Document mpNmKRmrGe1YQbNboKzz7VN2Z
INTRODUCTION
Thio database summarizes the results of Reactive Chemicals compatibility testing of various leak repair sealants with UVD process chemicals. In addition to leak repair sealants, the compatibility of valve packings, gaskets, thread sealants, O-rings, coatings, and adhesives with proc ss chemicals are also included. This database was updated in July, 1994 and documented in CRI report, LAD-AR 94.11.
According to LAD Safety & Loss Prevention Standard S-317, leak repair sealants may be used to temporarily stop leaks on operating lines or equipment. The leak repair is not a substitute for routine preventative maintenance and scheduled equipment repair. The line or equipment must be permanently repaired within 6 months, or with manager's approval, no later than the next scheduled shutdown. If the leak was caused by internal corrosion, or erosion, permanent repair must be made within 3 months.
The standard also states that "the leak-stop compound must be compatible with the operating line or equipment contents by Dow Reactive Chemicals testing." Reactive Chemicals testing of the compatibility of leak repair Bealant and process chemicals is necessary to prevent a reaction that could cause a fire, explosion, and/or spill resulting in injury and/or property loss. Not only could the reaction between the sealant and the process chemical be a problem, but the heat of this reaction could initiate another reaction of the process chemical itself, or a reaction between the process chemical and the line or equipment material of construction.
Before a sealant is used on a process line or piece of equipment, the user must be sure that the sealant and process chemical are compatible. Below is a discussion of the interpretation of the test results. If there is any doubt if a sealant is compatible with a process chemical based on the test results, the Reactive Chemicals group should be consulted (phone Gerald Wagener at 1828 or Joe Schell at 1639). Also, if a sealant and process chemical are not on the list, the Reactive Chemicals group must be contacted for testing.
Vendors sometimes give assurances that their sealants are compatible with certain process chemicals based on prior field usage, experience, consultation, chemical theory, or testing by their company, it is important to remember that these assurances are not adequate and that LAD Safety & Loss Prevention Standard S-317 requires Dow reactive chemical testing of the sealant with the line or equipment contents. Therefore, vendor literature is not accepted as proper documentation.
Reactivity testing only addresses chemical compatibility and in no way does it address or imply anything about a sealant's performance. It should not be assumed that because the reactivity of a sealant has been tested that it will adequately perform as a sealant in the process.
This database will be updated periodically as new tests are run. These include re-checks, new sealants, and sealants used with new process chemicals. Therefore, if a sealant is not in the table, the Reactive
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Chemicals group should be contacted to see if it was run since the laBt update.
EXPERIMENTAL
The reactivities of the sealants with process chemicals summarized in the database were tested using Differential Thermal Analysis (DTA), Differential Scanning Calorimetry (DSC), Heat of Mixing Calorimetry (HOM), and Accelerating Rate Calorimetry (ARC).
Differential Thermal Analysis (DTA)
DTA was used prior to 1987 to detect exothermic or endothermic reactions and the reaction onset temperatures as the temperature of the sample was increased at a set rate . DTA measures the difference in temperature between the sample and reference, and not the heat flow; therefore, an accurate determination of the heat of reaction cannot be made.
Differential Scanning Calorimetry (DSC)
DSC is currently used as a screening tool to determine the exothermic or endothermic heat of reaction at elevated temperatures and the reaction onset temperature. The DSC method is similar to the DTA method except that the sample and reference material are maintained at the exact sam temperature as the temperature is increased at a set rate. If the sealant and process chemical sample exothermically react at a certain temperature, the sample heater requires less energy input than the reference heater to maintain the same temperature. This energy input difference is precisely equivalent to the exothermic heat evolved and is a direct calorimetric measure of the heat of reaction. Thus DSC is considered to be more quantitative than DTA.
2-Drop Heat of Mixing Calorimetry (HOM)
The LAD Reactive Chemicals lab uses a 2-Drop Heat of Mixing Calorimeter to measure heat of mixing at ambient temperature. A 50 microliter sample of liquid process chemical is injected by syringe into a 2 milliliter vial containing approximately 50 milligrams of a sealant sample. If the process chemical is a gas, a 10 milliliter sample is purged through the vial containing the sealant sample. The heat of mixing of the samples is calculated by dividing the sample peak area by the peak area of a one calorie standard.
Accelerating Rate Calorimetry (ARC)
If more accurate and detailed thermal data are deemed necessary after the DSC and heat of mixing tests, then an ARC test is performed. Larger samples of the sealant and process chemical are loaded into an ARC sphere and a wait-search-heat sequence with a heat step usually of 10 degrees C is repeated from ambient temperature to the desired end temperature. If the self heat rate of an exothermic reaction between the sealant and the process chemical exceeds 0.02 degrees C per minute, the reaction is allowed to proceed on its own under near-adiabatic conditions. This method gives an accurate measure of the heat of
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reaction aft r corrections are mad for the thermal inertia of the sample container, and also a fairly conservative estimate of the conditions for a runaway reaction. The ARC onset-of-reaction temperature is more accurate than the DSC onset temperature. Also, pressure data is collected during the ARC run. INTERPRETATION OP TEST RESULTS The table includes the process chemical, sealant, plant, reference number (corresponding to the Reactive Chemicals test number), test (DTA, DSC, HOM, or ARC), and reactivity and onset temperature. If no thermal reactivity was observed between the sealant and the process chemical, and the test was run, for example, to 200 degrees C, the remark under the Reactivity heading would read "No exo to 200 C." If an exothermic reaction was observed with an onset temperature of 100 degrees C, the remark would read "Exo at 100 C." If HOM and DSC or ARC test results indicate no reactivity between a sealant and a process chemical at ambient and elevated temperatures, then they can be considered compatible. If only DTA, DSC, or ARC tests were run and indicated no reactivity at elevated temperatures, then a HOM test should be performed to check for reactivity at ambient temperature before a sealant and process chemical are considered compatible. If HOM and/or DSC or ARC test results indicate an exothermic reaction between a sealant and a process chemical, then the Reactive Chemicals group should be consulted to help interpret the results to decide if the sealant should or should not be used.
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PROCESS CHEMICAL
ACETYLENE ACID GAS BLEND ACID GAS BLEND ACID GAS BLEND AIR AIR AIR AIR AIR AIR AIR AIR INSTRUMENT) AIR INSTRUMENT) AMMONIA (5% N WATER) AMMONIA (5% N WATER) AMMONIA |16%) - D-270 AMMONIA 116%) - 0-270 AMMONIA (16%) - D-270 AMMONIA (16%) - D-270 AMMONIA (16%) - D-270 AMMONIA (15%) D-270 AMMONIA (20% N H20) AMMONIA (AQUEOUS) AMMONIUM HYDROXIDE ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA AT-200 SCRUBBER EFFLUENT AT-200 SCRUBBER EFFLUENT BENZENE (CRUDE) BENZENE (CRUDE) BENZENE PLANT PYROLYSIS GAS BENZENE-TOLUENE-XYLENE IT-1602) BENZENE-TOLUENE-XYLENE (T-1602) BENZENE-TOLUENE-XYLENE fT-16021 BETA-TRICHLOROETHANE BETA-TRICHLORGETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE
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TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICALI
SEALANT
PLANT
REF. NO.
TEST
TEAM LEAK REPAIRS VALVEPACK B STEAM & PROCESS SP-1011 STEAM & PROCESS SP-60 STEAM & PROCESS SP-CM SP-1011 (30 MM CURE 1 ST RUNI SP-1011 (30 MIN CURE 2ND RUN) SP-1011 (30 MIN CURE 3RD RUN) SP-1011 (UNCURED SAMPLE) SP-102 ICUREO @300 C / 48 HOURS) TEAM LEAK REPAIRS SEALANT 2W TEAM LEAK REPAIRS SEALANT 2X STEAM B PROCESS SP-102 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS VALVEPACK VP-AX TEAM LEAK REPAIRS VALVEPACK VP-AX CORTEC VC1-309 COHTEC VCI-309 CORTEC VCI-368 CORTEC VCI-368 STEAM 6 PROCESS SP-60 STEAM a PROCESS SP-102 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS PTFE SEALANT TEAM LEAK REPAIRS SEALANT IX DOW CORNING 44 LUBRICANT FEL-PRO HI-TEMP NICKEL EASE STEAM a PROCESS SP-1016 TEAM LEAK REPAIRS PTFE SEALANT TEAM LEAK REPAIRS SEALANT #16 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS VALVEPACK B STEAM a PROCESS SP-2000 STEAM a PROCESS SP-CM STEAM a PROCESS SP-1011 STEAM a PROCESS SP-103 TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-68 FURMANITE FSC-0B TEAM LEAK REPAIRS SEALANT #6 a F-14 FIBERS FURMANITE FSC-44D FURMANITE FSC-44D FURMANITE FSC-68 FURMANITE FSC-6B STEAM a PROCESS SP-289 STEAM a PROCESS SP-2B9 STEAM a PROCESS SP-3100 STEAM a PROCESS SP-3100 TEAM LEAK REPAIRS SEALANT #2X
LHC 2 LGTI LGTI LGTI CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 POWER 2 POWER 2 POWER 2 LGTI LGTI DOWANOLS DOWANOLS LGTI LGTI LGTI LGTI LGTI LGTI LGTI DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS CAUSTIC CAUSTIC CAUSTIC CHLORINE CHLORINE BENZENE BENZENE BENZENE LHC 3 LHC 3 LHC 3 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2
RCL-86-2233 DTA
RCL-88-0305 DSC
RCL-B8 0306 DSC
RCL-88 0308 DSC
RCL-88-0612 DSC
RCL-88-0613 DSC
RCL-88-0614 DSC
RCL-88-0611 DSC
RCL-BS-0762 DSC
RCL-92-320X DSC
RCL-92-320X DSC
RCL-88-0309 DSC
RCL-88-0307 DSC
RCL-95-0441 DSC
RCL-9S-0441 HOM
RCL-95-1373 DSC
RCL-95-1373 HOM
RCL-95-6371 DSC
RCL-96-6371 HOM
RCL-87-146X DSC
RCL-87-146X DSC
RCL-89-336X DSC
RCL 1039
DTA
RCL-91-239X DSC
RCL-93-121X DSC
RCL-93-121X DSC
RCL 1232
DTA
RCL1038
DTA
RCL 1010
DTA
RCL 1007
DTA
RCL 1181
DTA
DCL-91-296X DSC
RCL-91-296X DSC
RCL-84-O031 DTA
RCL-84-003X DTA
RCL-B6-053X DTA
RCL-92-199X DSC
RCL-92-199X DSC
RCL-92-199X DSC
RCL-93-6002 DSC
RCL-93-6002 HOM
RCL-93-6003 DSC
RCL-93-6003 HOM
RCL-93-6004 DSC
RCL-93-6004 HOM
RCL-93-6006 DSC
RCL-93-6005 HOM
RCL-93-6006 DSC
Dow ConfktantW
REACTIVITY
NO EXO TO 210 C EXO AT 45 C NO EXO TO 300 C EXO AT 60 C EXO AT 160 C EXO AT 60 C EXO AT 273 C EXO AT 178 C EXO AT 420 C NO EXO TO 600 C NO EXO TO 600 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 235 C NO EXO TO 300 C NO EXO TO 176 C NO EXO TO 130 C NO EXO TO 155 C NO EXO TO 250 C NO EXO TO 320 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C EXO AT 40 C NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C EXO AT 269 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 360 C NO EXO AT 22 C EXO AT 263 C NO EXO AT 22 C NO EXO TO 350 C
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TABLE t. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE
BETZ 1125L BETZ1125L BETZ 1125L BETZ 112SL BETZ BALANCED POLYMER 6403 BETZ BALANCED POLYMER 6403 BETZ BALANCED POLYMER 6403 BETZ BALANCED POLYMER 6403 BETZ BALANCED POLYMER 6403 BETZ BALANCED POLYMER 6403 BETZ BALANCED POLYMER 68701 BETZ BALANCED POLYMER 68701 BETZ BP-P-1B 150%) + COfl-TROt 77BP (50*1 BETZ BP-P-1B 160*1 4 COR-TROL 778P (60*) BETZ COR-TROL 778-P BETZ COR-TROL 778-P BETZ COR-TROL 778-P BETZ COR-TROL 778-P BETZ COR-TROL 778-P BETZ COR-TROL 778-P BETZ INHIBITOR 38K BETZ INHIBITOR 38K BOILER WATER WITH COR-TROL, EDTA. PIB BOILER WATER WITH COR-TROL, EDTA, Pffl BRINE BRINE BRINE BRINE BRINE WTO AT-280 BRWE OUT AT-200 1.3-BUTADIENE 1.3-BUTADIENE C-2 RECYCLE GAS C-2 RECYCLE GAS C-450 FEED TO C6S 4 LTTES C-450 FEED TO CSS 4 UTES C-6O0 FEED PYGAS 4 LUES C-SOO FEED PYGAS 4 LUES CALCIUM STEARATE CARBON STEEL 4 CONCRETE 4 WATER CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE
TEAM LEAK REPAIRS SEALANT 42X TEAM LEAK REPAIRS SEALANT 16 TEAM LEAK REPAIRS SEALANT 46 TEAM LEAK REPAIRS VALVEPACK A CORTEC VCI-309 CORTEC VCI-309 CORTEC VCI-388 CORTEC VCI-368 CHESTERTON ARC 988 PART A SEALANT CHESTERTON ARC 988 PART A SEALANT CHESTERTON ARC 982 PART A SEALANT CHESTERTON ARC 982 PART A SEALANT CHESTERTON ARC 791 PART A SEALANT CHESTERTON ARC 791 PART A SEALANT FURMANITE FSC-6B FURMANUE FSC-08 TEAM LEAK REPAIRS SEALANT 46 & F-14 FIBERS TEAM LEAK REPAIRS SEALANT 46 8 F-14 FIBERS CHESTERTON ARC 988 PART A SEALANT CHESTERTON ARC 988 PART A SEALANT CHESTERTON ARC 982 PART A SEALANT CHESTERTON ARC 982 PART A SEALANT CHESTERTON ARC 791 PART A SEALANT CHESTERTON ARC 791 PART A SEALANT CMS 2000 PUMP SEALANT CMS 2000 PUMP SEALANT TEAM LEAK REPAIRS SEALANT OB-22 & F-10 FIBERS TEAM LEAK REPAIRS SEALANT OB-22 & F-10 FIBERS TEAM LEAK REPAIRS SEALANT 46 TEAM LEAK REPAIRS SEALANT 46 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX PROTECTO-COAT BOO G PROTECTO-COAT 800 G TEAM LEAK REPAIRS VALVEPACK B TEW LEAK REPAIRS VALVEPACK B-EC TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT X-36 TEAM LEAK REPAIRS SEALANT 46 TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 46 TEAM LEAK REPAIRS SEALANT 2X STEAM PROCESS SP-3100 STEAM * PROCESS SP-520 FURMANUE FSC-44D FURMANUE FSC-44D FURMANUE FSC-6B FURMANUE FSC-68
Dow Confidential
VINYL 2 VINYL 2 VINYL 2 VINYL 1 LGTI LGTt LGTI LGTI LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 3 LHC 3 POWER 1 POWER 1 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 GLYCOL 2 GLYCOL 2 POWER 1 POWER 1 BRWE BRINE BRINE BRINE CHLORINE CHLORINE LHC 2 VECTOR GLYCOL 2 GLYCOL 2 LHC 3 LHC 3 LHC 3 LHC 3 POLY C POWER 2 VINYL 2 VINYL 2 VWYL2 VWYL2
RCL-93-5006 RCL-93-6007 RCL-93-5007 RCL-84-189X RCL-95-1374 RCL-95-1374 RCL-95-6372 RCL-95-6372 RCL-95-0831 RCL-95-0831 RCL-95-0832 RCL-95-0832 RCL-95-0833 RCL-95-OB33 RCL-94-0921 RCL-94-0922 RCL-92-176X RCL-92-176X RCL-9S-0834 RCL-9S-OS34 RCL-96-0836 RCL-95-0835 RCL-95-0836 RCL-95-0836 RCL-96-1362 RCL-96-1362 RCL-92-183X RCL-9 2-1B3X RCL-96-0791 RCL-96-0791 RCL-94-0621 RCL-84-0621 RCL-88-169X RCL-88-169X RCL-88-2234 RCL-93-0621 RCL-91-117X RCL-91-116X RCL-90-3861 RCL-90-38S3 RCL-90-3862 RCL-90-3864 RCL-93-194X RCL-92-3271 RCL-93-5008 RCL-93-600B RCL-93-6009 RCL-93-6009
HOM DSC HOM OTA DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM HOM DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM HOM DSC DSC DSC DTA DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC HOM
REACTIVITY
NO EXO AT 22 C EXO AT 284 C NO EXO AT 22 C EXO AT 276 C NO EXO TO 200 C St. EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 260 C NO EXO AT 22 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 335 C NO EXO AT 22 C NO EXO TO 260 C SL. EXO AT 22 C NO EXO TO 260 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO AT 22 C NO EXO TO 226 C EXO AT 165 C EXO AT 68 C NO EXO TO 210 C EXO AT 105 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 180 C EXO AT 225 C NO EXO AT 22 C EXO AT 223 C NO EXO AT 22 C
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TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL {SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE (CRUDE. 93%) CARBON TETRACHLORIDE (CRUDE, 93%) CARBON TETRACHLORIDE (CRUDE, 03%) CARBON TETRACHLORIDE (CRUDE. 93%) CAUSTIC (25%) CELL EFFLUENT <10% SODIUM HYDROXIDE) CELL EFFLUENT (10% SODIUM HYDROXIDE) CELL EFFLUENT (10% SODIUM HYDROXIDE) CELL EFFLUENT (10% SODIUM HYDROXIDE) CELL EFFLUENT 110% SODIUM HYOROXIDE) CELL EFFLUENT (10% SODIUM HYOROXIDE) CELL EFFLUENT (10% SODIUM HYOROXIDE) CELL EFFLUENT (10% SODIUM HYOROXIDE) CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORHE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORHE CHLORHE CHLORINE CHLORINE CHLORINE
SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK IUCAR CARBON CO GRAFOILI SAFE SEAL GRAFPAK IUCAR CARBON CO GRAFOILI SAFE SEAL MULTIPAK (JOHN CRANE SKBI SAFE SEAL MULTIPAK IJOHN CRANE 6KBI STEAM ft PROCESS SP-326 STEAM a PROCESS SP-325 STEAM a PROCESS SP-CM STEAM a PROCESS SP-CM TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT *11 TEAM LEAK REPAIRS SEALANT #0 TEAM LEAK REPAIRS SEALANT *0 CHESTERTON 810 STEEL PUTTY (CURED) CHESTERTON 810 STEEL PUTTY (CURED) CHESTERTON 96B STEEL PUTTY (CURED) CHESTERTON 850 STEEL PUTTY (CURED) TEAM LEAK REPAIRS PRF102C (THREADS) TEAM LEAK REPAIRS SEALANT 1BX TEAM LEAK REPAIRS SEALANT 1BX TEAM LEAK REPAIRS F-14 FIBER STEAM a PROCESS SP-1011 STEAM a PROCESS SP-2000 STEAM a PROCESS SP-00 THORTEX METAL TECH E.G. BASE THORTEX METAL TECH E.G. BASE ANCHOR VALVE PACKING 375 ANCHOR VALVE PACKING 4205 BELZONA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL CELL PUTTY CHRYSOTK.E ASBESTOS FIBER GSKT CONLEY TEFLON PASTE FELPOXY STEEL GARLOCK VALVE PACKING 0130 GARLOCK VALVE PACKING 7130 GORE PACKHG PTFE W/ GRAPHITE GORTEX PTFE GORTEX SEALANT (TEFLON) JOHN CRANE VALVE PKG C-1050 JOHN CRANE VALVE PKG C-00 JOHN CRANE VALVE PKG C-7702 JOHN MANSVLLE VALVE PKG AF-5331 LOCTITE #50747 PST LOCTITE #69231 (WITH TEFLON) LOCTITE 271 ADHESIVE/SEALANT
METHANES METHANES METHANES METHANES METHANES METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 SOLVENTS/EDC SOLVENTS/EDC SOLV ENTS/EDC SOLVENTS/EDC CAUSTIC CHLOR-ALKALI 2 CHLOR-ALKALI 2 VINYL 2 CHLORINE CHLORINE CHLORINE LHC 2 LHC 2 CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLOR-ALKALI 2 CHLORINE CHLORINE CHLORHE CHLORHE CHLORHE CHLORHE SOLVENTS/EDC CHLORHE CHLORHE CHLORHE CHLORHE CHLORHE CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2
RCL-94-0009 HOM RCL-94-0009 DSC RCL-94-5005 HOM RCL-94-5005 DSC RCL-94-0005 HOM RCL-04-0605 DSC RCL-93-5010 DSC RCL-93-5010 HOM RCL-93-5011 DSC RCL-93-6011 HOM RCL-93-5012 DSC RCL-93-5012 HOM RCL-93-5013 DSC RCL-93-5013 HOM RCL-92-2981 DSC RCL-92-2991 HOM RCL-92-29B2 DSC RCL-92-29B2 HOM RCL-91-098X DSC RCL-90-0361 DSC RCL-96-0351 HOM RCL-93-129X DSC RCL-92-180X DSC RCL-92-180X DSC RCL-92-180X DSC RCL-95-1021 DSC RCL-95-1021 HOM RCL-84-138X DSC RCL-84-006X DTA RCL-85-1742 DTA RCL-84-1B4X DTA RCL-85-1721 DTA ARC 91-047X ARC RCL-90-022X DSC RCL-83-0004 DTA RCL-84-183X DTA RCL-84-007X DTA RCL-84-008X DTA RCL-B6-2O0X DTA RCL-85-1301 DTA ARC 91-010 ARC RCL-B4-141X DSC RCL-84-140X DSC RCL-84-O003A DTA RCL-84-144X DTA RCL-90-282X DSC RCL-90-2821 ARC RCL-89-071X DSC
Dow Confidential
REACTIVITY
NO EXO AT 22 C EXO AT 297 C NO EXO AT 22 C EXO AT 325 C NO EXO AT 22 C EXO AT 185 C EXO AT 262 C NO EXO AT 22 C EXO AT 247 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 150 C NO EXO AT 22 C NO EXO TO 150 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C SL EXO AT 180 C SL EXO AT 170 C SL EXO AT 194 C NO EXO TO 200 C SL. EXO AT 22 C EXO < 30 C EXO AT 136 C EXO AT 35 C EXO < 25 C EXO AT 30 C EXO AT B0 C NO EXO TO 250 C EXO AT 100 C EXO < 25 C EXO AT-83 C EXO AT-70 C NO EXO TO 200 C NO EXO TO 260 C NO EXO TO 200 C EXO AT 36 C EXO AT 46 C EXO AT 102 C EXO < 30 C EXO AT 115 C EXO AT 33 C EXO AT -5 C
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PROCESS CHEMICAL
CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE (LIQUIDI CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUIDI CHLORINE (LIQUIDI CHLORINE (LIQUIDI CHLORINE (UOUIDI CHLORINE (UOUIDI CHLORME (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUIDI CHLORINE (LIQUID) CHLORINE ILKHJID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUIDI CHLORINE (LIQUIDI CHLORINE (TRACE WATER, HCBDI CHLORINE VENT GAS CHLORINE VENT GAS CHLORINE VENT GAS CHLORINE VENT GAS CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CITRIKLEEN DEGREASER CITRIKLEEN DEGREASER COAL (LOC 33A| COAL (LOC 33AJ :OAL CHAR SLURRY (LOC 3SC)
:OAL CHAR SLURRY (LOC 3SC)
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TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL!
SEALANT
PLANT
REF. NO.
TEST
PARKER HANNIFIN VALVE PKG 2287-Bfl PARKER HANNIFIN VALVE PKG 2287-GL PTFE/KEVLAR SEAL-ITT #34 SENTRY POLYMERS SEMLASTIC 5100 SEALANT SILASTIC 732-RTV SILICONE RUBBER STEAM & PROCESS SP-1011 TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT #0 + F-14 FIBER UNCURED EPDM RUBBER CASTROL BRAYCOTE1728 COPALTfTE HIGH TEMPERATURE SEALANT DOW CORNING 3120 RTV SEALANT GARLOCK 900 GASKET GOR-TEX GR GASKET GRAFOIL GHE KADa SN N-75 SEALANT KLINGER K-01 GASKET PERMATEX FORM-A-GASKET 2 ICURED) SAFE SEAL - CHEMOLA TERON STEAM ft PROCESS SP-2020 STEAM & PROCESS SP-292 STEAM a PROCESS SP-300D STEAM a PROCESS SP-376 STEAM a PROCESS SP-CM STEAM a PROCESS SP-TFLO TEAM LEAK REPAIRS VALVEPACK OX (TERON) TORLON SN T210 SEALANT USADURIAN SBR RUBBER CPE-TAC DERAKANE 470 (CUREO 6/14/881 IPI EPOXY (CURED) RED PRIMER ICURED) WHITE DURDICK 800 G SAFE SEAL - CHEMOLA TERON SAFE SEAL - CHEMOLA TERON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIU SAFE SEAL MULTPAK (JOHN CRANE 0KB) SAFE SEAL MULTPAK (JOHN CRANE 6KB) STEAM a PROCESS SP-CM TEAM LEAK REPAIRS SEALANT DB-2 C5A FR PRO NO. 725 NICKR ANTISEIZE STEAM 0 PROCESS SP-102 STEAM a PROCESS SP-00 CORTEC VC1-309 CORTEC VCI-308
Daw Confidential
CHLORINE CHLORINE CHLOR-ALKAU 2 CHLORINE CHLORINE CHLOR-ALKAU 2 CHLOR-ALKALI 2 VINYL 1 VINYL 1 CHLOR-ALKALI 2 CHLORINE CHLORINE CHORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE METHANES CHLORINE CHLOR-ALKALI 2 CHLORINE CHLORINE CHLORINE CHLORINE CHLOR-ALKALI 2 CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES POWER 1 POWER 1 LGTI LGTI LGTI LGTI
RCL-84-142X RCL-84-143X RCL-B9-322X RCL-90-2771 RCL-90-0211 RCL-84-100X RCL-89-322X RCL-83-093X RCL-83-095X ARC 91-649 ARC 91-586 RCL-94-9851 RCL-94-9848 RCL-92-9737 RCL-93-9771 ARC 91-596 RCL-93-9809 RCL-92-9738 RCL-94-9855 RCL-94-9882 ARC 92-092 RCL-93-9831 ARC 92-711 RCL-93-9830 ARC 92-70B ARC 92-715 RCL-92-9764 RCL-93-9799 RCL-94-9853 RCL-B4-211X RCL-88-172X RCL-88-172X RCL-88-188X RCL-88-109X RCL-94-0009 RCL-94-0609 RCL-94-6004 RCL-94-5004 RCL-94-0604 RCL-94-0604 RCL-85-1334 RCL-82-0039 RCL-89-050X RCL-89-050X RCL-87-145X RCL-87-146X RCL-95-1377 RCL-95-6374
DSC DSC DSC DSC HOM OTA DSC DTA DTA ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC ARC DTA DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC DTA DTA DSC DSC DSC DSC DSC DSC
REACTIVITY
EXO < 30 C EXO AT 38 C EXO AT 48 C EXO AT 90 C EXO AT 22 C EXO AT 100 C EXO AT 40 C EXO AT 90 C EXO AT 130 C EXO AT 98 C EXOAT 107 C EXOAT 113 C EXO AT 36 C EXO AT 26 C NO EXO TO 175 C EXO AT 104 C EXOAT 182 C EXO AT 27 C EXO AT 22 C EXO AT 9 C EXO AT 20 C NO EXO TO 250 C EXO AT 20 C NO EXO TO 260 C EXO AT 20 C NO EXO TO 175 C NO EXO TO 250 C EXO AT 109 C EXO AT 59 C EXO AT 135 C EXO AT 30 C NO EXO TO 250 C EXO AT 40 C EXO AT 35 C NO EXO AT 22 C EXO AT 310 C NO EXO AT 22 C EXO AT 200 C NO EXO AT 22 C EXO AT 224 C NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 300 C EXO AT 78 C NO EXO TO 235 C NO EXO TO 235 C NO EXO TO 200 C NO EXO TO 200 C
10
DO 0 7 2 4 4 3
PROCESS CHEMICAL
COAL CHAR SLURRY ILOC 35CI COAL CHAR SLURRY ILOC 35CI CP-1000 OIL SATURATED WITH HCL CRACKED GAS CRACKED GAS CRACKED GAS CRACKED GAS CRACKEO GAS CRACKED GAS CRACKED GAS CRACKED GAS CRACKED GAS (2C-S0) CRACKEO GAS I2C-S0) CRACKED GAS I2C-50J CRACKED GAS I2C-50BI CRACKED GAS |H2,C1.C2.C3.C4,H*GHERS| D-102 QUENCH LIQUOR D-1220 BOILER BLOWDOWN D-13 HEXES D-13 HEXES D-270 LIQUIO DIETHANOLAMME DIETHANOLAMW E DIETHANOLAMME DIETHANOLAMINE DIETHANOLAMME DIETHANOLAMME DIMETHYL ETHER DIMETHYL SULFIDE DITCHWATER (LHC 2 ft LGTI) DITCHWATER (LHC2 ft LGTI) DNDA CATALYST (BATCH 886) DNDA CATALYST (BATCH 886) DOWANOL DB DOWANOL DF 250 DOWANOL DF 250 DOWANOL DPM DOWANOL OPM DOWANOL EB OOWANOL EB DOWANOL EB DOWANOL EB g 0 DOWANOL EB 2 O OOWANOL EB DOWANOL EB y DOWANOL EB 'll y DOWANOL EB SERIES (EB.OB.TBH)
2 i* DOWANOL PM
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
SEALANT
PLANT
REF. NO.
TEST
STEAM ft PROCESS SP-102 STEAM ft PROCESS SP-60 TEAM LEAK REPAIRS SEALANT #6 FURMANITE FSC-500 SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) SAFE SEAL MULTPAK (JOHN CRANE 6KB) TEAM LEAK REPAIRS SEALANT OB-22 TEAM LEAK REPAIRS VALVEPACK BEC TEAM LEAK REPAIRS VALVEPACK VP-GX TEAM LEAK REPAIRS VALVEPACK VP-EPX FURMANITE FSC-46D (TEFLON 3001 STEAM ft PROCESS SP-102 STEAM ft PROCESS SP-CM CHESTERTON 858 PUTTY - PARTS A ft B TEAM LEAK REPAIRS SEALANT #6 FURMANITE FSC-6B TEAM LEAK REPAIRS SEALANT *18 FURMANITE FSC-5C FURMANITE FSC-6B TEAM LEAK REPAIRS F14 FIBERS FURMANITE FSC-500 FURMANITE FSC-500 TEAM VALVEPACK VP-GX TEAM VALVEPACK VP-GX TEAM VALVEPACK VP-EPX TEAM VALVEPACK VP-EPX TEAM LEAK REPAIRS SEALANT DB-2 FURMANITE FSC-6B CURED AVANTI AV-202 MULTIGROUT CURED AVANTI AV-220 MULTIGROUT SEMSTONE 145-S SEMSTONE 246 TEAM LEAK REPAIRS VALVEPACK E TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT *6 EPR EO 962 "O'-RNG EPR RED DOT "O'-RING STEAM ft PROCESS SP-1011 STEAM ft PROCESS SP-102 STEAM ft PROCESS SP-3100 STEAM ft PROCESS SP-60 STEAM ft PROCESS SP-CM VITON YELLOW DOT 'O'-RMG STEAM ft PROCESS SP-IOIB EPR EO 862 "O'-RING
LGTI LGTI METHANES LHC 2 LHC 2 LHC 2 LHC 2 LHC 3 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 VINYL 2 LHC 3 SOLVENTS/EDC SOLVENTS/EDC GLYCOL 1 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 METHANES LHC 2 LHC 3 LHC 3 POLY B POLY B DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS OOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS
RCL-87-145X RCL-87-145X 92288 RCL-95-1473 94033 94033 94033 90243 90236 RCL-96-0563 RCL-98-0554 93135 92065 92065 92104 RCL 736 89208 89151 92196 92196 91169 RCL-96-1472 RCL-95-1472 RCL-96-0561 RCL-96-0561 RCL-96-0562 RCL-96-0552 RCL 82-043 91221 871171 871172 90146 90146 RCL 1491 92016 92016 62016 92016 92339 92339 93014 93014 93014 93014 93014 92339 84E104 92339
DSC DSC DSC HOM DSC DSC DSC DSC DSC HOM HOM DSC DSC DSC DSC DTA DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC HOM DTA DSC DSC DSC DSC DSC
DTA HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DSC
Dow Confidential
REACTIVITY
EXO AT 165 C NO EXO TO 235 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 250 C NO EXO AT 22 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 400 C EXO AT 338 C NO EXO TO 150 C NO EXO TO 400 C NO EXO TO 200 C NO EXO TO 250 C EXO AT 344 C EXO AT 270 C NO EXO TO 250 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 180 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 260 C EXO AT 223 C NO EXO TO 350 C NO EXO AT 25 C NO EXO TO 200 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 210 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C
11
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL!
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
DOWANOL PM
DOWANOL PM .
DOWANOL PM
DOWANOL PM
DOWANOL PM
DOWANOL PM
DOWANOL PM
DOWANOL PM
DOWANOL PM
DOWANOL PM SERIES (PM.DPM.TPM)
DOWANOL PM, DPM, TPM. KOH MIX IOV-114!
DOWANOL TBH AND HIGHERS (T-1301
DOWANOL TPM
DOWANOL TPM
DOWANOL TPM ft HIGHERS
OOWTHERM A
OOWTHERM A
OOWTHERM A
OOWTHERM A
DOWTHERM A
DOWTHERM A
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
OOWTHERM G
DOWTHERM G
OOWTHERM G
DOWTHERM G
DOWTHERM G OOWTHERM G OOWTHERM G OOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G
n oo
.-->
no O"Tl iN\ J1 2^ H `H -k
TXvr
OOWTHERM G
DOWTHERM G
OOWTHERM G
ETHANE
ETHANE
ETHANE/ETHYLENE <20-52 OVERHEAD GAS)
ETHANOLAMWES IMEA.DEA.TEA1
ETHANOLAMINES (MEA.DEA.TEA)
EPR RED DOT *0*-RWG STEAM A PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-3100 STEAM & PROCESS SP-80 STEAM & PROCESS SP-CM TEAM LEAK REPAIRS SEALANT #8 TEAM LEAK REPAIRS SEALANT #0 VITON YELLOW DOT 'O'-RING STEAM & PROCESS SP-2000 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #8 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 5G TEAM LEAK REPAIRS SEALANT X-36 TEAM LEAK REPAIRS VALVEPACK AX FURMANfTE FSC-5C FURMAN[TE FSC-EC FURMANITE FSC-6B FURMANfTE FSC-8B STEAM A PROCESS SP-1011 STEAM A PROCESS SP-1011 STEAM A PROCESS SP-102 STEAM A PROCESS SP-102 STEAM A PROCESS SP-109 TEAM LEAK REPAIRS 16X A FURMANITE FSC-6B TEAM LEAK REPAIRS SEALANT 418X TEAM LEAK REPAIRS SEALANT #16X TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT 16X
TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK 8-EC TEAM LEAK REPAIRS VALVEPACK ER TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS SEALANT *8 TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS SEALANT #6 STEAM ft PROCESS SP-1012 STEAM ft PROCESS SP-2007
Dow Confidential
DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS POLY C POLY C POLY C POLY C POLY C POLY C VINYL 2 VWYL 2 VINYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VINYL 2 . METHANES VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VINYL 2 VINYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 VWYL 2 PROMIX LHC 2 LHC 2 DOWANOLS DOWANOLS
92339 93014 93014 93014 93014 93014 92018 92018 92339 84E105 92251 92251 92018 92018 92251 B7033B 93080 93080 87033A 87033C B7083A B9188 93164 92100 93154 93154 93164 93164 93154 RCL 1468 92100 92100 93164 93164 93164 92100 92100 92100 93154 92100 82100 92100 83154 94071 B8223G RCL 1016 84E108 B4E107
TEST
DSC DSC DSC DSC DSC DSC HOM DSC DSC DTA DSC DSC HOM DSC DSC DTA DSC HOM DTA DTA DSC DSC HOM DSC HOM DSC HOM DSC HOM DTA DSC DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC DSC HOM DSC DTA DTA OTA DTA
REACTIVITY
NO EXO TO 250 C EXO AT 275 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 300 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 400 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 290 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 360 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 260 C
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
ETHANOLAMINES (MEA.DEA.TEA)
ETHYL CHLORIDE
ETHYL CHLORIDE
ETHYL CHLORIDE
ETHYLENE
ETHYLENE
ETHYLENE
ETHYLENE
ETHYLENE
ETHYLENE
ETHYLENE
ETHYLENE
ETHYLENE
ETHYLENE
ETHYLENE
ETHYLENE DICHLORIDE
ETHYLENE DICHLORIOE
ETHYLENE DICHLORIDE
ETHYLENE DICHLORIDE
ETHYLENE BICHLORIDE
ETHYLENE DICHLORIDE
ETHYLENE DICHLORIDE ETHYLENE DICHLORIOE ETHYLENE DICHLORIOE ETHYLENE OfCHLORlOE
r> oo
o ~n
ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIOE ETHYLENE DICHLORIDE
HO O sS rn \j
z&
H fv JT*->\ cn
ETHYLENE DICHLORIOE
ETHYLENE DICHLORIDE
ETHYLENE DICHLORIDE
ETHYLENE OICHLOROE IC-250 REFLUX)
ETHYLENE DICHLORIOE (C-260 REFLUX)
ETHYLENE DICHLORIOE (CRUDE - EDC + VCM + HCL)
ETHYLENE DICHLORIDE ID-16 VESSa SAMPLE)
ETHYLENE OICHLORiDE + BETA-TRICHLOROETHANE
ETHYLENE DICHLORIOE + BETA-TRICHLOROETHANE
ETHYLENE GLYCOL
ETHYLENE GLYCOL
ETHYLENE GLYCOL
ETHYLENE GLYCOL
ETHYLENE GLYCOL
ETHYLENE GLYCOL
ETHYLENE GLYCOL (1%) IN CONDENSATE
ETHYLENE GLYCOL (1 %) IN WATER
TEAM LEAK REPAIRS SEALANT #6 GRAFOL GHE GRAFOIL GHR TEAM LEAK REPAIRS SEALANT #0 FURMANITE FSC-6B STEAM ft PROCESS SP-2000 STEAM ft PROCESS SP-2026 TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK AW W1 FIBERS TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B + G FIBERS TEAM LEAK REPAIRS VALVEPACK GX COWER OIL TOOL DIVISION WKM NO. 114 FURMANITE FSC-5B FURMANITE FSC-5B FURMANITE FSC-8B FURMANITE FSC-6B STEAM ft PROCESS SP-289 STEAM ft PROCESS SP-2B9 STEAM ft PROCESS SP-325 STEAM ft PROCESS SP-325 TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT *2XH TEAM LEAK REPAIRS SEALANT 0 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX FURMANITE FSC-5C FURMANITE FSC-0B WKM VALVEPACK 114ft "STP* LUBRICANT STEAM ft PROCESS SP-325 TEAM LEAK REPAIRS SEALANT #8 TEAM LEAK REPAIRS VALVEPACK A CMS PUMP SEALANT CMS PUMP SEALANT FURMANITE FSC-0B MOLYKOTE 44 LUBRICANT STEAM ft PROCESS SP-1011 STEAM ft PROCESS SP-2000 STEAM ft PROCESS SP-1011 FURMANITE FSC-6B
Daw Confidential
DOWANOLS GLYCOL 2 GLYCOL 2 SOLVENTS/EDC LHC 3 VINYL 1 VINYL 1 VINYL 1 VINYL 1 POLY C BRINE BRINE LHC 3 POLY C LHC 3 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 1 VINYL 2 VINYL 2 VINYL 1 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 SOLVENTS/EDC VWYL 1 VINYL 1 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2
B4E108 90311 90311 90024 92306 RCL B3-111 RCL 83-112 84E194 84E186 88183A 94052 94052 86223F 86183B 93207 93042 93164 93164 93154 93164 93154 93154 93154 93154 93164 93164 93154 93154 3108-46 93154 93154 84E188 93154 93154 4791-29A 4791-29A 93060 93144 84E193 84E190 RCL-95-1361 RCL-96-1361 92143 94030 94030 94030 92194 92143
DTA DSC DSC DSC DSC DTA OTA OTA OTA OTA HOM DSC OTA OTA DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DTA DSC HOM OTA DSC HOM DSC DSC OSC OSC DTA DTA DSC HOM DSC DSC OSC OSC DSC DSC
REACTIVITY
NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 225 C NO EXO TO 130 C NO EXO TO 250 C NO EXO TO 375 C NO EXO AT 22 C NO EXO TO 108 C NO EXO TO 350 C NO EXO TO 325 C NO EXO TO 200 C NO EXO TO 310 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 325 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 300 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 160 C EXO AT 40 C EXO AT 130 C NO EXO TO 300 C NO EXO TO 400 C EXO AT 276 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 200 C EXO AT 205 C NO EXO TO 350 C NO EXO TO 360 C NO EXO TO 250 C NO EXO TO 105 C
13
TABLE 1. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIOE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIOE ETHYLENE OXIOE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIOE REACTOR OUTLET GAS ETHYUDENE NORBORNENE ETHYLIOENE NORBORNENE FLARE DRUM LIQUID FLIGHTGARD 2000 FREON 12 FREON 12 FUEL OIL FUEL OIL HCI115%) + METHYL CHLORIDE (85%) HO (16%) + METHYL CHLORIDE (85%) HCI (50%) + CHLORINE (50%) Ha (50%1 -I- CHLORINE (50%) Ha (50%) + CHLORME (50%) Ha, Ml, M2, M3. M4 (T-851) HCI. Ml, M2. M3. M4 (T-861) HCLM1 ,M2,M3,M4 IK-360 SUCTION) HYDROGEN HYDROGEN HYDROGEN HYDROGEN CHLORIDE HYDROGEN CHLORIOE
O oo 2O
O O \i m *~7 4f.* H '-f O'
3M NEOPRENE 80 CONTACT ADHESIVE 3M NEOPRENE 80 CONTACT ADHESIVE CHEMRAZ O-RING MATERIAL CMS 2000 PUMP SEALANT CMS 2000 PUMP SEALANT COLTEC CARBON CERAMIC PTFE GRADE 324 COLTEC CARBON GRAPHITE PTFE FILED PEEK - 580 E0982 O-RING MATERIAL EPR EO 982 "O'-RING EPR RED DOT -O'-RING FURMANITE FSC-5B FURMANFTE FSC-5B FURMANITE FSC-6B FURMANITE FSC-6B GRAFOIL GHE GRAPHONICS GASKET GRAPHONICS GASKET (ADHESIVE STRIP) STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1012 STEAM & PROCESS SP-106 STEAM ft PROCESS SP-109 STEAM ft PROCESS SP-2000 STEAM ft PROCESS SP-60 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK B VITON YELLOW DOT 'O'-RWG LAMONS SPIROSEAL GSKT (GRAPHITE) GARLOCK 9B PACKING GARLOCK 99 PACKING TEAM LEAK REPAIRS VALVEPACK OX O.E.fl. 331 EPOXY RESIN STEAM ft PROCESS SP-2007 STEAM ft PROCESS SP-2028 ROYAL PURPLE BARRIER FLUID 22 ROYAL PURPLE BARRIER FLUID 22 STEAM ft PROCESS SP-1011 STEAM ft PROCESS SP-103 CURED DB 22 SLASTIC 732 RTV TEAM LEAK REPAIRS SEALANT *8 STEAM ft PROCESS SP-2800 STEAM ft PROCESS SP-CM STEAM ft PROCESS SP-2000 STEAM ft PROCESS SP-2000 TEAM LEAK REPAIRS VALVEPACK AW ft FIBERS TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-6B FURMANITE FSC-8B
GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 DOWANOLS DOWANOLS GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 1 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 * DOWANOLS GLYCOL 2 EPDM EPDM LHC 2 GLYCOL 2 METHANES CHLORINE LHC 3 LHC 3 METHANES METHANES SOLVENTS/EDC SOLV ENTS/EDC SOLVENTS/EDC METHANES METHANES METHANES CHLOR-ALKALI 2 POLY C LHC 2 GLYCOL 2 GLYCOL 2
93034 93034 B9147 RCL-95-1363 RCL-95-1363 RCL-98-0151 RCL-96-0162 89147 92339 92339 90318 RCL-95-0922 RCL-95-0821 RCL-95-0821 90185 92050 93077 94030 85197D RCL 1230 85197B 94030 85197A 90003 90003 92339 90131 RCL-96-0181 RCL-96-0182 91058 90270 RCL 82-037 90051 92169 92189 RCL1145 RCL 1147 4791-9A 4791-9A 4791-9A RCL 82-014 RCL 1400 RCL B2-119 93199 B8191A 86223B 92143 92143
DSC HOM DSC DSC HOM ARC DSC DSC DSC DSC DSC HOM DSC HOM DSC DSC DSC DSC DTA DTA DTA DSC OTA DSC DSC DSC DSC DSC HOM DSC DSC DTA DSC DSC HOM DTA DTA DSC DSC DSC DTA DTA DTA HOM DTA DTA DSC DSC
REACTIVITY
EXOAT 190 C EXO AT 22 C NO EXO TO 250 C EXOAT 150 C EXO AT 22 C EXOAT 161 C EXOAT 178 C NO EXO TO 250 C EXO AT 195 C EXO AT 195 C NO EXO TO 200 C EXO AT 22 C NO EXO TO 160 C EXO AT 22 C NO EXO TO 300 C NO EXO TO 194 C NO EXO TO 250 C EXOAT 120 C EXO AT 255 C NO EXO TO 250 C EXO AT 260 C EXO AT 320 C NO EXO TO 350 C EXO AT 126 C NO EXO TO 250 C EXOAT 188 C EXO AT 360 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 150 C NO EXO TO 100 C NO EXO TO 100 C NO EXO TO 250 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 360 C EXOAT 146 C EXO AT 25 C EXO AT 170 C EXO AT 126 C NO EXO TO 500 NO EXO TO 300 NO EXO TO 200 NO EXO TO 26 C NO EXO TO 375 C NO EXO TO 210 C NO EXO TO 260 C NO EXO TO 260 C
oou
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL!
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE (ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYOROGEN CHLORIDE (ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIOE (ANHYDROUS)
HYDROGEN CHLORIDE IANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE 1ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUSI
HYDROGEN CHLORIDE (ANHYDROUSI
HYDROGEN SULFIDE GAS
HYOROGEN SULFIDE GAS
HYOROGEN SULFIDE GAS
HYDROLYZER BOTTOMS
ISOPAR E
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ISOPAH E
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ISOPAR E ISOPAR E
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ISOPAR E
ISOPAR E ISOPAR E
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ISOPAR E
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ISOPAR E
ISOPRENE
Ml. M2. M3, M4, 4 HC1
Ml. M2. M3. M4, 4 HCI
MEA,DEA.TEA,KOH (REACTOR EFFLUENT)
METHANE
METHANES E-259 VENT (HCf,Mf.M2.M3f
METHANES R-300 OUTLET 1M1.M2.M3.M4.HCII
METHANOL
METHANOL
SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TERON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) SAFE SEAL MULTIPAK (JOHN CRANE 6KB) SAFE SEAL MULTIPAK (JOHN CRANE 6KB) COOPER OIL TOOL DIVISION WKM NO. 114 FURMANITE FSC-5B FURMANITE FSC-5B FURMANITE FSC-6C FURMANITE FSC-6B FURMANITE FSC-8B STEAM & PROCESS SP-1011 STEAM PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM S PROCESS SP-102 STEAM PROCESS SP-2000 STEAM a PROCESS SP-2007 STEAM a PROCESS SP-CM TEAM LEAK REPAIRS SEALANT fIX TEAM LEAK REPAIRS SEALANT #1X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT *2X TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT DB-2 TEAM LEAK REPAIRS VALVEPACK A STEAM a PROCESS SP-3100 STEAM a PROCESS SP-770 TEAM LEAK REPAIRS SEALANT 18X SYNTHO-GLASS NEPTUNE RESEARCH STEAM a PROCESS SP-326 STEAM a PROCESS SP-325 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT IX TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT EG TEAM LEAK REPAIRS SEALANT DB 20 TEAM LEAK REPAIRS SEALANT X-36 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX STEAM a PROCESS SP-326 STEAM a PROCESS SP-326 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS VALVEPACK B SIASTIC 732-RTV SILICONE RUBBER STEAM a PROCESS SP-2000 STEAM a PROCESS SP-1016 STEAM a PROCESS SP-1016 4 SP-2000
METHANES METHANES METHANES METHANES METHANES METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VWYL 2 VINYL 2 VINYL 1 VINYL 1 METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 1 METHANES VINYL 1 LGTI LGTI LGTI GLYCOL 1 POLY C POLY C POLY C POLY C POLY C POLY C POLY C POLY C POLY C VECTOR METHANES METHANES DOWANOLS LHC 2 METHANES METHANES METHANES DOWANOLS
94080 94080 94080 94080 94060 94080 93042 92148 93164 4791-29A 92146 93164 93164 93164 93164 93164 RCL 84-007 RCL B4-006 BS133P 93164 93164 93164 93164 RCL 84-009 RCL B2-042 RCL 94-008 93022 93022 93032 91175 93215 93215 87033G S7033D B7033E 87033F S7033H 870331 87033J 93089 93093 93093 RCL1270,71 86223E RCL 83-092 RCL B2-045 B5173A RCL-95-1061
HOM DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC HOM DSC HOM DSC HOM DTA DTA DTA DSC HOM DSC HOM DTA OTA DTA DSC DSC DSC DSC DSC HOM DTA DTA DTA DTA OTA DTA DTA DSC DSC HOM DTA DTA DTA DTA DTA DSC
Dow Confidential
REACTIVITY
SL. EXO AT 22 C NO EXO TO 450 C SL. EXO AT 22 C EXO AT 380 C EXO AT 22 C NO EXO TO 325 C EXO AT 225 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 70 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 400 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 186 C NO EXO TO 260 C EXO AT 80 C SL. EXO AT 22 C EXO AT 117 C SL. EXO AT 22 C NO EXO TO 185 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 300 C EXO AT 316 C NO EXO TO 150 C EXO AT 170 C NO EXO AT 22 C NO EXO TO 280 C NO EXO TO 280 C NO EXO TO 280 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 280 C NO EXO TO 260 C NO EXO TO 200 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 310 C NO EXO TO 225 C NO EXO TO 200 C
IS
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
METHANOL
METHANOL
METHYL CHLORIDE
METHYL CHLORIDE
METHYL CHLORIDE
METHYL CHLORIDE
METHYL CHLORIDE
METHYL CHLORIDE
METHYL CHLORIDE
METHYL CHLORIOE
METHYL CHLORIOE
METHYL CHLORIDE
METHYL CHLORIDE
METHYL CHLORIDE
METHYL CHLORIDE + DIMETHYL ETHER
METHYL CHLORIDE + DIMETHYL ETHER
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE (LOC48)
METHYLENE CHLORIDE
METHYLENE CHLORIDE
METHYLENE CHLORIDE
METHYLENE CHLORIDE
METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIOE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE MONOETHYLENE GLYCOL MONOPROPYLENE GLYCOL + WATER
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MONOPROPYLENE GLYCOL + WATER
N-PROPANOL 160%) + WATER (50%)
NITROGEN
OIL BOTTOMS (T-102C TOWER)
PER/TET (CRUDE)
PER/TET ICRUOE)
PER/TET (CRUOE)
PER/TET (CRUDE)
STEAM A PROCESS SP-1015 + SP-2000 TEAM LEAK REPAIRS SEALANT DB-2 755 STICK SEALANT SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOtt.) SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) SAFE SEAL MULTIPAK (JOHN CRANE 6KBI SAFE SEAL MULTIPAK (JOHN CRANE 6KB| STEAM k PROCESS SP-1300 STEAM k PROCESS SP-2007 STEAM k PROCESS SP-2020 STEAM k PROCESS SP-CM TEAM LEAK REPAIRS SEALANT DB-2 TEAM LEAK REPAIRS SEALANT #0 TEAM LEAK REPAIRS SEALANT #0 CORTEC VCt-309 CORTEC VC1-309 CORTEC VC1-308 CORTEC VCF308 NICKEL ANTISEIZE NICKEL ANTISEIZE k PERMATEX PERMATEX TEAM LEAK REPAIRS SEALANT #8 TEAM LEAK REPAIRS SEALANT #0 STEAM k PROCESS SP-CM SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOILI SAFE SEAL GRAFPAK IUCAR CARBON CO GRAFOILI SAFE SEAL MULTIPAK (JOHN CRANE 6KB) SAFE SEAL MULTIPAK (JOHN CRANE 6KBI STEAM k PROCESS SP-103 STEAM k PROCESS SP-1300 STEAM k PROCESS SP-1360 STEAM k PROCESS SP-2020 STEAM k PROCESS SP-CM TEAM LEAK REPAIRS SEALANT DB-2 FURMANITE FSC-8B TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 2X SEMSTONE 145-S STEAM k PROCESS SP-00 TEAM LEAK REPAIRS SEALANT *6 FURMANITE GASKET COATING (CL2| TEAM LEAK REPAIRS SEALANT #10 -I- F-45 FIBER TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS VALVEPACK OX
Daw
DOWANOLS METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES . METHANES METHANES METHANES METHANES METHOCEL METHOCEL LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI METHANES METHANES METHANES METHANES
METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES GLYCOL 2 GLYCOL 1 GLYCOL 1 POLY B LGTI GLYCOL 1 SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC
RCL-95-1081 RCL 82-041 91128 94000 94000 94000 94080 94000 94000 RCL 1578 84E150 85132A 85133B RCL 82-040 93196 93196 RCL-96-1372 RCL-95-1372 RCL-95-1379 RCL-96-1379 93098 93099 93098 RCL-95-0851 RCL-95-0851 4791-5A 94000 94060 94000 94000
94000 94000 RCL 1584 RCL1582 RCL1677 861328 85133C RCL 82-038 92143 91140 91146 90148 4791-43A 4791-36B
91004 89228 89141 89141
HOM DTA DSC HOM DSC HOM DSC HOM DSC DTA DTA DTA DTA DTA DSC HOM DSC HOM DSC HOM DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC
HOM DSC DTA DTA DTA DTA OTA DTA DSC DSC DSC DSC OSC DSC DSC DSC DSC OSC
REACTIVITY
NO EXO AT 22 C NO EXO TO 175 C NO EXO TO 175 C NO EXO AT 22 C EXO AT 375 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO TO 140 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 190 C NO EXO TO 190 C a. EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C EXOAT 125 C EXO AT 100 C NO EXO TO 200 C NO EXO TO 260 C a. EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C EXO AT 228 C NO EXO AT 22 C EXO AT 336 C NO EXO AT 22 C EXO AT 120 C NO EXO TO 160 C NO EXO TO 160 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 260 C NO EXO TO 250 C EXO AT 350 C NO EXO TO 190 C NO EXO TO 260 C EXO AT 246 C EXO AT 80 C EXOAT 145 C
10
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL!
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
POTASSIUM CARBONATE 122%) IN WATER PROPANE PROPANE PROPANE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE (2C-54 OVERHEADI PROPYLENE + REGAL 32 OIL PROPYLENE + REGAL 32 OIL PROPYLENE DICHLORIDE. CI2, AIR. HO. WATER IE-IB) PROPYLENE DICHLORIDE. CI2, AIR. HO, WATER (E-IB) PROPYLENE DICHLORIDE. CI2. AIR. Ha. WATER (E-IB) PROPYLENE DICHLORIDE, CI2, AIR. HC1, WATER (E-IB) PROPYLENE GLYCOL PROPYLENE GLYCOL (2%) IN WATER PROPYLENE GLYCOL (2%) IN WATER PROPYLENE GLYCOL (2%) IN WATER PROPYLENE GLYCOL (2%) IN WATER PROPYLENE OXIDE PROPYLENE OXIDE ICRUDE) PROPYLENE OXIDE (CRUOE) PROPYLENE OXIDE (CRUDE) PROPYLENE OXIDE PROPYLENE OXIDE + DIMETHYL ETHER/ METHYL CL PYGAS PYROLYSIS GAS PYROLYSIS GAS PYROLYSIS GASOLINE ft RESIN OIL PYROLYSIS GASOLINE ft RESIN OIL QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR
TEAM LEAK REPAIRS SEALANT #0 TEAM LEAK REPAIRS SEALANT 18 TEAM LEAK REPAIRS SEALANT X-30 AftB TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-58 FURMANITE FSC-5B FURMANITE FSC-6B FURMANITE FSC-6B LOCTITE 290 STEAM ft PROCESS SP-1011 STEAM ft PROCESS SP-1011 STEAM ft PROCESS SP-2000 STEAM ft PROCESS SP-2000 TEAM LEAK REPAIRS SEALANT *2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT *2XH TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK GX LOCTITE 290 FURMANITE FSC-46D FURMANITE FSC-460 STEAM ft PROCESS SP-1380 STEAM ft PROCESS SP-2026 TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT OB-2 TEAM LEAK REPAIRS SEALANT #6 FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-3A FURMANITE FSC-3A GRAFOIL VALVE PACKING STEAM ft PROCESS SP-32S STEAM ft PROCESS SP-102 STEAM ft PROCESS SP-389 TEAM LEAK REPAIRS SEALANT #0 TEAM LEAK REPAIRS TC-4 (CURED) FURMANITE FSC-8B ROYAL PURPLE BARRIER FLUID 22 ROYAL PURPLE BARRIER FLUID 22 TEAM LEAK REPAIRS SEALANT f0 TEAM LEAK REPAIRS SEALANT X30 AftB FURMANITE FSC-0B FURMANITE FSC-0B STEAM ft PROCESS SP-1011 STEAM ft PROCESS SP-1011
Dow Confidential
GLYCOL 2 PROMIX LHC 3 LHC 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 LHC 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 1 VINYL 1 LHC 2 LHC 3 LHC 2 LHC 3 LHC 3 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 METHOC& LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 VINYL 2 VNYL 2 VINYL 2 VINYL 2
91092 94071 9212* 80223H 93154 93154 93154 93154 92148 93154 93154 93164 93154 93154 93154 93154 93154 84E195 84E187 90223A 93207 92148 93104 93164 RCL1661 RCL 1560 RCL 1658 RCL 1659 91199 92026 92020 92028 92020 84EO08 RCL-98-0261 RCL-90-0202 RCL-90-O263 89285 90324 91100 92109 92169 92124 92124 93154 93154 93154 93164
DSC DSC DSC DTA DSC HOM DSC HOM DSC DSC HOM DSC HOM DSC HOM DSC HOM DTA DTA OTA DSC DSC DSC HOM DTA DTA OTA DTA DSC DSC HOM DSC HOM DTA DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC HOM DSC HOM
REACTIVITY
NO EXO TO 200 C NO EXO TO 178 C NO EXO TO 100 C NO EXO TO 300 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 225 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 260 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 400 C NO EXO TO 210 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 210 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 190 C NO EXO TO 260 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 235 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C EXOAT 200 C EXOAT 120 C NO EXO TO 200 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 360 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C
DO 0 7 2 4 5 0
CONFIDENTIAL
17
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH OIL (C-10 BOTTOMS) QUENCH OIL (C-10 BOTTOMS) R-2 a R-102 HYDROLYZER BTMS RANDO 08 OIL RANDO 08 OIL RANDO 08 OIL REGAL 32 OIL REGAL OL 32 RESIN ON. RESIN ON. SHELL THERMIA C ON. WITH DISSOLVED HCL SHELL THERMIA ON. C SHELL THERMIA OIL C SILICONE SWS-101 SN.ICONE SWS-101 SILICONE SWS-101 SIMULATED VENT GAS SIMULATED VENT GAS SLAG ILOC 37B) SLAG ILOC 37B) SLAG WATER (LOC 37) SLAG WATER (LOC 37) SODIUM BISULFITE SOLUTION IN WATER SODIUM BISULFITE SOLUTION IN WATER SODIUM HYDROXIDE (10%) SODIUM HYDROXDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SOOIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (3%l SODIUM HYDROXIDE (40%) - HE-201 SODIUM HYDROXIDE (60%) SODIUM HYDROXIDE (60%) SODIUM HYDROXIDE (60%) SODIUM HYDROXIDE (60%)
STEAM & PROCESS SP-325 STEAM a PROCESS SP-325 TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #0 TEAM LEAK REPAIRS SEALANT #8 FURMANITE FSC-5B FURMANITE FSC-0B STEAM a PROCESS SP-2000 STEAM a PROCESS SP-2000 STEAM a PROCESS SP-2021 STEAM a PROCESS SP-325 TEAM LEAK REPAIRS SEALANT #0 SEAL-ITT +34 ROYAL PURPLE BARRIER FLUID 22 ROYAL PURPLE BARRIER FLUID 22 ULTRAMETAL LIQUID METAL (CURED) STEAM a PROCESS SP-1011 STEAM a PROCESS SP-109 SAFE SEAL - CHEMOLA TEFLON SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) SAFE SEAL MULTIPAK IJOHN CRANE 0KB) TEAM LEAK REPAIRS SEALANT OB-22 TEAM LEAK REPAIRS SEALANT DB-22 STEAM a PROCESS SP-102 STEAM a PROCESS SP-00 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX FURMANITE MASTER WRAP FURMANITE MASTER WRAP FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-112A FURMANITE FSC-0B FURMANITE FSC-0B FURMANITE FSO0B PIG REPAIR PUTTY EPOXY STICK PIG REPAIR PUTTY EPOXY STICK SEAL-ITT #34 STEAM a PROCESS SP-1011 STEAM a PROCESS SP-2000 STEAM a PROCESS SP-00 SEMSTONE 145-S STEAM a PROCESS SP-6000 BELZONA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL SERVICE GROUP INC 107 ABB BONDER
VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 LHC 3 LHC 3 GLYCOL 1 POLYA POLYA POLYA LHC 3 CHLORINE LHC 3 LHC 3 METHANES METHANES METHANES LHC 2 LHC 2 LHC 2 VINYL 2 VINYL 2 LGTI LGTI LGTI LGTI LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 CAUSTIC CAUSTIC CHLORINE CHLORINE CHLORINE CHLORINE POLY B CAUSTIC CHLORINE CHLORINE CHLORINE CAUSTIC
93154 93154 93154 93154 93154 93154 91303 91303 89379 93210 93210 93210 90034 90277 92169 92169 9302B 90400 90400 94038 94038 94038 92302 92302 4791-8A 4791-8A 94006 94006 RCL-95-0401 RCL-95-0401 92093 92093 92093 92093 92093 92093 92137 92437 90277 92100 921 BO 92180 90146 4791-30B 86172F 04ElBO 86172C 89223
DSC HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC HOM DSC HOM HOM DSC HOM HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC DSC DTA DTA DTA DSC
Dow ConfUontlot
REACTIVITY
NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 200 C EXO AT 36 C NO EXO TO 200 C NO EXO TO 250 C EXOAT 106 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXOAT 120 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 120 C NO EXO AT 22 C NO EXO TO 235 C NO EXO TO 235 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO AT 26 C EXO AT 165 C NO EXO AT 22 C NO EXO AT 25 C NO EXO TO 200 C NO EXO AT 22 C EXO AT ISO C NO EXO AT 25 C EXO AT 160 C EXOAT 190 C EXOAT 170 C EXOAT 194 C EXOAT 155 C EXO AT 90 C NO EXO TO 260 C EXO AT 160 C NO EXO TO 250 C NO EXO TO 250 C
PROCESS CHEMICAL
SODIUM HYDROXIDE <50%l
SODIUM HYDROXIDE <SO%l
SODIUM HYDROXIDE |50%)
SODIUM HYDROXIDE 150%)
SODIUM HYDROXIOE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%) + AMMONIA
SODIUM HYDROXIDE (50%) -I- AMMONIA
SODIUM HYOROXIDE 150%) + NH40H
SOUR CONDENSATE
SS, CAST FE. CU. HAST. GRAPHITE, H20
STYRENE
SULFUR (LOC 24f
SULFUR (LOC 24)
SULFUR (LOC 24)
SULFUR (LOC 24)
SULFUR ILOC 24)
SULFURIC ACID
SULFURIC ACID (96%)
SULFURIC ACID (96%)
SULFURIC ACID 190%)
SULFURIC ACID (90%)
SULFURIC ACID (90%)
SULFURIC ACS> SOLUTION 110 Ml
SULFURIC ACID SOLUTION (10 N|
SULFURIC ACID SOLUTION 110 N)
SULFURIC ACID SOLUTION (10 N)
SYNGAS
SYNGAS
SYNGAS
SYNGAS
SYNGAS
SYNGAS
O
SYNGAS SYNGAS
OO \
SYNGAS SYNGAS SYNGAS
<- o O NI ^^
SYNGAS
SYNGAS SYNGAS
--( tn
"*
SYNGAS BLEND SYNGAS BLEND SYNGAS BLEND T-62 BTMS T-8-2 BOTTOMS TET, PER. HCE. HCL CHLORINE TOLUENE- XYLENE MIXTURE
18
TABLE I. REACTIVrTY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMfCALI
SEALANT
PLANT
REF. NO.
TEST
STEAM 0 PROCESS SP-1011 STEAM 9 PROCESS SP-1015 STEAM 9 PROCESS SP-00 TEAM LEAK REPAIRS SEALANT *10 TEAM LEAK REPAIRS SEALANT *0 TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT #10 TEAM LEAK REPAIRS SEALANT #0 TEAM LEAK REPAIRS TC-4 EPOXY BONDER TEAM LEAK REPAIRS SEALANT #0 DOW CORNING 111 LUB/SEALANT TEAM LEAK REPAIRS VALVEPACK AX CORTEC VCF309 CORTEC VCF388 STEAM 9 PROCESS SP-1011 STEAM 9 PROCESS SP-102 STEAM 0 PROCESS SP-00 TEAM LEAK REPAIRS SEALANT DB-2 BELZONA CERAMIC-fl METAL 8ELZ0NA E-METAL BELZONA SUPER METAL STEAM 9 PROCESS SP-2007 STEAM a PROCESS SP-2020 GRAFOIL GHE GASKET GRAPHITE MAT'L GRAFOIL GHE GASKET GRAPHITE MAT'L GRAFOR. GHE GASKET METAL MAT'L GRAFOIL GHE GASKET METAL MAT'L CORTEC VCF309 CORTEC VCF309 CORTEC VCF308 NEPTUNE RESEARCH SYNTHO-GLASS STEAM 9 PROCESS SP-3000 STEAM 9 PROCESS SP-429 TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 19X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT RF 300 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK EPX UTEX 8B4 SEALANT STEAM 9 PROCESS SP-1011 STEAM 9 PROCESS SP-102 STEAM a PROCESS SP-00 TEAM LEAK REPAIRS SEALANT *0 9 F-14 FIBERS FURMANITE FSC-6B TEAM LEAK REPAIRS CURED HI-PRO BELZONA 1311 CERAMIC R-METAL SEALANT
METHANES DOWANOLS CHLOR-ALKALI 2 CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC LGTI LHC 3 VECTOR LGTI LGTI LGTI LGTI LGTI METHANES CHLORINE CHLORINE CHLORINE CHLOR-ALKALI 2 CHLOR-ALKALI 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI GLYCOL 2 GLYCOL 2 SOLVENTS/EDC LHC 2
RCL1T40 RCL 1233 92320 RCL 1008 RCL 1005 B71121 RCL 1009 RCL 1000 RCL1308 870901 89271 93009 RCL-95-1370 RCL-96-0373 4791-5A 4791-5A 4791-5A RCL 82-044 85172E 84E213 85172B 851018 85101A 93011 93011 93011 93011 RCL-96-137S RCL-95-1375 RCL-95-6375 93038 93125 93125 92318 92316 93123 93123 93072 92318 92318 RCL-95-0281 4791-42A 4791-43A 4791-43A 92160 93131 91060 RCL-96-0461
DTA DTA DSC DTA DTA DSC DTA DTA DTA DSC DSC DSC DSC DSC DSC DSC DSC DTA DTA DTA DTA OTA DTA DSC HOM DSC HOM DSC HOM HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC
Dow ConfMontld
REACTIVITY
NO EXO TO 295 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 230 C NO EXO TO 190 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 85C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 45 C NO EXO TO 250 C EXO < 30 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO AT 22 C EXO AT 137 C NO EXO TO 250 C NO EXO TO 76 C NO EXO AT 22 C NO EXO AT 22 C NO EXO TO 600 C NO EXO TO 500 C NO EXO TO 285 C NO EXO TO 400 C NO EXO TO 400 C EXO AT 362 C NO EXO TO 500 C NO EXO TO 500 C NO EXO TO 400 C NO EXO TO 400 C NO EXO TO 000 C EXO AT 47 C EXO AT 100 C EXO AT 306 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C
19
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL {SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO.
TEST
TOLUENE- XYLENE MIXTURE
1.1,1 -TRICHLOROETHANE
1,1,1-TRlCHLO ROETHANE
TRIETHANOLAMINE
TRIETHANOLAMINE
TRIETHANOLAMINE
VINYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORIDE VINYL CHLORIDE
O
VINYL CHLORIDE
^
VINYL CHLORIDE VINYL CHLORIDE
>- O ^^
VMYL CHLORIDE
-
VINYL CHLORIDE
H Cl
VINYL CHLORIDE
'x)
VINYL CHLORIDE
f-
VINYL CHLORIDE
VMYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORIDE
VINYL CHLORtOE (80%) + ANHYDROUS Ha (20%)
VINYL CHLORIDE (80%) + ANHYDROUS Ha (20%)
VINYL CHLORIDE (80%) + ANHYDROUS Ha (20%I
VMYL CHLORIDE (80%) + ANHYDROUS Ha (20%)
VMYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VMYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VMYL CHLORIDE (80%) 4 ANHYDROUS Ha (20%)
VMYL CHLORIDE (80%) 4 ANHYDROUS Ha (20%)
VMYL CHLORIDE <80%| 4 ANHYDROUS Ha (20%)
VMYL CHLORtOE <80%l 4 ANHYDROUS Ha (20%)
VMYL CHLORtOE (80%) 4 ANHYDROUS Ha (20%)
VMYL CHLORIDE (80%) 4 ANHYDROUS HCI (20%)
VMYL CHLORtOE (80%) 4 ANHYDROUS Ha (20%)
VMYL CHLORtOE <90%l 4 ANHYDROUS Ha (20%)
VMYL CHLORIDE 180%) 4 ANHYDROUS Ha (20%)
WASTE WATER EFFLUENT (P-B)
WATER {COOLMG TOWER)
WATER IE7F)
WATER (E7F)
WATER (LOCT-1441
BELZONA 1311 CERAMIC R-METAL SEALANT C5A Fa PRO NO. 725 NICKa ANTISEIZE MOLYKOTE 44 LUBRICANT STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 FURMANITE FSC-46D FURMANITE FSC-40D FURMANITE FSC-5C FURMANITE FSC-6C FURMANITE FSC-6B FURMANITE FSC-6B STEAM S PROCESS SP-1011 STEAM S PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM 8 PROCESS SP-2007 STEAM PROCESS SP-325 STEAM 8 PROCESS SP-325 STEAM 8 PROCESS SP-429 TEAM LEAK REPAIRS SEALANT *11 TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT *2X TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT 42XH TEAM LEAK REPAIRS SEALANT 0B-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-48D FURMANITE FSC-46D FURMANITE FSC-6C FURMANITE FSC-6C STEAM a PROCESS SP-1011 STEAM a PROCESS SP-1011 STEAM a PROCESS SP-325 STEAM a PROCESS SP-325 TEAM LEAK REPAIRS SEALANT *1BX TEAM LEAK REPAIRS SEALANT 418X TEAM LEAK REPAIRS SEALANT *0 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 4 F-14 FIBER TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS SEALANT 18X STERLNG STUFFING BOX SEALANT f1 TEAM LEAK REPAIRS 16X a F-10 a F-14 FIBERS TEAM LEAK REPAIRS SEALANT 10X a F-10 FIBERS STEAM a PROCESS SP-102
Dow ConfidantM
LHC 2 POWER 1 POWER 1 GLYCOL 2 GLYCOL 2 GLYCOL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VMYL 1 VINYL 2 VINYL 2 METHANES VMYL 2 VMYL 2 VMYL 2 VINYL 2 VINYL 2 VMYL 1 VMYL 1 VMYL 1 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 2 VMYL 1 VMYL 1 VMYL 1 GLYCOL 1 LHC 3 GLYCOL 2 GLYCOL 2 LGTI
RCL-96-0401 89050 89050 94030 94030 94030 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 3108-40 93154 93164 93179 93147 93164 93154 93154 93164 84E190 3108-40 3108-40 93154 93154 93154 93154 93154 93154 93154 93164 93164 93154 93164 93154 RCL 83-090 RCL 83-097 84E191 90204 91135 92100 92100 4791-5A
HOM DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DTA DSC HOM DSC DSC DSC HOM DSC HOM DTA DTA DTA DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DTA DTA DTA DSC DSC DSC DSC DSC
HEAcnvrrY
NO EXO AT 22 C EXOAT 125 C EXOAT 133 C EXO AT 240 C EXO AT 320 C EXO AT 319 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C EXOAT 149 C SL. EXO AT 22 C NO EXO TO 350 C SL. EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NONE NO EXO TO 220 C NO EXO AT 22 C EXO AT 114 C EXOAT 136 C EXO AT 330 C NO EXO AT 22 C EXO AT 204 C NO EXO AT 22 C NO EXO TO 225 C NONE NONE NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C EXO AT 178 C NO EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 400 C NO EXO TO 250 C NO EXO TO 260 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C
PROCESS CHEMICAL
WATER (LOC T-1441
WATER WITH < 1 % GLYCOLS
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM
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WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
20
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL ISOHTED BY PROCESS CHEMICAL)
SEALANT
PLANT
REF. NO.
TEST
STEAM A PROCESS SP-80 STEAM a PROCESS SP-1011 COPALTfTE CEMENT SEALANT CORTEC VCP309 CORTEC VCP309 CORTEC VO-368 CORTEC VCI-368 FURMANITE DENEEF FLEX-LV SEALANT FURMANITE DENEEF FLEX-LV SEALANT FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-11C FURMANITE FSC-3A FURMANITE FSC-8B FURMANITE FSC-6B FURMANITE FSC-7C FURMANITE FSC-50D FURMANITE FSC-SOD PLIDCO S.P. SEALANT IJ-STICKI SERVICE GROUP INC SG-101 LIQUID SERVICE GROUP INC SG-101 SOLID SERVICE GROUP INC SG-101HT SERVICE GROUP WC SG-102 SOLIO SERVICE GROUP INC SG-106 LIQUID SERVICE GROUP INC SG-108 ABB SERVICE GROUP INC SG-109 SERVICE GROUP INC SG-110 SOLID SERVICE GROUP INC SG-113 SERVICE GROUP WC SG-201 SERVICE GROUP WC SG-201 HT SERVICE GROUP WC SG-260 SERVICE GROUP INC SG-302 SERVICE GROUP INC SG-303 SERVICE GROUP WC SG-304 SERVICE GROUP WC SG-300 SERVICE GROUP WC SG-312 SERVICE GROUP WC SGC FIBER SERVICE GROUP INC SGK FIBER STEAM a PROCESS SP-1011 STEAM a PROCESS SP-1011 STEAM a PROCESS SP-102 STEAM a PROCESS SP-102 STEAM a PROCESS SP-2000 STEAM a PROCESS SP-2000 STEAM a PROCESS SP-2016 STEAM a PROCESS SP-2611 TEAM LEAK REPAIRS SEALANT 41 TEAM LEAK REPAIRS SEALANT 418X
LGTI GLYCOL 2 LHC 3 LGTI LGTI LGTI LGTI LHC 3 LHC 3 VINYL 2 VINYL 2 LHC 3 LHC 3 LHC 3 VINYL 2 LHC 3 LHC 2 LHC 2 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 METHANES VINYL 2 VWYL2 VWYL 2 VINYL 2 VWYL 2 CHLOR-ALKALI 2 METHANES METHANES VWYL 2
4791-5A 92194 4792-25A RCL-95-1371 RCL-95-1371 RCL-95-1378 RCL-95-1378 RCL-96-0501 RCL-98-0501 831S4 93164 93020 90312 91052 93154 90312 RCL-95-1471 RCL-95-1471 4792-25A B9272 89272 89272 89272 89272 B9272 89272 89272 89272 89272 B9272 89272 89272 89272 89272 B9272 89272 89272 89272 90037 93154 93164 93164 93154 93164 84E134 B60BOA RO. 83-017 93154
DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC HOM OTA DTA OTA DSC
Dow ConfklantM
REACTIVITY
NO EXO TO 250 C NO EXO TO 250 C EXO AT 130 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C EXO AT 34 C EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 285 C NO EXO TO 360 C NO EXO TO 400 C NO EXO AT 22 C NO EXO TO 320 C NO EXO TO 250 C NO EXO AT 22 C EXO AT 339 C NO EXO TO 320 C EXO AT 117 C NO EXO TO 350 C NO EXO TO 330 C NO EXO TO 340 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 276 C EXOAT 185 C EXO AT 76 C EXO AT 125 C NO EXO TO 326 C NO EXO TO 350 C EXO AT 280 C NO EXO TO 325 C NO EXO TO 290 C NO EXO TO 350 C NO EXO TO 326 C NO EXO TO 326 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 326 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 276 C NO EXO TO 150 C NO EXO TO 300 C
PROCESS CHEMICAL
WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATEFVSTEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM
ZEROL 300 OIL
TABLE 1. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICALI
SEALANT
PLANT
REF. NO.
TEST
TEAM LEAK REPAIRS SEALANT fIBX TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT *2X TEAM LEAK REPAIRS SEALANT #8 TEAM LEAK REPAIRS SEALANT #8 TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT PRM02C TEAM LEAK REPAIRS SEALANT SW TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK EPX THOHTEX CERAMI-TECH F.G. CURED SEALANT THORTEX CERAMI-TECH E.G. CURED SEALANT WHITE BAKERSEAL SEALANT
VINYL 2 VINYL 2 VINYL 2 GLYCOL 1 VINYL 2 GLYCOL 1 CAUSTIC GLYCOL 1 LGTI VINYL 2 VINYL 1 DOWANOLS POWER 2 LHC 2 LHC 2 LHC 3
93154 93154 93154 90041 93154 RCL-90-2681 671122 91159 930B8 93075 RCL 83-01B 94015 91152 RCL-95-0841 RCL-95-0842 4792-26A
HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC OTA DSC DSC DSC DSC DSC
TEAM LEAK REPAIRS PRH02C (THREADS)
POLYA
91028
DSC
REACTIVITY
NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 335 C NO EXO AT 22 C NO EXO TO 308 C NO EXO TO 295 C NO EXO TO 300 C NO EXO TO 230 C NO EXO TO 275 C NO EXO TO 150 C NO EXO TO 315 C NO EXO TO 350 C NO EXO TO 250 C NO EXO TO 250 C EXO AT 380 C
NO EXO TO 260 C
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Dow Confidential
