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responsibilities of a navigator of a C-123 airplane during herbicide operations in Vietnam; the duties and responsibilities of a targeting officer for herbicide operations in Vietnam; the health experience of persons in Vietnam who used or were otherwise exposed to herbicides containing 2,4,5-T. 23. George C. Kempson. Monsanto's marketing and sale of herbicides containing 2,4,5-T, both to the United States Government and to commercial customers; the health experience of persons who used or were otherwise exposed to herbicides containing 2,4,5-T. 24. Kettering Laboratory. University of Cincinnati Cincinnati, Ohio Work performed for Monsanto by the Kettering Laboratory in the 1950`s regarding the health experience of Monsanto workers exposed to materials formed during a runaway reaction in the manufacture of sodium trichlorophenate at Monsanto's Nitro, West Virginia plant in 1949 and/or to the 2,4,5-T process, including the treatment of affected workers and efforts to determine the toxicity of the materials formed during the runaway reaction and of 2,4,5-T and its process intermediates. 25. Paul Lacey. 117 Rosetta Court Springdale, Ohio The methods and procedures used to aerially disseminate herbicides in Vietnam; the duties and responsibilities of a flight mechanic of a C-123 airplane during herbicide operations in Vietnam; the health experience of persons in Vietnam who used or were otherwise exposed to herbicides containing 2,4,5-T. -7- 26. John S. Leary, Jr. 2002 Sea Cove Court Nassau Bay, Texas Contacts in the 1960's between Monsanto and the United States Government regarding the toxicity of 2,4,5-T. 27. Charles F. Luecke. ^ 12747 Spruce Pond Drive St. Louis, Missouri Monsanto's manufacture, marketing, and sale of herbicides containing 2,4,5-T, both to the United States Government and to commercial customers; the health experience of Monsanto workers involved in the 2.4.5- T process and persons who used or were otherwise exposed to herbicides containing 2,4,5-T; the United States Government's specifications for Agent Orange and Monsanto's compliance with them; the historical knowledge of the toxicity of herbicides containing 2.4.5- T and of the toxicity of dioxin; Monsanto's efforts to identify impurities, including dioxin, created in its manufacture of 2,4,5-T. 28. Charles E. Minarik. P.O. Box 682 W. Harwich, Massachusetts The United States Government's development, testing, and use of Agent Orange; the Government's specifications for Agent Orange. 29. John Mullendore. 1020 Grove Evanston, Illinois Monsanto's manufacture of phenoxy herbicides; contact with the United States Government regarding dioxin. 15315 30. Verne L. Rhodes. 2120 Windport Lane St. Louis, Missouri Monsanto's production of 2,4,5-T in the 1960's; Monsanto's efforts to reduce worker exposure to its 2,4,5-T process; Monsanto's efforts to reduce or to remove dioxin in its 2,4,5-T process. 31. Frank S. Serdy. 13275 Windy Gate Lane Creve Coeur, Missouri The United States Government's field testing of herbicides in Thailand; the health experience of persons who used or were otherwise exposed to herbicides containing 2,4,5-T. 32. Robert G. Sido. 7611 Shirley Drive Clayton, Missouri The United States Government's specifications for Agent Orange and Monsanto's compliance with them; registration of Monsanto products containing 2,4,5-T. 33. Anthony Sinclitico. 7800 William Road Baltimore, Maryland The United States Government's specifications for Agent Orange. 34. Milt Smid. #3 Zinzer Court St. Louis, Missouri The United States Government's specifications for Agent Orange and Monsanto's compliance with them. m ->m K. Smith. Monsanto's contracts with the United States Government for sale of herbicides containing Monsanto-manufactured 2,4,5--T; Monsanto's manufacture and sale of herbicides containing 2,4,5-T. Robert E. Soden. 15998 Kettington Road Clarkson Valley, Missouri y The health experience of Monsanto workers exposed to the 2,4,5-T process in the 1950's; Monsanto's efforts to determine the toxicity of 2,4,5-T and its process intermediates; Monsanto's efforts to reduce worker exposure to the 2,4,5-T process. John R. Spey. 850 Tarpon Drive Fort Walton Beach, Florida rb methods and procedures used to aerially disseminate jicides in Vietnam; the duties and responsibilities af a pilot of a C--123 airplane during herbicide operations in Vietnam; the health experience of oersons in Vietnam who used or were otherwise exposed :o herbicides containing 2,4,5-T. mes E. Springgate. 3060 East Sunset Drive .os Altos Hills, California onsanto's production of 2,4,5-T in the 1960's; onsanto's efforts to reduce worker exposure to its ,4,5-T process; the health experience of Monsanto orkers involved in the 2,4,5-T process. arl Spurrier. adison Building, Suite 301 L55 15th Street N.W. ishington, D.C. le methods and procedures used to apply herbicides ) ining 2,4,5-T for weed control in the United -10- States; the health experience of persons who used or were otherwise exposed to herbicides containing 2 ,4 ,5-T. 40. Jack C. Strum. 712 Short Spoon Circle Rocky Mount, North Carolina ^ Monsanto's production of 2,4,5-T in the 1960's; Monsanto's efforts to reduce worker exposure to its 2,4,5-T process; Monsanto's efforts to reduce or to remove dioxin in its 2,4,5-T process; the health experience of Monsanto workers involved in the 2,4,5-T process. 41. Frank E. Take, Jr. 480 Hillbrook Drive Ballwin, Missouri Monsanto's manufacture of 2,4,5-T at its Nitro, West Virginia plant; the United States Government's specifications and Monsanto's compliance with them; Monsanto's efforts to identify impurities, including dioxin, created in its manufacture of 2,4,5-T; Monsanto's efforts to reduce or remove dioxin in its 2,4,5-T process; the health experience of Monsanto workers involved in the 2,4,5-T process. 42. Wayne E . Vandeventer. The United States Government's specifications for Agent Orange and Monsanto's compliance with them. 43. Richard C. Wallace. P.O. Box 230 St. Albans, West Virginia The health experience of Monsanto workers involved in the 2,4,5-T process. 15318 44. Robert T . Webber. 4 Media Drive St. Louis, Missouri Monsanto's efforts to reduce worker exposure to its 2,4,5--T process. 45. Elmer P. Wheeler. ^ 110 Cool Springs Drive Camden, South Carolina Monsanto's efforts to identify impurities, including dioxin, created in its manufacture of 2,4,5-T; Monsanto's efforts to determine the presence of dioxin in its 2,4,5-T process and to reduce or remove it from that process; the historical knowledge of the toxicity of herbicides containing 2,4,5-T and the toxicity of dioxin; the health experience of Monsanto workers involved in the 2,4,5-T process and of persons who used or were otherwise exposed to herbicides containing 2,4,5-T; contacts with United States Government representatives and others outside Monsanto concerning all of the above. 46. Herbert Woodcock. The methods and procedures used to aerially disseminate herbicides in Vietnam; the duties and responsibilities of a navigator of a C-123 airplane during herbicide operations in Vietnam; the health experience of persons in Vietnam who used or were otherwise exposed to herbicides containing 2,4,5-T. 47. Younger Laboratories. Monsanto's efforts to determine the toxicity of 2,4,5-T and its process intermediates. New York, New York March 26, 1984 TOWNLEY & UPDIKE By: ^.JhfL- d . //. A Member of the Firm ^ Attorneys for Defendant Monsanto Company 405 Lexington Avenue New York, New York 10174 <212) 682.-4567 CERTIFICATE OF SERVICE I HEREBY AFFIRM THAT I am an attorney d,uly admitted to practice in the State of New York and in the Eastern District of New York. I HEREBY CERTIFY that on March 26, 1984 I caused to be served a true and correct copy of the Second List of Monsanto's Fact Witnesses by courier on all counsel on the attached service list. DANIEL COBRINIK 15320 AGENT ORANGE SERVICE LIST Wendell B. Alcorn, Esq. Cadwalader, Wickersham & Taft One Wall Street New York, N.Y. 10005 Leonard L. Rivkin, Esq. Rivkin, Leff, Sherman & Radler 100 Garden City Plaza Garden City, N.Y. 11530 Thomas Beck, Esq. Arthur, Dry & Kalish, P.C. 1230 Avenue of the Americas New York, N.Y. 10020 William Krohley, Esq. Kelley, Drye & Warren 101 Park Avenue New York, N.Y. 10178 Paul V. Esposito, Esq. Lewis, Overbeck & Furman 135 South LaSalle Street Suite 1060 Chicago, Illinois 60603 Morton G. Silberman, Esq. Clark, Gagliardi & Miller The Inns of Court 99 Court Street White Plains, N.Y. 10601 Richard Goldstein, Esq. Shea 'S Gould 330 Madison Avenue New York, N.Y. 10017 Howard Lester, Esq. Lester Schwab Katz & Dwyer 120 Broadway New York, N.Y. 10005 David R. Gross, Esq. Budd, Larner, Kent, Gross, Picillo & Rosenbaum 33 Washington Street Newark, New Jersey 07102 PLAINTIFFS David J. Dean, Esq. Dean, Falanga, Sinrod & Rose 1 Old Country Road Carle Place, N.Y. 11514 Benton Musselwhite, Esq. Law Offices of Benton Musselwhite, Inc. 609 Fannin - Suite 517 Houston, Texas 77002 Thomas Henderson, Esq Baskin & Sears Frick Building - 10th Floor Pittsburgh, Pa. 15219 Victor J. Yannacone, Jr., Esq. Yannacone & Yannacone Post Office Drawer #109 62 Rose Avenue Patchogue, New York 11772 Stephen J. Schlegel, Esq. Schlegel & Trafelet, Ltd. One North LaSalle Street Suite 3900 Chicago, Illinois 60602 Irving Like, Esq. Reilly, Like & Schneider 200 West Main Street Babylon, New York 11700 15321 GOVERNMENT COUNSEL Arvin Maskin, Esq. Department of Justice Safeway Building - R o o m 904 D 52112th Street, N .W . Washington;;D.C. 20530 Hon. Raymond J. Dearie United States Attorney By: L. Kevin Sheridan' Executive Assistant U.S. Attorney U.S. District Court Brooklyn, New York 11201 OTHERS Sol Schreiber, Esq. Special Master ' Milberg, Weiss, Bershad, Specthrie & Lerach One Penn Plaza Suite 4915 New York, N.Y.' 10119 / Clerk of Panel Judicial Panel on Multidistrict Litigation 1120 Vermont Avenue, N.W. Suite 1002 Washington, D.C. 20005 :,:nr' . ..r ; Hon. Shira Scheindlin Magistrate U.S. Courthouse 225 Cadman Plaza East Brooklyn, N.Y. 11201 Agent Orange Plaintiffs.' Management Committee f.-..'; 26 Court Street, Room 905 Brooklyn, New York 11242 153o 9 -2- 1 UNITED STATES DISTRICT COURT EASTERN DISTRICT OF NEW YORK -------------------------------------------------------------------- X In Re "AGENT ORANGE" PRODUCT LIABILITY LITIGATION -X MDL NO. 381 3 s ^'! " A.fc? DEFENDANTS LIST OF FACT WITNESSES SUBMITTED PURSUANT TO THE SCHEDULING ORDER FOR THE COMPLETION OF DISCOVERY BUDD, LARNER, KENT, GROSS, PICILLO & ROSENBAUM, P.C. 33 Washington Street Newark, New Jersey 07102 (201) 622-7400 15323 UNITED STATES DISTRICT COURT EASTERN DISTRICT OF NEW YORK ------------------------------------------------------------------- X In Re "AGENT ORANGE" PRODUCT LIABILITY LITIGATION X MDL NO. 381 / DEFENDANTS LIST OF FACT WITNESSES SUBMITTED PURSUANT TO THE SCHEDULING ORDER FOR THE COMPLETION OF DISCOVERY BUDD, LARNER, KENT, GROSS, PICILLO & ROSENBAUM, P.C. 33 Washington Street Newark, New Jersey 07102 (201) 622-7400 DEFENDANTS LIST OF FACT WITNESSES SUBMITTED PURSUANT TO THE SCHEDULING ORDER FOR THE COMPLETION OF DISCOVERY On behalf of all defendants, and pursuant to the Scheduling Order For The Completion Of Discovery dated January 10, '1984, counsel for Thompson Chemical Company hereby submits the following list o f potential witnesses to be called at trial, attached hereto as Schedule A. These witnesses shall be called to testify as to the issue of the government contract defense. Furthermore, attached hereto as Schedule B, defendants hereby submit a list of witnesses presently scheduled to be deposed at a future date. Therefore, defendants reserve the right, after these witnesses are deposed to determine whether or not these individuals shall be called upon at trial. Each individual defendant also reserves the right to submit an additional list of witnesses on their own behalf which they may choose to call upon to testify. Dated February 29, 1984 Respectfully submitted, BUDD, LARNER, KENT, GROSS, PICILLO & ROSENBAUM, P.C. Newark, New Jersey 07102 (201)622-7400 Attorneys for Defendant Thompson Chemical Company RIVKIN, LEFF, SHERMAN & RADLER 100 Garden City Plaza Garden City, New York 11530 Attorneys for Defendant The Dow Chemical Company & --V ^ " cc: Service List TOWNLEY & UPDIKE.. 405 Lexington Avenue New York, New York 10174 (212)682-4567 Attorneys for Defendant Monsanto Company ARTHUR, DRY & KALISH, P.C. 1230 Avenue of tlie Americas New York, New York 10020 (212) 841-9300 Attorneys for Defendant Uniroyal, Incorporated KELLEY, DRYE & WARREN 101 Park Avenue New York, New York 10178 (212)808-7800 Attorneys for Defendant Hercules Incorporated SHEA <5c GOULD 330 Madison Avenue. New York, New York 10017 Attorneys for Defendant Uniroyal, Incorporated CLARK, GAGLIARDI & MILLER 99 Court Street White Plains, New York 10601 (914) 946-8900 Attorneys for Defendant T H Agriculture & Nutrition Company, Inc. 15326 * -S-c-h-e-d-u-l-e--A Andrew W. Anderson 1311 Thomas Run Road Belaire, Maryland 21014 Gordon A. Anderson 102 Hickory Lane Naugatuck, Connecticut Robert J. Anderson 3624 North 36th Road Arlington, Virginia 22207 Robert L. Andreoli 25 Eighth Avenue Iron River, Michigan John Angel Box 78 Yellville, Arkansas Kenneth Arndt, M.D. 330 Brookline Avenue Boston, Massachusetts Louis B. Arnoldi 512 North Overlook Drive Alexandria, Virginia John C. Atkinson 1222 Merchant Lane McLean, Virginia 22101 Dr. Joseph D. Avellino 2219 South Broad Street Philadelphia, Pennsylvania 19148 Carl Gwin Baker 19408 Charline Manor Road 0 lney, Maryland John D. Baldeschwieler 619 South Hill Avenue Pasadena, California William F. Barthel Route 2 Mount Vernon, Iowa Richard R. Bates 2810 Pheasant Lane Clarksburg, Maryland Frank L . Bauer 600 Grant Street Pittsburgh, Pennsylvania / Russell H. Betts Weldon Bills Peter S. Bing, M.D. 7900 W. Pico Boulevard Los Angeles, California Donald J. Birmingham 19811 Wedgewood Drive Gross Point Woods, Michigan Warren R. Bontoyan 3910 Meeting House Road Perry Hall, Maryland 21228 Rodney William Bovey Dept, of Range Science Texas A&M University College Station, Texas 77343 Lester Boyer Edgewood Church Road Frederick, Maryland Harold Brown 101530 Third Street, N.W. Washington, D. C. Major William Andrew Buckingham,Jr. Department of Political Science U. S. Air Force Academy Colorado At the present time, addresses on these witnesses are unavailable; however, they will be supplied as soon as possible. 15327 Schedule A - Page 2 John L. Buckley P. 0. Box 263 Whitnes Point, New York George W. Connell Route 2, Box 626 Warrenton, Virginia Levi T . Burcham Katherine D. Courtney, Ph.D. 4701 Crestwood Way Sacramento, California Environmental Biology Division EPA Environmental Research Center Research Triangle Park, N.C. 27711 Dr. Edward James Burger, Jr. 2233 Wisconsin Avenue, Suite 324 Nicholas H. Cox Washington, D. C. 20007 2516 East Cass St. Joliet, Illinois Jack E. Burton 204 Vivian Lane Robert E . Cox San Antonio, Texas 203 East Belerest Rd. Bel Air, Maryland Charles E. Bushey 374 South Peoria Circle William J. Crawford Aurora, Colorado 80012 524 Margaret Dr. Fairborn, Ohio Dohrman H. Byers 12060 Lawnview Avenue William MUrlin Creasy Cincinnati, Ohio 3910 Molly Rd. Pine Bluff, Arkansas 71603 Theodore Carroll Byerly 6J Ridge Road . Greenbelt, Maryland Eugene Cutright 1474 Maplewood Dr. Macon, Georgia 31210 John F. Callahan, Sr. 2612 Green Road Baldwin, Maryland Roswell G. Daniels 226 West Edgewood St. Morton, Illinois 61550 David M. Cawthorne P. 0. Box 293 Forest Hill, Maryland Robert A. Ddrrow 7613 Baltimore-National Pike Milton K. Christensen Frederick, Maryland 21701 1089 Clubhouse Boulevard New Smyrna Beach, Florida Thomas R. Dashiell 304 Thomas Ave. Frederick, Maryland 21701 Joseph F. Coates 3738 Kanawaha St., N.W. Delmore, BG Fred J. Washington, D.C. 1600 S. Eads Arlington, Va. *George Xollins Joseph Amadeo DiPaolo 6605 Melody Lane Bethesda, Maryland 20034 *At the present time, addresses on these witnesses are unavailable; however, they will be supplied as soon, as possible. 15328 Schedule A - Page 3 William W. Dorrell 8600 Pine Cliff Drive Frederick, Maryland *Dr. Hans Falk Paul Doty 4 Kirkland Place Cambridge, Mass. William A. Fenner 2713 Roffin Road Hopewell, Virginia 23860 . Francis Gene Douglas 3101 South 54th St. Kansas City, Kansas Henry N. Doyla 5303 Augusta St. Bethesda, MD. Lee A. DuBridge 1730 Hornet Rd. Pasadena, California Robert H. Duguid 107 South Lyndbrook Rd. Bel Air, Maryland Sigmund R. Eckhaus 4208 Colonial Rd. Pikesville, Maryland Fred I. Edwards 5206 Worthington Drive Bethesda, Maryland David Firestone HFF 426 200 C. Street S.W. Washington, D.C. 20204 Henry Fischbach. 5627 Bradley Blvd. Alexandria, Virginia Lawrence Fishbein 3203 Misty Lane Littlerock, Arkansas 72207 Oscar G. Fitzhugh 4208 Dresden St. Kensington, Maryland John Stewart Foster 2737 Sinton Place Pepper Pike, 44124 *John Frawley Dr. Kenneth Endicott . 11317 Broad Green Drive Potomac, Maryland Herbert G. Fredericks 2414 Diana Road William B. Ennis, Jr. Baltimore, Maryland 1131 S.W. 74 Terrace Plantation, Fla. 33317 Seymour L. Friess 6522 Lone Oak Court Graydon Casper Essman Bethesda, Maryland 11 Holcomb Drive Williamsburg, Virginia Verne C. Fryklund, Jr. 6805 Broyhill St. Donald W. Falconer McLean, Virginia 22101 115 Kline Blvd. Frederick, Maryland 21701* Donald W.. Fuhlhage Rural Route 1 Tonganoxie, Kansas * At the present time, addresses on these witnesses are unavailable; however, they will be supplied as soon as possible. 22 Schedule A - Page 4 James Gardner 1616 Arlington Drive Salt Lake City, Utah 84103 Benjamin Harris 11323 Glenarm Road Glenarm, Maryland Major Robert M. Gastineau, M.D. 2381 Rexford Drive Pittsburgh, Pennsylvania 15241 E. Ross Hart 1160 Chain Bridge Road McLean, Virginia 22101 .*Perry Gehring Wayland J. Hayes 2317 (Sold Club Lane Nashville, Tennesse John H. Gerety, Jr. North Entrance Friendhsip Inn P.O. Box 1885 Klamath Falls, Oregon *Thomas Gervason Harry W. Hays 3900 Watson Place, N.W.., Apt. 2G Building A Washington, D.C. 20016 Albert E. Hayward. 5716 Jefferson Blvd. Braddock Heights, Maryland 21714 William Godel 711 Ledo Park Dr. Newport Beach, Ca. 92660* *John Gordon Robert J. Heaston 8231 Stonewall Drive Vienna,Virginia 22180 James A. Hebbeler 821 Park Court Palm Harbor, Florida Nathan Gordon 4990 Sentinel Drive Apartment 301 Bethesda, Maryland 20816 Dr. Herschel E. Griffin 11274 Pabelln Court San Diego, California 92124 *David Henry Groth *Harry Heimann Brunildo Antonio Herrero 616 Lake Hollingsworth Drive Lakeland, Florida Garnett Higginbotham Division of Food and Color Additive FDA 200 C Street, S.W. Washington, D.C. 20204 General Paul Donai Harkins 65104 Northport Drive Dallas, Texas 75230 Donald F. Hornig 16 Longfellow Park Cambridge, Mass. *At the present time, addresses on these witnesses, are unavailable; however, they will be supplied as soon as possible. 15330 Schedule A - Page 5 Richard G . Horton 208 East Ring Factory Road Bel Air, Maryland 21014 Philip Charles Kearney Building 050 BARC-West Beltsville, Maryland William Horwitz 9830 Cherry Tree Lane Silver Spring, Maryland 20901 Surgeon M. Keeny, Jr. 3600 Albermarle St., N.W., Washington, D.C. Riley D. Housewright 147 Fairview Avenue Frederick, Maryland Dr. Marcus M. Key University of Texas Health Science Center, at Houston Harry Otto Huss Route 1 Box 352 P.O. Box 20186 Houston, Texas 77025 Uhrichsville, Ohio' 44683 Dr. Henry A. Kissinger 435 East 52nd St. Kent R. Irish New York, New York 1604 Rock Creek Drive Frederick, Maryland Michael Klein 1800 South East St. Lucie Blvd. Keith H. Jacobson Building 10-306 740 Beall Avenue Stuart, Florida Rockville, Maryland Dyton L. Klingman Dr. Bernard J. Jandorf 2028 Forest Hill Drive 6017 Baywood Avenue Silver Spring, Maryland 20903 Baltimore, Maryland 21209 Albert Christian Kolbye Marc Jeffries '4802 Fort Summer Drive 2108 Hyden Ct. Bethesda, Maryland Fallston, Maryland 21067 Wesley Rudolph Koster Dr. William Jurgelski 105 Northlake Dr., Apt. 215A Office of Health Hazard Assessment Orange City, Florida 32763 National Institute of Environmental Health Science William George Kratz Research Triangle Park, N.C. 27709 985 North Capitol Many, Louisiana 71449 *Abram Saul Kaplan George M. Lawton 1388 Almond Ave. Livermore, California Ronald Joseph Kassel 222 East Belcrest Road Bel Air, Maryland * At the present time, addresses on these witnesses are unavailable; however, they will be supplied as soon as possible. Schedule A - Page 6 John S'. Leary, Jr. 2002 Sea Cove Court Nassau Bay, Texas Douglas H.K. Lee 421 Wood Duck Drive Sarasota, Florida Jane Lewis 5125 Temple Hills Road Temple Hills, Maryland 20748 Dr. Douglas Lindsey 1501 North Campbell St. Tuscon, Arizona Gordon J. MacDonald 20 Occom Ridge Hanover, New Hampshire Harold Noble MacFarland 2320 Harrah Manner Drive Pittsburgh, Pennsylvania 15238 Dr. Arthur H. McCreesh 1317 Saratoga Drive Bel Air, Maryland 21014 Harold Joseph Magnuson, M.D. 12305 Fernando Drive San Diego, California 92128 Walter W. Melvin 413 Bobolink Court Fort Collins, Colorado 80526 Edward A. Metcalf 906 Wellington Rd. Baltimore, Maryland 21212 Lester L. Miller 437 Blueridge Drive York, Pennsylvania Charles E. Minarik P .0. Box 682 West Harwich, Mass. Ian Alastair Mitchell, M.D. 110 Parmele Blvd. ^ Wrightsville Beach, N.C. Francis W. Morthland 5602 Garrett Rd. Durham, North Carolina Donald W.. Norberg 9153 East Stanford Ave. Englewood, Colorado 80111 Dr. Harold T. Magnuson 12305 Fernando Drive San Diego, Cal. 92128 Dr. Arthur H. McCreesh 1317 Saratoga Drive Bel Air, Maryland 21014 William D. McElroy 9651 Black Gold Road LaJolla, Cal. 92037 Robert S . McNamara 2419 Tracy Place Washington, D.C. Vincent McRae 12000 Old Georgetown Rd. Rockville, Maryland John F . O 'Leary Route 1, Box 213 Queenstown, Maryland 21658 Peter G. Olenchuk 6801 Baron Rd. McLean, Virginia 22101 Normand E. Olivier 31 Mosher St. South Dartmouth, Mass. Boris J. Osheroff 13102 Camellia Drive Silver Spring, Maryland 20906 15332 Schedule A - Page 7 Arthur Joseph Pallotta 601 Abbott Lane Falls Church, Virginia Maj. Gen. Jacquard H. Rothschild 2323 N. Central Ave. Phoenix, Az. 85004 Laverne A. Parks 322 E. Garden Green Port Hueneme, Cal. 93041 Dr. Jack Phillip Ruina 28 Hawthorne St. Cambridge, Mass. 02138 *Vernon Perone Umberto Saffiotti 5114 Wissioming Road Bethesda, Maryland Lawrence M. Petrucelli 5600 Cedar Parkway Chevy Chase, Maryland Samuel Sass 17 North Read Street Bel Air, Maryland 21014 Alan P. Poland 2918 Nottingham Way Madison, Wisconsin Paul Aaron Possick 46 Winding Way Woodcliff Lake, N.J. Melvin M. Rabstein 4401 Gulf of Mexico Drive Long Boat Key, Florida Eberhardt Rechtin 1665 Cataluria Palos Verdes Estates, Cal. Kennard A. Reynard 2496 Cedarwood Drive Adrian, Michigan Bernard Schwetz 1101 30th Street, N.W. Suite 205 Washington, D.C. 20007 Robert A. Shade 199 Rooster Drive Eagle, Indiana Warren C. Shaw 1907 Edgewater Parkway Silver Springs, Maryland Carleton G. Shead 1406 Flying W.. Trail Helotes, Texas 78023 *John R. Shoemaker Merl Ringenberg 612 Rock Spring Road Bel Air, Maryland Ralph T. Ross Room 330A Administration Building U.S. Department of Agriculture Washington, D.C. Seymour D. Silver 2920 Strathmore AVe. Baltimore, Maryland Dr. Van Murray Sim 1615 Toll Gate Road Bel Air, Maryland *At the present time, addresses on these witnesses are unavailable; however, they will be supplied as soon as possible. Schedule A - Page 8 Dr. Thomas C. Simmons 2706 Bynum Hill Circle Bel Air, Maryland Charles H. Townes 1988 San AnLonio Ave. Berkeley, California ^ Anthony N. Sinclitico 1800 Willann Road Baltimore, Maryland 21237 John L. Traub 610 West Baker Ave. Abingdon, Maryland Marshall Steinberg 927 Jaysmith Street Great Falls, Virginia Thomas A. Treglia / Dr. Jesse L. Steinfeld John Wilder Tukey 115 Arreton Rd. Princeton, N.J. *Herbert E. Stokinger William Martin Upholt 525 East Indian Drive Silver Springs, Maryland William W.. Stone 434 Sanahelena Drive Solana Beach, California Cyrus Robert Vance One Battery Park Plaza New York City Marshall Stubbs 2001 Columbia Turnpike Arlington, Virginia Wayne E. Vandeventer Walter Edward Sultan Filiberto Vargas 1203 Springwoods Terrace 6165 East I Lift Ave. Fallston, Maryland 21047 Apartment 308 B Denver, Colorado 80222 William H. Summerson 5108 Brittany Drive South Henry L. Verhulst Stu Petersburg, Florida 5917 Walton Rd. Bethesda, Maryland Steve S. Szabo 20 Milrose Lane Frank J. Vocci Monsey, New York 6009 Winthrope Ave. Baltimore, Maryland 21206 General Maxwell D. Taylor 2500 Massachusetts Ave. N.W. Dorothy M. Ward Washington, D.C.* 345 Homeland South Way Baltimore, Maryland 21212 *At the present time, addresses these witnesses, are unavailable however, they will be supiplied as soon as possible. Schedule A - Page 9 Paul C . Warnke Cummings, Burlington, Rubier, Acheson & Shaw Washington, D.C. John T. Weimer 1500 South View Rd. Bel Air, Maryland 21014 Frank H. Westheimer 3 Berkeley St. Cambridge, Mass. 02138 William Childs Westmoreland Box 1059 Charleston, S.C. 29402 Jerome B. Wiesner 61 Shattuck Rd. Watertown, Mass. Jerome Wilkenfeld 5757 Owensmouth Ave. Woodland Hills, California Donald Whittam 10308 Brookmoor Drive Silver Spring, Maryland 20901 James H. Wills 9706 Bellevue Dr. Bethesda, Maryland Herbert F. York 6110 Camino De LaCosta LaJolla, California Dr. Mitchell Zavon Occidental Chemical Corp. P.O. Box 728 Niagara Falls, New York 14302 Walter Leo Zielinski, Jr. 12705 Ddrnestown Rd. Gaithersburgh, Maryland 20878 SCHEDULE B DEPOSITIONS SCHEDULED AFTER FEBRUARY 29, 19-84 1. Donald Barnes 2. General Stanzwick Hay 3. Julius Johnson 4. Harold Kinney 5. Dbdas Mukerjee 6. Elmer Wheeler / UNITED STATES DISTRICT COURT EASTERN DISTRICT OF NEW YORK In Re "AGENT ORANGE" PRODUCT LIABILITY LITIGATION MDL NO. 381 DEFENDANTS LIST OF FACT WITNESSES SUBMITTED PURSUANT TO THE SCHEDULING ORDER FOR THE COMPLETION OF DISCOERY BUDD, LARNER, KENT, GROSS, PICILLO & ROSENBAUM, P.C. 33 Washington Streert Newark, New Jersey 07102 (201)622-7400 Attorneys for Defendant Thompson Chemical Company CO eo io UNITED STATES DISTRICT COURT EASTERN DISTRICT OF NEW YORK In re "AGENT ORANGE" Product Liability Litigation DEFENDANT DIAMOND SHAMROCK CHEMICALS COMPANY'S PRELIMINARY LISTING OF FACT WITNESSES___ Pursuant to the Special Master's Final Amended Recommended Scheduling Order, approved by the Court on January 10, 1984, defendant Diamond Shamrock Chemicals Company ("Diamond Shamrock") sets forth below its preliminary listing of fact witnesses who may give live testimony at trial in support of Diamond Shamrock's claims and defenses. This listing does not address deposition testimony that may be used at trial, which will be identified as part of preparation of the pretrial order. In accordance with the Scheduling Order and the Magistrate's Pretrial Order No. 9, Diamond Shamrock reserves the right to supplement and amend this preliminary listing. Name and Present Address Warren C. Shaw 1907 Edgewater Parkway Silver Spring, Maryland Description of General Nature of Testimony___ Testimony concerning DSDA regulation of 2,4,5-T under FI FRA in 19 5 0's and 196 0's, a n d U.SDA research and investigation con cerning health effects and efficacy of 2,4,5-T. F. Gordon Steward Diamond Shamrock Agricul tural Chemicals Inc. P.O. Box H Tuscaloosa, Alabama 35404 / Testimony concerning manufacturing operations at Diamond Shamrock's former Newark plant, including: the development, installation and operation of a method for removing dioxin from trichlorophenol; the O.S. Public Health Service study of the Newark workers in 1968-69? and the production and shipment of Agent Orange pursuant to contracts with the United States. Dated: New York, New York February 29, 1984 Respectfully submitted, CADWALADER, WICKERSHAM & TAFT Byl/Qjt/lnr/U/tl QA A Member of the Firm Attorneys for Defendant Diamond Shamrock Chemicals Company One Wall Street New York, New York 10005 (212) 908-7000 -3- AFFIDAVIT OF SERVICE STATE OF NEW YORK ) ss. : COUNTY OF NEW YORK ) MICHAEL M. GORDON, being duly sworn, deposes and says: 1. I am not a party to this action, am over 18 years of age and reside in New York County, ^New York. 3. On February 29, 1984, I served the annexed Defen dant Diamond Shamrock Chemicals Company's Preliminary Listing of Fact Witnesses on each of the persons named on the annexed list by depositing a true copy of same enclosed in a postpaid properly addressed wrapper, in an official depository under the exclusive care and custody of the United States Postal Service within the State of New York. The copy to David J. Dean, Esq. was sent by Federal Express. A copy was also sent by Federal Express to the Agent Orange Plaintiffs' Management Committee, 26 Court Street, Suite 905, Brooklyn, New York. Sworn to before me this i f day of February, 1984 C o m m o n Exp,TM service list tor defendants Leonard L. Rivkin Rivkin, teff, S h a m a n t Radiar (for DOW CHEMICAL) 100 Cardan City Plaza Cardan City, Maw York 11530 Morton C. Silbaraan Clark, Gagliardi & Millar (for T B AGRICULTURE & NUTRITION COMPANY, INC.) Tha Inna of Court 99 Court Straat Whita Plains, Naw York 10601 John C. Sabatta Tovnlty 6 Updika (for MONSANTO) 405 Laxington Avanua Naw York, Naw York 10174 William Krohlay Kelley Drya a Warren (for HERCULES, INC.) 101 Park Avanua Naw York, Naw York 10178 John M. Fitzpatrick Dilworth, Paxson, Kalish a L e w (for HOOKER PLASTICS a CHEMICALS CORP.) 2600 Tha Fidelity Building Philadelphia, Pennsylvania 19109 Richard Goldstein Shea t Gould 330 Madison Avanua New York, Naw York 10017 Thomas Back Arthur, Dry 6 Kalish, P.C. (for UNIROYAL) 1230 Avenus of the Americas Naw York, New Yosk 10020 David R. Gross Budd, L a m e r , Kant, Gross, Picillo 6 Rosenbaum (for THOMPSON CHEMICALS) 33 Washington Straat Newark, New Jersey 07102 Arvin Haskin Department of Justice (for THIRD PARTY DEFENDANT USA) Safeway Building 521 12th Straat, M.W. Washington, D.C. 20530 L. Ravin Sheridan Executive Assistant U.S. Attorney Eastern District of New York United States Courthouse 225 Cadman Plaza East Brooklyn, Naw York 11201 COPIES OF ALL DOCUMENTS MUST BE SENT TO:__________________ Clark of the Panai Judieial Panel on Multidistrict Litigation 1120 Vermont Avanua, M.N. Suite 1002 Washington, D.C. 20005 FOR PLAINTIFFS Victor J. Tannacene, Jr. Yannaeona 6 Yannacone Post Office Drawer <109 Patchogue, Naw York 11772 Stephan J. Sehlagal Schlagal a Trafelet, Ltd. One North LaSalle Straat Suite 3900 Chicago, Illinois 60602 Benton Musselwhite Law Offices of Benton Musselwhite, Inc. Suita 517 609 Fannin Houston, Texas 77002 Thomas Henderson Baskin 6 Sears Frick Building - 10th Floor Pittsburgh, Pennsylvsnia 15219 David J. Dean, Esq. Dean, Falanga 6 Rose 1 Old Country Road Carle Place, New.York 11514' UNITED STATES DISTRICT COURT EASTERN DISTRICT OF NEW YORK ---------------X In Re "AGENT ORANGE" Product Liability Litigation _ _ _ _ _ _ _ _ _ _ _ _ ____X MDL No. 381 (All Cases) PLAINTIFFS' PRE-TRIAL ORDER APRIL 11, 1984 PLAINTIFFS' MANAGEMENT COMMITTEE Stephen J. Schlegel, Esq. Schlegel & Trafelet, Ltd. One North LaSalle Street Suite 3900 Chicago, Illinois 60602 Thomas W. Henderson, Esq. Henderson & Goldberg, P.C. Frick Building, Suite 1612 Pittsburgh, Pennsylvania 15219 Benton Musslewhite, Esq. Suite 517 - 609 Fannin Houston, Texas 77002 Phillip E. Brown, Esq. Hoberg, Finger, Brown, Cox & Molligan 703 Market Street, 18th Floor San Francisco, California 94103 Stanley Chesley, Esq. Phil Allen, Esq. Waite, Schneider, Bayless & Chesley 1513 Central Trust Tower Cincinnati, Ohio 45202 David Dean, Esq. Dean, Falanga & Rose One Old Country Road Carle Place, New York 11514 a John O'Quinn, Esq. O'Quinn, Hagans & Wettraan 3200 Texas Commerce Tower Houston, Texas 77002 Gene Locks, Esq. & Neal R. Peterson, Esq. Greitzer & Locks 1500 Walnut Street, 22nd Floor Philadelphia, Pennsylvania 19102 Newton B. Schwartz, P.C. Houston Bar Center Building 723 Main, Suite 325 Houston, Texas 77002 Irving Like, Chairman, Law Committee Reilly, Like 6c Schneider 200 West Main Street P .0. Box 218 Babylon, New York 11702 Aaron Twerski, Esq. Hofstra University School of Law Hempstead, New York 11550 V. Donald Russo, Esq. 7 Bonnie Drive Northport, New York 11768 Albert J. Fiorella, Esq. 1565 Franklin Avenue Mineola, New York 11501 15344 TABLE OF CONTENTS I. INTRODUCTION......................................... 1 - 1 II. SUPPLEMENTATION OF THE PRE-TRIAL ORDER............. II - 1 III. STIPULATION AS TO ADMITTED FACTS.................. Ill - 1 IV. PLAINTIFFS' EXHIBITS (Per Paragraph IV of Magistrate's Pre-Trial Order No.17).......... ................. IV.A.1 A. Separate document list per Paragraph IV (E) (1) of Pre-Trial Order No. 17...................... IV.A.1 B. Separate Document list per Paragraph IV (E) (2) of Pre-Trial Order No. 17.................... IV.B.1 C. Separate Document list per Paragraph IV (E) (3) of Pre-Trial Order No. 17. ....................... IV.C.1 D. Demonstrative Evidence per Paragraph IV (H) of Pre-Trial Order No. 17. . . .................IV.D.1 V. WITNESS LISTS A. Live Witnesses.......................... .. V.A.1 B. Deposition Witnesses........................ . V.B.1 VI. ISSUES TO BE P R O V E D .............................. VI - 1 With respect to: A. Dow Chemical Company ................................ B. Hercules Incorporated................................ C. Monsanto Chemical Company............................ D. Diamond Shamrock Corporation . . ..................... E. T H Agriculture & Nutrition Company.................. F. Uniroyal, Inc........................................ G. Thompson Chemical Company............................ H. The United States Government ........................ VII. DISPUTED ISSUES OF FACT AND L A W .................. VII - 1 INTRODUCTION Plaintiffs submit this Pre-Trial Order dated April 11, 1984 in response to the Magistrate's Pre-Trial Order No. 17. Wherever possible, plaintiffs have attempted to follow the format set forth in that Pre-Trial Order. The table of contents and numbering of Exhibits attempt to follow the Order as closely as possible. Where "Bates" numbers appeared on the documents produced by the defendants or by the United States Government, or where the defendants or the Government used other designations in identifying the documents produced previously, plaintiffs have designated such documents by those numbers as a "Pretrial Identification Number" or "PIN" number in the text of the exhibit lists comprising portions of this order. Where portions of the Pre-Trial Order are to be completed at later dates pursuant to the terms of Pre-Trial Order No. 17, the plaintiffs have simply made general statements to that effect, so as to allow the format to remain in conformity with the numbering system contained in the Magistrate's Pre-Trial Order. Plaintiffs reserve the right, in view of the Magistrate's congnizance of the fact that discovery is continuing in these causes, to supplement this Pre-Trial Order on the terms set forth in Pre-Trial Order No. 17. The medical records of the individual plaintiffs are not being tendered at this time as exhibits to this Pre-trial Order. Plaintiffs and defendants continue to assemble those records and plaintiffs presume that discussions will take place between counsel for all parties attempting to reach a stipulation regarding a common set of exhibits of that kind. Plaintiffs have not in this submission copied and tendered the I-1 153 voluminous contracts of each defendant relative to the sale of Agenr Orange herbicides to the United States Government. Those contracts are on file with the Clerk of the District Court in the defendants' several responses to Pre-trial Order No. 33. Plaintiffs have likewise not copied the defendants' answers to various interrogatories as exhibits with this submission. They, too, are all on file with the Clerk. Time constraints have made it literally impossible to either review all of the documents produced through the course of discovery or to completely paginate deposition testimony references and plaintiffs respectfully request the opportunity to continue doing so for the purpose of including relevant documents and testimony in their amended submissions to be filed hereafter. I2 II SUPPLEMENTATION OF THE PRE-TRIAL ORDER Pursuant to the terms of the Magistrate's Pre-Trial Order No. 17, specifically paragraph "II" thereof, plaintiffs will supplement their Pre-Trial Order in conformity with those terms from time to time hereafter. II 1 15343 Ill STIPULATION AS TO ADMITTED FACTS In Supplements to this Pre-trial Order, plaintiffs will set forth any stipulations achieved with respect to facts admitted in this litigation. Thus far, no such stipulations have been entered into. III - 1 QA IV. A. Plaintiffs hereby submit the following list of identified Exhibits in response to requirements of Paragraph IV (E) (1) of the Magistrate's Pretrial Order No. 17. Due to the fact that discovery in the form of depositions and document production to date has been so voluminous, plaintiffs believe that they should be allowed to supplement this list at the time that both the amendatory and final form Pretrial Orders are filed without regard to whether or not a specific document has been previously produced. Time constraints imposed in connection with the requirement of filing this Pretrial Order have been such that it has been physically impossible to review every document produced in this litigation despite the fact that plaintiffs' counsel have deployed many of themselves and their assistants on a round-the-clock basis to attempt to compile important documents for the purpose of including them in this list. The voluminous copies of the individual plaintiffs' medical records are purposefully not being submitted at this time. Plaintiffs' and defendants' counsel have been attempting to reconcile and exchange such records in order to be certain that all parties have identical and complete sets of those records. Plaintiffs presume that it would be in all parties' best interests to attempt to stipulate as to a common set of such exhibits. Plaintiffs will attempt to achieve such stipulation prior to the time that the amendment to this Pretrial Order is due. Plaintiffs also have purposefully not recopied each of the government contracts involved in this litigation for the reason that defendants have appended each of the contracts they claim to have fulfilled in each of their responses to Pretrial Order No. 33, all of which such copies are on file with the Clerk of this Court. Plaintiffs intend to rely upon those contracts as filed and further intend to rely upon statements contained in the defendants' filed answers to interrogatories from time to time throughout the course of this trial or of the trial of these IV. A. 1 15350 cases. The plaintiffs' Exhibits are, as follows Exhibit #P0001 PIN # Date Author Addressee Description D0E120911 HELEN KRIZEK JONES, LINN Bibliography - A Technicque for Testing Acnegenic Potency in Rabbits. Exhibit #P0010 PIN # Date Author Addressee Description 120224-26 MARK WILTSE BRYANT, CLYDE memo entitled "tordon Chronology" bearing Dow D o c u m e n t No. 120224. Exhibit #P0011 PIN # Date Author Addressee Description A&G 500206 LABEL LABEL SAMPLE OF COMMERCIAL HERBICIDES LABEL. Exhibit #P0012 PIN # 005867-9 Date Author Addressee Description ELMER P WHEELER MEMO OF ELMER P. WHEELER. Exhibit #P0013 PIN # Date Author Addressee Description Exhibit #P0014 005995 ELMER P WHEELER DUNLAP, W. P. LETTER FROM ELMER P. WHEELER TO W. P. DUNLAP. TIVV. AA. 29 i1 -a PIN # Date Author Addressee Description 006002 R EMMET KELLY MD EAKIN, FRANK LETTER FROM R. EMMET KELLY, M.D. TO FRANK EAKIN, NITRO. Exhibit #P0015 PIN # Date Author Addressee Description D0W1568528 NONE DOW NOONE Handrwitten description Boehringer process redacted. Exhibit #P0016 PIN t Date Author Addressee D0W120791-2 R A HICKMAN BEUTEL, A . P . & OTHERS AT DOW Description MONTHLY MARKETING REPORT Exhibit #P0041 PIN # Date Author Addressee DOW278613 01-Aug V K ROWE MD UNINTELLIGBLE WILLIAMS, G J & SMITH, H L & OTHERS Description Letter denying the causal relationship between an exposed womans illness and her exposure to 245-T. Exhibit #P0042 PIN # Date Author Addressee Description DOW980428-41 04-Apr-40 UNKNOWN UNKNOWN PHENOXY ACETIC ACID This report goes through the different stages on how to make Phenoxy Acetic Acid. Exhibit #P0045 PIN # Date Author Addressee Description DOW0614560 24-Feb-49 UNKNOWN UNKNOWN WARD, JUSTUS C. & USDA WASHINGTON, D.C. Incomplete (p 7) memo re health precautions to be used with 2,4,-D and 2,4,5-T IV. A. 3 - -v- ; f~\ Exhibit #P0047 PIN # Date Author Addressee Description 042221 16-Aug-49 LOUIS SCHWARTZ MD NELSON, DR. CONFIDENTIAL LETTER OF 08-16-49 FROM LOUIS SCHWARTZ M.D. TO DR. NELSON AT MONSANTO. Exhibit #P0054 PIN # Date Author Addressee DOW32707-13 23-Aug-50 VERALD K ROWE AGPROJCOMM. & DOW LYNN, GEORGE E. & IRISH,D.D. Description Results of Toxicological Tests on 2,4,5Trichlorophenoxyacetic Acid reported by V.K. Rowe,"moderate acute oral toxicity"rat most resistant of four species;Material markedly irritating to the eyes";"slightly to moderately irritating to the skin upon prolonged exposure." Exhibit #P0061 PIN # Date Author Addressee Description 006006 0 6 -Oct-52 C 0 KOCH KELLY, DR. MEMO TO DR. KELLY FROM C. 0. KOCH. Exhibit #P0067 PIN * Date Author Addressee Description DOW767092 27-Oct-53 F OYEN BOUNDY, R.H. & DIRECTOR OF RESEARCH GAY, H.H. & ALLINSON, R.L. SUNDERLAND,W.W. & LYNN, GEORGE E. Reply to 060970 letter to R. Maybury re residue methodology re phenoxyacetic acids. Refers to Yip's methodl111extration procedure5ction procedure. Quantitation by GLC. Refers to Pesticide Methodology Manual, Food and Drug Directorate. Also, "Analytical Methods for Pesticide Residues in Foods" Exhibit #P0071 PIN # Date Author Addressee Description DOW874256-7 09-Mar-54 WW SUNDERLAND WHITE, R.O. & PESTICIDES SECTION U.S.D.A. & PLANT PEST CONTROL WASH., D.C. Letter provides revised label copy for IV. A. 4 15353 Kuron to U.S.D.A.; gives information regarding similarities of herbicide to 2,4-D and 2,4,5-T formulations. Exhibit #P0077 PIN # Date Author Addressee Description DOW278614 18-Jul-55 HAROLD H GAY MD ROWE, V K. & CRANDALL, R A SMITH, H L & WILLIAMS, G J UNINTELLIGABLE, MD Letter expanding upon Dr Rowe's letter of 7/12/55 which supports claim that Esteron 245 has not caused injury to man. Exhibit #P0078 PIN # Date Author Addressee Description DOW278609 24-Aug-55 HAROLD GAY MD TAYLOR, HAROLD & SMITH, H L ROWE, V K & YOST JR, F N Letter in which Dow's Medical Director denies causal relation between human illness and 24-D Esteron Weed Spray. Exhibit #P0079 PIN # Date Author Addressee Description DOW645090 26-Aug-55 A WIDIGER CENTRAL RESEARCH & MIDLAND RES.INDEX A. GRISWOLD Sc W.H. WILLIAMS E.C.BRITTON Sc F.N. ALQUIST Letter from E. Wanless, Head, Drug Section, Canadian Department of National Health and Welfare, to H.A. Thomson outlining recommended methodology for detection of unnamed substances in phenoxy herbicides includ ing SUILVEXZ . MENTIONS ENTIONSentions 1 ppm standard. [A Exhibit #P0083 PIN # Date Author Addressee Description 16349 07-Dec-55 R E SODEN DURLAND, DR. J. A. CONFIDENTIAL MEMO FROM R. E. SODEN TO DR. J. A. DURLAND DATED 12-07-55. Exhibit #P0087 PIN # Date Author Addressee DOW782178-98 01-Apr-56 T R TORBLAN MCCOLLISTER D.D. IV. A. 5 - hiir Description results of range finding toxicological test on M-531. the report states the problem, conclusions, hazards, precautions for safe handling and first aid meausres such as ingestion,eye contact, skin contact-irritation, skin absorbption and the forms that go along with these tests. Exhibit #P0088 PIN # Date Author Addressee Description I* I* Mi DOW782202-20 11-Apr-56 MARK A WOLF MCCOLLISTER, D. D. results of range finding toxicological tests on 2-formulations of reddon. this states the problem, conclusions and first air measures for the areas of ingestion, eye contact, skin contact - LrrLtation, skin contact - absorption, and form with f h p r p 1 1 1 t~ f* f r o m I' 11 o f* o n i- i . r1I l U l i l l i l I / I I II I 'I H I*1N / ate Author Addressee Description <I 1II1!iIVII .1 II 1I1 'III eIIIaII>'1nm1i1uJ. :l III'1h' II11 ilIl' I 1!t I h i w ' x i MM I 'I I II 22-Fub-5/ WALTER TRAPP GOERGEN & ROWE, V.K. OTHERS AT DOW Dow Chemical International Ltd. writes letter to Boehringer Sohn thanking it for information re preparation of TCP to avoid chloracne but notes 1955 skin irritation problem Givaudan Corporation, Geneva and New Jersey with cover note distributing to trap from Goergen directing return of information to Lueck. Exhibit #P0099 PIN # Date Author Addressee DOW278591-92 21-Jun-57 V K ROWE PLETCHER St CONNER, D.L. GAY, H.H St ASHWORTH, R.H. IV. A. 6 5: Description The pilot experienced eye, nasal, and throat irritation when applying Esteron 44. This suggests that the operation was being carried out with little regard for safety. Exhibit #P0102 PIN # Date Author Addressee Description DOW767184 06-Aug-57 MARK WOLF BOUNDY, R.H. & MCINTYRE, H.H. LYNN, G.E. & BARRONS, K. MUSSELL, D.R. & SCOLES, G. Mark Wolf of Dow Writes report of Results of Range Finding Toxicological Tests an M-1086 (a 2,4,5T and 2,4-D Alkyl Amine Formulation checked by D.D. McCollister and Distributed to many other at Dow. Shows material in undiluted form is markedly irritating and damaging to the eye, causing marked internal effects, with little healing in 7 days. Chemical workers goggles must be worn where eye contact likely and protective clothing Exhibit #P0107 PIN # Date Author Addressee Description DOW767243 20-Dec-57 K OLSEN MCINTYRE,H.H. & WOLF,MARK A. BIOCHEM RES.LAB. & MCCOLLISTER, D.D. BOUNDY R.H. & LYNN, G.E. Results of Range Finding Toxicological tests on Inverton Brush Killer showing that the undiluted material is severely damaging to the eye, resulting in conjunctivitis with extensive sweg and moderate corneal damage and internam capillary infiltration. Exhibit #P0109 PIN # Date Author Addressee Description DOW728167 14-May-58 MARK WOLF MCCOLLISTER, D.D. & HOYLE, H.R. BIOCHEM RES.LAB. Data Sheet of Properties, Health hazards, and Precautions for Safe Handling of Materials of Veon Brush Killer M-1086; corrosive to metals but apparently safe to man. Exhibit #P0110 PIN # DOW767213 1535 c IV. A. 7 Date Author Addressee Description 21-May-58 K OLSEN COULTER,L.L. & MCCOLLISTER,D.D. BOUNDY, R.H. & MCINTYRE, H.H. PERKINS, R.P. & HART, A. Results of Range Finding Toxicological tests on weed killer formulation M-1094 containing a 2,4,5T ester; the undiluted material is moderately irritating to the eye, with direct contact likely to produce conjunctival swelling and corneal damage Exhibit #P0111 PIN # Date Author Addressee DOW728101 16-Jun-58 MARK WOLF MCCOLLISTER, D.D. & HOYLE, H.R. Description Data Sheet of Properties, Health Hazards, and Precaution for safe Handling of Materials re; Dowanol 97B70 ester of 2,4,5T acetic acid 64.4% Exhibit #P0112 PIN # Date Author Addressee DOW727967 30-J u n - 58 MARK WOLF MCCOLLISTER, D.D. & HOYLE, H. R. Description Data Sheet of Properties, Health Hazards, and Precautions for Safe Handling of Materials; May cause some permanent loss of vision; single prolonged exposure may cause reddening of the skin Exhibit #P0113 PIN # Date Author Addressee Description DOW728103 30-Jun-58 MARK WOLF MCCOLLISTER,D.D. & HOYLE, H.R. BIOCHEM RES.LAB. DATA SHEET OF HEALTH HAZARDS OF REDDON CONCENTRATE Exhibit #P0116 PIN # Date Author Addressee Description DOW123584-95 01-Jan-59 F BAHRBOHM READER'S OF & DEUTSCH, GESUNGH, WES. VOLUME 14 AN ARTICLE ON THE DANGERS INVOLVED IN BEING ASSOCIATED WITH CHLORINATED PHENOLS AND NINETEEN FATAL CASES ARE REPORTED IN THE LITERATURE OF WORKING WITH 15357 IV. A. 8 PENTACHLOROPHENOL AND SODIUM PENTACHLOROPHENOL. A SURVEY WAS ALSO PROVIDED. Exhibit #P0124 PIN # Date Author Addressee Description 005693 16-Jun-59 ELMER P WHEELER WEGER, L. C. LETTER FROM ELMER P. WHEELER TO L. C. WEGER, NITRO, WEST VIRGINIA, DATED 06-16-59 REGARDING THE "CHLORACNE PROBLEM - GERMAN ARTICLE." Exhibit #P0126 PIN # Date Author Addressee Description DOW728049 02-Jul-59 K OLSON OYEN, FRITZ & HOYLE, H.R. BIOCHEM.RES.LAB Data Sheet of Properties, Health Hazards, and Precautions for Safe Handling of Materials re; M-1459 formulation of Dowanol Ester 24D and 2,4,5T Exhibit #P0139 PIN # Date Author Addressee Description DOW1123078 09-Jun-60 CHEMICAL DOW THE LABEL FOR 2,4-DICHL0R0PHEN0XY-ACETIC ACID, BUTYL ESTER FOR MANUFACTURING PURPOSES. CAUTION MAY CAUSE SKIN IRRITATION. Exhibit #P0154 PIN # Date Author Addressee Description DOW1123026 09-Jan-61 CHEMICAL DOW THE DOW CHEMICAL COMPANY LABEL FOR DOW BUTYL 265 A 2,4-D WEED KILLER. FOR CONTROLLING MOST BROAD-LEAVED WEEDS ON FARMS. CONTAINS 3 1/3 LBS PER GALLON OF THE BUTYL ESTERS OF 2,4-D. 2,4-D ACID EQUIVALENT 2 2 / 3 PLBS PER GALLON. Exhibit #P0157 PIN # Date Author Addressee Description DOW1122109-0 22-Sep-61 CHEMICAL DOW THE DOW CHEMICAL COMPANY LABEL FOR TIPPON 2-2 BRUSH AND WEED KILLER. CAUTION: MAY K IV. A. 9 CAUSE SKIN IRRITATION. Exhibit #P0194 PIN # Date Author Addressee Description DOW728053 08-Jan-63 KENNETH OLSON OYEN, FRITZ & HOYLE,H.R. B IOCHEMRESLAB Data sheet of Properties, Health Hazards, and precautions For Safe Handling of Dowanol PIB ester of 2,4,5-T (91%) -relatively no problems noted, except skin irritation, and slight eye irritation Exhibit #P0196 PIN # Date Author Addressee Description D0W816874 15-Jan-63 DEPT OF DOW BIOPRODUCTS TABLE OF CONTENT - CONTAINING TOXICOLOGICAL PROPERTIES OF TORDON AND TOXICOLOGICAL PROPERTIES OF TORDON 101 MIXTURE. A PRIVATE COMMUNICATION NOT FOR PUBLICATION REPRODUCTION, OR GENERAL DISTRIBUTION. Exhibit #P0199 PIN # Date Author Addressee Description DOW650469 01-Feb-63 GEORGE DOWNARD DOW CHEMICAL & FALSEY, BILL U.S.D.A. Notice of Registration under FIFRA issued over sig. of G. Downard, Head of Registration Section, Pesticides Regulation Division re; Esteron 2,4,5-T concentrate on the basis of information "furnished by the registrant"(Dow) Exhibit #P0203 PIN # Date Author Addressee Description D0W816959-60 07-Mar-63 CHEMICAL DOW THE DOW CHEMICAL COMPANY COPY OF A LABEL FOR TORDON 101 MIXTURE WITH USE DIRECTIONS, USE PRECAUTIONS AND WARNING STATED. Exhibit #P0204 PIN # Date Author Addressee Description DOW816955-56 07-Mar-63 CHEMICAL DOW THE DOW CHEMICAL COMPANY LABEL FOR TORDON 101 MIXTURE. THE LABEL CONTAINS USE IV. A. 10 15359 DIRECTIONS, USE PRECAUTIONS, AND WARNING (SEE EXHIBIT 207) Exhibit #P0205 PIN # Date Author Addressee Description D0W818958 12-Mar-63 MARK WOLF MCINTYRE, M. M. SUBJECT: SUGGESTED PRECAUTIONARY LABELING FOR TORDON 101 MIXTURE. STATES WHAT EFFECTS THE CHEMICAL HAS AND WHAT TO DO IF CONTACT OCCURS. THIS IS A SAMPLE LABEL. Exhibit #P0207 PIN # Date Author Addressee Description DOW820879 27-Mar-63 CHEMICAL DOW CONFIDENTIAL: COMPLETE INGREDIENT STATEMENT FOR TORDON 101 MIXTUE M-2439, THIS STATES ACTIVE AND INERT INGREDIENTS AND HOW MUCH OF EACH. Exhibit #P0213 PIN # Date Author Addressee DOW119118-21 19-Apr-63 MARK A WOLF MNNAMARA, BERNARD & LYNN. G. E. Description A TABLE CONTAINING A SUMMARY OF ACUTE ORAL TESTS (BY INTUBATION) ON 2,4-D AND 2,4,5-T AND A NUMBER OF THEIR DERIVATIVES PREPARED BY BIOCHEMICAL RESEARCH LABORATORY. Exhibit #P0215 PIN # Date Author Addressee Description 0402786 22-Apr-63 GEORGE LYNN DELMORE, GEN.FRED & SHAW, DR. WARRENC. U.S. ARMY & U.S.DEPT.DEFENSE U.S.D.A. & ARMY CHEMICAL CENTER LYNN LETTER TO DELMORE RE 24D&245T TOXICITY Exhibit #P0216 PIN # Date Author Addressee D 802819-20 22-Apr-63 G E LYNN DELMORE, GEN. FRED J & SHAW, DR. WARREN C. Description G. E. lynn's letter dated 04-22-63 to Brigadier General Fred J. Delmore. Exhibit #P0220 15360 IV. A. 11 PIN # Date Author Addressee Description DOW650079-83 29-Apr-63 MILT HUNT LYNN, GEORGE & JOHNSON, JULIUS COULTER, L.L. & WOLF, MARK MCINTYRE,H.H. & FALKENSTEIN, W.J. limited release for sales directed to many at Dow relating to Verton CE with Diesel Fuel Oil and with sample label attached refers to meeting customer (AT&T) specifications Exhibit #P0221 PIN # Date Author Addressee DS 17940-41 02-May-63 R J MARRESE CECIL, LARRY & GUIDI, R. A. KING, J. 0. & CHANDLER, E. L. Description diamond alkali co. confidential interoffice correspondence from R. J. Marrese to Larry Cecil dated 05-02-63. Exhibit #P0226 PIN # Date Author Addressee Description DOW650262-70 17-May-63 JULIUS JOHNSON LYNN, GEORGE & BARRON, K.C. WOLF, MARK & MCINTYRE, H.H. FALKENSTEIN, W.J. & COULTER, L.L. limited release to sales of a 2,4,5-T formulation known as Verton T, with notes of Julius Johnson and George Lynn, H.H. McIntyre and others relating to use, labeling, and fact that product had to be registered to be sold to to customers identified and with reference to competing against Amchem for business. Exhibit #P0232 PIN # Date Author Addressee Description DOW820874 12-Jun-63 M W DUNDERLAND DOWNARD, C.M. & LOARY, J. S. LYNN, G. E. LETTER FROM M.W. DUNDERLAND, STAFF ASSISTANT, BIOPRODUCTS DEPARTMENT TO C.M. DOWNARD REGARDING TORDON 10 MIXTURE AND A ADDITIONAL INVESTIGATION OF THE EFFECTS. Exhibit #P0233 PIN # Date Author DOW820866 28-Jun-63 G M DOWNARD IV. A. 12 1536 Addressee Description SUNDERLAND, W. W. LETTER DATED 06-28-63 FROM G. M. DOWNARD HEAD, REGISTRATION SECTION TO MR. W. W. SUNDERLAND OF DOW C CHEMICAL COMPANY. CONTAINING A REGISTRATION NOTICE UNDER THE FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT FOR TORDON 101 MIXTURE. REGISTRATION NUMBER IS 464-306. Exhibit #P0234 PIN # Date Author Addressee Description H 2 8 1 14 03-Jul-63 JOHN FRAWLEY ROWE, V.K. & DUNN, C.L. HUNT, WM.H..PH.D. George Lynn, then Director of Registration, Bioproducts Department of Dow, writes Brig. General Fred J. Delmore, U.S. Army at the request of Dr. Warren C. Shaw of U.S.D.A. and encloses toxicity data re 2,4,5T and 2,4D, stating "We would like to also mention that we have been manufacturing 2,4-D and 2,4,5-T for over ten years and ...to the best of our knowledge, none of the workmen in these factories have shown any ill effects as a result of working with these Exhibit #P0235 PIN # Date Author Addressee H281 14-1 5 03-Jul-63 JOHN P FRAWLEY ROWE, V.K. & HUNT, W. H. Description iohn p. frawley's letter to V. K. rowe of 07-03-63. Exhibit #P0239 PIN # Date Author Addressee Description JUS215 1947 19-Jul-63 ARMY ARMY 1963 MILITARY SPECIFICATIONS. Exhibit #P0240 PIN # Date Author Addressee Description DOW981607 19-Jul-63 ARMY ARMY MILITARY SPECIFICATIONS FOR HERBICIDE N-BUTYL 2,4,5-TRICHLOROPHENOXYACETATE. Exhibit #P0253 PIN # D0W816941 15362- IV. A. 13 Date Author Addressee Description 18-Nov-63 MARK G WILTSE LYNN,G . E. & HAMMER, O.N. RITTY, P. M. & BRYANT, C. A FALSEY, W. P. & OTHERS LETTER DATED 11-18-63 FROM MARK G. WILTSE, MANAGER, TORDON PRODUCT PALNNING TEAM TO G. E. LYNN, BIOPRODUCTS DEPT. REGARDING THE CORRECTION OF TORDON 101 LABEL. Exhibit #P0256 PIN # Date Author Addressee Description DOW820863 04-Dec-63 CHEMICAL DOW CONFIDENTIAL: A LISTING OF INGREDIENTS CONTAINED IN TORDON 101 MIXTURE AND THE AMOUNT OF EACH Exhibit #P0257 PIN # Date Author Addressee Description DOW820861-63 05-Dec-63 N W MCINTYRE MR. GEORGE M BERNARD & BIOPRODUCTS WASHINGTON OFFICE Revisions in labeling due Co new findings regarding puricy of product. Exhibit #P0263 PIN # Date Author Addressee Description DOW820833 13-Jan-64 G M DOWNARD SIDNEY B SACHS U.S. Department of Agriculture is advising Dow Chemical Company that the proposed new labeling is not acceptable due to implied change in weight. Exhibit #P0274 PIN # Date Author Addressee Description DOW620859 09-Mar-64 ILLEGIBLE ILLEGABLE DR/MR LEARY This memorandum is totally illegible. Exhibit #P0293 PIN # Date Author Addressee Description D0W816938 18-May-64 WP FALSEY C .A . HIGHHILL & C. A. BRYANT G.E. LYNN & L.L. COULTER R. C. DOSSER & OTHERS Because there is evidence that there is a large amount of Tordon Acid below the 65% IV. A. 14 15363 purity level, specifications are given on how to blend it with other materials going into Tordon 101 to achieve an AVERAGE of 65% purity. Mention is made that normally, this impure Tordon Acid would not be used. Exhibit #P0308 PIN # Date Author Addressee Description D0W816937 29-Jun-64 MR FALEDY A.L. HOLIDAY & G.E. LYNN J .A. TELLY & D. B. FLETCHER GLENN SHAW Request for written statements on waste disposal and statement that product is not being placed in water, streams, etc. They wish to avoid adverse publicity. Exhibit #P0313 PIN # Date Author Addressee Description A&G85-87DOW 30-Jul-64 RAY HOLMES HOYLE, H.R. 3 page letter giving history of process changes in 199 bldg, by holmes, supervisor of plant, and which documents high production and beginning of outbreak of chloracne in February, 1964 with dated summary of events on last page. Exhibit #P0314 PIN # Date Author Addressee Description DOW 766762-4 30-Jul-64 RAY HOLMES HOYLE, H. R. Ray holmes' letter to H. R. hoyle dated 07-30-64. Exhibit #P0319 PIN # Date Author Addressee Description D0W132506 08-Sep-64 L WESTOVER HOLMES, RAY Westover reports that Lab tests in 5 sample of caustic insoluble oil from TCP process estimates TCDD level at .2% and refers to the presence of other halogenated mamaterials detected as well. Exhibit #P0320 PIN # Date Author Addressee DOW 132506 08-Sep-64 L B WESTOVER HOLMES, R 153 IV. A. 15 Description 09-10-64 westover report to holmes re: results of analysis of dioxin in certain samples. Exhibit #P0323 PIN # Date Author Addressee Description DOW568604-5 15-Sep-64 DR HANS MERTZ DOW CHEMICAL CO. Dr. Mertz related visit of Trapp, Lueck, and Silverstein and encloses confidential paper re isolation of chloracne exciters and production of 2,4,5-T acid dated 12/09/56. Exhibit #P0325 PIN # Date Author Addressee D0W132504-5 05-Oct-64 RAY HOLMES GOERGEN, G.G. & HUTCHENREUTHER,C.0. DYLEWSKI, S.W. & HABERSTR0H, W.H. Description Holmes writes others at Dow re chloracne producing material, and states attempts to reduce the TCDD type materials made in our process have not been encouraging; and "I am not confident that we have done or are doing enough at 199 Bldg, to overcome the chloracne trouble" but "number of people are encouraging me..to continue" at capacity Exhibit #P0326 PIN # Date Author Addressee DOW 132504-5 05-Oct-64 R D HOLMES GOERGEN, G. G. & HUTCHENREYTHER, C DYLEWSKI, S. W. & HABERSTRCH, W. H. Description Ray holmes' letter of 10-05-64 to G. G. Goergen and others. Exhibit #P0331 PIN # Date Author Addressee Description DOW766704-8 20-Nov-64 RAY HOLMES UNKNOWN Ray Homes, Supervisor of 199 bldg.at Dow, writes Report (which has been re-dacted, in pertinent part),re; Hydrolysis of TetraChlorobenzene using Flake Caustic In (redaction);describes differences is pro cess from '46-52 and '55-62 1536 IV. A. 16 Exhibit #P0334 PIN # Date Author Addressee Description D0W119502-3 03-Dec-64 DAVID H GROTH E.T. UPTON Author speculates on root of skin an liver toxicity in 2,4,5-T is due to some by-product. Asks for samples of purest 2,4,5-T and commercial 2,4,5-T and product before the emulsifiers have been added for testing. Exhibit #P0336 PIN # Date Author Addressee Description A&G 500040-1 04-Dec-64 DR DAVID GROTH UPTON, EDWARD T. 12-04-64 LETTER FROM DR. DAVID GROTH TO MR. UPTON. Exhibit #P0338 PIN # Date Author Addressee Description DOW33304-17 08-Dec-64 N E SKELLY BRADLY, K.B. & COULTER, K.E. DELISLE, N.G. & GILL, H.M. GOERGEN, G.G & OTHERS Isolation and Identification of possible Acnegens from the Caustic-Insoluble Portion of the products from the 2,4,5-T Process. Skin sensitivity tests on rabbits have positively shown 2,3,7,-T to be by far the most severe skin irritant among the group of compounds identified. Exhibit #P0339 PIN # Date Author Addressee Description 00000000 11-Dec-64 LINDLEY S DEATLEY DOSSER P C 12- 11-64 LETTER FROM MR. DEATLEY TO DOSSER OF DOW. Exhibit #P0341 PIN # Date Author Addressee Description DOW568606-8 15-Dec-64 DR HANS MERTZ DOW CHEMICAL CO. Same exhibit as 370 except third page attached which shows molecular drawing of TCDD. Exhibit #P0342 PIN # DOW568609-13 153b IV. A. 17 3 Date Author Addressee Description 17-Dec-64 DR HANS MERTZ SILVERSTEIN, LARRY Boehringer informs Silverstein of Dow of rabbit testing data done in 1955 showing death, liver damage, kidney and lung failures. Exhibit #P0343 PIN # Date Author Addressee Description DOW820336 20-Dec-64 NONE NONE General Memorandum regarding materials of 3,5,6-T Chemical Tordon and directions for use. Back panel with caution shown. Exhibit #P0344 PIN # Date Author Addressee Description D0W14050-57 22-Dec-64 HAROLD GILL COULTER,K.E. & GOERGEN, G.G. HOLMES, RAY D. & HOYLE, H.R. KEY, M. & SILVERSTEIN, L. Harold Gill of Dow writes Analytical Method to determine TCDD in caustic insolubles of 2,4,5-TCP process and distributes it to 19 others at Dow Exhibit #P0345 PIN # Date Author Addressee Description DOW 14050-57 22-Dec-64 HAROLD GILLS COULTER, K. L. & YRBLE, R. ERLEY, D. S. & GREENE, L. M. GOARGEN 0. C. & HABERSTRCH, W. H. Harold gill's gas/liquid chromatographic procedure to analyze caustic insoluables for compounds capable of causing chlorance, principally 2,3,7,8-tetrachlorodibenzo-p-dioxin. Exhibit #P0346 PIN # Date Author Addressee Description 00000000 28-Dec-64 LINDLEY S DEATLEY DOSSER, P. C. 12-28-64 LETTER OF DEATLEY TO DOSSER OF DOW. Exhibit #P0351 PIN # Date Author 00000000 12--Gan --65 L S DEATLEY H EC Q ^ ^ lOdt) / IV. A. 18 Addressee THOMPSON, BOB & HOWARD, HAROLD Description 01-12-65 T-H INTEROFFICE MEMO. Exhibit #P0352 PIN # Date Author Addressee Description D0W7 66687-94 12-Jan-65 N POFFENBERGER SAUERS, R. & TRAPP, W.B. POFFENBERGER, N. & WIDIGER, A. LUECK, A & OTHERS This information consists of diagrams and formulas which are difficult to interpret. Exhibit #P0355 PIN # Date Author Addressee Description 00000000 14-Jan-65 EDWIN T UPTON GROTH, DR. DAVID 01-14-65 LETTER FROM MR. UPTON TO DR. GROTH. Exhibit #P0356 PIN # Date Author Addressee Description D O W 1 120903 14-Jan-65 EDWIN T UPTON GROTH, DR. DAVID M. letter dated 01-14-65 from edwin t. upton to Dr. David M. Groth regarding the samples that were requested for the study of the chloracne problem. Exhibit #P0357 PIN # Date Author Addressee Description DOW568569-72 26-Jan-65 WALTER B TRAPP CHAMBERLAIN, L.C. & COULTER, K.E. HABERSTROH, W.H. & GOERGEN, G.G. SAUERS, R.C. Three page summary attached to cover letter admits TCDD chloracne exciter shows conditions which minimize TCDD formation and shows conditions which favor TCDD formation "the disadvantage of the non-aqueous solvent system is . . . which can plug a tube reactor." Exhibit #P0358 PIN # Date Author Addressee Description DOW569137-38 27-Jan-65 WALTER TRAPP DOW CHEMICAL CO. Graphs show Dow discovered increase in production of TCDD at higher temperature; 2nd page initialed A.H.W. and dated January 28, 1964; A.H.W. is Dow's Widiger. Exhibit #P0359 PIN # Date Author Addressee Description DOW568535-7 28-Jan-65 WALTER B TRAPP MERTZ, DR. HANS This letter contains a report of a telephone conversation between four Dow people and Dr. Merz with recitation of questions and answers. Exhibit #P0360 PIN # Date Author Addressee Description D0W1120905 31-Jan-65 DAVID H GROTH KRAUS, GUNTHER E. reports stating people developing chloracne and liver damage from over exposure to 2,4,5t in industry. Exhibit #P0361 PIN # Date Author Addressee Description D0W7 66309-36 03-Feb-65 N POFFENBERGER LUECK.AL & COULTER, K. STAEHLING, E. & TRAPP, WALTER HABERSTROH,W .H . & OTHERS Preliminary process design for the man ufacture of 245-Trichlorophenol using 100% NaOH distributed to manufacturing personnel at Dow, and designed at Dow Exhibit #P0362 PIN # Date Author Addressee Description D0W7 66309-36 03-Feb-65 N POFFENBERGER A process design is presented, that advantage be taken of the high reaction rates. This document goes into detail about various Recycle, Reaction, and Analysis Profiles. Exhibit #P0363 PIN # Date Author Addressee DOW569168-92 03-Feb-65 N POFFENBERGER TRAPP, W. & COULTER, K. LUECK, A. & OTHERS AT DOW Description Poffenberger of Dow prepares and distributed processed design to prepare IV. A. 20 2,4,5-TCP using 100 percent sodium hydroxide. Exhibit #P0364 PIN # Date Author Addressee UNKNOWN 05-Feb-65 KY HANSON SPALDING, J.L. & PATENT DEPARTMENT 566 BUILDING & DOW CHEMICAL Description Letter shows Dow sold surplus 245-T and surplus 2,4-D,to which was added 481,500 pounds iso-butyl ester 2,4,5-T and sold to Army procurement at price of $229,338. in November, 1961; Letter also refers to other sales, and bids and sales of Monsanto, Hercules & Diamond, and royalties due Dow on such sales. Exhibit #P0365 PIN # Date Author Addressee Description DOW569105-12 09-Feb-65 SAME ILLEGIBLE ANDERSON & LUCEK WOLF & WEST TRAPP & OTHERS This document provided by Dow Chemical are the Safety Techniques suggested. Exhibit #P0366 PIN # Date Author Addressee Description 00000000 1O-Feb-65 LINDLEY S DEATLEY WILLIAMS, G. J & GRANT, L .B CORBIN, W. L. & HARRIS, T. W. TUCKER, J. C. & THOMPSOM, R. S. MEMO OF DISCUSSIONS AT DOW CHEMICAL CO. HELD 2/10-11/65, SIGNED BY MR. DEATLEY AND DATED 2-15-65. Exhibit #P0367 PIN # Date Author Addressee Description D0W568549 15-Feb-65 WALTER B TRAPP DOLL, DR. 0. Trapp thanks Boehringer for help, says restriction in communication because of our secrecy agreement and because of this, Koopmann not fully information of seriousness of Dow health problem. Exhibit #P0369 PIN # Date 0000000 17-Feb-65 15379 IV. A. 21 Author EDWIN T UPTON Addressee GROTH, DR. DAVID M Description 02-17-65 LETTER TO MR. UPTON TO DR. GROTH. Exhibit #P0370 PIN # Date Author Addressee Description D0W107810-11 17-Feb-65 FRANK S DAVIS GIBSON, JOHN letter dated 02-17-65 from frank S. davis, research plant physiologist to Mr. John Gibson of dow and a paper on moisture stress based on an article given at WSA (on the Mechanism of inhibition of KAD-linked dehydrogenese Systems by Piclorax. Exhibit #P0371 PIN # Date Author Addressee Description DOW129844-6 22-Feb-65 DONALD PLETCHER ROWE, V.K. & FALSEY, W.P. HOYLE, H.R. & GILL, W.M. SILVERSTEIN, LARRY & LYNN, GEORGE E. minutes of meeting held at Dow among Dow employees; notes Dow knows rabbit ear tests sensitive to 4 ppb and "agreed that Rowe should move ahead with contact with U. S. Public Health Service and Department of Agriculture representatives as soon as our data is better correlated." "contacts to be made with other" manufacturers; "Rowe to serve as Dow contact for any inquiries" Exhibit #P0372 PIN # Date Author Addressee Description DOW 129844-6 22-Feb-65 D E PLETCHER ROWE, V. K. 4 FALSEY, W. P. BARRON, K. C. & CORBIN, W. L HOFF, R. C. & HOYLE, H. R. D. E. pletcher report dated 2-22-65 of the "exciter problem" meeting which took place 2-18-65. Exhibit #P0374 PIN # Date Author Addressee 5972-3 24-Feb-65 EMMET KELLY FILE & MONSANTO Description Emmet Kelly, M.D. of Monsanto writes memo to file of his Telephone conversation with V.K. Rowe of Dow concerning Dow's analysis of Monsanto's 2,4,5-T at 3-10 ppm TCDD; 15371 IV. A. 22 together with customer complaint references and meetings to be held. Exhibit #P0375 PIN # Date Author Addressee Description 005972-3 24-Feb-65 R EMMET KELLY MD MEMO FROM R. EMMET KELLY, M.D. REGARDING HIS DISCUSSIONS WITH V. K. ROWE OF DOW, DATED 02-24-65. Exhibit #P0376 PIN # Date Author Addressee Description MON 005972-3 24-Feb-65 EMMET KELLY FILE DOW HAS 20 CASES OF CHLORACNE. DOW HAS ANALYSES SAMPLES FROM MONSANTO AND FOUND OUR 2,4,5-T AHS 3-10 PPM OF TCDD WHICH KELLY SAYS ROWE IS SURE IS THE CHLORACNE CAUSING AGENT. DOW WILL HAVE MANAGEMENT MEETING TODAY; ROWE WANTS CRASH MEETING WITH ALL PRODUCERS TO REACH A SPEC LEVEL IN ORDER TO ELIMINATE THIS PARTICULAR CONTAMINANT BEFORE THE PUBLIC HEALTH SERVICE GOT INTO THE ACT. Exhibit #P0378 PIN # Date Author Addressee Description 00000000 26-Feb-65 DR DAVID H GROTH UPTON, EDWIN T. 02-26-65 LETTER OF MR. UPTON TO DR. GROTH. Exhibit #P0379 PIN # Date Author Addressee Description DOW 19294-5 0 1 -Mar-65 J D DOEDENS ROWE, V. K. TRICHLOROPHENOL SUMMARY D. DOEDENS OF DOW. DATED 3-1-65, BY J. Exhibit #P0380 PIN # Date Author Addressee DOW19294-5 0 1 -Mar-65 J D DOEDENS ROWE,V .K . 4 UNKNOWN Description J.D. Doedens of Dow writes a very descriptive summary of the trichlorophenol producers, his personal knowledge of toxicology, V.K. Rowe's contacts (and those of others at Dow) with other producers, the 15372 IV. A. 23 scheduled meeting in March, 1965;"most toxic materials known"..."positive action at 40 parts per billion" ..."equivocal results at 4 ppb"..identifies symmetrical dioxin as the agent. Exhibit #P0381 PIN # Date Author Addressee Description DOW569221-33 02-Mar-65 J L CORNELL COULTER, K. E. & DELISLE, N. G. DYLEWSKI, S. W. & GOERGEN, G. G. HUTCHENREYTHER C 0 & OTHERS this contains the following information: authorization request, project schedule projected targets, manpowerprocess review, reactor procurement, plot plan and site, research program and figures. Exhibit #P0382 PIN # Date Author Addressee Description D0W129925 02-Mar-65 V K ROWE BARRONS, K.C. & CORBIN, W.L. HOYLE, H.R. This meeting was called to discuss the disposition of the Monsanto 2,4,5-T which contains from 3 to 7 ppm. Exhibit #P0383 PIN # Date Author Addressee Description DOW569221-33 02-Mar-65 S J HARRIS LUECK, A F & COULTER, K E DELISLE, N G & GOERGEN, G G HUTCHENREUTHER, C 0 & OTHERS This project deals with Authorization Request, Project Schedule - Project Targets, Manpower, Process Review, and Discussion. Questions were raised regarding many "if's" involved with this proj ect. Exhibit #P0385 PIN # Date Author Addressee Description D0W1111-1127 1O-Mar-65 LARRY SILVERSTEIN LYNN, GEORGE it HUTCHENREUTHER GOERGEN & STAEHLING BAILEY & UNIT INDEX Early History of the Chloracne Problem Biochem's Contribution authored by Larry Silverstein of Dow and distributed to other Dow Employee's; Describes at length the 15373 IV. A. 24 chloracne outbreak, the disease,the ident ification of TCDD, liver damage, european experience, rabbit ear testing, german pro blems in '55, and '57 active samples from 199 Bldg, at Dow. Exhibit #P0386 PIN # Date Author Addressee Description D0W129927 10-Mar-65 LARRY SILVERSTEIN ROWE, VERALD K. & LYNN, GEORGE HUTCHENREUTHER,C .0. & GILL, W.M. PLETCHER, DONALD & OTHERSDOWNUMEROUS Memo to 23 Dow employees relating the hazard found in Dow's analyses of lots of Monsanto's 2,4,5-T acid;"Material represents a definite hazards requiring all the precautions used in 199 building.." Exhibit #P0387 PIN # Date Author Addressee Description D0W129927 1O-Mar-65 L G SILVERSTEIN RILEY, P. H. & TUCKER, J.C. SMILEY, R.N. & HARRIS, J. W. GRANT, L.B. & OTHERS Rabbit ear tests on twelve lost of Monsanto 2,4 T acid have shown moderate to severe response in eight to 20 percent concentration in ethanol. This material presents a definite hazard which would require all the precautions used in 199 Bldg and 349 Bldg. Exhibit #P0388 PIN # Date Author Addressee Description DOW172136-37 1O-Mar-65 G SILVERSTEIN RILEY, F.H. & TUCKER, J.C. SMILEY, R.N. & HARRIS, J.W. GRANT, L.B. & OTHERS Rabbit ear tests have shown moderate to severe response in eight cased as 10% concentration in ethanol. This material presents a definite hazard which would require all precautions used in 199 Bldg and 349 Bldg to prevent injury. Shipping this material to Riverdale and Woodbury is a definite risk to their employees, espcially since they are probably unaware of the problem and are probably taking no precautions. Exhibit #P0389 IV. A. 25 PIN # Date Author Addressee DOW569141-42 1O-Mar-65 A H WIDIGER TRAPP & DOW CHEMICAL CO. Description Widiger of Dow prepares graphs showing t ime--temperature, factors in reaction to produce tetrachlorobenzene. Exhibit #P0390 PIN # Date Author Addressee Description DOW 1111-27 11-Mar-65 LARRY SILVERSTEIN "EARLY DOW HISTORY OF THE CHLORACNE PROBLEM--BIOCHEM'S CONTRIBUTION" DATED 03-11-65 OVER INITIALS OF LARRY SILVERSHEIN OF DOW. Exhibit #P0391 PIN # Date Author Addressee Description DOW1111-27 11-Mar-65 LARRY SILVERSTEIN BAILEY & HUTCHENSUTTEN GOERSEN Sc LUCEK OTHER ILLEGIBLE An outbreak of chloracne in the trichlorophenol process has resulted in approximately 40 cases of chlora in Dow people. Chloracne is a skin disorder characterized by the appearence of black heads and small bumps. Exhibit #P0393 PIN # Date Author Addressee Description DOW569239-43 15-Mar-65 R E ANDERSON DELISLE, N. G. Sc COULTER, K. E. WOLF, R. W. & GOERCEN, G. G. LUSCK, A Sc OTHERS this reports states the reason for building a new facility. Exhibit #P0394 PIN # Date Author Addressee Description DOW5 69239-43 15-Mar-65 R E ANDERSON COULTER, K.E. Sc WOLF, R LUSCK, A. & TRAPP, W. OTHERS The major consideration in the design of the new plant is to prevent the production of chloracne compounds but to minimize operator contact with process streams and 15375 IV. A. 26 equipment. Exhibit #P0395 PIN # Date Author Addressee Description DOW569251-4 17-Mar-65 UNKNOWN REA UNKNOWN Dow document, evidently internal, composed by "R.E.A." describing the Trichlorophenol Reactor cycle. Exhibit #P0398 PIN # Date Author Addressee Description DOW569247-50 18-Mar-65 J S HARRIS ANDERSON, R. E & LUECK, A. F. DELISLE, N .G & WEHN, W. E. CORNELL, J. L. & OTHERS discussed were preliminary/drying flow sheets,steel shell and tube phenate colers with temperature controls, etc. Exhibit #P0399 PIN # Date Author Addressee Description DOW569247-50 18-Mar-65 J S HARRIS COULTER, K.E. & GRAVES, H.E. WOLF, R.R. & HABERSTROH, W.H. DYLEWSKI, S.W. & OTHERS The purpose of the meeting was to review the preliminary reactor and neutralization/drying flow sheets. Exhibit #P0400 PIN # Date Author Addressee D0W1 19084-5 19-Mar-65 CH BOEHRINGER SOHN DOW CHEMICAL & BRANCH, C.B.,V.P. Description C.H. Boehringer Sohn of Germany writes Dow letter form agreement calling for the payment by Dow to the German firm for disclosure of processes aimed at the prevention of chloracne arising out of the production of sodium 2,4,5-trichlorophenate; Calls for payment of $35,000 (sic?) (copy if not clear). Exhibit #P0401 PIN # Date Author Addressee 19193-8 19-Mar-65 LARRY SILVERSTEIN ROWE,V.K. & LYNN, GEORGE HUTCHENREUTHER C.O. & WILTSE, MARK IV. A. 27 Description PETERSEN, JACK & OTHERS Larry Silverstein of Dow writes detailed report concerning the discussion held at Dow on 3-24-65 among representatives of Dow, Hooker, Diamond Alkali and Hercules; document references the presentations tha t were made by Dow employees at the meet ing, together with extensive knowledge of the toxic properties of dioxin. Exhibit #P0402 PIN # Date Author Addressee Description 379-80 19-Mar-65 VERALD ROWE KELLY, EMMET, M.D. & WILKENFELD, DR.J. VERHOEZE, RAYMOND & KENNEDY, FRANCIS CHANDLER, ED & FRAWLEY, DR. JOHN P. 3-19-65 letter from V.K. Rowe of Dow to various manufacturer's representatives, describing conversations he has had with them, and setting up meeting to be held 3-24-65 at Dow, Midland, MI. Exhibit #P0403 PIN # Date Author Addressee DOW 119084-5 19-Mar-65 C H BOEHRINGER SOHN BRANCH, C. B. & DOW CHEMICAL CO. Description LETTER FROM AGREEMENT BETWEEN C. H. BOERINGER SOHN AND DOW CHEMICAL COMPANY, DATED 3-19-65. Exhibit #P0404 PIN # Date Author Addressee Description D0W19200-1 19-Mar-65 V K ROWE KELLY, EMMET & WILKENFELD, DR. J VERHOEZE, RAYMOND & KENNEDY, FRANCIS CHANDLER, DR. ED & OTHERS letter inviting each to Midland to dicusss the toxicological problems caused by the presence of certain highly toxic impurities in 2,4,5-t and related materials. Exhibit #P0405 PIN # Date Author Addressee Description DOW568796-7 19-Mar-65 SOHN BOEHRINGER DOW CHEMICAL English translation of an agreement letter. Exhibit #P0415 15377 IV. A. 28 PIN # Date Author Addressee Description DOW 19193-98 29-Mar-65 L Q SILVERSTEIN RILEY, F. H. & SMILEY, R. N. GRANT, L. B. & HUTCHENREUTHER, C.O. AMSTUTZ, F. C. & FALSEY, W. P. 03-29-65 "REPORT ON THE CHLORACNE PROBLEM MEETING ON 03-24-65" BY L. G. SILVERSTEIN OF DOW TO V. K. ROWE AND MANY OTHERS. Exhibit #P0416 PIN # Date Author Addressee Description DOW019193 29-Mar-65 V K ROWE RILEY, F.H. GRANT, L.B. PLETCHER, D illegible & SMILEY, R.N. & LYNN, 0. & OTHERS Exhibit #P0417 PIN # Date Author Addressee Description DOW29959-64 29-Mar-65 V K ROWE RILEY,F.H. & SMILEY, R.H. GRANT, L.B. & HUTCHENREUTHER, C AMSTUTZ, F.C. & OTHERS Dr. Holder reviewd the medical side of the Dow and said that we now have approximately 60 to 70 cases of individuals with chloracne ranging from severe cases to mild cases. The limit is 1 ppm for 2,4,5-T and for 2,4,5-T Acid, either acetic or pro pionic. Exhibit #P0424 PIN # Date Author Addressee Description DOW568583 09-Apr-65 WALTER B TRAPP MERTZ, DR. HANS & FRANKFORT OFFICE DOW AMOS DOW INT'L Trapp reports results of Dow studies on Boehringer TCP samples including rabbit tests and analyses of TCBD content. Exhibit #P0427 PIN # Date Author Addressee Description DOW751869 15-Apr-65 HAROLD L GORDON FLAMMANG 4 DIVISION MANAGER MAGNA CORP. & ROWE, V.K. OTHERS AT DOW Medical Director of Dow writes Division Manager of a customer giving complete assurance that impurity present in Dowicide 153fi>rio0 IV. A. 29 2 could not cause chloracne even with gross overexposure and sa;ys Dow imposed standard on finished product of zero using an analytical method to 1ppm. Exhibit #P0428 PIN # Date Author Addressee D0W5 68577-8 22-Apr-65 CH BOEHRINGERSOHN DOW CHEMICAL & RE245TC0NTRACT Description Letter in german from C.H. Boehringer Sohn to Dow Chemical Company, Midland, Michigan, re; 2,4,5-T"KontraKt" Exhibit #P0431 PIN # Date Author Addressee Description DOW012036-37 04-May-65 L C WHITE JR AMSTUTS, F.C. & HOFF, R. C. SOULATI, J. J. & SILVERSTEIN, L. DOSSER, R. C. & SMITH, K. A. a conference to discuss the dioxin addition to the specification.a tentative program of testing for the dioxin was set up. Exhibit #P0433 PIN # Date Author Addressee Description DOW765918 19-May-65 JS HARRIS COULTER, K.E. & LUECK, A.F. TRAPP, W. & HABERSTROH, W.H. WIDIGER, A.H. & OTHERS 2,4,5-trichlorophenol process data and phys- ical properties summary showing heats of re- action data "assembled to assist those work- ing on the trichlorophenol process problem Exhibit #P0434 PIN # Date Author Addressee Description DOW765918-19 19-May-65 J S HARRIS COULTER, K.E. & GRAVES, H.E. ANDERSON, R.E. & LUECK, A.F. WEHN, W.E. & OTHERS Existing and generated raw material, intermediate and byproduct, and product data are herein assembled assist those working on the trichlorophenol process problem. Exhibit #P0436 PIN # D0W1 07740-45 l t3 IV. A. 30 Date Author Addressee Description 01-Jun-65 UNIVERSITY COLORADO STATE an article by Colorado state university, "how safe are chemical weed killers". it states the steps of testing that is done before a chemical goes on the market. Exhibit #P0438 PIN # Date Author Addressee Description DOW 004 02-Jun-65 EDWIN T UPTON GROTH. DR. DAVID H 06-02-65 LETTER OF MR. UPTON TO DR. GROTH. Exhibit #P0441 PIN # Date Author Addressee Description 21745-48 22-Jun-65 UNKNOWN DOWCHEMICAL NOT SHOWN Dow's Method for the Determination of 2,3,7,8 TCDD in 2,4,5-T by GLC dated June 22, 1965 Exhibit #P0442 PIN # Date Author Addressee Description DOW12986061 24-Jun-65 VERALD ROWE MULHOLLAND, ROSS & SILVERSTEIN, LARRY HOLDEMAN, GRADY & GOERGEN, G. HOYLE, H. & FALSEY, W. Dow's V.K. Rowe writes, Ross Mulholland of Dow of Canada, and describes the concern arising out of the contamination of tcp and 245-t ; he describes the "exceptional toxicity" of dioxin; and "P.S. Under no circumstances may this letter be repro duced, shown, or sent to anyone outside of Dow Exhibit #P0443 PIN # Date Author Addressee Description DOW 129860-1 24-Jun-65 V K ROWE MULHOLLAND, ROSS & SILVERSTEIN, L. OTIS, C. & HOLDEMAN, ORADY AMSTUTZ, F. C. & GOARGAN, 0 V. K. ROWE'S LETTER TO ROSS MULHOLLAND DATED 06-24-65. Exhibit #P0445 PIN # Date Author DOW568533-34 07-Jul-65 WALTER B TRAPP Addressee MERZ, DR. HANS & BOEHRINGER, SOEN Description Germans ask Dow for information re analytical methods using GLC to determine TCDD; encloses copy of method for analysis for dioxin in 2,4,5-T acid (MLW 65.11). Exhibit #P0452 PIN # Date Author Addressee Description DOW547077-82 24-Aug-65 UNKNOWN DOW UNKNOWN Description of EWsteron T2 formulation with labeling information on Dow letterhead refers to patent and recommendations for use. Exhibit #P0454 PIN # Date Author Addressee DOW547074 02-Sep-65 SIDNEY SAGHS DOWNARD, GEORGE M. & USDA HAMMER, O.H. & SUNDERLAND, W.W. Description Letter from Dow to USDA enclosing materials to review to issue registration for Esteron T2 formulation Exhibit #P0455 PIN # Date Author Addressee Description DOW547074 02-Sep-65 SIDNEY B SAGHE DOWNARD, GEORGE M. & HAMMER, 0. H. SUNDERLAND, W. W. letter dated 09-02-65 from Sidney B. sache to Mr. George M. Downard on the subject: Initial registration of Est???? t2. Exhibit #P0457 PIN # Date Author Addressee 001564-69 14-Sep-65 W R UDELL TAKE - NITRO, E.F. & DUNLAP, W. P. STEPHENS, J. A. & SHARP, D. B. Description REPORT FROM W. R. UNDELL OF AGRICULTURAL RESEARCH DATED 09-14-65. Exhibit #P0459 PIN # Date Author Addressee Description D0W19800-2,4 15-Sep-65 DR KEITH C BARRONS final contract report covers the laboratory 15381 IV. A. 32 and greenhouse testing of new chemical structures synthesized as potential herbicides. Exhibit #P0461 PIN # Date Author Addressee Description DOW816919-20 20-Oct-65 CONFIDENTIAL DOW a dow confidential statment on the ingredients in TORDON 101 mixture (active and inert ingredients and the amount of each). Exhibit #P0462 PIN # Date Author Addressee Description DOW201091 20-0ct-65 W R DIXON BOSSCHER, H. & HENSKE, J.M. PLETCHER, D.E. Decision has been made on the Midland Division Trichlorphenol Plant. Exhibit #P0480 PIN # Date Author Addressee Description D0W124400-01 03-Mar-66 BILL GILL WILTSE, MARK & HANSON, K. Y. OTIS, C. E. & BRYANT, C. A. MCCOY, W. J. & RYAN, W. J. Questions asked by Olmstead airforce and answered by dow chemical regarding the quantity of tordon 101 and 2,4,5-t. Exhibit #P0484 PIN # Date Author Addressee Description D0W1120842 14-Apr-66 JACK MATHES BILLS, WELTON & COLLINS, GEORGE BARBARINE, AUGUST & BRUCE, JAMES HENDLEY, M. J. & OTHERS form regarding the quantities of orange. Exhibit #P0485 PIN # Date Author Addressee Description DOW009037 22-Apr-66 RICHARD G CARLSON MR. HAROLD BOSSCHER Memo is "blanked" in parts of text, but describes the two steps and overall plan being used to produce tetrachlorobenzene. Memo cites exposure to tetrachlorobenzene fumes presently exceed the long-term Industrial Hygiene Standard in exisiting 153 O O o O IV. A. 33 facility. Exhibit #P0486 PIN # Date Author Addressee Description DOW0201033 22-Apr-66 J D VANARSDALE R.G. CARLSON Memo to Phenol Section from Production Planning and Control which projects the demand for 2,4-ST acid equivalent from 1966 to 1970 and, the portion attributed to government bid business. Exhibit #P0487 PIN # Date Author Addressee DOW765248 22-Apr-66 FD AXE ROWE, V.K. & HOYLE,H.R. Description F.D. Axe, Safety Department, Dow Chemical writes Rowe and Hyle of Dow to report that "we have just seen the first new cases of chloracne in the Tordon plant in more than six months." Since "the Pittsburg Tordon Plant (picoline process) will continue to operate to two or three years..we won't let up on the chloracne problem." Exhibit #P0489 PIN # Date Author Addressee Description D0W120843-46 13-May-66 R A HICKMAN ARNOLD, C. W. & BEUTEL, 0. E. BRYANT, C .A & HANES, J. H. MAASBERG, A. T. & OTHERS subjects covered in the Report of call tordon/orange herbicide - defoliants, trichloroethylene, anti-freeze, methylene chloride, and dursban. Exhibit #P0490 PIN # Date Author Addressee Description DOW0201026 23-May-66 H BOSSCHER MAX KEY, DIR OF MFG. Memorandum which is "blanked", cites that new equipment for removal of "?" will be at new location. Memo cites that capacity will be increased and that the removal of "?" will reduce the incidences of chloracne in the Trichlorophenol Plant. Exhibit #P0491 PIN # DOW816964-65 15333 IV. A. 34 Date Author Addressee Description 27-May-66 CONFIDENTIAL DOW dow confidential letter stating the ingredients in m-3083 brush killer. Composition consists of active and inert ingredients and raw materials. Exhibit #P0492 PIN # Date Author Addressee Description DOW820792-94 31-May-66 MR LYNN WARD, JUSTUS letter dated 05-31-66 from G. E lynn, director to Mr. Justus Ward, Director on how the chemical tordon is to be used or not used and what not to mix with. Exhibit #P0494 PIN # Date Author Addressee Description D437060-102 22-Jun-66 HOWARD H GRAVES This report is a summary of the pilot plant data obtained on the Boehringer Process for the caustic hydrolysis of 1,2,4,5-T using meOH as a solvent to produce 2,4,5-T (TCP). Exhibit #P0497 PIN # Date Author Addressee DOW1119993 05-Jul-66 C E OTIS CORBIN, W. L. & BRANAMAN, R. J. BEUTEL, DR. & YANKA, D. E. Description amendment to W. J. mccoy's july 5 letter to w. j. ryan on the subject "basis for pricing of orange." the price of orange to the government at $7.39 per gallon and the reasons why. Exhibit #P0498 PIN # Date Author Addressee Description DOW119541-47 11-Jul-66 ARMY ARMY military specification on herbicide; n-butyl 2,4,5-trichlorophenoxyacetate. Standard sections regarding are included: Scope, Applicable documents, etc. note: precaution - not for domestic use. Exhibit #P0500 ' IV. A. 35 PIN # Date Author Addressee Description DOW00013078 13-Jul-66 J S JR CORT A .B . TILLMAN Appropriation request is for funds for expansion of the 2,4-D Acid facility, modification of the 2,4,5-T Acid facility, purification of TCP and additional warehousing facilities. Memo cites that TCP purification is designed to eliminate a major health problem at Newark and potential health problems with customers. Exhibit #P0504 PIN * Date Author Addressee Description DOW201024 0 1 -Aug-66 DOW BD OF DIRECTORS BD OF DIRECTORS Meeting addresses Tetracholobenzene Expansion on a new building. This new facility is needed to provide for sales primarily of 2,4,5-t and of silvex,ronnel and Dowicides. Exhibit #P0505 PIN # Date Author Addressee D0W816681 06-Aug-66 0 H HAMMER WOLF, M.A. & LYNN, G. E. Description technical information on tordon requested by ralph C wands. supplied on governmental agencies on a semi-confidential basis and not for reproduction, publication or general distribution. Exhibit #P0506 PIN * Date Author Addressee DOW19997-8 11-Aug-66 C E OTIS CORBIN, W. L MCCOY, W. J. & COWELL, J. H. & WILTSE, M. G. Description states the military needs for orange in gallons for 1966 -1967 by the month. also states what orange is composed of : 4 lbs. a/e of 2,4,5-t and 4 lbs. a/e of 2,4-d per gallon. Exhibit #P0513 PIN # D0W119483-84 Date 08-Sep-66 V Author SUPPLY CENTER DEFENSE GENERAL Addressee IV. A. 36 Description order form, contract #: dsa-400-67-c-1820 for a grand total shipped 377123 gallons. Exhibit #P0515 PIN # Date Author Addressee Description DOW201022 26-Sep-66 CHESTER OTIS DIXON, W.R. 4 BOSSCHER, H. HARDING, K. & ARMSTRONG, C. C. PLETCHER, D. E. & OTHERS The Plant Science business feels it is necessary to defer the Tetrachlorobenzene expansion (new building), auth. no. MP-32383A. Exhibit #P0533 PIN # Date Author Addressee Description DOW770187-95 04-Nov-66 A WIDIGER JOHNSON,A. & DUGAN,G.F. COULTER,K.E. & GOERGEN,G.G LOUCK,A. & OTHERS Widiger, Johnson, and Dugan of Dow report on new process developed to prepare 245TCP from Trichlorobenzene; claims that although the process is more complicated than the present Dow process, it is continuous oriented and of simpler design which "should require less capital, less maintenance labor, and less operating labor." Exhibit #P0535 PIN # Date Author Addressee DOW0400-406 07-Nov-66 PROJECT ARMY MU PN 6840 A040 & MILITARY SPECS Description Supercedes spec of 19-July-63. Gives military specs for ordering one type of herbicide consisting of normal-butyl 2,4,5-Trichlorophenoxyacetate molecular weight 311.60. Specs include standards requirements (composition, appearance, etc.), Quality Assurance Provisions, Packaging, Testing, Marking, etc. Gov't reserved inspection rights but vendor can use any acceptable lab. Marking specs contain provision for marking in accordance with MIL-STD-129 and in compliance with the Federal Exhibit #P0547 PIN # DOW0035-53 15386 IV. A. 37 / Date Author Addressee Description 01-Dec-66 GEORGE F COLLINS DOW CHEMICAL CO. Contract issued by Directorate for Procurement and Production - Defense General Supply Center to Dow Chemical at the Abbott Road Bldg. This is a confirming telegraphic offer dated 11/25/66 and acceptance dated 12/01/66. Order is for 6840 NSN, Herbicide, Butyl Esters: MIPR No. MA-6-16445. Section B relates product specifications. Exhibit #P0548 PIN # Date Author Addressee Description DOW119485 01-Dec-66 NONE DEFENSE SUPPLY DOW GENERAL Reference to contract DSA-400-67-C-4029/PC409 Total amount of contract cited as 128,000 gal. with a 5% increase 0% decrease variation clause. Columns relate to quantity expected and quantity shipped from 2/13/67 to 3/2/67. Exhibit #P0553 PIN # Date Author Addressee Description DOW88930-41 09-Dec-66 GEORGE LYNN HAMMER,0.H. & TOXIC LAB BIO-PRODUCTS CENTER Reports after requests for screening or application testing re: a Dow herbicide formula - includes toxicological evaluation and results of animal testing. Exhibit #P0554 PIN # Date Author Addressee Description D0W1120855 09-Dec-66 R A HICKMAN WHITESELL, RUSS & BEUTEL, A. P. CORBIN, W. L. & DIXON, W. R. GOWELL, J. H. & OTHERS Bdsa inquiry - tetrachlorobenzene capacity, states in view of the in-company shortage of tetrachlorobenzene, they were not in a position to supply the material to other producers. Exhibit #P0555 PIN # Date Author Addressee DOW1120224-6 01-Jan-67 MARK WILTSE BRYANT, CLYDE & COWELL, JIM IV. A. 38 Description a chronological report based on information from mark wiltse, Clyde bryant and jim cowell. for the period of early 1965 thru1967 when the texas plant came on stream and the price of tordon was reduced to 6.4443. Exhibit #P0560 PIN # Date Author Addressee Description D0W1120862 14-Jan-67 SUPPLY CENTER DEFENSE GENERAL BENDALL, T. L. Sc BEUTEL, A. P. BYRD, B. C. & CORBIN, W. L. GOWELL, J. H. & 10 OTHERS requirements from the field still call for tremendous qunatities of orange to be shipped by 3-31. Exhibit #P0562 PIN # Date Author Addressee DOW751877 17-Jan-67 L G SILVERSTEIN GILMAN, DR. HENRY Sc IOWA STATE UNIV. Description Silverstein says tetrabromodioxin sample about as potent as TCDD in rabbits. Exhibit #P0564 PIN # Date Author Addressee Description DOW120078 24-Jan-67 H D DOAN J. M. LYLE Memo stresses the safe peace time use of Tordon 101 as a brush killer. Memo further expounds upon virtues of Dow with regard to development and use of its herbicides. The ultimate debate is over price. Exhibit #P0565 PIN # Date Author Addressee D0W120836 27-Jan-67 D PLETCHER DIXON, W.R. Sc HICKMAN, R.A. STACHLING, E Sc MCCOY, W. Description Because of certain inefficiencies and because of certain health problems which require extra cost for employee protection, we hope to replace our present TCB facility with on or two years. Major Concerns are: Strata not suited for wells for wasted disposal, Alternate will be expensive in dollars and time. Little or no processing 153G8' IV. A. 39 equipment. Exhibit #P0566 PIN # Date Author Addressee Description DOW500-03 27-Jan-67 D E PLETCHER DIXON, W.R. & HICKMAN, R.A STROHLING, E.C. & MCCOY,W.S. DELINE, D. & OTHERS Because of certain inefficiencies and because of certain health problems which require extra cost for employee protection, we hope to replace our present TCB facility with 1 to 2 years. Exhibit #P0569 PIN # Date Author Addressee Description D0W120840-41 30-Jan-67 R A HICKMAN BEUTEL, A .P . & CORBIN, W.L. DIXON, W.R. & GOWELL, J.H. HICKMAN, R.A. & OTHERS We advised Gen. Hebbeler that our people had called from Muscle Shoals and advised that it would be very expensive to build the plant and that we were developing an interim report based on total cost of building a plant to produce "orange" starting with the production of tetrachlorobenzene. Exhibit #P0570 PIN # Date Author Addressee Description DOW0069-87 31-Jan-67 GEORGE F COLLINS DOW CHEMICAL CO CONTRACT FOR 6840 NSN HERBICIDE, BUTYL ESTERS MIPR NO MA 6-16445 PRI 02. CONTRACT CALLS FOR 2,4-D AND 2,4,5-T IN A 50-50 BLEND CONFORMING TO MIL-H-51147 (MU) OF 19-JUL-63 EXCEPT ACID PURITY SHALL BE 99.0% MINIMUM BY WEIGHT ACID EQUIVALENT SHLL NOT BE LESS THAN 79.9% NOR MORE THAN 80.0%; THE FREE ACID SHALL NOT BE MORE THAN 0.5% 50% OF N-BUTYL 2,4,5-T CONFORMING TO MIL-H-51148 (MU) DATED 19-JUL-63, EXCEPT ACID PURITY SHALL BE 98.0% MINIMUM BY Exhibit #P0571 PIN # Date Author Addressee Description D0W119200 02-Feb-67 R H BOUNDY DOW CHEMICAL Supplement addresses the resolution for 15309 IV. A. 40 supplemental costs potentially due Dow. Exhibit #P0572 PIN # Date Author Addressee Description DOW751971 03-Feb-67 W J MCCOY CORBIN, W.L. 4 PLETCHER, D. E. GOWELL, J.H. Call indicating that he believed they have a severe chloracne problems with some of their employees. Exhibit #P0573 PIN # Date Author Addressee DOW751874 03-Feb-67 W J MCCOY ROWE, V.K. & CORBIN, W.L. PLETCHER, D.D. & GOWELL, J.H. Description McCoy of Dow advises of phone call from Thompson Chemical indicating severe chloracne problem "we do not feel friendly towards this competitor . . . but believe that any advice would be in order." Exhibit #P0576 PIN # Date Author Addressee Description JUS 215 09-Feb-67 A P BEUTEL TRAUB.JOHN L. & CHIEF, CHEM.PROC. A R M Y ,EDGEWOOD Beutel advises Army Dow management reviewing whether it will participate in army plan to produce Orange at Wilson Dam, Alabama. Report to come. Exhibit #P0577 PIN # Date Author Addressee Description DOW0201020 13-Feb-67 D E PLETCHER E.B. BARNES 5c HAROLD BOSSCHER E.C. STAEHLING & G.G. GOERGEN W.R. DIXON & OTHERS Memo deals with Dow's decision that it is still more cost effective to "make" rather than "buy" Tetrachlorobenzene. Also mentioned is the fact that the new facility is necessary to correct environmental health problems. Exhibit #P0578 PIN # Date Author DOW201020-21 13-Feb-67 D E PLETCHER 15390 IV. A. 41 Addressee Description BOSSCHER HAROLD & STAEHLING, E GOERGEN, G & DIXON, W HENSKE, J & GILL, W We are asking that we proceed at once with Phase IV engineering on this project. While this is a logical steop to meet our projected commercial requirements, it is also a first step if the situation is realized where DOW moves to provide very substantially increased quantities of Orange for the Defense Department. Exhibit #P0579 PIN # Date Author Addressee DOW751872 13-Feb-67 V K ROWE CORBIN, W.L. COWELL, J.H. & PLETCHER, D.E. & MCCOY, W.J. Description Dow received a call from Thompson Chemical Co. stating that some men thought they had rec'd chloracne. They wondered if Dow could advise them to medical practice. Under certain circumstances the caustic insloulbe oils coulnd contain considerable amounts of a very highly toxic substance which was identified as 2,3,7,8-T. Exhibit #P0580 PIN # Date Author Addressee Description DOW751872 15-Feb-67 V K ROWE DIXON, WILLIAM B & CORBIN. W.L. PLETCHER, D.E. & GOWELL, J.H. MCCOY, W.J. & HOLDER, B.B., M.D. V.K. Rowe relates developments regarding Thompson Chemical Company request for information concerning Thompson's chloracne problem. Rowe advised existence TCDD "extremely toxic systemically . . . also . . . potent chloracnegen; extreme precautions to clean up equipment "the information on the physiological activity was perhaps even less than . . . given . . . other producers of TCP over a year ago. . . . because . . . apparent Buckley had little understanding of . . . problem." Exhibit #P0584 PIN # Date Author Addressee DOW816875 20-Feb-67 G F LYNN W. R. DIXON & D. E. PLETCHER W. L. CORBIN & J. HL COWELL IV. A. 42 Description J. N. O'CONNOR & OTHERS Dow is trying to get restrictions lifted from the label of Tordon 101. Dr. Hays is reluctant to enter into a controversy with potential legal implications. The procedure of appeal to the NAS was pursued. Exhibit #P0588 PIN # Date Author Addressee Description D0W816873 24-Feb-67 GEORGE LYNN DIXON, W.R. & PLETCHER, D.E. CORBIN, W.L. & O'CONNOR, J.N. WILTSE, M.G. & OTHERS I called Dr. Hays concerning the Tordon 101 label. He has discussed the matter in detail with the USDA attorney, Mr.Robertson, and between them, do not see any reason to do anything concerning either the TORDON 101 Label or the Barovert label. Unless we re-open the matter I gather the USDA will consider it closed. Exhibit #P0589 PIN # Date Author Addressee JUS215-524-6 24-Feb-67 A P BEUTEL TRAUB, JOHN.ARMY & EDGEWOOD Description Dow reports its attitude to army proposal to produce orange at phosphate development works, Wilson Dam, Ala.,cites large capital required, time for engineering & construction.manpower problems, and concludes the proposal does not appear to have the potentional to meet the urgency of the U.S. Gov't requirements. Exhibit #P0591 PIN # Date Author Addressee Description DOW088969 27-Feb-67 K J OLSON F. OYEN & H. R. HOYLE DOW EMPLOYEES Data Sheet of Precautions cites possible skin disorders for Tordon 105 Mixture; 2,4,5-T Servere eye irritation possible; safety glasses required. Exhibit #P0594 PIN # Date Author D0W120107 07-Mar-67 R A HICKMAN IV. A. 43 Addressee Description MR. WOLTON BILLS Dow is trying to get committment of money or guarantees for building of new facility to supply government with Tordon 101 or Super Orange Exhibit #P0597 PIN # Date Author Addressee Description DOW091173-76 17-Mar-67 KEN OLSON F.OYER & R.H. BOUNDY B. HOLDER, MD & D. KILIAN, MD R.D. MOSS & OTHERS A sample mix of Tordon 105 composed of 21.6% 2,4,5-T, and 5.4% of 4-amino 3,5,6 tri. acid and 44.1% water proved to be only slightly irritating to intact or freshly abraded skin. Exhibit #P0598 PIN # Date Author Addressee Description 120679 21-Mar-67 R HICKMAN CLYDE BRYANT & CHET OTIS BILL RYAN Letter states that The United States Government is now Dow Chemicals Number Two Customer through the Bioproducts Department and the Tordon area. Exhibit #P0600 PIN # Date Author Addressee D0W119501 24-Mar-67 UNKNOWN UNKNOWN DOW & HICKMAN Description Letter directs Dow to accelerate delivery of existing contract for the defoliant "Orange" at a monthly rate of 93,000 gallons 4/3/67. Also directed to give monthly reports on production, shipments and inventory. Exhibit #P0602 PIN # Date Author Addressee Description D0W120720-22 29-Mar-67 R A HICKMAN HOSLEY R. KOETER Dow states experimental deliveries made to the government since 1962 and that selected type orange and tordon 101 have been supplied since fall of 1965. Dow is commenting on differential pricing and ability to provide herbicides to the 1 IV. A. 44 government in the future based on financial committment by government. Exhibit #P0603 PIN # Date Author Addressee 120671,720-2 29-Mar-67 R A HICKMAN BILLS, WELTON & KOSTER, WOALEY R Description R. A. hickraan letter of 3-30-67 to Mr. Welton Bills , Defense General SUpply Center Exhibit #P0605 PIN # Date Author Addressee Description D0W120671 30-Mar-67 R A HICKMAN MR. WELTON BILLS Confidential report attached (not with exhibit) was prepared for BDSA outlining Dow's ability to supply defoliation chemicals. They further request contracts for Tordon 101 and Orange ASAP. Exhibit #P0609 PIN # Date Author Addressee Description DOW120432-58 17-Apr-67 GEORGE F COLLINS DSASR an award/contract between dow chemical company and directorate of procurement & production Attn:pc433 it states what the product herbicide, butyl esters should consist of, how to be shipped and supply warranty. Exhibit #P061 0 PIN # Date Author Addressee Description D0W119947-52 17-Apr-67 W R NUMMY PLETCHER, D. E. & BOSSCHER, H. TIMM, W. C. & COULTER, K.E. TRACEY, W. J. & OTHERS Fredricks' Letter dated March 31,1967 solicited reasonable solutions to the problem of supplying all or any part of the estimated additonal requir- ment of 8,000,000 gallons of "Orange" per year. It further stated that more detailed proposals would be requested for those solutions considered to be most feasible. Exhibit #P0613 PIN # D0W1120723 15394 IV. A. 45 Date Author Addressee Description 21-Apr-67 R A HICKMAN HEATH, OTIS & GILL, W. HANES, J H & NUMMY, W R PATTERSON, R. M. & OTHERS letter dated 04-21-67 from R. A. hickman to Otis heath regarding the conversation with jane lewis confirming no relaxation in waivers of import duty on 2,4,5-t and 2,4-d. if imported and duty was paid, it may be sold in civilian market and not subject to directive issued by BDSA recently. Exhibit #P0614 PIN # Date Author Addressee DOW120724,26 25-Apr-67 R A HICKMAN BALLMAN, DONALD K. & BEUTEL, A. P. EVERSON, J. W. & WILLIAMS, G. J. COFFEY, W. H. & OTHERS Description report states a contract of 167,000 gallons a month from august 1967 thru march 1969, the government asked this be kept confidential because of the size of the contract, other suppliers were also bidding. Exhibit #P0622 PIN # Date Author Addressee DOW650139-45 22-May-67 BARRY BYRD DOW SALES & JOHN SPALDI Description Sales release cites that Tordon 155 mixture should never be mixed with water and should not be allowed to contaminate soil used to grow desirable plants such as vegetables, etc. Do not store near food, seeds, etc. Avoid breathing mist, harmful if swallowed, may cause irritation Exhibit #P0623 PIN # Date Author Addressee Description Exhibit #P0626 PIN # Date Author Addressee DOW650139 22-May-67 BARRY BYRD DOW201049-50 31-May-67 RICHARD G CARLSON HAROLD BOSSCHER fc Q K 0 0^0 5 Description Blanked out memo relates to step one of 2 step expansion plan. New 819 building is to be constructed. Existing 636 building is cited as being congested and in violation of long term Industrial Hygiene Standard. Exhibit #P0629 PIN # Date Author Addressee Description DOW201044 08-Jun-67 HAROLD BOSSCHER DR. E. B. BARNES Memo cites 636 building is extremely congested and resulting in problems in safety, maintenance and operation. They hope to reduce chloracne problem. Exhibit #P0633 PIN # Date Author Addressee 0000000 28-Jun-67 GEORGE F COLLINS THOMPSON-HAYWARD & CHEMICAL CO. Description JUNE 1967 CONTRACT TO PRODUCE AGENT ORANGE. Exhibit #P0634 PIN # Date Author Addressee Description D0W120735 28-Jun-67 R A HICKMAN BALLMAN, DONALD K & BEUTEL, A. P. EVERSON, J. W. & WILLIAMS, G. J. COFFEY, W. H. & OTHERS states a shortage due to increased military use of orange and tordon 101, the shipments of other weed killing agents increased, a new plant to be built in two untis in weldon springs, missouri for production of 2,4-d and 2,4,5-t. purchase of this product will be transferred from DSA to army, and coded as a weapon rather than a herbicide. Exhibit #P0636 PIN # Date Author Addressee Description DOW0426-36 30-Jun-67 ARMY ARMY DOW Supercedes MIL-9-51 239(MU) 30-Dec-65. Mostly illegible, but contains standard paragraphs regarding inspection, labeling, precautions, etc. Exhibit #P0647 PIN # D0W1 120680 1 53;'i8 IV. A. 47 3 Date Author Addressee Description 01-Aug-67 R A HICKMAN BALLMAN, DONALD K. Sc BEUTEL, A. P. EVERSON, J. W. Sc WILLIAMS, G. J. COFFEY, W. H. & OTHERS military increases consumption of tordon and orange . 2,4-d and 2,4,5-t forced into short supply, other weed killers are being bought by government agencies (Esteron 99 Concentrate). Exhibit #P0654 PIN # Date Author Addressee Description D0W1120687 30-Aug-67 R A HICKMAN BALLMAN, DONALD K. Sc BEUTEL, A. P. EVERSON, J.W. Sc WILLIAMS, G. J. COFFEY, W. H. & OTHERS due to continued shortage of 2,4-d and 2,4,5-t through shipments of orange is accelerating shipment of esteron 99, sodium tea, and other herbicides. Exhibit #P0655 PIN # Date Author Addressee Description DOW979868 01-Sep-67 R W WRIGHT BARNES, E. B. Sc BEUTEL, A. P. BOSSCHER, H. Sc COFFEY, W. H. HICKMAN, R. & OTHERS Exhibit #P0656 PIN # Date Author Addressee DOW979868-74 01-Sep-67 R A HICKMAN BEUTEL, A. P. Sc NUMMY, W.R. P LETCHER, D.E. Sc MANYOTHER DOW Description Hickman prepared lengthy call report describing conversations with various government representatives concerning the policies and needs of the Gov't for Orange; report cites many of these conversations. Exhibit #P0658 PIN # Date Author Addressee D0WH15454-56 05-Sep-67 M A TAVES REGAN J M Sc RANO P J TURK E DR. & GIVENS K T WILDER H K Sc OTHERS Description On September 1, 1967, Bill Clark and Regan 1 c q o *7 JL vJ O -i IV. A. 48 visited the Defense Center to discuss the procedure used to analyze "orange" herbicide mixture. Exhibit #P0659 PIN # Date Author Addressee H15454-56 05-Sep-67 M A TAVES WILDER, H. E. & SIDWELL, DR. A. E. CLARK, W. H. & RENO, P. J. TURK, DR. E. & SCOTT, DR. R. B. Description Herculesletter from M. A. Taves to Mr. J. M. Eagan, dated 09-05-67. Exhibit #P0661 PIN # Date Author Addressee DOW979869 06-Sep-67 W J TACEY C. BAILEY & R. CARLSON F. CHASE & J. COPPAGE D. DELINE & OTHERS Description The accompanying chart list the Unit Ratios for use in the new 8.1 MM gallon Orange Plant Study. The Ratios list are, in general, the 1967 standards. Exhibit #P0662 PIN # Date Author Addressee D0W1120692-3 07-Sep-67 R A HICKMAN GOWELL, J. H. & BEUTEL, A. P. KEIL, R. M. & NUMMY, W. R. ROBERTSON, R. W. & OTHERS Description when first discussed tordon there were only laboratory results and mini-plant production, dow states that sales to the civilian market would be more profitable for them than to the government and proven an effective weapon in Vietnam. this is the only other effective weapon for its specific use except orange. 15338 IV. A. 49 Exhibit #P0667 PIN # Date Author Addressee Description D0W817294-99 13-Sep-67 M LONG points to consider in connection with use of tordon - 2,4-d in rangeland and pasture are what it does to the grass, cattle and crops. Exhibit #P0670 PIN # Date Author Addressee Description D0W3444 26-Sep-67 J M ILLEGIBLE DOW LAB Report of laboratory analysis on t-acid from drier. Concentration of dioxin of t.c.p. used to produce t-acid=1.9 to get 1.5 in t-acid. Exhibit #P0678 PIN # Date Author Addressee D0W1124975 11-Oct-67 L C WHITE SCULATI, J. J. & HAWLEY, H. M. Description dow chemical co. raw material specification form for 2,4,5-t. it states test items, limits and test methods. Exhibit #P0684 PIN # Date Author Addressee Description DOW1125124 24-Oct-67 V K ROWE SNYDER, FRED H this is in response to a letter of 10-18-67 regarding acnegens and laboratory methond for evaluatin same. IV. A. 50 15399 Exhibit #P0686 PIN # Date Author Addressee Description D0W119486-7 30-Oct-67 SUPPLY CENTER DEFENSE GENERAL order form, contract # dsa-400-67-c-5534 /pc440, total amount of contract - 170,000 gallons with a 5% increase 0% decrease variation clause. also contract # dsa-400-67-c-8032. Exhibit #P0691 PIN # Date Author Addressee Description DOW852482-3 08-Nov-67 C L DUNN MEMBERS NATIONAL & AGRICULTURAL CHEMICALS ASSOC. report states tolerances of phenoxy herbicides on range and pasture grasses at high residue levels shortly after application. Exhibit #P0694 PIN # Date Author Addressee Description D0W1120713 09-Nov-67 R A HICKMAN HEATH, OTIS & GILL, W COWELL, J. M. & RYAN, W. J. YANKS, D. E. the conversation entailed questions like: it tc3 imported, could it be converted to 2.4.5- t and sold to customers other than government. the directive that had been issued against dow and industry called all 2.4.5-t capacity and production be made available to government. Exhibit #P0695 PIN # Date Author Addressee Description D0W1120714-5 09-Nov-67 R A HICKMAN GOWELL, J. H & GILL, W. HEATH, 0 & RYAN, W. J. YANKA, D. E. memo states the requirements for 1968 to be IV. A. 51 15400. 6? gallons of herbicide.mr. Minarik stated the figures for 1969 in the area of 11-15m gallons. Exhibit #P0697 PIN # Date Author Addressee DOW852481 27-NOV-67 C L DUNN MEMBERS NATIONAL CHEMICALS ASSOC. & AGRICULTURAL & ?, J. A. Description the conference dealt with the farmers and the prod uct phenoxy herbicides. Exhibit #P0700 PIN # Date Author Addressee Description DOW1120717 29-Nov-67 R A HICKMAN BALLMAN, DONALD K regarding a bid for supplying a quantity of tetrachlorobenzene to be used in the production of orange at weldon springs. Exhibit #P0701 PIN # Date Author Addressee Description DOW817053 02-Dec-67 UNKNOWN UNKNOWN NANCY note to nancy regarding tordon 155 mixture and the label for this product, stating something about a new ingredient. Exhibit /P0706 PIN # Date Author Addressee D0W1112041-2 22-Dec-67 R A HICKMAN MCCOY, V. J. & HANSON, K. Y. Description reason for call was to review the oct. report filed by otis heath of dow. There was an error in the report which caused BDSA to make an incorrect analysis of the 15401 IV. A. 52 ability to produce trichlorophenol and 2,4,5-t. Exhibit #P0707 PIN # Date Author Addressee D0W1120743-5 27-Dec-67 R A HICKMAN BALLMAN, DONALD K & BEUTEL, A.P. EVERSON, J. W. & QUIGLEY, F. K. COFFEY, H. H. & OTHERS Description a review states, tordon and orange requirements for fiscal year 1969 the period 4/1/68 thru 3/31/69. a team went to edgewood arsonal, and dow's management decided not to bid the 30,000,000 lbs. tetrachlorobenzene plant and bid on the 10,000,000 lbs. plant whose end product to be used by the government operated plant at weldon springs, missouri, in production of orange. Exhibit #P0711 PIN # Date Author Addressee Description DOW119555-6 31-Dec-67 COMPANY DOW CHEMICAL NONE analysys of competitive bidding on orange delivered for the year ended 12-31-67 contains: contract No., gallons delivered, dow's unit price and amount, lowest non-dow bid unit price and amount, and average nondow high and low bid unit price and amount, the comparison with competitive prices received on solicitation of orange bid proposals (furnished by eastern regional renegotiation board) contains: contract date nad number, bids received per gallon for dow and all competitors by number. Exhibit #P0712 PIN # Date Author Addressee DOW893805-8 01-Jan-68 C E MINARIK IV. A. 53 15402 3 Description che article states how the herbicides were used in Vietnam and what some effects were, it also contains when and where some of the spraying took place. Exhibit #P0717 PIN # Date Author Addressee D0W817423 08-Jan-68 GEORGE E LYNN NUMMY, W.R. & BARRONS, K.C. HAMMER, O.H. & SUNDERLAND, WW WILTSE,M.G . & LENG, M.L. Description Lynn writes report to Nummy and others at Dow, of Conference with Pesticides Regulation Division, USDA, of 1-4-68; reference the Division's position that Tordon does not appear useful for the purposes for which tolerances were being sought. Exhibit #P0720 PIN # Date Author Addressee Description DOW820921-36 11-Jan-68 0 H HAMMER ALFORD, HAROLD G. & USDA LICHY, C.T. & SUNDERLAND, W.W. TALCOTT, A.T. Hammer of the Registration Section of Dow encloses a report of the Toxicological Properties and Industrial Handling Hazards of Tordon 144 mixture Herbicide Exhibit #P0728 PIN # Date Author Addressee DOW821106-7 26-Jan-68 HAROLD ALFORD MCINTYRE, H.H. & DOW CHEMICAL LABELING & REG'N & MIDLAND, MI. Description Alford, of USDA writes McIntyre of Dow Labeling and Product Registration Section \ that the labelling submitted previously was not acceptable and gives form letter advising Dow of additional materials^ IV. A. 54 required. Exhibit #P0729 PIN # Date Author Addressee D0W120759-60 26-Jan-68 R A HICKMAN BEUTEL,A.P. & DOUGLAS, BURKE HANSON, K.Y. & MCCOY, W.J. RYAN,W .J . & YANKA,D.E. Description Hickman, U.S. Gov't Marketing Mgr.of Dow, advises others at Dow as to details of situation regarding Dow's bids to supply orange and efforts to supply Tordon. Exhibit #P0733 PIN # Date Author Addressee Description D0W120761-3 31-Jan-68 R A HICKMAN DOW EMPLOYEES Example of monthly report written to numerous Dow employees by the Gov't Marketing Mgr., and also refers to efforts of Dow to sell Tordon to the Gov't for use in S.E.Asia Exhibit #P0734 PIN # Date Author Addressee D0W120766 02-Feb-68 R A HICKMAN BEUTEL,A.P. & DOUGLAS, BURKE HANSON, K.Y. & MCCOY, W.J. RYAN,W.J. & YANKA,D.E. Description Hickman reports that he spoke with Miss Jane Lewis and Mr. Carl Rolle separately and they advised as to herbicide require ments and fact of gov't disappointment that Dow did not bid on TCP plant of the Edgewood Arsenal, "we were not too concerned about keeping other chemical companies honest" IV. A. 55 15404 Exhibit #P0737 PIN # Date Author Addressee Description D0W816698 09-Feb-68 GEORGE LYNN DRAFT & DISTRIBUTORS TORDON Draft of "Important Notice" to be sent to distributors advising that the labeling of Tordon and Borolin has been revised to delete the use on cropland Exhibit #P0738 PIN # Date Author Addressee D0W120769 16-Feb-68 R A HICKMAN BEUTEL, A.P. MCCOY, W.J. YANKA, D.E. & GOWELL, J. & RIDNER, J.H. & DOW INTERNAL Description Hickman, Gov't Marketing Mgr. of Dow writes memo of telephone conf. with Jane Lewis of government advising that Hoffman-Taft in position to make Orange; Other producers had their equipment ordered. Exhibit #P0740 PIN # Date Author Addressee DOW120770-1 21-Feb-68 R A HICKMAN BEUTEL, A.P. & YANKA, D.E. BYRD, B.C. & GOWELL, J.H. NUMMY, W.R. & PAC Description Hickman writes a summary of a strategy meeting where it was agreed to try to reconfirm strategy for future herbicide production by Dow. Exhibit #P0744 PIN # Date Author Addressee DOW817051 26-Feb-68 DOW UNKNOWN UNKNOWN & DOW EMPLOYEES IV. A. 56 Description Dow Confidential description of composition of active ingredients, inerts and acid equivalence of Tordon 155. Exhibit #P0747 PIN # Date Author Addressee Description D0W120772-4 27-Feb-68 R A HICKMAN BEUTEL, A . P . & BALLMAN, D.K. EVERSON, J.W. & QUIGLEY, F.K. SALES DEPARTMENT Hickman writes monthly report of sales activities to Department Personnel and Supervisor "strategies have been developed for pushing Super-Orange as a long range replacement for both Tordon and Orange" -Edgewood requests the Dow bid again on TCB plant "for all practical purposes, the door closed for future opportunities to bid on this plant." Exhibit #P0751 PIN # Date Author Addressee DOW816696-7 04-Mar-68 G E LYNN NUMMY, W.R. & JOHNSON, J.E. WILTSE, M.G. & GOWELL, J.H. BARRONS, K.C. & OTHERS AT DOW Description Lynn reports his telephone conference with Harold Alfred, U.S.D.A., re Tordon registration difficulties Exhibit #P0752 PIN # Date Author Addressee D0W120775 04-Mar-68 R A HICKMAN BARRONS, K.C. & GOWEL, J.H. Description Hickman reports Jane Lewis interested in Gowel's comments in view of many criticisms directed at use of herbicides in Vietnam. JL5408 IV. A. 57 Exhibit #P0755 PIN # Date Author Addressee Description DOW!2779 19-Mar-68 R A HICKMAN BEUTEL, A .P . & GOWEL, J.H. MCCOY, W.H. & YANKA, D.E. OTHERS AT DOW The Hickman reports that Miss Lewis discussed slowdown on shipments of Orange to the Government and fact that Government would let industry police itself in sale of 2,4,5-T to existing customers to make sure of no black market. Exhibit #P0756 PIN # Date Author Addressee Description D0W120776-78 22-Mar-68 R A HICKMAN GOWEL, J.H. & WILTSE, M . G . OTHERS AT DOW Hickman discusses strategy meeting re Super-Orange and fulfillment of Tordon contract and notes concerns about attitude at Fort Detrick involving Army's indicated need for additional data; shows Dow actively pursuing government market. Exhibit #P0757 PIN # Date Author Addressee D0W120781 28-Mar-68 R A HICKMAN BEUTEL, A .P. & GOWEL, J.H. MCCOY, W.J. & OTHERS AT DOW Description Hickman reports riisens si.nns at St. Louis meeting between he and five others (non-Dow); further references Thompson Chemical and Sterans and Roger. Exhibit #P0758 PIN # Date Author Addressee D0W538350-1 08-Apr-68 DREW M BAKER DUNN, C.L. & CHAIRMAN NACA IV. A. 58 INDUSTRY TASK FORCE & USDA PEST. DIV. Description Mr. Baker of HEW describes the residued data HEW wants submitted in order to support industry requests for residue tolerances of 2,4,5-T. Exhibit #P0770 PIN # Date Author Addressee D0W120795-6 14-May-68 R A HICKMAN CORBIN, W.L. GOWEL, J.H. & GILL, W.M. & OTHERS AT DOW Description Hickman describes telephone conversations with Jane Lewis, BBSA, and George Collins, DGSC, re supply of TCP to Woodbury Chemical "we might . . . help her . . . if we could supply TCP to Woodbury * * * this . . . might hurt our obtaining as large a portion of future Orange contracts as we would like." Exhibit #P0773 PIN # Date Author Addressee DOW720805-31 01-Jun-68 J L ENGER DOW PERSONNEL & DOW SUB-PERSONNEL Description A report of Dow marketing research regarding pesticide exports during 1967 re 2,4-D and 2,4,5-T. Exhibit #P0775 PIN # Date Author Addressee Description D0W120804-5 0 7 -Jun-68 R A HICKMAN DOW INTERNAL Hickman reports "we have kept very close to Miss Lewis as a source of factual . . . completely accurate information." Discusses quantity of herbicide to be sprayed in fiscal 1969 developed from pilot information; also discusses lack off Tordon acceptance. a Exhibit #P0779 PIN # Date Author Addressee Description DOW014082-3 17-Jun-68 E MONROE GREENE, L. M. letter states the analytical method, along with the letter is a routine sheet for the release of technical information regarding the determination of 2,3,7,8-tetrachlorodibenzo-p-dioxin in 2,4,5- trichlorophenoxyacetic acid by gas-liquid chromatography. Exhibit #P0780 PIN # Date Author Addressee Description D0W120808-9 21-Jun-68 R A HICKMAN INTERNAL DOW Hickman summarizes quality control and shipping problems in calls made to various government employees and inspectors to solve the same "planes flew Sorties like hell all last month." Exhibit #P0782 PIN # Date Author Addressee DOW811635-48 28-Jun-68 0 H HAMMER MCCOLLISTER, D.D. & LYNN, BLAIR, E.H. & WILTSE, M. LENG, M.L. & OTHERS G.E. Description Hammer responds to McCollister request to pull together his thoughts on "what seems to be needed prior to . . . any further requests to USDA for registration of use of Tordon . . . . o n crop land. Exhibit #P0786 PIN # Date DOW120816 17-Jul-68 IV. A. 60 Author Addressee Description A P BEUTEL ASST. CHIEF OF STAFF & FORCE DEVELOPMENT ARMY & PENTAGON, WASH. D.C. GENERAL HEBBELER Beutei, Vice-President and Director of Government affairs at Dow writes Brig. Gen. J.A. Hebbeler attempting to extol the merits of Super-Orange. Exhibit #P0787 PIN # Date Author Addressee Description 9369 23-Jul-68 NONE NONE Excerpts of the Twenty-First Meeting of Research Laboratories Review Point I Committee, dated July 23, 1968. Exhibit #P0788 PIN # Date Author Addressee D0W120829 31-Jul-68 R A HICKMAN BEUTEL, A .P . ECCLES, R.P. & BALLMAN, & QUIGLEY, D.K. F.K. Description Monthly report for July, 1968, re Government Exhibit #P0792 PIN # Date Author Addressee Description DOW580567-85 22-Aug-68 UNKNOWN UNKNOWN DOW Technology Review on products-Dowanol Chloroacetate, Butuil Chloracetate, Iso-Octyl Chloroacetate. Uses - 2,4,D Weed Killers and 2,4,5 T Weed Killers Exhibit #P0793 PIN # Date Author D0W120818-22 28-Aug-68 R A HICKMAN IV. A. 61 15410 Addressee BEUTEL, A .P . & BALLMAN, D.K. ECCLES, R.P. & QUIGLEY, F.K. Description Hickman's report includes reference to presentation made on Super-Orange and requirements for Tordon 101 together with bulk movement of defoliants and possible storage and mixing facilities in Vietnam but states if supply depot damaged by bomb possibly too much liquid herbicide in the area to ever again use the land for growth of any kind and other uses of 55 gallons drums of such wide variety; drums have advantages in and of themselves. Exhibit #P0794 PIN # Date Author Addressee DOW979845-61 30-Aug-68 A P BEUTEL SHEAD, COL. C.G. & KELLY AIR FORCE BASE Description Buetel writes Col. Shead enclosing a Dow proposal planning document re bulk shipment (converting from drums), suggests Dow should manage program and again seeks to sell Super-Orange Exhibit #P0795 PIN # Date Author Addressee D0W120827 04-Sep-68 R A HICKMAN BEUTEL, A .P . & GOWEL, J.H. MCCOY, W.J. & OTHERS AT DOW Description Hickman writes of his concerns and those of industry people that Weldon Springs plant would produce Orange causing industry to supply TCB and referencing serious situation regarding pollution such plant would cause. Exhibit #P0798 PIN # Date Author D0W119942 17-Sep-68 W J ZEPP IV. A. 62 Addressee HICKMAN, R.A. & ROLLE, CARL LEWIS, JANE & OTHER GOVT. EMP. Description W.J. Zepp of the Government relieves Dow of the 93,000 additional gallons per month over base of 222,000 gallons per month on Orange contract cited. Exhibit #P0800 PIN # Date Author Addressee Description D0W120655-7 25-Sep-68 R A HICKMAN BEUTEL, A .P . & BALLMAN, P.K. OTHERS AT DOW hickman r Hickman reports 222,000 gallons per month continue to be shipped and references opportunity to bid on Tordon. Exhibit #P0802 PIN # Date Author Addressee Description DOW979843-63 30-Sep-68 K E HONEYCUTT BEUTEL, A .P . & HICKMAN, OTHERS AT DOW R.A. Exhibit #P0804 PIN # Date Author Addressee Description D0W17180-83 04-Oct-68 M F WILKERSON HOCHBERG M Based upon present industry capacity to produce both D and T as opposed to present purchase patterns of the military, it was concluded we have a case to present to the defense and Commerce Departments. Exhibit #P0805 PIN # Date Author Addressee Description DS 17180-3 04-Oct-68 M F WILKERSON HOCHBERG, H INTEROFFICE CORRESPONDENCE DATED 10-04-68 15412 IV. A. 63 FROM M. F. WILKERSON TO H. HOCHBERG OF DIAMOND SHAMROCK. Exhibit #P0807 PIN # Date Author Addressee Description D0W120633 07-Oct-68 R A HICKMAN HOLDEMAN, GRADY & MCCOY, W.J. OTHERS AT DOW Hickman writes Dow sales people re conversations with Carl Rolle and Fred Knapp where they asked Dow to write specs for Super-Orange and to quote in their procurement when order is placed; Knapp also asked Dow to update Tordon specifications. Exhibit #P0809 PIN # Date Author Addressee Description 125528-32 18-Oct-68 R A HICKMAN BEUTEL, DR. A P R. A. Hickman letter of 10-18-68 to Dr. A. P. Beutel and others. Exhibit #P0810 PIN # Date Author Addressee D0W125528-32 18-Oct-68 RA HICKMAN BEUTEL, A .P . GOWELL, J.H. & CORBIN,W.L. & OTHERS AT DOW Description Hickman reports because of the "concern" of his department and other departments at Dow on the status of the military herbicide business and Dow's efforts to sell to the Gov't with predicitions as to effects on business if bombing stops in North Viet Nam, and other considerations. Exhibit #P0812 PIN # D0W120654 IV. A. 64 Date Author Addressee 30-Oct-68 R A HICKMAN CORBIN,W.L. & DOW AG PROD SALES Description Hickman report of conversation with Jane Lewis of Gov't indicates industry had a law firm deliver a letter which concerned her; re; deliveries of 2,4-D and 2,4,5-T and reports his info, re actual gallons required by U.S. Exhibit #P0825 PIN # Date Author Addressee D0W119490 31-Dec-68 R G GOVT KNOTT DOW CHEMICAL & USGOV'TAGENCIES Description Sample Shipping and Receiving Form issued by U.S. Gov't appropropriate agencies re; some of Orange delivered by Dow to U.S. Exhibit #P0831 PIN # Date Author Addressee Description D7 25 522-44 06-Jan-69 UNKNOWN UNKNOWN PRODUCT SPECIFICATION FOR BRUSH KILLER T-334 Exhibit #P0837 PIN # Date Author Addressee Description DOW538375 25-Jan-69 C L DUNN DUBRIDGE,LEE, DR. & DIR.OFFICE OF SCIENCE & TECH. & PRES. USA OTHERS Author states that a soundly designed experiment is absolutely necessary to determine if a teratologic hazard is associated with 245-T. Requests support in request to FDA to defer action on 245-T until additional information is available for study and evaluation. 15414 T V A . ftS Exhibit #P0839 PIN # Date Author Addressee DOW852450 07-Feb-69 JAMES B LAMB DUNN, C.L. & NACA INDUST.TASK FORCE & USDA Description HEW writes Industry Task Force on Phenoxy Herbicides regarding deficiencies in the petitions proposing tolerances for residues of 2,4,5-T,2,4-D,Silvex,and MCPA.and noting further info.required. Exhibit #P0843 PIN # Date Author Addressee Description 001502-3 21-Feb-69 J C STRUM NITRO PROGRESS RPT NITRO PLANT PROGRESS DATED 02-21-69. REPORT FROM J.C. STRUM Exhibit #P0845 PIN # Date Author Addressee DOW276151-52 27-Feb-69 EUGENE BENEGNA RIDER, J.M. & RITTY, P.M. SHAVER, R.J. & SHELDON N.W. SOUTHWICK, R & OTHERS Description Comparison of the toxicological effect of herbicides to fish is difficult because of the wide variation in test methods. Exhibit #P0848 PIN # Date Author Addressee DOW124722-7 18-Apr-69 D E YANKA BEUTEL,A.P. & COFFEY, W.H. GOWELL, J.H. & HICKMAN,R.A. WRIGHT,R.W. & OTHERS AT DOW N Description Yanka of Dow writes Report on Renegotiable Dow Contracts to 10 Dow co-employees; The 15415 IV. A. 66 report argues that only renegotiable area of Dow's business for 1967 involve sales of Tordon and Agent Orange to the United States. Complains of fact that Dow had large (millions) investment in comm'l market, and huge demands of U.S.,which caused industry to expand capacity beyond comm'l market; complains of low U.S.gov't price com- pared to comm'l market. Exhibit #P0854 PIN # Date Author Addressee DOW856385 23-Jul-69 B C BYRD LYNN,GEORGE E. & MOSS, R.D. LANING, E.R. & HYMAS, T .A. HANSEN,J.C. & DAVIDSON, J.H. Description Product Technical Specialist of Ag. Dep't Dow writes memo to co-employees of tel. call from A1 Young, Lt.,USAF, advising Young said he had to "go to the top" to get permission for joint Dow-Air Force publication-with references to permission to classify if results not in interest of either Dow or the Air Force;"There is no way of predicting whether normal degradation of phenoxies would occur under this regime" Exhibit #P0856 PIN # Date Author Addressee DOW 817491-0 04-Aug-69 GEORGE E LYNN MCCOLLISTER,D.D. & LANING,E.R. BLAIR,ETCYL H. & NUMMY,W.R. LENG,M.L. & OTHERS AT DOW Description Five Dow employees attended a meeting with the USDA Pesticides Regulation Division on 7/29/65 re; application for registration of Tordon 225 to control mesquite on permanent rangelands and pastures;and proposing tolerances for residues in forage grasses, meat & Milk. This is the Dow internal report of that meeting. 15418 IV. A. 67 Exhibit #P0861 PIN # Date Author Addressee Description DOW981712-18 26-Sep-69 GSA USFEDSUPPSERV USA federal specifications for herbicide 2,4,5-T (both salts and esters) superceding prior specs. Exhibit #P0862 PIN # Date Author Addressee DOW550401-07 30-Sep-69 J E MUTCHLER TREE R M & PLEPYS R A BAILEY C Z & KRAMER C G MORSE D B & OTHERS Description Temperature controls have been installed on penta feed line to the prill pot. September wipe tests are now nearing completion. Four samples are active including two new active samples, both located near the fluid bed drier. Exhibit #P0864 PIN # Date Author Addressee DOW124858-61 1O-Nov-69 C L DUNN NACA & INDUSTRY TASK FORCE ON PHENOXY & HERBICIDE MEMBERS Description Report of urgent meeting of Oct.28, 1969 between industry and gov't reps.; re ;Bionetics indications of teratogenicity,and reports of birth defects in Vietnam;also references DuBridge's announcement and positions of the parties in attendance, with listing of persons present; On Hercules letterhead. Exhibit #P0867 PIN # Date D0W754888-89 25-Nov-69 .~ A* IV. A. 68 Author Addressee Description G E LYNN ROWE V.K. Dow identified the principal chloracnegen as the sym Tetrachlorodibenzyl-p-Dioxin in late 64'.Dow was bu Herculos is late 65' and sample was from 3rd or 4th batch shipped and high dioxin thought to "pushing" capacity of plant. Exhibit #P0868 PIN # Date Author Addressee DOW 754888-9 25-NOV-69 G E LYNN JOHNSON, J. E. & ROWE, V. K. Description Notes for J. E. Johnson from G. E. Lynn and V. K. Rowe dated 11-25-69. Exhibit #P0869 PIN # Date Author Addressee D0W7 54888-9 25-Nov-69 GEORGE E LYNN ROWE,V.K. & JOHNSON, JULIUS E. Description These notes outline knowledge lynn & rowe claim Dow had of acnegen, Dow Feb.,1964 problems, 2,4,5- T also contained the chloracnegen; the 3/24/65 meeting; and an outline of contamination of various manufacturers' products.Also cites Hercules at up to 3 ppm. Exhibit #P0871 PIN # Date Author Addressee Description DOW549692-93 01-Dec-69 CHEMICAL EXP LOG Statistical Analysis on Report It 23.14-23-6/5065. Exhibit #P0874 PIN # DOW 28610-1 1 154-8 IV. A. 69 Date Author Addressee 10-Dec-69 GEORGE LYNN HANSEN, J C & JOHNSON, J E MCCOLLISTER, D D &NAEGELE, ROBINSON, V B it OTHERS RE Description Exhibit #P0875 PIN # Date Author Addressee DOW766734-36 12-Dec-69 ALEX WIDIGER CHANG,K Y & LEAVITT, F C DEMONTT, D N & POFFENBERGER, N SCHMIDTKE, D & OTHERS Description Chemical companies are offering flake 2,4,5 T on world market which is strongly rsistent to blooming. We have found the following affects reduce the tendancy to bloom: proglonged heat treating, thinner flakes, the presence of caustic insoluable methoxy compounds. Exhibit #P0883 PIN # Date Author Addressee Description DOW538377 29-Dec-69 CL DUNN F. MCFARLAND & FDA HARRY HAYS & NED BAYLEY L.L. DANIELSON LETTER NOTES THERE HAS BEEN NO RESPONSE TO REQUEST OF 12/5/69 REGARDING EXTENTION FOR ACTION ON PESTICIDE PETITION 8F0669 (2,4,5-T) AND IN ACCORDANCE WITH FEDERAL REGULATIONS WITHDRAWS WITHOUT PREJUDICE SAID PETITION. Exhibit #P0884 PIN # Date Author Addressee 000657-660 07-Jan-70 H H STEHL ROWE, V K & GILL, H SKELLY, N & HALLEY, C DUNN, F Description JANUARY 7, 1970 DOW SCIENTISTS DETERMINED THAT SAMPLES TESTED OF DIAMOND SHAMROCK 2,4,5-T (trichloro- phenoxyacetic acid) AVERAGED 27 PPM (PLUS OR MINUS 8 PPM THEREFORE, AVERAGED 19 PPM - 35 PPM) USING GAS LIQUID-LIQUID CHROMATOGRAPHY METHOD OF EXTRACTION. Exhibit #P0885 PIN # Date Author Addressee Description D817130-218 08-Jan-70 M MCCLURE MORGAN R.W. Meeting to discuss the reasons given by PRD for rejection of the Dow Applications for Temporary Permit to Ship Tordon 166 Mixture and Tordon 169 Mixture herbicides. The outcome of this parley was assent by PRD to reconsider issurance of the Permits is resubmitted. Exhibit #P0886 PIN # Date Author Addressee DOW 1257-59 12-Jan-70 GEORGE E LYNN EGEBERG, DR. & LINDSAY DALE DR. KOTIN, PAUL DR. & BURGER EDWARD DR. MITCHELL IAN DR. & OTHERS Description Concerned that the sample used could have contained a highly toxic impurity. We stronly urge that action concerning the status of 2,4,5-T be held in abeyance until the testing program is completed. Exhibit #P0887 PIN # Date Author Addressee DOW23034-36 12-Jan-70 GEORGE E LYNN EGEBERG, DR. ROGER & HEW LINDSAY, DALE, FBA & BAYLEY, NED D. USDA 4 KOTIN, PAUL, ETAL. Description Lynn's letter to Egeberg and other governmental officials advises Dow's 15420 IV. A. 71 knowledge in 50's; activity of TCDD, Dow1s 1 ppm spec., bionetics samples 27+ ppm contamination; describes Dow's coming territological testing. Exhibit #P0888 PIN t Date Author Addressee Description D0W746134-38 15-Jan-70 V K ROWE BURGER, E.J. & OST PRESIDENT USA Rowe encloses summary data oral toxicity TCDD. Exhibit #P0889 PIN # Date Author Addressee 1232987-91 16-Jan-70 V K ROWE BURGER, EDWARD J. & CC: OTHERS Description IN RESPONSE TO INQUIRY OF OFFICE OF SCIENCE AND TECHNOLOGY, EXECUTIVE OFFICE OF PRESIDENT, WASH., D.C., JANUARY 1970, DR. ROWE MERELY INDICATES THAT HE HAS ENCLOSED TABLES ON RATS AND GUINEA PIGS FOR THE GOVERNMENT TO INTERPRET. "NO RELIABLE DATA FOR RABBITS LD50 TO BE ESTABLISHED." RABBITS DIED. Exhibit #P0891 PIN # Date Author Addressee DOW746169 19-Jan-70 G E LYNN VERRETT, J.M. & FDA RICHARDSON, H.L. & FDA Description Letter recites Dow sending 25 gr. 2,4,5-T representing that sample meets Dow's 1 ppm specification. Exhibit #P0892 PIN # 999600-02 IV. A. 72 o 1 Date Author Addressee Description 19-Jan-70 RUDOLPH H STEHL ROWE, V K it DUNN, F GILL, H & SKELLY, K. BAILEY, C IN SAMPLES OF DOW 2,4,5-T TESTED BY DOW'S OWN LABORATORY, RESIDUES WERE LEFT IN THE 100-150 PPM, BUT DOW'S CLAIMS THE TCDD RESIDUE IS ONLY IN THE 3-8 PPM RANGE. Exhibit #P0893 PIN # Date Author Addressee DOW028238-42 21-Jan-70 G E LYNN BLAIR, E. H. & BROWER, H. H. CRUMMETT, W. R. & FERNANDEZ, J. E. HANSEN, J.C. & 8 OTHERS Description stating he is keeping a record of all samples of 2,4,5-t , 2,4-d and silvex (including derivatives) that are sampled. Exhibit #P0894 PIN # Date Author Addressee 028238-42 21-Jan-70 GEL LYNN ROWE, VK & BLAIR, E H CRUMMETT, W R & FERNANDEZ, J B GETZENDANER, M E & HANSEN, J C. ET AL Description DOW IN-HOUSE MEMO REGARDING ANY OUTGOING SAMPLES TO BE SENT TO THE EPA OR ANY OTHER GOVERNMENTAL AGENCY MUST BE CLEARED THROUGH LYNN. THE SAMPLES SUPPLIED MUST MEET THE DOW SPEC, AND LAB REFERENCE STANDARD OF VERY HIGH PURITY- LIMITED IN SUPPLY MUST BE CAREFUL NOT TO LET JUST ANY OLD SAMPLE OF 2,4,5-T OUT OF THIS COMPANY. Exhibit #P0898 PIN # Date Author Addressee 746158-616 06-Feb-70 V K ROWE FALK, HANS DEPT. HEW & TRIANGLE PARK, NC nO IV. A 73 Description LETTER OF ROWE, FROM DOW TO DR. HANS FALK, DIRECTOR OF LABORATORY RESEARCH, RESEARCH PARK, NORTH CAROLINA, DEPARTMENT OF HEALTH, EDUCATION AND WELFARE DISCUSSING SENDING THE SAMPLES OF PURIFIED 2,3,7,8 -TCDD AND THE EXTREME TOXICITY OF THIS COMPOUND. THE REASONS GIVEN FOR THE DELAY IN SHIPPING WAS THE NECESSARY PRECAUTIONS THAT HAD TO BE TAKEN NOT TO CONTAMINATE OTHERS. ALSO DOW INFORMED GOVERNMENT THAT IT HAD A NEW METHOD OF DETECTING TCDD,"DOW ANALYTICAL METHOD MLW -65.11" WHICH ROWE FORGOT TO INCLUDE, SEE NEXT EXHIBIT IN WHICH DR. FALK RESPONDS. Exhibit #P0902 PIN # Date Author Addressee Description DOW1119842 10-Feb-70 UNKNOWN UNKNOWN LOGAN? DOCUMENT ENTITLED PURCHASE DESCRIPTION HERBICIDE ORANGE SETTING FORTH AN AMENDMENT TO PURCHASE DESCRIPTION AFFID 6840-1, 1/2/70 WITH REGARD TO PARAGRAPH 4.2.4.1. Exhibit #P0903 PIN # Date Author Addressee Description DOW028605 10-Feb-70 HANS L FALK ROWE, DR. V.K. letter of thanks for information and a request for missing data, dow called and the problem of shipment of the dioxin is solved, now the next set of experiments can get under way. Exhibit #P0904 PIN * Date Author Addressee Description 028605 10-Feb-70 HANS FALK HEW & TO ROWE, VK RE 434 DR. HANS FALK OF THE DEPARTMENT HEALTH, EDUCATION AND WELFARE, DIRECTOR FOR LABORATORY RESEARCH NATIONAL INSTITUTE OF 9Q IV. A. 74 HEALTH, TRIANGLE PARK, NORTH CAROLINA IS ASTONISHED AT THE EXTREME TOXICITY DATA THAT DR. V.K.ROWE HAS JUST SENT IN EXHIBIT 434. Exhibit #P0905 PIN # Date Author Addressee Description DOW445809 11-Feb-70 UNKNOWN UNKNOWN LEGATOR, FDA 5c VERRETT, FDA RICHARDSON, FDA & MANY OTHER FDA AND USDA Notice of meeting of government scientists with technical personnel of Dow to discuss chick edema factor methodology shows Dow reps to attend. Exhibit #P0907 PIN # Date Author Addressee Description D0W1130312 13-Feb-70 UNKNOWN DOW AGRI PRODUCTS DOCUMENT ENTITLED SALES SPECIFICATION WITH RESPECT TO 2,4,5-T ACID SETS FORTH 2,3,7,8-TCDD AT 1 PPM. Exhibit #P0908 PIN # Date Author Addressee DOW028232-36 13-Feb-70 GEORGE LYNN WILLIAMS, C G DONALDS, JOHN NAEGELE, R E & SPARTA, TOM JOHNSON, JULIUS 6c ROWE, VK ET AL Description GEORGE LYNN GOVERNMENT REGULATORY RELATIONS FOR DOW CHEMICAL REPORTS IN A CONFIDENTIAL MEETING MEMO THE MEETING BETWEEN DOW (CRUMMETT, HOLDER, LEAVITT LYNN) AND THE FDA HELD IN WASHINGTON, FEBRUARY 11,1970. DR. CAMPBELL MADE THE PRESENTATION FOR FDA; CRUMMETT AND HOLDER MADE THE PRESENTATION FOR DOW. THE FDA IS CONCERNED THAT CDD'S MAY BE WIDESPREAD IN ENOUGH QUANTITY TO BE HAZARD TO HUMANS; CARCINOGENIC RISK;SAME IV. A. 75 PERSISTENCE AS DDT AND BIOMAGNIFICATION ;DR KRAYHILL SAID SHOULD NOT BE PERMITTED; "ONE MOLECULE IS TOO MUCH." DR KRAYBILL. DR. A. D. CAMPBELL, CHIEF CONTAMINANTS BRANCH, FDA WASHINGTON, DC Exhibit #P0909 PIN # Date Author Addressee Description DOW751916-7 20-Feb-70 RALPH C WANDS LONGENECKER, W.H. & FT. DETRICK ROWE, V.K. Wands' director, Advisory Center on Toxicology, NAS, suggests Longenecker arrange meeting with V.K. Rowe to learn something of the toxicology of TCDD. Exhibit #P0912 PIN # Date Author Addressee DOW040862-66 27-Feb-70 GEORGE LYNN MASON, JOHN & WILLIAMS, G.J. SPARTA, TOM & NAEGELE, R.E. DONALDS, JOHN & OTHERS Description Goal: To establish the principal uses of Chlorophenols and to utilize this information in seeking out the ways in which they could possibly be related to the presence of chlorodebenzp-p-dioxins in fats, soap stocks,etc. Exhibit #P0914 PIN # Date Author Addressee Description DOW538598 10-Mar-70 HAROLD ALFORD FED REG & ECONOMIC POISON Letter states additional safety studies are needed for 2,4,5-T currently registered, among others and that data on carcinogenicity or teratogenicity should be submitted immediately. If such data is not available studies are requested immediately. Epidemiological studies also IV. A. 76 requested Exhibit #P0917 PIN # Date Author Addressee Description DOW007830 17-Mar-70 JAMES ILLEGIBLE Dow scientists presented detailed evidence showing that a contaminant rather than the compound 2,4,5-T was probably the cause of birth abnormalities. The National Cancer Institute indicated higher than normal rates of birth defects in test animals treated with massive doses of 2,4,5-T. Exhibit #P0918 PIN # Date Author Addressee 392436-38 17-Mar-70 G L SPARSCHU DUNN, F L & ROWE, V K Description PAPER PRESENTED AT THE MEETING OF THE SOCIETY OF TOXICOLOGY ATLANTA, GEORGIA, MARCH 17, 1970 RESULTS INDICATE A HIGH LEVEL OF MATERNAL AND FETAL TOXICITY TOXICITY TO BE ASSOCIATED WITH 2,3,7,8-TCDD, STUDY BY DOW. TERATOGENIC Exhibit #P0919 PIN # Date Author Addressee D0W392434-35 17-Mar-70 J L EMERSON GERBIG, C G & ROBISON, V B Description THIS ABSTRACT WAS PRESENTED SIMULTANEOUSLY WITH THE EXHIBIT NO'S 437 AT THE SOCIETY OF TOXICOLOGY IN ATLANTA, GA; HOWEVER THE FINDINGS OF THIS GROUP OF DOW SCIENTISTS DISAGREE WITH THE BIONETICS RESEARCH LABS, BETHESDA, MD. Exhibit #P0921 IV. A. 77 PIN # Dace Author Addressee D0W120584 18-Mar-70 GEORGE E LYNN HAYS,HARRY W. & USDA LINDSAY,DR.DALE & FDA/HEW BCCDOW OTHERS & & ACTION FILE 245T Description leteter seeks to assure Department of Agriculture about the quality of the composition of commercial 2,4,5-T acid produced by Dow Chemical. Claims that in 1965 a rigid production standard was imposed by Dow of less than 1 ppm of TCDD in 2,4,5-T. Exhibit #P0924 PIN # Date Author Addressee DOW582853 23-Mar-70 C DOW JOHNSON, J.E. & LUECK, A . T . LYNN, G.E. & BLAIR, E.H. Description Memo re status of 2,4,5-T backup program. Exhibit #P0926 PIN # Date Author Addressee D0W28243-44 26-Mar-70 GEORGE LYNN JOHNSON, J & WILLIAMS, C J NAEGELE, R & DONALDS, JOHN BLAIR, E & OTHERS Description Dow and Monsanto can begin to predict where the bulk of the chlorophenols are going and evaluate some of the potentials for contaminent problems. Exhibit #P0927 PIN # Date Author Addressee DOW028243-44 26-Mar-70 GEORGE E LYNN WILLIAMS, C J 4 NAEGELE, R. E. DONALDS, JOHN E. & SPARTA, TOM A. LEAVITT, F. C. & OTHERS 15427 IV. A. 78 Description the report is from meetings 2/25, 3/19, 3/23. Exhibit #P0928 PIN # Date Author Addressee Description DOW582854-55 26-Mar-70 GEORGE E LYNN JOHNSON, JULIUS & WILLIAMS, G.J. OTHERS AT DOW Lynn writes Johnson, Rowe and 12 others at Dow to report on meetings of 02/25, 03/19, and 03/23, re dioxin and Monsanto koppers human health problems. Exhibit #P0929 PIN # Date D0W1104-8 31-Mar-70 Author Addressee BENJAMIN B HOLDER LYNN, GEORGE E. & NO OTHERS SHOWN Description Letter is a summary of clinical information distirbuted to various institutions by Dow regarding the 1964 chloracne episode at the Midland Plant. Attached to the letter is a "Review of occupational health problems associated with th the manufacture of chlorinated phenols a t Midland, MI in 1964. Notes that disease primarily affects the skin and with extreme exposure "... a general organ toxicity can result." Liver and nervous disords ders naote noted and no specific treatment for disease is known. Exhibit #P0930 PIN # Date Author Addressee 1170342 31-Mar-70 V K ROWE DUNN, F L & GORDON, H L HOLDER, B B 5c HINMAN, C W HOYLE, H R 5c JOHNSON, J E Description WE DO NOT HAVE ENCLOSURE IV. A. 79 154k Q Exhibit #P0932 PIN # Date Author Addressee Description D0W1103 02-Apr-70 GEORGE LYNN In discussing the attached information with Dr. Holder he says the chloracne problem was related to the "accident" in the 2,4,5-T plant and the culprit was principally 2,3,7,8-T. Exhibit #P0934 PIN # Date Author Addressee Description DOW999363-67 07-Apr-70 CHARLES KRAMER JOHNSON, JULIUS One hundred thirty employees who have worked more than six months in areas where exposure to 2,4,5-T occurred and on whom recent medical examination data was available. Exhibit #P0935 PIN # Date Author Addressee Description DOW119849-68 07-Apr-70 CHARLES KRAMER JULIUS JOHNSON At present we are involved in an extensive reworking of the program based on review of the "first cycle" results. Approximately 10 percent of the subjects participating in the health inventory have prompt follow up by a physician on the basis of suspected abnormalities detected during inventory. Exhibit #P0936 PIN # Date Author Addressee Description DOW549641-91 10-Apr-70 F D AXE DOW Measurements to describe the chemical exposures of workmen engaged in the IV. A. 80 1 manufacture of 2,4,5-T. Dry Dust of 2,4,5-T has the capacity to produce upper respiratory irritation. Dust levels are frequently high enough to be very noticebly irritating. Observations indicate nasal irritation sneezing and a bitter taste may result from brief exposures. Exhibit #P0937 PIN # Date Author Addressee 549641-660 10-Apr-70 F D AXE FILE & LYNN, G E DELINE, DD & SCHMIDTKE, D J HODSON, R E & MILLER, D E OTHERS Description BIOCHEMICAL RESEARCH LAB AT DOW CHEMICAL CO., F. D. AXE DISTRIBUTED A STUDY OF CHEMICALLY EXPOSED WORKERS IN BUILDING 267 BUILDING (2,4,5-T PLANT); ALTHOUGH HE STATES THE LEVELS OF EXPOSURE ARE BELOW MINIMUN THRESHOLD LIMIT VALUE, DRY DUST HAS CAPACITY TO PRODUCE UPPER RESIRATORY IRRITATION AT LEVELS MUCH LOWER THAN TLV; RECOMMENDS IMPROVE DUST CONTROL AT THE PACKING STATION- DUST ESCAPES FROM SEAL(FAULT OF EITHER SEAL OR INSUFFICIENT AIR VELOCITY). Exhibit #P0939 PIN # Date Author Addressee Description DOW392412-23 15-Apr-70 JULIUS JOHNSON SENATE COMMITTEE Reference to birth defects observed in tests. The most sensitive toxic reaction observed in humans to this inpurity was manifested by a condition known as chloracne, a skin disorder suffered by teenagers. Exposure to this waste oil was the cause of the acne in the workmen. Exhibit #P0940 ; pin # DW 392412-23 Date 15-Apr-70 IV. A. 81 15430 Author Addressee JULIUS E JOHNSON SUBCOMMITTEE ON & ENERGY Description STATEMENT BY JULIUS E. JOHNSON, VICE PRESIDENT AND DIRECTOR OF RESEARCH, THE DOW CHEMICAL COMPANY, BEFORE THE SUBCOMMITTEE ON ENERGY, NATURAL RESOURCES AND THE ENVIRONMENT OF THE SENATE COMMITTEE ON COMMERCE, DATED 04-15-70. Exhibit #P0941 PIN # Date Author Addressee DOW130436-7 15-Apr-70 JULIUS JOHNSON USA PUBLIC & HART SENATE COMM. Description Copies from Dow produced documents of minutes of Julius Johnson's testimony given April15, 1970, before Hart Senate sucommittee on the environment, presumably from the Federal Register or Congressional Record; confirms Johnson of Dow made disclosures contained in full text of speech drafted for him at Dow. Exhibit #P0945 PIN # Date Author Addressee Description DOW547219-20 20-Apr-70 HARRY W HAYS ECONOMIC POISONS This herbicide may present an imminent health hazard to women of child-bearing age and has recommended suspension of certain registered uses of 2,4,5-T. In order to prevent an imminent hazard containing 2,4,5-T to the public it is necessary to suspend the registration for these products. Exhibit #P0946 PIN # Date Author Addressee Description DOW547221 20-Apr-70 HARRY HAYES DOW CHEMICAL It is hereby found that in order to prevent 15431 IV. A. 82 an imminent hazard to the public it is necessary to suspend the registration for purducts containing 2,4,5-T. Exhibit #P0947 PIN # Date Author Addressee Description 999173 23-Apr-70 R L LAPE LYNN, G E & ROWE, V K FERNANDEZ, J DOW TESTED 10 BATCHES OF AGENT ORANGE FROM FT DETRICK AND FOUND IT CONTAINED BETWEEN 1-15PPM OF 2,3,7,8-TCDD Exhibit #P0948 PIN # Date Author Addressee Description DOW119606 01-May-70 G J WILLIAMS Letter written by G.J. Williams stating how he feels that Dow should make its position known to the rest of the Government rather than give the Department of Defense an option. Exhibit #P0949 PIN * Date Author Addressee Description D0W130323-24 11-May-70 PROD AND MKT CANADA DEPT AGR Further evidence show that 2,4,5-T is potentially capable of causing abnormal development. This dioxin can also cause a serious skin condition known as chloracne. Findings suggest that this couldd constitute a hazard to children and women exposed during pregnancy. Exhibit #P0950 PIN # Date Author DOW582846-7 11-May-70 FRED LEAVITT IV. A. 83 Addressee BLAIR, E. & 31 OTHER DOW EMP. Description Memo re environmental problems re chlorinated phenols. Exhibit #P0951 PIN # Date Author Addressee Description D0W119791-7 14-May-70 GARETH OWEN LYNN, GEORGE E along with the letter are the results of teratological studies done in Charles river cd rats. Exhibit #P0952 PIN # Date Author Addressee DOW582836-7 22-May-70 R A PLEPYS LYNN, G. & BLAIR, E.H. ROWE, V.K. & HOLDER, V.B. LUECK, A. & 19 OTHER DOW EMP. Description Minutes of meeting eco-studies of chlorophenols. Exhibit #P0954 PIN # Date Author Addressee DOW770705-09 25-May-70 P BRADY HABERSTROH W.H & WILLIAMS L VOGELSANG P & CHASE F KENSICKI R & SCHMIDTKE D Description The manufacture of Phenoxy-Herbicides requires the removal of unreacted phenols from the reactor product mix. Laboratory data indicates that a flow of ------ lbs. of Trichlorobenzene for each pound of Silvex solution using --- stages will remove ------ of the unreacted phenol. Exhibit #P0955 IV. A. 84 15433 PIN # Date Author Addressee Description DOW956820-24 28-May-70 GEORGE LYNN US DEPT OF AGRIC. Cancellationof 2,4,5-T Products bearing certain directions for use. All uses on food crops intended for human consumption shall cease. Exhibit #P0956 PIN # Date Author Addressee Description D0W119607 03-Jun-70 BARSTOW BLDG DOW CHEMICAL CLIFFORD M. HARDIN TORDON has limited registration for use on non-food cropland and right of waymaintenance in the United States. Requests for registration on pasture and rangeland have been submitted. Exhibit #P0960 PIN # Date Author Addressee DOW424633-64 15-Jun-70 C J WILLIAMS LAIRD, MELVIN & DR. LEE DUBRIDGE ELLIOT RICHARDSON & WALTER J. HICKEL Description There is abundant evidence that 2,3,7,8-T is highly toxic. The Dow Company recommends stronly that the government set appropriate specifications and controls to insure that no 2,4,5-T be used if it contains more than on part per million 2,3,7,8-T. Exhibit #P0961 PIN # Date Author Addressee Description DOW392412-23 15-Jun-70 JULIUS JOHNSON SENATE COMMITTEE The possibility of a highly toxic impurity being formed in 2,4,5-T as a side reaction under conditions of elevated processing temperatures. This impurity is a condition known as chloracne, a skin disorder. It is IV. A. 85 in these oils that the impurities are con centrated. Exposure to this waste oil was the cause of the acne in the workmen. Exhibit #P0962 PIN # Date Author Addressee Description DOW 424633-4 15-Jun-70 G J WILLIAMS LAIRD, HON MELVIN R G. J. WILLIAMS , VICE PRESIDENT OF DOW, LETTER TO HON. MELVIN R. LAIRD, SECRETARY OF DEFENSE, DATED 06-15-70. Exhibit #P0966 PIN # Date Author Addressee DOW119979 29-Jun-70 D D MCCOLLISTER DREW BAKER, JR. & DR. W. UPHOLT MR. K.K. KRAUSCHE & MR. C.L. DUNN Description Analytical chemists of the Dow Chemical Co. have utilized a GLC procedure essential that for analyzing 2,3,7,8-T. The procedure was sensitive enough to detect as little as 0.1 ppm. Exhibit #P0967 PIN # Date Author Addressee Description DOW129637-42 01-Jul-70 SAMUEL EPSTEIN READER OF ENVIRON Linking birth defects to the week killer 2,4,5-T have resulted in restrictionson the use of this product. The warnings stem from the discovery that several variants, or esters of 24-D including the one commonly used in weed control, have caused birth defects in animals. Exhibit #P0968 PIN # Date DOW766740-50 20-Jul-70 IV. A. 86 15435 Author Addressee KOU YUAN CHANG TOU,JAMES C. & LOOK, A. SHEETZ, D. & DEMOTT, D.N. POFFENGERGER N. & OTHERS Description Two major concerns in Che production of 2,4,5 T are the chloracne problem and the product quality. It is unlikely that a change in the reaction con- dition of the present process can eliminate the formation of raethxydichlorophenols. Exhibit #P0970 PIN # Date Author Addressee Description DOW149715-42 23-Jul-70 PRESIDENT ADVISORY COMM In general, 2,4,5-T residues can be expected to be unstable materials in the environment. Chemistry analysis is provided. Exhibit #P0972 PIN # Date Author Addressee DOW367964-66 11-Aug-70 MARGUERITE L LONG K.C. BARRONS & E.M. BLAIR J.M. DAVIDSON & G.E. BLAIR D.D. MCCOLLISTER & OTHERS Description Studies by the Dow Chemical have shown that cows fed 700 ppm 2,4,5-T in the total diet gave milk containing in the neighborhoold of 0.3 ppm 2,4,5-T. Exhibit #P0974 PIN # Date DOW12388-423 26-Aug-70 Author JULIUS JOHNSON Addressee DOW CHEMICAL Description The purpose is to explore possible public health consequences of widespread use. The data presented will emphasize exposure v. toxicity and chemistry. There were detectable levels of 2,4-D and 2,4,5-T in .5438. IV. A. 87 the air up to 0.06 micrograms per cubic meter. Direct skin contact, together with vapor and mist exposure are encountered in varying degress by applicators and employees in manufacturing plants. Exhibit #P0975 PIN # Date Author Addressee Description DOW018868-83 15-Sep-70 UNKNOWN UNKNOWN MOUNTAIN LAKE Sc ROW MAINTENANCE CONFERENCE. this was an oral presentation, along with the article are chemical diagrams. Exhibit #P0978 PIN # Date Author Addressee D0W538823-30 01-Nov-70 G L SPARSCHU DUNN F L (AUTHOR) & ROWE V K (AUTHOR) Description Exhibit #P0979 PIN # Date Author Addressee DOW751854-55 18-NOV-70 D D MCCOLLISTER J.E. JOHNSON Sc G.E. LYNN E.H. BLAIR & P.M. RITTY E.E. KENAGA Sc OTHERS Description One notable void in this package is the information that Dr. Danielson requested on the acute oral toxicity of the various chlordioxins. A group of experts from EP Board in Sweden have been appointed to evaluate the phenoxy herbicide situation. Exhibit #P0982 PIN # Date Author DOW538372 05-Dec-70 CL DUNN IV. A. 88 15437 Addressee JAMES LAMB & HEW FDA DUBRIDGE & H.L. LEY NED BAYLEY & H. W, HAYS Description requests an extension until April 1970 on the Pesticide Petition 870669 on 2,4,5, -T which deadline was set for january 1,197 J January 1 1970. Letter states that additional studies are underway which will would present aimportant data to be reeviewed. Exhibit #P0984 PIN # Date Author Addressee Description DOW 00842 11-Dec-70 L A DALTON J.E.JOHNSON Conclusion of tested showed that all skin contact with the test material should be avoided. Exhibit #P0985 PIN # Date Author Addressee Description DOW120142-9 30-Dec-70 MATTHEW MESELSON WESTING, ARTHUR H. & CONSTABLE, JOHN D. COOK, ROBERT E. herbicide assessment commission of the american association for the advancement of science. Exhibit #P0986 PIN # Date Author Addressee Description DOW579003-9 31-Dec-70 MIKE SIEDEL This spec has no written description, it is a diagram of the Alkaline Hydrolysis. Exhibit #P0995 PIN # Date JUS215-704-8 08-Mar-71 IV. A. 89 15438 Author Addressee Description RICHARD M PATTERSON CHMN.ARMED FORCES & PEST CONTROL BOARD WASH.,D.C. Gov't relations mgr. Dow writes AFPCB to advise Dow's capabilities in destroying herbicides, the combustion of TCDD on incineration, and encloses report re same given 2-24-71 ; states "more than 40%) of the Orange inventory is unusable because of a dioxin level higher than one part per million". Exhibit #P1000 PIN # D0W120239-40 Date 31-Mar-71 Author A T TALCOTT Addressee KANESHIRO K.R. & O'CONNOR J.N MCCOLLISTER D. D. & LYNN G.E. PIPPENGER P. & OTHERS Description This letter contains the total number of containers of 2,4,5-T in inventory on April 29, 1970. Exhibit #P1001 PIN # Date Author Addressee Description D0W119670-84 01-Apr-71 DOW DOW CHEMICAL The EPA has also advised that a specific tolerance for phenoxies in grass is necessary: a tolerance in grass had not been requested by ITFPHT as it did not appear necessary. Exhibit #P1005 PIN # Date Author Addressee DOW 047457 01-Jun-71 GEORGE LYNN R.E. NAEGELE & JULIUS JOHNSON F.H. BLAIR & T.A. BYMAS D.D. MCCOLLISTER & OTHERS Description A letter stating that a report will be IV. A. 90 considered by the Administrator of EPA in making his descions about the suspended and cancelled registrations of 2,4,5-T. Exhibit #P1009 PIN # Date Author Addressee DOW550150-71 06-Jul-71 R D OLSEN D. D. DELINE& C.Z. BAILEY E. M. SEIDE&L R.E. SNYDER B.B. HOLDER & OTHERS Description Particular emphasis placed on potential chloracne hazards. Wipe Samples indicate an increase to an all time high of 38% in February and May, 1971. Exhibit #P1010 PIN # Date Author Addressee Description H27741 29-Jul-71 F STEHL CRUMMETT, W & CHAMPLAIN,C .E OTHERSAT DOW Report of Analysis of Hercules, 2,4,5-T sample x-17394-21-5 showing .1SppmTCDD and reports 50 ppb in dow sample. Exhibit #P1013 PIN # Date Author Addressee Description D0W119883-89 19-Aug-71 V K ROWE BATES, RICHARD DR. & LYNN, G.E. ROWE VK Summary of Toxicological information graphd and diagrams. Many Exhibit #P1014 PIN # Date Author Addressee H4E1-2 28-Oct-71 DONALD D MCCOLLISTER WEIR,DR. ROBERT & BIONETICS LABS FRAWLEY, J.P. IV. A. 91 1;Ov/ Description Dow encloses their lab reports analyzing the 245T used by Bionetics in their rat study indicating more recent studies in mice used Hercules product ,18ppm TCDD Exhibit #P1016 PIN # Date Author Addressee Description D0W7 67059-60 01-Nov-71 DOW DOW This is directions on how to use Veon Brush Killer. Exhibit #P1017 PIN # Date Author Addressee Description H4(E)0000 09-Nov-71 E ROSS HART MCCOLLISTER,D.D. & FALSEY, DR.J.P. WEIR.DR.R.J. Weir asked Hart of Bionetics to respond to Dow's 10-28-71 re use of Hercules 245T in continuing bionetics lab mice studies; Hart unable to comment but agrees that "caution must be exercised in statements that would appear in publication". Invites Dow to make specific suggestions re that. Exhibit #P1018 PIN # Date Author Addressee H4(E)813 09-Nov-71 E ROSS HART FRAWLEY,DR.J.P. & NO OTHERS Description Hart enclosed abstract submitted for inclusion in program of Toxicology Society in March, referencing fact that no specific results were obtained and solicits suggestions from Frawley as to how to state results obtained. Exhibit #P1019 PIN # 538832-630 IV. A. 92 I 5 4 d^lJl Date Author Addressee 09-Nov-71 G L SPARSCHU DUNN, F L & ROWE, V K Description ARTICLE WHICH IS PUBLISHED OF THE DOW STUDY AGREEING WITH BIONETICS REPORT AND COMPORTS WITH THE PREVIOUSLY SUBMITTED ABSTRACT. Exhibit #P1020 PIN # Date Author Addressee H4(K)240 15-Nov-71 W C KENYON SHEARER,P.W. HALL,DR.R.T. & TAVES, DR.M.A. & FORD,J.J. Description Hercules cannot refute results reported, but notes ambiguity in statements of reports, which ref- erence both .18ppra and elevations corresponding to 3.8ppm TCDD. Exhibit #P1022 PIN # Date Author DOW129635-36 17-Nov-71 G LYNN Addressee Description Exhibit #P1023 PIN # Date Author Addressee Description DOW026811-2 04-Dec-71 J C WILSON the dow chemical company request for preliminary toxicological studies form on the product 2,4,5-t acid, analysis for this is on form ral-al-24-6??? Exhibit #P1028 PIN # Date Author Addressee 1 5 4 { 'Z H4(K)254-5 17-Jan-72 D D MCCOLLISTER HART,DR.E.ROSS & BIONETICS LABS IV. A. 93 DUNN,C.L. & WEIR,DR.R.J. Description USDA & FDA had published that Hercules lot of 245-T used in animal studies was "less than .05ppm"; Dow states "in our opinion there was no method available in 1970 which could be shown with adequate documentation to detect as little as .05ppm". Dow suggests bionetics ignores the differences of opinion and merely present their results as "on the order of .05ppm". Exhibit #P1031 PIN # Date Author Addressee Description D0W126112-18 15-May-72 DOW CHEMICAL RENEGOTIATION BOARD Text of presentation of Dow to May 15, 1972 meeting of statutory renegotiation board where Dow attempts to obtain renegotiation of the price that received for its Orange and gives argument and support thereof. Exhibit #P1032 PIN # Date Author Addressee Description DOW053909 1O-Jul-72 B A SCHWETZ GEHRING P J Work to be done to supplement the existing information on the toxicity of the chlorinated dibenzo-p-dioxins. Exhibit #P1033 PIN # Date Author Addressee Description DOW123061-68 06-Oct-72 COMPANY DOW CHEMICAL two bibliography's - 1) determination of chlorinated dibenzo-p-dioxins and 2)analytical chemistry of herbicides Exhibit #P1034 IV. A. 94 PIN # Date Author Addressee Description D0W119557 22-Nov-72 T YATES DCASR DETROIT Award Contract Exhibit #P1049 PIN # Date Author Addressee D0W710839-56 21-Feb-74 G J ROUSH J.L. DEGEER & R.E. WINTERS F.L. WILLIAMS & R.R. LANGER B.B. HOLDER & OTHERS Description Bldg. 267 of the Midland Division is slated to be ravaged. The chemicals of concern were judged to be TBC and TCBD. Tertiary Butyl dust is highly irritating to the skin and eyes. Eye contact may cause permanent loss of vision. Exhibit #P1050 PIN # Date Author Addressee Description DOW 005592 08-Jul-74 MARGUERITE LENG MCCOLLISTER, D. D. HANDWRITTEN MEMOS BETWEEN MARGUERITE LENG AND D. D. MCCOLLISTER OF DOW DATED 07-08-74. Exhibit #P1060 PIN # Date Author Addressee Description DOW119974-77 29-Mar-77 UNKNOWN WJR DOW Four page document contains Dow's capability for pro- duction of 2,4-D and 2,4,5-T and delinates herbicide contracts , Defense General Supply Center, dated March 29, 1967. Exhibit #P1061 IV. A. 95 PIN # Date Author Addressee Description NONE 15-Sep-77 PAUL F OREFFICE ALL DOW SUP'RS President Orrefice of Dow writes all Dow U.S.A. Supervisors regarding Dow's Records Retention Policy and contains "WHEN IN DOUBT, THROW IT AWAY!!!" Exhibit #P1066 PIN # Date Author Addressee Description DOW047290 21-Jun-78 P J GEHRING CROW DR. This letter states by Mr. Gehring that he cannot support a study using doses which are likely to produce discernible effects. Exhibit #P1091 PIN # Date Author Addressee Description D0W1132503 03-Mar-81 LU LAPOINTE RAY HOLMES LETTER INDICATES THAT HOLMES REFERRED TO THE TCDD PROBLEM AS 10/5/64 WHICH ACCORDING TO THE AUTHOR WAS SOME TWO MONTHS PRIOR TO THE ANALYTICAL LABS ISOLATION OF THE CHLORAGEN. LETTER STATES THAT IT APPEARS THAT SOME "PRESSURE" WAS APLLIED TO HOLMES TO CONTINUE PLANT OPERATIONS WITH ONLY MINOR CHANGES THAT HOLMES WAS NOT IN AGREEMENT WITH. Exhibit #P1107 PIN # Date Author Addressee Description NO NUMBER 16-Dec-83 ARVIN MASKIN WITT, GRETCHEN LEAH EXCERPTS FROM DECLASSIFIED RANCH HAND DOCUMENTS PRODUCED BY THE GOVERNMENT. IV. A. 96 Exhibit #P0009 PIN * Date Author Addressee Description 1079 27-Dec-00 G P RUSSELL MONSANTO COMPANY Document requesting constant temperature control to reduce TDD. Exhibit #P0017 PIN # Date Author Addressee Description 006005 R EMMET KELLY M D UNINTELLIGIBLE Document referring to medical 2,4,5-T manufacturers. history of Exhibit #P0018 PIN # Date Author Addressee Description 73256-62 J AND K H KIMMIG SCHULTZ UDELL, W Kimmig & Schultz article translated 3/59 with copy sent to Udell. Title of said article is "Occupational Acne". Exhibit #P0019 PIN # Date Author Addressee Description 1570-1577 UNKNOWN UNKNOWN UDELL? HAND WRITTEN NOTES FROM FEBRUARY-AUGUST 1965 ENTITLED 2,4,5-T QUALITY NUMBERED 9-23-76001-2102 WITH PROBLEM AS REDUCTION OF CONCENTRATION OF CHLORACNa GENIC T.D.D. IN 2,4,5-T PRODUCT AND IMPROVEMENT OF COLOR OF PRODUCT. IV A. 97 Exhibit #P0020 PIN # Date Author Addressee Description 1079,1068 G P RUSSELL NITRO Document states in part that TDD can be reduced via the utilization of automatic temperature controls in the autoclaves. The manual controls are "very crude" and permits variations of plus and minus 4 degrees while the auto control will limit this to plus or minus 1 degree. Exhibit #P0021 PIN # Date Author Addressee Description 46112-13 UNKNOWN UNKNOWN UNKNOWN Page 3 Sc 4 of 16, Professional and Technical Personnel Required. Exhibit #P0022 PIN # Date Author Addressee Description 73992 JAMES M REA SIDO, G ROBERT 2,4-D/2,4,5-T Butyl Esters, USDA Reg. No. 524-150. Your application of April 8, 1970, is the subject of this document. Exhibit #P0023 PIN # Date Author Addressee Description 89678-92 JUDITH A ZACK ET AL UNKNOWN The Mortality Experience of Workers Tetrachlorodibenzodioxin in a Trichlorophenol Process Accident. of Dr. Suskinds mortality study. to Draft 154 aKJ IV. A. 98 Exhibit #P0024 PIN # Date Author Addressee Description 88248-51 JUDITH A ZACK ET AL UNKNOWN The Mortality Exerience of Workers Exposed to Tetrachlorodibenzodioxin in a Trichlorophenol Process Accident. Exhibit #P0044 PIN # Date Author Addressee 4872 14-Sep-48 M C MCKONE R L SIBLEY & W G KRUMRICH C A HOCHWALT & D J BEAVER SCOTT-RUABON & FILE COPY Description Final Report on 2,4,5-T dated 9/14/48. Exhibit #P0046 PIN # Date Author Addressee 71386 23-May-49 C J MCKONE W G KRUMMRICH & DR D J BEAVER P G MARSH & H R NASON DR R L SIBLEY & DR W P METZER Description Interim Report on an Investigation of the 2,4,5- Trichlorophenol Process. Nitro Report No. ?107 dated May 23, 1949. Exhibit #P0048 PIN # Date Author Addressee Description 042220 16-Aug-49 LOUIS SCHWARTZ M D (?) C. NELSON Document discusses medical descriptions of individuals affected by the Nitro incident of 1949. 1 jl 5448 IV. A. 99 Exhibit #P0053 PIN # Date Author Addressee Description 73928 01-Mar-50 J CRESCE 2,4,5-T EMPLOYEES Hygiene requirements in 2,4,5-T plant is the subject of this document. Exhibit #P0055 PIN # Date Author Addressee Description 74618-42 30-Jan-51 G ROBERT SIDO DEPT OF AGRICULTURE Registration of 2,4,5-T with U.S.D.A. the subject of this document. is Exhibit #P0056 PIN # Date Author Addressee Description 75359 02-Apr-51 F V REAGEL MONSANTO CHEMICAL CO User of 2,4,5-T developed health condition working at Missouri State Highway Department. Exhibit #P0057 PIN # Date Author 75360 09-Apr-51 R EMMET KELLY M D Addressee F V REAGEL Description Letter indicating that injury related to 2,4,5-T use was unrelated. IV. A 100 15449' Exhibit #P0058 PIN # Date Author Addressee Description 33391 03-Jan-52 WILLIAM F ASHE M D DR HORACE D DAVIDSON Letter requesting liver biopsy of Jessie Steele from Dr. Wallace. Exhibit #P0059 PIN # Date Author Addressee Description 42047 03-Mar-52 XYZ BOWLES VIRGINIA WEBB Document refers to list of 119 employees injured at Nitro in 1949. Exhibit #P0060 PIN # Date Author Addressee Description 1771 08-Aug-52 W H AND E A SEATON AND FIKE L C WEGER & M C THRODAHL W P METZNER & R L SIBLEY OTHER EMPLOYEES Nitro Progress Report regarding atmospheric pressure hydrolysis of TCB and TCP. Exhibit #P0062 PIN * Date Author Addressee 1587-89 07-Nov-52 E A FIKE DR W P METZNER Sc DR G W STEAHLY Description Proposal that TCP be distilled as a means of reducing toxicity. 15450 IV. A 101 Exhibit #P0063 PIN # Date Author Addressee Description 1580-86 17-Nov-52 W G CANHAM W A GARLETTE JR & L C WEGER H G KIRTLEY & E R HAMILTON E G VOLZ Minutes of Meeting November 11, 1952 Sodium Trichlorophenate Purification with the hopes of reducing toxicity was the subject of the document. Exhibit #P0065 PIN # Date Author Addressee Description 41815 03-Jun-53 H H SCHRENK PH D MR. SMITH Document referring to report on rabbit-ear chloracne tests utilized prior to June 1953. Exhibit #P0066 PIN # Date Author Addressee Description 4675-80 13-Oct-53 H L HUBBARD ET AL UNKNOWN Final report on Minor Plant investigation 1952 through 1953 is the title of this document. Exhibit #P0068 PIN # Date Author Addressee Description 71194-222 24-Nov-53 T R BOCH NITRO INDIVIDUALS Process Description For The Manufacture of 2,4,5-T in Department 57. TV. a . m ? Exhibit #P0069 PIN # Date Author Addressee Description 71223-66 03-Dec-53 L P HARICH ET AL NUMEROUS PERSONNEL Process Description for The Manufacture of Sodium 2,4,5-Trichlorophenate in Department 64 Building 51. Exhibit #P0070 PIN # Date Author Addressee 73930 07-Jan-54 J CRESCE BILLY HICKS ET AL & LISTED EMPLOYEES Description Memo notifying 32 workers that they will be layed off unless an adequate number of 2,4,5-T employees can be obtained. Exhibit #P0072 PIN # Date Author Addressee 75409-38 01-Dec-54 D P CLAYPOOL ET AL J CRESCE & C M EAKER R E HOWARD & VARIOUS OTHERS Description Final Report On 2-(2,4,5-Trichlorophenoxy) Propionic Acid dated 12/1/54. Exhibit #P0075 PIN # 74597- Date Author Addressee Description 05-Jul-55 MONSANTO CO UNKNOWN Numerous 2,4,5-T Butyl Ester Brush Killer Labels. IV. A. 103 Exhibit #P0076 PIN # Date Author Addressee Description 74530-91 05-Jul-55 COMPANY MONSANTO UNKNOWN 2,4,5-T Butyl Ester 524-83. B.K. Registration No. Exhibit #P0082 PIN # Date Author Addressee Description 42170-73 18-Nov-55 L C WEGER SODEN, R & MCCLAIN, J R KELLY MD, R E Letter discussing in part psychoneurosis amongst Nitro workers dated 11/18/55. Exhibit #P0084 PIN # Date Author Addressee 21663-68 13-Dec-55 R A MURIE LESSLIE, T E SOLSTEN, R T & ROARK, J N & STEAHLEY, G W Description Method of analysis for 2,4,5-T BE Ester. Exhibit #P0086 PIN # Date Author Addressee 22986-87 16-Feb-56 R W WISE GEISMAN, R A & EDWARDS, P W LUECKE, C P & LESSLIE, T E Description Method of analysis for the purpose of determining sodium 2,4,5-T in 2,4,5-T ac Exhibit #P0089 PIN # Date Author Addressee Description 73926 13-Apr-56 T R BOCH UNKNOWN Document lists total number of workers and number of chloracne cases since January 1953 in the Monsanto plant. Exhibit #P0090 PIN # Date Author Addressee Description 41652-42177 13-Apr-56 NONE NONE NONE Transcript of Workmens Compensation Hearing of Louis Hallman, individual injured in the Nitro incident in 1941. Exhibit #P0091 PIN # Date Author Addressee 5867-69 12-Jun-56 ELMER P WHEELER KELLY, R EMMET & NASON, H K SODEN, R E & WEGGER, L C Description Letter discusses meeting with German scientist, Dr. Oettel, wherein it was discussed that the Germans exposed in the 1953 Badische incident had similar symptoms as the Nitro workers, i.e., fatigue, vertigo, loss of libido, painful joints, etc. Exhibit #P0092 PIN * Date Author Addressee Description 75448-73 11-Sep-56 T E LESSLIE ET AL NUMEROUS MON. EMP. Study of prepn. of 2-butoxyethyl 2,4,5-trichlorophenoxyacetate from the reaction of sodium trichlorophenate with 2-butoxyethyl chloroacetate is described. 1 5 4 ;tr-,4 IV. A. 105 Exhibit #P0097 PIN # Date Author Addressee 77-80 03-May-57 J AND K H KIMMIG SCHULTZ LUECKE & SILVERSTEIN TRAPP & OTHER Description Rough draft translation of the 1957 Kimmig and Schultz article. Exhibit #P0098 PIN # Date Author Addressee 65551 13-Jun-57 L P HARICH MCCLAIN, J R & LUECKE, C F CONWAY, C S & SHIFT FOREMAN Description Document indicates in part that the 2,4,5-T Plant had a crew of 5 men. Exhibit #P0101 PIN # Date Author Addressee Description 87829-Jul-57 C H BOEHRINGER SOHN DR. PRAHL Partial translation of letter from C.H. Boehringer Sohn, on Hooker Electrochemical Company stationery, which identifies Dioxin in Tri-Chlorophenol. Said document further discusses the properties of Dioxin. Exhibit #P0108 PIN # Date Author Addressee Description 71273-330 06-Feb-58 L P HARICH ET AL NUM. DEPTS. MONSANTO Standard Manufacturing Process for 2,4,5-T Acid, revised 11/24/53. Exhibit #P0114 PIN # Date Author Addressee Description 1836-1891 30-Jul-58 L HARICH NITRO RESEARCH ET AL PAPER DESCRIBES STANDARD MANUFACTURING PROCESS FOR SODIUM 2,4,5-TRICHLOROPHENATE CONSISTS OF 56 PAGES IN DATA SHEETS, EXHIBITS AND APPENDICES. NOTED IN PAPER THAT SODIUM TCP PRODUCES A FORM OF DERMATITUS KNOWN AS CHLORACNE AND THAT CARE MUST BE TAKEN TO AVOID CONTACTING SOLUTION OR HOT VAPORS OF THE SOLUTION. ALSO NOTED AS A CORROSIVE MATERIAL. Exhibit #P0118 PIN # Date Author Addressee Description 73736 25-Mar-59 PAUL N BIVEN NONE Specif ications for 2,4,5-T Acid. Exhibit #P01 19 PIN # Date Author Addressee Description 73065 01-May-59 JOHN RODDY STARRETT ATTORNEY FROM WAUSAU INSURANCE COMPANY OF WISCONSIN REQUESTS INFORMATION REGARDING THE TOXICITY OF 2,4-D AND 2,4,5-T AS AN EMPLOYEE ALLEGED SPRAYING OF THESE CHEMICALS ADVERSELY AFFECTED HIM. REQUEST PERTAINS TO ANY DATA, PAMPHLETS OR OTHER REFERENCES REGARDING CHEMICALS AND THEIR EFFECTS ON HUMANS. Exhibit #P0120 PIN # Date Author Addressee Description 73063 06-May-59 J. Starrett Kelly & Olcott Zorsch Letter requested that letter of Roddy dated Dr. Kelly respond 01-May-59. to s Exhibit #P0121 PIN # Date Author Addressee 73064 08-May-59 Emmett Kelly Roddy & Olcott Zorsch & Starrett Description Kelly responded that they had not been encountered any clinical evidence of injury to their employees. Exhibit #P0122 PIN # Date Author Addressee Description 5695 12-May-59 L WEGER WHEELER Letter states that John Burton of Diamond Alkali had seen the article on chloracne by Kimming and Schultz while in Germany in Dermatologicia 1957. Weger stated that a translated copy will be available upon reques t . Exhibit #P0123 PIN # Date Author Addressee Description 0 01 -Jun-59 L WEGER WHEELER Letter confirms that Diamond Alkali is in receipt of German Article on Choracne. Exhibit #P0125 PIN # Date Author Addressee Description 5693 16-Jun-59 ELMER WHEELER WEGER Acknowledges receipt of German Article on Chloracne and translation acknowledges translation thereof, chlorinated dibensedioxine acknowledged as an important causing agent of the disorder. IV. A. 108 Exhibit #P0127 PIN # Date Author Addressee 33394 14-Aug-59 UNKNOWN BLAGG ET AL STUBBS & WORK COMP Description Letter attached to brief of Monsanto's regarding Workmen's Compensation cases of the 2,4,5-T manufacturers. Exhibit #P0131 PIN # Date Author Addressee 2210-11 14-Jan-60 M A TERPSTRA BROWN, R T Sc CROUCH, J L GEISMAN, R A & HUBBARD, H L Description Document deals with what should be done with "off-quality" 2,4,5-T. Exhibit #P0133 PIN # Date Author Addressee Description 19470-475 23-Feb-60 G W OLSEN VARIOUS INDIVIDUALS & NITRO RESEARCH & GENERAL OFFICE OTHER Procedure to expand 2,4,5-T production capacity from 175,600 lbs. per month to 3.2 million lbs. per month. Exhibit #P0134 PIN # Date Author Addressee Description 18982-87 16-Mar-60 L C WEGER MILLER, R L & EKBERG, J B EDWARDS, P W Sc COHN, L A OTHERS Trip report to the Diamond Alkali Company for the purpose of investigating the i960 Diamond Alkali incident. IV. A. 109 Exhibit #P0135 PIN # Date Author Addressee Description 18998 29-Mar-60 L P HARICH EDWARDS, P W & STEAHLY, G W WEGER, L C & HINCHCLIFF, W B GALLOWAY, H M Meeting recommendations resulting from Weger's investigation of the Diamon Alkali incident and what could be done to avoid a reoccurence. Exhibit #P0136 PIN # Date Author Addressee 21377-79 27-Apr-60 D L MANSFIELD ROARK, J N & HINCHCLIFF, JR W B Description 2,4,5-Trichlorophenol-Sodium Salt assayprocedure . Exhibit #P0138 PIN # Date Author Addressee Description 23156 23-May-60 UNKNOWN UNKNOWN VARIOUS EMPLOYEES Butyl 2,4,5-Trichlorophenoxyacetate specs. Exhibit #P0142 PIN # Date Author Addressee 76294-76350 06-Jul-60 L P HARICH ET AL TECHNCL SRVCS DEPT & PLANT MANAGER DIRECTOR OF MFG. ft DEPT. SUPERVISOR DEPT. FOREMAN & NITRO RSRCH DPT LIBR Description Standard Manufacturing Process for Sodium 2,4,5-Trichlorophenate in Department 817.35, written July 6, 1960, supercedes Standard Manufacturing Process Manual prepared by L.P. Harich July 30, 1958. 9 IV. A. 110 Exhibit #P0143 PIN # Date Author Addressee Description 5971 22-Jul-60 R EMMET KELLY MD WALLACE MD, RICH & WEGER, L C OTHER Document indicating that there was to be a meeting 8/4/60 with Dr. Oettel, Dr. Susskind, Mr. Wheeler, and Dr. Kelly for the purpose of updating Monsanto's information regarding the German experiences. Exhibit #P0146 PIN # Date Author Addressee Description 05024-41 12-Aug-60 B 0 SEVERSON THRODAHL, M C & ZERBE, R 0 STEAHLY, G W 6c EDWARDS, P W NITRO RSRCH LAB & OTHERS Report on the 245-T engineering study of continous acidification and recovery of TCP. Exhibit #P0147 PIN # Date Author Addressee Description 18967 13-Oct-60 G W OLSEN HARICH, L P & EDWARDS, R W COHN, L A & HINCHCLIFF, W B OTHERS The document refers to a progress report dated 10/13/60 and refers to the need for a capacity increase in the NaTCP plant within the next two years. Exhibit #P0148 PIN / Date Author Addressee Description 73773-77 01-Nov-60 UNKNOWN UNKNOWN FOR NITRO, W. VA Standard Manufacturing Process for 2,4,5-T Acid dated November 1960, Nitro, W. Va. Document includes section on current problems and refers to the "wild Sod TCP batch" incident in Building 41. Also refers to increased resistance from all plant personnel to work assignments in either the Sod. TCP or 2,4,5-T departments. IV. A. 111 Exhibit #P0149 PIN # Date Author Addressee Description 1407-08 01-Nov-60 NONE MAW UNKNOWN Document sets forth the analytical procedure in which one can determine the amount of TDD in 2,4,5-T. Exhibit #P0150 PIN # Date Author Addressee Description 23225-30 01-Jan-61 WILLIAM R UDELL BARKLEY, L B Progress Report from William R. Udell stating the need to find an economical route to 2,4,5-T Acid. Said document states project was initiated with the ultimate aim of reducing cost of manufacture of 2,4,5-T acid. Exhibit #P0153 PIN # Date Author Addressee 19530-34 03-Jan-61 M T WHITE JR COHN, L A & HINCHCLIFF, W B KELLOGG, W R 4 OLSEN, G W STEAHLY, G W & OTHERS Description Progress Report 2,4,5-T Capacity Increase dated January 3, 1961. IV A . 112 Exhibit #P0155 PIN t Date Author Addressee Description 75773-77 28-Jun-61 FRED M YOUNGER MONSANTO CHEMICAL CO Study from Younger Laboratories of CP 18443-(2) - 0-Ethyl 0-(2,4,5-trichlorophenyl) methylphosphonothionate, requested by Monsanto Chemical Company. Said study states that product was fed to Sprague-Dawley strain albino rats, male and female. Product was applied to New Zealan white rabbits, male and female. The compound was classed as highly toxic by oral ingestion in both female and male rats. Said document also states that compound was classed as highly to extremely toxic by skin absorption in female rabbits and compound was classed as highly toxic by skin absorption in male rabbits. Exhibit #P0156 PIN # Date Author Addressee 73908-09 28-Aug-61 C M RUSSELL STITES, J & ROARK, J W BARKLEY, L B & LUECKE, C F WEBBER, R T & OTHERS Description Letter from Russell providing stites with 2,4,5-T acid specifications. Exhibit #P0158 PIN # Date Author Addressee Description 51851-59 27-Nov-61 RESEARCH LAB DOW CHEMICAL UNKNOWN Results of 90-day Dietary Feeding Studies of Dowanol 97B Ester 2,4,5-T in Rats. IV. A. 113 Exhibit #P0159 PIN # Date Author Addressee Description 21391 13-Dec-61 C H RUSSELL ROARK, J N Separation and Identification of 2,4-D and 2,4,5-T Acid by Paper Chromatography. Exhibit #P0160 PIN # Date Author Addressee 22268 01-Jan-62 A J BURNS ET AL STEPHENS, J A & LUECKE, C F RUSSELL, C H & COPANAS, F W WISE, W R & KOLLOFF, R H Description The Analysis of Sodium 2,4,5-TrichIorophenate by Gas Liquid Chromatography. Exhibit #P0164 PIN # Date Author Addressee Description M 0 148 05-Apr-62 R EMMET KELLY MD EDWARDS, PAUL W Document discusses the general disregard of worker hygiene. Document also discusses medical implications which might occur as a result of same. Exhibit #P0165 PIN # Date Author Addressee 828 1O-May-62 F M CALKINS WEBBER, R T & LUECKE, C F HINCHCLIFF, W & HARICH, L P STICKLEY, J F & NUMEROUS OTHERS Description DEVELOP NEW CAPITAL REQUIREMENTS, CAPACITY, AND MANUFACTURING COST DATA FOR 2,4,5-T ESTER MANUFACTURE IN THE BUILDING 46 AVADEX EQUIPMENT. ry)(*, 154 IV. A. 114 Exhibit #P0167 PIN # Date Author Addressee Description 73068 15-May-62 L EDWARD GAUL MD MONSANTO CHEMICAL CO Letter dated May 15, 1962 from Dr. L. Edward Gaul to Monsanto Chemical Company. Said document states patient complained after using Brush Killer, 2,4-D, 2,4,5-T. Exhibit #P0168 PIN # Date Author Addressee Description 21544 29-May-62 C H RUSSELL ROARK, J K & LUECKE, C F COPON??, ? W Russell's letter to Roark in which Dow's infrared method for analyzing 2,4,5-T was discussed. Exhibit #P0169 PIN # Date Author Addressee 62976-90 01-Jun-62 F B MATTHEWS ET AL LUECKE, C F 5c KUHN, W A MATTHEWS, F B 5c ST LOUIS RESEARCH VITAL RECORDS CNTR & VARIOUS OTHERS Description Process Description for the Manufacture of Isobutyl 2,4,5-T in Dept. 268. Exhibit #P0170 PIN # Date Author Addressee 62926-54 01-Jun-62 F B MATTHEWS ET AL LUECKE, C F & KUHN, W A RUMER, R R & MATTHEWS, F B VITAL RCRDS CNTR 5c VARIOUS OTHERS Description Process Description for the Manufacture of Butyl 2,4,5-T in Dept. 268 (894.12) (June, 1962). TT7 A 1 1 C 154Ci Exhibit #P0172 PIN # Date Author Addressee Description 24598-24642 26-Jun-62 J T PEBWORTH UNKNOWN Standard Manufacturing Process for Sodium 2,4,5-Trichlorophenate in Department 895.06. Standard Manufacturing Process Manual prepared by L.F. Harich, July 6, 1960, revised June 26, 1962 by J.T. Pebworth. Document states the Sodium TCP solution produced contains chemical compounds known as "chloracnegens." Exhibit #P0173 PIN # Date Author Addressee Description 76236-41 26-Jun-62 J T PEBWORTH UNKNOWN Standard Manufacturing Process For Sodium 2,4,5-Trichlorophenate In Department 895.06 dated June 26, 1962, revises Standard Manufacturing Process Manual prepared by L.P. Harich dated July 6, 1960. Exhibit #P0174 PIN # Date Author Addressee 1778-1835 26-Jun-62 J T PEBWORTH DEPT. SUPERVISOR & DEPT. FOREMAN TECHNICAL SRVCS LIBR & VARIOUS OTHERS Description Standard Manufacturing Process for Sodium2, 4 ,5-Trichlorophenate In Department 895.06, revises Standard Manufacturing Process Manusl prepared by L.P. Harich July 6, 1960. IV. A. 116 15465 Exhibit #P0176 PIN # Date Author Addressee 76242-93 01-Jul-62 J T PEBWORTH PROD. SUPERVISOR & PRODUCTION FOREMAN TECHNICAL SRVS DEPT. ft NITRO RSRCH LIBRARY DIRECTOR OF MFG. ft OTHERS Description Standard Manufacturing Process for 2,4,5-T Acid Department 57. Exhibit #P0177 PIN # Date Author Addressee Description 24664-714 01-Jul-62 J T PEBWORTH UNKNOWN Standard Manufacturing Process for 2,4,5-T Acid in Nitro Dept. 57. Includes finished product specifications, physical constants data, and matters relating to safety and toxicity. Exhibit #P0179 PIN # Date Author Addressee Description 74217-19 02-Aug-62 G ROBERT SIDO LABELING FILE Letter from Sido about 2,4,5-T Amine Brush Killer labels. Exhibit #P0192 PIN # Date Author Addressee Description 32308 02-Jan-63 H E WEBB JR BOWLES, P N Employee discussed was R.E. Adkins in regard to award being high considering alleged degree of disability. Webb inclined to leave award as is. the IV. A. 117 m es Exhibit #P0195 PIN # Date Author Addressee 24660-61 14-Jan-63 J T PEBWORTH EDWARDS, P. W. h COPANAS, F. W. GORDON, R. S. ft STEPHENS, J. A. SOLSTEN, R. T. ft OTHERS Description Tentative Amendment F to Standard Manufacturing Process for 2,4,5-T Acid contains an objective permitting the use of spent acid from the TCI? recovery step. Exhibit #P0197 PIN # Date Author Addressee 24658-59 23-Jan-63 J T PEBWORTH EDWARDS. P. W. & COPANAS, F. W. RUMER, R. R. ft GORDON, R. S. STEPHENS, J. A. ft OTHERS Description Tentative Amendment G to Standard Manufacturing Process for 2,4,5-T Acid with objective of permitting the use of acid filtrate to partially acidify the TCP in the recovery step. The proposal calls for a 60 day test period. Exhibit #P0198 PIN # Date Author Addressee 73051 29-Jan-63 R EMMET KELLY MD BAVER DR . , L D & HANNAH, L H Description Document discusses pentachlorophenol causing chloracne in Europe and reports of acute intoxication with reports of death using pentachlorophenol in Borneo as well as France and Mexico. Exhibit #P0200 PIN # 247-48 Date 08-Feb-63 Author C RUSSELL Addressee ARVAN Description Document acknowledges that Russell forked '\ out tentative specifications for the Government. A meeting was to be held with Mr. Pearson on February 18, 1963. 15467 IV. A. 118 Exhibit #P0202 PIN # Date Author Addressee 241-43 22-Feb-63 C H RUSSELL HOFFMAN, DR & ARVAN DR., P G DANIELS, S D & KUHN, W A LUECKE, C F & MATTHEWS Description 2/8/63 meeting, Russell & Bourland, U.S. Army Biological Laboratories. Purpose was to satisfy U.S. Army about specs & physical properties on next type of blend they will be purchasing, normal butyl D and normal butyl T. Exhibit #P0238 PIN # Date Author Addressee 21754-55 09-Jul-63 R KOLLOFF ROARK, J & COPANAS CANOBEKK & KUECKE RUSSELL & STEPHENS, JA Description GLC Analysis of 2,4,5-TCP & 2,4,5-T acid. Exhibit #P0245 PIN # Date Author Addressee 63998-64076 0 1 - A u g - 63 R A VODER WEBBER, R. T. * YODER, R. A. LUECKE, C. F. & PEBWORTH, J. T. STEPHENS, J. H. ft OTHERS Description 2,4,5-T plant expansion at Nitro BLdg. 92 is the subject of this document. The document addresses the need for a major increase in production of 2,4,5-T for a month. Exhibit #P0249 PIN # Date Author Addressee Description ILLEGIBLE 04-Oct-63 UNKNOWN UNKNOWN UNKNOWN Product label registration record for 2,4-D/2,4,5-T Butyl Ester Brush Killer. IV. A. 119 15468 Exhibit #P0250 PIN # Date Author Addressee 18782-83 1O-Oct-63 P W EDWARD DIR OF MFG & COVERT, M. C. EDWARDS, P. W. & RUMER, R. R. LUECKE, C. F. & OTHERS Description Document makes reference to a request for agitation in NaTCP storage tank for the purpose of keeping undissolved salts in suspension, thereby eliminating problems of cleaning out accumulated salts and inaccurate inventory of NaTCP. Exhibit #P0252 PIN # Date Author Addressee 24654-57 05-Nov-63 F M CALKINS STEPHENS J. A. COPANAS, F. W. EDWARDS, P. W. & PEBWORTH, J. T. & SPEZIALE, A. J. h UNKNOWN OTHERS Description Tentative Amendment H to Standard Manufacturing Process for 2,4,5-T Acid with objective of exploring effect on 2,4,5-T yield, quality, and cost of the condensation reactor variables. Exhibit #P0254 PIN # Date Author Addressee 65436 25-Nov-63 F W COPANAS CALKINS, F. M. & PEBWORTH, J. T. LUECKE, C. F. & EDWARDS, P. W. HINCHCLIFF, W. B. ft OTHERS Description Document advising that there is 200,000 lbs. of "out of spec" 2,4,5-T. 15469 Exhibit #P0258 PIN # Date Author Addressee 004756-85 1O-Dec-63 W R UDELL SPEZIALE, A. J. * WALDO, W. H. STEPHENS, J. A. & CONNAUGHTON, J. M. LUECKE, C. F. h OTHERS Description Literature survey-review of 2,4,5-T Acid process includes physical constants data of 12/10/63 for 2,4,5-T and NaTCP. Exhibit #P0259 PIN # Date Author Addressee Description 65437-38 11-Dec-63 M T WHITE LUECKE, C. F. ft EDWARDS. P. W. KELLOGG, W. R. ft PEBWORTH, J. T. CALKINS, F. M. ft OTHERS It is proposed that 200,000 lbs. of out-of-spec. 2,4,5-T be reworked in the old 2,4,5-T Dept, in Bldg. 34. Exhibit #P0260 PIN # Date Author Addressee 7421 1 18-Dec-63 G R SIDO LABELING FILE & HOFFMAN, P. R. RUSSELL, C. H. ft SAMAHA, D. Description Document confirming conversation with Russell and Hoffman regarding text of label for 2,4-D/2,4,5-T Amine Brush Killer (USDA Registration 524-99 dated 12/16/57). Exhibit #P0264 PIN # Date Author Addressee Description ILLEGIBLE 15-Jan-64 UNKNOWN UNKNOWN UNKNOWN Product Label Registration Record for 2.4.5- T Butyl Ester Brush Killer, consisting of 37.5% isobutyl ester'of 2.4.5-T trichlorophenoxyacetic acid, 15.3 % n-Butyl ester of 2.4.5-Trichlorophenoxyacetic acid, and 47.2 % inert ingredients. 15470 IV. A. 121 Exhibit #P0265 PIN # Date Author Addressee Description 054547 15-Jan-64 UNKNOWN UNKNOWN UNKNOWN PRODUCT LABEL REGISTRATION RECORD FOR 2,4,5-T ACID REPLACES RECORD OF OCT 1963. Exhibit #P0266 PIN * Date Author Addressee Description 054549 15-Jan-64 UNKNOWN UNKNOWN UNKNOWN PRODUCT LABEL REGISTRATION RECORD FOR 2,4,5-T AMINE BRUSH KILLER REPLACES RECORD OF OCT 1963. Exhibit #P0267 PIN # Date Author Addressee Description ILLEGIBLE 15-Jan-64 UNKNOWN UNKNOWN UNKNOWN PRODUCT LABEL REGISTRATION RECORD FOR BRUSH-O-CIDE BRUSH KILLER REPLACES RECORD OF OCT 1983. BRUSH-O-CIDE'S ACTIVE INGREDIENTS INCLUDE 46.6% ISOOCTYL ESTER OF 2,4-DICHLOROPHENOXYACETIC ACID AND 44.5% ISOOCTYL ESTER OF TRICHLOROPHENOXYACETIC ACID, WITH 8.9% OF THE PRODUCT CONSISTING OF INERT INGREDIENTS. Exhibit #P0268 PIN # Date Author Addressee Description 054554 15-Jan-64 UNKNOWN UNKNOWN PRODUCT LABEL REGISTRATION RECORD FOR BRUSH-BLITZ BRUSH KILLER REPLACES RECORD OF OCT 1963. 88% OF INGREDIENTS IN BRUSH-BLITZBRUSH-BLITZ IS AN ISOOCTYL ESTER OF 2,4,5-TRICHLORO-PHENOXYACETIC ACID AND 12% INERT INGREDIENTS. 15471 IV. A. 122 Exhibit #P0269 PIN # Date Author Addressee 21697 29-Jan-64 C H RUSSELL ROARK, J. N. ft LUECKE, C. F. HOFFMAN, P. F. h CONNAUGHTON, J. M. Description RUSSELL SENDING J.N. ROARK AT NITRO A SAMPLE OF 2,4,5-T ACID MADE BY HERCULES BECAUSE MONSANTO IS CONSIDERING PURCHASING SOME TO MAKE UP FOR DEFICIENCIES DUE TO DIFFICULTIES AT NITRO. RUSSELL ASKED THAT THE 2,4,5-T ACID BE ASSAYED USING "OUR TRADITIONAL METHODS" AND STRESSES THAT THE REQUEST IS URGENT. Exhibit #P0270 PIN * Date Author Addressee Description 21695 07-Feb-64 J N ROARK RUSSELL, C. H. & CONNAUGHTON, J. M. RINCHELIFF, W. B. ft HOFFMAN, P. F. LUECKE, C. F. ANALYSIS OF HERCULES 2,4,5-T ACID SAMPLE #B-1-12464 SHOWS LEVELS OF 1.3% TCP AND 90.3% 2,4,5-T AS COMPARED WITH .2% TCP AND 93.4% 2,4,5-T BEING TYPICAL IN MONSANTO'S PRODUCT." "THERE IS A CONSIDERABLE AMOUNT OF LUMPY MATERIAL IN THIS PRODUCT, CECIL." Exhibit #P0283 PIN # Date Author Addressee Description 64955-65037 01-Apr-64 L E DOTSON UNKNOWN SECTIONS OMITTED INCLUDE: 10) OPERATION OF T-ACID RECOVERY SYSTEMS; 2) DETAILED OPERATIONS FOR TCP RECOVERY SYSTEM; AND 3) DETAILED OPERATIONS FOR T-ACID RECOVERY SYSTEM. ALSO, PART OF SECTION ENTITLED, OPERATION OF TCP RECOVERY SYSTEM, IS OMITTED. THE AFOREMENTIONED WAS INADVERTENTLY NOT SUPPLIED TO PLAINTIFFS BY DEFENDANTS. IV. A. 123 15472. Exhibit #P0286 PIN # Date Author Addressee Description 21 987 14-Apr-64 F L RUPEL RUSSELL, C. H. & LUECKE, C. F. CONNAUGHTON, J. M. Ft ROARK, J. N. STEPHENS, J. A. Document lists an analysis of Dow's 2,4,5-T. Exhibit /P0291 PIN * Date Author Addressee 010667 01-May-64 CHARLES P ZORSCH DEF FUEL SUPP CENT 4 FILE Description Document describes modifications of Agent Orange specifications. Exhibit #P0292 PIN # Date Author Addressee 21385 13-May-64 D L MANSFIELD RUMER, R. R. St RUSSELL, C. H. ROARK, J. N. it CONNAUGHTON, J. M. KELLOGG, W. R. & OTHERS Description Document discusses need to recover 2,4,5-T in Nitro's production process. It is estimated that approximately 1,000/lbs per day was being lost. Exhibit #P0295 PIN # Date Author Addressee Description 055514 28-May-64 ILLEGIBLE ILLEGIBLE RESEARCH NOTES USEFULNESS OF RESEARCH NOTES SHOWING ANALYSIS OF 2,4,5-T IS UNCLEAR. IV. A. 124 15473 Exhibit #P0300 PIN # Date Author Addressee 010782-83 04-Jun-64 C F LUECKE PAYTON & HOFFMAN, P. F. KAMENKO & CONNAUGHTON, J. M. Description Document advises that Hooker does not have TCB and cannot comply with their old schedule of production. Exhibit #P0302 PIN # Date Author Addressee 010784 05-Jun-64 CARL SCHUMACHER TIPPEE, H. W. & HOFFMAN, P. F. LUECKE, C. F. & ZORSCH, C. P. DYKSTRA, R. A. & OTHERS Description BOB DYKSTRA CALLED SCHUMACHER AND SAID HE COULD BEGIN PRODUCING 2,4,5-T ESTERS FOR MONSANTO ON A FIVE DAY A WEEK BASIS STARTING JUNE 11. Exhibit Exhibit #P0307 PIN # Date Author Addressee 010683-84 25-Jun-64 C P ZORSCH FILE & SCHUMACHER, C. P. LUECKE, C. F. ft HOFFMAN, P. MCCARVILLE, W. J. ft OTHERS F. Description Contract for Governmental purchase of 48,950 gallons of a product containing 50% 2,4-D N-Butyl Ester; 30% 2,4,5-T N-Butyl Ester; and 20% 2,4,5-T Iso-Butyl Ester. 15474 IV. A. 125 Exhibit #P0 315 PIN # Date Author Addressee Description 008255-57 01-Aug-64 UNKNOWN UNKNOWN UNKNOWN Label for 2,4,5-T acid. Exhibit #P0316 PIN # Date Author Addressee ILLEGIBLE 12-Aug-64 UNKNOWN UNKNOWN KRUMMRICH PLANT & OTHERS UNKNOWN Description GAS-LIQUID CHROMATOGRAPHIC PROCEDURE FOR DETERMINING THE COMPOSITION OF THE ESTER ALONE OR IN A MIXTURE WITH ONE OR MORE OF THE ESTERS. Exhibit #P0324 PIN # Date Author Addressee 046115-21 01-Oct-64 R M DICKEY COLLERAN, W. E. Ft COMERFORD, EASLEY, K. W. & EBY, C. J. LINXWEILER, T. G. Ft OTHERS D. G. Description DEFOLIANT SYNTHESIS MODIFICATION NO.3 TO CONTRACT NO. DA18-0648.064.AMC.69(A). Exhibit #P0327 PIN # Date Author Addressee Description 2623-26 20-Oct-64 FRED YOUNGER MONSANTO Study performed by the Younger Lab regarding the toxic effects of TCP Distillation Residue. Study dealt with rabbits and it was discovered that four of the six tested died within 4-8 weeks. Jaundiced livers were noted as well as renal congestion. IV. A. 126 15475 Exhibit #P0329 PIN # Date Author Addressee 73242-73249 22-Oct-64 WILLIAM H HUNT PHD STEPHENS, J A & LUECKE, C F UDELL, W R & NUMEROUS OTHERS Description Circulation of study referred to in document #2700, the rabbit study done by the Younger Lab showing their death when exposed to TCP distillation residue. Document also contains a comparison chart to other compounds. Exhibit #P0332 PIN # Date Author Addressee Description 460 24-Nov-64 C H RUSSELL CARTY, C W & ZORSCH, CP HOFFMAN, P F Document whereby Russell informs the Army that the Government specs are identical to Monsanto's "official specification". Exhibit #P0349 PIN # Date Author Addressee 20696 06-Jan-65 J STRUM SPRINGGATE & KELLOGG HAMILTON & BRICK SOLSTEN & PRITCHARD ET AL Description PROGRESS REPORT ON ATTEMPT TO INCREASE NITRO PLANT CAPACITY OF PRODUCTION OF 2,4,5-T FROM 400,000 LBS. PER MONTH TO 500,000 LBS. PER MONTH TO MEET SALES COMMITMENTS. RECOMMENDATION OF INSTALLATION OF A SURGE HOPPER AND A VARIABLE-SPEED FEEDER TO ELIMINATE PROCESS DOWNTIME. IV. A. 127 15478 Exhibit #P0350 PIN # Date Author Addressee Description 9815-9816 08-Jan-65 UNKNOWN UNKNOWN COMMANDER & DEFENSE GENERAL & SUPPLY CENTER CONFIDENTIAL MESSAGE ON FORM TO COMMANDER OF DEFENSE GENERAL SUPPLY CENTER IN RICHMOND, VA. MESSAGE SETS FORTH PURITY LEVELS FOR A 50/50 BLEND OF 2,4-D AND 2,4,5-T, DATE OF DELIVERY, AMOUNTS, PRICES. Exhibit #P0377 PIN t Date Author Addressee 5972-73 24-Feb-65 R EMMET KELLY MD FILE & WHEELER E P Description Memo of conversation between Kelly and Roe whereby Kelly was advised that the contaminant in 2,4,5-T was dioxin. Exhibit #P0392 PIN # Date Author Addressee Description 000229 11-Mar-65 CARL SCHUMACHER HOSTETTER COVER LETTER AND MEMO REGARDING GOVERNMENT BIDS FOR 50/50 2,4 D AND 2,4,5 T BLENDS AND MOSANTO'S POSITION REGARDING ACCEPTANCE OF BIDS BASED ON SUCH VOLUME. Exhibit #P0396 PIN # Date Author Addressee 73255 17-Mar-65 EMMETT KELLY STEPHENS & HOFFMAN Description Warning letter regarding 2,3,7 ,8tetrachlorodibenzyl- dioxin received from the DOW CHEMICAL COMPANY. Therein it is claimed that DOW had thought it to be the "... most toxic compound they have ever experienced." IV. A. 128 Exhibit #P0419 PIN # Date Author Addressee 72054 30-Mar-65 EMMETT KELLY HOFFMAN & ARVAN DUNLAP & RUMER Description LETTER DESCRIBES MEETING BETWEEN DOW, HOOKER, DIAMOND, HERCULES AND OTHERS OF REGARDING THE CONTENT OF DIOXIN IN DOW'S 2,4,5-T ACID. AUTHOR AGREES THAT DIOXANE IS "... A POTENT CONTAMINANT." ALSO THAT "...IT CAN BE A POTENT CARCINOGEN." HE ALSO VOICED CONCERN ABOUT ANOTHER EPIDEMIC OCCURRING AT NITRO. Exhibit #P0422 PIN # Date Author Addressee Description 5983 01-Apr-65 E WHELLER FRAWLEY COVER LETTER ENCLOSING ARTICLE ENTITLED "OCCUPATIONAL ACNE" BY KIMMING AND SCHULTZ. AND OTHER FILES ON THE SUBJECT IN CONTROL OF AUTHOR. Exhibit #P0439 PIN # Date Author Addressee Description 20824-20828 07-Jun-65 R NULL SPRINGGATE, ET AL PROGRESS REPORT ON 2,4,5-T TO NITRO PLANT OFFICIALS AND OTHERS REGARDING RIGID QUALITY IMPROVEMENT. PROGRAM. Exhibit #P0456 PIN # Date Author Addressee Description 75614-75635 13-Sep-65 S NORBERT SIDE ROBERT ELKINS & JACKSON KELLY & HOLT 0'FARRELL COVER LETTER REGARDING WARNING LABELS TO BE AFFIXED ON PRODUCT FOR WEED & BRUSH CONTROL THAT CONTAIN 2,4-D AND 2,4,5-T. IV. A. 129 15478 r Exhibit #P0458 PIN # Date Author Addressee 1564-1569 14-Sep-65 W UDELL TAKE & DUNLAP STEPHENS & SHARP Description MEMO FROM AGRICULTURAL RESEARCH-ST. LOUIS TO NITRO PLANT REGARDING FORMATION AND CONCENTRATION OF TDD WITH ATTACHED GRAPHS. MEMO NOTES RECENT INCREASE IN TDD FORMATION AND STATES THAT A DETAILED LABORATORY STUDY IS IN THE PLANNING STAGES AND SHOULD REVEAL REASONS FOR RECENT INCREASES IN FORMATION. Exhibit #P0468 PIN # Date Author Addressee 8223-8226 22-Dec-65 ROBERT BRANDON KUHN & LANDWEHR TRAIL & TAKE Description MEMO REGARDING VIABILITY OF EXPANDING THE NITRO 2,4,5-T PLANT. SEEK ADDITIONAL TESTING TO BE DONE IN ORDER TO DETERMINE THE EFFECT OF PARTICLES IN AIR LEAVING THE DRYING SYSTEM. Exhibit #P0470 PIN # Date Author Addressee Description 76884-76888 30-Dec-65 L DOTSON UNKNOWN MANUFACTURING AND PROCESS DATA REGARDING TOXICITY OF 2,4,5-T WITH ATTACHED CHARTS AND GRIDS. WARNING THAT EXTREME CARE MUST BE USED IN HANDLING THE COMPOUND BECAUSE OF ITS TOXICITY AND CONTAINMENT OF CHLOROACNEGEN AGENTS. IV A . 130 15479 Exhibit #P0471 PIN t Date Author Addressee Description 1402 30-Dec-65 L DOTSON PROCESS BRIEF Document displays process of T and further indicates that the raw materials and final product are toxic. Exhibit #P0472 PIN # Date Author Addressee Description 63212-66 01-Jan-66 D R MIDDLETON LUECKE, C F & STEPHENS, J A ARMSTRONG, D C & LEISY, A E ROBIRDS, W R & OTHERS Standard Manufacturing Process For ISO OCTYL 2,4-D ISO OCTYL 2,4,5-T, dated 11/69 Exhibit #P0476 PIN # Date Author Addressee Description 21396 04-Jan-66 M A WILLIAMS ROARK, J N & DOTSON, L E KELLOGG, W R & STRUM, J C TAKE, E F Document indicates that in 12/65 all time production record 571,220 lbs. were achieved. Previous operating conditions called for less than recent production, which may account for poor quality. Exhibit #P0478 PIN # Date Author Addressee 5996 13-Feb-66 CARL BOHL FILE & MED DEPT Description 2,4,5-T PLANT MEDICAL DEPARTMENT MEMO FROM CARL BOHL, INDUSTRIAL HYGIENIST, REGARDING REMOVAL OF TOXIC MATERIAL TDD FROM THE FINAL PRODUCT. STATES THAT MR. RHODES SUGGESTED TWO APPROACHES; ADD METHANOL SODIUM HYDROXIDE UNDER PRESSURE AND, SECONDLY, CLOSE CONTROL OF THE TEMPERATURE IN THE REACTOR. 15480 IV. A. 131 t Exhibit #P0488 PIN # Date Author Addressee Description 2081 5 22-Apr-66 J C STRUM FILE & SPRINGGATE, J E RHODES, V L & TAKE, E F OTHERS Late 1965 production increase of more than 25% in the T Plant without major equipment revisions. Exhibit #P0495 PIN # Date Author Addressee 22362 23-Jun-66 F L RUPEL JR RUSSELL, G H & CUTRIGHT, E A RHODES, V L 6c BOLLINGER, P G Description Document lists analysis of Dow's dried 2,4,5-T. Exhibit #P0499 PIN # Date Author Addressee 1560 11-Jul-66 W R UDELL BOLLINGER, F G 6c BALDERSON, P B SHARP, D B & STEPHENS, J A Description Letter from Udell to the aforementioned addressees which enclosed GLC procedure to detect TDD in T. Document also indicates that the samples are highly toxic. Exhibit #P0502 PIN t Date Author Addressee Description 1487 22-Jul-66 F L RUPEL JR CUTWRIGHT, E A 6c BALDERSON, P B RUSSELL, C M 6c STEPHENS, J A UDELL, W R Analysis of 1966 2,4,5-T reaching as high as 28ppm. Document also indicates that the "typical values should range between 5 to 18 p p m ." 15481 IV. A . 132 Exhibit #P0507 PIN # Date Author Addressee 1179-81 11-Aug-66 J C STRUM SPRINGGATE, J E & CUTWRIGHT, E A RHODES, V L & NUMEROUS OTHERS Description Document states that TDD is a toxic material and is contained in NaTCP, recovered TCP and dry 2,4,5-T . Exhibit #P0549 PIN # Date Author Addressee 1697-1770 01-Dec-66 L E AND V L DOTSON RHODES LUECKE, C F & CUTWRIGHT, E A RHODES, V L & STEPHENS, J A DUNLAP, W P 4 OTHERS Description Standard Manufacturing for 2,4,5-Trichlorophenoxyacetic Acid, revised November 1966, issued December 1966. Exhibit #P0586 PIN # Date Author Addressee 5993 23-Feb-67 CARL D BOHL WHEELER, ELMER P & KELLY, R E Description Document discusses February 22, 1967 meeting between Stephens, Udell, Sharp and Bohl regarding Dioxin. Document also refers to contamination levels between 10 and 30ppm. The group decided that they needed animal testing so that they could gain further information. Said testing was discussed and Kelly was apprised. IV. A . 13 3 1~ ^- Exhibit #P0592 PIN # Date Author Addressee Description 5995 01-Mar-67 ELMER P WHEELER DUNLAP, W P & BOHL, C D KELLY, R E The document addresses the fact that V. K. Rowe "opened the can of worms" on the 2,4,5-T situation. Indicated further is the fact that Dow isolated tetrachlordiphenylen-dioxyd. Also, Rowe indicated that the materials were so potent that putting it on the skin of an animal regardless of location resulted in a "positive" response. Exhibit #P0593 PIN t Date Author Addressee Description 5994 06-Mar-67 CARL D BOHL KELLY, R E & SPRINGGATE, J E OUTRIGHT, E A & STEPHENS, J A DUNLAP, W P Report Bohl's trip to Nitro on 2/27/67 and 2/28/67. Document further indicated that TDD is created in hold cycle of TCP Process. Outright suggested either a cutdown of hold time or a cutdown in charge time in order to significantly reduce TDD in the final product. Exhibit #P0595 PIN # Date Author Addressee 1296 09-Mar-67 PETER M HOWELL SPRINGGATE, J & KELLOGG, RHODES, V L & OTHERS WR Description Document indicates that personnel exposed to 2,4,5-T dust constituted a serious hazard. I V. A. 134 15483 Exhibit #P0596 PIN # Date Author Addressee Description 681-84 16-Mar-67 COMPANY DEF GEN SUP MONSANTO Production and Forecast of D and T for 1966 and 1967. Exhibit #P0606 PIN # Date Author Addressee 1145 03-Apr-67 UNKNOWN PMH WRK & BFP VLR & HAD EAC 5c JES Description AUTHORIZATION FOR EXPENDITURE FOR THE NITRO PLANT TO INSTALL 2,4,5-T AUTOCLAVE SAMPLERS AS IT IS NOTED THAT THE EXISTING SAMPLER IS CONSTITUTES A SEVERE EXPOSURE HAZARD. Exhibit #P0631 PIN # Date Author Addressee Description 1495 12-Jun-67 P B BALDERSON RHODES, V L Document indicates TDD levels as of 6/12/67 as high as 24ppm. Exhibit #P0637 PIN # Date Author Addressee Description 8938-8960 30-Jun-67 UNKNOWN UNKNOWN COVER LETTER OVER GOVERNMENT DOCUMENTS DELINIATING REQUIREMENTS FOR BIDS ON DEFOLIANT; ORANGE, ORANGE II, AND ORANGE III. IV. A. 135 15484 Exhibit #P0639 PIN # Date Author Addressee 40421 05-Jul-67 UNKNOWN UNKNOWN TSD FILE & RHODES, V L Description Document indicates that exact hold periods are necessary in order to reduce the personnel exposure problem in 2,4,5-T. Manual control varies as much as 30 minutes. Exhibit #P0651 PIN # Date Author Addressee Description 73288-73307 23-Aug-67 UNKNOWN UNKNOWN NONE List of equipment used in the manufacturer of 2,4,5-T. Exhibit #P0652 PIN # Date Author Addressee 1451 24-Aug-67 VERNE L RHODES WOODS, W. C. ft OUTRIGHT, E. A. DOLIN, OWEN & MILLER, H. K. Description ANALYSIS OF CONTROL SAMPLES FOR TDD IN NATCP. Exhibit #P0665 PIN # Date Author Addressee Description 1436 08-Sep-67 JR Q C LAB UNKOWN Analysis of T dated 09-08-67 with readings as high as 22 ppm. IV. A. 136 15485 Exhibit #P0676 PIN # Date Author Addressee Description 1432 06-Oct-67 JMS Q C LAB UNKNOWN Analysis of 2-4-5-T for TDD with readings as high as 25ppm. Exhibit #P0679 PIN # Date Author Addressee Description 206-207 11-Oct-67 C H RUSSELL ZORCH, C.P. St CAYARD,D .B . STEPHENS, J .A. & FISCHER, D.R. OTHERS Letter discusses a meeting in Washington which addressed the issue of what analysis of the esters was being performed. Russell also admits that it was he who wrote the n-butyl D, T, and Orange specifications. Exhibit #P0681 PIN # Date Author Addressee 84-85 13-Oct-67 C H RUSSELL WISWESSER, W J & CAYARD, D E STEPHENS, J A & ZORSCH, C P Description Letter setting forth the fact that it was Russell who worked on writing the military specifications. Exhibit #P0682 PIN # Date Author Addressee Description 86 16-Oct-67 C H RUSSELL WISWESSER, W J & CAYARD, D E CONNAUGHTOU, J M & HOFF, D N ZORSCH, C P Document indicating that Monsanto was opposed to having the free acid specification reduced from 1% to .5%. IV. A. 137 Exhibit #P0689 PIN # Date Author Addressee Description 1426 06-Nov-67 C R Q C LA UNKNOWN Analysis of 2,4,5-T by C.R. dated 11/6/67 for TDD with readings at 25ppm. Exhibit #P0690 PIN # Date Author Addressee 1485 07-Nov-67 W C WOODS RHODES, V L & OUTRIGHT, DOLIN, 0 E & BALDERSON, EA PB Description Analysis of TDD, 25ppm as one of the readings. Exhibit #P0704 PIN # Date Author Addressee 21403 13-Dec-67 W C WOODS DOLIN, 0 & OUTRIGHT, E A RHODES, V L & KELLOG, W R Description Document indicated that cost savings was more important than safety of product. Exhibit #P0709 PIN # 68 Date Author Addressee 28-Dec-67 C H RUSSELL MIDDLETON, D R & ZORSCH, C P OARTY, CARL W & WISWESSER, W J Description Document requesting modification of proposed military specification. Said document outlines numerous requests for change in said specification. 15486 IV. A. 138 Exhibit #P0713 PIN # Date Author Addressee 66038 01-Jan-68 V RHODES OUTRIGHT & ATKINSON DOLIN & KELLOGG Description REQUEST TO ANALYZE AND COMPARE PURCHASED NaTCP WITH NITRO PRODUCT. SERVICE REQUEST STATES THAT NaTCP STEP IS LIMITING PRODUCTION OF 2,4,5-T ACID AND DOWNTIME RE SULTS IN LOST PRODUCTIVITY. Exhibit #P0726 PIN # Date Author Addressee Description 53636 25-Jan-68 UNKNOWN UNKNOWN UNKNOWN DOCUMENT INDICATES THAT WELDON SPRINGS PROBABLY COULD PROBABLY NOT FUNCTION AFTER THE WAR IF MONSANTO WERE TO BUILD A NEW PLANT. MONSANTO MUST IMPROVE COSTS OR WELDON SPRINGS COULD "RUN THEM OUT".WELDON SPRINGS PROBABLY CAN'T RUN AFTER WAR IF MONSANTO BUILDS NEW D PLANT. MONSANTO MUST IMPROVE COST OR WELSON SPRINGS COULD RUN THEM OUT. Exhibit #P0732 PIN t Date Author Addressee Description 11112-11114 30-Jan-68 GEORGE KEMPSON BARTLETT DISCUSSION OF MONSANTO'S OBJECTION TO SPECIFICATIONS REGARDING THE CONTENT OF ORANGE FSC 684Q. IV. A . 139 15487 Exhibit #P0741 PIN # Date Author Addressee Description 11165-11168 23-Feb-63 UNKNOWN DOCUMENT CONTAINS INFRARED METHOD FOR ANALYZING ORANGE HERBICIDE. Exhibit #PU742 PIN # Date Author Addressee Description 8893-8948 23-Feb-68 UNKNOWN UNKNOWN UNKNOWN PURCHASE DESCRIPTION FOR HERBICIDE-ORANGE WHICH SETS FORTH REQUIREMENTS AND DELINIATES QUALITY ASSURANCE PROVISIONS. Exhibit #P0750 PIN # Date Author Addressee Description 53773-53781 01-Mar-68 CHARLES ZORSCH ROY MEYERS DOCUMENT IS A NINE PAGE PERFORMANCE SUMMARY FOR DEFENSE CONTRACT FOR ORANGE BEGINNING 6/1/67 THROUGH 2/29/68 PREPARED BY MONSANTO. Exhibit #P0763 PIN # Date Author Addressee 74220-74221 23-Apr-68 LARITA IVES VIRGINIA KOENIG & J J JURKIEWICZ Description MEMO CONCERNING LISTED LABELS AND NOTATION OF WHERE STOCK IS LOCATED AND QUANTITY OF KNOWN STOCK. IV. A. 140 15488 Exhibit #P0769 PIN # Date Author Addressee Description 16U-65 1O-May-68 C P ZORSCH NUMEROUS EMPLOYEES Document addresses meeting held with the General Supply Division of Government whereby supply and demand was discussed. Exhibit #P0771 PIN # Date Author Addressee Description 53742 17-May-68 JANE LEWIS ZORSCH LEWIS NOTIFIED ZORSCH THAT THEIR MILITARY DEFOLIANT CONTRACT HAD BEEN SIGNED. Exhibit #P0785 PIN # Date Author Addressee 66601-747 11-Jul-68 CARL BOHL MCGUIRE, B. G. * WEBB, H.R. STRATMEYER, R.J. Ft MEDICAL DEPT. Description Document is a Comprehensive Survey of the entire Nitro Plant operation. The document exhibits in part that there is a chloracne problem resulting from an impurity in the final product. It was hoped that at the end of two years, this contaminant would be eliminated. IV. A. 141 1548'9: Exhibit #P0797 PIN # Date Author Addressee 53744-46 16-Sep-68 TRB KRUMMRICH LAB & OTHERS UNKNOWN Description Document discusses some of the risks associated with use of a product containing 2,4,5-T. Exhibit #P0801 PIN # Date Author Addressee Description 004073 25-Sep-68 V L RHODES NITRO TECH SERV & CUTRIGHT, E. A. DOTSON, L. E. & RHODES, V. L. RUSSELL, G. P. TEMP CONTROL IS = PLUS OR MINUS 4 DEGREES CENT FROM TARGET. "WE NOW HAVE INFORMATION LEAKED FROM HERCULES THAT PRECISE TEMPERATURE CONTROL MAY BE THE KEY TO CHLORACNE REEDUCTION. FOR THIS REASON WE NOW REQUEST INSTALLATION OF INSTRUMENT HARDWARE TO ALLOW US TO REMOVE THE HUMAN ELEMENT AND CONTROL AUTOCLAVE TEMPERATURES AT PLUS OR MINUS 1 DEGREE CENT." Exhibit #P0803 PIN # Date Author Addressee Description 001344-57 01-Oct-68 R A ATKINSON UNKNOWN 2,4,5-T PROCESS IMPROVEMENT PLAN. Exhibit #P0811 PIN # Date Author Addressee 000692-704 29-Oct-68 JOHN D CONNER MORRIS, THOMAS D. & WELD Description LAW FIRM SELLERS, CONNOR & CUNEO WRITING ON BEHALF OF DIAMOND SHAMROCK, HERCULES, MONSANTO, T.H. AND CHIPMAN REGARDING THEIR OPPOSITION TO THE BUILDING OF THE WELDON SPRING PLANT. ON BEHALF OF CONCERN OF D.S., HERC., MONSANTO, T.H., AND CHIPMAN OF IMPLICATIONS OF WELDON SPRING PLANT ON THESE PHENOXY HERBICIDE PRODUCERS. IV. A. 142 15490 Exhibit #PU813 PIN # Date Author Addressee 000690-91 31-Oct-68 JOHN D CONNER HOWARD, HAROLD H. & WILKERSON, M. F. GIVENS, KENNETH T. & MATTISON, S. A. RUMER, ROBERT & OTHERS Description ACKOWLEDGEMENT THAT LETTER TO ASST S E C Y DEFENSE THOMAS D. MORRIS WAS FILED ON OCT 30, 1968 WITH DEPT OF COMMERCE AND DEPT OF DEFENSE, AND WAS HAND DELIVERED TO MR . KOSTER AND MISS LEWIS, REGARDING THE WELDON SPRING PROJECT. Exhibit #P0814PIN # Date Author Addressee 001407-08 01-Nov-68 MAW NITRO ORGAN CHEM DIV & OTHERS UNKNOWN Description DETERMINATION OF TDD IN 2,4,5-T ACID FROM SOLID SAMPLE, INCLUDING METHOD FOR CALCULATING PPM OF TDD. Exhibit #P0815 PIN # Date Author Addressee 75645-73 08-Nov-68 G R SIDO ARK POIS LABEL FILE & LITTEKEN, M. F. Description MEMO CONFIRMS DISCUSSION WITH HENRY D SALVO REGARDING ALLOWABLE COLORS OF LABELS FOR 2,4,5-T & 2,4-D IN ARKANSAS. Exhibit #P0821 PIN * Date Author Addressee Description 001521-48 12-Dec-68 J C STRUM NITRO TECH SERV DEPT PLAN TO IMPROVE PERFORMANCE OF 2,4,5-T PROCESS IN THE AREAS OF RATE, RAW MATERIAL USAGE, QUALITY, SAFETY, POLLUTION, MECHANICAL RELIABILITY, AND MANUFACTURING TECHNOLOGY. 15491 XV. A. 143 f Exhibit #P0822 PIN # Date Author Addressee 000704 19-Dec-68 JOHN D CONNER WILKERSON, M. F. h GIVENS, KENNETH T. HOFF, DOUGLAS N. * MCCOY, W. G. THOMPSON, R. S. b OTHERS Description Document indicating that Government contract for Agent Orange had been cancelled. Exhibit #P0826 PIN # Date Author Addressee Description 76062-81 01-Jan-69 W R KELLOG NITRO & MONTHLY REPORT TECH SERVICE DEPT. Nitro Tech Service Monthly report dated 1/69, indicating that a trial run of the autoclaves is planned with the intention of reducing the TDD content in NaTCP from 40-50 ppm to 5-6 ppm. Exhibit #P0827 PIN # Date Author Addressee 4800-47 01-Jan-69 J L W R SIMS UDELL LUECKE, C. F. & RUSSELL, CUTRIGHT, E. A. & KELLY, RHODES, V. L. & OTHERS C.F. R. E. Description Final report #150 regarding attempts to reduce TDD in 245-T. The report addresses the acute toxicity of TDD as well as the process of production and analysis. IV. A 144 15432 Exhibit #P0833 PIN # Date Author Addressee 1063 09-Jan-69 J C STRUM RHODES, V & EAC STRUM, J C 6c DOLIN, Description January, 1969 document which discusses plan to reduce the level of TDD in NaTCP from 50 to 5 ppm. Document also discusses the belief that TDD is produced in the NaTCP autoclaves. Exhibit #P0834 PIN # Date Author Addressee Description 1062 09-Jan-69 J C STRUM CUTRIGHT, E A 6c RHODES, V L HELMER, F J 6c STRUM, J C DOLIN, 0 E Jan. 9, 1969 plan to reduce TDD in NaTCP from 50 ppm to 5 ppm. Exhibit #P0835 PIN # Date Author Addressee Description 1452-54 15-Jan-69 J C STRUM ET AL RESEARCH DEPT. 6c RHODES, VL CUTRIGHT, E A 6c STEPHENS, J A OTHERS Formal tentative amendment to reduce TDD in NaTCP from 40-50ppm to 5-6ppm. Lists present NaTCP reaction conditions and the newly proposed plan. IV A. 145 15493 Exhibit #P0836 PIN # Date Author Addressee Description 1517-1520 19-Jan-69 UNKNOWN UDELL, W R & OUTRIGHT, E A RHODES, V L ix STRUM, J C PATRICK, C E & OTHERS "Minutes of Meeting With W R Udell". Document indicates that he believes that approximately 35 ppm is being produced in the autoclaves consistently. It states that TDD is highly sensitive to temperature , with slight increases resulting in significant increases in TDD. Exhibit #P0844PIN # Date Author Addressee 1502-04 21-Feb-69 J G STRUM CUTRGHT,E A & DOTSON, L E BALDERSON, P B & UDELL, W R LEUCKE, C F c OTHERS Description Progress report for plan to reduce TDD level from 40 ppm as in 1968 experience to 5 - 7 ppm. Present trial run showed reduction to 3.05 ppm. A 30-day plant trial run will begin on February 24 to complete the demonstration. Exhibit #P0846 PIN * Date Author Addressee Description 76101-19 01-Mar-69 W R KELLOG NONE Document speaks of a problem with the GLC analysis which appears to be resolved with the flame detection method. IV. A. 146 Exhibit #P0847 PIN # Date Author Addressee 6002 16-Apr-69 R EMMET KELLY EAKIN, FRANK & BOHL, C.D. Description Letter from Dr. Kelly indicating that even less that 1 ppm could cause chlorachne. Exhibit #P0849 PIN # Date Author Addressee 76138-155 01-May-69 W R KELLOG JACKSON, D W & SAVAGE, J R LEUCKE, C F & WEBBER, R T EDWARDS, P w & OTHERS Description Tech. Service monthly report indicating a significant reduction of TDD in NaTCP, an average of 4ppm. Exhibit #P0850 PIN # Date Author Addressee Description 1500 08-May-69 J C STRUM BAKIN, F. A. & DOLIN, C. B. HELMER, F.J. ft BALDERSON, P WOODS, W. C. May 1969 document which states that Curt Woods was to set up a program for routine analysis for the TDD in 245-T finished goods. Routine is indicated to mean between 2-4 per week. Exhibit #P0851 PIN # Date Author Addressee Description 6000 14-Jun-69 R EMMETT KELLY MD WEBB, H B Memo of Dr. Kelly asking "I don't want to be cynical, but are there any employees in the department who don't have chloracne already? IV. A. 147 Exhibit #P0852 PIN # Date Author Addressee 76171-82 01-Jul-69 W R KELLOGG LUECKE, C F & WEBBER, R T SAVAGE, J R & SEPULVEDA, C H DODD, H A & OTHERS Description Document indicating that TDD is highly toxic. Exhibit #P0853 PIN # Date Author Addressee 11227 14-Jul-69 C H RUSSELL MIDDLETON, D R & ZORSCH C P ROBIRDS, W R & LEISY, A E Description The document indicates they were discontinuing their investigation of VPC analysis procedures of Orange when their contract was cancelled. Exhibit #P0855 PIN # Date Author Addressee 76183-94 01-Aug-69 W R KELLOGG NITRO & GENERAL OFFICES KRUMMRICH & QUEENY ANNISTON & OTHER PLANTS Description August, 1969, monthly report of Nitro's technical service dept. It is noted that approval was received on Tentative Amendment No. N which permits control of the condensation reaction pH with 34% NaTCP solution instead of 25% NaOH--a trial run on August 19-23 showed no adverse effects on quality or yield. IV. A. 148 Exhibit #P0858 PIN # Date Author Addressee Description 22929-34 29-Aug-69 J C STRUM SAFETY DEPT. Ft PLANT MANAGER OTHERS Document is entitled "Process Safety Audit" and addresses, in question and answer form, safety questions regarding: raw materials, process, finished goods and equipment and layout. Document also indicates that the finished goods may be somewhat toxic and that the containers are properly labelled for toxicity. Exhibit #P0859 PIN # Date Author Addressee 76195-205 01-Sep-69 W R KELLOGG NITRO & GENERAL OFFICES KRUMMRICH & ANNISTON QUEENY & OTHER PLANTS Description SEPTEMBER, 1969, MONTHLY REPORT FOR THE TECHNICAL SERVICES DEPARTMENT OF THE NITRO PLANT. Exhibit #P0860 PIN # Date Author Addressee Description 29050-144 15-Sep-69 E M EMERY ET AL SHARP, D B & DOLIN, 0 EMERY E M & MEADE, FRANK NUMEROUS OTHERS Monsanto Organic Chemicals Division Research Report -3598;"Final Report on Gas Chromatography Method Development - L968. IV A . 149 Exhibit #P0872 PIN # Date Author Addressee Description 1693-96 05-Dec-69 R L DILLON ET AL ROBIRDS, W R Sc STRUM, J C PAYNE, R L & EAKIN, F A RESEARCH DEPT. ft OTHERS Official tentative amendment to the manufacturing process for 2,4,5-T acid. Amendment requires in part reduction of the TCB feed time from 2 1/2 hrs to 1 hr. Exhibit #P0876 PIN # Date Author Addressee 68292 16-Dec-69 WILLIAM H HUNT SPEZIALE, A. J. h SHARP, D. B. Description Reference to preliminary mutagenic report of NCI. Hunt says Medical Dept, has report but feels data is meaningless and that mutagenic activity in bacteria cannot be extrapolated to mammals until mammalian data are available. Exhibit #P0877 PIN # Date Author Addressee 73231-41 19-Dec-69 A J SPEZIALE BALDESCHWEILER, J D & BURGER DR. STEPHENS J A Sc UDELL W R KELLY, R E & OTHERS Description Letter indicating Monsanto's knowledge of TDD as well as levels of contamination from 1953, methods of analysis for TDD in autoclave and technical 2,4,5-T, sample chromatograms, and numerous forms of correspondence. IV. A. 150 15498 CERTIFICATE OF SERVICE The undersigned Benton Musslewhite, Esq. does hereby certify that on the 11th day of April, 1984 he served the enclosed Pre-trial Order on all those shown on the attached service list by hand delivery through a Delivery Service. Benton Musslewhite i 15500 154S9 SERVICE LIST Leonard Rivkin, Esq. Rivkin, Leff, Sherman & Radler Attorneys for Dow Chemical Company 100 Garden City Plaza Garden City, N.Y. 11530 Wendell B. Alcorn, Jr., Esq. Cadwallader, Wickersham & Taft Attorneys for Diamond-Shamrock One Wall Street New York, New York 10005 Judith L. Spanier, Esq. Shea & Gould Attorneys for Uniroyal, Inc. 330 Madison Avenue New York, New York 10017 off David R. Gross, Esq. Budd, Larner, Kent, Gross, Picillio & Rosenthal Attorneys for Thompson Chemical 33 Washington Street Newark, New Jersey 17102 William A. Krohley, Esq. Kelley Drye & Warren Attorneys for Hercules, Inc. 101 Park Avenue New York, N.Y. 10178 Phillip E. Brown, Esq. Hoberg, Finger, Brown, Cox & Molligan, P.C. Central Tower 703 Market Street San Francisco, California 94103 David J. Dean, Esq. Dean, Falanga & Rose One Old Country Road Carle Place, New York 11514 Gene Locks, Esq. Greitzer & Locks 1500 Walnut Street - 21st Floor Philadelphia, Pennsylvania 19102 John C. Sabetta, Esq. Townley & Updike Attorneys for Monsanto Co. 405 Lexington Avenue New York, New York 10017 Thomas Beck, Esq. Arthur, Dry & Kalish Attorneys for Uniroyal, Inc. 1230 Avenue of the Americas New York, New York 10020 Morton B. Silberman, Eqq. Clark, Gagliardi & Miller Attorneys for T&H Agriculture 99 Court Street White Plains, New York 10601 Arvin Maskin, Esq. Civil Division United States Department of Justice Safeway Building, Room 9040 Washington, D.C. 20530 Hon. Shira Scheindlin Magistrate United States District Court 225 Cadman Plaza East, Rm. 28 Brooklyn, New York 11201 Stanley M. Chesley, Esq. Waite, Schneider, Bayless & Chesley, Co., L.P.A. 1513 Central Trust Tower Cincinnati, Ohio 45202 Thomas VMS, Henderson, Esq. Henderson & Goldberg Frick Building, Rm. 1601 Pittsburgh, Pennsylvania 1521 Benton Musselwhite, Esq. 609 Fannin, Suite 517 Houston, Texas 77002 15501 John O'Quinn, Esq. O'Quinn, Hagans & Wettman 3200 Travis Commerce Tower 600 Travis Houston, Texas 77003 Newton B. Schwartz, Esq. Houston Bar Center Building 723 Main, Suite 325 Houston, Texas 77002 Stephen J . Schlegel, Esq. Schlegel & Trafelet, Ltd. One N. LaSalle St., Suite 3900 Chicago, Illinois 60602 / 1.5502 Exhibit #P0878 PIN # Date Author Addressee Description 73727-29 19-Dec-69 C H RUSSELL UNKNOWN Product specification for 2,4-D/2,4,5-T Butyl Ester Brush Killer. Exhibit #P0879 PIN # Date Author Addressee Description 73730-31 19-Dec-69 C H RUSSELL UNKNOWN Product specification for 2,4-D/2,4,5-T Low Volatile Brush Killer. Exhibit #P0880 PIN # Date Author Addressee Description 73732-33 19-Dec-69 C H RUSSELL UNKNOWN Product specification for Brush-O-Cide Brush Killer. Exhibit #P0881 PIN t Date Author Addressee Description 73734-35 19-Dec-69 C H RUSSELL UNKNOWN Product specification for 2,4-D/2,4,5-T Amine Brush Killer. IV. A . 151 15503 Exhibit #P0896 PIN * Date Author Addressee 1894-1949 01-Feb-70 J C STRUM STEPHENS, J A & ROBIRDS, LEUKE, C F it OTHERS WR Description Standard Manufacturer Process for 2,4,5Trichlorophenoxyacetic Acid Department 895.01 supersedes Standard Manufacturing Process for 2,4,5-T dated January, 1966, by L.E. Dotson, revised November, 1966 by V.L. Rhodes. Exhibit #P0897 PIN # Date Author Addressee 1894-1949 01-Feb-70 J C STRUM STEPHENS, J A & ROBIRDS, W R LEUKE, C F 4 NUMEROUS OTHERS Description Standard Manufacturing Process For 2,4,5- Trichlorophenoxyacetic Acid Department 895.01. Supercedes Standard Manufacturing Process for 2,4,5-T dated January, 1966, by L.E. Dotson, revised November, 1966 by V.L. Rhodes. TDD 1968 as high as 50ppm. Good process description. Exhibit #P0900 PIN # Date Author Addressee Description 040807-70 07-Feb-70 L G SILVERSTEIN UNKNOWN Report on safe handling of tetrachlorodibenzo-p-dioxin points out TCBD's extreme toxicity and necessary safety procedures. IV. A. 152 155 04 Exhibit #P0910 PIN # Date Author Addressee Description 1444-45 22-Feb-70 C H RUSSELL EAKEN, D A & ELLIOTT UDELL & DOLIN STEPHENS Nitro needs extra equipment for analysis of each lot. Exhibit #P0915 PIN # Date Author Addressee 15613-17 11-Mar-70 JACK FARLY MCCARVILLE DR, WM J & SPEZIALE DR, A J Description Present were, J. Mason, J. Early,(Monsanto); George Lynn, Dr. Blair(Dow); Harris Miller, Jerome Wildenfeld , Al Schlumberger(Hooker); Charles Dunn, A.E. Sidwell (Hercules). All in agreement that 2,3,7,8tetrachlorodibenzo-p-dioxin is contaminant causing high level teratogenicity, possibly less than 1ppm will cause harm. Exhibit #P0922 PIN # Date Author Addressee 76005-15 19-Mar-70 JACK D EARLY SPEZIALE DR, A J 6c SHARP, D B Description Dow Teratology Studies. Note in Monsanto possession. 2,3,7,8-Tetrachlorodibenzo-p-Dioxin highly toxic to embryos of pregnant rats. Exhibit #P0925 PIN # Date Author Addressee Description 73896 24-Mar-70 MATHEW HUDSON BOCK, EDWARD J. Letter from shareholder to President/Monsanto re: findings Bionetics study. in IV. A. 153 15505 Exhibit #P0931 PIN # Date Author Addressee Description 52983 01-Apr-70 J L SIMS EMERY, E M & LIPPMAN, A E CONKIN, R A Ascertain low limits of detection, descriptions of analysis. Exhibit #P0933 PIN # Date Author Addressee Description 73897-98 02-Apr-70 R EMMET KELLY MD HUDSON, MATHEW Kelly responds to the letter of Hudson in which he states in part that there are no teratological effects and does not know where Agent Orange was used. Exhibit #P0944 PIN # Date Author Addressee Description 7825 17-Apr-70 DON R FISCHER DISTRICT MGR S . & REGIONAL SALES DIR. PROD.MGRS.&SUPRVSRS & MRKT DVLPMNT MGRS MRKT DVLPMNT SPRVSR Document pushes for sales of all 2,4,5-T Acid, ester and formulation products or else substantial financial loss will occur if government bans product. Exhibit #P0953 PIN # Date Author Addressee Description 7658-61 24-May-70 C P ZORSCH FISCHER, D R Summarization of current situation relating to federal restrictions for the use of 2,4,5-T. IV. A. 154 15506 Exhibit #P0976 PIN # Date Author Addressee 1012 28-Sep-70 LOWELL E MILLER MANUFACTURERS OF Sc ECONOMIC POISONS Description Notice to Manufacturers, Formulators, Distributors and Registrants of Economic Poisons. Can't use chlorodioxin products. Exhibit #P0977 PIN # Date Author Addressee Description 72953 06-0ct-70 R EMMET KELLY GILLESPIE, JOSEPH Regarding rework of 2,4,5-T to get rid of the dioxin - document states should be meeting with Garrett or Wheeler of industrial hygiene group to avoid epidemic of chloracne in workers handling the impurity during stages of removal and cleanup. Exhibit #P0983 PIN # Date Author Addressee Description 146 08-Dec-70 V G PRITCHARD HABERMOHL, D E No method of analysis available for 2,4,5-T ester formulations in order to determine chlorodioxin content. Exhibit #P0991 PIN # Date Author Addressee Description 96-97 15-Jan-71 CHARLES P ZORSCH GEORGIA-PACIFIC CORP & BLACK, REX HARRIS, WERNER Working to reduce TDD to less than .5ppm for sale since Monsanto claims that said level is not detectable, and thus implicitly safe. 155C7 IV. A. 155 Exhibit #P0992 PIN # Date Author Addressee 74229-33 25-Jan-71 UNKNOWN UNKNOWN DUNLOP, R H & BURKE, B J WESSELS, R G & BAILEY, R E BONHAM, F S & NUMEROUS OTHERS Description Monthly Report - Labeling - Registration and Transportation Claims January 1971. Exhibit #P1002 PIN # Date Author Addressee 74223-26 30-Apr-71 T E ADAMCZYK LETTEKEN, MARK F & MONSANTO COMPANY Description Will not grant continuous registration must petition for renewals every 5 years, responded the U.S.D.A. to Monsanto's request. Exhibit #P1003 PIN # Date Author Addressee Description 40890-93 07-May-71 JAMES G WILSON UNKNOWN Mr. Wilson in this document indicated that TDD was not rapidly degradeable in the environment and that the data available substantiates embryotoxicity. He further believes that all species would have the same results if doses of 2,4,5-T were high enough. IV. A. 156 155CS / Exhibit #P1004 PIN # Date Author Addressee 6426-27 07-May-71 GLYNN DAVIS ROBIRDS, W R & UDELL, W R WILLIAMS, H L 4 BRATSC.l, G L JACKSON, D W & NUMEROUS OTHERS Description Document contains history of process used to reduce dioxin levels in Isooctyl T Ester of 2,4,5-Trichlorophenoxyacetic Acid. Exhibit #P1030 PIN # Date Author Addressee Description 74600-17 23-Mar-72 G ROBERT SIDO US DA Various applications for registration renewals for: 2,4,5-T Isopropyl Ester, dated 3/22/72; 2,4,5-T Isopropyl Ester dated 4/1/66; 2,4,5-T Isopropyl Ester, dated 3/15/51 . Exhibit #P1072 PIN # Date Author Addressee Description 5665-66 05-Feb-79 UNKNOWN UNKNOWN UNKNOWN Document includes, in part, key dates with regard to Monsanto's manufacture of 2,4,5-T. Exhibit #P1073 PIN # Date Author Addressee Description 90000-01 19-Feb-79 UNKNOWN UNKNOWN UNKNOWN Accident in plant involving spillage of 2,4,5-trichlorophenol which generates the highly carcinogenic dioxins. One hundred and fourteen employees with chloracne have been identified as being involved in the operation in which accident the occurred. IV. A. 157 15509 Exhibit #P1074 PIN # Date Author Addressee Description 88721-24 26-Jun-79 G EDWARD PAGET UNKNOWN Document entitled "Chlorinated Dibenzo Dioxins" - A Position Paper For Consideration By M.C. Throdahl. Exhibit #P1075 PIN # Date Author Addressee 91348-50 20-Aug-79 F J HOLZAPFEL BISHOP, D R 5c CALL IS, C F GAFFEY, W R & MCCARVILLE, W J MEYER, F C & NUMEROUS OTHERS Description Nitro Health Study Task Force Minutes of Meeting of 8/17. Dr. Sudking suggested changes in Monsanto draft of "Mortality Study". Exhibit #P1076 PIN # Date Author Addressee 87695-96 24-Aug-79 F J HOLZAPFEL GAFFEY, W R & MCCARVILLE, W J MEYER, C 5c PARK, P S WANDER, B J 5c OTHERS Description Nitro Health Study Task Force Minutes of Meeting 8/24/79. Dr. Suskind has not yet approved draft of Monsanto "Mortality Study". Study involved 121 people involved in 1949 Nitro incident who had chloracne. Carbide/University of Pittsburgh study higher incidences of 3 types of cancer in 819 deceased workers. IV. A . 158 15510 Exhibit #P1077 PIN # Date Author Addressee Description 90240-50 24-Oct-79 UNKNOWN UNKNOWN UNKNOWN Dioxins - Dibenzofuranes/Status Summary. Contains all incidents worldwide of human exposure. Exhibit #P1085 PIN # Date Author Addressee Description 91563-66 01-Mar-80 UNKNOWN UKNOWN UNKNOWN Agent Orange...What are the facts? Monsanto article in its own publication addresses AO lawsuit - highly emotional issue. Didn't produce TCB as raw material of 2,4,5-T. Exhibit #P1086 PIN # Date Author Addressee Description 91517-18 17-Mar-80 COMPANY MONSANTO UNKNOWN Monsanto News Backgrounder. Publication by Monsanto entitled "Agent Orange... What are the facts?" Monsanto Company Perspective. Exhibit #P1087 PIN # Date Author Addressee Description 91514-16 07-Apr-80 R M SCOTT NITRO PLANT & EMPLOYEE RETIREE & AND FAMILY 0 Letter in response to an inquiry regarding Agent Orange in which articles published by Monsanto were enclosed. IV. A. 159 15511 Exhibit #P1092 PIN # Date Author Addressee 90035-36 27-Apr-81 WILLIAM R GAFFEY ROUSH, G. & MCCARVILLE, W. J. LEVINSKAS, G. J. ft COLEMAN. D. L. PARK, P. S. & OTHERS Description Report on Selikoff study criticizes presentation of chloracne cases as not surprising. Exhibit #P1096 PIN # Date Author Addressee Description 94391-95 16-Dec-81 UNKNOWN UNKNOWN UNKNOWN Monsanto Company Response to Nitro W. VA Lawsuit Allegations. Press release re Nitro W. VA lawsuit, pg. 4 - 1 2 1 employees developed symptoms including skin rash known as chloracne, eye & respiratory tract irritation, headache, dizziness, nausea and liver disorders. Exhibit #P1098 PIN # Date Author Addressee Description 90157-59 16-Dec-82 JAMES H SPRAUL MD UNKNOWN Draft by James H. Spraul, M.D., document states that TCDD is highly toxic. Exhibit #P1099 PIN # Date Author Addressee Description 94334-38 21-Dec-82 UNKNOWN UNKNOWN UNKNOWN Article which discusses the effects of 2,4,5-T. IV. a . 160 1551? Exhibit #P0163 PIN # Date Author Addressee 01912-45 04-Apr-62 J E WILDER EAGAN, J.M. ABORN, H.F. & DELLINGER, R. & SIDWELL, A.E. Description Wilder to Egan memo re: facts concerning Jacksonville, Arkane, Arkansas plant; plant manual - prohibits temperature in excess of 180 degrees c . Exhibit #P0236 PIN # Date Author Addressee 26114-5 03-Jul-63 JOHN F FRAWLEY ROWE, V.K. & HUNT, W.H. Description Frawley relates clinical reports of neuropathy. . . " On the basis of these reports Leary feels that the hazards associated with the use of 2,4-D and 2,4,5-T should be understood more thoroughly" - suggests Dow and Hercules conduct a study. Exhibit #P0237 PIN # Date Author Addressee Description 26116 03-Jul-63 JOHN FRAWLEY Note re: letter of 07/03/63 from Rowe to Frawley. Note reads in reference to anti-trust laws. Exhibit #P0294 PIN # Date Author Addressee Description 00000 20-May-64 W A SMITH TURK, E. & BELLINGER, E. EAGAN, J.M. & BECKROTH, M . F . DISWELL, A.E. Progress Report - discusses recognition of an "unknown" constituent in the 2,4,5-T of IV. A . 161 1551^ approximately 8% by volume. Exhibit #P0305 PIN t Date Author Addressee Description 28118 17-Jun-64 WILD RICE ELECTRIC LYON CHEMICAL Letter from Wild Rice Electric Cooperative, Inc. to Lyon Chemical, Inc. re: report of person becoming ill after eating berries from an area sprayed with a 2,4-D and 2,4,5-T brush spray. Exhibit #P0333 PIN # Date Author Addressee Description 00000 30-NOV-64 DOW CHEMICAL Dow Analytical Method - Dow report provided to Hercules recognizing existence of dioxin and that it causes chloracne - includes example of gas chromatogram for dioxin. Exhibit #P0368 PIN # Date Author Addressee 28122 16-Feb-65 H F PIERCE FRAWLEY, J. & NEAL, J. YATES, R. & SPELTZ, D. FEDDERMAN, M. & KUNTHOLM, J. Description Letter from Pierce to Frawley re: relates a claim regarding injuries to powerline construction employees. Exhibit #P0373 PIN # Date Author Addressee 28123 22-Feb-65 JOHN F FRAWLEY WYMAN & OTHER DOW EMPLOYEES Description Letter from Frawley to Wyman - relates a 15514 IV. A. 162 claim re: injuries to powerline construction employees. Exhibit #P0406 PIN # Date Author Addressee 01282-3 19-Mar-65 V K ROWE KELLY, MONSANTO & WILKENFELD, HOOKER VERHOEZE, HOOKER & KENNEDY, DIAMOND CHANDLER, DIAMOND & FRAWLEY, HERCULES Description Rowe to each chemical company inviting manufacturers to Midland meeting . .to discuss the toxicological problems caused by the presence of certain highly toxic impurities in certain samples of 2,4,5-TLP II Exhibit #P0408 PIN # Date Author Addressee Description 01297-304 24-Mar-65 C L DUNN HERCULES FILE Dunn's handwritten minutes and notes relating to Dow's discovery of employee chloracne; 2,4,5-T; TCP; fatigue and that chloracne may be systemic; cases 25 years before; rabbit tests and damaged livers. Exhibit #P0409 PIN # Date Author Addressee Description 01290 24-Mar-65 C L DUNN HERCULES FILE Detailed Notes on Dow Visit of 03/24/65 toxic materials in 2,4,5-TCP. re Exhibit #P0410 PIN # Date Author Addressee 706001-3 25-Mar-65 E L CHANDLER KENNEDY, F.R. & KING, J.O. 15515 IV. A. 163 Description WILKERSON, M.F. Chandler reports on meeting of 03/24/65 at Dow; employees listless, fatigued; Dow concluded 1 ppm with repeat exposure can create problem; purpose of meeting to help solve "problem before outsiders confuse issue." Exhibit #P0412 PIN # Date Author Addressee Description 01347 26-Mar-65 HERCULES CORP HERCULES FILE Hercules Animal Study PPM - test results of positive response to exposure to as little as 0.4 ppm. Exhibit #P0413 PIN # Date Author Addressee 32466-7 26-Mar-65 JOHN P FRAWLEY COPELAN, JOHN G. & MAYFIELD, PAUL MADDOCK, CHARLES & MCGEE, LEMUEL RENO, P.J. & 6 OTHERS AT HERCULES Description Frawley report of 03/24/65 meeting with Dow - chloracne a systemic disease, a potent liver toxicant, lethal to rabbits; discusses constant monitoring of TCP and 2,4,5-T production for protection against illegitimate claims. Exhibit #P0414 PIN # Date Author Addressee 032489-90 26-Mar-65 C L DUNN COPELAND, J.G. SCOTT, R.B. Sc EAGAN, J.M. Sc Sc GEORGE, R.S. BELLINGER, E.S. 5 OTHERS AT HERCULES Description Memo from Dunn to Copeland re: "Highly Toxic Impurities in 2,4,5-TCP." IV. A. 164 15516 Exhibit #P0418 PIN # Date Author Addressee Description 32488 29-Mar-65 J M EAGAN WILDER, H.E. Letter from Eagan to Wilder re: toxic impurities in 2,4,5-TCP; operation of Hercules' TCP process; reactions and recommendations. Exhibit #P0420 PIN # Date Author Addressee Description 32514-5 30-Mar-65 A E SIDWELL FRAWLEY, JOHN F. & WILDER EAGAN, J.M. & DUNN, C.L. TECH. FILE Memo from Sidwell to Frawley "confidential" report of Dow meeting will be held in confidence. Exhibit #P0423 PIN # Date Author Addressee 32464-87 0 1 -Apr-65 C L DUNN HALL, R.T. & COPELAND, J.G. GEORGE, R.S. & YATES, R.T. SCOTT, R.B. & 11 OTHERS Description Memo from Dunn to Hall re: Toxic Impurities in 2,4,5-T; establish periodic examination of further production. Exhibit #P0425 PIN # Date Author Addressee Description 01348 09-Apr-65 JOHN F FRAWLEY DUNN, C.L. & EAGAN, J.M. SIDWELL, A.D. Memo from Frawley to Dunn re: Frawley aware of Monsanto and Badische history of problems which " . . . confirm the high degree of toxicity of the chloracnegens. . IV. A. 165 15517 Exhibit #P0426 PIN # Date Author Addressee Description 01348 14-Apr-65 JOHN P FRAWLEY JACKSONVILLE FILE & DUNN, C.L. EAGAN, JOHN Frawley note to Jacksonville plant file re: 2.4.5- T; Dow test results on Hercules 2.4.5-T acid shipments; some Dow rejections because a third in increasing amounts of acnegens was indicated. Exhibit #P0432 PIN # Date Author Addressee HERC0484 13-May-65 V K ROWE FRAWLEY, JOHN P. & WHEELER, E.P. Description Letter from Rowe to Frawley relates problem in analyzing for dioxin. Exhibit #P0435 PIN # Date Author Addressee Description HERC0486-7 27-May-6 5 P A TIFFANY FORD, JOHN Letter from Tiffany at Dow to Ford re: retesting 2,4,5-T acid; higher ppm than before. Exhibit #P0437 PIN # Date Author Addressee Description 00000 01-Jun-65 FRED HAGER SIDWELL, A . E . Letter from Hager at Naugatuck to Sidwell relates 1 ppm "have induced serious industrial hygiene problems." IV. A. 166 15518 Exhibit #P0444 PIN # Date Author Addressee Description 32952 30-Jun-65 HERCULES CORP HERCULES FILE Notes re: samples. Exhibit #P0448 PIN # Date Author Addressee 01384 12-Jul-65 JOHN P FRAWLEY JACKSONVILLE FILE & COPEIAND, EAGAN, JOHN & DUNN, C.L. WILDER, H.E. & 2 OTHERS JACK Description Memo to Jacksonville plant reports Dow's and Hercules' awareness that no one else has done anything to clean up their 2,4,5-T. Fears Congressional investigation and restrictive legislation. Exhibit #P0450 PIN # Date Author Addressee Description 00000 19-Jul-65 HERCULES CORP DEFENSE SUPPLY Contract between Defense Supply Agency and Hercules Power Co. date 07/19/65 to supply 638,400 lbs. of, and more at a sale price of $1,501,200; all supplies free from defects. Exhibit #P0453 PIN # Date Author Addressee Description 32512-3 26-Aug-65 J FORD TAVES, M. Memo from Ford to Taves re: summary of analytical data showing dioxin content of current production of 2,4,5-T highest single value = 4 . 8 ppm and lowest being 1.1 ppm. 15519 IV. A. 167 Author Addressee Description J HARVEY PIERCE, HENRY F. Letter from Lyon to Pierce relating that a Visko-Rhap employee had chronic complaint resulting in surgery at Mayo Clinic; how to respond to questions on the herbicide's toxicity. Exhibit #P0469 PIN # Date Author Addressee Description 28125 22-Dec-65 JOHN F FRAWLEY HARVEY, JOE Letter from Frawley to Harvey at Lyon re: Pierce letter of 11/21/65. Exhibit #P0473 PIN # Date Author Addressee Description 00000 01-Jan-66 HERCULES CORP HERCULES FILE Clinical Studies - Occupational Acne (1966) - Translated by Z.B. Blums May 4, 1967. Exhibit #P0479 PIN # Date Author Addressee 03896 24-Feb-66 E E CHRISTOFANO WILDER & SIDWELL, A.D. FORD, J.J. & EAGAN, J.M. Description Memo from Christofano to Wilder re: possible NAL study of Jacksonville plant. Exhibit #P0493 PIN # Date Author Addressee 01466 20-Jun-66 J J FORD CHRISTOFANO & DUNN, C.L. TAVES, N.A. & CONNER, A.Z. WILMINGTON FILE IV. A. 169 15521