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RESIDUAL VCM ANALYSES TEXAS CITY VINYL RESINS PRODUCTION March, 1977 Author: L. D. Morgan Supervisor: ^ G. F. Tacquard Date: April 1, 1977 Attached in Table I is a summary of the residual VCM levels in suspension vinyl resins produced during the month of March. The residual VCM level of QSAL-7 and QSAN-7 showed a decrease from February production. QSAH-7 showed a increase In residual VCM level from February production. VSJE-10 and VSKK-10 remained consistent from previous production. Tables II-XIII summarize individual blend and bin data from suspension vinyl resins production for month of March. Shown in Tables XIV and XV are residual VCM levels in non-solvent and solvent resins, respectively. One VYHH and one VYNS solvent resin bin was reblended to achieve <1 ppm residual VCM. /kw RESINS LABORATORIES UNION CARBIDE CORPORATION CHEMICALS AND PLASTICS DIVISION TEXAS CITY PLANT UCC 054891 TABLE I SUMMARY OF VCM ANALYSIS OF SUSPENSION VINYL RESINS March, 1977 Type QSAl-7 0SAN-7 VCM1, ppm Bin Blend - 31 10 31 22 % Blends <10 ppm < 1 ppm 77 15 54 6 0SAH-7 362 225 -- QSAF-7 - 268 -- QSAP-7 - 36 -- VSJE-10 830 471 -- VSKK-10 1584 1170 *- - ucc 054892 TABLE II RESIDUAL VCM CONTENT OF QSAL-7 BLEND SAMPLES March, 1977 alend Number 1245 1246 1247 1248 1249 1250 1251 1252 1253 1254 1255 1256 1257 VCM, ppm 27 7 7 50 3 <1 <1 4 3 26 2 1 3 UCC 054893 TABLE III RESIDUAL VCM CONTENT OF QSAN-7 BLEND SAMPLES March, 1977 Blend Numbers 7299 * 7300 7301 7302 7303 7304 7305 7306 7307 7308 7309 7310 7311 7312 7313 7314 7315 73; 6 7317 7318 7319 7320 7321 7322 7323 7324 7325 7326 7327 7328 7329 7331 7332 7333 VCM, ppm 30 1 46 r 5 6 27 5 12 33 . <1 23 <1 O 18 4 3 59 7 7 4 7 9 5 27 38 6 1 6 3 1 94 2 Blend Numbers 7334 7335 7336 7339 7340 7341 7343 7345 7346 7347 7348 7349 7350 7351 7352 7353 7354 7355 7356 7357 7358 7359 7360 7361 7362 7363 7364 7365 7366 7367 7368 7369 7370 VCM, ppm 19 10 30 9 24 31 32 2 2 10 4 5 29 41 6 4 14 7 12 13 9 59 93 10 12 33 313 16 <1 1 44 2 43 UCC 054894 TABLE IV RESIDUAL VCM CONTENT OF CJSAH-7 BLEND SAMPLES March, 1977 V Blend Number VCM, ppm 1956 1957 1958 1959 1960 196~1 1962 1963 1964 1965 1966 1967 1968 1969 1970 1971 1972 1973 1974 1975 1976 1977 1978 1979 1980 1981 1982 1983 1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994 1995 1996 1999 2000 176 283 640 149 ?: 1M 34 74 6f 25 197 108 127 407 219 301 410 105 122 178 483 113 148 40 90 64 197 55 119 170 239 394 187 624 298 482 368 366 894 95 60 91 74 UCC 054895 TABLE V RESIDUAL VCM CONTENT OF QSAF BLEND SAMPLES March, 1977 Blend Number 73 74 75 76 PPI5 190 380 302 200 UCC 054896 TABLE VI RESIDUAL VCM CONTENT OF QSAP BLEND SAMPLES March, 1977 Blend Number VCM, PPm 895 45 896 31 897 33 ucc 054897 TABLE Y11 RESIDUAL VCM CONTENT OF QSAP BLEND SAMPLES March, 1977 Blend Number 1207 1208 1209 ^210 1210 1211 1212 1213 1215 1216 1217 1218 1219 1221 1222 1223 1224 1225 VCM, ppm 371 811 490 765 358 407 479 217 498 391 252 428 410 396 689 340 450 731 UOC 054898 TABLE VIII RESIDUAL VCM CONTENT OF VSKK-10 BLENO SAMPLES March, 1977 Blend No. 1201 1202 1203 1204 1205 1206 1207 1208 1209 1210 1211 1212 1213 1214 1215 1216 1217 1218 1219 1220 1221 1222 1223 1224 1225 1226 1227 1228 1229 1230 1231 1232 1233 VCM, ppm 1722 970 1154 1214 1604 1167 510 743 644 921 815 1555 1406 1340 1355 1405 1429 1900 1668 2122 1288 2003 1556 1537 1732 1493 1038 728 399 787 314 207 1596 Blend No. 1234 1235 1236 1237 1238 1239 1240 1241 1242 1243 1244 1245 1246 1247 1248 1249 1250 1251 1252 1253 1254 1255 1256 1257 1258 1259 1260 1261 1262 1263 1264 1265 1266 VCM, ppm 622 926 1253 841 410 593 1078 764 869 784 1250 1387 966 760 1074 526 930 1133 791 699 1000 1000 836 1656 1075 1430 1622 2613 1716 2528 1411 1121 1265 ucc 054899 TABLE IX RESIDUAL VCM CONTENT OF QSAL-7 SIN SAMPLES March, 1977 Bin 402 05 408 403 * 406 09 12 411 402 405 414 415 406 408 409 403 412 -------- 405 402 411 415 414 412 408 403 406 Date 3/1 It M 3/2 H it tl II 3/3 It (1 3/4 II It 3/5 ii II 3/6 il H II 3/7 ii (t it Ii VCMjjpjWL 55 237 28 6 25 3 5 35 9 5 38 <1 5 9 36 14 49 40 18 24 26 40 23 7 50 18 UCC 054900 Bin Date 412 406 408 405 414 402 403 415 411 412 405 408 414 409 406 415 414 403 408 402 411 405 403 406 415 409 405 402 403 411 414 406 412 604 605 402 415 408 3/9 ii H M II 3/10 ii ti 3M /11 il 3/12 n il 3/13 i ii ii ii 3/14 ii 3/15 3/16 ii ii ii <i 3/17 ii ii ii ii ii ti 3/18 it H ll TABLE X RESIDUAL VCM CONETNE OF QSAN-7 BIN SAMPLES March, 1977 VCM. ppm 22 21 34 5 41 23 15 35 12 18 25 15 22 20 53 32 37 44 31 134 27 162 <1 13 27 30 44 48 2 22 44 53 14 9 19 4 6 105 Bi_n_ Date 409 401 404 403 405 606 411 412 408 415 407 606 602 411 414 402 406 601 409 607 405 403 412 406 605 415 609 411 401 403 608 602 606 408 414 402 412 403 3/18 H M ii 3/19 H H 11 3/20 ii II il II Ii ii 3/21 n il ll ll ii H 3/22 Ii ii n il 3/23 II il ii ii ii II II 3/24 VCM, ppm 11 25 <1 27 <1 8 3 26 1 5 31 11 1 4 37 5 29 8 42 18 62 71 105 36 19 41 74 13 21 18 21 85 80 62 37 52 11 23 Bin 604 406 601 603 412 415 607 608 403 405 601 603 609 605 606 608 406 409 411 414 604 606 410 609 411 601 604 415 402 403 406 608 412 605 405 415 607 Date 3/24 II ll 3/25 It 3/26 II II II 3/27 3/27 II 3/28 ll It 3/29 Ii ll ll 3/30 II It It II II 3/31 II VCM, ppm 59 17 90 135 62 10 13 9 8 30 10 61 7 39 50 28 18 28 5 12 7 8 5 8 83 6 20 10 21 32 31 54 43 32 48 5 28 ucc 054901 TABLE XI RESIDUAL VCM CONTENT OF QSAH-7 BIN SAMPLES March, 1977 Bin 608 606 603 * 609 608 602 605 601 604 603 608 605 601 602 604 606 605 609 603 602 606 602 608 609 604 603 605 609 608 602 606 605 603 608 601 602 Date 3/1 ii 3/2 3/3 ii tt 3/4 it 3/5 it 3/6 H 3/7 II ll It 3/8 II 3/9 II M 3/10 ii H 3/12 H II II 3/13 II II 3/14 ll ll It ll VCM. Dpm 247 P9 i 24 427 365 380 4l9 268 :68 34 66 220 515 208 653 507 209 238 276 248 282 533 238 991 490 321 331 427 506 317 554 647 464 519 345 262 UCC 054902 TABLE XII RESIDUAL VCM CONTENT OF VSJE-10 BIN SAMPLES March, 1977 Bin 708 709 702 703 707 704 702 705 706 708 709 707 709 706 703 703 706 703 708 704 705 701 702 704 707 703 705 Date 3/22 II 3/23 II H II 3/24 II II 3/25 II II II II II 3/26 II 3/28 II II 3/29 it 3/30 H ii II 3/31 VCM. Dpm 1578 602 968 1041 1577 952 878 1563 890 1117 577 744 481 586 595 301 314 315 573 313 560 282 892 524 529 1118 2530 ucc 054903 TABLE XIII RESIDUAL VCM CONTENT OF VXKK-10 BIN SAMPLES March, 1977 Bin 704 707 708 705 706 702 703 709 701 708 702 704 705 707 709 706 708 702 703 704 709 707 706 709 701 705 708 707 703 702 704 701 706 707 704 709 701 707 Date 3/1 li II 3/2 tl 3/3 tl II l II ll 3/4 ! II II 3.5 II II ll ll 3/6 II ii II 3/7 II ll II II 3/8 3/9 II II 3/10 II 3/11 II VCM, ppm 1062 1625 1686 1210 822 1569 1470 1348 809 1556 1864 1361 1825 1191 1464 1965 2618 2174 2036 1712 2165 1680 1527 1863 1708 2286 2801 1286 1584 1593 769 1006 1308 425 579 304 614 3480 Bin 703 708 704 706 702 703 705 704 709 708 704 707 705 701 706 703 702 709 704 707 708 7C2 703 704 701 705 706 709 707 708 702 703 704 705 703 707 702 705 Oate 3/11 3/12 ll 3/13 M II II II II 3/14 n 3/15 It If ll 3/16 ll II II II II 3/17 ll II 3/18 11 II II 3/19 II 3/20 II 3/21 II II II II II 577 1389 2225 1586 893 1058 1267 1352 1491 2467 1889 1092 1272 1300 645 1273 1911 1933 1546 1836 877 1213 1194 1387 1064 1079 1105 1445 1151 1780 2032 1652 885 1665 1715 1449 769 693 UCC 054904 t TABLE XIV RESIDUAL VCM CONTENT OF NON-SOLVENT BLEND SAMPLES March, 1977 Blend 1483 1483 1494 1494 1494 QYNL Box 576 830 * 521 322 781 VCM, ppm <0.2 <0.2 8 13 <0.2 Blend 3951 3955 3955 3955 3956 VYNW Box VCM, ppm 871 4 644 17 342 14 646 5 211 26 1494 506 2 3956 753 39 1501 TR 4381 <0.2 3962 597 <0.2 1501 TR 4380 <0.2 3962 119 12 1502 TR 4132 1 3962 766 17 3966 - <I 3969 TR 4380 <1 ucc 054905 TABLE XV RESIDUAL VCM CONTENT OF SOLVENT VINYL RESIN BIN SAMPLES March. 1977 VMCH Bin VCM, ppm 82 <0.2 82 <0.2 72 <0.2 VMCC 31n VCM, pi 74 < 0.2 81 < 0.2 74 < 0.2 83 < 0.2 71 < 0.2 82 <0.2 VYHH Bln VCM. ppm Bin VCM, p| 52 < 0.2 11 < 0.2 33 < 0.2 12 < 0.2 53 < 0.2 21 < 0.2 54 0.6 22 < 0.2 41 < 0.2 14 < 0.2 31 < 0.2 12 < 0.2 51 < 0.2 21 < 0.2 32 < 0.2 23 < 0.2 44 < 0.2 22 0.6 34 < 0.2 13 < 0.2 43 < 0.2 33 < 0.2 52 < 0.2 41 < 0.2 53 < 0.2 42 0.8 54 < 0.2 42 < 0.2 31 0.6 32 < 0.2 51 < 0.2 41 < 0.2 43 < 0.2 34 < 0.2 52 0.9 UCC 054906 DISTRIBUTION TEXAS CITY Mr. R. M. Arnold Mr. M. E. Eisenhour Mr. R. L. Frantz Mr. W. T. Gray Mr. J. L. Hockersmith/F. L. Johnson Mr. R. F. Keefe Mr. W. a. Mazzolini Dr. C. E. Moyer/D. R. Montgomery Mr. F. S. Provenzano BOUND BROOK Dr. R. J. Anderson Mr. T. F. Archer Mr. H. Johnson NEW YORK OFFICE Mr. R, W. Annonio Mr. J. B. Hollingsworth Mr. R. W. Lasher Mr. G. T. Scott SOUTH CHARLESTON PLANT Mr. C. E. Fry Mr. R. N. Wheeler UCC 05490"?