Document oGLzB4VQw8pEjDEx4aj71b3g

SCOPE REPORT CEA 2l8 AROCLOR DISTILLATION NEWPORT HONS 03S974 APPR0PR3 ATI ON SCOPE REPORT CBA 2518 AROCLOR______DISTILLATION NEWPORT PLANT - SOUTH VALES Date t October 34 1971 Prepared bvi A.J. Heinze S. Wood Approval signatures are on the following page Thie document is the property of Monsanto Company and the recipient is responsible for its safekeeping and disposition. It contains confidential information which must not be reproduced, revealed to unauthorised persons or sent outside the company without proper authorisation. MONS 038975 : *1: (f W. |j, I? i di. i * I Specialty Products Business Group Mr.nuf a: liu'i.Mg business Group - Europe lv.V. kcekea Manufacturing Hcpi <. ^envolive (Newport) ..Clifcnk n. Sisley r 'Works Mruvigor (Kovport) D.B. Sheen n Mrmifacturing Manager, Business Group - U.S.A ProJcc t Manager -v J,R, SavaIggCe i E. iiackhursl r' A?/1/ ?S rr. W;?-7/ Ar.1r.7r .V/?s/?y. . 8 (lAu-ff;, l MONS 038976 DISTRIBUTION FULL COPIES Copy No. CEP - EUROPE 1 2 3 k 5 6 7,8,9 10 11,12, 1 3,1* F. R. Ashby P.H.Darmer/N.H.Beechey A. Akroyd F.Campbell/D.F.Bailey/R.F.Bean B. Clegg/1, Christie M. J. Hemingway J, E. Backhurst (3) Field Construction Engineer Design Co-ordinator (*0 SUMMARY ONLY Copy No. a b CEP - EUROPE C.L.Pari eh/C.R.Young J.S. Brough ST,. LOUIS IS A. J. Heinze 16 R. M. Kountz 17 R. E. Howard J8 J. R, Savage 19 J. M. Depp 20 R. L. Miller 21 S. B. Johnson 22 Central File 23 W. R.. Richards 2k F. j., Holzapfel 23 F. P, LaBelle 26 R. E. Lenz 27 M. Dmytryszyn BRUSSELS 28 E. V. Weekes NEWPORT 29*30,31 H. Disley (3) ST. LOUIS 0 H.S.Bergen d T.L.Gossage e E.M.Potter f G.G.Kosup BRUSSELS g N.H.Dahlstrom/P.J,Marsh NEWPORT MONS 03897 7 TABLE OF CONTENTS I.PROJECT SCOPE SUMMARY A. Title B. Objectives C. Tone D. Design Capacity E. Project Status F. Description of Facilities G. Check List II. PROCESS TECHNOLOGY A. Process Description B. Technology and Status of Process C. Raw Materials D. Products and By-Products E. Yields and usages F. Manning G. Waste Streams, Pollution Sources and Control H. Personnel, Property and Public Hazards III. BATTERY LIMITS FACILITIES A. Design Capacity B. Flexibility C. Future Expansion D. Physical Appearance E. Storage and Shipping F. Description of Facilities IV. EX-BATTERY LIMITS FACILITIES A. utilities Summary B. Description of Facilities V. EXPENSE ITEMS VI. FIELD CONDITIONS A. Intermediate and product Specifications B. Equipment Information Summary Sheets C. Utility Summary and Requirement Sheets D. Process Flow Diagrams and Material Balance E. Instrument List F. Plot Plan and Preliminary Equipment Layout G. Scope of Work H. Electrical Area Classification J. Exclusions K. Preliminary Project Schedule L. Initial LP & EC Review Reports PAGES 1 - *1 5-8 9 - lU 15 - 16 17 18 2 pages k pages 2 pages 8 pages 2 pages 3 drawings 9 pages 1 drawing 2 pages 1 page 6 pages MONS 038978 PROJECT SCOPE SUMMARY A. Title Project Title: Product Name: Division: Plant: CEA Number: Expected Cost: Expected Completion: Aroclor Distillation - Newport Aroclor 1016 Organic Chemicals/International Newport, Mon. Great Britain 2518 About $1 ft December, 1972 B. Objectives Recent pollution problems associated with polychlorin ated biphenyls (PCBs) have created a need for PCBs with minimum amounts of the more slowly degradable homologs. The primary objective of this project is to provide the necessary manufacturing facilities to pro duce a less persistent product (Aroclor 1016) in the ecology at a volume consistent with current and fore seeable sales requirements. C. Tone Due to the ecological nature of this project, the mini mum time for project completion consistent with low cost is required. Hence, no overtime engineering or construction work is planned. Furthermore, no premium iB allowed for abnormal expediting and contracts will be let on a lump-sum basis where cost savings can be attained. D. Design Capacity The design capacity of the new column Bystem at approx imately 90% O.S.T. is 12.5 M lbs./year of Aroclor 1016 overhead product. This Aroclor 1016 design rate represents a 21% excess capacity over and above the expected Aroclor 1016 sales volume for the year 1976 as shown on the July 20, 1971 Aroclor sales forecast for Europe. MGNS 038979 2 E. Project Status All pertinent research and engineering information are available for the design of the new column system. Furthery the design work on the Newport column project will be supplemented by the experience already gained on the currently operating WGK Aroclors distillation column. Therefore! process risks are minimal. Al80t the same manufacturing process currently used at the Newport plant will be employed to produce the crude Aroclor 11^2 feedstock for the column. F. Description of Facilities This project provides for the installation of distillation facilities to produce Aroclor 1016 as an overhead product from crude Aroclor 11^2 feedstock. These new facilities include a 30-1 ray vacuum distillation column uxtd auxiliaries and a new crude Aroclor intermediate storage tank. Existing raw material and finished goods tankage will be utilized. One new finished product tank is provided. The new column and auxiliaries will be located west of the existing Aroclor building 35 at the Newport plant. A new small control panel for the column pane1-mounted instruments will be installed in the existing Aroclors department control room. New starters for motors will be incorporated into a new motor control centre in an extension of the existing Aroclors switch room. The main electrical supply will be in common with that of the existing Aroclors switch room. The project utility requirements will be supplied as extensions of the existing Newport plant utilities facilities. MOWS 038980 - 3- G. Chock List Page number or appendix number is entered for each item. If item does not appear in the report or an appendix, X is entered instead of page number. An explanation for each X entry ie given at the end of this eection. 11. PROCESS TECHNOLOGY Process description Technology and status of process Raw materials Products and by-products Yields and usages Manning Waste streams, pollution sources* control Personnel, property, public hazards III. BATTERY LIMITS FACILITIES Design capacity Flexibility Future expansion Physical appearance Storage and shipping Description of facilities Process flow diagram Engineering flow diagram Preliminary plot plan Building and site requirements Equipment information summary Instrument list Piling list Excavation requirements Foundation requirements Supports, platforms, structures Piping index Sewers Item 51 62 63 .. ,6J 7 .7 . 7 8 5 6 7 8 99 12 10 12 11 12 12 13 13 13 14 D 15 16 F 17 K 18 B 19 E 20 G 21 G 22 G 23 G 24 G 25 G 26 MONS 038981 4 IV. EX-BATTERY LIMITS FACILITIES Utilities summary Description of facilities Engineering flow diagram Preliminary plot plan Equipment information summary Excavations and foundations Supports, platforms* structures V. EXPENSE ITEMS Dismantling Repairs Relocation and modification VI . FIELD CONDITIONS Item c 27 15 28 29 30 31 32 33 G 36 G 35 G 36 (183)37 EXPLANATION OF X ITEMS X 16 Process Design not complete. X 18 Adequately covered in Appendix G. X 29,30,31,32,33 Utilities supplied as extensions, to existing facilities. MONS 038982 5 XI. PROCESS TECHNOLOGY A. Process Description Aroclor 1016 Aroclor 1142 (column feed) will be produced vie the existing manufacturing process in two of the three (3) existing batch chlorinators and batch blow (aeration) tanks. Recovered HC1 from the chlorina tion operation is sent to the muriatic acid depart ment, as presently done. The air-blown crude Aroclor 1142 is transferred into a new 16,500 imp. gallon storage feed tank. The new column system is operated semi-continuously in which two equal-volume fractions are distilled over at 3:1 and 5:1 reflux ratios. An initial 1142 charge, including lime, will be pumped into the column still pot. Vapors are then generated by pumping the still pot liquid through the oil-fired reboiler and the column is put on total reflux. After temperatures have lined out, distillate product is cut forward and pumped through the existing Porocel column to storage. As distillate product is withdrawn, an equal volume of crude Aroclor 1142 enters the still pot on level con trol. The last (approximately) 2.5% of the total over head product is taken off at 5:1 reflux ratio with the 1142 feed shut off. With the distillation completed, the pot residue is transferred to the residue surge tank. Residue from the residue surge tank is pumped to the existing still (1207) where "high boilers" are taken overhead and Montar is removed. This distillate high boiler stream is then batch chlorinated to Aroclor 1154 and 1160 in the existing No. 3 chlorinator. The Aroclor 1154 or 1160 is then distilled in the existing 1207 still, refined in the existing earth treatment facilities and then pumped to storage. The following reference gives the process details for the Aroclor 1016 product: "Tentative Process on MCS 1016", Report No. P-1579 dated 7 October 1970 by J. E. Silver. M0NS 038983 6 B. Technology and Status of Process Aroclor 1016 The design of the new distillation column facilities proposed for the Newport plant is essentially identi cal to the currently operating WGK Aroclors column system. The only significant difference between the two locations is the method of crude Aroclor 1142 production. Aroclor 1142 is produced continuously (both chlorination and air blowing) at WGK versus batchwise 1142 production at Newport. All process design data are available and considered adequate for this project. Process risks associated with this distillation technology are minimal. No design scale-up difficulties are anticipated and no exotic materials of construction are involved. The new equipment will be mainly carbon steel. Existing facilities (chlorinators, blow tanks, etc.) will be utilized for the production of crude Aroclor 1142 feedstock as currently done. Existing raw material and finished product tankage will also be used with some changes in service compared to present operation. Utility requirements for the new distillation column system are such to need only extensions of the exist ing Newport plant utilities facilities. C. Raw Materials The basic raw materials (biphenyl, chlorine and ferric chloride) used to produce Aroclor 1142 will be the same as currently used. The Aroclor 1142 currently produced in the batch chlorinators will be used as feedstock for Aroclor 1016. The in-plant specification for Aroclor 1142 will be the same as currently used. Aroclor 1142 will be stored in a new 16,500 imp. gallon storage tank which will serve as surge volume between the chlorinators and column system. D. Products and By-Products On completion of this project, the Newport Aroclor department will be producing six Aroclor products. These are (i) A-1016, (2> A-1221, (3) A-1254, (4) A-1260, (5) A-1248 and (6) A-1242. Aroclors 1260 and 1242 are forecasted to phase out of the market at the end of 1975> The Aroclor 1016 and Aroclor 1221 product specifications are Ino-luded in Appendix A. Marketing cannot-at this stage confirm that the Aroclor 1016 specification will meet European requirementss Should further post distillation treatment be found necessary (e.g. an additions \ porocel column) it will be the subject of a variance on this scope. No provision is made in the project at present as it is probable that the Aroclor 10l6 will meet European requirements* The product specifications for Aroclors 1242, 1248, 1254 and 1260 will remain the same as currently used. Shipping of all the Aroclor products will be via drums or road tanker as per current practice. HONS 0 3 8 9 8 4 7 E. Yields and UBages Crude Aroolor and lime usages for Aroclor 1016 pro duction is as follows: Material Aroclor 1142 Lime Usage Lbs./lOO Lbs. 122.0 0.13 For Aroclor 1016, the remaining 22 lbs. of Aroclor 1142 feed is the still pot residue. This residue is further distilled in the existing Aroclors depart ment still where about 98% of the residue is re covered. The recovered residue distillate is further chlorinated to Aroclor 1254 and 1260 products. F. Manning There will be no change in the Aroclors department manning requirements as a result of this project. The new column system will be designed such that the process can be monitored from the control room and many of the operations can be executed remotely from the control panel. Operator attention in the depart ment will be required mainly for making up lime slurry for each column run. G. Waste Streams and Pollution Sources and Control The major potential waste stream which would require disposal (incineration) is excess residue or high boilers from the column operation. One of the basic economic premises of this project is that all the column high boilers will be further chlorinated to Aroclor 1254 or 1260. With the current Aroclor 1016 sales forecast, all the high boilers would be con sumed in making the forecasted volume of Aroclor 1254 and 1260. However, a product requirement im balance could occur such that the high boilers' pro duction would exceed the higher Aroclor requirements. Should this situation materialize, the excess high boilers would be sent to Purle Bros, for incineration. The Montar (1207 still bottoms) waste volume should be the same as present. We anticipate no change in the disposal of this waste as a result of this project. MONS 038985 8 G. Waste Streams and Pollution Sources and control (con'd) The Aroolor atmospheric emission from the new column jet ejectors should be in the order of less than 1 lb./day. H. Personnel. Property and public Hazards The project will not create any new hazards in the Newport Aroclors department compared to the present manufacturing process. Precautions must be taken by personnel when processing or transferring Aroclor at high temperatures. MOHS 038986 9 III. BATTERY LIMITS FACILITIES A. Design Capacity 1. New Column System The design capacity of the new column system at approximately 90% O.S.T. (7,900 operating hours/yr.) is 12.5 M lbs./year of Aroclor 1016. The anticipated column cycle time (EX chlorinator hold-up time) is 64 hours/run, broken down as follows: Hours/ a. Charge initial 1142, heat charge, establish Run trays inventory and line out temperatures. 3.0 b. Distill 3:1 reflux ratio 24.0 c. Distill 5:1 reflux ratio (including boil down) 36.0 d. Cut burner and continue circulating 0.3 e. Pump out residue and turnaround ColumnCycle Time 0.7 64.0 The actual total column cycle time will be approx imately 68.5 hours/run which includes sufficient time for crude Aroclor 1142 volume accumulation from the chlorinators. To minimize the Aroclor time-attemperature in the still pot/column system, a minimum of approximately 2900 imp. gallons of Aroclor 1142 will be accumulated in the crude storage tank prior to a column run. 2. Crude Aroclor Production The nominal total capacity of the existing_three batch chlorinatorB (and blow tanks) is 20 M lbs./yr. This crude production capacity is adequate through 1976 and beyond based on current sales forecasts for all Aroclor products. Chlorinator occupancy calculations for years 1973 and 1976 based on current sales forecasts are shown on Table 1. chlorinator capacities when producing Aroclors 1121, 1142, 1148, 1154 and 1160 are given in Table 2. M0NS 038987 TABLE 1 Aroclor Product 1016 1221 1248 1254(4) 1254(5) 1260 Aroclor Crude 1142 1121 1148 1154 1154 1160 Crude IrTroauct 1.22 1.03 1.03 1.03 1.03 1.03 Crude Rate R/raonth(l) 1-22(2) 0.70(3) 0.60(3) 1.36(3) 0.54(3) ' 0.55(3) Aroclor Product Product Sales M*(6) 1973 Req^d Crude M# Chlorinator Months Nos. 1&2 No. 3 Chlorinators Chlorinator 1016 8.7 10.61 8.7 -- 1221 0.6 0.62 -- 0.89 1248 2.4 2.47 -- 4.12 1254(4)) 2.13 -- 1.57 1254(5)) 3.4 1.37 -- 2.54 1260 0.1 0.10 -- 0.18 No. 3 Chlorinator Occupancy 9.30 Product Sales M*(6) 10.3 0.9 1.6 4.4 -- 1976 Chlorinator Months Req_M Crude Nos. 1&2 No. 3 M# Chlorinators Chlorinator 12.57 10.3 -- 0.93 -- 1.33 1.65 -- 2.75 2.53 -- 1.86 2.0 -- 3.7 ---- 9.64 NOTES cx z u oo 4 OD 1. Rate at 9096 O.S.T. 2. 1142 rate from 2 chlorinators. 3. Rate from 1 chlorlnator. 4. 1154 made from distilled residue. 5. 1154 made from biphenyl. 6. From 20 July *71 forecast. This latest forecast dated 23rd September 1971 shows Aroclor 1242 gradually being phased out as Aroclor 1016 is phased in over the period 1973-76. The crude 1142 requirement does not change. o TABLE 2 NEWPORT CHLORINATORS1 CAPACITY Cycle Time, Hrs. Charge Biphenyl (Residue) Chlorinate Circulate and Sample Pump Out and Turnaround Total Cycle Tin Batch weight Per Chlorinator, Lbs Lbs/Hr/Chlorinator @ 90% O-S.T. M I>s/Month/Chlorinator 1121 0.30 3.5 0.25 0.35 4.4 4700 961 0.70 1142 0.30 6.75 0.25 0.35 7.65 7200 847 0.61 1148 0.30 8.0 0.25 0.35 8.90 8200 829 0.60 1154(1) (0.40) 3.25 0.25 0.4 4.3 9000 1884 1.36 1154(2) 0.30 9.8 0.25 0.4 10.75 9000 753 0.54 1160(2) 0.30 12.1 0.25 0.4 13.0 11,000 761 0.55 Notes: 1. Made from Aroclor 1016 residue. 2. Made from biphenyl. HONS 0 3 8 9 8 9 - 12 - JJ1, Battery Limits Facilities B. Flexibility The new column and Auxiliaries will basically be designed for immediate and foreseeable future Aroclor 1016 requirements. However, selected equipment items including the crude Aroclor storage tank, still pot, column condenser and reboiler is sized also to permit producing 12. 5^ lbs/year of MCS-1043 based on Information available at this time. MCS-1043 is a more biodegradable possible future replacement product for Aroclor 1016. This equipment will also provide flexibility for the batch distillation of Aroclor 1111 to produce MCS-1109 (monochlorobiphenyl) at a reduced rate if and when a market is actually developed for this material. C. Future Expansion No specific provisions are provided in this project for future expansion with regard to the Aroclor 1016 product. Depending on the final research process for MCS-1043> an additional receiver for 4-4* - dichlorobiphenyl fraction may be needed for the production of this material. Also, due to the relatively high crystallizing point of this 4-41 cut, it may be neceaoaTy to change the condenser cooling medium to Santotherm 66. Should this need materialize, a email pump tank and Santotherm cooler would be required. Space near the column will be reserved for possible future installation of this equipment. (Note: the present tempered water pump could be used for circulating Santotherm service.) | Should a market develop for MCS-1109, new facilities (gas scrubber) may be required to remove biphenyl from the HC1 off-gas prior to use as muriatic acid. Comparable facilities have not as yet been installed at VGK and therefore this area of MCS-1109 manufacture has not been demonstrated. D. Physical Appearance Paragraph (f) of this section adequately describes the general type of construction to be employed for the new column system. One special consideration inherent in this project is adequate provision to minimize the possibility of allowing Aroclor materials (PCB's) of significant quantity to enter the environment, such as through spills, equipment leakage, etc. This objective will be achieved through the use of concrete slabs under and curbs around all new equipment installed on this project which contains or handles PCB's, HONS 038990 - 13 - E. storage and Shipping Existing facilities will be used to load tank trailers and to produce the required Pyroclor blends. No exten sions are to be made to the existing loading/unloading facilities. The finished goods from the Aroclors department will be stored in existing aluminum storage tanks as follows: Product Existing Tank Item No. Volume Imp. Gal. Aroclor 1016 1308,1312 40,000 Two Tanks Aroclor 1221 1286-2 6, 230 Compartmented Tank Aroclor 1248 1286-1 6,230 Compartmented Tank Aroclor 1254 Aroclor 1260 Aroclor 1242 1305-1,2 1225-2 1307,Nsv 12,470 5,800 l573O,007 Compartmented Tank One Tank Two tanka The product specification sheets for Aroclor 1016 and Aroclor 1221 are included in Appendix A of this report. The specifications for the Aroclor 1248, 1254, 1260 and 1242 products will remain as currently documented. F. Description of Facilities The following information is included in the Appendix of this report: a. Equipment Summary Sheets - Appendix B b. Process Flow Diagrams - Appendix D c. instrument List - Appendix E d. Plot Plan and Equipment Layout - Appendix F e. Scope of Work - Appendix G f. Electrical Area Classification - Appendix H The major equipment items to be installed for the produc tion of the Aroclor 1016 product are as follows: MQNS 038991 14 F. Description of Facilities (cont'd) 3. Distillation Column and Still Pot - A 30 sieve-tray column integral with 17,000 imp. gallon still pot. Carbon steel* insulated, and self-supported unit. 2. Column Condenser - A 475 sq.ft. Monel (tubes) shclland-tube unit supported above the top of the column for gravity reflux return back to the column top tray. 3. Column Reboiler Furnace - A vertical, oil-fired tubular heater rated for 4.0fl BTU/hr absorbed. 4. Residue Surge Tank - A 7,500 imp. gallon, horizontal, steel, insulated saddle supported vessel. 5. Crude Aroclor Storage Tank - A 16,500 imp. gallon, steel, insulated storage vessel. 6. Finished Product Aroclor Storage Tank - A 10,000 i. gallon steel, insulated storage vessel. HONS 030992 15 IV. EX-BATTERY LIMITS FACILITIES The utility requirements along with the various utility sources are discussed below. A. Utilities Summary The utilities summary and requirements sheets for the new column system and auxiliaries installed as part of this project are attached as Appendix C of this report. B. Description of Facilities The required utilities for the new column system will be supplied as extensions of the existing Newport plant utilities. Sources of these utilities are as follows: 1. 175 PSIG Saturated Steam - The design requirement for 175# steam is 770 lbs/hr. Connection will be made to the existing 3" line supplying building 35 2. Cooling Tower Water - The design requirement for cooling water is 100 1GPM. Connection will be made to the existing 6" header feeding building 35 and will bo immediately pressure-boosted by item 1-116 before distribution. 3. Fuel Oil - The reboiler furnace will be fired with gas oil with the following typical properties Specific Gravity 0 60F Flash point (PM) F Viscosity, Kinematic # 100F LS Water jt vol. Conradson Carbon $ wt.(10$ btms) Ash wt. Sulphur <f> wj. Pour point F Sediment, mg/lOO ml. Initiai boiling point C Final boiling point, C Gross Htg. value BTU/lb Net Htg. value, BTU/lb 0.890 l60 2.8 Negligable 0.03 0.0002 0. 30 15 0.3 195 350 19610 18390 The source of this oil for the new reboiler fur nace will be the existing 3940 fuel oil tank. The design fuel oil usage rate is 37 IGPH. 4. 100 PSIG Plant Air - Design requirements are 3,500 ACFH. This air will be supplied from the exist ing 2" supply header. MONS 038993 16 B. Description of Facilities (cont'd) 5. Electrical - Design requirements for 4l5 v power is 88,5 connected HP. The power supply source will be existing substation "C". 6. Process water - Design requirements are for 5 IGPM and will be taken from a new connection on tho existing 8" main. 7. Nitrogen - The supply will be taken from a new tie in to the nitrogen main running along 3rd Street. Usage will be a nominal 25 S.C.F.H. HONS 038994 EXPENSE JTBMS No major expense work is J.nvolvod. work refer to AppondJx (j. For specific expense MGNS 038995 FIELD CONDITIONS The installation is in an existing plant and will be by contractors* Installation will take place in the period spring to winter. Interference to existing production facilities will be kept to a minimum by making use of routine shut downs but two weeks of process downtime will be budgetted* Utilities shut downs will be required for tie-ins to the process water and nitrogen mains. The labour conditions at the site are satisfactory and services and access roads are adequate. A waste area retaining wall just north of 3rd Street will be removed to improve access to the tank farm area of the project. No difficulties are invisaged in locating temporary construction offices and warehouse. HONS 038996 AROCLOR 1016 TENTATIVE SPECIFICATIONS Appendix A-l Unrestricted Information (R) Color (APHA) (R) Condition (R) Sp. Gr. at 25/15.5 C. (R) Acidity (rag. KOH/g.) (R) Moisture (R) Refractive Index at 25C. (R) inorganic (Free) Chlorides (R) Pour Point (R) Dielectric Constant (60 Hz at 100 C) (R) Resistivity (500 VDC at 100C, 0.1" Gap) (R) Hydrolysis Stability Test (As Chlorides) (R) Monsanto Stability Test (As Chlorides) (R) Distillation Range (ASTM D-20 corrected) 10% Distilled by Wt. 90% Distilled by Wt. (R) Penta and Hexachloro Biphenyls* Sulfates Dielectric Strength 9 25C. KV Flash Point, F. Fire point Corrosion Test (6 hrs @ 210C with bright Al foil) Change in wt. of Al % A.C. Color (APHA) A.C. Condition A.C. Acidity (mg. KOH/G) A.C. Inorganic (Free) Chlorides Vise. 9 100F (SUS) 40, max. Clear 1.362 - 1.372 0.010 max. 35 ppm, max. 1.6215-1.6235 0.05 ppm., max. -14C. or lower 4.70 - 4.90 500, min. 0.5 ppm, max. 0.4 ppm, max. 323C. min. 356C. max. 0.4% max. None 35 min. 338 min. None to B.P. 0.0 60, max. Clear 0.010, max. 0.05 ppm, max. 71-81 General Information Specific Heat 9 25C. Coefficient of Expansion <25-65 C) CC/CC C Fixed Chlorine Power Factor 9 100C. Typical Values 60 Hz 1,000 Hz 0.30 0.00068 41.3 t .5% 5% (R) Routine Analysis: all others by request only. By Physical Chemistry Method 71-11, Job No. 1348522. Disc integrator is standard. Electronic integrators may be used after proper standardization against a disc integrator. HONS 0 3 8 9 9 7 Monsanto OROANIC CNCMIC Atl OlVItlON . FINISHED PRODUCT SPECIFICATION PRODUCTION H WllUan. 2/19/69 TlI* Jt. Ault IJISJU- PRODUCT VCUsT " _o_n_TAi ntrnrlaictoiinv_i_ 3-1-69 AA0C10R 1221 PUDouct cook _82*r10_ toIDT. 1 Ann. 608 Ui T,r SllAL_______ 1040-225-04/11-009 . , M. 7 Clbba 3/12/69 IOUALiy v CONTROL (Chtt Cfilat) R. Blovera 3/26/69 C. W. Kllilf 2/15/69 CMCMICAL Y4HHUL* HIX1UU 4//H MtALl * AMAlvaia 2 x 1/2 Ml. Aaber Bottlea G. Miller (R) Condition (R) Color, APHA (R) Specific Brevity (23/15.3*0 (R) Acidity, (Hg K/r) (R) Vlecoelty 9 100*T Clear 100 Max. 1.182-1.192 ' 0.014 Max. 38-41 SIS 4.0-5.5 Cp C-l 046 032 030 049 MONS 038998 Monsanto Afpsa/oix. 3-; CENTRAL * 'MEEKING DEPARTMENT I "AOJCC-r Ntut n 7\ . AroCloR's OisxiLi./VTfON - a/Siaj Port CCUI AMENT NUMHT OTT, 1-1 01-000 1 1-1 OZ-OOO 1 1-103-^ l 1-104- 1 I-1O5-C00 1 EOUIAMCMT name 31 PH *)Y L STORA6 TAUK Sip^e/'Jy CHflR&E PUWP <: ; P H A) y L At> TAnK t)liTlLLrO RE-5>EJU RECEIVE* b!S-T. RE i IDuS TRA'Ji. PumP Slit. MATINS. moocl. ere. 4oo<a imp. G*;.. CrwT^/Pu&AL (.SO ifJip, Ji:, II i 490 ,M A Cf.L. t&fJTPlFu&PL. | AACA*AtO A.-J. Hein-*- a*o*cd .t.c-5 lOUtBMfNT OC3CA1BTION MATCAIALOA coiTue non Steel. IRoiJ STETTL ^TeEL/ AL. ZPCA'/en iRotJ 1- lot-ooo 1- \ 01-000 1- lO"f- OO 1 1-1 08-000 1-109' 1- i io-ooo 1-111- ooo 1 1- wz-ooo \ W-l CHLoR/aJAToR )jC2 CH UORiaj ATOlZ /ooo /< <J/9i. 3-(.'4k t&'-l,* SAM* AS IT. 1-111 srceL 1- 113-060 1 l-l\4-ooo 1 AJ-3 CHLORiuatoR. OFF- Gi AS Cooler 1-1 IS- ooo l 1- 1 lfc-OOO 1 dATCH TAw< TOujER HlATrR P SOST R pup 1- ncs-ooi l P'jMp Motor. HONS 038999 SAME AS IT. l-lll 1 2.0 Sfi?. FT. shell Am* Tl)B *740 iwP. *L. 5lo4> A A-O* \osKSPM (S> -1' TO N rA HP 2 /fflo STEEL CrtiT xcaM _ equipment information mmart CCA NO. j * BASE 2 5-/J 1 1 * ^ INITIAL ISSUC ACT. MO. [ ACT. ISSUED T-lS-TI 1 M Sct-ii ACMAAHS CSTIMATCO v AA ICC cc IS) HoKiiourAi EEx\;t. It.392S-I sup.M'^sro . ExuT. Vt. 39X4/1 VE/JT'CA'L EXliT. IT. 120 1 E Com PARTM6j1E0 SxisT JT. IZ79 E Deleted E rcLTt> "OfLETrO DElETeC TiELETrO DEJ-ETcO VBCT'chl. exur rtr izox/i EH>5T. IT. ilAz/z E*ixt. it. 1242 Exiir. IT. IZ14 xist. rt C5a/tiFoAAl PflZHErb ZTcyT / c PC. N A/ !** *T IOUCl: N -N*W t . CKISTINO A - TO 1C HCLOCATIO Monsanto ______________ /\PPMD1X g-zCEKnAL******w*TM*TM l EQUIPMENT INFORMATION NUMMARY EQUIPMENT SUU( "C**t3 V A.J. HeiutE PBtOVtO AROCLORS DlST It-C ATIO'J - Newport TTT1 (OUIOMENT NAME SIZE. RATINt, MODEL. ETC. COUINIIMI OEtCRIRTIOM MATURIAL or CONSTRUCTION ct no. *** sc zsn 1 St O* ^ initial issue I*. NO. ncv. issueo 7-25-7/ 2. REMARKS a X e ?i ESTIMATE!} PKICI ISJ t- in-ooc 1 fJ -- | Cu>!0 TAPIC. }ZOO/Mfl SAL ____ v-TETL eVERTICAL EXIST. IZ04-/I 1- /13-000 1 1- M-000 1 1- 1 2.0-000 l --------- -------------- z.1- 12,0-0o\ 1- \zl-ooo i-ai-oo i 1 1 V! 1 CRuOE AROC.LOR STORA6E K'o. ( CRuCE ARoCLoCJ Po<MI M? z CRUDE ARoCLOR storag' SToRASE tank HEATHS PANEL M3 2 CRUDE STORA6I Pum P Po*aP motoC. 2<A5o ifl Sal. ________ A/ORU. ___________________ _________________________ __________________________ EXl&T. 4o SPM < -)/UT QBAiTQtPuiAL, ?.Zf TO * /*0A/ EXiiT. Ifc&l 16.5oo "*p. gal. />' d < iz'-r -TEE1_ vert. Flat Z5b*C AtA. sS. tMfosiro Panel! 1Ca TdPfA <*> 9o'TCAf iTEEL CAST /RoaJ ,, I6"<mioE^,. Rolled to f7 (P JfnirAii-rtAL mech. :eal / 0 //P iSae RPW ~ TEFC M aJ M A/ 1- /22-OO0 t i.iwf 5Li!\ Ry TAA^K 4oo ImP. Gal. A'-O* A 5 - 31 __ STEEL VMthal Z/JT'C 30PSI fij 1- I2Z-OOI 1 TA^k A&itatoR. Axi AU Ftooi) TuRl/uf 45 PirtH ST5TL. /So *<=>** kI l-tzn-ooz 1 l-l 23-000 1 A itatoC r/omjL lime Slurry PUM P ? //P / ooo jcr^ ZO XfiAA <*> 32)' TNL CAST /RoiU tefc. CMTi?iFUSAl ACA. JfAL V /V 1-1 23-001 1 PumP /notoR, /.<ao iRPM 1- 124-0 or f- US-GOci 1 I-I25-0OI 30 1- (Z6-0OO 1 l- 127-000 1 1- I 27-oot 1 1- 17. 8-000 C(-124 lf. I-0| I LIME HoiDT Distillation C.O LUM N , fioLUNO TRAy$ COLUMN STILL PoT + - 6 L> 1 ft, TO,-0,,HlSm si vf ryp x s/ic.** 4 Moles 2 ij oot> lM Q'U. *l5T</xn'0'*f. 'TILL ClRC. Fui.iP 2,25'ICP*1 o 9S ` TOH Ri'*'ip McrroR. g2,^^PiCPA, column io^DA^TR. o4?5 r X.T3 pt: tieuCI: N-NDI K EIliTlNS - T O NC LOC * * CD STEEL ,, STfcEL "-- SrEEL lEFC. 350-CLT.SUPPORT. "t F.V. A/ Aet5 'bur'll A/ ,, 18 SPA<l/*J6 VERT. lnjfc*<L! J-Ta'c P.V. A/ CAST STEFLFLLii SVITE,-) CENTRiPuSAL MEZH. -let) L Al --. Ti=c ij imoajfc ^JoWruaes STESl ShEU. 5rLoe i/t-Tuse A/ 24oC FV Monsanto Appendix. B-3 CENTRAL P*r*INEEmN6 DEPARTMENT I EQUIPMENT INFORMATION ?JM#ARV ARoc.lors Distill/\tto*/ -- bi*>po%~r COUI PMCNT NUMSES 1-121-000 ott. I EQUIPMENT NAME 'lOLUMlJ vemt (LoA'OEAjieA 1- 130-000 > |- 131-000 I Columm ejector. C.ouT>Ew.r.irR TEmP. '/iatetC. Pum P SIZE. SATINS, MODEL, ETC. 4-0 Sa. FT. pxts 30 '-ei/tffc' tr/c. JO 2Omm 3.<b I5PM > So'TOH W*. 1 PB(Cl*EO A.O. Heiwte *PB*oED ST zr-t-2,. EQUIPMENT OESCNItPTiON HT(*IIL Q( CONSTRUCTION MOWEl Tu6e3 steel Shell model noitlE 0. T. Eoiiy rAa*t ce o. zi% *C 1 ACE 3 o.4 INITI4L tSSUC C- NO. PCv. ISSUEO r7-IE--7(___ 7_ 11.0 a ^ esTiM* i 'V cr PAICI (Si VERTICAL is.sc. F.V. iJ tjo Stasr waw-Cowi. CE'-TRiTuSAl PflCK/HG a/ Aj 1- I3l-00| 1 1- 1? 2-aoo 1 !- >33-000 1 1- 133-^01 1 \- \34-ooo l 1- 135-000 1 PumP motor. K'iioi/f RECEIVER RESiOug PumP Pump m'ito/S. RE Boiler Fop mace Gas oil Pump ,'ioo /CP *4 75oo /Mfi 5^1. "4> a 14.'-s" i?o 16PM 40* TDK ~l 7v HP 1500 rpm ^0 M 6Tu/*. />J0a. V ten. 44 ftotu 4oisph 1? Ifln PSlG LascM, "Te'L TEFZ. H0K.1l. 3Z>"*r SOASI _______3c' 1 rRif<al n-T PTEEL. Me.CH.SEAL _____ -- 1 t Pc. VERTICAL 5TrL TUBES 01* p#** cast / RoA/ Rotary 6eaa PACKiwfl a/ a; aJ ij A/ |J l-\3l3-ooi 1 Pump motor. \ HP 1600 R P "Tfc FCp |J I-I3&-000 1 1-13,1-000 1 1- 135-000 1 t- 131-a 00 1 GsAS Oil St6.Tan< 0/ STI U- AT E PROD. RECEIVER P0R0C6L Columm FIFO PumP po ROCSL Aj ISOQ IMP. SAL. 4 TSPA4 meteRim& POMp 3-o"<$*lS' Steel ZlTlC- SPRAYER steel CAST rrEEi_ 0 Alum,L/UM Exist. 3A4o Exist. iza 1 EXIST. 1302. EXIST. 13 00 e 1- >40-000 > Aroolor Still ^ \ tt-t STEEL. EXIST, izot 1- I4i-ooo 1 1- t+z-000 1 1- 143-000 1 1-144-000 C E-224 <E . 1-701 1 still Receive*. earth treatment TiM K -iLTeK press PUMP Filtcate Receive*. 9so lloo - __ 'ro&pT(^ O'tcv. - ,, ,. 43 0 /Ay/? SAX. aSOUMCC: M NEW ( CIIITIMS K TO ( MkOCATIO momel o liIC-5PRAYEO c steel BRonze Z/>C- SARAYfO StES-L exist, istis/r AEitATES exut. i*i<s exist, izri/i EXiET. 12*3 Monsanto AppfAJDix B-A CEWTRAL F"~llCCR*WG DtPARTCNT 1 EQUIPMENT INFORMATION SUMMARY UU|(t ARoii.0^5 -------- j Oi;tillatiom - NewpaRr mt. ut'nc, WOOtL. ETC- i-lAS-ooo 1 - \44-ooo \-4T-ioo 1 \ i-t43-ooo 1 1- I4'i-ooo t l- 150-000 1 AfiOQiaR (Z5"4 ^TOR A6E TV'MK. A/- / Al?OCiOR IOH, iron A<s A- IO 1 Co iTOCAGE PumP ASOClo* 12.MZ. StoSagc t^nk. hji ? AfioCLOC loifc Z-re>RAC Tfl uk AROOLOP > 1 C.O :.~oRA<;r PumP 12,470 ImP. Srfi.. Z0,ooo IMP. Crc 7,0, OOO ImR, S>il. ZO. ooo ImP. a`i.. loo Z &P*A s To' tD U 1- 150-001 1 l-\5i-e>o<j 1 PumP MOTOR- ARocloR I2.4Z iToRASE Pump 1 'll. 4P / 5"oe> A/H | 90 X P M a 7' T DM V-15l- ool \ !-1 *5?- 3ev3 1-153.^00 \ i -\54 -ooa 1 l-i5^-ooo 1 PuM p MOTO e_ <>*( * a - x /z-Jg St* Compz - A 11X1 STpa AROCLoR iRll/MJ SToRACE ?UMP AR0C.LOR |iC>8 i.TORAC TAP* ARocloR |Z54 iToft ASE p'JMp T/j. H-f> /Yea PPrA '2,470 ImP. f.ti CtnrtiPi'tAi. 5, 8oo i*>P. Sal. / O XGP*A 7o ' 7-0 M , 1- 155-00 | 1 1 --oo- 1 / ~ ! ''$ - o 00 1 1 - '3 7 - .Wl / Pump AAsTot pic'r^iu.-cr cc**4"J z Sw,>'Ai( r/T TUTcUr. STsiAl,.- -TAlJU.. bSA7 'N6 PAfJSt-i 7 'll. *VP 1 S"oo R PM c P *)*. ' lx 10. ooo i\t. Q4Un- U P* #J X il V ir<- S;s T WHiTT Em ZtrMZJi__r/}h4s-L _ 1- '801 - ooo 1 MOTOR ^SWTRCL ccntr .. . - . HUNS 039002 A.O. He imiE BOVCC 'J H COU>MCNT DtjeTION MTUIAS or constauc 'ioh cs no. ze/s INI Tt w ltOE '7-/S--7/ 1 a c.4 tv. NO. e. itsuec V U 'Cof TI^M* r7e1s "e ___ i * AuuM !(iUM A UUM UM ALUM j W .J A Rlui.i i M v`7*t EXIST. 1305-12 v*r. EV*T* vx*r. I3Q? V/rn 5x-r. 130$ vT4.AU e e AJ - Alum/mpm TeFc. AJ A4^CH IftHL C^T*CPu/lL AJ TEF/L Al HCC/2 xlST.I28-lfZ flLisrs. iT<=FU vre-ru rfc cXiin 12 85 UOE'-ZfXIST. 12HSpl t: AtetM. xtw.. CfWJP'Put^L k/ _________ [ rrtg/ TeFO. Hi** 5*0 % /* Ato;4-y O-- PATft /V PUxM.kum iTEtL - >y^r /I ._ _____________zii___. p ~r .' S V Av/ ---------------i V I j- C(-U< ("*' *'' ______________________________ 1______________________________________________________________________________________ (Ounce N NE* C (HITIH6 ' <o 1C MLOCMIO UTILITIES 5 MMARY Acentral engineering department P Pga/Qix, *e9JEt C-l C**EO S' j OVtC CC* NO Akoclous Distillatioai - biewpoKrr A - 0. HEia/t \ ---------------------------- 1 UTILITY | SERVICE i UNITS INITIAL ISSUE 1 --*--T-e------n------i1-s------n---i--------1 REV. 1 i 3ept: n \ !IVEAASI DCHSN AVCAA6C SCSI SN rr t j . Z5 JB REV. 2 CATC - -J AV|B<C( 1 OCSlCN ! *E* j *SE j 1 \/ REV. 3 2. AVIRASE OCI'C*! R5 Psig, Steam!lbVi/fc Coauik/4 i -i"vuA WrtrCR IXSPNS &>&o (oO Pueu On. Electrical. Process Air. XGi PH Co am1. HP ACFH 25 -- 3 ooo M itRogea/ Pros. WatEft IN5T Air SCFH XG.PM SCFM Zoo 5 to 7 70 C*So 7 7o (T\ 0 IOO too 37 zs 37 (,<,.5 35oo Z47S -- 11.5 WrcOtlTTf-U UKT 3ooo %SaO irgA>r OZB Oi S s g" IS /O / *OZ u> oou> cc i< Blank Space Indicates This Utility Requirement Has Net Been Checked Since Last Revision Repeated Nunkei Indicates This Utility Requirement Has Been Checked Since The Last Revision, and Remains The Same CCKTKAt CM6fNCnwC DC*MTm*7 UTILITIES REQUIREMENTS POR Ne+t SY3TA4 /IgOCLORS PtSTILLATtO*! ^fWPO^r cn Ins psi srfMi Coolm>< "7o*>* FufL 0<l Electric al XgPM igpH Coa/a/. HP P-J. HlNZC x*/t fi. PPEVOiX C-Z "** i*-- > j ^ *- 2 P/fcJCESS As UlTRO&U Fkoc.'Z, HtrsK SC PH SCPH ) X 6 PM ' 1-107 I- 106 l-io9 l-H fe M7.0_ I-I2JL >-<2.2 4?; OKucT Arac_iok. Sr4^ *7# 2, C A v Cc' [tME Su/RET Tit, >-123 >->24 (- I2fr >->27 1-/26 >- >2*1 1-130 1-t 3 > I- l U 1-1341-135 1=JL*5- Rgy Pump LfMg rial i-r Still por Still Pua*P \ie*jr (Lomo. sr*A T-OA Heat< o+jui 5*40 S"0 IKE-SIDCC Pt>MP 0OLVA/77'*'* HLATrH* Q*nX 4t_ |R*frL ffit PlM^ A->?&Q Sts, fWip| Ai24i STC.P.<p R-1254 Snt PoaiP M^fgAC i 'TqtAl 5 56 j--"-- UiP , 40 as 25" _1Z_ 25 3I_ T/e 10 ^T'Tg >0 r/2 T/a 7 V* 7'/ gy.r 3ooo | 35^0 1 --** I ~~ MQNS 039004 /\ __ s > HONS 0 3 9 0 0 5 l >** r <S) I1 ________t__-. I -i __ - . ^ V~!i ` li '.'. 9 0 0 6E0 I w HONS 039009 U--- .T--- _ MATERIAL cgA-XfQA Appta/o/x D-a Km. js Otr. ?J STRgAA* *JumOER(0 1 z St fea^ Nflg CPJOg PKozloA From SToRASf LIM? SwwAny 3 TOTAC. Stiww p*>r 4 jpo/ia feed ARocloS ion. 0PRAricvJ AR'.ILoR lOlfa v^wiw CoaeKi IA10 430 -- ( 3030) (144000) (47 o) (Ji.Sco) (l6S)(l> (It5) 5u V/lPo outlet TO CoWOM*/ tf < > A 6L5 1 [Com p<9&irio<^ 7 Cotv**J 0o*O*f (-IQurO AvE. * 1 fO // fZ / 2 ste/e* % CetuMM CatlNwA fxrEA'Wt auo*sc4 Reflux Ave. Ave. CoLVMM A?oocr A*r. COLV"V Remove veo'r N/c <JA! CooJbeabxa Col4/4^ a/ cJ*T3 2400 - - - - - - (3l,5oo) - -- -- -- -- ((.45) -- -- Tot aw ^'/HK Toru t4oo M 144,<?oo PKsz-.vkc , fc'fi (*) 0 3 345 /do 0 150,000 150,000 12,000 <(,600 7,?oo ITiJ&iS -- -- -- -- -- /do 0 /do **'*/ 300 Ml. (l4o) 175 *4M 35 max. (14) ZCo tf*. Z4o M/w. iSS ** 3CO MAX. 300 MAX- Z4-0 max. (140) (<4o) (40) 5,Soo -- 24 144,000 23,245 d5 (4o) 45* 0 Joo **. 0 1 -- &S 0 WF6U6. 3f (43-) NoTg a \. Sg P*oci ri,M "D'ACfcAM a Herr* 3 *^0 4. Z. A>/t. A*cLeft n+2 Ftro Ratc DuRjmC CoutiaJuouj P*r Pmazc op Column x c 3. UVACE IS 3 - ss LB. BAZt/4'J z In 4. THE Stream i total Lfts/RuJ meiuMS Rm iaJtmw 3J,5o i*J> op ARoCwA H4* CHARGE To THE STiLU P*T. U> <> C IV MbJM rBlBBro ClNTRAL Knsinokino D TBln 1 II 1 IJ STRUMEUT___List || 11 (|PL*NT MEW PORT ..DIVISION. 6R6AN1L. 11_____ ... ApP*rDX -i II., AJ. He i/utf IJoATe.'T-lS-'JI tMICT ~J-- or _^L 1 IX 0.1 ?i iwsr. MS DESCRIPTION TYPE Lot. Auto. Valve SiEf Mat'l. TJR1- I-IIO-I 1-135-1 1-IZ5-2 l-IZS-3 1-125-4 i-iat-t t-l*6-l 1-12*1- \ 1-132-1 1-13-4-1 Multipoint Temp, Pr. 1 Scrubber <54s outlet 2 Column Bottom TRAy 3 Column TRAy Mi 4 Column TOP rfcfiY 5 Columm Reflux u Sti ll Pot Liquid 7 Condenser n/c & fiats ft H/c Eases to Jets 7 PvEmooe Receiver Liquid '0 Rego/LEE ouTi.tr* II SPARE 12 SPARE Record PANEL FI \li- 1 FI III- 1 Fl H3- I LI 120-1 PCv 12.0-2 PCV 110-3 LI 122-1 F=IC 125-5 PDT 125-4. LRC I2L-2 PCV I2L-3 PSE I2L- + FQ Kit FI X.CV XCV 126-2 '28-2 12ft- 3 126-4 128-5 ^ CV US'6 M2 1 CHiofi. A/*. Fu>n Nil N*. 3 INDICA7E INDic A7T ind/catt Local Local Loc/Tc N3z Crude -VToRAcr Level inlet N2 $i'lAtor. Vent ourt.tr RCt,ulA*. indicate -- Panel local. LOCAL Lime Slurrx tank Level I"0ICAT* Local Column Prcisvr* Control IN Die PTC Column PRe t. "Diff eRiental /NDitArf Paajb l PfiHSL. Still Pot Liquid Level 577ll Par A>* RfSuLAreE Still Por RupTUftF DiiC. Record _ -- PANEL Local Local DISTILLATE Total IlCE Dior. Plolu Controlled Reflux Flow Diotill. RiMMr Slock - x r * er -1rC--nXL) " RELIEF VALUE f WATER.) Valve- INDICATE IMDIC ATT 1 N DlC Arc pLUfi, Pa nel Panel Local -- -- ---- -- r C.r. i" c.x. -- r -- Stee l -- /* STEEL i" e.i. (weave l] -- i" -- i'A" ii' -- 3iL s.s. (HL S.i.. Alum. .. . n U* J MONS 039013 IMTRAl KNOtNCIRINO Dimmmint .m.S.iftvj*ioLC LivT UP*0J/Df*T ---- *LANT POfi. T *PIVI||QN_ IWST. KJS PdV 130-1 XCV 130-Z De sc K iPriow type Jfcti 5t-AAa Rt G ULflTafi. _ Sucnou hue /?motc Value Plus CfA NO. ZtML. a n t a no . _,, D * T E .^-`|S *7 f E ' . C 4t/ i LoC. __ -- i>-" FcTT7 A 0 7 f ValuC Size _MAT /" J7E t L 4" TIC 13/- 1 FX 131- X. TemP. WattE QomtKolleH. Tt MPE RED WATCE Flow INDICATE imOic ate Local Local l/i'' SrfE L ---- LI 132- 2 Residue Rteii/tk Ltvei_ tpoic/ne P/1 A/E L -- -- Pse 133-3 Receivc/z Rupture Due. (mooel) FlC PCV FX TX BE /34-Z 114-3 134-4 134-5 134-0 ReeoiLtft Fl.ec Coutroller. Steam PRem. owr, l/ALv Proc, Outlet Flow.) 4 Ctacl temfe* atuRz 4 Flume Failure 4 iMOicAre -- 1/jDlCArE lw{ 1 CA7F -- PawEl -- PAlIFL Loc. Ra.jel ~ 34 * -- -- JrtfL still. -- -- LI 131- 1 tnvr. Recfiver. level IwDicatE PflWEL -- -- Trtt FolcouuwS Liw-MfM/r^o /a/ 5T(fuM*/ri A/Ce Zlt.ro lci.ow;ti : 8- Banrca/-Type Pressure 4ae:. 4- CHeaiiCAL SEAL-TYPE PRESSURE GPGEJ. 4 - Af-OLUTE ReAO/AjS MAHOMbTEK. TYPE VACUUM GACtL. & - Bi-/vibT/it.Lic 7>i/)l THtXMoMfmJ. 5- miic, XwiTduMnir Aift. /ireRegulator: (Vv'iu*) I " ^4 Li'CAL i'l ov. TaT,Unfe - l^n\aCifA iu A/t.'/ I ' 4 Lt>Cul<- ticxjJ ~lo-'AD iFK. FXoii Si- uJAI'E/C fu Z'r't.y . MONS 039014 APPENDIX G SCOPE OF WORK G-l O.l. - Equipment Items Refer to Equipmont Information Summary Sheets, Appendix B. Allowance is made for platforms and cat-ladders to be supplied with major items of equipment as iollows: Item 1-120 Allow 1 ton Items 1-125,1-126,1-128 Allow 3 ton total 02 - Instrument Items Refer to the preliminary Instrument Index, Appendix E. Instrumentation Features Pajjel mounted instrumentation will be electronic, Fisher AC , wherever possible* Where suitable electronic equipment cannot be purchased, pneumatic equipment will be supplied and used with converters. All control loops mounted wholly in the field will be pneumatic and suitably weather protected. Flow, pressure, and temperature Indicators will be direct reading with level indicators having a percontage linear scale. Recorder charts will not necessarily be direct reading. All valve positioners and actuators will Differential pressure level transmitters but displacement type level transmitters and used with converters* be pneumatic. will be electronic will be pneumatic Control Room The control room is existing and is located on the first floor of building 35 (see Appendix F, Drwg. 2518-051-01-X-L2). Approximately 4 ft. wide by 7 ft, high of panel space is available, of which 2 ft. width will be used for this project and the remainder for CEA 2525* Electrical accessories (110 volts 50 cycles) will bo mounted behind the panel. HONS 039015 03 - Setting and Testing Equipment. No unusual difficulties are anticipated. It should be noted that the new fractionator and auxiliary equipment will bo erected inside the existing Aroclors department battery limits and that "tight" conditions may exist as far as the mobility of construction equipment is concerned. (See plot plan and layout drawings - Appendix F). Note that a 100 ft. 50 ton crane is required for erection of the distillation . I | column system. C-2 0/4 - Setting and Testing Instrumonts No unusual circumstances are anticipated. Normal instrument setting and testing factors may be used, after allowing for AC2 instrumentation in the panel. 05 - Piling An allowance is included for a piling site survey. The following equipment will be supported by 50-foot long, 50 ton concrete shell piles: Item No. Description No. of piles 1-120 1-125 1-126 1-132 1-134 1-157 No. 2 Crude Aroclor Stg. Distillation Column Column Still Pot Residue Receiver Reboiler Furnace Pipetrack Structure No2 Aroclor 1242 Storage Total number of piles required 06 - Excavation 4 4 4 j 38 The following excavation and backfill volumes will bo required: Item No. ____________ Description ^^_ Cu Yds Excavation Backfill Ground Slabs (max# depth top surface below 1surrounding grade 1 611) 1-120 No# 2 Crude Aroclor Stg. 1-122 Lime Slurry Tank 1-125 1-126 Distillation Column Column Still Pot 1-132 Residue Receiver 1-134 Rcboller Furnace Misc. Pumps, Etc. 1-157 No2 Aroclor 1242 Storage Totals 500 k 25 28 22 15 30 il 692 100 30 1 5 10 8 3 - 162 Allowance should be made for the costs involved in removal of spoil from the area and unforeseen underground obstructions. MONS 039016 Ci- 'J 07 - Foundations The following colume of concrete is required: Item No. Dcgcriptlon Cu. Yds. 1-120 No. 2 Crude Aroclor Stg. 1-122 Lime Slurry Tank 1-125 Distillation Column [-126 Still Pot 1-332 1-13*1 Residue Receiver Reboiler Surface 1-157 No.2 Aroclor 12*42 Storage Misc. Pipe Supports 6" concrete slab to tank farm (hand trowelled) 6" wide x 1'6" high concrete kerb 6" wide x 9" high concrete kerb 1** 8 25 18 14 12 25 10 150 125 12 Total concrete *113 The following allowances have also been made:- 300 300 U0 25 2 yd_ yd^ yd^ yd^ of of of of Shuttering 6M hardcore for tank farm slab 2" blinding for tank farm slab 2" blinding under foundations 3" bedding of oiled sand for tank for all above foundations. foundations The above includes for 80 ft. run of 12" wide x 9h deep drainage channel in the apron area. 08 Supports. Platforms A Structures (a) 1-122 Slurry Tank Structural steelwork Open tread flooring Handrailing (2 rails) 3 tone 100 sq. ft. 60 ft. (b) 1-132 Residue Receiver Allow steelwork flooring cat ladder 1 ton 25 sq. ft. one of 10 ft. 1 one (c) 1-13*1 Reboiler Furnace Allow steelwork opentread flooring handrailing (2 rails) cat ladder 2.5 100 50 one of ton sq. ft. ft. 20 ft. : ong HONS 039017 G-4 (d) East-West pipetrack Allow steelwork Allow one cat ladder 20 ft. long 10 tons (g) Miscellaneous new steelwork in building 35 and Avenue * B' piperack extension allow 3 tons 09 - Other Building Items p 500 ft. of translucent sheeting are required for sides and roofing of lime slurry platform, 10 - Sprinklers and Fire Protection Allow C500 for possible fire protection at top of column subject to insurance review. This would be linked into local condenser boosted water supply. 33.- PIning An indication of the amount of process and utilities piping can be obtained from the preliminary piping list given below. Process piping will be 150 lb. ASA flanged or screwed pipe and will include considerable parallel steam-traced pipelines. Process pipe handling crude Aroclors upstream fi'om the new column will be steel, Spec. ID-M-E (Spec. 3E-E-F for the reboiler furnace process piping) Process pipe handling Aroclors (distillate) downstream from the new column will be aluminium Spec. 1J2-i'2-H The utility piping to be used is as followsi- UtJ 11 tv Pi pe Ma terial Sizes an-K- Piping Spec. 175 lb. Steam Cooling Tower Water Fuel Oil Instrument Air Nitrogen Process Air Steel Steel Steel Gal Steel Steel Steel i"-3" 1" - 6 " . 11 - 1 .1 11.11. b'-ii" 11.1 fi 1C-M-D 1B-B-B 1C-D-C LA-L-B 1B-A-A 1B-A-A Liberal allowance has been made for steam tracing as the majox'ity of the process pipe will be traced. HONS 03901b 1] - l'jnlng 1 tem Use 101 3 02 3 03 lOlt 105 106 ) 107 ) 3 08 ) 109 ) 310 ) 13 1 ) 112 ) 113 ) 11 Ij ) 115 ) 136 Existing Existing Overflow to 104 Existing to 103 Deleted Extg. Eqpt. To utilities Si y,e Mail. Length Jnsul, Valves 3" C.S. 200 Yes 2" C. S. 200 Yes None 2 3" C.S. 20 No 3 117 138 339 120 123 122 123 125 126 127 128 Existing Existing to 120 to 122 to 121 to 126 Recycle to 120 to 123 Vent Scrubber Recyle to 122 to 126 Bottoms to 126 to 128 to 127 to 139 to 132 to 125 to 137 2" 2" k" V if H" 3" l*" li" IV U" V k" 3" 2" C.S. 170 Yes C.S. 20 Yes C.S. 20 Yes C.S. 30 Yes C.S. 30 Yes C.S. 25 Yes C.S. 15 Yea C.S. 30 Yes C.S. 60 Yes Integral Const. C.S. 20 Yes C.S. 20 Yes C.S, 65 Yes C.S. 60 Yes A1 * 20 Yes A1 . 180 Yes MONS 039019 2 2 1 2 1 2 1 1 2 None 1 2 2 1 2 G-6 3 tom 128 129 130 131 132 133 1 39 135 136 137 138 139 l9o ) ) ) ) l4l 1*12 ) 1N 3 ) 199 ) 195 196 ) 197 ) 198 199 150 151 152 ) 153 ) 159 155 156 801 155 157 Use to 129 to 131 to 125 to 130 C.W.R. to Atmos* to 128 to 133 Vent to 120 Recycle to 132 to 1 NO to Road Tanker to 126 Recycle to 136 to 139 to 135 Size Mil t J . 6" A1. r t. Length 3 nsul. 20 Yes n o o f Valves 1 6" C.S. 110 Yes 2 1" Al. 25 Yes 0 6" C.S. 20 No 1 1" C.S. 80 Yes 2 6" C.S. 15 No None 6" C.S. 120 Yes 9 4" C.S. 20 Yes 1 2" C.S. 50 Yes 0 4" C.S. 20 Yes 2 4" C.S. 200 Yes 3 3" C.S. 290 Yes 5 4" C.S. 75 Yea 2 1" C.S. 30 Yes 2 1" C.S. 120 Yes 2 1" C.S. 25 Yes 3 Existing to 109 3" C.S. Existing to 155 Existing to 151 Existing to Tankers Existing 3" Al. 3" Al. 3,, Al. Existing to 150 3" Al. to Tankers 3" Al. No piping required No piping required Drumming 3" Al. to 151 3" AJ . 200 20 20 130 20 40 80 30 Yes Yes Yes Yes Yes Yes Yes Yes 9 1 1 9 1 3 9 2 HONS 0 3 9 0 2 0 G-7 I tem Cooling Water: Supply Rc turn Main to 127 to 131 to 129 from 127 from 131 from 129 Main Ft. No. of Si zo Mail. L enrth Valves 3" C.S. 1" c.s. 3" C.S. 1" c.s. 1" c.s. 3" c.s. 3 " c.s. 3" c.s. 250 50 60 80 io 70 80 65 2 2 2 2 1 2 2 2 375 Big Steam: Main to 3-120 to 1-128 to 1-130 to 1-132 to 1-1311 Tracing Tracing Tracing Hose Station 2" c.s. 1)00 1 " c.s. 1" c.s. 25 25 1" c.s. 70 1" c.s. 1" c.s. c.s. 25 25 1)00 i" Copper 5000 1" C.S. 1)00 c.s. 60 6 1 1 1) 1 1 12 2*1 2 Trap Assemblies: Allow for 135 trap assemblies (3 valve type TA7A) Condensete: Main 3" c.s. 1)00 3 Main 2" c.s. 300 3 1-120 i- c.s. 30 2 1-132 i" c.s. ^0 2 Tracing i" c.s. 800 A11 owed TA f s Process Water: Main 3-122 Hose Station i" c.s. i" c.s. i" c.s. 300 70 50 2 2 2 MONS 039021 <;-m Nitrogen: Process Air: J t cm Mu i 11 to 1-J26 to 1-132 . Hose station Instrument Air: Main Sub-headers S i y.e Ft. Mu 1 i . l/i-nr M No of Vu Ives . C. S. ;> ,, < C.S. C.S, 2 50 23 25 ;; I 1 * C.S. 2U0 2 2" Gal v. 1" Gal v. 200 200 2 8 The following items have not been included i n the above take off* An allowance should be included in the estimate to cover them. 1. Sight flow glasses - 5 off. 2. Expansion flexibles - 10 off 2", 10 off 3"( 10 off V 321 S.S. 3. 3* Flexible Hose (high temperature) - 20 ft. x 3'* k. Flame arrestors - 3 off say 3M 5. Condensate flash pot - 1 off (l'6M dia x 3 ft) 6. Steam entrainment separator - 1 off V' 7* Instrument impulse line isolation valves 8. Piping high vents and low drains 9. Pipe supports - ordinary supports are adequate 10. Tracing of instrument impulse lines - allow 500 ft, coppertracing; 15 trap assemblies typo TA7A 11. Cutting into existing utilities lines for the tie-ins indicated in Section IV of the Scope. 12. 2 off 3" S.S. eductors required for mixing in tanks 1 -1 *4 6 and 1-1*49 13. The above is estimated to be an 90$ take off. Therefore an additional 10$ should be allowed for missing items. HONS 039022 12 - Ductwork Nono required. 13 - Electrical Starters G- \) Item No. 1-116-001 1-121-001 1-122-002 1-123-001 1-127-001 1-131-001 1-133-001 1-135-001 1-150-001 1-151-001 1-155-001 Description Tower Water Booster Pump Motor No. 2 Crude Stg.Pump Motor Lime Slurry Agitator Motor Dime Slurry Pump Motor Still Pot Pump Motor Condenser Water Pump Motor Residue Pump Motor Gas Oil Pump Motor A 1260 Storage Pump Motor A 125*) Storage Pump Motor A-12^6 Storage Pump Motor Remote HP P .Be n No 10 Yes 3 No 2 No 25 Yes 10 7i No No 1 Yes 7} Yes Z7j} Yes Yes Inter lock Yes Yes No No Yes Yes No Yes No No No The above starters plus a triple pole and neutral switch fuse (required for lighting) will be arranged, along with the starters on CEA 2.525* into one composite M.C.C. and located in what was termed the Fitters Room adjacent to the East wall. No separate incoming isolator is required. Lighting All lighting will be mercury vapour with industrial woll glass fittings with the exception of the top platform of column 1-125 which will have Division 2 fittings. Building 35 will be covered by six new 80W fittings and six relocated fi t.ti ngs . Tank farm grade lighting will be by five pole-mounted 125V fittings Column 1-125,assuming two intermediate platforms, will have two 125W fittings per platform and three 80W fittings on the top platform. Emergency lighting is confined to column 1-125 consisting of throe emorgency lighting fittings having rechargeable batteries with automatic operation on mains failure. Control of the lighting will be by an isolator supplied from the multi-way distribution board in the switchroom. HONS 039023 G- I V Fire Alarm Ono break glass switch will be located at the North end of the tank farm and will bo tied into the existing system. The existing system has its own alarm annunciators and is not represented on the 2518 panel. P.A. System Tho project will provide one new two-way speaker. This will be connected to a spare point in the existing system and will be located in the Northern area of the tank farm. Supply The 300 amp combination fuse switch in the switch room has a spare capacity of not less than 140 amps. The spare capacity is taken directly from the existing bus-bars, extended by cable through the wall to the adjacent room, and feeds directly to the new starter system. Also see Exclusions 11 and 12. Cable All cable will be M.I.C.C. 600 V grade wih black F.V.C. sheathing having a minimum size of 2.5 mm for use on lighting and push-button stations. Distribution to be via heavy gauge galvanised cable tray. bocal Controls Start/stop stations with the stop-locking feature will be mounted adjacent to all motors. Ten will be industrial classification, one flameproof. Motor Classification 1-116-001 1-121-001 1-122-002 1-123-001 1-127-001 1-131-001 1-133-001 1-135-001 1-150-001 1-151-001 1-155-001 Industrial 11 ti it it n Division 2 Industrial 11 HONS 039024 Auxiliary Supply G- 1 1 A six way triple polo and neutral fuse board will supply lighting sub circuits and also the control panel. Field Socket Outlets No provision for welding socket outlets or power points. Earthlng The distillation column will havo coppor straps ovor any flanges so being considered self conducting and will not havo lightning protection. All vessels will bo earthed in two places with a ring type earth system. Earthing materials will be 1 inch by 4 Inch copper tape and 25 mm green P.V.C, covered cable. An earth electrode will be driven outside the Aroclor bund wall. Electrical equipment will be earthed through the cable sheath. Annunciator A new 15*point annunciator is provided (AC^). lU - Site Preparation 11 16 None required. Sewers, Drains and Plumbing Allow for 70' Cl drainage channel covers in concrete slab and covers for two sumps approximately 2' x 2'. Also allow 15* of buried 2" Cl pipe from outside the kerb near the sumps to the existing channel in the road between Building 35 and the tank form. Underground Molns 'A'ilowujice sfiouJd be made for one cooling tower water return tie-in from the now process aroa to the existing underground wator return main. Allow for 25 ft. of 6 inch main, U ft. below grade. 17 - Yards. Roads and Fencing None required. J8 - Rai1 roods None . MGNS 039025 G-12 11 Insulation Thermal Insulation for elevated temperatures will be ns follows; Equipment tops - cftlciuni si 1 icnl.c with P.V.A. mnstic Equi pment s ides (K1032-100-lll5) - rigid glass fibre with reeded and corrognted aluminium. (KIO32-IO3A-I63) Equipment bottom - rigid glass fibre with P.V.A. mastic Smn11 Equipment (K1032-103A-1^5) - glass fibre,blnnket with P.V.A. mastic Items (o.g. glues) (KI032-107-I/15) Pipework - rigid glass fibre with reeded aluminium (K1032-103A-161) See Category 11 for quantity of insulated process and utilities lines. About 20% of the traced lines will be thermonised. The new equipment will be insulated as follows:- Item No. Thickness Surface ] -] 20 1-121 1-122 1-123 1-125 1-126 1-127 1-128 1-131 1-132 1-133 1-150 1-151 1-152 No. 2 Crude Aroclor Storage No. 2 Crude Storage Pump Line Slurry Tank Lime Slurry Pump Distillation Column Column Sti11 Pot Still Circulating Pump Condenser (Heads only) Condenser Water Pump Residue Receiver Residue Pump A 125^ Storage Pump A 1260 Stornce rump A 12^8 Storage Pump 2" 1" 1" 1" 3., j,, 2" 1" 1" 3" 2" 1" 1" 1" 735 5 100 5 1,350 975 5 30 5 660 5 5 5 5 Allowance should be mode for instrument metering applications and for Insulation required on steam and condensate line* and steam trap assemblies. 1-120 will .stand on a 2 pad on fibrous glass (K1032-103). 20 - Painting The main painting requirements will be much of the steel platforms, pipe gantries etc., listed under Code 08. Painting in accordance with the current Newport plant practice for the Aroclors department (Exposure Category "C"). Pipe supports, nitrogen, air, uninsulated water line. 21 - Walls, Masonry, Poofs and Roofing ` None Acquired, 22 - Snares n) Sparc rcboilor co.il for 1-13^. b) Spare Vet end for 1-127 pump. MQNS 039026 G -13 >o . Hi uniitiii ) inr Expense J A I I ownin' for cl .-ring out i'immii known oh " l` i I. IcrH ronui" I i* r M.C.C. Thin inv I vos roniovn I nl' ;i Cixoil work ImuioIi nlxnil 6 x 2 1 l`i vi* !.< I siiolvox, nn uio (mini. /mil n (owe r |m> ini.. 2. Allowance for removal of wnJJcd-in waste men .just North <J 3rd Street - remove 30' of 4-jM brick waJ 1 3' high. Leave concrete slab. 92 - Ronairs Expense 2 1, 70 yd of 2" dressing of stone chippings covering back fill to bund kerb. 2. Allow for repairs to make good damage to new equipment before o during transit and installation. 93 - Keloaction and Modification Expense The following allowances are made: 1. Allow for slight repositioning of two light fittings inside building 35 control room. 2. Clearing of bricked-in doorway on East side of existing switch room. This involves removing 31 x 6*6" of brick wall from existing archway. 3. Removal, addition of two nozzles, and replacement of 1-137 distillate product receiver. Allow for cleaning vessel 2 man days. 4. 23 process and utility tie-ins with minor pipework modifications. 3. Extra nozzle for dip-pipe in 1-101. vessel 2 man days. Allow for cleaning 6. Allow 100 for making good Category 90, item 1. 7. Addition of three 6" nozzles on existing items 1-146, 1-148 and 1-149 to take new dip-pipes. Allow for cleaning tanks 4 man days each. 8. Making good of six 1* square holes in existing north-south firewall in Building 35 Tor new process pipe. 94.- Start-up Expense This is made up as follows:- Allow contractor crews for start-up, instrument and electrical technicians, mechanical filters and welders Say 10 man weeks at ordinary time 15 man weeks at overtime (or shift) Allow assistance from vendors for 2 man weeks. Allow miscellaneous materials (piping, Insulation, cable etc.) for start up modifications at 0.5$ total capital cost. MONS 039027 APPENDIX J J- KxclusJ uiis j, Lifting beams other than a t SVL davit at the top of the distillation column. No hoists are included for maintenance purposes. (Davits will be supplied for vertical manhole covers on the distillation column). 2. No special surface finishes are provided for floors, walls or roofs. 3. Nopair work to existing facilities is part of the manufacturing budget, unless specifically included in the Description of Works section of this Scope, or due to damage while the facilities are under CED responsibility. "Repair Work" includes repainting existing facilities. k. Dismantling of existing redundant facilities is limited to that necessary to meet the project objectives. Any additional dismantling is part of the manufacturing budget. 3* This project provides no installed, nor uninstalled spares. * Spare parts necessary to ensure continual operation of the plant are a manufacturing responsibility and CED assistance will be confined to providing vendors* lists of recommended spares. This is in accordance with CED Procedure 26 and Controllers Bulletins 12-10 and 09*03. 6. Also excluded, with reference to CED Procedure 28, are all safety supplies (which include portable fire extinguishers), desks, filing cabinets and other supplies stores items. 7* No laboratory test or analysis equipment is included. No pollution control or measuring equipment is included. Any additional facilities will be justified,by and provided for, under the manufacturing budget and estimates for the A.R. 8. No additional personnel facilities (toilets, lunch rooms, otc.) are included. Existing facilities are adequate. 2 9. Testing and calibration equipment for the AC Instruments will be provided under the manufacturing budget. 10. No provision is made for waste disposal under this CEA. The project will provide only a line from the residue pump 1-133 1o a tanker loading point on the east side of the plot (Avenue * B *) (in the event that all column residues cannot be further chlorinated to Aroclor 3 25*0 Tlie project does not provide loading platforms, layby or containers. 4 Except as detailed under Category 22 of Appendix G. MOMS 039028 J-2 11. 12. 1^. No omorgoncy power is supplied to the control panel. No cmoreoicy power is supplied to the M.C.C. No thorinn] insulation boxes are provided for pumps. Fixed insulation will be provided. MONS 039029 MOIlSnlitl) TO AHJr'KUJ'K J A J JiUl'i aourft or./i * m "v i v i i A. Aliroyd, London (s, & P. P, Kuropc) 1 21 h August, .1973 i t; Pi cry.b C.V.A .V_r)3 8 - Arocj or 1)j s ti 1 1 ati i:n K r-yport Loss l'rcventioi) rand !' f', Pcv.i ew (73-LJ ) J.K. lUCKUUliST U , A . Pobl, pTujsc.rl*Ull6.ec] 1 b. Mi 3 lC7-, St . I.* .11 i s c'. & ]',]' Project ct. Loc.-:' i on C01`7 ES TO THOSb A. A)'.royd - London J ,K. llucklmrst - London T.V. Ooinlsh - Newport A. Dawkins - London Ji. D i ftj ey - S' ewpc j i K 1!, Jones - London I '. .S * "3 o (, u - London Up-dated to revised scope dated Septembe 8, 1971 PATE AND FLACK OF .MLLTiNG 3rd August, 3 971 Parnell House, London n;A_ >7 31 - A POr.LOH . 1)3 ST1LLA TUN_. - NKVPOKT Tb j_s_ .i^ljcr t i g ..Ho,s^cd ^on^ tb Frcliriinni y scone repoi t dated July 15, 1971 and rough layout ch r.. ] opened by J ,E Hn ol.baj : 1 . The project is concerned with the provision of memii'nctur i ng I facilities for the production of improved biodegradable Aruolcu 3 03 6, The new column system will have a capacity (hof.. ost ) of Ajoc] or I 3 016, 12.5M I.HS/YH. New 1'a c i 3. i ti c r- will in cl tide a .30 troy distillation column * tcl mo; i Maries* and a new crude Arcelor i n termedia te .1 fn op, * tank. These v; i 3 1 be located west of the e\ i i Aroc.lor bu.Mdi.ng I'i. 1 ii}.i.ruments and motor starters will be intel led in wi lb the c'xifd Jne facilities and utility requ iremMit s will be entered Lor by existing supplies. The eompletion date is December, 1972. JdvKSj'NNLL 'I'll j I'j.c'jeci wiJ.I j, {.i, I HI j (|( ) f. l'ff i 'if rot create an> u--v. in/-a id to (be exi-iii r m-itetinls *Jji phony J, (-hlm-ine 'ltr1 h'nit Bfilllf 1'll'Tf`H I J y U .*" < < l . HUNS 039030 /... - I. M ... j i - 2- The new distillation column will be approximately 4*6" diameter x 70*0" high, self supporting, carbon steel 30 sieve trays. It is to have a top platform on which will be a column condenser, vent condenser and an ejector. Access will be by vertical ladders. It is suggested this be discussed further when arrangement drawings are being drawn. 1. Design of the top platform will require careful consideration for access for operators and maintenance. Safety hoops must be affixed to the ladders as per Monsanto Standard. The Lime mix tank will be charged by hand from 25 kg sacks. Thesenill be hoisted to the charging platform by means of an air hoist on pallets. 2. The charge manhole on the tank should be located such that operators can charge the sacks without straining. Electrical Classification 3 Since neat Biphenyl will not now be present at the top of the column the project will be unclassified. TIRE PROTECTION The existing fire hydrants and deluge systems were discussed at this meeting. T.V. Cornish will discuss and ascertain the exact positions of the existing hydrants with Des Chappel, Fire Officer, Newport. It is believed that these will accommodate the additions to the area. GENERAL 4. The Aroclor equipment (Column, Furnace, Still, Storage Tanks and Pumps) should be placed on a concrete kerbed area to contain possible spills. Kerb height of a height to contain largest tank volume. The furnace area should have a separate bund in the same area for segregation from the main area. . All relief systems will be sized to latest standards. LOSS EXPOSURE The maximum probable loss would be a complete failure of the furnace. This could result in a 3 months shut down and cost 130,000 to replace. HONS 039031 /... 3 The Business Interuption Loss would be in the region of $600,000 but this could be alleviated by supplies from V.G.K, plant. LOSS PREVENTION REVIEW CHECK LIST Attached to J.E* Backhurst's copy of this report is a copy of form 0*1425 (Loss Prevention Review Check List) which should be used as a check list for the project. LOSS PREVENTION REVIEW BY PLANT The S. A P.P. Branch of CED cannot review design prints and follow construction progress in detail during the project. S, A P.P. requests Interested plant personnel, including safety personnel, to hold additional loss prevention reviews at the plant to follow the development of design drawings, and to check the compliance with loss prevention recommen dations. SAFETY MANAGER A. Akroyd will be Safety Manager for this project. contact him for additional reviews during design. Please A. AKROYD / MOWS Q39032 1.W.1! u!t*`hhi w. Monsanto location) ' B* JONES, C*E*B EUROPE ... sCcJPMgeaSSEnOs l6th Sept. 1971 CEA 2518 - Aroclor Distillation, i Newport. MPIfllNCl t ENG/KBJ/JVH TO : J. E, BACKHURST APPENDIX L.2 A . Akroyd, S A PP T.W. Cornish, Newport II. Disloy, Newport A. Dorkings, London K.B. Jones, London R.S. Yates, London F.R. Ashby, London B,J, Boland, London S. Wood, London P. Cunningham, St. Louis CEA 2518 Project file D.O. File PRE PROJECT ENVIRONMENT CONTROL REVIEW TUESDAY AUGUST 3rd 1971 - PARNELL HOUSE Attendance at Review Meeting A. Akroyd J.E. Backhurst T.W, Cornish H. Dleley A. Dorkings K.B. Jones R.S. Yates - S A PP - Project Manager - Newport - Newport - London - London - London REVISED SEPT. 16TH FOLLOWING DELETION OF MCS 1109 FROM SCOPE Review Basis This pre-project review is based on the Provisional Project Soope dated July 15th 1971 prepared by A.J. Helnze (St. Louis), and approved scope issued 8th September 1971* Project Objectives 12,5 The primary object of |the_project is to provide manufacturing facilities to produce ihR M lb/year of Aroclor 1016 which will contain less persistent polychlorinated biphenyls (P.C.B's) than in Aroclor products previously manufactured. Aroclor 1016 would thus contribute towards the reduction of the_environmental hazards associated with P.C.B's. -I-addAtte-08-N-lb/yeae of manohlansbl|heiyl-(.NC&-:H09)-Mhlsh-ls-ale-biedagadablo -wlll-bs-preduced .Ceos -the-new -column -system - Process Description Aroclor 1016 will be produced by the distillation of Aroclor llll2 from the existing 3 batch chlorinator process using a new semi-continuous column system. Monoohlonoblphonyl -VVG9-)- -wtMr -be -produced -from -AreeAer t 111-5 -also. -Csam -the -above -existing -ebLerineter-preeess r MONS 039033 rage <c Tho new facilities will have the following waate stream l- 1. Gaseous Effluent The effluent containing P.C.B's would be discharged from vacuum ejectors in the new column system. According to the Scope the emission should be "in the order of less than 1 lb. per day". 2. Liquid Effluent (a) Aroolor residue The excess residue or high boilers from the new column I system oftetk Aroclor 1016 aadwH66-A109 which contains a high concentration of non-biodegradable P.C.B's would be recycled within the system to produce Aroclor 1254. On the basis of current sales forecasts of Aroclor 12)4 the above major potential waste streams will thus be eliminated. If the waste quantities to be absorbed in this way exceed Aroclor 1254 requirements then the excess high boiler waste would be incinerated off site by Purle Bros. (b) Lime Slurry * The wsste stream, used in chlorine and HCL scrubbing will not be increased by CEA 2518. It will continue to be discharged to the existing effluent system. 3. Spills Any liquid leaks or spills from the new storage and column system would contain dangerous concentrations of P.C.B's. Discussion . ' After consideration in depth of P.C.B's both in general and at Newport the following relevant data was noted. 1. No U.K. statutory limits so far established. ^ 2. Maximum allowable concentration in atmosphere used by Monsanto 0,5-1 m.g./m3. 3. Sampling of plant atmospheres around the present Aroclor plant for P.C.B. contamination has shown variations from . 0.93 mg/m? to zero. A top concentration of 1.6l mg/m? in Aroclor control room had been reported but this was considered to be spurious. 4. Newport are fully aware that the potential increase in P.C.B. emission arising from the new column systom could ' exacerbate the present situation. They have sot up a regular procedure for P.C.B. sampling of the liquid and gaseous effluents at various locations including the column ejoctor. The necessity for additional instrument tatlon to detect potential upsets has still to be deter mined. MONS 039034 Pago 3 5* The gaseous effluent from the top of the new column, which will be approx. 70 ft. high, will be heavier than air but of a molecular structure which is biodegradable. Further information of the speed of degradation is required in order to check if the possibility of fall out within and outside the plant area will be a hazard. The meeting was of the opinion that a non-condensing ejector at the top of the column will be the moat efficient method of reducing P.C.B. emission. 6. Solubility of P.C.B*s in water ------ 200 parts/billion. 7. Long term aim of P.C.B. concentration mixed with Newport effluent and discharged to sea is ----- 10 parts/billion. 6. To eliminate tho diffusion of P.C.B's after spills and leaks via surface rainwater or fire water the concrete curbed area referred to in the scope would be developed into a bund sufficient to contain the largest tank volume, 16.500 namolvyi.^OQQ-4igeAg. The bund would be emptied via a *i. gals, steam ejector with an effluent sump for discharge either to Purls Bros, road tanker in the event of spills or to the factory effluent system when uncontaminated. It is recommended that an effective method of bund and effluent sump sampling be provided. ---Jha- -effec-t- f- feabcfe. of- MGS- 1109- .t*rms- of affluent emission-as-compsur&CLal-th--tho- _ apsratiao. Asu .the- USA wi 11- ad- be- koowa- before, plaab. s-tswNi--UfK- - Mewpoat- wore- svo-t- adldpallag- eay- ^iMdmaaUbdmmmmrn NB. The following Information was obtained after the review meeting from A. Vodden - Ruabon Research Dept. Talks between Monsanto and the Ministry of the Environment suggest statutory limits of P.C.B. emission unlikely. Control may be left to the voluntary co-operation between the P.C.B, producers and the users and limitation of auppllea to approved users. The reference to the limit of 1 lb. per day of P.C.B's refers to the total omission of the plant as a whole and not to the emission from the new equipment provided only by this project. K. B. JONES mqns 039035