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CAUSTIC 1 / CHLOR-ALKALI2 1997
REACTIVE CHEMICALS REVIEW MAINTENANCE PROCEDURES
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MAINTENANCE
Cleaning / Purging Equipment and Lines:
Chlorine:
Hot water or steam is recommended over solvents
Preferred solvent for cleaning chlorine equipment is carbon tetrachloride
Purge chlorine systems with dry air or nitrogen - take necessary precautions to prevent contaminating an instrument air system when using dry air
Dry all chlorine equipment with nitrogen to a dew point of - 60 F
Caustic:
All materials to be thermal cut, heated, or welded should be washed with 3 % (1 N) HC1 (This includes post weld heat treatment area).
Rinse with water after acidizing.
*Chlorothene and other chlorinated organic cleaning agents should not be used in caustic service. Exothermic reactivity with caustic varies depending on the structure of the chlorinated organic. Flammable and explosive chloro and dichloroacetylenes can be formed and in some cases it is possible to form unstable and highly reactive dichlorocarbenes.
Sandblast inside and outside of pipe or material in the area where cutting, welding, or postweld heat treatment will take place.
Re-acidize and rinse area as per above steps.
A Dow employee should test the material with litmus paper or phenolphthalein to assure that it has been cleaned and rinsed properly. The pheno will turn from a clear liquid to a pink to purple color when caustic is present.
Dow Confidential
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MAINTENANCE
METALS:
Dry Chlorine Service:
Service where materials will be in contact with chlorine where the moisture content is less than 5 PPM water by weight in chlorine.
Recommended Materials:
Carbon Steel - Safe at temperatures less than 155 C (311 F) Iron - Safe at temperatures below 175 C (347 F)
Dry chlorine reacts violently with hot steel
- No welding on chlorine lines that have not been isolated and depressured
- Welding cables must not be clamped to chlorine lines
WARNING:
At ordinary temperatures, dry chlorine reacts with:
- Aluminum - Arsenic -Gold - Mercury - Selenium - Tellurium -Tin - Titanium
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MAINTENANCE
METALS: Wet Chlorine Service:
Recommended Materials: Titanium - High resistance to wet chlorine gas
The amount of water necessary to prevent a chlorine - titanium reaction will vary with temperature and pressure Note: Titanium is highly reactive with dry chlorine gas and liquid chlorine Storage:
Titanium equipment and materials are clearly identified (purple paint) and stored in a designated area in CA - 2 warehouse. This area is separated from other parts and locked. Material controller is responsible for this area.
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MAINTENANCE
tK METALS: Caustic Service:
Service where materials will be in contact with caustic varying in concentration from 8.5% to 50%.
Note: High corrosion rates will be caused by elevating temperatures and / or concentrations.
Recommended Materials:
Steel Pipe - 8.5 % caustic less than 150 F and stronger concentrations of caustic below 120 F
Nickel Pipe - Concentrations above 8.5 % with a temperature greater than 120 F
Aluminum is rapidly attacked by caustic and its use should be avoided.
Miscellaneous Applications:
Heat Transfer Materials - Hot water, steam, and "Hi-Tec" salt are recommended for heat transfer applications. Avoid organic materials that react with chlorine.
Filter Elements - Wound fiber glass and sintered metal are recommended as filter elements. Avoid using polypropylene and organic materials that react with chlorine.
Dow Confidential
01/27/97
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lad chlor-alkau Process Materials
REACTIVE CHEMICAL MATRIX
PROCESS CHEMICALS
Air Carbon Tetrachloride Caustic 50% < 120 degrees Caustic 50% > 120 degrees Cell Effluent <120 degrees Cell Effluent >120 degrees Chlorine-DRY Chlorine-WET Freon 11 Freon 12 Freon 123 Hydrochloric acid Hydrogen Methane Oils (all) Sodium Bisulfite Sodium Carbonate Sodium Hypochlorite Sodium Thiosulfate30% Sulfuric Acid (weak<90%) Sulfuric Acid (strong>=90%)
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This reactIva chemical matrix was created using the knowledge of process engineers, process technologists, chemists, and MSD sheets This guide summarized the potential reactivity hazards of mixtures of chemicals.
D The Information herein does not constitute or by any means suggest suitable material compatabillty O lor the chemicals and materials listed. Consult plplngflnstrument specifications for material
of construction application.______________________________________ ___________ ______
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Dow Confidential Page:1
Rev. Date: 10/31/96 Print Date: 1/27/97
C O N F ID E N T
MAINTENANCE
(
Plant Absorbents:
Powersorb Oil Sorbant Sheets Type 157 Produced by 3M
Oil & Grease Absorbent Calcined Supplied by Butler Paper Company
Auto-Dri Floor Absorbent Produced by Special Minerals and Colors Group Englehard Corporation
K-Sorb Absorbent (Cellulose) Supplied by Butler Paper Company
ABSORB.DOC
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INTRODUCTION
This database summarizes the results of Reactive chemicals compatibility testing of various leak repair sealants with LAD process chemicals. In addition to leak repair sealants, the compatibility of valve packings, gaskets, thread sealants, O-rings, coatings, and adhesives with process chemicals are also included. This database was updated in July, 1994 and documented in CRI report, LAD-AR 94.11.
According to LAD Safety Loss prevention Standard S-317, leak repair sealants may be used to temporarily stop leaks on operating lines or equipment. The leak repair is not a substitute for routine preventative maintenance and scheduled equipment repair. The line or equipment must be permanently repaired within 6 months, or with manager's approval, no later than the next scheduled shutdown. If the leak was caused by internal corrosion, or erosion, permanent repair must be made within 3 months.
The standard also states that "the leak-stop compound must be compatible with the operating line or equipment contents by Dow Reactive Chemicals testing." Reactive Chemicals testing of the compatibility of leak repair sealant and process chemicals is necessary to prevent a reaction that could cause a fire, explosion, and/or spill resulting in injury and/or property loss. Not only could the reaction between the sealant and the process chemical be a problem, but the heat of this reaction could initiate another reaction of the process chemical itself, or a reaction between the process chemical and the line or equipment material of construction.
Before a sealant is used on a process line or piece of equipment, the user must be Bure that the sealant and process chemical are compatible. Below is a discussion of the interpretation of the test results. If there is any doubt if a sealant is compatible with a process chemical based on the test results, the Reactive Chemicals group should be consulted (phone Gerald Wagener at 1828 or Joe Schell at 1639). AIbo, if a sealant and process chemical are not on the liBt, the Reactive Chemicals group must be contacted for testing.
Vendors sometimes give assurances that their sealants are compatible with certain process chemicals based on prior field usage, experience, consultation, chemical theory, or testing by their company. It is important to remember that these assurances are not adequate and that LAD Safety 6 Loss Prevention Standard S-317 requires Dow reactive chemical testing of the sealant with the line or equipment contents. Therefore, vendor literature is not accepted as proper documentation.
Reactivity testing only addresses chemical compatibility and in no way does it address or imply anything about a sealant's performance. It should not be assumed that because the reactivity of a sealant has been tested that it will adequately perform as a sealant in the process.
This database will be updated periodically as new tests are run. These include re-checks, new sealants, and sealants used with new process chemicals. Therefore, if a sealant is not in the table, the Reactive
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Chemicals group should be contacted to see if It was run since the last update.
EXPERIMENTAL
The reactivities of the sealants with process chemicals summarized in the database were tested using Differential Thermal Analysis (DTA), Differential Scanning Calorimetry (DSC), Heat of Mixing Calorimetry (HOM), and Accelerating Rate Calorimetry (ARC).
Differential Thermal Analysis (DTA)
DTA was used prior to 1987 to detect exothermic or endothermic reactions and the reaction onset temperatures as the temperature of the sample was increased at a set rate . DTA measures the difference in temperature between the sample and reference, and not the heat flow; therefore, an accurate determination of the heat of reaction cannot be made.
Differential Scanning Calorimetry (DSC)
DSC is currently used as a screening tool to determine the exothermic or endothermic heat of reaction at elevated temperatures and the reaction onset temperature. The DSC method is similar to the DTA method except that the sample and reference material are maintained at the exact same temperature as the temperature is increased at a set rate. If the sealant and process chemical sample exothermically react at a certain temperature, the sample heater requires less energy input than the reference heater to maintain the same temperature. This energy input difference is precisely equivalent to the exothermic heat evolved and is a direct calorimetric measure of the heat of reaction. Thus DSC is considered to be more quantitative than DTA.
2-Drop Heat of Mixing Calorimetry (HOM)
The LAD Reactive Chemicals lab uses a 2-Drop Heat of Mixing Calorimeter to measure heat of mixing at ambient temperature. A 50 microliter sample of liquid process chemical is injected by syringe into a 2 milliliter vial containing approximately 50 milligrams of a sealant sample. If the process chemical is a gas, a 10 milliliter sample is purged through the vial containing the sealant sample. The heat of mixing of the samples is calculated by dividing the sample peak area by the peak area of a one calorie standard.
Accelerating Rate Calorimetry (ARC)
If more accurate and detailed thermal data are deemed necessary after the DSC and heat of mixing tests, then an ARC test is performed. Larger samples of the sealant and process chemical are loaded into an ARC sphere and a wait-search-heat sequence with a heat step usually of 10 degrees c is repeated from ambient temperature to the desired end temperature. If the self heat rate of an exothermic reaction between the sealant and the process chemical exceeds 0.02 degrees C per minute, the reaction is allowed to proceed on its own under near-adiabatic conditions. This method gives an accurate measure of the heat of
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reaction after corrections are made for the thermal inertia of the sample container, and also a fairly conservative estimate of the conditions for a runaway reaction. The ARC onaet-of-reaetion temperature is more accurate than the DSC onset temperature. Also, pressure data is collected during the ARC run. INTERPRETATION OF TEST RESULTS The table includes the process chemical, sealant, plant, reference number (corresponding to the Reactive Chemicals test number), test (DTA, DSC, HOH, or ARC), and reactivity and onset temperature. If no thermal reactivity was observed between the sealant and the process chemical, and the test was run, for example, to 200 degrees C, the remark under the Reactivity heading would read "No exo to 200 C." If an exothermic reaction was observed with an onset temperature of 100 degrees C, the remark would read "Exo at 100 C." If HOM and DSC or ARC test results indicate no reactivity between a sealant and a process chemical at ambient and elevated temperatures, then they can be considered compatible. If only DTA, DSC, or ARC tests were run and indicated no reactivity at elevated temperatures, then a HOM test should be performed to check for reactivity at ambient temperature before a sealant and process chemical are considered compatible. If HOM and/or DSC or ARC test results indicate an exothermic reaction between a sealant and a process chemical, then the Reactive Chemicals group should be consulted to help interpret the results to decide if the sealant should or should not be used.
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C O N F ID E N T IA L
PROCESS CHEMICAL
ACETYLENE ACID GAS BLEND ACID GAS BLEND ACID GAS BLEND AIR AIR AIR AIR AIR AIR AIR AIR (INSTRUMENT! AIR (INSTRUMENT) AMMONIA |5% IN WATER) AMMONIA (5% IN WATER! AMMONIA (tS%) - D-270 AMMONIA (16%) - D-270 AMMONIA |1S%| - D-270 AMMONIA U 5%! - D-270 AMMONIA (1S%) - D-270 AMMONIA (15%) - D-270 AMMONIA (20% IN H20) AMMONIA (AQUEOUS! AMMONIUM HYDROXIDE ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA AT-200 SCRUBBER EFFLUENT AT-200 SCRUBBER EFFLUENT BENZENE (CRUDE) BENZENE (CRUDE) BENZENE PLANT PYROLYSIS GAS BENZENE-TOLUENE-XYLENE (T-1602) BENZENE-TOLUENE-XYLENE (T-16021 BENZENE-TOLUENE-XYLENE (T-16021 BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICI (LOROETHANE
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TABLE 1. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTEO BY PROCESS CHEMICAL)
SEALANT
PLANT
REF. NO.
TEST
TEAM LEAK REPAIRS VALVEPACK B STEAM & PROCESS SP-1011 STEAM & PROCESS SP-60 STEAM & PROCESS SP-CM SP-1011 (30 MIN CURE 1ST RUN) SP-1011 (30 MIN CURE 2ND RUN) SP-IOt 1 (30 MIN CURE 3RD RUN! SP-1011 (UNCURED SAMPLE) SP-102 (CURED @300 C 1 48 HOURS) TEAM LEAK REPAIRS SEALANT 2W TEAM LEAK REPAIRS SEALANT 2X STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS VALVEPACK VP-AX TEAM LEAK REPAIRS VALVEPACK VP-AX CORTEC VCt-309 CORTEC VCF309 CORTEC VCF36B CORTEC VCI-368 STEAM & PROCESS SP-60 STEAM S PROCESS SP-102 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS PTFE SEALANT TEAM LEAK REPAIRS SEALANT IX DOW CORNING 44 LUBRICANT FEL-PRO HI-TEMP NICKEL EASE STEAM & PROCESS SP-1016 TEAM LEAK REPAIRS PTFE SEALANT TEAM LEAK REPAIRS SEALANT *16 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS VALVEPACK B STEAM 6 PROCESS SP-2000 STEAM & PROCESS SP-CM STEAM & PROCESS SP-1011 STEAM a PROCESS SP-103 TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-5B FURMANITE FSC-6B TEAM LEAK REPAIRS SEALANT *6 a F-14 FIBERS FURMANITE FSC-44D FURMANITE FSC-44D FURMANITE FSC-EB FURMANITE FSC-6B STEM) a PROCESS SP-289 STEAM a PROCESS SP-2B9 STEAM a PROCESS SP-3100 STEAM a PROCESS SP-3100 TEAM LEAK REPAIRS SEAt ANT *2X
LHC 2 LGTI LGTI LGTI CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 POWER 2 POWER 2 POWER 2 LGTI LGTI DOWANOLS OOWANOLS LGTI LGTI LGTI LGTI LGTI LGTI LGTI DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS CAUSTIC CAUSTIC CAUSTIC CHLORINE CHLORINE BENZENE BENZENE BENZENE LHC 3 LHC 3 LHC 3 VINYL 2 VINYL 2 VtJYL 2 VINYL 2 VINYL 2 VINYL 2 VMYl 2 VINYL 2 VINYL 2
nCL-Bft-2233 OTA
RCL-BB-0305 DSC
RCL-B8-0306 DSC
RCL-B8-030B DSC
RCL-88-0612 DSC
RCL-88-0613 DSC
RCL-SS-0614 DSC
RCL-aa-oai i DSC
RCL-88-0752 DSC
RCL-92-320X DSC
RCL-92-320X DSC
RCL-B8-0309 DSC
RCL-B8-0307 DSC
RCL-95-0441 DSC
RCL-95-0441 HOM
RCL-95-1373 DSC
RCL-95-1373 HOM
RCL-95-637T DSC
RCL-95-8371 HOM
RCL-87-146X DSC
RCL-B7-I45X DSC
RCL-89-336X DSC
RCL1039
DTA
RCL-91-239X DSC
RCL-93-121X DSC
RCL-93-121X DSC
RCL 1232
DTA
RCL1038
DTA
RCL 1010
DTA
RCL 1007
DTA
RCL 1181
DTA
RCL-91-296X DSC
RCL-91-296X DSC
RCL-84-0031 DTA
RCL-B4-003X DTA
RCL-B5-053X DTA
RCL-92-199X DSC
RCL-92-199X DSC
RCL-92-199X DSC
RCL-93-5002 DSC
RCL-93-6002 HOM
RCL-93-5003 DSC
RCL-93-5003 HOM
RCL-93-5004 DSC
RCL-93-5004 HOM
RCL-93-6005 DSC
RCL-93-5005 HOM
RCL 93 5006 DSC
REACTIVITY
NO EXO TO 210 C EXO AT 45 C NO EXO TO 300 C EXO AT 50 C EXO AT 160 C EXO AT 60 C EXO AT 273 C EXOAT 17BC EXO AT 420 C NO EXO TO 500 C NO EXO TO 600 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 235 C NO EXO TO 300 C NO EXO TO 176 C NO EXO TO 130 C NO EXO TO 155 C NO EXO TO 250 C NO EXO TO 320 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C EXO AT 40 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXO AT 269 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 253 C NO EXO AT 22 C NO EXO TO 360 C
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7
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICALI
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
BETA-TRICKLOROETHANE
BETA-TRICHLOROETHANE
BETA-TRICHLOROETHANE
BETA-TRICHLOROETHANE
BETZ 1125L
BETZ 1125L
BETZ1125L
BETZ 112SL
BETZ BALANCED POLYMER 0403
BETZ BALANCED POLYMER 0403
BETZ BALANCED POLYMER 0403
BETZ BALANCED POLYMER 6403
BETZ BALANCED POLYMER 0403
BETZ BALANCED POLYMER 0403
BETZ BALANCED POLYMER 08701
BETZ BALANCED POLYMER 08701
BETZ 8P-P-1B 150%) + COR TROL 778P (60%)
BETZ BP-P-1B (50%) + COR-TROL 77SP (60%)
BETZ COR-TROL 778-P
BETZ COR-TROL 77B-P
BETZ COR-TROL 778-P
BETZ COR-TROL 778-P
BETZ COR-TROL 778-P
BETZ COR-TROL 778-P
BETZ INHIBITOR 38K
BETZ INHIBITOR 38K
BOXER WATER WITH COR-TROL. EDTA. * PIB
BOXER WATER WITH COR-TROL. EDTA. 6 PIB
BRINE
BRINE
BRINE
BRINE
BRINE WTO AT-260
BRINE OUT AT-260
1.3-BllTADIENE
1.3-BUTADIENE
C-2 RECYCLE GAS
C-2 RECYCLE GAS
C-450 FEED TO CSS + LITES
C-450 FEED TO CSS + LITES
C-600 FEED PYGAS + LITES
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C-500 FEED PYGAS + LITES CALCIUM STEARATE CARBON STEEL + CONCRETE + WATER CARBON TETRACHLORIDE CARBON TETRACHLORIDE
Sr CARBON TETRACHLORIDE
CARBON TETRACHLORIDE
TEAM LEAK REPAIRS SEALANT 42X TEAM LEAK REPAIRS SEALANT *0 TEAM LEAK REPAIRS SEALANT (0 TEAM LEAK REPAIRS VALVEPACK A CORTEC VCI-309 CORTEC VCI-309 CORTEC VC1-368 CORTEC VC1-368 CHESTERTON ARC 9B8 PART A SEALANT CHESTERTON ARC 988 PART A SEALANT CHESTERTON ARC 982 PART A SEALANT CHESTERTON ARC 982 PART A SEALANT CHESTERTON ARC 791 PART A SEALANT CHESTERTON ARC 791 PART A SEALANT FURMANITE FSC-6B FURMANITE FSC-0B TEAM LEAK REPAIRS SEALANT 6 6 F-14 FIBERS TEAM LEAK REPAIRS SEALANT *8 A F-14 FIBERS CHESTERTON ARC 988 PART A SEALANT CHESTERTON ARC 988 PART A SEALANT CHESTERTON ARC 982 PART A SEALANT CHESTERTON ARC 982 PART A SEALANT CHESTERTON ARC 791 PART A SEALANT CHESTERTON ARC 791 PART A SEALANT CMS 2000 PUMP SEALANT CMS 2000 PUMP SEALANT TEAM LEAK REPAIRS SEALANT OB-22 F-10 FIBERS TEAM LEAK REPAIRS SEALANT DB-22 & F-10 FIBERS TEAM LEAK REPAIRS SEALANT 46 TEAM LEAK REPAIRS SEALANT *0 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX PROTECTO-COAT 800 G PROTECTO-COAT 800 G TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B-EC TEAM LEAK REPAIRS SEALANT 10X TEAM LEAK REPAIRS SEALANT X-30 TEAM LEAK REPAIRS SEALANT 46 TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 46 TEAM LEAK REPAIRS SEALANT 2X STEAM & PROCESS SP-3100 STEAM & PROCESS SP-620 FURMANITE FSC-44D FURMANITE FSC-44D FURMANITE FSC-6B FURMANITE FSC-EB
VINYL 2 VWYL 2 VINYL 2 VINYL 1 LGTI LGTI LGTI LGTI LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 3 LHC 3 POWER 1 POWER 1 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 GLYCOL 2 GLYCOL 2 POWER 1 POWER 1 BRINE BRINE BRINE BRNE CHLORME CHLORINE LHC 2 VECTOR GLYCOL 2 GLYCOL 2 LHC 3 LHC 3 LHC 3 LHC 3 POLY C POWER 2 VWYL2 VINYL 2 VINYL 2 VINYL 2
RCL-93-5000 HOM RCL-93-5007 DSC RCL-93-5007 HOM RCL-B4-189X DTA RCL-95-1374 DSC RCL-95-1374 HOM RCL-9S-0372 DSC RCL-95-6372 HOM RCL-95-0831 DSC RCL-95-0831 HOM RCL-95-OB32 DSC RCL-95-0B32 HOM RCL-95-0833 DSC RCL-95-0833 HOM RCL-94-0921 HOM RCL-94-0922 DSC RCL-92-176X DSC RCL-92-175X HOM RCL-96-0834 DSC RCL-95-0834 HOM RCL-95-0836 DSC RCL-95-0936 HOM RCL-96-0830 DSC RCL-95-0830 HOM RCL-95-1362 DSC RCL-95-1362 HOM RCL-92-1B3X DSC RCL-92-1B3X HOM RCL-96-0791 DSC RCL-90-0791 HOM RCL-94-0621 HOM RCL-94-0521 DSC RCL-89-169X DSC RCL-88-109X DSC RCL-80-2234 DTA RCL-93-0021 DSC RCL-91-117X DSC RCL-91-116X DSC RCL-90-3861 DSC RCL-90-3863 DSC RCL-90-3852 DSC RCL-90-3854 DSC RCL-93-194X DSC RCL-92-3271 DSC RCL-93-5008 DSC RCL-93-5008 HOM RCL-93-5008 DSC RCL-93-5009 HOM
Daw Confidential
REACTIVITY
NO EXO AT 22 C EXO AT 284 C NO EXO AT 22 C EXO AT 276 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 260 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 336 C NO EXO AT 22 C NO EXO TO 260 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO AT 22 C NO EXO TO 226 C EXO AT 165 C EXO AT 68 C NO EXO TO 210 C EXO AT 105 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 180 C EXO AT 226 C NO EXO AT 22 C EXO AT 223 C NO EXO AT 22 C
ts
TABLE l REACTIVITY Of SEALANT WITH PROCESS CHEMICAL ISORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE (CRUDE, 03%) CARBON TETRACHLORIDE (CRUDE, 93%) CARBON TETRACHLORIDE ICRUDE, 93%l CARBON TETRACHLORIDE ICRUDE. S3%) CAUSTIC (25%) CELL EFFLUENT (10% SODIUM HYDROXIDE) CELL EFFLUENT |10% SODIUM HYDROXIDE) CELL EFFLUENT (10% SODIUM HYDROXIDE) CELL EFFLUENT (10% SODIUM HYDROXIDE) CELL EFFLUENT (10% SODIUM HYDROXIDE] CaL EFFLUENT (10% SODIUM HYDROXIDE) CELL EFaUENT (10% SODIUM HYDROXIDE) CELL EFFLUENT (10% SODIUM HYDROXIDE) CHLORINE CHLORINE CHLORINE CHLORME CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE n HLORINE O q HLORINE 2 O .HLORINE ]] CHLORINE O ^ CHLORINE
'n O CHLORINE ^ ^ CHLORINE Z, ^ CHLORINE
J> \J CHLORINE -&> CHLORINE CHLORME CHLORINE
SEALANT
SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEaON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOKJ SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOU SAFE SEAL MULTIPAK (JOHN CRANE 6KB| SAFE SEAL MULTIPAK POHN CRANE 6KB| STEAM & PROCESS SP-326 STEAM & PROCESS SP-325 STEAM & PROCESS SP-CM STEAM & PROCESS SP-CM TEAM LEAK REPAIRS SEALANT *11 TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT #8 CHESTERTON 810 STEEL PUTTY ICURED) CHESTERTON BIO STEa PUTTY ICURED) CHESTERTON B68 STEa PUTTY (CURED) CHESTERTON 858 STEa PUTTY (CURED) TEAM LEAK REPAIRS PRM02C (THREADS) TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS F-14 FIBER STEAM B PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-60 THORTEX METAL TECH E.G. BASE THORTEX METAL TECH E.G. BASE ANCHOR VALVE PACKING 375 ANCHOR VALVE PACKING 4205 BELZONA CERAMIC-R METAL BELZONA E-METAL BaZONA SUPER METAL CELL PUTTY CHRYSOT1LE ASBESTOS FIBER GSKT CONLEY TEaON PASTE FELPOXY STEEL GARLOCK VALVE PACKING 0130 GARLOCK VALVE PACKING 7130 GORE PACKING PTFE W/ GRAPHITE GORTEX PTFE GORTEX SEALANT (TEaON) JOHN CRANE VALVE PKG C-1050 JOHN CRANE VALVE PKG C flO JOHN CRANE VALVE PKG C-7762 JOHN MANSVILLE VALVE PKG AF-5331 LOCTITE #66747 PST LOCTITE #59231 IWITH TERON) LOCTITE 271 ADHESIVEfSEALANT
Dow Confkfontid
PLANT
METHANES METHANES METHANES METHANES METHANES METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 SOLVENTS/EDC SOLV ENTS/EDC SOLV ENTSIEOC SOLVENTSIEDC CAUSTIC CHLOR-ALKALI 2 CHLOR-ALKALI 2 VINYL 2 CHLORINE CHLORINE CHLORINE LHC 2 LHC 2 CHLORME CHLORINE CHLORINE CHLORINE CHLORINE CHLOR-ALKAU 2 CHLORME CHLORINE CHLORINE CHLORME CHLORINE CHLORINE SOLVENTS/EDC CHLORINE CHLORINE CHLORME CHLORME CHLORME CHLOR-ALKAU 2 CHLOR ALKALI 2 CI&OR-ALKALI 2
REF. NO.
TEST
HCL-94-0609 HOM RCL-84-0809 DSC RCL-94-5005 HOM RCL-94-5005 DSC RCL-94-060S HOM RCL-84-0605 DSC RCL-93-5010 DSC RCL-93 5010 HOM RCL-83-60H DSC RCL-93-5011 HOM RCL-83-5012 DSC RCL-83-5012 HOM RCL-93 5013 DSC RCL-83-5013 HOM RCL-92-2981 DSC RCL-92-29B1 HOM RCL-92-2982 DSC RCL-92-2982 HOM RCL-91-098X DSC RCL-96-0351 DSC RCL-96-0351 HOM RCL-93-128X DSC RCL-92-180X DSC RCL-92-180X DSC RCL-82-180X DSC RCL-95-1021 DSC RCL-95-1021 HOM RCL-B4-138X DSC RCL-B4-OOSX DTA RCL-85-1742 DTA RCL-84-184X DTA RCL-B5-1721 DTA ARC 91-847X ARC RCL-90-022X DSC RCLB3 0O04 OTA RCL-84-183X DTA RCL-94-007X DTA RCL-B4-0O8X DTA RCL-B6-206X DTA RCL-85-1361 DTA ARC 91-616 ARC RCL-84-141X DSC RCL-84-140X DSC RCL-94-0003A DTA RCL-84-144X DTA RCL-90-282X DSC RCL-90-2821 ARC RCL89 071X DSC
REACTIVITY
NO EXO AT 22 C EXO AT 297 C NO EXO AT 22 C EXO AT 325 C NO EXO AT 22 C EXO AT 185 C EXO AT 252 C NO EXO AT 22 C EXO AT 247 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 360 C NO EXO AT 22 C NO EXO TO 160 C NO EXO AT 22 C NO EXO TO 150 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C SL EXO AT 180 C SL EXO AT 170 C SL EXO AT 194 C NO EXO TO 200 C SL. EXO AT 22 C EXO < 30 C EXOAT 136 C EXO AT 35 C EXO < 25 C EXO AT 30 C EXO AT B6 C NO EXO TO 250 C EXO AT 100 C EXO < 25 C EXO AT -S3 C EXO AT -78 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C EXO AT 36 C EXO AT 46 C EXO AT 102 C EXO < 30 C EXO AT 116 C EXO AT 33 C EXO AT -5 C
IJU A 0 3 6 6 7 5
OONFTOFNTTA!
PROCESS CHEMICAL
CHLORME CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORME ILIQUIOI CHLORINE IUQUIDI CHLORINE ILIQUIOI CHLORINE IUQUIDI CHLORME ILIQUIOI CHLORINE ILKHJIDI CHLORINE ILIQUIOI CHLORINE (UQU1DI CHLORINE (DQU1DI CHLORINE (LIQUIOI CHLORINE ILIQUIOI CLS.ORINE (LKHJIOI CHLORINE IUQUIDI CHLORINE IUQUIDI CHLORINE (LIQUID) CHLORINE IUQUIDI CHLORME IUQUIDI CHLORINE IUQUIDI CHLORINE ILIQUIOI CHLORINE (TRACE WATER, HCBOJ CHLORINE VENT GAS CHLORINE VENT GAS CHLORINE VENT GAS CHLORME VENT GAS CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CITRIKLEEN DEGREASER CITRIKLEEN OEGREASER COAL (LOC 33A| COAL ILOC 33A| COM. CHAR SLURRV (LOC 36C) COAL CHAR SLURRY ILOC 35C)
9
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL!
SEALANT
PLANT
REF. NO.
TEST
PARKER HANNIFM VALVE PKG 2287-BR PARKER HANNIFM VALVE PKG 2287-GL PTFE/KEVLAR SEAL-ITT #34 SENTRY POLYMERS SEMLASTIC 6100 SEALANT SILASTIC 732-RTV SILICONE RUBBER STEAM & PROCESS SP-1011 TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT #6 + F-14 FIBER UNCUREO EPDM RUBBER CASTROL BRAYCOTE1728 COPALTITE HIGH TEMPERATURE SEALANT DOW CORNING 3120 RTV SEALANT GARLOCK 900 GASKET GOR-TEX GR GASKET GRAFOfi. GHE KADEL SN N-76 SEALANT KLMGER K-61 GASKET PERMATEX FORM-A-GASKET 2 (CURED) SAFE SEAL - CHEMOLA TEFLON STEAM 8 PROCESS SP-2020 STEAM 8 PROCESS SP-292 STEAM 8 PROCESS SP-300D STEAM 8 PROCESS SP-376 STEAM 8 PROCESS SP-CM STEM# 8 PROCESS SP-TFLO TEAM LEAK REPAIRS VALVEPACK OX (TEFLON! TOFB.ON SN T210 SEALANT USADURIAN SBR RUBBER CPE-TAC DERAKANE 470 (CURED 8/14/88) IPI EPOXY ICUREDI RED PRIMER (CUREO) WHITE DURDICK 800 G SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOLI SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOLI SAFE SEAL MULTPAK (JOHN CRANE 8KBI SAFE SEAL MULTIPAK UOKN CRANE 8KB) STEAM 8 PROCESS SP-CM TEAM LEAK RB>AIRS SEALANT OB-2 C5A Fa PRO NO. 726 NICKa ANTISEIZE STEAM 8 PROCESS SP-102 STEAM 8 PROCESS SP-60 CORTEC VCF30S CORTEC VCF368
CHLORME CHLORME CHLOR-ALKAU 2 CHLORINE
CHLORINE CHLOR-ALKAU 2 CHLOR-ALKAU 2 VMYL 1 VMYL 1 CHLOR-ALKAU 2 CHLORME CHLORME CHLORME CHLORINE CHLORINE CHLORINE CHLORINE CHLORME CHLORME METHANES CHLORME CHLOR-ALKAU 2 CHLORME CHLORME CHLORME CHLORME CHLOR-ALKAU 2 CHLORME CHLORME CHLORME CHLORME CHLORME CHLORME CHLORME METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES POWER 1 POWER 1 LGTI LGTI LGTI LGTI
RCL-B4-142X DSC RCL-B4-143X DSC RCL-89-322X DSC RCL-90-2771 DSC RCL-9B-0211 HOM RCL-84-100X DTA RCL-89-322X DSC RCL-B3 093X DTA RCL-B3-095X DTA ARC 91-648 ARC ARC 91-686 ARC RCL-94-9851 ARC RCL-94-9848 ARC RCL-92-9737 ARC RCL-93-9771 ARC ARC 91-688 ARC RCL-93-9809 ARC RCL-82-9738 ARC RCL-94-9B66 ARC RCL-94-9892 ARC ARC 92-692 ARC RCL-93-9831 ARC ARC 92-711 ARC RCL-93-9830 ARC ARC 92-708 ARC ARC 92-716 ARC RCL-92-8764 ARC KCL-93'9799 ARC RCL-94-9863 ARC RCL-B4-211X DTA RCL-BB-172X DSC RCL-88-172X DSC RCL-88-188X OSC RCL-BB-189X DSC RCL-94-0809 HOM RCL-94-0609 DSC RCL-94-6004 HOM RCL-94-6004 DSC RCL-94-0804 HOM RCL-94-06O4 DSC RCL-86-1334 DTA RCL-82-0039 DTA RCL-89-060X DSC RCL-89-0SOX DSC RCL-B7-146X DSC RCL-87-146X DSC RCL-86-1377 DSC RCL-86-6374 DSC
Dow Confidential
REACTIVITY
EXO < 30 C EXO AT 38 C EXO AT 48 C EXO AT 90 C EXO AT 22 C EXOAT 160 C EXO AT 40 C EXO AT 90 C EXO AT 130 C EXO AT 98 C EXOAT 187 C EXO AT 113 C EXO AT 36 C EXO AT 20 C NO EXO TO 176 C EXO AT 104 C EXO AT 162 C EXO AT 27 C EXO AT 22 C EXO AT 8 C EXO AT 20 C NO EXO TO 260 C EXO AT 20 C NO EXO TO 260 C EXO AT 20 C NO EXO TO 176 C NO EXO TO 260 C EXO AT 109 C EXO AT 69 C EXOAT 135 C EXO AT 30 C NO EXO TO 260 C EXO AT 40 C EXO AT 36 C NO EXO AT 22 C EXO AT 310 C NO EXO AT 22 C EXO AT 200 C NO EXO AT 22 C EXO AT 224 C NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 300 C EXOAT 78 C NO EXO TO 236 C NO EXO TO 236 C NO EXO TO 200 C NO EXO TO 200 C
1
PROCESS CHEMICAL
COAL CHAR SLURRY (LOC 3SCI COAL CHAR SLURRY ILOC 35C) CP-1000 OIL SATURATED WITH HCL CRACKED GAS CRACKED GAS CRACKED GAS CRACKED GAS CRACKEO GAS CRACKED GAS CRACKED GAS CRACKED GAS CRACKED GAS (2C-60| CRACKED GAS (2C-50I CRACKED GAS (2C-60) CRACKED GAS I2C-50B) CRACKED GAS IH2.C1 .C2,C3.C4.HIGHERS) 0-102 QUENCH LIQUOR D-1220 BOILER BLOWDOWN 0-13 HEXES D-13 HEXES 0-270 LIQUID DIETHANOLAMINE DIETHANOLAMINE DIETHANOLAMINE DIETHANOLAMINE DIETHANOLAMIN E DIETHANOLAMINE DIMETHYL ETHER DIMETHYL SULFIOE DITCHWATER ILHC 2 6 LGTQ DITCHWATER (LHC2 & LGTD DNDA CATALYST (BATCH 88B) DNDA CATALYST (BATCH 886) DOWANOL DB OOWANOL DF 250 DOWANOL DF 250 DOWANOL DPM DOWANOL DPM DOWANOL EB DOWANOL EB DOWANOL EB O DOWANOL EB 2 O DOWANOL EB Tf DOWANOL EB
^ 1> DOWANOL EB 2 DOWANOL EB 2 DOWANOL EB SERIES IEB.DB.TBHI H > DOWANOL PM
10
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
SEALANT
PLANT
REF. NO.
TEST
STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS SEALANT *6 FURMANITE FSC-60D SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFORJ SAFE SEAL MULTIPAK (JOHN CRANE 6KB| TEAM LEAK REPAIRS SEALANT DB-22 TEAM LEAK REPAIRS VALVEPACK BEC TEAM LEAK REPAIRS VALVEPACK VP-GX TEAM LEAK REPAIRS VALVEPACK VP-EPX FURMANITE FSC-46D (TEFLON 3001 STEAM & PROCESS SP-102 STEAM & PROCESS SP-CM CHESTERTON 858 PUTTY - PARTS ABB TEAM LEAK REPAIRS SEALANT 16 FURMANITE FSC-6B TEAM LEAK REPAIRS SEALANT FI 8 FURMANITE FSC-6C FURMANITE FSC-6B TEAM LEAK REPAIRS FH FIBERS FURMANITE FSC-50D FURMANITE FSC-50D TEAM VALVEPACK VP-GX TEAM .VALVEPACK VP-GX TEAM VALVEPACK VP-EPX TEAM VALVEPACK VP-EPX TEAM LEAK REPAIRS SEALANT DB-2 FURMANITE FSC-6B CURED AVANTI AV-202 MULTIGROUT CURED AVANTI AV-220 MULTIGROUT SEMSTONE 145-S SEMSTONE 245 TEAM LEAK REPAIRS VALVEPACK E TEAM LEAK REPAIRS SEALANT 48 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT *6 EPR EO 982 *0"-RWG EPR RED DOT *0"-RING STEAM B PROCESS SP-1011 STEAM B PROCESS SP-102 STEAM B PROCESS SP-3100 STEAM B PROCESS SP-60 STEAM B PROCESS SP-CM VITON YELLOW DOT "O' RING STEAM B PROCESS SP-1016 EPR EO 962 *0"-RING
LGTI LGTI METHANES LHC 2 LHC 2 LHC 2 LHC 2 LHC 3 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 VNYL2 LHC 3 SOLVENTS/EDC SOLVENTSJEDC GLYCOL 1 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 METHANES LHC 2 LHC 3 LHC 3 POLY B POLY B DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS
RCL-87-146X RCL-87-145X 92288 RCL-95-1473 84033 94033 94033 90243 90236 RCL-98-0563 RCL-98-0664 93135 92065 92065 92104 RCL738 89208 89151 92196 92196 91169 RCL-95-1472 RCL-95-1472 RCL-96-0551 RCL-96-0661 RCL-90-0652 RCL-96-0552 RCL 82-043 91221 871171 871172 90146 90146 RCL 1491 92016 92016 92016 92016 92339 92339 93014 93014 93014 93014 93014 92339 B4E104 92339
DSC DSC DSC HOM DSC DSC DSC DSC DSC HOM HOM DSC DSC DSC DSC DTA DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC HOM DTA DSC DSC DSC DSC DSC DTA HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DSC
Dow Confidential
REACTIVITY
EXOAT 166 C NO EXO TO 235 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 250 C NO EXO AT 22 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 400 C EXO AT 338 C NO EXO TO 150 C NO EXO TO 400 C NO EXO TO 200 C NO EXO TO 250 C EXO AT 344 C EXO AT 270 C NO EXO TO 250 C NO EXO TO 260 C NO EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 190 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C EXO AT 223 C NO EXO TO 350 C NO EXO AT 25 C NO EXO TO 200 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 210 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C
DO A 0 0 6 6 7 7
C O N F ID E N T IA L
11
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTEO BY PROCESS CHEMICALI
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM SERIES IPM.OPM.TPMI DOWANOL PM. DPM, TPM. KOH MIX (DV-114) DOWANOL TBH AND HIGHERS (T-130) DOWANOL TPM DOWANOL TPM DOWANOL TPM ft HIGHERS DOWTHERM A DOWTHERM A DOWTHERM A DOWTHERM A DOWTHERM A DOWTHERM A DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G ETHANE ETHANE ETHANE/ETHYLENE I2C-62 OVERHEAD GAS| ETHANOLAMINES IMEA.DEA.TEA) ETH ANOLAMINES IMEA.OEA.TEA)
EPR RED DOT 'O'-RING STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-3100 STEAM & PROCESS SP 60 STEAM & PROCESS SP-CM TEAM LEAK REPAIRS SEALANT f8 TEAM LEAK REPAIRS SEALANT *8 VITON YaLOW DOT *0'-RING STEAM ft PROCESS SP-2000 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS SEALANT *8 TEAM LEAK REPAIRS SEALANT #8 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT EG TEAM LEAK REPAIRS SEALANT X-38 TEAM LEAK REPAIRS VALVEPACK AX FURMANITE FSC-5C FURMANITE FSC-SC FURMANITE FSC-6B FURMANITE FSC-6B STEAM ft PROCESS SP-1011 STEAM ft PROCESS SP-1011 STEAM ft PROCESS SP-102 STEAM ft PROCESS SP-102 STEAM ft PROCESS SP-109 TEAM LEAK REPAIRS 18X ft FURMANITE FSC-8B TEAM LEAK REPAIRS SEALANT f16X TEAM LEAK REPAIRS SEALANT f18X TEAM LEAK REPAIRS SEALANT *2XH TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK B-EC TEAM LEAK REPAIRS VALVEPACK ER TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS SEALANT *8 TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS SEALANT *8 STEAM ft PROCESS SP-1012 STEAM ft PROCESS SP-2007
DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS POLY C POLY C POLY C POLY C POLY C POLY C VINYL 2 VINYL 2 VWYL 2 VINYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 METHANES VWYL 2 VWYL 2 VWYL 2 VWYL 2 VINYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 PROMIX LHC 2 LHC 2 DOWANOLS DOWANOLS
92339 93014 93014 93014 93014 83014 92018 92018 82339 84E106 92261 92261 92018 82018 82261 87033B 93080 03080 B7033A B7033C 87083A 891B8 93164 92100 93164 93164 93164 93164 93154 RCL 1468 92100 92100 93164 93164 93164 92100 82100 92100 93164 92100 92100 92100 93164 84071 88223G RCL 1016 B4E108 B4E107
Dow Confidential
TEST
DSC DSC DSC DSC DSC DSC HOM DSC DSC DTA DSC DSC HOM OSC DSC DTA DSC HOM DTA OTA DSC DSC HOM DSC HOM DSC HOM DSC HOM DTA DSC DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC DSC HOM DSC DTA DTA DTA DTA
REACTIVITY
NO EXO TO 250 C EXO AT 276 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C SL EXO AT 26 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 260 C NO EXO TO 300 C NO EXO TO 300 C SL EXO AT 26 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 360 C NO EXO TO 360 C NO EXO AT 22 C NO EXO TO 360 C NO EXO TO 360 C NO EXO TO 350 C NO EXO TO 400 C NO EXO AT 22 C NO EXO TO 360 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 290 C NO EXO TO 360 C NO EXO TO 360 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 360 C NO EXO TO 360 C NO EXO TO 360 C NO EXO AT 22 C NO EXO TO 360 C NO EXO TO 360 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 260 C NO EXO TO 260 C
00 A 036678
OONFTDFNTTAl
12
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
ETHANOLAMWES IMEA.OEA.TEA) ETHYL CHLORIDE ETHYL CHLORIDE ETHYL CHLORIDE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE 01CHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICKLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE IC-250 REFLUXI ETHYLENE DICHLORIDE (C-260 REFLUXI ETHYLENE OICHLORIDE (CRUDE EDC + VCM + HCL) ETHYLENE DICHLORIOE (D IB VESSEL SAMPLE! ETHYLENE DICHLORIDE + BETA-TRICHLOROETHANE ETHYLENE DICHLORIDE + BETA-TRICHLOROETHANE ETHYLENE GLYCOL ETHYLENE GLYCOL ETHYLENE GLYCOL ETHYLENE GLYCOL ETHYLENE GLYCOL ETHYLENE GLYCOL ETHYLENE GLYCOL |1%) IN CONDENSATE ETHYLENE GLYCOL (1 %| IN WATER
TEAM LEAK REPAIRS SEALANT *6 GRAFOIL GHE GRAFOR. GHR TEAM LEAK REPAIRS SEALANT f6 FURMANITE FSC-6B STEAM & PROCESS SP-2000 STEAM II PROCESS SP-2028 TEAM LEAK REPAIRS SEALANT 0B-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK AW W/ FIBERS TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK BEG FIBERS TEAM LEAK REPAIRS VALVEPACK GX COOPER OIL TOOL DIVISION WKM NO. 114 FURMANITE FSC-5B FURMANITE FSC-6B FURMANITE FSC-6B FURMANITE FSC-BB STEAM & PROCESS SP-289 STEAM & PROCESS SP-289 STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 TEAM LEAK REPAIRS SEALANT *2X TEAM LEAK REPAIRS SEALANT *2X TEAM LEAK REPAIRS SEALANT *2XH TEAM LEAK REPAIRS SEALANT *2XH TEAM LEAK REPAIRS SEALANT 46 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX FURMANITE FSC-5C FURMANITE FSC-6B WKM VALVEPACK 114 A *STP" LUBRICANT STEAM & PROCESS SP-325 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS VALVEPACK A CMS PUMP SEALANT CMS PUMP SEALANT FURMANITE FSC-6B MOLYKOTE 44 LUBRICANT STEAM & PROCESS SP-1011 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-1011 FURMANITE FSC-8B
DOWANOLS GLYCOL 2 GLYCOL 2 SOLVENTSIEDC LHC 3 VINYL 1 VINYL 1 VINYL 1 VINYL 1 POLY C BRINE BRINE LHC 3 POLY C LHC 3 VWYL 2 VINYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 1 VWYL 2 VWYL 2 VWYL 1 VWYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 SOLVENTS/EDC VINYL 1 VWYL 1 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2
84E108 90311 90311 90024 92306 RCL B3-111 RCL 83-112 84E194 84E1B0 96183A 94052 94052 86223F 861B3B 93207 93042 93164 93164 93154 93164 93154 93154 93164 93154 93154 93154 93154 93164 3108-46 93164 93154 84E18B 93154 93154 4791-29A 4791-29A 93066 93144 84EI93 84E190 RCL-95-1361 RCL-95-1361 92143 94030 94030 94030 92194 92143
OTA DSC OSC DSC DSC DTA DTA DTA DTA DTA HOM DSC DTA DTA DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DTA DSC HOM DTA DSC HOM DSC DSC DSC DSC DTA DTA DSC HOM DSC DSC DSC DSC DSC DSC
Dow Conlidontial
REACTIVITY
NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 225 C NO EXO TO 130 C NO EXO TO 250 C NO EXO TO 375 C NO EXO AT 22 C NO EXO TO 10B C NO EXO TO 350 C NO EXO TO 325 C NO EXO TO 200 C NO EXO TO 310 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 360 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 325 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 300 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 160 C EXO AT 40 C EXOAT 130 C NO EXO TO 300 C NO EXO TO 400 C EXO AT 276 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 200 C EXO AT 265 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 260 C NO EXO TO 106 C
/
PROCESS CHEMICAL
ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE REACTOR OUTLET GAS ETHYUDENE NORBORNENE ETHYLIOENE NORBORNENE FLARE DRUM LIQUID FLIGHTGARD 2000 FREON 12 FREON 12 FUEL OX FUa OX HO (15%) + METHYL CHLORIDE (86%I HQ (15%) + METHYL CHLORIDE <86%I Ha (50%) 4 CHLORINE <50%l HCI (50%) 4 CHLORNE (60%I Ha (50%) 4 CHLORINE (50%) Ha, Ml. M2. M3. M4 (T-BS1I HCI. Ml. M2. M3. M4 (T-BS1) HCI.M1.M2.M3.M4 IK-350 SUCTIONI HYDROGEN HYDROGEN HYDROGEN HYDROGEN CHLORIOE HYDROGEN CHLORIDE
13
TABLE 1. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
SEALANT
PLANT
REF. NO.
TEST
3M NEOPRENE 80 CONTACT ADHESIVE 3M NEOPRENE BO CONTACT ADHESIVE CHEMRAZ O-RING MATERIAL CMS 2000 PUMP SEALANT CMS 2000 PUMP SEALANT COLTEC CARBON CERAMIC PTFE GRADE 324 COLTEC CARBON GRAPHITE PTFE FXLED PEEK - 660 E0962 O-RING MATERIAL EPR EO 962 "O'-RING EPR RED DOT "O'-RING FUFWANITE FSC-6B FURMAN ITE FSC-6B FURMANITE FSC-6B FURMAN ITE FSC-6B GRAFOX GHE GRAPHONICS GASKET GRAPHONICS GASKET (ADHESIVE STFUP) STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1012 STEAM & PROCESS SP-106 STEAM & PROCESS SP-109 STEAM X PROCESS SP-2000 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK B viton yellow dot *o"-rwg LAMONS SPtROSEAL GSKT (GRAPHITE) GARLOCK SB PACKING GARLOCK 98 PACKING TEAM LEAK REPAIRS VALVEPACK OX D.E.R. 331 EPOXY RESIN STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2026 ROYAL PURPLE BARRIER aUID 22 ROYAL PURPLE BARRIER FLUID 22 STEAM X PROCESS SP-1011 STEAM X PROCESS SP-103 CURED DB 22 SXASTIC 732 RTV TEAM LEAK REPAIRS SEALANT #6 STEAM X PROCESS SP-2600 STEAM X PROCESS SP-CM STEAM X PROCESS SP-2000 STEAM X PROCESS SP-2000 TEAM LEAK REPAIRS VALVEPACK AW X FIBERS TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-6B FURMANITE FSC-66
GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 DOWANOLS DOWANOLS GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 1 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 ' DOWANOLS GLYCOL 2 EPDM EPDM LHC 2 GLYCOL 2 METHANES CHLORINE LHC 3 LHC 3 METHANES METHANES SOLVENTS/EDC SOLVENTS/EDC SOLVENTSJEOC METHANES METHANES METHANES CHLOR-ALKAU 2 POLY C LHC 2 GLYCOL 2 GLYCOL 2
93034 93034 89147 RCL-95-1363 RCL-95-1363 RCL-96-0161 RCL-96-0162 B9147 92339 92339 90318 RCL-85-0822 RCL-95-0821 RCL-96-0821 90165 92050 93077 94030 861970 RCL 1230 861978 94030 B6197A 90003 90003 92339 90131 RCL-96-0161 RCL-96-0182 91068 90270 RCL 82-037 90061 92169 92169 RCL1146 RCL1147 4791-9A 4791-9A 4791-9A RCL 82-014 RCL 1400 RCL 82-119 93199 88191A 86223B 92143 92143
OSC HOM DSC DSC HOM ARC DSC DSC DSC DSC DSC HOM DSC HOM DSC DSC DSC DSC DTA DTA DTA OSC DTA DSC DSC DSC DSC DSC HOM DSC DSC DTA DSC DSC HOM DTA DTA DSC DSC DSC DTA DTA DTA HOM DTA DTA DSC DSC
Dow ConfidantM
REACTIVITY
EXO AT 190 C EXO AT 22 C NO EXO TO 260 C EXOAT 150 C EXO AT 22 C EXO AT 151 C EXO AT 176 C NO EXO TO 250 C EXO AT 196 C EXOAT 196 C NO EXO TO 200 C EXO AT 22 C NO EXO TO 160 C EXO AT 22 C NO EXO TO 300 C NO EXO TO 194 C NO EXO TO 260 C EXOAT 120 C EXO AT 265 C NO EXO TO 260 C EXO AT 260 C EXO AT 320 C NO EXO TO 350 C EXOAT 126 C NO EXO TO 260 C EXO AT 186 C EXO AT 360 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 160 C NO EXO TO 100 C NO EXO TO 100 C NO EXO TO 250 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 360 C EXO AT 146 C EXO AT 26 C EXOAT 170 C EXOAT 126 C NO EXO TO 600 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 25 C NO EXO TO 376 C NO EXO TO 210 C NO EXO TO 260 C NO EXO TO 260 C
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TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL!
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIOE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUSI
HYDROGEN CHLORIOE (ANHYDROUS)
HYDROGEN CHLORIOE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYOROUS)
HYDROGEN CHLORIDE 1ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUS) .
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE 1ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIOE IANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE 1ANHYDROUSI
HYDROGEN SULFIDE GAS
HYDROGEN SULFIDE GAS
HYDROGEN SULFIDE GAS
HYDROLY2ER BOTTOMS
ISOPAR E
ISOPAR E
ISOPAR E
ISOPAR E
ISOPAR E
ISOPAR E
ISOPAR E
ISOPAR E
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METHANE METHANES E-259 VENT (HCI.M1.M2.M3) METHANES R-300 OUTLET (M1.M2.M3.M4.HCD METHANOL
METHANOL
SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOU SAFE SEAL GRAFPAK IUCAR CARBON CO GRAFOKJ SAFE SEAL MULTIPAK UOHN CRANE 6KB| SAFE SEAL MULTPAK (JOHN CRANE 6KBI COOPER OL TOOL DIVISION WKM NO. 114 FURMANtTE FSC-6B FURMANITE FSC-5B FURMANITE FSC-6C FURMANITE FSC-68 FURMANITE FSC-68 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2007 STEAM & PROCESS SP-CM TEAM LEAK REPAIRS SEALANT #1X TEAM LEAK REPAIRS SEALANT I1X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT DB-2 TEAM LEAK REPAIRS VALVEPACK A STEAM & PROCESS SP-3100 STEAM & PROCESS SP-770 TEAM LEAK REPAIRS SEALANT 16X SYNTHO-GLASS NEPTUNE RESEARCH STEAM ft PROCESS SP-325 STEAM ft PROCESS SP-325 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT IX TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 5G TEAM LEAK REPAIRS SEALANT OB 20 TEAM LEAK REPAIRS SEALANT X-36 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX STEAM ft PROCESS SP-325 STEAM ft PROCESS SP-325 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS VALVEPACK B StASTIC 732-RTV SILICONE RUBBER STEAM ft PROCESS SP-2000 STEAM ft PROCESS SP-1016 STEAM ft PROCESS SP-1015 + SP-2000
METHANES METHANES METHANES METHANES METHANES METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VWYL 2 VINYL 2 VWYL 2 VWYL 2 VINYL 1 VINYL 1 METHANES VWYL 2 VWYL 2 VINYL 2 VWYL 2 VWYL 1 METHANES VWYL 1 LGTI LGTI LGTI GLYCOL 1 POLY C POLY C POLY C POLY C POLY C POLY C POLY C POLY C POLY C VECTOR METHANES METHANES DOWANOLS LHC 2 METHANES METHANES METHANES DOWANOLS
04000 94060 94060 94060 94060 94060 93042 92146 93164 4791-29A 92140 93164 93154 93154 93154 93154 RCL B4-007 RCLB4-006 85133F 93154 93164 93154 93154 RCL 84-009 RCL 82-042 RCL 84-008 93022 93022 93032 91175 93215 93215 07033G B7033D 87033E 87033F 87033H 870331 87033J 93069 93093 93093 RCL1270.71 86223E RCL 63 092 RCL 82-045 B5173A RCL-9S-1061
HOM DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC HOM DSC HOM DSC HOM DTA DTA DTA DSC HOM DSC HOM DTA OTA DTA DSC DSC DSC DSC DSC HOM DTA DTA DTA DTA DTA DTA DTA DSC DSC HOM DTA DTA DTA DTA DTA DSC
Dow Confidanrtid
REACTIVITY
SL. EXOAT 22 C NO EXO TO 450 C SL. EXO AT 22 C EXO AT 360 C EXO AT 22 C NO EXO TO 325 C EXO AT 225 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 70 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 400 C SL. EXO AT 22 C NO EXO TO 200 NO EXO TO 185 NO EXO TO 250 C EXO AT BO C SL. EXO AT 22 C EXO AT 117 C SL. EXO AT 22 C NO EXO TO 1B6C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 300 C EXO AT31BC NO EXO TO 160 C EXO AT 170 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 260 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 260 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 310 C NO EXO TO 225 C NO EXO TO 200 C
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DO A 0 3 6 6 8 1 C O N F ID E N T IA L
i
PROCESS CHEMICAL
METHANOL METHANOL METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE + DIMETHYL ETHER METHYL CHLORIDE + DIMETHYL ETHER METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMWE METHYL DIETHANOLAMME METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE (LOC4B) METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE MONOETHYLENE GLYCOL MONOPROPYLENE GLYCOL + WATER MONOPROPYLENE GLYCOL + WATER N-PROPANOL (50%> + WATER (50%) NITROGEN OX BOTTOMS (T-102C TOWER) PER/TET (CRUDE) PER/TET (CRUDE) PER/TET (CRUDE) PER/TET ICRUOEI
is
TABLE 1. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL ISORTEO BY PROCESS CHEMICAL)
SEALANT
PLANT
REF. NO.
TEST
STEAM A PROCESS SP-1016 + SP-2000 TEAM LEAK REPAIRS SEALANT DB-2 756 STICK SEALANT SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOLI SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOLI SAFE SEAL MULTIPAK (JOHN CRANE 8KB| SAFE SEAL MULTIPAK (JOHN CRANE BKB) STEAM & PROCESS SP-1380 STEAM & PROCESS SP-2007 STEAM & PROCESS SP2026 STEAM A PROCESS SP-CM TEAM LEAK REPAIRS SEALANT OB-2 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT *6 CORTEC VCI-309 CORTEC VCI-309 CORTEC VCI-308 CORTEC VCF3QB NICKEL ANTISEIZE NICKEL ANTISEIZE & PERMATEX PERMATEX TEAM LEAK REPAIRS SEALANT *0 TEAM LEAK REPAIRS SEALANT 48 STEAM & PROCESS SP-CM SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK IUCAR CARBON CO GRAFOKJ SAFE SEAL GRAFPAK IUCAR CARBON CO GRAFOIL) SAFE SEAL MULTPAK (JOHN CRANE 6KB| SAFE SEAL MULTPAK (JOHN CRANE 6KB| STEAM ft PROCESS SP-103 STEAM ft PROCESS SP-1300 STEAM ft PROCESS SP-1380 STEAM ft PROCESS SP 2026 STEAM ft PROCESS SP-CM TEAM LEAK REPAIRS SEALANT OB-2 FURMANITE FSC-6B TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 2X SEMSTONE 145-S STEAM ft PROCESS SP-60 TEAM LEAK REPAIRS SEALANT 48 FURMANITE GASKET COATING ICL21 TEAM LEAK REPAIRS SEALANT 410 + F-46 FIBER TEAM LEAK REPAIRS SEALANT 411 TEAM LEAK REPAIRS VALVEPACK OX
Daw ConMartial
DOWANOLS METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHOCEL METHOCEL LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES GLYCOL 2 GLYCOL 1 GLYCOL 1 POLY B LGTI GLYCOL 1 SOLVENTS/EDC SOLV ENTS/EDC SOLVENTS/EDC SOLVENTS/EDC
RCL-95-1061 RCL 82-041 81126 94060 84060 B4060 94060 94060 94060 RCL 1679 84E156 85132A 86133B RCL 02-040 93196 93196 RCL-96-1372 RCL-96-1372 RCt-96-1379 RCL-96-1379 9309B 9309B B3098 RCL-95-0861 RCL-960861 4791-6A 04060 94060 94060 94060 94060 84060 RCL 1584 RCL 15B2 RCL 1677 86132B B6133C RCL 82-038 92143 91146 91146 90146 4791-43A 4791-36B 91064 09229 09141 89141
HOM DTA DSC HOM DSC HOM DSC HOM DSC DTA DTA DTA DTA DTA DSC HOM DSC HOM DSC HOM DSC DSC DSC DSC
HOM DSC HOM DSC HOM DSC HOM DSC DTA DTA DTA OTA DTA DTA DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC
REACTIVITY
NO EXO AT 22 C NO EXO TO 176 C NO EXO TO 175 C NO EXO AT 22 C EXO AT 375 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO TO 140 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 260 C NO EXO TO 190 C NO EXO TO 190 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C EXOAT 126 C EXO AT 160 C NO EXO TO 200 C NO EXO TO 260 C SL. EXO AT 22 C NO EXO TO 260 C NO EXO AT 22 C EXO AT 228 C NO EXO AT 22 C EXO AT 335 C NO EXO AT 22 C EXOAT 120 C NO EXO TO 160 C NO EXO TO 150 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 260 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXO AT 360 C NO EXO TO 190 C NO EXO TO 250 C EXO AT 245 C EXO AT 90 C EXO AT 145 C
1)0 A 0 3 6 6 8 ?
OONF T D F N T IA l
16
TABLE 1. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICALI
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
POTASSIUM CARBONATE 122%) IN WATER PROPANE PROPANE PROPANE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE (2C-64 OVERHEAD) PROPYLENE + REGAL 32 OIL PROPYLENE + REGAL 32 OIL PROPYLENE DICHLORIDE. CI2, AIR. Ha, WATER IE-1B) PROPYLENE DICHLORIDE. CI2. AIR. HCt WATER IE-1B) PROPYLENE DICHLORIDE. Q2, AIR. KCL WATER IE-1B) PROPYLENE DICHLORIDE. CI2. AIR. HCt. WATER IE-1B) PROPYLENE GLYCOL PROPYLENE GLYCOL 12%) N WATER PROPYLENE GLYCOL 12%) IN WATER PROPYLENE GLYCOL 12%) N WATER PROPYLENE GLYCOL (2%) IN WATER PROPYLENE OXIDE PROPYLENE OXIDE (CRUDE) PROPYLENE OXIDE (CRUDE) PROPYLENE OXIDE (CRUDE) PROPYLENE OXIDE PROPYLENE OXIDE + DIMETHYL ETHER/ METHYL CL PYGAS
YROLYSIS GAS 3 3 'YROLYSIS GAS 2 O `YROLYSIS GASOLINE 6 RESIN OL ^ 3YROLYSIS GASOLINE & RESIN OL 3 ^ QUENCH LIQUOR
-Ti 3 QUENCH LIOUOR 2 U> QUENCH LIQUOR >"--1J fT\ QUENCH LIOUOR
TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT 36 TEAM LEAK REPAIRS SEALANT X-38 ALB TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-5B FURMANITE FSC-6B FURMANITE FSC-6B FURMANITE FSC-6B LOCTITE 290 STEAM ft PROCESS SP-1011 STEAM & PROCESS SP-IOt 1 STEAM & PROCESS SP-20O0 STEAM & PROCESS SP-2000 TEAM LEAK REPAIRS SEALANT 32X TEAM LEAK REPAIRS SEALANT 32X TEAM LEAK REPAIRS SEALANT 32XH TEAM LEAK REPAIRS SEALANT *2XH TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK GX LOCTITE 290 FURMANITE FSC-40D FURMANITE FSC-46D STEAM & PROCESS SP-1300 STEAM & PROCESS SP-2026 TEAM LEAK REPAIRS SEALANT ft 1 TEAM LEAK REPAIRS SEALANT DB-2 TEAM LEAK REPAIRS SEALANT 36 FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-3A FURMANITE FSC-3A GRAFOL VALVE PACKNG STEAM & PROCESS SP-325 STEAM ft PROCESS SP-102 STEAM & PROCESS SP-389 TEAM LEAK REPAIRS SEALANT 36 TEAM LEAK REPAIRS TC-4 ICUREDI FURMANITE FSC-8B ROYAL PURPLE BARRIER FLUID 22 ROYAL PURPLE BARRIER FLUID 22 TEAM LEAK REPAIRS SEALANT 36 TEAM LEAK REPAIRS SEALANT X36 A&B FURMANITE FSC-6B FURMANITE FSC-6B STEAM & PROCESS SP-1011 STEAM ft PROCESS SP-1011
Dow Confidential
GLYCOL 2 PROMIX LHC 3 LHC 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 LHC 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL t VINYL 1 LHC 2 LHC 3 LHC 2 LHC 3 LHC 3 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 METHOCEL LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 VINYL 2 VINYL 2 VINYL 2 VINYL 2
91092 94071 92124 B6223H 93164 93164 93164 93164 92149 93154 93154 93164 93154 93164 93164 93164 93164 B4E196 84E197 66223A 93207 92149 93164 93164 RCL 1661 RCL1660 RCL 155B RCL 1669 91199 92026 92026 92026 92026 B4E069 RCL-96-0281 RCL-96-0262 RCL-98-0263 B9285 90324 91100 92169 92169 92124 92124 93164 93164 93164 93164
DSC DSC DSC OTA DSC HOM DSC HOM DSC OSC HOM DSC HOM DSC HOM DSC HOM DTA DTA OTA DSC OSC DSC HOM DTA DTA DTA DTA DSC DSC HOM DSC HOM DTA DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC HOM DSC HOM
REACTIVITY
NO EXO TO 200 C NO EXO TO 179 C NO EXO TO 160 C NO EXO TO 300 C NO EXO TO 260 C NO EXO AT 22 C NO EXO TO 226 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 260 C NO EXO AT 22 C NO EXO TO 260 C NO EXO AT 22 C NO EXO TO 260 C NO EXO AT 22 C NO EXO TO 260 C NO EXO TO 400 C NO EXO TO 210 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 210 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 190 C NO EXO TO 260 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 235 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 200 C EXO AT 120 C NO EXO TO 200 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 360 C NO EXO AT 22 C
DO A 0 3 6 6 8 3
C O N F ID E N T IA L
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL!
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LiaUOR QUENCH LIOUOR QUENCH LIQUOR QUENCH OK. IC-10 BOTTOMSI QUENCH OIL IC-10 BOTTOMSI R-2 & R-102 HYDROLYZER BTMS RANOO SB OIL RANDO 6B OR. RAN DO 6B OIL REGAL 32 OIL REGAL OR. 32 RESIN OIL RESIN OIL SHELL THERMIA C OIL WITH DISSOLVEO HCL SHELL THERMIA OR. C SHELL THERMIA OR. C SILICONE SWS-101 SMJCONE SWS-101 SS.ICONE SWS-101 SIMULATED VENT GAS SMULATED VENT GAS SLAG (LOC 37BI SLAG (LOC 37B) SLAG WATER (LOC 37| SLAG WATER (LOC 371 SODIUM BISULFITE SOLUTION M WATER SODIUM BISULFITE SOLUTION M WATER SODIUM HYDROXIDE (10%| SODIUM HYDROXIDE (10%l SODIUM HYDROXIDE (10%l SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%| SODIUM HYDROXIDE (10%)
ODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (3%) SODIUM HYDROXIDE (40%) HE-201 SODIUM HYDROXIDE <50%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE |S0%| SODIUM HYDROXIDE (50%)
STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT *2X TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT *6 FURMANITE FSC-5B FURMANITE FSC-6B STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2021 STEAM & PROCESS SP-325 TEAM LEAK REPAIRS SEALANT *6 SEAL-ITT +34 ROYAL PURPLE BARRIER RUIO 22 ROYAL PURPLE BARRIER RUIO 22 ULTRAMETAL LIQUID METAL (CURED) STEAM & PROCESS SP-1011 STEAM & PROCESS SP-109 SAFE SEAL - CHEMOLA TERON SAFE SEAL GRAFPAK IUCAR CARBON CO GRAFOM SAFE SEAL MULTPAK IJOHN CRANE 6KB) TEAM LEAK REPAIRS SEALANT DB-22 TEAM LEAK REPAIRS SEALANT DB-22 STEAM & PROCESS SP-102 STEAM & PROCESS SP-00 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX FURMANITE MASTER WRAP FURMANITE MASTER WRAP FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-flB FURMANITE FSC-6B FURMANITE FSC-6B PIG REPAIR PUTTY EPOXY STICK PIG REPAIR PUTTY EPOXY STICK SEAL-ITT *34 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-60 SEMSTONE 14S-S STEAM & PROCESS SP-6000 BELZONA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL SERVICE GROUP INC 107 ASB BONDER
VMYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 LHC 3 LHC 3 GLYCOL 1 POLYA POLYA POLYA LHC 3 CHLORME LHC 3 LHC 3 METHANES METHANES METHANES LHC 2 LHC 2 LHC 2 VINYL 2 VINYL 2 LGTI LGTI LGTI LGTI LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 CAUSTIC CAUSTIC CHLORME CHLORME CHLORME CHLORINE POLY B CAUSTIC CHLORME CHLORME CHLORME CAUSTIC
93154 93154 93154 93154 93154 93164 91363 91363 89378 93210 93210 93210 90034 90277 92169 92169 9302B 90400 90400 9403B 94038 94039 92302 92302 4791-6A 4791-6A 94065 94065 RCL-95-O401 RCL-95-0401 92093 92093 92093 92093 92093 92093 92137 92137 90277 92180 92180 921 BO 90146 4791-30B 85172F 84E180 86172C 89223
DSC HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC HOM DSC HOM HOM DSC HOM HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC DSC OTA OTA OTA DSC
Dow Confidential
REACTIVITY
NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 200 C EXO AT 36 C NO EXO TO 200 C NO EXO TO 260 C EXO AT 165 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 250 C EXOAT 126 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 120 C NO EXO AT 22 C NO EXO TO 235 C NO EXO TO 235 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO AT 25 C EXO AT 165 C NO EXO AT 22 C NO EXO AT 25 C NO EXO TO 200 C NO EXO AT 22 C EXO AT 160 C NO EXOAT 26 C EXO AT 166 C EXO AT 180 C EXOAT 170 C EXOAT 194 C EXOAT 166 C EXO AT 90 C NO EXO TO 260 C EXOAT 160 C NO EXO TO 250 C NO EXO TO 250 C
DO A 0 3 6 6 8 4 CO NFIDENTIAL
PROCESS CHEMICAL
SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) + AMMONIA SODIUM HYDROXIDE (50%) + AMMONIA SODIUM HYDROXIDE (50%) + NH40H SOUR CONDENSATE SS. CAST FE. CU. HAST. GRAPHITE. H20 STYRENE SULFUR (LOC 24) SULFUR (LOC 24) SULFUR (LOC 24) SULFUR (LOC 24) SULFUR (LOC 24) SULFURIC ACID SULFURIC ACID (96%) SULFURIC ACID 196%) SULFURIC ACID |96%l SULFURIC ACID (96%l SULFURIC ACID (96%| SULFURIC ACID SOLUTION (10 N) SULFURIC ACID SOLUTION |10 N) SULFURIC ACID SOLUTION 110 N) SULFURIC ACID SOLUTION |10 N| SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS BLEND SYNGAS BLEND SYNGAS BLEND T-62 BTMS T-B-2 BOTTOMS TET. PER. HCE, HQ. CHLORME TOLUENE- XYLENE MIXTURE
TABLE l REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
SEALANT
PLANT
REF. NO.
TEST
STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1015 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS SEALANT *16 TEAM LEAK REPAIRS SEALANT 16 TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT *16 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS TC-4 EPOXY BONDER TEAM LEAK REPAIRS SEALANT *6 DOW CORNING 111 LUB/SEALANT TEAM LEAK REPAIRS VALVEPACK AX CORTEC VCF309 COHTEC VCF368 STEAM 6 PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS SEALANT DB-2 BELZONA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2026 GRAFOR. GHE GASKET GRAPHITE MATT GRAFOR. GHE GASKET GRAPHITE MATT GRAFOR. GHE GASKET METAL MAI L * GRAFOR. GHE GASKET METAL MATT CORTEC VCF309 CORTEC VCF309 COHTEC VCF368 NEPTUNE RESEARCH SYNTHO-GLASS STEAM & PROCESS SP-3000 STEAM & PROCESS SP-429 TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 19X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT RF 300 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK EPX UTEX 684 SEALANT STEAM & PROCESS SP-1011 STEAM 8 PROCESS SP-102 STEAM 8 PROCESS SP-60 TEAM LEAK REPAIRS SEALANT *6 8 F-14 FIBERS FURMANITE FSC-5B TEAM LEAK REPAIRS CURED HI-PRO BELZONA 1311 CERAMIC fl-METAL SEALANT
METHANES DOWANOLS CHLOR-ALKAU 2 CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC LGTI LHC 3 VECTOR LGTI LGTI LGTI LGTI LGTI METHANES CHLORME CHLORINE CHLORME CHLOR-ALKAU 2 CHLOR-ALKAU 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI GLYCOL 2 GLYCOL 2 SOLVENTS/EDC LHC 2
RCL 1146 RCL 1233 92326 RCL 1008 RCL1005 871121 RCL 1009 RCL 1006 RCL 1368 870901 89271 93069 RCL-95-1376 RCL-95-6373 4791-5A 4791-5A 4791-BA RCL 92-044 B5172E B4E213 B5172B 851018 85101A 93011 93011 93011 83011 RCL-95-1376 RCL-95-1376 RCL-95-6376 93036 93125 93125 92318 92316 93123 93123 93072 92318 92318 RCL-96-0281 4791-42A 4791-43A 4791-43A 92160 93131 91050 RCL-96-0461
OTA OTA DSC DTA DTA DSC DTA DTA DTA DSC DSC DSC DSC DSC OSC DSC OSC OTA DTA DTA DTA DTA DTA DSC HOM DSC HOM DSC HOM HOM DSC DSC OSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC
Dow Confidential
REACTIVITY
NO EXO TO 295 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 230 C NO EXO TO 190 C NO EXO TO 200 C NO EXO TO 200 C EXO AT BSC NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 46 C NO EXO TO 250 C EXO < 30 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 250 C NO EXO AT 22 C EXOAT 137 C NO EXO TO 250 C NO EXO TO 76 C NO EXO AT 22 C NO EXO AT 22 C NO EXO TO 600 C NO EXO TO 600 C NO EXO TO 2B6 C NO EXO TO 400 C NO EXO TO 400 C EXO AT 362 C NO EXO TO 600 C NO EXO TO 600 C NO EXO TO 400 C NO EXO TO 400 C NO EXO TO 800 C EXO AT 47 C EXO AT 160 C EXO AT 366 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
TOLUENE- XYLENE MIXTURE
1.1.1 -TRICHLOROETHANE
1.1.1 -TRICHLOROETHANE TRIETHANOLAMINE TRIETHANOLAMINE TRIETHANOLAMINE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE
VINYL CHLORIDE VINYL CHLORIDE
VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIOE VINYL CHLORIDE VINYL CHLORIDE VMYL CHLORIDE VINYL CHLORIOE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE 180%) + ANHYOROUS HCt (20%) VINYL CHLORIDE {80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE 180%) + ANHYDROUS Ha (20%) VINYL CHLORIDE (80%) ANHYOROUS Ha (20%) .VINYL CHLORIDE (80%| + ANHYDROUS Ha (20%) VINYL CHLORIDE (80%| + ANHYDROUS HO (30%) VINYL CHLORIDE (80%) + ANHYDROUS HO (20%)
VMYL CHLORIDE (B0%) + ANHYDROUS Ha (20%I VINYL CHLORIDE (B0%) + ANHYDROUS Ha (30%) VMYL CHLORIDE (80%) + ANHYOROUS Ha (20%I
VMYL CHLORIDE (80%) + ANHYDROUS Ha 120%) ''MYL CHLORIDE (80%) + ANHYDROUS HCI 120%) n MYL CHLORIDE (80%) + ANHYDROUS HCI (20%) O O WYL CHLORIDE (80%) + ANHYDROUS HCI (20%) z O MYL CHLORIDE 180%) + ANHYDROUS Ha (20%l ' VASTE WATER EFFLUENT (P-6) C? WATER (COOLMG TOWER) "Tl O WATER IE7FI fj % WATER (E7F) -c b WATER (LOCT-144)
CO
Cn
BaZONA 1311 CERAMIC R-METAL SEALANT C5A Fa PRO NO. 725 NICKa ANTISEIZE MOLYKOTE 44 LUBRICANT STEAM 8 PROCESS SP-1011 STEAM 8 PROCESS SP-2000 FURMANITE FSC-460 FURMANITE FSC-460 FURMANITE FSC-5C FURMANITE FSC-6C FURMANITE FSC-68 FURMANITE FSC-6B STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM 8 PROCESS SP-2007 STEAM 8 PROCESS SP-325 STEAM 8 PROCESS SP-326 STEAM 8 PROCESS SP-429
TEAM LEAK REPAIRS SEALANT *11 TEAM LEAK REPAIRS SEALANT *2X TEAM LEAK REPAIRS SEALANT f2X TEAM LEAK REPAIRS SEALANT *2XH TEAM LEAK REPAIRS SEALANT (2XH TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-46D FURMANITE FSC-460 FURMANfTE FSC-6C FURMANITE FSC-SC STEAM 8 PROCESS SP-1011 STEAM 8 PROCESS SP-1011 STEAM 8 PROCESS SP-325 STEAM 8 PROCESS SP-326 TEAM LEAK REPAIRS SEALANT #18X TEAM LEAK REPAIRS SEALANT 418X TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT 48 TEAM LEAK REPAIRS SEALANT 48 + F-14 FIBER TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS SEALANT 18X STERUNO STUFFING BOX SEALANT 41 TEAM LEAK REPAIRS 16X 8 F-10 8 F-14 FIBERS TEAM LEAK REPAIRS SEALANT 18X 8 F-10 FIBERS STEAM 8 PROCESS SP-102
Dow Confidanttil
LHC 2 POWER 1
POWER 1 GLYCOL 2 GLYCOL 2 GLYCOL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VMYL 2
VMYL 2 VMYL 2 VMYL 2
VMYL 2 VINYL 2 VMYL 1 VMYL 2
VMYL 2 METHANES VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 1 VMYL 1 VMYL 1 VMYL 2 VMYL 2 VMYL 2
VMYL 2 VMYL 2
VMYL 2 VMYL 2 VMYL 2
VMYL 2 VMYL 2
VMYL 2 VMYL 2 VMYL 1 VMYL 1 VMYL 1 GLYCOL 1 LHC 3
GLYCOL 2 GLYCOL 2 LGTI
RCL-96-0461 89050
89050 94030 94030 84030 83164 83164 83164 93154 93154 93154
83164 93164 93164
93164 3109-46
93154 93164 93179 93147 93164 93164 93164 93164 94E196 3108-46
3108-46 93164
93164 93164 93164
93164 93164 93164
93164 93164 93164
93164 93164 RCL 83-096 RCL 83-097 84E191 90264 91135 82180 92160 4791-6A
HOM
DSC DSC DSC DSC DSC DSC HOM DSC
HOM DSC
HOM DSC
HOM DSC
HOM OTA
DSC HOM DSC DSC DSC HOM DSC HOM DTA DTA
DTA DSC
HOM DSC
HOM DSC
HOM DSC
HOM DSC HOM
DSC HOM DTA DTA DTA DSC DSC DSC DSC DSC
REACTIVITY
NO EXO AT 22 C EXO AT 126 C EXOAT 133 C EXO AT 240 C EXO AT 320 C EXO AT 319 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C EXO AT 149 C a. EXO AT 22 C NO EXO TO 350 C a. EXO AT 22 C NO EXO TO 200 C a. EXO AT 22 C NONE NO EXO TO 220 C NO EXO AT 22 C EXO AT 114 C EXOAT 136 C EXO AT 336 C NO EXO AT 22 C EXO AT 264 C NO EXO AT 22 C NO EXO TO 226 C NONE NONE NO EXO TO 360 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C EXOAT 17BC NO EXO AT 22 C NO EXO TO 250 C
SL. EXO AT 22 C NO EXO TO 250 C a. EXO AT 22 C NO EXO TO 260 C a. EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 400 C NO EXO TO 250 C NO EXO TO 260 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 260 C
DO A 0 3 6 6 8 6
GONFTDFNTTAL
PROCESS CHEMICAL
WATER ILOCT-1441 WATER WITH < 1 * GLYCOLS WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM
VATER/STEAM O ATER/STEAM p ^ ATER/STEAM
^ ATER/STEAM
-f X> ATER/STEAM ^ ATER/STEAM 2 ATER/STEAM
H ?' ATER/STEAM r| ^ ATER/STEAM - F ATER/STEAM
20
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL!
SEALANT
PLANT
REF. NO.
TEST
STEAM & PROCESS SP-00 STEAM & PROCESS SP-1011 COPALTITE CEMENT SEALANT CORTEC VCI-309 CORTEC VCI-309 CORTEC VCF38B CORTEC VCF388 FURMANITE OENEEF FLEX-LV SEALANT FURMAN ITE OENEEF FLEX-LV SEALANT FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-11C FURMANITE FSC-3A FURMANITE FSC-6B FURMANITE FSC-8B FURMANITE FSC-7C FURMANITE FSC-SOD FURMANITE FSC-60D PUDCO S.P. SEALANT (3-STTCK) SERVICE GROUP INC SG-101 LIQUID SERVICE GROUP PIC SG-tOt SOLID SERVICE GROUP PIC SG-101HT SERVICE GROUP PIC SG-102 SOLID SERVICE GROUP PIC SG-100 LIQUID SERVICE GROUP PIC SG-108 ABB SERVICE GROUP PIC SG-109 SERVICE GROUP PIC SG-110 SOLID SERVICE GROUP PIC SG-113 SERVICE GROUP PIC SG-201 SERVICE GROUP PIC SG-201HT SERVICE GROUP PIC SG-250 SERVICE GROUP PIC SG-302 SERVICE GROUP PIC SG-303 SERVICE GROUP PIC SG-304 SERVICE GROUP PIC SG-306 SERVICE GROUP PIC SG-312 SERVICE GROW PIC SGC FIBER SERVICE GROUP INC SGK FIBER STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2016 STEAM ft PROCESS SP-2S11 TEAM LEAK REPAIRS SEALANT *1 TEAM LEAK REPAIRS SEALANT P1BX
LGTI GLYCOL 2 LHC 3 LGTI LGTI LGTI LGTI LHC 3 LHC 3 VftlYL 2 VINYL 2 LHC 3 LHC 3 LHC 3 VftlYL 2 LHC 3 LHC 2 LHC 2 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 METHANES VftlYL 2 VftlYL 2 VftlYL 2 VftlYL 2 VftlYL 2 CHLOR-ALKALI 2 METHANES METHANES VftlYL 2
4791-SA 92194 4792-26A RCL-96-1371 RCL-05-1371 RCL-95-1378 RCL-95-1378 RCL-9B-0501 RCL-96-0501 93154 93154 93020 90312 91052 93164 90312 RCL-95-1471 RCL-95-1471 4792-26A B9272 B9272 B9272 B9272 B9272 B9272 B9272 B9272 B9272 B9272 B9272 99272 89272 89272 89272 B9272 B9272 B9272 B9272 90037 93164 93164 93154 93164 93154 84E134 860BOA RCL 93-017 93164
DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC HOM OTA DTA OTA DSC
Dow Confidential
REACTIVITY
NO EXO TO 260 C NO EXO TO 260 C EXO AT 130 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C EXO AT 34 C EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 296 C NO EXO TO 380 C NO EXO TO 400 C NO EXO AT 22 C NO EXO TO 320 C NO EXO TO 260 C NO EXO AT 22 C EXO AT 339 C NO EXO TO 320 C EXO AT 117 C NO EXO TO 350 C NO EXO TO 330 C NO EXO TO 340 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 276 C EXOAT 1B5 C EXO AT 76 C EXO AT 126 C NO EXO TO 325 C NO EXO TO 350 C EXO AT 280 C NO EXO TO 325 C NO EXO TO 290 C NO EXO TO 360 C NO EXO TO 325 C NO EXO TO 326 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 325 C NO EXO AT 22 C NO EXO TO 260 C NO EXO TO 276 C NO EXO TO 160 C NO EXO TO 300 C
PROCESS CHEMICAL
WATER/STEAM WATERJSTEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM
ZEROL 300 OIL
i
21
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL!
SEALANT
PLANT
REF. NO.
TEST
TEAM LEAK REPAIRS SEALANT #1BX TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT 12X TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT PRM02C TEAM LEAK REPAIRS SEALANT SW TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK EPX THORTEX CERAMI-TECH F.G. CURED SEALANT THORTEX CERAMFTECH E.G. CURED SEALANT WHITE BAKERSEAL SEALANT
VINYL 2 VINYL 2 VINYL 2 GLYCOL 1 VWYL 2 GLYCOL 1 CAUSTIC GLYCOL 1 LGTI VINYL 2 VINYL 1 DOWANOLS POWER 2 LHC 2 LHC 2 LHC 3
93154 93154 93154 90041 93154 RCL-90-2001 971122 91159 930B8 93075 RCL B3-019 94016 91162 RCL-95-0641 RCL-95-0642 4792-26A
HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC DTA DSC DSC DSC DSC DSC
TEAM LEAK REPAWS PRI-102C (THREADS)
POLYA
91028
DSC
REACTIVITY
NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 335 C NO EXO AT 22 C NO EXO TO 309 C NO EXO TO 2B5 C NO EXO TO 300 C NO EXO TO 230 C NO EXO TO 275 C NO EXO TO 160 C NO EXO TO 316 C NO EXO TO 350 C NO EXO TO 250 C NO EXO TO 260 C EXO AT 300 C
NO EXO TO 250 C
DO A 0 3 6 6 8 7
CONFTDFNTTAl
Dow Confidential
CHLOR ALKALI
SHUTDOWN, AND TURNAROUNDS REACTIVE CHEMICALS CONCERNS
ISOLATION AND CLEARING
CHLORINATED HEAVIES
TAFFY POTS (D-227'S ) PURIFICATION LIQUID CHLORINE EVAPORATION
CAUSTIC
WATER ENTERING CAUSTIC VESSELS
CHLORINE
ISOLATION FROM TITANIUM EQUIP. AND MOISTURE
FUEL GAS & HYDROGEN
PURGE PROCEDURES, NITROGEN PURGES AS INTERMEDIATES
HYDROGEN
ANALYZERS - CORRECT OPERATION
SULFURIC ACID
HEAT OF DILUTION & CORROSION
Document in GENERAL.OBD
Dow Confidential
1/27/97 ^
Co/v^rnc,'3^6f5f5
