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IO ROBINTECH INCOMOMT CD corporate orrice* (817) 332-7323 P.a BOX 2342 FORT'WORTH, TEXAS 76101 STATEMENT OF ARTHUR A, SMITH Vice President of Operations Robintech Incorporated Fort Worth, "Texas Prepared for Presentation at the Department of Labor Hearing on Vinyl Chloride; Occupational Exposure Standard June 25, 1974 - I am Arthur A. Smith, presently Vice President of Operations for Robintech Incorporated, headquartered in;Fort Worth, Texas. Robintech is a producer of polyvinyl chloride resin with; plant in Painesville, Ohio. A second plant is cinder construction at Freepbrt, Texas. f' Robintech is also a manufacturer of PVC pipe and fittings. We currently operate nine plants in eight states with the tenth plant under construction. We have two other plants on the drawing boards. I left the teaching profession and began itiy industrial work career in the early 1950s, when I was employed .by a PVC Resin Producer (Diamond Alkali), as a chemist in its quality control laboratory. This work assignment required daily analysis of vinyl chloride monomer and polyvinyl chloride resin. Due to the state of the art at that time, my activity required daily contact with liquefied vinyl chloride monomer. As our product line expanded, I began working on polymer develop ment in our polymerization pilot plant to develop and prove out recipes for new and/or improved resins. At this point in time, I began doing some Technical Service work OLI 938 *\ RDBINTECH ihceroR*tto CO**RATE OFFICES Statement of Arthur A. Smith Occupational Exposure Standard Page 2 * with customers in their processing or converting plants. In the late 1950s, I changed assignments and began working solely in Technical Service and Sales, calling on all types of processors and convertors using polyvinyl chloride resin. 4 This involved working with customers on their equipment in search of solutions to specific problems in extrusion, calendering, and molding. Since the early 1960s, I have been in the management of either sales or manufacturing (processing) of polyvinyl chloride resin. In my present position, when we received word about the alleged tie between vinyl chloride monomer and angiosarcoma of the liver this year, we began monitoring our products for residual VCM, monitoring our PVC plant, and monitoring^>ur pipe and fittings plants. As the potential for processing plant involvement became a question, I became associated with the SPI committee and worked with the task force assigned to study the fabricator situation. It would first be well to recognize there are hundreds of processing plants with multi-product lines within the same facility. Many processing plants utilize only pelletizing compounds. Some use both resin and pelletized compound, while others use only specialized OLI 939 \ RDBINTECH iNCOBPOMATCO corporate offices Statement of Arthur A. Smith Occupational Exposure Standard Page 3 resins. The main difference between pelletized compound and resin is that the pelletized compound has additives incorporated and has been subjected to an extensive heat history. There is still another category of processor who utilizes a powder blend compound which has also been subjected to heat history. There are combinations of types of processing plants such as molding, calendering, extrusions, and coatings. There are also numerous combinations within these types of processes. I have been working on the task force investigating and collecting data from the processors plants. We have collected data from numerous sources, even some from Europe. Since no two plants are alike, we set out to have all our plants monitored and results obtained on the same methodology with same instruments and same technicians. In addition to this, we have requested our insurance carrier to make the same survey with their Industrial Hygienist and both sets of this data are attached. This data teaches us that our range is from no detectable level on the low side to tfisS ppm; that level being present only directly above the intensive mixer. Personnel carbon tube sample for the same ar a shows 15.4 ppm vinyl OLI 940 N RDBINTECH inco*oaat co COftfOftATE OFFICES Statement of Arthur A. Smith Occupational Exposure Standard Page 4 37-L, chloride. This high level of ppm can readily be eliminated by venting the mixer through safe work procedures. The mixing room areas range from zero ppm to a high of 20.5 ppm. In connection with this area of the plant operation, it is felt that if the area meets the current clean air portion of an existing standard - 1910.93, the employee will not be exposed to hazardous levels of vinyl chloride monomer. Based on all our findings, we join in the view that processing plants should be excluded from the coverage of the proposed standard, since it has been demonstrated that there is no significant exposure for employees in ar as other than in mixing operations, where readily attainable ventilation and work practice procedures will eliminate any possible danger. * AAS/if Arthur A. Smith OLI 941 \ RDESNTECH INLt*dl'r.O corporate offices (817) 332-7323 P.O. BOX 2342 FORT WORTH, TEXAS 76101 PLANT SURVEY All the values shown here are results of carbon tube (Siptn Pumps) at the locations noted. Robintech Incorporated Springfield, Kentucky 1. Extruder Operator 2. Operator at Cut-Off Saw 3. Blending Operator (Transferring Material) 4. Operator at Cut-Off Saw & Belling Vinyl Chloride 1.3 ppm 1.4 ppm 0.3 ppm 0.5 ppm Robintech Incorporated Pace, Florida 1. Mixing Operator during Cycle (AM) 2. Mixing Operator during Cycle (AM) h Mixing Operator during Cycle (AM) 4. Mixing Operator during Cycle (PM) 5. Mixing Operator during Cycle (PM) 6. Mixing Operator during Cycle (PM) 7A. Extruder Operator 8A. Extruder Operator 9A. Extruder Operator 10A. Extruder Operator 24.6 ppm 15.4 ppm 18.6 ppm 17.2 ppm 32.2 ppm 18.6 ppm 0.4 ppm 1.0 ppm 5.6 ppm 4.6 ppm OLI 942 \ ro I U RDBENTECH INCO*^OHATED CORPORATE OFFICES Plant Survey Page 2 - continued Robintech Incorporated Anderson, South Carolina 7B. Main Office Building Office 8B. Belling Machine Operator (3/4" Dual Line) (BT-100) 9B. Belling Machine Operator (4" Dual Line)(A4/125/125) 10B. Operator Walking over Entire Plant 11. Extruder Operator A4/125 12. Blender Room Operator Transferring Material, only Vinyl Chloride <0.2 ppm <0.2 ppm <.0.2 ppm < 0.2 ppm < 0.2 ppm < 0.2 ppm Some Industries (Robintech Subsidiary) Rolla, Missouri 13. 14. 15. 16. 17. 18. *19. Extruder Operator Extruder Operator (Smoking during test) Blender Operator in Area of Screening Extruder Operator Blender Operator in the Screening Operation Mixing Operator during Mixing Cycle Mixing Operator during Mixing Cycle CM O V < 0.2 ppm 0.2 ppm 7.5 ppm PPm 7.4 ppm 37.6 ppm 19.2 ppm * Recheck of No. 18 OLI 943 ro ( iw RDBINTECH !NCCOMTip CORPORATE OFFICES Plant Survey - Continued Page 3 Robintech Incorporated Grinnell, Iowa 20. Extruder Operator 21. Extruder Operator 22. Extruder Operator 23. Mixing Operator during Transfer of Material (not mixing) 24. No Sample - (battery down) Vinyl Chloride <0.2- ppm <0.2 ppm <0.2 ppm <0.2 ppm ppm Robintech Incorporated Hillsboro, Texas 24. Extruder Operator 25. Extruder Operator 26. Injection Molding Machine Operator (Van Dorn Machine) - 27. Grooving Machine Operator (#2) 28. Grooving Machine Operator (#4) 29. Grooving Machine Operator (#3) 30. Injection Molding Machine Operator (Lombard Machine) 31. Injection Molding Machine Operator (Lombard Machine) 32. Injection Molding Machine Operator <0.2 ppm < 0.2 ppm 0.6 ppm 1.0 ppm 2.0 ppm 1.4 ppm 1.2 ppm <0.2 ppm <0.2 ppm OLI 944 r) Ij U ROOINTECH IHCOHFOUATEO CORPORATE OFFICES Plant Survey - Continued Page 4 Vinvl Chloride 33. Injection Molding Machine Operator <0.2 ppm 34. Injection Molding Machine Operator 35. Grooving Machine Operator (#2) *0.2 ppm <0.2 ppm 36. Injection Molding Machine Operator * 0.2 ppm Robintech Incorporated Newman, California 37. Extruder Operator (Dual Line) 38. Grinder Operator 39. Belling Operator (3 "pipe) 40. Extruder Operator (Single Line) 41. Quality Control Laboratory (Table) 42. Mixing Room.Operator (Not mixing) 43. Mixing Room Operator (Transferring * Material) 0.2 ppm <0.2 ppm < 0.2 ppm 1.7 ppm <0.2 ppm < 0.2 ppm <0.2 ppm Robintech Incorporated Elsinore, California 44. Extruder Operator (Purging material) 45. Extruder Operator (BT-100 Dual Line) 46. Extruder Operator (Purging Machine) 47. Mixing Room Operator (Not mixingTransferring) 48.] 49.] Tubes Voided N <0.2 ppm < 0.2 ppm < 0.2 ppm 1.1 -BrokenOLI 945 ~ ROOiNTECH v v/ iNCQ"*OfATCD CORPORATE OFFICES Plant Survey - Continued Page 5 Robintech Incorporated Vestal, New York Vinyl Chloride 50. Office (Main Office Building) 51. Extruder Operator <0.2 ppm <0.2 ppm 52. Grinding Operator < 0.2 ppm 53. Inside Water Drainline in Field (Process Drain Water) 0.2 ppm 54. Laboratory Supervisor at Desk 1.6 ppm 55. Cable Assembler at Work-2nd Floor <0.2 ppm 56. Mixing Room in Application Laboratory <0.2 _ppm AAS/if V OLI 946 The CONTINENTAL INSURANCE companies INC CONTINENTAL INSURANCE COMPANY FIREMEN'S INSURANCE COMPANY NIAGARA FIRE INSURANCE COMPANY TO FIDELITY AND CASUALTY COMPANY COMMERCIAL INSURANCE COMPANY SOSTON OLD COLONY INSURANCE COMPANY NATIONAL>REN FRANKLIN COMPANIES SEABOARD FIRE i MARINE INSURANCE COMPANY BUCKEYE UNION INSURANCE COMPANY KANSAS CITY FIRE B MARINE INSURANCE COMPANY THE GLENS FALLS INSURANCE COMPANY PACIFIC INSURANCE COMPANY 1810 Commerce Street, Dallas, Texas 75201 May 29, 1974 INDUSTRIAL HYGIENE SURVEY BDBINTECH, INC. PLASTIC PIPE PLANT HILLSBORO, TEXAS HAY 10, 1974 On May 10, 1974, an industrial hygiene survey was conducted at the above location to determine concentrations of vinyl chloride in the working atmosphere. Recent studies have implicated vinyl chloride as the possible cause of a rare form of liver cancer known as angiosarcoma. Present Federal standards limit permissible working air concentrations of vinyl chloride to a ceiling value of 50 parts per million. A new standard has been proposed, however, which would make any detectable level of vinyl chloride a violation (based on a method sensitive to 1 part per mi 1.1 ion). Battery-operated MSA Monitaire Pomps were used in conjunction with activated charcoal tubes to collect seven (7) air samples in the resin mixing and ex trusion areas. Subsequent analysis by gas chromatography yielded the fol lowing results' . Sample # Area ppm Vinyl Chloride 1 Resin Mixing Area (Operator1s Breathing Zone) 0.4 2 Mixed Resin Storage Area 0.1 3 Resin Mixing Area (No Activity) None Detectable* 4 Extruder 0. (Operator's Breathing Zone) "" 5 Extruder 0. (Adjacent to Point of Extrusion) " OLI 947 \ m CONTINENTAL INSURANCE COMPANIES Robintech, Inc. Hillsboro, Texas May 29, 1974 Page 2 Sample # 6 7 Area Extruder #1 (Adjacent to Point of Extrusion) Extruder #2 (Adjacent to Point of Extrusion) Detectable Limit--.005 ppm ppm Vinyl Chloride None Detectable* tt " Comments Vinyl Chloride concentrations in a plant extruding FVC are a direct' function of the purity of the polymer resin. The use of a resin with large amounts of unreacted monomer v/ill obviously produce higher air concentrations of vinyl chloride. This data indicates the use of a high quality PVC resin. If this continues, VC air concentration should remain low. If there are any questions regarding this report, please contact me. Patrick Murphy J Industrial Hygienist PM/mde Original: Mr. Johnny Miller, Plant Manager - Hillsboro cc: Mr. B. G. Corbett, President - Robintech, Inc. - Ft. Worth cc: i/Mr, Ed Bardgett, Director of Industrial Relations - Ft. Worth cc: Mr. Tom Gastineau - Paul Rathgerber & Company - Ft. Worth cc: Mr. Charley Griffith, General Manager - Hillsboro cc: Mr. Kenneth King - Special Risk Department cc: Mr. Ronald Williams - LC&E Department INDUSTRIAL HYGIENE SURVEYS ARE MADE FOR EITHER RATING PURPOSES OR AS PART OF THE COMPANY'S OPTIONAL ADVISORY SERVICE FOR ASSISTING YOU WITH YOUR LOSS CONTROL PROBLEMS. THESE INSPECTIONS ARE IN NO WAY INTENDED AS A SUBSTITUTE FOR YOUR OWN LOSS CONTROL PROGRAM AND MORE FREQUENT LOSS CONTROL INSPECTIONS AND BECAUSE OF THEIR PURPOSE AND RELATIVE INFREQUENCY, SHOULD NOT BE REGARDED AS A SUBSTITUTE FOR YOUR OWN EFFORTS AT SAFETY AND HEALTH MAINTENANCE. OLI 948 V ACM ?Qt4A INTER-OFFICE COMMUNICATION THK CONTINBIMTAL. INSUftANCC OOMMANtU TO D. McNamara AT Industrial Hygienist - Dallas FROM A. K. Roy-Chowdhury AT Environmental Health Laboratory SUBJECT Robintech Vinyl Chloride Samples DATE June 18, 1974 Please receive the following results on air borne samples obtained by our Departmental Industrial Hygienist. Surveyed by: D. J. Going - Pacific Industrial Hygienist June 13, 1974 - Elsimore, Ca. 5 extruders, (3 & 5 off) Equipment: SKC Charcoal Tubes Bendix C115 pump ser#1074 & 1090 Setting: 35 - 0.1 liter/min Type Sampled Location Volume sampled in Liters Field EHL Sample# Sample# Results Per. Area Area Area Area Fer. Area Area Area Blank M. Rodriguez 2.0 Machine Tender Control Pannel //I 2.0 Line - 6" pipe IKC Same as (2) 2.3 Between extruder 2-4 2.1 Same as (4) 2.0 A. Harvey 2.0 Machine Tender Between 4-5 (5 off) 2.0 Same as (7) 1.8 Blending Room 1.7 (No work) Blank * D7000 D7001 D7002 D7003 D7004 D7006 D7005 D7007 D7008 D7009 D7010 A1064 A1065 A1066 A1067 A1068 A1069 A1070 A1071 A1072 A1073 A1074 0.00 ppm <0.05 ppm <0.05 ppm <0.05 ppm <0.05 ppm <0.05 ppm <0.05 ppm <0.05 ppm <0.05 ppm 0.09 ppm 0.00 ppm Surveyed by: Gerry Tovatt - Western Department Industrial Hygienist June 17, 1974 - Grinnell, Iowa 1 liter/min ^Sample was taken on edge of bin as PVC filled it from hopper above, cycle actually only lasted 5-6 min. Blank #2 extruder 1* away 15 1 foot from extrusion 15 Cutting cold tube, 3* 15 away Mixing platform 15 #5 extruder 1/2-1* 15 D8001 D8002 D8003 D8004 D8005 D8006 A1085 A1086 A1087 A1088 A1089 A1090 0.00 ppm 0.04 ppm 0.03 ppm 0.74 ppm 0.00 ppm 0.05 ppm OLI 949 V OEM Trtl4 INTER-OFFICE C MMUNICAHON *m continental. in*uwamc* com^anim _______________________________________________________________________________ TO D. McNamara FKQM A. K. Roy-Chowdhury UmjBCT Robintech Page 2 AT Industrial Hygienits - Dallas AT Environmental Health Laboratory OATE June 18, 1974 Type Sampled Location Mixing * #4 above extruder 1/2-1' #4 Same as 8009 Volume Sampled in Liters 15 15 15 Field EHL Sample # Sample # D8008 D8009 A1091 A1092 D8010 A1093 Results 0.27 ppm 0.06 ppm 0.00 ppm Surveyed by: Gerry Tovatt - Western Department Industrial Hygienist June 17, 1974 - Rolla, Missouri * This plant mixes PVC with Polystyere - Grinnell plant had premixed batches in R. R. cars Top mixing platform addition of PVC to Polystyene 15 D8011 A1075 5.42 ppm ik Underneath mixing 15 platform, auto controls D8012 A1076 2.95 ppm Extruder, same as 8014 #4 15 D8013 A1077 0.34 ppm Extruder, open to room #4 (low rate had to readjust) 18 * D8014 A1078 0.49 ppm #5 extruder, closed train to water 15 D8015 A1079 0.14 ppm #5 extruder #2 extruder, closed train to ^o 15 15 D8016 D8017 A1080 A1081 0.70 ppm 0.33 ppm Blank #2 extruder Mixing platform, same as 8011 Blank 15 15 Blank D8018 D8019 D8020 A1082 A1083 A1084 0.28 ppm 12.22 ppm 0.00 ppm * Sample #A1076 (D8012) was analysed for breakthrough of second compartment and found to have 2.21 ppm. The quantity of airborne contaminant in the work place would exceed 5.16 ppm as absorption is taking place concurrent with desorption of vinyl chloride on the charcoal tube. OLI 950 N CM 70UA INTER-OFFICE COMMUNICATION THE CONTINENTAL INSURANCE COMPANIES TO D. McNamara FROM A. K. Roy-Chowdhury SUBJECT Roblntech Page 3 AT Industrial Hygienist - Dallas AT Environmental Health Laboratory BATt June 18, 1974 Surveyed by: D. J. Going - Pacific Industrial Hygienist June 14, 1974 - Newman, Ca. Plant Manager - Gary Zunino 6 extruders (4, 5, 6 off) Sampling rate 0.1 liters per minute Bendix C115 pump ser #1074 & 1090 Type Sample Location Volume sampled in liters Field EHL . Sample # Sample // Area Area Area Per. Area Area Area Blank Between 2-3 extruder Take off between line 1 & 2 Same as 12 J. Alvemaz, line 3 operator 2" Ag pipe Between 1-2 extruders Blending Room (No work) Same as 16 Blank 2.1 1.9 2.0 2.0 1.8 2.0 2.0 D7011 D7012 D7013 D7014 D7015 D7016 D7017 D7018 D7019 A1055 A1056 A1057 A1058 A1059 A1060 A1061 A1062 A1063 Results 0.00 ppm 0.19 ppm 0.41 ppm 0.88 ppm 0.20 ppm 0.26 ppm 0.20 ppm 0.20 ppm 0.00 ppm Surveyed by: R. Gils, Industrial Hygienist Southeastern Department June 12, 1974 - Anderson, S. C. Person Interviewed - Joe Perry, Manager All area samples except D5016 and D5018 were collected via a gas pump equipped with a calibrated orifice (1L). All other samples were collected via Bendix C115 pumps calibrated to .5L before and after each sampling period to assure accuracy. G. Hayes, Blending 5 Operator Blending Room with blower in operation (PVC 10 pellets being drawn in) D5008 A1042 D5009 A1043 0.11 ppm 0.04 ppm B. Hargraves, Machine Tender, Line 3 C.Price, Machine Tender, Line 4 J. Johnson A. Dubois, Machine Tender, Line 5 Maintenance Shop C nter of room 5 5 5 5 10 D5010 D5011 D5012 D5013 D5014 A1044 A1045 A1046 A1047 A1048 0.22 ppm 0.09 ppm 1.31 ppm 0.26 ppm 0.04 ppm OLI 951 QtN TOUA cINTCR-OFnCI MMUNICATION THK COMriNKNTAI. INSURAfXCK COMOANIKS TO D. McNamara PWOM A. K. Roy-Chowdhury AT Industrial Hygienist - Dallas AT Environmental Health Laboratory SUSJDCT Robintech Page 4 BATS June 18, 1974 Type Sample Location Volume Sampled In Liters Field EHL Sample # Sample # C. Hall 5 Maintenance Man * Line #1, on 5 cooling tank * Line it5 west wall 10 Regrind storage Bldg. 5 * Sample between lines 10 2&3 D5015 D5016 D5017 D5018 D5019 A1049 A1050 A1051 A1052. A1053 Results 0.00 ppm 0.07 ppm 0.04 ppm 1.36 ppm 0.00 ppm * Indicates area sample. Surveyed by: W. C. Christoffer, Industrial Hygienist Western Department June 14, 1974 - Springfield, Kentucky Per. Worn by Employee 15 Area Platform above bins 20 being filled Blank Line #0 -4" 1 ft. from 20 open extruder head - (flow pulsation was noted on this sample, probably because of heat)i D8500 D8501 D8502 D8503 A1023 A1024 A1025 A1026 0.27 ppm 0.26 ppm 0.00 ppm 0.12 ppm Same as above 20 D8504 A1027 0.11 ppm Line #1 - 4"- 1 ft. from enclosed extruder head 20 D8505 A1028 0.05 ppm Feed hopper for line #1 between #0 and it 1 extruder 22 D8506 A1029 0.21 ppm Same as above 15 D8507 A1030 0.22 ppm Line #5 - 4" - 1ft. from open extruder head 16 D8508 A1031 0.16 ppm Line #4 - 2" by pipe cutter 1.5 ft. from pipe 15 D8509 A1032 0.03 ppm Line #2 - 8" by pipe cutter 1.5 ft. from pipe 18 D8510 A1033 0.03 ppm Line #2 - 8" end of cooling line 1 ft. from pipe 20 D8511 A1034 0.06 ppm OU 952 \ CM tOMA INTER-OFFICE C MMUNICATION THK CONTINKNTAI. INSURANCE COM^ANIU TO D. McNamara AT Industrial Hygienist -Dallas moM A. K. Roy-Chowdhury SUBJSCT Robintech Page 5 AT Environmental Health Laboratory BATS June 18, 1974 Surveyed by: R. Gils, Industrial Hygienist Southeastern Department June 14, 1974 - Pace, Florida Mr. Bob Odgers, Plant Manager Mr. Walt Martin,, Technician - Chicago All samples were collected via Bendix C115 pumps calibrated to .5L before and after each sampling period to assure accuracy,k Type Sample Location Volume Sampled in Liters Field EHL Sample t Sample # Results Operates desk end of extruder A4125 5 T. Needhel - Plant Supt. 5 B. Hopkins, Line tender 5 Raw materials storage area (center of room) 5 Blending area on work platform (No blending) 5 Blending room flcor or. top of freshly blended PVC (no blending underway) 5 Collected at extruder port during starting up of extruder BT-100 (great deal of smoke) pump stopped functioning between 10-20 minutes after started sampling >2.5 Sample conditions same as (D 5026) collected on machine A2280 cooling tank during start-up of unit BT-100 (Great deal of smoke from decomposition of PVC pipe) 3.75 Sample conditions same as (D5026) except collected on extruder A4L25 great deal of smoke from decomposition of PVC pipe 3.5 Blank D5020 D5021 D5022 D5023 D5024 A1130 A1131 A1132 A1133 A1134 D5025 A1135 0.00 ppm 0.00 ppm 0.16 ppm 0.66 ppm 0.25 ppm 0.98 ppm D5026 A1136 <0.37 ppm D5027 A1137 0.33 ppm D5028 D5029 A1138 A1139 0.30 ppm 0.00 ppm CN .TftliA INTER-OFFICE COMMUNICATION THK eONTlNKMTOU. INSUPIANCK COMPANIES TO FMOM SUUCCT D. McNamara AT Industrial Hygienist - Dallas A. K. Roy-Chowdhury AT Environmental Health Laboratory Roblntech Page 6 DATS June 18, 1974 Surveyed by: Ron Kipp.Industrial Hygienist Glens Falls June 16, 1974, Vestal, New York Type Sample Location Volume Sampled in Liters Field EHL Sample # Sample # Results Zaffar Heating & Belling Saleem line #5 (also at saw) 11 Craig Glis Heating & belling line #2 - 2AC (also at saw) 10 Dick Glis Craig At extruder head line n 16 Heating & belling line Gilh #2 - 2AC (also at saw) 18 Zaffar Heating & belling Line 19 Saleem #5 Dick Heating and belling Geis line #2 - 2AC (also at saw) 9 Zaffar Heating & belling Line Saleem #2 - 2 AC (also at saw) 14 -- "" 6" from sizing sleeve line #2 13 Craig Gilh Heating & belling line 92 ~ 2 AC (also at saw) 14. Line 95 at heater on belling station, 4" distance A. David 91 Bend fabrication 6 2 heaters/fab. area #1 13 T. 92 bend fabrication Hromada "ID to Down Stair" 92 13 D. 93 bend fabrication Martio process sample 12" above 4R heater 8 Above 1 11 D1000 D1001 D1002 D1003 D1004 A1112 A1113 A1114 A1115 A1116 D1005 D1006 D1007 D1008 A1117 A1118 A1119 A1120 D1009 D1010 D1011 A1121 A1122 A1123 D1012 D1013 A1124 A1125 0.74 ppm 0.64 ppm 0.57 ppm 0.64 ppm 0.90 ppm 0.66 ppm 0.24 ppm 0.26 ppm 0.31 ppm 0.43 ppm 0.56 ppm 0.13 ppm 0.51 ppm 0.48 ppm OLI 954 CM TOMA INTEROFFICE COMMUNICATION THK CONTINENTAL. INSURANCE COMANII TO moM D. McNamara A. K. Roy-Chowdhury MJRT Roblntech Page 7 Type Sample Location i AT Industrial Hygienist - Dallas AT Environmental Health Laboratory BATE June 18, 1974 Volume Sampled in liters Field EHL Sample # Sample # Results Above 2 Above 3 #1 station 10 10 D1014 D1015 D1016 A1126 A1127 A1128 1.62 ppm 1.11 ppm 1.10 ppm Should you have any further questions, please advise. A. K. Roy-Chowdhury, Ph.D. Supt. of Industrial Hygiene Laboratories .- R. A. Reennnniicckkfc Director of Industrial Hygiene RQSIWTECH INCORPORATED CORPORATE OFFICES (817) 332-7323 P.O. BOX 2342 FORT WORTH, TEXAS 76101 June 19, 1974 - PLANT SURVEY - All the values below were obtained with a Century OVA, Model 98 B Unit which had incorporated the column for specific vinyl chloride monomer. Additional results based on Sipin Pump - Carbon Tube. Robintech Incorporated Pace, Florida (10 ppm .Total Hydrocarbon) (ba ck ground) Vinyl Chloride I. Rail car of resin A. Inside compartment when freshly opened 490 ppm B. One and one half foot above port opening - no detectable level -0- II. Mixing Room (using Robintech 414-3 Resin) * A. Five feet from Mixer (Port Open) _____ 4 ppm B. Three feet from Mixer Port Opening (top) (downwind) 20,5 ppm C. Three feet from Mixer Port Opening (top) Up Wind) _____ 5.5 ppm III. Extrusion Lines Throughout Plant - No detectable level IV. Powder Blend Transportation Bins Two feet above * No detectable level Two inches above compound _____ 5.0 ppm OLI 956 S ROEiNTECH o INCO*pO**TD CORPORATE OFFICES Page 2 V. Perimeter of Plant (total) No detectable level Robintech Incorporated Anderson, South Carolina --------------------------------------- (85 degrees F. - 57% Relative Humidity) (lOppm Total Hydrocarbon) (background) Vinvl Chloride I. Rail Car Compound A. Inside Car Freshly Opened 190 ppm B. 1-1/2 feet away from Port -0- ppm' II. Blending Room No blending - during transfer from car No detectable level -0- III. Extrusion Line A . Area - No detectable level -0- IV. Outside perimeter of plant No detectable level -0- Robintcch Subsidiary- SOME INDUSTRIES Rolla, Missouri (11 ppm Total Hydrocarbon) ------------------------------------------- (background) I. Rail Car Resin A. Inside Car freshly opened B. One and one-half feet from Port No detectable level C. Above duplicated - same results 740 ppm -0- OLI 957 S ROBINTECH incqrpopatcd CORPORATE OFFICES II. Extrusion Lines A. Area - No detectable level B. Inside Pipe III. Perimeter of Plant No detectable level Robintech Incorporated Grinnell, Iowa (10 ppm Total Hydrocarbon) ------------------------------------ (background) I. Rail Car of Compound A. Inside car Opened (Empty) B. Inside car freshly opened (Full) II. Mixing Area (Transferring to Bins) A. Five feet above bin * III. Extrusion Lines * Area - No detectable level IV. At pipe cutoff Saw V. At the Printer above Pipe No detectable level VI. Grinder Area No detectable level VII. Perimeter of Plant No detectable area Page 3 Vinyl Chloride 0- 3 ppm -0- ppm 40 ppm 16 ppm 3___ ppm -0- ppm 3 ppm 0- -0-0- OLI 958 INCORPORATED corporate OFFICES Robintech Incorporated Hillsboro, Texas (12 ppm Total Hydrocarbon) ------------------------ ----- (background) I. Rail Car Compound A. Inside car freshly opened II. Mixing Room A. No mixing (transferring material) No detectable level III. In area of Silo No detectable level IV. Extrusion Line A. Over extruder Vent B. Area - No detectable level V. Office Area - No detectable level Unitech (within Robintech @ Hillsboro Hillsboro, Texas (12 ppm I. Injection Molding Machine Area No detectable level II. Fittings Storage Warehouse No detectable level III. Pelletized Compound Boxes No detectable level Robintech Incorporated Newman. California (See next page) Page 4 Vinyl Chloride 68 ppm 0- - 20 ppm 0- -_______ 0- - ~0~ __PPm ~0~ ._PPm -0- ppm OLI 959 RQBINTECH inC0R0*aT CD CORPORATE OFFICES Robintech Incorporated Newman, California (11 ppm Total Hydrocarbon) (background) I. Inside Rail Car Port Opening II. Truck Unloading Area (Including along Conveying Lines) III. Silo Area during Filling & Unloading IV. Compressor Room V. Employee Lunchroom VI. Tool Room VII. Compound Storage & Transportation Bins (Two inches from Compound) VIII. Quality Control Lab & Control Room IX. Mixing Area (Next to Mixer) (During transfer of material) X. Ceiling of Mixing Room (Approximately 10 inches from ceiling) XI. Perimeter of Plant Area Robintech Incorporated Elsinore, California (18 ppm Total Hydrocarbon) (background) I. Rail Car Inside car freshly opened port II. Purging Extruder III. Extruder Area (BT-100 Dual) (One inch from Extrudate) IV. Quality Control Laboratory Page 5 Vinyl Chloride 85 ppm -0- ppm -0- ppm * -0- ppm -0- ppm -0- ppm -0- ppm -0- ppm -0- ppm -0- ppm -0- ppm 110 ppm -0- ppm 2 ppm -0- ppm OLI 960 S RDEINTECH ico**oArf:o CORPORATE OFFICES Continued - Elsinore V. Plant Perimeter Robintech Incorporated Vestal, New York (18 ppm Total Hydrocarbon) (background) I. Main Office Building II. Rail Car A. Inside 3/4 Empty Compartment B. Inside Empty Compartment III. Warehouse Area IV. Grinding Machine Area V . Extrusion Line Area (downstream) VI. Process Water (cooling) Drain Line in Field VII. Perimeter of Plant Area Robintech Incorporated Springfield, Kentucky (12 ppm Total Hydrocarbon) Page 6 Vinyl Chloride ppm -0- ppm 10 ppm 4 ppm -0- ppm -0- ppm -0- _Pprn 2 ppm -0- ppm Hydrogen not pure, therefore, no reliable VCM readings obtained. Only total hydrocarbon readings were obtained and were in line with other plants. N OLI 961