.024 Tremc)p 149.532 149.532 149.532 149.328 149.532 149.328 149.532 149.430 149.430 149.430 149.634 149.532 149.430 149.227 149.430 149.430 149.328 149.125 149.430 149.328 149.227 149.430 149.532 149.532 149.532 149.430 149.532 149.023 149.227 149.227 149.328 149.328 149.430 149.430 149.430 149.328 149.532 149.328 149.430 149.430 149.532 149.532 149.634 149.532 149.532 149.532 149.532 149.328 149.532 149.328 149.532 149.430 149.430 149.430 149.634 149.532 149.430 149.227 149.430 149.430 149.328 149.125 149.430 149.328 149.227 149.430 149.532 149.532 149.532 149.430 149.532 25.175 28.153 29.191 29.349 29.214 27.497 24.923 23.345 24.382 27.524 28.574 28.932 29.039 28.528 26.021 24.339 24.270 27.789 28.796 29.375 29.311 27.653 25.255 23.313 25.538 27.526 27.327 27.049 27.584 25.746 22.905 23.340 26.691 27.963 27.802 27.553 27.238 24.213 22.085 23.024 26.916 27.921 27.811 27.275 24.714 22.363 21.157 23.083 26.426 27.724 27.744 148.311 148.107 148.209 148.311 148.209 148.514 148.311 148.311 148.209 148.311 148.311 148.209 148.107 148.107 148.107 148.107 148.209 148.209 148.107 148.107 148.107 148.209 148.311 148.514 148.413 148.209 148.209 148.311 148.413 148.514 148.311 148.209 148.209 148.209 148.107 148.311 148.107 148.311 148.209 148.311 148.413 148.311 148.311 148.311 148.311 148.311 148.311 148.311 148.311 148.209 148.311 1.011 1.011 1.011 1.012 1.011 1.011 1.012 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.012 1.011 1.011 1.012 1.011 1.011 1.011 1.006 1.005 1.005 1.005 1.005 1.005 1.018 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.012 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.012 1.011 1.011 1.012 1.011 1.011 1.011 1.011 1.011 1.011 1.011 1.012 1.011 1.011 1.012 1.011 1.011 1.011 1.006 1.005 1.005 1.005 1.005 1.005 0.937 0.938 0.937 0.937 0.937 0.943 0.948 0.950 0.943 0.941 0.941 0.940 0.942 0.943 0.947 0.942 0.942 0.943 0.945 0.938 0.938 0.939 0.940 0.945 0.943 0.942 0.946 0.948 0.937 0.951 0.946 0.942 0.938 0.939 0.941 0.941 0.940 0.945 0.947 0.941 0.943 0.945 0.941 0.946 0.942 0.943 0.949 0.944 0.941 0.937 0.941 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00127 PCS Phosphates Raw FTIR Data Spectrum PRE-TEST QA_0052.LAB PRE-TEST QA_0053.LA8 PRE-TEST QA_0054.LA8 PRE-TEST QA_0055.LAB PRE-TEST QA_0056.LAB PRE-TEST QAJ3057.LAB PRE-TEST QA_0058.LAB PRE-TEST QA_0059.LA8 PRE-TEST QA_0060.LAB PRE-TEST QA_0061.LA8 PRE-TEST QA_0062.LAB PRE-TEST QA_006B.LAB PRE-TEST QA_0064.1AB PRE-TEST QA_0065.1AB PRE-TEST QA_0066.LAB PRE-TEST QA_0067.LAB PRE-TEST QA_0068.LAB PRE-TEST QA_0069.LA8 PRE-TEST QA_0070.LAB PRE-TEST QA_0071.LAB PRE-TEST QA_0072.LA8 PRE-TEST QA_007B.LAB PRE-TEST QA_0074.1AB PRE-TEST QA_0075.LAB PRE-TEST QA_0076.LAB PRE-TEST QA_0077.LAB PRE-TEST QA_0078.LAB PRE-TEST QA_0079.LAB PRE-TEST QA_0080.LAB PRE-TEST QA_0081.LAB PRE-TEST QA_0082.LAB PRE-TEST QA_0083.LAB PRE-TEST QA_0084.LAB PRE-TEST QA_0085.1AB PRE-TEST QA_0086.LAB PRE-TEST QA_0087.LAB PRE-TEST QA_0088.LA8 PRE-TEST QA_0089.LAB PRE-TEST QA_0090.LAB PRE-TEST QA_0091.LAB PRE-TEST QA_0092.LAB PRE-TEST QA_0093.LA8 PRE-TEST QA_0094.LAB PRE-TEST QA_0095.LAB PRE-TEST QA_0096.LAB PRE-TEST QA_0097.LAS PRE-TEST QA_0098.1AB PRE-TEST QA_0099.LAB PRE-TEST QA_0100.LAB PRE-TEST QA_0101.LAB PRE-TEST QA_0102.LAB PRE-TEST QA_0103.LAB PRE-TEST QA_0104.LA8 PRE-TEST QA_0105.LAB PRE-TEST QA_0106.LAB Run #1 RUN#1_0001.LAB RUN#1_0002.LAB RUN#1_0003.LAB RUN#1_0004.LAB RUN#1_0005.LAB RUN#1_0006.LA8 RUN#1_0007.LAB RUN#1_0008.LA8 RUN#1_0009.LA8 RUN#1_0010.LA8 RUN#1_0011.LA8 Run #1 Post Test Spike RUN#1 QA_0001.LAB RUN#1 QA_0002.LAB RUN#1 QA_0003.LAB RUN#1 QA_0004.LAB RUN#1 QA_0005.LAB RUN#1 QA_0006.LAB RUN#1 QA_0007.LAB RUN#1 QA_0008.LAB RUN#1 QA_0009.LAB RUN#1 QA_0010.LAB RUN#1 QA_0011.LAB RUN#1 QA_0012.LAB RUN#1 QA_0013.LAB RUN#1 QA_0014.LAB RUN#1 QA_0015.LAB RUN#1 QA_0016.LAB RUN#1 QA_0017.LAB RUN#1 QA_0018.LAB RUN#1 QA_0019.LAB RUN#1 QA_0020.LAB RUN#1 QA_0021.LAB RUN#1 QA_0022.LAB RUN#1 QA_0023.LAB RUN#1 QA_0024.LAB RUN#1 QA_0025.LAB RUN#1 QA_0026.LAB RUN#1 QA_0027.LA8 RUN#1 QA_0028.LAB RUN#1 QA_0029.LAB RUN#1 QA_0030.LAB RUN#1 QA_0031.LAB RUN#1 QA_0032.LAB RUN#1 QA_0033.LAB Run #1 Post Test CTS RUN#1 CTS_0001.LAB RUNS1 CTS_0002.LAB RUN#1 CTS_0003.LAB RUN#1 CTS_0004.LAB Run #2 RUN#2_0001.LAB RUN#2_0002.LA8 RUN#2_0003.LA8 RUN#2_0004.LAB RUN#2_0005.LA8 RUN#2_0006.LAB RUN#2_0007.LA8 RUN#2_0008.LA8 RUN#2_0009.LA8 RUN#2_0010.LA8 RUN#2_0011.LA8 Date Time 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 4/3/2014 18:50:46 18:51:44 18:52:42 18:53:40 18:54:38 18:55:36 18:56:34 18:57:32 18:58:30 18:59:28 19:00:27 19:01:25 19:02:23 19:03:21 19:04:19 19:05:17 19:06:15 19:07:13 19:08:11 19:0909 19:10:07 19:11:05 19:12:03 19:13:01 19:14:00 19:14:58 19:15:56 19:16:54 19:17:52 19:18:50 19:19:48 19:20:46 19:21:44 19:22:42 19:23:40 19:24:38 19:25:36 19:26:35 19:27:33 19:28:31 19:29:29 19:30:27 19:31:25 19:32:23 19:33:21 19:34:19 19:35:17 19:36:15 19:37:13 19:38:11 19:39:09 19:40:08 19:41:06 19:42:04 19:43:02 HF (ppm) l 289 l 312 l 316 l 346 l 380 l 431 l 432 l 260 0 669 0 491 0 391 0 350 0 322 0 303 0 282 0 497 0 963 1 071 1 134 1 152 1 214 1 276 1 291 1 249 1 180 1 277 0 931 0 662 0 518 0 428 0 349 0 327 0 305 0 262 0 237 0 195 0 656 0 980 1 153 1 157 1 142 1 175 1 204 1 260 1 319 1 350 1 293 1 225 0 843 0 419 0 303 0 283 0 260 0 253 0 246 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 9:1001AM 9:15:12 AM 9:20OlAM 9:25:08 AM 9:30:11AM 9:3504 AM 9:40:15 AM 9:47:23 AM 9:5304 AM 10:02:01AM 10:07:38AM 0 338 0 239 0 169 0 140 0 135 0 065 0 079 0 101 0 111 0 123 0 125 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 10:10:31AM 10:11:29 AM 10:12:27 AM 10:13:25AM 10:14:23AM 10:15:21AM 10:16:19 AM 10:17:17 AM 10:18:15AM 10:19:13AM 10:20:11AM 10:21:10AM 10:22:08AM 10:23:06AM 10:24:04AM 10:25:02AM 10:26:00AM 10:26:58AM 10:27:56AM 10:28:54 AM 10:29:52AM 10:30:50AM 10:31:48AM 10:32:46AM 10:33:44AM 10:34:43AM 10:35:41AM 10:36:39AM 10:37:37 AM 10:38:35AM 10:39:33AM 10:40:31AM 10:41:29 AM 0 141 0 343 0 177 0 104 0 063 0 045 0 032 0 106 0 160 0 229 0 162 0 053 0 253 0 723 0 903 1 141 1 289 1 266 1 235 1 197 1 250 1 325 1 465 0 764 0 402 0 250 0 197 0 180 0 161 0 210 0 262 0 174 0 113 4/4/2014 4/4/2014 4/4/2014 4/4/2014 10:46:59 AM 10:47:57 AM 10:48:55AM 10:49:53AM 0.000 -0.001 -0.001 0.002 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 11:09:38AM 11:13:02AM 11:15:26AM 11:17:50AM 11:21:20AM 11:23:44 AM 11:26:08AM 11:29:12AM 11:31:36AM 11:34:00AM 11:36:31AM 0 184 0 236 0 166 0 131 0 194 0 135 0 087 0 151 0 075 0 077 0 158 SF6 (ppm) 0 647 0 647 0 656 0 663 0 672 0 683 0 667 0 434 0 060 0 045 0 048 0 054 0 052 0 052 0 056 0 425 0 651 0 636 0 643 0 636 0 651 0 652 0 646 0 633 0 634 0 628 0 079 0 050 0 055 0 061 0 063 0 060 0 058 0 059 0 065 0 063 0 612 0 644 0 655 0 645 0 625 0 622 0 613 0 628 0 633 0 636 0 618 0 602 0 161 0 032 0 030 0 031 0 026 0 025 0 031 0 038 0 038 0 040 0 039 0 038 0 039 0 042 0 044 0 042 0 043 0 044 0 042 0 041 0 042 0 040 0 040 0 042 0 043 0 038 0 042 0 039 0 043 0 039 0 462 0 661 0 668 0 680 0 681 0 665 0 649 0 648 0 649 0 661 0 664 0 041 0 042 0 051 0 044 0 041 0 048 0 043 0 038 0 046 0 049 0.006 0.006 0.005 0.006 0 042 0 040 0 045 0 046 0 044 0 041 0 040 0 039 0 045 0 038 0 042 SiF4 (ppm) 0 037 0 039 0 034 0 034 0 034 0 039 0 037 0 036 0 038 0 037 0 039 0 039 0 037 0 034 0 031 0 036 0 040 0 040 0 037 0 038 0 035 0 038 0 037 0 036 0 042 0 041 0 042 0 033 0 042 0 035 0 032 0 031 0 038 0 045 0 042 0 036 0 036 0 036 0 034 0 034 0 033 0 046 0 037 0 034 0 038 0 041 0 039 0 033 0 038 0 041 0 039 0 034 0 041 0 037 0 034 CO (ppm) 109.658 91.671 99.748 89.514 97.773 86.124 99.735 111.618 105.848 93.304 98.131 105.760 98.043 94.303 101.011 99.204 98.094 90.316 104.366 95.870 105.932 86.043 103.118 87.868 89.303 88.827 105.478 98.087 103.644 101.474 106.695 107.312 113.487 105.342 112.565 101.536 88.052 88.073 86.885 93.164 94.851 87.440 85.278 81.287 82.197 81.742 85.765 84.892 91.274 92.248 92.167 81.809 73.109 71.197 71.617 0 020 0 015 0 018 0 017 0 019 0 017 0 017 0 017 0 019 0 018 0 020 0 020 0 020 0 025 0 020 0 015 0 018 0 016 0 025 0 025 0 018 0 027 0 020 0 018 0 025 0 015 0 020 0 019 0 019 0 018 0 018 0 015 0 020 0 016 0 018 0 021 0 020 0 016 0 022 0 018 0 018 0 013 0 018 0 016 0.006 0.007 0.007 0.007 121.622 111.360 111.636 119.798 120.880 123.551 136.759 140.158 133.526 133.750 134.910 123.960 123.355 130.934 115.909 116.613 117.725 186.776 112.123 107.299 119.493 124.160 139.114 152.087 108.390 126.219 117.365 111.017 118.085 112.129 129.667 118.001 109.116 158.696 109.309 132.365 143.293 130.827 118.455 137.303 117.906 114.368 129.399 132.298 13.300 13.280 13.253 13.456 0 009 0 013 0 Oil 0 012 0 012 0 Oil 0 Oil 0 015 0 Oil 0 013 0 Oil 151.613 127.089 131.831 137.615 125.666 135.871 123.500 133.265 149.001 121.772 153.170 C02 (%) 4 255 4 208 4 375 4 141 4 252 4 115 4 353 4 773 4 717 4 371 4 544 4 686 4 575 4 456 4 580 4 358 4 309 4 045 4 578 4 134 4 533 4 055 4 429 4 136 4 213 4 109 4 746 4 611 4 611 4 579 4 836 4 674 4 742 4 579 4 557 4 508 4 082 4 287 4 018 4 222 4 323 3 913 3 159 3 318 3 455 3 539 3 558 3 549 3 853 3 986 4 038 3 915 3 993 4 368 4 531 5 170 5 170 5 014 5 152 5 264 5 265 5 514 5 591 5 463 5 448 5 553 5 224 5 402 5 579 5 182 5 130 5 085 5 677 5 020 5 066 5 081 5 377 5 371 5 194 4 379 4 928 4 712 4 693 4 799 4 621 4 882 4 677 4 663 5 045 4 904 5 397 5 446 5 293 5 145 5 479 5 242 5 145 5 493 5 421 0.001 0.001 0.001 0.001 5 467 5 234 5 264 5 214 5 108 5 179 5 067 5 083 5 216 4 948 5 131 CH4 (ppm) 9.513 7.886 9.744 7.993 9.526 10.043 9.488 10.878 9.337 7.216 7.077 8.569 7.329 8.670 9.543 11.063 8.810 7.925 9.221 8.572 7.943 7.034 7.895 7.144 8.968 8.513 8.584 7.803 8.727 9.476 9.460 10.349 9.375 8.762 9.992 9.027 6.990 7.442 8.479 7.736 6.494 5.207 4.191 4.044 4.426 4.147 4.106 4.197 4.528 4.852 4.606 4.094 3.743 3.627 3.794 7.371 7.232 6.652 6.681 6.741 6.277 6.810 7.332 7.266 7.630 7.569 7.269 6.927 6.746 7.152 6.197 6.343 7.047 6.729 6.393 6.959 6.723 7.060 6.676 5.940 6.431 5.996 6.393 6.211 5.781 6.458 6.525 6.023 6.763 6.635 6.780 6.749 6.423 6.319 6.568 6.648 5.977 7.196 6.381 0.226 0.055 -0.114 -0.108 6.753 7.029 6.618 6.125 6.632 6.491 5.965 6.831 6.980 5.688 7.122 NH3 (ppm) 0.081 0.113 -0.217 -0.153 -0.161 -0.233 -0.499 -0.206 0 334 0 489 0 506 0 453 0 411 0 070 0 047 -0.222 -0.104 -0.151 -0.050 -0.112 -0.036 -0.063 -0.109 -0.002 -0.255 0 198 0 446 0 428 0 185 0 047 0 001 0 174 0 353 0 300 0 062 0 136 0 027 -0.158 -0.256 -0.106 0 115 0 152 0 160 0 053 -o 004 0 138 0 210 0 111 0 301 0 461 0 287 0 347 0 309 0 446 0 322 HCi (ppm) -0.612 -0.594 -0.630 -0.604 -0.588 -0.583 -0.443 -0.663 -0.641 -0.643 -0.613 -0.634 -0.628 -0.609 -0.593 -0.646 -0.623 -0.581 -0.639 -0.610 -0.625 -0.581 -0.625 -0.577 -0.615 -0.601 -0.640 -0.614 -0.621 -0.637 -0.683 -0.657 -0.655 -0.641 -0.674 -0.670 -0.608 -0.598 -0.594 -0.586 -0.604 -0.562 -0.537 -0.559 -0.534 -0.584 -0.558 -0.578 -0.596 -0.609 -0.600 -0.544 -0.585 -0.549 -0.598 0 770 0 559 0 659 0 523 0 490 0 618 0 369 0 247 0 310 0 265 0 145 0 022 0 181 0 087 0 164 0 151 0 333 0 321 0 181 0 293 0 012 0 217 0 089 0 000 0 030 -0.022 -0.041 -0.028 -0.133 0.153 0.050 0.100 -0.125 -0.067 0 219 0 299 0 191 0 248 0 366 0 149 0 195 -o 016 0 138 0 105 -0.024 -0.036 -0.052 -0.064 -0.213 -0.200 -0.193 -0.211 -0.213 -0.227 -0.230 -0.214 -0.216 -0.209 -0.227 -0.457 -0.480 -0.533 -0.555 -0.504 -0.543 -0.545 -0.519 -0.495 -0.500 -0.569 -0.579 -0.543 -0.499 -0.525 -0.460 -0.453 -0.529 -0.498 -0.528 -0.468 -0.439 -0.449 -0.490 -0.537 -0.588 -0.571 -0.519 -0.537 -0.546 -0.508 -0.525 -0.538 0.043 0.033 0.019 0.034 0 295 0 282 0 307 0 208 0 188 0 203 0 303 0 244 0 152 0 203 0 137 -0.235 -0.202 -0.228 -0.188 -0.211 -0.219 -0.229 -0.215 -0.221 -0.234 -0.224 N20 (ppm) 7 792 7 402 7 636 7 662 7 733 7 921 7 441 7 967 8 181 8 623 8 115 7 872 8 384 8 563 8 033 8 074 7 737 7 388 7 387 8 015 8 246 8 752 8 223 8 005 7 791 7 403 7 772 8 302 8 532 8 838 8 784 9 230 9 130 8 649 8 465 8 375 7 883 8 141 8 420 8 087 8 260 13.298 15.771 16.337 17.940 19.998 20.986 20.277 23.230 23.549 22.486 21.247 21.906 2 441 22.822 NO (ppm) 45.146 51.293 49.341 51.341 45.728 53.528 51.946 48.552 50.955 57.757 57.125 50.386 52.085 55.710 52.841 53.046 48.408 54.586 46.329 48.819 42.441 52.072 46.293 54.841 51.528 50.971 49.731 49.172 50.399 51.103 53.151 51.322 51.537 51.926 51.927 53.314 52.257 48.671 54.237 55.233 48.823 53.576 57.691 56.892 57.661 60.545 60.987 63.258 65.258 63.078 62.159 65.954 68.875 63.684 59.140 N02 (ppm) 17.070 17.431 16.394 17.068 16.845 17.292 16.802 16.451 16.102 15.372 15.272 15.046 15.507 15.661 16.203 630 779 198 16.016 16.457 15.776 15.543 15.391 13.993 15.550 572 786 15.280 15.394 15.724 567 15.708 15.561 16.229 17.734 16.440 15.922 15.543 16.749 15.714 17.989 18.848 17.228 16.591 -0.032 -0.031 -0.029 -0.029 61.347 65.410 62.940 62.530 56.681 50.976 52.778 50.337 53.435 56.830 55.515 59.712 59.867 58.806 66.435 65.878 65.738 49.131 60.302 66.672 63.289 65.139 56.361 43.665 54.656 49.380 52.869 53.828 56.563 57.071 48.824 54.247 55.161 46.878 67.224 65.249 53.308 56.037 59.786 51.691 52.459 62.329 54.818 53.906 17.161 17.122 17.179 17.299 7.815 8.052 3.952 7.931 7.282 6.131 -0.170 0.704 7.593 7.800 7.500 864 16.039 15.840 15.195 15.487 16.320 15.741 16.378 15.793 16.679 16.605 48.101 56.700 60.524 58.807 60.129 59.140 61.386 56.949 55.368 61.047 54.824 5.708 7.800 -0.850 6.892 6.641 5.124 3.797 9.478 4.370 3.457 8.831 H20 (%) 27.063 26.470 25.789 23.043 21.473 20.756 24.061 27.440 29.537 29.435 29.388 28.912 27.575 24.780 23.173 24.054 25.985 26.764 27.397 27.004 24.383 22.290 24.274 26.666 27.928 27.123 28.986 27.059 24.632 23.772 27.663 29.061 29.725 29.658 29.696 29.032 26.650 23.742 22.563 25.300 26.663 26.443 25.396 22.729 21.117 21.361 24.486 26.136 27.832 28.105 27.934 27.017 24.649 23.117 22.408 29.935 27.929 29.060 30.089 29.678 32.841 31.207 31.531 30.325 30.390 30.528 27.491 27.008 27.411 30.779 32.216 32.352 32.708 30.093 27.026 25.265 28.594 32.540 31.765 30.085 30.572 27.402 24.882 27.658 29.913 30.376 29.551 26.534 24.453 25.761 29.894 32.549 32.566 32.239 30.688 27.143 25.564 28.169 31.761 0.016 0.015 0.007 0.009 32.742 28.705 31.653 32.748 27.378 31.856 32.889 28.079 32.732 32.519 27.774 Tremc)p 148.311 148.413 148.311 148.209 148.413 148.311 148.514 148.209 148.311 148.311 148.413 148.311 148.413 148.311 148.311 148.311 148.311 148.311 148.311 148.311 148.311 148.311 148.514 148.311 148.107 148.311 148.311 148.209 148.413 148.311 148.311 148.413 148.311 148.209 148.413 148.311 148.413 148.514 148.514 148.311 148.311 148.311 148.311 148.311 148.413 148.311 148.413 148.311 148.311 148.311 148.413 148.311 148.311 148.209 148.413 Pressure (atm) 0 943 0 944 0 940 0 947 0 955 0 944 0 938 0 935 0 939 0 942 0 938 0 946 0 943 0 939 0 945 0 946 0 943 0 943 0 940 0 942 0 941 0 946 0 950 0 941 0 939 0 946 0 942 0 943 0 942 0 946 0 935 0 936 0 934 0 944 0 940 0 949 0 947 0 952 0 944 0 942 0 942 0 943 0 946 0 946 0 946 0 943 0 947 0 946 0 942 0 940 0 946 0 947 0 946 0 947 0 950 148.413 148.311 148.413 148.413 148.311 148.514 148.413 148.514 148.311 148.413 148.413 148.413 149.125 148.413 148.413 148.311 148.311 148.107 148.209 148.311 148.311 148.413 148.311 148.209 148.209 148.107 148.311 148.311 148.311 148.311 148.107 148.413 148.514 148.413 148.209 148.209 148.413 148.209 148.311 148.311 148.514 148.311 148.209 148.311 149.023 148.921 148.718 149.125 0 943 0 934 0 952 0 933 0 943 0 943 0 936 0 942 0 944 0 944 0 938 0 950 0 943 0 938 0 936 0 938 0 938 0 936 0 943 0 943 0 946 0 945 0 936 0 941 0 945 0 940 0 943 0 947 0 943 0 940 0 943 0 944 0 943 0 941 0 941 0 933 0 933 0 936 0 938 0 943 0 950 0 942 0 938 0 944 1 027 1 030 1 027 1 012 148.311 148.311 148.311 148.209 148.209 148.311 148.311 148.311 148.209 148.413 148.413 0 934 0 930 0 927 0 929 0 935 0 929 0 928 0 935 0 927 0 935 0 934 17cv1906 Sierra Club v. EPA- 6/22 Production ED 001523 00007569-00128 PCS Phosphates Raw FTIR Data Spectrum RUN#2_0012.LAB RUN#2_0013.LAB RUN#2_0014.LAB RUN#2_0015.LA8 RUN#2_0016.LA8 RUN#2_0017.LAB RUN#2_0018.LAB RUN#2_0019.LA8 RUN#2_0020.LAB RUN82_0021.LAB RUN#2_0022.LA8 RUN#2_0023.LAB RUN#2_0024.LA8 RUN#2_0025.LA8 RUN#2_0026.LA8 RUN#2_0027.LAB RUN#2_0028.LA8 RUN#2 QA_0001.LAB RUN#2 QA_0002.LAB RUN#2 QA_0003.LAB RUNS2 QA_0004.LAB RUN#2 QA_0005.LA8 RUNS2 QA_0006.LAB RUN#2 QA_0007.LA8 RUN#2 QA_0008.LAB RUN#2 QA_0009.LA8 RUNS2 QAJD010.LAB RUN#2 QAjOOll.LAB RUNS2 QA_0012.LAB RUN#2 QA_0013.LAB RUN#2 QA_0014.LAB RUN#2 QA_0015.LA8 RUN#2 QA_0016.LAB RUN#2 QA_0017.LA8 RUNS2 QA_0018.LAB RUN#2 QA_0019.LA8 RUNS2 QA_0020.LA8 RUN#2 QA_0021.LAB RUN#2 QA_0022.LAB RUNS2 QA_0023.LAB Run #2 Post Test CTS RUNS2 CTS_0001.LAB RUN#2 CTS_0002.LAB RUN#2 CTS_0003.LA8 Date Time 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 11:39:28AM 11:41:52AM 11:44:30AM 11:46:54AM 11:49:18AM 11:52:02AM 11:54:26AM 11:57:04AM 12:00:07 PM 12:02:32 PM 12:05:22 PM 12:08 06 PM 12:10:43 PM 12:13:14 PM 12:15:38 PM 12:18:03 PM 12:20:47 PM HF (ppm) 0.065 0.042 0.056 0.003 0.039 0.025 0.007 0.007 0.035 -0.002 0.072 0.027 0.039 0.039 -0.009 -0.020 0.115 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 12:25:14PM 12:26:12 PM 12:27:10PM 12:2808 PM 12:2906 PM 12:30 :04PM 12:31 02 PM 12:32 :01PM 12:32 :59 PM 12:33 :57 PM 12:34 :55 PM 12:35 :53 PM 12:36 :51PM 12:37 :49 PM 12:38 :47 PM 12:39 :45 PM 12:40 :43 PM 12:41 :41PM 12:42 :39 PM 12:43 :37 PM 12:44 :35 PM 12:45 :34 PM 12:46 :32 PM -0.047 0.033 0.073 0.122 0.025 -0.021 -0.013 0.448 0.700 0.872 1.042 1.127 1.018 0.970 1.006 1.000 0.479 0.267 0.228 0.127 0.053 0.012 0.008 4/4/2014 4/4/2014 4/4/2014 12:51:10PM 12:52:08 PM 12:53:06 PM 0.001 0.008 0.004 SF6 (ppm) 0.041 0.042 0.046 0.046 0.040 0.043 0.047 0.044 0.046 0.047 0.042 0.043 0.041 0.047 0.045 0.050 0.046 0.044 0.046 0.046 0.044 0.047 0.039 0.206 0.675 0.670 0.675 0.685 0.692 0.667 0.663 0.661 0.656 0.130 0.041 0.044 0.042 0.057 0.051 0.049 0.004 0.004 0.007 SiF4 (ppm) 0.009 0.009 0.013 0.005 0.012 0.011 0.013 0.005 0.011 0.009 0.006 0.011 0.012 0.010 0.008 0.012 0.012 CO (ppm) 135.428 140.029 144.339 155.803 154.113 154.071 157.448 156.438 131.557 152.403 161.270 146.543 135.971 138.767 148.416 145.350 129.658 0.011 0.013 0.013 0.015 0.014 0.011 0.008 0.012 0.019 0.012 0.014 0.018 0.006 0.012 0.017 0.016 0.011 0.007 0.009 0.011 0.004 0.007 0.007 133.017 178.684 140.746 125.988 139.195 140.330 144.089 134.473 124.027 135.900 118.282 124.166 121.099 194.524 131.042 161.708 133.627 129.788 122.894 133.420 145.046 147.512 144.665 -0.001 -0.001 0.002 13.306 13.522 13.307 C02 (%) 5.195 5.208 5.378 5.310 5.324 5.487 5.302 5.383 5.329 5.431 5.394 5.495 5.283 5.369 5.296 5.170 5.120 5.026 5.730 5.027 5.154 5.445 5.323 5.286 4.651 4.657 4.754 4.706 4.795 4.610 5.114 4.501 4.940 4.940 5.023 5.067 5.193 5.257 5.212 5.009 0.000 0.000 0.000 CH4 (ppm) 6.349 5.667 6.667 6.877 6.501 8.117 6.808 6.644 6.652 5.857 6.832 6.265 6.179 6.616 6.254 6.397 6.488 NH3 (ppm) 0.186 0.192 0.212 0.258 0.182 0.135 0.232 0.099 0.230 0.126 0.076 0.096 0.009 0.094 0.196 0.169 0.122 HC! (ppm) -0.233 -0.234 -0.250 -0.242 -0.232 -0.220 -0.221 -0.233 -0.199 -0.217 -0.224 -0.234 -0.208 -0.221 -0.215 -0.212 -0.229 5.655 6.103 6.234 6.892 6.161 5.536 6.440 6.106 5.853 5.815 5.726 5.299 6.125 6.747 5.733 6.128 6.288 6.496 5.799 6.224 7.320 6.156 6.459 0.251 0.121 -0.028 0.062 0.091 0.103 -0.064 -0.121 -0.217 -0.128 -0.210 -0.114 -0.169 -0.032 -0.145 -0.092 0.129 0.071 0.210 0.156 0.136 0.216 0.213 -0.550 -0.551 -0.517 -0.531 -0.587 -0.541 -0.543 -0.517 -0.507 -0.511 -0.472 -0.504 -0.506 -0.545 -0.558 -0.547 -0.525 -0.542 -0.466 -0.532 -0.565 -0.553 -0.517 -0.052 -0.156 -0.195 0.010 -0.016 -0.039 0.003 0.015 0.012 N20 (ppm) 16.361 16.089 16.579 16.523 16.249 16.883 15.989 15.722 16.128 14.928 15.282 15.544 14.146 14.642 14.115 14.432 14.606 NO (ppm) 54.632 51.941 50.517 47.871 46.676 46.680 53.371 47.270 54.303 48.836 45.956 49.069 50.628 52.108 52.263 55.172 56.453 15.097 14.463 14.890 15.072 14.651 14.543 13.594 13.390 13.027 13.149 13.484 13.859 13.498 13.435 13.892 13.521 14.764 14.798 15.48 1 15.324 14.334 14.028 14.845 59.600 44.961 56.341 55.385 53.864 52.897 48.895 49.819 51.829 50.811 48.898 51.666 55.484 41.792 52.044 42.278 54.446 58.154 61.267 61.769 58.978 51.934 61.950 -0.049 -0.050 -0.042 17.281 17.834 17.185 N02 (ppm) -0.041 4.600 8.452 9.731 5.351 8.208 7.936 4.851 8.130 6.700 11.621 8.611 4.412 3.721 7.145 6.438 7.046 H20 (%) 31.528 33.257 30.473 34.558 32.049 29.726 34.288 32.591 30.332 34.064 28.848 30.433 31.410 29.448 34.171 33.874 27.040 Temp ( C) 148.209 148.413 148.209 148.209 148.311 148.006 148.107 148.413 148.209 148.209 148.413 148.107 148.107 148.107 148.209 148.413 148.413 Pressure (atm) 0.933 0.932 0.924 0.931 0.939 0.939 0.924 0.934 0.929 0.927 0.941 0.933 0.939 0.931 0.931 0.933 0.939 33.061 33.039 27.549 25.772 28.107 31.646 31.972 30.022 29.841 27.308 24.785 25.525 28.918 30.351 30.445 30.757 32.979 28.638 26.535 29.932 32.459 33.634 33.155 148.311 148.514 148.209 148.209 148.209 147.904 148.209 148.209 148.311 148.006 148.209 148.311 148.209 148.107 148.311 148.107 148.209 148.107 148.209 148.209 148.311 148.107 148.209 0.930 0.930 0.934 0.941 0.932 0.930 0.934 0.931 0.935 0.937 0.938 0.936 0.935 0.936 0.935 0.932 0.933 0.937 0.931 0.928 0.928 0.930 0.926 0.006 0.008 0.008 148.107 148.514 148.311 1.039 1.003 1.003 RUN#3_0001.LAB RUN#3_0002.LAB RUN#3_0003.LAB RUN#3_0004.LAB RUN#3_0005.LAB RUN#3_0006.LAB RUN#3_0007.LA8 RUN#3_0008. LAB RUN#3_0009.LAB RUN#3_0010.LA8 RUN#3_0011.LAB RUN#3_0012.LAB RUN#3_0013.LAB RUN#3_0015.LA8 RUN#3_0016.LA8 RUN#3_0017.LAB RUN#3_0018.LAB RUN#3_0019.LAB RUN#3_0020.LAB RUN#3_0021.LAB RUN#3_0022.LAB RUN#3_0023.LAB RUN#3_0024.LAB Run #3 Post Test Spike RUN#3 QA_0001.LA8 RUNS3 QA_0002.LAB RUN#3 QA_0003.LAB RUN#3 QA_0004.LA8 RUN#3 QA_0005.LA8 RUNS3 QA_0006.LAB RUNS3 QA_0007.LAB RUNS3 QA_0008.LA8 RUN#3 QA_0009.LA8 RUNS3 QA_0010.LA8 RUN#3QA_0011.LAB RUN#3 QA_0012.LA8 RUN#3 QA_0013.LAB RUNS3 QA_0014.LA8 RUN#3 QA_0015.LA8 RUN83 QA_0016.LAB RUN#3 QA_0017.LA8 RUN83 QA_0018.LAB RUN#3 GA_0019.LA8 RUNS3 QA_0020.LA8 RUN#3QA_0021.LAB RUN#3 QA_0022.LA8 RUN#3 QA_0023.LAB RUN#3 QA_0024.LAB RUNS3 QA_0025.LAB Run #3 Post Test CTS RUNS3 CTS_0001.LA8 RUN#3 CTS_0002.LAB RUN#3 CTS_0003.LAB RUNS3 CTS_0004.LAB RUN#3 CTS_0005.LAB RUN#3 CTS_0006.LA8 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 1:02:47 PM 1:05:37 PM 1:08:01PM 1:10:39 PM 1:13:29 PM 1:15:53 PM 1:18:57 PM 1:21:47 PM 1:24:18 PM 1:27:55 PM 1:30:32 PM 1:32:56 PM 1:35:53 PM 1:40:55 PM 1:43:19 PM 1:47:47 PM 1:50:11PM 1:52:42 PM 1:55:26 PM 1:57:50PM 2:00:21PM 2:03:11PM 2:05:49 PM 0.001 -0.005 0.113 -0.006 -0.023 0.072 -0.011 -0.008 0.080 -0.029 0.066 -0.002 -0.002 -0.052 -0.028 -0.055 0.024 0.030 -0.032 0.059 -0.014 -0.066 0.033 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 2:08:49 PM 2:09:47 PM 2:10:44 PM 2:11:41PM 2:12:38 PM 2:13:35 PM 2:14:32 PM 2:15:29 PM 2:16:26 PM 2:17:24 PM 2:18:21PM 2:19:18 PM 2:20:15 PM 2:21:12 PM 2:22:09 PM 2:23:06 PM 2:24:04PM 2:25:01PM 2:25:58 PM 2:26:55 PM 2:27:52 PM 2:28:49 PM 2:29:46 PM 2:30:44PM 2:31:41PM -0.031 0.049 0.134 0.073 0.105 0.093 0.070 0.173 0.500 0.679 0.753 0.952 1.065 1.130 1.032 0.975 0.980 0.978 0.603 0.358 0.305 0.281 0.192 0.127 0.101 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 2:38:35 PM 2:39:04 PM 2:39:33 PM 2:40:08 PM 2:40:31PM 2:41:00PM 0.016 0.004 -0.003 0.012 0.002 0.014 0.042 0.042 0.039 0.045 0.042 0.040 0.048 0.043 0.043 0.046 0.041 0.048 0.043 0.047 0.045 0.046 0.038 0.043 0.047 0.043 0.045 0.048 0.047 -0.001 0.008 0.006 -0.001 0.000 0.000 0.032 0.499 0.635 0.628 0.636 0.667 0.670 0.670 0.638 0.629 0.629 0.626 0.072 0.003 0.001 0.001 0.003 -0.002 -0.001 0.006 0.005 0.006 0.005 0.005 0.006 0.010 0.014 0.012 0.015 0.011 0.015 0.015 0.017 0.014 0.010 0.013 0.014 0.010 0.013 0.014 0.014 0.010 0.012 0.013 0.016 0.014 0.013 0.010 141.442 133.393 127.027 148.908 132.791 130.305 150.169 132.118 131.243 138.425 121.426 135.454 137.334 136.770 138.800 137.459 130.051 123.251 130.764 123.786 131.374 147.42 1 134.198 5.058 4.981 4.960 5.186 5.003 5.083 5.146 4.914 5.215 5.094 5.000 5.212 5.093 5.148 5.112 5.129 5.020 5.026 4.958 4.924 5.037 5.013 5.067 0.016 0.016 0.014 0.013 0.017 0.013 0.009 0.017 0.015 0.011 0.013 0.016 0.012 0.005 0.014 0.014 0.018 0.015 0.009 0.010 0.008 0.012 0.011 0.010 0.017 144.155 156.690 163.548 126.267 118.865 135.534 128.455 125.115 174.913 124.580 105.730 111.516 120.010 113.125 112.291 125.335 149.784 111.287 118.692 121.082 119.714 118.641 122.343 118.715 145.648 5.172 5.390 5.154 4.724 4.836 5.203 4.931 4.655 4.923 4.621 4.264 4.461 4.694 4.490 4.537 4.643 4.822 4.236 4.600 4.769 4.823 4.746 4.967 4.792 5.175 0.006 0.008 0.005 0.006 0.007 0.006 13.524 13.420 13.446 13.514 13.499 13.482 0.000 0.000 0.000 0.000 0.001 0.000 6.233 6.365 6.566 7.012 6.419 5.965 6.463 6.208 6.300 6.352 6.035 6.423 6.130 5.901 6.658 6.382 6.371 6.112 6.161 6.131 6.330 6.573 6.502 0.104 0.108 0.066 0.100 0.074 0.071 0.036 0.121 -0.009 0.036 0.079 0.031 -0.001 0.094 0.019 0.016 0.032 -0.007 0.021 0.073 -0.064 -0.062 0.027 6.361 6.512 6.063 6.392 6.427 6.385 6.520 6.442 6.473 5.890 5.224 5.128 5.989 5.771 5.013 5.663 6.268 5.633 5.718 5.793 6.100 6.043 4.998 5.396 6.795 -0.170 -0.106 -0.004 -0.174 -0.074 -0.084 -0.148 -0.193 -0.254 -0.272 -0.166 -0.147 -0.322 -0.327 -0.302 -0.448 -0.257 -0.127 -0.025 -0.180 -0.005 -0.153 0.091 -0.182 -0.098 -0.207 -0.239 -0.297 -0.018 -0.207 -0.166 0.013 -0.015 -0.005 0.017 -0.030 -0.002 -0.209 -0.209 -0.177 -0.218 -0.212 -0.202 -0.214 -0.206 -0.203 -0.187 -0.190 -0.214 -0.200 -0.226 -0.179 -0.212 -0.176 -0.187 -0.202 -0.182 -0.198 -0.219 -0.211 -0. 557 -0. 503 -0. 506 -0. 515 -0. 476 -0. 471 -0. 525 -0. 495 -0. 522 -0. 498 -0. 439 -0. 476 -0. 461 -0. 460 -0. 508 -0. 501 -0. 500 -0. 455 -0. 511 -0. 458 -0. 492 -0. 491 -0. 532 -0. 536 -0. 557 0.020 0.018 -0.015 0.017 0.024 0.018 15.095 14.452 15.445 15.529 14.860 15.326 15.035 15.159 15.596 15.424 15.467 16.022 15.021 15.813 14.391 15.023 14.834 15.329 14.603 15.061 14.958 14.207 15.196 57.110 58.083 62.341 58.947 56.847 60.453 58.414 60.402 60.826 59.614 58.548 62.121 56.716 57.712 53.633 58.629 61.819 66.720 62.963 63.397 63.313 56.353 56.893 13.738 13.717 13.299 15.558 15.512 14.766 16.886 14.044 13.485 14.074 14.682 13.460 13.688 13.493 14.282 13.966 13.402 14.759 14.899 14.102 14.299 15.169 16.113 15.187 14.657 60.816 53.147 51.240 60.938 65.697 58.050 68.109 60.906 46.601 52.518 64.680 61.677 50.968 61.557 62.756 58.001 49.303 62.041 72.899 69.937 66.791 67.322 71.100 69.580 61.822 -0.035 -0.035 -0.035 -0.042 -0.036 -0.040 17.187 17.096 17.043 17.007 17.163 17.038 3.552 3.846 5.671 7.714 -0.360 6.350 4.972 6.407 6.339 4.088 5.164 7.822 -0.491 3.200 3.540 5.137 8.039 4.843 6.351 6.100 7.140 3.847 5.624 32.857 31.234 25.272 30.159 31.054 26998 32.067 29.619 26584 32.018 26.796 30.047 31.139 32.721 29.055 31.938 27.905 27.400 30.395 25.317 29.844 31.853 27.041 148.107 148.107 148.311 148.413 148.311 148.209 148.311 148.209 148.107 148.311 148.209 148.107 148.413 148.311 148.311 148.107 148.107 148.311 148.311 148.311 148.107 148.311 148.209 32.443 33.569 33.783 27.619 25.212 24.637 28.268 28.776 29.021 29.173 28.699 25.471 23.515 24.225 27.963 29.067 29.761 29.015 30.748 27.475 25.227 23.896 27.836 29.972 31.426 148.311 148.718 149.125 148.413 148.311 148.209 148.311 148.209 148.107 148.107 148.209 148.209 148.311 148.311 148.209 148.209 148.107 148.209 148.209 148.311 148.311 148.514 148.209 148.311 148.311 0.001 -0.005 0.005 0.002 -0.004 0.002 149.023 149.125 149.023 149.023 149.125 149.125 0.928 0.936 0.939 0.927 0.938 0.932 0.929 0.935 0.928 0.932 0.934 0.926 0.935 0.924 0.938 0.934 0.933 0.935 0.937 0.940 0.929 0.937 0.934 0.923 0.931 0.927 0.933 0.935 0.932 0.930 0.933 0.932 0.928 0.934 0.935 0.938 0.933 0.937 0.930 0.929 0.932 0.930 0.936 0.934 0.934 0.933 0.930 0.926 1.000 1.000 0.999 0.999 0.999 RUN#4_0002.LA8 RUN#4_0003.LA8 RUN#4_0004.LAB RUN#4_0005.LA8 RUN#4_0006.LAB RUN#4_0007.LA8 RUN#4_0008.LAB RUN#4_0009.LAB RUN#4_0010.LAB RUN#4_0011.LA8 RUN#4_0012.LA8 RUN#4_0013.LA8 RUN#4_0014.LA8 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 2:57:43 PM 3:01:06 PM 3:04:03 PM 3:06:27 PM 3:08:58 PM 3:11:35 PM 3:14:00PM 3:16:43 PM 3:19:27 PM 3:22:11PM 3:24:49 PM 3:27:13 PM 3:29:50PM 0.0908 -0.0220 0.0009 0.0898 -0.0407 -0.0044 0.0561 -0.0319 -0.0343 -0.0133 -0.0574 0.0321 0.0015 0.0391 0.0415 0.0386 0.0364 0.0447 0.0413 0.0375 0.0492 0.0397 0.0359 0.0457 0.0418 0.0416 0.0141 0.0108 0.0130 0.0101 0.0120 0.0119 0.0108 0.0124 0.0072 0.0078 0.0079 0.0098 0.0082 118.7788 138.4728 127.9347 130.1600 133.9861 138.9877 123.4445 146.7073 143.3518 126.8171 138.4318 123.9263 133.7841 4.9601 5.1512 4.9274 5.2305 5.1092 5.1891 5.0577 5.2437 5.0724 4.9544 4.9775 4.8766 5.0563 6.0568 6.5961 6.3113 6.3249 6.6070 6.5179 7.0643 6.9673 6.9809 6.6361 6.7706 6.6457 6.7464 -0.0258 0.0519 0.1453 0.0842 0.0670 -0.0236 0.0625 -0.0287 -0.1168 0.0095 -0.0475 -0.1005 -0.0509 -0.2005 -0.2306 -0.1916 -0.2047 -0.2278 -0.1904 -0.1983 -0.2120 -0.2002 -0.2055 -0.1858 -0.1782 -0.1925 15.5340 14.4309 14.1136 14.9590 14.3420 13.3573 14.9621 14.1376 14.2573 14.8278 13.6889 14.2724 14.8130 61.6278 60.4084 58.8508 61.5482 60.5267 58.5578 62.6328 58.7396 58.4635 65.6086 67.2750 65.1820 68.7537 4.9098 -1.0525 3.3085 4.8971 -0.9403 5.7978 4.4512 7.0942 6.4433 7.0945 3.4377 4.4453 6.2931 25.7009 31.1314 29.3094 25.5859 31.1104 29.9756 25.7744 30.8569 30.1888 28.708C 31.2784 26.109C 28.3016 148.1075 147.9039 148.0057 148.1075 148.2092 148.3110 148.3110 148.1075 148.2092 148.1075 148.0057 148.2092 148.1075 0.9330 0.9278 0.9404 0.9304 0.9304 0.9291 0.9268 0.9271 0.9284 0.9294 0.9242 0.9314 0.9262 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00129 PCS Phosphates Raw FTIR Data Spectrum RUN#4_0015.LA8 RUN#4_0016.LA8 RUN#4_0017.LA8 RUN#4_0018.LA8 RUN#4_0019.LAB RUN#4_0020.LAB RUN#4_0021.LA8 RUN#4 QA_0002.LAB RUN#4 QA_0003.LAB RUN#4 QA_0004.LA8 RUN#4 QA_0005.LA8 RUN#4 QA_0006.LAB RUN#4 QA_0007.LA8 RUN#4 QA_0008.LA8 RUN#4 QA_0009.LAB RUN#4 QA_0010.LAB RUN#4 QAJDOll.LAB RUN#4 QA_0012.LAB RUN#4 QA_0013.LAB RUN#4 QA_0014.LAB RUN#4 QA_0015.LA8 RUN#4 QA_0016.LAB RUN#4 QA_0017.LAB RUN#4 QA_0018.LA8 RUN#4 QA_0019.LA8 RUN#4 QA_0020.LAB RUN#4 QA_0021.LAB RUN#4 QA_0022.LAB RUN#4 QA_0023.LAB RUN#4 QA_0024.LAB RUN#4 QA_0025.LA8 RUN#4 QA_0026.LAB RUN#4 QA_0027.LA8 RUN#4 QA_0028.LA8 RUN#4 QA_0029.LA8 RUN#4 QA_0030.LA8 RUN#4 QA_0031.LA8 Date Time 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 3:34:11 PM 3:37:02 PM 3:41:11PM 3:45:45 PM 3:49:48 PM 3:57:22 PM 4:01:25 PM HF (ppm) 0.0225 0.0221 -0.0593 0.0110 -0.0694 -0.0061 -0.0262 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4:09:54 PM 4:10:51PM 4:11:48 PM 4:12:45 PM 4:13:42 PM 4:14:39 PM 4:15:37 PM 4:16:34PM 4:17:31PM 4:18:28 PM 4:19:25 PM 4:20:22 PM 4:21:19 PM 4:22:17 PM 4:23:14 PM 4:24:11PM 4:25:08 PM 4:26:05 PM 4:27:02 PM 4:27:59 PM 4:28:57 PM 4:29:54 PM 4:30:51PM 4:31:48 PM 4:32:45 PM 4:33:42 PM 4:34:39 PM 4:35:36 PM 4:36:34 PM 4:37:31PM -0.116 -0.135 -0.035 -0.018 0.351 0.473 0.526 0.590 0.708 0.870 0.964 0.967 0.875 0.847 0.853 0.838 0.979 1.103 1.173 1.128 0.552 0.182 0.060 0.028 0.009 0.055 0.067 SF6 (ppm) 0.0394 0.0399 0.0379 0.0360 0.0401 0.0365 0.0392 0.039 0.039 0.041 0.038 0.039 0.631 0.708 0.689 0.657 0.666 0.680 0.692 0.706 0.693 0.680 0.689 0.678 0.653 0.672 0.684 0.706 0.713 0.699 0.112 0.036 0.029 0.051 0.049 0.030 0.041 SiF4 (ppm) 0.0084 0.0095 0.0035 0.0114 0.0113 0.0063 0.0146 CO (ppm) 128.8173 131.3690 145.6029 125.3831 127.8951 125.6897 123.6633 C02 (%) 4.8829 4.9096 4.9229 4.8520 4.8139 4.7463 4.8241 0.017 0.007 0.011 0.014 0.008 0.005 0.010 0.014 0.014 0.015 0.001 0.016 0.014 0.001 0.011 0.008 0.017 0.011 0.010 0.007 0.007 0.007 0.008 0.010 0.007 0.008 0.004 0.006 0.018 0.014 130.851 147.925 134.473 122.722 161.130 123.437 118.443 128.791 114.299 138.353 128.814 116.862 108.676 123.833 127.076 130.605 130.704 122.588 125.257 106.567 129.268 114.946 132.274 122.289 138.372 129.777 140.846 126.806 115.554 131.373 4.582 5.050 4.732 4.774 5.049 4.631 4.404 4.611 4.124 4.697 4.517 4.408 4.268 4.624 4.529 4.544 4.649 4.396 4.477 4.172 4.705 4.579 4.879 4.807 5.078 4.849 4.998 4.850 4.760 5.189 CH4 (ppm) 6.4472 6.4857 6.8682 6.5839 6.7083 6.8903 6.9660 NH3 (ppm) -0.0611 -0.0108 -0.0660 -0.0143 0.0965 -0.1328 -0.0352 HC! (ppm) -0.1792 -0.1783 -0.2267 -0.1623 -0.1975 -0.1878 -0.2068 N20 (ppm) 13.7076 14.9561 14.3011 15.1372 14.1707 14.6839 15.2230 NO (ppm) 63.6118 65.3776 62.2882 66.8658 62.1854 64.0974 67.2238 N02 (ppm) 5.1464 5.4187 5.0004 5.2620 8.5310 5.3093 5.0160 6.783 6.500 7.071 6.352 7.147 6.579 5.998 6.132 5.710 6.295 5.850 5.957 6.191 5.772 5.805 6.316 6.207 5.612 5.604 5.707 5.658 6.330 5.931 6.294 6.384 6.161 6.273 6.065 5.569 6.418 -0.047 0.021 -0.091 -0.085 -0.223 -0.149 -0.327 -0.213 -0.301 -0.122 -0.256 -0.365 -0.181 -0.243 -0.164 -0.185 -0.215 -0.199 -0.225 -0.283 -0.055 -0.287 -0.254 -0.153 -0.174 0.045 0.035 -0.060 -0.127 -0.047 -0.507 -0.498 -0.511 -0.469 -0.495 -0.463 -0.466 -0.463 -0.453 -0.485 -0.473 -0.429 -0.436 -0.512 -0.473 -0.492 -0.482 -0.504 -0.481 -0.422 -0.446 -0.437 -0.479 -0.505 -0.558 -0.537 -0.544 -0.527 -0.501 -0.511 15.393 15.030 15.570 16.403 15.996 14.684 15.745 14.311 14.533 13.444 13.834 14.975 14.845 14.822 13.789 14.958 14.023 14.811 14.293 14.759 13.870 14.695 14.476 16.029 15.126 15.649 14.289 15.373 15.567 15.084 66.821 60.355 60.454 65.238 51.848 60.772 59.116 57.778 66.582 52.616 52.561 56.716 60.113 61.351 55.546 55.968 53.049 57.573 57.596 63.895 55.280 54.105 53.435 61.621 57.334 64.184 58.864 61.603 65.649 57.912 H20 (%) 26.5383 25.5597 30.6302 26.2686 28.9799 26.2549 26.9541 Temp ( C) 148.2092 148.1075 148.1075 148.0057 148.2092 148.3110 148.2092 Pressure (atm) 0.9365 0.9339 0.9249 0.9284 0.9343 0.9411 0.9281 30.939 31.350 28.602 25.696 24.079 23.140 27.238 28.272 28.438 29.035 27.327 23.656 21.873 24.940 28.184 28.632 29.120 29.388 28.772 25.720 23.207 22.079 25.966 30.110 31.609 31.838 31.448 30.965 27.139 24.871 148.311 148.209 148.107 148.209 148.209 148.209 148.107 148.209 148.209 148.209 148.311 148.107 148.311 148.209 148.107 148.311 148.209 148.107 148.107 148.311 148.311 148.209 148.209 147.904 148.209 148.107 148.006 148.311 148.209 148.311 0.926 0.927 0.932 0.933 0.933 0.934 0.929 0.930 0.937 0.929 0.933 0.936 0.938 0.936 0.938 0.927 0.928 0.934 0.933 0.938 0.936 0.937 0.931 0.931 0.927 0.931 0.934 0.932 0.932 0.932 RUN#5_0001.LAB RUN#5_0002.LA8 RUN#5_0003.LAB RUN#5_0004.LA8 RUN#5_0005.LA8 RUN#5_0006.LAB RUN#5_0007.LAB RUN#5_0008.LAB RUN#5_0009.LA8 RUN#5_0010.LAB RUN#5_0011.LAB RUN#5_0012.LAB RUN#5_0013.LAB RUN#5_0014.LA8 RUN#5_0015.LA8 RUN#5_0016.LA8 RUN#5_0017.LA8 RUN#5_0018.LA8 RUN#5_0019.LAB RUN#5_0020.LA8 RUN#5_002 l.LAB RUN#5_0022.LAB RUN#5_0023.LA8 RUN#5_0024.LAB RUN#5_0025.LAB RUN#5_0026.LAB RUN#5_0027.LAB RUN#5_0028.LA8 RUN#5_0029.LA8 RUN#5_0030.LAB RUN#5_003 l.LAB 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4:42:38 PM 4:45:32 PM 4:49:12 PM 4:50:57 PM 4:51:55 PM 4:52:53 PM 4:53:51PM 4:56:46 PM 4:59:11PM 5:00:09 PM 5:02:05 PM 5:03:03 PM 5:04:01PM 5:04:59 PM 5:06:26PM 5:07:24PM 5:08:23 PM 5:13:47 PM 5:14:45 PM 5:17:11PM 5:18:38 PM 5:20:34PM 5:21:32 PM 5:22:30PM 5:25:24 PM 5:26:22 PM 5:27:49 PM 5:28:48 PM 5:29:46 PM 5:30:44PM 5:31:42 PM -0.054 0.027 -0.016 -0.006 0.047 0.089 0.054 -0.068 0.043 0.048 -0.085 -0.057 -0.082 -0.072 -0.034 0.034 0.067 0.038 0.034 0.006 -0.083 -0.077 0.069 0.025 -0.082 -0.075 -0.065 0.075 0.073 -0.065 -0.054 0.043 0.038 0.040 0.035 0.041 0.033 0.041 0.037 0.035 0.038 0.040 0.043 0.043 0.037 0.042 0.032 0.033 0.032 0.032 0.039 0.037 0.041 0.034 0.040 0.037 0.043 0.039 0.026 0.037 0.039 0.036 0.006 0.006 0.009 0.011 0.013 0.006 0.010 0.009 0.008 0.010 0.006 0.010 0.000 0.009 0.013 0.010 0.014 0.015 0.006 0.010 0.005 0.009 0.013 0.010 0.008 0.003 0.010 0.009 0.010 0.008 0.008 135.009 122.398 134.323 147.935 126.060 109.560 148.300 131.897 118.786 127.939 135.012 147.422 136.686 130.998 121.518 111.350 110.708 108.648 126.071 123.789 123.722 129.016 118.006 121.066 128.076 130.299 132.685 116.936 122.410 137.558 128.876 5.088 4.814 5.120 5.110 4.840 4.602 5.361 4.872 4.705 4.845 4.920 4.832 4.780 4.693 4.759 4.519 4.539 4.469 4.792 4.723 4.512 4.865 4.814 4.787 4.738 4.796 4.852 4.517 4.929 5.120 4.807 6.662 6.422 7.148 7.272 6.874 6.264 6.611 6.994 6.616 6.996 7.296 7.133 6.222 6.075 6.158 6.384 5.556 5.923 6.791 5.978 6.068 6.159 6.306 6.556 6.661 6.370 7.640 5.703 6.234 7.639 6.634 0.059 -0.030 -0.122 -0.154 0.027 0.002 -0.101 0.015 -0.098 -0.145 -0.116 -0.047 0.128 0.022 0.151 0.086 0.015 -0.118 -0.077 0.055 -0.101 -0.061 -0.100 -0.051 -0.002 0.065 -0.055 -0.118 0.050 -0.076 -0.303 -0.203 -0.205 -0.197 -0.192 -0.152 -0.183 -0.188 -0.213 -0.188 -0.155 -0.194 -0.185 -0.194 -0.217 -0.198 -0.174 -0.160 -0.184 -0.183 -0.177 -0.219 -0.173 -0.162 -0.177 -0.192 -0.211 -0.180 -0.130 -0.175 -0.206 -0.190 14.720 14.972 15.644 14.016 15.038 15.888 14.759 15.130 15.580 14.875 15.337 15.371 14.999 15.131 15.108 15.700 16.649 16.870 15.469 16.548 16.018 15.105 15.674 17.039 16.640 16.099 15.845 15.253 17.051 16.214 16.494 58.775 63.665 61.960 60.186 63.665 74.306 60.881 60.704 65.318 65.176 66.471 58.643 66.563 66.366 62.936 71.797 80.474 71.502 64.460 70.544 70.532 60.498 64.707 67.886 65.922 65.447 57.248 61.015 68.730 64.823 64.940 2.867 6.705 6.597 7.732 6.019 5.217 5.376 7.593 4.875 5.213 7.842 3.643 3.943 -1.323 6.360 4.822 5.313 5.225 6.133 7.998 -2.354 8.380 5.401 5.529 7.547 5.881 7.543 4.821 5.735 6.981 5.755 31.833 27.334 28.754 28.070 25.368 23.253 23.604 29.082 24.719 23.987 29.100 31.556 31.572 31.099 27.045 23.490 22.723 25.044 23.222 27.560 30.921 27.824 24.549 23.781 28.896 30.558 28.395 23.885 25.690 28.520 30.009 148.107 148.311 148.107 148.209 148.413 148.311 148.413 148.107 148.311 148.311 148.616 148.413 148.514 148.514 148.514 148.718 148.311 148.311 148.514 148.209 148.311 148.921 149.328 148.616 148.413 148.311 148.514 149.125 148.820 148.311 148.413 0.925 0.936 0.922 0.932 0.934 0.935 0.931 0.928 0.931 0.934 0.929 0.926 0.930 0.931 0.943 0.939 0.935 0.939 0.938 0.930 0.929 0.939 0.940 0.935 0.925 0.930 0.932 0.997 0.934 0.928 0.927 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00130 PCS Phosphates Raw FTIR Data Spectrum RUN#5_0032.LAB RUN#5_0033.LA8 RUN#5_0034.LAB RUN#5_0035.LA8 RUN#5_0036.LA8 RUN#5_0037.LA8 RUN#5_0038.LAB RUN#5_0039.LA8 Run #5 Post Test Spike RUN#5 QA_0001.LA8 RUN#5 QA_0002.LAB RUN#5 QA_0003.LAB RUN#5 QA_0004.LA8 RUN#5 QA_0005.LAB RUN#5 QA_0006.LAB RUN#5 QA_0007.LA8 RUN#5 QA_0008.LA8 RUN#5 QA_0009.LAB RUN#5 QA_0010.LAB RUN#5 QA_0011.LAB RUN#5 QA_0012.LAB RUN#5 QA_0013.LA8 RUN#5 QA_0014.LAB RUN#5 QA_0015.LA8 RUN#5 QA_0016.LA8 RUN#5 QA_0017.LA8 RUN#5 GA_0018.LA8 RUN#5 QA_0019.LAB RUN#5 QA_0020.LA8 RUN#5 QA_0021.LAB RUN#5 QA_0022.LAB RUN#5 QA_0023.LAB RUN#5 QA_0024.LA8 RUN#5 QA_0025.LAB RUN#5 QA_0026.LA8 Run #6 RUN#6_0002.LAB RUN#6_0003.LA8 RUN#6_0004.LAB RUN#6_0005.LA8 RUN#6_0006.LAB RUN#6_0007.LA8 RUN#6_0008.LA8 RUN#6_0009.LA8 RUN#6_0010.LAB RUN#6_0011.LA8 RUN#6_0012.LAB RUN#6_0013.LA8 RUN#6_0014.LA8 RUN#6_0015.LA8 RUN#6_0016.LA8 RUN#6_0017.LAB RUN#6_0018.LAB RUN#6_0019.LA8 RUN#6_0020.LAB RUN#6_0021.LAB RUN#6_0022.LAB RUN#6_0023.LAB RUN#6_0024.LA8 RUN#6_0025.LA8 RUN#6_0026.LA8 RUN#6_0027.LAB RUN#6_0028.LAB RUN#6_0029.LA8 RUN#6_0030.LA8 RUN#6_0031.LAB RUN#6_0032.LAB RUN#6_0033.LA8 RUN#6_0034.LA8 RUN#6_0035.LAB RUN#6_0036.LAB RUN#6_0037.LAB RUN#6_0038.LAB RUN#6_0039.LA8 RUN#6_0040.LAB RUN#6_0041.LAB RUN#6_0042.LA8 RUN#6_0043.LA8 RUN#6_0044.LA8 RUN#6_0045.LAB RUN#6_0046.LA8 RUN#6_0047.LAB RUN#6_0048.LA8 RUN#6_0049.LA8 RUN#6_0050.LA8 RUN#6_0051.LAB RUN#6_0052.LA8 RUN#6_0053.LAB RUN#6_0054.LAB RUN#6_0055.LA8 Run #6 Post Test Spike RUN#6 QA_0001.LAB RUN#6 QA_0002.LAB RUN#6 QA_0003.LAB RUN#6 QA_0004.LA8 RUN#6 QA_0005.LAB RUN#6 QA_0006.LAB RUN#6 QA_0007.LA8 RUN#6 QA_0008.L4B RUN#6 QA_0009.LAB RUN#6 QA_0010.LAB RUN#6 QA_0011.LAB RUN#6 QA_0012.LAB RUN#6 QA_0013.LAB RUN#6 QA_0014.LAB RUN#6 QA_0015.LA8 RUN#6 QA_0016.LAB RUN#6 QA_0017.LAB RUN#6 QA_0018.LAB RUN#6 QA_0019.LAB RUN#6 QA_0020.LAB RUN#6 QA_0021.LAB Run #6 Post Test CTS RUN#6 CTS_0001.LAB RUN#6 CTS_0002.LAB RUN#6 CTS_0003.LAB Date Time 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 5:32:40 PM 5:33:38 PM 5:34:36 PM 5:35:34 PM 5:36:32 PM 5:37:30 PM 5:38:28 PM 5:39:26 PM HF (ppm) -0.062 -0.076 -0.045 0.001 0.025 -0.077 -0.070 -0.070 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 5:42:11PM 5:43:09 PM 5:44:07 PM 5:45:05 PM 5:46:03 PM 5:47:01 PM 5:47:59 PM 5:48:57 PM 5:49:55 PM 5:50:53 PM 5:51:51PM 5:52:50 PM 5:53:48 PM 5:54:46 PM 5:55:44 PM 5:56:42 PM 5:57:40 PM 5:58:38 PM 5:59:36 PM 6:00:34 PM 6:01:32 PM 6:02:30 PM 6:03:28 PM 6:04:26 PM 6:05:54 PM 6:06:52 PM -0.032 0 151 0 582 0 639 0 661 0 702 0 733 0 835 0 961 1 066 1 132 1 132 0 982 0 952 0 942 0 957 1 052 0 644 0 286 0 175 0 087 -0.009 -0.039 -0.061 -0.052 0.038 SF6 (ppm) 0 035 0 039 0 036 0 038 0 034 0 046 0 042 0 043 0 046 0 605 0 703 0 679 0 669 0 659 0 664 0 666 0 680 0 700 0 714 0 690 0 673 0 652 0 655 0 649 0 680 0 098 0 043 0 038 0 044 0 044 0 046 0 040 0 044 0 036 SiF4 (ppm) 0 012 0 008 0 012 0 007 0 013 0 010 0 002 0 012 CO (ppm) 138.636 126.611 131.145 167.164 118.645 158.568 136.913 134.605 0 010 0 010 0 007 0 007 0 013 0 009 0 012 0 015 0 010 0 004 0 005 0 011 0 003 0 006 0 009 0 007 0 012 0 008 0 015 0 006 0 017 -o 001 0 008 0 012 0 007 0 009 119.705 101.195 128.618 127.661 112.073 121.069 122.555 114.787 111.569 115.914 106.137 136.029 129.098 114.229 127.423 121.320 106.104 120.580 117.948 146.084 125.359 147.969 129.590 148.330 126.610 120.987 C02 (%) 5 025 4 780 5 012 5 307 4 590 5 410 44 875 865 4 884 4 280 4 962 4 836 4 429 4 619 4 624 4 451 4 535 4 578 4 415 4 869 4 733 4 313 4 688 4 489 4 326 4 877 4 800 5 310 4 706 5 170 4 963 4 991 4 803 4 856 CH4 (ppm) 6 303 6 253 7 229 7 578 7 075 7 407 6 999 6 424 6 529 6 287 6 416 6 269 5 623 5 960 5 863 5 296 5 609 5 791 6 056 5 853 5 758 5 483 5 747 5 813 5 422 6 811 6 077 7 168 6 660 6 532 6 934 6 708 6 907 6 225 NH3 (ppm) -0.086 0.026 -0.011 -0.143 0.033 -0.145 -0.284 -0.056 HCi (ppm) -0.190 -0.177 -0.212 -0.165 -0.166 -0.199 -0.180 -0.189 -0.129 -0.171 -0.262 -0.340 -0.160 -0.212 -0.164 -0.181 -0.294 -0.291 -0.164 -0.405 -0.347 -0.398 -0.078 -0.275 -0.048 -0.024 0.016 -0.156 0.060 -0.070 -0.031 0.025 0.028 -0.115 -0.470 -0.455 -0.486 -0.472 -0.447 -0.463 -0.455 -0.434 -0.451 -0.421 -0.449 -0.321 -0.470 -0.457 -0.470 -0.502 -0.423 -0.491 -0.429 -0.477 -0.511 -0.505 -0.512 -0.514 -0.452 -0.472 N20 (ppm) 16.060 17.027 15.140 16.353 17.487 15.946 15.942 15.184 NO (ppm) 61.118 64.264 56.979 50.647 62.220 53.915 58.026 61.157 15.511 15.432 14.317 14.656 15.088 13.562 14.690 14.494 14.209 14.299 14.716 14.907 14.290 14.703 13.345 13.977 13.993 14.251 16.068 15.417 16.474 15.285 14.587 15.667 15.112 15.532 58.995 62.403 53.745 51.957 58.023 59.849 55.508 57.161 56.902 53.268 56.670 55.073 51.990 61.882 54.968 55.495 60.895 58.958 65.245 61.319 63.959 59.217 58.066 59.790 58.452 62.094 N02 (ppm) 6 014 7 224 5 092 6 871 5 001 5 758 -0.456 -0.498 H20 (%) 30.028 30.487 28.254 25.973 24.631 29.009 31.024 31.145 26.164 22.160 23.748 28.053 28.532 28.488 28.493 27.761 24.115 22.160 21.141 24.872 28.448 28.613 29.318 28.906 25.510 24.587 23.199 26.952 29.564 30.843 31.742 31.565 27.621 24.378 Tremc)p 148.311 148.413 148.514 148.616 148.820 148.820 148.718 148.311 Pressure (atm) 0 928 0 933 0 934 0 932 0 936 0 927 0 928 0 927 148.514 148.718 148.718 148.820 148.820 148.514 148.718 148.820 148.820 149.023 148.921 148.820 148.718 148.616 148.718 148.718 148.718 148.921 148.921 148.820 148.921 148.820 148.718 148.718 148.718 148.921 0 932 0 936 0 930 0 926 0 929 0 927 0 928 0 930 0 936 0 938 0 936 0 932 0 928 0 927 0 926 0 931 0 935 0 936 0 934 0 929 0 933 0 923 0 925 0 922 0 935 0 941 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 6:24:09 PM 6:25:07 PM 6:26:05 PM 6:27:03 PM 6:28:01 PM 6:28:59 PM 6:29:57 PM 6:30:55 PM 6:33:20 PM 6:34:18 PM 6:35:16 PM 6:36:14 PM 6:37:13 PM 6:38:11PM 6:39:38 PM 6:40:36 PM 6:41:34 PM 6:42:32 PM 6:43:59 PM 6:44:57 PM 6:45:55 PM 6:47:22 PM 6:48:20 PM 6:49:18 PM 6:50:17 PM 6:51:15 PM 6:52:13 PM 6:53:11PM 6:54:09 PM 6:55:36 PM 6:56:34 PM 6:57:32 PM 6:58:30 PM 6:59:28 PM 7:00:26PM 7:01:24PM 7:04:53 PM 7:05:51PM 7:06:49 PM 7:07:47 PM 7:08:45 PM 7:10:12 PM 7:11:11PM 7:12:09 PM 7:13:07 PM 7:14:05 PM 7:15:03 PM 7:16:01PM 7:16:59 PM 7:17:57 PM 7:18:55 PM 7:19:53 PM 7:20:51PM 7:21:49 PM -0.026 -0.028 -0.048 -0.054 0.015 0.041 0.059 0.049 -0.038 -0.047 -0.055 0.041 0.047 0.039 -0.037 -0.064 -0.058 -0.061 0.025 0.056 0.041 -o 053 -o 070 -o 053 -o 057 -o 016 0.023 0.042 -o Oil -o 059 -o 073 -o 078 -o 065 0.000 0.025 0.017 -0.073 -0.071 -0.002 0.046 0.030 -o 057 -o 081 -o 063 -o 040 -o 031 0 033 -o 020 -o 069 -o 084 -o 077 -o 057 0.011 0.021 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 4/4/2014 7:25:02 PM 7:26:00 PM 7:26:58 PM 7:28:25 PM 7:29:23 PM 7:30:21PM 7:31:19 PM 7:32:17 PM 7:33:16 PM 7:34:14PM 7:35:12 PM 7:36:10PM 7:37:08 PM 7:38:35 PM 7:40:31PM 7:41:29 PM 7:42:27 PM 7:43:25 PM 7:44:23 PM 7:45:22 PM 7:46:20 PM 0 370 0 559 0 629 0 862 0 994 1 026 0 950 0 864 0 897 0 950 1 056 1 117 1 180 1 029 0 954 0 911 0 344 0 226 0 150 0 074 0 018 4/4/2014 4/4/2014 4/4/2014 7:55:01PM 7:55:59 PM 7:56:57 PM -0.003 -0.020 0.010 0 049 0 044 0 037 0 045 0 046 0 042 0 042 0 040 0 044 0 043 0 046 0 038 0 033 0 040 0 041 0 043 0 044 0 042 0 040 0 036 0 046 0 037 0 041 0 043 0 045 0 035 0 035 0 033 0 048 0 034 0 033 0 045 0 034 0 035 0 040 0 042 0 043 0 041 0 037 0 033 0 034 0 042 0 036 0 035 0 043 0 036 0 035 0 044 0 040 0 045 0 040 0 042 0 035 0 031 0 650 0 648 0 651 0 669 0 680 0 667 0 648 0 646 0 656 0 669 0 653 0 668 0 678 0 647 0 628 0 470 0 030 0 031 0 037 0 034 0 033 -0.001 -0.001 -0.002 0 022 0 014 0 Oil 0 014 0 018 0 016 0 014 0 020 0 007 0 Oil 0 013 0 Oil 0 019 0 016 0 013 0 Oil 0 009 0 010 0 009 0 009 0 017 0 015 0 007 0 004 0 015 0 016 0 Oil 0 006 0 010 0 013 0 017 0 016 0 009 0 010 0 017 0 010 0 008 0 010 0 008 0 013 0 017 0 012 0 017 0 010 0 015 0 010 0 012 0 014 0 018 0 016 0 Oil 0 015 0 013 0 008 0 Oil 0 007 0 016 0 008 0 014 0 012 0 014 0 013 0 010 0 009 0 014 0 014 0 007 0 012 0 012 0 Oil 0 012 0 Oil 0 013 0 009 0 004 0.002 0.002 0.001 128.166 125.397 132.452 137.973 129.860 128.743 121.132 117.450 141.211 140.548 130.121 129.742 118.515 132.922 125.180 126.162 128.765 128.923 126.472 121.039 114.424 127.304 125.917 131.399 128.252 114.204 121.981 107.464 128.875 139.396 122.163 137.754 115.735 109.754 122.525 120.025 121.566 124.019 121.410 112.256 113.497 120.548 113.258 126.255 134.751 116.770 109.278 118.930 126.033 123.062 122.392 116.545 105.000 112.280 114.058 114.651 125.407 107.760 102.675 107.161 110.913 110.302 112.788 133.804 98.089 98.105 110.464 116.357 108.943 121.330 112.973 118.735 116.716 122.359 119.709 13.570 13.898 13.935 4 938 4 706 4 788 4 762 4 742 4 883 4 794 4 682 4 947 5 020 4 883 4 836 4 595 5 092 4 745 4 869 4 703 4 742 4 995 4 819 4 839 4 941 4 802 4 893 4 852 4 663 4 927 4 574 5 081 4 949 4 780 5 103 4 780 4 721 5 077 5 002 4 862 4 838 4 974 4 934 4 844 4 912 4 667 4 884 5 058 4 904 4 810 4 991 5 002 4 814 4 786 4 861 4 638 4 914 4 409 4 443 4 780 4 542 4 374 4 557 4 501 4 435 4 429 4 899 4 090 4 337 4 565 4 603 4 362 4 712 4 611 4 801 4 954 45 000 877 0.000 0.000 0.000 7 219 6 835 6 184 6 886 6 477 6 450 7 433 6 192 7 045 7 218 6 696 6 380 6 702 6 942 6 650 6 330 7 131 6 729 6 841 7 156 6 945 6 571 6 659 6 583 7 407 6 697 7 573 6 719 7 297 6 711 6 275 6 941 6 928 6 276 7 926 7 722 7 183 6 809 6 554 6 247 6 233 6 461 6 714 7 238 7 946 7 234 6 725 6 657 6 957 7 471 7 021 7 424 6 264 5 630 5 921 5 746 6 809 6 223 5 836 6 400 6 039 6 656 6 486 6 897 6 201 5 935 6 540 6 623 6 396 6 427 6 746 6 908 7 182 7 235 6 821 0.071 0.120 -0.102 -0.049 -0.080 -0.132 0.002 -0.126 -0.104 -0.261 -0.040 -0.050 -0.274 -0.072 -0.101 -0.074 0.024 -0.061 -0.198 -0.095 -0.039 -0.072 -0.130 -0.022 -0.059 0.002 -0.087 -0.080 0.055 -0.240 -0.219 -0.185 0.131 -0.078 -0.048 0.107 -0.071 -0.210 -0.025 -0.028 -0.146 -0.134 0.192 -0.063 -0.190 -0.035 -0.096 -0.121 0.034 -0.045 0.034 -0.140 -0.143 -0.045 -0.102 -0.041 -0.122 -0.152 -0.372 -0.135 -0.393 -0.239 -0.257 -0.052 -0.179 -0.167 -0.406 -0.230 -0.243 -0.312 -0.266 -0.142 -0.172 0.115 -0.186 -0.020 -0.307 0.010 -0.004 -0.031 -0.019 -0.213 -0.180 -0.192 -0.147 -0.146 -0.155 -0.176 -0.158 -0.174 -0.159 -0.163 -0.136 -0.140 -0.161 -0.186 -0.154 -0.168 -0.141 -0.126 -0.174 -0.143 -0.131 -0.184 -0.162 -0.180 -0.167 -0.147 -0.126 -0.175 -0.156 -0.109 -0.182 -0.142 -0.153 -0.160 -0.122 -0.173 -0.165 -0.114 -0.116 -0.114 -0.146 -0.146 -0.186 -0.159 -0.166 -0.120 -0.167 -0.149 -0.146 -0.152 -0.188 -0.122 -0.144 -0.381 -0.351 -0.388 -0.396 -0.379 -0.360 -0.365 -0.427 -0.408 -0.391 -0.347 -0.354 -0.374 -0.393 -0.443 -0.400 -0.389 -0.384 -0.409 -0.456 -0.433 -0.008 0.028 -0.009 15.505 15.537 15.091 15.757 15.704 15.332 15.919 17.397 15.380 15.453 15.837 15.672 16.020 16.490 16.319 15.056 15.615 16.214 14.894 16.280 17.355 15.929 15.033 15.194 15.300 16.401 15.345 16.514 15.897 15.654 16.497 15.203 17.226 16.707 15.698 17.480 16.090 16.017 16.687 15.798 16.513 15.422 15.660 14.827 15.109 16.371 17.063 16.502 15.457 15.179 15.248 15.736 16.861 16.027 14.721 14.627 14.092 13.853 15.772 15.496 15.463 15.456 14.936 14.189 15.766 15.427 15.035 15.059 16.006 15.217 17.400 16.722 17.258 17.229 16.590 -0.042 -0.048 -0.042 62.623 64.476 65.355 60.158 62.332 59.485 59.074 70.021 59.536 56.785 60.861 57.987 71.129 61.350 64.418 63.069 64.089 65.536 59.067 62.352 63.820 63.867 63.262 58.066 61.101 63.698 56.894 67.980 64.562 58.794 64.327 58.856 63.630 65.357 60.870 62.176 63.283 69.192 58.480 63.490 67.467 67.846 69.384 67.243 57.842 60.661 68.540 67.452 66.079 64.163 66.458 62.465 70.501 65.962 63.565 63.807 54.395 62.096 65.557 61.388 65.298 63.434 64.335 53.776 64.822 67.736 63.883 60.208 61.766 60.110 69.664 68.621 69.364 70.688 67.971 16.939 16.934 17.004 6 088 3 773 2 071 2 885 7 155 4 673 5 510 5 084 4 624 3 048 6 824 5 789 4 518 5 435 6 200 4 740 3 556 4 958 5 478 4 691 4 728 5 601 0 567 2 506 2 628 5 318 5 834 3 756 7 099 7 361 0 689 1 833 5 874 3 237 4 729 5 102 6 276 4 027 4 358 4 041 5 164 5 478 4 320 5 772 4 997 4 019 4 447 4 254 4 170 -2 226 5 647 5 537 4 249 4 245 30.482 31.581 31.730 31.326 28.305 25.712 24.066 25.822 30.531 31.094 29.689 26.479 24.051 25.565 30.554 31.413 31.214 30.441 26.018 24.159 24.455 30.015 31.313 31.553 31.175 27.508 25.075 23.108 26.675 30.453 30.913 31.755 29.742 26.568 24.561 24.029 30.726 30.453 27.164 24.539 25.364 30.180 30.527 30.180 29.176 26.263 23.951 27.565 30.017 30.904 30.124 27.714 25.088 23.595 28.707 28.382 28.150 24.038 22.194 23.517 27.501 28.117 28.172 27.808 24.176 22.030 21.936 27.088 28.883 29.594 27.653 25.203 24.798 28.735 30.334 -0.006 0.007 0.000 148.820 148.820 148.820 148.820 148.718 148.820 148.718 148.718 148.718 148.718 148.514 148.616 148.718 148.718 148.514 148.514 148.616 148.616 148.718 148.820 148.718 148.718 148.718 148.718 148.718 148.921 148.718 148.718 148.820 148.718 148.820 148.718 148.718 148.718 148.921 148.718 148.820 148.718 148.718 148.921 148.820 148.718 148.718 148.820 148.718 148.718 148.718 148.718 148.718 148.718 148.820 148.820 148.718 148.718 149.023 148.921 149.023 148.921 148.921 148.820 148.820 148.921 148.820 148.820 148.718 148.820 148.718 148.718 148.718 149.125 149.125 148.921 148.514 148.514 148.514 148.921 149.023 149.125 0 926 0 925 0 924 0 929 0 929 0 934 0 934 0 930 0 926 0 927 0 928 0 933 0 933 0 929 0 929 0 925 0 926 0 929 0 934 0 932 0 930 0 924 0 922 0 924 0 934 0 935 0 933 0 937 0 930 0 929 0 930 0 921 0 930 0 933 0 932 0 932 0 924 0 922 0 934 0 931 0 937 0 930 0 932 0 933 0 934 0 931 0 930 0 929 0 926 0 925 0 938 0 935 0 935 0 937 0 926 0 932 0 929 0 937 0 935 0 940 0 932 0 932 0 925 0 927 0 936 0 936 0 933 0 930 0 930 0 929 0 936 0 935 0 935 0 927 0 927 1 014 1 015 015 17cv1906 Sierra Club v. EPA- 6/22 Production ED 001523 00007569-00131 Example Calculations. Based on Run #1 Barometric Pressure at the Sampling Location, Corrected (EPA Method 2, Section 6.5) Pbar = Pbar,meas - (E!ev x 0.1/100) Pbar,meas = Barometric pressure as measured E!ev = elevation of sampling location relative to barometer Pbar = Barometric pressure at the sampling site 29.89 100 29.79 in. Hg feet in. Hg Pbar = 29.89 100 x 0.1 100 Pbar = 29.79 Absolute Stack Pressure (EPA Method 2, Section 6.5) Pbar = Barometric pressure at the sampling site = Pg = Stack Static Pressure = Ps = Absolute Stack Pressure = in. Hg in. Hg in. Hg Ps = 29.77 Volume of Water Vapor Condensed, corrected to standard conditions, ft3 (US EPA Method 4, Sect. 12.1.2 and 12.1.3) Vw(std) = K3 x (Wf-Wi) K3 = Conversion Constant = (Wf - Wi) = Total weight of liquid collected = 0.04715 Vw(std) = 0.04715 x Vw(std) = 14.03 ft3 Moisture Content, proportion, by volume (US EPA Method 5, Eq. 5-3) Vw(std) Vw(std) = Volume of water vapor condensed Vm(std) = Dry Gas Volume Bws ________ 14.027_________ 33.885 + 14.027 Bws = 0.2928 Moisture content at saturation: From ASME 1967 Steam Tables (Lookup Table) Bws (sat) = 26.064 0.3 For further calculations: Bws = 0.293 29 Dry Molecular Weight of Stack Gas, Ib/lb-mole (US EPA Method 3, Eq. 3-1) Md = MWC02(%C02) + MW02(%02) + MWN2(%N2) MWC02= Molecular weight of C02, divided by 100 %C02 = Percent C02 by volume, dry basis MW02 = Molecular weight of 02, divided by 100 %02 = Percent 02 by volume, dry basis MWN2 = Molecular weight of N2, divided by 100 2 = 100% - %CO - %C02 - %02 - %H2 - %CH4 Md =( 0.44 6.1 ) + ( 0.32 Md = 29.56 ib/lb-mole 0,44 ib/ib-mole 6.1 % 0,32 ib/ib-mole 14.7 % 0,28 ib/lb-mole 79.3 % 14.7 ) + ( 0.28 79.3 ) Calciner3_M13B_040414.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Example Calculations ED 001523 00007569-00132 Molecular Weight of stack gas, Ib/lb-mole (US EPA Method 2, Eq. 2-6) Ms Md (1-Bws)+18.0(Bws) Md= Dry molecular weight of stack gas Bws= Proportion of water vapor, by volume 18.0 = Molecular Weight of H20 Ms 29.56 x { 1 - 0.261 ) + { 18.00 x 0.261 ) Ms 26.54 Dry Gas Volume, corrected to actual conditions, ft3 Vm(actual) = Vm x Y Vm = Volume of gas sample, dry Y = Dry gas meter calibration factor Vm(actual) = 36.119 x 0.9808 Vm(actual) = 35.426 Dry Gas Volume, corrected to standard conditions, ft3 (US EPA Method 5, Eq. 5-1) Vm(std) = Vm Y x Tstd x (Pbar + (deitaH / 13.6)) Tm xPstd Vm = Volume of gas sample, dry Y = Dry gas meter calibration factor Tstd = Standard Temperature Pbar = Barometric pressure at the sampling site DH = Average pressure differential across the orifice meter 13.6 = Conversion factor Tm = Absolute average DGM temperature 36.119 0,9808 528.0 ft3 deg R 29.79 in. Hg 1.28 in. H20 13.6 in. H20/in. Hg 551.3 deg R Vm(std) = 36.119 Vm(std) = 33.885 528.0 551.3 29.79 + ( 1,28 29.92 13.6 )) Average Stack Gas Velocity, ft/sec (US EPA Method 2, Eq. 2-7) vs = Kp x Cp x SqrtDPavg x sqrt(Ts/(Ps x Ms)) Kp= Velocity equation constant Cp = S type pitot tube coefficient SqrtDPavg=ave. sqrt. of the velocity head of stack gas Ts = Absolute stack temperature Ps = Absolute stack pressure Ms = Molecular Weight of stack gas vs = 85.49 0.84 85.49 0,84 0,58 611.04 29.77 26.54 ft/sec[((lb/lb-mole)(in.Hg))/((degR){in.H20))]1/2 in.H20 deg R in. Hg ib/lb-mole -)0.5 vs = vs = 36.39 ft/sec 2,184 ft/min Average Stack Gas Volumetric Flow Rate, Actual Conditions Qactual vs A vs = Average stack gas velocity A = Cross sectional area of stack 36.39 ft/sec 28.27 ft2 Qactual = Qactual = Qactual = Qactual = 36.39 28.27 1029 cubic feet per second 61,740 cubic feet per minute 3,704,400 cubic feet per hour Calciner3_M13B_040414.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Example Calculations ED 001523 00007569-00133 Average Stack Gas Dry Volumetric Flow Rate, dscf/hr { US EPA Method 2, Eq. 2-8) Q = 3600 x (1-Bws) x vs x A x Tstd x Ps Ts x Pstd 3600= Conversion factor Bws = Proportion of water vapor, by volume vs= Average stack gas velocity A = Cross sectional area of stack Tstd = Standard absolute temperature Ps = Absolute stack pressure Ts = Absolute stack temperature Pstd = Standard absolute pressure 3600 0.293 36.39 28.27 528 29.77 611.0 29.92 sec/hr proportion ft/sec ft2 degR in. Hg degR in. Hg Qs = 3600 1,00 Qs = 2,252,659 dscf/hr = 37,544 dscf/min 0.293 ) x 611.0 x 36.39 29.92 28.274 Average Stack Gas Wet Basis Volumetric Flow Rate (scf/hr) Qw =_____ Q (1-Bws) Q = Average Stack Gas Dry Volumetric Flow Rate Bws = Proportion of water vapor, by volume 2,252,659 dscf/hr 0,293 proportion Qw = 2,252,659 { 1.00 - Qw = 3,185,169 wscf/hr = 53,086 wscf/min 0.293) Isokinetic Variation, % (US EPA Method 5, Eq. 5-8) ! _ 100 x Ts x Vm(std) x Pstd 60 x Tstd x Ps x vs x An x min x (1 - Bws) 100 = Conversion to Percent = Ts = Absolute stack temperature = Vm(std) = Dry Gas Volume = Pstd = Standard absolute pressure = 60 = Sec/Min = Tstd = Standard absolute temperature = Ps = Absolute stack pressure = vs = Average stack gas velocity = An = Cross-sectional Area of nozzle = min = Total sampling time = Bws = Proportion of water vapor, by volume = 100 611.0 degR 33.885 ft3 29.92 in. Hg 60 Sec/Min 528.00 degR 29.77 in. Hg 36.39 ft/sec 0.000415 ft2 60 minutes 0.261 proportion . 100 x 611.0 x 33.885 60.00 x 528.00 x 29.77 x 36.39 x 0.000415 I 97.92 Calciner3_M13B_040414.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Example Calculations ED 001523 00007569-00134 Post-Test Calibration Check (US EPA Guideline Document EMTIC GD-26) Yqa = min / Vm _______ 0.0319 x Tm DH@ x (Pbar + DH/13.6) 29 (DH)1/2avg Md min = Total sampling time Vm(actual) = Dry gas volume, actual conditions Tm = Absolute average DGM temperature DH@ = Meter orifice pressure at 0.75 ft3/min sampling rate Pbar = Barometric pressure at the sampling site DH = Average pressure differential across the orifice meter (DH)1/2avg = Average of square root values of DH Md= Dry molecular weight of stack gas 60 36.119 551.3 1.91 minutes ft3 degR in. H20 29.79 in. Hg 1.28 in. H20 1.122 29.56 ib/lb-mole Yqa = min / Vm 0.0319 x 551.333 1.91 x (29.79 + 1.28/13.6) 29 29.56 1.122 Yqa = 1.025 Concentration Calculation ppmv Mpoll x (T(K) + C) (CF)(MW) Mass units of measurement: mg/dscm Pollutant species Fluoride Mpoll = mass of pollutant in recovered sample T = Std Temperature C = Ambient Temperature CF = Conversion factor MW = Molecular weight of gas 0,715 273.15 20 12.187 18.998 mg/dscm K Ce 0.715 x 2.93E+02 231.534 Ce = 0.905 ppmv Oxygen Correction Calculation C@ x% 02 = Ce x (20.9-CBQ2) (20.9-02) Ce = concentration of specified pollutant emitted CB02 = Oxygen concentration correction basis 02 = Measured oxygen concentration 9.05E-01 ppm 3 % 02 14.7 % C@ 3%02 = 9.05E-01 (20.9 - 3) (20.9-14.70) C@ 3%02 = 2.61 ppmv @3% 02 Calciner3_M13B_040414.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Example Calculations ED 001523 00007569-00135 mMMQMMMRm Aurora Division Date Tech start Stop /J&7 Refrig.... ^ oC Non-Routine Water Analyses F- Meter Calib 0.3 ppm F- O 'H'i MV= A?/$ n/a Notes /&<////#;&/ &//20/y7 1 ppm F- 1.0^ MV= j p6>&' 10 ppm F- m- V3,/ 5~fb 1 y1 1 //KTOmA fjrptix fadO Crv. Siooe^y MV 0.1 ppm= 0`99?J fSeM(dbvA'- Std. Methods Sample location Test-1 Test-2 Test-3 Test-4 Test-4 (0) ^ 47? 7 4500 F L Fluorides (2 dec.) 8&?S. mu- 0/7?, * ~w. /67/p 9A/9 a/9f 7)P oj/r/ n/s? 7/p n/'47 4o mf9/ 79.9?/ IDS 2540 C TSS 2540 C DMRQA /0!/p. *//.77 Dup. { ) 3t.d. Wt.(gms): ct Wt(gms): W)esP#fect?osyertis 2.0 P 0.1 mg/I F~ 0.1 mg/I Total Hat dness 0 - 200 mg/I osisjjtoiwn? TDS 10.0 mg/I (Rd.Out x DU.) Hardness TSS 4.0 mg/I Id.Out x 5Q)/Aliq. Titr x 40 TDS = (Wt 2 - Wt 1)x(1x1QAS)/Wt 1 TSS = (Final- Tare)x(1x10A6)/aliq F- ig* P i'.ifj;! m OA Sl3. 'M/ Tatt VSSttiSS- Lrs: Nos. 7M/s 7 ...... TH i.iij/1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00136 A Waters Company Stationary Source Audit Program Data Reporting Form Project#: 031114R Lab Name: URS Corporation ERA Customer Number: U119153 INSTRUCTIONS: Please fill in the results, methods references and analysis dates for the analyte(s) you wish to report for Project #031114R. Questions? See the Data Reporting Instructions section of your Data Package or call ERA at 1-800-372-0122. Please photocopy this form if you are reporting multiple methods. Stationary Source Audit Program Fluoride in Impinger Solution (cat# 1141) Method DescrlpttonJjjZ!pi'fV E'"T* H' O' 0 ;| `tb'Q ': flev/Edj ; ` : Analysis Date (mm-dd) Analyst PCS' ! fjj workgroup ; ' : ; TNI Code 1730 Fluoride Analyte | Units | mg/dscm PTRL 0.850 | Concentration Range j 1.00 to 50.0 Reported Value : : : :Ov4*1; P 4 Of 4 16341 Table Mountain Pkwy * Golden, CO 80403 * 800.372.0122 * 303.431.8454 * fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00138 A Waters Company Packing Slip Bill To: URS Corporation 1600 Perimeter Park Suite 400 Morrisvilie, NC, USA 27560 Accounts Payable invoice # Customer# Date Page 715990 U119153 3/11/2014 1 of 1 Project # Ship To: PCS Phosphate Aurora 1530 NC Hwy 306 S Aurora, NC, USA 27806 031114R Jimmy Hardy Email Address: stephanie.chesebro@urs.com Order Comments: TPID: 31829570.0006fiffiK|M13b BBBI^^^^BP Oust Svc Rep Payment Terms Shipping Method NET 30 FEDEX SOS QTY CAT# Product 1 1441 Fluoride in Impinger Solution (919) 461-1539 '1281119* Purchase Order # Order# 31829570.0006 EP-407 1-5DDWOYQ31114FS Type PT Lot# 110-1141 REQUEST Study# SSAP110 REPORT ANY PROBLEMS WITHIN 5 DAYS Please check all items in the shipment against the attached packing list immediately upon receipt. ERA will immediately replace any broken or incorrect items related to this shipment that are reported within 5 business davs. CALL ERA CUSTOMER SERVICE AT 1-888-372-0122 FOR PROBLEMS WITH THIS SHIPMENT 17cv1906 Sierra Club v. EPA - 6/22 Production All products Country of Origin: USA Unless otherwise specified. 715990 ED 001523 00007569-00139 A Waters Company Jimmy Hardy PCS Phosphate 1530 NC Hwy 306 S Aurora, NC 27806 Air and Emissions Proficiency Testing 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00140 A Waters Company 031114R Evaluation Final Complete Report Jimmy Hardy PCS Phosphate 1530 NC Hwy 306 S Aurora, NC 27806 252-322-8154 EPA ID: ERA Customer Number: Not Reported T217202 TNI Analyte Code Analyte Units Reported Value Assigned Value Acceptance Limits Performance Evaluation Method Description Analysis Date SSAP Fluoride in Impinger Solution (cat# 1141) Study Dates: 03/11/14 - 04/15/14 1730 Fluoride mg/dscm 0.491 0.499 0.424-0.574 Acceptable EPA 13B 2000 4/7/2014 Z Score 0 Study Mean Study Standard Deviation Analyst Name PCS 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production Page 3 of 3 0$^) ED 001523 00007569-00141 Attach ment C Process Data 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00142 Caiciner No. 2 (EP ID No. 202) Time Phosphate ore mass flow rate to the caiciner Beneficiated rock mass flow rate to the Product mass flow rate from the caiciner Phosphate ore moisture content Beneficiated rock moisture content 3/30/14 0:00 (tons/hr) 26.7 (tons/hr) 23.4 (tons/hr) 21.6 (%> 12.2 (%> 12.2 3/30/14 1:00 23.7 20.8 19.2 12.2 12.2 3/30/14 2:00 20.8 18.2 16.8 12.2 12.2 3/30/14 3:00 17.8 15.6 14.4 12.2 12.2 3/30/14 4:00 14.8 13.0 12.0 12.2 12.2 3/30/14 5:00 11.8 10.4 9.6 12.2 12.2 3/30/14 6:00 8.9 7.8 7.2 12.2 12.2 3/30/14 7:00 5.9 5.2 4.8 12.2 12.2 3/30/14 8:00 2.9 2.6 2.4 12.2 12.2 3/30/14 9:00 15.3 13.4 12.4 12.2 12.2 3/30/14 10:00 38.6 33.9 31.3 12.2 12.2 3/30/14 11:00 17.6 15.5 14.3 12.2 12.2 3/30/14 12:00 16.1 14.1 13.0 12.2 12.2 3/30/14 13:00 40.5 35.6 32.9 12.2 12.2 3/30/14 14:00 31.6 27.7 25.6 12.2 12.2 3/30/14 15:00 15.3 13.4 12.4 12.2 12.2 3/30/14 16:00 25.3 22.3 20.5 12.2 12.2 3/30/14 17:00 48.1 42.3 39.0 12.2 12.2 3/30/14 18:00 45.3 39.8 36.7 12.2 12.2 3/30/14 19:00 42.4 37.3 34.4 12.2 12.2 3/30/14 20:00 39.6 34.7 32.1 12.2 12.2 3/30/14 21:00 36.7 32.2 29.7 12.2 12.2 3/30/14 22:00 33.8 29.7 27.4 12.2 12.2 3/30/14 23:00 31.0 27.2 25.1 12.2 12.2 3/31/14 0:00 28.1 24.6 22.7 12.4 12.4 3/31/14 1:00 25.2 22.1 20.4 12.4 12.4 3/31/14 2:00 22.4 19.6 18.1 12.4 12.4 3/31/14 3:00 19.5 17.1 15.8 12.4 12.4 3/31/14 4:00 16.6 14.6 13.5 12.4 12.4 3/31/14 5:00 13.8 12.1 11.1 12.4 12.4 3/31/14 6:00 10.9 9.6 8.8 12.4 12.4 3/31/14 7:00 8.1 7.1 6.5 12.4 12.4 3/31/14 8:00 5.2 4.6 4.2 12.4 12.4 3/31/14 9:00 2.3 2.0 1.9 12.4 12.4 3/31/14 10:00 32.4 28.4 26.2 12.4 12.4 3/31/14 11:00 49.6 43.5 40.1 12.4 12.4 3/31/14 12:00 48.7 42.7 39.4 12.4 12.4 3/31/14 13:00 47.7 41.8 38.6 12.4 12.4 3/31/14 14:00 46.7 41.0 37.8 12.4 12.4 3/31/14 15:00 45.8 40.1 37.0 12.4 12.4 3/31/14 16:00 44.8 39.3 36.3 12.4 12.4 3/31/14 17:00 49.2 43.1 39.8 12.4 12.4 3/31/14 18:00 48.2 42.2 39.0 12.4 12.4 3/31/14 19:00 46.3 40.6 37.5 12.4 12.4 3/31/14 20:00 44.5 39.0 36.0 12.4 12.4 3/31/14 21:00 42.6 37.3 34.5 12.4 12.4 3/31/14 22:00 40.7 35.7 32.9 12.4 12.4 3/31/14 23:00 38.9 34.1 31.4 12.4 12.4 4/1/14 0:00 37.0 32.4 30.4 12.4 12.4 4/1/14 1:00 35.1 30.8 28.8 12.4 12.4 4/1/14 2:00 33.3 29.2 27.3 12.4 12.4 4/1/14 3:00 31.4 27.5 25.8 12.4 12.4 4/1/14 4:00 29.5 25.9 24.3 12.4 12.4 PhosSURVEY_Process Parameter Test Data_ PCS Phosphte_Aurora_203.xisx 17cv1906 Sierra Club v. EPA - 6/22 Production Calciner2 ED 001523 00007569-00143 Caiciner No. 2 (EP ID No. 202) Time 4/1/14 5:00 4/1/14 6:00 4/1/14 7:00 4/1/14 8:00 4/1/14 9:00 4/1/14 10:00 4/1/14 11:00 4/1/14 12:00 4/1/14 13:00 4/1/14 14:00 4/1/14 15:00 4/1/14 16:00 4/1/14 17:00 4/1/14 18:00 4/1/14 19:00 4/1/14 20:00 4/1/14 21:00 4/1/14 22:00 4/1/14 23:00 4/2/14 0:00 4/2/14 1:00 4/2/14 2:00 4/2/14 3:00 4/2/14 4:00 4/2/14 5:00 4/2/14 6:00 4/2/14 7:00 4/2/14 8:00 4/2/14 9:00 4/2/14 10:00 4/2/14 11:00 4/2/14 12:00 4/2/14 13:00 4/2/14 14:00 4/2/14 15:00 4/2/14 16:00 4/2/14 17:00 4/2/14 18:00 4/2/14 19:00 4/2/14 20:00 4/2/14 21:00 4/2/14 22:00 4/2/14 23:00 4/3/14 0:00 Phosphate ore mass flow rate to the caiciner Beneficiated rock mass flow rate to the Product mass flow rate from the caiciner Phosphate ore moisture content Beneficiated rock moisture content (tons/hr) 27.7 (tons/hr) 24.2 (tons/hr) 22.7 (%> 12.4 (%> 12.4 25.8 22.6 21.2 12.4 12.4 23.9 21.0 19.7 12.4 12.4 22.1 19.3 18.1 12.4 12.4 20.2 17.7 16.6 12.4 12.4 18.3 16.1 15.1 12.4 12.4 16.5 14.4 13.5 12.4 12.4 14.6 12.8 12.0 12.4 12.4 12.7 11.2 10.5 12.4 12.4 10.9 9.5 8.9 12.4 12.4 9.0 7.9 7.4 12.4 12.4 7.1 6.3 5.9 12.4 12.4 5.3 4.6 4.3 12.4 12.4 3.4 3.0 2.8 12.4 12.4 1.5 1.3 1.3 12.4 12.4 32.2 28.2 26.4 12.4 12.4 56.4 49.4 46.3 12.4 12.4 59.6 52.2 49.0 12.4 12.4 59.8 52.4 49.1 12.4 12.4 59.9 53.3 49.9 11.1 11.1 60.1 53.4 50.0 11.1 11.1 60.2 53.5 50.1 11.1 11.1 60.4 53.7 50.3 11.1 11.1 60.5 53.8 50.4 11.1 11.1 60.6 53.9 50.5 11.1 11.1 61.9 55.0 51.5 11.1 11.1 47.6 42.3 39.7 11.1 11.1 53.7 47.7 44.7 11.1 11.1 43.7 38.8 36.4 11.1 11.1 28.1 25.0 23.4 11.1 11.1 12.6 11.2 10.5 11.1 11.1 21.7 19.3 18.1 11.1 11.1 40.4 35.9 33.7 11.1 11.1 24.8 22.1 20.7 11.1 11.1 26.7 23.8 22.3 11.1 11.1 27.3 24.3 22.7 11.1 11.1 10.6 9.4 8.8 11.1 11.1 30.0 26.6 25.0 11.1 11.1 47.2 42.0 39.4 11.1 11.1 55.1 49.0 45.9 11.1 11.1 32.1 28.6 26.8 11.1 11.1 59.4 52.8 49.5 11.1 11.1 59.3 52.7 49.4 11.1 11.1 54.8 48.4 45.3 11.6 11.6 PhosSURVEY_Process Parameter Test Data_ PCS Phosphte_Aurora_203.xisx 17cv1906 Sierra Club v. EPA - 6/22 Production Calciner2 ED 001523 00007569-00144 Caiciner No. 3 (EP ID No. 203) Time 4/2/14 12:00 4/2/14 13:00 4/2/14 14:00 4/2/14 15:00 4/2/14 16:00 4/2/14 17:00 4/2/14 18:00 4/2/14 19:00 4/2/14 20:00 4/2/14 21:00 4/2/14 22:00 4/2/14 23:00 4/3/14 0:00 4/3/14 1:00 4/3/14 2:00 4/3/14 3:00 4/3/14 4:00 4/3/14 5:00 4/3/14 6:00 4/3/14 7:00 4/3/14 8:00 4/3/14 9:00 4/3/14 10:00 4/3/14 11:00 4/3/14 12:00 4/3/14 13:00 4/3/14 14:00 4/3/14 15:00 4/3/14 16:00 4/3/14 17:00 4/3/14 18:00 4/3/14 19:00 4/3/14 20:00 4/3/14 21:00 4/3/14 22:00 4/3/14 23:00 4/4/14 0:00 4/4/14 1:00 4/4/14 2:00 4/4/14 3:00 4/4/14 4:00 4/4/14 5:00 4/4/14 6:00 4/4/14 7:00 4/4/14 8:00 4/4/14 9:00 4/4/14 10:00 4/4/14 11:00 4/4/14 12:00 4/4/14 13:00 4/4/14 14:00 4/4/14 15:00 4/4/14 16:00 4/4/14 17:00 4/4/14 18:00 4/4/14 19:00 4/4/14 20:00 4/4/14 21:00 Phosphate ore mass flow rate to the caiciner Beneficiated rock mass flow rate to the Product mass flow rate from the caiciner Phosphate ore moisture content Beneficiated rock moisture content (tons/hr) 18.7 (tons/hr) 16.5 (tons/hr) 15.4 (%> 11.9 (%> 11.9 58.9 51.9 48.6 11.9 11.9 37.7 33.2 31.1 11.9 11.9 16.5 14.5 13.6 11.9 11.9 37.9 33.4 31.3 11.9 11.9 59.7 52.6 49.2 11.9 11.9 60.6 53.4 50.0 11.9 11.9 61.7 54.3 50.9 11.9 11.9 62.8 55.3 51.8 11.9 11.9 63.9 56.3 52.8 11.9 11.9 64.6 56.9 53.3 11.9 11.9 62.9 55.4 51.9 11.9 11.9 61.0 53.9 50.5 11.6 11.6 61.0 53.9 50.5 11.6 11.6 61.5 54.4 50.9 11.6 11.6 62.0 54.8 51.3 11.6 11.6 62.5 55.2 51.7 11.6 11.6 63.0 55.6 52.1 11.6 11.6 63.4 56.1 52.5 11.6 11.6 63.9 56.5 52.9 11.6 11.6 64.4 56.9 53.3 11.6 11.6 55.8 49.3 46.2 11.6 11.6 37.9 33.5 31.4 11.6 11.6 20.4 18.0 16.9 11.6 11.6 11.5 10.2 9.5 11.6 11.6 34.8 30.7 28.8 11.6 11.6 57.3 50.6 47.4 11.6 11.6 24.5 21.6 20.3 11.6 11.6 52.0 46.0 43.1 11.6 11.6 56.8 50.2 47.0 11.6 11.6 51.8 45.8 42.9 11.6 11.6 40.5 35.8 33.5 11.6 11.6 29.2 25.8 24.2 11.6 11.6 17.9 15.8 14.8 11.6 11.6 6.6 5.8 5.5 11.6 11.6 27.8 24.6 23.1 11.6 11.6 28.4 24.9 23.4 12.2 12.2 68.4 60.1 56.3 12.2 12.2 112.3 98.6 92.3 12.2 12.2 65.2 57.2 53.6 12.2 12.2 60.2 52.9 49.5 12.2 12.2 60.4 53.0 49.7 12.2 12.2 60.6 53.2 49.8 12.2 12.2 60.8 53.3 50.0 12.2 12.2 60.9 53.5 50.1 12.2 12.2 61.1 53.7 50.3 12.2 12.2 59.4 52.1 48.9 12.2 12.2 51.9 45.6 42.7 12.2 12.2 44.1 38.7 36.2 12.2 12.2 36.2 31.8 29.7 12.2 12.2 28.3 24.8 23.3 12.2 12.2 20.4 17.9 16.8 12.2 12.2 12.5 11.0 10.3 12.2 12.2 4.6 4.1 3.8 12.2 12.2 55.6 48.8 45.7 12.2 12.2 61.1 53.7 50.3 12.2 12.2 61.2 53.7 50.3 12.2 12.2 61.3 53.8 50.4 12.2 12.2 PhosSURVEY_Process Parameter Test Data_ PCS Phosphte_Aurora_203.xisx 17cv1906 Sierra Club v. EPA - 6/22 Production Calciner3 ED 001523 00007569-00145 Caiciner No. 3 (EP ID No. 203) Time 4/4/14 22:00 4/4/14 23:00 4/5/14 0:00 4/5/14 1:00 4/5/14 2:00 4/5/14 3:00 4/5/14 4:00 4/5/14 5:00 4/5/14 6:00 4/5/14 7:00 4/5/14 8:00 4/5/14 9:00 4/5/14 10:00 4/5/14 11:00 4/5/14 12:00 4/5/14 13:00 4/5/14 14:00 4/5/14 15:00 4/5/14 16:00 4/5/14 17:00 4/5/14 18:00 4/5/14 19:00 4/5/14 20:00 4/5/14 21:00 4/5/14 22:00 4/5/14 23:00 4/6/14 0:00 4/6/14 1:00 4/6/14 2:00 4/6/14 3:00 4/6/14 4:00 4/6/14 5:00 4/6/14 6:00 4/6/14 7:00 4/6/14 8:00 4/6/14 9:00 4/6/14 10:00 4/6/14 11:00 4/6/14 12:00 Phosphate ore mass flow rate to the caiciner Beneficiated rock mass flow rate to the Product mass flow rate from the caiciner Phosphate ore moisture content Beneficiated rock moisture content (tons/hr) 61.4 (tons/hr) 53.9 (tons/hr) 50.5 (%> 12.2 (%> 12.2 61.4 53.9 50.5 12.2 12.2 61.5 55.1 51.6 10.4 10.4 61.6 55.2 51.7 10.4 10.4 61.7 55.3 51.8 10.4 10.4 61.8 55.3 51.8 10.4 10.4 61.8 55.4 51.9 10.4 10.4 61.9 55.5 52.0 10.4 10.4 62.0 55.5 52.0 10.4 10.4 62.1 55.6 52.1 10.4 10.4 62.1 55.7 52.2 10.4 10.4 62.2 55.8 52.2 10.4 10.4 62.3 55.8 52.3 10.4 10.4 62.4 55.9 52.4 10.4 10.4 62.6 56.1 52.5 10.4 10.4 63.9 57.2 53.6 10.4 10.4 62.4 55.9 52.3 10.4 10.4 62.8 56.3 52.8 10.4 10.4 63.3 56.8 53.2 10.4 10.4 65.1 58.3 54.6 10.4 10.4 65.5 58.7 55.0 10.4 10.4 65.9 59.0 55.3 10.4 10.4 66.2 59.3 55.6 10.4 10.4 66.8 59.8 56.0 10.4 10.4 68.6 61.4 57.5 10.4 10.4 68.4 61.3 57.4 10.4 10.4 64.2 55.9 52.4 12.9 12.9 59.9 52.1 48.8 12.9 12.9 55.5 48.3 45.3 12.9 12.9 51.1 44.5 41.7 12.9 12.9 46.8 40.7 38.1 12.9 12.9 42.4 36.9 34.6 12.9 12.9 38.0 33.1 31.0 12.9 12.9 33.7 29.3 27.5 12.9 12.9 29.3 25.5 23.9 12.9 12.9 24.9 21.7 20.3 12.9 12.9 20.5 17.9 16.8 12.9 12.9 16.2 14.1 13.2 12.9 12.9 11.8 10.3 9.6 12.9 12.9 PhosSURVEY_Process Parameter Test Data_ PCS Phosphte_Aurora_203.xisx 17cv1906 Sierra Club v. EPA - 6/22 Production Calciner3 ED 001523 00007569-00146 Date/Time 3/30/2014 0:00 3/31/2014 0:00 4/1/2014 0:00 4/2/2014 0:00 4/3/2014 0:00 4/4/2014 0:00 4/5/2014 0:00 4/6/2014 0:00 4/7/2014 0:00 4/8/2014 0:00 Raw Coal Bin Inventory 901.7 755.7 837.1 751.3 595.3 576.2 824.4 638.3 481.6 322.6 Silo Change 146.0 -81.4 85.8 156.0 19.1 -248.2 186.2 156.7 159.0 Railcar Tons Unloaded 0.0 306.8 105.7 0.0 209.1 408.6 0.0 0.0 0.0 Wet Coal Consumption Calciner Total Production 65C 146.0 225.3 191.5 156.0 228.2 160.4 186.2 156.7 159.0 7006 8301 7080 7772 5487 6172 8075 8745 7308 Wet Coal Coal Ib/Ton 65C Moisture Method Tested 41.67 54.28 54.09 40.14 83.18 51.96 46.11 35.83 43.53 6.8 6.8 EPA Method 30b 6.8 EPA Method 30b 6.8 6.8 EPA Method 320/13b 6.8 6.8 6.8 6.8 2014 Calciner Process Data Request.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Coal ED 001523 00007569-00147 REPORT Attachment B, Original Petition EPA INFORMATION COLLECTION REQUEST EMISSION TESTING PCS PHOSPHATE COMPANY, INC. - AURORA. NC Prepared for: PCS Phosphate Company, Inc. PCS Phosphate 1530 NC Highway 306 South Aurora, North Carolina 27806 Prepared by: HRS URS Corporation - North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 (919) 461-1100 URS Project No. 31827270 November 2010 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00148 TABLE OF CONTENTS Section 1 Section 2 Section 3 Introduction, ...1-1 1.1 Summary of Test Program.............................................................................. 1-1 Facility Description........................................................................................2- 1 2.1 Site Location....................................................................................................2-1 2.2 Overview of Operations................................................................................. 2-1 2.2.1 Mining and Mill Area....................................................................... 2-1 2.2.2 Sulfuric Acid Production.................................................................. 2-2 2.2.3 Phosphoric Acid Production.............................................................2-3 2.2.4 Fertilizer Production..........................................................................2-3 2.2.5 Superphosphoric Acid Production...................................................2-4 2.2.6 Purified Acid Production.................................................................. 2-4 2.2.7 Defluorinated Feed Phosphate Production......................................2-5 2.3 Sampling Locations........................................................................................2-5 2.3.1 Air Emissions Sampling Locations................................................. 2-5 2.3.2 Solid Sampling Locations...............................................................2-12 2.3.3 Liquid Sampling Locations............................................................ 2-12 2.4 Process Operating Data................................................................................ 2-17 Test Results..................................................................................................... 3-1 Section 4 Section 5 Test Methods. 4-1 4.1 Volumetric Flow, Moisture, and Molecular Weight....................................4-1 4.2 Particulate Matter............................................................................................ 4-1 4.3 Hydrogen Fluoride - Method 26A................................................................4-2 4.4 Total Fluoride - Method 13B........................................................................ 4-3 4.5 Metals - EPA Method 29...............................................................................4-3 4.6 EPA SW-846 Method 0061 (Chromium 6+)............................................... 4-4 4.7 Mercury............................................................................................................ 4-4 4.8 EPA Method 320 (FTIR)............................................................................... 4-6 Quality Assurance/Quality Control.................................................................. 5-1 5.1 Sampling QA/QC............................................................................................ 5-1 5.2 Other QA/QC...................................................................................................5-1 5.3 Test Method Exceptions and Test Program Notes...................................... 5-2 URS 17cv1906 Sierra Club v. EPA - 6/22 Production 29-NOV-IOW 1 ED 001523 00007569-00149 TABLE OF CONTENTS APPENDICES Appendix A Sampling Data A-l Calciner 3 (EP-203) A-2 DFP Kiln (EP-701) A-3 PA2 Crossflow Scrubber (EP-404) A-4 PA2 Cyclonic Scrubber (EP-403) A-5 PA4 Crossflow Scrubber (EP-409) A-6 PA4 Cyclonic Scrubber (EP-408) A-7 DAP-2 (EP-303) A-8 MAP-3 (EP-302) A-9 SPA 2 (EP-331) A-10 SPA 3/4 (EP-332) A-l 1 PAP Chiller (EP-501) A-12 PAP Scrubbers (EP-502) A-13 Rock Dryer (EP-210) (to be submitted separately) Appendix B Analytical Data B-l Enthalpy Analytical Labs - EPA Methods 26A, OTM-028, and Method 5 B-2 Test America - Method 29 SW846-0031 Analysis B-3 Test America - EPA SW-846 Method 0061 B-4 Test America - ASTM D6784 Ontario Hydro Method B-5 URS Method 30B Analysis for Mercury B-6 PCS - Total Dissolved Solids (TDS) and Total Suspended (TSS) Analysis and Total Fluoride Analysis B-7 Columbia Analytical Hg - Scrubber Water Analysis Appendix C Process Data Appendix D Field Data Sheets and QA/QC Supporting Data Appendix E Solid Material Assay (PCS) Appendix F EPA ERT Files and Spreadsheets Appendix G Test Plans and Correspondence URS 17cv1906 Sierra Club v. EPA - 6/22 Production 29-NOV-IOW 11 ED 001523 00007569-00150 TABLE OF CONTENTS TABLES Table 1-1 PCS Phosphate ICR Emission Test Matrix (Revised).................................................... 1-2 Table 2-1. TDS TSS Results Summary - Calciner 3 (EP-203)......................................................2-12 Table 2-2. TDS TSSResults Summary -DFP Kiln (EP-701).......................................................2-12 Table 2-3. TDS TSSResults Summary -PA2 Crossflow Scrubber (EP-404)........................... 2-13 Table 2-4. TDS TSSResults Summary -PA2 Cyclonic Scrubber (EP-403)..............................2-13 Table 2-5. TDS TSSResults Summary -PA4 Crossflow Scrubber (EP-409)........................... 2-13 Table 2-6. TDS TSSResults Summary -PA4 Cyclonic Scrubber (EP-408)..............................2-13 Table 2-7. TDS TSS Results Summary - SPA-2 (EP-331)............................................................ 2-14 Table 2-8. TDS TSS Results Summary - SPA-3/4 (EP-332)......................................................... 2-14 Table 2-9. TDS TSS Results Summary - DAP-2 (EP-303)........................................................... 2-14 Table 2-10. TDS TSS Results Summary - MAP-3 (EP-302)........................................................ 2-14 Table 2-11. TDS TSS Results Summary - PAP Scrubbers (EP-502)........................................... 2-15 Table 2-12. Method 1631 Hg Analysis - Calciner 3 (EP-203)...................................................... 2-15 Table 2-13. Method 1631 Hg Analysis - DFP Kiln (EP-701).....................................................2-15 Table 2-14. Method 1631 Hg Analysis - PA2 Crossflow Scrubber (EP-404).......................... 2-16 Table 2-15. Method 1631 Hg Analysis - PA2 Cyclonic Scrubber (EP-403).............................2-16 Table 2-16. Method 1631 Hg Analysis - PA4 Crossflow Scrubber (EP-409).......................... 2-16 Table 2-17. Method 1631 Hg Analysis - PA4 Cyclonic Scrubber (EP-408).............................2-17 Table 2-18. Method 1631 Hg Analysis - Rock Dryer (EP-210)................................................... 2-17 Table 3-1. Test Result Summary - Calciner 3 (EP-203)................................................................. 3-1 Table 3-2. Test Result Summary - DFP Kiln (EP-701).................................................................... 3-2 Table 3-3. Test Result Summary PA2 Crossflow Scrubber (EP-404)............................................ 3-3 Table 3-4. Test Results Summary - PA2 Cyclonic Scrubber (EP-403)..........................................3-4 Table 3-5. Test Results Summary - PA4 Crossflow Scrubber (EP-409).......................................3-5 Table 3-6. Test Results Summary - PA4 Cyclonic Scrubber (EP-408)..........................................3-6 Table 3-7. Test Results Summary - SPA-2 (EP-331)........................................................................3-7 Table 3-8. Test Results Summary of SPA-3/4 (EP-332).................................................................. 3-7 Table 3-9. Test Results Summary -DAP-2 (EP-303)........................................................................ 3-8 Table 3-10. Test Result Summary - MAP-3 (EP-302)..................................................................... 3-9 Table 3-11. Test Result Summary PAP Scrubbers (EP-502)........................................................3-10 Table 3-12 Test Results Summary PAP Chiller Stack (EP-501)...................................................3-10 Table 3-13 Test Results Summary Rock Dryer (EP-210)..............................................................3-11 Tins 29-NOV-IOW fli 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00151 TABLE OF CONTENTS Figures Figure 2-1. Calciner #3 (EP-203).........................................................................................................2-6 Figure 2-2. DFP Kiln (EP-701)............................................................................................................ 2-6 Figure 2-3. PA2Crossflow Scrubber (EP-404)..................................................................................2-7 Figure 2-4. PA2 Cyclonic Scrubber (EP-403)...................................................................................2-7 Figure 2-5. PA4 Crossflow Scrubber (EP-409).................................................................................2-8 Figure 2-6. PA4 Cyclonic Scrubber (EP-408)...................................................................................2-8 Figure 2-7. DAP #2 (EP-303)...............................................................................................................2-9 Figure 2-8. DAP/MAP #3 (EP-302)................................................................................................... 2-9 Figure 2-9. Superphosphoric Acid Plant #2 (EP-331)....................................................................2-10 Figure 2-10. Superphosphoric Acid Plant #3/4 (EP-332).............................................................. 2-10 Figure 2-11. PAP Chiller Stack (EP-501)........................................................................................ 2-11 Figure 2-12. PAP Scrubber Stack (EP-502)....................................................................................2-11 Figure 2-13. Rock Dryer (EP-210) (to be submitted separately).................................................. 2-11 URS 17cv1906 Sierra Club v. EPA - 6/22 Production 29-NOV-IOW IV ED 001523 00007569-00152 SICTIONONE Introduction 1.1 SUMVIARY OF TEST PROGRAM On April 3, 2010, the United States (US) Environmental Protection Agency (EPA) issued an Information Collection Request (ICR) to phosphoric acid and phosphate fertilizer manufacturing facilities (NAICS code 325312), including the PCS Phosphate Company Inc. (PCS Phosphate) Aurora, North Carolina (NC) facility. The ICR was received by PCS Phosphate on April 15, 2010. The PCS Phosphate facility located near Aurora, NC includes phosphate rock mining operations, as well as manufacturing of granular and liquid phosphate fertilizers, fertilizer grade phosphoric acid, technical and food-grade phosphoric acid, superphosphoric acid, and phosphate rock products. The ICR issued by EPA has two parts: a data survey and an emission testing requirement. This report describes the results of the testing completed to fulfill the requirements of the emissions testing requirement of the ICR for the Aurora facility. Emission testing was performed for thirteen (13) sources. Table 1-1 presents the emission tests conducted for each source. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 1-1 \29-NOV-10W ED 001523 00007569-00153 SECTIONONE Species: NonMcmiry Metals Table 1-1 PCS Phosphate ICR Emission Test Matrix (Revised) Hydrogen Total Ilc\a\alcn( Fluoride Fluoride Chromium "s: "4 MIDIs EP Emission Unit Description EP-210 Rock Dryer EP-203 Calciner 3 EP-701 EP-403 EP-404 EP-408 EP-409 DFP Kiln Stack PA-2 Belt Filter Scrubber Stack (amber acid) PA-2 Crossflow Scrubber Stack (amber acid) PA-4 Belt Filter Scrubber Stack (green acid) PA-4 Crossflow Scrubber Stack (green acid) EP-331 SPA-2 Plant Scrubber Stack EP-332 SPA-3&4 Plant Scrubber Stack EP-303 DAP Plant No. 2 EP-302 MAP Plant No. 3 EP-502 PAP Scrubber Stack EP-501 PAP Chiller Stack Method 29 Method 26A X X X X X X X X Method 13B X X X a X X a X X a X X a X X a X X a X X a X X a c X X SW-846 Method 0061 X X X Method 30B X X X ASTM D6784-02 (Ontario Hydro) X X X X X X X X X X X X X X X b b X b b X b b X b b X b b X b Method 320 X X Introduction PM; 5 PM (condensable) Method 5 X X X X X X X X X X X OTM28 X X X X X X X X X X X X a Method 13B - Historical date collected previously by PCS will be used. b Hg testing of downstream sources waived. c HF by Method 320. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 1-2 \29-NOV-10W ED 001523 00007569-00154 SICTIONTWO Facility Description 2.1 SITE LOCATION PCS Phosphate owns and operates a phosphate rock mining and phosphoric acid manufacturing facility located near Aurora, in Beaufort County, North Carolina. Beaufort County is located in the eastern coastal region of North Carolina. The facility falls under the standard North American Industry Classification System (NAICS) codes 212392 for phosphate rock mining and 325312 for phosphoric acid manufacturing. 2.2 OVERVIEW OF OPERATIONS The PCS Phosphate Aurora facility mines phosphate rock and uses this raw material to produce granular and liquid phosphate fertilizers, fertilizer grade phosphoric acid, technical and foodgrade phosphoric acid, superphosphoric acid, and phosphate rock products. The Aurora site mines and processes approximately 6 million tons per year (tpy) of phosphate rock. The site includes process operations that fall into two main categories: Mining and Mill operations and Mineral Processing operations. The following are the main process areas covered by the ICR request at the plant: Mining and Mill Areas: Ore milling, calcination, drying, and grinding Mineral Processing Areas: Sulfuric acid production Phosphoric acid production Fertilizer production Superphosphoric acid production Purified acid production Defluorinated feed phosphate Silicon tetrafluoride production The main raw materials used at the Aurora site are mined phosphate rock, elemental sulfur, and anhydrous ammonia. Phosphate ore is mined in adjacent open-pit mines and transported in a water slurry in enclosed pipes to the mill area. Elemental sulfur is transported in railcars and barges to the Aurora site where it is steam heated and unloaded as molten sulfur. Anhydrous ammonia is transported to the site in railcars. Process flow diagrams for the individual process operations were included in the survey response submitted on August 12, 2010. The following presents a brief summary of the operations in each area. 2.2.1 Mining and Mill Area Mined phosphate ore (14% P2O5) is beneficiated by screening, removal of clay, froth flotation, and flocculation to separate sand and other foreign material. The beneficiated rock is stored in a wet pile. The rock can then be transferred to the rock dryer to remove moisture prior to sale or IIPQ 2-1 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00155 SICTIONTWO Facility Description further use in fertilizer production, or to the calciners prior to sending to the phosphoric acid plant to make green phosphoric acid, or directly to the phosphoric acid plant to make amber phosphoric acid. The following sections describe the process operations in the mill area covered by the ICR testing program. 221.1 Calcination Beneficiated phosphate rock is received from wet rock storage via conveyors to calcination for removal of moisture and carbonaceous material. Six fluidized-bed calciners are fueled by bituminous coal/coke mixture (or No. 6 fuel oil or used oil as backup fuel) to maintain temperature necessary for oxidation of carbonaceous material in the fluidized bed. The calciners consist of a pre-heat section, fluidized bed calcination, and a cooling compartment for the calcined rock. The rock is cooled by direct water spray downstream of the calciners, discharged through a level control valve, and transferred to either storage silos or the phosphoric acid production area. Vent streams from the preheat bed and the aftercooler chambers of each calciner exhaust through individual cyclones and a venturi scrubber, using water as the scrubbing solution. Each calciner is also equipped with a wet electrostatic precipitator (WESP) following the scmbber for additional emissions control. The calciners must meet Maximum Achievable Control Technology (MACT) requirements outlined in 40 CFR Subpart AA for Phosphoric Acid Manufacturing Plants. 221.2Drying A rock dryer removes moisture in the wet rock (downstream of mining and beneficiation) in a fluidized-bed dryer fueled by No. 6 fuel oil. Moisture content of the rock is decreased from approximately 10% moisture, down to less than 1% moisture. Dried phosphate rock can be used in the phosphoric acid production process or transferred to shipping for sale. 2.2.2 Sullurlc Acid Production Sulfuric acid is used to react with phosphate rock to produce phosphoric acid. The sulfuric acid production area currently includes three sulfuric acid (SA) plants (SA Plant Nos. 5, 6, and 7), one cogeneration plant, and one auxiliary boiler. All of the sulfuric acid plants use the double-absorption contact process to produce sulfuric acid, which consists of the following steps: Bum elemental sulfur in the presence of air to form sulfur dioxide (S02); Combine S02 with oxygen (02) in the presence of a catalyst to produce sulfur trioxide (S03); and Absorb S03 in the sulfuric acid (EESO4) to which water is added to dilute the acid to 96%. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 2-2 \29-NOV-10W ED 001523 00007569-00156 SICTIONTWO Facility Description Testing of the sulfuric acid production portion of the Aurora plant was not part of the ICR Emission Testing program. 2.2.3 Phosphoric Acid Production The Aurora site produces phosphoric acid in four trains using the wet process. The phosphoric acid is used internally to produce fertilizers, superphosphoric acid, and purified (food-grade) phosphoric acid. Acid not consumed internally is sold and shipped off site via truck, railcar or barge. Two types of phosphoric acids are produced: "green" acid (from calcined rock) and "amber" acid (from uncalcined rock). The four phosphoric acid trains are similar in design. Production of phosphoric acid by the wet process involves three unit operations: phosphate rock digestion, filtration, and concentration. Digestion occurs in the attack vessel, or acidulator, where phosphate rock and sulfuric acid are added to a recirculatory acid slurry. Because the acidulation reaction is exothermic, the hot slurry must be cooled to reduce/prevent scaling during filtration. Vapors from the flash cooler are condensed and sent to a hot well. Emissions from the reactors and associated equipment from each train are exhausted through a spray-crossflow packed bed scrubber. There are four scrubbers, one per train. The P205 concentration of the phosphoric acid is about 26 percent when it processed through tilting pan and belt filters. Acid from the filtration step is sent to vacuum receivers and then to filtrate pumps or filtrate seal tanks and then to storage tanks for solids settling. Emissions from the belt filters and belt filter seal tanks are controlled by two cyclonic wet scrubbers, one for Trains No. 1 and No. 2 and the second for Trains No. 3 and No. 4. The ICR testing program included the cyclonic and crossflow scmbbers for the PA-2 plant producing amber acid, and the cyclonic and crossflow scrubbers for the PA-4 plant producing green acid. 2.2.4 Fertilizer Production In the fertilizer production area, PCS Phosphate manufactures granular and liquid phosphate fertilizer products. The area includes three separate fertilizer plants, of which the Diammonium Phosphate Plant No. 2 and Monoammonium Plant No. 3 were selected for the ICR testing. 2.2.4.1 DAP No. 2 Plant The ammoniated phosphates are produced by reacting anhydrous ammonia with a blend of various types and grades of phosphoric acid. This reaction takes place in two steps. The initial reaction occurs in the reactor tank. The final reaction occurs in the granulator drum. The purpose of the granulator is to mix the ammoniated slurry and phosphoric acid with the dry recycle to form granules and comp lete the reaction. The granulated product is dried in a dryer, screened to separate product sized granules, and cooled. Coating oil is added to the product in the cooler as a dust suppressant prior to shipment or storage. Oversized granules are ground in enclosed mills and recycled to the granulator along with the undersized granules. URS 2-3 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00157 SICTIONTWO Facility Description The process generates product- and reactant-bearing off-gases. Product dust is recovered in three cyclones: one on the discharge stream of the dryer, another on the discharge stream from the cooler and the third on certain materials handling equipment. Three venturi scrubbers, using an ammoniated phosphate solution and/or water as a scrubbing medium, remove additional product dust from the cyclone exhausts and recover ammonia and some fluorides in the off-gas from the reactor and granulator. The venturi scrubbers exhaust to two packed bed scrubbers for final control of dust, ammonia, and fluoride emissions. Both packed bed scrubbers exhaust to a common stack (ID No. 303). 2.24.2 MAPNo. 3 Plant MAP No. 3 Plant has been configured to produce MAP since 1986, and permitted to produce DAP since 1992. The plant produced MAP for the tests conducted under the ICR program. The MAP and DAP processes in this plant are similar to those described above for the DAP No. 2 Plant, except that DAP No. 3 utilizes a pipe reactor versus a tank reactor for the initial reaction of ammonia and phosphoric acid. The slurry is sprayed into a granulator vessel where it is mixed with a recycled product stream in a rotating cylindrical vessel to produce a granular product. The granular product is then dried in the dryer, screened, cooled, and sprayed with a light oil prior to shipment or storage. Oversize granules are ground in enclosed chain mills prior to being recycled to the granulator along with undersize granules. The processes described above generate product-be aring off gases. Product dust is collected in cyclones and returned to the process. The exhaust gas from the cyclones, along with fumes and dust from the reactors and granulator are controlled by scrubbers. The exhaust from the four primary scrubbers is combined prior to passing through the tail gas scaibber, which uses a scrubber liquor consisting of fresh water or tail gas scrubber water from the DAP No. 2 Plant. The tail gas scrubber exhausts to a single stack (ID No. 302). 2.2.5 Superphosphoric Acid Production In the superphosphoric acid production area, PCS Phosphate operates four superphosphoric acid plants. The superphosphoric acid (SPA) production process concentrates various grades of phosphoric acid by removing water. SPA plants 1 and 2 have two stage, falling film evaporators that can operate in parallel, series, or stand alone. SPA plants 3 and 4 have forced circulation, single stage evaporators. SPA plants 1 and 2 each have a venturi scrubber that controls fluoride emissions from the product storage tank and evaporator hotwell and discharges through stack IDs 330 and 331, respectively. SPA plants 3 and 4 share a common venturi scrubber that controls fluoride emissions from the product storage tanks and evaporator hotwells and discharges through stack ID 332. The scrubber stacks for SPA-2 and SPA-3&4 were tested as part of the ICR program. 2.2.6 Purified Acid Production The purified acid production area consists of four production trains in Purified Acid Plants No. 1 and 2. PAP No. 1 and PAP No. 2 purify phosphoric acid by solvent extraction to produce (1) low-alkali, high-purity phosphoric acid suitable for use in technical and food grade URS 2-4 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00158 SICTIONTWO Facility Description manufacturing; (2) high-alkali phosphoric acid suitable for manufacturing technical grade derivatives; and (3) raffinate which contains constituents removed during the production of the first two products and is used in manufacturing fertilizers at the Aurora site. The PAP plants have an approximate maximum design capacity of 1,200 tons P205 feed per day each. In the PAP plants, phosphoric acid is mixed with a solvent in two extraction columns which are operated in parallel. In the extraction columns, the phosphoric acid preferentially dissolves in the solvent forming an extract of phosphoric acid and solvent, which is recovered as a stream, and leaving a portion of phosphoric acid, water, and certain constituents from the solvent process as raffinate, which is also recovered as a stream. The phosphoric acid-solvent extract streams enter two release columns which are also operated in parallel. A stream of purified, low-alkali phosphoric acid is recovered from near the middle of each release column; a stream of purified, high-alkali phosphoric acid is recovered from near the bottom of each column. The high-alkali acid streams from the release columns of the PAP plants are passed through stream strippers where residual solvent is removed and recycled to a solvent storage tank. The two acid streams are evaporated to a 57-63 percent P2O5 concentration, defluorinated, and stored until shipment. The solvent-laden storage tanks and process vessels are kept under a nitrogen blanket system that vents to a chilled stack that condenses the solvent for reuse. Spray tower scrubbers control the fluoride emissions from the concentrators and defluorination columns in the low alkali acid and high alkali acid streams. The scrubber and chiller stacks for PAP-2 were tested as part of the ICR program. 2.2.7 Defluorinated Feed Phosphate Production Defluorinated phosphate (DFP) is a sodium modified tri-calcium phosphate mineral used in poultry feeds. The production of DFP utilizes three primary raw materials: phosphate rock, phosphoric acid, and soda ash. The three raw materials are blended in a pug mill. Emissions from the pug mill are controlled by a high-efficiency limestone wet scrubbing system. Blended feed is transferred directly to a rotary defluorination kiln, where heat from combustion of pulverized coal is used to defluorinate phosphate rock. Exhaust from the kiln is controlled by a wet limestone scrubbing system. Emissions from the DFP kiln stack was tested as part of the ICR testing program. In the kiln, the mixed feed undergoes a chemical transformation. Organics, sulfates, carbonates, and fluorides are removed. In addition, the calcium phosphates and sodium form a solid known as rhenonite. After the passing through a product cooler for energy recovery, the clinker from the kiln is transported to a crushing and screening circuit. Finished DFP is conveyed to the product storage facilities. 2.3 SAMPLING LOCATIONS 2.3.1 Air Emissions Sampling Locations Sampling locations for the thirteen emission points are outlined in Table 1-1. As directed in the ICR letter, locations and numbers of traverse points met the specifications of EPA Method 1 IIPQ 2-5 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00159 SICTIONTWO Facility Description (reference Appendix A to 40 CFR Part 60). Figures 2-1 through 2-9 present the stack configurations for the individual sources tested. The SPA-2 test location was tested on single traverse during isokinectic sampling due to limited port size and access. A full velocity traverse was made prior to and after the sampling run. Figure 2-1. Calciner #3 (EP-203) Stack Diameter 72" Figure 2-2. DFP Kiln (EP-701) Stack Diameter 5' (60") URS 17cv1906 Sierra Club v. EPA - 6/22 Production 2-6 \29-NOV-10W ED 001523 00007569-00160 SICTIONTWO Facility Description Figure 2-3. PA2Crossflow Scrubber (EP-404) Stack Diameter 40" '' "T i > 5' > 2 Diameters 31'10" 9.6 Diameters Figure 2-4. PA2 Cyclonic Scrubber (EP-403) Stack Diameter 28 75" i > 5' > 2 Diameters .... . J ; 22'8" 9.5 Diameters URS 17cv1906 Sierra Club v. EPA - 6/22 Production 2-7 \29-NOV-10W ED 001523 00007569-00161 SICTIONTWO Facility Description Figure 2-5. PA4 Crossflow Scrubber (EP-409) Stack Diameter 40" > S' > 2 Diameters 32'10" 9 8 D,ameters Figure 2-6. PA4 Cyclonic Scrubber (EP-408) Stack Diameter 28 75'* >5' > 2 Diameters P 2rir 9.1 Diameters URS 17cv1906 Sierra Club v. EPA - 6/22 Production 2-8 \29-NOV-10W ED 001523 00007569-00162 SICTIONTWO Figure 2-7. DAP #2 (EP-303) Stack Diameter 7* (84") 58' ?* (870") 8.1 Diameters Facility Description 57* 8" (690") 8.2 Diameters Figure 2-8. DAP/MAP #3 (EP-302) Stack Diameter 9 (108"; 18* 0" <216 ) 2 0 Diameters 03' 0" 1758*') 7 u Dimeters URS 17cv1906 Sierra Club v. EPA - 6/22 Production 2-9 \29-NOV-10W ED 001523 00007569-00163 SICTIONTWO Facility Description Figure 2-9. Superphosphoric Acid Plant #2 (EP-331) J Figure 2-10. Superphosphoric Acid Plant #3/4 (EP-332) Stack Diameter 24" 202" 8.4 Diameters porthole 296" 12.3 Diameters URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 2-10 ED 001523 00007569-00164 SICTIONTWO Facility Description Figure 2-11. PAP Chiller Stack (EP-501) Flow disturbance: >8 ed upstream, >2 ed downstream Figure 2-12. PAP Scrubber Stack (EP-502) Stack Diameter 29" &W 2.S Diameters ]-- 20'0H 8.3 Diameters Figure 2-13. Rock Dryer (EP-210) (to be submitted separately) URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 2-11 ED 001523 00007569-00165 SICTIONTWO Facility Description 2.3.2 Solid Sampling Locations Solid material analysis was requested for facilities that operate a phosphate rock beneficiation, phosphoric acid manufacturing and/or phosphate fertilizer production facility. The following solids were identified for analysis: ore from the mine; beneficiated phosphate rock to the dryer and calciner; post dried and calcined phosphate rock; and phosphogypsum from the active stack. PCS Phosphate identified and recorded the date, time and location of all process samples collected for the program. 2.3.3 Liquid Sampling Locations Samples from wet scrubbers upstream of the air emissions sampling points were taken during the testing in order to determine mercury, total suspended solids (TSS), and total dissolved solids (TDS) in the scrubbing liquor. Liquid samples were taken from the scrubber vessel sump or recirculation line during the time of testing for this purpose. Three samples were collected during the prescribed test method and analyzed. PCS Phosphate process operation personnel collected the liquid samples. The TSS and TDS water sample analysis was conducted on site by the PCS Environmental Laboratory. The water samples for mercury (Hg) analysis were analyzed by Columbia Analytical Service. The analytical results for TSS and TDS and scrubber liquid recirculation rates are present in Tables 2-1 through 2-11 for each source tested during the ICR program. These water samples were collected during the corresponding Method 5 /OTM-28 test runs. The scrubber water TSS and TDS sample analysis was conducted by the PCS Phosphate Aurora Environmental Lab. Table 2-1. TDS TSS Results Summary - Calciner 3 (EP-203) Sample ID Cal -3 Cal -3 Cal -3 Cal -3 Run # 1 2 3 Average Total Dissolved Solids (TDS) (Mg/L) 7,400 7,076 7,190 7,222 Total Suspended Solids (TSS) (Mg/L) 21,130 31,160 31,380 27,890 Scrubber Liquid Flowrate dPm) 1,042 1,007 1,008 1,019 Table 2-2. TDS TSS Results Summary - DFP Kiln (EP-701) Sample ID Run # DFP DFP DFP DFP 2 3 4 Average Total Dissolved Solids (TDS) Total Suspended Solids (TSS) Scrubber Liquid Flowrate (Mg/L)(Mg/L)(Ipm) 7,440 41,820 22,414 7,180 62,020 22,349 10,375 40,160 22,324 8,332 48,000 22,362 URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 2-12 ED 001523 00007569-00166 SICTIONTWO Facility Description Table 2-3. TDS TSS Results Summary - PA2 Crossflow Scrubber (EP-404) Sample ID Run# PA2 Xfiow PA2 Xfiow PA2 Xfiow PA2 Xfiow 1 2 3 Average Total Dissolved Solids (TDS) (Mg/L) 45,040 45,360 46,400 45,600 Total Suspended Solids (TSS) (Mg/L) 29.4 40.2 59.2 42.9 Scrubber Liquid Flowrate (Ipm) 3,530 3,390 3,199 3,373 Table 2-4. TDS TSS Results Summary - PA2 Cyclonic Scrubber (EP-403) Sample ID Run # PA2-Cyclonic PA2-Cyclonic PA2-Cyclonic PA2-Cyclonic 1 2 3 Average Total Dissolved Solids (TDS) (Mg/L) 45,360 45,980 45,390 45,577 Total Suspended Solids (TSS) (Mg/L) 128.0 67.6 46.6 80.7 Scrubber Liquid Flowrate dPm) 247 241 241 243 Table 2-5. TDS TSS Results Summary - PA4 Crossflow Scrubber (EP-409) Sample ID Run # PA4 -Xfiow PA4-Xflow PA4 -Xfiow PA4-Xflow 1 2 3 Average Total Dissolved Solids (TDS) (Mg/L) 50,050 49,550 50,000 49,867 Total Suspended Solids (TSS) (Mg/L) 36.6 31.6 40.8 36.3 Scrubber Liquid Flowrate (Ipm) 3,485 3,547 3,123 3,385 Table 2-6. TDS TSS Results Summary - PA4 Cyclonic Scrubber (EP-408) Sample ID Run # PA4-Cyclonic PA4-Cyclonic PA4-Cyclonic PA4-Cyclonic 1 2 3 Average Total Dissolved Solids (TDS) (Mg/L) 51,550 52,100 51,775 51,808 Total Suspended Solids (TSS) (Mg/L) 33.6 50.8 47.6 44.0 Scrubber Liquid Flowrate (Ipm) 252 262 262 259 URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 2-13 ED 001523 00007569-00167 SICTIONTWO Facility Description Table 2-7. TDS TSS Results Summary - SPA-2 (EP-331) Sample ID Run # SPA 2 SPA 2 SPA 2 SPA 2 1 2 3 Average Total Dissolved Solids (TDS) (Mg/L) ND ND ND ND Total Suspended Solids (TSS) (Mg/L) ND ND ND ND Scrubber Liquid Flowrate (Ipm) 512 505 501 506 Table 2-8. TDS TSS Results Summary - SPA-3/4 (EP-332) Sample ID Run # SPA 3/4 SPA 3/4 SPA 3/4 SPA 3/4 1 2 3 Average Total Dissolved Solids (TDS) (Mg/L) ND ND ND ND Total Suspended Solids (TSS) (Mg/L) ND ND ND ND Scrubber Liquid Flowrate (Ipm) 524 528 526 526 Table 2-9. TDS TSS Results Summary - DAP-2 (EP-303) Sample ID Run # Total Dissolved Solids (TDS) ________________________________ (Mg/L) DAP-2 1 DAP-2 2 DAP-2 3 30,180 30,860 33,040 DAP-2 Average 31,360 Total Suspended Solids (TSS) (Mg/L) 2,060 4,530 2,690 3,093 Scrubber Liquid Flowrate (Ipm) 13,695 13,687 13,707 13,696 Table 2-10. TDS TSS Results Summary - MAP-3 (EP-302) Sample ID Run # MAP-3 MAP-3 MAP-3 MAP-3 1 2 3 Average Total Dissolved Solids (TDS) (Mg/L) 95,160 96,040 20,020 70,407 Total Suspended Solids (TSS) (Mg/L) 29,910 35,660 40,650 35,407 Scrubber Liquid Flowrate (Ipm) 5,734 5,748 5,726 5,736 URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 2-14 ED 001523 00007569-00168 SICTIONTWO Facility Description Table 2-11. TDS TSS Results Summary - PAP Scrubbers (EP-502) Sample ID Run # PAP PAP PAP PAP 1 2 3 Average Total Dissolved Solids (TDS) (Mg/L) 24,550 25,800 25,460 25,270 Total Suspended Solids (TSS) (Mg/L) 12.0 13.0 13.2 12.7 Scrubber Liquid Flowrate (Ipm) 10,364 10,295 10,198 10,286 The Hg water sample analytical results and scrubber liquid recirculation rates are presented in Tables 2-12 through 2-18. Table 2-12. Method 1631 Hg Analysis - Calciner 3 (EP-203) Cai -3 Slurry 1 Cai -3 Slurry 2 Cal -3 Slurry 3 Cal -3 Slurry Average 3 Liquid fraction of sample 'Solid fraction of sample ' 4-hour average during Hg testing 0.52 0.88 0.61 0.67 Analytical Flag BDL BDL BDL Hg Method 1631 b (ng/g) 243 273 241 252 Analytical Flag ADL ADL ADL Scrubber Liquid Flowratec (Ipm) 924 Table 2-13. Method 1631 Hg Analysis - DFP Kiln (EP-701) Sample ID Run# DFP Scrubber 1 DFP Scrubber 2 DFP Scrubber 3 DFP Scrubber Average 3 Liquid fraction of sample 'Solid fraction of sample ' 4-hour average during Hg testing Hg Method 1631 a (ng/L) 3.84 4.06 10.2 6.03 Analytical Flag ADL ADL ADL Hg Method 1631 b (ng/g) 5.3 25.7 22.1 17.7 Analytical Flag ADL ADL ADL Scrubber Liquid Flowratec (Ipm) 22,113 URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 2-15 ED 001523 00007569-00169 SICT1QMTW0 Facility Description Table 2-14. Method 1631 Hg Analysis - PA2 Crossflow Scrubber (EP-404) Sample ID Run # PA2Xflow 1 PA2Xflow 2 PA2Xflow 3 PA2Xflow Average 3 Liquid fraction of sample 'Solid fraction of sample ' 4-hour average during Hg testing Hg Method 1631 a (ng/L) 1.03 0.70 1.49 1.07 Analytical Flag ADL BDL ADL Hg Method 1631 b (ng/g) 0.4 0.6 0.6 0.5 Analytic Flag BDL BDL BDL Scrubber Liquid Flowratec (Ipm) 3,135 Table 2-15. Method 1631 Hg Analysis - PA2 Cyclonic Scrubber (EP-403) Run # PA2 Cycionic 1 PA2 Cycionic 2 PA2 Cycionic 3 PA2 Cyclonic Average Liquid fraction of sample b Solid fraction of sample 0 4-hour average during Hg testing Hg Method 1631 a (ng/L) 1.83 6.69 1.31 3.28 Analytical Flag ADL ADL ADL Hg Method 1631 b (ng/g) 0.7 1.3 0.7 0.9 Analytical Flag BDL ADL BDL Scrubber Liquid Flowratec (Ipm) 285 Table 2-16. Method 1631 Hg Analysis - PA4 Crossflow Scrubber (EP-409) Sample ID Run # PA4 Xfiow 1 PA4 Xfiow 2 PA4 Xfiow 3 PA4 Xfiow Average a Liquid fraction of sample b Solid fraction of sample 0 4-hour average during Hg testing Hg Method 1631 (n9/L) 1.57 0.90 0.98 1.15 Analytical Flag ADL BDL BDL Hg Method 1631 b (ng/g) 0.6 0.5 0.4 0.5 Analytical Flag BDL BDL BDL Scrubber Liquid Flowratec (Ipm) 3,326 URS 17cv1906 Sierra Club v. EPA - 6/22 Production 2-16 \29-NOV-10W ED 001523 00007569-00170 SICT1QMTW0 Facility Description Table 2-17. Method 1631 Hg Analysis - PA4 Cyclonic Scrubber (EP-408) Sample ID PA4-Cyclonic 1 PA4-Cyclonic 2 PA4-Cyclonic 3 PA4-Cyelonic Average 3 Liquid fraction of sample 'Solid fraction of sample ' 4-hour average during Hg testing Hg Method 1631 a (ng/L) 0.63 1.03 0.81 0.82 Analytical Flag BDL ADL BDL Hg Method 1631 b (ng/g) 1.1 0.7 1.7 1.2 Analytical Flag ADL BDL ADL Scrubber Liquid Flowratec (Ipm) 260 Table 2-18. Method 1631 Hg Analysis - Rock Dryer (EP-210) (to be submitted separately) 2.4 PROCESS OPERATING DATA Testing was conducted under normal operating conditions throughout the testing periods. Process data during the emission testing as requested in the ICR Enclosure 2 (Table 1.3) request is presented in Appendix C. URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 2-17 ED 001523 00007569-00171 SICTIONTHREE Test Results The ICR emission testing at PCS Phosphate Aurora was conducted between June 1 and October 22, 2010. The emission test results of 12 of the 13 sources are presented in this report. The completion of the emission testing on the rock dryer was delayed till late October due to limited operation. The test results of the rock dryer will be presented separately after completion of the analysis. The URS test team conducted the EPA requested ICR emission testing under representative conditions according to the test methods identified in the Enclosure 2 and subsequent guidance as provided on the website guidance and communications with EPA representatives. The average test result by method and parameter are summarized in Table 3-1 through 3-13 for each emission source. Individual test runs for each test method are contained in Appendix A. The supporting analytical data for each test method is contained in Appendix B. Table 3-1. Test Result Summary - Calciner 3 (EP-203) Test Method EPA Method 5 EPA Method OTM-28 EPA Method 29 SW-846 Method 0061 ASTM D6784-02 (Ontario Hydro) EPA Method 30B EPA Method 26A EPA Method 13B Target Analyte Filterable PM Condensible PM Antimony Arsenic Beryllium Cadmium Chromium Cobait Lead Manganese Nickel Phosphorus Selenium Chromiuirf6 Total Mercury Average Test Result 4.67E-03 4.98E-03 1.02E-07 2.03E-07 2.72E-08 6.51 E-06 4.43E-06 2.00E-07 3.29E-06 1.01 E-06 3.54 E-06 1.37E-03 3.20E-07 2.85E-07 5.77E-05 Total Mercury Hydrogen Fluoride Total Fluoride 4.34E-05 1.30E+00 3.12E-04 9.03E-01 Units gr/dscf @ 3% 02 gr/dscf @ 3% 02 gr/dscf @ 3% 02 gr/dscf @ 3% 02 gr/dscf @ 3% 02 ppmvd @ 3% 02 gr/dscf @ 3% 02 ppmvd @ 3% 02 URS 17cv1906 Sierra Club v. EPA - 6/22 Production 3-1 \29-NOV-10W ED 001523 00007569-00172 SICTIONTHREE Test Results Table 3-2. Test Result Summary - DFP Kiln (EP-701) Test Method EPA Method 5 EPA Method OTM-28 EPA Method 29 Target Analyte Filterable PM Condensible PM Antimony Arsenic Beryllium Cadmium Chromium Cobait Lead Manganese Nickel Phosphorus Selenium Average Test Result 2.88E-02 2.70E-02 4.66E-06 2.1 IE-05 8.17E-07 3.17E-04 4.48E-04 9.09E-07 1.08E-05 2.07E-06 3.78E-06 1.56E-03 2.37E-05 Units gr/dscf @ 3% 02 gr/dscf @ 3% 02 SW-846 Method 0061 Chromium*6 1.53E-06 gr/dscf @ 3% 02 ASTM D6784-02 (Ontario Hydro) Total Mercury 1.93E-05 gr/dscf @ 3% 02 EPA Method 30B Total Mercury 1.58E-05 gr/dscf @ 3% 02 EPA Method 26Aa Hydrogen Fluoride 2.57E+00 ppmvd @ 3% 02 EPA Method 13Ba 4.40E-03 Total Fluoride 1.27E+01 gr/dscf @ 3% 02 ppmvd @ 3% 02 aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 3-2 ED 001523 00007569-00173 SICTIONTHREE Test Results Table 3-3. Test Result Summary PA2 Crossflow Scrubber (EP-404) Test Method Target Analyte Average Test Result Units EPA Method 5 EPA Method OTM-28 Filterable PM Condensible PM 1.39E-03 1.75E-03 gr/dscf EPA Method 29 Antimony 1.28E-08 Arsenic 2.65E-08 Beryllium 3.55E-09 Cadmium 1.76E-07 Chromium 7.27E-07 Cobait 3.56E-08 gr/dscf Lead 4.17E-07 Manganese 4.67E-07 Nickel 7.76E-07 Phosphorus 1.02E-04 Selenium 2.03E-07 SW-846 Method 0061 Chromium+6 1.93E-08 gr/dscf ASTM D6784-02 (Ontario Hydro) Total Mercury 1.88E-08 gr/dscf EPA Method 30B Total Mercury 1.48E-08 gr/dscf EPA Method 26Aa Hydrogen Fluoride 4.40E+00 ppmvd aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SiF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 3-3 \29-NOV-10W ED 001523 00007569-00174 SICTIONTHREE Test Results Table 3-4. Test Results Summary - PA2 Cyclonic Scrubber (EP-403) Test Method Target Analyte Average Test Result Units EPA Method 5 EPA Method OTM-28 Filterable PM 5.47E-04 Condensible PM 1.64E-03 gr/dscf Antimony 3.89E-09 Arsenic 1.19E-08 Beryllium 2.77E-09 Cadmium 7.44E-08 Chromium 6.36E-07 EPA Method 29 Cobait 4.43E-08 gr/dscf Lead 1.72E-07 Manganese 4.33E-07 Nickel 9.67E-07 Phosphorus 5.27E-05 Selenium 6.07E-08 SW-846 Method 0061 Chromium+6 2.92E-07 gr/dscf ASTM D6784-02 (Ontario Hydro) Total Mercury 2.14E-08 gr/dscf EPA Method 30B Total Mercury 2.16E-08 gr/dscf EPA Method 26Aa Hydrogen Fluoride 2.17E+00 ppmvd aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 3-4 \29-NOV-10W ED 001523 00007569-00175 SICTIONTHREE Test Results Table 3-5. Test Results Summary - PA4 Crossflow Scrubber (EP-409) Test Method Target Analyte Average Test Result Units EPA Method 5 EPA Method OTM-28 Filterable PM 2.00E-01 Condensible PM 2.39E-01 gr/dscf Antimony 7.12E-09 Arsenic 4.33E-08 Beryllium 3.29E-09 Cadmium 1.69E-07 Chromium 1.67E-06 EPA Method 29 Cobait 4.22E-08 gr/dscf Lead 1.58E-07 Manganese 3.98E-07 Nickel 1.20E-06 Phosphorus 1.07E-04 Selenium 1.25E-07 SW-846 Method 0061 Chromium+6 3.97E-08 gr/dscf ASTM D6784-02 (Ontario Hydro) Total Mercury 2.41 E-08 gr/dscf EPA Method 30B Total Mercury 4.24E-08 gr/dscf EPA Method 26Aa Hydrogen Fluoride 2.66E+00 ppmvd aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SiF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 3-5 \29-NOV-10W ED 001523 00007569-00176 SICTIONTHREE Test Results Table 3-6. Test Results Summary - PA4 Cyclonic Scrubber (EP-408) Test Method Target Analyte Average Test Result Units EPA Method 5 EPA Method OTM-28 Filterable PM 6.09E-04 Condensible PM 7.50E-04 gr/dscf Antimony 4.95E-09 Arsenic 2.47E-08 Beryllium 3.25E-09 Cadmium 6.69E-08 Chromium 7.37E-07 EPA Method 29 Cobait 6.13E-08 gr/dscf Lead 9.31 E-08 Manganese 6.76E-07 Nickel 1.12E-06 Phosphorus 5.63E-05 Selenium 7.01 E-08 SW-846 Method 0061 Chromium+6 4.15E-07 gr/dscf ASTM D6784-02 (Ontario Hydro) Total Mercury 8.24E-09 gr/dscf EPA Method 30B Total Mercury 1.48E-08 gr/dscf EPA Method 26Aa Hydrogen Fluoride 6.20E+00 ppmvd aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SiF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 3-6 \29-NOV-10W ED 001523 00007569-00177 SICTIONTHREE Test Results Table 3-7. Test Results Summary - SPA-2 (EP-331) Average Test Test Method Target Analyte Result Units EPA Method 5 EPA Method OTM-28 Filterable PM 2.48E-03 Condensible PM 9.04E-04 gr/dscf Antimony 1.30E-08 Arsenic 2.54E-08 Beryllium 2.53E-08 Cadmium 2.84E-07 Chromium 1.46E-06 EPA Method 29 Cobait 2.73E-08 gr/dscf Lead 5.96E-08 Manganese 5.74E-07 Nickel 6.05E-07 Phosphorus 1.1 IE-03 Selenium 6.09E-08 SW-846 Method 0061 Chromium+6 2.33E-07 gr/dscf EPA Method 26Aa Hydrogen Fluoride 1.55E+00 ppmvd aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. Table 3-8. Test Results Summary of SPA-3/4 (EP-332) Test Method Target Analyte Average Test Result Units EPA Method 5 EPA Method OTM-28 Filterable PM 3.89E-03 Condensible PM 1.43E-03 gr/dscf Antimony 1.35E-08 Arsenic 2.97E-08 Beryllium 1.19E-08 Cadmium 1.49E-07 Chromium 1.15E-06 EPA Method 29 Cobait 2.55E-08 gr/dscf Lead 1.24E-07 Manganese 5.21 E-07 Nickei 1.83E-06 Phosphorus 4.93E-04 Selenium 8.40E-08 SW-846 Method 0061 Chromium+6 1.45E-07 gr/dscf EPA Method 26Aa Hydrogen Fluoride 5.50E+00 ppmvd aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. URS 3-7 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00178 SICTIONTHREE Test Results Table 3-9. Test Results Summary -DAP-2 (EP-303) Test Method Target Analyte Average Test Result Units EPA Method 5 EPA Method OTM-28 Filterable PM 6.04E-03 Condensible PM 3.72E-03 gr/dscf Antimony 1.99E-08 Arsenic 7.12E-08 Beryllium 9.62E-09 Cadmium 2.57E-06 Chromium 1.9 IE-06 EPA Method 29 Cobalt 3.46E-06 gr/dscf Lead 3.81 E-07 Manganese 1.17E-06 Nickel 1.24E-05 Phosphorus 3.17E-04 Selenium 1.70E-07 SW-846 Method 0061 Chromium+6 6.08E-07 gr/dscf EPA Method 26Aa Hydrogen Fluoride 5.98E+00b ppmvd aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. DPCS Phosphate operations personnel and management have reviewed the operating parameters of the DAP2 plant during Method 26A ICR testing on July 9, 12, and 13, 2010. Based on this evaluation, it is apparent that the operating conditions and test results for the first run (07/09/2010) were not representative of normal operations. The conclusion of this evaluation indicates that the results of the first run should not be included in the report.______________________________________________________________ URS 17cv1906 Sierra Club v. EPA - 6/22 Production 3-8 \29-NOV-10W ED 001523 00007569-00179 SICTIONTHREE Test Results Table 3-10. Test Result Summary - MAP-3 (EP-302) Test Method Target Analyte Average Test Result Units EPA Method 5 EPA Method OTM-28 Filterable PM Condensible PM 1.78E-03 1.72E-03 gr/dscf Antimony 3.94E-08 Arsenic 7.44E-08 Beryllium 1.29E-08 Cadmium 2.14E-07 Chromium 1.46E-06 EPA Method 29 Cobait 1.42E-07 gr/dscf Lead 5.45E-07 Manganese 4.45E-07 Nickel 6.80E-06 Phosphorus 4.44E-04 Selenium 7.70E-08 SW-846 Method 0061 Chromium+6 4.04E-07 gr/dscf EPA Method 26Aa Hydrogen Fluoride 2.22E-01 ppmvd aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 3-9 \29-NOV-10W ED 001523 00007569-00180 SICTIONTHREE Test Results Table 3-11. Test Result Summary PAP Scrubbers (EP-502) Test Method Target Analyte Average Test Result Units EPA Method 5 EPA Method OTM-28 Filterable PM Condensible PM 4.87E-04 5.80E-04 gr/dscf Antimony 4.56E-09 Arsenic 1.85E-08 Beryllium 2.89E-09 Cadmium 7.77E-08 Chromium 4.32E-07 EPA Method 29 Cobalt 1.82E-08 gr/dscf Lead 3.31 E-07 Manganese 2.84E-07 Nickel 5.25E-07 Phosphorus 2.57E-05 Selenium 6.26E-08 SW-846 Method 0061 Chromium+6 2.72 E-07 gr/dscf EPA Method 320 MIBK 1.47E+00 Hydrogen Fluoride Not Detected ppmvd ppmvd EPA Method 13Ba Total Fluoride 5.92E-04 1.71E+00 gr/dscf ppmvd aWet process phosphoric acid contains fluosilicic acid produced during the reaction of sulfuric acid and phosphate rock (fluorapatite). The two fluoride compounds in the vapor phase over fluosilicic acid are HF and SiF4. When measuring fluoride content of these vapors, it is important to note that a total fluoride result will represent both fluoride present as HF and fluoride present as SiF6. Table 3-12 Test Results Summary PAP Chiller Stack (EP-501) Test Method EPA Method 320 Target Analyte ____________ MIBK Hydrogen Fluoride Average Test Result 5.78E+03 Not Detected Units ppmvd ppmvd URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 3-10 ED 001523 00007569-00181 SICTIONTHREE Test Results Table 3-13 Test Results Summary Rock Dryer (EP-210) (To be submitted separately) URS 17cv1906 Sierra Club v. EPA - 6/22 Production \29-NOV-10W 3-11 ED 001523 00007569-00182 SICTIONFOUR Test Methods The following sections present information on the test methods used for the test program. 41 VOLUMETRIC FLOW, MOISTURE, AND MOLECULARWEIGHT EPA Reference Methods 1, 2, 3, and 4 were used to determine the sample traverse point locations, volumetric flow, flue gas molecular weight, and the gas moisture content. Vent gas velocity and moisture content were measured at the stack location in conjunction with isokinetic sampling trains. Flue gas molecular weight was calculated using EPA Method 3A/3B to determine concentrations of O2 and CO2 in the stack gas. 42 PARTICULATE MATTER The particulate matter (PM) was determined for both the filterable (front half) and back half (condensable) particulate matter fractions for the test program. Because the stack flue gas characteristics after the wet scrubber are such that the presence of entrained water droplets exist, the PM-2.5 (condensable) concentrations were determined using EPA Method 5 in combination with Other Test Method (OTM) 028. A measured volume of stack gas was drawn from the stack isokinetically through a button hook style glass nozzle followed by a heated quartz filter. The remaining sample gas passed through a heated transfer line followed by a vertical water-jacketed condensing coil before entering the impinger train. The front half of the impinger train consisted of an oversized short stem impinger followed by a standard modified impinger. The two parts of the impinger train were connected with an in-train Teflon membrane filter. The sample gas passing through the filter was monitored and maintained at just below 85 F by controlling the temperature of the front half water bath surrounding the impingers. The back half of the impinger train consisted of two standard size modified Greenberg-Smith impingers, the first of which contained 100 ml of organic free water with the final impinger containing silica gel. The back half of the sampling train was immersed in an ice bath to maintain the exit temperature to below 68 F. After exiting the impinger train, the dry gas was measured using a dry gas metering console. Particulate matter trapped in the heated probe and filter assembly was recovered by brushing and rinsing each fraction individually with acetone into separately labeled sample. Front half rinse samples were dried, desiccated for 24 hours, and analyzed gravimetrically at the Enthalphy Analytical in Durham, NC. The glass fiber filter was also desiccated, and the weight gain was added to the rinse weight. The back half of the sampling train, including the heated transfer line and condensing coil, was rinsed with high purity organic free water, high purity acetone, and high purity methylene chloride (MeCl) to recover any condensable matter that may have accumulated during the test run. The impinger train was sealed and transported to the mobile laboratory where it was purged with nitrogen at 20 1pm for one hour before being recovered and extracted with high purity organic free water, high purity acetone, and high purity MeCl to remove and preserve the condensable particulate for evaporation and gravimetric analysis at the laboratory. Rinses were kept separate from the condensed moisture fraction until combined by the laboratory. (Note: During the course of the sampling campaign, the extraction solvent was changed from MeCl to hexane to conform with a facility wide ban on the use of MeCl.) URS 4-1 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00183 SICTIONFOUR Test Methods Moisture in the gas streams was determined using EPA Method 4. In this method, the weight gain in the chilled impingers is used to calculate the percentage of moisture in the stack gas sample. Molecular weight, carbon dioxide, and oxygen content of the gas samples were determined using EPA Method 3A/ 3B. Stack gas velocity and volumetric flow rate were determined using EPA Method 2. In this method, a Type S pitot is used to traverse the duct using traverse points determined by EPA Method 1. The pitot pressures and temperature data collected during each sampling traverse are used to calculate the stack gas velocity. Samples were all given a unique identification code and logged as they were collected and recovered. Identification codes were included on the sample containers during the analytical process. All EPA Method 5 samples were analyzed at Enthalpy Analytical of Durham, North Carolina. Enthalpy also performed the EPA Method OTM-028 analysis. Appendix B-l contains the analytical data sheets and laboratory reports from Enthalpy Analytical. 43 HYDROGEN FLUORIDE - METHOD 26A EPA Method 26A was used to determine emissions of HF in the gas stream. A sample of the stack gas was extracted from the test location through a glass nozzle, heated probe, and filter assembly prior to entering the sample train. The sample was filtered through a Teflon filter maintained at greater than 248 degrees Fahrenheit meeting the specifications for particle retention of 99.95 % for 0.3 um as prescribed in the test method. The sample then passed thorough a knockout Greenberg-Smith impinger containing 50 ml of 0.1 N H2SO4 followed by two standard size Greenberg-Smith impingers also containing 0.1N H2SO4. The sample then passed through two standard size modified Greenberg-Smith impingers containing 0.1N NaOH followed by a silica gel impinger before being measured by a dry gas meter. Hydrogenated halogen compounds, including hydrogen fluoride, were captured in the acidic impinger solutions while the remaining elemental halogens are captured in the basic impinger solutions. After completion of the test run, a leak check was performed and the sampling system was partially disassembled and transported to the mobile laboratory for recovery. Sampling trains were weighed gravimetrically for moisture calculations, and recovered into appropriately labeled sample jars with deionized H20. Enthalpy Analytical in Durham, North Carolina performed the analysis for the acidic impinger fractions for HF by ion chromatography. The filter and NaOH impingers fractions of the sample train were not analyzed but were archived. Enthalpy calculated detection limits by the analysis of at least seven replicate standards at a concentration near the expected MDL. To determine the MDL value, the standard deviation of the replicate analysis was calculated and that number was multiplied by the Student t-factor that corresponds to the number of replicates analyzed. The MDL value meets the criteria stated in CFR Title 40, Part 136B. If the MDL determined did not meet these criteria, a default MDL value was used of 1/10 of the concentration of the standard used to produce the MDL value. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 4-2 \29-NOV-10W ED 001523 00007569-00184 SICTIONFOUR Test Methods 44 TOTAL FLUORIDE - METHOD 13B Total fluoride emissions were measured using EPA Method 13B on four sources during the ICR test campaign. PCS Phosphate field personnel conducted the Method 13B testing during the ICR test period on three of the four sources. URS field personnel conducted the 13B testing on the PAP scrubber source. Previous test data collected by PCS Phosphate personnel using Method 13B was used in lieu of new testing on the other eight sources as allowed in Enclosure 2 instructions. Samples were collected on paper filters and in impingers containing DI water. Sampling was performed isokinetically with the filter temperature maintained at 248 25 F. To analyze the samples, the particulate fraction was combined with the impinger solution and brought to known volume. The combined particulate fraction and the back-half (gaseous fraction) were then analyzed for total fluoride content by specific ion electrode. The 13B fluoride analysis was performed by on-site by the PCS Environmental Lab per their standard operating procedure. The historical Method 13B test data for total fluoride collected by PCS Phosphate personnel is contained in Appendix A-14. 45 METALS-EPA METHOD 29 Emissions of specific metals (antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, phosphorus, and selenium) were determined using the procedures prescribed in EPA 29. A sample of the stack gas was withdrawn isokinetically from the source through a glass nozzle, heated probe, and heater filter prior to entering the impinger train. The impinger train was maintained in an ice bath with an exit temperature of less than 68 F. Gas volume was measured by a dry gas meter. The impinger train consisted of an oversized modified GreenburgSmith impinger, one standard Greenburg-Smith impinger, and three standard sized, modified Greenburg-Smith impingers. The second and third impingers contained a solution of 5% HNO3 and 10% H202 in water. The fourth impinger was empty, and the final impinger contained silica gel. At the completion of each test run, following the final leak check, the sampling train was partially disassembled and transported to the mobile laboratory for sample recovery. The probe and nozzle was first rinsed and brushed with acetone followed by 0.1 N HNO3 into separate jars. In the laboratory, the train was weighed gravimetrically for moisture determinations and recovered as prescribed in the test method. Once the samples were transported back to the URS Laboratory in Morrisville, North Carolina, the acetone rinses were dried down at ambient temperatures and desiccated along with the filters. Following gravimetric analysis of the samples, the acetone rinses were reconstituted with 0.1N HNO3 and added to the front half nitric rinses. Samples were then shipped to the Test America Laboratory in Sacramento, California for analysis by ICP-MS and CVAAS. The metals analysis laboratory reports are contained in Appendix B-2. Test America calculates an MDL using the method of 7 replicate samples spiked at greater than 3 times the estimated MDL. Regent blanks showed no significant levels of contamination. The analytical results for metals were blank corrected where the reagent blank level was measured above the analytical limit of detection. All raw and calculated results are shown on the Metals Emission Summary sheets in Appendix A for each source tested. URS 4-3 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00185 SICTIONFOUR Test Methods 46 EPASW-846 METHOD 0061 (CHROMIUM 6+) EPA SW-846 Method 0061 was used for the determination of hexavalent chromium. The flue gas was collected isokinetically through a glass nozzle and probe, followed by Teflon impingers. A teflon line was placed down the probe liner to continuously recirculate the impinger reagent (KOH), thereby preventing the reduction of Cr+6 between the nozzle and impinger. A peristaltic pump was used to recirculate the absorbing solution at > 50 ml/min. A series of four telfon impingers were used to contain the absorbing solution, followed by a glass impinger containing silica gel for moisture removal. All sample train components were cleaned prior to use by soaking in a 10 % HN03 bath. Reagent grade water was used for sample train recovery. The pH impinger reagent in the sample train was checked during sampling run to verify that it remains above 8.5. The sample train was removed to field lab for purging with nitrogen for 30 minutes immediate after the sample run completion. The recovered impinger solution was filtered on-site through a disposable 0.45 micron acetate filter to remove insoluble matter. The option of determining total chromium from the sample train was not used. The filtered solution was shipped for analysis to Test America Laboratories (TAL) in Knoxville, Tennessee for Cr+6 analysis by ion chromatography. The analytical reports from TAL for Cr+6 are contained in Appendix B-3 47 MERCURY EPA Method 30B EPA Reference Method 30B "Determination of Total Vapor Phase Mercury Emissions From Coal-Fired Combustion Sources Using Carbon Traps" was used to determine vaporous mercury concentration. With Method 30B, flue gas is extracted from a stack or duct using paired, sorbent media traps at a constant flow rate. The use of in-stack sorbent traps minimizes potential loss of mercury during transport through a probe/sample line. For each test run, paired train sampling is used to determine measurement precision and verify acceptability of the measured emissions data. A dual console Apex Instruments Model XC 260 sorbent tube sampling system was used to sample flue gas onto the sorbent traps. The sorbent trap material was procured from Ohio Lumex and packed by URS. For the field recovery test the front section of one tube in each pair was spiked by URS with a known concentration of elemental mercury prior to sampling. The level of the spike was determined by collection and analysis of preliminary sorbent tube. The minimum spike level was 25 ng. An unspiked speciated trap was used in combination with a spiked trap for each train run pair. QA/QC procedures required by Method 30B were adhered to throughout the program. The sorbent traps were analyzed using an Ohio Lumex 915+ thermal analyzer with M324 attachment. A Field Recovery Test based on recovery of an elemental Hg spike was used to assess measurement bias and to verify data acceptability. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 4-4 \29-NOV-10W ED 001523 00007569-00186 SICTIONFOUR Test Methods In accordance with Method 30B section 8.2.3.1.1, an Hg analytical bias test was performed to confirm that the analytical system results were within 10% of the target value. All samples were analyzed by the URS laboratory in Morrisville, NC. In accordance with Method 30B section 8.2.3.1.2, an Hg+2 analytical bias test was performed prior to field deployment to confirm that the analytical system results were within 10% of the target value. As previously approved by the EPA, sources where the presence of mercury is anticipated to be low (example oil-fired sources), spiking should be done at a level were spike is reliable and reproducible. The minimum spike level for this program was 25 ng. In this situation, if the QA/QC criteria for paired trap agreement of spike concentration with respect to sample concentration are not met, the test runs will still be considered as valid. A total of 3 paired Method 30B test mns of 1-hour duration each, were conducted simultaneously with a single corresponding Ontario Hydro (OH) Method. The moisture and flow rate from the corresponding OH sample train was used for mass rate determination. ASTM Standard D6784-02 ASTM Standard D6784-02 (Ontario Hydro Method) was used to determine concentrations of particle-bound, oxidized, and elemental mercury in the flue gas. The method requires isokinetic sampling of the flue gas at predetermined sample points derived from EPA Method 1. The sample passed through a glass buttonhook style nozzle and through a glass-lined sample probe. Particle-bound mercury in the flue gas was collected on the probe liner and on a heated quartz filter heated to 248 F. The sample was then pulled through a series of eight chilled impingers. The first three impingers contained 0.1N potassium chloride (KC1) to absorb oxidized mercury in the flue gas. The fourth impinger contained a solution of 5% nitric acid (HN03) and 10% hydrogen peroxide (H2O2) that oxidizes elemental mercury in the flue gas. After being oxidized, the elemental fraction is collected in the three impingers containing an acidified potassium permanganate (KMn04) solution. The final impinger contains silica gel to collect any residual moisture. The impingers are partially submerged in an ice bath to cool the flue gas sample to <68 F. After completing the test run, the train was partially disassembled and transported to a mobile laboratory to be recovered and preserved. A field blank was collected for method QA/QC. Samples were logged and transported to an off-site laboratory for analysis. The Ontario Hydro sample analysis for mercury species was performed by Test America in Knoxville Tennessee. The samples were shipped in batches periodically during the test program. The OH analytical reports are in Appendix B-4. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 4-5 \29-NOV-10W ED 001523 00007569-00187 SICTIONFOUR Test Methods 48 EPA METHOD 320 (FTIR) URS conducted EPA Method 320 testing to determine the concentration of Methyl Isobutyl Ketone (MIBK) and HF using FTIR from the Purified Acid Plant (PAP) chiller and scrubber sources. A series of three 1-hour test runs were conducted at each source along with pre and post sampling analyte (or surrogate) spiking. Moisture and molecular weight were determined from the FTIR data. The stack gas velocity (delta P) was determined before and after each FTIR test run by a electronic manometer (Hastings Shortridge Model ADM-870). The Method 320 field test summary and tabular results along with the supporting quality assurance (QA) field data are presented in Appendix A-l 1-1 and A-12-5. URS 17cv1906 Sierra Club v. EPA - 6/22 Production 4-6 \29-NOV-10W ED 001523 00007569-00188 SECTIONFIVE Qualm flssuranoe/Quallty Control Specific quality assurance and quality control (QA/QC) procedures were used during the test program to cover field sampling, recovery, sample analysis, data reduction, and interpretation of results. QA/QC procedures were followed to ensure the production of useful and valid data. This section will describe these procedures and will report the test program QA parameters, which indicate data quality. 5.1 SAMPLING QA/QC Prior to and immediately following each test run, leak checks of all manual method sampling trains were performed to verify no sample dilution of the sampled stack gas was occurring during the test. All leak checks were recorded properly and met the leak criterion. Where any leak check failed, the test run was aborted and repeated. Prior to and following the tests, pitot leak checks were performed on the pressure differential measuring systems. The oxygen and carbon dioxide analyzers used to measure the flue gas molecular weight from integrated bags were calibrated using EPA Protocol 1 gases. Copies of the gas cylinder certifications are included in the QA appendix. Sampling media and glassware were prepared using the prescribed procedures for the applicable test method. Glassware was re-cleaned in the laboratory between the testing on different source types. Field blanks were taken periodically (for each source group) to verify cleanliness between source units. 5.2 OTHER QA/QC The sampling and recovery procedures specified in EPA Methods 5, 26A, 29, OTM-028, SW846-0061, and ASTM D6784 were utilized. The following QA/QC procedures were satisfied for the purpose of ensuring valid results: All sampling equipment passed a thorough visual and operation check prior to and after transport to ensure clean and operable parts. Equipment that failed to pass this check was not used in the field. Manometers were leveled and zeroed before measuring the differential pressure across the Stype pitot tubes. Each leg of the S-type pitot tube achieved the prescribed leak criterion described in EPA Method 2. The temperature measurement system was capable of measuring the ambient temperature prior to each traverse to within 2C of the average measured ambient temperature. The field personnel reviewed sampling data forms daily on-site during testing. Checks of the isokinetic sampling rate were conducted in the field. Any test run that failed the isokinetic criteria were repeated. Ice was maintained in the impinger baths at all times; exit temperatures were maintained at less than 20C (<68F) except for the front half of the OTM028 impinger train which was maintained at less than 29C (<85F). Readings of the dry gas meter, stack gas velocity head (AP), sample line orifice meter pressure differential (AH), temperature, and vacuum pump were made during sampling at each traverse point at five minutes intervals. ins 5-1 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00189 SECTIONFIVE Qualm flssuranoe/Quallty Control Dry gas meters were calibrated before the test program and the calibration was rechecked after the test was completed using the ALT-009 Gamma QA procedure. When the gamma QA criterion was exceeded the dry gas meter was recalibrated and the lower meter calibration coefficient was used to calculate the final results. Field blanks were conducted and analyzed for each manual test method performed on-site. Reagent blanks were collected and archived in case of further need for analysis. 5.3 TEST METHOD EXCEPTIONS AND TEST PROGRAM NOTES The following exceptions to test methods and test program notes effecting the execution and quality control of the emissions testing are noted in this section. Due to the large sample volume (3.4 m3) requested and the high stack gas moisture encountered, the Method 0061 sampling train was modified to incorporate extra knockout impingers prior to the final silica gel impinger. Even with the extra impingers the sampling runs were stopped periodically to empty the impinger contents into a dedicated sample container. The pH of the sampling solution was checked during the impinger change. Multiple changes of the knock out and silica gel impingers were required for a majority of the sources due to the high moisture. After completion of the testing sequence at the DFP Kiln (EP-701) during the data review process, a leak was determined to have occurred in the integrated bag collection system on the meter box. Subsequent collection of integrated bags on an independent collection system at the source the following week indicated a significantly different (lower) 02 content. All integrated bag samples collected during the test period were voided. A default value of 8.1 % C02 and 13.1 % 02 was used in the calculation of molecular weight and oxygen correction calculations. The default value was determined from previous CEM test data on the source and verified for reasonableness by additional bag samples after completion of the DFP Kiln emission test sequence. The emission test results for combustion type sources are with expressed in the test report corrected to 3 % oxygen. These sources include the Calciner, DFP Kiln and the Rock Dryer. All other sources in the test program are expressed at the as measured oxygen concentration without correction as the majority of the sources are not combustion type processes. EPA test method representatives approved this approach. On the non-combustion sources tested during the program, if an individual Method 3A/3B integrated bag result was compromised the average value from the remaining valid runs was averaged and used as a default value to calculate the molecular weight. After completion of the Phosphoric Acid plant emission testing, additional dry gas meter calibrations were conducted when the dry gas meter gamma QA acceptance criterion was exceeded. Final results were calculated with the dry gas meter calibration factor which yielded the lower gas volume per prescribed reference method guidance. The 14-day hold time for Method 0061 analysis was exceeded for the PA-4 sources due to an instrument failure in the laboratory. The samples exceeding the hold time were reanalyzed on July 24th with similar results. The higher value from the first analysis (7/7/10) was used to calculate the presented results. URS 5-2 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00190 SECTIONFIVE Qualm flssuranoe/Quallty Control Based on the low level of Hg in the preliminary samples at the Phosphoric Acid plants, the EPA Method 3 OB test runs were conducted at the lowest spiking level available (25 ng) and an increased sample flue gas. Because the levels of flue gas Hg were so low, the test data did not meet the method recommendation for spiking levels being 50-150% of the actual measured values. Discussion with the EPA confirmed the spiking criteria is guidance, but is not as a requirement of the test method. The speciated 30B sorbent tubes for mercury at the Phosphoric Acid sources were at or below the analytical detection limit of 2.6 ng for individual bed components. Therefore the speciated Hg tube results from Method 30B are no considered valid nor presented in the results summary. The as measured amounts are presented in the analytical data. Method 30B Run 1 traps at the PA-4 Crossflow Scrubber was lost during the analysis due to an instrument calibration error. After completion of the mercury testing on the Phosphoric Acid plants, it was determined that mercury sampling would be discontinued for the Aurora plant downstream sources because the measured mercury content was below the measured method sensitivity. EPA test method representatives approved the decision to discontinue further Hg testing during the ICR test program. The extraction solvent for the OTM-28 train (Methylene Chloride) was changed to hexane during the course of the ICR test program. The change was approved by EPA test method representatives. No impact upon the data quality is expected. The stack gas velocity head (delta P) was determined with an electronic manometer (Hastings Shortridge ADM-680) rather than an inclined manometer for all emissions testing on the SPA2, SPA3/4 and PAP sources due to low stack gas velocity. The ADM-680 calibration certificates are in Appendix D. Water samples from the SPA 2, SPA3/4 and Rock Dryer test locations were not collected. A suitable sample collection location from the scrubbers was not available in the SPA Process area. The configuration of scrubber effluent piping in the SPA process area was such that the scrubber water was discharged into a combined effluent stream (ditch) that precluded collection of the water sample during the OTM-28 testing. Installation of a tap to isolate the water discharge stream would have required shutting down the process units. The collection of water samples at the Rock Dryer during OTM 28 test method was inadvertently overlooked. The test ports on SPA3/4 were too small to accommodate the combined pitot tube and probe assembly. Therefore with EPA permission, two ports 90 degrees apart just above the sample port were used to determine the velocity profile prior to and after the sampling traverse. The isokinetic sampling runs were completed along a single traverse at a lower port which would accommodate the sample train. The dwell time at each point on the isokinetic traverse was doubled. The sample ports exceeded the equivalent diameter criterion of Method 1. Due to the low stack gas velocity for the source there is expected to be little impact on data quality. The geometry and size of the exhaust duct at the PAP chiller precluded simultaneous measurements of gas velocity and MIBK concentration. The internal diameter of the exhaust duct was less than 4 inches. In addition, the withdrawn of sample via heated line to the FTIR altered the measured stack velocity because it was so low. Therefore the flue gas velocity was measured independently before or after the Method 320 test run. The Method 320 testing used formaldehyde as spiking surrogate for hydrogen fluoride. ins 5-3 \29-NOV-10W 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00191 Appendix A Sampling Data 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00192 Appendix B Analytical Data 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00193 Appendix C Process Data 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00194 Appendix D Field Datasheets And QA/QC Supporting Data 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00195 Appendix E Solid Material Assay [PCS) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00196 Appendix F EPA EBT Files & Spreadsheet 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00197 Appendix G Test Plans & Correspondence 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00198 Appendix A-1 -6 Emission Test Data for Total Fluoride 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00199 URS Sample Calciner#3 R1 Calciner#3 R2 Calciner #3 R3 Pollutant Date - 8/3/2010 - 8/3/2010 - 8/3/2010 Average Start 9:19 10:50 15:35 End 10:35 12:06 17:16 Analytical Flag mass / sample v. 0.303 Sample Volume Emission Concentration dscf mg/dscf 44.976 41.867 45.546 44.129 0.0075 0.0071 0.0061 0.0069 Volumetric Flow Rate dscfm 40799 39775 41182 40,585 Emission Rate o2 Ib/hr % 4.06E-02 14.8 3.72E-02 14.8 3.30E-02 14.8 3.69E-02 14.8 a Method 13B collected and anlayzed by PCS - Results presented here for purpose of Data Entry into ERT Emission Concentration gr/dscf @ 3% 02 3.40E-04 3.20E-04 2.74E-04 3.12E-04 Calciner3 M13B 17cv1906 Sierra Club v. EPA - 6/22 Production Collected by PCS F conc&emis ED 001523 00007569-00200 URS Date Location/Condition Run Worksheet Tab Name Start Time End Time Source Area (ft`) Nozzle Diameter (") DGM # DGM Calibration Factor (YD) H@ Pitot (Cp) Stack Barometric Pressure ("Hg) Static Pressure ("H20) Test Duration (min) Minutes per point Meter Volume x DGMCF (ftJ) Impinger Mass Gain (g) Meter Temperature (R) Average H (in H20) Meter Pressure ("Hg) % H20 at saturation % h2o % co2 % o2 % n2 Dry Molecular Weight (mw3rj.) Source Molecular Weight (mw.) Avg. SORT Delta P Avg. Source Temperature (R) Avg. Source Pressure ("Hg) Gas Velocity (ft/s) Stack Gas Flow Rate (acfm) Stack Gas Flow Rate (dscfm) Standard Sample Volume (dscf) Average Isokinetic % Average sqrt( H) Y(qa) Y ( 5%) 3 3 20 0 Calciner #3 ' Calciner #3 R1 9: 3 0:35 23.27 0.236 =CS-2 ' .005 ' .369 0.34 30.09 -0.23 72 3 45.230 729.6 535.6 '..44 30.20 32.' 32.' 3.6 4.3 76.6 30.0 26.' 0.65 620.: 30.07 4'.4 70,270 40.799 44.976 97.4 V3 ' .030 2.5 8/3/2010 Calciner #3 2 Calciner #3 R2 10:50 12:06 28.27 0.284 PCS-2 1.005 1.869 0.84 30.12 -0.28 72 3 42.426 695.5 540.0 1.30 30.22 32.1 32.1 8.6 14.8 76.6 30.0 26.1 0.63 620.2 30.10 40.3 68,411 39,775 41.867 93.9 1.14 1.052 4.7% 8/3/2010 Calciner #3 3 Calciner #3 R3 15:35 17:16 28.27 0.286 PCS-2 1.005 1.869 0.84 30.12 -0.28 72 3 46.258 843.9 541.5 1.48 30.23 32.8 32.8 8.6 14.8 76.6 30.0 26.0 0.66 621.1 30.10 42.3 71,749 41,182 45.546 97.7 .: 1.029 2.4% Calciner #3 Average 28.27 0.286 0.84 30.11 -0.28 72.00 3.00 44.64 756.32 539.02 1.41 30.21 32.34 32.34 8.60 14.80 76.60 29.97 26.10 0.65 620.48 30.09 41.35 70,143 40,585 44.13 96.32 1.18 1.04 3.2% Calciner 3 M13B 17cv1906 Sierra Club v. EPA - 6/22 Production Collected by PCS Summary ED 001523 00007569-00201 URS Client PCS Phosphate Run Date duration (min) 8/3/2010 Sample Pt. Average Total Start End NW1 2 3 4 5 6 7 8 9 10 11 12 SW1 2 3 4 5 6 7 8 9 10 11 12 Time 1:12 9:19 10:35 9:19 9:22 9:25 9:28 9:31 9:34 9:37 9:40 9:43 9:46 9:49 9:52 9:55 9:59 10:02 10:05 10:08 10:11 10:14 10:17 10:20 10:23 10:26 10:29 10:32 10:35 Location Calciner#3 Diameter {or width) 72 Area {ft") 28.27 Test Method DGMCF (Yd) 7 Reading (ft-) 45.005 13B 1.005 0.84 Delta P 0.429 Length (if rectangular) Measured Pbarf'Hg) Static P ("H:<0) . Delta P Delta H f'l-UO) (HH?0) | 0.649 | 1.438 | 30.19 -0.28 Source Temp. 160.5 Height rel. to barometer (ft) Adjusted Pbar Nozzle Dia.(") DGM Temp. Inlet (F) | 75.9 100 30.09 0.286 Outlet DGf' min/po Veloc (ft/s | 41.4 600.500 0.14 0.37 0.46 160 72 7~ 23.9 601.5 0 0.56 1.21 164 72 7;' 35.6 603.2 0.36 0.60 1.17 165 72 7" 38.4 604.8 0.36 1.17 164 73 1 38.4 606.5 0.39 0.62 1.27 164 73 1 40.0 608.4 0.43 0.66 1.4 165 74 74 42.0 610.3 0.56 0.75 1.83 161 74 74 47.8 612.4 0 0.76 1.89 161 75 1 48.6 614.6 0 . ` 1.86 160 75 1 48.2 616.7 0 1.89 160 76 76 48.6 619.1 0.60 0.77 1.96 163 76 76 49.5 621.5 0.54 1.77 164 77 1 47.0 623.572 623.572 0 0.52 1.56 167 77 1 625.0 0.36 1.17 160 77 1 626.6 0.39 0.62 1.27 160 77 1 628.0 0 0.62 1.25 162 77 1 39.4 630.2 0.40 1.31 161 78 1 40.4 632.0 0.42 0.65 1.37 157 78 1 41.2 633.9 0.46 0.68 1.5 159 78 1 43.2 635.8 0.46 0 68 1.5 150 78 1 42.9 637.8 0.40 1.31 152 78 1 40.1 639.7 0.43 0.66 1.41 153 78 1 41.6 641.8 0.45 1.47 163 78 1 42.9 643.8 0.46 1.5 156 78 1 43.1 645.505 PCS-2 1.869 3 Impinger Train Mass Measurments Impinger Initial (g) Final (g) 1 691.5 950.2 2 664.2 877.3 3 654.5 827.2 4 786.8 872.1 5 6 7 Gain (g) 258.7 213.0 172.6 85.3 0.0 0.0 0.0 Sum 729.6 Molecular Weight Measurements C02 (%) o2(%) 1 8.6 . ... 4 4 Avg 8.6 JVoH;,0 (sat)------ --TTT Bws {H;iO) 0.321 \\\ . MW wet 29.97 26.13 Vw std 34.38 Mol Fraxn dry 0.6789 Vm 45.005 Tmeter (R) 535.6 Pmeter 30.20 Vm std 44.976 % Isokinetic 97.4 14.8 76.6 76.6 Ca!ciner3 M13B 17cv1906 Sierra Club v. EPA - 6/22 Production Collected by PCS Stack R1 ED 001523 00007569-00202 URS PCS Client Phosphate Run 2 Date duration (min) 8/3/2010 72 Sample Pt. Average Total Start End NW1 2 3 4 5 6 7 8 9 10 11 12 SW1 2 3 4 5 6 7 8 9 10 11 12 Time 1:12 12:06 10:53 10:56 10:59 11:02 11:05 11:08 11:11 11:14 11:17 11:20 11:23 11:26 11:30 11:33 11:36 11:39 11:42 11:45 11:48 11:51 11:54 11:57 12:00 12:03 12:06 Location Calciner #3 Diameter (or width) 72 Area (ft1') 28.27 Test Method DGMCF (Yd) Cp DGM Reading (ft') 42.215 646.000 647.1 648.9 650.6 652.1 653.8 656.5 657.2 659.2 661.2 663.3 665.4 667.542 667.542 669.1 670.5 672.0 673.9 675.6 677.5 679.3 681.1 683.2 684.8 686.4 688.215 13B 1.005 0.84 Delta P ("H:,Oj 0.404 0.2 0.34 0.34 0.2 0.42 0.4 0.49 0.2 0.2 0.56 0.2 0.2 0.36 0.36 0.2 0.4 0.4 0.2 0.4 0.4 0.2 0.4 0.4 Length (if rectangular) Measured Pbar("Hg) Static P ("H,:0) SORT Delta P Delta H fU.O) ("H:,0) | 0.632 | 1.301 | 30.22 -0.28 Source Temp. (F) 160.5 Height rel. to 100 barometer (ft) Adjusted Pbar 30.12 Nozzle Dia.C) 0.2841 DGM Temp. Inlet Outlet (F) (F) | 80.3 DGM# min/point Velocity (ft/'s) | 40.3 156 1.03 156 78 78 35.9 1.1 164 78 78 37.3 1.1 164 79 79 1.23 163 79 79 39.4 1.36 163 79 79 41.4 1.36 160 80 80 41.3 1.58 158 80 80 44.5 1.67 163 81 81 46.5 1.71 164 81 81 46.6 1.81 154 81 81 47.5 1.67 161 82 82 46.0 0.90 162 81 1.16 155 81 1.16 159 81 1.19 162 81 1.32 158 81 1.32 162 81 1.23 162 81 1.29 162 81 1.32 156 81 1.19 162 81 1.42 163 81 1.36 163 81 81 33.8 81 38.1 81 38.2 81 38.8 81 40.8 81 40.9 81 39.4 81 40.4 81 40.7 81 81 42.4 81 41.4 PCS-2 1.869 3 Impinger Train Mass Measurments Impinger Initial (g) Final(g) 1 676.1 932.3 2 679.8 867.9 3 680.5 848.5 4 782.7 866.0 5 6 ` Gain (g) 256.2 188.1 168.0 83.3 Sum 695.5 Molecular Weight Measurements C02 (%) o2(%) 8.6 2 3 4 Avg %H?U (sat)------ --T27T t5WS (H;;U) 0.321 14.8 14.8 v.\ . 7 Vw std Mol Fraxn dry 29.97 26.13 32.77 0.6793 Vm Tmeter (R) 42.215 540.0 Pmeter Vm std 30.22 41.867 % Isokinetic 93.9 N2 (%) 76.6 76.6 Caiciner3 M13B 17cv1906 Sierra Club v. EPA - 6/22 Production Collected by PCS Stack R2 ED 001523 00007569-00203 URS PCS Client Phosphate Run 3 Date duration (min) 8/3/2010 72 Sample Pt. Average Total Start End NW1 2 3 4 5 6 7 8 9 10 11 12 SW1 2 3 4 5 6 7 8 9 10 11 12 Time 1:12 15:35 17:16 12:21 12:24 12:27 12:30 12:33 12:36 12:39 12:42 12:45 12:48 12:51 12:54 12:55 12:58 13:01 13:04 13:07 13:10 13:13 13:16 13:19 13:22 13:25 13:28 13:31 Location Calciner #3 Diameter (or width) 72 Area (ff) 28.27 Test Method DGMCF (Yd) . 7 Reading (ft') 46.028 688.700 689.0 691.4 693.3 695.4 697.2 699.3 701.6 703.8 706.1 708.2 710.5 712.628 712.628 714.3 716.0 717.7 719.5 721.3 723.3 725.2 727.1 729.0 730.9 732.8 734.728 13B 1.005 0.84 Delta P ("HjOj 0.444 0.2 0.2 0.4 0.2 o.e 0.56 0.56 0.59 0.54 0.2 0.56 0.2 0.2 0.4 0.39 0.4 0.4 0.4 0.4 0.4 0.44 0.44 0.4 Length (if rectangular) Measured Pbarf'Hg) Static P ("H:iO) SORT Delta P Delta H ("H;;Oj ("H,0) | 0.662 | 1.483 | 30.22 -0.28 Source Temp. (F) 161.4 Height rel. to barometer (ft) Adjusted Pbar Nozzle Dia.(") DGM Temp. Inlet (F) | 81.8 100 30.12 0.2855 Outlet (F) DGM# H@ min/point Velocity (ft/s) | 42.3 0.60 163 27.2 0.94 163 80 80 33.9 1.235 163 80 80 38.9 1.569 163 81 81 43.9 1.737 161 81 2.000 161 81 81 46.1 81 49.5 1.870 161 81 81 47.8 1.870 161 82 82 47.8 1.970 161 82 82 49.1 1.80 162 82 82 47.0 1.737 160 82 82 46.0 1.870 161 82 82 47.8 1.035 155 82 82 35.4 1.170 160 82 82 37.8 1.336 160 82 82 40.4 1.303 161 82 82 39.9 1.402 163 82 82 41.5 1.503 162 82 82 42.9 1.503 162 82 82 42.9 1.336 163 83 83 40.5 1.436 163 83 83 42.0 1.470 163 83 83 42.5 1.470 163 83 83 42.5 1.436 159 83 83 41.8 PCS-2 1.869 3 Impinger Train Mass Measurments Impinger Initial (g) Final(g) 1 662.6 979.8 2 641.3 889.7 3 691.3 785.9 4 680.4 864.1 5 6 7 Gain (g) 317.2 248.5 94.5 183.6 Sum 843.9 Molecular Weight Measurements C02 (%) o2{%) 8.6 2 3 4 Avg %H?U (sat)------ -- t5WS (H;;U) 0.328 v.\ . 29.97 7 26.04 Vw std 39.76 Mol Fraxn dry 0.6716 Vm 46.028 Tmeter (R) 541.5 Pmeter 30.23 Vm std 45.546 % Isokinetic 97.7 14.8 14.8 Nj (%) 76.6 76.6 Calciner3 M13B Collected by PCS Aurora 17cv1906 Sierra Club v. EPA 6/22 Production Stack R3 ED 001523 00007569-00204 PCS AMENDED PETITION - ATTACHMENT B UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WAS) ;!f'K, I Of 1 0 (, 'u DEC i 4 W5 OFFICE OF AIR AMD RADIATION Ms. Casey Penning Bradford. Counsel for PCS Jones Day 1420 Peachtree Street. \F Suite 800 Atlanta. Georgia 30300-3053 Dear Ms. Bradford: This is in reply to your October 16. 2015 petition for reconsideration of the final rule. "Phosphoric Acid Manufacturing and Phosphate Fertilizer Production RTR and Standards of Performance for Phosphate Processing" (80 FR 50386. August 19. 2015). which you submitted pursuant to section 307(d)(7)(B) of the Clean Air Act (CAA). on behalf of your client. Potash Corporation of Saskatchewan (PC'S). The C.S. Hnvironmenlal Protection Agency has received multiple petitions for reconsideration of this final rule. Your petition seeks reconsideration of two issues: (1) the total fluoride emission limit for ealeiners in the final rule, and (2) the requirement in the final rule for liquid-to-gus ratio monitoring of low energy scrubbers. In response to your petition asking the KPA to reconsider several aspects of this rule, and pursuant to CAA section 307(d)(7)(B). I grant reconsideration of the final rule on both of the above issues. The FPA intends to issue a Federal Register notice proposing the results of our reconsideration process on the issues identified above expeditiously, although the schedule of this proposal may depend on the time required for industry to respond to our request for additional information to support the reconsideration request. The petition letter also requests a stay of the final rule for 90 days under the Administrative Procedures Act or the CAA. We intend to take final action on the request for a stay of the rule no later than the date we take final action on the issues described above. if you have any questions regarding the reconsideration process, please contact Peter Tsirigotis. Director of the Sector Policies and Programs Division, at (919) 541-9411. We thank you for your continuing interest in this rule and look forward to hearing from \ou during the reconsideration process. Sincerely. Janet G. McCabe Acting Assistant Administrator 17rvl QDfi Sierra Club v. EPA - 6/22 Production ED 001523_00007569-00205 PCS AMENDED PETITION - ATTACHMENT C RE: PCS - Calciner MACT Test Report Casey F Bradford/JonesDay to: Fairchild, Susan 4.8119 "Barnett, Keith", "brandon.long@erg.com", "Garwood, Gerri", "jason.renzaglia@erg.com", "Jessica.DeMonte", RSmith 05/10/2016 05:37 PM Susan, Thank you for your email. Attached is a letter that I was preparing about the emission limits for both mercury and total fluorides at the PCS Aurora calciners when I received your email. PCS does wish to meet with EPA. Available dates for PCS to come to Raleigh are: 5/24 or 5/26. Please let me know what dates work and who will be attending for EPA. I can let you know who will attend for PCS in the coming days. As explained in the letter, PCS thinks that the mercury limit for the calciners needs to be revised. PCS was surprised by the compliance test results for mercury which exceeded the MACT floor standard at three of the calciners. Since that time, PCS has collected a large amount of new data on mercury emissions and related process variables to try to understand the test results, but no straightforward explanation has been identified. We would like to present the additional mercury information to EPA at the meeting and seek a path forward to updating the MACT floor to reflect the current emissions data for the calciners. PCS does not make this request lightly. At this point in its testing and analysis of mercury emissions, PCS does not see any other reasonable alternative. We will also be prepared to update you on our assessment of the fluoride limit based on the compliance test results. Thanks again, Casey -5.10.2016 PCS Letter.PDF Casey Fernung Bradford (bio) Partner JONES DAY - One Firm Worldwide. 1420 Peachtree Street, N.E. Suite 800 Atlanta, GA 30309 Office+1.404.581.8119 cbradford@jonesday.com This e-mail (including any attachments) may contain information that is private, confidential, or protected by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. "Fairchild, Susan" From: To: Cc: Date: "Fairchild, Susan" <Fairchild.Susan@epa.gov> Casey F Bradford <cbradford@jonesday.com> "Barnett, Keith" <Barnett.Keith@epa,gov>, "Garwood, Gerri" <Garwood.Gerri@epa.gov>, "jason.renzaglia@erg.com" <jason.renzaglia@erg.com>, "brandon.long@erg.com" <brandon.long@erg.com> 05/09/2016 12:55 PM 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00206 Subject RE: PCS - Calciner MACT Test Report Casey, We've reviewed the data and think it may be a good point to discuss with PCS where we are on this. If you would like to meet with ERA, please let me know your available dates and times and I'll set something up with the involved parties here. Thanks, Susan Fairchild Senior Environmental Scientist (919) 541-5167 USPS Address: OAQPS/SPPD/MMG Mail Code D 243-04 Research Triangle Park, NC 27711 From: Casey F Bradford [mailto:cbradford@jonesday.com] Sent: Thursday, March 31, 2016 11:25 AM To: Fairchild, Susan <Fairchild.Susan@epa.gov> Cc: Barnett, Keith <Barnett.Keith@epa.gov>; TBaker@potashcorp.com; Jessica.DeMonte@potashcorp.com Subject: PCS - Calciner MACT Test Report Susan, Please see the attached MACT test report that PCS submitted to North Carolina DEQ for the calciners. PCS is also submitting these results electronically via ERT reports as required by the recent changes in Subpart AA. ERT reports are being submitted for each calciner according to the applicable 60-day reporting period. As I mentioned in a previous email, Hg emissions from three calciners were above the new MACT floor limit at the time of testing. Mercury emissions from the other three calciners were close to but did not exceed the limit. To understand these results, PCS has been studying process data at the time of testing and collecting a large amount of additional process data for the calciners. The study so far has revealed a lot more variability in feed mercury content than was anticipated. PCS is concerned that the 2010 and 2014 ICR data (which are the basis for the MACT floor limit) do not reflect the variability that actually occurs in feed mercury content. Because mercury in the feed cannot be predicted or controlled, PCS is studying other process and control device parameters to figure out whether there is a feasible way to make the limit achievable during representative operating conditions, which include significant variability in feed mercury content. We are still collecting data and waiting for lab results at this point. We anticipate having new information to share by the end of April or early May. You will also see that the recent fluoride results were below the new fluoride limit for all calciners. While this is certainly good news, PCS is still concerned that the fluoride limit is not achievable during other representative operating conditions; including, for example, the conditions experienced during the 2014 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00207 fluoride testing which produced results in excess of the limit that was established in 2015. PCS has explained that the 2014 fluoride results (expressed in pounds per ton of feed ) were obtained during a period of low feed inventory, which led to high feed moisture content and therefore low feed rates and high residence time. Although PCS continues to believe that feed rate can influence fluoride emissions, PCS has been collecting more data on fluoride in the calciner feed and looking for other information that could shed light on fluoride emissions variability. As with mercury, we expect to have more information to share with EPA in April or early May. Thanks, Casey Casey Fernung Bradford (bio) Partner JONES DAY - One Firm Worldwide 1420 Peachtree Street, N.E. Suite 800 Atlanta, GA 30309 Office+1.404.581.8119 cbradford@ionesday.com This e-mail (including any attachments) may contain information that is private, confidential, or protected by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. This e-mail (including any attachments) may contain information that is private, confidential, or protected by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. This e-mail (including any attachments) may contain information that is private, confidential, or protected by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00208 JONES DAY 1420 PEACHTREE STREET, N.E. SUITE 800 ATLANTA, GEORGIA 30309.3053 TELEPHONE:+1.404.581.3939 FACSIMILE.+1.404.581.8330 May 10,2016 Sent Via Email & Certified Mail Ms. Susan Fairchild Environmental Protection Agency 109 T.W. Alexander Drive Mail Code: D243-04 Research Triangle Park, NC 27711 Susan. Fairchild@epa. gov Re: PCS Phosphate Company, Inc. / MACT Limit for Mercury Emissions from Existing Phosphate Rock Calciners Dear Ms. Fairchild: Thank you for your May 9,2016 email. As suggested in your email, PCS Phosphate Company, Inc. (PCS) does wish to have an in-person meeting with EPA to discuss the need for a revision of the MACT floor limit that EPA set on mercury emissions from existing phosphate rock calciners in the August 2015 final rule to revise 40 C.F.R. Part 63 Subpart AA. 80 Fed. Reg. 50,386 (Aug. 19,2015). After collecting and reviewing a considerable amount of new data on mercury emissions and other process variables, which PCS would like to present to EPA at a meeting, PCS has concluded that the calciner mercury limit in the final rule does not reflect the MACT floor for mercury emissions during the expected range of representative operating conditions at the PCS calciners in Aurora, North Carolina. As such, PCS requests an opportunity to collect additional Method 30B test data on mercury emissions which can then be used to re-calculate the mercury MACT floor. Under section 112(d)(3)(B) of the Clean Air Act, a MACT floor limit must reflect the average emissions achieved by the best performing five sources in a source category with fewer than 30 sources. The six calciners at PCS' facility in Aurora are the only existing phosphate rock calciners in the Subpart AA source category. Therefore, the mercury MACT floor is supposed to reflect the average emissions already achieved by the PCS calciners. EPA determined the MACT floor in its August 2015 final rule based on mercury test data collected for the PCS calciners in 2010 and 2014. EPA applied its Upper Prediction Limit (UPL) methodology to the results of 2010 and 2014 mercury testing and determined the MACT floor to be 0.14 mg/dscm at three percent oxygen. As required by the final rule, PCS conducted initial performance testing of mercury emissions from the calciners earlier this year. The test report sent to you on March 31,2016 shows that initial performance test results for Calciners 1, 3 and 4 exceeded the new MACT floor limit for mercury emissions from existing calciners. Mercury emissions from the other three calciners (Nos. 2, 5 and 6) were close to, but did not exceed, the new mercury limit. For all six calciners, ALKHOBAR AMSTERDAM ATLANTA BEIJING BOSTON BRUSSELS CHICAGO CLEVELAND COLUMBUS DALLAS DUBAI DOSSELDORF FRANKFURT HONG KONG HOUSTON IRVINE JEDDAH LONDON LOS ANGELES MADRID MEXICO CITY MIAMI MILAN MOSCOW MUNICH NEW YORK PARIS PERTH PITTSBURGH RIYADH SAN DIEGO SAN FRANCISCO SAO PAULO SHANGHAI SILICON VALLEY SINGAPORE SYDNEY TAIPEI TOKYO WASHINGTON 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00209 Ms. Susan Fairchild May 10,2016 Page 2 JONES DAY the initial performance test results were significantly higher than the results of the 2010 and 2014 mercury testing that EPA used to set the MACT floor. Since receiving the performance test results, PCS has collected and reviewed a large amount of additional process and emissions data for the calciners in an effort to understand mercury emissions variability. These data indicate that mercury emissions are more variable than reflected in the 2010 and 2014 test data or the UPL analysis that EPA used to set the MACT floor. PCS requests an opportunity to review the emissions and process data with EPA and discuss the path forward. In addition to reviewing mercury-related data, PCS would like to update you on its assessment of the total fluoride emission limit for existing phosphate rock calciners. Our team would be available for a meeting in Raleigh, NC on May 24 or 26. Please let me know if any of these dates would work for EPA. You can reach me by telephone or email to schedule a meeting with PCS and discuss any questions you may have in the meantime. PCS appreciates EPA's attention to these matters which have a significant impact on the Aurora facility. Respectfully submitted, Casey Bradford (404)581-8119 cbradford@j onesday.com Outside Counsel for PCS cc: Mr. Keith Barnett Environmental Protection Agency 109 T.W. Alexander Drive Mail Code: D243-04 Research Triangle Park, NC 27709 Bamett.keith@Epa.gov Mr. Jonathan Averback, Esq. Office of General Counsel Environmental Protection Agency 1200 Pennsylvania Avenue, NW Mail Code: 2344A Washington, DC 20460 Averback.jonathan@Epa.gov NAI-1500990111v3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00210 PCS AMENDED PETITION - ATTACHMENT D PCS - Calciner MACT Test Report -I '-'fn- l'if'. .!'/ Fairchild, Susan a.k i i y l,c: "Barnett, Keith", TBaker, Jessica.DeMonte 03/31/201611:25AM Susan, Please see the attached MACT test report that PCS submitted to North Carolina DEQ for the calciners. PCS is also submitting these results electronically via ERT reports as required by the recent changes in Subpart AA. ERT reports are being submitted for each calciner according to the applicable 60-day reporting period. As I mentioned in a previous email, Hg emissions from three calciners were above the new MACT floor limit at the time of testing. Mercury emissions from the other three calciners were close to but did not exceed the limit. To understand these results, PCS has been studying process data at the time of testing and collecting a large amount of additional process data for the calciners. The study so far has revealed a lot more variability in feed mercury content than was anticipated. PCS is concerned that the 2010 and 2014 ICR data (which are the basis for the MACT floor limit) do not reflect the variability that actually occurs in feed mercury content. Because mercury in the feed cannot be predicted or controlled, PCS is studying other process and control device parameters to figure out whether there is a feasible way to make the limit achievable during representative operating conditions, which include significant variability in feed mercury content. We are still collecting data and waiting for lab results at this point. We anticipate having new information to share by the end of April or early May. You will also see that the recent fluoride results were below the new fluoride limit for all calciners. While this is certainly good news, PCS is still concerned that the fluoride limit is not achievable during other representative operating conditions; including, for example, the conditions experienced during the 2014 fluoride testing which produced results in excess of the limit that was established in 2015. PCS has explained that the 2014 fluoride results (expressed in pounds per ton of feed) were obtained during a period of low feed inventory, which led to high feed moisture content and therefore low feed rates and high residence time. Although PCS continues to believe that feed rate can influence fluoride emissions, PCS has been collecting more data on fluoride in the calciner feed and looking for other information that could shed light on fluoride emissions variability. As with mercury, we expect to have more information to share with EPA in April or early May. Thanks, Casey - Final Calciner Report.pdf Casey Fernung Bradford (bio) Partner JONES DAY - One Firm Worldwide. 1420 Peachtree Street, N.E. Suite 800 Atlanta, GA 30309 Office+1.404.581.8119 cbradford@jonesday.com This e-mail (including any attachments) may contain information that is private, confidential, or protected 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00211 by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. This e-mail (including any attachments) may contain information that is private, confidential, or protected by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00212 ^ PotashCorp* Helping Nature Provide PotashCorp-Aurora March 24,2016 CERTIFIED MAIL Mr, Robert Fisher, Regional Supervisor NCDEQ - Division of Air Quality 943 Washington Square Mall Washington, North Carolina 27889 Subject: PCS Phosphate Company, Inc, Permit No. 4176T53 Facility ID: 0700071 Calciner No. 1 through No. 6 (ep 201 through 206) Compliance Tests - Particulate, Total Fluoride and Mercury Dear Robert; Enclosed are the results of performance testing of total particulate, total fluoride and mercury emissions from the phosphate rock calciners in Aurora, North Carolina. PCS Phosphate Company, Inc, (PCS) is submitting the particulate test results in accordance with Specific Limitations and Conditions 2.1.2.A.1.C and 2.c of Air Quality Permit No, 4176T53 and 40 C.f.R, Part 63 Subpart AA. which require annual testing of particulate emissions. The test results demonstrate compliance with the permitted limit for particulate emissions. On August 19, 2015, U.S. EPA issued a final rule with new MACT limits for total fluoride and mercury emissions from phosphate rock calciners under Subpart AA. 80 Fed. Reg. 50,386. The final rule allowed 180 days to conduct initial performance testing of total fluoride and mercury emissions, PCS conducted initial performance testing by the 180-day deadline for all calciners except No. 6, which had to be shut down unexpectedly due to equipment failure. By letter to North Carolina DEQ on February 10, 2016, PCS requested a 14-day force majeure extension of the testing deadline for mercury emissions at Calciner No. 6 under 40 C.F.R. 63.7(a)(4) to allow time for repairing and resuming operation of the calciner. Initial performance testing of mercury emissions was completed at Calciner No, 6 by the extended deadline. The enclosed results demonstrate compliance with the total fluoride emissions limit at all six calciners. In response to a PCS petition, U.S. EPA is reconsidering the new fluoride limit but has not stayed the effectiveness of that limit pending reconsideration. Although the enclosed test results comply with the new fluoride limit. PCS is still working with U.S. EPA to reconsider NAl-1500927533vl 1530 NC Hwy 306 South, Aurora, NC USA 27806 T (252) 322-4111 PotashCorp. | www.potashcorp.com 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00213 whether that limit is achievable over the full range of representative operating conditions. For mercury, the enclosed results demonstrate compliance with the new limit at three calciners. Mercury emissions from the other three calciners (No.l, No, 3 and No. 4) exceeded the new MACT limit at the time of testing. As DEQ is aware, we have been studying the mercury test results and numerous process variables to evaluate potential reasons for the results and to determine whether the new mercury limit is achievable during representative operating conditions. Our assessment so far indicates significant variability in the mercury content of calciner feed over time, which was not reflected in the emissions data that U.S. EPA used to set the mercury limit. PCS is continuing to evaluate the mercury results and working toward a plan for retesting mercuiy emissions. We have advised U.S. EPA's rulemaking team of the initial mercury test results and our ongoing review of potential causes. We will update North Carolina DEQ and U.S EPA once we have completed our review. As required by the recent changes to 40 C.F.R. 63.607(c), PCS will also be submitting the enclosed results of MACT performance testing of mercury, total fluoride, and total particulate emissions to U.S. EPA's Compliance and Emissions Data Reporting Interface (CEDR1) using the Electronic Reporting Tool (ERT). If there are any questions concerning this subject, please contact me at 252-322-8270 Sr. Environmental Engineer PotashCorp-Aurora (PCS Phosphate Company, Inc.) Enclosures cc: Susan Fairchild, U.S. EPA (Fairchild.Susan@epa.gov) Keith Barnett, U.S. EPA (Barnett.Keith@epa.gov) NAI-l 500927533v 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00214 Subject: Calciner No. 1 through No. 6 Plant (ep 201 through 206) Compliance Tests - Particulate, Total Fluoride and Mercury Certification by Responsible Official [15A NCAC 2Q ,0520] As the responsible official for PCS Phosphate - Aurora Division, 1, Mark Johnson, General Manager, certify that based on information and belief formed after reasonable inquiry, the statements and information in this document are true, accurate, and complete. Signature of Responsible Official Date of Certification NAl-l 500927533v 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00215 40 CFR 63 SUBPART AA PERFORMANCE TEST REPORT FOR CALCINER NOS. 1 THROUGH 6 PCS PHOSPHATE COMPANY, INC. AURORA, NC Prepared for: Phosphate 1530 NC Highway 306 South Aurora, North Carolina 27806 Prepared by: AECOM 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 (919)461-1100 March 2016 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00216 PCS CalcinerNos. 1-6 TABLE OF CONENTS 1.0 INTRODUCTION..................................................................... 2.0 SUMMARY OF RESULTS.................................................... 3.0 SOURCE DESCRIPTION...................................................... 3.1 Sampling Loc ations............................................................... 4.0 SAMPLING AND ANALYTICAL PROCEDURES.............. 4.1 EPA Methods 1, 2 and 3 A.................................................... 4.2 EPA Method 5..................................................................... 4.3 EPA Method 13B................................................................... 4.4 EPA Method 3 0B................................................................. 5.0 QUALITY ASSURANCE / QUALITY CONTROL (QA/QC), 5.1 Field Sampling QA/QC........................................................ 5.2 EPA Method 30B QA/QC.................................................... 5.3 EPA Method 5 and 13B QA/QC.......................................... 5.3.1 Audit Samples......................................................................... 5.3.2 PM Sampling QA/QC............................................. 5.4 Deviations and Corrective Action........................................ Aurora, NC Page .... .-31 .... 3-1 ..... 41 .... 4-1 ..... 4-1 ..... 4-2 ..... 4-2 .... 51 .... 5-1 .... 5-1 .... 5-2 ..... 5-2 .... 5-3 .... 5-3 APPENDICES Appendix A Detailed Summary of Emission Results Appendix A-1 Calciner No. 1 Appendix A-2 Calciner No. 2 Appendix A-3 Calciner No. 3 Appendix A-4 Calciner No. 4 Appendix A-5 Calciner No. 5 Appendix A-6 Calciner No. 6 Appendix B Process Operating Data Appendix C Equipment Calibrations Appendix D Example Calculations Appendix E Analytical Laboratory Data Appendix F Test Protocols and Related Correspondence Table 2-1 Table 2-2 Table 2-3 Table 4-1 Table 5-1 Table 5-2 Table 5-3 Table 5-4 LIST OF TABLES Page Summary of PM Test Results PCS Calciner Nos. 1-6.......................................... 2-1 Summary of FF Test Results PCS Calciner Nos. 1-6........................................... 2-2 Summary of Mercury Test Results PCS Calciner Nos. 1-6.................................. 2-2 Measurement Parameters and Reference Methods................................................ 4-1 Sampling QA/QC Requirements..............................................................................5-1 EPA Method 30B Field Sampling QA/QC............................................................. 5-1 EPA Method 30B Analysis QA.............................................................................. 5-2 Audit Sample Results............................................................................................... 5-3 ii 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00217 PCS CalcinerNos. 1-6 Aurora, NC 1.0 INTRODUCTION AECOM was contracted by PCS Phosphate Company, Inc. (PCS), located near Aurora, North Carolina to perform emissions testing on the Calciner Nos. 1-6 (EP-201-206) to demonstrate compliance with 40 CFR Part 63, Subpart AA - National Emission Standards for Hazardous Air Pollutants (NESHAP), from Phosphoric Acid Manufacturing Plants. Testing was performed for mercury (Hg) and total fluorides (F`) on all six calciners at the PCS Phosphate Company, Inc. (PCS) facility on January 26 - February 19, 2016. Testing was performed on Calciner Nos. 2, 4, 5 and 6 for filterable particulate matter (PM) between January 26 - February 9, 2016. Calciner Nos. 1 and 3 were tested during previous deployments (2015). EPA Methods 5, 13B and 30B were performed on Calciner Nos. 1 - 6 to satisfy requirements stated in 40 CFR 63 Subpart AA - National Emission Standards for Hazardous Air Pollutants (NESHAP) from Phosphoric Acid Manufacturing Plants. An AECOM test team consisting of David Marzec, Willie Lea, Francisco Cobo, Lance Burleson, Lee Marchman and Sam Wamock performed the emission testing. Brad Lee of PCS provided oversight for the sampling program. Questions regarding this test report should be directed to Pam Jestness of PCS at (252) 322-8270. 1-1 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00218 PCS CalcinerNos. 1-6 Aurora, NC 2.0 SUMMARY OF RESULTS The objective of this test program was to demonstrate compliance with 40 CFR 63 Subpart AA. An EPA Method 5 sampling train was used to sample PM. Airflow was manually measured using EPA Methods 1 and 2 in conjunction with the EPA Method 5 sampling train. EPA Method 5 was used to determine stack gas moisture. The data quality objectives of the test program were met with regard to data availability and quality assurance for sample collection, flue gas monitoring and analysis activities. The test method quality requirements are discussed in Section 5 of this report. Tables 2-1 through 2-3 summarize the results of the emission testing and compares the results to the emission limits stated in 40 CFR 63 Subpart AA. Results are based on the average of three 72 minute test runs for PM and FF and three 60 minute test runs for Hg on Calciner Nos. 1-6. The process operating parameters recorded during the test program by PCS personnel are presented in Appendix B. Table 2-1. Summary of PM Test Results PCS Calciner Nos. 1-6 Source / ID EP-201h Calciner No. 1 Average Test Result:1 (g/dsem) 0.0108 Result Pass Emission Limit (g/'clscm) EP-202 Calciner No. 2 0.0075 Pass EP - 203b Calciner No. 3 EP - 204 Calciner No. 4 0.0124 0.0065 Pass 0.181 Pass EP - 205 0.0109 Pass Calciner No. 5 EP - 206 Calciner No. 6 0.0112 Pass a Results include water wash during second run of the test program. Calculations including all Runs and the water wash can be found in Appendix A. b CalcinerNos. 1 and3 results are from test programs performed in 2015. Calciner 1 emissions testing was performed by AECOM, Calciner 3 emissions testing was performed by PCS. 2-1 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00219 PCS CalcinerNos. 1-6 Aurora, NC Table 2-2. Summary of FI' Test Results PCS Calciner Nos. 1-6 Source / II) EP-201 Calciner No. 1 Average l est Result (Ib/Ton Feed-Wet11) 0.0004 Result Pass E mission Limit (Ib/Ton Feed-Wet) EP-202 0.0005 Pass Calciner No. 2 EP - 203 Calciner No. 3 0.0004 Pass 0.0009 EP - 204 Calciner No. 4 0.0004 Pass EP - 205 Calciner No. 5 0.0003 Pass EP - 206 Calciner No. 6 0.0004 Pass Wet ton Feed is based on entering any phosphate rock dryer or phosphate rock calciner including moisture and extraneous material as well as ore materials. Table 2-3. Summary of Mercury Test Results PCS Calciner Nos. 1-6 Source / II) EP-201 Calciner No. 1 EP-202 Calciner No. 2 Average Test Result (iiig/dsciii' 3%()i) 0.149 0.144 Result Fail llg Emission Limit (mg/dscni'V/ 3%()2) Passa EP-202 Calciner No. 2 0.139 Pass EP - 203 Calciner No. 3 0.157 Fail 0.14 EP - 204 Calciner No. 4 0.146 Fail EP - 205 Calciner No. 5 0.125 Pass EP - 206 Calciner No. 6 0.140 Pass Calciner2 Fig Test series were conducted twice on 1/30/16 and again on 2/13/16. 2-2 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00220 PCS CalcinerNos. 1-6 Aurora, NC 3.0 SOURCE DESCRIPTION PCS Phosphate operates six fluidized-bed calciners in Aurora, NC. Phosphate rock is used to manufacture phosphoric acid, defluorinated feed phosphate (DFP), and fertilizer. Phosphate rock may be calcined, dried or consumed directly as wet phosphate rock. Calcined or wet phosphate rock is consumed in phosphoric acid manufacturing. Dried rock is consumed in DFP manufacturing. Calcination takes place in the mill area. Beneficiated phosphate rock is received from wet rock storage via conveyors and is calcined in fluidized-bed calciners using hot air at a velocity high enough to keep the charge in a fluidized state. In the calcining process, the wet phosphate rock is fed to the top of the preheat compartment which dries the rock using heat supplied by flue gases from the calcining bed below. Dry rock from the preheat compartment drops through internal or external down-comers into the calcining compartment. The temperature of the calcining bed is maintained below 1600F by direct injection of bituminous coal/coke fuel mixture into the bed of suspended particles. The calciners can also fire No. 6 fuel oil as backup fuel. Hot calcined rock from the calcining bed drops through an internal down-comer to a cooling compartment. The cooled calcined rock product is discharged through a level control valve and transferred via covered conveyors to storage silos or to the phosphoric acid production area. A venturi scrubber provides some particulate control before the exhaust enters the Wet Electrostatic Precipitators (WESPs). All calciners are equipped with WESPs for additional particulate control. 3.1 Sampling Locations Calciners No. 1 through 6 are identical in design and measurement. The calciner stacks are 6 feet in diameter at the opening and are approximately 100 feet above grade elevation. The sample ports are approximately 25 feet downstream and 11 feet upstream from the nearest flow disturbance. Figure 3-1 is an example diagram of a calciner stacks located at PCS Aurora, NC. 3-1 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00221 PCS CalcinerNos. 1-6 Downstream disturbance 10'10" Sample Port Leveb Upstream Disturbance 24'10" Aurora, NC Figure 3-1. Example of Calciner Stack Diagram 3-2 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00222 PCS CalcinerNos. 1-6 Aurora, NC 4.0 SAMPLING AND ANALYTICAL PROCEDURES Table 4-1 summarizes the test methods (40 CFR 60, Appendix A) used during testing. Table 4-1. Measurement Parameters and Reference Methods Piir:i meter ReI'erence Method" Air Flow EPA Methods 1 and 2 Molecular Weight (02 and C02) EPA Method 3Ab Moisture Filterable Particulate Matter EPA Method 5 Total Fluorides EPA Method 13B Vapor Phase Mercury EPA Method 30B a 40 CFR 60 Appendix A b For Calciners 1-5 oxygen and carbon dioxide were collected using integrated bag samples and analyzed by Method 3 A (CEM). ForCalciner6, three 1-hour test runs were performed to obtain oxygen and carbon dioxide. These values were used to calculate molecular weight for the PM test runs 4.1 EPA Methods 1, 2 and 3A EPA Methods 1 and 2 were used to determine stack gas velocity during the EPA Method 5 test runs in order to provide volumetric flow rates for emission rate calculations. EPA Method 1 was used to determine the location of traverse points for EPA Method 2 and for determining the suitability of sampling locations. EPA Method 3A, using integrated bag samples, was used to obtain O2/CO2 values in order to calculate molecular weight for Calciner Nos. 1-5. EPA Method 3A using a CEM system was used to determine molecular weight. Cyclonic flow checks were conducted at each stack during compliance testing. The cyclonic measurement checks were greater than the 20 degree method criterion for Calciner No. 1, demonstrating that the stack flow was cyclonic. Due to the presence of cyclonic flow, the `alignment method' from EPA Guideline Document 8 - for Particulate Sampling in Cyclonic Flow procedures, was followed. The sample probe was turned into the flow at the average angle for each of the four stack quadrants. Calciners Nos. 2-6 were determined to be not cyclonic and were sampled per EPA Method 2 specifications. EPA Method 2 was used to determine stack gas velocity with S-type pitot probes. The probe dimensions were verified to be within the design specifications of EPA Method 2, therefore a pitot tube coefficient of 0.84 was assumed. Field data sheets are presented in the Appendix A. 4.2 EPA Method 5 Emissions of filterable particulate matter were measured by EPA Method 5. Gas was withdrawn from the stack isokinetically at sampling points determined using EPA Method 1. Particulate 4-1 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00223 PCS CalcinerNos. 1-6 Aurora, NC matter was collected on a glass fiber filter maintained at 248 25F. The nozzle and probe liner were rinsed with acetone. 4.3 EPA Method 13B EPA Method 13B was used to determine the total fluoride (F) content of the flue gas. EPA Method 13B was used in conjunction with EPA Methods 1, 2 and 4. All samples were collected according to isokinetic conditions. The impinger solutions were distilled deionized (DI) H20 in a series of three impingers. A Whatman # 1 filter was placed in a 21/2-inch filter holder between the 3rd and 4th impingers per Method specifications. The glass components prior to the filter were rinsed with DI water during the sample train recovery process. The filter was recovered with the impinger contents and rinses into a single polyethylene sample container for total fluoride analysis by specific ion electrode. The fluoride analysis was conducted onsite by PCS laboratories. 4.4 EPA Method 30B EPA Method 30B was performed to determine the vapor phase of total mercury mass concentration using sorbent trap sampling. A volume of flue gas was extracted at a flow rate of 0.75 liters per minute (1pm) and collected on paired trains to determine precision and verify acceptability of measured concentrations. Emissions calculations were determined by following the procedures in EPA Method 30B Section 12.0. Analytical analysis for EPA Method 30B Hg analysis was performed by direct thermal analysis from an Ohio Lumex analyzer in the AECOM Hg Laboratory. Equipment calibration data sheets can be found in Appendix C. During 30B Hg testing, Method 3A was used for oxygen measurement. Integrated bags samples were used initially for collection followed by instalment analysis. During the test program a full Method 3A with direct analysis using the system below was implemented for enhanced quality control and process monitoring: Sample Probes The sampling probe was constructed of stainless steel, with a particulate matter filter at the probe opening. Heated Lines Heated sample lines were used to transfer the flue gas samples to the instrument trailer. These lines were heated to 250F to prevent condensation. All heat traced lines contained two Teflon tubes. One tube carries the sample and the second tube was for calibration and leak checks. Sample line temperatures were monitored with Type K thermocouples. A heated-head pump pulled the sample through the heated lines and exhausts the sample to the gas conditioning system. 4-2 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00224 PCS CalcinerNos. 1-6 Aurora, NC Gas Conditioning A condenser style gas conditioning system was used to separate the moisture from the flue gas. The conditioning system cools the gas to 34F and condenses moisture in the sample using glasschilled cyclones. Condensate was immediately removed from the sample path through a continuous drain, reducing the potential for sample bias. Additionally, the system operates under positive pressure, eliminating the possibility of a leak. After the sample is dried in the condenser, it passes through a 5-micron filter to remove any particulate matter remaining in the gas stream. Calibration The EPA reference methods require that a linearity check be performed once prior to testing at a facility. A three-point linearity test was performed at the beginning of the test day. Zero and span gases were introduced through a calibration valve at the probe to establish the calibration curve. Then, the mid-range gas was introduced as a QC check. The analyzers were calibrated with Protocol 1 calibration gases. A QC check for instrument drift was performed after each one hour test ran using zero and mid range gases. Gases were introduced through the entire sampling system for each drift check. The instrument responses were compared to the pretest calibration value. Results for calibration error and drift and bias checks can be found in Appendix A. 4-3 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00225 PCS CalcinerNos. 1-6 Aurora, NC 5.0 QUALITY ASSURANCE / QUALITY CONTROL (QA/QC) 5.1 Field Sampling QA/QC Table 5-1 summarizes the Quality Assurance and Quality Control (QA/QC) requirements for the field sampling. All of the QA/QC requirements of the test methods were met. Table 5-1. Sampling QA/QC Requirements QA/QC Para meter Upstream and Downstream EPA Method 1 Distances from Flow Disturbances Manometer Leak Check EPA Method 2 Passing Pitot Tube Inspection Manometer Leak Check Sampling System Leak Check EPA Method 5 Dry Gas Meter Calibration Factor (Yd), Initial Dry Gas Meter Calibration Factor (Yd), Final Isokinetic Sampling Impinger Condenser/Silica Gel Exit Temperature Requirement > 2 diameters dow nstream and >0.5 diameters upstream No leaks at > 3" water column Dimensions specified in EPA Method 2 No leaks at 3" water column < 4% of sampling rate (or < 0.02 efrn); > 15" Hg vacuum 0.95-1.05 Initial Yd 5% 100 % 10% < 20C (68F) Requirement Mel Or Exceptions Met Met Met Met Met Met Met Met Met 5.2 EPA Method 30B QA/QC EPA Method 3 OB data quality is measured by multiple criteria for sampler console operation. Table 5-2 contains the QA/QC requirements for EPA Method 30B field testing. Table 5-2. EPA Method 30B Field Sampling QA/QC QA/QC Psirsuneler Gas flow meter calibration (at 3 settings or points) Gas flow meter post-test calibration check (Single-point) Temperature sensor calibration Barometer calibration Pre-test leak check Post-test leak check Requirement Calibration factor (Yi) at each flow rate must be within 2% of the average value (Y) Calibration factor (Y;) must be within 5% of the Y value from the most recent 3-point calibration Absolute temperature measured by sensor within 1.5% of a reference sensor Absolute pressure measured by instrument within 10 mm Hg of reading with a mercury barometer < 4% of target sampling rate < 4% of target sampling rate Sliilus Met Met Met Met Met Met 5-1 2016 40 CFR 63 Subpart AA Emissions Test 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00226 PCS CalcinerNos. 1-6 Aurora, NC EPA Method 3 OB data quality (precision and accuracy) is measured by multiple criteria during analysis. Table 5-3 contains the laboratory QA/QC for EPA Method 30B. Detailed lab analysis and associated QA can be found in Appendix E. Table 5-3. EPA Method 30B Analysis QA QA/QC Parameter Requirement Result11 Multipoint analyzer calibration Analysis of continuing calibration verification standard (CCV) Sorbent trap section 2 breakthrough Paired sorbent trap agreement Each analyzer reading within 10% of true value and r2>0.99 Within 10% of true value <10% of Section 1 Hg mass for Hg concentrations > 1 pg/dsem; <20% of Section 1 Hg mass for Hg concentrations < 1 pg/dsem <10% Relative Deviation (RD) mass for Hg concentrations > 1 pg/dsem; <20% (RD) mass for Hg concentrations <1 pg/dsem; Met Met Met with Exceptions b Met Sample analysis Within valid calibration range Met Sample analysis Spike recovery (Field recovery test) Within bounds of Hg and HgCl2 analytical bias Met test Average recovery between 85% and 115% for Hg Met a CalcinerNos. 1 and 3 did not pass all laboratory requirements. See details in the Laboratory analytical summary sheets in the appendices. b Some sorbent tubes were noted as containing noticeable moisture, which is suspect of contributing to higher than desired breakthrough. The paired traps indicated that in those cases, precision was acceptable. 5.3 EPA Method 5 and 13B QA/QC AECOM reduced and validated all of the sampling and field measurement data collected. The collected field and laboratory data were reviewed for correctness and completeness. PCS analyzed the EPA Method 13B samples for fluoride. Enthalpy Analytical Inc. of Durham, North Carolina performed analysis for PM. Collected field samples were transported by AECOM under standard chain of custody procedures to the analytical lab. The complete analytical results are contained in Appendix E along with supporting QA/QC analytical data. All field samples were above the analytical detection limit. 5.3.1 Audit Samples Audit samples through the Source Sampling Audit Sample (SSAS) program were acquired from an Accredited Audit Sample Provider (AASP). The SSAS were analyzed in conjunction with the field samples in the laboratory. Table 5-4 summarizes the results PCS generated based on the 5-2 2016 40 CFR 63 Subpart AA Emissions Test 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00227 PCS CalcinerNos. 1-6 Aurora, NC SSAS that was sent from the AASP as well as which sources samples were analyzed with audit samples. Parameter Fluoride SSAS ID# 011216A 011216B Table 5-4. Audit Sample Results Source ID EP - 204 EP - 203 Units mg/dscm Laboratory Result 0.961 6.76 Acceptable Range 0.850- 1.15 5.95-8.05 Assigned Value Acceptable Acceptable 5.3.2 PM Sampling QA/QC Pretest multi-point flow calibrations and post-test flow calibration checks were performed on the gas sampling meter and all calibration checks met EPA Method 5 criteria. All pre- and post-test meter console calibration data are provided in Appendix C. Leak checks of each sampling system were performed before and after each test run. The results of leak checks for all runs met the acceptance criteria of EPA Method 5. All samples were collected isokinetically. All sampling system components that contacted the samples and all equipment used in sampling and recovery operations were cleaned according to the procedures described in EPA Method 5, per 40 CFR part 60 Appendix A. Samples were delivered promptly from the field to the analytical laboratory. 5.4 Deviations and Corrective Action During the second test run for each calciner, water washing was performed while PM testing was conducted per standard practice for this source. This resulted in higher PM emissions for the second run on each calciner stack. Emission limits were not exceeded as a result. The first PM test run on Calciner 2 failed the post-test leak check, therefore an additional (4th ) test run was conducted. 5-3 17cv1906 Sierra Club v. EPA - 6/22 Production 2016 40 CFR 63 Subpart AA Emissions Test ED 001523 00007569-00228 APPENDIX A DETAILED SUMMARY OF EMISSION RESULTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00229 A-l Calciner No. 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00230 PCS Phosphate Operations - Stack Test Results Test Information Location Product Source Stack ID No Start Date Pollutant Method Calciner No. 1 Single Float Calcined Rock WESP 201 5/22/2015 Particulate 5/202 Production Data Date Feed Rate, Wet, TPH (During Test) Bulk Moisture of Rock (Lab Analyses) Rock Feed Rate Dry, TPH Lbs. Coal/Ton of Dry Feed Coal Feed, TPH Process Weight Rate, TPH Loss On Ignition Production Rate During Test, TPH Product Test Parameters/Conditions Time of Start Time of Finish Stack Gas Flow Rate Calculations Stack Flow Rate, DSCFM Sample Volume (DSCF) Condensable Particulate Determination, Inorganic Fraction | Net Sample Weight, mg Condensable Particulate Determination, Organic Fraction Net Sample Weight, mg Train Blank, mg CPM, mg/DSCF Particulate Determination, Filterable Beaker Final Weight, mg Final Filter Weight, mg Net Sample Weight, mg Mg Particulate/DSCF Mg Particulate/DSCF, Averaged for Wash Cycle Procedures grams/DSCM Total Particulate Determination PM Emission Rate, Lbs./Hr - Filterable PM Emission Rate, Lbs./Hr - Condensable-Inorganic PM Emission Rate, Lbs./Hr - Condensable-Organic PM Emission Rate, Lbs./Hr -Total Condensable (corrected with train blank) PM Emission Rate, Lbs./Hr - Total Particulate Average Daily PM Emission Rate, Lbs./Hr - Filterable Average Daily PM Emission Rate, Lbs./Hr -Condensible Average Daily PM Emission Rate, Lbs./Hr - Total Particulate PM Emission Rate, Lbs./Day PM Emission Rate, grams/dscm PM Emission Rate, grains/dscf Allowable PM Rate, grain/dscf Green indicates hard entry 5/21/2015 70.0 11.29% 62.1 55.9 1.74 63.8 5.81% 58.5 5/22/2015 70.0 10.57% 62.6 55.9 1.75 64.4 5.81% 59.0 3 12:45 14:01 4 09:50 11:05 5 11:40 12:54 Average N/A N/A 35.359 50.326 39,538 52.962 38,474 49.388 37,790 50.892 Run 3 3.91 Run 4 2.58 Run 5 2.26 Average 2.917 3.67 0.1109 2.13 5.90 8.03 0.1596 0.0056 0.75 0.36 0.34 0.52 1.26 1.15 3.23 0.0327 1.63 99.31 100.94 1.9059 0.0673 9.97 0.25 0.11 0.17 10.14 1.88 0.0433 1.60 12.48 14.08 0.2851 0.0101 1.45 0.23 0.19 0.22 1.67 2.233 N/A 0.0623 1.7867 39.2300 41.0167 0.7835 0.3065 0.0277 4.05 0.28 0.22 0.30 4.36 1.542 0.360 1.902 45.640 0.0108 0.005 0.080 Calciner 1_Prod data calc_From 2015_updated 2016 17cv1906 Sierra Club v. EPA - 6/22 Production Top ED 001523 00007569-00231 Data For Avg Daily Emission Rate Calculation (inputs in red cells only) Total PM Ibs/hr Total PM Ibs/hr Run with wash (enter cell address) (Es) Ave Hrs washing per 24 Hrs (S)___________________________________ Run Time, Hours_________________________________________________ Wash Time during test in hours (A)________________________________ Run Time During test not Washing in hours (B)____________________ Total PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) Filterable PM Ibs/hr Filterable PM Ibs/hr Run with wash (enter cell address) (Esl Ave Hrs washing per 24 Hrs (S) Run Time, Hours Wash Time durinq test in hours (A) Run Time During test not Washing in hours (B) Filterable PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) Condensible PM Ibs/hr Condensible PM Ibs/hr Run with wash (enter cell address) (Es) Ave Hrs washing per 24 Hrs (S) Run Time, Hours Wash Time durinq test in hours (A) Run Time During test not Washing in hours (B) Condensible PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) PM Emission rate g/dscm Filterable PM g/dscm Run with wash (enter cell address) (Es)_____________ Ave Hrs washing per 24 Hrs (S)_________________________________________ Run Time, Hours_______________________________________________________ Wash Time during test in hours (A)______________________________________ Run Time During test not Washing in hours (B)__________________________ Filterable PM g/dscm Avg of two non-wash runs (enter cell addresses)(EN) PM Emission rate mg/dscf Filterable PM mg/dscf Run with wash (enter cell address) (Es)_____________ Ave Hrs washing per 24 Hrs (S)_________________________________________ Run Time, Hours_______________________________________________________ Wash Time during test in hours (A)______________________________________ Run Time During test not Washing in hours (B)___________________________ Filterable PM mg/dscf Avg of two non-wash runs (enter cell addresses)(EN) 'Water Wash Performed on Run 2 (R=24hrs) Eavg= EsS (A+B)/AR) + E(((R-S)/R)-(BS/AR)) 9.97 0.4167 1.20 0.42 0.78 1.10 0.17 0.4167 1.20 0.42 0.78 0.37 0.07 0.42 1.20 0.42 0.78 0.01 1.91 0.42 1.20 0.42 0.78 0.22 Calciner 1_Prod data calc_From 2015_updated 2016 17cv1906 Sierra Club v. EPA - 6/22 Production Top ED 001523 00007569-00232 AXOM Emissions Test Run Summary Facility: PCS Location: Calciner#1 Condition Normal Sample Type: Method 13B Was the run used? Run Number: Date: Total Sampling Time (min) Corrected Barometric Pressure (in Hg) Absolute Stack Pressure (in Hg) Stack Static Pressure (in H20) Average Stack Temperature (F' Stack Area (sq in) Actual Meter Volume (cu ft) Average Meter Pressure (in H20) Average Meter Temperature (F' Moisture Collected (g) Carbon Dioxide Concentration (%V) Oxygen Concentration (%V) Nitrogen Concentration (%V) Dry Gas Meter Factor (y5) Nozzle Diameter (in) Pitot Constant Average Sampling Rate (dscfm) Standard Metered Volume (dscf) Standard Metered Volume (dscm) Stack Moisture (%V) Saturated Moisture (%V) Mole Fraction Dry Stack Gas Dry Molecular Weight Wet Molecular Weight Average SORT of Delta P Stack Gas Velocity (fps) Stack Gas Velocity (mpm) Volumetric Flow Rate (acfm) Volumetric Flow Rate (acmm) Volumetric Flow Rate (dscfm) Volumetric Flow Rate (dscmm) Percent Isokinetic Post Test Meter QA (yqa) Yes 1 10-Feb-16 72.0 29.85 29.83 -0.24 146.3 4072 44.411 1.39 45.5 386.3 6.3 15.1 78.7 0.9943 0.269 0.84 0.641 46.169 1.307 28.3 23.0 0.770 29.61 26.94 0.68 35.9 11.0 60979 1727 40785 1155 96.4 1.031 Yes 2 10-Feb-16 72.0 29.79 29.77 -0.24 149.8 4072 44.465 1.29 62.6 384.5 6.3 15.1 78.7 0.9943 0.269 0.84 0.620 44.638 1.264 28.9 24.8 0.752 29.61 26.73 0.66 35.1 10.7 59610 1688 38614 1094 98.4 1.010 Yes 3 10-Feb-16 72.0 29.77 29.75 -0.24 148.1 4072 46.539 1.46 59.4 388.2 6.3 15.1 78.7 0.9943 0.269 0.84 0.653 47.001 1.331 28.0 24.2 0.758 29.61 26.80 0.69 37.1 11.3 62885 1781 41144 1165 97.2 1.023 Fluoride Emission Rate Calculations Orion 901 Meter Reading, ppm__________ Liquid Sample Volume, ml_______________ Sample Aliquot__________________________ Sample Dilution_________________________ Total Fluoride, mg_______________________ Fluoride Concentration, mg/DSCF_______ Fluoride Emissions, lbs F/hr_____________ Rock Feed (Wet TPH)___________________ Fluoride Emissions, lbs F/Ton Rock Feed 0.26 1000 10 10 0.2610 0.0057 0.0305 69.98 0.0004 0.18 1000 10 10 0.1800 0.0040 0.0206 69.98 0.0003 0.26 1000 10 10 0.2560 0.0054 0.0296 69.98 0.0004 Average 72.0 29.80 29.79 -0.24 148.1 4072 45.138 1.38 55.9 386.3 6.3 15.1 78.7 0.9943 0.269 0.84 0.638 45.936 1.301 28.4 24.0 0.760 29.61 26.82 0.68 36.1 11.0 61158 1732 40181 1138 97.3 1.021 Average N/A N/A N/A N/A 0.2323 0.0050 0.0269 70.0 0.0004 Calciner#1 M13B_Wet-Cyclonic DT_sc_3.24.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run Summary ED 001523 00007569-00233 Run Used: Correction for Cyclonic Flow: Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yy) Minutes per Point Barometric Pressure 02/C02 Method Orsat C02 Percent Replicate 1 6.3 Replicate 2 Replicate 3 Average 6.3 Yes Yes Method 13B PCS 60402248 Calciner #1 Normal N-45 0.9943 3.0 29.95 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter AN@ Pitot Constant Port Height (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (or Length) (in) Stack Width (If Rectangle) (in) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in' Nozzle ID (In) 2/10/2016 RLM/WL 1 3.20 1.7992 0.84 100 -0.24 C 72.0 0.264 0.273 0.269 0.269 Impinger 1 Impinger 2 Impinger 3 impinger 4 impinger 5 impinger 6 impinger 7 impinger 8 impinger Weights (g) initial Final 635.4 898 724.8 825.9 656.1 665.9 881.1 893.9 Moisture Collected (g) Net Gain 262.6 101.1 9.8 12.8 0 0 0 0 386.3 Saturated Percent Moisture Calculated Percent Moisture isokinetic % 22.97 28.29 96.4 Standard Volume (dscf) 46.2 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 11:10:00 11:13:00 11:16:00 11:19:00 11:22:00 11:25:00 11:28:00 11:31:00 11:34:00 11:37:00 11:40:00 11:43:00 11:46:00 11:50:00 11:53:00 11:56:00 11:59:00 12:02:00 12:05:00 12:08:00 12:11:00 12:14:00 12:17:00 12:20:00 12:23:00 12:26:00 Dry Gas Meter Reading Vm (ft3) 973.308 975.470 977.720 979.760 981.810 983.790 985.655 987.510 989.380 991.110 992.780 994.490 996.193 996.193 998.150 1000.040 1001.940 1003.730 1005.440 1006.990 1008.710 1010.410 1012.200 1014.000 1015.850 1017.719 Velocity Head (m (in H20) 0.66 0.68 0.60 0.59 0.53 0.48 0.48 0.47 0.39 0.40 0.40 0.41 0.48 0.49 0.49 0.42 0.36 0.30 0.35 0.43 0.42 0.45 0.42 0.44 Orifice Pressure Diff (AN) (in H20) 1.98 2.04 1.80 1.77 1.59 1.44 1.44 1.41 1.17 1.20 1.20 1.23 1.44 1.47 1.47 1.26 1.08 0.90 1.05 1.29 1.26 1.35 1.26 1.32 Stack Temp Ts (F) 143 147 150 145 145 150 142 149 143 147 148 147 149 138 147 149 146 149 147 142 147 148 142 151 Dry Gas Meter Temperature Tm in Tm out (F) (F) 37 36 41 37 43 37 45 37 46 37 48 39 48 39 49 40 49 41 49 41 50 42 50 42 Refer to Ceil A2 for use of calc cyclonic flow Yaw Angle (deg) 43 36 40 43 31 26 8 15 15 12 12 16 48 43 46 48 43 48 49 43 55 50 43 66 53 45 41 54 45 11 55 46 7 54 46 6 54 46 13 53 46 10 53 46 28 53 47 7 Calciner #1 M13B_Wet-Cyclonic DT_sc_3.24.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run 1 ED 001523 00007569-00234 Run Used: Correction for Cyclonic Flow: Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yy) Minutes per Point Barometric Pressure 02/C02 Method Orsat C02 Percent Replicate 1 6.3 Replicate 2 Replicate 3 Average 6.3 Yes Yes Method 13 PCS 60402248 Calciner #1 Normal N-45 0.9943 3.0 29.89 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter AW@ Pitot Constant Port Height (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (or Length) (in) Stack Width (if Rectangle) (in) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 78.7 Nozzle ID (in) 2/10/2016 RLM/WL 2 3.00 1.7992 0.84 100 -0.24 C 72.0 0.264 0.273 0.269 0.269 impinger 1 Impinger 2 impinger 3 impinger 4 impinger 5 impinger 6 impinger 7 impinger 8 impinger Weights (g) initial Final 742.9 994.6 662.6 767.4 642.4 655.4 891 906 Moisture Collected (g) Net Gain 251.7 104.8 13 15 0 0 0 0 384.5 Saturated Percent Moisture Calculated Percent Moisture isokinetic % 24.80 28.88 98.4 Standard Volume (dscf) 44.6 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 13:05:00 13:08:00 13:11:00 13:14:00 13:17:00 13:20:00 13:23:00 13:26:00 13:29:00 13:32:00 13:35:00 13:38:00 13:41:00 13:44:00 13:47:00 13:50:00 13:53:00 13:56:00 13:59:00 14:02:00 14:05:00 14:08:00 14:11:00 14:14:00 14:17:00 14:20:00 Dry Gas Meter Reading Vm (ft3) 18.589 20.680 22.570 24.350 26.040 27.540 29.210 31.010 32.790 34.680 36.470 38.300 40.081 40.081 42.010 44.100 46.560 48.590 50.260 52.040 53.880 55.720 57.590 59.400 61.210 63.054 Velocity Head (AK) (in H20) 0.57 0.46 0.42 0.35 0.27 0.36 0.42 0.42 0.45 0.40 0.42 0.47 0.51 0.51 0.47 0.44 0.42 0.39 0.45 0.45 0.44 0.42 0.39 0.45 Orifice Pressure Diff (AN) (in H20) 1.71 1.38 1.26 1.05 0.81 1.08 1.26 1.26 1.35 1.20 1.26 1.26 1.53 1.53 1.41 1.32 1.26 1.17 1.35 1.35 1.32 1.26 1.17 1.35 Stack Temp Ts (F) 150 150 142 149 144 150 149 152 152 149 153 147 149 151 151 152 146 152 156 152 149 153 147 151 Dry Gas Meter Temperature Tm in Tm out (F) (F) 54 57 55 62 55 64 55 64 56 67 56 64 65 57 65 57 66 57 66 59 65 58 69 59 >0 indicates Cyclonic Flow Yaw Angle (deg) 43 36 40 43 31 26 8 15 15 12 12 16 69 59 46 65 61 48 69 62 55 69 62 66 69 62 41 69 63 11 68 64 7 68 64 6 68 64 13 68 63 10 64 62 28 62 61 7 Calciner #1 M13B_Wet-Cyclonic DT_sc_3.24.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run 2 ED 001523 00007569-00235 Run Used: Correction for Cyclonic Flow: Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yy) Minutes per Point Barometric Pressure 02/C02 Method Orsat C02 Percent Replicate 1 6.3 Replicate 2 Replicate 3 Average 6.3 Yes Yes Method 13B PCS 60402248 Calciner #1 Normal N-45 0.9943 3.00 29.87 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter AN@ Pitot Constant Port Height (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (or Length) (in) Stack Width (If Rectangle) (in) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in' Nozzle ID (In) 2/10/2016 RLM/WL 3 3.20 1.7992 0.84 100 -0.24 C 72.0 0.264 0.273 0.269 0.269 Impinger 1 Impinger 2 Impinger 3 impinger 4 impinger 5 impinger 6 impinger 7 impinger 8 impinger Weights (g) initial Final 625 898.5 749.8 847.3 657.2 663.8 890.4 901 Moisture Collected (g) Net Gain 273.5 97.5 6.6 10.6 0 0 0 0 388.2 Saturated Percent Moisture Calculated Percent Moisture isokinetic % 24.21 28.03 97.2 Standard Volume (dscf) 47.0 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 14:40:00 14:43:00 14:46:00 14:49:00 14:52:00 14:55:00 14:58:00 15:01:00 15:04:00 15:07:00 15:10:00 15:13:00 15:16:00 15:20:00 15:23:00 15:26:00 15:29:00 15:32:00 15:35:00 15:38:00 15:41:00 15:44:00 15:47:00 15:50:00 15:53:00 15:56:00 Dry Gas Meter Reading Vm (ft3) 63.305 65.610 67.920 70.110 72.230 74.400 76.380 78.240 80.220 82.100 84.970 85.810 87.661 87.661 89.650 91.680 93.530 95.260 96.920 98.590 100.114 102.350 104.270 106.100 107.970 109.844 Velocity Head (AF) (in H20) 0.70 0.68 0.65 0.57 0.57 0.52 0.45 0.45 0.48 0.42 0.42 0.46 0.55 0.52 0.45 0.39 0.32 0.35 0.45 0.46 0.48 0.42 0.44 0.44 Orifice Pressure Diff (AN) (in H20) 2.10 2.04 1.95 1.71 1.71 1.56 1.35 1.50 1.35 1.44 1.26 1.26 1.69 1.56 1.35 1.17 0.96 1.05 1.35 1.38 1.44 1.26 1.32 1.32 Stack Temp Ts (F) 148 150 150 148 149 148 149 148 147 144 150 152 147 150 143 149 147 145 144 149 150 150 150 148 Dry Gas Meter Temperature Tm in Tm out (F) (F) 50 52 63 59 66 59 66 60 67 60 65 59 65 60 62 60 63 59 63 58 63 58 62 57 >0 indicates Cyclonic Flow Yaw Angle (deg) 43 36 40 43 31 26 8 15 15 12 12 16 63 58 46 63 58 48 62 58 55 62 58 66 62 58 41 62 59 11 58 56 7 58 55 6 56 54 13 56 54 10 59 55 28 56 55 7 Calciner #1 M13B_Wet-Cyclonic DT_sc_3.24.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run 3 ED 001523 00007569-00236 AECONi PCS Phosphate Calciner #1 Mercury Emission Calculations EPA Method 30B Emission Results 02 Correction Basis Run AVERAGE Pollutant: Mercury Total Hg Catch Sample Volume Hg Concentration mg/dscm 0.0488 0.0500 0.0470 0.0486 Hg Concentration ppmV____ 0.0059 0.0060 0.0056 0.0058 Oxygen % 15.05 15.05 15.05 15.05 Hg Concentration mg/dscm @ 3% 0.149 0.153 0.144 0.149 Flow Rate dscfm 46.173 45.200 47.081 46,151 Calciner _1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Mercury ED 001523 00007569-00237 Method 2 Veloci ty Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure i PCS 60402248.1 Calciner#1 Normal -0.24 100 30.23 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 6.27 6.27 02 Percent 15.05 15.05 N2 Percent 78.7 | Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 24.52 24.52 0.755 29.61 26.76 2/11/2016 CB/DM 0.84 C 72.0 4071.5 30.13 30.11 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head <AR) (in H20) 0.50 0.56 0.54 0.52 0.40 0.40 0.38 0.44 0.43 0.43 0.45 0.46 0.48 0.41 0.50 0.46 0.40 0.36 0.35 0.38 0.45 0.47 0.42 0.37 Stack Temp Ts (F) 148 149 151 154 148 148 148 147 146 144 151 153 146 151 153 154 149 147 149 144 147 151 152 149 Square Root of A/P SQRT(AR) 0.707 0.748 0.735 0.721 0.632 0.632 0.616 0.663 0.656 0.656 0.671 0.678 0.693 0.640 0.707 0.678 0.632 0.600 0.592 0.616 0.671 0.686 0.648 0.608 Average Stack Average SUK1 Temp AP 149.13 0.66 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) Stack Gas Velocity (fps) 44.1 46.7 46.0 45.2 39.5 39.5 38.5 41.3 40.8 40.8 41.9 42.5 43.1 40.0 44.3 42.5 39.5 37.4 36.9 38.3 41.8 42.9 40.6 38.0 Average Velocity 41.34 70125 61177 46173 Calciner_1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R1 ED 001523 00007569-00238 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 2 PCS 60402248.1 Calciner #1 Normal -0.24 100 30.21 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 6.27 6.27 02 Percent 15.05 15.05 N2 Percent 78.7 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 23.94 23.94 0.761 29.61 26.83 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (A8) (in H20) 0.46 0.48 0.49 0.50 0.47 0.44 0.42 0.41 0.43 0.40 0.39 0.39 0.30 0.38 0.44 0.40 0.36 0.31 0.35 0.41 0.44 0.46 0.46 0.40 Stack Temp Ts (F) 147 148 150 153 149 148 149 146 145 143 149 151 147 150 154 154 148 146 150 146 147 150 152 147 Square Root of AP SQRT(AB) 0.678 0.693 0.700 0.707 0.686 0.663 0.648 0.640 0.656 0.632 0.624 0.624 0.548 0.616 0.663 0.632 0.600 0.557 0.592 0.640 0.663 0.678 0.678 0.632 Average Stack Average SQRT Temp AP 148.71 0.64 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) Calciner_1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2/11/2016 CB/DM 0.84 C 72.0 4071.5 30.11 30.09 Stack Gas Velocity (fps) 42.2 43.2 43.7 44.2 42.8 41.3 40.4 39.8 40.8 39.3 39.0 39.0 34.1 38.5 41.5 39.6 37.4 34.6 36.9 39.8 41.3 R2 ED 001523 00007569-00239 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 3 PCS 60402248.1 Calciner #1 Normal -0.24 100 30.16 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 6.27 6.27 02 Percent 15.05 15.05 N2 Percent 78.7 | Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 23.98 23.98 0.760 29.61 26.82 2/11/2016 CB/DM 0.84 C 72.0 4071.5 30.06 30.04 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (A8) (in H20) 0.52 0.51 0.49 0.45 0.45 0.37 0.42 0.50 0.50 0.49 0.51 0.51 0.35 0.44 0.43 0.36 0.33 0.36 0.43 0.51 0.53 0.52 0.50 0.40 Stack Temp Ts (F) 145 147 147 151 150 152 150 147 146 143 148 150 147 151 154 154 149 146 148 147 148 152 150 149 Square Root of M> SQRT(AR) 0.721 0.714 0.700 0.671 0.671 0.608 0.648 0.707 0.707 0.700 0.714 0.714 0.592 0.663 0.656 0.600 0.574 0.600 0.656 0.714 0.728 0.721 0.707 0.632 Average Stack Average SORT Temp AP 148.79 0.67 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) Stack Gas Velocity (fps) 44.9 44.5 43.6 41.9 41.9 38.1 40.5 44.1 44.0 43.5 44.5 44.6 36.9 41.5 41.1 37.6 35.9 37.4 40.9 44.5 45.4 45.1 44.2 39.5 Average Velocity 41.92 71117 61932 47081 Calciner_1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R3 ED 001523 00007569-00240 ACCOM Date 2/11/2016 Plant PCS Phosphate Location Calciner#1 Sample Type 30 B Run Number/Side (A/B) Operator DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL304567 30.13 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002547 1.0180 1.0180 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) 10:25:00 10:30 10:35 10:40 10:45 10:50 10:55 11:00 11:05 11:10 11:15 11:20 11:25 Digital Gas Meter Reading (L) 0.000 4.56 9.01 12.95 16.74 20.52 25.03 30.12 35.16 40.11 43.76 47.77 52.628 52.628 Mechanical Gas Meter Reading <m3) 52.6280 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) 152 152 146 152 152 147 152 150 153 152 152 145 146 151 Trap Temp, (deg. F) 245 268 250 272 257 240 272 243 268 239 267 237 265 256 Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 33 33 228 35 35 235 36 36 240 34 33 237 34 34 237 34 34 236 34 34 236 34 34 235 34 34 235 34 34 236 34 34 235 34 34 235 34 34 236 34 34 235 Pump Vacuum r Hg) 2 3 3 3 3 3 3 3 3 3 3 3 3 3 Target Volume Spike Amount (ng) Comments: 2000 Stack Temp for Run 1A and IB is an average of Runs 2 and 3. Barometric Pressure corrected for elevation Total Volume (L) Mechanical Totalizer 57647.1734 57.6471734 Calciner_1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 1A ED 001523 00007569-00241 AECONl Date 2/11/2016 Plant PCS Phosphate Location Calciner#1 Sample Type 30 B Run Number/Side (A/B) Operator DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 18 Final Leak Check (L/min @ "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL321213 30.13 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002511 1.0280 1.0280 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 10:25:00 0.000 5 10:30 4.89 10 10:35 9.03 15 10:40 13.50 20 10:45 17.68 25 10:50 21.81 30 10:55 25.73 35 11:00 29.62 40 11:05 33.95 45 11:10 38.34 50 11:15 42.89 55 11:20 47.27 60 11:25 51.969 51.969 51.969 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 152 245 33 152 268 35 146 250 36 152 272 34 152 257 34 147 240 34 152 272 34 150 243 34 153 268 34 152 239 34 152 267 34 145 237 34 146 265 34 151 256 34 33 228 33 235 33 240 33 237 33 237 34 236 34 236 34 235 34 235 34 236 34 235 34 235 34 236 34 235 Pump Vacuum <" Hg) 3 4 4 4 4 4 4 4 4 4 4 4 4 4 Target Volume Spike Amount (ng) Comments: Stack Temp for Run 1A and 1B is an average of Runs Sind 3. Mechanical Totalizer Total Volume (L) 57484.51192 57.4845119 Calciner_1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production IB ED 001523 00007569-00242 AECONl Date 2/11/2016 Plant PCS Phosphate Location Calciner#1 Sample Type 30 B Run Number/Side (A/B) 2 | A Operator LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 8 Final Leak Check (L/min @ "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL306813 30.11 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002547 1.0180 1.0180 72 Page 1 of Run No. 2 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (U) Mechanical Gas Meter Reading (m3) 12:00:00 12:05 12:10 12:15 12:20 12:25 12:30 12:35 12:40 12:45 12:50 12:55 13:00 0.000 6.73 10.87 14.38 17.92 22.10 25.85 29.82 33.52 36.83 40.21 44.05 48.298 48.2980 48.2980 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 156 267 34 34 151 258 35 34 145 269 34 34 153 257 35 34 153 256 35 34 145 271 34 35 152 283 35 35 154 280 35 35 150 274 35 35 158 268 36 35 143 272 35 35 150 271 36 36 153 249 36 38 151 267.31 35.00 34.92 Pump Vacuum <" Hg) -6 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3.23 Target Volume Spike Amount (ng) 2000 Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (!_] 52778.6658 52.7786658 Calciner_1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2A ED 001523 00007569-00243 AZCOM Date 2/11/2016 Plant PCS Phosphate Location Calciner #1 Sample Type 30 B Run Number/Side (A/B) Operator LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 Final Leak Check (L/min @ "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" l-feO) Barometric Pres. (" Hg) OL321115 30.11 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002511 1.0280 1.0280 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point A1 TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 12:00:00 12:05 12:10 12:15 12:20 12:25 12:30 12:35 12:40 12:45 12:50 12:55 13:00 0.000 6.830 11.230 14.890 18.880 23.550 27.200 30.890 34.000 37.650 40.850 44.360 48.0070 48.0070 48.0070 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 156 267 35 151 258 35 145 269 34 153 257 35 153 256 35 145 271 34 152 283 35 154 280 36 150 274 35 158 268 36 143 272 36 150 271 36 153 249 36 151 267.31 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35.00 Pump Vacuum (' Hg) -6 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3.23 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 52951.29772 52.9512977 Calciner _1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2B ED 001523 00007569-00244 AECONl Date 2/11/2016 Plant PCS Phosphate Location Calciner #1 Sample Type 30 B Run Number/Side (A/B) Operator DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL304582 30.06 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002547 1.0180 1.0180 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 13:35:00 0.000 5 13:40 4.280 10 13:45 8.310 15 13:50 12.760 20 13:55 16.880 25 14:00 20.750 30 14:05 24.780 35 14:10 28.950 40 14:15 33.180 45 14:20 37.640 50 14:25 42.250 55 14:30 46.800 60 14:35 51.3130 51.3130 51.3130 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 154 259 40 151 244 39 151 267 39 144 243 39 151 269 40 153 251 37 162 265 37 150 260 36 146 241 36 152 269 38 153 243 38 151 270 37 33 241 33 242 33 243 33 254 33 244 33 243 33 242 33 243 33 243 33 245 33 245 33 242 152 257 38 33 244 Pump Vacuum <" Hg) 3 3 2 3 3 3 3 3 3 3 3 3 3 Target Volume Spike Amount (ng) 2000 Comments: Mechanical Totalizer Total Volume (L) 55642.80284 55.6428028 Calciner _1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3A ED 001523 00007569-00245 AECONl Date 2/11/2016 Plant PCS Phosphate Location Calciner #1 Sample Type 30 B Run Number/Side (A/B) Operator DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 19 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H,0) Barometric Pres. (" Hg) OL321152 30.06 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002511 1.028 1.028 Page 1 of_____ 1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 13:35:00 0.000 5 13:40 4.590 10 13:45 8.550 15 13:50 13.840 20 13:55 17.510 25 14:00 22.860 30 14:05 26.420 35 14:10 30.850 40 14:15 36.360 45 14:20 40.680 50 14:25 44.970 55 14:30 49.350 60 14:35 53.6120 53.6120 53.6120 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 154 259 40 151 244 41 151 267 40 144 243 40 151 269 40 153 251 38 162 265 38 150 260 37 146 241 37 152 269 39 153 243 39 151 270 38 33 241 33 242 33 243 33 254 33 244 33 243 33 242 33 243 33 243 33 245 33 245 33 242 152 256.75 38.92 33.00 243.92 Pump Vacuum <" Hg) 4 4 4 3 3 3 3 3 3 3 3 3 3.25 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 58598.93715 58.5989372 Calciner _1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3B ED 001523 00007569-00246 AZCOM FIELD SAMPLING DATA SHEET Flow and Moisture ____EPA Methods 2 & 4 PAGE OF 17r\/i qdr Rifirra Club v. EPA - 6/22 Production ED 001523_00007569-00247 AECOM FIELD SAMPLING DATA SHEET Sample and Velocity Traverse for Stationary Sources EPA Method 1 Client/ Plant: 'VCIb Project#: yAiOZZ^AO Location: Number of Traverse Points Chosen: IA Number of Ports: 2- 1 Date: Z,- to- (4 Number of Points per Port: | z. Duct Diameters From Downstream Flow Disturbance (A/D) 0. 1.0 1.5 2.0 T"' A -JB 1! r Disturbance Mssur*m*nt Mta Disturbance VU ^2----, D ; _____ ; r( N / N loV A \ ST -"D W 2tV 8 or 9. Stack Diameter = 0.30 to 0.81 m (12 -24 In.) 234 S6? 8 9 10 Duct Diameters From Upstream Flow Disturbance (B/D) 4 6 8 10 12\ 14 16 18 20 22 24 1 6.7 4.4 3.2 2.6 2rP 1.6 1.6 1.4 1.3 1.1 1.1 2 25.0 14.6 10.5 8.2 6.7 5.7 4.9 4.4 3.9 3.5 3.2 Deq = 2LW / (L+W) Dnstream Diameters (A/D) Upstream Diameters (B/D) 3 75.0 29.6 19.4 14.6 11.8 9.9 8.5 7.5 6.7 6.0 5.5 4 93.3 70.4 32.3 22.6 17.7 14.6 12.5 10.9 9.7 8.7 7.9 S 85.4 67.7 34.2 25.0 20.1 16.9 14.6 12.9 11.6 10.5 6 95.6 80.6 65.8 35.6 26.9 22.0 18.8 16.5 14.6 13.2 7 89.5 77.4 64.4 36.6 28.3 23.6 20.4 18.0 16.1 8 96.8 85.4 75.0 63.4 37.5 29.6 25.0 21.8 19.4 Cross-Sectional Layout of Rectangular Stacks 9 91.8 82.3 73.1 62.5 38.2 30.6 26.2 23.0 Traverse Points Matrix 10 97.4 88.2 79.9 71.7 61.8 38.8 31.5 27.2 11 93.3 85.4 78.0 70.4 61.2 39.3 32.3 9 3x3 12 13 [97.9) 90.1 83.1 76.4 69.4 60.7 39.8 \J 94.3 87.5 81.2 75.0 68.5 60.2 12 4x3 14 15 98.2 91.5 85.4 79.6 73.8 67.7 95.1 89.1 83.5 78.2 72.8 16 4x4 16 17 98.4 92.5 87.1 82.0 77.0 95.6 90.3 85.4 80.6 20 5x4 18 19 98.6 93.3 88.4 83.9 96.1 91.3 86.8 25 5x5 20 21 98.7 94.0 89.5 96.5 92.1 22 98.9 94.5 23 96.8 24 98.9 Traverse Point Fraction Distance of From Diameter Wall. Nipple Length Point Location LOCATION OF TRAVERSE POINT N RECTANGULAR STACKS. 1 la i-sr i > 4-5 2 G/V. ___ 1____ 3 cl.'* i'hS 4 iLA \AA 2 3 4 5 6 7 8 9 10 11 12 1 25.0 16.7 12.5 10.0 8.3 7.1 6.3 5.6 5.0 4.5 4.2 2 75.0 50.0 37.5 30.0 25.0 21.4 18.8 16.7 15.0 13.6 12.5 3 83.3 62.5 50.0 41.7 35.7 31.3 27.8 25.0 22.7 20.8 5 "LClO 6 . 'bSA, 7 LA .4 dti,* 8 t~AtO Vh i-d Av.K* 514 4 87.5 70.0 58.3 50.0 43.8 38.9 35.0 31.8 29.2 5 90.0 75.0 64.3 56.3 50.0 45.0 40.9 37.5 6 91.7 78.6 68.8 61.1 55.0 50.0 45.8 7 92.9 81.3 72.2 65.0 59.1 54.2 9 Qt.'b. 8 10 m> . 9 11 **h> -Al'~L 10 12 A> t A^CL. 11 93.8 83.3 75.0 68.2 62.5 94.4 85.0 77.3 70.8 95.0 86.4 79.2 95.5 87.5 12 95.8 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00248 Test Run 1 STRATA Version 3.2.112 02 C02 % % Begin calculating run averages 02-12-2016 12:44:02 -0.089 02-12-2016 12:45:01 -0.098 02-12-2016 12:46:01 -0.101 -0. 223 -0. 223 -0. 222 Pause End Pause 02-12-2016 12:48:01 02-12-2016 12:49:01 02-12-2016 12:50:01 Pause 19.335* 19.364* 19.370* 20. 481 20. 470 20. 475 End Pause 02-12-2016 12:52:02 02-12-2016 12:53:02 02-12-2016 12:54:02 10.108 10.083 10.074 9. 862 9. 858 9. 849 Pause End Pause 02-12-2016 12:57:01 11.601 6. 256 02-12-2016 12:58:01 02-12-2016 12:59:01 02-12-2016 13:00:01 13.823 15.687 17.115 6. 286 6. 276 6. 275 Pause End Pause 02-12-2016 13:03:01 02-12-2016 13:04:01 02-12-2016 13:05:01 02-12-2016 13:06:01 15.084 15.036 15.043 15.047 0. 767 0. 666 0. 471 0. 393 02-12-2016 13:07:01 Run Averages 15.048 02 % 0. 388 C02 % 02-12-2016 13:07:12 12.340* 6. 866 Operator: David Marzec Plant Name: Location: Test Run 1 End PCS Aurora Calciner #1 Page 1 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00249 TTR<* wFmEmISp FIELD SAMPLING DATA SHEET Flow and Moisture . ' EPA Methods 2 & 4 PAGE \ OF 1 <X:(M jj Plant Name /f v r *. - 1! if Project Number 42 - 5 O 3 . fi "location (Source) ! ^ f 1 Meter ID & Cal Factors 55554 3 *s jr Id 7k* jj Sornent Trap IDs 2)6i-SZ|g.\T> ' It Date / y - ,, Condition ZOoff^A&.A Run 5. | Page Initial Leak Rate Operate. _ Bar. Press, (in. H2O.) ftinal Leak Rate, Elevation (relative to Barometer) (ft) (OO Third Bed Spike Level ------------------------------------ | of f 1) 3 (0) TO "Hg 2) @ "1 D @ "Hg 2) @ "Hg 1) Z^oo CM 2) 0 k U :rap Clock Time j Volume (l, dry) Flow Rate (Lorn) AP' (in. HiO) Sorbent Temperature (F) Chiller Heat-Traced Line Meter Vacuum (in. Hg) Tt> iL :^<T ?) /1 / \X i--' - J >> 34 T.j 3 57 iTftO" H5 7M> 33 3t/c te>D 5 3*- 3 0 i L/ ,w *54 TOT |* C -3 2. lrL 3 5, D>T *3 4 [i 2< H*/ 7.^4 .-33 3< 1 o- < X 55 25- 33-- 5 f 1 %>.<' ?D 3tV " tv - o; 35 ,>C 5 -v Z4o 3; 53/ 37 -| I X 23 ,03 1S^ 135 7^7 3u Z2D 237" >3o 7r""' 3 4 l M. V X(37 v'_ .37 .3.c IS?> ?5|5> X 7 37 37 5 3 tj 53to 35, % 53 454 3 ! l'y 5 5 . 3; .45' 33 3 75 \ lo V 43 It 333 3f JH 5/ 23 5 ./ 757*v5 ! 52 2; 44. ? 35 33' 3/ 7v>5 47.5%-! 5. 74333 \|diiZ) ^7 5 53 '53 25 14 35 3 4 5 ' '75 TC 7,-5 TXmi la l 3f ' 055 /te, / 54 3f 53b 17cv1906 Sierra Club v. EPA - 6/22 Production AICOM 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00252 AZCQM ' Plant Name ` `' Project Number ' /*/ t\ .! Location (Source) 7- ,, ,, ; - Meter ID & Cal Factors ' i) Sorbent Trap IDs " '/' ' 2) - . S ' T Date ^ Condition , ,. . Run '.v- ` (Operator Bar. Press, (in, H20) Elevation (relative to Barometer) (ft) Trap 1) 1) 2) 1) 2) 1) i 2) 1) 2) 2) 2) 2) Clock Time Volume (L, dry) s _ ,-i f* v 7S , ,,^ S' ' , > 1 1 Row Rate j AP j I (LPm) \ | " (in. H ,0) 'Tti- _ ,!' ' i 'j> " Y. , Hq) Ho7) 3 {$) J * jS'.. J,, ' " / 3 , , , / ^, cj | j a </\&f lf, 3 " Z. Ld * ^ j -* ' J * 5| ! fl *J s . ,T / <' / / i / .. / U?1 Sorbent Z-. '5 s l " ^' / /* .* i' 2 li S 71.&/ jit / s? /c' \ Cym Page Initial Leak Rate final Leak Rate Third Bed Spike Level Tempers ture (F) Chiller Heat-Traced Line , V .... . -3 "'i J , t, 7 7 / S T .( .n ..j' ..A. / / > J- 2 u ij - . ITT ^ j "' y ' of 1) < @ , "Hg 2) _ . ) . -? "Hg 1) .. _ { , > @ . "Hg 2; W.. 2T>Cu_ i>--e| .. , 2) Meter T 'V '`"I -r * "'< ""7 C / y / ^ Vacuum (in. Hg) J9 > >7 ' ' .1 v '2 y - -J`3 1) 2 '.'.i 2) |H \!j ' u` - 1 J . ' --* . 1) < v 3 *S 2) Die /* J > a, ,uiL* Zli ( 53 2-/3 ? J.s S 3^ 2 3 h'- '? i -? S 1) ' / O -;_Y - -s 2) '- . v 1 \ ?' 1) 2) !.. / . K `"T '/ 3 .r , r-:; j, ` i 7 /|/ ^ / :t . , ,* .... j -A 3 J i '2\ 2) ^ , ? Li(t, Sh . ' 5j 2) Vf. 52 S, j *3 / s , ! : t) iSSs 5 / 5 / J f i 2) S t Y ` /; S -SJ >' 3 22 2j 1) 2) 1) 2) Comments: i___________ .............................. ....... 17cv1906 Sierra Club v. EPA - 6/22 Production ............... ................. SOS-35: Mercury by Sorbent Trap - Method 30B ED 001523 00007569-00253 AECOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE OF Client/Plant: 'S'cs Project#: UaHoZZM-ffl0 Date: Location: f Condition: l Run #: Operator{s): &l(Y) % -- Duration (min): If. DGM#: CF (Yd): 0.W13 AH@: I Cp: 0.84 K-Factor: ^<0 PbarC'Hg): 24 Height w.r.t. Barometer (ft): Initial Leak S (<0.02 ft3/min; >10"Hg) C it '0 ft3/min: O.0 Vac. (Hg): Source Height (ft): static ("H20): *L Duct Diameter ("): n Final Leak (<0.02 ft3/min; >max vacuurrffiyft3/min: 0 <> Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak (>3"H20) +P ("H20): - P ("H20}: Nozzle D1(")0: Q.Zl&H Probe & Pitot ID: t Nozzle D2 (") 0: Q, Z^3 SPamoinptle Time Clock (Rmuinn) VDo(lGfut3mM) e AP AH C'HzO) ("HzO) Source At me? $ 4T3.20S U /4f z i\t^ 3 Z.6^ 3 m 6 4 A>Z, * if iSo 4 \H 4 4... "ft t>fc l.Tl i*K 5 M1Z It I 145 (o \ t 25 15 Ti TI -*jp t -vy ISA 1 u'in 4 u 31 *2. J * i,Zi mi ,SI . 4> t.HI 14^ 4 1*34 ...to \\T7- ?T .44 K13 143 1-? ii ItHO 0 f. '? |2~ UH3 33 <? M 1 U45 3A If I 3? L3 14 U Sft 3#, U 53 34 H 54 12 US4 4$ .1# 1.44 .*?<? {,14 n % n.aia tMT t44 ,MZ 1 M M 5 H0Z HS ,%L I4t 15 15 6 its <; 51 _5*4H 1 iZOf $4 i.4f * 3 6 4 * 4 5 1,65 1. 4> >* %f ti ST 9.ZI 14^ 2* it 1H 1(3*4 I _.*-H--f-Z---- \Hb m2 r% . I* ai> <3 a. to .4 f \ 13 JF m M 1*21.0 14.00 .H'i U Tt ts z tzzl if-S I.T2- is i a i ri Tt I>,7f4 ' 2P4r8ob2e5 H A Nozzle D3 H 0: p, 2<o? Average Nozzle D ("): - zjJ\ Temperature ("F) 24R8lte2rS Impinger SE6x8it DGM Inlet ODuGtlMet PVuamc.p ("Hg) hM \ 3* 3Jb, 41 3^ 3 f4.. *4$. M l Hf H% 31- 1 J3- 3 Jf 3 3 Mi H-4 41 ,^ 5 c ' < SV, fz \ .5/5 4 2_ X `fS - 5* ' \ 4.3 s H4 Nv43 4_____ V S'? 4 ' A 55 # 4 V/- * < W~ 6 53 M4 <L 52 6^ I t COMMENTS J \V ' / .s' s' 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00254 AECOM Client/Plant: jfcS Location: tterX**' Impinger# 1 2 3 4 Impinger Contents Dl H20 Dl H20 Empty Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 13A/B Project#: LbUoU^lf,/o Condition: Norm*,I Date: 2-2.~lio Run #: | FYi-- Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD G3ZY o 100 GS w.r % IS-9 -- MOD 6SL>.i -- MOD VW. t ? Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dl H20 Rinse) COMMENTS: V f______________________________________________________ ' . K.i J . r 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00255 AECOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE f OF - I Client/Plant: Project #; '2-2-H^VO Date: Operators); Vlc-Wv Jw i Location:^-^ Condition: tOoC-rCtA-i- Run #: *2. Duration (min): "^-Z. DGM#: h) - H5 CF (Yd): fit,^**? AH: Cp: 0.84 K-Factor: ,<> PbarC'Hg): 3AvZi Height w.r.t. Barometer (ft): Pstatic ("H?.0):-,, Initial Leak s (<0.02 ff/min; >10"Hg) 0. OOjf fr/min: 0-0^ Vac. ("B Source Height (ft): /GO Duct Diameter ("): Final Leak S (<0.02 ft3/min;>max vacuum) ft3/min: ff.oog- Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak (>3"H20) +P ("H2o]T " Nozzle D1 (") 0: ^ t 20? COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00256 AECOM Client/Plant: Location: Impinger# 1 2 3 4 Impinger Contents DI H20 DI H20 Empty Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) Project#: 60Y0/o Condition: Method 4 Moisture Determination Approximate Volume (ml) Configuration" Initial (g) METHOD 13A/B Final (g) Gain (g) 100 MOD IUZ'7 7f4M 100 GS loh2.b !(<>? - MOD W7. </ teSS.1/ - MOD trf/. o , ?O(0. o J ' Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (DI H20 Rinse) COMMENTS: 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00257 AECONi I FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE 7 OF / Client/Plant: Location: Project #: 4o*t> -til Condition: ^ 6 Date: XRun #: ^3 4 Operators): 2tk/iAj L. ~~ Duration (min): 'r? 2. DGM#: fO - H% K-Factor: J ,Q ' CF (Yd): PbarC'Hg): te.%- AH@: i Height w.r.t. Barometer (ft): Cp: 0.84 .. ' PstaticC`H20): ^.2iH Initial Leak V (<0.02 ft /min; >10"Hg) ft /min: Q,o Vac. ("Hg): 15H Source Height (ft): c? Duct Diameter ("): 'Sfr-gy- Final Leak S (<0.02 ff/min; >max vacuum) Pitot Leak (>3"HzO) +P ("H20): ft3/min: 0`VOD Vac. ("Hg): jg P ("H20); Duct Width ("): Duct Length ('*): Nozzle D1 (*) 0: p, y i^tj Probe & Pitot ID: <% ^ \ Nozzle P2QS: Time Sample Point Clock Run (min) DGM Volume (ft3) AP ("H20) AH Source \ gup $ &1 0 M ? 3 oe>*.?55 Ck3t 7^45, i j o* l r 2^ ISO _____2_ Hi 4 o n,*r* ILJbS ms VSQ H Q_____ n 1m3= v 5 52 il_____ o "izn*, Q`J.3z h S *5 0 (? 5X li*. -n S9 _i____ JLJizlS Q-H5.. 43 S (M5 9 _____1_ 40 II Of - M 03 t& 2J_____ V\ XT So o ^,54.. 0 xz @#*4 5 Qit.iQ VHf OFM > <T*f- -d-HZ i>5 \,35 IHf IHM iS 6 \a a 33 m ^5*2 it> 34 k i iszo 3k 2. *3 ? *t2 30 H5 o9^,Ul Qm H4 & f'T' f 4| ?* .45 <?* $2 O^i, tf#v'T4^5_ i .3f 1,47 t*f L 15 0.. h?5 un> 3* Hf 4 34 si 6 *iz 6 35 l,feT 3*f SH' 6,Hf 1,35 HZ 5T t. Oti tl'A & ,m 1,^8 IMA 5 H5 40 102,35 6 MS 15-0 11> m 45 1 OM.lT 6*Mi_ l ,Z4 \ 5 b m 106, \ O />3M (.32 (5P IX si (5 tjwrr 105^ ,l - - a, ms m/rHH '4------------- / r t>l7 'iP \ " Probe 24825 Nozzle D3 C`) Q: Q . 2. to j Average Nozzle D ("}: Q ,, X Vf Temperature ('F) Filter 24825 impinger Exit S68 DGM Inlet DGM Outlet Pump Vac. ("Hg) ~W-- aas.i$ 55 ... 3 5V 3 M1 Ml .. 44 GO -P*3.---------- - 4T- 60 *S HM H5 45 5T 65 60 +M1 4T- 40 4 43 T 4 ^ -- .....45 ^..... 6^5 .... SSr* M*X 4a . . S?T*r 'i ' ' kH. - HZ... 4f ' 5^2^ ` v H*) _ 45 Sr # HH- 62 59- t* : 42 6 4L H i> n S'l M5 H5 J? ss HM s% Si 4 54 SM 4 _yj_ -- s? H4 5-4 ff Jb /, ; ' /'* ' , / COMMENTS ,4 J'>;vx - -V __ ,i ,,, 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00258 AECOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 13A/B Client/Plant: ft5 Location: Li # i Impinger# Impinger Contents Project #: /O Condition: Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 1 2 3 . 4 Dl H20 100 Di HzO 100 Empty - Silica Gel -- MOD GS MOD MOD 1 bZS.D (pSl, z mo.1/ u3. r ?0f.O ~ \ , ' Sum ; . H Recovery Container Weights Filter (no weights) PNR & Impinger-Catch (D! H20 Rinse) Tare (g) ? . < Final (g) 8: Gain(g) COMMENTS: , > '4 4-A 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00259 A-2 Calciner No. 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00260 PCS Phosphate Operations - Stack Test Results Test Information Location Product Source Stack ID No Start Date Pollutant Method Calciner No. 2 Single Float Calcined Rock WESP 202 2/1/2016 Particulate 5/202 Production Data Green indicates hard entry Production Rate During Test, TPH Product Test Parameters/Conditions Stack Gas Flow Rate Calculations Condensable Particulate Determination, Inorganic Fraction Condensable Particulate Determination. Organic Fraction Net Sample Weight, mg Train Blank, mg CPM, mg/DSCF Particulate Determination, Filterable Beaker Final Weight, mg____________________________________ Final Filter Weight, mg______________________________________ Net Sample Weight, mg_____________________________________ Mg Particulate/DSCF________________________________________ Mg Particulate/DSCF, Averaged for Wash Cycle Procedures grams/DSCM Total Particulate Determination PM Emission Rate, Lbs./FIr - Filterable PM Emission Rate, Lbs./FIr - Condensable-Inorganic PM Emission Rate, Lbs./FIr - Condensable-Organic PM Emission Rate, Lbs./Hr -Total Condensable (corrected with train blank) PM Emission Rate, Lbs./Hr - Total Particulate Average Daily PM Emission Rate, Lbs./Hr - Filterable Average Daily PM Emission Rate, Lbs./Hr -Condensible Average Daily PM Emission Rate, Lbs./Hr - Total Particulate PM Emission Rate, Lbs./Day PM Emission Rate, grams/dscm PM Emission Rate, grains/dscf Allowable PM Rate, grain/dscf 3.87 0.2437 1.06 4.40 5.46 0.1599 0.83 0.99 0.59 1.27 2.11 | 2.60 I 2.20 0.0544 3.07 42.15 45.22 1.1172 5.81 0.26 0.28 0.28 6.09 1.94 0.1790 2.29 4.55 6.84 0.1696 0.90 0.95 0.25 0.95 1.84 N/A N/A 0.1590 N/A N/A N/A 0.4822 0.2124 0.0170 2.51 0.73 0.38 0.83 3.35 1.113 1.068 2.181 52.337 0.0075 0.003 0.080 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00261 Data For Avg Daily Emission Rate Calculation (inputs in red cells only) Total PM Ibs/hr "Water Wash Performed on Run 3 (R=24hrs) Eavg= EsS (A+BJ/AR) +EN (((R-S)/R)-(BS/AR)) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00262 Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner # 2 Condition Normal Sample Type: Method 5/202 Run Number: 1 Date: 1-Feb-16 2 1-Feb-16 3 2-Feb-16 Total Sampling Time (min) 72.0 72.0 72.0 Corrected Barometric Pressure (in Hg) 29.83 29.82 30.17 Absolute Stack Pressure (in H20) 29.81 29.80 30.15 Stack Static Pressure (in H20) Average Stack Temperature (F -0.24 146.5 -0.24 145.0 -0.24 146.1 Stack Area (sq in) Actual Meter Volume (cu ft) Average Meter Pressure (in H20] 4072 36.983 0.83 4072 36.468 0.81 4072 40.619 1.04 Average Meter Temperature (F 88.2 90.9 64.0 Moisture Collected (g) 301.1 275.9 356.5 Carbon Dioxide Concentration (%V) 6.2 6.2 Oxygen Concentration (%V) Nitrogen Concentration (%V) Dry Gas Meter Factor (y5) 14.8 79.0 0.9782 14.8 79.0 0.9782 14.8 79.0 0.9782 Nozzle Diameter (in) Pitot Constant 0.262 0.84 0.262 0.84 0.280 0.84 Average Sampling Rate (dscfm) 0.483 0.474 0.562 Standard Metered Volume (dscf) 34.808 34.142 40.476 Standard Metered Volume (dscm) 0.986 0.967 1.146 Stack Moisture (%V) 29.0 27.6 29.3 Saturated Moisture (%V) 23.0 22.4 22.7 Mole Fraction Dry Stack Gas Dry Molecular Weight 0.770 29.58 0.776 29.58 0.773 29.58 Wet Molecular Weight 26.92 26.99 26.95 Average SORT of Delta P 0.56 0.56 0.55 Stack Gas Velocity (fps) 34.6 34.3 Stack Gas Velocity (mps) 10.5 10.5 Volumetric Flow Rate (acfm) 59578 58670 58204 Volumetric Flow Rate (acmm) 1687 1662 1648 Volumetric Flow Rate (dscfm) Volumetric Flow Rate (dscmm) Percent Isokinetic Post Test Meter QA (yqa) 39805 1127 91.5 0.9963 39566 1120 90.6 1.0024 39484 1118 94.2 0.9908 Note: Run 1 failed the final leak check and there was not used in the overall average. 4 2-Feb-16 72.0 30.12 30.10 -0.24 146.8 4072 40.630 1.11 65.1 366.0 6.2 14.8 79.0 0.9782 0.280 0.84 0.560 40.338 1.142 30.0 22.8 0.772 29.58 26.95 0.56 34.9 10.6 59267 1678 40072 1135 92.5 1.0203 Average 72.0 30.04 30.02 -0.24 146.0 4072 39.239 0.99 73.3 332.8 6.2 14.8 79.0 0.9782 0.274 0.84 0.532 38.318 1.085 29.0 22.6 0.8 29.6 27.0 0.6 34.6 10.5 58713.7 1662.8 39707.4 1125 92.4 1.0045 Calciner #2 M5 202 3.15.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run Summary ED 001523 00007569-00263 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (~"d) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data Replicate 1 C02 Percent 6.2 Replicate 2 Replicate 3 Average 6.2 Method 5/202 PCS Phosphate 60402248 Calciner# 2 Normal N-54 0.9782 3.0 29.93 02 Percent 14.8 14.8 Date Operator Run Number K Factor Meter "H@ Pitot Constant Height of Location (ft) Static Pressure (Ps] Stack Geometry (R or C)? Stack Diameter (in] Stack Width (if Rectangle] Nozzle ID 1 (in] Nozzle ID 2 (in] N2 Percent Nozzle ID 3 (in] 79.0 || Nozzle ID (In) 2/1/2016 DM/RLM 1 2.62 1.8050 0.84 100 -0.24 c 72.0 impinger 1 impinger 2 impinger 3 impinger 4 Impinger 5 impinger 6 impinger 7 impinger 8 0.262 0.265 0.260 0.262 SatujafcqnJ ht Moisture CalciEted|lercent Moisture isokinetic % Traverse Point Location Sampling Time (min) Clock Time (24 hr) Dry Gas Meter Reading Vm (ft3) Velocity Head CP) (in H20) Orifice ^ | ^Sfe^k Pressure \jjt) * Temp Ts HCH20) | (F) Dry Gas Meter Temperature Tm in Tm out (F) (F) Calciner #2 M5_202_3.15 17cv1906 Sierra Club v. EPA - 6/22 Production Run 1 ED 001523 00007569-00264 Enter data in unshaded areas. Sample Type Method 5/202 Client/Plant " PCS Phosphate Project Number 60402248 Sampling Location__ Condition Calciner# 2 Normal Meter Box Number__ N-54 Meter Factor Td)__ 0.9782 Minutes per Point__ 3.0 Barometric Pressure__ 29.92 02/C02 Method Per historical Data C02 Percent 02 Percent Replicate 1 6.2 14.8 Replicate 2 Replicate 3 Average 6.2 14.8 Date Operator Run Number K Factor Meter H( Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Wic Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in W.o | Nozzle !D (in) 2/1/2016 DM/RLM 2 3.40 1.8050 0.84 100 -0.24 c 72.0 0.262 0.260 0.264 0.262 impinger 1 impinger 2 impinger 3 impinger 4 impinger 5 impinger 6 impinger 7 impinger 8 Impinger Weights (g) initial Final 484.5 715.0 546.7 696.3 568.0 708.2 911.8 924.0 Traverse Point Location B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 16:25:00 16:28:00 16:31:00 16:34:00 16:37:00 16:40:00 16:43:00 16:46:00 16:49:00 16:52:00 16:55:00 16:58:00 17:01:00 17:03:00 17:06:00 17:09:00 17:12:00 17:15:00 17:18:00 17:21:00 17:24:00 17:27:00 17:30:00 17:33:00 17:36:00 17:39:00 Dry Gas Meter Reading Vm (ft3) 683.282 684.800 686.100 687.600 689.000 690.500 692.100 693.200 695.100 696.900 697.800 699.700 701.015 701.015 702.400 703.900 705.900 706.900 708.800 710.200 712.000 713.700 714.800 716.100 717.400 719.750 Velocity Head CP) (in H20) 0.28 0.31 0.30 0.33 0.28 0.27 0.31 0.35 0.34 0.32 0.29 0.25 0.34 0.37 0.37 0.32 0.36 0.32 0.30 0.29 0.29 0.29 0.27 0.27 Orifice Pressure Diff CH) (in H20) 0.73 0.81 0.76 0.86 0.73 0.71 0.81 0.92 0.89 0.84 0.76 0.66 0.89 0.97 0.97 0.84 0.94 0.84 0.79 0.76 0.76 0.76 0.71 0.71 Stack Temp Ts (F) 145 139 146 146 146 148 148 145 138 146 147 143 146 148 141 146 140 142 147 148 147 144 147 148 Dry Gas Meter Temperature Tm in Tm out (F) (F) 94 95 93 94 90 92 90 92 90 92 90 93 90 93 89 93 89 92 88 92 89 93 89 93 90 92 90 93 90 93 90 93 89 92 89 92 89 92 88 92 88 91 88 91 88 91 88 91 Net 230.5 21.3 11.9 12.2 0.0 0.0 0.0 Calciner #2 M5_202_3.15 Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00265 Enter data in unshaded areas. Sample Type Method 5/202 Client/Plant " PCS Phosphate Project Number 60402248 Sampling Location__ Condition Calciner# 2 Normal Meter Box Number__ N-54 Meter Factor Td)__ 0.9782 Minutes per Point__ 3.0 Barometric Pressure__ 30.27 02/C02 Method Per historical Data C02 Percent 02 Percent Replicate 1 6.2 14.8 Replicate 2 Replicate 3 Average 6.2 14.8 Date Operator Run Number K Factor Meter H( Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Wic Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.0 || Nozzle !D (in) 2/2/2016 DM/RLM 3 3.40 1.8050 0.84 100 -0.24 c 72.0 0.276 0.285 0.279 0.280 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 10:30:00 10:33:00 10:36:00 10:39:00 10:42:00 10:45:00 10:48:00 10:51:00 10:54:00 10:57:00 11:00:00 11:03:00 11:06:00 11:12:00 11:15:00 11:18:00 11:21:00 11:24:00 11:27:00 11:30:00 11:33:00 11:36:00 11:39:00 11:42:00 11:45:00 11:48:00 Dry Gas Meter Reading Vm (ft3) 721.100 723.100 724.900 726.600 728.300 730.600 731.800 733.300 735.000 736.600 738.200 739.800 741.231 741.275 743.200 744.900 746.600 748.200 750.000 751.600 753.200 754.900 756.700 758.300 760.100 761.763 Velocity Head CP) (in H20) 0.36 0.34 0.35 0.33 0.32 0.30 0.28 0.29 0.27 0.29 0.27 0.22 0.32 0.30 0.33 0.31 0.30 0.28 0.28 0.31 0.34 0.40 0.30 0.28 Orifice Pressure Diff CH) (in H20) 1.20 1.20 1.20 1.10 1.10 1.00 0.95 0.99 0.92 0.98 0.92 0.75 1.10 1.00 1.10 1.10 1.00 0.95 0.95 1.10 1.20 1.30 1.00 0.96 impinger 1 impinger 2 impinger 3 impinger 4 impinger 5 impinger 6 impinger 7 impinger 8 Impinger Weights (g) initial Final 501.8 844.4 592.6 688.1 593.4 691.6 892.5 902.1 Stack Temp Ts (F) 147 142 148 144 149 144 149 149 149 143 148 148 148 146 148 145 143 148 148 142 145 148 148 138 Dry Gas Meter Temperature Tm in Tm out (F) (F) 60 62 60 62 60 63 59 64 59 64 60 65 60 65 61 66 61 66 62 66 62 67 62 67 64 68 65 69 64 68 65 68 64 67 64 67 64 66 64 66 63 66 63 66 63 66 63 65 Net 342.6 0.8 3.5 9.6 0.0 0.0 0.0 Calciner #2 M5_202_3.15 Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00266 Enter data in unshaded areas. Sample Type Method 5/202 Client/Plant " PCS Phosphate Project Number 60402248 Sampling Location__ Condition Calciner# 2 Normal Meter Box Number__ N-54 Meter Factor Td)__ 0.9782 Minutes per Point__ 3.0 Barometric Pressure__ 30.22 02/C02 Method Per historical Data C02 Percent 02 Percent Replicate 1 6.2 14.8 Replicate 2 Replicate 3 Average 6.2 14.8 Date Operator Run Number K Factor Meter H( Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Wic Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.0 || Nozzle !D (in) 2/2/2016 DM/RLM 4 3.48 1.8050 0.84 100 -0.24 c 72.0 0.276 0.285 0.279 0.280 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 13:37:00 13:40:00 13:43:00 13:46:00 13:49:00 13:52:00 13:55:00 13:58:00 14:01:00 14:04:00 14:07:00 14:10:00 14:16:00 14:16:00 14:19:00 14:22:00 14:25:00 14:28:00 14:31:00 14:34:00 14:37:00 14:40:00 14:43:00 14:46:00 14:49:00 14:52:00 Dry Gas Meter Reading Vm (ft3) 769.884 771.600 773.200 774.900 776.600 778.200 780.000 781.500 783.200 784.900 786.600 788.300 789.755 789.796 791.500 793.400 795.200 796.900 798.800 800.600 802.300 803.900 805.600 807.300 808.900 810.555 Velocity Head CP) (in H20) 0.32 0.37 0.32 0.28 0.30 0.29 0.30 0.30 0.32 0.32 0.31 0.25 0.36 0.40 0.40 0.36 0.36 0.32 0.31 0.28 0.29 0.31 0.28 0.27 Orifice Pressure Diff CH) (in H20) 1.10 1.30 1.10 0.97 1.00 1.00 1.00 1.00 1.10 1.10 1.10 0.87 1.30 1.40 1.40 1.30 1.30 1.10 1.10 0.97 1.00 1.10 0.97 0.94 impinger 1 impinger 2 impinger 3 impinger 4 impinger 5 impinger 6 impinger 7 impinger 8 Impinger Weights (g) initial Final 487.2 795.2 654.3 601.4 684.2 612.4 895.4 912.5 Stack Temp Ts (F) 144 148 141 148 148 139 147 148 149 149 143 148 149 144 150 147 150 147 150 148 150 144 150 143 Dry Gas Meter Temperature Tm in Tm out (F) (F) 65 66 65 66 64 66 63 66 64 67 63 67 63 67 63 67 64 67 63 67 64 68 64 66 65 68 65 67 64 67 64 67 64 67 64 67 63 66 63 66 63 66 63 66 63 65 63 65 Net 308.0 29.9 11.0 17.1 0.0 0.0 0.0 Calciner #2 M5_202_3.15 Run 4 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00267 jft W Mm mmm m arnmmm Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner#2 Condition Normal Sample Type: Method 13B Run Number: Date: Total Sampling Time (min) Corrected Barometric Pressure (in Hg) Absolute Stack Pressure (in H20) Stack Static Pressure (in H20) Average Stack Temperature (F) Stack Area (sq in) Actual Meter Volume (cu ft) Average Meter Pressure (in H20) Average Meter Temperature (F) Moisture Collected (g) Carbon Dioxide Concentration (%V) Oxygen Concentration (%V) Nitrogen Concentration (%V) Dry Gas Meter Factor (I) Nozzle Diameter (in) Pitot Constant Average Sampling Rate (dscfm) Standard Metered Volume (dscf) Standard Metered Volume (dscm) Stack Moisture (%V) Saturated Moisture (%V) Mole Fraction Dry Stack Gas Dry Molecular Weight Wet Molecular Weight Average SORT of Delta P Stack Gas Velocity (fps) Stack Gas Velocity (mps) Volumetric Flow Rate (acfm) Volumetric Flow Rate (acmm) Volumetric Flow Rate (dscfm) Volumetric Flow Rate (dscmm) Percent Isokinetic Post Test Meter QA ( qa) 1 3-Feb-16 72.0 29.94 29.92 -0.26 145.5 4072 39.755 0.98 83.1 289.3 6.2 14.8 79.0 0.9782 0.280 0.84 0.527 37.923 1.074 26.5 22.3 0.777 29.59 27.00 0.54 33.4 10.2 56714 1606 38416 1088 90.7 1.0032 2 12-Feb-16 72.0 30.16 30.14 -0.26 140.7 4072 37.979 0.98 26.8 318.6 6.2 14.8 79.0 0.9782 0.280 0.84 0.565 40.714 1.153 27.0 19.5 0.805 29.59 27.33 0.53 32.7 10.0 55470 1571 39531 1120 94.6 0.9863 3 12-Feb-16 72.0 29.99 29.97 -0.26 142.0 4072 37.596 0.97 37.4 319.5 6.2 14.8 79.0 0.9782 0.280 0.84 0.545 39.222 1.111 27.7 20.7 0.793 29.59 27.20 0.53 32.9 10.0 55875 1582 38948 1103 92.5 1.0057 Average 72.0 30.03 30.01 -0.26 142.7 4072 38.443 0.98 49.1 309.1 6.2 14.8 79.0 0.9782 0.280 0.84 0.546 39.286 1.112 27.1 20.8 0.792 29.59 27.18 0.53 33.0 10.1 56019 1586 38965 1103 92.6 0.9984 Fluoride Emission Rate Calculations Orion 901 Meter Reading, ppm_________ 0.27 Liquid Sample Volume, mi_____________ 1000 Sample Aliquot______________________ 10 Sample Dilution_____________________ 10 Total Fluoride, mg___________________ 0.2670 Fluoride Concentration, mg/DSCF______ 0.0070 Fluoride Emissions, lbs F/hr___________ 0.0358 Rock Feed (Wet TPH)________________ 69.87 Fluoride Emissions, lbs F/Ton Rock Feed 0.0005 0.23 1000 10 10 0.2340 0.0057 0.0301 65.80 0.0005 0.31 1000 10 10 0.3100 0.0079 0.0407 65.80 0.0006 Average N/A N/A N/A N/A 0.2703 0.0069 0.0355 67.2 0.0005 Calciner#2 M13B WetTPHv2 17cv1906 Sierra Club v. EPA - 6/22 Production Run Summary ED 001523 00007569-00268 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method from Hg Test C02 Percent Replicate 1 6.2 Replicate 2 Replicate 3 Average 6.2 Method 13E PCS Phosphate 60402248 Calciner# 2 Normal N-54 0.9782 3.0 30.04 02 Percent 14.8 14.8 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.0 Nozzle ID (in) 2/3/2016 WL/LB 1 3.40 1.8050 0.84 100 -0.26 c 72.0 0.28C 0.280 0.28C 0.28G impinger Weights (g) initial Final Net impinger 1 743.3 995.5 252.2 Impinger2 impinger 3 689.3 640.4 715.3 643.3 26.C 2.9 impinger 4 914.2 922.4 8.2 impinger 5 0.0 impinger 6 0.0 impinger 7 0.0 impinger 8 o.c Moisture Collected (g) Pitot Tube ID 289.2 6-4 Saturated Percent Moisture 22.33 Standard Calculated Percent Moisture 26.45 Volume (dsef) isokinetic % 90.7 37.9 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 14:10:00 14:13:00 14:16:00 14:19:00 14:22:00 14:25:00 14:28:00 14:31:00 14:34:00 14:37:00 14:40:00 14:43:00 14:46:00 14:50:00 14:53:00 14:56:00 14:59:00 15:02:00 15:05:00 15:08:00 15:11:00 15:14:00 15:17:00 15:20:00 15:23:00 15:26:00 Dry Gas Meter Reading Vm (ft3) 810.711 812.430 814.160 815.820 817.460 819.010 820.670 822.270 824.020 825.640 827.270 828.850 830.415 830.415 832.080 833.780 835.640 837.470 839.180 840.820 842.510 844.070 845.670 847.280 848.920 850.466 Velocity Head (AP) (in H20) 0.26 0.33 0.32 0.27 0.26 0.30 0.27 0.32 0.28 0.28 0.26 0.26 0.32 0.30 0.37 0.35 0.31 0.29 0.29 0.26 0.26 0.28 0.27 0.25 Orifice Pressure Diff (AH) (in H20) 0.88 1.12 1.08 0.91 0.88 1.02 0.91 1.08 0.95 0.95 0.88 0.88 1.08 1.02 1.25 1.19 1.05 0.98 0.98 0.88 0.88 0.95 0.91 0.85 Stack Temp Ts (F) 143 148 144 147 142 144 146 147 145 147 146 144 144 147 146 146 138 146 148 147 149 145 146 146 Dry Gas Meter Temperature Tm in Tm out (F) (F) 87 86 86 86 86 86 85 85 84 85 84 85 84 84 83 84 82 84 82 84 82 84 82 84 82 84 82 84 81 84 81 83 80 83 80 83 80 83 80 83 80 83 80 83 80 83 80 83 Calciner #2 M13B_WetTPH.xisx Run 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00269 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method from Hg Test C02 Percent Replicate 1 6.2 Replicate 2 Replicate 3 Average 6.2 Method 13E PCS Phosphate 60402248 Calciner# 2 Normal N-54 0.9782 3.0 30.26 02 Percent 14.8 14.8 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.0 Nozzle ID (in) 2/12/2016 RLM/LB 2 3.40 1.8050 0.84 100 -0.26 c 72.0 0.28C 0.280 0.28C 0.28G impinger Weights (g) initial Final Net impinger 1 731.6 873.1 141T Impinger2 impinger 3 758.6 665.9 916.2 677.7 157.6 11.8 impinger 4 850.3 858.0 7.7 impinger 5 0.0 impinger 6 0.0 impinger 7 0.0 impinger 8 0.0 Moisture Collected (g) Pitot Tube ID 318.6 6-4 Saturated Percent Moisture 19.52 Standard Calculated Percent Moisture 26.95 Volume (dsef) isokinetic % 94.6 40.7 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 10:10:00 10:13:00 10:16:00 10:19:00 10:22:00 10:25:00 10:28:00 10:31:00 10:34:00 10:37:00 10:40:00 10:43:00 10:46:00 10:49:00 10:52:00 10:55:00 10:58:00 11:01:00 11:04:00 11:07:00 11:10:00 11:13:00 11:16:00 11:19:00 11:22:00 11:25:00 Dry Gas Meter Reading Vm (ft3) 851.653 853.510 855.300 856.920 858.480 860.100 861.600 863.110 864.480 866.990 867.490 869.120 870.664 870.664 872.357 874.050 875.880 877.670 879.340 881.010 882.540 884.410 885.410 886.410 888.280 889.632 Velocity Head (AP) (in H20) 0.31 0.31 0.27 0.29 0.27 0.28 0.28 0.26 0.26 0.26 0.27 0.27 0.35 0.35 0.40 0.38 0.32 0.34 0.26 0.24 0.22 0.24 0.22 0.22 Orifice Pressure Diff (AH) (in H20) 1.05 1.05 0.92 0.99 1.05 0.95 0.95 0.88 0.88 0.85 0.91 0.91 1.20 1.20 1.36 1.29 1.09 1.15 0.88 0.82 0.75 0.82 0.75 0.75 Stack Temp Ts (F) 142 127 143 144 141 143 135 144 143 146 142 143 141 142 142 143 137 142 141 143 138 138 138 139 Dry Gas Meter Temperature Tm in Tm out (F) (F) 21 25 23 26 23 26 23 26 24 26 25 26 25 26 26 29 26 29 27 30 27 30 27 30 25 25 25 25 25 26 25 27 27 30 27 30 28 30 28 30 28 29 28 29 28 29 28 29 Calciner #2 M13B_WetTPH.xisx Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00270 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method from Hg Test C02 Percent Replicate 1 6.2 Replicate 2 Replicate 3 Average 6.2 Method 13B PCS Phosphate 60402248 Calciner #2 Normal N-54 0.9782 3.0 30.09 02 Percent 14.8 14.8 Date Operator Run Number K Factor Meter AH@ Pitot Constant Height of Location (ft) Static Pressure (Ps Stack Geometry (R or C)? Stack Diameter (in] Stack Width (If Rectangle Nozzle ID 1 (in] Nozzle ID 2 (in] N2 Percent Nozzle ID 3 (in] 79.0 || Nozzle ID (in) 2/12/2016 RLM/WL 3 3.40 1.805C 0.84 100 -0.26 c 72.0 0.28C 0.28C 0.28C 0.28C impinger Weights (g) initial Final Net impinger 1 778.8 1016.0 237.2 impinger 2 689.3 763.9 74.6 impinger 3 641.6 642.5 0.9 impinger 4 905.9 912.7 6.8 impinger 5 0.0 impinger 6 0.0 impinger 7 o.c impinger 0.0 Moisture Collected (g) Pitot Tube iD 319.; 6-4 Saturated Percent Moisture 20.66 Standard Calculated Percent Moisture 27.75 Volume (dsef) isokinetic f 92.5 39.2 Traverse Point Location B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 13:20:00 13:23:00 13:26:00 13:29:00 13:32:00 13:35:00 13:38:00 13:41:00 13:44:00 13:47:00 13:50:00 13:53:00 13:56:00 14:05:00 14:08:00 14:11:00 14:14:00 14:17:00 14:20:00 14:23:00 14:26:00 14:29:00 14:32:00 14:35:00 14:38:00 14:41:00 Dry Gas Meter Reading Vm (ft3) 890.205 891.720 893.180 894.710 896.300 897.800 899.280 901.130 902.730 904.300 905.840 907.390 908.852 908.852 910.870 911.416 913.348 915.280 917.100 918.730 920.310 921.800 923.300 924.790 926.260 927.801 Velocity Head (AP) (in H20) 0.31 0.31 0.26 0.28 0.29 0.25 0.26 0.29 0.27 0.27 0.26 0.24 0.38 0.29 0.34 0.40 0.40 0.30 0.27 0.24 0.25 0.25 0.23 0.24 Orifice Pressure Diff (AH) (in H20) 1.05 1.05 0.88 0.95 0.85 0.85 0.88 0.99 0.92 0.92 0.88 0.82 1.29 0.99 1.15 1.36 1.36 1.02 0.92 0.82 0.85 0.85 0.78 0.82 Stack Temp Ts (F) 138 144 145 146 136 143 146 141 144 148 142 144 140 141 141 140 138 136 140 138 147 138 146 146 Dry Gas Meter Temperature Tm in Tm out (F) (F) 39 39 39 38 37 38 36 38 37 38 36 39 37 36 36 39 36 39 36 39 37 40 38 40 38 38 37 38 37 38 37 39 38 38 37 37 35 38 37 38 35 38 35 37 35 37 35 37 Calciner #2 M13B_WetTPH.xisx Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00271 AECONi PCS Phosphate Calciner #2 Mercury Emission Calculations EPA Method 30B Emission Results 02 Correction Basis Run AVERAGE Pollutant: Mercury Total Hg Catch Sample Volume Hg Concentration mg/dscm 0.0526 0.0553 0.0527 0.0535 Hg Concentration ppmV 0.0063 0.0066 0.0063 0.0064 Oxygen % 13.99 13.99 13.99 13.99 Hg Concentration mg/dscm @ 3% 0.136 0.143 0.137 0.139 Flow Rate dscfm 37.788 38,103 37.178 37,690 Caiciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Mercury ED 001523 00007569-00272 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 1 PCS 60402248.1 Calciner #2 Normal -0.26 100 30.24 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 7.18 7.2 02 Percent 13.99 14.0 N2 Percent 78.8 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 22.18 22.18 0.778 29.71 27.11 2/13/2016 FC/CS 0.84 C 72.0 4071.5 30.14 30.12 T raverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (Afi) (in H2Q) 0.26 0.24 0.25 0.25 0.26 0.28 0.31 0.34 0.34 0.23 0.23 0.24 0.25 0.31 0.34 0.33 0.28 0.31 0.30 0.29 0.29 0.28 0.26 0.23 Stack Temp Ts (F) 143 148 144 147 142 144 146 147 145 147 146 144 144 147 146 146 138 146 148 147 149 145 146 146 Square Root of A/P SQRT(AR) 0.510 0.490 0.500 0.500 0.510 0.529 0.557 0.583 0.583 0.480 0.480 0.490 0.500 0.557 0.583 0.574 0.529 0.557 0.548 0.539 0.539 0.529 0.510 0.480 Stack Gas Velocity (fps) 31.5 30.4 30.9 31.0 31.4 32.7 34.4 36.1 36.0 29.7 29.7 30.3 30.9 34.5 36.1 35.5 32.5 34.4 33.9 33.3 33.4 32.7 31.5 29.7 Note: temperatures taken from 13A testing on 2/12/16 due to faulty thermocouple Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R1 ED 001523 00007569-00273 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 2 PCS 60402248.1 Calciner #2 Normal -0.26 100 30.22 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 7.18 7.2 02 Percent 13.99 14.0 N2 Percent 78.8 | Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 20.05 20.05 0.800 29.71 27.36 2/13/2016 FC/CS 0.84 C 72.0 4071.5 30.12 30.10 T raverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AR) (in H20) 0.24 0.24 0.25 0.26 0.26 0.27 0.30 0.31 0.33 0.25 0.25 0.24 0.24 0.28 0.31 0.28 0.28 0.30 0.26 0.28 0.27 0.27 0.26 0.23 Stack Temp Ts (F) 142 137 143 144 141 143 138 144 143 146 142 143 141 142 142 143 137 142 141 143 138 138 138 139 Square Root of A/P SQRT(AR) 0.490 0.490 0.500 0.510 0.510 0.520 0.548 0.557 0.574 0.500 0.500 0.490 0.490 0.529 0.557 0.529 0.529 0.548 0.510 0.529 0.520 0.520 0.510 0.480 Stack Gas Velocity (fps) 30.1 30.0 30.7 31.4 31.3 31.9 33.5 34.2 35.3 30.8 30.7 30.1 30.1 32.5 34.2 32.5 32.4 33.6 31.3 32.5 31.8 31.8 31.2 29.4 Average Stacr. Average SQRT Temp AP Average Velocity 141.25 0.52 31.80 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 53944 47659 38103 Note: temperatures taken from 13A testing on 2/12/16 due to faulty thermocouple Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R2 ED 001523 00007569-00274 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 3 PCS 60402248.1 Calciner #2 Normal -0.26 100 30.16 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 7.18 7.2 02 Percent 13.99 14.0 N2 Percent 78.8 | Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 20.61 20.61 0.794 29.71 27.29 2/13/2016 FC/CS 0.84 C 72.0 4071.5 30.06 30.04 T raverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AR) (in H20) 0.22 0.24 0.25 0.27 0.26 0.25 0.27 0.30 0.31 0.30 0.25 0.26 0.27 0.28 0.27 0.28 0.25 0.26 0.24 0.24 0.23 0.25 0.26 0.23 Stack Temp Ts (F) 138 144 145 146 136 143 146 141 144 148 142 144 140 141 141 140 138 136 140 138 147 138 146 146 Square Root of A/P SQRT(AR) 0.469 0.490 0.500 0.520 0.510 0.500 0.520 0.548 0.557 0.548 0.500 0.510 0.520 0.529 0.520 0.529 0.500 0.510 0.490 0.490 0.480 0.500 0.510 0.480 Stack Gas Velocity (fps) 28.8 30.2 30.8 32.1 31.2 30.8 32.1 33.7 34.3 33.9 30.8 31.4 31.9 32.5 31.9 32.5 30.7 31.2 30.1 30.0 29.6 30.7 31.5 29.6 Average Stacr. Average SQRT Temp AP Average Velocity 142.00 0.51 31.35 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 53179 46830 37178 Note: temperatures taken from 13A testing on 2/12/16 due to faulty thermocouple Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R3 ED 001523 00007569-00275 AZCOM Date 2/13/2016 Plant PCS Phosphate Location Calciner #2 Sample Type Run Number/Side (A/B) 30 B 1 Operator FC/CS Location Height Initial Leak Check (L/min @ "Hg) 0.000 22 Final Leak Check (L/min (5) "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL304526 30.14 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002494 1.0180 1.0180 72 Page 1 of_____1_ Run No, 1 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 10:55:00 0.000 5 11:00 4.34 10 11:05 8.74 15 11:10 12.88 20 11:15 17.06 25 11:20 21.21 30 11:25 25.61 35 11:30 29.06 40 11:35 33.66 45 11:40 37.20 50 11:45 41.63 55 11:50 45.87 60 11:55 50.004 50.004 50.0040 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) 150 150 150 152 158 156 157 159 159 162 149 142 Trap Temp, (deg. F) 296 298 285 260 238 229 246 290 279 261 233 225 Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 33 33 242 33 33 242 34 33 244 34 33 246 34 33 246 34 33 243 35 33 243 36 33 242 35 33 244 35 33 242 35 33 240 35 33 236 154 262 34 33 243 Pump Vacuum (" Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Target Volume Spike Amount (ng) 2000 Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 54761.9542 54.7619542 Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 1A ED 001523 00007569-00276 A~COM Date 2/13/2016 Plant PCS Phosphate Location Calciner #2 Sample Type Run Number/Side (A/B) 30 B 1 Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" l-feO) Barometric Pres. (" Hg) OL232758 30.14 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002663 1.0280 1.0280 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading <L) Mechanical Gas Meter Reading (m3) 10:55:00 11:00 11:05 11:10 11:15 11:20 11:25 11:30 11:35 11:40 11:45 11:50 11:55 0.000 4.33 8.70 12.91 17.12 21.33 25.78 29.19 33.71 37.51 41.94 46.21 50.610 50.610 50.610 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 150 296 33 150 298 33 150 285 34 152 260 34 158 238 34 156 229 34 157 246 35 159 290 36 159 279 36 162 261 36 149 233 36 142 225 36 33 242 33 242 33 244 33 246 33 246 33 243 33 243 33 242 33 244 33 242 33 240 33 236 154 262 35 33 243 Pump Vacuum (" Hg) 2 2 2 2 2 2 2 2 2 2 2 2 2 2.00 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 55932.33745 55.9323374 Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production IB ED 001523 00007569-00277 A~COM Date 2/13/2016 Plant PCS Phosphate Location Calciner #2 Sample Type 30 B Run Number/Side (A/B) Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 13 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL304530 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/002 Method 8002494 1.0180 1.0180 72 Page 1 of____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 12:40:00 0.000 5 12:45 4.76 10 12:50 9.03 15 12:55 13.16 20 13:00 16.88 25 13:05 20.52 30 13:10 24.42 35 13:15 27.92 40 13:20 31.89 45 13:25 35.92 50 13:30 39.87 55 13:35 43.64 60 13:40 47.226 47.2260 47.2260 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 162 268 36 154 252 36 157 237 37 152 239 36 164 276 37 155 298 37 163 289 38 163 278 37 160 248 37 158 237 37 162 255 37 154 284 37 160 290 37 159 265 37 33 241 33 241 33 239 33 235 33 234 33 236 33 236 33 236 33 235 33 232 33 232 33 235 33 237 33 236 Pump Vacuum <" Hg) 2 2 1 1 1 1 1 1 1 1 1 1 1 1.15 Target Volume Spike Amount (ng) 2000 Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 51432.40413 51.4324041 Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2A ED 001523 00007569-00278 A=COM Date 2/13/2016 Plant PCS Phosphate Location Calciner #2 Sample Type 30 B Run Number/Side (A/B) Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 13 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL321064 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002663 1.0280 1.0280 72 Page 1 of____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point A1 TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 12:40:00 12:45 12:50 12:55 13:00 13:05 13:10 13:15 13:20 13:25 13:30 13:35 13:40 0.000 4.660 9.020 13.260 17.080 20.850 24.770 28.220 32.090 36.070 39.820 43.610 47.1810 47.1810 47.1810 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 162 268 37 154 252 38 157 237 38 152 239 38 164 276 38 155 298 38 163 289 39 163 278 38 160 248 39 158 237 38 162 255 38 154 284 38 160 290 38 159 265 38 33 241 33 241 33 239 33 235 33 234 33 236 33 236 33 236 33 235 33 232 33 232 33 235 33 237 33 236 Pump Vacuum (" Hg) 3 3 2 2 2 2 2 2 2 2 2 2 2 2.15 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 51759.84167 51.7598417 Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2B ED 001523 00007569-00279 A~COM Date 2/13/2016 Plant PCS Phosphate Location Calciner #2 Sample Type 30 B Run Number/Side (A/B) Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 14 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL304748 30.06 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002494 1.0180 1.0180 72 Page 1 of_____1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 14:30:00 14:35 14:40 14:45 14:50 14:55 15:00 15:05 15:10 15:15 15:20 15:25 15:30 0.000 4.570 8.490 12.510 16.770 20.380 24.030 28.160 33.920 34.580 38.820 43.490 47.6680 47.6680 47.6680 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 161 261 39 160 295 40 160 293 40 159 269 40 161 255 39 161 241 38 162 253 38 160 269 38 159 271 38 161 264 38 160 242 38 160 230 38 33 243 33 247 33 250 33 253 33 257 33 248 33 247 33 242 33 242 33 241 33 242 33 239 160 262 39 33 246 Pump Vacuum <" Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1.00 Target Volume Spike Amount (ng) 2000 Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 51621.08654 51.6210865 Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3A ED 001523 00007569-00280 A~COM Date 2/13/2016 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30 B Run Number/Side (A/B) Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 15 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL321028 30.06 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002663 1.028 1.028 Page 1 of_____1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading <m3) 0 14:30:00 0.000 5 14:35 4.500 10 14:40 8.480 15 14:45 12.590 20 14:50 16.970 25 14:55 20.700 30 15:00 24.090 35 15:05 28.870 40 15:10 34.070 45 15:15 36.120 50 15:20 40.090 55 15:25 44.270 60 15:30 48.3130 48.3130 48.3130 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 161 261 40 160 295 42 160 293 41 159 269 41 161 255 40 161 241 39 162 253 39 160 269 39 159 271 39 161 264 39 160 242 39 160 230 39 33 243 33 247 33 250 33 253 33 257 33 248 33 247 33 242 33 242 33 241 33 242 33 239 160 262 40 33 246 Pump Vacuum (' Hg) 2 2 2 2 2 2 2 2 2 2 2 2 2.00 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 52718.91529 52.7189153 Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3B ED 001523 00007569-00281 AECOM FIELD SAMPLING DATA SHEET Sample and Velocity Traverse for Stationary Sources EPA Method 1 , 23456789 10 Duct Diameters From Upstream Flow Disturbance (B/D) Deq = 2LW / (L+W) Dnstream Diameters (A/D) Upstream Diameters (B/D) Cross-Sectional Layout of Rectangular Stacks Traverse Points Matrix 9 3x3 12 4x3 16 4x4 20 5x4 25 5x5 4 6 8 10 m 14 16 18 20 22 24 1 6.7 4.4 3.2 2.6 *27! IS 1.6 1.4 1.3 1.1 1.1 2 25.0 14.6 10.5 8.2 6.7 5.7 4.9 4.4 3.9 3.5 3.2 3 75.0 29.6 19.4 14.6 11.8 9.9 8.5 7.5 6.7 6.0 5.5 4 93.3 70.4 32.3 22.6 17.7 14.6 12.5 10.9 9.7 8.7 7.9 5 85.4 67.7 34.2 25.0 20.1 16.9 14.6 12.9 11.6 10.5 6 95.6 80.6 65.8 35.6 26.9 22.0 18.8 16.5 14.6 13.2 7 89.5 77.4 64.4 36.6 28.3 23.6 20.4 18.0 16.1 8 96.8 85.4 75.0 33.4 37.5 29.6 25.0 21.8 19.4 9 91.8 82.3 73.1 62.5 38.2 30.6 26.2 23.0 10 97.4 88.2 79.9 71.7 61.8 38.8 31.5 27.2 11 93.3 85.4 78.0 70.4 61.2 39.3 32.3 12 197,9/ 90.1 83.1 76.4 69.4 60.7 39.8 13 V 94.3 87.5 81.2 75.0 68.5 60.2 14 98.2 91.5 85.4 79.6 73.8 67.7 15 95.1 89.1 83.5 78.2 72.8 16 98.4 92.5 87.1 82.0 77.0 17 95.6 90.3 85.4 80.6 18 98.6 93.3 88.4 83.9 19 96.1 91.3 86.8 20 98.7 94.0 89.5 21 96.5 92.1 22 98.9 94.5 23 96.8 24 98.9 Traverse Point 1 Fraction Distance of From Diameter Wall 'Ll US Nipple Length a" Point Location US LOCATION OF TRAVERSE POINT IN RECTANGULAR STACKS. 2 3 4 5 6 7 8 9 10 11 12 2 UT- <=?,% 1 25.0 16.7 12.5 10.0 8.3 7.1 6.3 5.6 5.0 4.5 4.2 3 4 \tO- 2 75.0 50.0 37.5 30.0 25.0 21.4 18.8 16.7 15.0 13.6 12.5 3 83.3 62.5 50.0 41.7 35.7 31.3 27.8 25.0 22.7 20.8 5 7J5.0 \9rt> "23/0 4 87.5 70.0 58.3 50.0 43.8 38.9 35.0 31.8 29.2 6 SS-G ILfS G 3o, U 5 7 CSi A Afo.M `St ,4 6 90.0 75.0 64.3 56.3 50.0 45.0 40.9 37.5 91.7 78.6 68.8 61.1 55.0 50.0 45.8 8 ^7570 S-LD *5^,13 7 92.9 81.3 72.2 65.0 59.1 54.2 9 ^1.3 fcH.,3... 8 93.8 83.3 75.0 68.2 62.5 10 fe>S/S 11 cn-'L ... 9 10 94.4 85.0 77.3 70.8 95.0 86.4 79.2 12 11 -- 12 95.5 87.5 95.8 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00282 AECOM FIELD SAMPLING DATA SHEET Flow and Moisture EPA Methods 2 & 4 PAGE t OF CItent/PIant: Location: Project#: y(HQlZA% tt> Condition: ideftJUXjj Date; Moisture Run #: Operators): Duration (min): /JT DGM#: CF (Yd): AH@; Cp: 0.84 Pbar("Hg): Height w.r.t. Barometer (ft): Pstatic ("HzO): 2L Initial Leak (<0.02 fr/min; >10"Hg) ft3/min: Vac. ("Hg): Source Height (ft): Duct Diameter ("): Z}2' Final Leak S (<0.02 ft /min; >run maximum) ft/min: Vac. ("Hg): Duct Width ("): Duct Length ("); Pitot Leak (>3"H20) +P ("H20): 02 (%/time) % P ("H20): .X % Pitot Tube ID#: % C02 (%/time) % % % Time Moisture Determination DGM Volume (ft3) AH CH20) DGM Inlet T CD DGM Outlet T ("F) Flow Run #: | Start ^ SZ. Traverse Point p &p ("HaO) End Source T CF) Flow Run #: Start End AP ("HsO) Source T CF) Row Run #: Start End AP C"H20) Source T CF) Cyclonic Angle C) ht y z Zf\ ',,3t. wc H8 0 S ~ 3 *l s- _____ *L_ .0 -SO \so IO b> K3 0 Zf. .'Vz- / S' *2^ 3 S3z> ij 13 3 3 H .33 Hi \Z 7LXs, w? 7 _ 2> \ .53 H1 tz>> z 3 *-53 \H(1 W w 3 13 / S' XI HT Z2~ ? W H \%q- 3 X H4 A \st I'D - 2S~ l*t 2_ [f \3T~ 1 \3l / Comments: Mt'x. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00283 Test Run 2 STRATA Version 3.2.,112 02 C02 % % Begin calculating run averages 02-13-2016 15:28:54 -0.119 -0.207 02-13-2016 15:29:55 -0.138 -0.216 02-13-2016 15:30:55 -0.144 -0.219 Pause End Pause 02-13-2016 15:33:54 02-13-2016 15:34:54 19.354* 19.355* 20.666* 20.667* 02-13-2016 15:35:54 19.358* 20.663* Pause End Pause 02-13-2016 15:37:54 10.075 9.935 02-13-2016 15:38:54 10.060 9.938 02-13-2016 15:39:54 10.057 9.939 02-13-2016 15:40:54 10.052 9.937 Pause End Pause - 0o-'- 02-13-2016 15:46:54 10.048 7.217 02-13-2016 15:47:54 10.046 7.207 02-13-2016 15:48:54 10.050 7.209 Pause End Pause (12.^13-3016 15:51 : 5 5 , 1 4.7K4 .. 02-13-2016 15:52:55 13.988 9.918 02-13-2016 15:53:55 13.982 9.926 02-13-2016 15:54:55 13.980 9.927 Pause End Pause 02-13-2016 15:57:54 10.048 7.020 02-13-2016 15:58:55 10.052 7.166 02-13-2016 15:59:54 10.052 7.157 Pause End Pause 02-13-2016 16:02:55 14.056 9.880 02-13-2016 16:03:55 13.988 9.892 02-13-2016 16:04:55 13.990 9.898 02-13-2016 16:05:55 13.986 9.908 Pause End Pause 02-13-2016 16:08:55 10.056 6.197 02-13-2016 16:09:54 10.053 7.224 02-13-2016 16:10:55 10.054 7.213 Pause End Pause Pause End Pause 02-13-2016 16:13:55 9.876 02-13-2016 16:14:54 9.894 02-13-2016 16:15:54 . 002 9.906 02-13-2016 16:16:54 ,99! 9.930 Run Averages "02 C02 % % 02-13-2016 16:16:59 11.284* 9.034* Operator: David Marzec Plant Name: PCS Aurora Location: . Calciner #2 Test Run 2 End -yx~ CN&<^c ft OKp r i y_3 / Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00284 EPA Method 30B Emission Results PCS Phosphate Calciner #2 Mercury Emission Calculations 02 Correction Basis Run 1 2 3 AVERAGE Pollutant: Mercury Total Hg Catch ng 2464 2428 2110 2334 Sample Volume dscm 0.048 0.048 0.048 0.048 Hg Concentration CopctminiTion mg/dscm \V~>pmV 0.0514 < w \.0062 0.0508 /; iN 0.0061 0.0448/NA / 0.0054 0.0059 Oxygen % 14.8 14.8 14.8 14.8 Hg Concentration mg/dscm @ 3% 0.151 0.149 0.131 0.144 Flow Rate dscfm 37,838 37.523 37,474 37,612 & \<f^cO << Caiciner_2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production Mercury ED 001523 00007569-00285 Date 1/30/2016 Plant PCS Phosphate Location Calciner #2 Sample Type 30B Run Number/Side (A/B) _____ 1_____ 1____ A Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 22 Final Leak Check (L/min (S> "Hg) 0.000 7 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL304557 30.14 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor, 02/l 8002494 1.0180 1.0180^ Page 1 of_____ 1_ Run No, 1 Diagram of Duct & Traverse Points Single Point Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 11:00:00 11:05 11:10 11:15 11:20 11:25 11:30 11:35 11:40 11:45 11:50 0.000 4.06 8.51 11.80 15.28 18.62 22.42 26.40 29.95 33.47 36.68 Meter Flow Rate (Lpm) Stack Temp, Trap Temp, (deg. F) (deg. F) V^g- F) c ^ 44 0.75 150 0.75 150 44 0.75 143 j. LJ 43 0.75 146 y%74^ 43 0.75 m A 298 43 0.75 w 282 43 0.75 259 43 0.75 v\46 232 43 TO'iS2 0.75 * 227 44 '75/X 155 257 44 ' 146 298 45 55 11:55 40.86 60 12:00 44.613 148 294 44 155 278 44 TOTAL Target Volume Spike Amount (ng) 2000 44.613 i 44.6130 r A' Vs i 149 262 44 i i i Comments: Barometric Pressure corrected for Elevation Heated Line Chiller Temp, (deg. F) Temp. (deg. F) 32 254 32 254 32 253 32 253 32 255 32 256 32 256 32 255 32 253 32 252 32 252 32 255 32 256 32 254 Pump Vacuum C Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 i i i Mechanical Totalizer Total Volume (L) 47964,99849 47,9649985 O*' Calciner _2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production 1A ED 001523 00007569-00286 METHOD 30B Page 1 of_____ 1_ Run No, 1 Date 1/30/2016 Plant PCS Phosphate Location Calciner #2 Sample Type 30B Run Number/Side (A/B) _____ 1_____ 1____ B Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 24 Final Leak Check (L/min @ "Hg) 0.000 7 Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL321167 30.14 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor, O20/I 8002663 1.0280 1.028CH Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) 11:00:00 11:05 11:10 11:15 11:20 11:25 11:30 11:35 11:40 11:45 11:50 11:55 12:00 0.000 3.81 7.93 11.89 15.86 19.60 23.44 27.01 30.31 33.77 37.20 40.90 44.179 44.179 Target Volume Spike Amount (ng) i Comments: Barometric Pressure corrected for Elevation Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0.75 Stack Temp, (deg. F) 150 yRReffl^^ltp. Trap Temp, (deg. F) V^g-F) c ^ 45 0.75 150 45 0.75 143 j. 44 0.75 146 ^ VV4" 44 0.75 / 298 44 0.75 Y 282 44 0.75 259 44 0.75 k\46 232 45 0.75 f 0.75/V rr152 155 227 257 45 45 ___SvZ ' 146 298 44 , MZJ 148 294 45 155 278 46 44.179 J\2*75 rAT 149 262 45 A' Vs i i i i Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 32 254 32 254 32 253 32 253 32 255 32 256 32 256 32 255 32 253 32 252 32 252 32 255 32 256 32 254 i i i Pump Vacuum (" Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Mechanical Totalizer Total Volume (L) 47869.86051 47,8698605 Calciner _2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production IB ED 001523 00007569-00287 Date 1/30/2016 Plant PCS Phosphate Location Calciner #2 Sample Type 30B Run Number/Side (A/B) _____ ?_____ 1____ A Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 18 Final Leak Check (L/min (S> "Hg) 0.000 9 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL304508 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) ' Stack Diameter Assumed H20 % K-factor, 02/l 8002494 1.018Q 1,0180" Page 1 of_____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point TOTAL Target Volume Spike Amount (ng) Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) 12:20:00 12:25 12:30 12:35 12:40 12:45 12:50 12:55 13:00 13:05 13:10 13:15 13:20 Digital Gas Meter Reading (L) 0.000 4.26 7.98 11.74 15.50 19.39 22.85 25.86 30.71 34.15 37.61 41.44 44.717 44.7170 Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) Stack Temp, (deg. F) Trap Temp, (deg. F) V^g-F) r ^ 45 0.75 146 0.75 155 47 0.75 150 j. 44 0.75 149 V>64^ 45 0.75 A 237 46 0.75 Y 228 48 0.75 A V j4 247 45 0.75 287 46 0.75 f rr151 292 48 0.75/V k/ 146 272 50 FvV ' 143 252 52 146 229 54 44.7170 ^^3*75 157 236 55 149 263 48 r 2000 i Vs i i i i Comments: Barometric Pressure corrected for Elevation Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 32 247 32 252 32 253 32 255 32 255 32 253 32 252 32 254 32 256 32 261 32 263 32 263 32 262 32 256 Pump Vacuum C Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 i i i Mechanical Totalizer Total Volume (L) 47622,74277 47,6227428 Calciner _2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production 2A ED 001523 00007569-00288 Date 1/30/2016 Plant PCS Phosphate Location Calciner #2 Sample Type 30B Run Number/Side (A/B) _____ ?_____ 1____ B Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min (5) "Hg) 0.000 8 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL321009 30.12 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor, 02/l 8002663 1.0280 1.0280^ Page 1 of_____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point A1 TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) 12:20:00 12:25 12:30 12:35 12:40 12:45 12:50 12:55 13:00 13:05 13:10 13:15 13:20 0.000 4.440 8.430 12.410 16.180 19.590 22.670 24.940 29.920 33.170 36.980 41.190 44.5230 44.5230 Target Volume Spike Amount (ng) i Comments: Barometric Pressure corrected for Elevation Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0.75 Stack Temp, (deg. F) 146 yMe^l^^ip. Trap Temp, c (deg. F) v^g- F) ^ 44 >0* 0.75 0.75 0.75 V>64^ 155 150 j. 149 48 45 45 0.75 0.75 vJr0' W / 237 228 45 45 0.75 V 14\ 247 45 0.75 A140 287 46 _I-7f5AiVZJ 0.75 f U 146 > 143 146 292 272 252 229 48 51 52 54 rAT 44.5230 ,, 157 236 56 149 263 48 AVs 'i i i i Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 32 247 32 252 32 253 32 255 32 255 32 253 32 252 32 254 32 256 32 261 32 263 32 263 32 262 32 256 ii i Pump Vacuum (" Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Mechanical Totalizer Total Volume (L) 47889,16903 47,889169 Calciner _2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production 2B ED 001523 00007569-00289 Date 1/30/2016 Plant PCS Phosphate Location Calciner #2 Sample Type 30B Run Number/Side (A/B) _____ 3_____ 1____ A Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 14 Final Leak Check (L/min (S> "Hg) 0.000 6 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL304746 30.06 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor, 02 vM 8QQ2494 1.0180 1.0180^ Page 1 of_____ 1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) (L) Clock Time (min) Digital Gas Meter Reading 0 14:35:00 0.000 5 14:40 4.410 10 14:45 8.190 15 14:50 12.060 20 14:55 15.880 25 15:00 19.670 30 15:05 23.320 35 15:10 27.080 40 15:15 31.180 45 15:20 34.960 50 15:25 38.030 55 15:30 41.920 60 15:35 45.7190 45.7190 Target Volume Spike Amount (ng) 2000 i Comments: Barometric Pressure corrected for Elevation Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0.75 Stack Temp, (deg. F) 141 Trap Temp, c (deg. F) C^g-F) ^ 66 0.75 148 67 0.75 147 j. 68 0.75 144 4. W>60* 68 0.75 ^-I l J / 248 68 0.75 0.75 V Y 14\ 228 260 69 70 0.75 0.75 f v\48 /S>5 293 284 70 71 0.75/V C/ 148 267 72 " 146 248 72 , A' 146 229 72 vNV A>5 45.7190 148 267 69 rAT A' Vs i i i i Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 32 261 32 263 32 266 32 266 32 267 32 265 32 264 32 266 32 268 32 269 32 269 32 267 Pump Vacuum <" Hg) 3 3 3 3 3 3 3 3 3 3 3 3 32 266 3 i i i Mechanical Totalizer Total Volume (L) 46632,95745 46,6329575 O*' Calciner _2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production 3A ED 001523 00007569-00290 Date 1/30/2016 Plant PCS Phosphate Location Cal #2 Stack Sample Type 30B Run Number/Side (A/B) _____ 3_____ 1____ B Operator WL/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 15 Final Leak Check (L/min @ "Hg) 0.000 7 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL321426 30.06 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor, 02/l 8002663 1.028. 1.028 Page 1 of_____ 1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Digital Gas Clock Time (min) Meter Reading (L) 14:35:00 14:40 14:45 14:50 14:55 15:00 15:05 15:10 15:15 15:20 15:25 15:30 15:35 0.000 4.080 7.960 11.950 15.930 19.740 23.420 27.150 31.360 35.110 38.260 42.140 46.0250 46.0250 Target Volume Spike Amount (ng) i Comments: Barometric Pressure corrected for Elevation Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) Stack Temp. (deg- F) zssz Trap Temp, (deg. F) V^gF) r y 64 Chiller Temp, (deg. F) 0.75 141 32 0.75 148 65 32 0.75 147 j. 66 32 0.75 144 ^ V\60 66 32 0.75 / 248 66 32 0.75 Y 228 67 32 0.75 V mV 260 67 32 0.75 j 293 68 32 7S>50 0.75 284 68 32 0.75/V V/ 148 267 69 32 " 146 248 71 32 , A' 146 229 71 32 y\V 46.0250 rAT 148 267 67 32 Heated Line Temp, (deg. F) 261 263 266 266 267 265 264 266 268 269 269 267 266 A' Vs i i i i i i i Pump Vacuum C Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 Mechanical Totalizer Total Volume (L) 47593,6295 47,5936295 Calciner _2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production 3B ED 001523 00007569-00291 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 1 PCS 60402248.1 Calciner #2 Normal -0.27 100 30.24 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 6.20 6.2 02 Percent 14.80 N2 Percent 14.8 79.0 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 23.33 23.33 ,, 0.767 Ct 29'5fl^k ` 1/30/2016 DM/FC 0.84 C 72.0 4071.5 30.14 30.12 __ Calciner _2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production R1 ED 001523 00007569-00292 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 2 PCS 60402248.1 Calciner #2 Normal -0.27 100 30.22 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 6.20 6.2 02 Percent 14.80 N2 Percent 14.8 79.0 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 22.76 J 22.76 V 0.772L4ffj 2I!88N*h _2%95 J 1 1/30/2016 DM/FC 0.84 C 72.0 4071.5 30.12 30.10 4 C\ Calciner _2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production R2 ED 001523 00007569-00293 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 3 PCS 60402248.1 Calciner #2 Normal -0.27 100 30.16 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 6.20 6.2 02 Percent 14.80 N2 Percent 14.8 79.0 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 22.24 J 22.24 I 0.778 _2VI1 J 1 1/30/2016 DM/FC 0.84 C 72.0 4071.5 30.06 30.04 4 C\ Calciner _2 30B_updated BP (2) 17cv1906 Sierra Club v. EPA - 6/22 Production R3 ED 001523 00007569-00294 AiCOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE OF X X\ Client/Plant: Or % .......... -- --. \. -- jL---- >-- Location: AAf .... ^2- DGM#; Nii-- ......... ,/7-<y Project #: /t> Condition: . ?? $ CF(Yd): 0 7 Date: Run #: AHg Duration (min): Cp: 0.84 K-Factor: *-yg. PbarC'Hg): gOt/ Initial Leak {<0.02 ft7min; >10"Hg) ft3/min: Height w.r.t. Barometer (ft): l-ffQ static ;"H20): ~ O.Z io Vac. ("Hg): // Source Height (ft): loa Duct Diameter ("): Final Leak V (<0.02 ft /min; >max vacuum) ff/min: O Vac. ("Hg): Duct Widt|}.(``): Duct Length ("): Pitot Leak V (>3"H20) +P ("H20): .P("H2Q): Nozzle PI Q0: ,/%> Probe & Pitot ID: Nozzle D2 (") : <5rt> Nozzle D3 ("): , Time Sample Point Clock j&ff Run (min) DGM Volume (ft3) AP ("HzO) AH ("HjO) Source Probe 24825 fit //& o tip. 7// Mm 1 %/aj/? ,31 A/pl /Y% 3 6 %///& ^ /(9C /o'M /<y 9 9 0/5.00. ,37 <?/ J7 < /$ '0/7. 76 /9p a /r 01 Co / .30 /.op /yy !% 370,67 .37 /76 $ 9! 7?aQ,7 , 30 /,o 797 f /& . J&ZYi-- gatoa S10 97 * 95 /5 ,, 95 /7? U so W7.S7 .36 ,0g /<Y4 /J 33 4AM' ,/u jyv ___ /V76 76 03o A/S' / 0 f A/So Y/< * 33- /,o0 //Y s. 3# @33,0% :?a 7,03 /Yf 3 79 <331, 70 . 3 7 /QSS /Y6 i/ 9S 3J7 /7/9 /76 S' 4k?,Y7 .31 /ro,C /3$ 6 s g'sq.lf? ..P 3 9 V 9$ 'f 7 Si rp/ /rft 0Vf <7 SYS.?/ e r/n < 6$ 3/9,07 * 36 /Y7. /V* io &3 , vr /yy // /> w S'r/,^9, .37 *<tf fi /9 /CDA .Is f ... 73 090,90 090. t/61 *p.5 * /96 Temperature (*F) Filter 24825 Impinger Exit S68 DGM Inlet DGM Outlet Pump Vac. ("Hg) az. 9? 04 2 33's 78 6 77, s%> 67S 0A O AS &? cSt> A S< ..6>9 77 <Y m ssr 1 .sY c/ AFT <7 AS m sy XT fta. m 3 $ r' 97 ? S6 9SI sr 3 SA 06/ 99 S TAJ* Jzk- Sr gy 9 <A S SL r sc S6 S6S? S7 S7 ms 9j s' So S3 4/ f?o S'o M3 9? V 0,3 80 633 9a 03 <33 <Q3 ? >3 V )NTS / 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00295 AECOM Client/Plant: PCS Location: CS if 2, Impinger# 1 2 3 4 impinger Contents Di HzO Di H20 Empty Silica Gel FIELD SAMPLING DATA SHEET ____________ (RECOVERY)____________ METHOD 13A/B Project #: Condition: 2,2 Vf. /o Date: 2-7-/b Run #: ) Method 4 Moisture Determination Approximate Volume (mi) Configuration Initial (g) Final (g) Gain (g) 100 MOD M3.3 100 GS 1 is.3 - MOD Mo**/ - MOD ^zz. *4 Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (DI HzO Rinse) COMMENTS; Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00296 / AECOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE / OF / A /ient/Plant: C 1 V\ /Location: CzhLCPtatTC 2 Project#: UO^OZZ^/Sr-/O Condition: Date: r>/i 2,/ Zb 14* Run#; ^ ^ ^ Operators): ELM-- Duration (min): "12- DGM#: CF (Yd): AH@: i.fc 3 Cp: 0.84 K-Factor: 1 4. PbarCHg): 5?^ f Height w.r.t. Barometer (ft); ;<>c> Pstatic ("HzO); -O. 7(o Initial Leak V {<0.02 ft3/min; >10"Hg) ft3/min: , O Vac-C'Hg): ( 2_ Source Height (ft): p&O Duct Diameter ("): Final Leak V (<0.02 ft /min; >max vacuum) ft3/min: Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak (>3"H20) +P ("HzO): - P ("H20): Nozzle D1 (") 0: . Zjt> Probe & Pitot ID: Nozzle D2 (") : . Z%t> Nozzle D3 (") : ,, 2 Average Nozzle D ("): y&o Sample Point Time Clock Run (min) DGM Volume (ft3) AP (*'H20) AH ("HzO) r'.tfSf > Source Probe 24825 A / /bio (O 5s7. tHl 3/ (36# L ? n 73 93? 3i *31 # e t?5 f zz 3 \L (&' f S3 3 0 * 77- *^7. in C? "7 %?. 17 .St 54 ,. * ZT ' * 2l hoS /9M /VI 2 27 34 ff *19 lVK /9 3 7 * kfcO 0 X}S i ^ J? f 3t 2-j if 3&T- 72f // 30 .17 tJ,93 3T I z 26s /3 ,<?<t W . _. - r ^.* 1* H* (V-j i i. z a >9f /f: 12 X3 *33 it&Fh Zb> 9l9 ,(Z jh *1.1 ! * 11 / T4 3 { 0 / V 7 1 ^0 .uh 1,2. "RT * ( 5? #12 3s 7 > X /.z. /9"Z kX V. 2 : >..W /M 7 h t/ ^ l.Hi $ is of Jr 3 9 %T>. /.x ------)^ Z? \ ,01 tiV 1 0^ 1 0 2 5" i <321$ 2 l,K ,xl ii7 'IH? IM t f D i 9S2.5 8. S>7 - 143 19 m I 4 l( 19 ll 7? i --t 79 1._|-----ae^A_ 6 u l f ,V7 '3ft Ml , 3# L.4 ctH Atz \J -- . \ A 79 *iv t --- IPf , tLit. iS9 ill __N r Temperature ("F) Filter 248+25 Implnger Exit s68 to (<Sj VD DGM Inlet "Zf "73 ?,* ZJ3 DGM Outlet 2-5 74s 2^c5 2- 4 Pump Vac. ("Hg) / / f 7.Z. 7M 74 f 7 3 Zj 2 S 24 Z 61 7. -- 7 _ V z< 22 Hr 7L4 . -y--~ 27> 22 IT " 3/i", e 7' 2-7. 25 5*cP "T-2 2? 3q -y 22 z-7 22 -z r 2 9 ? < 2 5 2 5 77- 7' "7 C 7 7- V r* rzA T .H XT) ;2 2 2 Tn e 72 ^ 3A V N x__ 1/7 ,023h 77 ^2 3 0 sr 7 9^ ZJ\ <$ Z9 sr Lii_ 2 3 '7/ 3 7. r t _ ""7^: V *> -- ti - /--L. /7 * . 173 %~aj/)tc. H/i2P f? "><*'( i3c>7 n UP v^si \ X, f-r 17cv1906 Sierra Club v. EPA - 6/22 Production x ED 001523 00007569-00297 AECOfA Client/Plant: ?3 Location: PJ #>{ 1 Impinger# 1 2 3 4 Impinger Contents Dl H20 Dl HzO Empty Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 13A/B Project#: Condition: a /o Date: 7- j-iU, Run #: jy 2 1=0 Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD 13/.C t 100 GS Vlo.l - MOD (etoS, ? (ell. 3 - MOD O Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dl H2O Rinse) COMMENTS: , Tare (g) A Final (g) j Gain (g) ! jr * ** " \ t 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00298 AZCOM FIELD SAMPLING DATA SHEET EPA Megd13A/j* PAGE 1 OF _L Client/Plant: __________ Project#: isfitfoZZJ/'fcjQ Date: 12.rOp^5tor(sJfg,c>V\/uj U Location:Condition: i-^ Run#: 3 Duration (min): if K-Factor: PbarCHg): SO.f- Height w.r.t. Barometer (ft): /0y pstat-,c ("HzO): ~ 0,2 b Initial Leak / (<0.02 ft3/min; >10"Hg) _tt3/^nin: d,faQfvac. ("Hg): Source Height (ft):/&c> Duct Diameter ("): ^2. Final Leak s (<0.02jt3/mln; >max vacuum) ft3/min: & Q&fy Vac. (``Hg): < 0 [Duct Width {"): Duct Length ("j: Pitot Leak (>3"H2Q) +P ("H20): P("H20): NozzleD1 (")0; 5, 7<*-t> Probe & Pitot ID: Nozzle D2 (") <S>: Q^^t> Nozzle D3 f) Q: q, Z'&t) Average Nozzle D ("): O , 2 'y'O Sample Point Time Clock Run (min) DGM Volume (ft3) ip ("H20) AH C'HzO) Source Probe 248+25 > / i % ?> ilno .._3 3 _____ !jL *PGh*2d \SSfe rw; 4.^n *^'2- *? ___ IjL_ ) *15 L iS 0 e'SZS VDL kTtfjL, r^*4 . 9 ./ 4 ItU vz i bt > \3 ... vZl 2M t ^ . rl it D 30 ^,05), V*^ k TjL- "33 *t4 3 L 4^?S2 i*+H IH9 ' l H6> \%i> 14/3 IM4 tHt - " > V44 i .40* >952 UZFV2- \H& 7 xm. - 3 mtyifi MzTp vs; 3N ^ b HS'HR k if H 13 ,3h i .15* \aL \ >%1o I4t <*09 < , ft) *30 1,62- \3A *1 vi sh; vuo *? Q'hvM *Vf' ^iL \ *\%\s *25 . n it* t4 ill <H z? 3g *25 <k < 979 n 24 .27 k<f --f myo -V2- ----------- ^ *+.... 9( >c_1|------------ * T.. .<W (4 ^ fH4 C- , N> fe f ! cn V Temperature (*F) Impinger Exit ' <68 DGM Inlet 31 DGM Outlet 2Pi Pump Vac. ("Hg) f H *V ----- \--^-- L*f> n I *19 'Z'T "3 jk 34- 3 <5 | 7 i J -------\7------- "Z_ 5 s-qn ~ST" z H-*, . _. --'S-W- 1 < i , J 40 I HH 5 S' ' 4,TV z 42> ,J>K > J'fe' m z __ 3~1 _^dL_ : 5T --413..... GT- Hlb %5T 9 *? 7,'Sr s#-1 7_ 2 7 ? HD, 3S ..1 ( 37 ?? J UP ..If f .... f -3X- 3 S 37 <fe 71 7/ 77 -7 y ' \\ * \ jf * i 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00299 AtCOM FIELL. SAMPLING DATA SHEET (RECOVERY) METHOD 13A/B Impinger# 1 2 3 4 * Impinger Contents Di H20 D) HzO Empty Silica Gel Method 4 Moisture Determinate# , Approximate Volume (ml) Configuration Initial (g) Final (g) 100 100 - -- ' 1 MOD GS MOD MOD 1 i i | Sum - w.* ( i /o/(p, () loM.S J/Z.^ Gain (g) COMMENTS: \. / 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00300 AECOM Plant Name Project Number Location (Source) Date [ - 3o" I , [Q Condition Run *4f \ Page n of Initial Leak 1) 0<0 Rate 2) @ "Hg Meter ID & Cal Factors %p`M:j|4 i) OL'&tesl' Sorbent Trap IDs 2) ^ ~4r i Operator Bar. Press, (in. H2Q) 2p ,U9 Bevation (relative to Barometer) (ft) Rnal Leak Rats Third Bed Spike Level 1) PP '*=? "Hg 2) & $ @ "Hg 1) 'IS^O 2) tfh Trap Clock Time Volume CL, dry) Flow Rate (Lpm) m S Cindy)) Sorbent 1). 2) \ioo 0,00 O . OO i"?$r .M'S ISO zss* 1) M -OLr 2) Uo5 3.^-1 * -MT Iso 1) %s* 2) U id M.V3 .MS ..MS N3 238 1) 2) ms \\,V> H-^i ;i5 -K mu 21a| i) 2) it 2D tS,2? \5^lo .MS .M'S |d 3 1) \\z< 2) 0 D 9 cr VS.Mt /MS" .MS I'SO <D 7 CJcX--~ 1) U'bD 22-HZ- 2) *-Ms )H^ ^..--<123 / 1) 2) 2.c.mc> U35 'ZM.oi Ms,MS" l<4j- 732 1) 2) 1 Ho 7 So. M< (32 Z214 1) 2) lists' ^.MM- 0*M5 23,'44- |53" 2a?- 1) 11*50 2) bi>y& 21 .3o MS' n< l*~ft 1) Mo, Kt* 2) US6 Mo ^o Of> mr 2^4 1) 2) 12. CO 1) ;*T , I1M Temperature (F) Chiller Heat-Traced Line 2_ 7S4 3>Z_. 2A? "82- 253 Meter M4/ MS' HH "MS 13 MM 88 33 H4 32- 3>Z~. 838 87- 83, 38 2s5 "323Z. 2-58 32 3>2 Z-8T 32 tsu <21^ c-tZi Jr'b> MV M3 Ms-" &(Cf MS" 8 MS' Mil MV VM 4H Hw Vacuum (in. Hg) f ( 1 `i f 1 i ....1............ t l f i s \ t I 1 1 i 1 i t i t / / 2) 1) 2) Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production .f ' SbS-35: Mercury by Sorbent Trap - Method 308 ED 001523 00007569-00301 AECOM Plant Name Date HrSD'"tCo Project Number Q^-tOZ^V^. to Condition KlbfA^e-i Location (Source) Run <3^2- Meter ID & Cal Factors /(&hLH& Operator -X2V- /iFC i) 6L?PSorbent Trap IDs Bar. Press, (in. H2O) '3>gi. t>k> Trap Clock Time Volume (L, dry) 1) 0.00 2) \ZZD D.'CD 1) 4,2^ tti5 2) <4,a4 1) 2) (lib Qr^H'h 1) 2) nb( wnu r? ,41 1) IfTi^ 2) tl<to u.itf 1) 2) l/H") 1) .2) ;*Vl} 2) 1V9? -ZZ. 1) 3d.TI Pm> 2) V\RZ~ 1) t 2) u5 1) 2) )3io 3?.U "5L ,4FV 1) i-l 1, 2) I'ilS 1) 44, 2) /3'Zd 1) 2) 1) 2) Comments: Flow Rate (Lpm) Pt5 ,15 n< ,9<r TC 9?5 ."45 *3T i /5> .-as' -45 ,1S ~bS, &> t$//' &Zh?.o) Sorbent Mr^ 2SJ* 12 Z42 P4\ 14-h 71a /53T 1 IM-d lt> ( 224 "2? 2. 242 Z3Z [<4<r Z2) h-h Page Initial Leak Rate Final Leak Rate of 1) &fi 2) i) <^.5Z> 2) @ <Y "Hg @ TjO "Hg "Hg @ ^ "Hg Spike Level 2) Temperature (F) Chiller Heat-Traced Line , Meter 32 32 22 32 Z53 51 cFb Ucf <45 32 26 2> 2_ 32 ZS3 253 52 u<r /Lf (f? a<r c/r i-tC" <4<C 5<r 32 0- 22 -3^ 3z 3Z Zfei Zc5 22.5 2fcZ cz? <5? Q2^ H 5T <5^2..... Vacuum (in. Hg) / 1 1 ( ( 1 1 i 1 1 J / 1 J / / r / / . i 1 2 / 1 / i ' ' / 17cv1906 Sierra Club v. EPA - 6/22 Production SOS-35: Mercury by Sorbent Trap - Metfh ED 001523 00007569-00302 AECOM Plant Name Project Number * to Location (Source) V 2-- Meter ID & Cal Factoi^'^{1H / Sorbent Trap IDs 2)f?LmHzc, Date l-'&OiC Condition #3kni^D Run -^13 3 Operator Bar. Press, (in. H20) 2^. /<9 ' Elevation (relative to Barometer) (ft) Page Initial Leak Rate Final Leak Rate Third Bed \ of 1 1) 0.p0 @ /</ "Hg 2)yO O fC "Hfl i) jp>, o @ (o "Hg 2)..qc?o@ ^ "Hg 1) 2.000 2) Trap Clock Time 1) 2) NSS 1) 2) /vyo 1) 2) 1445 1) 2) /yso 1) 2) 1) 2) /Soo 'D' 2) /$0$ 1) 2) /5Vo i) 2) !S/5 1) 2) l$2o 1) 2) /$z$ 1) 2) /$3o 1) 2) . f$35 1) 2) 1) 2) Volume (L, dry) o 0 H, Hi N.bX /Zoo if. JS. nsr. f$.%3 13. 61 /?. 44 Z3- 3z 13.41 21. oV 21. 1$ 31 31.3io 34. 40 35. / / 3%. 03 SS'.Z (J> Hi. It Nlil 45.1 i 9 4.025 Flow Rate (Lpm) lEM(inFrttjO)- 0.15 Q.15 0.1 5 o,15 e>l s 0.1$ 0.15 o 15 0-15 0.15 o .15 0.15 o. is 0.15 Q. IS 0.1$ o.^5 0.15 o.lS 0.15 O IS 0.1$ 0.13 0.15 /v/ wv 143 m /$/ /S(o /Ni HI 2 $o /(* *% Sorbent Z?5 3'of 2r$ 2lffO 14^ 2Z<% 2(j>o 243 2.95 tf 2hl 24t 223 Temperature (F) Chiller Heat-Traced Line 2i 7(x>i 32 2 $3 3l 266 3l 2(j>io 3Z 2iol 32 2b$ 32 tui 32 2 Gi# 32 26<? 3z 24? 32 26? 32 261 Meter 66 $4 61 65 LT 66 (#9r (pO L4 66 6? m-.... lo 61 1 o 6<T 1l 6 25. 12 Ln iz a it .11. Vacuum (in. Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 6 3 * 3 3 '3 3 3 3 Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production SbS-35: Mercury by Sorbent Trap - Method 308 \ ED 001523 00007569-00303 AECOM Client/Plant: FIELD SAMPLING DATA SHEET Moisture 1 > "3 LL> ii tipi* t. iw* Project #: fe Date: \ - EPA Methods 2 & 4 PAGE OF Operators): S)^K /F<L_ Location: CioXc\c^> : DGM#: AJ^4 Condition: . CF (Yd): tlllzZitu Moisture Run #: 4H@: l fiZlX' Duration (min): Cp: 0.84 PbarCHg): ^0;u tjlw.f.|. Barometer (ft): ^static ("H2O): Initial Leak * {<0.02 fr/min; >10''Hg) Final-Leak (<0.02 ft7min; >run maximum) ' Sr Vac. ("Hg): SW fWT Vac. ("Hg): Source Height (ft); \Oo Duct Width ("): Duct Diameter ("): ^2 Duct Length ("): Comments: ?. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00304 Plant Name Date 2 -iJ1 " / 6-j Page ^ of ( Project Number (pC'SC'XX 9<tT* /C Condition r'Vvw* t Location (Source) X Meter ID & Cal Factors '3z*r> Run | H Operator fuC /C3 i) ol3o9SZ(* Sorbent Trap IDs 2) OL.Z311&9T Bar. Press, (in. H2O) 3 Q, /& Elevation (relative to Barometer) (ft) /Cl . ?7HcJLTMP. Initial Leak Rate Final Leak Rate Third Bed Spike Level l)&&&$> @ XX "Hg 2) <>, ffO0 @ Z.O "Hg 1)0,1)00 @ -j "Hg 2) 0 oto @ "Hg i) 2) fX/A Trap Clock Time Volume (L, dry) Flow Rate (Lpm) ms i) s 2) /55 1) 2) //oo 1) 2) //e'S 1) t //o 2) 1) 2) 11/5 1) 2) l/lo 1) 2) `US 1) H3o 2) 1) 2) 1/35 1) 2) nyo 1) 2) 1/45 1) 2) //So 1) // r5 2) 1) O\W0 0.13 t0OD 0.1*1 /So V.34 4.33 ft. 15 0. =)5 /So Sr. 9H O. 95 *r. 3 d o. 95 /So tl.VT 0.15 /z.h 0.95 /*z /l.ou /?./'*. zt. zt *-`*33 IS. (el 15. 3 S' 0.15 0.95 0.95 0.95 0.I5 0.15 /s^/St? o.I5 19./? 0.15 /Sf 3 3. (0 (*> 33.11 0.1S 0.9S /S<? %9. to 0.15 39. 5/ o.lS f(*l 9/. (m3 0.15 <n <? 0. is m 95. Tl 0,1s 0.15 /HI SXo .Go*/ 50 . {4^ Sorbent ZJY 1^5 2(e>0 13t ZZ<\ lH$. zHo ZCii 233 %ZS Temperature (F) Chiller Heat-Traced Line 33 Z4z 33 z4z 33 14<( 53 24c, 33 24/? 33 Z43 33 IHS 33 142. Z99 33 IHl 33 ZYo S3 23 U Meter 33 33 33 33 3$. 31 3f 39 3<f 39 39 39 39 33 35 3G 39> 3Ce 35 3(fj 35 3U 35 30 Vacuum (in. Hg) 1 2L I z. t z_ 1 z l z ) z f I z ( z. / 2. / z ( z 2) 1) 2) ............ .- Comments: * & l 17cv1906 Sierra Club v. EPA - 6/22 Production **/Y<w 5Mrr AA&rv-itr** At/ <Zsu*ha>ni` Tr>nn - AA*>+h*/4 1/V2 ED 001523 00007569-00305 AECOM Plant Name /"P C 3> Project Number (^(}M D'L'2-Hf'^, \Q Location (Source) C 2-- Meter ID & Cal Factors Date "TL'-' V2> " i ^ Condition 1 Run "d3p-'Z_ Operator ^Py^-A Bar. Press, (in. H20) H>0 .7. <s*c^ * '3&,S` Page Initial Leak Rate Final Leak Rate | of 1) 0.,e-0 <3 "Hg 2) 0.. cm @ "Hg 1) 0 . > @ ^ "Hg 2) o @ "Hg Elevation (relative to Barometer) (ft) Skck Third Bed Spike Level 2) Trap Clock Time Vnliimp (L, dry) Flow Rate (Lpm) JjtKo) Sorbent Temperature (F) Chiller Heat-Traced Line Meter Vacuum (in. Hg) 1) 2) Uio o.om O.dQm <"=K 1L 4 1 U3 yz yU z 3 1) 2) 1142 ..3,s~ lf,( 0 r=? :> ' |S^"/ 'ZgZ. "~7 '^.3 Ztf i Z 3 1) i.o0 1 &D l<r> zyy ^ ,-*7 225=) 1 2) 77 Z_ . 1) . Vb-U, ,X> V3\ 33 % i 2) ..... 3T Of `ht 2 1) vo.^s 'fcf \m 2) n.osr *53 22^ 1 7 1) 2) Z^iS'L to. 9^ t K &> 23- 3T~ l Z 1) 24-Ht ,?eC 2) * 1l> |(/3 33 23C. 2* 1 z~ 1) ft.. 1^6 2) ^ [Se3 '7jg 33 31- 23C 35? 1 z. 1) 3*. 2) 13X0 1) 36 2) .. 3t,p9 IC*> zyr S3 2-3^> ST- 1 Z- m 2,3-y S3 233 34 ( z i) lex. Ttss 33 2) 30j/ci, inz 1) nth a 70 tsM XScj 33 X-xZ 3T- I 2) 43 ,/t^J 1) 2) 210 33 23T 3h '%>ST l z 1) 2) 1) 2) Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production St)S-35; Mercury bv Sorbent Trnn - Mel. ED 001523 00007569-00306 AECOM Plant Name Date 2*" Page \ of j n- yet Number lO Location (Source) O/liaUx*-*-M. '23 Condition Run Initial Leak i) @ H "Hg Rate 2) 0.0 @ "Hg Meter ID & Cal Factors /<&V7,U,'1> Operator / fP-*C . i) OJbHlHft ^ Bar. Press, (in. H20) ^tCrs \ c*$(t Sorbent Trap IDs 2) QL-yL\oifo Elevation (relative to Barometer) (ft) / &> Final Leak 1) & & @ "Hg Rate 2) & t/6 @ 3 "Hg Third Bed 1) Zj>&> ^ Spike Level 2) Trap Clock Time Volume (L, dry) Flow Rate AP/''' (Lpm) jn!W Sorbent 1) 'B&b 2) 1^`iP O; frjrft * ~T\/Ss M 2^i 1) 2) ^4(5^ MSS' 4>t$D tu> 1) 2) .16" lw Z43 1) 2) 14 ^ 13, \&] Temperature (F) Chiller Heat-Traced Line 33 Z^3> 24 > 33 33 ^>3 Meter */? HO HZ. Ho hi *HO Hi Vacuum (in. Hg) l t 2- L ~L i 1) 2) I^GO U.S7- i .iK lCs?] IKK' 7O(kt-c) 0-- <&)_... Ho i ?. 1) 2) mb 'Z&'t ^5 i tS .h< \o Zfl 33 24% <7) i z 1) ^ .03 -7dT 2) l$DD ^ dn 9* Y,L / 3>3> 24-f ..65 I) 2) 0.95- *~Tr.3n J C&o ICpf 33 Zy^ s J/. 5 i) 33.12 O.^ 3f3f 2) |t>U> 3V. o^J e.35 f5f 2?l 33 zyz 39 z 1) 3.5ir o.^jr 2) 15 lb 30?. 1L (9'13 f(al 33 *Y/ 3%- / 3 2........ 2. 1) 2) S'S'.TL. 0.33 |V(U 0.35 14.0 ZHZ. 3 3 zy? 39 ) 3 1) o.qL5 / 2) nq.iy o.3S li&JO ZSo 35 23? 5.y 2. 1) VI-U? 2) yz 3/3 1) 2) 1) , 2) Comments: ' 17cv1906 Sierra Club v. EPA - 6/22 Production SOS-35: Mercury bv Sorbent Tran -a ED 001523 00007569-00307 AECOM Plant Name Date Page of Project Number Location (Source) Condition Run Initial Leak 1) Rate 2) Meter ID & Cal Factors 1) Sorbent Trap IDs 2) Trap Clock Time 1) 0 Volume (L, dry) Operator Bar. Press, (in. H20) Elevation (relative to Barometer) (ft) Flow Rate (Lpm) (in. H20) Sorbent Final Leak 1) Rate 2) TTiird Bed 1) Spike Level 2) Temperature (F) Chiller Heat-Traced Line Meter 2) 1) flPud A 1 0.2J* A t &,1A FfotZ) i o.Zt 2) Z o.M 1 * 24 A 2- O .If 1) 3..a..25 3 -`US' 3 o. 23" 2) H o.l5 4 .tv O.ll 1) 2) 5 o.TU U o.Z% > a2v y o .25 5 0.l<o a. z5 1) 1 0.3/ T >. X T o. 1% 2) S' o.$H -0. $ 1) * 0 3^> t o-32> o. 3f 2) to o.Zl * tp <s>, 2< /o &.3o 1) H o .Jb f2J vl O > ft o. 15 2) it o*. 2 t______ n. ft o. Me 1) 2) FCoulfi 1 0.23 Pjou2 ' V A. 'lA ^ o, Z *? 1) i 0.3i Z O' ^ 2 .is* 2) 3 *.,? / 3 3 O.Zl 1) H **$ 3 H O'tV H O Z5r 2) 5 o.lS * 5 5 o.Zf 1) <t. o-3l u> 4> 0 . lb 2) 2 o.$l i > . lv 4 o.iH 1) * 6.1 r ^ 0-^8 r o. m 2) 1 o. X' ^ Q-Zfr 1 o. ,23 1) 0. 1* ' to .XT- to o.if 2) t( o.Zi i h a, % (1 o. IX> 1) it o>z ? !fl Or ft o. 2) 1) 2) Comments: HXp "Hg "Hg "Hg "Hg Vacuum (in. Hg) ( 17cv1906 Sierra Club v. EPA - 6/22 Production W.r- zt lus..... *tti-35: AAarrjtrv bv Snrhp.nt Trttn - Mathnrf ED 001523 00007569-00308 AECOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 EPA Method 5/202 PAGE OF Client/Plant 'M>CS Project#: jk>4dttA7> tp Date: QZ-Q\ - H*, Operator(s): /iLM^ Location: Condition: Run #: Duration (min): 17- Console#: /\] -4(^? K-Factor; Zt. GZ- CF(Yd): fy.UlB Pbar("Hg): zjjM'H AH@: j y G H Height w.r.t. Barometer (ft): Cp: 0.84 static ("H20): *~* c zM Initial Leak V (<0.02 ft /min; >10''Hg) ft3/min: e> Vac. ("Hg): ( Source Height (ft): (,<o2> Final Leak V (<0.02 ft /min; >run maximum) ft3/min: Vac. ("Hg): Duct Width (" Duct Diameter ("): D-;? Duct Length ("): - Pitot Leak / (>3"H20) Initial +P: tX Final +P: -P: Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat C02 (%/time) % ( Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat C02 (%/time) % ( Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat C02 (%/time) % ( Nozzle D1 (") 0: zgz Nozzle D2 Q S>: r Z^LfZ Nozzle D3 (") Q: 7UD Average Nozzle D ("): ^ ZG2, Sample Point Time Clock Run (min) DGM Volume (ft3) AP C'HiO) AH C'HaO) Source Probe 248 25 Temperature ("F) Filter 248 25 Impinge r Exit 68 CPU Filter 65 85 DGM Inlet DGM Outlet Pump Vac. ("Hg) \Z>Zo O ' _.-Z>G.. NH Z'A (o~A S 7 3 c3q. i .n- )HZ ZAi* 7.<S7 LA A~b> w tZ>Z> +---1h 3 4 7 fa 1 <2 10 (\ \Zf5H A l No ~L 3 4 <r ('p/* A 2 l0 (i G 1 iZ IS 1% ZH zi 'ho 33 3g Zft A? iT IS S 1 SH Oa C?z> bU (A GHO . Cp lmza VM 3 .A (MilH | G44 9 GShi MM &>S~r U fcG \ 1 A' bUQ>t Z> bH-. A (tCfiA 00,1- CH3 , 1 3Z_ ZS?3 TAD A3 VHT- ZST Z<r 1 (0^3 <?t> ZAl <aC -3d *3D ..H \ Z&X Zo H9 Z35 2%o 9-1 t aw , 1>o \co 2&D m az <*> 2-^? ..-Gfe \H7- fSA Zl9 bO gS .i9o 2.SZ-V ZM^ AH 30. oil I4L 7.St AS >C=> (ol~ < <3XGC?T M iC?a* XHA 2.S"l ' A b FT Afr 141 ZHft sy bl ZMA K^Vtcr- S\ b% ,,37 \H So Si oS?- \1< ZST1 SAT Mb !4~0 2^ XAc- H b (*$ *97, \H9 Zso '7CZ. AG (At .<24 \H> zm ZAD qr OM ?<Sh 2So *2>7 H* ZSH Hb PNy^2I imA Z14 ZS'/ H?-> No 69 *>Z>% Hi ZSL ZS\ MA <o 3o_ X i/9 ZSA Z49 lb .33 HZ 2Tb 73^1 Ah bio 9Ft Mb 9S W>cz> fA Ml %A SAi tbA 9b t(&0sXO3-' lr? Id 3o 9> ,7> 3 ' 3 3 3 3 3 7> T/ 3 Q0 3 1 3 TM- 9o My- 9/ 3 ~WT a 1 3 m g 9 97 . x a- 91 9f 9i SA 97 9 7 3 H 1 7 -y - STAi> HS'M 1?. / / ~y > / / _y /|7 COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00309 AZCOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant: PdfS Location: daj #Z- Project#: l0Qijo22H<tr. to Condition: Date: Z-{- / b Run#: t Impinger # Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 0 VCON 0 KO 0 MGS 100 MGS (oOh 350 MGS Final (g) LaO I, Sum Gain (g) Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: CPM Filter Temp Rotameter Reading Stop: Cl: Filter Recovery Container Weights PNR - Acetone Filter CPM Filter Impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: ID#: AV .2 V ID#: ID#: Tare Wt. (g) Tare Wt. (g) Tare Wt. (g) 0.31531- Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00310 AECOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 EPA Method 5/202 PAGE ' OF Client/Plant Project#: ycH&lZu*, ( C> Date: Operator(s): ^W'EiA Location: Condition: Run #: Duration (min): Console#: CF (Yd): (T) Pf^fl AH@: ) Cp: 0.84 K-Factor: -7,. i^TL- Pbar("Hg): Height w.r.t. Barometer (ft): static (UH20): Initial Leak V (<0.02 ft3/min; >10"Hg) ft /min: (jj) Vac. ("Hg): Source Height (ft): Igrfj Duct Diameter ("): Final Leak V (<0.02 ft /min; >run maximum) ft /min: Vac. ("Hg); Duct Width (**): Duct Length ("): COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00311 AECOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant; Location: f^2T Project #: Condition:" VlU^, {Q Date: Run #: Ik. Impinger# Condenser 1 2 3 4 - i Impinger Contents MT Method 4 Moisture Determination Approximate Volume (ml) Configuration>^r;' Initial (g) VCON J MT 0 KO ... MT 0 <&_________ ' Water iqo MGS MGS Silica Gel 350 , MGS Final (g) ' ,.;v ' r _ Gain (g) 'S^Jo . 2 <?2^.6 Sum Purge Train with UHP nitrogen at 14 liters per minute forpne,,hpur prior to sample recovery ' ' . v, -s- ; . v,`^*hj*.VVA''^ - < ' ' ' ; - ' Purge Time CPM Filter Temp Rotameter Reading Start: - ..... --- . - . * - -- Stop: , - A r'% ' Cl: Filter * 'CiSfe. ID#: Hli& * . Tare Wt. (g) ID#: TareWt. (g) ID#: Tare Wt (g) Recovery Container Weights PNR - Acetone Filter CPM Filter impinger & Water Rinse ; ' Acetone and Hexane Rinses . s ' ' <t.;V COMMENTS: Tare (g) Final (g) r' ` Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00312 AECOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 EPA Method 5/202 PAGE OF Client/Plant ^PCS Project#: Q&{0Z24%Ko Date: 2- 2- lu Operators): 7XLa/&LM. Location: O.gXoX^cA'L Condition: Run #: Duration (min): PZ_ Console#: K-Factor. /O - <74 CF (Yd): Pbar( PS): 30 , SO AH@: 1, Cp: 0.84 Height w.r.t. Barometer (ft): static C'H20): 24 Initial Leak V (<0.02 ft /min; >10"Hg) ft3/min: 3 0 Vac. ("Hg): )> Source Height (ft): I o o Duct Diameter ("): Z4-~? Final Leak V (<0.02 ft3/min; >run maximum) ft3/min: p-P Vac. ("Hg): ^ Duct Width ("): Duct Length ("): Pitot Leak V(>3"HzO) Initial +P: -P: vZ Final +P: -P: Nozzle D1 {") 0: Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat CO2 (%/time) % Nozzle D2 Q &: Fyrite/Orsat 02 (%/time) Fyrite/Orsat 02 (%/time) % ( ) Fyrite/Orsat CO2 (%/time) % ( Nozzle D3 (") Q: % ( ) Fyrite/Orsat CO2 (%/time) % ) Average Nozzle D ("): . Z.%0 Sample Point Time Clock Run (min) DGM Volume (ft3) AP (*H20) AH (H20) . Source Probe 248 25 Temperature (F) Filter 248 25 Impinge r Exit sea CPM Filter 68 85 Si lC>30 1-21 < loo ft SC* t,/2* HT ZS5 Z41 (J5 l ^23 -1 t.2_ N2. 2s?_ zs\ 70 3 4-24,5 UZ iM'Z 2S3 zso HZ 5-1 H A. 1 145 Z55 2So HZ c t*L "77.6 ,32. 1. ' 145 ZSI H<r p 15 --\ .0 m zse> H1.. hi- t ft 43l? _?2^_^51 '7m ZSt) 41 (*9- ti ^3,3 m 2SD ( z t;?3<3o - 144 ..2.3^ 2S1 41^ Ctf VO "TS 6. 6 *ZH A 4? W5 ZS3 43 Zo it a> ~=r%K.T. .toZTf- ass' 2&1 4-Z It 33 SroP \sofs .J3.6_ s 1-- -rrt'>XVa- 2s? ~T C ZSZ) ZMArb 43 65 Ar ( ___2L 3 4 4 6 O 74,273" ia "ZS^ Z^i 6fS 54 'm-h.t- a3o u-d HU ZSS 2.4-5 4 l M *544,4 u \ Hf> zm an 4^ 520 45 354c- * V* .3 \ -.1, 1 1`4'S-T Z.&Z ZSZ) H (s, "9-0 4^ 549.-2. \vO 143 233 Zo 5l TSP,0 fis Hfr -2^2* Z45 -/6~ Cs> ) 54 . G* .Z% m3 2sz r> 5 (JO 14 HZ. ZsIt ZZ/ HfT 1 ,Z- /4b" ZC*4 b 63 ~/oo, .f- inr* 9^4 (bCs> H C6 #sS.3. t. O 158~ ZSc 24"?- 4 / 61b it 560 > 1 43^ Z4s 47 270l> II nZ/ 4c, 1 .Tts DGM Inlet DGM Outlet Pump Vac. ("Hg) C*o LZ S'*" 6 Z 3r (JO 63 .<r 4H .s .m C<4 S Cp GS~ G<r --- 6*1 66 6<L. t? ? C.C, CTb f >47- 6f H 65" m 6*4 6S f fer 6*g> 4y 64 67 i 6H 66 6-7 5" 35 66 t3 66 63 Cs> r C 3 1 tr COMMENTS tuc - ||4l 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00313 A3COM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant: 'PCS Location: Cat &? impinger# Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Project#: LoVbZZyfr. /o Condition; Date: -g- 2. - 1 ~ \ ie> Run#: 3 Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 0 VCON 0 KO so/.r 0 MGS 100 MGS i 350 MGS <(92.5 Final (g) w. v 523. V Lg9/- (g> JoZ, 1 Sum Gain (g) Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: CPM Filter Temp Rotameter Reading Stop: Cl: Filter ' Recovery Container Weights PNR - Acetone Filter CPM Filter Impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: ID#: /*HZZ ID#: ID#: Tare Wt. (g) Tare Wt (g) Tare Wt. (g) Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00314 AECOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 ERA Method 5/202 PAGE OF Client/Piant pcs Location: C^pXsju^T 6 Console#: /l3- <,A Project #: Condition: CF(Yd): Q.^^S Date: C>Z <SZ~ l C Run #: AHs /,63> Operators): Duration (min): K-Factor: 3>,4g Pbar("Hg): Height w.r.t. Barometer (ft): Initial Leak S (<0.02 ft /min; >10"Hg) ft/min: Vac. ("Hg): Source Height (ft): Final Leak v' (<0.02 ft3/min; >run maximum) ft3/min:/, / Vac. ("Hg): Duct Width ("): Pitot Leak S (>3"H20) Initial +P: Final +P: -P: Fyrite/Orsat O2 (%/time) % ( Fyrite/Orsat CO2 (%/time) % ( Fyrite/Orsat O2 (%/time) % ( Fyrite/Orsat CO2 (%/time) % ( Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat CO2 (%/time) % ( Sample Point Time Clock Run (min) A * Z 5 A <r lr <2 131#- O 3 I' A & 1? 21 94 lo Z* U VL 36 (hi ---n ----i l 7^--1 3 W 3 42 4 45 4 4? Cf 51 9 4 h II 11. . v/ T% CX> (Jh U& -tfV DGM Volume (ft3) ap CHaO) AH mo) ,32 -L4> Source Probe 248 25 HTf- 2s& TM. CHZ, 2*194.1 *?yh f 32.ZS 1.3 t.i 44- Hr 753 W I 75% ZS2> y Q=*6,z_ ~3o <>25? t .0 uo )M$r 297 13=1 3S4 180 .0 4?\ ,5: -=B5>Z~ .3 ~Sf7 32 t. 0 \ ,0 to Nr 143-. .ZKH 1T4.1 43? 401 A0! 2FST 17R4 *'(e? m,*> .-51 -4?..\. A&b /,> dS ZS'S' Zee --;--;<TAr2 < 32T j'is-6^ ZS4 AQ&.Z .4 IN 1.4 1.3 Hi ?S5" jlT) 2S3 192, sr 3 O' 1.3 *3Z u ,,.^>i l,( /:57> hi|t5T7 2F4 2SS&lo 9t>2s3 ^ 2^, HK 25% `.3| l.o ...1,1. /4p 2S4 zlt H'T /Ft? ^ -37 44 _i4 2^4 9(o, 5<5 Temperature fF) Filter 248 + 25 Impinge rExit S68 CPM Filter 65 85 234 ?sx / 4. 49 ZSi 44 69 DGM Inlet (eAZ J~ a DGM Outlet dii? i** 64 Pump Vac. ("Hg) 4 <2 24% 43 Zst A/4^ 6*3 3^ Uc, f t6> 64 349 arD Z3o Zfso 4r3 H?. 43? &1-. / --<^*TP k? -r- "5^ or=h V, o3 41- 4 Cp3 cl 4 . <2. gt- 3 2q 4/ G>c? 3 f 497 Z9Z) ^// ~9q 6H C=C* z9. Z-j 04 ^ -C=- 2Sd Ai Q& 6B 4 zn 4^ 4 ^ S:| Z3i 4/ 0 Nd -=? 1 qz] 24^ 4 I +7 . ?\ A~L "=2/ 244* 43> ~4/ tq 44 44..... 73 293 aaU 3-2 Lsfi y? 44- U4 4f 277- -z_i 6*7- V (fr iJ Q=b C3 Cs-3 6c 30 (43 4>j4 LaG? is*? ^3- GC 3 w" COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production */ / ED 001523 00007569-00315 A=COM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant: PCS Location: /**/ 4! 2 Impinger # Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Project#: LrOij>ZZLi%'. /O Condition: AlorwA,\ Date: 2-1-Uo Run#:-^- H Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 0 VCON 0 KO W-2 0 MGS 1,5V. 3 100 MGS ioOl.i/ 350 MGS t9S.</ Final (g) 2 L3V.2 f/i.5 Sum Gain (g) Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: CPM Filter Temp Rotameter Reading Stop: " Cl: Filter ,. . : : Recovery Container Weights PNR-Acetone Filter CPM Filter Impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: ID#: mfD 9 ID#: ID#: TareWt, (g) Tare Wt. (g) TareWt, (g) 0.3117J Tare(g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00316 A-3 Calciner No. 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00317 PCS Phosphate Operations - Stack Test Results Test Information Location Product Source Stack ID No Start Date Pollutant Method Calciner No. 3 Single Float Calcined Rock WESP 203 6/9/2015 Particulate 5/202 Production Data Date Time Start Time Finish Feed Rate, Wet, TPH (During Test) Bulk Moisture of Rock (Lab Analyses) Rock Feed Rate Dry, TPH Lbs. Coal/Ton of Dry Feed Coal Feed, TPH Process Weight Rate, TPH Loss On Ignition Production Rate During Test, TPH Product 6/9/2015 13:16 14:36 70.0 10.15% 62.9 54.62 1.72 64.6 6.41% 58.9 Test Parameters/Conditions Time of Start Avg Stack Temperature oF Stack Wet Bulb Temperature oF S.V.P. Vapor Pressure Barometric Pressure, in. Hg Stack Static Pressure, in. H20 Stack Pressure, in Hg Stack Diameter, inches Stack Area, ft2 Nozzle Diameter, inches Nozzle Area, ft2 Pitot Tube Coefficient Sampling Time, minutes Dry Molecular Wt Stk Gas Run 1 13:16 157 157 8.981 8.981 29.80 -0.25 29.78 72 28.27 0.2897 0.00046 0.84 72 29.000 Stack Gas Flow Rate Calculations Total water collected, grams Increase of silica gel, grams Gas Volume, DSCF Sample Gas Volume % Moisture, Bws by Collection % Moisture, Bws By Vapor Pressure Wet Molecular Wt of Stk Gas Stack Velocity, ft/sec Stack Flow Rate, ACFM Stack Flow Rate, SCFM Stack Flow Rate, DSCFM Isokinetic Sampling Rate 424.54 11.87 40.612 61.189 33.63% 30.16% 25.68 33.14 56,220 47,859 33,427 104 6/10/2015 09:35 15:28 70.0 10.72% 62.5 54.62 1.71 64.2 6.41% 58.5 Run 3 09:35 159 159 9.424 9.424 30.01 -0.22 29.99 72 28.27 0.2897 0.00046 0.84 72 29.000 548.78 13.64 42.519 69.037 38.41% 31.42% 25.54 32.80 55,638 47,563 32,619 112 Run 4 13:54 160 160 9.652 9.652 30.30 -0.34 30.28 72 28.27 0.2897 0.00046 0.84 72 29.000 513.36 11.30 38.787 63.524 38.94% 31.88% 25.49 32.04 54,358 46,863 31,922 104 Average N/A 159 159 9.352 9.352 30.04 -0.27 30.02 N/A N/A N/A N/A N/A N/A 29.000 495.56 12.27 40.639 64.583 36.99% 31.15% 25.57 32.66 55,405 47,428 32,656 107 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00318 Page 2 Calciner No. 3 06/09/15 Condensable Particulate Determination. Inorganic Fraction Net Sample Weight, grams ( From EnthalpyAnalytical) Condensable Particulate Determination. Organic Fraction Net Sample Weight, grams ( From EnthalpyAnalytical) CPM, mg/DSCF Particulate Determination. Filterable Beaker Tare Weight, grams Beaker Final Weight, grams Tare Filter Weight, grams Final Filter Weight, grams Net Sample Weight, grams Mg Particulate/DSCF Mg Particulate/DSCF, Averaged for Wash Cycle Procedures grams/DSCM Total Particulate Determination PM Emission Rate, Lbs./FIr- Filterable PM Emission Rate, Lbs./FIr - Condensable-Inorganic PM Emission Rate, Lbs./FIr - Condensable-Organic PM Emission Rate, Lbs./FIr-Total Condensable PM Emission Rate, Lbs./FIr - Total Particulate Average Daily PM Emission Rate, Lbs./FIr - Filterable Average Daily PM Emission Rate, Lbs./FIr -Condensible Average Daily PM Emission Rate, Lbs./FIr - Total Particulate PM Emission Rate, grams/dscm PM Emission Rate, grains/dscf Allowable PM Rate, grain/dscf Run 1 0.0079 0.0047 0.3122 126.8178 126.8270 0.6290 0.6310 0.0112 0.2758 0.0097 1.22 0.86 0.52 1.38 2.60 Run 3 0.0059 0.0122 0.4240 176.8216 176.8338 0.6292 0.6306 0.0136 0.3199 0.0113 1.38 0.59 1.24 1.83 3.21 Run 4 0.0047 0.0055 0.2619 179.2970 179.3159 0.6390 0.6727 0.0526 1.3561 0.0479 5.73 0.51 0.60 1.11 6.83 Average N/A N/A N/A N/A N/A N/A N/A N/A 0.6506 0.3507 0.0230 2.78 0.66 0.78 1.44 4.21 1.521 1.580 3.101 0.0124 0.005 0.080 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00319 AICOM Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner#3 Condition Normal Sample Type: Method 13B Run Number: 1 Date: 13-Feb-16 2 13-Feb-16 3 13-Feb-16 Total Sampling Time (min) Corrected Barometric Pressure (in Hg) Absolute Stack Pressure (in H20) Stack Static Pressure (in H20) Average Stack Temperature (F Stack Area (sq in) Actual Meter Volume (cu ft) Average Meter Pressure (in H20) Average Meter Temperature (F Moisture Collected (g) Carbon Dioxide Concentration (%V) Oxygen Concentration (%V) Nitrogen Concentration (%V) Dry Gas Meter Factor (y6) Nozzle Diameter (in) Pitot Constant 72.0 30.16 30.14 -0.24 147.0 4072 41.249 1.27 35.8 353.3 5.7 15.1 79.2 1.0189 0.280 0.84 72.0 30.18 30.16 -0.24 146.6 4072 41.098 1.29 37.5 204.6 5.7 15.1 79.2 1.0189 0.280 0.84 72.0 30.17 30.15 -0.24 151.3 4072 42.404 1.37 40.0 370.3 5.7 15.1 79.2 1.0189 0.280 0.84 Average Sampling Rate (dscfm) Standard Metered Volume (dscf) Standard Metered Volume (dscm) Stack Moisture (%V) Saturated Moisture (%V) Mole Fraction Dry Stack Gas Dry Molecular Weight Wet Molecular Weight Average SORT of Delta P Stack Gas Velocity (fps) Stack Gas Velocity (mps) Volumetric Flow Rate (acfm) Volumetric Flow Rate (acmm) Volumetric Flow Rate (dscfm) Volumetric Flow Rate (dscmm) Percent Isokinetic Post Test Meter QA (yqa) 0.629 45.257 1.282 26.9 23.3 0.767 29.52 26.83 0.60 37.1 11.3 63013 1785 42348 1199 98.2 1.0219 0.625 44.973 1.273 17.7 22.7 0.823 29.52 27.49 0.60 36.6 11.2 62135 1760 44890 1271 92.1 1.0394 0.641 46.156 1.307 27.4 25.7 0.743 29.52 26.56 0.62 38.9 11.9 65960 1868 42636 1207 99.5 1.0404 Average 72.0 30.17 30.15 -0.24 148.3 4072 41.584 1.31 37.8 309.4 5.7 15.1 79.2 1.0189 0.280 0.84 0.631 45.462 1.287 24.0 23.9 0.778 29.52 26.96 0.60 37.6 11.4 63703 1804 43291 1226 96.6 1.0339 Fluoride Emission Rate Calculations Orion 901 Meter Reading, ppm__________ 0.25 Liquid Sample Volume, ml______________ 1000 Sample Aliquot_________________________ 10 Sample Dilution________________________ 10 Total Fluoride, mg______________________ 0.2480 Fluoride Concentration, mg/DSCF_______ 0.0055 Fluoride Emissions, lbs F/hr____________ 0.0307 Rock Feed (WetTPH)__________________ 67.39 Fluoride Emissions, lbs F/Ton Rock Feed 0.0005 0.13 1000 10 10 0.1340 0.0030 0.0177 67.39 0.0003 0.22 1000 10 10 0.2180 0.0047 0.0266 67.39 0.0004 Average N/A N/A N/A N/A 0.2000 0.0044 0.0250 67.4 0.0004 Calciner#3 M13B WetTPH.xIsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run Summary ED 001523 00007569-00320 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method from Hg Test C02 Percent Replicate 1 5.7 Replicate 2 Replicate 3 Average 5.7 Method 13E PCS Phosphate 60402248 Calciner# 2 Normal N-54 1.018S 3.0 30.26 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.2 Nozzle ID (in) 2/13/2016 RLM/WL 1 3.00 1.8639 0.84 100 -0.24 c 72.0 0.28C 0.28G impinger Weights (g) initial Final Net impinger 1 732.2 1033.6 301.4 Impinger 2 771.5 813.3 41X impinger 3 668.8 672.1 3.3 impinger 4 857.8 864.6 6.8 impinger 5 0.0 impinger 6 0.0 impinger 7 ox impinger 8 0.0 Moisture Collected (g) 353.2 Pitot Tube ID 6-4 Saturated Percent Moisture 23.31 Standard Calculated Percent Moisture 26.90 Volume (dsef) isokinetic % 98.2 45.3 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 9:40:00 9:43:00 9:46:00 9:49:00 9:52:00 9:55:00 9:58:00 10:01:00 10:04:00 10:07:00 10:10:00 10:13:00 10:16:00 10:19:00 10:22:00 10:25:00 10:28:00 10:31:00 10:34:00 10:37:00 10:40:00 10:43:00 10:46:00 10:49:00 10:52:00 10:55:00 Dry Gas Meter Reading Vm (ft3) 999.801 1001.470 1003.020 1004.710 1006.230 1007.830 1009.430 1011.180 1014.290 1015.380 1016.480 1018.180 1019.890 1019.890 1021.480 1023.230 1025.150 1027.240 1029.250 1031.190 1033.210 1035.150 1036.980 1038.350 1039.830 1041.050 Velocity Head (AP) (in H20) 0.38 0.32 0.36 0.30 0.30 0.33 0.36 0.40 0.35 0.34 0.33 0.33 0.32 0.40 0.47 0.51 0.51 0.46 0.40 0.40 0.30 0.28 0.25 0.24 Orifice Pressure Diff (AH) (in H20) 1.14 1.15 1.12 1.08 1.08 1.20 1.30 1.40 1.26 1.22 1.18 1.20 1.15 1.40 1.70 1.84 1.84 1.65 1.65 1.40 1.08 1.00 1.00 0.36 Stack Temp Ts (F) 147 139 144 146 140 149 145 144 144 145 151 142 145 151 149 150 154 155 154 153 151 144 147 139 Dry Gas Meter Temperature Tm in Tm out (F) (F) 31 35 32 34 31 33 32 35 36 35 35 35 37 33 37 33 37 33 37 33 37 33 38 34 39 35 39 35 38 34 36 35 40 35 40 35 39 35 40 35 40 35 40 36 40 36 39 36 Calciner #3 M13B_WetTPH.xisx Run 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00321 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method from Hg Test C02 Percent Replicate 1 5.7 Replicate 2 Replicate 3 Average 5.7 Method 13E PCS Phosphate 60402248 Calciner# 2 Normal N-54 1.018S 3.0 30.28 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.2 Nozzle ID (in) 2/13/2016 WL/LM 2 3.00 1.8639 0.84 100 -0.24 c 72.0 0.28C 0.28G impinger Weights (g) initial Final Net impinger 1 767.4 961.8 194.4 Impinger 2 692.0 697.6 5.6 impinger 3 643.9 643.6 -0.3 impinger 4 904.5 909.4 4.9 impinger 5 O.C impinger 6 0.0 impinger 7 O.C impinger 8 O.C Moisture Collected (g) Pitot Tube ED 204.G 6-4 Saturated Percent Moisture 22.72 Standard Calculated Percent Moisture 17.66 Volume (dsef) isokinetic % 92.1 45.0 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 12:20:00 12:23:00 12:26:00 12:29:00 12:32:00 12:35:00 12:38:00 12:41:00 12:44:00 12:47:00 12:50:00 12:53:00 12:56:00 12:59:00 13:02:00 13:05:00 13:08:00 13:11:00 13:14:00 13:17:00 13:20:00 13:23:00 13:26:00 13:29:00 13:32:00 13:35:00 Dry Gas Meter Reading Vm (ft3) 41.751 43.470 45.100 46.840 48.330 50.000 51.580 53.170 54.980 56.530 58.180 59.840 61.435 61.435 63.500 65.460 67.530 69.620 71.580 73.470 75.230 76.920 78.440 80.020 81.450 82.849 Velocity Head (AP) (in H20) 0.37 0.32 0.38 0.30 0.33 0.33 0.29 0.38 0.31 0.32 0.34 0.28 0.53 0.49 0.53 0.53 0.48 0.43 0.36 0.34 0.27 0.29 0.23 0.23 Orifice Pressure Diff (AH) (in H20) 1.33 1.15 1.36 1.08 1.18 1.18 1.04 1.36 1.11 1.15 1.22 1.00 1.90 1.76 1.90 1.90 1.72 1.54 1.29 1.22 0.97 1.04 0.82 0.82 Stack Temp Ts (F) 143 150 141 150 142 138 144 146 141 146 150 147 151 153 153 144 148 152 149 150 147 144 143 147 Dry Gas Meter Temperature Tm in Tm out (F) (F) 35 35 36 35 37 35 38 35 39 35 39 35 39 35 39 35 39 35 39 35 40 36 40 36 39 36 40 36 41 36 41 36 41 36 41 36 41 36 40 36 40 36 40 36 40 36 40 36 Calciner #3 M13B_WetTPH.xisx Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00322 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method from Hg Test C02 Percent Replicate 1 5.7 Replicate 2 Replicate 3 Average 5.7 Method 13E PCS Phosphate 60402248 Calciner# 2 Normal N-54 1.018S 3.0 30.27 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 79.2 Nozzle ID (in) 2/13/2016 RLM/WL 3 3.00 1.8639 0.84 100 -0.24 c 72.0 0.28C 0.28G impinger Weights (g) initial Final Net impinger 1 644.7 874.1 229.4 Impinger 2 763.2 889.2 126.C impinger 3 656.8 663.2 6.4 impinger 4 905.1 913.6 8.5 impinger 5 O.C impinger 6 0.0 impinger 7 O.C impinger 8 O.C Moisture Collected (g) Pitot Tube ID 370.2 6-4 Saturated Percent Moisture 25.74 Standard Calculated Percent Moisture isokinetic % 27.45 99.5 Volume (dsef) 46.2 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 14:31:00 14:34:00 14:37:00 14:40:00 14:43:00 14:46:00 14:49:00 14:52:00 14:55:00 14:58:00 15:01:00 15:04:00 15:07:00 15:10:00 15:13:00 15:16:00 15:19:00 15:22:00 15:25:00 15:28:00 15:31:00 15:34:00 15:37:00 15:40:00 15:43:00 15:46:00 Dry Gas Meter Reading Vm (ft3) 83.600 85.420 87.100 88.760 90.470 91.880 93.700 95.430 97.140 98.820 100.570 102.070 103.887 103.837 105.770 107.610 109.670 111.600 113.700 115.830 117.670 119.450 121.130 122.810 124.340 125.954 Velocity Head (AP) (in H20) 0.47 0.36 0.32 0.36 0.24 0.45 0.37 0.35 0.35 0.37 0.42 0.35 0.52 0.40 0.50 0.45 0.56 0.54 0.39 0.40 0.35 0.25 0.25 0.31 Orifice Pressure Diff (AH) (in H20) 1.58 1.30 1.20 1.30 0.86 1.62 1.33 1.26 1.26 1.33 0.95 1.26 1.80 1.44 1.80 1.62 2.00 1.94 1.40 1.44 1.15 0.90 1.00 1.11 Stack Temp Ts (F) 153 155 157 154 155 155 153 156 151 141 145 150 151 152 152 150 148 148 148 144 151 160 154 149 Dry Gas Meter Temperature Tm in Tm out (F) (F) 39 38 39 40 38 41 42 38 43 38 43 38 42 39 43 39 43 39 43 39 43 39 43 39 41 39 42 39 42 38 42 39 42 38 42 38 42 38 41 38 41 38 41 38 41 37 40 37 Calciner #3 M13B_WetTPH.xisx Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00323 AECONi PCS Phosphate Calciner #3 Mercury Emission Calculations EPA Method 30B Emission Results 02 Correction Basis 3 Run AVERAGE Pollutant: Mercury Total Hg Catch Sample Volume Hg Concentration mg/dscm 0.0524 0.0511 0.0500 0.0512 Hg Concentration ppmV 0.0063 0.0061 0.0060 0.0061 Oxygen % 15.08 15.08 15.08 15.08 Hg Concentration mg/dscm @ 3% 0.161 0.157 0.154 0.157 Flow Rate dscfm 37.692 37.380 37.389 37,487 Calciner _3 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Mercury ED 001523 00007569-00324 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 1 PCS 60402248.1 Calciner #3 Normal -0.27 100 30.05 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5.73 5.7 02 Percent 15.08 N2 Percent 15.1 79.2 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 23.47 23.47 0.765 29.52 26.82 1/30/2016 DM/FC 0.84 C 72.0 4071.5 29.95 29.93 Traverse Point Location B1 2 3 4 5 6 7 8 9 10 11 12 A1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head ( P) (in H20) 0.32 0.36 0.34 0.31 0.27 0.27 0.28 0.29 0.26 0.25 0.23 0.20 0.28 0.29 0.31 0.29 0.28 0.27 0.29 0.29 0.31 0.31 0.31 0.27 Stack Temp Ts (F) 143 143 142 144 145 147 148 149 149 150 151 151 146 150 150 150 149 150 149 148 148 145 145 145 Square Root of P SQRT( P) 0.566 0.600 0.583 0.557 0.520 0.520 0.529 0.539 0.510 0.500 0.480 0.447 0.529 0.539 0.557 0.539 0.529 0.520 0.539 0.539 0.557 0.557 0.557 0.520 Stack Gas Velocity (fps) 35.2 37.3 36.3 34.7 32.4 32.5 33.1 33.7 31.9 31.3 30.0 28.0 33.0 33.7 34.9 33.7 33.1 32.5 33.7 33.7 34.8 34.7 34.7 32.4 Average Stack Average S(ikT Temp P Average Velocity 147.38 0.53 33.39 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 56640 49254 37692 Calciner _3 30B_Updated BP 17cv1906 Sierra Club v. EPA - 6/22 Production R1 ED 001523 00007569-00325 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 2 PCS 60402248.1 Calciner #3 Normal -0.27 100 30.03 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5.73 5.7 02 Percent 15.08 N2 Percent 15.1 79.2 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 22.91 22.91 0.771 29.52 26.88 1/30/2016 DM/FC 0.84 C 72.0 4071.5 29.93 29.91 Traverse Point Location B! 2 3 4 5 6 7 8 9 10 11 12 A1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head ( P) (in H20) 0.32 0.30 0.30 0.32 0.31 0.30 0.27 0.26 0.25 0.25 0.25 0.23 0.27 0.28 0.28 0.27 0.25 0.26 0.27 0.27 0.29 0.30 0.30 0.27 Stack Temp Ts (F) 142 141 145 146 148 148 150 148 150 151 152 151 147 148 148 147 146 146 147 145 144 144 144 143 Square Root of P SQRT( P) 0.566 0.548 0.548 0.566 0.557 0.548 0.520 0.510 0.500 0.500 0.500 0.480 0.520 0.529 0.529 0.520 0.500 0.510 0.520 0.520 0.539 0.548 0.548 0.520 Stack Gas Velocity (fps) 35.2 34.0 34.1 35.3 34.8 34.2 32.5 31.8 31.3 31.3 31.3 30.0 32.4 33.0 33.0 32.4 31.2 31.8 32.4 32.4 33.5 34.1 34.1 32.3 Average Stack Average S(ikT Temp P Average Velocity 146.71 0.53 32.85 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 55735 48488 37380 Calciner _3 30B_Updated BP 17cv1906 Sierra Club v. EPA - 6/22 Production R2 ED 001523 00007569-00326 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 3 PCS 60402248.1 Calciner #3 Normal -0.27 100 30.03 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5.73 5.7 02 Percent 15.08 N2 Percent 15.1 79.2 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 22.34 22.34 0.777 29.52 26.95 1/30/2016 DM/FC 0.84 C 72.0 4071.5 29.93 29.91 Traverse Point Location B1 2 3 4 5 6 7 8 9 10 11 12 A1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head ( P) (in H20) 0.31 0.32 0.30 0.29 0.30 0.28 0.26 0.27 0.25 0.24 0.24 0.22 0.27 0.28 0.27 0.25 0.26 0.26 0.28 0.27 0.30 0.29 0.30 0.27 Stack Temp Ts (F) 141 141 142 143 144 146 149 150 151 151 151 150 147 147 147 147 145 143 143 143 144 144 142 143 Square Root of P SQRT( P) 0.557 0.566 0.548 0.539 0.548 0.529 0.510 0.520 0.500 0.490 0.490 0.469 0.520 0.529 0.520 0.500 0.510 0.510 0.529 0.520 0.548 0.539 0.548 0.520 Stack Gas Velocity (fps) 34.5 35.1 34.0 33.4 34.0 32.9 31.8 32.5 31.3 30.6 30.6 29.3 32.4 33.0 32.4 31.2 31.7 31.7 32.9 32.3 34.0 33.5 34.0 32.3 Average Stack Average S(ikT Temp P Average Velocity 145.58 0.52 32.56 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 55234 48142 37389 Calciner _3 30B_Updated BP 17cv1906 Sierra Club v. EPA - 6/22 Production R3 ED 001523 00007569-00327 AECOM Date 2/12/2016 Plant PCS Phosphate Location Calciner#3 Sample Type 30 B Run Number/Side (A/B) 1 Operator RLM/LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 10 Final Leak Check (L/min (a) "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL304643 29.95 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002494 1.0220 1.0220 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) 0 16:10:00 5 16:15 10 16:20 15 16:25 20 16:30 25 16:35 30 16:40 35 16:45 40 16:50 45 16:55 50 17:00 55 17:05 60 17:10 Digital Gas Meter Reading (L) 0.000 3.63 7.04 10.47 14.18 17.83 21.30 24.70 27.62 30.35 32.57 35.43 38.734 38.734 Mechanical Gas Meter Reading (m3) 38.7340 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) 148 149 153 152 145 152 154 155 154 155 155 158 157 153 Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 265 40 32 260 47 32 264 46 32 276 47 32 228 46 32 234 47 32 276 47 32 272 48 32 270 48 32 260 47 32 248 46 32 235 47 32 241 47 32 256 46 32 Pump Vacuum r Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Target Volume Spike Amount (ng) Comments: 2000 Stack Temp for Run 1A and IB is an average of Runs 2 and 3. Total Volume (L) Mechanical Totalizer 41317.01902 41.317019 Calciner_3 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 1A ED 001523 00007569-00328 A~COM Date 2/12/2016 Plant PCS Phosphate Location Calciner #3 Sample Type Run Number/Side (A/B) 30 B 1 Operator RLM/LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL321218 29.95 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/002 Method 8002663 1.0220 1.0220 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading <L) Mechanical Gas Meter Reading (m3) 16:10:00 0.000 16:15 3.89 16:20 16:25 7.10 11.06 16:30 16:35 16:40 15.35 19.21 22.70 16:45 16:50 25.30 29.10 16:55 31.70 17:00 34.24 17:05 37.38 17:10 40.292 40.292 40.292 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 148 265 41 32 149 260 48 32 153 264 45 32 152 276 45 32 145 228 47 32 152 234 48 32 154 276 48 32 155 272 47 32 154 270 48 32 155 260 48 32 155 248 48 32 158 235 48 32 157 241 48 32 153 256 47 32 Pump Vacuum C Hg) 1 2 2 2 2 2 2 2 2 2 2 2 2 1.92 Target Volume Spike Amount (ng) Comments: Stack Temp for Run 1A and 1B is an average of Runs 2 and 3. Mechanical Totalizer Total Volume (L) 42939.75348 42.9397535 Calciner _3 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production IB ED 001523 00007569-00329 A~COM Date 2/12/2016 Plant PCS Phosphate Location Calciner #3 Sample Type 30 B Run Number/Side (A/B) Operator RLM/LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL30466 29.93 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002494 1.0220 1.0220 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 17:45:00 0.000 5 17:50 3.62 10 17:55 6.93 15 18:00 10.58 20 18:05 14.18 25 18:10 17.71 30 18:15 20.95 35 18:20 24.28 40 18:25 28.23 45 18:30 31.42 50 18:35 34.68 55 18:40 38.46 60 18:45 42.120 42.1200 42.1200 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 156 285 48 34 158 259 48 36 158 258 48 36 150 287 47 36 147 258 48 36 149 295 48 35 148 292 48 35 156 293 48 35 157 255 48 35 157 258 47 34 155 251 47 34 158 292 48 34 157 286 48 34 154 274.54 47.77 34.92 Pump Vacuum C Hg) -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1.00 Target Volume Spike Amount (ng) Comments: 2000 Mechanical Totalizer Total Volume (L) 44776.30319 44.7763032 Calciner _3 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2A ED 001523 00007569-00330 A=COM Date 2/12/2016 Plant PCS Phosphate Location Calciner #3 Sample Type 30 B Run Number/Side (A/B) Operator RLM/LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 14 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL321027 29.93 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002663 1.0220 1.0220 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point A1 TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 17:45:00 17:50 17:55 18:00 18:05 18:10 18:15 18:20 18:25 18:30 18:35 18:40 18:45 0.000 3.640 6.920 10.740 14.060 17.900 21.200 24.890 28.910 32.220 35.600 39.320 42.6800 42.6800 42.6800 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 156 158 158 150 147 149 148 156 157 157 155 158 157 154.3076923 285 259 258 287 258 295 292 293 255 258 251 292 286 274.54 49 49 49 49 48 48 50 50 50 49 49 50 49 49.15 34 36 36 36 36 35 35 35 35 34 34 34 34 34.92 Pump Vacuum (" Hg) -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 45248.15406 45.2481541 Calciner _3 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2B ED 001523 00007569-00331 AECONl Date 2/11/2016 Plant PCS Phosphate Location Calciner #3 Sample Type 30 B Run Number/Side (A/B) Operator DM Location Height 100 Initial Leak Check (L/min @ "Hg) 0.000 19 Final Leak Check (L/min @ "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL304565 29.93 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002494 1.0220 1.0220 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 19:05:00 19:10 19:15 19:20 19:25 19:30 19:35 19:40 19:45 19:50 19:55 20:00 20:05 0.000 7.770 11.270 14.820 18.350 22.130 25.560 29.630 33.230 37.090 41.120 43.890 47.4620 47.4620 47.4620 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 153 263 44 152 261 44 155 249 44 158 239 44 152 232 42 150 238 42 149 231 42 156 238 42 149 281 42 155 285 42 155 286 42 149 277 42 148 259 42 152 257 43 34 260 34 260 34 248 34 237 34 239 34 241 34 243 34 247 34 251 34 249 34 250 34 252 34 248 34 248 Pump Vacuum <" Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Target Volume Spike Amount (ng) 2000 Comments: Mechanical Totalizer Total Volume (L) 50972.90741 50.9729074 Calciner _3 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3A ED 001523 00007569-00332 AECONl Date 2/11/2016 Plant PCS Phosphate Location Cal #3 Stack Sample Type 30 B Run Number/Side (A/B) Operator DM Location Height 100 Initial Leak Check (L/min @ "Hg) 0.000 15 Final Leak Check (L/min @ "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" 4,0) Barometric Pres. (" Hg) OL321450 29.93 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002663 1.022 1.022 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 19:05:00 19:10 19:15 19:20 19:25 19:30 19:35 19:40 19:45 19:50 19:55 20:00 20:05 0.000 8.610 12.250 15.550 19.140 22.870 26.310 30.120 33.360 36.800 40.370 43.710 47.7040 47.7040 47.7040 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 153 152 155 158 152 150 149 156 149 155 155 149 148 152.3846154 263 261 249 239 232 238 231 238 281 285 286 277 259 256.85 48 48 47 43 43 43 43 43 43 45 43 43 43 44.23 34 34 34 34 34 34 34 34 34 34 34 34 34 34.00 260 260 248 237 239 241 243 247 251 249 250 252 248 248.08 Pump Vacuum <" Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1.00 Target Volume Spike Amount (ng) Comments: Mechanical Totalizer Total Volume (L) 51068.56883 51.0685688 Calciner_3 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3B ED 001523 00007569-00333 Test Run 1 STRATA version 3.2.112 02 C02 Begin calculating run averages 02-12-2016 12:05:19 -0.022 -0.226 02-12-2016 12:06:19 -0.079 -0.231 02-12-2016 12:07:18 -0.086 -0.232 02-12-2016 12:08:18 -0.085 -0.235 Pause End Pause 02-12-2016 12:10:18 19.328* 20.466 02-12-2016 12:11:18 19.395* 20.495 02-12-2016 12:12:18 19.398* 20.465 Pause End Pause 02-12-2016 12:13:19 15.291* 13.576 02-12-2016 12:14:19 10.119 9.854 02-12-2016 12:15:19 10.096 9.856 02-12-2016 12:16:19 10.097 9.855 Pause End Pause 02=12=2044--42-f49*48-----Ll~03__ 7--293 02.12 2010.i2r20;10- -t-3r3-9~ " 5.305 Pause End Pause 02-12-2016 12:24:19 18.833 5.717 02-12-2016 12:25:19 19.318* 5.736 02-12-2016 12:26:19 19.692* 5.738 02-12-2016 12:27:18 19.959* 5.730 Pause End Pause oa-*a-aoifi 12:30:18 15.1! 9_. 0 ..il52 02-12-2016 12:31:19 15.085 0.047 02-12-2016 12:32:19 15.083 0.047 02-12-2016 12:33:19 15.082 0.035 02-12-2016 12:34:18 15.079 0.030 Pause End Pause Run Averages 02 C02 % % 02-12-2016 12:34:59 12.667* 6.008 Operator: David Marzee Plant Name: PCS Aurora Location: Calciner #3 Test Run 1 End Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00334 AECOM FIELD SAMPLING DATA SHEET EPA Method 13A/B t PAGE f OF Client/Plant: p/' < Location: Calc, ii 3 DGM#: N-54 K-Factor: Project#: OcH&lMT Condition: CF (Yd): Pbar{"Hg): Date: ,0 3- \ 2 - ZO (L Run #: [ AH@: \ .o'.Sri Height w.r.t. Barometer (ft): Operators): 6k\l/ w i- Duration (min); 'Z-- Cp: 0.84 Pstatic ( HjO): ~ . X4 Initial Leak v'- (<0.02 ft /min; >1Q"Hg) Q. f Q ft3/min: Qct> Vac. ("Hg): \ 2* Source Height (ft): (00 Duct Diameter ("): Final Leak V (<0.02 ft3/min; >max vacuum) ft3/min: $.0 Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak V (>3"H20) +P ("H20) -P("H20): Nozzle D1 (") 0: Probe & Pitot ID: Nozzle D2 (") 0: Nozzle D3 (") 0: Average Nozzle D ("): , D SPamoinptle Time Clock (Rmuinn) VDolGumMe (ft3) ' Temperature ("F} m&oP ) ("HAHjO) f Source 2P4r8oib2e5 Filter 24825 ImpE<i6xn8igt er DInGleMt DGM Outlet PVuamc.p C'Hg) l M4t 7 -Q TW. % u*t VH> 3 \ \ 2 7 TTi |45 i 3^f 3 s ?y^ 3M { 3 L tyi 3,62. w Di Hh 31 Is < <a n 1 3-1 .. >r.*>s> . iib \ ,oy l C3 li t.?. 3 5 -4M7- 7C 3 f 1. 4 4 q T l M 12 1 o*^ W i 7. K t<* a,43 21 '& J l. 2- ;> its.. ,4 44 *4*5 V HA\ 7.3 ; ..1" 30 i 4 f H % 3? 34 rimsm > t* > > i mr C " ---- M V^l- ,, 33 U'X im LIU m *32 ___U3 iv|J 1^7 3 ;3 t .li . TS* i? r JJ / / J-t4 r ' A .'*---*r* 3 T - 4^ T1 ZZ It 31 I 3 __3^5) T ^ZiTi :?s 2 Tt 3T* >s ? > H S I. "f J 3 XI ih <71 4 . m2 k 1-3 IHT 3 2 s, IS ..si i,t | SO i? tS 3s J s tsL l .yj m 445 tf 1i - i4Jf /4t, i. JV4- x < aHt i. s 2-1 3< .IS c -2 i 51 23 M 3{? 3/<P>"1 3V3U *28 33 ? ci * > % H4 he J 4> pSf 13<f >4 4& 1 > 3 /__ / j? <M# y ? M0 ? 'Ll U 33S 3 T3 y 3S ...5 3 D ?s 3 L( > 5 3P ...r y7 V COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production # ED 001523 00007569-00335 AECOM Client/Plant: PC^ Location: f'a/ ^ Impinger# ' Impinger Contents 1 DI H20 2 DI H20 3 Empty 4 Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 13A/B Project#: ^0^022^^ /0 Condition: pJprM&Jk Date: \ z~ \y Run#:g Method 4 Moisture Determination Approximate Volume (ml) Configuration initial (g) Final (g) Gain (g) 100 MOD 132.1 /0 S3, U> 100 GS 111. 6 in 3,3 -- MOD (*(olr. r felz. 1 _ -- MOD Smi Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Di H20 Rinse) COMMENTS: Tare (g) - | -- . " . 1r Final (g) Gain (g) fJ4 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00336 A-COM FIELD SAMPLING DATASHEET EPA Method 13A/B PAGE jL___ OF / Client/Plant: S Project#: Date: Operators): 11// </*? Location: (00/_ **3 DGM#: Condition: /%/<? ,'> .'/i / CF (Yd): A$/i f Run #: AH Duration (min): Cp: 0.84 K-Factor: 31 (% Q PbarC'Hg): -Joasr Height w.r.t. Barometer (ft): Initial Leak (<0.02 ft /min; >10"Hg) ft3/min: 9 Vac. ("Hg); /& Source Height (ft): |OQ Duct Diameter ("): T^L_ Final Leak V (<o.Q2 ft /min; >max vacuum) ft3/min; Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak (>3"H20) +P fH20) P ("H20): Nozzle D1 (") 0: Probe & Pitot ID: Nozzle D2 (") 0; Nozzle D3 (") : Average Nozzle D ("): 4 1/9? Sample Point Aid Time Clock Run (min) DGM Vo(lfut3m) e P ("H20) AH C'H20) Source c? -*WWi ,r? /. ? T /?? 3 0/3.. 99 '(3^- /so 3 0H<y\/O 77/ H 1 a 3 ~0 uttS /So f .> 3 3 J/43L 6 8 Xti'fa.eo 03 3 A/$ /3$ 7 jS-- 0</.g ,3? 7 jyy Cf w >1 M i x 3 H s L y 40 A 36 yv n y * % i. , 3p. /'/f // /Y6- 30 OfgJg ? i A.JA />> ~?3 Wo i/yf 34 O&hVtt - ott, yyf , sr. A 45/ 34` * w /y& 4 90 <PMM tfi /S3 Y9 .y? / 37 ?&>*/* 43 076 ^ , 90. , 3 A 70, /?$ /, (V /sk Jl44L <$73'VO , 36 y,L*; /V/ 1 r s'? 07S/A7 W /`pi /Sr? a f)7/Pv9o t -) *y. ` 97 /W 1 63? 0703/6 /Pe>*f /w n o%~&Ap Q <<?%/, Vir -< ip /??/ 'ip o&a.g* , 0 .1/3 - (s iV7 Probe 248+25 c Temperature (F) Rlter 24825 ' Imptnger Exit 68 DGM Inlet ?r DGM Outlet 3.S Pump Vac. ("Hg) 3Q> 3 3<r 30 ...?7 .. 3<T' Q ? / 30 3 <T 3/ T 1 o 3 r 1*7 3S a J/ 31 30 3 ?/ ?/0 l 3/*i/ 3S /O ? 3r o 3j 33 .JRjL 3/ o--_m_1 _-- '3 V o Vr? VO 3 3> ? 30 3 3s J3 3 .3 w 3A S 9/ _;?3 V/ _ / _^3.. 9/ 34 ? s < 3V < 3< / 3D Vo IS 301 fr? 30 Oo 3( VO ?r< O' 3^ 30 .. i 7 1 # 33 7 - COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production V ED 001523 00007569-00337 AECOM Client/Plant: fC5 Location: #3 Impinger# 1 2 3 4 Impinger Contents Dl H20 Dl H20 Empty Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 100 MOD 100 GS M2. 0 -- MOD M3. 9 -- MOD METHOD 13A/B Final (g) Ju. V Gain (g) Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dt H20 Rinse) COMMENTS: 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00338 AICOM FIELD SAMPLING DATA SHEET I EPA Method 13A/B j PAGE / OF / Client/Plant: ftl 5 LocationC^lc:. Project #: (gC^p 22A? Condition: O e ct,wvv Date: 9~- IS 0014 Run#: ^ Operators): jM /uOL_ Duration (min): 7jL ^ PGM#: _<SH CF (Yd): (t Q\<s<=i PbarC'Hg): pVlf" AH@: Height w.r.t. Barometer (ft): Cp: 0.84 Pstatic ( H2O): ,24 Initial Leak ** {<0.02 ft /min; >10"Hg) .Jr/min: /).? Vac. ("Hg): IZ Source Height (ft): i-ob Final Leak V (<0.02 ft3/min; >max vacuum) ft3/min: tQfi' j'Vac, ("Hg): / iJf Duct Width ("): Duct Diameter ("): q-'Q Duct Length ("); Pitot Leak V (>3"H20) +P ("HzO): O . O P ("H20): G . O Nozzle D1 (") 0: Probe & Pitot ID: Nozzle D2 (") 0: Nozzle D3 (") : Sample Point Time Clock Run (min) DGM Volume (ft3) ("HAzPO) ("HAzHO) Source Probe 24825 a / 5 oO OH .ZOO c.ai \S'\ i "ZS n. 4X f. 3L? . is *5 h , t DO ..- Si 1 0 T_ 1 O' T* 3 2 l UM 5 IZ Mte, H7- 4 *jtii 15 5 Ls> 15 __ H3/ t, h> 2S- t ss 7 15 qS.TF-'O <,11 i.35 \<% 2a 035 i <i 2. is. t5b |t> ZM M3. \ M .....,35 z> 1.33 15 V \H1 1 {j (1 tZ l SO'-?' t.S7 35 tel * 5*7- 1.M2,35' > izic> 145 155^ 30 i .;T>- _ io 4 - #'> Z,, 41 R> / tS 1 W 4, 3, 4 7 ______ I ios-43 v4/1 3 t.(2 M5 W5D l.<5 [S\ 4r 151 H 1 is j oct. t m5 \ ttZ 137> ...... S' Z * sz 74 e> lM5 s i 54 n xZu Um im _LH9 '7 ______SI M -7'7 'USjT'Z If & -*Z 1 n * 47 5. 4 \ MWl V -..I 2 {j>5 l (X * MH & 35 } .15 LSI l, I'D _____ L 3 T| >m,3i 0 a.^i U 11 i> RJi tZJUB'l t 7 5 1 ' \sM- l "2^ 4 1 '3| \M hrLj _ t ~S--c~?vrx.r 49- - I , 2. __ S, Vt,<Vc Average Nozzle D ("): t Temperature (F) Filter 248+25 Impinger Exit see DGM Inlet DGM Outlet Pump Vac. ("Hg) 7*0, ?A. 3 S 'Z-7 -2 p 7H M Z> 52-Si I M r-> --- l\-----Hr 1 \ 5 \ 2 ?? ..MO 4\ c-it7 M) H \ Ho 43 .? g*47 5*7 ----^----43 S7al/ <5V ----l^----4l SA] 1 43 --- --1----1 4 H "2> H 3 3C7-'----- 32> 77. 3 T "3-7 7<? 33.. 3A 3.^1 _ w m s Ml 3h 5 M 7 Hi ' a. M? 3<3T >7- H'7 ,3V 9_. 14-T 4 ) Hi <? M < ?? ^-1 t C- M Z> Z3 p - COMMENTS ^ SV fZ ~3P tV*?U ! IUhJ- . jt Arvcto-,_____________ ___________________\ 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00339 AECOM Client/Piant; pcS Location: da! Impinger# 1 2 3 4 impinger Contents Dl HzO Dl H20 Empty Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 13A/B Project #: i0Qi/oZZ V T, /O Condition: /v^o/vmaI Date: t- n - Ita Run #: 2, Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD 100 GS ^ W.l L -- MOD r bt>3, Z - MOD -fSrtr-J?oS- 1 & Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dl H2b Rinse) COMMENTS: Gain (g)` 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00340 A~COM 17cv1906 Sierra Club v. EPA - 6/22 Production ED 00169^ nnnn7^Ra_nrv3/M AZCOM Plant Name Project Number Location (Source) ^ k5 "^TTTTT^T Meter ID & Cal Factors y 1/ " - -A *- . j' * IT" soroent i rap Ids < (2) . l l Date ) i' `i. t Condition Duct D V ! Run 7 ^ Operator XU,l _ I. j} Bar . Press, (m. H20) i Elevation (lelative to Barometer) (ft) Trap CiocxTime ' Volume (L, dry) 1) 2j X ! 2) 1) \~>UC ** V ' .J f 2) i _! ./ c i ?) 1 i) 1 2) 1 _ i; i(.X /' [ 2) nr ?) i) t; 2) 1) S 2) S ( & s. 1 I 2) l) T 2) i) 2) ! i) 2) 1) .J / ` \ \\,`~J([ ' y f 0 ; -* T ' T ; S *> V 1 ' K |y, ^V 3* tv- ' <v 1 M j'? / */>. "7 ;j i i ....# ... - j- I ....'' > ^ ( -74 7 7 n i .. W j-Jj ^ l 77.. ' V ,, . ' T. . t 'X \ , , `L. '"'Vs -IX, How Rate (Ipm) TM. " V 'j AP (in. H-O) , / ` X (' *g i7,J * , 6 /S i > (j 1 * f *} 0 i ? . . 4 --7>cu o ' . * .( i > 1 , 1 1 \ J J , ! /Ol ,7 f ___ __________! . i x"' X- 1 y; 4 , S J ,, / .^5 f, 'l ; I| v) | 'i^ysxxj , a '.D2 V Sorbent ' / . pf <*" , XJ 'Ly c! / s0 wy ` > r^r * n r^Cy L-X> o . L J Hi ,-j. "7 ) "I / ' ' Cc .. . L*j> fj a <i :.^r ' .... t?'\ S " :i V Page / of Initial Leak Rate Final Leak Rate 1) l' ,, 2) {}%. y 1) 2) X. 7 / | @ iO "Hg @ /"Hg @ "Hg @7 "Hg Third Bed 1) Spike Level 2) Tempera ture (F) Chiller ,t0mKt i XI * ii Heat-Traced Line ~ 7 / ' ^ Meter ^V^~~ Vacuum (in. Hg) J - 1 '> '.X v ^ - " - ( ..T wTv / 7 y .2 -V ....... ' v y f ' y? "'S',* / * X T t y- i t/r( 1 f 1 . ' y #i v y t "-Lt ! y r l : ~ f .-y r - . /1 V 4 y b. - } / ' ' ,L r vh y L ' c.,'7 ' | X f ? l- x - ' .yf f J _ f \ 1 \ ** ' S/-' - - - - vV,`"rAJTj -- i 2) i) 2) - rHC--omments: 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00342 AZCOM Trap Clock Time Volume (L, dry) Flow Rate (Lpm) 1) 2) 1) 2) t) 2) i) ti 2> i) 2) 1) ?) 1) I 2) L ,}^ i i) j jj) Lii , 1........... !-^i Ci Ptf) <' , " ' -, i. rf% i. A 11 /y "t, V r'i ip . 1A ` V,T t " ' , ...... *_____________ > .1 - \ .... f'/ ... -M ______ \1CI\Ti f;1L,| * /"Vi /'Tf'S 1 'i% " 5 w. ****- j a*7 / i, fs- cIL / \ j ,7 ^ .. ,..^v......r.... ...... | st'*nr . r < ' .' J 7J *:K 7< i -J i) pEI j-. rv | i) j\ ( i /V'l CA ' ! 2) lyU'~` V --^..-A_it-- ! 1) , /"*? k / .... \..r , 4(> ,, I f A **% 3\ I " i 1 ! i) 2) 1} 2) tps .-(In. H30) i ,<- 1 OL*. X l *' i iCx^ ' ' .. , / ^ rsvs' V / f~~-MS*-" 1 ">3 I'/ l/jf Sorbent ; ; '* ^^7 / - I / a Z </.31, i *' S*} yy Cyf .... .. fl fj / .A"V ** ' " "" ' > :.A....'C : 'G'l. Temperature (F) Chiller Heat-Traced tine " / .... "v ... -' 31! <L_Jc3^ Meter '' iJ f ' " r *> A -? Vacuum (in. Hg) j S H 0 f t f \-4O | "'v .? ... ^ ^1 / l ^'2 / ^2 /**" 'AlJ J s >. )-v; C_--3 i '"J.... 1 / * U 'k... S' rS 'IIW. ,f r A A'') aTM. .' l a-AJ ^4'3 i "i /; 'J a. a 'i ~ f J ' I I - i .. V'-'". s-fIL, S, ---------------------- --_ | pi-------------------- c/ ^ ^, " /ilk 3 ` J* --iz_i_-------------- t1 i ..sJ A~'' f 17cv1906 Sierra Club v. EPA - 6/22 Production SBS-35: Mercury bv Sorbent Trao ~ Method 308 ED 001523 00007569-00343 A-4 Calciner No. 4 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00344 PCS Phosphate Operations - Stack Test Results Test Information Location Product Source Stack ID No_____ Start PaxPollutant Method ______ CalcinerNo. 4______ Single Float Calcined Rock WESP 204 _________ 2/3/2016_________ Particulate 5/202 Production Data Date_____________________________________ Feed Rate, Wet, TPH (During Test)_______ Bulk Moisture of Rock (Lab Analyses) Rock Feed Rate Dry, TPH________________ Lbs. Coal/Ton of Dry Feed Coal Feed, TPH__________________________ Process Weight Rate, TPH_______________ Loss On Ignition__________________________ Production Rate During Test, TPH Product 2/3/2016 63.6 12.30% 55.8 40.22 1.12 56.9 3.36% 53.9 Test Parameters/Conditions Green indicates hard entry 2/3/2016 63.6 12.30% 55.8 40.22 1.12 56.9 3.36% 53.9 2/9/2016 67.4 13.00% 58.6 40.22 1.18 59.8 3.36% 56.7 Stack Gas Flow Rate Calculations Stack Flow Rate, DSCFM______________________ Sample Volume (DSCF)_______________________ Condensable Particulate Determination, Inorganic Fraction |Net Sample Weight, mg Condensable Particulate Determination, Organic Fraction Net Sample Weight, mg Train Blank, mg CPM, mg/DSCF Particulate Determination, Filterable Beaker Final Weight, mg___________________________________ Final Filter Weight, mg_____________________________________ Net Sample Weight, mg___________________________________ Mg Particulate/DSCF______________________________________ Mg Particulate/DSCF, Averaged for Wash Cycle Procedures grams/DSCM Total Particulate Determination PM Emission Rate, Lbs./Hr - Filterable PM Emission Rate, Lbs./Hr - Condensable-Inorganic PM Emission Rate, Lbs./Hr - Condensable-Organic PM Emission Rate, Lbs./Hr-Total Condensable (corrected with train blank) PM Emission Rate, Lbs./Hr - Total Particulate Average Daily PM Emission Rate, Lbs./Hr - Filterable Average Daily PM Emission Rate, Lbs./Hr-Condensible Average Daily PM Emission Rate, Lbs./Hr - Total Particulate PM Emission Rate, Lbs./Day PM Emission Rate, grams/dscm PM Emission Rate, grains/dscf Allowable PM Rate, grain/dscf 36,550 38.310 Run 1 14.81 3.45 0.4244 0.61 5.20 5.81 0.1517 0.73 1.87 0.44 2.05 2.79 36,726 38.024 Run 2 20.64 11.23 2.60 0.7856 1.90 41.46 43.36 1.1403 5.54 2.64 1.43 3.82 9.36 40,574 41.244 37,950 39.193 Run 3 7.06 Average N/A 1.04 0.1479 1.36 3.53 4.89 0.1186 0.64 0.92 0.14 0.79 1.43 N/A N/A 0.4526 N/A N/A N/A 0.4702 0.1854 0.0166 2.30 1.81 0.67 2.22 4.52 0.928 1.543 2.470 59.283 0.0065 0.003 0.080 Calciner4_Prod data calc-Updated 3.14 17cv1906 Sierra Club v. EPA - 6/22 Production Top ED 001523 00007569-00345 Data For Avg Daily Emission Rate Calculation (inputs in red cells only) Total PM Ibs/hr Total PM Ibs/hr Run with wash (enter cell address) (Esi Ave Hrs washing per 24 Hrs (S) Run Time, Hours Wash Time during test in hours (A) Run Time During test not Washing in hours (B) Total PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) Filterable PM Ibs/hr Wash Time during test in hours (A) Run Time During test not Washing in hours (B) Filterable PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) Condensible PM Ibs/hr Wash Time during test in hours (A) Run Time During test not Washing in hours (B) Condensible PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) PM Emission rate g/dscm Filterable PM g/dscm Run with wash (enter cell address) (Es) Ave Hrs washing per 24 Hrs (S) Run Time, Hours Wash Time durinq test in hours (A) Run Time During test not Washing in hours (B) Filterable PM g/dscm Avg of two non-wash runs (enter cell addresses)(EN) PM Emission rate mg/dscf Filterable PM mg/dscf Run with wash (enter cell address) (Es) Ave Hrs washing per 24 Hrs (S) Run Time, Hours Wash Time durinq test in hours (A) Run Time During test not Washing in hours (B) Filterable PM mg/dscf Avg of two non-wash runs (enter cell addresses)(EN) 'Water Wash Performed on Run 2 (R=24hrs) Eavg= EsS (A+B)/AR) + E(((R-S)/R)-(BS/AR)) 0.04 0.42 1.20 0.42 0.78 0.00 1.14 0.42 1.20 0.42 0.78 0.14 Calciner4_Prod data calc-Updated 3.14 17cv1906 Sierra Club v. EPA - 6/22 Production Top ED 001523 00007569-00346 Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner#4 Condition Normal Sample Type: Method 5/202 Run Number: Date: 1 3-Feb-16 2 3-Feb-16 3 9-Feb-16 Total Sampling Time (min) 72.0 72.0 72.0 Corrected Barometric Pressure (in Hg) 30.01 29.98 29.59 Absolute Stack Pressure (in H20) 29.99 29.96 29.57 Stack Static Pressure (in H20) -0.26 -0.24 -0.24 Average Stack Temperature (F) 151.2 150.8 145.0 Stack Area (sq in) 4072 4072 4072 Actual Meter Volume (cu ft) 38.685 38.399 39.502 Average Meter Pressure (in H20) 0.98 0.95 1.06 Average Meter Temperature (F) Moisture Collected (g) 86.2 299.3 85.6 293.7 50.9 233.1 Carbon Dioxide Concentration (%V) 6.0 6.0 6.0 Oxygen Concentration (%V) 15.1 15.1 15.1 Nitrogen Concentration (%V) 78.9 78.9 78.9 Dry Gas Meter Factor (JG) 1.0189 1.0189 1.0189 Nozzle Diameter (in) Pitot Constant 0.269 0.84 0.269 0.84 0.269 0.84 Average Sampling Rate (dscfm) 0.532 0.528 0.573 Standard Metered Volume (dscf) Standard Metered Volume (dscm) Stack Moisture (%V) 38.310 1.085 26.9 38.024 1.077 26.7 41.244 1.168 21.0 Saturated Moisture (%V) Mole Fraction Dry Stack Gas 25.9 0.741 25.3 0.747 22.6 0.790 Dry Molecular Weight Wet Molecular Weight 29.56 26.57 29.56 26.64 29.56 27.13 Average SORT of Delta P Stack Gas Velocity (fps) 0.53 33.6 0.53 33.5 0.56 35.1 Stack Gas Velocity (mps) Volumetric Flow Rate (acfm) 10.2 56940 10.2 56766 10.7 59572 Volumetric Flow Rate (acmm) 1613 1608 1687 Volumetric Flow Rate (dscfm) 36550 36726 40574 Volumetric Flow Rate (dscmm) 1035 1040 1149 Percent Isokinetic Post Test Meter QA (Jqa) 104.4 1.0142 103.1 1.0080 101.5 1.0030 Average 72.0 29.86 29.84 -0.25 149.0 4072 38.862 0.99 74.3 275.4 6.0 15.1 78.9 1.0189 0.269 0.84 0.544 39.192 1.110 24.9 24.6 0.759 29.56 26.78 0.54 34.0 10.4 57759 1636 37950 1075 103.0 1.0084 Calciner#4M5 202 17cv1906 Sierra Club v. EPA - 6/22 Production Run Summary ED 001523 00007569-00347 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (Jd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data Replicate 1 C02 Percent 6.0 Replicate 2 Replicate 3 Average 6.0 Method 5/202 PCS Phosphate 60402248 Caiciner#4 Normal N-55 1.0189 3.0 30.11 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter' H@ Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 78.9 || Nozzle ID (In) 2/3/2016 DM/RLM 1 3.47 1.8639 0.84 100 -0.26 c 72.0 0.269 Impinger Weights (g) Initial Final Net Impinger 1 485.3 766.5 281.2 Impinger 2 547.5 547.3 -0.2 Impinger 3 707.2 713.0 5.8 Impinger 4 Impinger 5 888.9 901.4 12.5 0.0 Impinger 6 0.0 Impinger 7 0.0 Impinger 8 0.0 Moisture Collected (g) Pitot Tube ID 299.3 8-4 Saturated Percent Moisture 25.87 Standard Calculated Percent Moisture 26.92 Volume (dscf) Isokinetic % 104.4 38.3 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 10:02:00 10:05:00 10:08:00 10:11:00 10:14:00 10:17:00 10:20:00 10:23:00 10:26:00 10:29:00 10:32:00 10:35:00 10:38:00 10:43:00 10:46:00 10:49:00 10:52:00 10:55:00 10:58:00 11:01:00 11:04:00 11:07:00 11:10:00 11:13:00 11:16:00 11:19:00 Dry Gas Meter Reading Vm (ft3) 859.691 861.300 862.900 864.500 866.200 867.800 869.400 870.900 872.300 874.000 875.600 877.300 879.122 879.275 880.800 882.400 884.100 885.700 887.300 888.900 890.600 892.100 893.800 895.400 896.900 898.529 Velocity Head CP) (in H20) 0.30 0.27 0.27 0.38 0.25 0.27 0.23 0.27 0.30 0.32 0.35 0.36 0.30 0.28 0.28 0.27 0.28 0.26 0.29 0.27 0.27 0.27 0.27 0.25 Orifice Pressure Diff C H) (in H20) 1.00 0.94 0.94 1.30 0.86 0.94 0.80 0.80 1.00 1.10 1.20 1.20 1.00 0.97 0.97 0.94 0.97 0.90 1.00 0.94 0.94 0.94 0.94 0.87 Stack Temp Ts (F) 144 151 154 154 153 150 152 153 151 151 146 154 152 145 152 146 156 153 151 145 153 152 155 155 Dry Gas Meter Temperature Tm in Tm out (F) (F) 82 82 84 82 85 82 86 83 87 83 88 83 88 84 89 84 89 84 90 85 90 85 90 85 88 85 89 85 89 85 89 85 89 85 89 85 89 85 89 85 89 85 89 85 89 85 89 85 Ca{ciner#4M5 202 Run 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00348 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (Jd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data Replicate 1 C02 Percent 6.0 Replicate 2 Replicate 3 Average 6.0 Method 5/202 PCS Phosphate 60402248 Caiciner#4 Normal N-55 1.0189 3.0 30.08 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter' H@ Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 78.9 || Nozzle ID (In) 2/3/2016 DM/RLM 2 3.30 1.8639 0.84 100 -0.24 c 72.0 0.269 0.269 0.269 0.269 Impinger Weights (g) Initial Final Net Impinger 1 503.1 769.2 266.1 Impinger 2 Impinger 3 594.1 691.0 594.3 703.7 0.2 12.7 Impinger 4 Impinger 5 901.8 916.5 14.7 0.0 Impinger 6 0.0 Impinger 7 0.0 Impinger 8 0.0 Moisture Collected (g) Pitot Tube ID 293.7 8-4 Saturated Percent Moisture 25.27 Standard Calculated Percent Moisture Isokinetic % 26.70 103.1 Volume (dscf) 38.0 Traverse Point Location B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 12:30:00 12:33:00 12:36:00 12:39:00 12:42:00 12:45:00 12:48:00 12:51:00 12:54:00 12:57:00 13:00:00 13:03:00 13:06:00 13:43:00 13:46:00 13:49:00 13:52:00 13:55:00 13:58:00 14:01:00 14:04:00 14:07:00 14:10:00 14:13:00 14:16:00 14:19:00 Dry Gas Meter Reading Vm (ft3) 901.267 902.850 904.500 906.100 907.800 909.250 910.700 912.450 914.100 915.850 917.500 919.000 920.614 920.660 922.300 923.900 925.400 927.000 928.650 930.200 931.800 933.400 934.950 936.500 938.150 939.712 Velocity Head CP) (in H20) 0.28 0.30 0.26 0.30 0.24 0.25 0.37 0.32 0.37 0.27 0.29 0.27 0.29 0.27 0.29 0.27 0.28 0.25 0.29 0.27 0.26 0.30 0.27 0.27 Orifice Pressure Diff ('H) (in H20) 0.98 1.00 0.90 1.00 0.83 0.87 1.20 1.10 1.20 0.89 0.96 0.89 0.96 0.89 0.96 0.89 0.98 0.83 0.96 0.89 0.86 0.99 0.89 0.89 Stack Temp Ts (F) 151 154 150 145 152 151 154 146 152 146 148 148 150 151 154 150 155 154 145 149 153 154 155 151 Dry Gas Meter Temperature Tm in Tm out (F) (F) 85 83 87 83 87 83 88 83 88 84 88 84 89 84 89 84 89 84 89 84 89 84 89 84 85 84 85 84 86 84 87 84 87 83 87 84 88 84 88 84 88 84 88 84 88 84 87 83 Ca{ciner#4M5 202 Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00349 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (Jd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data Replicate 1 C02 Percent 6.0 Replicate 2 Replicate 3 Average 6.0 Method 5/202 PCS Phosphate 60402248 Caiciner#4 Normal N-55 1.0189 3.0 29.69 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter' H@ Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 78.9 || Nozzle ID (In) 2/9/2016 DM/RLM 3 3.30 1.8639 0.84 100 -0.24 c 72.0 0.264 0.273 0.269 0.269 Impinger Weights (g) Initial Final Net Impinger 1 502.7 687.9 185.2 Impinger 2 Impinger 3 592.5 702.0 620.6 710.5 28.1 8.5 Impinger 4 Impinger 5 928.1 939.4 11.3 0.0 Impinger 6 0.0 Impinger 7 0.0 Impinger 8 0.0 Moisture Collected (g) Pitot Tube ID 233.1 8-4 Saturated Percent Moisture 22.59 Standard Calculated Percent Moisture 21.04 Volume (dscf) Isokinetic % 101.5 41.2 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 9:37:00 9:40:00 9:43:00 9:46:00 9:49:00 9:52:00 9:55:00 9:58:00 10:01:00 10:04:00 10:07:00 10:10:00 10:13:00 10:23:00 10:26:00 10:29:00 10:32:00 10:35:00 10:38:00 10:41:00 10:44:00 10:47:00 10:50:00 10:53:00 10:56:00 10:59:00 Dry Gas Meter Reading Vm (ft3) 940.123 942.200 943.850 945.450 946.950 948.600 950.100 951.850 953.350 955.150 956.500 958.100 959.745 960.296 961.950 963.900 965.600 967.400 969.200 970.950 972.600 974.200 975.700 977.150 978.650 980.176 Velocity Head CP) (in H20) 0.31 0.33 0.31 0.28 0.29 0.27 0.31 0.30 0.30 0.27 0.31 0.30 0.42 0.45 0.39 0.43 0.40 0.38 0.32 0.27 0.26 0.25 0.26 0.26 Orifice Pressure Diff C H) (in H20) 1.00 1.10 1.00 0.93 0.96 0.89 1.00 0.99 0.99 0.89 1.00 0.99 1.40 1.50 1.30 1.40 1.30 1.30 1.10 0.89 0.86 0.83 0.86 0.86 Stack Temp Ts (F) 149 144 148 145 142 149 147 148 142 145 143 150 139 141 147 144 147 145 144 146 139 146 145 145 Dry Gas Meter Temperature Tm in Tm out (F) (F) 48 47 48 47 50 47 51 48 52 47 52 48 53 48 52 48 53 48 53 48 53 48 53 48 52 49 53 49 54 49 55 49 56 50 56 50 56 50 55 50 55 50 55 50 55 50 55 51 Ca{ciner#4M5 202 Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00350 Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner#4 Condition Normal Sample Type: Method 13B Run Number: 1 Date: 1-Feb-16 2 1-Feb-16 3 1-Feb-16 Total Sampling Time (min) Corrected Barometric Pressure (in Hg) Absolute Stack Pressure (in H20) Stack Static Pressure (in H20) Average Stack Temperature (F Stack Area (sq in) Actual Meter Volume (cu ft) Average Meter Pressure (in H20) Average Meter Temperature (F Moisture Collected (g) Carbon Dioxide Concentration (%V) Oxygen Concentration (%V) Nitrogen Concentration (%V) Dry Gas Meter Factor (y6) 72.0 29.85 29.83 -0.26 151.1 4072 32.821 0.73 81.5 269.7 6.0 15.1 78.9 1.0189 72.0 29.82 29.80 -0.26 152.5 4072 33.896 0.73 84.7 257.0 6.0 15.1 78.9 1.0189 72.0 29.83 29.81 -0.26 152.7 4072 34.366 0.75 83.3 254.6 6.0 15.1 78.9 1.0189 Nozzle Diameter (in) Pitot Constant 0.240 0.84 0.240 0.84 0.240 0.84 Average Sampling Rate (dscfm) Standard Metered Volume (dscf) Standard Metered Volume (dscm) Stack Moisture (%V) Saturated Moisture (%V) Mole Fraction Dry Stack Gas Dry Molecular Weight Wet Molecular Weight Average SORT of Delta P Stack Gas Velocity (fps) Stack Gas Velocity (mps) Volumetric Flow Rate (acfm) Volumetric Flow Rate (acmm) Volumetric Flow Rate (dscfm) Volumetric Flow Rate (dscmm) Percent Isokinetic Post Test Meter QA (yqa) 0.453 32.591 0.923 28.1 26.0 0.740 29.56 26.55 0.56 35.4 10.8 60051 1701 38272 1084 106.2 1.0299 0.464 33.428 0.947 26.6 26.7 0.734 29.56 26.49 0.56 35.5 10.8 60209 1705 37942 1075 109.9 1.0012 0.472 33.993 0.963 26.1 26.7 0.739 29.56 26.55 0.57 36.0 11.0 61058 1729 38743 1097 109.4 1.0003 Average 72.0 29.83 29.81 -0.26 152.1 4072 33.694 0.73 83.1 260.4 6.0 15.1 78.9 1.0189 0.240 0.84 0.463 33.337 0.944 26.9 26.5 0.738 29.56 26.53 0.56 35.6 10.9 60439 1712 38319 1085 108.5 1.0105 Fluoride Emission Rate Calculations Orion 901 Meter Reading, ppm__________ 0.178 Liquid Sample Volume, ml______________ 1000 Sample Aliquot_________________________ 10 Sample Dilution________________________ 10 Total Fluoride, mg______________________ 0.1780 Fluoride Concentration, mg/DSCF_______ 0.0055 Fluoride Emissions, lbs F/hr____________ 0.0276 Rock Feed (WetTPH)__________________ 67.9 Fluoride Emissions, lbs F/Ton Rock Feed 0.0004 0.189 1000 10 10 0.1890 0.0057 0.0284 67.9 0.0004 0.193 1000 10 10 0.1930 0.0057 0.0291 67.9 0.0004 Average N/A N/A N/A N/A 0.1867 0.0056 0.0284 67.9 0.0004 Calciner#4 M13B WetTPH.xIsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run Summary ED 001523 00007569-00351 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data C02 Percent Replicate 1 6.0 Replicate 2 Replicate 3 Average 6.0 Method 13E PCS Phosphate 60402248 Calciner# A Normal N-55 1.018S 3.0 29.95 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (If Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 78.9 Nozzle ID (in) 2/1/2016 WL\BM 1 2.32 1.8639 0.84 100 -0.26 c 72.0 0.241 0.240 0.24C 0.24G impinger Weights (g) initial Final Net impinger 1 616.3 847.7 231.4 Impinger 2 714.4 741.3 26.S impinger 3 656.1 659.2 3.1 impinger 4 929.2 937.5 8.3 impinger 5 o.c impinger 6 0.0 impinger 7 OX impinger 8 0.0 Moisture Collected (g) 269.7 Pitot Tube iD 6-4 Saturated Percent Moisture 26.01 Standard Calculated Percent Moisture 28.07 Volume (dsef) isokinetic % 106.2 32.6 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 12:50:00 12:53:00 12:56:00 12:59:00 12:16:00 12:19:00 12:22:00 12:25:00 12:28:00 12:31:00 12:34:00 12:37:00 12:40:00 13:29:00 13:32:00 13:35:00 13:38:00 13:41:00 13:44:00 13:47:00 13:50:00 13:53:00 13:56:00 13:59:00 14:02:00 14:05:00 Dry Gas Meter Reading Vm (ft3) 757.610 758.640 759.380 760.770 762.220 763.580 764.950 766.320 767.640 768.990 770.310 771.680 773.089 773.087 774.620 776.130 777.630 779.070 780.580 782.020 783.430 784.760 786.270 787.730 789.090 790.429 Velocity Head (AP) (in H20) 0.31 0.29 0.32 0.35 0.30 0.30 0.27 0.27 0.29 0.29 0.30 0.31 0.37 0.36 0.36 0.33 0.39 0.32 0.31 0.27 0.37 0.32 0.30 0.28 Orifice Pressure Diff (AH) (in H20) 0.71 0.67 0.74 0.81 0.69 0.69 0.62 0.62 0.67 0.67 0.69 0.71 0.85 0.83 0.83 0.76 0.90 0.74 0.71 0.62 0.85 0.74 0.69 0.64 Stack Temp Ts (F) 130 148 149 152 153 153 155 152 152 147 152 153 152 154 155 152 154 155 150 151 153 152 153 150 Dry Gas Meter Temperature Tm in Tm out (F) (F) 78 79 78 78 78 79 79 79 80 79 81 79 81 79 81 79 81 79 83 79 83 80 83 80 83 80 83 80 84 80 84 80 85 81 85 81 86 81 86 81 87 81 87 81 88 82 88 82 Calciner #4 M13B_WetTPH.xisx Run 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00352 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data C02 Percent Replicate 1 6.0 Replicate 2 Replicate 3 Average 6.0 Method 13E PCS Phosphate 60402248 Calciner# A Normal N-55 1.018S 3.0 29.92 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (If Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 78.9 Nozzle ID (in) 2/1/2016 WL\BM 2 2.32 1.8639 0.84 100 -0.26 c 72.0 0.241 0.240 0.24C 0.24G impinger Weights (g) initial Final Net impinger 1 767.5 996.2 228.7 Impinger 2 673.0 691.6 1ST impinger 3 642.0 644.5 2.5 impinger 4 907.0 914.2 7.2 impinger 5 0.0 impinger 6 0,0 impinger 7 0.0 impinger 8 o.c Moisture Collected (g) 257.C Pitot Tube ED 6-4 Saturated Percent Moisture 26.69 Standard Calculated Percent Moisture 26.61 Volume (dsef) isokinetic % 109.9 33.4 Traverse Point Location B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 14:29:00 14:32:00 14:35:00 14:38:00 14:41:00 14:44:00 14:47:00 14:50:00 14:53:00 14:56:00 14:59:00 15:02:00 15:05:00 15:08:00 15:11:00 15:14:00 15:17:00 15:20:00 15:23:00 15:26:00 15:29:00 15:32:00 15:35:00 15:38:00 15:41:00 15:44:00 Dry Gas Meter Reading 791 790.819 792.340 793.870 795.450 796.870 798.310 799.740 801.210 802.580 804.210 805.590 806.970 808.316 808.316 809.130 811.170 812.460 813.850 815.230 816.630 818.010 819.370 820.800 822.020 823.380 824.715 Velocity Head (AP) (in H20) 0.35 0.38 0.39 0.33 0.32 0.32 0.35 0.29 0.41 0.32 0.30 0.28 0.33 0.32 0.28 0.29 0.30 0.31 0.29 0.29 0.27 0.26 0.28 0.28 Orifice Pressure Diff (AH) (in H20) 0.81 0.88 0.90 0.76 0.74 0.74 0.81 0.67 0.95 0.74 0.69 0.64 0.76 0.74 0.64 0.67 0.69 0.71 0.67 0.67 0.62 0.60 0.64 0.64 Stack Temp Ts (F) 156 157 156 145 147 152 154 156 155 154 156 154 155 149 155 154 148 145 153 148 152 153 154 152 Dry Gas Meter Temperature Tm in Tm out (F) (F) 84 83 85 83 86 83 87 83 87 84 88 84 88 84 89 84 89 84 89 84 89 84 89 84 82 83 82 83 82 83 83 83 84 83 85 83 86 83 86 83 86 83 86 83 86 83 86 83 Calciner #4 M13B_WetTPH.xisx Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00353 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data C02 Percent Replicate 1 6.0 Replicate 2 Replicate 3 Average 6.0 Method 13E PCS Phosphate 60402248 Calciner# A Normal N-55 1.018S 3.0 29.93 02 Percent 15.1 15.1 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (If Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 78.9 Nozzle ID (in) 2/1/2016 WL\BM 3 2.32 1.8639 0.84 100 -0.26 c 72.0 0.241 0.240 0.24C 0.24G impinger Weights (g) initial Final Net impinger 1 635.6 864.1 228T Impinger 2 723.9 738.6 14.7 impinger 3 656.6 658.4 1.8 impinger 4 871.7 881.3 9.6 impinger 5 0.0 impinger 6 0.0 impinger 7 0.C impinger 8 0.0 Moisture Collected (g) 254.6 Pitot Tube ED 6-4 Saturated Percent Moisture 26.68 Standard Calculated Percent Moisture 26.10 Volume (dsef) isokinetic % 109.4 34.0 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 17:25:00 17:28:00 17:31:00 17:34:00 17:37:00 17:40:00 17:43:00 17:46:00 17:49:00 17:52:00 17:55:00 17:58:00 18:01:00 18:03:00 18:06:00 18:09:00 18:12:00 18:15:00 18:18:00 18:21:00 18:24:00 18:27:00 18:30:00 18:33:00 18:36:00 18:39:00 Dry Gas Meter Reading Vm (ft3) 824.965 826.350 827.760 829.270 830.610 832.050 833.480 834.930 836.280 837.710 839.140 840.570 841.925 841.925 843.570 845.080 846.490 847.960 849.420 851.000 852.340 853.770 855.220 856.620 857.970 859.331 Velocity Head (AP) (in H20) 0.29 0.31 0.33 0.32 0.34 0.33 0.33 0.29 0.31 0.33 0.32 0.28 0.42 0.36 0.35 0.33 0.34 0.34 0.32 0.33 0.33 0.31 0.30 0.29 Orifice Pressure Diff (AH) (in H20) 0.67 0.71 0.76 0.74 0.78 0.76 0.76 0.67 0.71 0.76 0.74 0.64 0.97 0.83 0.81 0.76 0.78 0.78 0.74 0.76 0.76 0.71 0.69 0.67 Stack Temp Ts (F) 152 151 155 156 156 152 153 154 141 152 153 154 154 154 153 153 150 148 151 152 155 156 156 154 Dry Gas Meter Temperature Tm in Tm out (F) (F) 83 83 83 83 84 82 84 82 85 82 85 82 85 82 85 82 86 82 86 82 86 82 86 82 85 81 85 81 85 81 85 81 85 81 85 81 85 81 85 81 85 81 85 81 85 81 85 81 Calciner #4 M13B_WetTPH.xisx Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00354 AECONi PCS Phosphate Calciner #4 Mercury Emission Calculations EPA Method 30B Emission Results 02 Correction Basis Pollutant: Mercury Run AVERAGE Total Hg Catch Sample Volume Hg Concentration mg/dscm 0.0494 0.0453 0.0471 0.0473 Hg Concentration ppmV 0.0059 0.0054 0.0056 0.0057 Oxygen % 15.1 15.1 15.1 15.1 Hg Concentration mg/dscm @ 3% 0.153 0.140 0.146 0.146 Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Mercury ED 001523 00007569-00355 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 1 PCS 60402248.1 Calciner #4 Normal -0.28 100 29.89 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5.99 6.0 02 Percent 15.11 N2 Percent 15.1 78.9 | Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 26.72 26.72 0.733 29.56 26.47 2/10/2016 LB 0.84 C 72.0 4071.5 29.79 29.77 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AB) (in H20) 0.26 0.33 0.35 0.34 0.35 0.33 0.36 0.34 0.37 0.32 0.33 0.14 0.32 0.37 0.41 0.42 0.43 0.43 0.38 0.32 0.28 0.27 0.21 0.16 Stack Temp Ts (F) 154 148 147 147 148 146 150 151 150 151 151 151 154 153 153 153 157 157 156 156 155 155 153 153 Square Root of SQRT(AR) 0.510 0.574 0.592 0.583 0.592 0.574 0.600 0.583 0.608 0.566 0.574 0.374 0.566 0.608 0.640 0.648 0.656 0.656 0.616 0.566 0.529 0.520 0.458 0.400 Average Stack Average SORT Temp AP 152.04 0.57 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) Stack Gas Velocity (fps) 32.3 36.2 37.3 36.7 37.3 36.2 37.9 36.9 38.4 35.8 36.3 23.7 35.9 38.5 40.6 41.0 41.7 41.7 39.1 35.9 33.6 33.0 29.0 25.3 Average Velocity 35.85 60810 52196 38250 : Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R1 ED 001523 00007569-00356 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 2 PCS 60402248.1 Calciner #4 Normal -0.28 100 29.88 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5.99 6.0 02 Percent 15.11 N2 Percent 15.1 78.9 | Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 28.07 28.07 0.719 29.56 26.32 2/10/2016 LB 0.84 C 72.0 4071.5 29.78 29.76 T raverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AB) (in H20) 0.24 0.28 0.32 0.35 0.36 0.35 0.35 0.36 0.34 0.34 0.32 0.18 0.33 0.35 0.39 0.43 0.43 0.43 0.39 0.35 0.27 0.27 0.20 0.17 Stack Temp Ts (F) 154 155 157 156 157 154 153 155 153 152 152 151 152 153 155 153 154 156 156 154 154 154 155 152 Square Root of A/P SQRT(AB) 0.490 0.529 0.566 0.592 0.600 0.592 0.592 0.600 0.583 0.583 0.566 0.424 0.574 0.592 0.624 0.656 0.656 0.656 0.624 0.592 0.520 0.520 0.447 0.412 Average Stack Average SORT Temp AP 154.04 0.57 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Stack Gas Velocity (fps) 31.1 33.7 36.1 37.7 38.2 37.6 37.6 38.2 37.0 37.0 35.9 26.9 36.5 37.6 39.7 41.7 41.7 41.8 39.8 37.6 33.0 33.0 28.5 26.2 Average Velocity 36 00 61078 52237 37575 R2 ED 001523 00007569-00357 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 3 PCS 60402248.1 Calciner #4 Normal -0.28 100 29.87 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5.99 6.0 02 Percent 15.11 N2 Percent 15.1 78.9 | Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 23.62 23.62 0.764 29.56 26.83 2/10/2016 LB 0.84 C 72.0 4071.5 29.77 29.75 T raverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AB) (in H2Q) 0.32 0.37 0.35 0.33 0.32 0.30 0.34 0.37 0.42 0.36 0.32 0.18 0.41 0.42 0.44 0.42 0.40 0.40 0.35 0.33 0.31 0.26 0.24 0.20 Stack Temp Ts (F) 145 144 144 146 147 148 149 151 150 151 151 148 150 148 147 148 146 145 145 146 147 148 149 149 Square Root of A/P SQRT(AB) 0.566 0.608 0.592 0.574 0.566 0.548 0.583 0.608 0.648 0.600 0.566 0.424 0.640 0.648 0.663 0.648 0.632 0.632 0.592 0.574 0.557 0.510 0.490 0.447 Average Stack Average SORT Temp AP 147.58 0.58 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Stack Gas Velocity (fps) 35.4 38.0 37.0 35.9 35.4 34.3 36.6 38.2 40.7 37.7 35.5 26.6 40.2 40.6 41.5 40.6 39.6 39.5 37.0 35.9 34.9 32.0 30.7 28.1 Average Velocity 36.33 61633 53255 40677 R3 ED 001523 00007569-00358 AZCOM Date 2/10/2016 Plant PCS Phosphate Location Calciner #4 Sample Type 30 B Run Number/Side (A/B) Operator LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 25 Final Leak Check (L/min (5) "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL328484 29.79 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002663 1.0220 1.0220 72 Page 1 of_____1_ Run No, 1 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 12:25:00 0.000 5 12:30 5.75 10 12:35 9.38 15 12:40 12.90 20 12:45 16.42 25 12:50 19.88 30 12:55 23.05 35 13:00 24.58 40 13:05 32.78 45 13:10 36.42 50 13:15 40.10 55 13:20 43.55 60 13:25 46.931 46.931 46.9310 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 153 303 43 41 151 273 42 43 148 265 42 40 153 236 41 40 153 236 42 40 150 274 44 41 151 275 44 41 153 268 48 43 152 246 44 42 147 248 46 42 150 236 54 44 152 273 48 44 154 303 50 44 151 264 45 42 Pump Vacuum <" Hg) -4 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 Target Volume Spike Amount (ng) Comments: 2000 Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 49907.00114 49.9070011 Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 1A ED 001523 00007569-00359 AECONl Date 2/10/2016 Plant PCS Phosphate Location Calciner#4 Sample Type 30 B Run Number/Side (A/B) Operator LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 25 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" HjO) Barometric Pres. (" Hg) OL304707 29.79 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002663 1.0220 1.0220 72 Page 1 of_____1_ Run No, 1 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 12:25:00 0.000 5 12:30 5.80 10 12:35 9.80 15 12:40 13.35 20 12:45 16.79 25 12:50 20.30 30 12:55 23.39 35 13:00 27.65 40 13:05 32.80 45 13:10 33.89 50 13:15 37.54 55 13:20 41.10 60 13:25 44.586 44.586 44.586 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 153 303 42 41 151 273 42 43 148 265 42 40 153 236 43 40 153 236 43 40 150 274 46 41 151 275 45 41 153 268 45 43 152 246 46 42 147 248 45 42 150 236 55 44 152 273 49 44 154 303 48 44 151 264 45 42 Pump Vacuum <" Hg) -4 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1.23 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 47391.63862 47.3916386 Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production IB ED 001523 00007569-00360 AECONl Date 2/10/2016 Plant PCS Phosphate Location Calciner #4 Sample Type 30 B Run Number/Side (A/B) Operator LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 12 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL328302 29.78 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002494 1.0220 1.0220 72 Page 1 of____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 13:45:00 0.000 5 13:50 3.45 10 13:55 6.25 15 14:00 10.20 20 14:05 14.15 25 14:10 17.88 30 14:15 21.23 35 14:20 25.35 40 14:25 28.50 45 14:30 32.40 50 14:35 35.85 55 14:40 39.56 60 14:45 43.049 43.0490 43.0490 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 150 255 48 44 152 291 47 45 152 291 48 44 150 260 54 46 152 235 50 46 154 238 49 45 154 271 48 44 148 301 40 44 150 286 48 50 146 260 49 46 156 276 46 48 152 255 49 46 146 265 52 46 151 268.00 48.31 45.69 Pump Vacuum (" Hg) -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1.00 Target Volume Spike Amount (ng) Comments: 2000 Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 45486.26901 45.486269 Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2A ED 001523 00007569-00361 A=COM Date 2/10/2016 Plant PCS Phosphate Location Calciner #4 Sample Type 30 B Run Number/Side (A/B) Operator DM/FC Location Height Initial Leak Check (L/min @ "Hg) 0.000 12 Final Leak Check (L/min @ "Hg) 0.000 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL321049 29.78 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002663 1.0220 1.0220 72 Page 1 of____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point A1 TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 13:45:00 13:50 13:55 14:00 14:05 14:10 14:15 14:20 14:25 14:30 14:35 14:40 14:45 0.000 3.780 6.800 10.780 14.730 18.460 21.780 25.460 29.000 32.660 35.980 39.630 43.2890 43.2890 43.2890 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 150 152 152 150 152 154 154 148 150 146 156 152 146 150.9230769 255 291 291 260 235 238 271 301 286 260 276 255 265 268.00 50 49 49 52 52 50 49 49 49 49 49 50 50 49.77 44 45 44 46 46 45 44 44 50 46 48 46 46 45.69 Pump Vacuum <" Hg) -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1.00 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 45608.63307 45.6086331 Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2B ED 001523 00007569-00362 AECONl Date 2/10/2016 Plant PCS Phosphate Location Calciner#4 Sample Type 30 B Run Number/Side (A/B) Operator LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 Final Leak Check (L/min @ "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL304654 29.77 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002494 1.0220 1.0220 72 Page 1 of_____1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 15:05:00 15:10 15:15 15:20 15:25 15:30 15:35 15:40 15:45 15:50 15:55 16:00 16:05 0.000 4.00 7.29 10.97 14.75 18.23 21.83 25.82 28.75 32.37 35.91 39.43 43.472 43.4720 43.4720 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 150 154 149 153 155 150 151 156 149 155 152 153 156 152.5384615 256 251 241 241 242 251 252 251 281 304 303 300 297 266.92 50 51 51 52 52 51 52 51 51 52 53 50 51 51.31 47 46 46 46 46 47 46 46 45 45 46 45 45 45.85 Pump Vacuum <" Hg) -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1.00 Target Volume Spike Amount (ng) Comments: 2000 Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 45648.2056 45.6482056 Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3A ED 001523 00007569-00363 AECONl Date 2/10/2016 Plant PCS Phosphate Location Calciner #4 Sample Type 30 B Run Number/Side (A/B) Operator LB Location Height Initial Leak Check (L/min @ "Hg) 0.000 Final Leak Check (L/min @ "Hg) METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL321104 29.77 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002663 1.022 1.022 Page 1 of_____1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 0 15:05:00 0.000 5 15:10 4.050 10 15:15 7.710 15 15:20 11.490 20 15:25 15.400 25 15:30 19.000 30 15:35 22.100 35 15:40 25.760 40 15:45 28.830 45 15:50 32.590 50 15:55 36.100 55 16:00 39.620 60 16:05 43.3900 43.3900 43.3900 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 150 154 149 153 155 150 151 156 149 155 152 153 156 152.5384615 256 251 241 241 242 251 252 251 281 304 303 300 297 266.92 57 52 51 51 52 51 51 52 51 51 51 50 50 51.54 47 46 46 46 46 47 46 46 45 45 46 45 45 45.85 Pump Vacuum (" Hg) -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1.00 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 45541.53309 45.5415331 Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3B ED 001523 00007569-00364 AECOM FIELD SAMPLING DATA SHEET Sample and Velocity Traverse for Stationary Sources EPA METHOD 1 Client/Plant: Project#: 4^0214Sr Location: Number of Traverse Points Chosen: 4 Number of Ports: Duct Diameters From Downstream Flow Disturbance (A/D) 0. 1.0 1.5 2.0 Hgber Number is for Rectangular Stacks or Duds 3 24 or 25 F&rtfculate t!n r |. Disturbance Measurement Site B i Disturbance 2 16 v\f StsdtDfametur >0.61m{24 !a) 1 10 I_8or9. Non - Rarticulate Stack Diameter *0.30 to C.6tm(12 -24 In.) Date: Z /SAV Number of Points per Port: (X 234 567 8 9 10 Duct Diameters From Upstream Flow Disturbance (B/D) Deq = 2LW / (L+W) Dnstream Diameters (A/D) Upstream Diameters (B/D) Cross-Sectional Layout of Rectangular Stacks Traverse Points Matrix 9 3x3 12 4x3 16 4x4 20 5x4 25 5x5 Traverse Point 1 2 Fraction Distance of From Diameter Wall z.v Nipple Length CC" Point Location U.C 3 \u% tVS 4 5 ZSvO rt.O 6 2S.L 7 8 . 9 <*i*5 10 (/3-5 . 11 T*>,3 12 XTfA 4 6 8 10 w 14 16 18 20 22 24 i 6.7 4.4 3.2 12.1 1.8 1.6 1.4 1.3 1.1 1.1 2 25.0 14.6 10.5 8.2 6.7 5.7 4.9 4.4 3.9 3.5 3.2 3 75.0 29.6 19.4 14.6 11.8 9.9 8.5 7.5 6.7 6.0 5.5 4 93.3 70.4 32.3 22.6 17.7 14.6 12.5 10.9 9.7 8.7 7.9 5 85.4 67.7 34.2 25.0 20.1 16.9 14.6 12.9 11.6 10.5 6 95.6 80.6 65.8 35.6 26.9 22.0 18.8 16.5 14.6 13.2 7 89.5 77.4 64.4 36.6 28.3 23.6 20.4 18.0 16.1 8 96.8 85.4 75.0 63.4 37.5 29.6 25.0 21.8 19.4 9 91.8 82.3 73.1 62.5 38.2 30.6 26.2 23.0 10 97.4 88.2 79.9 71.7 61.8 38.8 31.5 27.2 11 93.3 85.4 78.0 70.4 61.2 39.3 32.3 12 ,97.9 90.1 83.1 76.4 69.4 60.7 39.8 13 94.3 87.5 81.2 75.0 68.5 60.2 14 98.2 91.5 85.4 79.6 73.8 67.7 15 95.1 89.1 83.5 78.2 72.8 16 98.4 92.5 87.1 82.0 77.0 17 95.6 90.3 85.4 80.6 18 98.6 93.3 88.4 83.9 19 96.1 91.3 86.8 20 98.7 94.0 89.5 21 96.5 92.1 22 98.9 94.5 23 96.8 24 98.9 LOCATION OF TRAVERSE POINT IN RECTANGULAR STACKS. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00365 AZCOM FIELD SAMPLING DATA SHEET Flow and Moisture EPA Methods 2 & 4 PAGE J-- OF Client/Plant PClS Location: j &L Project #: ^ Condition: , )p Date: ^/// /'& Moisture Run #: / Operators): UJ L. / /3 Duration (min): PGM#: ^ C CF(Yd): AHS: Cp: 0.84 PbarCHg): Height w.r.t. Barometer (ft): Pstaflc {"H2O): oLS> Initial Leak V (<0.02 ft3/mln; >10"Hg) ft7m!n: Vac. ("Hg): Source Height (ft): 'yoD Duct Diameter ("): ^7 Final Leak V (<0.02 ft3/min; >run maximum) ft3/min: Vac. ("Hg): Duct Width (*): Duct Length ("): Pitot Leak (>3"H20) +P ("H20) p ("h2o): Pitot Tube ID#: 02 (%/time) % % % C02 (%/time) % % % Flow Run #: / Flow Run #: Flow Run #: Moisture Determination Start Traverse End Start Ertd Start End Cyclonic Time DGM Volume (ft3) AH ("H20) DGM DGM Inlet T Outlet T (F) CD Point 113Q /SL-`0& AP Source T AP (*H20) ("F) ("H20) Source T (T) AP ("HjO) Angle () Source T (F) /f/ 163 /# A .sr /S6 3.0 3 .33 /.ST' /a 9 , 35 /S6 ? 1 . /</ /a 6 f<3 & ? /7 10 __ r0g. /SI ft 9 *3S^ /<>3 W fd> /63 // /9T /.< U Jtt.... .3? /? ? .38 /SZ( ,31.. /sf S JS< 6 *36 /$.< /> O /> / /o. /s 6 9 0 w.... /> .3/ .12 // *39 /si >$(, /si /so r<e>... 6 dST| ol/ O m /& 26X Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00366 Test Run 4 STRATA Version 3.2.112 02 C02 % % Begin calculating run averages 02-11-2016 08:18:08 -0.140 -0.168 02-11-2016 08:19:08 -0.161 -0.170 02-11-2016 08:20:08 -0.161 -0.169 02-11-2016 08:21:08 -0.165 -0.170 02-11-2016 08:22:08 -0.167 -0.169 Pause End Pause 02-11-2016 08:25:08 19.276* 20.576 02-11-2016 08:26:08 19.282* 20.561 02-11-2016 08:27:08 19.279* 20.551 02-11-2016 08:28:07 19.279* 20.557 02-11-2016 08:29:07 19.279* 20.566 02-11-2016 08:30:07 19.290* 20.553 Pause End Pause 02-11-2016 08:33:08 10.022 9.789 02-11-2016 08:34:08 10.011 9.771 02-11-2016 08:35:08 10.012 ' 9.767 02-11-2016 08:36:08 10.010 9.774 .02-11-2016 08:37:08 10.006 9.765 Pause End Pause 02-11-2016 08:41:08 20.766* 5.203 02-11-2016 08:42:08 20.783* 5.214 02-11-2016 08:43:08 20.818* 5.181 02-11-2016 08:44:08 20.802* 5.227 02-11-2016 08:45:08 20.801* 5.095 Pause End Pause 02-11-2016 08:48:08 ' 15.286 -0.140 02-11-2016 08:49:08 15.281 -0.141 02-11-2016 08:50:08 15.282 -0.138 02-11-2016 08:51:08 15.289 -0.138 02-11-2016 08:52:08 15.288 -0.139 02-11-2016 08:53:08 15.284 -0.138 02-11-2016 08:54:08 15.289 -0.142 02-11-2016 08:55:08 15.290 -0.141 Pause End Pause * 02-11-2016 08:57:08 20.780* 5.643 02-11-2016 08:58:08 20.813* 5.993 02-11-2016 08:59:08 20.815* 5.986 02-11-2016 09:00:08 20.819* 5.992 02-11-2016 09:01:07 20.818* 6.006 02-11-2016 09:02:07 20.826* 6.016 Pause End Pause 02-11-2016 09:05:08 15.113 -0.097 02-11-2016 09:06:08 15.104 . -0.130 02-11-2016 09:07:08 15.106 -0,128 02-11-2016 09:08:08 15.112 -0.117 02-11-2016 09:09:08 15.107 -0.117 02-11-2016 09:10:07 15.103 -0.115 02-11-2016 09:11:07 15.104 -0.123 Pause End Pause , 02-11-2016 09:14:08 20.796* 5.108 02-11-2016 09:15:08 ' 20.796* 5.220 02-11-2016 09:16:08 20.792* 5.213 02-11-2016 09:17:08 20.803* 5.213 02-11-2016 09:18:08 20.806* 5.202 02-11-2016 09:19:08 20.801* 5.184 Pause End Pause 02-11-2016 09:22:08 15.133 -0.110 02-11-2016 09:23:07 15.119 -0.119 02-11-2016 09:24:07 15.125 -0.110 02-11-2016 09:25:07 15.116 -0.107 02-11-2016 09:26:08 15.120 -0.117 Run Averages 02 C02 % % 02-11-2016 09:26:53 15.422* 5.120 Operator: Lance Burleson Plant Name: PCS Aurora 'Location: Calciner #4 Test Run 4 End Page 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523_00007569-00367 ACCOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 EPA Method 5/202 1 ( PAGE OF Client/Plant '444 Location: 4J, >.:** 4 Console#; /% -q>4 3 K-Factor: 2\ \ 45 Project #: f 4 (<n . Condition: p, CF (Yd): PbarC'Hg): S- 4,4 1 Date: Run #: AH@: 1, y 4 H s 1 s/,34 Height w.r.t. Barometer (ft): /fc Operators): Uc t s-\ Duration (min): ~1 5 Cp: 0.84 Pstatic ("H2O): Zh Initial Leak 5 (<0.02 ft3/min; >10"Hg) Vac. ("Hg): \-. Source Height (ft); Hi' Duct Diameter ("): Final Leak S (<0.02 ft /min; >run maximum) Pitot Leak (>3"H20) Initial +P: Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat O2 (%/time) % Fyrite/Orsat O2 (%/time) % ( ft /min: q? , <J> Vac. ("Hg): -P: 4 Final +P: H Fyrite/Orsat CO2 (%/time) ) Fyrite/Orsat C02 (%/time) Fyrite/Orsat CO2 (%/time) Duct Width ("): -P: -3 % ( ) % Duct Length ("); -- Nozzle D1 (") 0: 2 ,, ( Nozzle D2 (") 0: If', Nozzle D3 (") Q: UJ*i Average Nozzle D ("): Sample Point Time Clock Run (min! 13 1 Oij 2, 4), f i jo I *7 Si 5? L 4 4 % S'- L IS 1 9 -.... ---- \iC M Z4 2 1 H j---* i , It i -4 H4 'To p, \ 'is l '4 *1 1 4 L 9 3 -cJ 3 L- 5| 3 % P'1 4 1,0 1 If Hu 44 1? l/ 444 II iH DGM Volume (ft3) \p <"H20) Wm/iT .. 36 45t , 5 - (. 5 354 . 9 - 77 45, <2 43, - ^ , 7 7 .35 3 G4?, 9 3 3 35 /i Z 1 - 3# 343,0 [ 3z, 4 74. o 444 tzz. , 34 Y 94434/ , 3/ TSH'lj , Fc * 24 K'ec'. m ,3 4Vq , | c ,5 rco; hi .. 47 __ ,2.......3 4441 44 3%. A- 34 X Vi'*> , 5 vTi's. i , 24 , 7-1 4 4 471, 9 54454 4% \H l`H20) AO /H . %/_( 1! ? . / n'H </v> V .0 M' (uZ VvZ i:#' , 94 hi 44 % ( 44 f 4 ,, 11 fH M t A f- Temperature (F) Source i'YH Probe 248 25 Filter 248 + 25 234 Impinge r Exit <68 CPM Filter 65 85 39 DGM Inlet iH 1 S.s- 4 3 t>f 4? '2 i l%?j 1^4 Z<4 c4, z-4 y ,'t LI: c-5 4-1 3 5" 45 tS 7 34.1 44' 4 Ls.. 74)- 94; 2' f 4 4/ r5 44 s % 1 S' { 4:4. <4fi 444 44 *5? /.5 4/ 44' fin 54 4ri ?3H 4> C '5% rvT 44 14 44 ...4 HfHt .... 4w/ /l....... <tu 41 3 2fL ...... . . ... 14 "34-' Hi 4 44 14*rvr *'4 133 4/ ZHHL- 3SL 7c- % 343 "4l, H3 4? 34/, 133 V% t 4 2.44 2- ) */ c^ > 53 '^Ll. rX' 2-trO h 4 4 54 3*34 34 LL'T 'r / ,43 'H; 2lV 54 %4 5 3 a 4 - cv i C\ io/ rt / s-2 5 4 *44 V4) 239 3 3 Ci-O %4 - p' > Ki 24 cs i 2^') 7s, 4 54 .... ....44. 4'/ 44 4.1... 41 6 1 4 ?n DGM Outlet Pump Vac. ("Hg) 54. 4 54 - q, 3> J! 3.5 5 v > 4T A 5>c| 4 54 4 4 44 V 3.. * 7 "3 - J3 '-Z <- . 3 al><~j~ 0^ C ^ HP / f ) B5 4C5 <9 4 43 .4 4> 3 74 43 4. 4 3 _"7J 44 35 . '3 3 5> '7 > COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00368 AZCOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant: y, 1; Location: < , , * -/ Project#: (pi /t Condition: / , , Date: Run#: | Impinger # Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 0 VCON 0 KO hV' 0 MGS .w . 100 MGS r-1 350 MGS a ; 4. / Final (g) Gain (g) "'{ i<~. r. > // c >< /, y Sum Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: CPM Filter Temp Rotameter Reading Stop: Cl: Filter Recovery Container Weights PNR - Acetone Filter CPM Filter Impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: ID#: //// ID#: ID#: Tare Wt. (g) Tare Wt (g) Tare Wt. (g) a 3-1SSI Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00369 Fyrite/Orsat O2 (%/time) Fyrite/Orsat 02 (%/time) Fyrite/Orsat O2 (%/time) % ( ) Fyrite/Orsat CO2 (%/time) % ( : ) Nozzle D2 (") : % ( ) Fyrite/Orsat CO2 (%/time) % ( : ) Nozzle D3 (") : Fyrite/Orsat CO2 (%/time) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00370 fC.COM FIELD SAMPLING DATA SHEET (RECOVERY) ' METHOD 5/202 Client/Plant: &(' t Location; /' < r '/ Project#: ^ Condition: rl /<, Date: / ,./ Run #: 2 impinger # Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 0 VCON 0 KO 6o$. / 0 MGS ' ,V / 100 MGS T// ' 350 MGS ; > Final (g) Mm / i. // , I"? ! "f9//{a0 * <iC0 Sum Gain (g) Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: 1 Filter Temp Rotameter Reading Stop: Cl i Filter ID#; /'/V/Y ID#: ID#: TareWt, (g) Tare Wt. (g) ' . /P >/ Tare Wt (g) Recovery Container Weights PNR - Acetone Filter CPM Filter Impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00371 AZCOM Client/Plant fo FIELD SAMPLING DATA SHEET Particulate Matter MS/909 ---------- ----- . .; -- . Project#: (o Date: EPA Method 5/202 PAGE 1 OF 1 Operator(s): ,y // ^, Location: ( Console#: jxJ K-Factor: Condition: /v) - ..^-3 CF (Yd): l.cif/, Pbar ( Hg); 2,7, L- Run #: 3 AH@: iIt Vi Height w.r.t. Barometer (ft): Duration (min): 9 ~i_ Cp: 0.84 Pstatic ( H2O): " , Z.it Initial Leak V (<0.02 ft3/min; >10"Hg) ft3/min: p. Vac. ("Hg) v: Final Leak S (<0.02 ft3/min; >run maximum) ft3/mi Vac. ("Hg) Source Height (ft): (Cc Duct Width ("): -- Duct Diameter ("): 9 ? Duct Length ("): -- Pitot Leak (>3"H20) Initial +P; -P: Final +P, -P: \/ Nozzle D1 (") 0: ; / i,,f( Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat C02 (%/time) % ( Fyrite/Orsat CO2 (%/time) % ( Nozzle D2 (") 0: L, 2 1 -j Nozzle D3 (") Q: f l L-Ct Sample Point l b -1 Time Clock Run Uock | (min) DGM Volume {%) Vv.Vf V 4 ..Vl.t 0 `MS lV V 'iVfV.HV AP AH ("H20) Source , u ... t . 'O 1 V, . v> L 1 H4 , 1 c 13.b - If uVliJ N'i Probe 248 25 /' . s ?S7. Temperature (T) Filter 248 + 25 Impinge r Exit <68 CPM Filter 65 85 DGM Inlet DGM Outlet Pump Vac. ("Hg) ' tc / .t V") /s? 3/ Vto ill -.i /s L ! (,-L l/ -I r i S`V `7 7 * r4. dl- 1 _ILJ 'If, 1 n. V~V, IT .... Si HI VVI 1st s 1 i3 si rll 1 1 r14? . L is vi /V? ZoV Si 0 ? -Dt\ 1 3 43____ V%lM 1 , >t 1.0 MTV Z5! V 7 0 0 w "i V 1 is 3.0 St Vl i , ...... _ Vi zi \*T. Ti - - --- - i 0 4s'5. IS' 77 /.11 iAf V ' n vz 2 S'} 3 2 t 1 vz. 7 V i C-'aV sL //. "1& l 15V mV 4 1 HP, l is >*' SsV .< Vs i.\iu H3 2<sV ZSM Vj? c-> / <49; I si `VlV ;! . iolJ. > h 1 W i`S?t cL i'5t Zsi- - tit T Z5T L ItV C c- S3 SV. < ------------------ - ... , . V t to /V H 1 c, b 'ty f V I Vi TV..... k> G s? tiS> 2 M iU V! n VI IV/ 34 L? 3 V VV 3 M2 Mt MV . Vi i.V f3> 4 24 c zsv / y V 5 V i,t <( 3 4 V 3 % M la ti IT r%r> 1C`P i 47 V OS , Q 4 7 7 71 <4 SI ml z 74 QIC 31V 'ST- n?i. & V j l'94, V- .43 ,7 6 ,.3 2 , Ig i, > C.'-'W Vv *1-"? nQ!3. is VW > C% * n-u / Z-V Zv 1.4 IV 1,5 VV> 1,1 fv ,vu \ s , SL. vA> MV /hV /%? i N u IHS" t V ?4V 2-+i 40 >/ :Vi 2TS Zi 1 W 7, V 2 tsl 2jQo Lsm Vsl zs'i V'SZ Mss zvx 4V 7V Vi. vv vv 1 S nlz 11 Iz 'SV V* f Vd li so Vi (< '? A 6'^ s G SI S~L 39 S3 /> s S'5 S S '1/ d >7.: 'St `7Z-- -1 ST ,.wl.. SO f TO 1 V9 57 . n 3 "S 1_______ COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00372 ACCOM FI"' 2 SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant; Location; #4 Project#: Conditioi //VT Date: it Run Impinger # Condenser 1 2 3 4 impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) ^ Final (g) 0 VCON 'V, Z 0 KO -ifT 1 'I L *4 T V 0 MGS v/ ( 100 MGS ^ V f/ l )(' 5 350 MGS /J* f Sum Gain (g) Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: CPM Filter Temp Rotameter Reading Stop: Cl: Filter Recovery Container Weights PNR - Acetone Filter CPM Filter Impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: ID#: /^//? ID#: ID#: TareWt. (g) Tare Wt, (g) TareWt, (g) Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00373 AECOM Client/Plant: Location: Impinger# 1 2 3 4 5 Impinger Contents h2o h2o - Silica Gel FIELD SAMPLING DATA SHEET (MOISTURE RECOVERY) EPA METHOD 4 Project #: Condition: Date: Moisture Run #: Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 100 MOD 100 GS Empty MOD -- MOD Final (g) Gain (g) Sum COMMENTS: 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00374 ABCOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE OF -L Cllent/PIant: f*C,$ Project#: , \t> Date: / / / /A Operator(s): Qj L- / /j /Y\ Location: !, & */ PGM#: */ ~ Condition: A'jar^l CF (Yd): / o/%? Run #: A AHe: Y39 Duration (min): 7[ Cp: 0.84 K-Factor: R.33 PbarfHg): Height w.r.t. Barometer (ft): Pstatic ("H2O): 6 Initial Leak / (<0.02 ff/min; >10"Hg) ft3/min: Vac. ("Hg): / Source Height (ft): (00 Duct Diameter ("): 37. Final Leak V (<0.02 ff/min; >max vacuum) Pitot Leak (>3"H20) +P ("H20) ff/mln: & Vac. ("Hg): ^ - P ("H2O): Duct Width ("): Duct Length ("): Nozzle D1 (") 0: d> J21// Probe & Pitot ID: SS 0 -- Y Nozzle D2 (") <S>: ^ * J<73 Nozzle D3 (") 0: 0,J2 9a Average Nozzle D ("): ^ fp Sample Point Pe>f4~ Time Clock Run (min) DGM Volume (ft3) ip ("H20) AH ("H20) Source fa/ 0> 7.59-6)6 -.37 , 7/ /3o 0L *? 7S0.S1/ . 7.. /79 ? Y ?79, 3% 799 y 9 7S&. 77 ..is ,0( /So Jr 4? .3& / $ ? A /f 'U3~fS\ . 30 .69.. /J3 7 /% 7SY.4S *32 7 , 6,2. n.r % 3 / 7A ,3 7.. . dJL I9pk 9 '/79 /ss~. /# st 7 *768,94 1, 7 /V7 // /X /3Sd fUi-/ /30 9 J y 9 *770*3 i . 1>2> 31 77/9 6 3 / 37 773*087. 771.097 ..*29 39 777<2 , * 3 I/O 77A. 13 Y< 7 79 3 r9 . 7l /SO /S3 /0O72 ` ?o~ .03 ,74 /SY /SjT /so jr 9% 774.0 7- .90 /& A 9/ 0P>O.S8> . 33 ,70 )$C 7 3 Si 70S. <32 . ! ,7/ /SO $7 703.93... ......17 *> 63 /SL 9 do 70Y,7. 37 .$s /S3 p.o A3 706,07 3p . 7 9 /O..... // Ad 7/07.73 .9 /SI 72 f Q .on .7 (So /Ye C 9?o. 77/ Probe 24825 /7 Temperature OF) Filter 24825 Impinger Exit 68 DGM Inlet DGM Outlet Pump Vac. ("Hg) AY 0/ 0 O . S9 <9 s'n s .97 SB S ^0 ' s& 78 78 78 79 0t Si 8/ % ( 03 m m 1 78 / 70 l Of / 79 1 79 f 79 1 OO 70/ nl--------/ 79 m> if 09 ---- SA/V . &3 S3 SY ~~Ws~ 3 ffs .3 (80 3 ( SY 3 s9 81 _//> ss' &( Y - SB_ SS m Y 5 Q S> Sl 3 V s<3 78 "7 & i S9 BO g( 9 0 8% 8J? Y SO f)% IS/s c/ COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00375 AZCOM Client/Plant: pS Location: /jg/4- Impinger# 1 2 3 4 Impinger Contents Di HzO DIH2O Empty Silica Gel FIELD SAMPLING DATA SHEET ___________ (RECOVERY)___________ Date: j Run#: ) METHOD 13A/B Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD 4?/is>, 3 100 GS ^(14. L| -- MOD Lsis,, 1 (o5?,Z -- MOD 921. Z 93?. 5 Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (DI H20 Rinse) COMMENTS: Tare (g) Final (g) Gain (g) * ' 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00376 ABCOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE j-- OF a*f ^ f$io 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00377 Client/Plant: jR?S Location: a! Impinger# 1 2 3 4 Impinger Contents Dl H20 Dl HaO Empty Silica Gel FIELD SAMPLING DATA SHEET ___________ (RECOVERY)___________ METHOD 13A/B Project#: Ibo1IoZ2 /tj Condition: Date: 2-1- /to____________________ Run #: 2 Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD ^>1.5 9 96, z 100 GS (a 13-0 U>9/.tr. -- MOD UL(Z. O -- MOD Joi, O 9/tf.Z Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dl H20 Rinse) COMMENTS: Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00378 > AECOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE / OF J Client/Plant: CJ3 Project #: Location: ^ Condition: PGM#: a7->S K-Factor: r) , CF (Yd): F*bar( Hg): Initial Leak (<0.02 ft /min; >10"Hg) Final Leak / (<0.02 ft3/min; >max vacuum) Pitot Leak V (>3"H20) +P ("H2O) Probe & Pitot ID: ISOfYvM ft3/min: <2> ft3/min: @ Operators)\ ft)l, /j/Tn. Duration (min): 7 Cp: 0.84 Height w.r.t. Barometer (ft); static (*HjO): A Vac. fHg):/J Source Height (ft): |oO Duct Diameter Vac. ("Hg): ft) Duct Width ("); Duct Length ("): P ("H20): 6^ Nozzle D1 (") 0: <29 - Y / Nozzle P2(")Q: g? , ^ G Sample Point Time Clock Run (min) DGM Volume (ft3) AP fH20) AH ("H20) Source Probe 24825 Temperature ("F) Filter 248+25 Impinger Exit S68 DGM Inlet DGM Outlet Pump Vac. ("Hg) /ft /7& > '.JX3.. ,67 /o ^3 1 ? 76, .37 ,3 1 .- 7/ // (?3 i... 1 97 7.7/ ,33 .76 '/& A a. 03 / 9 9 93 9. Si 7 ,7V /S6 IT 79 8a ) S /? * 3 9_ _,y/? 7S6 6 /<r Sd3o ' ,37... ,I?9> /S2, 9 f? /...... f?6 fA 7 i 7 7 /S3 * 37 __jt-7 7,0 79f __9 &< ( 77 39,93 ,39.... ...Lj 7 ;S 3f>___ \ 9 //? d# .1 gix.ag *31- , 71 79/ 727 37,7/ *37 , 76 /SS // Xc> 3397 ,3.2 . 77 763 61 o>_ &l t f-y 5>( \ @6 ( / s?? WY&&7 *69 /SY /8i 3 &( )o3 7 ,.V--- ,97 / 9 ci9 / A 39 (93 7S9 > rj>` tyfX-cijrT!.' 0S~ <s ~&r 3s9- { .--- PI sdoP/j ') a 72 8*4.0 ft , 3f ,09 /& &( s> 9 ,37 .7/ 141 < 3/ s .. 77,96 , 37 *7% /d "&V > / < 6 SJ &Y9YSL *7/9 793 .S6 m /sS1 9 <9 3 A * ytf /Sf 7 %/ rA 8SA.I* .33 , ? 7> 9 6q <3,77 . 7 6 lK td> /? sss.aa .3/ \ 7/ /U // // 8SL(,X ,30 %9 &S7.4 7 /7?39 7'2 $59,311 J%697 /`yX /S9 _L l 9 sr 81 A S7 S Sjr7f S7 3T <3*-? 8/ 9i s^r <8( O' . cP I I COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00379 Client/Plant: W15 Location: #f> ij Impinger# 1 2 3 4 Impinger Contents Dl H20 D! H20 Empty Silica Gel FIELD SAMPLING DATA SHEET ____________ (RECOVERY)____________ METHOD 13A/B Date: 7~\~ b Run#: ^ Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 100 MOD (*35. .<> 100 GS U3.7 -- MOD (s>S(e- (o -- MOD L 9 Final (g) Gain (g) _ btt. v Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (D| H20 Rinse) COMMENTS: 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00380 A-COM FIELD SAMPLING DATA SHEET Flow and Moisture EPA Methods 2 & 4 PAGE ^ OF ^ Client/Plant: Project#: {^^&Z2sdklKD Date: to-- IL. Operator{s): L~? Location: Condition: Moisture Run #: Duration (min): DGM#: CF (Yd): AH@: . Cp: 0,84 PbarCHg): Height w.r,t. Barometer (ft): PstaticC`H20): ww Initial Leak S (<0.02 ft3/min; >1Q"Hg) ft3/min: Vac. ("Hg): Source Height (ft): tOo Duct Diameter f): Final Leak s (<0.02 ft3/min; >run maximum) ft3/min: Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak (>3"H20) +p ("H20): -P("H20): Pitot Tube ID#: Fyrite/Orsat 02 (%/time) Fyrite/Orsat C02 (%/time) % ( % ( Moisture Determination Time V " DGM Volume (ft3) L AH ("H20) DGM DGM inlet T Outlet T CO ) .% ( ) I' %( ) ) %( ) 1 %( ) Flow Run #: | Flow Run#: 2 Flow Run #: YVW TTto Traverse Start End Start End Start Point lYLO? IS U AP fH20) Source T (F) (*AHPO^pT* ^ > Source CD T AP CH20) End IS Cyclonic Angle (=} Source T CF) M (0 *h(sj KM w "iHTf tfr3x 6o*V> WV n/p V4? `\W 037 t44 \<n 0.3^ o.-'.r TmhT 6'^S- Ka G.'H d-'VL m o-yb iMc VTM 0 IS 0-30 "W (ML lSr) \rs c yj 0-3 H ix*? iTr 0-T>t $'3 ? n$r \$Q 0 rii IO OOH 0,wt~ ) So \ 0,'h'L ,f| \5t OrsM d.-5r 0 V.f) iSl O/Yl ID \4 .ifl 0.ft iky I? rye ^ASZ om i-r* on~i \n 0-T.S- 6-m 14 5? 6 -Ml 15'^ 0 ML- K5 <sn O-'Vt k) .Ml O.MM IMT o.tf 2 w 0-M^ P OH'S IHp TTfc op \d ww~ % 0-11 Uk O.'it, TIT \ 5~4 0 ^ 0-33 \tf & 6,<L<| 0-tl KF v sj ?> AJ) 0-S1 O'lP one IQ"? my (W '$-3 \Tr u> fj.lH o-t (? irt 0A1 0.%D Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523_00007569-00381 AECOM Plant Name MC 4 Project Number . (.Q Location (Source) C<A\ A.1iMfUkJ Meter ID a Cal Factors i) Sorbent Trap IDs 2) 6LOoh 7<r? Date 7-1 \ 0( | {q Condition A/CH'V^H/I Run \ Operator ( XS Bar. Press, (in. H20) 14 17 o Elevation (relative to Barometer) (ft) Trap Clock Time Volume (L, dry) Flo(LwpmRa) te bP (in. H20) Sorbent 1) 2) vm _____ S.-7.T 6 u.ir i) 2) mo \io fl -7 T ^ /?r 'll'} 1) 2) \i% <hn>q 6-?f- \Hn 0r7.C' 1) 2) r ilo \1.H0 o nc I'V'Sf 0 nc \b') in>L 1) 2) \ IMS' H.-M'L OnT \(..~7) 6.-7=: |SO lr>(> \5<b 1) 2) 1'LSO W ^ enf on $ in 1) 2) ttS-S fj.TC a ,ir t7f 1) 6~7,r |f3 2) \kTO T/. & 5 0--7C 1) 2) YboS /) "7C jia'o 0-7r |7_ IMS* 1) 2) I'M 0r?<T 7/ 0--7 r 1) 2) Vi\!> M,..fl... Mr 0 75" 1) IP155~ a.7c 2) Vi'20 U\.vo, 0 7<" In') 1) 2) vws> mmoT 0,-71 \SH mm 5M? OK- lol 1) 2) 1) 2) Page Initial Leak Rate \oO Final Leak Rate Third Bed Spike Level Temperature (F) Chiller HeatL-iTnreaced Ml IT Ho Mo Ho Ml Hi Hi Hz Hi. 4H MM of \ 1) O @ 2ST"Hg 2) C5 @ 2.5T "Hs 1) 6 @ "7 "Hg 2) O @ --) "Hg 1) %6'Cr0 A/M 2) Meter -C7' `.. V(ianc. uHugm) M7 ~u Ml ....Ml- nt -M - 1 ^n~ M i - 1 Ml * ( Ml - 1 % -1 -l M3 -( Uv| - 1 -1 Mm A * MY MS'MM M.t H<r 5 M sr ... M ... Me\ -f - i - f --t -i --i -- ** . ---/f---- --- Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production SOS-35: Mercury bv Sorbent Traa - Method 308 ED 001523 00007569-00382 r \ L x^ Ku, AECOM Plant Name %\ 2y>r,')' Date l^jjo}/f(,_________________ ________ _ Page \ of \ Project Number Location (Source) 4 ( ft It:, ^ U , i 5 Meter ID & Cal Factors i) CLm-wu Sorbent Trap IDs 2) 61AU 0H<>] Condition C/f(f<*6oj Run 'L Operator ly|3 1 Bar. Press, (in. H20) % ( Elevation (relative to Barometer) (ft) ' Initial teak 1) , Rate 2) O e n "Hg a @ I't "Hg Final Leak r 1) 0 ' ' ' , ` Rate. .v>n. 2) ?o y "Hg 2 "Hg Third Bed #' .... Spike Level 2) Da ' Trap Clock Time Volume (L, dry) Flow Rate (Lpm) fiP (In, H20) Sorbent 1) 2) L2 llo 15S- i) on 'VMS' r 2) 'S n<l l\-7T j Si i) 2) li-f Mr \n vo o.o'r 1r 040 1) 2) TfluTo 1W h -?r YSb i) 2) m <r \H~7yA i V""'' fe/7 * 6 -~ar \5A 115' i) 2) WiS \(AU(y V>* \Hi 61?$" ftr?r i) 2) \M10 M 7TE5 0 -,'9 IkTi. 6.-7r i) 2) tqn TS-bSX S M(g O-OT- r 6^7 lo) i) aao 0<7C 2) HS ,i.oa ISl 1) 2) Hlf o-itr Or7S~ VsO i) 2) Hit) \a on*T tnf- tic i) 2) mss' OPT 151 ISr i) 2) m OfTSl .Mytyt fng H& td 1) Temperature (F) Chiller Heat-Traced Line M'H q<r qq (p Mi vfC Mq 0 Ht Meter Vacuum (in, Hg) w<r Vl -1 5M 5^ .$5 Hi U4 So HA Hi id Mm ? -), Hi MMit j * Hi H Mm Mm ST_ 5*0 2) 1) 2) Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production SOS-35: Mercury by Sorbent Trap - Method 30B ED 001523 00007569-00383 A=COM Plant Name p (_ Project Number Location (Source) Cc4.(4 Meter ID & Cal Factors VO M Sorbent Trap IDs 2) amw Date i(f Condition .McaTvWvA Run Operator Bar. Press, (in. H20) Aj\. A Elevation (relative to Barometer) (ft) \ ($@ Page \ Initial Leak 1) Rate 2) Final Leak 1) Rate 2) Third Bed 1) Spike Level 2) of \ O @ Q "Hg 0 @ 9 "Hg @ "Hg @ "Hg % 6V^ /\/g Trap Clock Time Volume (L, dry) Flow Rate (Lpm) 4P (in. HjO) Sorbent 1) \Sos 0 O-HS* i 2) D 6 n c '1^ 1) |DlO bnc lbt| zsi 2) HAS 0 rrC 1) V-\S n.r\ &n<r j_jY_ 14a 5H| 2) On S' 1) 2) 1 S'LjD io An nr 0.~7T 15 > aH) 1) 2) \ S'Lb V4,^7 5" 0:75" 1 S.M6 s'7T \ss; 141 1) 2) 1^1)0 Ww bns~ 0~7<r l5o TS\ 1) 2) flK-<0 Islxo 5-"7C 0-7C tb t 1ST- 1) OHO 2) 0r^ ^ 'TC.-Ji, O.-7 c OG US) 1) Vins &ncr 2) On `LHA^b C 1) 2) V&S6 'ii-pi Mi/* br?C 0n<~ 54 \ 'bo1-j 1) ll&SS 2) ^>SA\ ~%.\0 0 '"-7 )bl OrllT 1) \ Loo 2) o-ir 077 c \5 > lob 1 V) ____ l__ 1) "WW \k( 0i7<f 2) e)n<r an 1) 2) 1) 2) Comments: Temperature (F) Chiller Heat-Traced Line 47 V 46 46 L| i M (42 HI Hg ' Hi? MS MS M6 45 45 Meter So S7 Tl S*L 7 ST) Si sn si s\ Sj S'2 S 1 Si-- ...1.1 Si 5-*L s\ S \ S 0 So S \ sx> Vacuum (in. Hg) **- \ ~t A - i A ~\ -I -- \ nAf~ A A A A A -\ - \ -( A .Hi -l 1 17cv1906 Sierra Club v. EPA - 6/22 Production SOS-35: Mercurv bv Sorbent Tran - Method 30B ED 001523 00007569-00384 A-5 Calciner No. 5 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00385 PCS Phosphate Operations - Stack Test Results Test Information Location Product Source Stack ID No Start Date Pollutant Method Calciner No. 5 Single Float Calcined Rock WESP 205 1 26 20'6 Particulate 5/202 Production Data Date Feed Rate, Wet, TPH (During Test) Bulk Moisture of Rock (Lab Analyses) Rock Feed Rate Dry, TPH Lbs. Coal/Ton of Dry Feed Coal Feed, TPH Process Weight Rate, TPH Loss On Ignition Production Rate During Test, TPH Product 1/26/2016 67.2 12.30% 59.0 46.67 1.38 60.3 2.98% 57.2 Test Parameters/Conditions Green indicates hard entry Stack Gas Flow Rate Calculations Stack Flow Rate, DSCFM_______________________ Sample Volume (DSCF)________________________ Condensable Particulate Determination. Inorganic Fraction |Net Sample Weight, mg Condensable Particulate Determination, Organic Fraction Net Sample Weight, mg Train Blank, mg________ CPM, mg/DSCF 35.675 42.390 Run 1 11.27 11.40 0.4876 Particulate Determination, Filterable Beaker Final Weight, mg Final Filter Weight, mg Net Sample Weight, mg Mg Particulate/DSCF Mg Particulate/DSCF, Averaged for Wash Cycle Procedures grams/DSCM Total Particulate Determination PM Emission Rate, Lbs./Hr - Filterable PM Emission Rate, Lbs./Hr - Condensable-Inorganic PM Emission Rate, Lbs./Hr - Condensable-Organic PM Emission Rate, Lbs./Hr -Total Condensable (corrected with train blank) PM Emission Rate, Lbs./Hr - Total Particulate Average Daily PM Emission Rate, Lbs./Hr - Filterable Average Daily PM Emission Rate, Lbs./Hr-Condensible Average Daily PM Emission Rate, Lbs./Hr - Total Particulate PM Emission Rate, Lbs./Day PM Emission Rate, grams/dscm PM Emission Rate, grains/dscf Allowable PM Rate, grain/dscf 0.90 12.31 13.21 0.3116 0.0110 1.47 1.25 1.27 2.30 3.77 37.653 44.861 Run 2 5.52 1.38 2.30 0.1092 21.03 65.23 86.26 1.9228 0.0679 9.58 0.61 0.15 0.54 10.12 35.630 42.055 36,319 43.102 Run 3 9.59 Average N/A 1.54 0.2171 N/A N/A 0.2713 1.05 4.67 5.72 0.1360 0.0048 0.64 1.07 0.17 1.02 1.66 N/A N/A N/A 0.7902 0.3088 0.0279 3.90 0.98 0.53 1.29 5.19 1.482 1.606 3.088 74.114 0.0109 0.005 0.080 Calciner 5_Prod data calc-Updated 3.8 17cv1906 Sierra Club v. EPA - 6/22 Production Top ED 001523 00007569-00386 Data For Avg Daily Emission Rate Calculation (inputs in red cells only) Total PM Ibs/hr Total PM Ibs/hr Run with wash (enter cell address) (Es) Ave Hrs washing per 24 Hrs (S) Run Time, Hours Wash Time during test in hours (A) Filterable PM Ibs/hr Filterable PM Ibs/hr Run with wash (enter cell address) (Es) Ave Hrs washing per 24 Hrs (S) Run Time, Hours Wash Time during test in hours (A) Run Time During test not Washing in hours (B) Filterable PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) Condensible PM Ibs/hr Condensible PM Ibs/hr Run with wash (enter cell address) (Esl Ave Hrs washing per 24 Hrs (S) Run Time, Hours Wash Time during test in hours (A) Run Time During test not Washing in hours (B) Condensible PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) PM Emission rate g/dscm Filterable PM g/dscm Run with wash (enter cell address) (Es^ Ave Hrs washing per 24 Hrs (S) Run Time, Hours Wash Time during test in hours (A) Run Time During test not Washing in hours (B) Filterable PM g/dscm Avg of two non-wash runs (enter cell addresses)(EN) PM Emission rate mq/dscf Wash Time during test in hours (A) Run Time During test not Washing in hours (B) Filterable PM mg/dscf Avg of two non-wash runs (enter cell addresses)(EN) 'Water Wash Performed on Run 2 (R=24hrs) Eavg= EsS (A+BJ/AR) En (((R-S)/R)-(BS/AR)) Calciner 5_Prod data calc-Updated 3.8 17cv1906 Sierra Club v. EPA - 6/22 Production Top ED 001523 00007569-00387 Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner # 5 Condition Normal Sample Type: Method 5/202 Run Number: 1 Date: 26-Jan-16 2 26-Jan-16 3 26-Jan-16 Total Sampling Time (min) Corrected Barometric Pressure (in Hg) Absolute Stack Pressure (in H20) Stack Static Pressure (in H20) Average Stack Temperature (F) Stack Area (sq in) Actual Meter Volume (cu ft) Average Meter Pressure (in H20) Average Meter Temperature (F) Moisture Collected (g) Carbon Dioxide Concentration (%V) 72.0 30.06 30.04 -0.22 157.7 4072 42.041 1.17 81.6 407.6 7.7 72.0 30.06 30.04 -0.22 158.0 4072 43.986 1.31 75.7 405.5 7.7 72.0 30.07 30.05 -0.22 159.4 4072 41.035 1.19 73.1 435.4 7.7 Oxygen Concentration (%V) Nitrogen Concentration (%V) 13.5 78.8 13.5 78.8 13.5 78.8 Dry Gas Meter Factor (y5) 1.0266 1.0266 1.0266 Nozzle Diameter (in) Pitot Constant 0.280 0.84 0.280 0.84 0.280 0.84 Average Sampling Rate (dscfm) Standard Metered Volume (dscf) Standard Metered Volume (dscm) Stack Moisture (%V) Saturated Moisture (%V) Mole Fraction Dry Stack Gas Dry Molecular Weight Wet Molecular Weight Average SORT of Delta P Stack Gas Velocity (fps) Stack Gas Velocity (mps) Volumetric Flow Rate (acfm) Volumetric Flow Rate (acmm) Volumetric Flow Rate (dscfm) Volumetric Flow Rate (dscmm) Percent Isokinetic Post Test Meter QA (yqa) 0.589 42.390 1.200 31.2 29.9 0.701 29.77 26.25 0.55 34.9 10.7 59289 1679 35675 1010 109.2 0.9944 0.623 44.861 1.270 29.9 30.6 0.701 29.77 26.25 0.58 36.9 11.2 62594 1773 37653 1066 109.5 1.0008 0.584 42.055 1.191 32.8 31.4 0.686 29.77 26.08 0.56 35.7 10.9 60627 1717 35630 1009 108.5 1.0204 Average 72.0 30.06 30.05 -0.22 158.4 4072 42.354 1.22 76.8 416.2 7.7 13.5 78.8 1.0266 0.280 0.84 0.599 43.102 1.221 31.3 30.6 0.696 29.77 26.19 0.56 35.9 10.9 60837 1723 36319 1029 109.0 1.0052 Calciner#5M5 202.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run Summary ED 001523 00007569-00388 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Based on Hg Runs C02 Percent Replicate 1 7.7 Replicate 2 Replicate 3 Average 7.7 Method 5/202 PCS Phosphate 60402248 Calciner# 5 Normal N-44 1.0266 3.0 30.16 02 Percent 13.5 13.5 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft) Static Pressure (Ps Stack Geometry (R or C)? Stack Diameter (in] Stack Width (If Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 78.8 Nozzle ID (in) 1/26/2016 DM/LB 1 3.82 1.9218 0.84 100 -0.22 c 72.0 0.276 0.285 0.27S 0.28G impinger Weights (g) initial Final Net impinger 1 483.6 835.8 352.2 Impinger 2 544.8 573.4 28X impinger 3 721.0 732.8 11.8 impinger 4 895.8 910.8 15.C impinger 5 OX impinger 6 0.0 impinger 7 O.C impinger 8 OX Moisture Collected (g) 407X Pitot Tube ID 6-4 Saturated Percent Moisture 29.90 Standard Calculated Percent Moisture isokinetic % 31.19 109.2 Volume (dsef) 42.4 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 14:45:00 14:48:00 14:51:00 14:54:00 14:57:00 15:00:00 15:03:00 15:06:00 15:09:00 15:12:00 15:15:00 15:18:00 15:21:00 15:28:00 15:31:00 15:34:00 15:37:00 15:40:00 15:43:00 15:46:00 15:49:00 15:52:00 15:55:00 15:58:00 16:01:00 16:04:00 Dry Gas Meter Reading Vm (ft3) 193.675 195.300 196.650 198.550 200.100 201.600 203.900 205.300 206.600 208.100 209.800 211.900 213.441 213.441 216.200 217.950 219.900 221.900 223.600 225.400 227.200 229.100 231.100 232.800 234.700 235.716 Velocity Head (AP) (in H20) 0.23 0.22 0.21 0.25 0.25 0.25 0.32 0.30 0.30 0.33 0.37 0.34 0.36 0.40 0.36 0.35 0.35 0.33 0.34 0.30 0.31 0.29 0.30 0.25 Orifice Pressure Diff (AH) (in H20) 0.88 0.84 0.80 0.96 0.96 0.96 1.22 1.15 1.15 1.26 1.41 1.30 1.40 1.50 1.40 1.40 1.30 1.20 1.30 1.20 1.20 1.10 1.20 0.96 Stack Temp Ts (F) 156 152 159 157 152 152 153 157 158 156 153 162 158 161 159 158 162 157 158 161 160 162 162 159 Dry Gas Meter Temperature Tm in Tm out (F) (F) 75 79 78 80 78 80 78 82 77 83 78 85 78 84 78 86 78 86 78 86 78 86 78 86 80 85 79 85 79 86 80 86 79 86 81 87 78 86 82 86 80 86 78 86 78 86 78 87 Calciner #5 M5_202.xisx Run 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00389 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Based on Hg Runs C02 Percent Replicate 1 7.7 Replicate 2 Replicate 3 Average 7.7 Method 5/202 PCS Phosphate 60402248 Calciner# 5 Normal N-44 1.0266 3.0 30.16 02 Percent 13.5 13.5 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft) Static Pressure (Ps Stack Geometry (R or C)? Stack Diameter (in] Stack Width (If Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 78.8 Nozzle ID (in) 1/26/2016 DM/LB 2 3.82 1.9218 0.84 100 -0.22 c 72.0 0.276 0.285 0.27S 0.28G impinger Weights (g) initial Final Net impinger 1 501.4 867.8 366.4 Impinger 2 592.1 598.7 6.6 impinger 3 696.4 706.5 10.1 impinger 4 856.7 879.1 22.4 impinger 5 0.0 impinger 6 0.0 impinger 7 0.0 impinger 8 o.c Moisture Collected (g) 405.* Pitot Tube ED 6-4 Saturated Percent Moisture 30.63 Standard Calculated Percent Moisture 29.88 Volume (dsef) isokinetic % 109.5 44.9 Traverse Point Location B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 16:50:00 16:53:00 16:56:00 16:59:00 17:02:00 17:05:00 17:08:00 17:11:00 17:14:00 17:17:00 17:20:00 17:23:00 17:26:00 18:09:00 18:12:00 18:15:00 18:18:00 18:21:00 18:24:00 18:27:00 18:54:00 18:57:00 19:00:00 19:03:00 19:06:00 19:09:00 Dry Gas Meter Reading Vm (ft3) 235.990 237.900 239.600 241.500 243.600 245.400 247.100 248.900 250.800 252.500 254.100 255.800 257.318 257.318 258.700 260.556 262.100 264.000 265.800 267.300 269.265 271.300 273.400 274.500 276.500 279.976 Velocity Head (AP) (in H20) 0.40 0.40 0.39 0.43 0.36 0.32 0.34 0.38 0.39 0.32 0.28 0.21 0.29 0.28 0.29 0.28 0.33 0.34 0.36 0.35 0.34 0.35 0.34 0.36 Orifice Pressure Diff (AH) (in H20) 1.50 1.50 1.50 1.60 1.40 1.20 1.30 1.50 1.50 1.20 1.10 0.80 1.10 1.10 1.10 1.10 1.30 1.40 1.40 1.40 1.30 1.40 1.30 1.40 Stack Temp Ts (F) 162 164 159 157 154 160 161 161 161 154 159 157 159 161 154 151 156 156 160 156 156 158 160 156 Dry Gas Meter Temperature Tm in Tm out (F) (F) 76 78 75 77 77 78 74 79 74 81 74 80 76 80 76 81 74 81 74 79 74 78 74 79 76 79 74 80 74 77 73 77 72 75 72 77 72 77 69 72 69 73 72 74 72 76 72 79 Calciner #5 M5_202.xisx Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00390 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Based on Hg Runs C02 Percent Replicate 1 7.7 Replicate 2 Replicate 3 Average 7.7 Method 5/202 PCS Phosphate 60402248 Calciner# 5 Normal N-44 1.0266 3.0 30.17 02 Percent 13.5 13.5 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft) Static Pressure (Ps Stack Geometry (R or C)? Stack Diameter (in] Stack Width (If Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 78.8 Nozzle ID (in) 1/26/2016 DM/LB 3 3.82 1.9218 0.84 100 -0.22 c 72.0 0.276 0.285 0.27S 0.28G impinger Weights (g) initial Final Net impinger 1 485.7 893.9 408.2 Impinger 2 652.3 661.5 9.2 impinger 3 608.8 611.5 2.7 impinger 4 910.8 926.1 15.3 impinger 5 O.C impinger 6 0.0 impinger 7 O.C impinger 8 O.C Moisture Collected (g) 435.4 Pitot Tube ID 6-4 Saturated Percent Moisture 31.36 Standard Calculated Percent Moisture 32.80 Volume (dsef) isokinetic % 108.5 42.1 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 20:00:00 20:03:00 20:06:00 20:09:00 20:12:00 20:15:00 20:18:00 20:21:00 20:24:00 20:27:00 20:30:00 20:33:00 20:36:00 20:38:00 20:41:00 20:44:00 20:47:00 20:50:00 20:53:00 20:56:00 20:59:00 21:02:00 21:05:00 21:08:00 21:11:00 21:14:00 Dry Gas Meter Reading Vm (ft3) 280.845 282.800 284.000 285.900 287.600 289.200 291.200 292.300 294.000 295.300 297.100 299.300 300.569 300.569 302.400 304.400 306.500 308.200 310.200 312.100 314.100 315.700 316.800 318.800 320.200 321.880 Velocity Head (AP) (in H20) 0.24 0.27 0.28 0.27 0.28 0.27 0.29 0.30 0.32 0.35 0.36 0.37 0.35 0.40 0.39 0.39 0.38 0.36 0.37 0.29 0.26 0.27 0.25 0.26 Orifice Pressure Diff (AH) (in H20) 0.96 1.00 1.10 1.00 1.00 1.00 1.10 1.10 1.20 1.30 1.40 1.40 1.30 1.50 1.50 1.50 1.50 1.40 1.40 1.10 0.90 1.00 0.96 0.99 Stack Temp Ts (F) 161 159 157 158 159 160 160 161 160 156 161 159 161 160 161 162 159 162 160 157 157 157 159 160 Dry Gas Meter Temperature Tm in Tm out (F) (F) 65 69 67 72 66 69 67 69 66 69 68 76 72 76 76 78 76 78 74 78 75 79 74 79 72 76 73 78 72 78 74 80 71 78 69 77 70 75 69 76 70 77 70 76 69 75 70 76 Calciner #5 M5_202.xisx Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00391 Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner # 5 Condition Normal Sample Type: Method 13B Run Number: 1 Date: 27-Jan-15 2 27-Jan-15 3 27-Jan-16 Total Sampling Time (min) 72.0 72.0 72.0 Corrected Barometric Pressure (in Hg) 30.02 29.99 30.02 Absolute Stack Pressure (in H20) 30.00 29.97 30.00 Stack Static Pressure (in H20) -0.25 -0.25 -0.25 Average Stack Temperature (F] 153.4 154.5 150.2 Stack Area (sq in) 4072 4072 4072 Actual Meter Volume (cu ft) 32.469 33.952 34.149 Average Meter Pressure (in H20) Average Meter Temperature (F) 0.75 54.9 0.82 52.4 0.83 48.4 Moisture Collected (g) 306.9 280.4 284.6 Carbon Dioxide Concentration (%V) 13.5 13.5 13.5 Oxygen Concentration (%V) Nitrogen Concentration (%V) 7.7 78.8 7.7 78.8 7.7 78.8 Dry Gas Meter Factor (y5) 1.0266 1.0266 1.0266 Nozzle Diameter (in) 0.250 0.250 0.250 Pitot Constant 0.84 0.84 0.84 Average Sampling Rate (dscfm) 0.477 0.501 0.508 Standard Metered Volume (dscf) 34.358 36.074 36.602 Standard Metered Volume (dscm) 0.973 1.022 1.036 Stack Moisture (%V) Saturated Moisture (%V) 29.6 27.2 26.8 27.9 26.8 25.2 Mole Fraction Dry Stack Gas Dry Molecular Weight 0.728 30.47 0.732 30.47 0.748 30.47 Wet Molecular Weight Average SORT of Delta P 27.08 0.55 27.13 0.57 27.32 0.58 Stack Gas Velocity (fps) 34.2 35.6 35.6 Stack Gas Velocity (mps) Volumetric Flow Rate (acfm) 10.4 58005 10.9 60433 10.9 60478 Volumetric Flow Rate (acmm) 1643 1711 1713 Volumetric Flow Rate (dscfm) 36463 38063 39234 Volumetric Flow Rate (dscmm) 1033 1078 1111 Percent Isokinetic 108.6 109.2 107.5 Post Test Meter QA (yqa) 0.9970 0.9915 0.9897 Average 72.0 30.01 29.99 -0.25 152.7 4072 33.523 0.80 51.9 290.6 13.5 7.7 78.8 1.0266 0.250 0.84 0.496 35.678 1.010 27.8 26.8 0.736 30.47 27.18 0.56 35.2 10.7 59639 1689 37920 1074 108.5 0.9927 Fluoride Emission Rate Calculations Orion 901 Meter Reading, ppm_________ 0.211 Liquid Sample Volume, ml______________ 1000 Sample Aliquot________________________ 10 Sample Dilution_______________________ 10 Total Fluoride, mg_____________________ 0.2110 Fluoride Concentration, mg/DSCF_______ 0.0061 Fluoride Emissions, lbs F/hr 0.0296 Rock Feed (Wet TPH)_________________ 67.20 Fluoride Emissions, lbs F/Ton Rock Feed 0.0004 Calciner #5 M13B WetTPH.xIsx 0.186 1000 10 10 0.1860 0.0052 0.0260 67.20 0.0004 0.104 1000 10 10 0.1035 0.0028 0.0147 67.20 0.0002 Average N/A N/A N/A N/A 0.1668 0.0047 0.0234 67.2 0.0003 Run Summary 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00392 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method From Hg Test runs C02 Percent Replicate 1 13.5 Replicate 2 Replicate 3 Average 13.5 Method 13B PCS Phosphate 60402248 Calciner#5 Normal N-44 1.0266 3.0 30.12 02 Percent 7.7 7.7 Date Operator Run Number K Factor Meter AH@ Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 78.8 Nozzle ID (in) 1/27/2015 WL\BM 1 2.50 1.9218 0.84 100 -0.25 c 72.0 0.250 0.250 0.250 0.250 Impinger Weights (g) Initial Final Net Impinger 1 641.5 923.9 282.4 Impinger 2 722.5 737.3 14.8 Impinger 3 655.7 657.7 2.0 Impinger 4 916.3 924.0 7.7 Impinger 5 0.0 Impinger 6 0.0 Impinger 7 0.0 Impinger 8 0.0 Moisture Collected (g) 306.9 Pitot Tube ID 6-4 Saturated Percent Moisture 27.17 Standard Calculated Percent Moisture 29.63 Volume (dscf) Isokinetic % 108.6 34.4 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Calciner#5 M13B WetTPH.xisx Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 11:38:00 11:41:00 11:44:00 11:47:00 12:16:00 12:19:00 12:22:00 12:25:00 12:28:00 12:31:00 12:34:00 12:37:00 12:40:00 12:44:00 12:47:00 12:50:00 12:53:00 12:56:00 12:59:00 13:02:00 13:05:00 13:08:00 13:11:00 13:14:00 13:17:00 13:20:00 Dry Gas Meter Reading Vm (ft3) 322.211 323.580 325.010 326.530 327.710 329.150 330.480 331.680 332.970 334.160 335.480 336.810 338.116 338.116 339.330 340.570 341.900 343.210 344.580 346.060 347.580 349.220 350.390 351.840 353.260 354.680 Velocity Head (AP) (in H20) 0.31 0.35 0.38 0.33 0.33 0.29 0.25 0.25 0.24 0.28 0.28 0.28 0.23 0.26 0.27 0.27 0.31 0.35 0.37 0.32 0.30 0.33 0.33 0.33 Orifice Pressure Diff (AH) (in H20) 0.77 0.87 0.95 0.82 0.82 0.72 0.62 0.62 0.60 0.70 0.70 0.70 0.57 0.65 0.67 0.67 0.77 0.87 0.92 0.80 0.75 0.82 0.82 0.82 Stack Temp Ts (F) 152 160 157 155 154 150 158 157 153 150 152 155 157 157 146 149 157 151 150 153 153 153 151 152 Dry Gas Meter Temperature Tm in Tm out (F) (F) 53 53 53 54 54 53 54 53 53 53 53 52 53 52 53 52 53 53 54 53 55 53 56 53 57 54 57 54 58 54 58 54 58 54 59 54 59 55 59 55 59 55 59 55 60 55 60 55 Run 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00393 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method From Hg Test runs C02 Percent Replicate 1 13.5 Replicate 2 Replicate 3 Average 13.5 Method 13B PCS Phosphate 60402248 Calciner#5 Normal N-44 1.0266 3.0 30.09 02 Percent 7.7 7.7 Date Operator Run Number K Factor Meter AH@ Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 78.8 Nozzle ID (in) 1/27/2015 WL\BM 2 2.50 1.9218 0.84 100 -0.25 c 72.0 0.250 0.250 0.250 0.250 Impinger Weights (g) Initial Final Net Impinger 1 759.1 1012.9 253.8 Impinger 2 687.3 704.4 17.1 Impinger 3 640.8 642.3 1.5 Impinger 4 899.6 907.6 8.0 Impinger 5 0.0 Impinger 6 0.0 Impinger 7 0.0 Impinger 8 0.0 Moisture Collected (g) 280.4 Pitot Tube ID 6-4 Saturated Percent Moisture 27.87 Standard Calculated Percent Moisture 26.82 Volume (dscf) Isokinetic % 109.2 36.1 Traverse Point Location B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 Calciner#5 M13B WetTPH.xisx Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 13:40:00 13:43:00 13:46:00 13:49:00 13:52:00 13:55:00 13:58:00 14:01:00 14:04:00 14:07:00 14:10:00 14:13:00 14:16:00 14:28:00 14:31:00 14:34:00 14:37:00 14:40:00 14:43:00 14:46:00 14:49:00 14:52:00 14:55:00 14:58:00 15:01:00 15:04:00 Dry Gas Meter Reading Vm (ft3) 354.918 356.210 357.510 358.720 360.170 361.510 363.000 364.480 365.990 367.470 369.050 370.570 372.010 372.010 373.520 375.020 376.480 377.970 379.560 380.950 382.310 383.580 384.870 386.180 387.540 388.870 Velocity Head (AP) (in H20) 0.26 0.28 0.30 0.28 0.31 0.34 0.38 0.35 0.37 0.42 0.35 0.35 0.39 0.35 0.34 0.37 0.36 0.32 0.35 0.27 0.25 0.28 0.30 0.28 Orifice Pressure Diff (AH) (in H20) 0.65 0.70 0.75 0.70 0.77 0.85 0.95 0.87 0.92 1.05 0.87 0.87 0.97 0.87 0.85 0.92 0.90 0.80 0.87 0.67 0.62 0.70 0.75 0.70 Stack Temp Ts (F) 150 157 157 156 154 155 153 154 155 159 152 153 160 156 159 152 155 157 154 155 149 151 153 153 Dry Gas Meter Temperature Tm in Tm out (F) (F) 56 54 56 54 55 54 56 53 55 52 55 52 55 52 55 52 55 51 55 51 52 49 52 49 53 50 53 49 50 49 54 49 54 49 55 49 55 49 55 49 54 49 54 49 54 49 54 49 Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00394 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method From Hg Test runs C02 Percent Replicate 1 13.5 Replicate 2 Replicate 3 Average 13.5 Method 13B PCS Phosphate 60402248 Calciner#5 Normal N-44 1.0266 3.0 30.12 02 Percent 7.7 7.7 Date Operator Run Number K Factor Meter AH@ Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 78.8 Nozzle ID (in) 1/27/2016 WL\BM 3 2.50 1.9218 0.84 100 -0.25 c 72.0 0.250 0.250 0.250 0.250 Impinger Weights (g) Initial Final Net Impinger 1 633.5 856.2 222.7 Impinger 2 731.1 786.5 55.4 Impinger 3 656.1 657.0 0.9 Impinger 4 923.8 929.4 5.6 Impinger 5 0.0 Impinger 6 0.0 Impinger 7 0.0 Impinger 8 0.0 Moisture Collected (g) 284.6 Pitot Tube ID 6-4 Saturated Percent Moisture 25.24 Standard Calculated Percent Moisture 26.83 Volume (dscf) Isokinetic % 107.5 36.6 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Calciner#5 M13B WetTPH.xisx Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 16:20:00 16:23:00 16:26:00 16:29:00 16:32:00 16:35:00 16:38:00 16:41:00 16:44:00 16:47:00 16:50:00 16:53:00 16:56:00 16:59:00 17:02:00 17:05:00 17:08:00 17:11:00 17:14:00 17:17:00 17:20:00 17:23:00 17:26:00 17:29:00 17:32:00 17:35:00 Dry Gas Meter Reading Vm (ft3) 389.116 390.420 391.780 393.170 394.640 396.110 397.550 398.990 400.340 401.570 402.950 404.260 405.588 405.588 406.940 408.360 409.690 411.100 412.580 414.150 415.640 417.180 418.610 420.150 421.730 423.265 Velocity Head (AP) (in H20) 0.26 0.31 0.31 0.36 0.35 0.33 0.35 0.28 0.26 0.31 0.29 0.29 0.29 0.30 0.31 0.34 0.36 0.40 0.36 0.38 0.35 0.39 0.40 0.40 Orifice Pressure Diff (AH) (in H20) 0.65 0.77 0.77 0.90 0.87 0.82 0.87 0.70 0.65 0.77 0.72 0.72 0.72 0.75 0.77 0.85 0.90 1.00 0.90 0.95 0.87 0.97 1.00 1.00 Stack Temp Ts (F) 150 151 146 141 143 149 142 155 154 149 154 153 145 156 155 150 154 146 155 150 154 153 150 149 Dry Gas Meter Temperature Tm in Tm out (F) (F) 46 46 46 46 46 45 47 45 47 45 48 45 49 45 49 45 50 46 50 45 50 45 50 45 50 46 51 47 52 47 53 47 53 47 53 47 54 48 54 47 54 48 54 48 54 48 54 48 Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00395 AECONi PCS Phosphate Calciner #5 Mercury Emission Calculations EPA Method 30B Emission Results 02 Correction Basis 3 Pollutant: Mercury Run 1 2 3 AVERAGE Total Hg Catch ng 2643 2460 2337 2480 Sample Volume dscm 0.050 0.048 0.047 0.048 Hg Concentration mg/dscm 0.0533 0.0508 0.0499 0.0513 Hg Concentration ppmV 0.0064 0.0061 0.0060 0.0061 Oxygen % 13.5 13.5 13.5 13.5 Hg Concentration mg/dscm @ 3% 0.129 0.123 0.121 0.125 Flow Rate dscfm 35.540 37,753 35.340 36,211 Calciner _5 30B _Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Mercury ED 001523 00007569-00396 Method 2 Velocilty Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure i PCS 60402248.1 Calciner#5 Normal -0.22 100 29.71 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) 2/9/2016 DM/WL 0.84 C 72.0 4071.5 29.61 29.59 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 30.35 30.35 0.696 29.77 26.20 Velocity Head (AR) (in H20) 0.24 0.23 0.21 0.26 0.27 0.26 0.32 0.29 0.30 0.34 0.36 0.34 0.35 0.41 0.37 0.36 0.36 0.34 0.33 0.31 0.33 0.30 0.30 0.26 Stack Temp Ts (F) 155 157 157 159 162 162 156 155 159 155 162 160 158 162 155 149 154 155 162 155 155 159 161 158 Square Root of AZP SQRT(AR) 0.490 0.480 0.458 0.510 0.520 0.510 0.566 0.539 0.548 0.583 0.600 0.583 0.592 0.640 0.608 0.600 0.600 0.583 0.574 0.557 0.574 0.548 0.548 0.510 Average Stack Average SQRT Temp AP 157.58 0.55 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) Stack Gas Velocity (fps) 31.3 30.7 29.4 32.7 33.4 32.8 36.2 34.4 35.1 37.3 38.6 37.4 37.9 41.2 38.9 38.2 38.3 37.3 37.0 35.6 36.7 35.1 35.2 32.7 Average Velocity 35.57 60345 51029 35540 Calciner_5 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R1 ED 001523 00007569-00397 Method 2 Velocilty Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 2 PCS 60402248.1 Calciner#5 Normal -0.22 100 29.75 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 7.66 7.7 02 Percent 13.53 13.5 N2 Percent 78.8 ] Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 28.88 28.88 0.711 29.77 26.37 2/9/2016 DM/WL 0.84 C 72.0 4071.5 29.65 29.63 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AR) (in H20) 0.38 0.41 0.40 0.44 0.35 0.33 0.34 0.39 0.35 0.29 0.25 0.23 0.31 0.29 0.29 0.28 0.32 0.34 0.36 0.34 0.35 0.33 0.34 0.35 Stack Temp Ts (F) 149 156 156 155 153 157 155 154 154 152 153 151 160 162 155 153 156 156 162 158 158 156 160 157 Square Root of A/P SQRT(AR) 0.616 0.640 0.632 0.663 0.592 0.574 0.583 0.624 0.592 0.539 0.500 0.480 0.557 0.539 0.539 0.529 0.566 0.583 0.600 0.583 0.592 0.574 0.583 0.592 Average Stack Average SQRT Temp AP 155.75 0.58 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) Stack Gas Velocity (fps) 39.1 40.8 40.3 42.3 37.6 36.7 37.1 39.8 37.7 34.2 31.8 30.5 35.6 34.5 34.3 33.7 36.1 37.2 38.4 37.2 37.8 36.6 37.3 37.8 Average Velocity 36.85 62506 53086 37753 Calciner_5 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R2 ED 001523 00007569-00398 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 3 PCS 60402248.1 Calciner #5 Normal -0.22 100 29.79 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 7.66 7.7 02 Percent 13.53 N2 Percent 13.5 78.8 i Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 31.77 31.77 0.682 29.77 26.03 2/9/2016 DM/WL 0.84 C 72.0 4071.5 29.69 29.67 Traverse Point Location B1 2 3 4 5 6 7 8 9 10 11 12 A1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (A8) (in H20) 0.25 0.26 0.28 0.28 0.30 0.29 0.28 0.31 0.32 0.34 0.36 0.35 0.36 0.41 0.38 0.38 0.40 0.37 0.37 0.31 0.27 0.26 0.25 0.24 Stack Temp Ts (F) 160 161 157 157 158 161 160 160 161 162 159 158 162 159 160 162 160 159 163 161 158 158 157 159 Square Root of AiP SQRT(AB) 0.500 0.510 0.529 0.529 0.548 0.539 0.529 0.557 0.566 0.583 0.600 0.592 0.600 0.640 0.616 0.616 0.632 0.608 0.608 0.557 0.520 0.510 0.500 0.490 Average Stack Average SORT Temp AP 159.67 0.56 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) Stack Gas Velocity (fps) 32.2 32.8 34.0 34.0 35.2 34.7 34.0 35.8 36.4 37.6 38.6 38.0 38.7 41.2 39.7 39.7 40.7 39.1 39.2 35.9 33.4 32.8 32.1 31.5 Average Velocity 36.13 61287 51791 35340 Calciner_5 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R3 ED 001523 00007569-00399 ACCOM Date 2/9/2016 Plant PCS Phosphate Location Calciner#5 Sample Type 30 B Run Number/Side (A/B) 1 Operator WL/DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min (a) "Hg) 0.000 11 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL328488 29.61 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002494 1.0180 1.0180 72 Page 1 of Run No. Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) 0 14:15:00 5 14:20 10 14:25 15 14:30 20 14:35 25 14:40 30 14:45 35 14:50 40 14:55 45 15:00 50 15:05 55 15:10 60 15:15 Digital Gas Meter Reading (L) 0.000 5.74 9.61 13.34 17.09 20.70 24.56 28.27 32.32 36.30 40.35 43.88 48.268 48.268 Mechanical Gas Meter Reading (m3) 48.2680 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) 160 Trap Temp, (deg. F) 311 314 300 275 276 276 277 286 285 280 279 279 278 286 Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 54 37 254 57 34 257 58 35 259 54 35 260 55 35 261 56 35 261 56 35 260 57 35 261 57 35 264 60 35 264 60 35 264 62 35 264 62 35 264 58 35 261 Pump Vacuum r Hg) 3 2 2 2 2 2 2 4 3 3 3 4 4 3 Target Volume Spike Amount (ng) Comments: 2000 Stack Temp for Run 1A and IB is an average of Runs 2 and 3. Barometric Pressure corrected for elevation Total Volume (L) Mechanical Totalizer 49609.65052 49.6096505 Calciner_5 30B JJpdated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 1A ED 001523 00007569-00400 A-COM Date 2/9/2016 Plant PCS Phosphate Location Calciner #5 Sample Type 30 B Run Number/Side (A/B) 1 Operator WL/DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 10 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL321111 29.61 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002663 1.0180 1.0180 72 Page 1 of_____ 1_ Run No, 1 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading <L) Mechanical Gas Meter Reading (m3) 14:15:00 14:20 14:25 14:30 14:35 14:40 14:45 14:50 14:55 15:00 15:05 15:10 15:15 0.000 4.05 7.54 11.82 15.89 20.02 24.19 28.19 32.07 35.97 40.01 44.22 48.356 48.356 48.356 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 311 55 314 55 300 54 275 58 276 55 276 55 277 55 286 57 285 57 280 63 279 63 279 62 278 62 160 286 58 37 254 34 257 35 259 35 260 35 261 35 261 35 260 35 261 35 264 35 264 35 264 35 264 35 264 35 261 Pump Vacuum (" Hg) 3 3 3 3 2 3 3 3 3 3 3 3 3 3 Target Volume Spike Amount (ng) Comments: Stack Temp for Run 1A and IB is an average of Runs 2 and 3. Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 49677.93114 49.6779311 Calciner _5 30B JJpdated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production IB ED 001523 00007569-00401 A-COM Date 2/8/2016 Plant PCS Phosphate Location Calciner #5 Sample Type 30 B Run Number/Side (A/B) Operator WL/DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 10 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL304686 29.65 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002494 1.0180 1.0180 72 Page 1 of____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading <L) Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0 15:30:00 0.000 5 15:35 4.16 10 15:40 8.12 15 15:45 12.13 20 15:50 16.21 25 15:55 20.13 30 16:00 24.02 35 16:05 28.04 40 16:10 31.81 45 16:15 35.99 50 16:20 40.20 55 16:25 44.13 60 16:30 47.890 47.8900 47.8900 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 161 286 65 161 279 65 161 278 64 158 280 63 163 281 63 161 282 62 159 281 61 160 280 62 161 279 62 161 278 61 160 282 61 159 280 61 160 281 61 160 281 62 35 264 35 264 35 266 35 266 35 266 35 262 35 264 35 263 35 262 35 261 35 259 35 261 35 261 35 263 Pump Vacuum <" Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 3 Target Volume Spike Amount (ng) Comments: 2000 Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 48830.10662 48.8301066 Calciner _5 30B JJpdated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2A ED 001523 00007569-00402 AZCOM Date 2/8/2016 Plant PCS Phosphate Location Calciner #5 Sample Type 30 B Run Number/Side (A/B) Operator WL/DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 10 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL321123 29.65 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % eo2% 02/C02 Method 8002663 1.0180 1.0180 72 Page 1 of____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point A1 TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0 15:30:00 0.000 5 15:35 4.270 10 15:40 8.340 15 15:45 12.310 20 15:50 16.480 25 15:55 20.370 30 16:00 24.240 35 16:05 28.170 40 16:10 32.130 45 16:15 36.210 50 16:20 40.120 55 16:25 43.700 60 16:30 47.2670 47.2670 47.2670 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 161 286 65 161 279 65 161 278 65 158 280 64 163 281 63 161 282 63 159 281 63 160 280 63 161 279 63 161 278 63 160 282 63 159 280 63 160 281 63 160 281 64 35 264 35 264 35 266 35 266 35 266 35 262 35 264 35 263 35 262 35 261 35 259 35 261 35 261 35 263 Pump Vacuum <" Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 3 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 48088.5913 48.0885913 Calciner _5 30B JJpdated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2B ED 001523 00007569-00403 A-COM Date 2/8/2016 Plant PCS Phosphate Location Calciner #5 Sample Type 30 B Run Number/Side (A/B) Operator WL/DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 10 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" hfeO) Barometric Pres. (" Hg) OL328317 29.69 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02 % C02% 02/C02 Method 8002494 1.0180 1.0180 72 Page 1 of_____ 1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0 16:41:00 0.000 5 16:46 3.410 10 16:51 6.900 15 16:56 10.870 20 17:01 14.880 25 17:06 18.970 30 17:11 22.980 35 17:16 26.830 40 17:21 30.030 45 17:26 33.900 50 17:31 37.950 55 17:36 42.010 60 17:41 45.5150 45.5150 45.5150 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 155 278 53 157 280 53 159 281 53 160 283 53 161 280 55 161 279 55 162 277 55 158 280 54 157 281 54 158 281 54 160 280 54 160 279 54 158 279 54 159 280 54 35 256 35 260 35 261 35 261 35 261 35 262 35 261 35 262 35 262 35 262 35 259 35 260 35 260 35 261 Pump Vacuum (" Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 3 Target Volume Spike Amount (ng) Comments: 2000 Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 47236.71212 47.2367121 Calciner _5 30B JJpdated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3A ED 001523 00007569-00404 A-COM Date 2/8/2016 Plant PCS Phosphate Location Calciner #5 Sample Type 30 B Run Number/Side (A/B) Operator WL/DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 10 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL321185 29.69 Meter Number Totalizer Cal Factor (Y) DGM Cal Factor (Y) Stack Diameter Assumed H20 % K-factor 02% C02% 02/C02 Method 8002663 1.018 1.018 Page 1 of_____ 1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0 16:41:00 0.000 5 16:46 3.320 10 16:51 8.280 15 16:56 12.120 20 17:01 16.050 25 17:06 19.560 30 17:11 22.810 35 17:16 26.410 40 17:21 30.160 45 17:26 33.550 50 17:31 37.360 55 17:36 41.400 60 17:41 44.8800 44.8800 44.8800 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 155 278 55 157 280 54 159 281 54 160 283 54 161 280 55 161 279 54 162 277 55 158 280 55 157 281 55 158 281 55 160 280 55 160 279 55 158 279 55 159 280 55 35 256 35 260 35 261 35 261 35 261 35 262 35 261 35 262 35 262 35 262 35 259 35 260 35 260 35 261 Pump Vacuum (" Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 3 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 46508.03463 46.5080346 Calciner _5 30B JJpdated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3B ED 001523 00007569-00405 AICOM Plant Name "^IPCS Date O 2-' Project Number Q, 07022-56. lO Condition CfOofrJ^ 'i Location (Source) Meter ID & Cal Factors OX ^ / Run | j Operator //d Z~ | / /) /f\ 1) Bar. Press, (in. H20) ; Sorbent Trap IDs 2) Of stuw ' Elevation (relative to Barometer) (ft) Page Initial Leak Rate Final Leak Rate ftiird Bed Spike Level \ of 1 1) CD eZ'Q> "Hg 2) Q> @ S2<0> "Hg 1) O @ // "Hg 2) O @ /> "Hg 1) Z-OCQv<s\, 2) ~c> ' Trap Clock Time Volume (L, dry) Flow Rate (Lprrt) AP (in. H2Q) Sorbent 1) o 735 2) 0 K 3v 1) 2) /W(5 5J7V 905 . 75 -7,7 J/y 1) 9,6/ ,7/7 2) V, 59 , 7S Jpo 1) /73<? 2) S3- 39 ...75T //, 2 *?c 1) /?<#? .73 2) 27 iS /`S.til . 7S' A'/S j 2 76 1) 2a, 70 * 7.r 2) HHo pO'QSL *3.r 1) 2) HHS j*;1? 1) 2 <3,2 7 2) M<,f> 25U5 . 7S' *7$ , 75 <07 f, i f84 1) 2k,32 * 755 2) H5S 33,o7 .7S' 1) 36, 3# -7.4 2) 16 oo 3S, 97 ...^.zr.i <300 1) 90.37 .7S' 37<? 2) 9<2 4 0 / ...* 72 1) V3. <32 r7.C . ... - ... j 2) /?/ 6 H9.32 . 7 S' .7 7 1 1) ma6% .AS' 2) />/ W.jSi 39s 1) ! 2) 1) 2) Comments; I Temperature (F) Chiller Heat-Traced Line Meter Vacuum (in. Hg) 59 3' J* 7 3. Sc/ fsr 3 57 a ?y 257 3 3S' 25^ s% XX X 3 59 2 ?<T J76 o SM 3 TT 3> IS' AS / S K rO 5 6 3 ir A 4 / ss' 3 .55 2 3s' 2 7? c) sX 3 ...... J"7 y 35 o? / 57 3 3(T 57 3 57 3 37 5>c> 7 S3 3 --j OCft bs f J/ 3< >1 ,, , / Aa> 7 ... 6. 3 3 2.- - ..... C/ . 5 72. 3 3r 5>5? 9 6SL 3 . 17cv1906 Sierra Club v. EPA - 6/22 Production AAcwfifr>%/ Aw CmAaM# TW. _ iA~J-L--l nr\r\ ED 001523 00007569-00406 AZCOM Plant Name CLS Project Number & 7^5? 1/$, / 0 Location (Source) Meter ID & Cal Factors ^6X i) t?i 7a Sorbent Trap IDs 2) (91-33//33 Date 03 / /6_____________ Page / of / Condition //A# r &/ Run ... ol Initial Leak 1) Rate 2) O @ "Hg > @ 323 "Hg Operator />>/*? Bar, Press, (in. H2O) | Elevation (relative to Baronjeter) (ft) Final Leak 1) 6 @ /O "Hg Rate 2) O @ /O "Hg Third Bed 1) 3^ & & jn Spike Level 2) O ' Trap Clock Time Volume (L, dry) Flow Rate (Lpm) Stack (F) 1) O 2) /S'To O .7s' /6t 1) V.u ,75 2) /3S l/,SL7 ..... * m 1) .7< 2) /5Nt> .75 /// 1) Ta.ri . 7<S 2) (5VS' TtST ...... 75$ 1) / /> ral / n$o 2) ,7<r ,7sr /63 1) So./-} a7g 2) /55( 7*, 37 77 C m 1) 3 7> 3 ,*7C 2) /boo 2L/>M -+2SL. Ay 1) ig.M , 7C 2) 5 Jv-n 1 /go 1) -?/.g/ I&IO 2) ,7 r7C / g/ 1) IS.`if ,7$ 2) Ibis 30,7 j ,ys /6; 1) Vo, do ....,?.s 2) UZo <?./& .7 A /60 1) W./3 ... ,7< f b/gf' 2) Hi, 70 /Sf 1) $3,1%a .?r 2) U)o 77 12/*7 .7cT / 66 1) 2) 1) 2) merits: N .... ...*^ S r | i Sorbent $kb Pvv a?g <9 So) \ $ gSL6>kl ... 1 '<5 p? 9 <P %.oL 9/a\p i | j i 1 Temperature (F) Chiller Heat-Traced Line 1C 7t* oU<f Asy J7 Meter $ l.?, tO A. 4V 30 35" 3A 35 dA 3O' ol 6 S-&6 <3 V .6.3 <03 A3- S 0/ g2 O/7 =2o ....... Al ....... A3 2 A3 6.2 . 6..3 6t 2 a .. .3 XV 63 gl f eP ) > / ...... 0 l 63 Vacuum (in. Hg) 3 y 3 3 3 3 3 3 s 3 y y 3 3 3 3 7 ? 3 y ? 3 3 3 j 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00407 AICOM Plant Name FC, S _____<y / &/ /< Page / of f Project Number Location (Source) Condition H/cS r- m / ^ S_____ Run '7 Initial Leak 1) Rate 2) "Hg @ X>4o "Hg Meter ID & Cal Factors So>JX / Operator LAj'Z-- //) /W Sorbent Trap IDs 2)i IdliI wK Bar, Press, (in. H2O) Elevation (relative to Barometer) (ft) -- Trap Clock Time Volume (L, dry) Flow Rate (Lpm) Stack (F) Sorbent i) 2) Ay/ C 7 <7 yfS' 'SC a 78 1) J. HI... .77 2) /6Y6 1..JJ .?o tSp AQo 1) As; 2) 9,28 .77 ,7C /S9 28/ 1) fO^'7 2) / 6 & J/Q/(p.. ,7C Uo 1) 2) r'/sy )7,d8 >7S . H 1 1) ..* it.. 2) fJoz, Jl.SS //; 283 g& 1) .3,<7.% 2) /7/f A $'/ /.7S' , 73 J 6 a 277 . 1) 2) r?/6 3. _ 1.7S A% __ lZS 1) 30, d 3 2) '7S j /6 / 7 s' >57 28) 1) 2) /7a t 2 3,%o. 1 ,7r 38) 1) 2) 1.?, i<F . ry" 1731 1,7 3 4... t/o >$o 1) 2) 17?/, 7d.o( ^ L Ho . 70 , yC /66 P Tf i) .77 2) /9 V) WMo ,75 /$8 p9 Final Leak Rate Third Bed Spike Level i) S) @ /"> "Hg 2) 3 @ /O "Hg 1) ao a 0 2> ' Temperature (F) Chiller Heat-Traced Line 30 3C 6 23 3<r J 3<C 22/ 3sr Jl J 3r A Meter O sss si S9 S3 Sc/ S3 SI ss sc ss Sf 3SC ~3JT 3 S' 3S A j SS SS .... sy jr^r oL p AS f TV Ss Slz ss S9 ... jr<; ^5 3 $ Aft 23d xr Sc/ so Vacuum (in. Hg) r 1 1 3/ 3 3 3 3 3 7 A 3 3 3 3 3 2 3 A 2 3 *3 1 T-9> . 3 T 3 1) 2) 1) 2) Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00408 AECOM FIELD SAMPLING DATA SHEET Sample and Velocity Traverse for Stationary Sources EPA Method 1 Client / Plant: Project #: (#tH ($]&(% Location: Number of Traverse Points Chosen: |Number of Ports: Z_ Duct Diameters From Downstream Flow Disturbance (A/D) 0, 1,0 1.5 2,0 Date: v (2-C=>j\/\gy 1 Number of Points per Port: VZ. t (t?V _ ) tt o UL B 23456789 10 Duct Diameters From Upstream Flow Disturbance (B/D) Deq = 2LW / (L+W) Dnstream Diameters (A/D) Upstream Diameters (B/D) Cross-Sectional Layout of Rectangular Stacks Traverse Points Matrix 9 3x3 12 4x3 16 4x4 20 5x4 25 5x5 Traverse Point 1 2 3 Fraction Distance of From Diameter Wall z.l t .% % Nipple Length S'* Point Location c.s nvg> vs .s' 4 6 8 10 16 18 20 22 24 1 6.7 4.4 3.2 2.6 f 2.1 1.8 1.6 1.4 1.3 1.1 1.1 2 25.0 14.6 10.5 8.2 ( 6.7 5.7 4.9 4.4 3.9 3.5 3.2 3 75,0 29,6 19.4 14.6 111.8 9,9 8.5 7.5 6.7 6.0 5.5 4 93,3 70.4 32,3 22.6 17.7 14.6 12.5 10.9 9.7 8.7 7.9 5 85,4 67.7 34.2 25.0 20.1 16.9 14.6 12.9 11.6 10.5 6 95,6 80.6 65,8 35.6 26.9 22.0 18.8 16.5 14.6 13.2 7 89.5 77.4 64.4 36.6 28.3 23.6 20.4 18.0 16.1 8 96.8 85.4 75.0 63.4 37.5 29.6 25.0 21.8 19.4 9 91.fi 82.3 73.1 62.5 38.2 30.6 26.2 23.0 10 97,4 88.2 79.9 71.7 61.8 38.8 31.5 27.2 11 93.3 85.4 78.0 70.4 61.2 39.3 32.3 12 \97-Gf 90.1 83.1 76.4 69.4 60.7 39.8 13 14 \V 7 94.3 98.2 87.5 91.5 81.2 85.4 75.0 79.6 68.5 73.8 60.2 67.7 15 95.1 89.1 83.5 78.2 72.8 16 98.4 92.5 87.1 82.0 77.0 17 95.6 90.3 85.4 80.6 18 98.6 93.3 88.4 83.9 19 96.1 91.3 86.8 20 98.7 94.0 89.5 21 96.5 92.1 22 98.9 94.5 23 96.8 24 98.9 LOCATION OF TRAVERSE POINT 1 N RECTANGULAR STACKS. 2 3 4 5 6 7 8 9 10 11 12 1 25.0 16.7 12.5 10.0 8.3 7.1 6.3 5.6 5.0 4.5 4.2 2 75.0 50.0 37,5 30,0 25.0 21.4 18.8 16.7 15.0 13.6 12.5 4 V7-1- 5 ZCXD V&.'D 6 2C-C 23 .O 3o.|fl 3 83.3 62.5 50.0 41.7 35.7 31.3 27.8 25.0 22.7 20.8 4 87.5 70.0 58.3 50.0 43.8 38.9 35.0 31.8 29.2 5 90.0 75.0 64.3 56.3 50.0 45.0 40.9 37.5 7 HC -H 6 91.7 78.6 68.8 61.1 55.0 50.0 45.8 8 "T-sLo 7 92.9 81.3 72.2 65.0 59.1 54.2 9 8 93.8 83.3 75.0 68.2 62.5 10 1 i/&. 9 11 12 LlrZ'M-A 7-D.S NJ 11.1 ^S.S 10 11 94.4 85.0 77.3 70.8 95.0 86.4 79.2 95.5 87.5 12 95.8 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00409 i AECOM FIELD SAMPLING DATA SHEET Flow and Moisture EPA Methods 2 & 4 PAGE OF Client/Plant: c. Location: Project#: botft2?VlT. JO Condition: k5&r^&Sl Date: \~2b-'\h* Moisture Run #: Operator{s): Duration (min): DGM#: PbarC'Hg): CF(Yd): AH@: (. Height w.r.t. Barometer (ft): joo Cp: 0.84 static C`H20): Initial Leak (<0.02 fP/min; >10"Hg) fr/min: Vac. ("Hg): Source Height (ft): Duct Diameter ("): '^7 Final Leak V {<0.02 ft /min; >run maximum) ft3/min; Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak V (>3"H20) +P ("H20): c/ P("H20): Pitot Tube ID#: 02 (%/time) % % %( C02 (%/time) % % % Time Moisture Determination DGM Volume (ft3) AH CHaO) DGM Inlet T CF) DGM Outlet T (F) Flow Run #: ( Flow Run #: Start Traverse POEtlt ` XV Z>Z AP (H20) 1 End (Z-53 Source T (F) Start AP ("H20} End Source T (*F) zm 5 Flow Run #: Start End AP (*H20) Source T fF) Cyclonic Angle () l ictf K r Kb 17 xsv \o 7 *m fS lT3 *7 f.t> \5Z H VS"3 m iz. 5 \ 'IHS ST z q. S HI H iht v 151 tsb t- 1 ^s> iSS 3 fa j<L_ H um 2 I-L z. \ \ \ 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00410 Test Run 1 STRATA Version 3,2.112 02 C02 % % Begin calculating run averages 02-08-2016 16:07:41 -0.095 -0.012 02-08-2016 16:08:40 02-08-2016 16:09:40 -0.090 -0.095 -0.009 0.007 02-08-2016 16:10:41 -0.092 -0.004 Pause End Pause 02-08-2016 16:12:40 19..096 21..076* 02-08-2016 16:13:41 19,.209 20..434* 02-08-2016 16:14:40 19..215 20,.098 02-08-2016 16:15:40 19..222 19..966 Pause End Pause 02-08-2016-16:19:40 02-08-2016 16:20:40 02-08-2016 16:21:40 02-08-2016 16:22:40 10.010 10.007 10.007 10.005 9.663 9.561 9.440 9.326 Pause End Pause 02-08-2016 16:27:40 02-08-2016 16:28:40 02-08-2016 16:29:40 18 .954 19 .xl 06 19'.017 8,.015 6..453 6..584 02-08-2016 16:30:40 19 .'307* 6..588 02-08-2016 16:31:40 19 .758* 6..529 Pause End Pause 02-08-2016 16:35.-40 02-08-2016 16:36:40 02-08-2016 16:37:40 13.952 13.959 13.968 3.468 -0.106 -0.095 02-08-2016 16:38:40 13.973 0.129 02-08-2016 16:39:40 02-08-2016 16:40:40 13.980 13.981 1.733 0.270 02-08-2016 16:41:40 Run. Averages 13.990 02 0.545 C02 % % 02-08-2016 16:42:23 Operator: Plant Name: Location: 12.569* 6.401 Lance Burleson PCS Aurora Calciner ^5' Test Run 1 End Page 1 icinfi Qif^rra niiih v EPA - 6/22 Production Test Run 1 STRATA Version 3,2.112 02 C02 % % Begin calculating run averages 02-08-2016 17:31:23 02-08-2016 17:32:23 -0.065 -0.067 0.035 0.054 02-08-2016 17:33:23 02-08-2016 17:34:23 02-08-2016 17:35:23 Pause -0.072 -0.072 -0.076 0.070 0.069 0.088 End Pause 02-08-2016 17:37:22 02-08-2016 17:38:22 02-08-2016 17:39:22 02-08-2016 17:40:22 02-08-2016 17:41:22 02-08-2016 17:42:22 19.197 19.229 19.239 19.235 19.240 19.241 20.528 20.797* 20.790* 20.782* 20.617* 20.596* Pause End Pause 02-08-2016 17:44:23 02-08-2016 17:45:23 02-08-2016 17:46:23 02-08-2016 17:47:23 02-08-2016 17:48:23 02-08-2016 17:49:23 Pause 10.034 10.023 10.023 10.022 10.019 10.018 9.960" 9.658 9.743 9.808 9.875 9.838 End Pause 02-08-2016 17:51:22 02-08-2016 17:52:23 20.680* 20.666* 7.089 7.435 02-08-2016 17:53:23 20,665* 7.474 02-08-2016 17:54:23 Pause 20.663* 7.516 End Pause 02-08-2016 17:56:23 14.393 0.375 02-08-2016 17:57:23 02-08-2016 17:58:23 02-08-2016 17:59:23 02-08-2016 18:00:22 13.630 13.629 13.618 13.625 -0.123 -0.118 -0.128 -0.123 Pause End Pause 02-08-2016 18:02:23 02-08-2016 18:03:23 02-08-2016 18:04:23 02-08-2016 18:05:23 02-08-2016 18:06:23 02-08-2016 18:07:23 Pause 18.834* 20.668* 20.684* 20.680* 20.680* 20.685* 3.316 7.857 7.868 7.886 7.910 7.930 End Pause 02-08-2016 18:10:22 02-08-2016 18:11:22 02-08-2016 18:12:22 02-08-2016 18:13:22 13.475 13.456 13.460 13.457 -0.058 -0.043 -0.038 -0.037 02-08-2016 18:14:22 13.461 -0.026 Run Averages 02 C02 % ' % 02-08-2016 18:14:45 13.684* 6.642* Operator: Lance Burleson Plant Same: Location: PCS Aurora Calciner *6 of i Test Run 1 End Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00412 .&.s pa. AECOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE 7 T of Client/Plant: JMLM Location: ^ j M- DGM#: /?/- W K-Factor: ot,$D Project#: {#01/0229 7. Jo Condition: fJBrrYU^ CF (Yd): /, 0 o2 4 6 Fbar("Hg): 3 O // Date: et /S>7//7 Run #: X AHe: /,$)?? Height w.r.t. Barometer (ft): Initial Leak V (<0.02 ft /min; >10"Hg) ft /min: Vac. ("Hg): /Q Source Height (ft): Operators): (//L /& /*1 Duration (min): ty ^ Cp: 0.84 static ("H20): .asr Duct Diameter ("): Final Leak (<0.02 ft /min; >max vacuum) Pitot Leak (>3"H20) +P ("H20): Probe & Pitot ID: /j* P P 6 -- 9 ft3/min: Vac. ("Hg): P ("H20): Duct Width ("): Duct Length ("); Nozzle D1 (") 0: . 3JiCo7* Nozzle D2 (") : -5.<s/<f 0-Xi- Nozzle D3 (") Q: -----e. Zi Average Nozzle D ("): .gg Sample Point pbr*h Time Clock Run (min) DGM Volume (ft3) AP C'H20) AH CH2O) Source Probe 24825 1L31. ft/ XL pp.ati / Jl JSJk 2 3 7~eT7r~ -jO- 351 ,87 760 20JML . SSI MMZ M *6 32 (>.<? 33. JX 76S X /St u XL 335,7/ 33- MA. iML MC- 3s8, i S ML 7a 1 So Z. 7% jJA 370,95 ,,QS ,7a AL 33hA0 OM JxM 7<7? MM ML 70 X? IS 1L -7JL /a^o 27 23AJA 522L 75o 36 33.5MA &8 70 /<2 33 3373/ am zd /5l 3A- zuMlM TMrM tin AL /Sl M A r 338.1/6 02 - . .57 757 Ml 332AM 31- .* 65 757 M2- 7>(?S7 XX AM 1MA 5 2ML35L AM -JxM JMM 9$ 3MLML ,3 \ 77 759 M 5LL 3MA3B- XX 396, f)6 57 77.S8 4- 60 3 if00 ML 63 JIMl JL J-jL- 35/M ML J4~ 353,76 /a.a 0 ml 35 V30o jM 2M 2A. 30 33 3223 37 If/ /<x Mn. JSM 72M iML jlM 753 *82 JSM 752 Temperature ("F) Filter 248+25 Impinger Exit 68 MS 6 SA. S MM. MS ML 99 STL 57J- 5 DGM Inlet <1 SM XV jSM XX ML 51_ Xl_ XL MM s<r 56 DGM Outlet <9 XX 53 3 2- - Xa 52- 53 XL XX 53 Pump Vac. ("Hg) A. SL A M JL 5) 5L X X M So MI MM SM iX XX Mm ma MA XX 7 SSL Mm SM OM 5q 9 S9 MA MA ma Lm- MA SL SS 3 S M 5 X .59 X XV A SM XL SM XL SM X SM XX mm- A COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00413 AECOM Client/Plant: Pt3 Location: Impinger# 1 2 3 4 Impinger Contents DI HzO di h2o Empty Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) Project#: Condition: \0 AIYr/u-c. I Date: Run #: i METHOD 13A/B Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD M/S U3S 100 GS 1ZZS 1.T7.3 - MOD 6*55,1 (oZl.l - MOD 7/6.3 Jz.o Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Di H20 Rinse) COMMENTS: Tare (g) Final (g) IT TT Gain (g) ' t ,, . , 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00414 AZCOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE J___ OF / Client/Plant: Mjl Location: /, J*~ 5 Project#: i#Ol/0?z c/fr, /0 Condition: AJeryn^l Date: Run #: Operators): /a//-7s/$\ Duration (min): DGM#: SJ/-9Y CF (Yd): / 0p 6 4 AH Cp: 0.84 K-Factor: 6 > $- L PbarfHg): ^o,// Initial Leak-/ (<0.02 ft/min; >10"Hg) ff/min: (p Height w.r.t. Barometer (ft): Vac. ("Hg): Source Height (ft): Duct Diameter ("): Final Leak / (<0.02 ft3/min; >max vacuum) ft3/min:t^jfl ' Vac. ("Hg): Duct Width ("): Duct Length (" Pitot Leak / (>3"H20) +P ("H2Q): Probe & Pitot ID: p - ~~7 P ("H20): Nozzle D1 (") 0: Nozzle D2 (") 0: Nozzle D3 (") : Average Nozzle D ("): f'C JJLJL ///~pt Sample Point Time Clock Run (min) DGM Volume (ft3) &p CH20) mAHo) Source Probe 248+25 /I j l^`/o 4? 359,9/8 ,06. , 6S /ra j? 356.0 / *p ft- , yo 777 ? 6 3S7,J7 ,30 ..?C 7C7 9/ f f 358,70 * a# .. 50 J56 J5 3/6,J7 -3 / . 77 / 57 6 261,5/ _t.$S Kg' 7 /f? 363,00 * fr 791 9 5> f 'll, V. VS , 35 .07 /57 9 57 365,97 J7 . 3 J8 c /a imm 55 3/7,77 ,ya, /,os 7.77 // / A. /y/6 /7/ *73/8 36 369,05- ,3$ 7 3 370.6 7 *35 3 7 s 70,0m 37.2,0/0 -jTf ,&y /50 ,77 JS3r ^ / & />/ ,97 /7$ 77 173,30. *3^ / 56 V Y* j75,pa v 3Y ,/?< 759 f yr 3767/7 * 3*7 . 7a /5a yr 7 y? 3o Z_f7 /36 *90 /58 379/36 ,3 b ,80 /57 r aY) Wo, 9 5 IS ,87 /7f s? 7 70.3/ 77 r 9 fo j 79 JO 7? iMBo lot , 76 /Si 1/ *5 66 69 386, m ,?r T&tr 3/?7.SV t. 7^ 153.. A3 Ko'j 5X 3ea.mt Temperature ("F) Filter 24825 Implnger Exit S68 DGM Inlet 56 5j 56 y? S5 5 6 78 55 9*7 55 | 97 55. f7 *78 55 zr c 97 55 95 SO 95 50 ~ r/A 007S7,6r6 ' 3 76 5 7 50 i9y/7'J 59 si 78 5/ 78 55 99 55 5o 57 79 5V 99 5V 99 DGM Outlet 59 57 57 53 5PK CO So 50 51 5/Jff 9 9 Pump Vao. ("Hg) 51 O 0 5 A 3 V 7 8 s < s $0 5 79 5 VI 6 6 79 6> 79 6 Vf 5 L/j 5 79- .5 79 f 99 r COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00415 A=COM Client/Plant; PC3 Location: wS Impinger# 1 . 2 3 4 Impinger Contents Dl H20 Dl HzO Empty Silica Gel FIELD SAMPLING DATA SHEET ______________ (RECOVERY)______________ Project #: QaC'oZZ^. Condition: Date: Run#: z METHOD 13A/B Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD 159./ /ott. 9 100 GS Lm3 -- MOD w.t (p^.3 -- MOD m* 6 Sum Recovery Container Weights Filter (no weights) ' PNR & Impinger Catch (Dl H20 Rinse) COMMENTS; Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00416 AECOM FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE OF jL Client/Plant; PCS Location: Cal, ^ .P DGM#: fj/- pp Project#: {^6^027.0^.2X2 Condition: kJ&rm&S CF (Yd): Date: O / / } 7 / / 6 Run #: 3 AH@: Operators): pj^ //J /n Duration (min): *y q Cp: 0.84 ' J5factor:...A.Sa_______^ PbarC'Hg): Initial Leak (<0,02 tt3/min; >ld"Hg) Final Leak S (<0.02 ft3/min; >max vacuum) 3d , H ft3/min: > ft3/min: O Height w.r.t. Barometer (ft): Vac. ("Hg):/^ Source Height (ft): Vac. ("Hg): g> Duct Width {"): Pstatic ("H2O): , 3SJ3 Duct Diameter ("): Duct Length ("): Pitot Leak v'^'-HaO) +P("H20): Probe & Pitot ID: /\ P S - if -P("H20): ~ ^-- Nozzle D1 (")0: -#.o-zsc Nozzle D2("): Nozzle D3 (") : Average Nozzle D ("): , Sample Point /W Time Clock Run (min) DGM Volume {ft3} ip ("H20) AH CHjO) . Source Probe 24825 Temperature (F) Rlter 248+25 Impinger Exit 68 DGM Inlet DGM Outlet Pump Vac. ("Hg) M fspd O ~WWT 57 /$*> 2 ? ^93. 777 /si t ?7/,70 ,3 1 ,77 /4 Cf f 393/7 , Its , 70 // 5 /I 377, 4 9 ,39 /9.7 ..6 fS 194,, U ,33 * $rk /vf Z zsz 9 .; tg 399S .3.5' ,87 /7k 3?B,99 , M t 70 fSS 7d0,39 . rt) . &S /$ /0 // " -=-"< - * 3X0 (Z4doJu?,S97S xjr 29 .. .77 ,7 vyf JS7 /X, ( 1 '3 3 707k& . 09 /&$i 3 h */o$S92 *94 / S3 Qffr~/ &/ /AS9 , 3$ _ >7a /Vf J 39 90 * 30 . 7,r iSA 3 7X 90$, ? b -31 77 izssr *j 97- 909,69 2H ,8s ../So ~w 7//J0 ,70 ,90 iS7 S S/ 9,a,.9TS Ao /. OO /74 l CM VP 4 oL -3H v0 74 3 31 7S> 7S Q 33 77 7S -338 7 7P S> 3> po 79 Po 79 H'S' 7S~ 9< ol 9/ So / So 74 3 7r P 7/ 7S X> . 7/ Sd <* SI --< 73 $0 7/ Si 7/ 70 S3 7/ S3 7o $3 7& p 77 77 c5 5 77 7 .? 7 37 7/7,/S'- A /rr S7 7iS<6 ,3 B 97 /So J7o 60 7/7J0 ,3f <87 JS7 03 HI 8.6/ ,3% A9 }<3 (f 00 72 0,1$ * Vo /. 00 /? /X 09 ml, 73 / 7o 2.00 ;i/q 7/ / / 7 XL 7X 73 S7 $7 $7 S7 $ $7 0 3 V7 3 3 0 3 ?> 3 3 P73S ?x COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00417 AECOM Client/Plant: fCS Location: ernes' & 5 Impinger# 1 2 3 4 Impinger Contents Dl H20 Dl H20 Empty Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) __________ METHOD 13A/B Project#: Condition: Date: i-2^- Run#: 3 Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 100 -- -- MOD 333.5 ^56-2 GS 13/. / m.5 MOD 353, \ 351,0 MOD 923,' Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dl H20 Rinse) COMMENTS: 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00418 AZCOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 EPA Method 5/202 PAGE OF Client/Plant_ ' > .. _ [ Project#: fef/// Location: Console#: S Condition: A , , J /t, -14 _ CF (Yd)- I /J / Cl /o Date: | - 2l> : U ^ Run#: j ~n 4Ha: >/, `y Operators): |+ Duration (min): i __ ' Cp: 0.84 , K-Fa- cto- n PiarfHg): t Zry 4 Ai Height w.r.t Barometer (ft): PstaUc ("H20): f i'L Initial Leak (<0 02 ftVmin. >10"Hg) final Leak / (<0.02 ftVmin, >run maximum) I jJPitot Leak (>3'HzO) | Iniiai+P- r Fynte/Orsat 0^ (%/time) Fyrite/Orsat O* (%/time) % ( % ( Fyrite/Orsat Of (%/time) |f"~ TT Time Ssr! --t 4r % { s* ft'3/min: V ; Vac. ("Hg)' f% Source Height fit): i > Duct Diameter {"): , ` ft3/min: ( Vac. ("Hg)' Duct Width f): - T Duct Length ("): - .... | _ -p.,.......... ...-..H . ..F..--in.a..l..+.P...:................... ---P--:--- Fyrite/Orsat C02 (%/time) % ( Nozzle Dt (*) 0: Nozzle D2(")&: % Fyrite/Orsat CO, (%/time) % ) !NQ^eD3ilSl <i 1 4 Fyrite/Orsat COz (%/time) % ( ) Average Nozzle D Q: # * T T ", Temperature (T) i ':>} <1 *-t--j oom * DO.P ir Po" ">=* h > , + i__i . . ,H'0' (MO) -- : I j 1 x _ _ 1 25 ^ 25 , *8_ , 85 52AfcSl . rxi PjEEL-l . K-?4*rL*t -'t-4 Jy ta , AT . ^ . , ;4'i] PI . 4" . , 'i t 4 ' I <;il .'tsCiiLfeL. jnv,- . '.'i , r-' i it , . , 2f,;' ( | .'4Li . 4 p/iil '' I x t' " 4_-J ^ [ . u................+r5'4z:<i^iTi^44^ 4t 4fi\ t * 4ri. l ' ,Li\- i W 4? 'i jft iti1 i%r :lf}' !^4 -<x/ Tvjb^?L_ k. _ , If 4- -- efepJ_L, ^.--' ,'pI v?y. 1 ' "^*;L ` 1 JJCT X Sa TJOU . ^ -? jH'i. ; ^ zz.b ->i: amp. -.a ^ > : >-v-1 -a,: ^ > ; w ^ _ - ti i rifi'u': i_4 LJ ' f/." / 45 4 VI H ,W , ^ ^4 ' &t i . _ 4 ^ 41! I <4 12-- __i_ 0_J L_I_ + iif' iZVx "f-4_aC4. 4 4 6 l^ .4 +j4 j 'xi. 4 H-S^? -, 2. ; 4 4. j W t <2^ lf^tVC ,`A 4 C AiK r'(T ^ % j * H 1 Ui"i 4 4, J4>44L14& Pit 12"i , " r. I' i 1' 4 m' ^ ^ i - *. ?zCgSt; M ^4 J u4li ^ + ^ .r 4' f -4 _4?..iL.l 4 -Cij t, & ^ JX x/ p "77v<A. t* ,# # "Vf f ^ j /l s-p.-;' ;,t ] ' Hii. . y4*441 . , '-~L. Ltl/ //.V T>. , 1 ,4^ 4* .44 4`-' w 444 I/Vi i-~it<4?! i. -'<*' ' 1 % <'^4'/C 4>4_ i %i_4 ' _ 4 . j& 424^. f ~T --f --j- -r -+ + 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00419 ACCOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant Location: ' Project # Condition Date: , Run # Impinger # Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination . Approximate Volumei mb ! , Configuration ' Initial (g) o J VCON 0 KO | i o 3>4? 0 MGS 1 f) _1_0_0_ 1 MGS f Jr i! 1: .. ...::: .. ? It 'll. 350 j MGS [ Final (g) 1 j ^ --11 Hf ! ( !f0* 5 Sum Gain (g) Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time CPM Filter Temp Rotameter Reading Start: l i ! Stop: Cl: Filter Recovery Container Weights PNR - Acetone Filter CPM Filter impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: Tare Wt. (g) Tare Wt (g) Tare Wt (g) Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00420 AICOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 EPA Method 5/202 1 PAGE OF -J Client/Plant Project#: yu/ozj yV. /x> Operators): j jLocation: Console#: JO - CF(Yd): 1 rr v Ron AH@: t.%1? ^Duration (min): '/ Cp: 0.84 *" K-Facton 2? Pbaf("Hg): Height w.r.t. Barometer (ft): Initial Leak {<0.02 ff/min; >10"Hg) ftVmin: J) Vac. ("Hg): | /f Source Height (ft): final teak V (<0.02 ft /min; >run maximum) ft3/min: 0* 'pitot leak (>3*H2Q) f Initial +P: X -P: Vac, `Hg). > Duct Width Final +P: /" -P: Nozzle D1 (") 0: Fyrite/Orsat O2 (%/time) 1 Fyrite/Orsat Oz (%/time) | Fyrite/Orsat O2 (%/time) % ( : ) Fyrite/Orsat CO: (%/time) : ) Fyrite/Orsat CO2 (%/time) Fyrite/Orsat COz (%/time) % ( : ) Nozzle D2 f) Q: % ( : ) Nozzle D3 (") Q: % ( : ) I Average Nozzle D ("}: Sample Point Time Clock Run (min) DGM Volume (ft3) Source Probe 248 i 25 Temperature (F) Filter j Impinge 248 | r Exit _25___L. sSB DGM Inlet DGM Outlet l " H S' r 3 t* \z iv \?y i#r^ to iL /'l t . L. i.i'/i - .. |.fO T"Klr_ ,3i t.r ' %v . vv ,'I . B ! ' ..;/ i. ^P* :Qz ^k> ZHL< '"'7 , H> ..It-La.. $% i rn% , . h l,/4 'Oh , s 'iS' fo ^r lm>1 V.-2L U^O X , -i ~/xr ~4& hfu Y , i'ZHr W ^ itsr , 1 ` /r; '7<Q Z-Uu .-TV, y.'/ ; TV ;V7 ,V1 ; v 1 rsq I 7>& X!, kt 74 Vj [T ~^o TH VS____4, ,Z[ /J_. _ _ . .... __ ___ _ WJ' f/ < h Sj if , `V 1 4 v' ` * % x /, 1 1 ..........^ im.^ rgi 13Q 3S3 .... . I V'. K3IC-S ... . ;V'i I x? ssm .[ W-i hrr-^ pA. 3/" Y '/'4`X ' ^ UM tsfcJ ' * I '< S'J. f' T Zsz. 22J_2|4- 214^^^--- ~TT / ^ ^ C X 3 ^ 5; ZfcQ 1253 '*' I ^4. ^ i? ''f ^ | ./'y . { , jM^ j/m4 _JirS___ :a l/. 17cv1906 Sierra Club v. EPA - 6/22 Production 4---- --u ED 001523 00007569-00421 ATCOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 ; Client/Plant [ Location: /' , Project# , Condition Date: Run#: _ Impinger # Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination Approximate Volume'mli |o 1 ! _ Configuration VCON Initial (g) 1 0 ..... [ KO / ' 0 MGS , 100 MGS j , ;, . 350 MGS j ,, , final (g) Gain (g) p' a n O* 0,40 | Sum ( Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: CPM Filter Temp Rotameter Reading Stop: Cl: Filter ID#: M30. ID#: ID#: Tare Wt. (g) Tare Wt. (g) Tare Wt (g) Recovery Container Weights PNR - Acetone Filter CPM Filb Impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: Tare(g) i , Final (g) Gain (g) | i ! I i i I i 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00422 AZCOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 fciient/Plani r-ocatiom Console#: Project #: (,,Qt/o??</&'. A Condition: /tj0tWtAl ^ (Yd): \.d1Xfi{g K-Factor '' Pbar("Hg): Initial Leak V (<0.02 fl'Vmin; >10"Hg) Final Leak V (<0.02 ftVmin; >run maximum) 3.i O ft3/min: | Vac. fHg): jg Vac. fHg):^ -P: Nozzle D1 (') %( : Nozzle D2 (") 0: % { : ) Nozzle D3 (") 0: %( : Average Nozzle D ("): ---------- | Source Probe 248 i 25 Temperature (*F) filter 248 25 Impinge r Exit S68 c,,2P" Fll,|rs65' dgm Intel dgm Outlet Pump Vac. ('Ha) Jtl , Sd_,A VA - ; M.-C 11; L`Lf. ; '-T 3i 3- --tfci f m it u ib i -A i A . O 13^ a 3, ^ a .TlAiii2 tlTiSAo itzsa.. jfeJsa.- l&g V, I.t, Ifc2- 2L>. istLl ! V*> ^ /l U-^n<5Z \ S Q < IEE-Zjfe3t .. jzd_ l a.? . i . '/ I; a A a Wh r 'X* b# ' ,, / * V, .JfefL 3d ...3gr X3 *T jTA 31 o /j \ *1. /fj' Oi'WXr 1 ** SXE AAk A". V' j <'A. i*<W ___ ._LlC_ / 'u [3 z^t i y~ ?7 il.Lt. A 1 / f/bw/ ^ . r ' a Jhsfev ^>\c> -Ar- tV2> 3T~ t/( | l(^Q!?.S`t>[Trfc| L ',r ,3 3 ^j2aijua4JSil2I].252Lk ir^ 'urpfegp , r ' A' 3 -- 3 vy-;: [ F 'V; ,,,^ 2.#- i 1 \ .0 VSV <_f_c_c 3aJ22_A_ '-71. : &. v. A/;, , v ; 2'Y, Av'.r 'jMi ' ,/< tsfTVz, L'< V4J'* ---------------------- --TM 0. .. . 1 I COMMENTS _____---- ! j j 1 f | j 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00423 AICOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant:' ;V, . Local _ Project # Condition- H i Date- , j ' Run #:,, Impinger # Condenser 1 2 3 ..... 4 1 Impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination Approximate Volume :'mii ' Configuration 0 VCON "p1 ..-..- r1 0 1 .. KO [ i MGS Initial (g) ' - -; > ^........ Final (g) Gain (g) P .... _____ 100 j MGS 350 | MGS ljOf <7/0. V u?//* 5 / Sum ( Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery I Purge Time 1 CPM Filter Temp , Rotameter Reading | Start; Stop: Recovery Container Weights PNR - Acetone Filter M Filter impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00424 A-6 Calciner No. 6 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00425 PCS Phosphate Operations - Stack Test Results Test Information Location Product Source Stack ID No Start Date Pollutant Method Calciner No. 6 Single Float Calcined Rock WESP 206 1/27/2016 Particulate 5/202 Production Data Date Feed Rate, Wet, TPH (During Test) Bulk Moisture of Rock (Lab Analyses) Rock Feed Rate Dry, TPH Lbs. Coal/Ton of Dry Feed Coal Feed, TPH Process Weight Rate, TPH Loss On Ignition Production Rate During Test, TPH Product Test Parameters/Conditions Time of Start Time of Finish Stack Gas Flow Rate Calculations Stack Flow Rate, DSCFM Sample Volume (DSCF) Condensable Particulate Determination, Inorganic Fraction [NifSample Weight, mg Condensable Particulate Determination, Organic Fraction Net Sample Weight, mg Train Blank, mg CPM, mg/DSCF Particulate Determination, Filterable Beaker Final Weight, mg Final Filter Weight, mg Net Sample Weight, mg Mg Particulate/DSCF Mg Particulate/DSCF, Averaged for Wash Cycle Procedures grams/DSCM Total Particulate Determination PM Emission Rate, Lbs./Hr - Filterable PM Emission Rate, Lbs./Hr - Condensable-Inorganic PM Emission Rate, Lbs./Hr - Condensable-Organic PM Emission Rate, Lbs./Hr -Total Condensable (corrected with train blank) PM Emission Rate, Lbs./Hr - Total Particulate Average Daily PM Emission Rate, Lbs./Hr - Filterable Average Daily PM Emission Rate, Lbs./Hr -Condensible Average Daily PM Emission Rate, Lbs./Hr - Total Particulate PM Emission Rate, Lbs./Day PM Emission Rate, grams/dscm PM Emission Rate, grains/dscf Allowable PM Rate, grain/dscf Green indicates hard entry 1 27 2016 67.0 12.30% 58.8 46.71 1.37 60.1 2.98% 57.0 1/27/2016 67.0 12.30% 58.8 46.71 1.37 60.1 2.98% 57.0 1/28/2016 67.0 12.30% 58.8 46.71 1.37 60.1 2.98% 57.0 40,293 43.216 38.204 40.997 36,670 40.113 38,389 41.442 Run 1 7.74 Run 2 5.57 Run 3 9.50 Average N/A 1.71 0.1724 0.23 8.84 9.07 0.2099 0.0074 1.12 0.95 0.21 0.92 2.04 0.88 2.30 0.1085 0.20 37.07 37.27 0.9091 0.0321 4.59 0.69 0.11 0.55 5.14 1.21 0.2171 0.28 14.19 14.47 0.3607 0.0127 1.75 1.15 0.15 1.05 2.80 N/A N/A 0.1660 N/A N/A N/A 0.4932 0.3165 0.0174 2.49 0.93 0.16 0.84 3.33 1.592 0.964 2.556 61.352 0.0112 0.005 0.080 Calciner 6_Prod data calc-Updated 3.8 17cv1906 Sierra Club v. EPA - 6/22 Production Top ED 001523 00007569-00426 Data For Avg Daily Emission Rate Calculation (inputs in red cells only) Total PM Ibs/hr Total PM Ibs/hr Run with wash (enter cell address) (Esl Ave Hrs washinq per 24 Hrs (S) Run Time, Hours Wash Time during test in hours (A) Run Time During test not Washing in hours (B) Total PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) Filterable PM Ibs/hr Filterable PM Ibs/hr Run with wash (enter cell address) (Esl Ave Hrs washinq per 24 Hrs (S) Run Time, Hours Wash Time durinq test in hours (A) Run Time During test not Washing in hours (B) Filterable PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) Condensible PM Ibs/hr Condensible PM Ibs/hr Run with wash (enter cell address) (Es) Ave Hrs washinq per 24 Hrs (S) Run Time, Hours Wash Time durinq test in hours (A) Run Time During test not Washing in hours (B) Condensible PM Ibs/hr Avg of two non-wash runs (enter cell addresses)(EN) PM Emission rate g/dscm Filterable PM g/dscm Run with wash (enter cell address) (Es)_____________ Ave Hrs washing per 24 Hrs (S)_________________________________________ Run Time, Hours_______________________________________________________ Wash Time during test in hours (A)______________________________________ Run Time During test not Washing in hours (B)__________________________ Filterable PM g/dscm Avg of two non-wash runs (enter cell addresses)(EN) PM Emission rate mg/dscf Filterable PM mg/dscf Run with wash (enter cell address) (Es)_____________ Ave Hrs washing per 24 Hrs (S)_________________________________________ Run Time, Hours_______________________________________________________ Wash Time during test in hours (A)______________________________________ Run Time During test not Washing in hours (B)___________________________ Filterable PM mg/dscf Avg of two non-wash runs (enter cell addresses)(EN) 'Water Wash Performed on Run 2 (R=24hrs) Eavg= EsS (A+BJ/AR) + E(((R-S)/R)-(BS/AR)) -------- 511-------0.42 1.20 0.42 0.78 2.42 4.59 0.4167 1.20 0.42 0.78 1.43 0.55 0.4167 1.20 0.42 0.78 0.99 0.03 0.42 1.20 0.42 0.78 0.01 0.91 0.42 1.20 0.42 0.78 0.29 Calciner 6_Prod data calc-Updated 3.8 17cv1906 Sierra Club v. EPA - 6/22 Production Top ED 001523 00007569-00427 Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner # 6 Condition Normal Sample Type: Method5/202 Run Number: Date: Total Sampling Time (min) Corrected Barometric Pressure (in Hg) Absolute Stack Pressure (in H20) Stack Static Pressure (in H20) Average Stack Temperature (F) Stack Area (sq in) Actual Meter Volume (cu ft) Average Meter Pressure (in H20) Average Meter Temperature (F) Moisture Collected (g) Carbon Dioxide Concentration (%V) Oxygen Concentration (%V) Nitrogen Concentration (%V) Dry Gas Meter Factor (y5) Nozzle Diameter (in) Pitot Constant 1 27-Jan-16 72.0 29.99 29.97 -0.24 147.3 4072 41.374 1.12 45.2 337.3 5.4 13.6 81.0 0.9943 0.277 0.84 2 27-Jan-16 72.0 30.03 30.01 -0.24 150.2 4072 39.099 1.03 43.8 260.2 7.9 13.5 78.6 0.9943 0.277 0.84 3 28-Jan-16 72.0 29.89 29.87 -0.24 151.8 4072 38.693 1.00 47.1 388.8 8.1 13.4 78.5 0.9943 0.277 0.84 Average Sampling Rate (dscfm) Standard Metered Volume (dscf) Standard Metered Volume (dscm) Stack Moisture (%V) Saturated Moisture (%V) Mole Fraction Dry Stack Gas Dry Molecular Weight Wet Molecular Weight Average SORT of Delta P Stack Gas Velocity (fps) Stack Gas Velocity (mps) Volumetric Flow Rate (acfm) Volumetric Flow Rate (acmm) Volumetric Flow Rate (dscfm) Volumetric Flow Rate (dscmm) Percent Isokinetic Post Test Meter QA (yqa) 0.600 43.216 1.224 26.9 23.4 0.766 29.41 26.73 0.57 35.6 10.9 60429 1711 40293 1141 100.9 0.9934 0.569 40.997 1.161 23.0 25.2 0.770 29.81 27.09 0.54 33.7 10.3 57188 1620 38204 1082 101.0 0.9993 0.557 40.113 1.136 31.4 26.0 0.740 29.83 26.76 0.54 33.9 10.3 57492 1628 36670 1039 103.0 1.0030 Average 72.0 29.97 29.95 -0.24 149.8 4072 39.722 1.05 45.4 328.8 7.1 13.5 79.4 0.9943 0.277 0.84 0.576 41.442 1.174 27.1 24.9 0.758 29.68 26.86 0.55 34.4 10.5 58370 1653 38389 1087 101.6 0.9986 Calciner #6 M5 202 v2.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Run Summary ED 001523 00007569-00428 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method 3A C02 Percent Replicate 1 5.4 Replicate 2 Replicate 3 Average 5.4 Method5/202 PCS Phosphate 60402248 Calciner# 6 Normal N-45 0.9942 3.0 30.09 02 Percent 13.6 13.6 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 81.0 Nozzle ID (in) 1/27/2016 DM/LB 1 3.45 1.7992 0.84 100 -0.24 c 72.0 0.275 0.279 0.276 0.277 impinger Weights (g) initial Final Net impinger 1 485.8 746.1 260.C Impinger2 547.9 641.6 93.7 impinger 3 732.4 697.4 -35.0 impinger 4 894.0 912.3 18.3 impinger 5 O.C impinger 6 0.0 impinger 7 O.C impinger 8 O.C Moisture Collected (g) 337.2 Pitot Tube ID 8-4 Saturated Percent Moisture 23.44 Standard Calculated Percent Moisture 26.90 Volume (dsef) isokinetic % 100.9 43.2 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 12:58:00 13:01:00 13:04:00 13:07:00 13:10:00 14:07:00 14:10:00 14:13:00 14:16:00 14:19:00 14:22:00 14:25:00 14:28:00 14:32:00 14:35:00 14:38:00 14:41:00 14:44:00 14:47:00 14:50:00 14:53:00 16:08:00 16:11:00 16:14:00 16:17:00 16:20:00 Dry Gas Meter Reading Vm (ft3) 849.921 852.700 854.100 855.900 857.300 858.700 860.300 862.800 864.200 866.100 867.600 869.400 871.215 871.215 873.500 875.000 876.600 879.100 880.400 882.000 883.400 885.000 886.800 888.300 889.700 891.295 Velocity Head (AP) (in H20) 0.35 0.27 0.25 0.26 0.25 0.28 0.32 0.37 0.38 0.39 0.36 0.38 0.42 0.35 0.32 0.43 0.30 0.30 0.35 0.32 0.34 0.31 0.28 0.26 Orifice Pressure Diff (AH) (in H20) 1.20 0.93 0.86 0.90 0.86 0.97 1.10 1.30 1.30 1.30 1.20 1.30 1.40 1.20 1.10 1.50 1.00 1.00 1.20 1.10 1.20 1.00 0.97 0.90 Stack Temp Ts (F) 151 145 141 143 142 155 157 143 155 143 154 139 146 143 147 146 135 151 153 157 152 146 137 154 Dry Gas Meter Temperature Tm in Tm out (F) (F) 47 50 48 52 48 52 48 53 48 54 43 45 42 46 42 45 42 45 42 46 41 46 42 47 41 45 42 47 42 47 42 48 41 47 42 47 41 47 41 46 42 46 40 45 41 46 41 47 Calciner #6 M5_202_v2.xisx Run 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00429 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method 3A C02 Percent Replicate 1 7.9 Replicate 2 Replicate 3 Average 7.9 Method5/202 PCS Phosphate 60402248 Calciner# 6 Normal N-45 0.9942 3.0 30.13 02 Percent 13.5 13.5 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft] Static Pressure (Ps Stack Geometry (R or C)7 Stack Diameter (in] Stack Width (If Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 78.6 Nozzle ID (in) 1/27/2016 DM/LB 2 3.45 1.7992 0.84 100 -0.24 c 72.0 0.275 0.279 0.276 0.277 impinger Weights (g) initial Final Net impinger 1 502.9 678.9 176X Impinger2 594.1 654.9 60. impinger 3 706.0 710.5 4.5 impinger 4 937.2 956.1 18.9 impinger 5 o.c impinger 6 0.0 impinger 7 o.c impinger 8 o.c Moisture Collected (g) 260.2 Pitot Tube ED 8-4 Saturated Percent Moisture 25.23 Standard Calculated Percent Moisture 23.03 Volume (dsef) isokinetic % 101.0 41.0 Traverse Point Location B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 17:40:00 17:43:00 17:46:00 17:49:00 17:52:00 17:55:00 17:58:00 18:01:00 18:04:00 18:07:00 18:10:00 18:13:00 18:16:00 18:18:00 18:21:00 18:24:00 18:27:00 18:30:00 18:33:00 18:36:00 18:39:00 18:42:00 18:45:00 18:48:00 18:51:00 18:54:00 Dry Gas Meter Reading Vm (ft3) 894.611 896.500 897.900 899.700 901.400 902.900 904.800 906.700 908.100 909.700 911.400 912.900 914.445 914.445 916.300 918.000 919.900 921.600 923.600 925.300 926.600 928.000 929.300 930.800 931.300 933.710 Velocity Head (AP) (in H20) 0.37 0.34 0.32 0.35 0.37 0.35 0.36 0.27 0.33 0.26 0.31 0.31 0.32 0.41 0.37 0.37 0.30 0.20 0.22 0.20 0.18 0.23 0.25 0.16 Orifice Pressure Diff (AH) (in H20) 1.30 1.10 1.10 1.20 1.30 1.20 1.30 0.93 1.10 0.90 1.00 1.00 1.10 1.40 1.30 1.30 1.00 0.70 0.76 0.69 0.61 0.79 0.86 0.85 Stack Temp Ts (F) 157 153 156 155 157 157 158 158 156 144 151 144 155 145 155 147 155 143 141 147 154 162 129 126 Dry Gas Meter Temperature Tm in Tm out (F) (F) 42 45 42 46 41 46 42 46 42 47 42 48 42 48 42 48 42 49 42 49 43 48 42 49 43 47 42 46 41 46 41 48 41 45 40 45 40 45 40 44 40 45 41 45 40 43 39 42 Calciner #6 M5_202_v2.xisx Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00430 Enter data in unshaded areas. Sample Type Client/Plant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method 3A C02 Percent Replicate 1 8.1 Replicate 2 Replicate 3 Average 8.1 Method5/202 PCS Phosphate 60402248 Calciner# 6 Normal N-45 0.9942 3.0 29.99 02 Percent 13.4 13.4 Date Operator Run Number K Factor Meter aH@ Pitot Constant Height of Location (ft) Static Pressure (Ps Stack Geometry (R or C)? Stack Diameter (in] Stack Width (if Rectangle Nozzle ID 1 (in Nozzle ID 2 (in N2 Percent Nozzle ID 3 (in 78.5 Nozzle ID (in) 1/28/2016 DM/LB 3 3.45 1.7992 0.84 100 -0.24 c 72.0 0.275 0.279 0.276 0.277 impinger Weights (g) initial Final Net impinger 1 487.2 754.3 267.1 Impinger2 654.8 743.2 88.4 impinger 3 610.9 625.2 14.3 impinger 4 877.5 896.5 19.0 impinger 5 0.0 impinger 6 0.0 impinger 7 o.c impinger 8 0.0 Moisture Collected (g) 388.8 Pitot Tube ID 8-4 Saturated Percent Moisture 25.98 Standard Calculated Percent Moisture 31.37 Volume (dsef) isokinetic % 103.0 40.1 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 9:55:00 9:58:00 10:01:00 10:04:00 10:07:00 10:10:00 10:13:00 10:16:00 10:19:00 10:22:00 10:25:00 10:28:00 10:31:00 9:55:00 9:58:00 10:01:00 10:04:00 10:07:00 10:10:00 10:13:00 10:16:00 10:19:00 10:22:00 10:25:00 10:28:00 10:31:00 Dry Gas Meter Reading Vm (ft3) 934.498 935.900 937.300 938.100 940.300 941.800 943.100 944.700 946.400 948.100 949.700 951.500 953.185 953.185 954.800 956.700 958.300 959.800 961.400 963.200 964.800 966.500 968.400 969.900 971.500 973.191 Velocity Head (AP) (in H20) 0.23 0.23 0.22 0.23 0.27 0.25 0.28 0.33 0.36 0.35 0.36 0.33 0.30 0.31 0.28 0.28 0.29 0.33 0.34 0.32 0.31 0.25 0.27 0.30 Orifice Pressure Diff (AH) (in H20) 0.79 0.79 0.76 0.79 0.93 0.86 0.97 1.10 1.20 1.20 1.20 1.10 1.00 1.10 0.97 0.97 1.00 1.10 1.20 1.10 1.10 0.86 0.93 1.00 Stack Temp Ts (F) 144 142 143 144 153 145 154 146 151 154 156 149 147 154 155 156 157 158 160 158 154 155 153 155 Dry Gas Meter Temperature Tm in Tm out (F) (F) 40 43 40 44 40 45 41 46 41 47 42 48 41 47 41 48 42 49 42 49 43 50 43 51 44 50 44 51 44 52 45 53 46 53 46 54 47 54 47 55 47 55 48 56 48 56 49 56 Calciner #6 M5_202_v2.xisx Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00431 Emissions Test Run Summary Facility: PCS Phosphate Location: Calciner # 6 Condition Normal Sample Type: Method 13B Run Number: 1 Date: 26-Jan-16 2 26-Jan-16 3 26-Jan-16 Total Sampling Time (min) Corrected Barometric Pressure (in Hg) Absolute Stack Pressure (in H20) Stack Static Pressure (in H20) Average Stack Temperature (F Stack Area (sq in) Actual Meter Volume (cu ft) Average Meter Pressure (in H20) Average Meter Temperature (F Moisture Collected (g) Carbon Dioxide Concentration (%V) Oxygen Concentration (%V) Nitrogen Concentration (%V) Dry Gas Meter Factor (y8) Nozzle Diameter (in) Pitot Constant Average Sampling Rate (dscfm) Standard Metered Volume (dscf) Standard Metered Volume (dscm) Stack Moisture (%V) Saturated Moisture (%V) Mole Fraction Dry Stack Gas Dry Molecular Weight Wet Molecular Weight Average SORT of Delta P Stack Gas Velocity (fps) Stack Gas Velocity (mps) Volumetric Flow Rate (acfm) Volumetric Flow Rate (acmm) Volumetric Flow Rate (dscfm) Volumetric Flow Rate (dscmm) Percent Isokinetic Post Test Meter QA (yqa) 72.0 30.08 30.06 -0.24 154.0 4072 41.568 1.16 73.7 418.6 7.1 13.5 79.4 0.9943 0.277 0.84 0.573 41.227 1.167 32.4 27.1 0.729 29.68 26.51 0.58 36.4 11.1 61687 1747 38851 1100 99.9 1.0287 72.0 30.06 30.04 -0.24 154.7 4072 39.089 1.03 67.5 366.5 7.1 13.5 79.4 0.9943 0.277 0.84 0.544 39.184 1.110 30.6 27.8 0.722 29.68 26.43 0.55 34.6 10.5 58660 1661 36525 1034 101.0 1.0291 72.0 30.07 30.05 -0.24 154.5 4072 42.620 1.21 64.8 392.3 7.1 13.5 79.4 0.9943 0.277 0.84 0.597 42.976 1.217 30.1 27.8 0.722 29.68 26.44 0.59 37.4 11.4 63385 1795 39502 1119 102.2 1.0173 Average 72.0 30.07 30.05 -0.24 154.4 4072 41.092 1.13 68.7 392.5 7.1 13.5 79.4 0.9943 0.277 0.84 0.571 41.129 1.165 31.0 27.6 0.724 29.68 26.46 0.57 36.1 11.0 61244 1734 38293 1084 101.0 1.0251 Fluoride Emission Rate Calculations Orion 901 Meter Reading, ppm_________ 0.199 Liquid Sample Volume, ml_____________ 1000 Sample Aliquot_______________________ 10 Sample Dilution_______________________ 10 Total Fluoride, mg____________________ 0.1990 Fluoride Concentration, mg/DSCF______ 0.0048 Fluoride Emissions, lbs F/hr 0.0248 Rock Feed (Wet TPH)_________________ 67.86 Fluoride Emissions, lbs F/Ton Rock Feed 0.0004 0.169 1000 10 10 0.1690 0.0043 0.0208 67.86 0.0003 0.264 1000 10 10 0.2640 0.0061 0.0321 67.86 0.0005 Average N/A N/A N/A N/A 0.2107 0.0051 0.0259 67.9 0.0004 Calciner #6 M13B WetTPH.xIsx Run Summary 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00432 Enter data in unshaded areas. Sample Type Client/Piant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data Replicate 1 C02 Percent 7.1 Replicate 2 Replicate 3 Average 7.1 Method 13B PCS Phosphate 60402248 Calciner#6 Normal N-45 0.9943 3.0 30.18 02 Percent 13.5 13.5 Date Operator Run Number K Factor Meter AH@ Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 79.4 Nozzle ID (in) 1/26/2016 WL/BM 1 3.45 1.7992 0.84 100 -0.24 c 72.0 0.275 0.279 0.276 0.277 Impinger Weights (g) Initial Final Net Impinger 1 772.1 990.4 218.3 Impinger 2 698.3 881.3 183.0 Impinger 3 638.7 644.7 6.0 Impinger 4 904.1 915.4 11.3 Impinger 5 0.0 Impinger 6 0.0 Impinger 7 0.0 Impinger 8 0.0 Moisture Collected (g) 418.6 Pitot Tube ID 6-7 Saturated Percent Moisture 27.11 Standard Calculated Percent Moisture 32.37 Volume (dscf) Isokinetic % 99.9 41.2 Traverse Point Location A1 A2 A3 A4 A5 A6 A7 AS A9 A10 All A12 STOP B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 13:55:00 13:58:00 14:01:00 14:04:00 14:07:00 14:10:00 14:13:00 14:16:00 14:19:00 14:22:00 14:25:00 14:28:00 14:31:00 14:52:00 14:55:00 14:58:00 15:01:00 15:04:00 15:07:00 15:10:00 15:13:00 15:16:00 15:19:00 15:22:00 15:25:00 15:28:00 Dry Gas Meter Reading Vm (ft3) 718.349 720.040 721.670 723.240 724.840 726.470 728.260 730.060 731.880 733.650 735.480 737.310 739.110 739.110 740.920 742.770 744.690 746.370 748.180 749.920 751.570 753.250 754.880 756.500 758.330 759.917 Velocity Head (AP) (in H20) 0.29 0.31 0.25 0.34 0.30 0.35 0.38 0.45 0.32 0.37 0.34 0.34 0.38 0.40 0.42 0.28 0.37 0.32 0.28 0.32 0.29 0.34 0.32 0.27 Orifice Pressure Diff (AH) (in H20) 1.00 1.06 0.86 1.17 1.03 1.20 1.31 1.55 1.10 1.27 1.17 1.17 1.31 1.38 1.62 0.96 1.27 1.10 0.96 1.10 1.00 1.17 1.10 0.93 Stack Temp Ts (F) 160 158 159 149 161 160 148 147 144 143 157 155 161 158 161 153 161 154 149 150 158 145 151 153 Dry Gas Meter Temperature Tm in Tm out (F) (F) 71 71 71 70 71 70 72 70 73 70 74 70 75 70 76 71 76 70 77 71 77 71 77 71 76 72 77 72 78 72 78 72 78 72 78 72 78 72 78 73 78 72 78 73 78 73 78 73 Calciner #6 M13B WetTPH.xisx Run 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00433 Enter data in unshaded areas. Sample Type Client/Piant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data Replicate 1 C02 Percent 7.1 Replicate 2 Replicate 3 Average 7.1 Method 13B PCS Phosphate 60402248 Calciner#6 Normal N-45 0.9943 3.0 30.16 02 Percent 13.5 13.5 Date Operator Run Number K Factor Meter AH@ Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 79.4 Nozzle ID (in) 1/26/2016 WL/BM 2 3.45 1.7992 0.84 100 -0.24 c 72.0 0.275 0.279 0.276 0.277 Impinger Weights (g) Initial Final Net Impinger 1 637.0 907.2 270.2 Impinger 2 722.8 805.0 82.2 Impinger 3 654.1 658.3 4.2 Impinger 4 906.5 916.4 9.9 Impinger 5 0.0 Impinger 6 0.0 Impinger 7 0.0 Impinger 8 0.0 Moisture Collected (g) 366.5 Pitot Tube ID 6-7 Saturated Percent Moisture 27.80 Standard Calculated Percent Moisture 30.60 Volume (dscf) Isokinetic % 101.0 39.2 Traverse Point Location B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP A1 A2 A3 A4 A5 A6 A7 AS A9 A10 All A12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 16:50:00 16:53:00 16:56:00 16:59:00 17:02:00 17:05:00 17:08:00 17:11:00 17:14:00 17:17:00 17:20:00 17:23:00 17:26:00 16:49:00 16:52:00 16:55:00 16:58:00 17:01:00 17:04:00 17:07:00 17:10:00 17:13:00 17:16:00 17:19:00 17:22:00 17:25:00 Dry Gas Meter Reading Vm (ft3) 760.221 761.980 763.570 765.710 767.000 768.720 770.380 772.010 773.620 775.230 776.840 778.460 780.085 780.085 781.760 783.310 785.020 786.670 788.210 789.870 791.460 792.930 794.480 796.170 797.368 799.310 Velocity Head (AP) (in H20) 0.34 0.30 0.32 0.37 0.37 0.32 0.29 0.27 0.28 0.30 0.29 0.27 0.31 0.32 0.32 0.28 0.29 0.36 0.25 0.26 0.27 0.27 0.28 0.28 Orifice Pressure Diff (AH) (in H20) 1.17 1.03 1.10 1.27 1.27 1.10 1.00 0.93 0.96 1.03 1.00 0.93 1.06 1.10 1.10 0.96 1.00 1.24 0.86 0.89 0.93 0.93 0.96 0.96 Stack Temp Ts (F) 150 160 154 151 150 160 158 148 151 152 143 153 151 158 161 150 161 156 160 159 161 154 154 158 Dry Gas Meter Temperature Tm in Tm out (F) (F) 69 70 69 70 69 68 69 68 69 68 69 67 69 67 69 66 69 67 69 66 69 66 69 66 68 66 68 66 68 66 68 66 68 66 68 66 68 66 67 66 67 66 67 66 67 66 67 66 Calciner #6 M13B WetTPH.xisx Run 2 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00434 Enter data in unshaded areas. Sample Type Client/Piant Project Number Sampling Location Condition Meter Box Number Meter Factor (yd) Minutes per Point Barometric Pressure 02/C02 Method Per historical Data Replicate 1 C02 Percent 7.1 Replicate 2 Replicate 3 Average 7.1 Method 13B PCS Phosphate 60402248 Calciner#6 Normal N-45 0.9943 3.0 30.17 02 Percent 13.5 13.5 Date Operator Run Number K Factor Meter AH@ Pitot Constant Height of Location (ft) Static Pressure (Ps) Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Nozzle ID 1 (in) Nozzle ID 2 (in) N2 Percent Nozzle ID 3 (in) 79.4 Nozzle ID (in) 1/26/2016 WL/BM 3 3.45 1.7992 0.84 100 -0.24 c 72.0 0.278 0.276 0.277 0.277 Impinger Weights (g) Initial Final Net Impinger 1 755.3 999.3 244.0 Impinger 2 674.5 807.1 132.6 Impinger 3 641.5 646.6 5.1 Impinger 4 915.3 925.9 10.6 Impinger 5 0.0 Impinger 6 0.0 Impinger 7 0.0 Impinger 8 0.0 Moisture Collected (g) 392.3 Pitot Tube ID 6-7 Saturated Percent Moisture 27.79 Standard Calculated Percent Moisture 30.09 Volume (dscf) Isokinetic % 102.2 43.0 Traverse Point Location B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 STOP A1 A2 A3 A4 A5 A6 A7 AS A9 A10 All A12 Sampling Time (min) 0 3 6 9 12 15 18 21 24 27 30 33 36 36 39 42 45 48 51 54 57 60 63 66 69 72 Clock Time (24 hr) 19:05:00 19:08:00 19:11:00 19:14:00 19:17:00 19:20:00 19:23:00 19:26:00 19:29:00 19:32:00 19:35:00 19:38:00 19:41:00 19:45:00 19:48:00 19:51:00 19:54:00 19:57:00 20:00:00 20:03:00 20:06:00 20:09:00 20:12:00 20:15:00 20:18:00 20:21:00 Dry Gas Meter Reading Vm (ft3) 799.610 801.350 802.980 804.650 806.370 808.260 801.070 811.850 813.660 815.870 817.270 819.260 821.012 821.012 822.870 824.680 826.570 828.450 830.270 832.140 833.880 835.560 837.210 838.990 840.670 842.230 Velocity Head (AP) (in H20) 0.29 0.30 0.31 0.34 0.42 0.34 0.37 0.37 0.35 0.38 0.38 0.38 0.39 0.37 0.40 0.38 0.36 0.41 0.34 0.31 0.28 0.38 0.31 0.27 Orifice Pressure Diff (AH) (in H20) 1.00 1.03 1.06 1.17 1.44 1.17 1.27 1.27 1.20 1.31 1.31 1.31 1.34 1.27 1.38 1.31 1.24 1.41 1.17 1.06 0.96 1.31 1.06 0.93 Stack Temp Ts (F) 152 141 159 160 159 160 152 160 158 157 155 152 145 156 144 149 158 150 156 151 157 157 159 160 Dry Gas Meter Temperature Tm in Tm out (F) (F) 62 63 62 62 63 62 64 62 64 61 66 62 66 61 67 62 68 62 68 62 68 62 68 62 66 62 68 62 68 62 69 63 69 62 69 63 70 63 70 63 70 63 70 63 70 63 70 63 Calciner #6 M13B WetTPH.xisx Run 3 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00435 AECONi PCS Phosphate Calciner #6 Mercury Emission Calculations EPA Method 30B Emission Results 02 Correction Basis 3 Pollutant: Mercury Run 1 2 3 AVERAGE Total Hg Catch ng 3009 2828 3016 2951 Sample Volume dscm 0.051 0.050 0.051 0.051 Hg Concentration mg/dscm 0.0593 0.0562 0.0587 0.0581 Hg Concentration ppmV 0.0071 0.0067 0.0070 0.0070 Oxygen % 13.60 13.46 13.43 13.50 Hg Concentration mg/dscm @ 3% 0.145 0.135 0.141 0.140 Flow Rate dscfm 44.433 44;579 43,830 44,281 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Mercury ED 001523 00007569-00436 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 1 PCS 60402248.1 Calciner #6 Normal -0.26 100 30.59 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 5.43 5.4 02 Percent 13.60 N2 Percent 13.6 81.0 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 25.47 25.47 0.745 29.41 26.51 2/19/2016 DM/WL 0.84 C 72.0 4071.5 30.5 30.47 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AB) (in H20) 0.41 0.42 0.36 0.35 0.42 0.40 0.38 0.43 0.39 0.44 0.38 0.26 0.43 0.44 0.43 0.45 0.43 0.40 0.53 0.44 0.51 0.49 0.32 0.35 Stack Temp Ts (F) 139 140 144 146 148 150 152 152 152 152 152 151 151 151 152 152 154 155 155 155 155 156 157 155 Square Root of SQRT(AB) 0.640 0.648 0.600 0.592 0.648 0.632 0.616 0.656 0.624 0.663 0.616 0.510 0.656 0.663 0.656 0.671 0.656 0.632 0.728 0.663 0.714 0.700 0.566 0.592 Stack Gas Velocity (fps) 39.6 40.1 37.3 36.8 40.4 39.5 38.5 41.0 39.0 41.5 38.5 31.8 41.0 41.4 41.0 41.9 41.1 39.6 45.6 41.6 44.8 43.9 35.5 37.1 Average Stack Average SORT Temp AP Average Velocity 151.08 0.64 39.94 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 67749 59615 44433 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R1 ED 001523 00007569-00437 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 2 PCS 60402248.1 Calciner #6 Normal -0.26 100 30.54 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 7.92 7.9 02 Percent 13.46 N2 Percent 13.5 78.6 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 23.68 23.68 0.763 29.81 27.01 2/19/2016 DM/WL 0.84 C 72.0 4071.5 30.4 30.42 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AB) (in H20) 0.44 0.46 0.45 0.40 0.40 0.37 0.35 0.34 0.35 0.34 0.29 0.27 0.42 0.39 0.38 0.40 0.42 0.45 0.48 0.52 0.53 0.50 0.42 0.28 Stack Temp Ts (F) 137 139 140 141 141 142 142 142 143 146 149 150 154 154 155 155 155 156 156 156 156 156 156 152 Square Root of SQRT(AB) 0.663 0.678 0.671 0.632 0.632 0.608 0.592 0.583 0.592 0.583 0.539 0.520 0.648 0.624 0.616 0.632 0.648 0.671 0.693 0.721 0.728 0.707 0.648 0.529 Stack Gas Velocity (fps) 40.6 41.6 41.2 38.8 38.8 37.4 36.4 35.8 36.4 36.0 33.3 32.2 40.2 38.8 38.3 39.3 40.3 41.7 43.1 44.8 45.3 44.0 40.3 32.8 Average Stack Average SORT Temp AP Average Velocity 148.88 0.63 39.05 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 66249 58411 44579 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R2 ED 001523 00007569-00438 Method 2 Velocity Traverse Run Number Client/Plant Project Number Sampling Location Condition Static Pressure (Ps) Location Height (ft) Barometric Pressure 3 PCS 60402248.1 Calciner #6 Normal -0.26 100 30.51 Date Operator Pitot Constant Stack Geometry (R or C)? Stack Diameter (in) Stack Width (If Rectangle) Stack Area (sq. in.) Corrected Baro. Pressure Abs. Stack Press, (in. Hg) Assumed Replicate 1 Replicate 2 Replicate 3 Average C02 Percent 8.07 8.1 02 Percent 13.43 N2 Percent 13.4 78.5 Moisture By: Saturation Saturated Percent Moisture Calculated Percent Moisture Mole Frac of Dry Stack Gas Average MW of Dry Gas Average MW of Wet Gas 24.30 24.30 0.757 29.83 26.95 2/19/2016 DM/WL 0.84 C 72.0 4071.5 30.4 30.39 Traverse Point Location A1 2 3 4 5 6 7 8 9 10 11 12 B1 2 3 4 5 6 7 8 9 10 11 12 Velocity Head (AB) (in H20) 0.41 0.40 0.38 0.38 0.40 0.39 0.37 0.35 0.33 0.32 0.31 0.29 0.46 0.51 0.49 0.48 0.46 0.46 0.42 0.40 0.37 0.39 0.42 0.27 Stack Temp Ts (F) 137 137 138 138 142 145 146 148 149 150 152 151 152 153 154 154 155 155 156 156 156 156 152 148 Square Root of SQRT(AB) 0.640 0.632 0.616 0.616 0.632 0.624 0.608 0.592 0.574 0.566 0.557 0.539 0.678 0.714 0.700 0.693 0.678 0.678 0.650 0.632 0.608 0.624 0.648 0.520 Stack Gas Velocity (fps) 39.3 38.8 37.8 37.8 38.9 38.5 37.6 36.6 35.6 35.1 34.6 33.4 42.1 44.4 43.5 43.1 42.2 42.2 40.5 39.4 37.9 38.9 40.2 32.1 Average Stack Average SORT Temp AP Average Velocity 149.17 0.63 38.77 Act Volumetric Flow Rate (acfm) Std. Volumetric Flow Rate (scfm) Dry Volumetric Flow Rate (dscfm) 65765 57900 43830 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production R3 ED 001523 00007569-00439 AZCOM Date 2/19/2016 Plant PCS Phosphate Location Calciner #6 Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 23 Final Leak Check (L/min (5) "Hg) 0.000 21 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H20) Barometric Pres. (" Hg) OL211412 30.49 Meter Number 8002494 Totalizer Cal Factor (Y) DGM Cal Factor (Y) 1.018 1.018 Stack Diameter 72 Assumed H20 % K-factor 02 % C02% 02/C02 Method Method 3A Page 1 of_____1_ Run No, 1 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) 11:30:00 11:35 11:40 11:45 11:50 11:55 12:00 12:05 12:10 12:15 12:20 12:25 12:30 Digital Gas Meter Reading <L) 0.000 3.65 7.29 11.22 15.20 19.40 23.31 27.19 31.04 34.90 38.97 43.12 46.631 46.631 Mechanical Gas Meter Reading (m3) 46.6310 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) 152 152 152 152 152 152 152 152 152 152 152 155 156 153 Trap Temp, (deg. F) 297 312 297 271 249 251 256 278 279 268 260 267 270 273 Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp. (deg. F) 44 32 251 44 32 254 44 31 261 45 32 257 45 32 257 45 31 257 46 32 256 48 31 259 47 31 258 47 31 259 48 31 259 48 31 257 48 31 257 46 31 257 Pump Vacuum <" Hg) 2 2 2 2 2 2 2 2 2 2 2 2 2 2 Target Volume Spike Amount (ng) 2200 Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 50469.96245 50.4699624 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 1A ED 001523 00007569-00440 A-COM Date 2/19/2016 Plant PCS Phosphate Location Calciner #6 Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 22 Final Leak Check (L/min @ "Hg) 0.000 18 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL232760 30.49 Meter Number 8002663 Totalizer Cal Factor (Y) 1.028 DGM Cal Factor (Y) 1.028 Stack Diameter 72 Assumed H20 % K-factor 02 % C02% 02/C02 Method Method 3A Page 1 of_____1_ Run No, 1 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 11:30:00 11:35 11:40 11:45 11:50 11:55 12:00 12:05 12:10 12:15 12:20 12:25 12:30 0.000 3.79 7.60 11.50 15.44 19.60 23.53 27.44 31.26 35.10 39.21 43.41 46.773 46.773 46.773 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 152 297 45 152 312 45 152 297 45 152 271 46 152 249 46 152 251 47 152 256 48 152 278 48 152 279 48 152 268 48 152 260 49 155 267 49 156 270 49 153 273 47 32 251 32 254 31 261 32 257 32 257 31 257 32 256 31 259 31 258 31 259 31 259 31 257 31 257 31 257 Pump Vacuum C Hg) 3 3 3 3 3 3 3 3 3 3 3 3 3 3.00 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 51012.31402 51.012314 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production IB ED 001523 00007569-00441 AECONl Date 2/19/2016 Plant PCS Phosphate Location Calciner #6 Sample Type 30 B Run Number/Side (A/B) Operator DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 20 Final Leak Check (L/min @ "Hg) 0.000 16 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL211407 30.44 Meter Number 8002494 Totalizer Cal Factor (Y) 1.018 DGM Cal Factor (Y) 1.018 Stack Diameter 72 Assumed H20 % K-factor 02 % C02% 02/C02 Method Method 3A Page 1 of____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0 12:50:00 0.000 5 12:55 4.46 10 13:00 8.38 15 13:05 12.30 20 13:10 15.96 25 13:15 19.96 30 13:20 24.13 35 13:25 28.42 40 13:30 32.00 45 13:35 35.47 50 13:40 39.04 55 13:45 42.78 60 13:50 46.778 46.7780 46.7780 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 160 237 48 163 260 48 150 297 49 156 314 49 166 300 49 151 257 50 156 240 50 163 268 50 164 301 51 163 309 50 162 270 51 159 246 51 149 252 51 159 273 50 32 253 32 253 31 255 31 253 32 258 31 259 31 257 32 255 31 256 32 257 32 262 32 258 32 253 32 256 Pump Vacuum (" Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1.00 Target Volume Spike Amount (ng) 2200 Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 50179.69175 50.1796918 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2A ED 001523 00007569-00442 AZCOM Date 2/19/2016 Plant PCS Phosphate Location Calciner#6 Sample Type 30 B Run Number/Side (A/B) Operator DM Location Height Initial Leak Check (L/min @ "Hg) 0.000 25 Final Leak Check (L/min @ "Hg) 0.000 14 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" hfeO) Barometric Pres. (" Hg) OL2322890 30.44 Meter Number 8002663 Totalizer Cal Factor (Y) 1.028 DGM Cal Factor (Y) 1.028 Stack Diameter 72 Assumed H20 % K-factor 02 % C02% 02/C02 Method Method 3A Page 1 of____ 1_ Run No, 2 Diagram of Duct & Traverse Points Single Point A1 TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0 12:50:00 0.000 5 12:55 4.430 10 13:00 8.220 15 13:05 12.170 20 13:10 15.840 25 13:15 19.890 30 13:20 24.080 35 13:25 28.400 40 13:30 32.010 45 13:35 35.630 50 13:40 39.230 55 13:45 43.130 60 13:50 46.831 46.831 46.831 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 160 237 51 163 260 55 150 297 52 156 314 53 166 300 52 151 257 51 156 240 53 163 268 51 164 301 54 163 309 51 162 270 52 159 246 52 149 252 52 159 273 52 32 253 32 253 31 255 31 253 32 258 31 259 31 257 32 255 31 256 32 257 32 262 32 258 32 253 32 256 Pump Vacuum C Hg) 3 3 2 2 2 2 2 2 2 2 2 2 2 2.15 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 50486.08703 50.486087 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 2B ED 001523 00007569-00443 A-COM Date 2/19/2016 Plant PCS Phosphate Location Calciner #6 Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height Initial Leak Check (L/min @ "Hg) 0.000 22 Final Leak Check (L/min @ "Hg) 0.000 18 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL211410 30.41 Meter Number 8002494 Totalizer Cal Factor (Y) 1.018 DGM Cal Factor (Y) 1.018 Stack Diameter 72 Assumed H20 % K-factor 02 % C02% 02/C02 Method Method 3A Page 1 of_____1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Time (min) 0 5 10 15 20 25 30 35 40 45 50 55 60 Clock Time (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) 14:00:00 14:05 14:10 14:15 14:20 14:25 14:30 14:35 14:40 14:45 14:50 14:55 15:00 0.000 4.650 8.350 12.800 16.590 20.570 24.490 28.520 32.410 36.270 40.550 44.500 47.893 47.893 47.893 Meter Flow Rate (Lpm) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 161 269 50 154 297 51 163 272 51 163 279 51 164 281 51 163 284 51 160 290 51 160 286 51 159 274 52 158 278 52 161 279 52 160 280 52 160 279 52 160 281 51 32 254 32 256 31 255 31 256 31 257 31 259 31 256 31 256 31 257 31 258 31 257 31 257 31 256 31 256 Pump Vacuum C Hg) 1 1 1 1 1 1 1 1 1 1 1 1 1 1.00 Target Volume Spike Amount (ng) 2200 Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 51170.61056 51.1706106 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3A ED 001523 00007569-00444 A-COM Date 2/19/2016 Plant PCS Phosphate Location Calciner #6 Sample Type 30 B Run Number/Side (A/B) Operator WL Location Height 100 Initial Leak Check (L/min @ "Hg) 0.000 25 Final Leak Check (L/min @ "Hg) 0.000 16 METHOD 30B Sorbent Trap Number Probe Length & Type Nozzle ID (inches) Probe Heat Set Point ( F) Tube Heat Set Point ( F) Minutes Per Point Ambient Temp. ( F) Static Pressure (" H2O) Barometric Pres. (" Hg) OL235498 30.41 Meter Number 8002663 Totalizer Cal Factor (Y) 1.028 DGM Cal Factor (Y) 1.028 Stack Diameter 72 Assumed H20 % K-factor 02 % C02% 02/C02 Method Method 3A Page 1 of_____1_ Run No, 3 Diagram of Duct & Traverse Points Single Point TOTAL Sampling Clock Time Time (min) (min) Digital Gas Meter Reading (L) Mechanical Gas Meter Reading (m3) Meter Flow Rate (Lpm) 0 14:00:00 0.000 5 14:05 4.540 10 14:10 8.250 15 14:15 12.730 20 14:20 16.460 25 14:25 20.350 30 14:30 24.270 35 14:35 28.300 40 14:40 32.420 45 14:45 36.630 50 14:50 40.510 55 14:55 44.270 60 15:00 48.017 48.017 48.017 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 Stack Temp, (deg. F) Trap Temp, (deg. F) Meter Temp, (deg. F) Chiller Temp, (deg. F) Heated Line Temp, (deg. F) 161 269 52 154 297 53 163 272 53 163 279 53 164 281 53 163 284 53 160 290 53 160 286 54 159 274 54 158 278 54 161 279 54 160 280 54 160 279 54 160 281 53 32 254 32 256 31 255 31 256 31 257 31 259 31 256 31 256 31 257 31 258 31 257 31 257 31 256 31 256 Pump Vacuum <" Hg) 2 2 2 2 2 2 2 2 2 2 2 2 2 2.00 Target Volume Spike Amount (ng) Comments: Barometric Pressure corrected for elevation Mechanical Totalizer Total Volume (L) 51597.33349 51.5973335 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production 3B ED 001523 00007569-00445 Calibration Error Test, Run 1 strata Version 3.2.112 Operator: Pat Turner Plant Name: PCS Aurora Location: Calciner #6 Reference Cylinder Numbers zero Low-range Mid-range 02 CC96938 CC313420 C02 CC96938 CC313420 High-range CC102927 CC102927 Date/Time 02-19-2016 Analyte 02 C02 Units % % zero Ref Cyl 0.000 0.000 Zero Avg 0.005 -0.024 Zero Error% 0.0% 0.1% Low Ref Cyl Low Avg Low Error'?; Mid Ref Cyl 10.100 9.670 Mid Avg 10.058 9.586 Mid Error% 0.2% 0.4% High Ref Cyl 19.260 20.760 High Avg 19.257 20.809 High Error% 0.0% 0.2% Calibration Error Test End 08:34:23 PASSED Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00446 Initial System Bias Check, Run 1 STRATA Version 3.2.112 Operator: Pat Turner Plant Name: PCS Aurora Location: Calciner #6 Reference Cylinder Numbers zero Span 02 CC96938 CC313420 C02 CC96938 CC313420 Date/Time 02-19-2016 Analyte 02 C02 Onits % % Zero Ref Cyl 0.000 0.000 Zero Cal -0.005 -0.024 Zero Avg 0.041 0.121 Zero Bias% 0.2% 0.7% Zero Drift% Span Ref Cyl 10.100 9.670 Span Cal 10.058 9.586 Span Avg 10.068 9.544 Span Bias% 0.0% 0.2% Span Drift% System Bias Check End 09:16:40 PASSED Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00447 Test Run 1 STRATA version 3.2.112 02 C02 ' % % Begin calculating run averages 02-19-2016 11:31:14 02-19-2016 11:32:14 13.676 13.463 5.363 5.064 02-19-2016 11:33:13 02-19-2016 11:34:13 14.138 14.424 4.214 4.918 02-19-2016 11:35:13 13.530 5.323 02-19-2016 11:36:13 02-19-2016 11:37:14 13.236 13.372 5.192 5.348 02-19-2016 11:38:14 02-19-2016 11:39:14 13.461 13.260 5.041 5.432 02-19-2016 11:40:14 12.798 5.447 02-19-2016 11:41:14 02-19-2016 11:42:14 13,316 13.126 5.160 5.409 02-19-2016 11:43:13 02-19-2016 11:44:14 13.044 12.931 5.452 5.521 02-19-2016 11:45:13 13.046 5.443 02-19-2016 11:46:13 02-19-2016 11:47:13 12.777 13.146 5.636 5.133 02-19-2016 11:48:13 13.108 5.486 02-19-2016 11:49:13 13.246 5.043 02-19-2016 11:50:13 13.420 4.996 02-19-2016 11:51:13 02-19-2016 11:52:13 13.456 13.872 5.038 4.729 02-19-2016 11:53:14 13.919 4.882 02-19-2016 11:54:14 02-19-2016 11:55:14 13.804 13.792 4.913 4.830 02-19-2016 11:56:13 02-19-2016 11:57:14 14.191 14.385 4.215 4.613 02-19-2016 11:58:13 02-19-2016 11:59:13 13.919 13.743 4.874 4.712 02-19-2016 12:00:13 13.850 4.591 02-19-2016 12:01:13 02-19-2016 12:02:13 14.060 13.736 4.601 4.855 02-19-2016 12:03:13 13.457 5.182 02-19-2016 12:04:13 13.221 5.195 02-19-2016 12:05:13 02-19-2016 12:06:14 02-19-2016 12:07:14 13.193 12.703 13.493 5.397 4.971 5.136 02-19-2016 12:08:14 13.247 5.520 02-19-2016 12:09:14 13.316 5.209 02-19-2016 12:10:13 13.696 5.115 02-19-2016 12:11:13 13.637 5.478 02-19-2016 12:12:13 13.720 5.178 02-19-2016 12:13:13 02-19-2016 12:14:14 13.921 13.932 5.400 5.455 02-19-2016 12:15:14 13.606 5.751 02-19-2016 12:16:14 13.708 5.392 02-19-2016 12:17:14 02-19-2016 12:18:14 13.988 13.741 5.752 5.765 02-19-2016 12:19:14 13.623 6.040 02-19-2016 12:20:13 02-19-2016 12:21:13 13.408 13.064 6.073 6.025 02-19-2016 12:22:13 13.116 6.327 02-19-2016 12:23:13 02-19-2016 12:24:13 02-19-2016 12:25:13 12.924 13.118 12.882 6.170 6.381 6.326 02-19-2016 12:26:14 12.999 6.236 02-19-2016 12:27:14 13.192 5.830 02-19-2016 12:28:14 02-19-2016 12:29:13 13.535 13.017 6.085 6.478 02-19-2016 12:30:13 13.258 5.834 Run Averages 02 C02 % % 02-19-2016 12:30:14 13.466 Operator: Pat Turner 5.353 Plant Name: PCS Aurora Location: Calciner #6 Test Run 1 End Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00448 Final System Bias Check, Run 1 STRATA Version 3.2.112 Operator: Pat Turner Plant Name: PCS Aurora Location: Calciner #6 Reference Cylinder Numbers Zero Span 02 CC96938 CC313420 C02 CC96938 CC313420 Date/Time Analyte Dnits Zero Ref Cyl Zero Cal Zero Avg Zero Bias% Zero Drift% Span Ref Cyl Span Cal Span Avg Span Bias% Span Drift% 02-19-2016 02 C02 % % 0.000 0.000 -0.005 -0.024 0.064 0.180 0.4% 1.0% 0.1% 0.3% 10.100 9.670 10.058 9.586 9.955 9.290 0.5% 1.4% -0.6% -1.2% PASSED Ini Zero Avg 0.041 Ini Span Avg 10.068 Run Avg 13.466 Co 0.052 Cm 10.012 Correct Avg 13.603 System Bias Check End 0.121 9.544 5.353 0.150 9.417 5.429 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00449 Test Run 2 STRATA Version 3.2.112 02 C02 % % Begin calculating run averages 02-19-2016 12:51:04 02-19-2016 12:52:03 02-19-2016 12:53:04 02-19-2016 12:54:03 02-19-2016 12:55:03 02-19-2016 12:56:03 02-19-2016 12:57:03 02-19-2016 12:58:03 02-19-2016 12:59:03 02-19-2016 13:00:02 02-19-2016 13:01:02 02-19-2016 13:02:02 13.953 13.379 13.208 13.405 12.547 12.928 12.934 13.184 12.893 12.581 13.037 12.945 7.611 7.968 7.394 8.274 8.017 7.827 7.718 7.797 8.352 8.191 7.590 8.201 02-19-2016 13:03:03 02-19-2016 13:04:03 02-19-2016 13:05:03 02-19-2016 13:06:02 02-19-2016 13:07:03 02-19-2016 13:08:03 02-19-2016 13:09:03 02-19-2016 13:10:03 12.369 12.365 12.726 12.914 12.809 13.680 13.241 13.101 8.349 8.215 7.582 8.272 7.095 7.452 7.755 7.680 02-19-2016 13:11:03 02-19-2016 13:12:03 02-19-2016 13:13:03 02-19-2016 13:14:03 02-19-2016 13:15:03 02-19-2016 13:16:03 13.453 13.943 13.514 14.334 14.117 13.702 6.860 7.636 6.478 6.689 6.928 7.727 02-19-2016 13:17:03 02-19-2016 13:18:03 13.208 14.142 7.061 6.591 02-19-2016 13:19:02 02-19-2016 13:20:02 02-19-2016 13:21:02 02-19-2016 13:22:02 02-19-2016 13:23:03 02-19-2016 13:24:03 02-19-2016 13:25:03 02-19-2016 13:26:03 14.391 14.219 13.846 13.477 13.623 14.036 13.153 12.455 6.618 7.034 7.402 7.359 7.021 7.022 8.217 7.789 02-19-2016 13:27:03 02-19-2016 13:28:03 02-19-2016 13:29:02 02-19-2016 13:30:03 02-19-2016 13:31:03 02-19-2016 13:32:03 02-19-2016 13:33:03 02-19-2016 13:34:03 12.812 12.706 12.061 12.343 12.559 12.461 12.545 12.596 7.766 8.481 8.290 7.820 7.971 8.088 7,731 7.926 02-19-2016 13:35:03 02-19-2016 13:36:03 02-19-2016 13:37:04 02-19-2016 13:38:03 02-19-2016 13:39:03 02-19-2016 13:40:03 02-19-2016 13:41:03 02-19-2016 13:42:03 02-19-2016 13:43:03 02-19-2016 13:44:03 02-19-2016 13:45:03 02-19-2016 13:46:03 02-19-2016 13:47:03 02-19-2016 13:48:02 02-19-2016 13:49:03 02-19-2016 13:50:03 Run Averages 13.031 13.173 12.462 12.566 13.492 13.429 13.335 13.441 13.462 13.662 14.029 13.711 13.896 13.578 13.714 14.018 02 7.258 7.793 8.264 7.271 7.018 7.529 7.061 7.343 7.076 6.940 6.987 6.846 7.207 7.114 6.865 6.905 C02 % % 02-19-2016 13:50:03 Operator: Plant Name: Location: Test Run 2 End 13.250 Pat Turner PCS Aurora Calciner #6 7.520 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00450 Final System Bias Check, Run 2 STRATA Version 3.2,112 Operator: Pat Turner Plant Name: PCS Aurora Location: Calciner #6 Reference Cylinder Numbers' 2ero Span 02 CC96938 CC313420 C02 CC96938 CC313420 Date/Time Analyte 0nits Zero Ref Cyl Zero Cal zero Avg Zero Bias% Zero Drift% Span Ref Cyl Span Cal Span Avg Span Bias% Span Drft% 02-19-2016 02 C02 % % 0.000 0.000 -0.005 -0.024 0.073 0.065 0.4% 0.4% 0.0% -0.6% 10.100 9.670 10.058 9.586 9.960 9.014 0.5% 2.8% 0.0% -1.3% 13:53:50 PASSED Ini Zero Avg 0.064 Ini Span Avg 9.955 Run Avg 13.250 CO 0.068 Cm 9.958 Correct Avg 13.462 System Bias Check End 0.180 9.290 7.520 0.122 9.152 7.923 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00451 Test Run 3 STRATA Version 3,2.112 02 C02 % % Begin calculating run averages 02-19-2016 14:01:03 12.953 7. 807 02-19-2016 14:02:03 12.878 7. 835 02-19-2016 14:03:03 13.148 7. 273 02-19-2016 14:04:02 13.685 7. 167 02-19-2016 14:05:02 13.781 7. 268 02-19-2016 14:06:02 13.463 7. 390 02-19-2016 14:07:02 13.580 7. 264 02-19-2016 14:08:02 13.446 7, 215 02-19-2016 14:09:02 13.781 6. 984 02-19-2016 14:10:02 13.841 7. 187 02-19-2016 14:11:03 13.604 7. 276 02-19-2016 14:12:03 13.628 7. 151 02-19-2016 14:13:03 13.932 6. 534 02-19-2016 14:14:03 14,350 7. 045 02-19-2016 14:15:03 13.392 7. 694 02-19-2016 14:16:03 02-19-2016 14:17:03 12.872 13.040 7. 704 7. 222 02-19-2016 14:18:02 13.052 8. 009 02-19-2016 14:19:02 12.207 8. 303 02-19-2016 14:20:02 12.170 7. 710 02-19-2016 14:21:02 12.704 7. 682 02-19-2016 14:22:03 12.400 8. 092 02-19-2016 14:23:03 12.714 7. 771 02-19-2016 14:24:03 12.370 7. 596 02-19-2016 14:25:02 12.820 7. 815 02-19-2016 14:26:02 12.494 7. 820 02-19-2016 14:27:02 12.705 7. 478 02-19-2016 14:28:02 13.159 7. 218 02-19-2016 14:29:02 13.373 7. 779 02-19-2016 14:30:02 13.278 6. 507 02-19-2016 14:31:02 13.978 7, 084 02-19-2016 14:32:02 13.388 7. 393 02-19-2016 14:33:02 13.047 7. 232 02-19-2016 14:34:03 13.606 6. 830 02-19-2016 14:35:03 13.593 6. 892 02-19-2016 14:36:03 13.947 7. 198 02-19-2016 14:37:03 13.426 6. 989 02-19-2016 14:38:03 13.404 7. 273 02-19-2016 14:39:03 13.475 6. 829 02-19-2016 14:40:03 13.938 6. 643 02-19-2016 14:41:03 02-19-2016 14:42:03 14.060 13.869 6. 793 7. 211 02-19-2016 14:43:03 13.375 7. 300 02-19-2016 14:44:03 13.282 7. 204 02-19-2016 14:45:03 13.783 6. 775 02-19-2016 14:46:02 13.749 7. 056 02-19-2016 14:47:02 13.382 7. 603 02-19-2016 14:48:02 13.032 7. 564 02-19-2016 14:49:03 12.814 7. 511 02-19-2016 14:50:03 13.155 7. 443 02-19-2016 14:51:03 12.907 7. 532 02-19-2016 14:52:03 12.807 7. 694 02-19-2016 14:53:02 12.682 7. 530 02-19-2016 14:54:02 12.983 7. 812 02-19-2016 14:55:02 12.700 7. 589 02-19-2016 14:56:02 12.625 7. 828 02-19-2016 14:57:03 12.421 8. 171 02-19-2016 14:58:03 12.277 7. 313 02-19-2016 14:59:03 13.227 7. 041 02-19-2016 15:00:03 13.211 7. 513 Run Averages 02 C02 &15 % 02-19-2016 15:00:03 13.215 7. 378 Operator: Pat Turner Plant Name: PCS Aurora Location: Calciner #6 Test Run 3 End Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00452 Final System Bias Check, Run 3 STRATA Version 3.2.112 Operator: Pat Turner Plant Name: PCS Aurora Location: Calciner #6 Reference Cylinder Numbers Zero Span 02 CC96938 CC313420 C02 CC96938 CC313420 Date/Time Analyte Units Zero Ref Cyl Zero Cal Zero Avg zero Bias% Zero Drit% Span Ref Cyl Span Cal Span Avg Span Bias% Span Drifts. 02-19-2016 02 C02 % % 0.000 0.000 -0.005 -0.024 0.091 0.094 0.5% 0.6% 0.1% 0.1% 10.100 9.670 10.058 9.586 9.958 8.632 0.5% 4.6% 0.0% -1.8% PASSED Ini Zero Avg 0.073 Ini Span Avg 9.960 Run Avg 13.215 Co 0.082 Cm 9.959 Correct Avg 13.430 System Bias Check End 0.065 9.014 7.378 0.079 8.823 8.072 Page 1 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00453 AECOM FIELD SAMPLING DATA SHEET Sample and Velocity Traverse for Stationary Sources EPA METHOD 1 Client/Plant: Project#: Q,&AoUlJXX Location: Number of Traverse Points Chosen: U\ Number of Ports: 7_ Duct Diameters From Downstream Row Disturbance (A/D) 0. 1.0 1.5 2.0 Date: cA~ Number of Points per Port: \ Duct Diameters From Upstream Flow Disturbance (B/D) Deq = 2LW / (L+W) Dnstream Diameters (A/D) Upstream Diameters (B/D) Cross-Sectional Layout of Rectangular Stacks Traverse Points Matrix 9 3x3 12 4x3 16 4x4 20 5x4 25 5x5 Traverse Point Fraction Distance of From Diameter Wall Nipple Length Point Location 1 Z. t us Lr`'C 2 G .T 4/k 3 Xh& 4 n;t 5 1^.0 7V> 6 5t>,L. 7 CMM 4LL.M 1.4 8 S=l.o 9 Usb 10 w.t . 11 ^fvT L7.1 __i i__ "?*rV 12 `TT-.i LOCATION OF TRAVERSE POINT IN RECTANGULAR STACKS. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00454 AzCOM FIELD SAMPLING DATA SHEET Flow and Moisture EPA Methods 2 & 4 PAGE / OF X Client/Plant;fits Project #: (/igljti'Z2 V 9*. to Date: ~>/~ Operator(s): 0 Location: tol *4 Condition: AJ0l^j Moisture Run #: / Duration (min): DGM#: CF (Yd): qfyj AHq: /, 7 Cp: 0.84 Pbar("Hg): Height w.r.t Barometer (ft); /0ti static ("H20): 9 Initial Leak (<0.02 ft3/min; >10"Hg) ft3/min: Vac. ("Hg): Source Height (ft): Duct Diameter ("): Final Leak * (<0.02 ft /min; >run maximum) ft /min Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak (>3"H20) +P ("H20): - P (H2O): Pitot Tube ID#: O2 (%/time) % % % CO2 (%/time) % % % , Time Moisture Determination DGM Volume (ft3) AH ("HzO) DGM inlet T CD DGM Outlet T CF) Flow Run #: f Row Run #: Traverse Point End m-mI/a. ST &p Source T fH20) CF) Start AP C'HsO) End Source T CF) 3/ /S3 Flow Run #: Start End AP Source T CH2o) CD Cyclonic Angle () a 2 /</*/ eg 3 *33 JSQ 0 7 ,3f 3 /<fi 4 4 /so 0 /V3 0 -j-- /93l /V& jo /fg // * <3J> ?JL,,. fJS', Aj frJl X3 3 tVQ /9T tvs /3 J 4 . 7 0 .30 /y/ /#> JSlS /37 ' ,47 / ? 7 1 /S'/ /0 /93 /( , 7.. mj fJ ,37 /f/ 0 a S // 7 *7 9 3 3 ' y fS /A /& /ft Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00455 AECONi FIELD SAMPLING DATA SHEET EPA Method 13A/B PAGE / OF __ t- MS. Client/Piant: Location: Co/. *4 DGM#: K-Factor: 5, c/A Project#: ^onozzg^ /o pate:.qJTmTt Condition: h)0fm^\ CF (Yd): PbarC'Hg): <2*7*0 Run#: / -A1f:..A/990. ** Height w.r.t. Barometer (ft):jo<y Operators): [jj_ /> ft -X - Duration (min); 2 Cp: 0.84 Pstatic C'HzO): M. Initial Leak-/ (<0.02 ft/min; >10''Hg) Vac. ("Hg):^f Source Height (ft): ^ Duct Diameter ("): Final Leak / (<0.02 ft /min; >max vacuum) Vac. ("Hg): / / Duct Width ("): Duct Length ("): Probe & Pitot ID: ft TP- Sample Point Time Clock Run (min) DGM Volume (ft3) AP f'H20) AH f'HzO) Source 3 AALSi j2_ App / 6O Jl 3L jL&A. iSJL 3 A vot,67 AT1 U JL0. X A 723AA > 1 Y Lm // 3 M- SAAll .30 JAL 7Lt X 'S' 026.Y7 22L /ALP API t /f 22.0A k 3A / ?/ A2A JL JA 2M AT /5X /Y7 ALL ZlLJA 30 /{*> 7YY to 3,7 713/S * 3? M3/L /YJ 4L 30 21s, y$. 32 A17_ A7 J3l 23- 7322 f RY LIT AS' /,3r mr Ag2 AL 732210 AO 7 723-JA 3y a> -4 /4/ T- 39 f/TYJL 30 AM 723 < LlX *J- 2d- TYOTS MT 1ST X yT A A AT S 7/637 22. LOT ZA & SL 728/& AT L/C AT 7 3/ AT IT t99 IT Z?/A 2 22 ./to /<# 7 Al 7$ST< M- A4>a ALL (b 63 23AM 33L /J7 Aas JA AA /Sms AT L to ISA Ml ZSM32. JL2- AL /<?- 7o3 2T 7S2AiT Nozzle D2 (") 0: Nozzle D3(")0: n Average Nozzle D (" Probe 248+25 Temperature (F)' Filter 24825 Impinger Exit S68 DGM Inlet DGM Outlet Pump Vac. ("Hg) a-i PL 7/ 3 s3L TA A3srs sy SSS TSL A3 3.8. sS- Ok,2 AS OiTP/ />/ S3 <47 sA A- SZ- S/>- ST 27 TT S7 S7 S2A *7-t r 7Y yAL 7A ZT 2T 7a 13723 AL PPL A _2a TO S- pa A ZL A TO nA 2A yt SA IT TP Z8- T..B? T& 70 TA T ZT 7: TO 2.0. ZA 24 70 72 ZD 71 73 72 TT- JeiL jSL SL 7 SL 7 T- 7 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00456 AECOM Client/Plant: /T* > Location: Impinger# 1 2 3 4 Impinger Contents Dl H20 Dl H20 Empty Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 13A/B Project#: Condition: Date: QXXMj-U- Run#: / Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD 1 100 GS 4 9 8.3 _&gy. 3...... - MOD ~ MOD <7&c/, ( Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dl H20 Rinse) COMMENTS: Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00457 COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00458 AxCOM Client/Plant: fc.3 &(* Location: C&kln&f #(& Impinger# 1 2 3 4 Impinger Contents Dl HzO Dl HzO Empty Silica Gel FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 13A/B Project #: MM DZlA^. lo Condition: Date: i-2fc-/G Run#: 2 Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD &31.0 ?ol. 2 100 GS izzr ... fvSo . -- MOD (*54/ -- MOD 9/6. t/ Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (PI H?Q Rinse) COMMENTS: \ 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00459 A=COM FIELD SAMPLING DATA SHEET Cllent/Plant: /& f Project#: y0i{027/6 Date: ~4//2lLLsI gLC* L *6- Condition: kLrwuJj Run #: 2 PGM#: fi/~ i/C CF(Yd): AH@: /, K-Factor: l^SL PbarC'Hg): 30, [p Initial Leak * (<0.02 ft /min; >10"Hg) ft7min: Height w.r.t. Barometer (ft):/^ Vac. ("Hg): / Source Height (ft): Duct Diameter ("): Final Leak V (<0.02 ft /min; >max vacuum) Pitot Leak {>3"HzO) +P("H20): ff/min: .V...a.c. . (1 "Hg):-- / )..*--D..u..c..t W-idth ("): RH-fHaO): Duct Length ("): Nozzle D1 (") 0: / Q_ T' <S~ Probe & Pitot ID: -/ -a-? Nozzle D2 (") Q: Nozzle D3 (") Q: / Sample Point Time Clock Run (min) DGM Volume (ft3) AP ("HpO) AH ("HjO) Temperature (F) Source Probe 248+25 Rlter 24825 Impinger Exit S68 DGM Inlet DGM Outlet Pump Vac. ("Hg) Qt XL 3 c/ $ s 7 9 if fJL ft! 73 _ y.. _ (0 ? 7 q m (l /9oS ^3%.. J.0Z> ___B&l A? % 2 >i.3 r\3 A 3 79/ 7<r Sat D ,3/ 7, & 9$ /SI vsr S3 ,5cL 3 9 qoh.&<t * 39 A/7 //>& 9S* AcH 3 17 &6A.37 /5f Vf. ( 4 / 8 goS.AL /,/7 //b y/ t>9> 7 $10.07 *37 A 77 /<ra 7v S C-> 4 f 5 x?/ 739 9,07 /to 59 8/3,6/ ..,3r /<ao / - . v 0-7" \%xWr ' - - A 37 7 97 -- " `*\v &> 817,37 sss /, 3/ /zr \ .iB J-JlL- /S~5- 98> 07 99 ''"-tzbor- /?. _99 7> % H-4-- i.A B So 5 5 (4o? " Uu\ 6 -- -7 -- 6 ScP S 198/ _2A_ 777 xS (\2A0j7 -- fW< ,39 /..?/ /9S <4 XT 6 39 800327 ,37 A 27 /St, - 98 Qstv.Ad ,9D /3g /w <1 SB 4 D 5 58 Sx? - Qa-66'7 h 3/ J99 .73 m S3 8 9% * 9,3.9___ JSB - S3 49 Sjo S? */ >7 *9i -A9J-- f<o S/~. 49 S3 SY 83MiM -.39 -A/7 /St ,<? .31 fSi Sft 70 63 59 70 63 4?} 03S.SL - * _1 /? 5% yo 03 4 7 7 #37.A! , 7 A 21 127 fa ,3! /* o 6 fS9 > 9 RHQ.i 7 ,0 7 - 33 /tv S8 70 Si SB 70 S ? ?S 70 43 & 302 i 890 <0.30 ': 1 < - 4 ` ' COMMENTS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00460 AECOM Impinger# 1 2 3 4 Impinger Contents Dl H20 Dl HzO Empty Silica Gel FIELD SAMPLING DATA SHEET ____________ (RECOVERY)____________ Project #: Condition: Date; Run#: 3 METHOD 13A/B Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) Final (g) Gain (g) 100 MOD 1SS.3 .3 100 GS uq.5 l -- MOD 6>V/5 UV(,.L -- MOD 9XS. 9 Sum Recovery Container Weights Filter (no weights) PNR & Impinger Catch (Dl H20 Rinse) COMMENTS: 17cv1906 Sierra Club v. EPA 6/22 Production / ED 001523 00007569-00461 AECOM Plant Name Pc S Project Location (Source) p f fa Meter ID & Cal Factors $>* Sorbent Trap IDs i) ^)/7J7l 2) 3 Date J.-/4-// Condition /{/d / Run / perator - Bar, Press, (In. H20) Elevation (relative to Barometer) (ft) \OD / Page / of / Initial Leak 1) Rate 2) 3 @ J23 "Hg <f> @ "Hg Final Leak 1) O @ Z\ "Hg Rate 2) O @18 "Hg Third Bed !) PrOO# Sl/cSZ Spike Level 2) <S> ^ Trap Clock Time Volume (L, dry) Flow Rate (Lpm) Stack (F) Sorbent 1) 2) //30 t) ,7r 0 /SZ 3.97 1) 2) nis' 1) 2) //Vo 3.6$ j,r? 7Jf 7 JO *7$r 7<C fyS .7T /JA /tA 3/Q 1) 2) //.J //v<r if.So .VS' 'Sa 7/ ./<.ao...... .7S' 2) ?(S0 /$jVi ,7S <2vf 1) /9.V# c ?P 2) //ss / So *7$ SSI \ 1) .7$ 2) /JLO O 3,$3 t 7$ 'Sa aso 1) $%/9 . 7r 2) At.VV *7$T 'sz a 7$ 1) 2) /Zio *7$r .7S' //Z ai 79 1) 27,90 .per 2) I3i<? K5./V ISA. 36 0 1) 39A V '?r 2) 34, AI /SrZ 1) VIJA..... 42 AT 2) 91VI .7^ 'SS 1) 96* hi i .?r 2) /S/SO / X) . 75~ /Si 2) P-67 -7o 1) Temperature (F) Chiller Heat-Traced Line 33. Meter 9/ $ 3a S" 3 i ja 3a U 77 SIS 7 vsr 7S' 76 7<r .96 3/ 3a 3 l 31 H 3! 3 t 1/ as 7 as/ SSV asg asv JSV -57 57 > 77 76 7^ 76 7/} 7*7 9# 77? 98 9% 7f 70 v% 9 Vacuum (in, Hg) a 3 3 oL Z 3 Jl 3 3 P 7 D 3 3! 3 3 3? 3 0 3 2) Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production SOS-35: Mercury by Sorbent Trap - Method 308 ED 001523 00007569-00462 AsCOM Plant Name Project Number (nCH&12M ^C. 10 Location (Source) eXt^jX \o Meter ID & Cal Factors u *2.\\ Sorbent Trap IDs 2) &L2&1&1D Date 2-R-IU Condition Ck.uflA Run -tSfL- Operator C|ju_ Bar, Press, (in. l ^ Elevation (relative to Barometer) (ft) it)0 Page Initial Leak Rate Final Leak Rate Third Bed Spike Level / of / 1) O @ %c> "Hg 2) P @ ZS^"Hg 1) 0 @ IL "Hg 2) @ H "Hg 1) ZZ0<Kjk . 2) ^ ' Trap Clock Time Volume (L, dry) Flow Rate (Lpm) Stack (F) Sorbent Temperature (F) Chiller . Heat-Traced Line Meter Vacuum (In, Hg) 1) 2) o- 02F tw> 23^- Zc i 2. 1) 12J5S 2) H,HU TtC. #T5f IU> 2 to 3-z, zo HZ @K> t z 1) 2) g\ t/L, tTD 2 AT- 3l ZS5" l z 1) v 1o l \-bt>h 2) vzziZrv \{p 3 ^ 3A 20 6Z> 1) 2) rs- ^ l/UC? 3^o 3^ W < 1 z 1) 2) Xb\C \^u (i. Zi 7< *c7-~KxjZ xr' 31 6X> 2-^ i z 1) 2) LJ>20 2A * Dfy AS" i${. TMo <31 y?*CX 6T> S3 1 Z- 1) Zt.HZ '!37S' 2) Z^>Ho UO "2gC 3z ....et> ZST c? / ' z 1) 3>Z. o-o 2) V3k) "3Z. oi M 1 -O i 31 *1 1) .*>"> H"? 2) 35Vli3> TS 1 to1? 33 ZCT <?o 6Z t 2 1) fS.- 6^ 2) "Z^.vh 2To 2t2- &l ....(5Z 1 z. 1) 2) tOjC HZ.^-S /5^ . .C..UTsOT.... W 61 1 z. 1) 2) 13SZ) Hu.ZZI .Z5 ]u^) 1 i 32- l> fZ 2 1) 2) 1) 2) Comments: 17cv1906 Sierra Club v. EPA - 6/22 Production SDS-35: Mercury by Sorbent Trap - Method SOB ED 001523 00007569-00463 AECOM Plant Name $ Date /-!<?-IU- Page 1 of f Project Number 7UOi-(o2.Zc{<Xs >1Q Location (Source) C3i (<5<ks>c ~Yc L=> Meter ID & Cal Factors /YS>23 i) oiJj^io sp&i Sorbent Trap IDs 2) 0LZ3S~41S Condition A3>wl Run Operator LA/ LBar. Press, (in. HzO) SOS \ Elevation (relative to Barometer) (ft) \>C> Initial Leak Rate Final Leak Rate Third Bed Spike Level 1) 0 @ ZZ "Hg 2) 0 @ '7^ "Hg DO /& "Hg 2) O @ / "Hg 2) Trap Clock Time Volume (L, dry) Flow Rate (Lpm) Stack (F) Sorbent 1) &#> 2) iHoo 0.90f> .... 1 .. 1) 2) 4.u<T HcS ......^ 2^ 247- 1) g.?<r ,7S' 2) ... z5 >63 JL7ZI 1) /p,8& * ?r... 2) / 9/5 ..l, ?J .., 7f 0 7*9 1) ...75 2) /c/& /6* 76 . ?f J65 ^3/ 1) qo*$7 2) /e/jf SO. 3 S' .?f /63 <0 0Y 1) M.Vf 2) >93 d <$9,47 ,7?.... , 75 / 60 A9o 1) M.SD .._ 2) rl%30 *75 96 5 A 1) y/ 2) /9/p 3a. vs <7T /5i A7</ 1) lb,a? /9 if 2) 16.6* . *75 vi 1) <10.56 2) >9 So `Jo. SI *7< 96/ ,75..:.. a 7 <9 1) MSf / ys 2) w/?.? ,75 1) ,?r 2) IS OO 9%. of 9 - 75 / 6 o <$ o /60 A <7f 1) Temperature (F) Chiller Heat-Traced Line 32 2ry Meter 50 S"z_ j/ 3 l ?l 3/ 3/ 3 f 3( i./ 3} 3) 3 / ?S 53 Asr .57 5"? 57 05 r* <7 As? 53 </ <557/ S3 <7 ASA .......53 ASS A5? AS$ </ .Si - 5A 59 SJ .......sv 5A AS7 5i cPS'A SOTV 50d ,XfL .5 i Vacuum (in. Hg) V .. ? * ... 3 / "2? / / 6? / 7? O / J> / 7 *2 / 4 / A / a 2) 1) 2) Comments: \ / 17cv1906 Sierra Club v. EPA - 6/22 Production - SOS-35: Mercury by Sorbent Trap - Method 308 ED 001523 00007569-00464 A-COM FIELD SAMPLING DATA SHEET Flow and Moisture EPA Methods 2 & 4 PAGE / OF / Client/Plant: PCS Project#: 6o^<?224Sr'. |0 Date: .-/ 9 '--/ Operators): Zj L /> fT Location: (' cj & Condition: Moisture Run #: / Duration (min): DGM#: /j/- 3*3 PbarfHg): CF (Yd): 0,9993 aH- Height w.r.t. Barometer (ft): Pstatlc C Cp: 0.84 Initial Leak V (<0.02 ft3/min; >10"Hg) ft3/min: Vac. ("Hg): Source Height (ft): Iqq Duct Diameter ("): Final Leak V (<0.02 ft3/min; >run maximum) ft3/min: Vac. ("Hg): Duct Width ("): Duct Length ("): Pitot Leak V (>3"H20) +P ("H20): P C'HaO); Pitot Tube iP#:fp- ft - ^ Fyrite/Orsat O2 (%/time) % Fyrite/Orsat CO2 (%/time) % Moisture Determination Time DGM Volume (ft3). AH CHsO) DGM Inlet T CF) ( ( DGM Outlet T CF) ) ) Traverse Point ftr-h %( ) %(:) %( ) %(: ) Flow Run #; J Start End Ro..w...R..u.n#;... ..-.O..... .. Flow Run #: .*? Start End Start End 4? 4 AP fH20$ /X-J2S \t CL Source T AP CF) fHsO) a:5> TTov Source T AP Source T CD fHsO) CF) Cyclonic Angle () /hi ,y/..1 /?? IH \'3 ^// r? `fa /tfO 3 \/ 15ft \Ho ,30 (3% V... if (9L ,a|o M> ,3* I3t / m %> W1 ,</o HZ 6 /$<? .'31- mt ,3t l<fS t? JZSL 1 * >93 H'L \ `-it'"" 'iVf / __5____ >?<? /is iq-1 /o if. V 0 / 1 3 !S /A2 4... /$/ 331 */ Kf .93 /f M tW ,3r Hi t$fe. m m ISS' ,34 ,31 iro ,Z<n ID _JtL ,S1 /S3 HI i^/ 9 /&.... HD /sr rtt ISV S /iV H4 1ST f> /33 HC. ? ,N<t fV LSI, % /isr tr^ Ho f iV to fU ,C5 ICW 1^7 Ji Jl30l~ /30 icy id. HZ (5X 1W" Comments: <-lo^S W( \Xg^ ^ ^k.U 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00465 AECOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 EPA Method 5/202 PAGE \ OF t Client/Piant Location: (ScVtWTH* Project#: Q, dH.OUMZ 70 Condition: Date: \~T4~ \te Run #: Operator(s): Duration (min): XX Console#: f\ CF (Yd): 0,^43 AH@: Cp: 0.84 K-Factor: 3 MS Pbar("Hg): gQj( Height w.r.t. Barometer (ft): /o-t. Pstatic ("H2O): .14 Initial Leak V (<0.02 ft /min; >10"Hg) ft3/min: Vac. {"Hg): \"L Source Height (ft): \gflf Duct Diameter ("): Xz. Final Leak V (<0.02 ft /min; >run maximum) ff/mimg, QQg Vac. f`Hg): q Duct Width ("): Duct Length ("): Pitot Leak V (>3"H20) Initial +P: Fyrite/Orsat 02 (%/time) % ( Final +P; a/ Fyrite/Orsat C02 (%/time) % ( Nozzle D1 (") 0: Nozzle D2 (") : 2 45 23S Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat C02 (%/time) % { Fyrite/Orsat C02 (%/time) % ( Nozzle D3 (") Q: - Z46 Average Nozzle D f): Sample Point Time Clock Run (min) DGM Volume (ft3) AP C`H20) AH rH2o) Source Probe 248 25 Temperature (F) Filter 248 25 Impinge rExIt 68 CPM Filter 65 85 DGM Inlet DGM Outlet Pump Vac. ("Hg) M HSft z 5 *4 G* 1 - W`T- 4 2 i fail to It H22> it IHlj, STo? ..iMi. U43Z 5 4 > `g. s \M<i> 10 W iX UaS 0 ,dS l.t <C-/ 2g ZZ 44 ^0 H4 Cb 3 &5Z.X Zl% S3 <g4 48 S"?!. X. t 8m. \ n\ 2<CL Z526 35 ter 4% z. <? t%s, 3 tfif -1 \43 7% 3 73Z 44 (oTi 4B 33 t. it ^SXf> *Z2T J^X ?*n ZSZ H4 4h <54 X 15 Vs8,T '2ir i5r zm XCO H'Z. &r S'3 sr S \t ;.3i M l1 7^1 ZT_ H'K L>i* ^'X l\ S?b?.T .34 N3 2SZ 23^f 3S (44 Sx nC </ 24 * 3S... JLiX- isr fc!o 14Z .. 4 Z~k 1 | So 5/6 257) *4t> -i^Z_ tSS zm 25-t Sx 4 Sr 33 33/! 1 *4 \/3 _13> 1 '2!Sb *f? Sz 3c Xpr j2"C (3u#at 3G *Sl.7t.X Ad__ 23^1 z.'Ci S7 &4..." "5/ 4<r <f 3 3)''' \ .x. H3 STHS.O 4, , Let <??*?, i ,S3 3 .30 i 14 ?& \ & 24 S A^o__ \3*T Z3<" 51 * srSw-/ W3 4 60 M.o , 3S~ -32e 3S <iO LX Ul LX Kj 153 1ST- 257 2.53 f3 ] Lo wT" *Z<r ?\4 LA. 2/3 Zg? ,2?53 DM7* ZCb eci 750 &itr 53 *32- 66 42- 6 rH3 4`3 4 L hT HI HZ S3. 'U &(a (74ef-, 4Z_ <44 H SqJ J4 *S2- S "Sr ^14- 2/ 4X. ' N'T 4 ZLl rx 4{ 4 H'2- f 6 4 No 4 S i 46 3 41 CfcZf- 3 COMMENTS feUT itAfi 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00466 AECOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant: fC5 Location: C^j (0 Project#: Condition: . VO jOaffuvM Date: i-Zi-iy Run#: | Impinger # Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 0 VCON 0 KO Hts.r 0 MGS 51-11. ? 100 MGS ISZ.y 350 MGS tW-o Final (g) Gain (g) IVt*. / <o4/. <> 7/2. /? Sum Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: CPM Filter Temp Rotameter Reading Stop: Cl: Filter Recovery Container Weights PNR - Acetone Filter CPM Fitter impinger & Water Rinse Acetone and Hexane Rinses COMMENTS; ID#: IVI2X ID#: TareWt. (g) 0.3b?2l Tare Wt. (g) ID#: 01 lb' lot TareWt (g) Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00467 AECOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 EPA Method 5/202 PAGE l OF I Client/Plant Location: Project#: Condition: /K^sjua^\ Date: l -- 2i? ik. Run #: Operator(s): CXa-~A-^> Duration (min): Console#: CF(Yd)^ AHs .m Cp: 0.84 K-Factor: 3j& PbarCHg): \3<M Height w.r.t. Barometer (ft): /00 Pstatic C'HzO): -% z4 Initial Leak V (<0.02 ft3/min; >10"Hg) ft /min: Vac. ("Hg): & Source Height (ft): ( 6 Duct Diameter ("): ~~fp , Final Leak V (<0.02 ft3/min; >run maximum) ft3/min: 0 Vac. ("Hg): % Duct Width ("): Duct Length ("): Pitot Leak V (>3''H20) Initial +P: Final +P: -P: Nozzle D1 (") 0: q # 21 X Fyrite/Orsat 02 (%/tlme) % ( Fyrite/Orsat COz (%/time) % ( Fyrite/Orsat 02 (%/time) % ( Fyrite/Orsat C02 (%/time) % ( Fyrite/Orsat 02 (%/tlme) % ( Fyrite/Orsat C02 (%/time) % ( ) Average Nozzle D ("): q. Time SPamoinptle Clock (Rmuinn) VDolGumMe ("HAP20) ("AHH20) Source P24r2o85be Temperature F) 2F42il8t5er ImrEpixnigte 68 FilCte8Pr5M65 DinGleMt ODuGtlMet P(V*uHamcg.p) St \ XH,> 7TTJL3l_ ISX 7C3 oC 47 V 7 s 3M M 143 7T<0' 4 3 (b WVv^t 4 -S7 .#3r v1M,21 - i ^2? im 2CT> 1 ir<r t<y Zfl jT3 kt) P z/7- p K \7 V3 7m. ZCZ) \C __ ..yr Ux ici- 2>D 0i V \*z 9 ?j 3^ 1*3 ^-<1 wH 4t>s 7s ic3 fc> 4 9H t .33 '.t.i. 2S Ht- Q> l*> S?- < T/fl.T- .2^ vf 2sn>- 7T? ?D 43 14 ti 'Zfo ,, nil ,4 u \si ZA^- 94 J& it- <?rz >4 S\ \ -ft Z^l e<M *-iZ- 34 K SW 3** IV 1 >** *? M kd sgp( 25Z? F C*o 6S: 43 4/ l 34 It i *r & T 4 foo fa t**i1 ^> C'}Ls (-.b --- <^t D s?19.3 4Z.v.^ O TO. > cystic* ASM. 5 to ntc? *4 1 `24- \3> ?sQ~ 2S4 (fk-' tf^K ZSDr Zrs 0>*r f$t \.3 l Ml- k&r 2<b O -7 4|q ?S7" LQ- t-P? o 21^ fit 33J* j,r2o.. \4^r -243 Zsi 1A m^>\ 14*4 231 zcn .23 I I/j7- .7k Y&fi/) I 2&.r; 2n & if* mu* T jg.r /> (/> fy-h or "42 4 4l H 4 41 4 44 -4 44 4 tr- 5 3 q-o .3 4f 3 *^0 43 3 COMMENTS CkfC* \ 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00468 AECOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Client/Plant: PCS Location: #! jJU Project#: Condition: Date: Run#: 2 Impinger # Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 0 VCON 0 KO 602.1 0 MGS 5W.j 100 MGS *}0G,.o 350 MGS ?31. z Final (g) L^/.f ^io. 5 ?5b. i Sum Gain (g) Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: CPM Filter Temp Rotameter Reading Stop: Cl: Filter Recovery Container Weights PNR - Acetone Filter CPM Filter Impinger & Water Rinse Acetone and Hexane Rinses ID#: W/ZT- ID#: Tare Wt, (g) 0.21313 Tare Wt. (g) ID#: Q}J(o-fOi TareWt, (g) U/l\ Tare(g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00469 AECOM FIELD SAMPLING DATA SHEET Particulate Matter M5/202 EPA Method 5/202 PAGE t OF \ 'MM ENTS / 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00470 AECOM FIELD SAMPLING DATA SHEET (RECOVERY) METHOD 5/202 Project #: Condition: , Ko Date: i Run #: 3 Impinger # Condenser 1 2 3 4 Impinger Contents MT MT MT Water Silica Gel Method 4 Moisture Determination Approximate Volume (ml) Configuration Initial (g) 0 VCON 0 KO LI%1.2 0 MGS 100 MGS (e/O.9 350 MGS Final (g) Gain (g) 15^.3 (*25,2 g-9/r.S Sum Purge Train with UHP nitrogen at 14 liters per minute for one hour prior to sample recovery Purge Time Start: CPM Filter Temp Rotameter Reading -- -- Stop: Cl: Filter ID#: W/Z(* ID#: ID#: 0//(>-/01 Tare Wt. (g) Tare Wt. (g) TareWt. (g) 0.3 A//a Recovery Container Weights PNR - Acetone Filter CPM Filter Impinger & Water Rinse Acetone and Hexane Rinses COMMENTS: Tare (g) Final (g) Gain (g) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00471 AZCOM Barometric Pressure (BP) Summary for PCSCalciner HFTesting (2016) Calciner Date Test Time BP (in. Hg) 1 2/10/2016 11:10-12:26 29.95 2/10/2016 13:05-14:20 29.89 2/10/2016 14:40-15:56 29.87 2 2/3/2016 14:10-15:26 30.04 2/12/2016 10:10-11:25 30.26 2/12/2016 13:20-14:41 30.09 3 2/13/2016 9:40-10:57 30.26 2/13/2016 12:20-13:35 30.28 2/13/2016 14:31-15:46 30.27 4 2/1/2016 12:50-14:05 29.95 2/1/2016 14:29-15:54 29.92 2/1/2016 17:25-18:39 29.93 5 1/27/2016 11:38-13:20 30.12 1/27/2016 13:40-15:04 30.09 1/27/2016 16:20-17:35 30.12 6 1/26/2016 13:55-15:28 30.18 1/26/2016 16:50-17:25 30.16 1/26/2016 19:05-20:21 30.17 Note: BP obtained from NWS station located in New Bern, NC(KB/VN). Elevation of KB/VN is approximately 10 ft. AEL Height of Calciner Ports (ft) = 100 BP Corrected for PCSCalciner Elevation (in. Hg) 29.85 29.79 29.77 29.94 30.16 29.99 30.16 30.18 30.17 29.85 29.82 29.83 30.02 29.99 30.02 30.08 30.06 30.07 PCS BP for Fluoride Runs.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Bar Pressure ED 001523 00007569-00472 AZCOM Barometric Pressure (BP) Summary for PCSCalciner PM Testing (2016) Calciner Date Test Time BP (in. Hg)` 2/1/2016 13:20-14:34 29.93 9 2/1/2016 16:25-17:40 29.92 2/2/2016 10:30-11:48 30.27 2/2/2016 13:37-14:52 30.22 2/3/2016 10:02-11:19 30.11 4 2/3/2016 12:30-14:19 30.08 2/9/2016 9:37-10:59 29.69 C 1/26/2016 14:45-16:04 30.16 1/26/2016 16:50-19:10 30.17 1/26/2016 20:00-21:14 30.17 1/27/2016 12:58-16:19 30.09 6 1/27/2016 17:40-19:53 30.13 1/28/2016 9:55-11:11 29.99 `Note: BP obtained from NWS station located in New Bern, NC(KB/VN). Elevation of KB/VN is approximately 19 ft. AEL Height of Calciner Ports (ft) = 100 BP Corrected for PCSCalciner Elevation (in. Hg) 29.83 29.82 30.17 30.12 30.01 29.98 29.59 30.06 30.07 30.07 29.99 30.03 29.89 PCS BP for PM Runs.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Bar Pressure ED 001523 00007569-00473 AZCOM Barometric Pressure (BP) Summary for PCSCalciner Hg Testing (2016) Calciner Date Test Time BP (in. Hg) 1 2 (Re-test) 3 4 5 6 2/11/2016 2/13/2016 2/12/2016 2/10/2016 2/8/2016 2/19/2016 10:25-11:25 12:00-13:00 13:35-14:35 10:55-11:55 12:40-13:40 14:30-15:30 16:10-17:10 17:45-18:45 19:05-20:05 12:25-13:25 13:45-14:45 15:05-16:05 14:15-15:15 15:30-16:30 16:41-17:41 11:30-12:30 12:50-13:50 14:00-15:00 30.23 30.21 30.16 30.27 30.27 30.27 30.05 30.03 30.03 29.89 29.88 29.87 29.71 29.75 29.79 30.59 30.54 30.51 Note: BP obtained from NWS station located in New Bern, NC(KEWN). Elevation of KEWN is approximately 19 ft. ASL Height of Calciner Ports (ft) = 100 BP Corrected for PCSCalciner Elevation (in. Hg) 30.13 30.11 30.06 30.17 30.17 30.17 29.95 29.93 29.93 29.79 29.78 29.77 29.61 29.65 29.69 30.49 30.44 30.41 PCS BP for Hg Runs_v2.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production BP during Hg ED 001523 00007569-00474 AICOM Measured PCSCalciner Q? and CQ2 Values (2016) Calciner Date 02 002 1 2/12/2016 15.05 6.27 2 1/30/2016 14.79 6.24 2 2/13/2016 13.99 7.18 3 2/12/2016 15.08 5.73 4 2/11/2016 15.11 5.99 5 2/8/2016 13.53 7.66 6 2/19/2016 13.50 7.14 Note: 02/002 Measured during Hg test runs. Minimum: 13.50 5.73 Maximum: 15.11 7.66 Standard Deviation: 0.74 0.72 Average: 14.44 6.60 Updated PCS Hg Results 2-22-16v2.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production 02_CQ2 Levels ED 001523 00007569-00475 APPENDIX B PROCESS OPERATING DATA 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00476 APPENDIX B-l PARTICULATES 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00477 PCS Calciners Stack Testing Matrix and Associated Process Data - 2016 Test Program Date Start Finish Dp (" H20) Flow (GPM) Feed Rate (TPH- Target Feed Rate wet) (TPH-wet) Mercury 2/11/2016 10:25 11:25 20.1 250.2 Caiciner #1 2/11/2016 2/11/2016 12:00 13:35 13:00 14:25 19.9 20.0 250.0 248.6 2/10/2016 2/10/2016 2/10/2016 11:10 13:05 14:40 12:26 9.1' 14:18 7.5' 15:57 5^ PM lc 2/1/2016 13:20 14:34 10.0 284.8 70.1 66.4 2 2/1/2016 16:25 17:40 6.7 286.8 70.1 3 2/2/2016 10:30 11:48 7.8 292.8 70.1 66.4 66.4 4 2/2/2016 14:52 10.0 277.9 69.7 66.4 Mercury Caiciner #2 Mercury 1 1/30/2016 11:00 12:00 7.9 2 1/30/2016 12:20 13:20 8.2 3 1/30/2016 14:35 15:35 7.6 4 2/13/2016 10:55 11:55 9.1 5 2/13/2016 12:40 13:40 9.5 6 2/13/2016 14:30 15:30 7.9 281.4 277.4 272.7 284.8 278.0 282.9 70.0 70.0 70.0 67.3 67.3 67.3 65.5 65.5 65.5 66.4 66.4 66.4 Fluoride _ 2/3/2016 14:10 ______ 9.0 284.5 2 2/12/2016 10:10 11:25 8.3 286.7 3 2/12/2016 13:20 14:41 8.4 273.6 Mercury 1 2/11/2016 16:10 17:10 10.4 253.4 2 2/11/2016 17:45 18:45 10.0 253.4 3 2/11/2016 19:05 20:05 9.5 253.3 Caiciner #3 Fluoride 1 2/13/2016 9:40 10:59 4.5 11 263.2 2 2/13/2016 12:20 13:35 3.5 11 262.8 3 2/13/2016 14:31 15:46 3.4d 264.7 PM 1 2/3/2016 10:02 11:19 14.1 316.6 2 2/3/2016 12:30 14:19 14.1 317.3 3 2/9/2016 9:37 10:59 11.1 269.8 69.9 65.8 65.8 70.0 70.0 70.0 67.4 67.4 67.4 63.6 63.6 67.4 66.4 66.4 66.4 66.5 66.5 66.5 66.5 66.5 66.5 61.4 61.4 67.4 Caiciner #4 Mercury 12.3 12.3 12.3 12.3 12.3 12.3 12.3 12.9 12.9 12.9 12.4 12.6 12.6 12.4 12.4 12.4 12.9 12.9 12.9 12.3 12.3 13.0 Feed Rate (TPH-dry) 61.5 61.5 61.5 61.1 61.4 61.4 61.4 58.7 58.7 58.7 _____ 57.5 57.5 61.3 61.3 61.3 58.7 58.7 58.7 55.8 55.8 58.6 Mercury Caiciner #5 2/1/2016 2/1/2016 2/1/2016 1/26/2016 1/26/2016 1/26/2016 2/8/2016 2/8/2016 2/8/2016 1/27/2016 1/27/2016 1/27/2016 1/27/2016 1/27/2016 1/28/2016 12:50 14:29 17:25 14:45 16:50 20:00 14:15 15:30 16:41 11:38 13:40 16:20 12:58 17:40 9:55 14:05 17:09 18:39 16:04 19:10 21:14 -0.5 11 13.411 1411 12.2 12.3 13.0 15:15 16:30 17:41 17.0 17.2 17.0 13:20 15:04 17:35 16:19 19:53 11:11 11.2 11.1 10.7 -Qt4 323.1 321.6 319.7 358.6 397.4 446.1 494.8 495.2 495.2 374.7 368.5 386.1 301.7 325.4 421.7 67.9 67.9 67.9 67.2 67.2 67.2 69.1 69.1 69.1 6'.._ 67.2 67.2 67.0 67.0 67.0 61.4 61.4 61.4 65.8 65.8 55.8 66.6 66.6 66.6 65.8 65.8 64.0 64.0 64.0 12.3 12.3 12.3 12.3 12.3 12.3 13.7 13.7 13.7 12.3 12.3 12.3 12.3 12.3 59.5 59.5 59.5 59.0 59.0 59.0 59.7 59.7 59.7 59.0 59.0 59.0 58.8 58.8 58.8 Caiciner #6 Mercury aDP may haved been cleared during/between tests due to increased Dp with constant flow. bDP and flow were averaged between 16:59 and 17:14. cRun #1 invalid due to a failed post run leak check. dThis data was used to set MACT operating ranges. PCS is in the process of arranging for improvements to monitoring equipment to address concerns about whether the existing monitors are recording accurate and reliable data on a consistent basis. If necessary, PCS wiii repeat total fluoride performance testing and set new operating ranges for pressure drop and flow to the Venturi scrubbers once changes to the monitoring equipment are complete. Stack Testing Summary Associated Process Data 2016 17cv1906 Sierra Club v. EPA - 6/22 Production 3-24-2016 ED 001523 00007569-00478 NUMBER PCS Phosphate CALCINER tons feed => hour 70.1 ) ( 100%-%H2Q ) 100 Tons dry feed hour ( 70.1 t feed) (100 hour DAILY FEED= ) = 61.5 tons dry feed 59.4 , tph 65-C hour PRODUCTION RATE j > DAILY 65-C PRODUCTION | 1.335 Loss on Ignition is calculated using assays. In the month of it was Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal) ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal________ or, at 1 ton dry feed 61.5 tons dry feed = hour 2472.6 lbs coal hour or, tons coal hour 02/26/16 10:58 AM 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00479 STACK TEST W<DRKSHEET<< CALCINER NUMBER DATE FEED RATE DURING TES7 PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00480 NUMBER PCS Phosphate CALCINER tons feed => hour 69.7 ) ( f00%-%H2Q 100 Tons dry feed hour ( 69.7 t feed) (100 - 61.1 tons dry feed hour daily i i:i:d= > 59.1 tph 65-C hour PRODUCTION RATE DAILY 65-C PRODUCTION 1.37 Loss on Ignition is enleulnted using assays. In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal) ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal________ or, at 1 ton dry feed 61.1 tons dry feed = hour 2458.4 lbs coal hour or, tons coal hour 02/26/16 11:05 AM 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00481 STACK TEST W<DRKSHEET<< CALCINER NUMBER DATE FEED RATE DURING TES7 PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00482 NUMBER PCS Phosphate CALCINER tons feed => hour 63.6 ) ( f00%-%H2Q 100 Tons dry feed hour ( 63.6 t feed) (100 - 55.8 tons dry feed hour daily i i:i:d= > 53.9 tph 65-C hour PRODUCTION RATE DAILY 65-C PRODUCTION 1.103 Loss on Ignition is enleulnted using assays. In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal) ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal________ or, at 1 ton dry feed 55.8 tons dry feed = hour 2243.3 lbs coal hour or, tons coal hour 02/26/16 3:41 PM 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00483 STACK TEST W<DRKSHEET<< CALCINER NUMBER DATE FEED RATE DURING TES7 PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00484 NUMBER PCS Phosphate CALCINER tons feed => hour 67.4 ) ( f00%-%H2Q 100 Tons dry feed hour ( 67.4 t feed) (100 - 58.6 tons dry feed hour daily i i:i:d= 56.7 tph 65-C hour PRODUCTION RATE | > | DAILY 65-C PRODUCTION= | 1.515 [ Loss on Ignition is ealeulnted using assays. In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal) ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal________ or, at 1 ton dry feed 58.6 tons dry feed = hour 2358.3 lbs coal hour or, tons coal hour 02/26/16 3:46 PM 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00485 STACK TEST W<DRKSHEET<< CALCINER NUMBER DATE FEED RATE DURING TES7 PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00486 NUMBER PCS Phosphate CALCINER (ons feed hour 67.22 ) ( 100%-%H2Q 100 Tons dry feed hour ( 67.22 t feed) (100 59.0 tons dry feed hour 57.2 tph 65-C hour daily m;i;d= I > PRODUC ION RATE DAILY 65-C PRODUCTION Loss on Ignition is calculaled using assays. In the month of it was % a Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 48.1 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0298 tons dry feed ) 46.67 lbs coal or, at 1 ton dry feed 59.0 tons dry feed = hour 2751.2 lbs coal hour or, 1.58 tons coal hour 02/23/16 9:34 AM 05_STK_01_26_2016_Particulate.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00487 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 05_STK_01_26_2016_Particulate.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00488 NUMBER PCS Phosphate CALCINER tons feed => hour 67 ) ( 100%-%H2Q 100 ) = Tons dry feed hour 67 t feed) (100 58.8 tons dry feed hour tph 65-C hour DAILY 1110= > ION RATE DAILY 65-C PRODUCTION Loss on Ignition is calculate! using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 48.1 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0298 tons dry feed ) 46.71 lbs coal______ or, at 1 ton dry feed 58.8 tons dry feed = hour 2744.5 lbs coal hour or, tons coal hour 02/24/16 8:36 AM 06_STK_01_27_2016_Particulate.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00489 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 06_STK_01_27_2016_Particulate.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00490 NUMBER PCS Phosphate CALCINER tons feed => ( hour 66.9 ) ( 100%-%H2Q 100 Tons dry feed hour ( 66.9 t feed) (100 58.7 tons dry feed hour 56.9 tph 65-C hour DAILY FFFD= I > PRODUCTION RATE DAILY 65-C PRODUCTION Loss on Ignition is calculated using assays. In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( ) 48.1 lbs coal ( ton calcine) ( 1 ton calcine) ( 1.0298 tons dry feed ) 46.71 lbs coal_______or, at 1 ton dry feed 58.7 tons dry feed = hour 2740.4 lbs coal hour or, tons coal hour 03/23/16 12:35 PM 06_STK_01 _28_2016_Particulate 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00491 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 06_STK_01 _28_2016_Particulate 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00492 APPENDIX B-2 FLUORIDE 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00493 NUMBER PCS Phosphate CALCINER tons feed => ( 69.98 ) ( 100%-%H2Q hour 100 ) = Tons dry feed hour ( 69.98 t feed) (100 61.4 tons dry feed hour tph 65-C hour daily m:i:d= > ION RATE DAILY 65-C PRODUCTION Loss on Ignition is ealeulalet using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal______ or, at 1 ton dry feed 61.4 tons dry feed = hour 2468.3 lbs coal hour or, tons coal hour 03/18/16 8:59 AM 01_STK_02_10_2016_Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00494 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 01_STK_02_10_2016_Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00495 NUMBER PCS Phosphate CALCINER (ons feed hour 69.87 ) ( 100%-%H2Q 100 Tons dry feed hour ( 69.87 t feed) (100 61.3 tons dry feed hour 59.2 tph 65-C hour daily i i;i;i)= > PRODUC ION RATE DAILY 65-C PRODUCTION Loss on Ignition is caleulalet using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal or, at 1 ton dry feed 61.3 tons dry feed = hour 2464.4 lbs coal hour or, 1.23 tons coal hour 03/18/16 8:04 AM 02_STK_02_3_2016_Fluoride Runl .xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00496 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 02_STK_02_3_2016_Fluoride Runl .xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00497 NUMBER PCS Phosphate CALCINER tons feed => ( hour 65.8 ) ( 100%-%H2Q 100 Tons dry feed hour ( 65.8 t feed) (100 57.5 tons dry feed hour 55.6 tph 65-C hour DAILY FFFD= I > PRODUCTION RATE DAILY 65-C PRODUCTION Loss on Ignition is calculated using assays. In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal for a Monthly value. ton calcine Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal) ( ton calcine) ( 1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal______ or, at 1 ton dry feed 57.5 tons dry feed = hour 2311.9 lbs coal hour or, tons coal hour 03/23/16 2:15 PM 02_STK_02_12_2016_Fluoride Run23 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00498 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 02_STK_02_12_2016_Fluoride Run23 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00499 NUMBER PCS Phosphate CALCINER (ons feed hour 67.39 ) ( 100%-%H2Q 100 Tons dry feed hour ( 67.39 t feed) (100 58.7 tons dry feed hour 56.7 tph 65-C hour daily i i;i;i)= > PRODUC ION RATE DAILY 65-C PRODUCTION Loss on Ignition is ealeulalet using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal or, at 1 ton dry feed 58.7 tons dry feed = hour 2360.7 lbs coal hour or, 1.18 tons coal hour 03/18/16 9:00 AM 03_STK_02_13_2016_Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00500 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 03_STK_02_13_2016_Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00501 NUMBER PCS Phosphate CALCINER ions feed hour 67.9 ) ( 100%-%H2Q 100 Tons dry feed hour ( 67.9 t feed) (100 59.5 tons dry feed hour 57.5 tph 65-C hour PRODUC ION RATE daily i i;i;i)= > DAILY 65-C PRODUCTION Loss on Ignition is caleulalet using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal or, at 1 ton dry feed 59.5 tons dry feed = hour 2395.0 lbs coal hour or, 1.20 tons coal hour 03/18/16 9:05 AM 04_STK_02_1_2016_Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00502 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 04_STK_02_1 _2016_Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00503 NUMBER PCS Phosphate CALCINER tons feed => hour 67.2 ) ( 100%-%H2Q 100 ) = Tons dry feed hour ( 67.2 t feed) (100 58.9 tons dry feed hour 57.2 tph 65-C hour PRODUC ION RATE daily m;ki)= > DAILY 65-C PRODUCTION Loss on Ignition is calculated using assays. In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 48.1 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0298 tons dry feed ) 46.71 lbs coal 1 ton dry feed or, at 58.9 tons dry feed hour 2752.7 lbs coal hour or, tons coal hour 03/18/16 9:14 AM 05 STK 01 27 2016 Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00504 STACK TEST W<DRKSHEET<< CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 05 STK 01 27 2016 Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00505 NUMBER PCS Phosphate CALCINER (ons feed hour 67.86 ) ( 100%-%H2Q 100 Tons dry feed hour ( 67.86 t feed) (100 59.5 tons dry feed hour 57.7 tph 65-C hour PRODUC ION RATE daily m;i;d= > DAILY 65-C PRODUCTION Loss on Ignition is calculalet using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 48.1 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0298 tons dry feed ) 46.71 lbs coal or, at 1 ton dry feed 59.5 tons dry feed = hour 2779.7 lbs coal hour or, 1.39 tons coal hour 03/18/16 9:24 AM 06_STK_01_26_2016_Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00506 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 06_STK_01_26_2016_Fluoride.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00507 APPENDIX B-3 MERCURY 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00508 NUMBER PCS Phosphate CALCINER tons feed hour 69.98 ) ( 100%-%H2Q 100 Tons dry feed hour ( 69.98 t feed) (100 61.3 tons dry feed hour tph 65-C hour ION RATE DAILY 1110= > DAILY 65-C PRODUCTION Loss on Iunilion is calculate! using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal______ or, at 1 ton dry feed 61.3 tons dry feed = hour 2465.5 lbs coal hour or, tons coal hour 03/21/16 8:08 AM 01_STK_02_11_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00509 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 01_STK_02_11_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00510 NUMBER PCS Phosphate CALCINER tons feed hour 70 ) ( 100%-%H2Q 100 Tons dry feed hour 70 t feed) (100 61.4 tons dry feed hour tph 65-C hour ION RATE DAILY IIIO= > DAILY 65-C PRODUCTION Loss on Iunilion is calculate! using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 54.7 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0298 tons dry feed ) 53.11 lbs coal______ or, at 1 ton dry feed 61.4 tons dry feed = hour 3260.3 lbs coal hour or, tons coal hour 03/24/16 8:28 AM 02_STK_01_30_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00511 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 02_STK_01_30_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00512 NUMBER PCS Phosphate CALCINER tons feed => ( hour 67.34 ) ( 100%-%H2Q 100 ) = Tons dry feed hour ( 67.34 t feed) (100 58.7 tons dry feed hour 56.7 tph 65-C hour PRODUC ION RATE DAILY IIII) > DAILY 65-C PRODUCTION Loss on Iunilion is calculate! using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal or, at 1 ton dry feed 58.7 tons dry feed = hour 2359.0 lbs coal hour or, 1.18 tons coal hour 03/21/16 8:37 AM 02_STK_02_13_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00513 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 02_STK_02_13_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00514 NUMBER PCS Phosphate CALCINER tons feed => hour 70 ) ( 100%-%H2Q 100 ) = Tons dry feed hour 70 t feed) (100 61.3 tons dry feed hour 59.3 tph 65-C hour PRODUC ION RATE DAILY III!) > DAILY 65-C PRODUCTION Loss on Iunilion is calculate! using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal or, at 1 ton dry feed 61.3 tons dry feed = hour 2466.2 lbs coal hour or, 1.23 tons coal hour 03/21/16 8:49 AM 03_STK_02_11_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00515 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 03_STK_02_11_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00516 NUMBER PCS Phosphate CALCINER tons feed hour 67.07 ) ( 100%-%H2Q 100 Tons dry feed hour ( 67.07 t feed) (100 58.8 tons dry feed hour tph 65-C hour ION RATE DAILY IIIO= > DAILY 65-C PRODUCTION Loss on Iunilion is calculate! using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal______ or, at 1 ton dry feed 58.8 tons dry feed = hour 2365.7 lbs coal hour or, tons coal hour 03/21/16 9:31 AM 04_STK_0.XLS 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00517 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 04_STK_0.XLS 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00518 NUMBER PCS Phosphate CALCINER tons feed hour 69.12 ) ( 100%-%H2Q 100 Tons dry feed hour ( 69.12 t feed) (100 59.7 tons dry feed hour tph 65-C hour ION RATE DAILY 1110= > DAILY 65-C PRODUCTION Loss on Iunilion is calculate! using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal______ or, at 1 ton dry feed 59.7 tons dry feed = hour 2399.1 lbs coal hour or, tons coal hour 03/21/16 9:40 AM 05_STK_02_8_2016_Mercury .xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00519 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 05_STK_02_8_2016_Mercury .xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00520 NUMBER PCS Phosphate CALCINER tons feed => hour 66.5 ) ( 100%-%H2Q 100 ) = Tons dry feed hour ( 66.5 t feed) (100 59.0 tons dry feed hour 57.0 tph 65-C hour PRODUC ION RATE DAILY IIII) > DAILY 65-C PRODUCTION Loss on Iunilion is calculate! using assays, In the month of it was % Coal usage is based on consumption per ton calcine produced, which is lbs coal ton calcine for a Monthly value. Calculate coal use during testwork based on Dry Feed: ( 41.6 lbs coal 1 ( ton calcine) (1 ton calcine) ( 1.0336 tons dry feed ) 40.22 lbs coal or, at 1 ton dry feed 59.0 tons dry feed = hour 2372.3 lbs coal hour or, l.l`> tons coal hour 03/21/16 9:58 AM 06_STK_02_19_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production STK-tst ED 001523 00007569-00521 STACK TEST WORKSHEET CALCINER NUMBER DATE FEED RATE DURING TEST PERCENT MOISTURE OF FEED FEED DURING ENTIRE DAY PREVIOUS MONTH YEAR PREVIOUS MONTH LOI PREVIOUS MONTH COAL #/T 06_STK_02_19_2016_Mercury.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production input ED 001523 00007569-00522 LIMIT MIN 36.78 96 3 0 0 LIMIT MAX 0 U:\ENVA\Air\RTR\ICR - Stack Test\2010 ICRAParametric Monitoring\[\VESPi6 M Data 020i2016.x!s]WESP2 Table 93 o| 96 96 0 200=TitleV,0==Ma(Wash=0, Run=200 off=0,SU/SD==100,ran=200 24.00 TimeStamp CAL2 VenturiE CAL2_Venturi_F wesp2_GVC_Sec1 wesp2_ModeStati wesp2_DevieeSta1 wesp2_IOStatus CAL2_ProcStatu: DataQuality 2/1/2016 12:44 2/1/2016 12:59 10.28 10.19 283.7120972 283.6917419 58.43 58.55 0 200 0 200 63 200 450 63 200 450 2/1/2016 13:14 2/1/2016 13:29 2/1/2016 13:44 2/1/2016 13:59 2/1/2016 14:14 2/1/2016 14:29 2/1/2016 14:44 11.04 10.11 9.90 9.39 11.15 9.44 8.86 284.7768555 285.0832214 284.6219177 284.9378967 284.0667114 284.5604248 285.817749 58.26 58.21 58.48 58.50 58.36 57.85 58.44 0 200 0 200 0 200 0 200 0 200 0 200 0 200 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 2/1/2016 14:59 10.14 284.7155151 58.14 0 200 63 200 450 2/1/2016 15:14 2/1/2016 15:29 2/1/2016 15:44 2/1/2016 15:59 2'1'2016 16:14 p 2/1/2016 16:29 | 2/1/201616:44 1 2/1/2016 16:59 2/1/2016 17:14 10.23 10.92 10.18 8.40 7.26 5.78 6.14 6.60 6.53 283.2062073 283.4639893 284.3764038 284.9002991 285.888916 287.165863 288.3653564 286.6656189 286.597229 58.20 58.40 58.39 58.41 57.58 58.03 57.82 57.75 58.08 0 200 0 200 0 200 0 200 0 200 0 200 0 200 0 200 0 200 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 63 200 4501 63 200 450| 63 200 450 63 200 450 2/1/2016 17:29 2/1/2016 17:44 2/1/2016 17:59 2/1/2016 18:14 2/1/2016 18:29 2/1/2016 18:44 2/1/2016 18:59 7.73 7.51 8.82 8.75 8.84 9.33 10.58 285.1633301 286.7986145 286.9550781 286.0020447 286.9703064 287.504303 288.9130554 58.30 57.56 58.09 58.36 58.06 57.19 57.31 0 200 0 200 0 200 0 200 0 200 0 200 0 200 63 200 4501 63 200 450| 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 Average Average Average dp Fiow volts 9.98 284.84 58.30 6.71 286.79 57.92 Stack Testing Detailed Data 17cv1906 Sierra Club v. EPA - 6/22 Production 02-01-2016 Cal 2 PM ED 001523 00007569-00523 LIMIT MIN 36.78 96 3 0 0 LIMIT MAX 0 93 96 96 R:\envirVMACT_DATA\\\TSP\[\VESP16_M_Data_02022016.x!s]\VESP2_Tab!e 0 0 o0n 1 o ' 200==TitleV,0=Mac Wash==0, Rim=200 off=0,SU/SD= 24.00 TimeStamp CAL2 Venturi DCAL2 Venturi F wesp2 GVC Sec^wesp2 ModeStati wesp2 DevieeStat >vesp2_IOStatus CAL2_ProcStatu`DataQuality 2/2/2016 9:59 7.43 294.7731934 58.41 0 200 63 200 450 2/2/2016 10:14 7.27 293.8833618 58.61 0 200 63 200 450 2/2/2016 10:29 2/2/2016 10:44 2/2/2016 10:59 2/2/2016 11:14 2/2/2016 11:29 2/2/2016 11:44 7.56 7.56 7.34 8.67 7.79 7.88 291.9526062 292.0074158 292.2038269 291.4221802 293.4343872 295.9596252 58.51 58.36 58.67 58.53 5.36 0.03 0 200 0 200 0 200 0 200 0 0 0 0 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 2/2/2016 11:59 2/2/2016 12:14 2/2/2016 12:29 2/2/2016 12:44 2/2/2016 12:59 2/2/2016 13:14 2/2/2016 13:29 8.53 7.77 7.43 7.58 9.73 11.08 11.35 297.109314 295.9080811 297.2171326 295.3805237 294.6233826 290.1147156 289.5517273 46.67 57.00 58.17 58.46 58.45 58.40 58.55 0 0 0 200 0 200 0 200 0 200 0 200 0 200 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 2/2/2016 13:44 2/2/2016 13:59 2/2/2016 14:14 2/2/2016 14:29 2/2/2016 14:44 2/2/2016 14:59 11.12 11.07 10.76 8.84 8.87 9.15 288.1797791 272.3088684 272.5941162 278.9927063 275,5931702 279.4927979 58,45 58.38 58.53 58.46 58.56 58.40 0 200 0 200 0 200 0 200 0 200 0 200 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 2/2/2016 15:14 2/2/2016 15:29 2/2/2016 15:44 2/2/2016 15:59 2/2/2016 16:14 9.22 9.14 9.04 8.86 8.44 282.4565735 283.8435364 287.1291504 289.0369263 290.6186523 58.51 58.44 58.33 58.38 58.53 0 200 0 200 0 200 0 200 0 200 63 200 450 63 200 450 63 200 450 63 200 450 63 200 450 Average Average Average dp Fiow voits 7.80 292.83 39.91 9.97 277.86 58.46 Stack Testing Detailed Data 17cv1906 Sierra Club v. EPA - 6/22 Production 2-2-2016 Cal 2 PM ED 001523 00007569-00524 LIMIT MIN 38.56 96 5 0 0 LIMIT MAX 0 91 96 96 U:\ENVA\Air\RTR\ICR - Stack Test\2010 ICR\Parametric Monitoring\[\\TESPi6_M_Data_020320i6.x!s]\\TESP4_TabIe 0 0 200==TitleV,0=Mac Wash==0, Rim=200 off=0,SU/SD= o0 n 1 o ' 24.00 TimeStamp CAL4 Venturi DCAL4 Venturi F wesp4 GVC Sec^wesp4 ModeStati wesp4 DevieeStat >vesp4_IOStatus CAL4_ProcStatu`DataQuality 2/3/2016 9:29 14.29 316.7032776 56.84 0 200 16 200 450 2/3/2016 9:44 14.24 317.2104492 56.87 0 200 16 200 450 2/3/2016 9:59 2/3/2016 10:14 14.16 14.07 316.6018677 316.1919861 57.01 56.79 0 200 0 200 16 200 450 16 200 450 2/3/2016 10:29 2/3/2016 10:44 14.06 14.06 316.2354736 316.6473389 56.96 56.91 0 200 0 200 16 200 450 16 200 450 2/3/2016 10:59 2/3/2016 11:14 14.15 14.16 317.5357056 316.2554016 57.03 56.72 0 200 0 200 16 200 450 16 200 450 2/3/2016 11:29 2/3/2016 11:44 2/3/2016 11:59 2/3/2016 12:14 ' 2/3/201612:29 1 2/3/2016 12:44 2/3/2016 12:59 i 2/3/201613:14 2/3/2016 13:29 2/3/2016 13:44 2/3/2016 13:59 I 2/3/201614:14 2/3/2016 14:29 2/3/2016 14:44 2/3/2016 14:59 2/3/2016 15:14 14.20 13.99 14.15 14.32 14.17 14.16 14.12 13.93 14.20 14.06 14,26 14,09 13.90 13.91 13.89 13.82 316.4833984 314.0281677 317.006073 317.0864563 316.5034-9 316.3639526 316.0639648 313.5877686 319.4709167 316,8587036 320.6643982 318.9646301 318.2307739 317.2648926 318.0776062 317.7071228 56.70 56.28 56.40 56.83 56.18 0.03 0.03 54.64 57.53 56.67 57.34 55.81 56.55 56.35 56.41 56.61 0 200 0 200 0 200 0 200 0 0 0 0 0 0 0 0 0 0 0 200 0 200 0 200 0 20o" 0 200 0 200 0 200 16 200 450 16 200 450 16 200 450 16 200 450 16 200 450; 16 200 450; 16 200 450! 16 200 450| 16 200 450! 16 200 450; 16 200 450! 16 200 450! 16 200 450 16 200 450 16 200 450 16 200 450 2/3/2016 15:29 13.73 318.1021729 56.50 0 200 16 200 450 Average Average Average dp Fiow voits 14.11 316.58 56.90 14.12 317.31 42.28 Stack Testing Detailed Data 17cv1906 Sierra Club v. EPA - 6/22 Production 2-3-2016 Cal 4 PM ED 001523 00007569-00525 LIMIT MIN 38.56 96 0 0 0 LIMIT MAX 0 96 96 96 R:\envii^ACTJ}ATA\\VESP\[WESP16_M_Data_02092016.xls]WESP4_Table 0| 0 200=TitleV,0=MacWash= 0, Run=200 off=0,SU/SD== 100,rim=200 24.00 Time Stamp CAL4 Venturi D CAL4 Venturi Flwesp4 GVC Sec\wesp4 ModeStatu wesp4 DeviceStat wesp4 IOStatus CAL4_ProcStatus DataQuality 2/9/2016 8:59 11.00 284.1963806 56.49 0 200 16 200 450 2/9/2016 9:14 10.74 272.5091858 56.35 0 200 16 200 450 2/9/2016 9:29 11.13 283.6186523 56.43 0 200 16 200 450 2/9/2016 9:44 11.26 283.1287537 56.44 0 200 16 200 450 2/9/2016 9:59 11.33 280.9006653 56.02 0 200 16 200 450 2/9/2016 10:14 11.45 279.3551941 55.64 0 200 16 200 450 2/9/2016 10:29 11.50 278.6768494 55.49 0 200 16 200 450 2/9/2016 10:44 11.16 269.3170776 55.70 0 200 16 200 450 2/9/2016 10:59 9.93 227.6318207 55.82 0 200 16 200 450 2/9/2016 11:14 9.18 204.1715698 55.72 0 200 16 200 450 2/9/2016 11:29 9.98 221.5030365 55.87 0 200 16 200 450 2/9/2016 11:44 9.83 223.1832886 55.72 0 200 16 200 450 2/9/2016 11:59 9.72 230.0381927 55.86 0 200 16 200 450 2/9/2016 12:14 11.43 285.1840515 55.55 0 200 16 200 450 Average Average Average dp Flow volts 11.10 269.84 55.8 Stack Testing Detailed Data 17cv1906 Sierra Club v. EPA - 6/22 Production 2-9-2016 Cal 4 PM ED 001523 00007569-00526 LIMIT MIN 37.95 96 4 2 0 LIMIT MAX 0 92 94 96 R:\envir\MACT_DATA\WESP\fWESP16 _M_Data_01262016,xis]WESP5_Table l 200==TitleV,0=Mact Wash=0, Run==200 2 off=0,SU/SD= 100,run=200 24.00 TimeStamp CAL5 Venturi DI CAL5 Venturi_FL wesp5_GVC_SecV wesp5_ModeStatus wesp5_DeviceStatu wesp5_IOStatus CAL5 _ProcStatus DataQuality 1/26/2016 13:59 11.71 386.0675964 55.32 0 200 16 200 450 1/26/2016 14:14 12.73 361.6223145 53.44 0 200 16 200 450 1/26/2016 14:29 12.49 360.7043457 50.86 0 200 16 200 450 1/26/2016 14:44 12.55 359.6759338 50.28 0 200 16 200 450 1/26/2016 14:59 12.18 358.8410034 51.98 0 200 16 200 450 1/26/2016 15:14 12.13 358.6596985 49.05 0 200 16 200 450 1/26/2016 15:29 12.24 358.6361694 49.20 0 200 16 200 450 1/26/2016 15:44 12.03 357.4496765 49.20 0 200 16 200 450 1/26/2016 15:59 12.14 358.0595093 47.80 0 200 16 200 450 1/26/2016 16:14 12.13 357.4216919 47.86 0 200 16 200 450 1 262016 16:29 1/26/2016 16:44 12.22 ' 12.09 357.6298828 357.4915771 46.51 48.22 0 200 1 " " " "o 1 ' ' 11,1 "2OO 16 200 450 16 200 ~450| 1/26/2016 16:59 11.83 357.6703186 15.85 0 0 16 200 450 1/26/2016 17:14 11.67 357.7156677 0.05 0 0 16 200 450 1/26/2016 17:29 11.29 357.4052429 8.14 0 0 16 200 450 1/26/2016 17:44 12.47 401.0337219 38.82 0 0 16 200 450 1/26/2016 17:59 1/26/2016 18:14 1/26/2016 18:29 1/26/2016 18:44 13.02 12.56 12.66 12.79 381.710144 396.5162048 437.3048706 440.0617676 49.81 42.23 43.42 41.09 0 200 0 200 0 200 0 200 16 200 450 16 200 45! 16 200 45oi 16 200 450 1/26/2016 18:59 12.64 440.544342 42.04 0 200 16 200 450 1/26/2016 19:14 12.65 443.3803101 44.14 0 200 16 200 4501 1/26/2016 19:29 12.76 446.7970276 46.13 0 200 16 200 450 1/26/2016 19:44 12.92 446.3763123 48.32 0 200 16 200 450 1/26/2016 19:59 12.94 445.3218384 51.64 0 200 16 200 450 1/26/2016 20:14 12.98 445.0393677 54.56 0 200 16 200 450 1/26/2016 20:29 12.94 445.9121399 55.44 0 200 16 200 450 1/26/2016 20:44 13.04 446.3884277 56.14 0 200 16 200 450 1/26/2016 20:59 13.05 447.3651733 55.38 0 200 16 200 450 1/26/2016 21:14 12.94 446.6663513 56.37 0 200 16 200 450 1/26/2016 21:29 12.74 444.9483643 56.20 0 200 16 200 450 1/26/2016 21:44 12.61 444.5867615 56.11 0 200 16 200 450 1/26/2016 21:59 12.58 444.1151123 56.03 0 200 16 200 450 1/26/2016 22:14 12.88 445.8430176 56.34 0 200 16 200 450 1/26/2016 22:29 12.84 445.7922668 56.24 0 200 16 200 450 Average Average Average dp Flow volts 12.21 358.55 49.59 12.33 397.35 33.98 12.98 446.12 54.92 Stack Testing Detailed Data 17cv1906 Sierra Club v. EPA 6/22 Production 1-26-2016 Cal 5 PM ED 001523 00007569-00527 LIMIT MIN 41.62 96 7 6 LIMIT MAX 0 89 90 i 01272016.xls]WESP6 Table 0| 6 200=TitleV,0=Mact Wash=0, Run=200 off=0,SU/SD=100,run=200 24.00 Time Stamp CAL6 Venturi DP CAL6 Venturi FL wesp6 GVC SecVolt wesp6 ModeStatus wesp6 DeviceStatus wesp6 IOStatus CAL6 ProcStatus DataQuality 1/27/2016 12:14 0.04 360.3501282 48.85 0 200 16 200 1/27/2016 12:29 -0.07 359.2035522 50.24 0 200 16 200 1/27/2016 12:44 -0.03 359.5548401 48.44 0 200 16 200 1/27/2016 12:59 -0.22 358.4898682 50.51 0 200 16 200 1/27/2016 13:14 -0.17 355.4556885 50.56 0 200 16 200 1/27/2016 13:29 0.56 354.5387878 51.04 0 200 16 200 1/27/2016 13:44 0.10 353.9650269 51.16 0 200 16 200 1/27/2016 13:59 0.36 353.1211548 49.19 0 200 16 200 1/27/2016 14:14 0.44 313.1800842 47.49 0 200 16 200 1/27/2016 14:29 0.35 272.9432678 46.26 0 200 16 200 1/27/2016 14:44 0.26 270.4306641 48.94 0 200 16 200 1/27/2016 14:59 1/27/2016 15:14 0.59 -0.18 267.0173645 265.4393005 46.78 47.70 0 200 0 200 16 200 16 200 1/27/2016 15:29 -0.12 265.0967407 47.15 0 200 16 200 1/27/2016 15:44 -0.43 265.9236145 48.50 0 200 16 200 1/27/2016 15:59 -0.31 263.5124512 48.85 0 200 16 200 1/27/2016 16:14 -0.27 263.9772339 50.01 0 200 16 200 1/27/2016 16:29 -0.03 267.0525208 46.29 0 200 16 200 1/27/2016 16:44 -0.11 262.7538147 47.93 0 200 16 200 1/27/2016 16:59 0.12 260.6062927 47.92 0 200 16 200 1/27/2016 17:14 -0.03 260.3843689 47.64 0 200 16 200 1 27/2016 17:29 -0.12 260.2634277 48.04 0 200 16 200 1/27/2016 17:44 1/27/2016 17:59 0.40 J 0.46 260.388031 260.884613 45.SI 45.86 7' 200 0 200 '"IS"'""1 ' 200 16 200 1/27/2016 18:14 0.22 261.6434631 46.44 0 200 16 200 1/27/2016 18:29 -0.29 263.5778198 9.63 0 0 16 200 1/27/2016 18:44 -0.44 261.2591248 0.06 0 0 16 200 1/27/2016 18:59 -0.43 253.2556915 0.11 0 0 16 200 1/27/2016 19:14 -0.44 440.5529175 12.19 0 0 16 100 1/27/2016 19:29 -0.43 465.460022 28.23 0 200 16 100 1/27/2016 19:44 1/27/2016 19:59 -0.44 -0.44 461.1738892 455.7711792 31.71 33.98 0 200 0 200 16 100 16 100 1 27/2016 20:14 -6.44 459.3521118 44.01 0 200 16 200 1/27/2016 20:29 -0.41 457.4414368 38.28 0 200 16 100 1/27/2016 20:44 -0.41 456.6829834 45.68 0 200 16 100 1/27/2016 20:59 -0.43 455.8738098 42.69 0 200 16 200 1/27/2016 21:14 -0.44 456.3980408 42.26 0 200 16 200 0 96 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 ' 450! 450! 450! 450: 450! 450! 450: 450! 450 450: 450 450 450 450 450 Average Average Average dp Flow volts 0.07 301.65 48.87 -0.18 338.40 25.37 Stack Testing Detailed Data 17cv1906 Sierra Club v. EPA - 6/22 Production 1-27-2016 Cal 6 PM ED 001523 00007569-00528 LIMIT MIN 41.62 96 0 9 0 LIMIT MAX 1 0 96 87 96 R:'-envir-MACT DATA WESP[WESPI6 M Data 01282016.xkjWESP6 Table l 9 200=TitleV:0=Mact Wash=0, Run=200 off=0,SU/SD==100:ran=200 24.00 Time Stamp CAL6 Venturi DP CAL6 Venturi FL wesp6 GVC SecVoIt wesp6 ModeStatus wesp6 DeviceStatus wesp6 IOStatus CAL6 ProcStatus DataQuality 1/28/2016 9:29 -0.44 416.320343 48.12 0 200 16 200 450 1/28/2016 9:44 -0.44 420.8109436 45.62 0 200 16 200 450 1/28/2016 9:59 -0.44 416.6587219 50.35 0 200 16 200 450 1/28/2016 10:14 -0.44 417.0959167 46.17 0 200 16 200 450 1/28/2016 10:29 -0.44 421.115448 44.46 0 200 16 200 450 1/28/2016 10:44 -0.44 422.4533997 44.83 0 200 16 200 450 1/28/2016 10:59 -0.44 427.180542 44.32 0 200 16 200 450 1/28/2016 11:14 -0.44 425.6403809 43.36 0 200 16 200 450 1/28/2016 11:29 -0.44 367.6949158 37.82 0 200 16 200 450 1/28/2016 11:44 -0.44 386.3194885 41.80 0 200 16 100 450 1/28/2016 11:59 -0.44 387.680603 49.39 0 200 16 200 450 1/28/2016 12:14 -0.44 385.9073486 47.99 0 200 16 200 450 1/28/2016 12:29 -0.44 385.6487427 49.31 0 200 16 200 450 Average Average Average dp Flow volts -0.44 421.69 45.58 Stack Testing Detailed Data 17cv1906 Sierra Club v. EPA - 6/22 Production 1-28-2016 Cal 6 PM ED 001523 00007569-00529 LIMIT MIN 37.17 96 3 0 0 LIMIT MAX R:\envir\MACT_DATA\WESP\[WESP16_M _Data_02102016.xls]WESP l_Table 0 93 l 96 96 0 200=TitleV,0==Mac Wash==0, Run=200 off=0,SU/SD=100,run==200 24.00 Time Stamp CALI Venturi D CALI Venturi F1WESP1 GVC Se(WESPl ModeSta WESP1 DeviceStiWESPl IOStatus CALI ProcStatus DataQuality 2/10/2016 10:44 3.92 258.7526245 56.71 0 200 63 200 450 2/10/2016 10:59 5.62 258.0686035 56.05 0 200 63 200 450 2/10/2016 11:14 8.19 252.7017365 56.46 0 200 63 200 450 2/10/2016 11:29 8.69 253.7298889 56.82 0 200 63 200 450 2/10/2016 11:44 9.83 252.8040466 56.53 0 200 63 200 450 2/10/2016 11:59 9.78 251.0621643 55.04 0 200 63 200 450 2/10/2016 12:14 9.46 254.7485199 56.84 0 200 63 200 450 2/10/2016 12:29 8.89 258.522583 55.89 0 200 63 200 450 2/10/2016 12:44 Hi/10/2016 LL59 7.82 258.3493042 7.30 ' " 258.2980347 56.48 56.34 0 200 0 200 63 200 450 63 200 450 2/10/2016 13:14 7.68 256.2337952 56.58 0 200 63 200 450 2/10/2016 13:29 7.61 258.5822144 56.08 0 200 63 200 450 2/10/2016 13:44 7.72 260.384552 56.43 0 200 63 200 450 2/10/2016 13:59 1 2/10/2016 14:14 2/10/2016 14:29 7.54 7.21 7.26 261.8625793 257.4872437 "2444981079 55.89 55.59 56.27 0 200 0 200 0 200 63 200 450 63 200 450) 63 200 450 2/10/2016 14:44 6.42 255.3092194 56.39 0 200 63 200 450 2/10/2016 14:59 5.12 256.5794983 56.04 0 200 63 200 450 2/10/2016 15:14 5.06 256.9254761 56.16 0 200 63 200 450 2/10/2016 15:29 4.56 257.0950317 55.81 0 200 63 200 450 2/10/2016 15:44 4.39 257.0889893 55.27 0 200 63 200 450 2/10/2016 15:59 4.54 256.2302856 55.77 0 200 63 200 450 2/10/2016 16:14 4.57 255.1434479 55.46 0 200 63 200 450 2/10/2016 16:29 4.48 255.556488 55.78 0 200 63 200 450 2/10/2016 16:44 4.58 255.0113068 55.91 0 200 63 200 450 2/10/2016 16:59 4.43 254.2060547 55.68 0 200 63 200 450 2/10/2016 17:14 4.62 254.8474426 55.07 0 200 63 200 450 Average Average Average dp Flow volts 9,14 253.93 56.26 7.51 258.81 56.15 5.02 256.54 55.91 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-10-2016 Cal 1 F ED 001523 00007569-00530 LIMIT MIN 36.78 96 1 0 0 LIMIT MAX R:\envir\MACT_DATAYWESP\jAVESP16_M_Data_02032016.xlsJWESP2_Table 0 95 l 96 96 0 200==TitleV,0=Mac Wash==0, Run=200 off=0,SU/SD==100,ran=200 24.00 Time Stamp CAL2 Venturi DCAL2 Venturi F wesp2_GVC_Sec^wesp2_ModeStatu wesp2 DeviceStat wesp2 IOStatus CAL2 ProcStatus DataQuality 2/3/2016 13:44 8.86 282.1556702 58.01 0 200 63 200 450 2/3/2016 13:59 8.95 283.7761841 57.76 0 200 63 200 450 2/3/2016 14:14 9.02 282.9382324 57.51 0 200 63 200 450 2/3/2016 14:29 2/3/2016 14:44 9.23 9.05 283.8735046 283.2476501 57.53 57.47 0 200 0 200 63 200 450 63 200 450 2/3/2016 14:59 9.03 284.849823 57.67 0 200 63 200 450 2/3/2016 15:14 2/3/2016 15:29 8.72 8.83 285.8150635 286.4745483 57.86 57.94 0 200 0 200 63 200 450 63 200 450 2'3/2016 15:44 8.92 285.1524048 58.21 0 200 63 200 450 2/3/2016 15:59 8.86 285.9041748 57.66 0 200 63 200 450 2/3/2016 16:14 8.77 285.7659302 58.15 0 200 63 200 450 2/3/2016 16:29 7.71 283.1392822 58.22 0 200 63 200 450 2/3/2016 16:44 8.01 287.9154968 58.28 0 200 63 200 450 Average Average Average dp Flow volts 8.98 284.53 57.66 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-3-2016 Cal 2 F ED 001523 00007569-00531 LIMIT MIN 36.78 LIMIT MAX C: Users'dav-id_marzec'AppData-Local Microsoft'Windows'Te Files- Con!ent.Outlook Y35TISKO' [Stack testing schedufend times 3-23-2016-2016abc.xisx]2-12-2016 Cal TF 2 6 PM 200=Tit!eV,0=Mact 24.00 TimeStamp CAL2_Venturi_DP C'AL2VenturiFL wesp2_GVC_SecVolt wesp2_ModeStatus 2/12/2016 9:29 9.91 256.6082764 53.11 2/12/2016 9:44 2/12/2016 9:59 2/12/2016 10:14 2/12/201610:29 2/12/201610:44 2/12/2016 10:59 2/12/2016 11:14 2/12/2016 11:29 2/12/2016 11:44* 9.96 10.21 10.32 10.40 8.03 10.32 10.11 11.68 13.06 253.7470703 263.4375305 279.388916" 281.7334595 161.0151367 441.4985352 496.3938904 495.8388062 *493.5860291 50.49 43.98 49.46 " 47.09 46.46 56.48 57.27 53.31 51.85 2/12/2016 11:59 11.75 491.397522 49.13 2/12/2016 12:14 10.12 488.6819153 51.82 2/12/2016 12:29 8.85 479.4499207 51.11 2/12/2016 12:44 10.43 474.6166077 53.67 2/12/2016 12:59 2/12/2016 13:14 2/12/201613^9TM 10.65 10.70 "" 10.99* 476.7000122 475.0110168 475.0350037 51.94 51.42 50.24 "" 2/12/2016 13:44 11.32 473.3886719 50.14 2/12/2016 13:59 2/12/2016 14:14 2/12/2016 14:29 2/12/2016 14:44 11.54 11.71 11.89 12.04 472.0480347 471.2991638 471.9445496 469.2303772 48.84 48.71 48.49 48.61 2/12/2016 14:59 12.13 468.1436157 48.35 2/12/2016 15:14 11.65 466.0432739 48.04 2/12/2016 15:29 11.71 466.0702515 47.13 2/12/2016 15:44 13.14 466.0709229 46.09 2/12/2016 15:59 13.79 465.3643188 46.82 96 0 93 l Wash=0, Run=200 wesp2_DeviceStatus 0 0 0 o " 0 0 0 0 0 0 0 0 0 0 0 0 o xTM 0 0 0 0 0 1T"TM 0 0 0 0 wesp2_IOStatus 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 "200 " ' 200 200 200 200 200 200 200 200 200 200 96 0 off=0,SU/SD=100,run=200 CAL2_ProcStatus 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 DataQuality 200 200 200 200" 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 96 450 450 450 '450I 45| 4501 4501 450I 45oj 450" 450 450 450 450 450 450 450| 450| 44455500I1[ 45o[ 450 450 450 450 450 Avg dp flow volt 10.14 359.31 51.68 11.58 472.16 49.17 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00532 LIMIT MIN 40.46 96 0 0 0 LIMIT MAX 0 96 96 96 R:\envii\MACTJ3ATA\WESP\fWESP 16_M_Data_0213 2016 ,xls]WESP3_Table 0| 0 200=TitleV,0=M< Wash=0, Run=200 off=0,SU/SD=100,run=200 24.00 Time Stamp CAL3_Venturi_i CAL3 Vcntui'i wesp3_GVC_Se< wesp3_ModeStai wesp3_DeviceSti wesp3_IOStatus CAL3_ProcStati DataQuality 2/13/2016 9:14 2/13/2016 9:29 6.23 5.74 263.3436279 264.4372864 56.38 56.26 0 200 0 200 16 200 450 16 200 450 2/13/2016 9:44 2/13/2016 9:59 2/13/2016 10:14 2/13/2016 10:29 2/13/2016 10:44 2/13/2016 10:59 5.33 5.10 4.82 4.44 4.18 3.17 263.9977112 262.9310608 262.763916 262.953064 262.9348145 263.6678467 56.03 56.26 56.12 56.21 56.16 56.24 0 200 0 200 0 200 0 200 0 200 0 200 16 200 450 16 200 450 16 200 450 16 200 450 16 200 450 16 200 450 2/13/2016 11:14 2.84 263.8062744 56.25 0 200 16 200 450 2/13/2016 11:29 2/13/2016 11:44 2/13/2016 11:59 2/13/201612-14 2/13/2016 12:29 2/13/2016 12:44 2/13/2016 12:59 2/13/2016 13:14 2/13/2016 13:29 2/13/2016 13:44 3.37 4.37 4.54 3.84 3.36 2.77 3.81 4.02 2.92 2.75 262.6755066 262.025116 262.0379333 264.4098816 263.6379395 260.6894836 262.6890564 262.5574341 262.5354919 263.0537415 56.22 56.17 55.80 55.88 55.92 56.18 56.27 55.73 56.16 56.26 0 200 0 200 0 200 0 200 0 200 0 200 0 200 0 200 0 200 0 200 16 200 450 16 200 450 16 200 450 16 200~ 4501 16 200 4501 16 200 4501 16 200 450!/ 16 200 450!! 16 200 4501 16 200 4501 2/13/2016 13:59 2/13/2016 14:14 2/13/2016 14:29 2/13/2016 14:44 2/13/2016 14:59 2/13/2016 15:14 2/13/2016 15:29 2/13/2016 15:44 3.36 4.37 5.10 4.74 3.48 2.83 2.23 1.76 262.9517212 262.9113464 261.9981384 265.6896973 264.401062 264.5167542 265.849823 265.7612915 56.11 56.26 56.02 55.70 55.97 56.11 56.07 55.98 0 200 0 200 o" 200 0 200 0 200 0 200 0 200 0 200 16 200 450 16 200 450 16 200 4501 16 200 4-5! 16 200 450 16 200 450 16 200 4501 16 200 4501 2/13/2016 15:59 0.90 266.8441467 56.12 0 200 16 200 450 2/13/2016 16:14 -0.17 265.9757385 56.01 0 200 16 200 450 2/13/2016 16:29 2/13/2016 16:44 -0.45 -0.45 264.9497375 265.7679749 56.28 56.39 0 200 0 200 16 200 450 16 200 450 2/13/2016 16:59 -0.45 266.2586975 56.16 0 200 16 200 450 Average Average Average dp Flow volts 4.51 263.21 56.17 3.35 262.80 56.06 3.36 264.70 55.98 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-13-2016 Cal 3 F ED 001523 00007569-00533 LIMIT MIN LIMIT MAX 38.56 96 0 U:\ENVA\Air\RTR\ICR - Stack Test\2010 ICR\Pararaetric Monitoring\[WESP16_M_Data_02012016.xls]WESP4_Table 4 92 o| 0 0 96 96 0 200==TitleV,0=Mac Wash=0, Run =200 off=0,SU/SD= 100,run=200 24.00 Time Stamp CAL4 Venturi DCAL4 Venturi F wesp4 GVC Sec' \vesp4 ModeStati wesp4 DeviceStat wesp4 IOStatus CAL4 ProcStatus DataQuality 2/1/2016 12:14 2/1/2016 12:29 -0.45 -0.45 319.944519 323.9185791 57.30 57.90 0 200 0 200 16 200 450 16 200 450 2/1/2016 12:44 -0.45 321.8739014 57.85 0 200 16 200 450 2/1/2016 12:59 -0.45 324.3770142 58.11 0 200 16 200 450 2/1/2016 13:14 -0.45 322.354126 57.84 0 200 16 200 450 2/1/2016 13:29 2/1/2016 13:44 2/1/2016 13:59 -0.45 -0.45 -0.45 323.0058289 324.5963745 322.3806458 57.96 58.11 57.89 0 200 0 200 0 200 16 200 450 16 200 450 16 200 450 2/1/2016 14:14 2/1/2016 14:29 2/1/2016 14:44 2/1/2016 14:59 2/1/2016 15:14 -0.45 -0.45 -0.45 -0.45 -0.45 323.7549744 " 322.3956299 321.2975769 322.8255005 322.9447632 58.03 57.68 57.92 57.83 57.84 0 200 0 200 0 200 0 200 0 200 16 200 450 16 200 ` 4501 16 200 450 i : 16 200 4501 16 200 45 of 2/1/2016 15:29 2/1/2016 15:44 2/1/2016 15:59 -0.45 0.10 -0.45 323.8586731 321.8209839 321.3792419 57.98 57.67 57.25 0 200 0 200 0 200 16 200 4501 16 200 4501 16 200 4501 2/1/2016 16:14 2/1/2016 16:29 2/1/2016 16:44 -0.45 5.58 9.14 322.0119019 320.6730652 321.9713135 57.27 57.54 57.81 0 200 0 200 0 200 16 200 4501 16 200 451! 16 200 4501 2/1/2016 16:59 2/1/2016 17:14 13.14 13.72 319.5913086 323.6791382 57.02 58.01 0 200 0 200 16 200 4501 16 200 4501 2/1/2016 17:29 2/1/2016 17:44 2/1/2016 17:59 13.53 13.70 14.02 321.0500488 322.1691895 316.9785156 57.81 57.86 57.20 0 200 0 200 0 200 16 200 450 16 200 450 16 200 450 2/1/2016 18:14 14.22 319.1817017 57.59 0 200 16 200 450 2/1/2016 18:29 2/1/2016 18:44 14.16 14.39 317.994751 320.625061 57.12 57.69 0 200 0 200 16 200 450 16 200 450 2/1/2016 18:59 14.22 319.2285767 57.28 0 200 16 200 450 2/1/2016 19:14 14.50 321.3409119 57.69 0 200 16 200 450 2/1/2016 19:29 14.51 320.4385376 57.55 0 200 16 200 450 2/1/2016 19:44 14.38 319.7770691 57.38 0 200 16 200 450 2/1/2016 19:59 14.21 319.3372192 57.18 0 200 16 200 450 Average Average Average dp Flow volts -0.45 323.10 57.96 13.43 321.64 57.65 14.00 319.67 57.54 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-1-2016 Cal 4 F ED 001523 00007569-00534 LIMIT MIN 37.95 96 4 5 LIMIT MAX 0 92 91 U:\ENVA\Aii\RTR\ICR - Stack Test\2010 ICR\Parametric Momtoring\[\\7ESP16_M_Data_012 2016.xls]WESP5_Tabie o| 5 O0 n 1 o' O0 n II 1 ho ' 1 200=TitleV,0==Mact off=0,SU/SD= 24.00 Time Stamp CAL5 Venturi DP CAL5 Venturi FL wesp5 GVC SecVowesp5 ModeStatus wesp5 DeviceStatu* wesp5_IOStatus CAL5 ProcStatus DataQuaiity 1/27/2016 0:14 12.34 443.3855591 55.54 0 200 16 200 1/27/2016 11:14 1/27/2016 11:29 12.11 11.80 380.8037415 384.8260498 55.78 50.93 0 200 0 200 16 200 16 200 1/27/2016 11:44 11.54 383.943573 49.66 0 200 16 200 1/27/2016 11:59 11.42 383.9141541 51.35 0 200 16 200 1/27/2016 12:14 1/27/2016 12:29 11.06 11.21 371.958313 371.1896057 50.29 46.16 0 200 0 200 16 200 16 200 1/27/2016 12:44 11.21 371,2919312 44.63 0 200 16 200 1/27/2016 12:59 11.03 369.9322815 45.08 0 200 16 200 1/27/2016 13:14 1/27/2016 13:29 11.00 10.88 370.3465576 370.178833 43.56 41.83 0 200 0 200 16 200 16 200 1/27/2016 13:44 11.13 369.3167725 43.01 0 200 16 200 1/27/2016 13:59 1 1/27/201614:14 1 1/27/201614:29 1 1/27/201614:44 1 1/27/201614:59 11.28 11.46 11.24 10.81 10.82 369.4450378 369.4263306 368.2403259 367.0921936 367.5924072 44.06 44.38 45.28 46.09 39.55 0 200 0 200 0 200 0 200 0 200 16 200 16 200 16 200 16 200 16 200 i ,27/2016 15:14 7.97 231.5898743 13.16 0 0 16 200 1/27/2016 15:29 5.65 128.4108582 0.04 0 0 16 200 1/27/2016 15:44 7.63 209.8193054 30.63 0 0 16 200 1/27/2016 15:59 2.62 -54.97972488 41.00 0 0 16 200 1/27/2016 16:14 2.84 5.265529633 41.92 0 200 16 100 1/27/2016 16:29 9.60 389.239563 53.72 0 200 16 100 1/27/2016 16:44 1/27/2016 16:59 10.90 10.92 385.243927 385.8101501 54.80 55.11 0 200 0 200 16 200 16 200 1/27/2016 17:14 10.97 385.7574768 55.58 0 200 16 200 1/27/2016 17:29 1/27/2016 17:44 10.99 10.79 385,5800781 385.0992126 55.67 55.67 0 200 0 200 16 200 16 200 1/27/2016 17:59 10.69 384.7618103 55.53 0 200 16 200 1/27/2016 18:14 10.60 384.484436 55.30 0 200 16 200 1/27/2016 18:29 10.49 384.7272339 55.73 0 200 16 200 1/27/2016 18:44 10.43 385.1109619 55.84 0 200 16 200 1/27/2016 18:59 10.18 383.2653503 55.80 0 200 16 200 0 96 450 450 450 450 450 450 450 450 450 450 450 450| 450 450 450 450 4501 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 Average Average Average dp Fiow voits 11.17 374.09 46.57 11.12 368.52 43.73 9.57 331.71 53.21 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA 6/22 Production 1-27-2016 Cal 5 F ED 001523 00007569-00535 LIMIT MIN 41.62 96 2 0 limit max | R:\envir\MACT_DATA\WESP\[WESP 16_M_Data_01262016 .xls]WESP6_Table 0 94 96 01 0 200=TitleV,0=Mact Wash=0, Run=200 off=0,SU/SD=100,ran=200 24.00 Time Stamp CAL6_Venturi_DP CAL6_Venturi_FL wesp6_GVC_SecVo wesp6_ModeStatus wesp6_DevieeStatu< wesp6_IOStatus CAL6_ProcStatus DataQuality 1/26/2016 13:59 6.87 309.1962891 50.35 0 200 16 200 1/26/2016 14:14 7.08 311.5437012 47.90 0 200 16 200 1/26/2016 14:29 6.92 309.4353333 50.00 0 200 16 200 1/26/2016 14:44 1/26/2016 14:59 1/26/2016 15:14 1/26/2016 15:29 1/26/2016 15:44 1/26/2016 15:59 6.78 6.72 6,31 6.47 6.41 6.37 296.2180481 284.6438599 284.5022888 281.5246277 280.2870178 277.6039124 48.15 49.40 50.33 49.81 50.73 49.54 0 200 0 200 0 200 0 200 0 200 0 200 16 200 16 200 16 200 16 200 16 200 16 200 1/26/2016 16:14 1/26/2016 16:29 6.39 6.12 273.0499268 277.58255 48.67 49.66 0 200 0 200 16 200 16 200 1/26/2016 16:44 1/26/2016 16:59 1/26/2016 17:14 1/26/2016 17:29 1/26/2016 17:44 1/26/2016 17:59 1/26/2016 18:14 6.12 5.84 5.74 5.60 5.81 5.57 4.69 276.6861572 277.0177307 278.0146484 276.7490845 275.5645447 275.2138977 275.7106934 50.61 49.40 48.18 49.68 47.39 48.81 49.05 0 200 0 200 0 200 0 200 0 200 0 200 0 200 16 200 16 200 16 200 16 200 16 200 16 200 16 200 1/26/2016 18:29 1/26/2016 18:44 3.75 3.58 275.6710815 274.456543 52.22 52.03 0 200 0 200 16 200 16 200 1/26/2016 18:59 1/26/2016 19:14 1/26/2016 19:29 1/26/2016 19:44 1/26/2016 19:59 1/26/2016 20:14 1/26/2016 20:29 3.57 4.28 4.53 4.44 4.43 4.57 4.29 274.0357361 273.7733765 274.885498 276.3596497 274.9865417 274.6878967 273.8627625 51.89 49.64 47.84 49.89 50.10 47.81 48.73 0 200 0 200 0 200 0 200 0 200 0 200 0 200 16 200 16 200 16 200 16 200 16 200 16 200 16 200 1/26/2016 20:44 1/26/2016 20:59 1/26/2016 21:14 1/26/2016 21:29 1/26/2016 21:44 4.16 4.45 4.38 4.31 3.43 274.2316895 274.321228 274.7125244 275.0152893 275.4522705 48.99 49.73 48.73 48.05 50.72 0 200 0 200 0 200 0 200 0 200 16 200 16 200 16 200 16 200 16 200 0 96 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 450 Average Average Average dp Flow volts 6.51 284.13 49. 5.62 276.42 49. 4.30 274.66 49. Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 1-26-2016 Cal 6 F ED 001523 00007569-00536 LIMIT MIN 37.17 96 3 LIMIT MAX 0 93 R:\envir\MACT_DATA\\\rESP\[\\rESP16_M_Data_021120i6.xls]\\rESPi_Table 0| 0 0 96 96 0 200=TitleV,0==Mac Wash==0, Rim=200 off=0,SU/SD=100,nm==200 24.00 Time Stamp CALI Venturi DCAL1 Venturi F WESP1 GVC SeWESPl ModeStaWESPl DeviceSt; WESP1 IOStatusCALl ProcStatus DataQuality 2/11/2016 9:44 20.17 251.1082458 56.22 0 200 63 200 450 2/11/2016 9:59 2/11/2016 10:14 20.42 20.67 250.4251862 249.8616486 55.61 54.64 0 200 0 200 63 200 450 63 200 450 2/11/2016 10:29 20.34 250.1308899 54.11 0 200 63 200 450 2/11/201610:44 20.39 249.7713928 55.54 0 200 63 200 450 2/11/2016 10:59 20.16 250.2320709 55.61 0 200 63 200 450 2/11/2016 11:14 2/11/2016 11:29 19.78 20.03 249.891983 250.9060974 55.70 55.73 0 200 0 200 63 200 450 63 200 450 2/11/2016 11:44 [*"2/11/201611:59 19.97 19.85 250.9214783 250.9376373 56.09 54,60 0 200 63 200 450 0 200 ' 63' 200 *450| 2/11/201612:14 19.80 250.319809 55.26 0 200 63 200 450 2/11/201612:29 2/11/2016 12:44 2/11/201612:59 19.84 19.71 20.08 249.8757172 249.7145996 249.1447906 55.21 55.61 55.12 0 200 0 200 0 200 63 200 450 63 200 450 63 200 4501 2/11/2016 13:14 20.11 248.7480011 55.80 0 200 63 200 450 2/11/2016 13:29 20.05 248.5127258 55.81 0 200 63 200 450 2/11/201613:44 20.15 248.7475586 55.28 0 200 63 200 450 2/11/2016 13:59 2/11/201614:14 19.96 19.84 248.709137 248.6884308 55.10 54.85 0 200 0 200 63 200 450 63 200 450 2/11/2016 14:29 19.79 248.1073456 55.58 0 200 63 200 450 2/11/2016 14:44 20.14 248.2310638 55.16 0 200 63 200 450 2/11/2016 14:59 20.15 247.8700867 55.65 0 200 63 200 450 2/11/2016 15:14 20.33 249.3988495 54.85 0 200 63 200 450 2/11/2016 15:29 20.60 252.7215424 54.69 0 200 63 200 450 2/11/2016 15:44 20.39 252.7888641 54.07 0 200 63 200 450 Average Average Average dp Fiow volts 20.14 250.19 55.34 19.85 250.00 55.16 19.96 248.55 55.33 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-11-2016 Cal 1 Hg ED 001523 00007569-00537 LIMIT MIN 36.78 96 3 0 0 LIMIT MAX 0 93 P:\Common ProjectsVField MeasurementsPreject Folders'P-T'.PCS Phosphate\2016\Calciners Jan Testmg'.Compliance'Feed Informationfrom PCS\[Copy of Stac' l 96 96 0 200=TitleV,0=Mact Wash=0, Run=200 off=0,SU/SD =100,run=200 24.00 TimeStamp CAL2 Venturi DP CAL2 Venturi FL wesp2 GVC SecVoit wesp2_ModeStatus wesp2_DeviceStatus wesp2 IOStatus CAL2 ProcStatus DataQuality 2/13/2016 10:29 6.86 290.6651306 43.53 0 200 63 200 450 2/13/2016 10:44 5.61 280.9512024 43.51 0 200 63 200 450 2/13/2016 10:59 2/13/2016 11:14 2/13/2016 11:29 8.75 282.5804138 8.91 284.8589478 9.55 285.1002808 43.69 44.30 43.62 0 200 63 200 0 200 63 200 450 0 200 63 200 450 2/13/2016 11:44 2/13/2016 11:59 9.58 285.0424194 8.62 286.3757935 43.61 46.83 0 200 63 200 450 0 200 63 200 2/13/2016 12:14 2/13/2016 12:29 9.87 10.32 279.8141174 275.3161926 43.31 42.29 0 200 63 200 450 0 200 63 200 450 f" 2/13/201612:44 2/13/201612:59 2/13/201613:14 2/13/201613:29 1 2/13/201613:44 9.80 9.97 10.02 9.43 8.15 276.3125916 277.3450012 277.706604 278.7950439 279.8729553 43.58 43.53 42.81 44.16 42.85 0 200 63 200 ^ ^ ^ "450J 0 200 63 200 450 0 200 63 200 450 0 200 63 200 450 0 200 63 200 450[ 2/13/2016 13:59 2/13/2016 14:14 f 2^3/201614:29 2/13/201614:44 J 2/13/2016 14:59 1 2/13/201615:14 J 2/13/201615:29 8.70 280.8685608 8.24 281.2093506 8.50 282.0545959 6.01 282.0765381 6.92 283.8583374 8.51 283.6979065 9.50 282.9277344 42.82 43.40 42.36 42.81 43.08 42.82 43.04 200 63 200 450 0 200 63 200 450 0 200 63 200 450 0 200 63 200 450 0 200 63 200 4501 0 200 63 200 450 0 200 63 200 450 2/13/2016 15:44 9.44 283.8655396 43.68 0 200 63 200 450 2/13/2016 15:59 10.35 342.5272827 43.34 0 200 63 200 450 2/13/2016 16:14 9.29 366.7206116 44.72 0 200 63 200 450 2/13/2016 16:29 2/13/2016 16:44 8.40 391.7495117 8.80 393.0188599 44.69 43.49 0 200 63 200 450 0 200 63 200 450 Average Average Average dp Flow volts 9.08 284.79 44.41 9.47 278.01 43.39 7.89 282.92 42.82 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-13-2016 Cal 2 Hg ED 001523 00007569-00538 LIMIT MIN LIMIT MAX ir MACT_DATA WESP [WESPI6_M_E a_01302016.\kjWESP2_Table 24.00 96 3 0 93 200=TitleV,0=Mact l Wash=0: Run=200 TimeStamp CAL2_Venturi_DP CAL2_Venturi_FL wesp2_GVC_SecVolt wesp2_ModeStatus 1/30/2016 9:59 9.42 276.2845764 58.36 1/30/2016 10:14 8.51 276.7911072 58.45 1/30/2016 10:29 8.04 276.017334 58.21 1/30/2016 10:44 7.96 279.2853699 8.45 wesp2_DeviceStatus wesp2_IOStatus 0 200 0 200 0 200 0 0 1/30/2016 10:59 1/30/2016 11:14 1/30/201611:29 1/30/2016 11:44 1/30/2016 11:59 7.92 282.6581726 7.66 281.4541931 8.59 280.8525085 7.87 281.2110901 7.57 280.960083 0.03 37.53 49.78 54.64 57.18 0 0 0 0 0 200 0 200 0 200 1/30/2016 12:14 " 1/30/2016 12:29 1/30/2016 12:44 1/30/2016 12:59 1/30/2016 13:14 7.75 278.8018799 7.55 277.7067566 8.56 277.2828979 9.53 276.6105652 7.43 276.4066162 57.89 57.92 57.95 57.48 56.26 0 200 0 200 0 200 0 200 0 200 1/30/2016 13:29 1/30/2016 13:44 1/30/2016 13:59 1/30/2016 14:14 7.48 275.2250366 8.37 271.8681641 8.38 280.3705444 7.35 271.9503174 57.23 57.49 57.32 57.41 0 200 0 200 0 200 0 200 1/30/2016 14:29 1/30/2016 14:44 1/30/2016 14:59 1/30/2016 15:14 1/30/2016 15:29 1/30/2016 15:44 1/30/2016 15:59 1/30/2016 16:14 1/30/2016 16:29 1/30/2016 16:44 1/30/2016 16:59 7.57 267.8730469 7.57 269.8012695 7.67 274.8222351 7.55 275.2582703 7.54 275.5130005 7.47 275.4533081 7.30 274.7626343 7.38 274.8636169 7.35 276.5568542 8.35 276.863678 8.42 271.1066284 54.95 55.28 55.22 54.92 54.53 56.27 56.69 55.94 56.37 57.65 58.43 0 0 0 0 0 ^200 o ^00 00 ^ a. 200................. 200 ^ 200 y\v* 200 \> 200 off=0,SU/SD=100,run: ~ 1 200 63 200 63 200 63 200 63 200 63 200 63 200 63 200 63 200 63 200 63 200 Average Average Average dp Flow volts 7.92 281.43 39.83 450 450 450 450 450 450 450 450 450 450 450 \<x^O 8 Stack Testing Detailed Datav2 17cv1906 Sierra Club v. EPA - 6/22 Production 1-30-2016 Cal 2 Hg ED 001523 00007569-00539 LIMIT MIN 40.46 96 4 0 0 LIMIT MAX 0 92 96 96 R:\envir'MACT_DATA\\VESP\[\VESPi6_M_Data_021120i6.x!s]'WESP3_Tab!e 0| 0 200==TitleV,0=Mac Wasli= 0, Rim=200 off=0,SU/SD==100,nm=200 24.00 TimeStamp CAL3 Venturi D CAL3_Venturi_F wesp3_GVC_Sec> wesp3_ModeStatu wesp3 DeviceStat wesp3 IOStatus CAL3_ProcStatus DataQuality 2/11/2016 15:44 10.68 252.8739166 55.81 0 200 16 200 450 2/11/2016 15:59 9.81 253.3942261 56.14 0 200 16 200 450 2/11/2016 16:14 10.14 253.3753052 56.07 0 200 16 200 450 2/11/2016 16:29 10.26 253.7281647 56.18 0 200 16 200 450 2/11/2016 16:44 10.38 253.1803894 56.22 0 200 16 200 450 2/11/2016 16:59 10.54 252.9416809 55.83 0 200 16 200 450 2/11/2016 17:14 10.60 253.5380096 55.44 0 200 16 200 450 2/11/2016 17:29 10.19 253.628418 55.78 0 200 16 200 450 p2m/2016 17:44 10.10 253.7892609 55.83 0 200 16 200 450 2/11/2016 17:59 10.09 253.2442322 56.17 0 200 16 200 450 2/11/2016 18:14 9.98 252.9442291 56.39 0 200 16 200 4508 2/11/2016 18:29 1 2/11/2016 18:44 10.07 9.88 253.3796692 253.5512695 56.36 56.22 0 200 0 200 16 200 450 16 200 450 2/11/2016 18:59 9.56 253.4882355 56.15 0 200 16 200 450 2/11/2016 19:14 9.50 253.6296387 56.20 0 200 16 200 450 2/11/2016 19:29 9.57 253.1040344 56.18 0 200 16 200 450 2/11/2016 19:44 9.64 252.8720093 56.50 0 200 16 200 450 2/11/2016 19:59 9.26 253.1803589 56.41 0 200 16 200 450 2/11/2016 20:14 9.31 253.1696777 56.37 0 200 16 200 450 2/11/2016 20:29 9.64 252.7218475 56.50 0 200 16 200 450 2/11/2016 20:44 10.03 253.0273895 56.31 0 200 16 200 450 2/11/2016 20:59 10.06 253.2677307 56.18 0 200 16 200 450 2/11/2016 21:14 9.78 253.4777222 56.18 0 200 16 200 450 Average Average Average dp Flow volts 10.38 253.35 55.95 10.02 253.38 56.19 9.51 253.25 56.29 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-11-2016 Cal 3 Hg ED 001523 00007569-00540 LIMIT MIN 38.56 96 4 0 0 LIMIT MAX R:\emdl\MACT_DATA\WESP\fWESP16_M_Data_02102016.xlslWESP4_TAle 0 92 0| 96 96 0 200=TitleV,0=Mai Wash=0, Run=200 off=0,SU/SD=100,nm=200 24.00 Time Stamp CAL4_Venturi_E CAL4_Venturi_F wesp4_GVC_Sec' wesp4_ModeStati wesp4_DeviceSta wesp4_IOStatus CAL4_ProcStatu DataQuality 2/10/2016 11:59 5.93 333.4341736 55.46 0 200 16 200 450 2/10/2016 12:14 4.51 323.917511 55.80 0 200 16 200 450 2.10/2016 12:29 3.33 323.7633057 55.74 0 200 16 200 450? 240 2016 12:44 2.02 325.1846924 56.01 0 200 16 200 450/ 2/10 2016 12:59 240/2016 13:14 2 10/2016 13:29 1.18 1.25 1.22 327.8613281 325.7514343 322.71698 56.11 55.85 55.93 0 200 0 200 0 200 16 200 450? 16 200 450| 16 200 450J 2/10,2016 13:44 2,10 2016 13:59 1.17 4.63 304.422699 283.3865662 56.06 56.23 0 200 0 200 16 200 450 16 200 450 240,2016 14:14 7.07 331.3538513 56.05 0 200 16 200 450 240/2016 14:29 2 40/2016 14:44 7.19 7,33 331.3825378 331.6476746 55.99 55.89 0 200 0 200 16 200 450 16 200 450 2/10,2016 14:59 7.54 334.4973755 56.06 0 200 16 200 450* 210.2016 15:14 7.68 334.4176636 55.71 0 200 16 200 450s 2 10'2016 15:29 7.66 331.0709839 55.93 0 200 16 200 4501 240 2016 15:44 2,40/2016 15:59 7.90 8.04 332.5897827 333.5845337 55.86 55.79 0 200 0 200 16 200 450' 16 200 450a 2 10 2016 16:14 8.00 332.5674438 55.84 0 200 16 200 450 2/10/2016 16:29 8.04 331.5926514 55.80 0 200 16 200 450 2/10/2016 16:44 8.00 334.7771606 55.88 0 200 16 200 450 2/10/2016 16:59 7.98 334.8189087 55.56 0 200 16 200 450 2/10/2016 17:14 8.13 335.7671509 55.87 0 200 16 200 450 Average Average Average dp Fiow voits 1.80 325.06 55.93 5.48 316.44 56.04 7.76 333.23 55.87 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-10-2016 Cal 4 Hg ED 001523 00007569-00541 LIMIT MIN 37.95 96 0 0 limit max | 0 96 96 R: envir MACT_DATA'WESP [\VESP16_M_Data_02082016.xkjWESP5_Table 0| 0 200=TitleV:0=Mact Wash=0: Run=200 off=0,SU/SD=100,run=200 24.00 TimeStamp CAL5_Venturi_DP CAL5_Venturi_FL wesp5_GVC_SecVolt wesp5_ModeStatus wesp5_DeviceStatus wesp5_IOStatus 2/8/2016 13:29 16.90 493.9317627 57.16 0 200 2/8/2016 13:44 16.83 494.3588257 57.11 0 200 2/8/2016 13:59 17.06 495.0139465 57.09 0 200 CAL5_ProcStatus DafaQuality 16 200 16 200 16 200 2/8/2016 14:14 2/8/2016 14:29 2/8/2016 14:44 2/8/2016 14:59 16.74 17.14 16.88 17.17 494.3547974 495.0810852 494.4953003 495.676178 56.84 57.23 56.82 57.09 0 200 0 200 0 200 0 200 16 200 16 200 16 200 16 200 2/8/2016 15:14 2/8/2016 15:29 2/8/2016 15:44 2/8/2016 15:59 2/8/2016 16:14 2/8/2016 16:29 17.10 17.04 17.17 17.27 17.24 17.16 494.6115417 495.4571838 495.1403809 495.2221069 494.8566284 495.1726685 557?.:2i21- 57.05 56.89 57.27 57.24 0 200 0 200 0 200 0 200 0 200 0 200 16 200 16 200 16 200 16 200 16 200 16 200 2/8/2016 16:44 2/8/2016 16:59 2/8/2016 17:14 2/8/2016 17:29 2/8/2016 17:44 17.16 17.23 16.92 16.96 16.66 495.1500244 495.5868835 495.8738098 494.6351318 494.9187012 57.32 57.31 57.28 56.92 56.83 0 200 0 200 0 200 0 200 0 200 16 200 16 200 16 200 16 200 16 200 2/8/2016 17:59 2/8/2016 18:14 2/8/2016 18:29 2/8/2016 18:44 2/8/2016 18:59 16.68 16.37 16.35 16.38 16.18 494.2401123 494.3402405 493.9665222 493.6100769 492.9337158 56.64 56.74 56.69 56.73 56.70 0 200 0 200 0 200 0 200 0 200 16 200 16 200 16 200 16 200 16 200 0 96 450 450 450 450 450 450 450 450 450 450 450 450 450| 450 450 450 450 450 450 450 450 450 450 Average Average Average dp Flow volts 17.01 494.84 57.04 17.18 495.17 57.11 16.99 495.23 57.13 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-8-2016 Cal 5 Hg ED 001523 00007569-00542 LIMIT MIN 41.62 96 4 LIMIT MAX | 0 92 P:\Common_ProjectsVField MeasurementsPreject Folders'P-TtPCS Phosphate\2016\Calciners Jan Testing'.ComplianceYFeed Informationfrom PCS\[Copy of Stac' 0| 200=TitleV,0=Mact Wash=0, Run=200 0 96 0 off=0,SU/SD=100,run=200 0 96 24.00 Time_Stamp CAL6_Yenturi_DP CAL6_Yenturi_FL wesp6_GVC_SecVo!t wesp6_ModeStatus wesp6_DeviceStatus wesp6_IOStatus CAL6_ProcStatus DataQuality 2/19/201610:44 2/19/201610:59 2/19/2016 11:14 7.96 7.98 7.84 295.069519 296.3065186 296.8320007 50.26 46.01 44.45 0 200 16 200 450 0 200 16 200 450 0 200 16 200 450 2/19/2016 11:29 2/19/2016 11:44 2/19/2016 11:59 2/19/2016 12:14 2/19/2016 12:29 8.02 8.08 7.92 8.10 8.14 297.2509155 296.3667908 296.2422485 298.2344666 299.7904968 45.11 45.40 47.14 49.41 47.56 0 200 16 200 450 0 200 16 200 450 0 200 16 200 450 0 2Q0 16 200 450 0 200 16 200 450 2/19/2016 12:44 2/19/2016 12:59 2/19/201613:14 2/19/2016 13:29 2/19/2016 13:44 7.97 7.86 7.91 7.77 7.78 301.1985779 301.1803589* 298.7610168 300.9979553 300.3608398 48.53 49.36 48.51 49.64 48.04 200 16 200 16 200 16 200 16 200 16 200 200 200 200 200 450 450| 450 45o| 450 2/19/2016 13:59 2/19/201614:14 2/19/2016 14:29 2/19/2016 14:44 2/19/2016 14:59 7.82 7.59 7.72 7.49 7.83 300.572052 293.3833313 288.9813538 295.0922852 298.8062134 47.24 46.03 45.09 46.15 45.53 Q 200 16 200 450 0 200 16 200 0 200 16 200 0 200 16 200 0 200 16 200 2/19/2016 15:14 2/19/2016 15:29 2/19/2016 15:44 2/19/2016 15:59 2/19/2016 16:14 8.66 9.34 9.07 9.12 9.32 542.8014526 602.9814453 602.1797485 603.2844238 602.4868164 47.42 48.13 50.59 47.83 47.91 0 200 16 200 450 0 200 16 200 450 0 200 16 200 450 0 200 16 200 450 0 200 16 200 450 Average Average Average dp Flow volts 8.05 297.58 46.92 7.83 300.37 48.56 7.69 295.37 46.01 Copy of Stack Testing Detailed Datavl 17cv1906 Sierra Club v. EPA - 6/22 Production 2-19-2016 Cal 6 Hg ED 001523 00007569-00543 APPENDIX C EQUIPMENT CALIBRATIONS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00544 PCS Phosphate 2/10/2016 Calciner # 1 Post Test Meter Calibration Check Meter No. N-45 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 Average Initial Meter y Deviation Post Test Meter QA (yjfa) 1.0310 1.0103 1.0231 1.0215 0.9943 2.7% Must be less than 5% Calciner #1 M13B.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00545 PCS Phosphate 2/13/2016 Calciner # 3 Post Test Meter Calibration Check Meter No. N-54 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 Average Initial Meter y Deviation Post Test Meter QA (yjfa) 1.0219 1.0394 1.0404 1.0339 1.0189 1.5% Must be less than 5% Calciner #3 M13B.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00546 PCS Phosphate 2/3/2016 Calciner # 2 Post Test Meter Calibration Check Meter No. N-54 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 Average Initial Meter y Deviation Post Test Meter QA (yjfa) 1.0032 0.9863 1.0057 0.9984 0.9782 2.1% Must be less than 5% Calciner #2 M13B.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00547 PCS Phosphate 2/1/2016 Calciner #4 Post Test Meter Calibration Check Meter No. N-55 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 Average Initial Meter y Deviation Post Test Meter QA (yj(a) 1.0299 1.0012 1.0003 1.0105 1.0189 0.8% Must be less than 5% Calciner #4 M13B.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00548 PCS Phosphate 1/27/2015 Calciner # 5 Post Test Meter Calibration Check Meter No. N-44 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 Average Initial Meter Deviation Post Test Meter QA Cqa) 0.9970 0.9915 0.9897 0.9927 1.0266 3.3% Must be less than 5% Calciner #5 M13B WetTPH 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00549 PCS Phosphate 1/26/2016 Calciner # 6 Post Test Meter Calibration Check Meter No. N-45 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 Average Initial Meter Deviation Post Test Meter QA ( <|a) 1.0287 1.0291 1.0173 1.0251 0.9943 3.1% Must be less than 5% Calciner #6 M13B WetTPH 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00550 PCS Phosphate 2/1/2016 Calciner # 2 Post Test Meter Calibration Check Meter No. N-54 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 2 3 4 Average Initial Meter y Deviation Post Test Meter QA (yjfa) 1.0545 1.0433 1.0731 1.0570 0.9978 5.9% Must be less than 5% Calciner #2 M5 202.xlsx 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00551 PCS Phosphate 2/23/2016 Calciner # 2 Post Test Meter Calibration Check Meter No. N-54 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 2 3 4 Average Initial Meter J Deviation Post Test Meter QA (Jqa) 1.0042 0.9936 1.0220 1.0066 0.9782 2.9% Must be less than 5% Calciner #2 M5_202 CT Change Example Calc Page 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00552 PCS Phosphate 2/3/2016 Calciner #4 Post Test Meter Calibration Check Meter No. N-55 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 Average Initial Meter Deviation Post Test Meter QA (4,a) 1.0142 1.0080 1.0030 1.0084 1.0189 1.0% Must be less than 5% Calciner #4 M5 202 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00553 PCS Phosphate 1/26/2016 Calciner # 5 Post Test Meter Calibration Check Meter No. N-44 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 Average Initial Meter Deviation Post Test Meter QA 0.9944 1.0008 1.0204 1.0052 1.0266 2.1% Must be less than 5% Calciner #5 M5 202 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00554 PCS Phosphate 1/27/2016 Calciner # 6 Post Test Meter Calibration Check Meter No. N-45 Per EPA EMTIC Guideline Document 26: Alternative Post-Test Calibration Run 1 2 3 Average Initial Meter Deviation Post Test Meter QA Cqa) 0.9934 0.9993 1.0030 0.9986 0.9943 0.4% Must be less than 5% Calciner #6 M5 202 v2 17cv1906 Sierra Club v. EPA - 6/22 Production Meter Calibration ED 001523 00007569-00555 DocNumber: 000008557 Praxair Distribution Mid-Atlantic One Steel Road East Morrisville, PA 19067 Tel:(800)638-6320 Fax:(215)736-5240 PGVP ID: F32014 CERTIFICATE OF ANALYSIS / EPA PROTOCOL GAS Customer & Order Information: PD I WHSE RALEIGH 2807 GRESHAM LAKE RD RALEIGH NC 276160000 Praxair Order Number: 04939769 Customer PO Number: __{jQne__ Customer Reference Number: Certified Concentration: Fill Date: 991 Pari Number: Lot Number: Cylinder Style and Outlet: Cylinder Pressure and Volume: 5/20/2014 Nl CD20.5O2E-AS 301613140403 AS CGA 590 2000 psig 157cu.f,. Expiration Date: Cylinder Number: 05/28/2022 CC102927 NIST Traceable Analytical Uncertainty: 20.76 19.26 % % Balance CARBON DIOXIDE OXYGEN NITROGEN 0.2 % 0.1 % Certification Information: Certification Date: 5/28/2014 Term: 96 Months Expiration Date: 05/28/2022 This cylinder was certified according to the 2012 EPA Traceability Protocol, Document #EPA-600/R-12/531, using Procedure G1. Do Not Use this Standard if Pressure is less than 100 PSIG. Analytical Data. (R=Reference Standard, Z=Zero Gas, C=Gas Candidate) 1 . Component: CARBON DIOXIDE Requested Concentration: Certified Concentration: Instrument Used: Analytical Method: Last Multipoint Calibration: 20.5 % 20.76 % SIEMENS ULTRAMAT 5E SN: D2-412 NON-DISPERSIVE INFRARED 05/21/2014 First Analysis Data: Z: o R: R: 19.89 Z: Z: 0 C: UOM: % 19.9 C: 0 C: 20.77 R: Date: 20.74 20.77 19.89 Cone: Cone: Cone: Mean Test Assay: 05/28/2014 20.74 20.77 20.77 20.76 % 2 . Component: OXYGEN Requested Concentration: Certified Concentration: Instrument Used: Analytical Method: Last Multipoint Calibration: 19.5 % 19.26 % SIEMENS OXYMAT5F PARAMAGNETIC 05/21/2014 First Analysis Data: Date: 05/28/2014 Z: 0 R: 23.15 C: 19.25 R: 23.15 Z: 0 C: 19.25 Z: o O 19.25 R: 23.15 Cone: Cone: Cone: 19.24 19.24 19.29 UOM: % Mean Test Assay: 19.26 Reference Standard Type: Ref. Std. Cylinder #: Ref. Std. Cone: Ref. Std. traceable to SRM #: SRM Sample #: SRM Cylinder #: GMIS CC182173 19.90 % 2745a 9-7-34 CAL016129 Second Analysis Data: Z: o R: R: o Z: Z: o C: 0 c 0 c 0 R Date: 0 Cone: 0 Cnc: 0 Cone: UOM: % Mean Test Assay: Reference Standard Type: Ref. Std. Cylinder #: Ref. Std. Cone: Ref. Std. traceable to SRM #: SRM Sample #: SRM Cylinder #: GMIS SA6707 23.14 % 2659A Second Analysis Data: Z: o R: R: o Z: Z: o C: UOM: o/o 0 c 0 c o R Date: 0 Cone: 0 Cnc: 0 Cone: Mean Test Assay: 0 o 0 q % 0 o 0 q o/0 Analyzed by: Judith Imperial Jeff Gosner Information contained herein has been prepared at your request by qualified experts within Praxair Distribution, Inc. While we believe that the information is accurate within the limits of the analytical methods employed and is complete to the extent of the specified analyses performed, we make no warranty or representation as to the suitability of the use of the information for any purpose. The information is offered with the understanding that any use of the information is at the sole discretion and risk of the user. In no event shall the liability of Praxair Distribution, Inc. arising out of the use of the information contained herein exceed the fee established for providing such information. Making Our Planet More Productive 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00556 -'.-'r-SmPRAXAIR DocNi 000013804 Praxair Distribution Mid-Atlantic One Steel Road East, Morrisville, PA 19067 Tel: (800) 638-6360 Fax:(215) 736 5240 PC :1 : . i Customer <$. Order Information PDMA WAREHOUSE =A'RlESS HI ONE STEEL RD E MORRISVILLE =A 2CS~: Praxair < inter A nn,i. C'ustomer P. () \im tv - 'ustomer Reference Sim "434158 '25 5543 Expiratior, Ea:e Cylinder Number. Certified Concentration: -2?;2023 CC313420 9.67 70.10 % CARBON DIOXIDE % OXYGEN Balance NITROGEN HU Date: Pan dumber: tM Number: Cylinder Style & Outlet: Cylinder Pressure <f Volume: 7/2312015 Ml GDI0010E-AS 301803204504 AS CGA 590 2000 psig 140 cu. ft. _________ 1__------------------------- - NIST Trappable AnalyficanJncertainty: 0.7 % 0.2 % Ceriifculion Information: Certification Date: 7/27/2015 : arm: 96 Months This cylinder was certified according to the 2012 ERA Traceability Protocol, Document #EPA-600;R-!2/531. using Procedure Gl. Co Not Use this Standard if P essu t y man iqo PSIG. Expiration Date: 7/27/2023 Analytical Data: 1 . Compor.snt CARBON DIOXIDE 1 -rcentranon Ceri.fsed' Ocn.-pr'sr :r Instrument Osct * Analytical Method Last Multiport Caiibr^p'' 're Virja-f Ze."j Gas C=Gas 10 % 9 678 S-EMF.4S ULTRAMAT 5 $M 02-412 MU-O.SFERSIVE INFRARED 7/25/2015 First Analysis Data: Z J R r- S9 Z: 0 R: 9 98 Z: 0 C: ' 57 UOM: 7, Date. C 3 89 Cone: C: 9 c7 Cone* R: & 98 Cone: fffan Test Assay: 7/2 u 69 9.67 V 17 / 0 87 % 2. Component: OXYGEN ~r Rcn-e&ter Con.e'Tct CeiliUd La :<n inr'-TuTie'" 0350 Ana pma Memod L.es: `A a'. pDT t Cal ora* cn First Analysis Data: Z:: 0 R: 21 14 C: 101 jp bnc 10 1 R:: 21 1b Z: 0 C. v, Z: 0 C: 10 ' R 21 J 4 ^ 10.1 UOM: Mean Test Analyzed by Reference Stsnda-d Type Rof 'i'G C'y r ce' Ref 5tc C or c Ref S`a Traceable to SRM # SRM Sample # SRM Cylinder# GMIS CCb7641 9.98% 2745 9-0-34 CAL01612& Second Analysis Data: Date: Z: 0 R: 0 C: w Cone: D R: 0 Z: 0 C: 0 Cone: 0 Z-. 0 C: 0 R: 0 Cone; 0 UOM: % Mean Test Assay: Reference Standard Type Ref Std Cylinder# Ref Std Cone Ref Std Traceao.-c -c SRM # -SRM Sample * SRM C v-1 odar# SRM CC182161 21 14 % 2SJ9A 7^-24 FF183C0 Second Analysis Data: Z: `j R. 5 : Cone: G R: Z: n C: , f; Cone: 0 Z n 0 R: 0 Cone. 0 UOM; zrv fo Irrormm cn tonta ned nefc-m has noen pieoured at yous regur-sf oy ouaiif cd experts wtnm praxair Listnbution, Inc While we believe that the information is accurate with'n the hrruts of the analytical methods employee is corr psete tht- rent rf ?be specific analyses performed we make no wc 'f drty or representation as to the suitability of the use of the- information for any purpose. The 0 uf m* 'nahon s uffe'ec witn the understanding that an/ use tne r'formation is at the sole discretion ar-d nsk of the user in no event shall tne liability of Praxair Distribution, Inc ansrng out of the use 9 of the rtormat.cn con tairru hercm pyceed `he P estabiisf-fec fix providing ^ucn information 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00557 mPRAXAIR DocN umber: 000008664 f'ravair Distribution Mid-Atlantic One Steel Road East, Morrisviiie, PA 19067 Tel: (800) 638-6360 J'ax'(2l5) 736 5240 PGVPID: F32014 CERTIFICATE OF ANALYSIS / EPA PROTOCOL GAS Customer & Order Information: PD! WHSE RALEIGH 2807 GRESHAM LAKE RD RALEIGH NC 276160 Praxair < Inter Nwither- 04939769 Customer P. (). Number: --None-- Customer Reference Number: Certified Concentration; Fill Dale: 5/28/2014 99 Part Number: EV NISD65ME-AS Lot Number: 304622148403 Cylinder Style Outlet: AS CGA660 Cylinder Pressure Volume: 2000 psig 140eu.fi Expiration Date: Cylinder Number: 6/9/2022 CC232070 NIST Traceable Analytical Uncertainty: 64.9 ppm SULFUR DIOXIDE Balance NITROGEN + 0.3 % Certifcuiion Information: Certification Date: 6/9/2014 Term: 96 Months This cylinder was certified according to the 2012 EPA Traceability Protocol, Document #EPA-600/R-12/531, using Procedure G1. Do Not Use this Standard if Pressure is less than 100 PSIG. Expiration Date: 6/9/2022 Analytical Data: (R-Reference Standard, Z~Zero Gas, C~Gas Candidate) 1. Component: SULFUR DIOXIDE Requested Concentration Certified Concentration instrument Used: Analytical Method: Last Multipoint Calibration: 65 ppm 64.9 ppm SIEMENS ULTRAMAT 6 NI-B3-331 NON-DISPERSIVE INFRARED 5/28/2014 First Analysis Data: Z: 0 R; 55 4 Z: 0 R: 55 6 Z: 0 C: 65 UOM; PPM Date: C: 64,5 C: 65,3 R: 55,6 Cone: Cone: Cone: Mean Test Assay; 6/2/2014 I 64.35 j 65,14 | 64.81 ! 64 78 PPM ' Analyzed by: Judith Imperial Reference Standard Type Ref Std Cylinder#: Ref, Std. Gone Ref. Std. Traceable to SRM # SRM Sample# SRM Cylinder # GMIS CC95916 55.4 PPM 1693a 9S-K-36 CAL015193 Second Analysis Data: Z: 0 1 R: 56.3 ! Z: 0 R: 56.1 Z: 0 C: 66.5 UOM: PPM Date: C: 85.3 Or 86 3 R: 56 4 Cone: Cone: Cone: Mean Test Assay: 6/9/2014 64 29 65 28 65,48 65 02 PPM Certified by: Jeff Gosner Information contained herein has been prepared at your request by qualified experts within Praxair Distribution, Inc. While we believe that the information is accurate within the limits of the analytical methods employed and is complete to the extent of the specific analyses performed, we make no warranty or representation as to the suitability of the use of the information for any purpose The information is offered with the understanding that any use of the information is at the sole discretion and risk of the user in no event shall the liability of Praxair Distribution. Inc,, arising out of the use of the information con tained herein exceed the fee established for providing such information 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00558 mPRAXAIR DocNumber: 000008731 Praxair Distribution Mid- Vthmlir One Steel Road East, Morrisville, PA 19067 Tel:(800)638-6360 Fax:{215)736-5240 PGVPID: P32014 CERTIFICATE OF ANALYSIS / EPA PROTOCOL GAS Customer & Order Information; PDI WHSE RALEIGH 2807 GRESHAM LAKE RD RALEIGH NC 276160 Praxair Order Number: 04966470 Customer P. O. Number: --None-Customer Reference Number: Certified Concentration: Fit! Date: 6/6/2014 99 Fart Nrnnhpt: EV NISD125ME-AS Lot Number: 304622157404 (ytmcJer Style N Outlet: AS CGA 660 t'ylituk-t Pn-\sun` A- Volume. 2000 psig 140 cu. ft, Expiration Date: Cylinder Number: 6/17/2022 CC3110Q0 NIST Traceable Analytical Uncertainty: 128.9 ppm SULFUR DIOXIDE Balance Ni rROGEN 0.4 % Certifcation Information: Certification Date: 6/17/2014 Term: 96 Months This cylinder was certified according to the 2012 EPA Traceability Protocol, Document #EPA-600/R-12/531, using Procedure G1, Do Not Use this Standard if Pressure is less than 100 PSIG. Expiration Date: 6/17/2022 Analytical Data: (R-Reference Standard, Z~Zero Gas, C=Gas Candidate) 1. Component: SULFUR DIOXIDE Requested Concentration Certified Concentration Instrument Used- 125 ppm 128.9 ppm SIEMENS ULTRAMAT 6 NI-B3-331 Analytical Method NON-DISPERSIVE INFRARED Last Multipoint Calibration S/28/2014 I First Analysis Data: Z: 0 R: 304 8 R: 305 4 Z: 0 Z 0 C: 129 3 UOM: PPM Date: C: 129 2 Cone: C: 129 5 Cone: R; 305 2 Cone: Mean Test Assay: 5/10/2014 128 76 129 08 128 86 128 9 PPM s ;. Analyzed by: 3 1 JudithTmperial Reference Standard Type Ref. Std Cylinder # Ref Std Cone Ref Std. Traceable to SRM # SRM Sample# SRM Cylinder# GMIS CC352685 304 1 PPM 1661A l " S Second Analysis Data: Date: S/17/2014 i Z: 0 1 R: 304 9 i Z: 0 R: 304 2 Z: 0 C: 1291 C: 129 1 Cone: C: 129 2 Cone: R: 304 8 Cone: Mean Test Assay: 128 87 128 97 128 87 128 91 PPM Certified by: Information contained herein has been prepared at your request by qualified experts within Praxair Distribution, Inc. While we believe that the information is accurate within the limits of the analytical methods employed and is complete to the extent of the specific analyses performed, we make no warranty or representation as to the suitability of the use of the information for any purpose, The information is offered with the understanding that any use of the information is at the sole discretion and risk of the user. In no event shall the liability of Praxair Distribution, Inc., arising out of the use of the information con tained herein exceed the fee established for providing such information. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00559 AZCOM Pitot tube No: RP 8-4 (ink) Pitot tube assembly level? Pitot tube openings damaged? S-TYPE PITOT TUBE INSPECTION Date: 12/23/2015 Performed By: Yes Yes (explain below) RLB No No D, ("): 3/8 Pa ("): PbC): (3/16"<Dt<3/8") Pa : 1.16 *Dt (1,05*Dt<PA B<1.5*Dt) Pb: TT7 *Dt (1.05*Dt<PAB<1.5*Dt) (PA=PB 0.063") A ("): 0.842 0.888 (<10) '(<10) 0 (<5) ' (<5) "izzzzQ"-' z = (A tan I): 0.015" (< 0.125) w = (A tan Jj: Comments: Calibration Required? ____________ Yes No Pitot tube No. RP 8-4 (ink) meets Method 2 specifications and is assigned a calibration factor of 0.84. Signature: Lance Burleson 0.029 " (< 0.03125) 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00560 5Point Console Dry Gas Meter Calibration Console ID Calibrated by Reviewed by N-55 Initials Date Initials Date RLM 12/1/15 DM 12/11/15 Expiration Date 30-Nov-2016 Orifice ID: Orifice K': Dry Gas Meter Initial Reading, (ft3) Final Reading, (ft3) Difference, (ft3) Initial Meter Temp., (F) Final Meter Temp., (F) Average Meter Temp., (F) Test Time (min.) Orifice Manometer Reading, ("H20) Barometric Pressure, ("Hg) Ambient Temperature, (F) Pump Vacuum, ("Hg) Standard Volume of the Meter, (Vmstd) Standard Volume of Critical Orifice, (Vcrstd) Flow Rate (cfm) DGM Calibration Factor, (Y) Average DGM Calibration Factor (Y) Delta H@, ("H20) Average H@, ("H20) Current Average Y All Individual Y within 2% of mean? Average Delta All individual fl-lg, within 0.20 "H20 of mean max Y Min Y Y - Hi Defl Y Lo Defl Max delta H @ Min delta H @ delta H@ hi deflection delta H@ low deflection N-ll 0.3084 Run #la 533.231 Run #lb 537.600 537.600 541.974 4.369 68 68 68.0 11 0.52 30.16 65 }. 4.374 68 68 73.0 :: 0.52 30.16 65 2; 4.408 4.465 0.401 1.013 4.371 4.465 0.397 1.021 1.017 1.776 1.760 1.768 1.019 TRUE 1.864 TRUE 1.023 1.014 0.004 0.004790702 1.921 1.768 0.057 0.096 N-16 N-19 N-23 N-30 0.4339 Run #2a Run #2b 546.340 551.925 551.925 557.506 5.585 68 69 68.5 10 1.10 30.16 65 20 5.581 69 69 69.0 10 1.10 30.16 65 20 5.637 5.711 0.564 1.013 5.628 5.711 0.563 1.015 1.014 1.920 1.919 1.920 0.5054 Run #3a Run #3b 514.590 524.839 624.839 533.231 10.249 67 67 67.0 16 1.45 30.16 65 19 8.392 67 68 67.5 13 1.45 30.16 65 19 10.383 10.644 0.649 1.025 8.494 8.648 0.653 1.018 1.022 1.874 1.873 1.874 0.6295 Run #4a Run #4b 557.506 565.576 565.576 582.397 8.070 69 69 69.0 10 2.30 30.16 66 18 16.821 69 69 69.0 21 2.30 30.16 66 18 8.162 8.278 0.816 1.014 17.012 17.384 0.810 1.022 1.018 1.921 1.921 1.921 0.8148 Run #5a Run #5b 582.501 592.768 592.768 b04.u48 10.267 64 65 64.5 10 3.65 30.17 64 16 I;l. i: 30.17 ':1 10.510 10.739 1.051 1.022 11.525 11.813 1.048 1.025 1.023 1.839 1.836 1.838 CDS-04S DM 5 point against orifice Per EM SOP-002 Revision Date; Oct 2015 0.034286 1.155 0.958536 0.041464 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00561 AECOM Pitot tube No: RP 8-4 (ink) Pitot tube assembly level? Pitot tube openings damaged? S-TYPE PITOT TUBE INSPECTION Date: 10/20/2015 Performed B\ RLM x______ Yes _______________ No Yes (explain below) _______ xNo Dt ("): PA ("): PB("): 3/8 0.45 045 iA____ 0 0.1 0 0.9 PA= 1.20 PB = 120 (3/16"<D,<3/8") *Dt (1,05*Dt<PA B<1 -5*Dt) *Dt (1.05*Ds<PAB<1.5*Dt) (PA=PB 0.063") 0.2 (<10) ~0 (<10) 1 0 (<5) 2J 0 (<5) z = (A tan I): 0.017 "(< 0.125) w = (A tan ): Comments: Calibration Required? ____________ Yes x No Pitot tube No. RP 8-4 (ink) meets Method 2 specifications and is assigned a calibration factor of 0.84. Signature: Lee Marchman 0.002 " (< 0.03125) Copy of RP 8-4 Flow spreadsheet 2015-10-15 17cv1906 Sierra Club v. EPA - 6/22 Production 12-23-15 ED 001523 00007569-00562 Orifice ID: Orifice K': Dry Gas Meter Initial Reading, (ft3) Final Reading, (ft3) Difference, (ft3) Initial Meter Temp., (F) Final MeterTemp., (F) Average MeterTemp., (F) Test Time (min.) Orifice Manometer Reading, ("H20) Barometric Pressure, ("Hg) Ambient Temperature, (F) Pump Vacuum, ("Hg) Standard Volume of the Meter, (Vmsld) Standard Volume of Critical Orifice, (Vcrstd) Flow Rate (cfm) DGM Calibration Factor, (Y) Average DGM Calibration Factor (Y) Delta H@, ("H20) Average i H@, ("H20) Current Average Y 2% Ail Individual Y within of mean? Average Delta H@ All individual! B@ within 0.20 "H20 of mean L Etoiint Console bry Gas Ivieter Calibration Console ID Calibrated bv Reviewed by N-54 initials Initials Date \ .. : Expiration Date 22-Feb-2017 N-ll 0.3084 Run frla 927.826 Run Trlb 936.182 936.182 943.909 61 64.5 23 0.51 30.59 22 7.727 68 71 69.5 16.5 0.51 30.59 70 22 ____ 7.884 9.425 0.374 1.095 6.761 0.478 0.858 0.976 1.763 1.746 1.754 N-16 N-19 N-23 N-30 0.4339 P2a Run Run #?2b 1010.656 1019.978 1019.978 1026.390 9.322 74 74 74.0 16 1.10 30.59 67 20 6.412 74 74 74.0 11 1.10 30.59 20 9.445 6.496 9.251 0.590 0.979 6.360 0.591 0.979 0.979 1.881 1.881 1.881 0.5054 PSa Run Run *f3b 52.284 60.432 60.432 67.226 8.148 74 6.794 74 74 74 74.0 74.0 12 10 1.40 1.40 30.59 67.5 19 30.59 67.5 19 ____ ____ 8.078 0.688 0.978 6.731 0.689 0.977 0.977 1.769 1.769 1.769 0.6295 PAa Run Run 4b 1035.400 : 1043.829 1052.283 8.429 74 8.454 74 74 74 74.0 74.0 10 10 2.20 2.20 30.59 67 18 30.59 67 18 ____ ____ 8.388 8.388 0.856 0.980 0.859 0.977 0.978 1.797 1.797 1.797 0.8148 PSa Run Run P5b . 973.061 973.061 988.266 29.152 71 15.205 72 72 71.5 72.5 27 14 3.70 3.70 30.59 17 30.59 67 17 _____ 15.545 29.315 1.106 0.982 15.200 1.110 0.978 0.980 1.825 1.822 1.823 0.9782 TRUE 1.805 TRUE CDS-04S DSM 5 point against orifice Per EM SOP-002 Revision Date: March 2013 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00563 rhree-Point Dry Gas Meter Calibration for Low-Flow Applications Using Critical Orifice! Console ID M30B#1 Thermometer ID RTP#1 DGM Calibration Initials Calibrated By Date RLM 2/5/2015 Initials Reviewed By Date Orifice Information DGM being Calibrated Test Conditions Calculated Values ID Number K Factor Nominal Flow Rate (l/min) Volume (1) Initial Final Tneter (F) Initial Final Meter Pressure (H2O) Pump Vacuum ("Hg) PbarC'Hg) Tambient ( F) Test Duration (minutes) Meter Volume (DGM) (1) Average DGM Temp (F) Std Volume (DGM) (dsL) Std Volume (orifice) (dsL) Flow rate (l/min) DGMCF.Y Average DGMCF, Yd Run 1 0 20.1 66 67 19 20 20.1 66.50 20.34 20.84 1.005 1.025 Run 2 2690-2 Sde A 0.7928 1.02 0 94.706 67 71 Run 3 0 16.409 71 71 19 30.2 68 93 94.706 69.00 95.37 96.90 1.018 1.016 1.018 Acceptable 19 16 16.409 71.00 16.46 16.67 1.026 1.013 Run 1 0 21.446 72 72 17 21 21.446 72.00 21.48 21.88 1.021 1.019 Acceptance Criteria: 1: Each individual Y value must be within 77 of the average Y value 2: Average Y value must be between xx and yy. Run 2 2690-2 Sde B 1.02 0 18.428 72 73 17 30.2 68 18.5 18.428 72.50 18.44 19.28 0.996 1.046 1.028 Acceptable Run 3 0 14.322 73 73 17 14 14.322 73.00 14.31 14.59 1.023 1.019 Pretest Y values Post Test YValues Side A 1.00 1.018 SideB 1.00 1.028 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00564 hree-Point Dry Gas Meter Calibration for Low-Flow Applications Using Critical Orifici Console ID M30B#2 Thermometer ID RTP#1 DGM Calibration Initials Calibrated By RLM Date 2/5/2015 Initials Reviewed By Date Run 1 Run 2 Run 3 Run 1 Orifice Information DGM being Calibrated ID Number K Factor Nominal Flow Rate (l/min) Volume (1) Initial Final Tmeter (F) Initial Final 0 32.599 66 67 2690-3 Side A 1.1601 1.49 0 130.984 67 70 0 22.436 70 71 0 32.915 71 72 Meter Pressure (H2O) Pump Vacuum ("Hg) 17 17 17 12 Test Conditions PbarC'Hg) 30.2 ^"ambient ( 62 Test Duration (minutes) 22 88 15 22 Meter Volume (DGM)(I) 32.599 130.984 22.436 32.915 Average DGM Temp (F) 66.50 68.50 70.50 71.50 Calculated Values Std Volume (DGM) (dsL) Std Volume (orifice) (dsL) Flow rate (l/min) 32.98 33.74 1.482 132.03 134.94 1.488 22.53 23.00 1.496 32.99 33.74 1.496 DGMCF.Y 1.023 1.022 1.021 1.023 Average DGMCF, Yd 1.022 Acceptable Acceptance Criteria: 1: Each individual Y value must be within 7? of the average Y value 2: Average Y value must be between xx and yy. Run 2 | 2690-3 Side B 1.1601 1.49 0 27.755 72 73 Run 3 0 19.479 71 72 12 30.2 62 18.5 27.755 72.50 27.77 28.37 1.500 1.022 1.022 Acceptable 12 13 19.479 71.50 19.52 19.93 1.498 1.021 Pretest Y values Post Test YValues % difference Side A 1.00 1.022 -2% SideB 1.00 1.022 -2% 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00565 APPENDIX D EXAMPLE CALCULATIONS 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00566 Example Calculations for Particulates Run 1 CalcinerNo. 3 6/9/2015 Gas Volume Collected. DCF VM = ( Final DGM - Initial DGM ) VM = (906.659-864.800) = 41.859 DCF Corrected Gas Volume. DCF Corrected VM = (y x VM ) Corrected VM = (1.032*41.859) = 43.198 DCF Gas Volume. DSCF Vmstd = (Corrected VM x 528 x ((Avg Delta FI/13.6) + Pbar)) / ((Avg Tm oF + 460 ) x 29.92 ) Vmstd = (43.198*528*((1.00/13.6)+29.80))/((101+460)*29.92) =40.612 DSCF Sample Gas Volume Total Vmstd = Vmstd+ ((Vwcg + Vwsg) x 0.04715) Total Vmstd = 40.612+(424.54+11.87)*0.04715 = 61.189 SCF % Moisture by Collection % H20 = ((Total Vmstd - Vmstd) / Total Vmstd ) x 100 % H20 = ((61.189-40.612)/61.189)*100 = 33.63% Vapor Pressure V.P. = S.V.P. - (0.000376 x Ps x ( Td - Tw) x (1 + (( Tw - 32 ) / 1571)) V.P. = 8.981-(0.000376*29.78*(157-157)*(1+(157-32)/1571)) =8.981 "Hg % Moisture by Vapor Pressure % FI20 = (V.P. / Ps ) *100 % H20 = (8.981/29.78)*100 = 30.16% Wet Molecular Wt of Stack Gas, Ib/lb mole Ms = ((1 - (% H20 /100 )) x Md ) + (18 x ( % H20 /100)) Ms = ((1-(30.16/100))*29.000)+(18*(30.16/100)) = 25.68 Ib/lb mole Stack Velocity, Ft/Sec vs = 85.49 x Cp x Avg SORT Delta P x (Ts oR / ( Ps x Ms ))A0.5 vs = 85.49*0.84*0.5137*(617/(29.78*25.68))A0.5 = 33.14 ft/sec Stack Flow Rate, ACFM Qaw = As x vs x 60 Qaw = 28.27*33.14*60 = 56220 ACFM Stack Flow Rate, SCFM Qsw = Qaw x ( 528 / Ts oR) x ( Ps / 29.92) Qsw = 56220*(528/617)*(29.78/29.92) = 47859 SCFM Stack Flow Rate, DSCFM QsD = (1 - ( % H20 )) x Qsw QsD = (1-(30.16/100))*47859 = 33427 DSCFM Isokinetic Sampling Rate Isokinetic Sampling Rate = (Ts oR x Vmstd x 29.92 x 100 ) / (528 x vs x Ps x Sampling Time x 60 x An x (1 - Bws )) Isokinetic Sampling Rate=(617*40.612*29.92*100)/(528*33.14*29.78*72*60*0.00046*(1-30.16%)) = 104% 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00567 Page 2 Example Calculations Continued Total PM Emission Rate Lbs./Hr Total PM Emission Rate, Lbs./Hr = (( Mg Particulate/DSCF + CPM mg/DSCF) x DSCFM x 60 /1000 / 453.59) Total PM Emission Rate, Lbs./Hr = ((0.2758+0.3122)*33427*60/1000/453.59) = 2.60 Lbs./Hr Filterable PM Emission Rate Lbs./Hr Filterable PM Emission Rate, Lbs./Hr = ( Mg Particulate/DSCF x DSCFM x 60 /1000 / 453.59) Filterable PM Emission Rate, Lbs./Hr = (0.2758*33427*60/1000/453.59) = 1.22 Lbs./Hr Condensable PM Emission Rate Lbs./Hr Condensable PM Emission Rate, Lbs./Hr = ( CPM Mg/DSCF x DSCFM x 60 /1000 / 453.59) Condensable PM Emission Rate, Lbs./Hr = (0.3122*33427*60/1000/453.59) = 1.38 Lbs./Hr CPM mg / DSCF CPM mg / DSCF = ( Mass of Organic Fraction + Mass of Inorganic Fraction ) / Gas Volume STP CPM mg / DSCF = (0.0047+0.0079)*1000/43.198 = 0.3122 mg/DSCF Average Daily PM Emission Rate Lbs./Hr. Eavg= EsS (A+B)/AR) +EN (((R-S)/R)-(BS/AR)) Eavg=((6.833*0.4028)*((0.4028+0.7972)/(0.4028*24))+2.90*(((24-0.4028)/24)-((0.7972*0.4028)/(0.4028*24))))=3.101 Lbs./Hr PM Emission Rate, qrains/dscf PM grains/dscf= ((((Eavg/60)*453590))/QsD)*0.015432) PM grains/dscf= (0.3507*7000)/453952 = 0.005 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00568 Page 3 Example Calculations Continued A= Hours of washing during test ACFM = Actual Cubic Feet per Minute An = Area of Nozzle, Ft2 As = Area of Stack, Ft2 B= Hours not washing during wash test Cp = Pitot Correction Factor CPM = Concentration of Particulate Matter corrected to Standard Conditons DCF = Dry Ft3 Delta H = Average Pressure Differential Across the Orifice Meter, in. H20 DGM = Dry Gas Meter DGV = Dry Gas Volume DSCF = Dry Standard Ft3 DSCFM = Dry Standard Ft3/Min Eavg = Average daily emission rate in Lbs/hr En= Average emissions Ib/hr of tests without wash cycle Es =Emission Rate Ib/hr for wash cycle test GVC = Gas Volume Collected Md = Dry Molecular Weight of Stack Gas-29.0 Assumed-Approved by DAQ Ms = Wet Molecular Weight of Stack Gas Nomenclature Pbar = Barometric Pressure, in. Hg Ps = Gas Pressure, in. Hg Qaw = Actual Wet Stack Gas Flow Rate, ACFM Qsd = Standard Dry Stack Gas Flow Rate, DSCFM Qsw = Standard Wet Stack Gas Flow Rate, SCFM R= Hours of operation per 24 hour period S.V.P. = Saturated Vapor Pressure S= Hours or washing per day SCF = Standard Ft3 SCFM = Standard Ft3/Min Td = Stack Temperature Dry Bulb oF Tm = Meter Temperature, F Total Vmstd = Sample Gas Volume, SCF Ts = Stack Gas Temperature, F Tw = Stack Temperature Wet Bult oF Vm = Gas Volume Collected Vmstd = Gas Volume at Standard Conditions, DSCF Vmstd = Gas Volume Collected Corrected to Standard Conditions VP = Vapor Pressure vs = Stack Gas Velocity, ft/sec Vwc = Volume of Water Collected (impingers), gm Vwsg = Water Collected in Silica Gel, gm y = Dry Gas Meter Correction Factor 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00569 Example Calculations for Particulates Run 1 CalcinerNo. 3 6/9/2015 Gas Volume Collected. DCF VM = ( Final DGM - Initial DGM ) VM = (906.659-864.800) = 41.859 DCF 41.859 Corrected Gas Volume. DCF Corrected VM = (y x VM ) Corrected VM = (1.032*41.859) = 43.198 DCF 43.19849 Gas Volume. DSCF Vmstd = (Corrected VM x 528 x ((Avg Delta FI/13.6) + Pbar)) / ((Avg Tm oF + 460 ) x 29.92 ) Vmstd = (43.198*528*((1.00/13.6)+29.80))/((101 +460)*29.92) =40.612 DSCF 40.59379 Sample Gas Volume Total Vmstd = Vmstd+ ((Vwcg + Vwsg) x 0.04715) Total Vmstd = 40.612+(424.54+11.87)*0.04715 = 61.189 SCF 61.18873 % Moisture by Collection % H20 = ((Total Vmstd - Vmstd) / Total Vmstd ) x 100 % H20 = ((61.189-40.612)/61.189)*100 = 33.63% 33.62859 Vapor Pressure V.P. = S.V.P. - (0.000376 x Ps x ( Td - Tw) x (1 + (( Tw - 32 ) / 1571)) V.P. = 8.981-(0.000376*29.78*(157-157)*(1+(157-32)/1571)) =8.981 "Hg 8.981 % Moisture by Vapor Pressure % FI20 = (V.P. / Ps ) *100 % H20 = (8.981/29.78)*100 = 30.16% 30.15782 Wet Molecular Wt of Stack Gas, Ib/lb mole Ms = ((1 - (% H20 /100 )) x Md ) + (18 x ( % H20 /100)) Ms = ((1-(30.16/100))*29.000)+(18*(30.16/100)) = 25.68 Ib/lb mole 25.6824 Stack Velocity, Ft/Sec vs = 85.49 x Cp x Avg SORT Delta P x (Ts oR / ( Ps x Ms ))A0.5 vs = 85.49*0.84*0.5137*(617/(29.78*25.68))A0.5 = 33.14 ft/sec 33.13499 Stack Flow Rate, ACFM Qaw = As x vs x 60 Qaw = 28.27*33.14*60 = 56220 ACFM 56212.07 Stack Flow Rate, SCFM Qsw = Qaw x ( 528 / Ts oR) x ( Ps / 29.92) Qsw = 56220*(528/617)*(29.78/29.92) = 47859 SCFM 47885.35 Stack Flow Rate, DSCFM QsD = (1 - ( % H20 )) x Qsw QsD = (1-(30.16/100))*47859 = 33427 DSCFM 33424.73 Isokinetic Sampling Rate Isokinetic Sampling Rate = (Ts oR x Vmstd x 29.92 x 100 ) / (528 x vs x Ps x Sampling Time x 60 x An x (1 - Bws ))=98.27 Isokinetic Sampling Rate=(617*40.612*29.92*100)/(528*33.14*29.78*72*60*0.00046*(1-30.16%)) = 104% 103.66788 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00570 Page 2 Example Calculations Continued Total PM Emission Rate Lbs./Hr Total PM Emission Rate, Lbs./Hr = (( Mg Particulate/DSCF + CPM mg/DSCF) x DSCFM x 60 /1000 / 453.59) Total PM Emission Rate, Lbs./Hr = ((0.2758+0.3122)*33427*60/1000/453.59) = 2.60 Lbs./Hr 2.599935 Filterable PM Emission Rate Lbs./Hr Filterable PM Emission Rate, Lbs./Hr = ( Mg Particulate/DSCF x DSCFM x 60 /1000 / 453.59) Filterable PM Emission Rate, Lbs./Hr = (0.3122*33427*60/1000/453.59) = 1.38 Lbs./Hr 1.380442 Condensable PM Emission Rate Lbs./Hr Condensable PM Emission Rate, Lbs./Hr = ( CPM Mg/DSCF x DSCFM x 60 /1000 / 453.59) Condensable PM Emission Rate, Lbs./Hr = (0.3122*33427*60/1000/453.59) = 1.38 Lbs./Hr 1.380442 CPM mg / DSCF CPM mg / DSCF = ( Mass of Organic Fraction + Mass of Inorganic Fraction ) / Gas Volume STP CPM mg / DSCF = (0.0047+0.0079)*1000/43.198 = 0.3122 mg/DSCF 0.29168 Average Daily PM Emission Rate Lbs./Hr. Eavg= EsS (A+B)/AR) +EN (((R-S)/R)-(BS/AR)) Eavg=((6.833*0.4028)*((0.4028+0.7972)/(0.4028*24))+2.90*(((24-0.4028)/24)-((0.7972*0.4028)/(0.4028*24))))=3.101 Lbs./Hr 3.09665 PM Emission Rate, qrains/dscf PM grains/dscf= ((((Eavg/60)*453590))/QsD)*0.015432) PM grains/dscf= (0.3507*7000)/453952 = 0.005 0.005408 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00571 Page 3 Example Calculations Continued A= Hours of washing during test ACFM = Actual Cubic Feet per Minute An = Area of Nozzle, Ft2 As = Area of Stack, Ft2 B= Hours not washing during wash test Cp = Pitot Correction Factor CPM = Concentration of Particulate Matter corrected to Standard Conditons DCF = Dry Ft3 Delta H = Average Pressure Differential Across the Orifice Meter, in. H20 DGM = Dry Gas Meter DGV = Dry Gas Volume DSCF = Dry Standard Ft3 DSCFM = Dry Standard Ft3/Min Eavg = Average daily emission rate in Lbs/hr En= Average emissions Ib/hr of tests without wash cycle Es =Emission Rate Ib/hr for wash cycle test GVC = Gas Volume Collected Md = Dry Molecular Weight of Stack Gas-29.0 Assumed-Approved by DAQ Ms = Wet Molecular Weight of Stack Gas Nomenclature Pbar = Barometric Pressure, in. Hg Ps = Gas Pressure, in. Hg Qaw = Actual Wet Stack Gas Flow Rate, ACFM Qsd = Standard Dry Stack Gas Flow Rate, DSCFM Qsw = Standard Wet Stack Gas Flow Rate, SCFM R= Hours of operation per 24 hour period S.V.P. = Saturated Vapor Pressure S= Hours or washing per day SCF = Standard Ft3 SCFM = Standard Ft3/Min Td = Stack Temperature Dry Bulb oF Tm = Meter Temperature, F Total Vmstd = Sample Gas Volume, SCF Ts = Stack Gas Temperature, F Tw = Stack Temperature Wet Bult oF Vm = Gas Volume Collected Vmstd = Gas Volume at Standard Conditions, DSCF Vmstd = Gas Volume Collected Corrected to Standard Conditions VP = Vapor Pressure vs = Stack Gas Velocity, ft/sec Vwc = Volume of Water Collected (impingers), gm Vwsg = Water Collected in Silica Gel, gm y = Dry Gas Meter Correction Factor 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00572 Example Calculations for Particulates Run 1 CalcinerNo. 3 6/9/2015 Gas Volume Collected. DCF VM = ( Final DGM - Initial DGM ) VM = (460.144-416.000) = 44.144 DCF 44.144 Corrected Gas Volume. DCF Corrected VM = (y x VM ) Corrected VM = (0.976*44.144) = 43.085 DCF 43.08454 Gas Volume. DSCF Vmstd = (Corrected VM x 528 x ((Avg Delta FI/13.6) + Pbar)) / ((Avg Tm oF + 460 ) x 29.92 ) Vmstd = (43.085*528*((1.17/13.6)+30.13))/((75+460)*29.92) = 42.931 DSCF 42.94198 Sample Gas Volume Total Vmstd = Vmstd+ ((Vwcg + Vwsg) x 0.04715) Total Vmstd = 42.931+(286.61+11.24)*0.04715 = 56.975 SCF 56.97463 % Moisture by Collection % H20 = ((Total Vmstd - Vmstd) / Total Vmstd ) x 100 % H20 = ((56.975-42.931 )/56.975)*100 = 24.65% 24.64941 Vapor Pressure V.P. = S.V.P. - (0.000376 x Ps x ( Td - Tw) x (1 + (( Tw - 32 ) / 1571)) V.P. = 7.202-(0.000376*30.11 *(148-148)*(1+(148-32)/1571)) = 7.202 "Hg 7.202 % Moisture by Vapor Pressure % FI20 = (V.P. / Ps ) *100 % H20 = (7.202/30.11)*100 = 23.92% 23.91896 Wet Molecular Wt of Stack Gas, Ib/lb mole Ms = ((1 - (% H20 /100 )) x Md ) + (18 x ( % H20 /100)) Ms = ((1-(23.92/100))*29.000)+(18*(23.92/100)) = 26.37 Ib/lb mole 26.3688 Stack Velocity, Ft/Sec vs = 85.49 x Cp x Avg SORT Delta P x (Ts oR / ( Ps x Ms ))A0.5 vs = 85.49*0.84*0.5309*(612/(30.11*26.37))A0.5 = 33.37 ft/sec 33.4713 Stack Flow Rate, ACFM Qaw = As x vs x 60 Qaw = 28.27*33.37*60 = 56615 ACFM 56602.19 Stack Flow Rate, SCFM Qsw = Qaw x ( 528 / Ts oR) x ( Ps / 29.92) Qsw = 56615*(528/608)*(30.11/29.92) = 49450 SCFM 49477.87 Stack Flow Rate, DSCFM QsD = (1 - ( % H20 )) x Qsw QsD = (1-(23.92/100))*49450 = 37620 DSCFM 37621.56 Isokinetic Sampling Rate Isokinetic Sampling Rate = (Ts oR x Vmstd x 29.92 x 100 ) / (528 x vs x Ps x Sampling Time x 60 x An x (1 - Bws ))=98.27 Isokinetic Sampling Rate=(608*42.931 *29.92*100)/(528*33.37*30.11*72*60*0.00044*(1-23.92%)) = 102% 101.79545 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00573 Page 2 Example Calculations Continued Total PM Emission Rate Lbs./Hr Total PM Emission Rate, Lbs./Hr = (( Mg Particulate/DSCF + CPM mg/DSCF) x DSCFM x 60 /1000 / 453.59) Total PM Emission Rate, Lbs./Hr = ((0.1561 +0.1025)*37620*60/1000/453.59) = 1.29 Lbs./Hr 1.286871 Filterable PM Emission Rate Lbs./Hr Filterable PM Emission Rate, Lbs./Hr = ( Mg Particulate/DSCF x DSCFM x 60 /1000 / 453.59) Filterable PM Emission Rate, Lbs./Hr = (0.1561*37620*60/1000/453.59) = 0.78 Lbs./Hr 0.7768 Condensable PM Emission Rate Lbs./Hr Condensable PM Emission Rate, Lbs./Hr = ( CPM Mg/DSCF x DSCFM x 60 /1000 / 453.59) Condensable PM Emission Rate, Lbs./Hr = (0.1025*37620*60/1000/453.59) = 0.51 Lbs./Hr 0.510071 CPM mg / DSCF CPM mg / DSCF = ( Mass of Organic Fraction + Mass of Inorganic Fraction ) / Gas Volume STP CPM mg / DSCF = (0.0028+0.0016)*1000/42.931 = 0.1025 mg/DSCF 0.10249 Average Daily PM Emission Rate Lbs./Hr. Eavg= EsS (A+B)/AR) +EN (((R-S)/R)-(BS/AR)) Eavg=((11.050*0.6500)*((0.6500+0.0833)/(0.6500*24))+1,39*(((24-0.6500)/24)-((0.0833*0.6500)/(0.6500*24))))=1,69Lbs./Hr 1.685153 PM Emission Rate, qrains/dscf PM grains/dscf= ((((Eavg/60)*453590))/QsD)*0.015432) PM grains/dscf= (0.6989*7000)/453952 = 0.01 0.010777 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00574 Page 3 Example Calculations Continued A= Hours of washing during test ACFM = Actual Cubic Feet per Minute An = Area of Nozzle, Ft2 As = Area of Stack, Ft2 B= Hours not washing during wash test Cp = Pitot Correction Factor CPM = Concentration of Particulate Matter corrected to Standard Conditons DCF = Dry Ft3 Delta H = Average Pressure Differential Across the Orifice Meter, in. H20 DGM = Dry Gas Meter DGV = Dry Gas Volume DSCF = Dry Standard Ft3 DSCFM = Dry Standard Ft3/Min Eavg = Average daily emission rate in Lbs/hr En= Average emissions Ib/hr of tests without wash cycle Es =Emission Rate Ib/hr for wash cycle test GVC = Gas Volume Collected Md = Dry Molecular Weight of Stack Gas-29.0 Assumed-Approved by DAQ Ms = Wet Molecular Weight of Stack Gas Nomenclature Pbar = Barometric Pressure, in. Hg Ps = Gas Pressure, in. Hg Qaw = Actual Wet Stack Gas Flow Rate, ACFM Qsd = Standard Dry Stack Gas Flow Rate, DSCFM Qsw = Standard Wet Stack Gas Flow Rate, SCFM R= Hours of operation per 24 hour period S.V.P. = Saturated Vapor Pressure S= Hours or washing per day SCF = Standard Ft3 SCFM = Standard Ft3/Min Td = Stack Temperature Dry Bulb oF Tm = Meter Temperature, F Total Vmstd = Sample Gas Volume, SCF Ts = Stack Gas Temperature, F Tw = Stack Temperature Wet Bult oF Vm = Gas Volume Collected Vmstd = Gas Volume at Standard Conditions, DSCF Vmstd = Gas Volume Collected Corrected to Standard Conditions VP = Vapor Pressure vs = Stack Gas Velocity, ft/sec Vwc = Volume of Water Collected (impingers), gm Vwsg = Water Collected in Silica Gel, gm y = Dry Gas Meter Correction Factor 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00575 Example Calculations. Based on Run #1 Barometric Pressure at the Sampling Location, Corrected (EPA Method 2, Section 6.5) Pbar= Pbarraa* -(EleV X 0.1/100) Pbar maas = Barometric pressure as measured E!ev = elevation of sampling location relative to barometer Pbar = Barometric pressure at the sampling site 30.09 100 29.99 in. Hg feet in. Hg Pbar= 30.09 100 x 0.1 100 Pbar = 29.99 Absolute Stack Pressure (EPA Method 2, Section 6.5) Pbar = Barometric pressure at the sampling site Pg = Stack Static Pressure Ps = Absolute Stack Pressure 29.99 -0.24 29.97 n. Hg n. Hg n. Hg P5 = 29.99 ) -0.24 13.6 ps = 29.97 Volume of Water Vapor Condensed, corrected to standard conditions, ft3 (US EPA Method 4, Sect. 12.1.2 and 12.1.3) Vw(sidl= K3 x (Wf-W,) K3 = Conversion Constant (Wf - W,) = Total weight of liquid collected ftJ/g Vw(sid)= 0.04715 x V,,|,,a,= 15.90 ft3 337.3 Moisture Content, proportion, by volume (US EPA Method 5, Eq. 5-3) Vwfsttl Vm(std) + Vv(std) Vw(s,d) = Volume of water vapor condensed = Vm(std) = Dry Gas Volume = 15.904 ft3 43.216 ft3 B _15.904 ** 43.216 + 15.904 Bws = 0.2690 Moisture content at saturation: B,ss (sat) = 23.442 0.23441603 For further calculations: Bws = 0.234 From ASME1967 Steam Tables (Lookup Table) Dry Molecular Weight of Stack Gas, ib/ib-moie (US EPA Method 3, Eq. 3-1) Md = MWC02(%C02) + MW02(%O2) + MWn2(%N2) MWc02= Molecular weight of C02, divided by 100 %C02 = Percent C02 by volume, dry basis MW02 = Molecular weight of 02> divided by 100 %02 = Percent C^ by volume, dry basis MWn2 = Molecular weight of N2, divided by 100 %N2 = 100% - %CO - %C02 - %02 - %H2 - %CH4 Md =( 0.44 7.9 ) + ( 0.32 Md = 29.80 ib/ib-moie 0,44 ib/ib-moie % 7.9 0,32 ib/ib-moie % 13.5 0,28 ib/ib-moie % 78.6 13.5 0.28 78.6 ) Calcmer#6 M5_202_v2 17cv1906 Sierra Club v. EPA 6/22 Production Example Calculations ED 001523 00007569-00576 Molecular Weight of stack gas, ib/ib-moie (US EPA Method 2, Eq. 2-6) Ms = Md (t-Bws)+18.0(Bws) Md= Dry molecular weight of stack gas Bws= Proportion of water vapor, by volume 18.0 = Molecular Weight of H20 29.80 0,2344 18.00 Ib/ib-moie proportion ib/ib-moie Ms = 29.80 x { 1 Ms = 27.04 - 0.234 ) + { 18.00 x 0.234 ) Dry Gas Volume, corrected to standard conditions, ft3 (US EPA Method 5, Eq. 5-1) Vm x y r m Tstd x (Pbar + (deitaH / 13.6)) Tm xPstd Vm = Volume of gas sample, dry Y = Dry gas meter calibration factor Tstd = Standard Temperature Pbar = Barometric pressure at the sampling site DH = Average pressure differential across the orifice meter 13.6 = Conversion factor Tm = Absolute average DGM temperature 41,374 0,9943 528.0 29.99 1.12 13.6 505.2 ft3 deg R in. Hg in. H20 in. H20/in. Hg deg R V^d) = 41.374 0.9943 528.0 x ( 29.99 1.12 V^std, = 43.216 505.2 x 29.92 13.6 )) Average Stack Gas Velocity, ft/sec (US EPA Method 2, Eq. 2-7) vs = Kp x Cp x SqrtDPavg x sqrt(Ts/(Ps x M,)) Kp= Velocity equation constant Cp = S type pitot tube coefficient SqrtDPavg=ave. sqrt. of the velocity head of stack gas Ts = Absolute stack temperature Ps = Absolute stack pressure Ms = Molecular Weight of stack gas 85.49 0,84 0,57 607.29 29.97 27.04 ft/sec[{(lb/lb-mole)(in.Hg))/({degR)(in.H20))3 in.H20 deg R in. Hg ib/ib-moie vs = 85.49 0.84 0.57 29.97 607.3 x 27.04 vs = vs = 35.42 ft/sec 2,125 ft/min Average Stack Gas Volumetric Flow Rate, Actual Conditions Q, vs = Average stack gas velocity = A = Cross sectional area of stack = ft/sec ft2 Q 35.42 x 28.27 Q 1001 cubic feet per second q 60,089 cubic feet per minute Q 3,605,335 cubic feet per hour Calcmer#6 M5_202_v2 17cv1906 Sierra Club v. EPA - 6/22 Production Example Calculations ED 001523 00007569-00577 Average Stack Gas Dry Volumetric Flow Rate, dscf/hr { US EPA Method 2, Eq. 2-8) Q = 3600 x (t-Bws) x vs x A x Tsld x Ps Ts x Pad 3600= Conversion factor Bws = Proportion of water vapor, by volume vs= Average stack gas velocity A = Cross sectional area of stack Tstd = Standard absolute temperature Ps = Absolute stack pressure Ts = Absolute stack temperature Pstd = Standard absolute pressure 3600 0.234 35.42 28.27 528 29.97 607.3 29.92 sec/hr proportion ft/sec ft2 degR in. Hg degR in. Hg Qs 3600 x ( 1.00 - 0.234 ) x 35.42 x 28.274 607.3 x 29.92 Q, 2,403,999 dscf/hr 40,067 dscf/min 528 x 29.97 Average Stack Gas Wet Basis Volumetric Flow Rate (scf/hr) Qw = Q (1-Bws) Q = Average Stack Gas Dry Volumetric Flow Rate Bws = Proportion of water vapor, by volume 2,403,999 dscf/hr 0.234 proportion Qw 2,403,999 1.00 - 0.234 ) Qw 3,140,086 wscf/hr 52,335 wscf/min isokinetic Variation, % (US EPA Method 5, Eq. 5-8) 100 x Ts x Vm(std| x Pad 60 x Tstd x Ps x vs x An x min x (1 - B.s) 100 = Conversion to Percent Ts = Absolute stack temperature 5Vm( td) = Dry Gas Volume Pstd = Standard absolute pressure 60 = Sec/Min Tstd = Standard absolute temperature Ps = Absolute stack pressure vs = Average stack gas velocity An = Cross-sectional Area of nozzle min = Total sampling time Bws = Proportion of water vapor, by volume 100 607.3 degR 43.216 ft3 29.92 in. Hg 60 Sec/Min 528.00 degR 29.97 in. Hg 35.42 ft/sec 0,000417 ft2 72 0.234 minutes proportion I 100 x 607.3 x 43.216 x 29.92 60.00 528.00 x 29.97 x 35.42 x 0.000417 72 I 101.46 Yqa = min / Vm Post-Test Calibration Check (US EPA Guideline Document EMTIC GD-26) ________ 0.0319 xTm DH@ x (Pbar + DH/13.6) 29 <DH)i;2avg Md min = Total sampling time Vm(actuau = Dry gas volume, actual conditions Tm = Absolute average DGM temperature DH@ = Meter orifice pressure at 0.75 ft3/min sampling rate Pbar = Barometric pressure at the sampling site DH = Average pressure differential across the orifice meter (DH)1,2avg = Average of square root values of DH Md= Dry molecular weight of stack gas 72 41.374 505.2 1.80 29.99 1.12 1.053 29.80 minutes ft3 degR in. H20 in. Hg in. H20 ib/ib-moie Yqa = min / Vm Yqa = 0.987 0.0319 x 505.167 1.80 x (29.99 -f- 1.12/13.6) 29 29.80 1.053 0.234 ) Calcmer#6 M5_202_v2 17cv1906 Sierra Club v. EPA - 6/22 Production Example Calculations ED 001523 00007569-00578 APPENDIX E ANALYTICAL LABORATORY DATA 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00579 AZCOM QC Summary Project Name AECOM Project # PCS -30B 60402248.10 Slope: Intercept: . i R2: i.uuu MDL (ng) DCS (ng) DL (ng) Temp, Profile 9.97 # 3 Air Flow 12.19 (l/min) 4 9.97 Lumex Hg Calibration Spike 2000 ' Sampling Analysis Date Date Sample ID Trap # Facility ID Unit/Stack # Sample # Fraction Known ng Peak Area ng % Recovery Trap Total ng % Breakthrough Sample Hg Cone Average Hg Crec Spike Pair %D Volume (pg/dsem) Cone Recovery % (Std L) (pg'dscm) 100.00 000.00 000.00 1000.00 000.00 42,160 85,250 167,500 331,400 504,700 502.0 1016.6 1998.9 3956.4 6026.0 2/11/2016 2/12/2016 PCS 2/11/2016 2/12/2016 Analyst: Reviewer: Nicole Lancaster Reviewed by: Bob Jongieux Sect Sect Sect Sect Sect Sect Sect Sect:' Section 1 Section 2 2000.00 389,400 27,590 193,500 28,200 412,900 1,056 196,200 0 393,400 730 164,300 4942.2 2341.7 Date 2/12/16 @2010 Calciner _1 30B_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Analytical Sheet ED 001523 00007569-00580 AECOM QC Summary Project Name AECOM Project # PCS-30B 60402248.10 7000.00 6000.00 5000.00 4000.00 3000.00 2000.00 1000.00 0.00 +00 Slope: Intercept: R2: y=0.012x-19.398 R2 = 0.999 MDL (ng) DCS (ng) DL (ng) Temp. Profile 9.97 # 3 Air Flow T'min) 4 -----r~ 4------------------------------ 1.0E+05 2.0E+05 3.0E+05 - UJJiA- .. - + 4.0E+05 5.0E+05 Spike 2000 6.0E Sampling Analysis Date Date 2/13/2016 2/15/2016 Facility ID Sample ID Unit/Stack 4 Sample # 50Qng re] lOOOng 2000ng 40Q0ng 6000ng Trap# Fraction Known ng Peak Area ng % Recovery Trap Total ng % Breakthrough 500.00 1000.00 2000.00 4000.00 6000.00 45.390 86,790 179,600 336,100 521,300 505.0 987.2 2068.3 3891.2 6048.3 101.094 98.7% 103.491 97.3% 100.894 Sample Hg Cone Average Hg Crec Spike Pair %D Volume (pg'dscm) Cone Recovery % (StdL) (|ig''dscm) 2/13/2016 2/15/2016 2/13/2016 2/15/2016 425,200 111 2/13/2016 2/15/2016 PCS PCS Analyst: Reviewer: Calciner #2 Calciner #2 - Stack 3 A Stack 3B OL30474 ' OL32102 %viioi; 1 Nicole Lancaster Stephanie Chesebro ........... 418,500 164 228,600 374 174,300 485 1. 2631' 11 4. 200 Date 2/15/2016 Date 2/16/2016 4852.8 2643.1 0.0% 0.2% 51.62 52.72 55.26 50.14 43.91 Calciner #2_30B Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Analytical Sheet ED 001523 00007569-00581 AECOM QC Summary Project Name PCS - 30B AECOM Project#_______ 60402248.10 Slope: 1.101.-02 Intercept: R2: 12.16 MDL (ng) DCS (ng) DL (ng) Temp. Profile 9.97 Air Flow (1/min) 4 mse Factor Spike 2000 Analyst: Nicole Lancaster Date Reviewer: Bob Jongleux Date Ca!ciner_3 30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Analytical Sheet ED 001523 00007569-00582 AECOM QC Summary Project Name AECOM Project # PCS - 30B 60402248.10 Slope: : Intercept: . R2: MDL (ng) DCS (ng) DL (ng) Temp. Profile 9.97 # 3 Air Flow 12.19 (1/min) 4 9.97 ..LumexJHg Calibration Spike Sampling Date 2/10/2016 2/11/2016 Facility ID Sample ID Trap # Fraction Known ng Peak Area ng % Recovery Sample # 500ng rei lOQOng 2000ng 4000ng 6000ng 500.00 1000.00 2000.00 4000.00 6000.00 42,340 84,520 160.000 354,000 506,800 521.5 1012.3 1890.8 4148.6 5926.9 104.3% 101.2% `M.5% 103.7% 98.8% % Breakthrough Sample Volume (Std L) Hg Cone (|ig''dscm) Average Hg Cone (|ig''dscm) Spike Recover,' % 2/10/2016 2/11/2016 PCS Calciner #4 - Stack 1A OL32848 i 365,600 428 523 6. PCS Calciner #4 - Stack IB OL30470 212,900 250 520 6. .6 2/10/2016 2/11/2016 PCS Calciner #4 - Stack 2A OL32830 341,900 400 319 .5 PCS Calciner #4 - Stack 2B OL32104 179,600 211 0 0. .9 rev ............ 170,500 201 Z/iU/ZUib Z/l 1/ZUib FCS calciner S4 - StaCK JA ULZU4bC i Vviioil 1 357,000 418 62 0. 2 PCS Calciner #4 - Stack 3B OL3211C 179,100 211 0 0. > Analyst: Reviewer: Nicole Lancaster Stephanie Chesebro Date 2/11/2016 Date 2/12/2016 0.2% 0.1% 0.0% 0.0% 0.0% 47.39 45.49 45.61 53.02 44.22 46.46 45.65 45.54 47.85 46.40 49.45 45.34 32.94 41.65 82.20 94.73 Calciner #4_updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Analytical Sheet ED 001523 00007569-00583 ACCOM QC Summary Project Name PCS - 30B AECOM Project #______ 60402248.10 Slope: 1.161.-02 Intercept: . . R2: MDL (ng) DCS (ng) DL (ng) Temp. Profile 25.92 Air Flow 11.89 (L'min) 4 Sampling Analysis Date Date 2/8/2016 2/11/2016 Facility ID Sample ID Unit/Stack # Sample # SOOngrel lOOOng 2000ng 4000ng 6000ng Trap# Fraction Known ng Peak Area ng % Recovery Trap Total ng % Breakthrough 500.00 1000.00 2000.00 4000.00 6000.00 42,340 84,520 160,000 354,000 506,800 521.5 1012.3 1890.8 4148.6 5926.9 104.314 101.214 94.5% 103.714 98.8% Sample Hg Cone Average Hg Crec Spike Volume (pg/dsem) Cone Recovery % (Std L) (gg/dsem) 2/8/2016 2/11/2016 2/8/2016 2/11/2016 2/8/2016 2/11/2016 Analyst: Reviewer: Nicole Lancaster Stephanie Chesebro Section : Section Section : Section Section Section Section Section Section Section Section ; Section 385,700 18,520 216,700 11 361,500 17.200 208,200 2,407 357,800 2,932 194,600 12,900 Date 2/11/2016 Date 2/12/2016 48.09 51.57 47.24 46.51 47.15 52.59 Calciner _5 30B _Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Analytical Sheet ED 001523 00007569-00584 AECOM QC Summary Project Name PCS - SOB AECOM Project #______ 60402248.10 Slope: i.! ;l.-02 Intercept: R7: 35.69 MDL (ng) DCS (ng) DL (ng) Temp. Profile 11.52 # 3 Air Flow T'min) 4 Spike 2200 Sampling Date Sample ID Facility ID Trap # Sample 5Q0ng reJ lOOOng 2000ng 4000ng 6000ng Fraction Known ng Peak Area ng % Recovery Trap Total ng % Breakthrough 500.00 1000.00 2000.00 4000.00 6000.00 45.990 90,780 178,800 346.400 526.400 493.7 1009.2 2022.3 3951.5 6023.3 98.7% 100.9% 101.1% 98.8% 100.4% Sample Hg Cone Averaae Ha Crec Spike Pair %D Volume (ua'dscm) Cone Recovery % (Std L) (pg'dscm) 2/19/2016 2/19/2016 PCS PCS 2/19/2016 2/19/2016 PCS PCS 2/19/2016 2/19/2016 PCS PCS Analyst: Calciner #6 - Stack 1A OL211412 Calciner #6 - Stack IB OL232760 Calciner #6 - Stack 2A OL211407 Calciner #6 Calciner #6 - s Cl V Slack 5 \ OL232890 Calciner #6 - S :v Nicole Lancaster Stephanie Chesebro Section : Section Section : Section Section Section 2 Section 2 Section 1 464,523 94 255,500 0 430,900 7,318 250,900 0 172.400 459,700 5.032 256,800 173 171.800 532: ; l." 290 . 0." 492 i . 79 " 285.' 0." 525 " 54 292" ' 1." 194 Date 2/29/2016 Date 2/20/2016 2905.2 5003.6 2852.2 5310.3 0.0% 0.0%, 1.6% 0.0%, 1.0% 0.1% 50.47 52.01 61.66 56.95 59.31 48.28 110.76 3.97 50.18 55.87 56.28 41.63 94.96 0.55 50.49 56.50 51.17 60.78 58.71 46.22 3.54 52.60 56.63 Average 404.3 2.69 Calciner #6_30B_Updated BP.xls 17cv1906 Sierra Club v. EPA - 6/22 Production Analytical Sheet ED 001523 00007569-00585 A Waters Company February 18, 2016 Stephanie Chesebro AECOM 900 Perimeter Park Dr. Morrisviile, NC 27560 Enclosed is your final report for ERA'S Stationary Source Audit Sample (SSAS) Program. Your final report includes an evaluation of all results submitted by your laboratory to ERA. Data Evaluation Protocols: All analytes in ERA'S SSAS Program have been evaluated comparing the reported result to the acceptance limits generated using the criteria contained in the TNI SSAS Table. For any "Not Acceptable" results, please contact your state regulator for any corrective action requirements. Thank you for your participation in ERA'S SSAS Program. If you have any questions, please contact our Proficiency Testing Departmental 1-800-372-0122. Sincerely, Patrick Larson Quality Officer cc: Project File Number 011216A 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com Project # : 011216A 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00586 A Waters Company Recipient Type Report Recipient Agency NC-Division of Air Quality Raleigh (SSAS) Facility 1641 Mail Service Center Raleigh, NC 27699 USA PCS Phosphate 1530 NC Hwy 306 S Aurora, NC 27806 USA Lab PCS Phosphate Tester 1530 NC Hwy 306 S Aurora, NC 27806 USA AECOM 900 Perimeter Park Dr. Morrisville, NC 27560 USA Contact Gregg O'Neal III, P.E. gregg.oneal@ncdenr.gov Phone: 919-707-8415 Brad Lee blee@pcsphosphate.com Phone: 252-322-8270 Brad Lee blee@pcsphosphate.com Phone: 252-322-8270 Stephanie Chesebro Stephanie.Chesebro@URS.com Phone: 919-461-1539 Project ID 60402248.09 ISG/iEC 17043.2010 17cv1906 Sierra Club v. EPA 6/22 Production Project#: 011216A ED 001523 00007569-00587 A Waters Company 011216A Laboratory Exception Report Brad Lee PCS Phosphate 1530 NC Hwy 306 S Aurora, NC 27806 252-322-8270 EPA ID: ERA Customer Number: Evaluation Checks There are no values reported with < where the assigned value was greater than 0. Not Acceptable Evaluations There were no Not Acceptable evaluations for this study. Not Reported T217202 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production Page 1 of 1 /jjjN Project#: 011216A \0/ ED 001523 00007569-00588 A Waters Company Final Report Results For Laboratory PCS Phosphate 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production Page 1 of 3 /jffjpX Project# : 011216A MlSM ED 001523 00007569-00589 A Waters Company SSAP Evaluation Report Project Number: 011216A ERA Customer Number: T217202 Laboratory Name: PCS Phosphate Inorganic Results 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production Page 2 of 3 /jffjpX Project# : 011216A MlSM ED 001523 00007569-00590 A Waters Company 011216A Evaluation Final Complete Report Brad Lee PCS Phosphate 1530 NC Hwy 306 S Aurora, NC 27806 252-322-8270 EPA ID: ERA Customer Number: TNI Analyte Code Analyte Units Reported Value Assigned Value Acceptance Limits Performance Evaluation Method Description Analysis Date SSAP Fluoride in Impinger Solution (cat# 1441, lot# 011216A) Study Dates: 01/12/16- 02/18/16 1730 Fluoride mg/dscm 0.961 1.00 0.850-1.15 Acceptable EPA 13B 2000 2/16/2016 Analyst Name Not Reported T217202 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production Page 3 of 3 /jffjpX Project# : 011216A MlSM ED 001523 00007569-00591 A Waters Company February 18, 2016 Stephanie Chesebro AECOM 900 Perimeter Park Dr. Morrisviile, NC 27560 Enclosed is your final report for ERA'S Stationary Source Audit Sample (SSAS) Program. Your final report includes an evaluation of all results submitted by your laboratory to ERA. Data Evaluation Protocols: All analytes in ERA'S SSAS Program have been evaluated comparing the reported result to the acceptance limits generated using the criteria contained in the TNI SSAS Table. For any "Not Acceptable" results, please contact your state regulator for any corrective action requirements. Thank you for your participation in ERA'S SSAS Program. If you have any questions, please contact our Proficiency Testing Departmental 1-800-372-0122. Sincerely, Patrick Larson Quality Officer cc: Project File Number 011216B 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com Project # : 011216B 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00592 A Waters Company Recipient Type Report Recipient Agency NC-Division of Air Quality Raleigh (SSAS) Facility 1641 Mail Service Center Raleigh, NC 27699 USA PCS Phosphate 1530 NC Hwy 306 S Aurora, NC 27806 USA Lab PCS Phosphate Tester 1530 NC Hwy 306 S Aurora, NC 27806 USA AECOM 900 Perimeter Park Dr. Morrisville, NC 27560 USA Contact Gregg O'Neal III, P.E. gregg.oneal@ncdenr.gov Phone: 919-707-8415 Brad Lee blee@pcsphosphate.com Phone: 252-322-8270 Brad Lee blee@pcsphosphate.com Phone: 252-322-8270 Stephanie Chesebro Stephanie.Chesebro@URS.com Phone: 919-461-1539 Project ID 60402248.09 ISG/iEC 17043.2010 17cv1906 Sierra Club v. EPA 6/22 Production Project#: 011216B ED 001523 00007569-00593 A Waters Company 011216B Laboratory Exception Report Brad Lee PCS Phosphate 1530 NC Hwy 306 S Aurora, NC 27806 252-322-8270 EPA ID: ERA Customer Number: Evaluation Checks There are no values reported with < where the assigned value was greater than 0. Not Acceptable Evaluations There were no Not Acceptable evaluations for this study. Not Reported T217202 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production Page 1 of 1 /jjjN Project#: 011216B \0/ ED 001523 00007569-00594 A Waters Company Final Report Results For Laboratory PCS Phosphate 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production Page 1 of 3 /SfN Project# : 011216B MlSM ED 001523 00007569-00595 A Waters Company SSAP Evaluation Report Project Number: 011216B ERA Customer Number: T217202 Laboratory Name: PCS Phosphate Inorganic Results 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production Page 2 of 3 /SfN Project# : 011216B MlSM ED 001523 00007569-00596 A Waters Company 011216B Evaluation Final Complete Report Brad Lee PCS Phosphate 1530 NC Hwy 306 S Aurora, NC 27806 252-322-8270 EPA ID: ERA Customer Number: TNI Analyte Code Analyte Units Reported Value Assigned Value Acceptance Limits Performance Evaluation Method Description Analysis Date SSAP Fluoride in Impinger Solution (cat# 1441, lot# 011216B) Study Dates: 01/12/16- 02/18/16 1730 Fluoride mg/dscm 6.76 7.00 5.95-8.05 Acceptable EPA 13B 2000 2/16/2016 Analyst Name Not Reported T217202 16341 Table Mountain Pkwy Golden, CO 80403 800.372.0122 303.431.8454 fax 303.421.0159 www.eraqc.com 17cv1906 Sierra Club v. EPA - 6/22 Production Page 3 of 3 /SfN Project# : 011216B MlSM ED 001523 00007569-00597 PCS Phosphate Aurora CALCINER SOURCE PERFORMANCE TESTING- ( V',i- '>) METHOD 13-8 MULTI-TEST ANALYSES WORKSHEET Analyst: -^4 /?. ....... _ Date : <? ) (> V C Observed Value ppm Midrange 5.0 ppm std= * SLooo 100.0 ppm Std = 97 O n/a % Recovery Midrange = iba % Recovery QA = W'H ^ % Recovery Spike A/% Difference Duplic # 1, % Difference Duplic# 2. % % Fluoride curve correlation coeff.= /,QCrCO TISAB lot # = ^ & 5rg> ^ 3 Hun# i 2 3 Source Cal #2 Cal #2 Cal #2 Sample Sample Date Aliquot volume pum Run# 2/2/2016 10 iooo mss 9,2.17 1 2/11/2018 10 1000 mis 0,239 2 2/11/2016 10 1000 mis 0,3/ (9 3 ......10 toco mis UupIrC Source Cal #4 Cal #4 Cal #4 Ca! #4 Sample Sample Date Aliquot volume ppm 2/1/2016 10 looo mis O'to* 2/1/2016 IS 1000 mis C/'/9f 2/1/2016 10 1000 mis o.ll! Blanks PPM __ 2/1/2016 .....10 JCOG mle 0-!l$ Wlcl-ranps sta. V* f S3 Run# X X X ,._x_ Run # / a 3 III1 Run# 1 X X Source X X X y Source Cal #1 Cal #1 Ca! #1 Source Cai#3Spike X X Sample Sample Sample Date Aliquot volume ppm Run# Source Sample Date Aliquot volume ppm X 10 1000 mis 1 CM 10 1000 mis U 3 X 10 10S0 mis ., .......... 10 1000 mis X 10 1000 mis X X X 10 1O0Q mis X p toon mis X X ........X____ __ 'O 1000 mis Blip Sample Sample Date Aliquot volume ppm 2/10/2016 10 1000 mis o,20t 2/10/2016 10 1000 mis oJfa Run# I 2 Source Cal #3 Cal #3 Sample Sample Date Aliquot volume 2/13/2016 213/2016 10 1000 mis 0.2W 10 1000 mis iSs: 0-i3i 2/10/2016 10 1006 mis &.%$G 3 Cal #3 2/13/2016 10 1000 mis QtekalCt BBBpj _ 10 lC'/0 mis WBKKSSk Sample Sample Date Aliquot volume 10 1000 mis 1.2.1 10 1000 mis C.7C X 10 1000 mis X 10 1000 ml* Duplic Cal #3 __ ?s.\z 10 1000 mis 111111111 POST f-Cures Standards 10.0 ppm 1.0 ppm 0.3 ppm mV 97. f fOC.3 ppm * Spite value = 1.00 /o.co (FT- Week#3) L*t nsM 0,3/f 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00598 PCS Phosphate Aurora CALCINER SOURCE PERFORMANCE TESTING- (WEEK#!) METHOD 13-B MULTI-TEST ANALYSES WORKSHEET Analyst: Op /U & F` Curve Standards 10.0 ppm 1.0 ppm mV *57 i3~& . ppm. fb.CrO },&& Slope- S9 9 Date: f ~/C Midrange 5.0 ppm std= * $1 9 100.0 ppm Std = / & X wa 0.3 ppm Blank (PCS) m,L firOoe'U Quality Assurance ERA QA Acceotable slope ranqe -54.0 mv to -60.0 mv % Recovery Midranete = l&l/L/ ^ % Recoverv QA = *99 ^ % Recoverv Spike = *9 S'99 % Difference Dtiplic #1 - H,1f Lot Number 240-506 {Known Value) Certified Value ^3mg/l 3,23 Observed Value ppm % Difference Duptic #2 l* S' 9Z SSAP &/W&D Observ Value "" ppm Fluoride curve correlation coeff.= & e'>cs TISAB lot # -9Sv#OC3 Run# i 2 3 *3->up Source Cai.#5 Cal,#5 Cal.#5 Cal.#5 Sample Sample Date Aliquot volume ppm Run# 1126/2015 10 1000 mis <Q.a// i 1/26/2015 1/26/2015 10 1000 mis 2 10 1008 mis &>/o f 3 1/26/2015 0j0_b_ 10 '1008 mis *3-Oi3 Source Cal. #6 Cal. #6 Cal. #6 Cal. #6 Sample Sample Date Aliquot volume ppm 1/26/2015 1/26/2015 10 1808 mis n.199 10 1808 mis @-W1 1/26/2015 1/26/2015 10 1608 mis 10 1000 mis Blank= ppM p.afls Mid-ranoestd.= S*0 *7 Run# Sample Sample Source Sample Date Aliquot volume ppm Run# Source Sample Date Allauot volume ppm 1 Run #1 Spike 1/26/2015 fS /. 0.1 1000 mis Spike value = 1.00 PPM Cal. #6 Run# X X X X Run# X X X X Source Sample Sample Date Aliquot volume ppm Run# Source Sample Sample Date Allauot volume X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Source Sample Sample Date Aliquot volume X X X X X X X X X X X X X X X X X X X X POST F- Curve Standards 10.0 ppm mV HSl ppm j 6,esG 1.0 ppm i2>% 0.3 ppm MPF"1____ oMC Ct.lW 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00599 APPENDIX F TEST PROTOCOLS AND RELATED CORRESPONDENCE 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00600 ^ PotashCorp' Helping Nature Provide January 19, 2016 CERTIFIED MAIL PotashCorp - Aurora Mr, Robert Fisher, Regional Supervisor NCDEQ - Division of Air Quality 943 Washington Square Mail Washington, North Carolina 27889 Subject: PCS Phosphate Company, Inc, Permit No. 4176T53 Facility ID: 700071 Calciner No. 1-6 Plants (ep 201-206) Compliance Tests - Particulate, Total Fluoride, Mercury and Sulfur Dioxide Dear Robert: As per the requirements of the Air Quality Permit No 4176T53 General Emissions and Reporting Requirements 3.JJ.1 an air emission testing protocol is being provided prior to air pollution testing. Please find attached for your approval, the protocol for the subject sampling at Calciners 1-6 (ep 201 -206) If there are any questions concerning this subject, please contact me at 252-322-8270. Pamela Justness Sr. Environmental Engineer PotashCorp-Aurora (PCS Phosphate Company, Inc.) Enclosures Pc: File/lab notebook M. Brom Robert Fisher - 2 copies T. Baker ec: R. Bonner (w/encl) (w/ end) (w/encl) (w/ summary only) (w/ summary only) R. Smith (w/ summary only) K. Alnahdy (w/ summary only) 1530 NC Hwy 306 South, Aurora, NC USA 27806 T (252) 322-4111 PotashCorp. | www.potashcorp.com <506 Sierra Club v. EPA - 6/22 Production ED 001523_00007569-00601 NCDENR Protocol Submittal Form (rev. 2010a) Division of Am Quality Page 1 of 2 Purpose: The goak of the Protocol Submittal Form are to initiate communication between representatives of the permitted facility, the testing consultants, and the DAQ as well as to identify and resolve any specific testing concerns prior to testing. Instructions: Use Guidance Document to fill out this form. Submit all forms and additional Information to the DAO Regional Supervisor at least 4S davs prior to testing. Complete one form for each sampling location. If this form does not supply sufficient space to completely answer all questions or if additional relevant information is necessary, attach additional documentation and/or information to the original form. Questions and/or comments should be directed to the appropriate Regional Supervisor. This form and its Gnidance Document are available from the DAQ website (http:. Specify Appropriate Regional Office: (check one) O Asheville Fayetteville Cl Mooresville Raleigh Washington O Wilmington Q Winston-Salem Facility Name: PCS Phosphate Company, Inc. Testing Company: AECOM Facility ID No: 07-00071 Facility Contact Person / mailing address & email: Testing Company Contact Person / mailing address & email: Pamela Jestaess PCS Phosphate Company 1530 NC Bwy, 306 South Aurora, NC 27806 Beaufort County Email Address: PKJestness@potashcorp.com Bob Jongleux AECOM 1600 Perimeter Park Drive Suite 400 MorrisviUe, NC 27560 Email Address: bob.jongleux@aecom.com Phone: 252.322.8270 Mobile No.: 252-402-6990 Fax: 252,322.4444'"-^ tO %$ Phone: 919.464.1242 Mobile No.: 919.949.2950 Fax: 919.461.1415 Air Permit Number & Revision: 4176T53 Permitted Source Name and ID No.: Calciner No. l-No.6 (EP-201 - 206) Permitted Maximum Process Rate: Maximum Normal Operation Process Rate: Target Process Rate for Testing: 105.1 tons per hoar (nominal feed) See Attachment A. See Attachment A. 1.1) What is the specific purpose for the proposed testing? (permit condition, NSPS, NESHAP, etc, see guidance doc): Permit 2.1.2.A.1 and 2.1,2A.2(a) Initial testing for NESHAP - 40 CFR Part 63 Subpart AA for Hg and FI' Is this an initial performance test? H Yes or B No 1.2) list all state and federal regulations that apply to the proposed testing (see guidance doc): 15A NCAC 20.1111 and 0501 (e) and, 40 CFR 63 Subpart AA 1,3) Will the test results be used for other regulatory purposes (e.g., emission inventories, permit application, etc.) beyond that stated above? 03 Yes or No If yes, explain. Annual emission Inventories 1.4) How will production/process & control device data be documented during testing (Est specific control equipment, process parameters, instrumentation that will be used, frequency of data collection, collected by computer/manually, etc.)? TEST WILL NOT BE ACCEPTED WITHOUT APPROPRIATE PRODUCTION/PROCESS & CONTROL DEVICE OPERATION DATA. Data to be recorded by control room: includes feed rate (tons per hour), feed moisture, coal feed rate, absorber change in pressure, scrubber water flow rate, and WESP secondary voltage. 1.5) Provide a brief description of the source (including control equipment) and attach source or process flow diagram from source through stack exit: The calcining operation includes six flnidized-bed ealemers which encompass four- distinct fluid beds, each performing a different function. The temperature in the calciners is maintained high enough to oxidize carbonaceous material adhered to the phosphate rock. The temperature of the calcining bed is maintained below 1600F by direct Injection of bituminous coal/coke fuel mixture. Vent streams from the preheat bed and the aftercooler chambers exhaust through individual duplex cyclones and a common venturi scrubber. In addition to the venturi scrubbers, Calciners arc equipped with wet electrostatic precipitators (WESPs) for additional particulate control. See attached process diagrams. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00602 Protocol Submittal Form (rev. 2010a) Division of Am Quality Page 1 of 2 1.6) Provide a brief description of the sampling location, attach schematic of sampling location, and indicate whether concurrent testing will be conducted at other sampling locations (Approval of protocol without this data will not exempt you from Method 1 criteria): The number and location of tie sampling points is determined by 1PA Method 1. See attached stack schematic for details of sampling location. 2.1)Frovide the following information for each test parameter. Target 1`nJutant PM Stack Volumetric Flow PMcoadeasable MW Fluoride Proposed Test Method 5 2 202 3 13B Number of Test Runs 3 Test Run Duration 72 minutes # of Sampling Points 24 Comments ......... ................................................. . ....... 12 points per traverse - 3 minutes per point 3 72 minutes 24 In conjunction with Method 5-12 points per port 3 72 minutes 24 In conjunction with Method 5-12 points per port 3 - - Assume MW of29.00 based on default value for Combustion Source per historical plant convention 3 72 minutes 24 Same time as M5/202 but as a separate run Sulfur Dioxide 6C 3 60 minutes 3 3 point traverse - S02 on Calciner 4 only Mercury 3 0B 3 60 minutes 1 Sample from center point of stack 2.2) Will all testing be conducted in strict accordance with the applicable test methods? If answer is no, attach complete documentation of all modifications and/or deviations to the applicable test methods. 2.3) Does the proposed sampling location meet the minimum EPA Method 1 criteria for acceptable measurement sites? Attach supporting documentation. See Attachment B 2.4) Has cyclonic flow been documented at this source (EPA Method 1 Section 11.4)? ABSENCE OF CYCLONIC FLOW MUST BE VERIFIED DURING CURRENT TESTING. El Yes 13 Yes M Yes 2.5) Will the oxygen concentration be determined by EPA Method 3 via Orsat or strict EPA Method 3A (specify) Ifanswer is no, see Question 2.2 above. (Fyrites are NOT allowed per 15A NCAC 2D .2606) Molecular weight will be based on the default value for combustion sources and therefore 02/C02 is not necessary to collect__________ ____ _______________________________ __ _____________________ _________ _____________ 2.6) Do any of the proposed test methods require analysis of EPA audit samples? If yes, notify Regional Office a minimum of45 days prior to testing to allow for audit sample preparation and shipment. Request submitted and approved. 2.7) Has all testing equipment been calibrated within the past year? If answer is no, explain. Yes 0 Yes 3 Yes 2.8a) Have all calibration gases been certified by EPA Protocol 1 procedures? (Answer only as applicable) 3 Yes No No No 13 No No No No 2.8b) Is a dilution system (via EPA Method 205) proposed? (Answer only as applicable) Yes No 2.8c) Attach a summary of expected calibration gas concentrations for all proposed instrumental test methods. 2.9) What is proposed test schedule? DAO Regional Supervisor must be notified a minimum of 15 days prior to the actual test datefs) THIS FORM DOES NOT CONSTITUTE 15 DAY REGIONAL OFFICE NOTIFICATION 1/18/2016 ional office notified in December 2015. Signatures: Representatives from the permitted facility and the contracted testing company must provide signatures below certifying that tfagjnformation provided on this form and any attached information is accurateand complete. Permitted Facilitymepresentative Name; Pamela Jestness Title: Senior Environmental Engineer Company: PCS Phosphate Company, Inc. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00603 CALCINER #1 Attachment A Calciner No, i- No, 6 Process and Target Rates for Compliance Testing CALCINER #2 CALCINER #3 CALCINER #4 CALCINER m CALCINER #6 2015 JAN FEB MAR APR MAY JUNE JULY AUG SEPT OCT NOV DEC Average Target Rate FEED 30,968 32,958 43,745 41,42? 40,117 38,738 38,593 21,344 39,307 32,723 38,989 38,498 36,449 RUN HOURS 584,6 596.7 713.4 684.1 671.5 660.8 727.1 366.4 617.8 559.4 600,3 689.2 622,6 Actual Rate Itons/hour) S3.0 55.2 61.3 60.6 59.7 58.6 53.1 58.3 63.6 58.5 64.9 55.9 | 58.6 58.6 FEED 29,517 28,690 30,422 40,552 40,769 36,299 32,140 33,145 38,399 42,967 33,526 41,563 35,666 RUN HOURS 575.6 533.9 487.6 675.1 667.4 629.9 579.3 584.2 626.3 742.0 $42.9 742.3 615.5 Actual Rate {tons/hour} 53.3 53.7 62.4 60.1 61.1 57.6 55.5 56.7 61.3 57.9 61.8 56.0 57.9 57.9 FEED 29,995 30,458 35,865 31,050 33,857 36,309 39,757 39,075 38,891 33,092 35.442 35,573 34,947 RUN HOURS 546.1 533.1 597.7 530.2 53S.9 632.2 703.4 660.6 634.1 562,2 571.8 651.5 596.6 Actual Rate {tons/hour} 54.9 57.1 60.0 58.6 63.2 57.4 S6-5 59.2 61,3 58.9 62.0 54.6 58.6 58.6 FEED 29,765 20,375 7,593 42,804 40,510 40,681 35,485 38,609 36,580 44,454 39,695 36,680 34,436 RUN HOURS 604.2 393.4 132.2 706.5 675.5 682.2 632.9 689.4 617.4 743.0 639,1 713.6 600.8 Actual Rate (tons/hour) 49.3 51.8 67.7 60.6 60.0 59.6 56.1 S6.0 59.2 59.8 62.1 51.4 57.8 57.8 FEED 32,464 19,378 27,793 39,264 41,594 17,436 39,431 42,452 38,236 40,072 41,220 23,113 33,538 RUN HOURS 626.4 408.6 488.5 652.8 705.1 2981 711.7 717.2 616.4 631.7 647.3 407.8 576.0 Actual Rate (tons/hour) 51.8 47.4 56.9 60.1 59.0 58.5 55,4 S9.2 62.0 63.4 63.7 S6.7 57.8 57.8 FEED 34,465 20,022 0 0 0 9,483 29,489 37.493 39,243 20,407 43,853 30,274 22,061 RUN HOURS 685.4 395.8 0.0 0.0 0.0 207.0 510.4 662.1 645.1 341.9 688.3 549.7 390.5 Actual Rate (tons/hour) 50.3 50.6 45.8 57.8 56.6 608 59.7 63.7 55.1 55,6 55.6 Production data for protocol Calciner 2015 Production Attachment i PCS Aurora Calciner No.l-No.6 Test Location Schematic Stack Diameter 72" 10*10" (130") 1.8 Diameters ] J_ pQfi^oie 24'10" (298*') 4.1 Diameters 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00605 17cv1906 Sierra Club v. EPA - 6/22 Production STACK (EMISSION POINT ID, No's 201 - Nos 202) ED_001523_00007569-00606 DRAWN S.LPeschat) CHECKED APPROVED ^ PotashCorp APPROVED U:' Engineering\Drawings\Flc|w Drawings\AFM-039-046; AUR1SLP, CutePDF Writer, ARCH A, 1:0,971429' 2/2011 12:43:1/ DRAWING TITLE FLOW MECHANICAL AREA - 039 PROCESS FLOW DIAGRAM OF CALC/MBT PROCESS No. 1 * No. 2 DRAWING No. AFM-039-046 17cv1906 Sierra Club v. EPA - 6/22 Production STACK ED_001523_00007569-00607 DRAW SLPascfiatf CHECKED APPROVED ^ PotashCorp APPROVED U Engineerinq\Pfawiotis\Fltfw Drawings\AFM-039-047 AlfiCftf^i;2/2011 12:49:0^ AUR1SLP, CutePDF Writer, ARCH A, 1:0.971429 DRAWING TITLE flOW MECHANICAL AREA 039 PROCESS now DIAGRAM OF CALONER PROCESS No. 3 four 6 (IDENTICAL) DATE; 3/26/2011 PCS AMENDED PETITION - ATTACHMENT E PCS Calciner Testing .iron' lr i . '/ Fairchild, Susan A..K I i! y l,c: "Barnett, Keith", "Jessica.DeMonte", RSmith, TBaker 02/17/201612:06 PM Susan, PCS wants to let you know that there have been some challenges with initial performance testing of mercury emissions from the Aurora calciners. We recently received preliminary test results for mercury emissions from 3 calciners that exceed the new mercury limit. Two other calciners passed their Hg tests. The sixth calciner was shut down due to an equipment failure, and PCS has requested that North Carolina DEQ issue a 2-week extension of the testing deadline for that calciner. North Carolina DEQ is aware of the mercury results obtained so far. PCS discussed the results with the state today and is in the process of determining a plan for retesting the calciners that exceeded the limit. PCS also will test Calciner 6 for mercury in the near future. Final test reports are being prepared and will be submitted to the ERT in due course. Based on preliminary data, it appears that the mercury content of calciner feed is significantly higher now than it was during prior ICR testing. However, PCS needs to complete a review of the relevant data before it can draw any conclusions about the results or whether the new mercury limit is achievable notwithstanding what appears to be significant variability in the mercury content of the feed. I will update you once we have more information. Please let me know if you have any questions in the meantime. Thanks, Casey Casey Fernung Bradford (bio) Partner JONES DAY - One Firm Worldwide. 1420 Peachtree Street, N.E. Suite 800 Atlanta, GA 30309 Office+1.404.581.8119 cbradford@jonesday.com This e-mail (including any attachments) may contain information that is private, confidential, or protected by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. This e-mail (including any attachments) may contain information that is private, confidential, or protected by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00608 PCS AMENDED PETITION - ATTACHMENT F PCS 5/26/16 Presentation Casey F Bradford/JonesDay to: Fairchild, Susan, Barnett, Keith 4-8119 ' Cc: "Jessica. DeMonte", RSmith 05/27/2016 04:00 PM Susan, Attached is the PCS presentation from our 5/26/16 meeting on the mercury floor standard for existing calciners. Please let me know if you have any other questions about this information or PCS' request to revise the mercury floor standard. We appreciate EPA's attention to this matter which has a significant impact on the PCS Aurora facility. Thanks, Casey NAI 1501071013 1 PCS Calciner Presentation 5 26 16.PPTX Casey Fernung Bradford (bio) Partner JONES DAY - One Firm Worldwide 1420 Peachtree Street, N.E. Suite 800 Atlanta, GA 30309 Office+1.404.581.8119 cbradford@jonesday.com This e-mail (including any attachments) may contain information that is private, confidential, or protected by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. This e-mail (including any attachments) may contain information that is private, confidential, or protected by attorney-client or other privilege. If you received this e-mail in error, please delete it from your system without copying it and notify sender by reply e-mail, so that our records can be corrected. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00609 \CT Floor Emission Limit for Mercury (Hg) r,-- Existing Phosphate Rock Calciners PCS Phosphate Company, Inc. Aurora, North Carolina May 26, 201 6 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00610 Proposed Agenda i. Hg MACT Floor Standard ii. ICR & Initial Compliance Test Results m. PCS Hg Study (January - May 201 6) IV. Conclusions / Next Steps ''Questions welcome at any time* 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00611 I. Hq Floor Standard CAA 1 1 2(d)(3)(B): Floor should be the average emissions already achieved by PCS calciners 201 5 Final Rule Set Hg floor at 0.14 mg/dscm at 3% 02 Based on only 1 2 Hg emission test results for PCS calciners from 2010 & 2014 information collection requests (ICR's) "|T]he Agency does not anticipate that any facilities wil need to install a new control device to meet the existing phosphate rock calciner Hg limit." 80 FR 50.398. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00612 II. ICR & Compliance Test Results C.iSO g E m is s io n s {m g /d s c m @ 3 % Q 2 ) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00613 III. PCS Ho study (2016) * Objective: Determine whether Hg floor limit is achievable during all representative operating conditions * Sampling & Analysis: >70 stack samples 21 stack samples for EPA Method compliance test 41 3 rock samples * PCS Evaluated: Hg Emissions Rock Feed Hg Concentration WESPs / Venturi Scrubbers 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00614 2016 Hg Emissions Test Results 0.250 0.240 0.230 Initial Compliance Test Hg Emissions Study 0.220 0.210 0.200 g 0.190 13'180 0.170 If 0.160 ^ 0.150 .............. ..........; ............... ............................. #.....................#.... .....#................................#...... *...................... w . w E 0.140 * ,, . " ' 0.130 .................................................................................. 'IF.................................................... 120 ........... *_____ _____ ________ .* o.no uu .............. # ...... ..................... ...... ` * " __ * , _____ ee o.ioo 0.090 0.080 0.070 ............w....... .............~................ ...................................... ~......................................-.............. 0.060 0.05 0.040 10 15 20 25 30 35 40 45 50 55 60 65 70 Run No. 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00615 Feed Hg Concentration Data (2010 & 2016) Analytical LOCI - Limit of Quantification 360 2010 feed Hg < 0,04 ppm (exact value unknown) 2016 Ave, Feed Hg fPre, Start, Mid) F eed H g C o n c e n tra tio n (p p m ) 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00616 H g F eed C o n c e n tra tio n (p p m ) 0.070 0.060 0.050 0.040 0.030 Short-Term Hg Variability in Feed Samples Collected During 2016 Emissions Testing (Runs 40 - 57} "Pee" Feed Sample (Collected 30 Min. Prior to Test Run) S "Start" feed Sample (Collected at Start of Test Run) "Mid" Feed Sample (Collected at Midpoint of Test Run) 0.020 0.010 mm 40 41 42 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00617 H g E m is s io n s (m g /d s c m @ 3% 0 2 } 0.180 0.170 ,160 0,150 0,140 0.130 0.120 0.110 0.100 0.09 0.080 0.000 2016 Hg Emissions & Wet Rock Feed Hg Concentration Complex relationship to Hg emissions .1FXF" j_ ---j-- --r-- 0.020 0.030 0,040 0.050 0.060 Wet Rock Mercury Concentration (ppm) ---r--- 0.070 ------r-- 0.080 -----1 0.090 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00618 Feed Hg Concentration * Significant short-term variability in Hg feed concentrations * Change in Limit of Quantification (LOQ) complicates analysis of historical data * Relationship to emissions is complex * PCS has no control over the Hg content of rock feed to the calciners 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00619 WESPs / Wet Scrubbers * Elemental Hq (Hq): Predominant species of Hg exiting PCS calciners (98-99% in ICR results) * EPA Response to Comments: Hg is "the form primarily released by phosphate rock calciners" * PCS WESPs / Scrubbers: Operating normally during all 2016 emissions testing * Conclusion: WESPs/Scrubbers do not effectively control Hg emissions to eliminate variability or achieve MACT floor 17cv1906 Sierra Club v. EPA - 6/22 Production 11 ED 001523 00007569-00620 IV. PCS Hq Study Conclusions * New Hg limit is not achievable during all representative operating conditions and does not meet MACT floor definition Hq Emissions: Several 201 6 test results > 0.14mg/dscm Hg at 3% 02 . Rock Feed Hq Concentration: Significant variability; not within PCS control . WESPs / Venturi Scrubbers: Do not effectively control Hg emissions to achieve MACT floor 17cv1906 Sierra Club v. EPA - 6/22 Production 12 ED 001523 00007569-00621 Next Steps * Due to high Hq variability in the ore supply and lack of effective Hq control capability. PCS requests that EPA recalculate the MACT floor and revise Hg limit for existing calciners 17cv1906 Sierra Club v. EPA - 6/22 Production 13 ED 001523 00007569-00622 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00623 PCS AMENDED PETITION - ATTACHMENT G CALCINER DATE (2016) TEST TIME FUEL Hg Emission Rate (mg/dscm@3% 02) Feed Pre, Mercury PPM Feed Start, Feed Mid, Mercury PPM Mercury PPM 1 2 1/30 30B Compliance Test #1 11:00 -12:00 Coal 0.055 2 2 1/30 30B Compliance Test #2 12:20-13:20 Coal 0.058 3 2 1/30 30B Colmpliance test #3 14:35 -15:35 Coal 0.131 0.047 4 5 2/8 30B Compliance Test #1 14:15 -15:15 Coal 0.129 0.067 5 5 2/8 30B Compliance Test #2 15:30-16:30 Coal 0.123 0.072 6 5 2/8 30B Colmpliance test #3 16:41 -17:41 Coal 0.121 0.072 7 4 2/10 30B Compliance Test #1 12:25 -13:25 Coal \j. j Do 0.057 8 4 2/10 30B Compliance Test #2 13:45 -14:45 Coal 0.140 0.078 9 4 2/10 30B Colmpliance test #3 15:05 -16:05 Coal 0.049 10 1 2/11 30B Compliance Test #1 10:25 -11:25 Coal 0.149 0.031 11 1 2/11 30B Compliance Test #2 12:00 -13:00 Coal 0.055 12 1 2/11 30B Colmpliance test #3 13:35 -14:25 Coal 0.053 13 3 2/11 30B Compliance Test #1 16:10-17:10 Coal 0.161 0.046 14 3 2/11 30B Compliance Test #2 17:45 -18:45 Coal 0.056 15 3 2/11 30B Colmpliance test #3 19:05 - 20:05 Coal 0.055 16 2 2/13 30B Compliance Test #4 10:55 -11:55 Coal 0.136 0.054 17 2 2/13 30B Compliance Test #5 12:40 -13:40 Coal 0.054 18 2 2/13 30B Colmpliance test #6 14:30-15:30 Coal 0.136 0.056 19 6 2/19 30B Compliance Test #1 11:30-12:30 Coal 0.083 20 6 2/19 30B Compliance Test #2 12:50-13:50 Coal 0.135 0.048 21 6 2/19 30B Colmpliance test #3 14:00 -15:00 Coal 0.059 22 6 2/25 Mercury Study Test 1 13:00 -14:00 Oil 0.122 0.027 0.056 0.047 23 6 2/25 Mercury Study Test 2 16:15 -17:15 Oil 0.112 0.075 0.060 0.034 24 6 2/26 Mercury Study Test 3 7:20-8:20 Oil 0.113 0.019 0.039 0.039 25 6 2/26 Mercury Study Test 4 8:32-9:44 Oil 0.122 0.045 0.078 0.035 26 6 2/26 Mercury Study Test 5 10:40 -11:40 Oil 0.141 0.048 0.069 0.045 27 6 2/26 Mercury Study Test 6 13:10-14:24 Oil 0.089 0.044 0.072 0.039 28 6 2/26 Mercury Study Test 7 15:20-16:20 Oil 0.138 0.042 0.034 0.036 29 6 2/26 Mercury Study Test 8 16:32 -17:32 Oil 0.120 0.034 0.041 0.043 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00624 30 6 2/29 Mercury Study Test 9 9:00 -10:00 Oil 0.041 0.049 0.038 31 6 2/29 Mercury Study Test 10 10:30-11:30 Oil 0.128 0.021 0.040 0.027 32 6 2/29 Mercury Study Test 11 12:30-13:30 Oil 0.140 0.035 0.022 0.018 33 6 2/29 Mercury Study Test 12 13:35 -14:55 Oil 0.040 0.026 0.043 34 6 2/29 Mercury Study Test 13 15:55 -16:55 Oil 0.015 0.021 0.020 35 6 2/29 Mercury Study Test 14 17:10-18:10 Oil 0.128 0.009 0.012 0.038 36 6 3/1 Mercury Study Test 15 9:30-10:30 Oil 0.136 0.010 0.027 0.041 37 6 3/1 Mercury Study Test 16 10:55 -12:45 Oil 0.123 0.036 0.031 0.033 38 6 3/1 Mercury Study Test 17 13:45 -14:45 Oil 0.122 0.045 0.061 0.052 39 6 3/1 Mercury Study Test 18 15:10-16:10 Oil 0.111 0.048 0.033 0.042 40 6 3/2 Mercury Study Test 19 12:10-13:10 Coal 0.116 0.032 0.040 0.047 41 6 3/2 Mercury Study Test 20 13:25 -14:25 Coal 0.134 0.038 0.026 0.025 42 6 3/2 Mercury Study Test 21 15:35 -16:35 Coal 0.142 0.024 0.027 0.025 43 6 3/2 Mercury Study Test 22 16:50-17:59 Coal 0.018 0.034 0.034 44 6 3/3 Mercury Study Test 23 8:00-9:00 Coal 0.041 0.022 0.014 45 6 3/3 Mercury Study Test 24 9:15 -10:15 Coal 0.019 0.047 0.051 46 6 3/3 Mercury Study Test 25 11:20-12:20 Coal 0.033 0.021 0.028 47 6 3/3 Mercury Study Test 26 12:40 -13:40 Coal 0.157 0.033 0.010 0.012 48 6 3/3 Mercury Study Test 27 14:40 -15:38 Coal 0.011 0.006 0.009 49 6 3/3 Mercury Study Test 28 16:05 -17:05 Coal 0.006 0.034 0.007 50 6 3/7 Mercury Study Test 29 12:00 -13:00 Coal 0.033 0.031 0.030 51 6 3/7 Mercury Study Test 30 13:15 -14:15 Coal 0.013 0.029 0.049 52 6 3/7 Mercury Study Test 31 15:15 -16:15 Coal 0.114 0.022 0.024 0.009 53 6 3/7 Mercury Study Test 32 16:25 -17:25 Coal 0.113 0.016 0.053 0.020 54 6 3/8 Mercury Study Test 33 7:45-8:45 Coal 0.128 0.038 0.030 0.045 55 6 3/8 Mercury Study Test 34 9:00 -10:00 Coal 0.122 0.015 0.037 0.048 56 6 3/8 Mercury Study Test 35 10:35 -12:02 Coal 0.128 0.044 0.021 0.026 57 6 3/8 Mercury Study Test 36 15:15 -16:15 Coal 0.117 0.009 0.019 0.061 58 6 3/10 Mercury StudyTest 37 12:30-14:57 Coal 0.124 0.009 0.050 0.009 59 6 3/10 Mercury Study Test 38 15:10-16:10 Coal 0.131 0.057 0.037 0.036 60 6 3/10 Mercury Study Test 39 16:30-17:57 Coal 0.137 0.035 0.028 0.036 61 6 3/14 Mercury StudyTest 38 10:05 -11:05 Coal 0.134 0.027 0.027 0.025 62 6 3/14 Mercury Study Test 40 11:20-12:20 Coal 0.024 0.037 0.032 63 6 3/14 Mercury Study Test 41 13:10-14:10 Coal 0.038 0.025 0.022 17cv1906 Sierra Club v. EPA - 6/22 Production ED 001523 00007569-00625 64 6 3/14 Mercury StudyTest 39 14:40 -15:40 Coal 0.034 0.024 0.023 65 6 3/14 Mercury Study Test 42 15:55 -16:55 Coal 0.152 0.033 0.027 0.037 66 6 3/16 Mercury Study Test 43 12:15 -13:15 Coal 0.039 0.030 0.044 67 6 3/16 Mercury StudyTest 40 14:05 -15:05 Coal 0.140 0.049 0.056 0.034 68 6 3/24 Mercury Study Test 44 9:35 -10:35 Coal 0.122 0.021 0.059 0.067 69 6 3/24 Mercury Study Test 45 10:45 -11:45 Coal U. 141 0.044 0.008 0.011 70 6 3/24 Mercury StudyTest 41 14:45 -15:45 Coal 0.136 0.028 0.026 0.027 71 6 3/24 Mercury Study Test 46 16:55 -17:55 Coal 0.133 0.016 0.080 0.025 17cv1906 Sierra Club v. EPA 6/22 Production ED 001523 00007569-00626