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DO A 041850 OONF TDFNTT At PHYSIOLOGICAL EFFECTS: Effects of Exposure Acute: Eyes; N.D.Believed to be minimally irritating. Skin: N.D. Believed to be minimally irritating. TEXACI 007QO Respiratory System: N.D. Believed to be minimally irritating if not in excess of per missible concentrations; see page 1. Chronic: N.D, Other: Sensitization Properties: Skin: Yes ____ No ,, Unknown X Respiratory: Yes ____ No____ Unknown X Median Lethal Dose (LD 50I-C so l(Species) Oral ... .. N..D. ;_. similar. prQduct._G.!.T,15. g/kg. ir.atJ; pracia!ly._nQn7tQXi.. Inhalation N, D. . ._ .. __ _ . _. ____ . . __ ,. . ........ ............. .... . Dermal N.D,.; similar product G.T\ 8 g/kg (rabbit); practically non:-toxic Other .. . ___ N. . D, .......... . .. ................ ...... Irritation Index. Estimation of Irritation (Species) skin n;P,; similar, product 0,13/8.0 (rabbit); ne. appreciable effect Eyes N.D,; similar. protfuct 2.33/110 (rabbit); no.appreciable effect Symptoms of Exposure N.D, ; See above.___________________ _ ______ . ....... . ........ .......................... FIRE PROTECTION INFORMATION Ignition Temp. F.____N.D.__________ Flash Point F (Method)380 F (COC) Flammable Liniits% Lower N.D. Upper N.D. Products Evolved When Subjected to Heat or Combustion: Carbon monoxide, carbon dioxide, aldehydes and ketones, tion products of nitrogen and sulfur. combus Recommended Fire Extinguishing Agents And Special Procedures. According to the National Fire Protection Association Guide, use water spray, dry chemical, "alcohol" foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons at tempting to stop the leak. Unusual i>< Explosive Hazards None. III) Nui ................... I . I I. .ii l (in NA Not Applicable fli.in - D0 A 0A 1 B5 1 CONFTDFNTTAl [TEXACO] ENVIRONMENTAL PROTECTION Code No. -00200 Watte Disposal Method: Under RCRA, it is the responsibility of the user of products to determine, at the time of disposal, whether product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render the result ing material hazardous.(See Remarks for Waste Classification) Procedures in Case of Breakage or Leakage: Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Remarks: Waste Classification: Product has been evaluated for RCRA charac teristics and does not meet criteria of a hazardous waste if discarded in its purchased form. PRECAUTIONARY LABEL NONE CONSIDERED NECESSARY. Requirements for Transportation, Handling and Storage: Minimum feasible handling temperatures should be maintained. Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. DOT Proper Shipping Name: N.A. DOT Hazard Class (if applicable): N.A. CHEMICAL AND PHYSICAL PROPERTIES Boiling Point (F) N . D. Vapor Pressure N.D. (mmHg) Specific Gravity - ftfifl 1 (H20=1) Vapor Density N.D. (Air= 1) Appearance and Odor N.D. pH of undiluted product__ Solubility N . 0. Percent Volatile by Volume__N . O. Viscosity___ rFt~ (3__ 4 0 C =____ 10 . S Evaporation U t D. Other ___________ --( 1=1 Hazardous Polymerizations ____ _____ _ Occur Do not occur the Material Reacts Violently With (It Others is checked below, see Additional Comments on Page 4 lor further details) Air Water Meat Swung Oxidizers Others None r^O A 04 165. Ill) Nut Determined NA Nut Applicable I < ' ) 11,1M tilt (lift I i 1,11 I ~ CONFTDFNTTAI COMPOSITION Components Presenting a Significant Hazard None Code No. QQ7QP % Other Components_________________ Mineral oil Additive package containing: sulfur, nitrogen, phosphorous Methacrylate polymer Dttertiarybutylphenol Additive package containing: Sulfur %______ Greater than 95 Less than 1 Less than 1 Less than 1 Less than 1 ADDITIONAL COMMENTS________________________________________________ TEXACO INTENDS TO COMPLY FULLY WITH PROVISIONS OF THE TOXIC SUBSTANCES CONTROL ACT STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED 1982) No critical materials present. , uctumiii.e applicability or died of any law or regulation with respect to tins product user should consult his legal advisor or the appropriate government agency. Texaco docs not undertake to furnish advice on such matters fly I' . 'I. Kli'li, tills time Q1 0 8 3 _ R New Title DiV. Consul V.ll H>U L ToX l_t_'Oh"jY D Revised, Supersedes III) lint [feter mint'd N A Nut Applicable I ' 1 t 11 111 hit 11 . i II m 11 /. TEXACO INC. INDUSTRIAL HYGIENE, TOXICOLOGY, AND MATERIAL SAFETY DATA SHEET NOTE: NO REPRESENTATION 1$ MADE AS TO THE ACCURACY OP THE INFORMATION HEREIN. SEE PAGE S FOR CONDITIONS UNDER WHICH DATA ARE FURNISHED. Trade Name and Synonyms 00702 REGAL OIL R&0 68 Manufacturer's Name Texaco Inc Address P.0. Box 509 Beacon. NY 12508 Chemical Name and/or Family or Description Turbine Oil THIS PRODUCT IS CLASSIFIED AS: ------ HAZARDOUS BY DEFINITION! Nin fQI .. WARNING STATEMENT: NONE CONSIDERED NECESSARY. Emergency Telephone No. (914) 831-3400 ext. 406 X . NOT HAZARDOUS: ON ATTACHED EXPLANATION SHEETS OCCUPATIONAL CONTROL PROCEDURES Protective Equipment (Type) Eyes: Chemical type goggles or face shield optional. Skirt Exposed employes should exercise reasonable personal cleanliness; this includes cleansing exposed skin areas several times daily with soap and water, and laundering or dry cleaning soiled work clothing at least weekly. Inhalation: Ventilation: None required if exposures are within permissible concentrations; see below. Normal Permissible Concentrations: Air: 5 mg/cubic meter of air for mineral oil mist averaged over an 8 hour daily exposure (ACGIH, 1983). EMERGENCY AND> |fl^ST:jA^.viPROCEDUR^^ ? .v First Aid Eyes: As with most foreign materials, should eye contact occur, flush eyes with plenty^of water. Skirt None considered necessary. Ingestion: None considered necessary. Inhalation: None considered necessary. Other Instructions: None. NU - Nut Uelei mined N.A. - Not Applicable < Less Than > Greater Than 1 rnwrA 041 54 Conft^nTtai Effects of Exposure Acute: Eyes: Believed to be minimally irritating. Skin: Believed to be minimally irritating. Respiratory System: Believed to be minimally irritating if not in exceaa of per* missible concentrations; see page 1. Chronic: N.D. Other: Sensitization Properties: Skin: Yes----- No -- Unknown -2L_ Respiratory: Yes ----- No -- Unknown X Median Lethal Dose (LDS0 LC so XSpecies) 0rai N.D.; similar product G.T.10 g/kg (rat): practically non-toxic Inhalation ------------ Dermal ----------------Other ------------------ --------------------------------------------------------------------- -----------------------------------------------------------N.D.; similar product G.T. 8 g/kg (rabbit): practically non-toxic N. D. __________________________________________________________ Irritation Index, Estimation of Irritation (Species) 5km N.D. : similar product 0.13/8.0 (rabbit); no appreciable effect Eyes N.D.; similar product 2.33/110 (rabbit): no appreciable effect Symptoms of Exposure ^ p* i FIRE PROTECTION INFORMATION MS Ignition Temp. F. Flammable Limits% N.D. Lower N.D. Flash Point F. (Method), Upper N.D. A10WF (COC) Products Evolved When Subjected to Heat or Combustion: 1 Carbon monoxide, carbon dioxide, aldehydes and Ketones, combus tion products of nitrogen and sulfur. Recommended Fire Extinguishing Agents And Special. Procedures: According to the National Fire Protection Association Guide, use water spray, dry chemical, foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons at tempting to stop the leak. Unusual or Explosive Hazards: None. DO A 041855 CONFTDFNTIAl NO Nut Delttmlned NA - Nut Applicable < Less Than > Greater Than 2 ENVIRONMENTAL protectio ', < ijt? J/ $ .. <J' <*" 'X; i, Waste Disposal Method; _. .............. ,, ,, Under RCRA, it is the responsibility of the user of products to determine, t the time of disposal, whether product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render the result ing material hazardous.(See Remarks for Waste Classification.) Procedures in Case of Breakage or Leakage: ., Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Waste Classification: Product has been evaluated for RCRA charac teristics and does not meet criteria of a hazardous waste if discarded in its purchased form. NONE CONSIDERED NECESSARY. Requirements for Transportation, Handling and Storage: Minimum feasible handling temperatures should be maintained. Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. DOT Proper Shipping Name: N.A. DOT Hazard Class (if applicable): N.A. Boiling Point PF) ____ N.D. Vapor Pressure ----- 1-- ImmHg) Specific Gravity .... ;8762, , (H^O* 1) Vapor Density N.P. (Air1) Appearance and Odor.Lftbt Pa 18--1 iquid _ . pH of undiluted product --.W.* A* Solubility _N.D.,._... Percent Volatile by Volume ^ r - Evaporation ^P ( )= 1 Viscosity___ 64.5cSt @ AQ Other Hazardous Polymerizations ---- Occur --2-- Do not occur The Material Reacts Violently With: (If others is checked below, see additional comments on page 4 for futher details) Air Water Heat Strong Oxidizers Others Non- -* Tl------ DO A 04185A ND. - Not Delei mined N.A. - Not Applicable < Less Than > Greater Than C.ONFTDFNTT Al Components Presenting e Sipnificant Hazard None Other Components Petroleum oil Methecrylete polymer Additive peckege eonteimng: sulfur, nitrogen, phosphorous Additive peckege conttining: sulfur Oitertierybutylphenol Aryl emine Greeter then 95 Less then 1 Less then 1 Less then 1 Less then 1 Less then 1 -I..".: . :::> -l ADDITIONAL COMMENTS TEXACO INTENDS TO COMPLY FULLY WITH PROVISIONS OF THE TOXIC SUBSTANCE5 CONTROL ACT STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED 1983) No criticel meteriels present ; To determine applicability or effect of eny lew or reguletion with respect to this product, user should consult his legel edvisor or the eppropriete government egency. Texoco does not undertoke to furnish odvicc on such metters. By R. T. Richard* Dete 01-06~83 TjtlBMar. Env. Conservation & Toxicology 0 DMew Revised. Supersedes NO. - Not Delemnned NA. - Not AppllCiblf i ace Than > fyfflalflr Than a INDUSTRIAL HYGIENE. TOXICOLOGY. AND MATERIAL SAFETY DATA SHEET NOTE: NO REPRESENTATION IS MADE AS TO THE ACCURACY OF THE INFORMATION HEREIN. SEE PAGE S FOR CONDITIONS UNDER WHICH DATA ARE FURNISHED, [TEXACOI da Name and Synonyms C. -ZJ2_ Manufacturer'* Name Address P.0. Box 509 Beacon. NY 12508 Chemical Name end/or Family or Description Turbine Oil THIS PRODUCT IS CLASSIFIED AS: HAZARDOUS BY DEFINITION NO.(S) WARNING STATEMENT: NONE CONSIDERED NECESSARY. too Emergency Telaphona No. <%59 m d o&itf'HoSsr X NOT HAZARDOUS: HP a ON ATTACHED EXPLANATION SHEET 4' ** 1/ j ' :,Vc ~%z ' Protective Equipment (Type) Eyes: Chemical type goggles or face shield optional. Skin: L Inhalation: Exposed employes should exercise reasonable personal cleanliness; this includes cleansing exposed skin areas several times daily with soap and water, and laundering or dry cleaning soiled work clothing at least weekly. None required if exposures are within permissible concentrations; see below. Ventilation Required; Normal Permissible Concentrations: Alr: 5 mg/cubic meter of air for mineral oil mist averaged over an 8 hour daily exposure (ACGIH, 1983). EMERGENCY AND FIRST AID PROCEDURES First Aid Eyes: As with roost foreign materials, should eye contact occur, flush eyes with plenty of1water. Skin: None considered necessary. Ingestion: None considered necessary. inhalation: None considered necessary. Jther Instructions: None. N D. - Not Determined N A. - Not Applicable < Less Than > Greater Than 1 on A 041858 OONF tofnttai WMa Eyes: ' Skin: N.D.Belifved to be minimally irritating. N.D. Believed to be minimally irritating. Respiratory System: N.D. Believed to be minimally irritating if not in excess of per missible concentrations; see page 1. Chronic:' N.D. Other: Sensitization Properties: In: Yes___ No ___ Unknown JL Respiratory: Yes No___ Unknown _2L Yleu . Lethal Dose (LD soLCsol(Specles) Oral N.D.; similar product G.T. 10 g/kg (rat); practically non-toxic Inhalation N t,B--------------------------- ------------- DermalN.D.; similar product G.T. 6 g/kq (rabbit); practically non-toxic Other _________________ Nj__D --------- -------- , Irritation Index, Estimation of Irritation (Species) SkinN.D.; Similar product 0.13/8.0 (rabbit); no appreciable effect .yesN.D.; similar product 2.33/110 (rabbit); no appreciable effect Symptoms of Exposure N.D.; See above ... -- ....-- -iRE PROTECTIONINFORMATION^^ jnition Temp. F. N.D. Flash Point F. (Method)430oF (COC) lammable Limits0/. Lower N.D. Upper N.D. Products Evolved When Subjected to Heat or Combustion; Carbon monoxide, carbon dioxide, aldehydes and ketones, combus tion products of nitrogen and sulfur. Recommended Fire Extinguishing Agents And Speclel Procedures; According to the National Fire Protection Association Guide, use water spray, dry chemical, foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons at tempting to stop the leak. UnL,.,,al or Explosive Hazards: None. --------------- ------------------------ ___--------------------------------------------------------------------------------------------------------------------- n - Nni Dutnrmlnsd N A. - Not Applicable < Less Than > Greater Than DO A 041859 CONFTDFNTTAt. TEXACO ENVIRONMENTAL PROJECTION Code No. Q071S Waste Disposal Msho^C._J" iln&r RCRA, it is the responsibility of the user of products to determine, at the time of disposal, whether product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render the result ing material hazardous.(See Remarks for Waste Classification) Procedures in Case of Breakage or Leakage: Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Remarks: Waste Classification: Product has been evaluated for RCRA charac teristics and does not meet criteria of a hazardous waste if discarded in its purchased form. PRECAUTIONARY LABEL NONE CONSIDERED NECESSARY? Requirements for Transportation, Handling and Storage: Minimum feasible handling temperatures should be maintained. Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. DOT Proper Shipping Name. N.A. DOT Hazard Class (if applicable): N.A. CHEMICAL AND PHYSICAL PROPERTIES --- Boiling Point (F) N . D.___________ Vapor Pressure - N . D.______ (mmHgl Specific Gravity flRA-)(H^O^I) Vapor Density__N . D., (Air=1) Appearance and rtrinf 1 i ghf pal p__Lifjll id---------------------------------------------------------------- _____ pH of undiluted product N.A. Solubility N . H .__________________________ Percent Volatile by Volume_D__D..____ Viscusity___ lii.i_cS.L_fi_IP C-,, Evaporation .tL.Il.( Other__z__________________________________ Hazardous Polymerizations __________ Occur . ,_X__ Do not occur The Material Reacts Violently With (It Olliers is checked below, see Additional Commenis on Page 4 lor lurdier detailel Air Water Heat Strong Oxidizers II n lint Dint I niininl N A f'Jul A (111| t in hi I1 i '. s Ilian (iituli'i I h .n i 'S Others None u! these X fa 0A1060 00 r,0NF T0FNTT COMPOSITION nponenis Presenting a SfgpftteAnt Haaard Non* ^'i HE- [TEXACO] Cod* No. : 007IS % Other Component*_______________ Mineral oil Additive package containing: sulfur, nitrogen, phosphorous Ditert I arybutyl phenol Additive package containing: sulfur %______ Greater than 95 Lett than 1 Less than 1 Less than 1 ADDITIONAL COMMENTS ___________________________________________ TEXACO INTENDS TO COMPLY FULLY WITH PROVISIONS OF THE TOXIC SUBSTANCES CONTROL ACT STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED 1982) No critical materials present. ... determine applicability or cited ol .my law or regulation with respect to this product, user should consult Ills Ilij.iI advisor or the appropriate government agency Texaco does not undertake to furnish advice on such neuters dy N ' !< LS-'lh!! `.U ii,i,, t'l 06-H) ^ New rule . [kijv. Gjd^sei vji t ion k Tox ieO I o<jy [] Pevisetl Supersedes tin Nut ( h'lci 11 lined >' Ini rj A Nut A|ipln-,lhltl << I........... 4 00 A 04186] confidential ffcXACO INC. INDUSTRIAL HYGIENE, TOXICOLOGY, AND MATERIAL --e SAFETY DATA SHEET ITEXACOI NOTE: NO REPRESENTATION IS MADE AS TO THE ACCURACY OF THE INFORMATION HEREIN. SEE FACE 5 FOR CONDITIONS UNDER WHICH DATA ARE FURNISHED. Trade Name and Synonyms 00715 REGAt 01^*10 150 Manufacturer's Name ______ Texaco Inc Address P.O. Box 509 Beacon. NY 12508 Chemical Name and/or Family or Description Turbine Oil THIS PRODUCT IS CLASSIFIED AS: HAZARDOUS BY DEFINITION NO IS) ..... WARNING STATEMENT: HONE CONSIDERED NECESSARY. Emergency Telephone No. (914) 831-3400 ext. 406 X NOT HAZARDOUS: ON ATTACHED EXPLANATION SHEET 4 OCCUPATIONAL CONTROL PROCEDURES Protective Equipment (Type) Eyas: Chemical type goggles or face shield optional. Skin: Exposed employes should exercise reasonable personal cleanliness; this includes cleansing exposed skin areas several times daily with soap and water, and laundering or dry cleaning soiled work clothing at least weekly. inhalation: None required if exposures are within permissible concentrations; see below. Vantilation Required: Normal Permissible Concantrationa: Air: 5 mg/cubic meter of air for mineral oil mist averaged over an 8 hour daily exposure (ACGIH, 1982). EMERGENCY AND FIRST AID PROCEDURES First Aid Eyav " As with most foreign materials, should eye contact occur, flush eyes with plenty.of water. Skin; None considered necessary, mgaation: None considered necessary. inhalation: None considered necessary. Other Instructions: None. NO Not Determined N A. Not Applicable Last Than Craatar Then 1 ................ DO A 041RA2 OONFTDFNTTAl PHYSIOLOGICAL EFFECTS: Effects of Exposure Acute: Eyes: N.D.Believed to be minimally irritating. Skin: N.D. Believed to be minimally irritating. [TEXACO] Cody 007IS Respiretory System: N.D. Believed to be minimally irritating if not in excess of per missible concentrations; see page 1. Chronic: N.D. Other: - Sensitization Properties: Skin: Yet___ No __ Unknown X Respiratory: Ye* __ No___ Unknown X Median lethal Oose (10 so1C so ((Species) oral ______ ________ .lQ.gZlia.lC4iiJ-.piflci.icfllly_Jicnitcxic Inhalation . N.Ei ________ ____ ____ _________ ___ ___ _____________ ___ -- ------ oarmai . N.Et;. similar product..S,_T,.6 g/kg_ (rabbit);,practically, non-tonic Other ___ N. D.____ ________ . ----- -- -------------- Irritation Index. Estimation of Irritation (Species) skin H.E.; similar-product JL13/9.Q (.rabbit);.no. appreciable effect Eyes N.E.; similar, product.2.33/110 (rabbit); no appreciable effect Symptoms of Exposure N.Ei.- 5SS-.AfaOyft............. --................... ... .............. ............................. FIRE PROTECTION INFORMATION Ignition Temp. F _____ N.D.__________ Flesh Point F. (Method)460~F (COC) Flammable Limits*/. Lower N.D. , Upper N.D. Products Evolved When Subjected to Heat or Combustion: Carbon monoxide, carbon dioxide, aldehydes and ketones, tion products of nitrogen and sulfur. combus Recommended Fire Extinguishing Agents And Special Procedures: According to the National Fire Protection Association Guide, use water spray, dry chemical, "alcohol" foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons at tempting to stop the leak. Unusual ur Enpioiive Haiirds None. till llnl Ouh'imlnuil DA Dill Ap|illi iililo I I!..m OrdiHi r TIwmi 2 DO A 041803 CONFTDFNTTAl [texacoI ENVIRONMENTAL PROTECTION Coda; NO. : : _.flQ71S Waste Disposal Method: Under RCRA, it is the responsibility of the user of products to determine, at the time of disposal, whether product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render the result ing material hazardous.(See Remarks for Waste Classification) Procedure* in Casa of Breakage or Laakaga: Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Remarks: Waste Classification: Product has been evaluated for RCRA charac teristics and does not meet criteria of a hazardous waste if discarded in its purchased form. PRECAUTIONARY LABEL NON! CONSIDERED NECESSARY. Requirement* for Transportation. Handling and Storage: Minimum feasible handling temperatures should be maintained. Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. DOT Proper Shipping Nama: N.A. 00T Hazard Class (if applicable): N.A. CHEMICAL AND PHYSICAL PROPERTIES Boiling Point (P) M.P._________ Vapor Pressure N.D._____ JmmHgl specific Gravity BBS ^(H^O'D Vapor Oensity^HLIL_______ (Air-1) Appearance and Odor light pale liquid -- ---------------- pH of undiluted product N.A. Solubility N.D. ...-- . Percent Volatile by Volume N. h. Evaporation H. D. ( 1*1 Viscosity___ 1 A I . B rSt B f Other ---------------------------------------- ------------------ Hazardous Polymerizations_________Occur --1C-- Do not occur The Material Reacts Violently With (II Others is checked below, see Additional Communis on Page 4 for further deieilsi Air Water Meet Strong Osidizers Other* None of Theso X M (> Nil! Ovuiriiiiiittit NA Nil! A|i|ihi'lth!l' I :** Himii Gieaiur fh.ni . DO A 041864 COMFTDFNTTAl Components Patenting a Significant Haiard Non* [TEXACO] % Other Components Mineral oil Additive package containing: aulfur. nitrogen, phosphorous Oltertlarybutylphenol Additive package containing: sulfur % Greater than 9S Lees than 1 toss than 1 teas than 1 ADDITIONAL COMMENTS TEXACO INTENDS TO COMPIV FULLY WITH PROVISIONS OF THE TOXIC SUBSTANCES CONTROL ACT STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED 19S2I No critical material* present. > , determine applicability or efloct ol any law or regulation with respect to tint product, user should consult In* gal advisor or the appropriate government agency Teiaco duet not undertake to furnish advice on such matters iy !< '!' Kicliauls ............ ......Mur. Env. Conservation fc Toxicology }jiu I'l C*6* 8T ___ , 0 C4ew [1 ftuvisod. Supv'sudus (Hi Uni ttflt'iiniiitiil NA Nnl A|i|tl!t.n!ilii l *SN 9 iiflil OffMior Flirtfi 4 DO A 041865 CONFTDFNTTAI -iS S 'S h I LamlU iNb. INDUSTRIAL HYGIENE, TOXICOLOGY, AND MATERIAL ITEXACOl SAFETY DATA SHEET LL~*T 1 NOTE NO REPRESENTATION IS MADE AS TO THE ACCURACY 0* THE INFORMATION HEREIN SEE PACE > FOR CONDITIONS UNDER WHICH DATA ARE FURNISHED r#d Nam* and Synonym* 01*31 REGAL OIL RlO 220 Manufacturer* Nme ...Ttkftcs Inc Addrcit . SI'i-Bfiacpn, Jjy_12SQ_ ChmiC*l N*m* and'O' Family or Description Circulating on %_________________ THIS PRODUCT IS CLASSIFIED AS _____ HAZARDOUS BY DEFINITION NO (SI WARNING STATEMENT: NONE CONSIDERED NECESSARY. Emergency Telephone No. AQL _X____ NOT HAZARDOUS ON ATTACHED EXPLANATION SHEET 4 OCCUPATIONAL CONTROL PROCEDURES Protective Equipment (Type) ---------- Vfo- Eye* Chemical type goggles or face shie Id optional .''l X 7Qo0 IND Hvn 92 MyGlEtiF n Skill Exposed employes should exeircise reasonable personar'cWityi iness; tins includes cleansing exposed skin areas several times daily with soap and water, and laundering or dry cleaning soiled work clothing at least weekly. Inhalation None required if exposures are within permissible concentrations; see below. Ventilation Required Normal Permiitibie Concentration* Al' 5> mg/cubic meter of air for mineral oil mist averaged over an 8 hour daily exposure (ACG1H, 1962'. EMERGENCY AND FIRST AID PROCEDURES riftl Aid Eyci As with most foreign materials, should eye contact occur, flush yes with plenty of water. Skin None considered necessary. Inyeviiuit None considered necessary. Inhalation None considered necessary. Other liiviiuciiiinv s.l r None. ftV- H I* Ui't LKIlimmiicJ !"*. Ih.iM N A Nut Afifjlit *iblc lit,hi 1 C0^TnFNTTAl6 PHYSIOLOGICAL EFFECTS: s 0< Exposure Eyci. N.D.Believed to be minimally irritating. Skin: N.D. Believed to be minimally irritating. Code ____Q1531. Reipntiory Svtttm N.D. Believed to be minimally irritating if not in excess of permissible concentrations; set page 1. Chrome: N.D. S*nsnil*tion Properties Skin. Yes ____ No ___ Unknown X Rtipiritofy Vet - No____ Unknown _2L lelhel Dote (LD jc,LC so KSpecinl Orel N.D.; believed iniiaUnun N.D. Ovnnai N.D.; believed Oilier N. D, to be G.T. > g'kg irat,;practicallynon-toxic to be G.T. 3 g/kg rabbit); practically non-toxic In nation hide*. Estimation ol Irritation (Species! Skin n.d.; believed to be L.T. I'.S'B.O (rabbit;; no appreciable effect Evtv N.D.; believed to be L.T. 15/110 (rabbit); no appreciable effect Symptoms ot Enpotun N.D,; Hone expected other than possible minimal irritation FIRE PROTECTION INFORMATION tyimion lump F N.D. Flesh Point F (Muthodl 47$ F COC> flammable limns";. lower N.D, Upper N.D. PmiKnu Ivoiaad When SubiCCted to Heat or Combustion Carlx>n mon&airio, carbon dicxidt, aldehydes anrl ketones, combus t ion products of nitrogen ar.d sulfur. Rfi ommemlud Fire Cilmyuif lung Agents And SpeCill Procedures According to the National Fire Protection Association Guide, use water spray, dry chemical, "alcohol" foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool (ire-exposed containers. If a leak or spill has not ignited, use water spray to disperse die vapors and to provide protect ten foi pri sons at i i-ii.p t 11 ig t <" stop lit*4 I i^ak . IM l*9llVtvC IlfW.WUv * Mwii*", ,; *' . s&fesr  , [TEXACO! ENVIRONMENTAL PROTECTION Coda No -01531 Warn Onposai Mttnoe Under RCRA, it is the responsibility of the user of products t determine, at the time of disposal, whether product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render the result ing material hazardous. See Remarks for Waste Classification) Procedure* <0 Ctlt 0< B'ttUtyt or leakage Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Remark* Waste Classification: Froduct has been evaluated tor RCRA charac teristics and does not meet criteria of a hazardous waste if discarded in its purchased form. PRECAUTIONARY LABEL NONE CONSIDERED NECESSARY Requirement* tor Titmpo'Uiion Handling nd Storage Minimum feasible handling temperatures should be maintained. Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. DOT Proper Snipping Name DOT Hata'd Ci*t (it applicable) It, A. N.A. CHEMICAL AND PHYSICAL PROPERTIES Boiling Ruint (*F) ...--.M^D--------------- Vapvr Pititu'O _Ji.(minltgl Spociin Gravity _ . . 6S21______ .... (M^OTI Vapor Damny. ,H. D.. ...... (Ainll ApppuraiiLe and Odor _ cleax. and red____ _______________________ -- _____ ,,_____________ pM lit uiidiliiteo p'uUuCI 11. A. _ So'ubtltly 11. D. _______________ _ ,, _ Furcant Volatile by Volume .. __ Evaporation iJ.D.___ ,, ______. ( 1*1 ViutHiiy 2.QS.5 i:SL l. 10 . C Oti.et ............ ... Mm/iH(Itmv Polymthi/dtHiiii B. , UcCuf tliu nes*civ Vmlfiiily Willi (If OtfiC't 'S All W.|ls* llMl 1 Un not tift u* l>CHw VL'C StMlilU III! fliil (trtlr ii.mc-iI In || A Ni-1 i. Altlr * . CiHimifitl* ih f*yC 4 flu* luflh|!r ilrt.til*,)1 (MtiVtV fJ**-* no a 0 tAI TEXACO INC. INDUSTRIAL HYGIENE, TOXICOLOGY. AND MATERIAL SAFETY DATA. SHEET NOTE NO REPRESENTATION IS MADE AS TO THE ACCURACY OF THE INFORMATION HEREIN. SEE PAGE 7 FOR CONDITIONS UNDER WHICH DATA ARE FURNISI-ED. Trade Name and Synonyms < t 008 3 Manufacturer's Name Texaco Inc. Emergency Telephone No. w f91Al 831-3400 ext. 204 Address P.0. Box 509 Beacon. NY 12508 Chemical Name and/or Family or Description Circulatinc Oils . i. } , * ' J ** $* THIS PRODUCT IS CLASSIFIED AS: X . NOT HAZARDOUS: HAZARDOUS BY DEFINITION NO.(S) WARNING STATEMENT: -tN0NE CONSIDERED .NECESSARYJ- >:- : ' ; . f s>7 - ON ATTACHED EXPLANATION SHEETS y!|fir,'/ *-70 i Jr : r-J j*r:-v3 eloitseia ',.// i+mlV'*.' < `1 "* - v" ^ - Xf.ci*,.'1*-' r*''V ' * . . .(! *W : >' A *' * > ~ Protective Equipment CTypal Eyas :< Cheatical type goggles or Face shield optional. Skin: Inhalation; Exposed employe* should exercise reasonable personal cleanliness; ^this\includes cleansing exposed skin areas several timee^daily ^ . . with soap and water, and laundering or dry cleaning Yolled'work trr*' clothing at least weekly '!*-' , * : t( .; .'.-i ' ,, _ r * *.5-' ".'v .. -None-required if exposures are within permissible concentrations; *?** V f i r ; *:T.- f!'* *t/ ........................ Vantilatiore ,, Adequate.to meat component permissible concentrations. , n , r* * -- * * y\ + J* < e**< ^ * *****/ f ^ Parmt**ibl*_Concantr*tiona:..,,.... m . t;- V ,Hf': i Ain None established for product; refer'. torpage-4' for> component1-'WW rr .<**' * ..o^-w^if'fcermisaible `concentrattiions . -------------* :>-v-A'' vv v;. Vx" V"! Cj#*t Aid "tf* ' \ ' -J V |,r * i*: -* ` T.-v* ( Eyem '^^^`^ Asiwith most foreign`materials. shouldieye contactsoccur,I'flush;'V ' l2.eyelivi_th_P1 anty of water.' ' 3 . .. -------JI-J?--_ ^^>>1 ' 1 *-*. !f ... vr* t .--x ? - ; .* - Skin: Wash exposed areas with soap and water.' Ingestion: None considered necessary. Inhalation; None considered necessary. Other. Instructions: None. N.D. - Not Determined < - Lass Than N.A. - Not Applicable > - Greater Than RECEIVED 'JAN 151993 IND. HYGIENE DEPT. r,o A CONr-TnFNTTW. I V'/v . PHYSIOLOGICAL EFFECTS Effect* of Exposure Acute: Eyes: ... . Believed to be minimally irritating* Skirt Believed to be minimally irritating. tt# yr V- Respiratory System: Believed to be minimally irritating if not' in excess of per missible concentrations; see page 1. Chronic \ , . T.' . , , r N.O. ~ '7 V " .7-'^ ~ ^ ' v. ,"j r>w. - * * - .;_ ------- - Vv..*"' 'tWrfff[)^BtJvii<aetC' b tm srlm5n1 ?.* . r.eLjjioji ->*:'*. *> .L.1+ *4<*^ r wr' ; a aer> *! or, o I a ;*n*` a'l^o p irrtor `e-* - : fyeaStjkji isT-vpr; ni^-t h "* h o r. .*fi i vrir.e ,<o rh}> I *.*n j tifiJ . Sensitixatjon}Properties: ^- ri-.u gnii^bmel brt ,iels'- *i1*V -. ` ' '1 ' '- " ,vf *< irt* -rar;* ? ' $*' r'ltftftii}'1? Skirt Ye*___ No -- Unknown A- Respiratory: Ye# ----- No----- Unknown JL v< i / * -.t`- Median Lethal Dose (LDgo t-Cgo KSpecies) _ 'W < Qcjj _________________ Believed to be >5 g/ka (rat): practically non-toxic inhalation -----------Dermsj - , N.D. Believed to be >3 g/kg (rabbit): practically non-toxic Other ------------------ N. D. Irritation Index. Estimation of irritation'(Species)V* - i Skin_________________ Believed to be <0.5/8.0 (rabbit); no appreciable effect Eyes*----------- :.-_-_--_--_-_--_ -- Believed to be <15/110-(rabbit) : no appreciable'effect-------ivmnrnnw nf c---None~expected other than possible minimal irritation 1*' v * v' in .? v:s-W:. "-v y^yJs-.a^.fc^y.WWfc Ignition Temo.F. N.D. Flash Point >F.' (Method) ^ 520 F -(COC Flammable Limits (%) Lower N.D. Upper N.D Products Evolved When Subjected to Heat or Combustion: ' r<- Carbon monoxide, carbon dioxide, and aldehydes and ketones may b formed. Recommended Fir* Extinguishing Agents And Special Procedures: According to the National Fire Protection Association Guide, use water spray, dry chemical, foam, or carbon dioxide. Mater or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons at tempting to stop the leak. Unusual or Explosive Haiards: None. N.D. - Not Determined < - Less Than N.A - Not Applicable > - Greater Than 2 A 04 i o ^ OONFTnFNTTM - Undar RCRA, it is the responsibility of the user of products t determine, at the time of disposal, whether product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render the resultirig' material hazardous.(See Remarks for Waste Classification.) Procedures in Cese of Breakage or {.eakage: (franspprtation Spills Cell CHEMTREC (800) 424-9300) Contain spill if possible. Wipe up or absorb on suitable material 1 >"*7-vand 'shovel up. - - r. j *-t ; - - 'I W<tr; f i /!', i '?'>'} jS.Tc I'.sr' Remarks; if* * ` * :* .a?i! s-'-- ..It * i - --! i -- % >: l*. i.'ij *,< f'r :<< r n j 1 -i. .v Waste Classification! Product has been evaluated for RCRA charac- teristies and does not meet criteria of a hazardotis waste if discarded in its purchased form. NONE CONSIDERED NECESSARY Requirements for Transportation. Handling and Storage; --- - - -- - ----- * ^Minimum feesible^handling .temperatures should be maintained.^' Periods' exposure to"high temperatures should be minimized,-^ Water contamination < should ber avoided. --ir j, < ' DOT Proper Shipping Name: N.A. DOT Hazard Class (if applicable): N.A. Boiling Point PF) Specific Gravity 0.8927 Appearance and rvw Dark red - Vapor Pressure fttPi . (H^O-1) Vapor Density- (mmHg) . (Air-1) pH of undiluted product __N. A.--n Solubility N*D` Percent Volatile by Volume N.Pt Viscosity AOQ cSt @_4Q C Evaporation h.D, Other >-1 Hi leaszeairuduouuas Pruoilyyimriecrizsaetiouniias em -- vO^ctcuuir vDuo intuot goccuir The Material Reacts Violently With: (If others is checked below, see additional comments on page for futher details! A*i"r W***ater Heat Strong Oxidizers Others None of These x oA-'f'7! N.D. - Not Determined < - Less Than N.A - Not Applicable > - Greater Than 3 oo C,0^F V '* r f" Chemical/Common Name 't CAS No. Expoiure Limit Rang in 1 Hydrotreated C25 bright^atoekrbased lubrica- . .72623837 ^.Sag/mS ACClH*(MIST) ting oil -1 . ' 5mg/m3 OSHA (MIST) :-:r 7 -'`77! ioiWstel. (mist) Solvent-dewaxed heavy paraffinic petroleum 64742650 5mg/st3 ACGIH (MIST) distillatea 5mg/m3 OSHA (MIST) 10mg/m3 STEL (HIST) 80.00 ~ 94.99 4.00 " 10.99 To the beat of our knowledge, none of the above listed components is hazardous according to OSHA (1910.1200) or one or more state Right-To-Know lists. i -?<s:*bH5 J* ifrl MSsulfi'-'t' fissd :<r. o \ ` i J.r,pi ! tr,eJ > p *Bf-W 3r ^rb'feVaia^ * *>i' ns.'. >" jrn^teeb bn*: Jen*? ... n > br.-ii e fs J b i 1 v" IT =t*v/ ;n L Title III Section 302/304' 4Extremely Hazardous Substance ' ' " r<` ' Component CAS No. NONE !1` % ,*J * *6 :r;X^ ' RQ (Lbs) ; ' TPQ (Lbs) II. CERCLA Section 102(a) Hazardous Substance Component NONE CAS No. RQ (Lbs) III. Title III Section 311 Hazard Categorization Acute Chronic Fire IV. Title III Section 313 Toxic Chemicals Component NONE . Pressure CAS No. Reactive Not Applicable X ^ A 04187 OOMrTDFNTTAI r ryAi 00838 REGAL OIL.390 NONE CONSIDERED NECESSARY Chemical/Common Name CAS No. Range in t Hydrotreated C25 bright stock-based lubrica- 72623837 80.00 - 94.99 ting oil i Solvent-dewaxed heavy paraffinic petroleum .64742650 4.00 - 10.99 distillate* i !. Totjhe beat of our knowledge, none of the above lifted component* ii hazardous according to OSHA (1910.1200) or one or more state Right-To-Know lists. Not hazardous according to DOT criteria ! | ; ; HMIS ! Health : 0 Reactivity 0 { Flammability: 1 Special - I i\ \ i i CAUTION: Misuse of empty containers can' be hazardous. Empty containers can be hazardous if used to store toxic, flammabl or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat Keep container closed and drum bungs in place. HEALTH EMERGENCY TELEPHONE: <914) 831-3400 <EXT. 204) For Additional information Concerning: Texaco Inc. 2000 Westchest r Avenue .White Plains/ New *York 10660 z9 > vd--d .\vr.v.wi*> Fuels/Lubricants/Antifreezes call <914) 831-3400 <EXT.204) Chemicals '.. ,; ball <512) 459-6543/; .V' ? Transportation Spills ^ .call CHEMTREC (800) 424-9300 DO A 041870 OONFXDFNTTAL 5  tm*-'si$i V' <"1' CodA' ^ *>X'V'* .' * '5*$^. x-. , No, '' >- 00836* TEXACO INTENDS TO COMPLY FULLY WITH PROVISIONS OF THE TOXIC SUBSTANCES CONTROL ACT STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED 1987) No critical materials present. .01 i'\i f:: n ' : ) nuohtessfl ei : i^ .F.It.J* W'Ti'vi' > , ' ,ir`-'.,fi ` .1 t/H 1 'i r * L'S wt * , Tf 1 \ f - ` ' ; 3 .'SVr-.r : -i V v;-i- . -' * " V.'Ort "u *' ' ''< j-. i'1 v : 'll ' ' i./f-1.' ./ j/lli' *tl ops 1*,4 o 1 i i To d termine *>plicability or effect of any law or regulation with respect to the product users should consult his legal advisor or the appropriate government agency. Texaco does not undertake to furnish advice on such matters. By _ R. T. Richards 04-19-&8 Date New Mar. Env, Conservation & Toxicology tti " ' "Tl i A-n7 ' ~ Q Revised. Supersedes m n -- Not N4 - Applicable DO A 041B7A CONFTDFNTTAl INDUSTRIAL HYGIENE, TOXICOLOGY, AND MATERIAL ^ SAFETY DATA SHEET rTEXACUl NOTE NO REPRESENTATION IS MADE AS TO THE ACCURACY OF THE INFORMATION^^^^ HEREIN. SEE PACE S FOR CONDITIONS UNDER WHICH DATA ARE FURNISHED Trade Name and Synonyms 02111 URSA 3WSIPWSfS*5AE 20-20W Manufacturer's Name Emergency Telephone No. Texaco Inc Address _______ (914) 831-3400 ext. 406________________________ P.O. Box 509 Beacon. NY 12508 Chemical Name and/or Family or Description Automotive Motor Oil THIS PRODUCT IS CLASSIFIED AS: X not hazardous HAZARDOUS BY DEFINITION NO (SI ON ATTACHED EXPLANATION SHEET 4 WARNING STATEMENT: WARNING: AVOID SKIN CONTACT WITH USED MOTOR OILS OCCUPATIONAL CONTROL PROCEDURES Protective Equipment (Type) Eyes. Chemical type goggles or face shield optional. Skin Exposed employes should exercise reasonable personal cleanliness; this includes cleansing exposed skin areas several times daily with soap and water, and laundering or dry cleaning soiled work clothing at least weekly. Inhalation None required if exposures are within permissible concentrations; see below. Ventilation Required: Normal Permissible Concentrations; Am 5 mg/cubic meter of air for mineral oil mist averaged over an 8 hour daily exposure (ACGIH, 1982). EMERGENCY AND FIRST AID PROCEDURES First Aid Eyes; As with most foreign materials, should eye contact occur, flush eyes with plenty of water. Skin None considered necessary. Ingestion: None considered necessary. inhalation; None considered necessary. Other Instructions: None. N D - Not Determined N4. Not Applicable - Less Than Greater Than 1 0 A (14 1 7 C, CONFTDFNTTAi / [TEXACO] / ENVIRONMENTAL PROTECTION Code _____ 02111. Waste Disposal Method: Under RCRA, it is the responsibility of the user of products to determine, at the time of disposal, whether product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render the result ing material hazardous.(See Remarks for Waste Classification.) Procedures in Case o< Breakage or Leakage: Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Remarks: Waste Classification: Product has been evaluated for RCRA charac teristics and does not meet criteria of a hazardous waste if discarded in its purchased form. PRECAUTIONARY LABEL WARNING: AVOID SKIN CONTACT WITH USED MOTOR OILS Used motor oils have caused skin cancer in laboratory ani mals when repeatedly applied and left In place between app lications. In case of skin contact, promptly wash thorough ly with soap and water. Oil-soiled clothing should be cleaned before reuse Requirements for Transportation. Handling and Storage: Minimum feasible handling temperatures should be maintained. Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. DOT Proper Shipping Name: N.A. DOT Hazard Class (if applicable): N.A. CHEMICAL AND PHYSICAL PROPERTIES Boiling Point N.D. Vapor Pressure . M-D- (mmHg) Specific Gravity -8871 (H-0=1) Vapor Density N.D. __ (Airl) Appearance and Orinr bright_and clear pH of undiluted product W - A. Solubility H.D. Percent Volatile by Volume H - D.___ Evaporation M. D. ( )*1 Viscosity 62^ 7 C-St @ iQ--C---- Other -- ----------------------------------------------------------------------------- Hazardous Polymerizations _________ Occur X.Do not occur The Material Reacts Violently With: (If Others is checked below, see Additional Comments on Page 4 for further details) Air Water Heat Strong Oxidizers Others None of These X N 0 Nut Dtiteriiilhod N A Nut Applicable v Less Than > Greater Than 3 00 A 041877 OONFIDFNTTAl COMPOSITION .omponents Presenting Significant Hazard None TEXACO jh. Code No. 02111 V. Other Components Mineral oil Methacrylate polymer Additive package containing: suitor, nitrogen, zinc, phoiphorus Alkenyl succimmide % 80 - 95 Less than 1 10 - 20 1 -5 ADDITIONAL COMMENTS TEXACO INTENDS TO COMPLY FULLY WITH PROVISIONS OF THE TOXIC SUBSTANCES CONTROL ACT STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED 1982) 0 12o zinc, conversion factor 7.4 pounds per gallon New and used motor oils have been tested for potential carcinogenicity in laboratory mice Only used motor oils were shown to cause skin cancer when repeatedly applied to mice without any effort to remove the material between applications Strict compliance to the occupational control procedures outlined in this Oata Sheet is believed to be adequate protection from such hazards. . jeternune applicability or effect of any law or regulation with respect to this product, user should consult his legal advisor or the appropriate government agency. Texaco does not undertake to furnish advice on such matters. By R. T. Richards Date: 01 -07-83 a New Title Mgr. Env. Conservation S. Toxicology 0 Revised. Supersedes NO Not Outurmined N A. - Not Applicable v Less Than > Greater Than .* PRODUCT CODE: 01659 PROOUCT NAME: RANDO OIL HO 68 PRODUCT LABEL Date Issued: 1 2/05/90 Superc des: ('6/21/89 READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT 01659 RANDO OIL HO 68 WARNING STATEMENT NONE CONSIDERED NECESSARY PRECAUTIONARY MEASURES AVO10 PROLONGED BREATHING OF MIST OR VAPOR WORKERS SHOULD WASH EXPOSED SKIN SEVERAL TIMES DAILY WITH SOAP AND WATER INGESTION: fLftST MB If more than several mouthfuls have been swallowed, give two glasses of water (16 oz.). Get medical attention. ZftiALATION: If Irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or symptoms persist. EYE CONTACT: Flush eyes with plenty of water for several minutes. Get medical attention If eye irritation persists. SKIN CONTACT: Wash skin with plenty of soap and water for several minutes. Get medical attention If skin irritation develops or persists. NOTE TO PHYSICIAN: High pressure Injection of material into skin. If not properly treated, can cause severe Injury, Most damage occurs during first few hours. Failure to debride the wound of all residual material can result In disfigurement, loss of function, or even require amputation of the affected area. The extent of the Injury cannot be determined by examining the wound. X-ray may reveal the presence of gas In tendon sheaths or soft tissue. FIRE In case of fire, use foam, dry chemical, or C02. Use water spray to keep containers cool. Chemical/Common Name CAS No. Range 1 n % $ 1vent-dewaxed heavy paraffinic petroleum 64742650 95.00 - 99.99 distillates Pr duct Is non-hazardous according to OSHA (1910.1200). Not classified as a hazardous material by DOT definition. HM1S Health : O Reactivity : O Flammability: 1 Special :- National Fire Protection Assoclatl n Health : 0 Reactivity : O Flammability: 1 Special :- CAUTION: Misuse of empty containers can be -hazardous. Empty containers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pr ssurlze or expose to open flame or heat. . Keep container closed and drum bungs in place. Manufacturer's Name Texaco Lubricants Company a Division of Texaco Refining and Marketing Inc. P.0. Box 4427, Houston, TX 77210-4427 TRANSPORTATION EMERGENCY Company: CHEMTREC: (914) 831-3400 (800) 424-9300 HEALTH EMERGENCY Company: (914) 831-3400 Co^?oe/JrJftJI9 - . ;. vP.O. Box 1666 k.'i Midland.-Michigan 48641-1666 ^|)>i96-^78'0 FACSIMILE: -(517) 496-3469 Section 1 Emergency Number: (517)496-3780 Product Name and Information Product(Trade Name and Synonyms): CP-4601 Series Chemical Name: Polyalphaolefin Chemical Family: Synthetic Hydrocarbon Formula. CionH20n+2 CAS#. Proprietary Section 2 Components and Hazard Statement This product is non-hazardous. The product contains no known carcinogens. No special warning labels are required under OSHA 29 CFR 1910.1200. Section 3 Safe Handling and Storage Handling. Do not take internally. Avoid contact with skin, eyes, and clothing. Upon contact with skin, wash with soap and water. Flush eyes with water for 15 minutes and consult physician. Wash contaminated clothing before reuse. Storage. Keep container tightly sealed when not in use. page 1 D0 A 0418fio CONFTDFNTTAI Section 4 Physical Data Appearance: Clear liquid, yellow to light brown tint Boiling Point:>300F Vapor Pressure:<0.01fnmHg @ 20C Specific Gravity(water=1 ):0.80-0.85 Volatiles, Percent by Volume. 0% Odor: None Solubility in Water: Insoluble Evaporation Rate(buty) acetate-1). Ni! Section 5 Fire and Explosion Hazards Flash Point (by Cleveland Open Cup): 310-550'F Flammable Limits: not established Autoignition Temperature: no data HMIS Ratings: Health: 0 Flammability: 1 Reactivity: 0 NFPA Ratings: not established Extinguishing Media: Dry chemical; C02 foam; water spray(fog) Unusual Fire and Explosion Hazards: None Special Fire Fighting Techniques: Burning fluid may evolve irritating/noxious fumes. Firefighters should use NIOSH/MNSA-approved self-contained breathing apparatus. Use water to cool fire-exposed containers. Use water carefully near exposed liquid to avoid frothing and splashing of hot liquid. page 2 pp A OAT 881 C.ONFTDFNTTAi Section 6 Reactivity Data Stability: Stable Hazardous Polymerization: Will not occur Incompatible Materials Strong oxidizers ^ Conditions to Avoid: Excessive heat Hazardous Decomposition Products Analogous compounds evolve carbon monoxide, carbon dioxide, and other unidentified fragments when burned See Section 5 Section 7 Health Hazard Data Threshold Limit Value 5mg/m3 ACGIH Situations to Avoid: Avoid breathing oil mists First Aid Procedures Ingestion: Consult physician at once DO NOT INDUCE VOMITING. May cause nausea and diarrhea Inhalation: Product is not toxic by inhalation If oil mist is inhaled, remove to fresh air and consult physician To the best of our knowledge the toxicity of this product has not been fully investigated. Analogous compounds are considered to be essentially non-toxic. Section 8 Personal Protection Information Respiratory Protection Use in well ventilated area Ventilation Local exhaust Protective Gloves Not required but recommended, especially for prolonged exposure Eye/Face Protection Goggles page 3 DO A 04i& CONFJDFNTT I> CD Section 9 Spill or Leak Procedures In Case of Spill: Wear suitable protective equipment, especially goggles. Stop source of spill. Dike spill area. Use absorbent materials to soak up fluid(i.e. sand, sawdust, and commercially available materials). Wash spill area with large amounts of water. Properly dispose of all materials. Section 10 Waste Disposal Methods Incinerate this product and all associated wastes in a licensed facility in accordance with Federal, state, and local regulations. The information in this material safety data sheet should be provided to all who use, handle, store, transport, or are otherwise exposed to this product CPI believes the information in this document to be reliable and up to date as of the date of publication, but makes no guarantee that it is. Prepared by 5 93 fstian Thelander, Chemist page 4 HO A 041883 CONFTDFNTTA1 03/07/90 11:49 0517 490 2313 4m CPI ENGINEERING 8)004 K'yo r\ n Emergency Number: (517)496-3780 -wCDU ^)Vi/l <u_ Section 1 (l-7*<fO Product Name and Infi Cpr-mofrlO-^g Product(Trade Name and Synonyms): Chemical Name: Polyalphaolefin Chemical Family: Synthetic Hydrocarbon Formula: Cl0nH20B+2 CAS#: Proprietary Section 2 Components and Hazard Statement This product is non-hazardous. The product contains no known carcinogens. No special warning labels are required under OSHA 29 CFR 1910.1200. Section 3 Safe Handling and Storage Handling. Do not take internally. Avoid contact with skin, eyes, and clothing. Upon contact with skin, wash with soap and water. Flush eyes with water for 15 minutes and consult physician. Wash contaminated clothing before reuse. Storage. Keep container tightly sealed when not in use. page 1 03/07/86 11:49 f}517 496 2313 CPI ENGINEERING (2)005 Section 4 Physical Data Appearance: Clear liquid, yellow to light brown tint Boiling Point:>300*F Vapor Pre$sure:<0.01mmHg @ 20'C Specific Gravity(water=1):0.80-0.85 Volatiles, Percent by Volume: 0% Odor. None Solubility in Water: Insoluble Evaporation Rate(buty! acetate-1): Nil Section 5 Fire and Explosion Hazards Flash Point (by Cleveland Open Cup): 310-550'F Flammable Limits: not established Autoignition Temperature: no data HMIS Ratings: Health; 0 Flammability: 1 Reactivity: 0 NFPA Ratings: not established Extinguishing Media: Dry chemical; C02 foam; water spray(fog) Unusual Fire and Explosion Hazards: None Special Fire Fighting Techniques: Burning fluid may evolve irritating/noxious fumes. Firefighters should use NIOSH/MNSA-approved self-contained breathing apparatus. Use water to cool fire-exposed containers. Use water carefully near exposed liquid to avoid frothing and splashing of hot liquid. page 2 A 04Iroc 03/07/86 11:30 317" 486 2313 CPI ENGINEERING 12 008 Section 6 Reactivity Data Stability: Stable Hazardous Polymerization: Will not occur Incompatible Materials: Strong oxidizers Conditions to Avoid: Excessive heat Hazardous Decomposition Products: Analogous compounds evolve carbon monoxide, carbon dioxide, and other unidentified fragments when burned. See Section 5. Section 7 Health Hazard Data Threshold Limit Value: 5mg/m3 ACGIH Situations to Avoid: Avoid breathing oil mists First Aid Procedures: Ingestion: Consult physician at once. DO NOT INDUCE VOMITING. May cause nausea and diarrhea. Inhalation: Product is not toxic by inhalation. If oil mist is inhaled, remove to fresh air and consult physician. To the best of our knowledge the toxicity of this product has not been fully investigated. Analogous compounds are considered to be essentially non-toxic. Section 8 Personal Protection Information Respiratory Protection: Use in well ventilated area Ventilation: Local exhaust Protective Gloves: Not required, but recommended, especially for prolonged exposure. Eye/Face Protection: Goggles DO A 041886 CONFTDFNTTA! narn =oevco sector sbc MATERIAL SAFETY DATA SHEET 1'X2 *013 P.BisVSS PENNZOtL PRODUCTS OOMMASY 1. PRODUCT IDENTIFICATION MANUFACTURER'S NAME PEMiZOIL COMPANY ADDRESS P.0. BOX 3857 HOUSTON. TX 77252-3087 EMERGENCY TELEPHONE NO. (800) 54C-G040 cas mooer* Nurgne MSD9 CODE* 006851 NFPA HAZARD IDOfTIFICATIlM 0E6REE OP HAZARD HAZARD RATINGS LEAST HEALTH: 1 1-SU8HT FIRE: 1 REACTIVITY* 3-MODERATE 5-HIGH 4-EOTZEME 8Y; ENVlRQftCNTAL, SAFETY | HEALIM (000) 548-6227 2. INGREDIENTS EFFECTIVE DATE; DECEMBER 21. 1953 SUPERSEDES DATEi JANUARY 33. 1993 COMPONENT NAME CAS NtMBER HAZARDOUS IN PERCENTAGE BLEND MIN MAI COMPONENT EXPOSURE LIMIT UNIT deterbdvt iimibitm BASE LUBRICAHNS OIL ORGANIC ALCOHOL TRADE SECRET NO NO NO 80 TO 75 25 TO 35 <1 09LA PEL acgih nv 09HA PEL ., acgzh TLV OSHA PEL ACGIH TLV NO LIMIT NO LIMIT NO UNIT NO UNIT NO LIMIT NO LIMIT 3. HEALTH INFORMATION AND PROTECTION EVE CONTACT: SKIN CONTACT: THIS PRODUCT IS PRACTICALLY NON-IRRITATING TO TIC EYES UPON DIRECT CtMTACT. BASED ON TESTING OF SIMILAR PRODUCTS Att/OR COMPONENTS. AVOID SKIN CONTACT. THIS PRODUCT 19 MINIMALLY IMITATING TO THE SKIN UPON DIRECT CONTACT. BASED ON TESTING OF SIMILAR PRODUCTS AIIQ/M CtffffDCNTS. PROLONGED OR REPEATED CmTACT NAY RESULT IN CONTACT OEmATITI* NKICH 19 OWRACTERIZED BY DRYNESS. CHAPPlNB, AND RfcDDENDC. THIS CONDITim MAY HAKE THE SKIN ROBE SUSCEPTIBLE TO OTTER IRRITANTS. SENSITIZERS. MD DISEASE. PROLONGED OR REPEATED CONTACT NAY RESULT IN OIL AOC U04 19 DIARACTERIZED BY BLAOMEADB WITH POSSIBLE SECONDARY llCTltH. SEE HEALTH DATA SECnON BELOW. 2B'd 01'd S6S tassest ol 83:^0 tr0-0-B66I 1363 3 t-0S DO A 041887 CONFTDFNTTAi LTMJ HUES .GO <L6l-92-B8 ON3 S1tJia33W nod: WOMd FROM SDEXCO (JECTQR SBC 504 3E3 BE9G 1W7.B9-82 t*>12 M13 P.0Z/B5 CODE: 006652 NAME: UCWA - SOLVE PAGE 12 XM1ALAT2QN: INGESTION: THIS PRODUCT HAS A IQH VAPOR PRESSURE MB IS NOT EXPECTED TO PRESENT Ml ntfAlATIW HAZARD AT AMIENT CONDITIONS. CAUTIf SHOULD BE TAKEN TO PREVENT AEROSOLIZATION OR MISTING Of THIS PMWET. DC rCKHXSSABLE EXPOSURE UNIT (PEL) AMO THCSHOLD LIMIT VALUE (tlV) FOR THIS PRODUCT AS OIL MIST 19 9 MS/M3. EXPOSURES BELOW 5 HE/H3 AFffiAR TO BE WITHOUT SIGNIFICANT HEALTH RISK. TTC SHORT-TERM EXPOSURE LIMIT FOR THIS PRODUCT AS AN OIL NIST 15 10 I&N3. DO NOT INBEST. THIS PRODUCT IS RELATIVELY WON-TOXIC BY INGESTION. THIS PRODUCT HAS LAXATIVE PROPERTIES AND KAY RESULT IN ABDOMINAL CRAM'S AND QIAMDCA. SEE ICALTH DATA SECTION BELOW.; HEALTH DATA: ON RARE OCCASIONS, PftOLOWED AW REPEATED EXPOSURE TO OIL NIST POSES A RISK OF PULMONARY DISEASE SUQf AS QttONIC LUNG INFLAMMATION, THIS CONDITION IS USUALLY ASYMPTOMATIC A3 A RESULT OF REPEATED SMALL ASPIRATIONS. SHORTNESS OF BREATH AND COUGH ME THE HOST COMM SYMPTOMS- THE INTERNATIONAL ACEWV FOR RESEARCH ON CANCER HAS CWCLUDCD THERE ARE INADEQUATE DATA TO EVALUATE TIC CaRCIHOBENICTTV TO EXPERIMENTAL ANIMALS OF THIS CLASS OF PRODUCTS. THUS THIS PRODUCT BELVIBS TO IARC CLASSIFICATION GROUP 3. HOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO MMANS.* THIS PROOUCT 19 NOT CARCINOGENIC ACCORDING TO THE OSHA HAZARD COMMICATION 9TMDARD. OOOROUS AM) TOXIC PIKES INCLUDING HYDROGEN SULFIDE. AM) OXIDES OF SULFUR. NITROGEN, PHOSPHORUS. CAlCIlM. HAfiNEStIK, SODZtft. AND ZINC m FORM FROM DECOMPOSITION OF THIS PRODUCT IF TEMPERATURES EXCEED ZSSF. 4. EMERGENCY & FIRST AID PROCEDURES EVE CONTACTr IMMEDIATELY FLUSH EVES WITH LANGE AMOUNTS OF HATER AW CONTINUE FIU94IN6 tMTIL IRRITATION SlfiSlDES. IF MATERIAL IS HOT, TREAT FOR THERMAL BURNS AW TAKE VICTIM TO HOSPITAL IMEDIATELV. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. MASH CONTAMINATED AREA THOROUGHLY WITH SOAP AND NATEft. IF MATERIAL IS HOT, S(J9(BE INJURED AREA IN COLD WATER. IF VICTIM IS SEVERELY BISOCD. REMOVE TO A HOSPITAL IMMEDIATELY. INHALATION' THIS MATERIAL HAS A LOW VAPOR PRESSURE AW IS NOT EXPECTED TO PRESENT AN IMALATION EXPOSURE AT AMBIENT CONDITIOW. INGESTION. 00 NOT INDUCE VOMITUB. SEEK ICOICAL ATTENTION. |5. PERSONAL HEALTH PROTECTION INFORMATION EYE PROTECTIONr EVE PROTECTION K NOT REQUIRED tHDER CONDITIONS OF NORMAL UB. IF MATERIAL IS HAWLED SUM THAT FT COULD BE SPLASHED INTO EVES, WAR PLASTIC FACE SHIELD OR SPLASi-PROOF SAFETY G0GDLE9. SKIN PROTECTION' W SKIN PROTECTION IS REQUIRED FOR SINGLE. SHORT DURATION EXPOSUCS. FOR PROLONGED OR REPEATED EXPOSURES, U5E IMPERVIOUS CLOTHING (BOOTS, GLOVES, APROS. ETC.) OVER PARTS OF THE BODY SUBJECT TO EXPOSURE. IF HAWllNO HOT MATERIAL, USE IWULATED PROTECTIVE CLOTHING (BOOTS. 0L0VE9. ATRONS, ETC.). LAUNDER SOILED CLOTIC3. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES Dtti UDINE SHOES, MUCH CAWOT BE DECONTAMINATED. A 04lfi8R CONFTDFNTTAl CB'd VC9 Qi AteJ MSfi'M iI-92-0B ti'd s&zn es:ia |70-0`86T XS69 S frBS 'onb sibtaaxaw moq: woaa PTOM :DEXCO VECTOR SBC S04 363 esse 1997.B9-B2 14:12 11013 P.03/K cooti 0OCOC2 NAWi HCBHA - SOLVE PMC >3 RESPIRATORY PROTECTION! ' LftDCft orRESPIRATORY PROTECTION IS NOT REQUIRED CONDITIONS NORMAL USE. IF VAPOR OR MIST 19 GENERATE!) WEN THE MATERIAL IS WATEO OR HANOLEO, USE Ml ORGANIC VAPOR RESPIRATOR WITH A DUST AND NIST FILTER. ALL RESPIRATORS MlST BE NZQOt CERTIFIED. M ROT USE CftFRESSED OXYGEN IN HVDROCARM ATMOSPHERES. VENTILATION; IF VAPOR OR MIST 19 GENERATED WEN THE MATERIAL IS ICATED OR HANDLED. ADEQUATE VENTILATION IN ACCORDANCE WITH 6000 ENGINEERING PRACTICE MUST BE PROVIDED TO MAINTAIN CONCENTRATION BELOW THE SPECIFIED EXPOSURE OR FLANHABLE LIMITS. OTHER. CONSUMPTION OF FOOD AND BEVERAGE SHOULD BE AVOIDED IN WORN AREAS WERE HYDROCARBONS ARE PRESENT. ALWAYS NASH HANDS AW FACE NITH SOAP AW WATER BEFORE EATIN6. DRINKlie, OR 9UXINE.____; _________________ 6. FIRE PROTECTION INFORMATION PLASH POINT: 40C F TEST JETHOO; C.O.C, AUTOIGNITION TEMPERATURE! NO DATA TEST NETHOOi NO DATA FlAWABLE UNITS IN AIR X BY VDIIKF LOVER: NO DATA UPPER: NO DATA EXTINGUISHING ffiDIAi SPECIAL FIRE FIGHTING PROCEDURES: USE DRY DfMICAL. FQAH, OR CARSON DIOXIDE. WATER MAY BE INEFFECTIVE BUT CAN BE USED TO COOL CONTAINERS EXPOSED TO WAT OR FLAW. CAUTION SHOULD BE EXERCISED WHEN USING WATER OR FOAM AS FROTHING NAY OCCUR. ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT, BURNING LIQUID. IABJ8UAL FIRE DENSE SMOKE MAY BE DEAERATED WILE BURNINfi. CARBON MONOXIDE. CARBON AND EXPLOSIVE DIOXIDE. AMD OTHER OXIDES HAY BE GENERATED AS PRODUCTS OF COMUSTIDN. CONDI HONS i r~ 7. REACTIVITY DATA STABILITY (11CMAL, LIGHT. TC.|i STABLE CONDITIONS TO AVOID; IDE HAZARDOUS POLYMERIZATION; MILL NOT OCOti CONDITIONS TO AVOID-. NONE INCOMPATIBILITY MATERIALS TO AVOID: MAY REACT WITH STRONG OXIDIZING AGENTS. HAZARDOUS DECOWOStTim PRODUCTS; NONE MM MS9CSE ax*d seen 8S:<ua I01 fo-co-8&6T Lim WUBBiBt IEBXSZ-B9 ON3 snaiaaiaw noa: woad FROM : ECXCO UGCTOR SBC laarr.BB-ae iti3 rai? p.Bxae CODE: 0DS8M NAME: TTCJ91A - SOLVE PACE M 8. ENVIRONMENTAL PRECAUTIONS STEPS TO BE TAKEN IF MATERIAL IS RELEASEO OR SPILLEDi C0N9ULT ICALTH EFFECT UFORHATION IN SECTION III. mSOHAL HEALTH PROTECTION UFODMUM IN SECTION V. FIRE PROTECTION IRFORNATION IN SECTION VI, AID REACTIVITY DATA IN SECTION VII. NOTIFY APPROPRIATE AUTHORITIES OF SPILL. CONTAIN SFILt MOCDIATELY. DO NOT ALLOW SPILL TO ENTER SEWRS OR WATERCOURSES. REMOVE ALL; SOURCES OF IGNITION. ABSORB WITH APPROPRIATE INERT MATERIAL SUCH AS SAW, CLAY, ETC. LARGE SPILLS MAY BE PICKED UP USING VACUUM PlfH, SHOVELS. BUCKETS. OR OTHER MANS AND PLACED IN DRUB OR OHO SUITABLE CONTAINERS. WASTE DISPOSAL NEIHOOi ALL DISPOSALS MUST COMPLY WITH FEDERAL, STATE, AID LOCAL REGULATIONS. T* MATERIAL, IF BPILlEO OR DISCARDED. HAY BE A REEULATED HASTE. KFER TO STATE AND LOCAL REGULATIONS. CAUTliM! IF RE8ULATED SOLVENTS ARE USED TO CLEM UP STILLED MATERIAL, THE RESULT0(6;WASTE HlXTllRE MAT BE REGULATED. DEPARTMENT OF TRANSPORTATION (DOT) REGULATION NAY APPLY FOR TRANSPORTING THIS MATERIAL WEN SPILLEO. WASTE MATERIAL NAY BE LAWFUlED OR INCINERATED AT M APPROVED FACILITY. MATERIALS WOULD BE RECYCLED IF POSSIBLE. 9. MISCELLANEOUS HAWLINB AND STORAGE REQUIREMENTS: ADDITIONAL ILFOBLATION: DO NOT TRANSFER TO UMARXED CONTAINERS. STORE IN CLOZD CONTAINERS AMAY FROM ICAT. SPARKS, OPEN FLAME, OR OXIDIZING MATERIALS. THIS PRODUCT IS NOT CLASSIFIED A5 HAZARDOUS UfflCR DOT REGULATIONS. FIRE EXTINGUISHERS SHOULD BE KEPT READILY AVARARLE. SEE NfPA 30 AID OSHA 191O.1O6--FLAWM0LE AW COMBUSTIBLE LIQUIDS. THIS MIXTURE MAY BE FORMULATED IN PART WITH CMTONENTS PURCHASED FROM OTHER COtR9AMIES. IN MANY HBTANCES. ESPECIALLY WEN PROPRIETARY OR TRADE SECRET MATERIALS ARE USED, PBMZOIL COMPANY MJST RELY UPON HC HAZARD EVALUATION OF SUCH CAffiNENTS SUBMITTED TO PEWZOIL BY THAT PROOUCT`9 MWUFACHJRER OR IMPORTER. 1H19 PRODUCT CONTAUB THE FOLLOWING SARA TITLE III. SECTION 313 octrois: ZINC COMPOIMDS, c 20.OX ALL INGREDIENTS OF THIS PRODUCT ME LISTED ON THE TOXIC 8UBSTMCE3 CONTROL ACT (1SCA) INVENTORY. SBd et -d sezt* wsacsc B5:^0 01 tra-rO'BGBI 1369 ESC W3S DO A 041890 OONFTDFNTTAI unm US.'Bi ,SiT-9E-B0 ON3 S*Wla3X3W nOQ: WOdd PROM >ECXCO VKCTTQR SBC m 3B3 GB36 !9a7;o9-ez 1<13 >013 P.IB6/0S CODE: 0O6062 MMEt THERMO - SOLVE 10. PHYSICAL PROPERTIES BOIL IMS POINT: MO DOTS percent volatile: mo data MELTING POINT: 4 IS F (PC* POINT) VAPOR OENSXTV (A1R=1): MO DATA APPEARANCE: CLEAR RRIWT LIQUID EVAPORATION RATE <EE*1). mo DATA TYPICAL FETR0LE1M ODOR SPECIFIC SUAVITY; .1711 VAPOR PRESSURE: M DATA MOLECULAR NEISHTi MO DATA SOLUBILITY: EMUL9IFICS SLlSmv WITH MATER DISCLAIMER OF MARRANTY- THE INFORMATION CONTAINED HEREIN IS BASED UPON DATA AVAILABLE TO IS, AND REFLECTS OUR BEST PROFESSIONAL JID6EHEWT, HOWEVER. NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE. OR ANY OTHER WARRANTY IS EXPRESSED OR IMPLIED RE6AABUS THE ACCURACY OF 9UD1 DATA, THE RESULTS TO BE OBTAINED FNON THE USE THEREOF. OR THAT ANY SUCH USE OQES NOT INFRINGE ANY PATENT. SINGE THE DffORKATIOW CONTAINED HEREIN NAY DC APPLIED IMDER CONDITIONS OF USE BEYOND OUR CONTROL AND WITH MICH WE HAY DC UNFAMILIAR, WE DD NOT AS5UE ANY RESPWSIBILITY FOR TTC RESULTS OF 3U APPLICATION. THIS IliFOfOMTlON IS FURNISHED UPON TVC CONDITION THAT THE PERSON RECEIVIN6 IT SiALL HARE NI3 OMi DETERMINATION OF T> SUITABILITY OF THE MATERIAL FOR HIS PARTICULAR PIAP09E. 90`d M'd seen WSSESE es-.^e DJ. t.0-0'866X T3S3 S W2S 00 A 041R91 conftofnttai ON3 STtJlaaXBW nOQ: WOfclJ TEXACO INC. INDUSTRIAL HYGIENE, TOXICOLOGY, AND MATERIAL [TEXACO]SAFETY DATA SHEET NOTE; NO REPRESENTATION IS MADE AS TO THE ACCURACY OF THE INFORMATION HEREIN. SEE PACE 5 FOR CONDITIONS UNDER WHICH DATA ARE FURNISHED. .wade Name and Synonyms 01515 TRANSFORMER OIL INHIBITED* Manufacturer's Name Texaco Inc Address P.0. Box 509 Beacon. NY 12508 Chemical Name and/or Family or Description Transformer Oil THIS PRODUCT IS CLASSIFIED AS: HAZARDOUS BY DEFINITION NO.(SI WARNING STATEMENT: NONE CONSIDERED NECESSARY. Emergency Telephone No. (914) 831-3400 ext. 406________________________ X NOT HAZARDOUS: ON ATTACHED EXPLANATION SHEET 4 OCCUPATIONAL CONTROL PROCEDURES Protective Equipment (Type) Eyes: Chemical type goggles or face shield optional. Skin; Exposed employes should exercise reasonable personal cleanliness; this includes cleansing exposed skin areas several times daily with soap and water, and laundering or dry cleaning soiled work clothing at least weekly. inhalation. None required if exposures are within permissible concentrations; see below. Ventilation Required Normal Permissible Concentrations. 5 mg/cubic meter of air for mineral oil mist averaged over an 8 hour daily exposure (ACGIH, 1982). EMERGENCY AND FIRST AID PROCEDURES First Aid Eyes As with most foreign materials should eye contact occur, flush eyes with plenty of water. Skin None considered necessary. Ingestion None considered necessary. Inhalation ' Ol 1 ln\li tn.lionS None considered necessary. IN'ne. Mil f J l . 1 ( ) (_' l L' 1 Mill .'(1 N A 1 il.l A | 11 >111 rliilf l , ........ (im ,n m 111 .ii i I 00 A O 4 7 cj q cqnf Tn FNTrA; PHYSIOLOGICAL EFFECTS: Effects of Exposure Acute: Eves: N.D.Believed to be minimally irritating. Skin- N.D. Believed to be minimally irritating. Cod** No. 03-5-liL Respiratory System: N.D. Believed to be minimally irritating if not in excess of per missible concentrations; see page 1. Chronic: N.D. Other; Sensitization Properties: Skin: Yes ____ No ___ Unknown X Respiratory: Yes ____ No____ Unknown X Median Lethal Dose (LD SOlC soMSpeciesI Oral Inhalation N.D,; be1ieved N.D. Dermal N.D,; belleved Other N. D. to be to be S.T, G.T. 5 g/kg (.rat); practically non-toxic 10 g/kg (.rabbit); practically non-toxic Irritation Index. Estimation of Irritation (Speciesl Skin N.D.; believed to be L.T. 0.5/8.0 (rabbit); no appreciable effect Eves N.D.; believed to be L.T. 15/110 (rabbit>; no appreciable effect Symptoms of Exposure N.D.; Hone expected other than possible minimal irritation FIRE PROTECTION INFORMATION lijmtmn Temp FN.D,__________________ Flash Point F (Method)295 F t COC ) Flammable limits0;, Lower N.D. Upper H. D. Pfuduiti, Evolved When Subjected to MeM or Combustion , Carbon monoxide, carbon dioxide, aldehydes and ketones, combus tion products of nitrogen and sulfur. Recommended Fire Extinguishing Agents And Special Procedures. According to the National Fire Protection Association Guide, use water spray, dry chemical, "alcohol" foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray ; to disperse ine vapors and r,. provide protection for persons at i eni| t i nu i i. '( the 1,-uk . Wntihu.tl in t |)l*)->iut NtMi-r . ii I I. i .I.i l OO A 041893 CONFIDENT IA1 ENVIRONMENTAL PROTECTION Code ^____ 01515 Waste Disposal Method: Under RCRA, it is the responsibility of the user of products to determine, at the time of disposal, whether product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render the result ing material hazardous.(See Remarks for Waste Classification) Procedures in Case of Breakage or Leakage: Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Remarks: Waste Classification: Product has been evaluated for RCRA charac teristics and does not meet criteria .of a hazardous waste if discarded in' its purchased form. PRECAUTIONARY LABEL NONE CONSIDERED NECESSARY. Requirements lor Transportation Handling and Storage. Minimum feasible handling temperatures should be maintained. Periods of exposure to high temperatures should be minimized. Water" contamination should be avoided. DOT Proper Shipping Name DOT Hazard Class (il applicable) M.A. N.A. CHEMICAL AND PHYSICAL PROPERTIES Bulling Point (F| M . 0____ Vapor pressure N -D-_____ (mmHyl Specilic Gravity - B R 9________ ____ (H..0=1| Vapor Density N.D.______ (Air=l) Appearance and Odor___ clear ~nd bright pH uf undiluted product N.A. Solubility ll^D.^ Percent Volatile by Volume . D.. .. Evaporation U . b . 1=1 Vi'., t.-.ity . w.U cL_!i.lU _C __ Other 00 A 0A1B9A CONFIOFNTTAI MtUitMlmiS Polyim'inations _ Occur A.. Do not otcuf ll.: IvLitcriril Rot!!, Vinlenil; WmIi (Il OiIkmi i. . below sec A.Idiliumil Comments m* F'.tyc 4 lor ImiMur dti.nK) Am yViihm Hctil Sunny 0*idi/ci .< (Min is IJomu il Ihcsu > Mli IJ >t IM fi l li ... iM I J A ................... i It t A111 l' - ti .. ' COMPOSITION Components Presenting a Significant Hazard None Other Components Mineral oil Ditertiarybutylphenol Code No- 01515 % Greater than 95 Less than 1 ADDITIONAL COMMENTS TEXACO INTENDS TO COMPLY FULLY WITH PROVISIONS OF THE TOXIC SUBSTANCES CONTROL ACT STATE OF MICHIGAN CRITICAL MATERIALS ACT (REVISED T9B2) No t.i nn.nl materials pii'seut I In mill......... ,1| n J11 >. <. IJ n 11V in ulltn i ol any law or lo.inlaimn with iesinn.1 in tins proilui.t uiei Simula consult Ins . irijal ain i in iif the a|.|iui|iriaie tjovL'riiineni nijcn, y Tesa.ti tines nut uniloitate to turniili ,nlvu t: on soi.l) mailcis II,' Kit 11 11 - In i,n,1 M'J1 . Kir.'. iT li.:," 1 .'.it 1 mi t. T. .si. -I DO A 041 B9S iwi I 11 o ii....' II it............ C.ONFTDFNTTAl !l r> ' Ml*1' Section 1 Imergtnoy Number (217)496-3790 \ Product Name andlnforrrwrtJqn ~ 0 Produet(Tradt Name and Synonyms): UL4 Series Chemical Name: Polyilphaoitfln Chemical Family: Synthetic Hydrocarbon Formula' CAS* Proprietary Section 2 Components and Hazard Statement This product ta non-hasardoue. The product contains no known ceroinoQeng, No peels] warning labels am required under OSHA 29 CFR 1810.1200. Section 3 Safe Handling and Storage Handling. Do not take internally. Avoid contact with akin, eyes, end clothing. Upon contact wfthekln, wash wttheoap and water, Flush eyes with water (or 15 minutes and consult phyilotan. Wash contaminated clothing before reuse. \' \ < Storage. Keep container tightly sealed when not in use. poeMr brand fax transmittal memo 7671 * of Mew* * stt"------ :-------------- CO. Phtr* ""* ***- >!>- Pax* Pile S~ WlWW.i i - --------- ----- DO A 041896 4 CONFTDFNTTAl W & ' p * C . *" ` 1 ' J~0+ , Iy.34 OulLnin wr\r^ * * * rF ;* 2/ Section 4 Physlot! Data Appaaranca: Claer liquid, yallow to light brown tint Boiling Polnt:>300*F Vapor Prs6uni:<0i6immHg Q 20*C 8pacific Gravlty(watar*1);0,8O-0.85 VolatiiM, Pereant by Volume: 0% Odor, Non* Solubility in Wat*r. tneelubla. Evaporation Rat^butyl acatataM); Nil Station 5 Flrt and Explosion Hazard* Fttssft Point (by Cleveland Optn Cup): 310-350*P Flammable Limit#: not established Autoignitlon Tfempesrsture: no data HMIS Rating* Health: 0 Flammability: 1 Reactivity: 0 NFPA Ratinga: not established Extinguishing Medio; Dry chamicd; COx foam; water apray(fog) Unusual Flrt and Explosion Huardat Nona Sptoial Flrt Flgmino Techniques: Burning fluid may evolve IrritatinQ/noxlou* fumaa, Firefighters should use NIOSH/MNSA-appreved aeff-eontalned braathing apparatua. Uaa watar to oooi fire-exposed oontalnarc. Use water carefully near exposed liquid to avoid frothing and aplaahlng of hot liquid. P*0*2 00 A D4lft97 CQfsip idfnttal **>** , ** > t * *"*w-** I W. 03 SULLAIR C0RP* - , *. Sections Reactivity Date i Stability: Stable Hazardous Polymerization; Will not occur Incompatible Materials: Stong oxidizers Conditions to Avoid: Exowiivs hast Hazardous Decomposition Products: Analogous compounds evolve oerbon monoxide, carbon dioxide, and other unldantifiad fragments whan burned, 6m Section 6.' Section 7 Health Hazard Data Threshold Limit Vtelue: Bmgftn* AC31H Situations to Avoid: Avoid breathing olf mists Flivt Aid Procedures: Ingestion: Consult physician at once. DO NOT INDUCE VOMITING. May oauae nausea and diarrhea, Inhalation: Product is not toxic by inhalation. If oil mist is inhaled, remove to fresh air and consult physician, To the beat of our knowledge ths toxlelty of thle product haa not been hilly tnveetiflited. Analogous oompounda art oonaldemd to be aaaentlaUy notvtoxio. SectionsPareonal Protection mfomwtion Respiratory Protection: Usa in well ventilated tree Ventilation: LoosI exhaust Protective Gloves: Not required, but recommended, especially for prolonged exposure. Eye/Face Protection: Goggles Poe3 DO A 04 1 ft A 8 C.ONF TDFNTT Ai  oc..< i u ACftv/A 'iecopier <ur/i 4-xo-w i iu; so t.' -> ' ? SULLAIR"CORP-*`r '' t itt */ 5 Section 0SfHilor Leak Procedurae In Cm of Spill: Wear nuitabl# protective equipment, especially goggles. Stop source of epilt. Dike spill area. Use absorbent materials to oak up fluldfl.e, send, sawdust, and commercially available materials). Wash pi!t area with largo amounts of watar. Preparly dispose of all materials. SedionlO ** Waste Disposal Methods ". t * *, incinerate this product and all aaaodatad wattes In a licensed fadltty In accordance with federal, stata, and local ragulatloni. The Information in this material safety data aheat should,be provided to ell who use, handle, store, transport, or an otherwise exposed to this product. CP) believes the Information In this document to be reliably end up to date si of the date of publication, but makes no guarantee' Prepared by. Thomas E. R^ewekl,Product Meneger 9.B4 * no A 041899 aonftdfntta L-4638 t MATERIAL SAFETY DATA SHEET Sept mber 19 An explanation ot Ota larma used heroin may be found In OSHA 39 CFR 1910.1300, available from OSHA regional or area office* (E**ntlally similar to U.S. Department ot Labor Form SHA-20 and generally accepted In Canada tor Information purpoaaa) Do Not Duplicate This Form. Request an Original. PRODUCT Oxygen CHEMICAL NAME FORMULA Oxygen Oj SYNONYMS CHEMICAL FAMILY MOLECULAR WEIGHT Not applicable Not applicable 32.00 TRADE NAME Oxygen ^;#^i^^^'^^I^AZATODUS:INGHEDIHNTSV^^-. For mixtures of this product request the respective component Material Safety Data Sheets. See Section IX. MATERIAL (CAS NO.) Oxygen (7782-44-7) Wt (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) 100 None currently established (None currently establish BOILING POINT, 760 mm. Hg -183C (-297.4 F) FREEZING POINT SPECIFIC GRAVITY (HaO = 1) Gas VAPOR PRESSURE AT 20 C. VAPOR DENSITY (air - 1) 1.105 @25C SOLUBILITY IN WATER, % by wt. PERCENT VOLATILES BY VOLUME 100 EVAPORATION RATE (Butyl Acetate - 1) APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and pressure. -218.4C (-361.1 F) Gas N gligible Not applicable IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 1-800-UCC-HELP (1-800-822-4357) In Canada 514 -- 640-6400 For routine information contact your local supplier Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of produc hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractor of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of it customers for the product, and (3) request such customers to notify their employees and customers for th pr duct of the same produc hazards and safety information. UNION CARBIDE CORPORATION LINDE DIVISION UNION CARBIDE CANADA LIMITED LINDE DIVISION D0 A 04 OONFTDFNT TAl Copyright 1985 Union Carbide Corporation r-age 1 o' L-4638-A PRODUCT: Oxygen -HEALTH HAZARDBATA THRESHOLD LIMIT VALUE: None currently established. L-4638-A September 1985 EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING -- No evidence of adverse effects from available information. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- Breathing 80% or more oxygen at atmospheric pressure for more than a few hours may cause nasal stuffiness, cough, sore throat, chest pain and breathing difficulty. Breathing oxygen at higher pressure increases the likelihood of adverse effects within a shorter time period. Breathing pure oxygen under pressure may cause lung damage and also central nervous system effects resulting in dizziness, poor coordination, tingling sensation, visual and hearing disturbances, muscular twitching, unconsciousness and convulsions. Breathing oxygen under pressure may cause prolongation of adaptation to darkness and reduced peripheral vision. SKIN CONTACT -- No evidence of adverse effects from available information. EYE CONTACT -- No evidence of adverse effects from available information. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE; See "Notes to Physician." MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: See "Notes to Physician." SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None currently known. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING -- This product is a gas at normal temperature and pressure. SKIN -- No emergency care anticipated. INHALATION -- Remove to fresh air. Give artificial respiration if not breathing. Keep victim warm and at rest. Call a physician. EYES -- No emergency care anticipated. NOTES TO PHYSICIAN: Supportive treatmentshould include immediate sedation, anti-convulsive therapy ifneeded, and rest. Animal studies suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, increases the susceptibility to toxicity from oxygen at high concentrations or pressures. Animal studies also indicate that vitamin E deficiency may increase susceptibility to oxygen toxicity. Airway obstruction during high oxygen tension may cause alveolar collapse following absorption of the oxygen. Similarly, occlusion of the eustachian tubes may cause retraction of the eardrum and obstruction of the paranasal sinuses may produce "vacuum-type" headache. Newborn premature infants exposed to high oxygen concentrations may suffer delayed retinal damage which can progress to retinal detachment and blindness (retrolental fibroplasia). Retinal damage can also occur in adults exposed to 100% oxygen under greater than atmospheric pressure, particularly in individuals whose retinal circulation has been previously compromised. All individuals exposed for long periods to oxygen at high pressure and all who exhibit overt oxygen toxicity should have ophthalmologic examinations. WHEN USED IN WELDING AND CUTTING; Read and understand the manufacturer's instructions and the precautionary label on the product. See American Standard Z49.1 "Safety In Welding and Cutting" published by the American Welding Society, P.O. Box 351040, Miami, Florida 33135 and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more detail. For further SAFETY AND HEALTH information, refer to Unde's tree publication, L-52-529, "Precautions and Safe Practic s for Electric Welding and Cutting", as well as L-2035, "Precautions and Safe Practices for Gas Welding, Cutting, and Heating." You may obtain copies from your local supplier, or by writing to Union Carbide Corporation, Unde Division, Communications Department, 39 Old Ridgebury Road, Danbury, Connecticut, 06817-0001. NOTE: Suitability for use as a component in underwater breathing gas mixtures is to be determined by or under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the effects, methodr and duration of use, hazards, side effects and precautions to be taken. r>r A 04 ] an 1 -------------------------------------------------------------------- =------------------------------------------------------------------------------------------- ^NFTDFNTTZI Page 2 of 4 PRODUCT: Oxygen L-4638September 1985 W.TIREiAND.'EXPLIOSlON HAZARDDATA FLASH POINT (feet method) Not applicable AUTOIGNITION TEMPERATURE Not applicable FLAMMABLE UMITS LOWER IN AIR, % by volume Not applicable UPPER Not applicable EXTINGUISHING MEDIA: Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (i.e. safety shower) is the preferred extinguishing media for clothing fires. ' SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately cool containers with water spray from maximum distance until cool, then move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Oxidizing agent, vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion. Container may rupture due to heat of fire. No part of a container should be subjected to a temperature higher than 52 C (approximately 125 F). Most containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. Smoking, flames and electric sparks in the presence of enriched oxygen atmospheres are potential explosion hazards. .REACTIVUYJ5ATA STABILITY UNSTABLE STABLE X CONDITIONS TO AVOID: See Section IX. INCOMPATIBILITY (materials to avoid): Combustible materials, asphalt, flammable materials, especially oils and greases. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION May Occur Will not Occur X CONDITIONS TO AVOID: None currently known. v^VII.^SPIUUDRXEAK-PROnEDJURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Shut off leak if without risk. Ventilate area of I ak or move leaking container to well-ventilated area. Remove all flammable materials from vicinity. Oxygen must never be permitted to strike an oily surface, greasy clothes, or other combustible material. WASTE DISPOSAL METHOD: Slowly release into atmosphere, in an open, outdoors area. Remove all flammable materials from vicinity. Oq ('Qhjpr 04 7 90$ Nj M/ ft 3of 4 PRODUCT: Oxygen L-4638-A September 1985 RESPIRATORY PROTECTION (specify type): Not required. LOCAL EXHAUST -- Not applicable. VENTILATION MECHANICAL (general) -- Acceptable. SPECIAL -- Not applicable. OTHER -- Not applicable. PROTECTIVE GLOVES: Preferred for cylinder handling. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR 1910.132 and 1910.133. .31X'SRECIALiPHECAlTTIDNS WARNING: High pressure gas. Vigorously accelerates combustion. Avoid contact with oils, greases and other flammable materials. Never use manifolds for oxygen cylinders unless specifically designed for such use. Use only with equipment conditioned for oxygen service. Use piping and equipment adequately designed to withstand pressures to be encountered. Protect container against physical damage. Isolate from combustible gas installations and combustible materials by adequate distance or by gas-tight, fire-resistive barriers. Protect against over-heating. Never use an oxygen jet for cleaning purposes of any sort, especially clothing, as it increases the likelihood of an engulfing fire. Note: Reverse flow into cylinder may cause rupture. Use a check valve or other protective apparatus in any line or piping from the cylinder to prevent reverse flow. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. Be sure to read and understand all labels and other instructions supplied with all containers of this product. NOTE: Compatibility with plastics should be confirmed prior to use. For safety information on general handling of compressed gas cylinders, obtain a copy ofpamphlet P-1, ` 'Safe Handling of Compressed Gases in Containers" from the Compressed Gas Association, Inc., 1235 Jefferson Davis Highway, Arlington, VA 22202. OTHER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then repair the leak. Never lubricate oxygen valves, regulators, etc., with any combustible substance. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. ______ ________________________________________________________________________ ____________ m UNION CARBIDE GENERAL OFFICES IN THE USA: Union Carbide Corporation Linde Division 39 Old Ridgebury Road Danbury, CT 06817-0001 IN CANADA: Union Carbide Canada Limited Linde Division 123 Eglinton Avenue East Toronto, Ontario M4P 1J3 L-4638-A 85-0928 9/85 45M Page 4 of 4 Other offices in principal cities all the world. DO A 04 1 900 Lithe, oonftdfntiai