Document gzxgQ2aEyJnqQ4VDv4ZG3r69
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Date Printed: 08-15-1996 Page 1 J.T.BAKER MSDS MSDS for METHANOL
1 -PRODUCT IDENTIFICATION
PRODUCT NAME: COMMON SYNONYMS:
CHEMICAL FAMILY: FORMULA: FORMULA WT.: CAS NO.: NIOSH/RTECS NO. : PRODUCT USE: PRODUCT CODES:
METHANOL METHYL ALCOHOL; WOOD ALCOHOL; CARBINOL; METHYLOL; WOOD
SPIRIT ALCOHOLS
CH30H 32.04
67-56-1 PC1400000 LABORATORY REAGENT 9074,9090,5536,9076,9049,9069,9070,9073,5217,9091,9075,9063
P704,9072,9071,9127,5370,9093,9068,9263
CHEMTREC # (800) 424-9300 LA-MAR-KA, INC.
10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814
EFFECTIVE: 05/01/89 REVISION #06
ISSUED: 04/14/90
KER SAF-T-DATA*
PRECAUTIONARY LABELING
SYSTEM
HEALTH
3 SEVERE
FLAMMABILITY - 3 SEVERE
REACTIVITY
1 SLIGHT
CONTACT
1 SLIGHT
(POISON) (FLAMMABLE)
LABORATORY PROTECTIVE EQUIPMENT
GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
U.S. PRECAUTIONARY LABELING
POISON DANGER
FLAMMABLE. HARMFUL IF INHALED. CANNOT BE MADE NON-POISONOUS. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE. FLUSH SPILL
AREA WITH WATER SPRAY.
PRECAUTIONARY LABELING (CONTINUED)
INTERNATIONAL LABELING
DO A 06,0759 CQNFIDFNTTAl
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J.T.BAKER MSDS MSDS for METHANOL
1 -PRODUCT IDENTIFICATION (continued)
HIGHLY FLAMMABLE. TOXIC BY INHALATION AND IF SWALLOWED. KEEP OUT OF REACH OF CHILDREN. KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. AVOID CONTACT WITH SKIN.
SAF-T-DATA* STORAGE COLOR CODE: RED (FLAMMABLE)
2 -COMPONENTS
COMPONENT METHANOL
CAS NO. 67-56-1
WEIGHT % 90-100
OSHA/PEL ACGIH/TLV 200 PPM 200 PPM
3 -PHYSICAL DATA
BOILING POINT: 65 C (149 F) (AT 760 MM HG)
MELTING POINT: -98 C (-144 F) (AT 760 MM HG)
_.ECIFIC GRAVITY: 0.79 (H20=l)
VAPOR PRESSURE (MMHG): 96 (20 C)
VAPOR DENSITY (AIR=1): 1.11
EVAPORATION RATE: 4.6 (BUTYL ACETATE = 1)
SOLUBILITY(H20): COMPLETE (100%)
% VOLATILES BY VOLUME: 100 (21 C)
PH: N/A
ODOR THRESHOLD (P.P.M.): N/A COEFFICIENT WATER/OIL DISTRIBUTION: N/A
PHYSICAL STATE: LIQUID
-
APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID. PUNGENT ODOR.
4 -FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (CLOSED CUP): 12 C (54 F)
NFPA 704M RATING: 1-3-0
AUTOIGNITION TEMPERATURE: 463 C (867 F)
FLAMMABLE LIMITS: UPPER - 36.0 %
LOWER - 6.0 %
FIRE EXTINGUISHING MEDIA USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE
INEFFECTIVE.)
A 060760 confidential
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J.T.BAKER MSDS
MSDS for METHANOL
4 -FIRE AND EXPLOSION HAZARD DATA (continued)
SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
UNUSUAL FIRE & EXPLOSION HAZARDS VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. BURNS WITH A CLEAR, ALMOST INVISIBLE FLAME.
TOXIC GASES PRODUCED CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE
EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED.
EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED.
-HEALTH HAZARD DATA
.THRESHOLD LIMIT VALUE (TLV/TWA): 260 MG/M3
(200 PPM)
THE TLV LISTED DENOTES TLV (SKIN).
SHORT-TERM EXPOSURE LIMIT (STEL): 310 MG/M3
(250 PPM)
PERMISSIBLE EXPOSURE LIMIT (PEL): 260 MG/M3
(200 PPM)
TOXICITY OF COMPONENTS
ORAL RAT LD50 FOR METHANOL
INTRAPERITONEAL RAT LD50 FOR METHANOL
SUBCUTANEOUS MOUSE LD50 FOR METHANOL
SKIN RABBIT LD50 FOR METHANOL
CARCINOGENICITY: NTP: NO
IARC: NO
Z LIST: NO
OSHA REG:
5628 9540 9800 20 NO
MG/KG MG/KG MG/KG G/KG
CARCINOGENICITY NONE IDENTIFIED.
REPRODUCTIVE EFFECTS NONE IDENTIFIED.
EFFECTS OF OVEREXPOSURE
DO A 060761 CONFIDENTIAL
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5 -HEALTH HAZARD DATA (continued)
INHALATION:
IS HARMFUL AND MAY BE FATAL, HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS, RESPIRATORY FAILURE, LOW BLOOD PRESSURE, CENTRAL NERVOUS SYSTEM DEPRESSION
SKIN CONTACT:
IRRITATION, PROLONGED CONTACT MAY CAUSE DERMATITIS
EYE CONTACT:
IRRITATION, MAY CAUSE TEMPORARY CORNEAL DAMAGE
SKIN ABSORPTION: NONE IDENTIFIED
INGESTION:
IS HARMFUL AND MAY BE FATAL, BLINDNESS, HEADACHE, NAUSEA, VOMITING, DIZZINESS, GASTROINTESTINAL IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION, HEARING LOSS
CHRONIC EFFECTS: KIDNEY DAMAGE, LIVER DAMAGE
TARGET ORGANS EYES, SKIN, CENTRAL NERVOUS SYSTEM, GI TRACT, RESPIRATORY SYSTEM, LUNGS
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE EYE DISORDERS, SKIN DISORDERS, LIVER OR KIDNEY DISORDERS
.IMARY ROUTES OF ENTRY INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT, ABSORPTION
EMERGENCY AND FIRST AID PROCEDURES
INGESTION:
CALL A PHYSICIAN. IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INDUCE VOMITING.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
SKIN CONTACT : IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE.
EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
SARA/TITLE III HAZARD CATEGORIES AND LISTS
ACUTE: YES CHRONIC: YES FLAMMABILITY: YES PRESSURE: NO REACTIVITY: NO
EXTREMELY HAZARDOUS SUBSTANCE: NO
CERCLA HAZARDOUS SUBSTANCE:
YES CONTAINS METHANOL (RQ = 5000 LBS)
DO A 06076? CONFIDENTIAL
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J.T.BAKER MSDS
MSDS for METHANOL ----------------------------------------------------------------------------------------------------------------------------------------------------------------+
5 -HEALTH HAZARD DATA (continued)
SARA 313 TOXIC CHEMICALS: GENERIC CLASS:
TSCA INVENTORY:
YES CONTAINS METHANOL C05
YES
6 -REACTIVITY DATA
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID:
HEAT, FLAME, OTHER SOURCES OF IGNITION
INCOMPATIBLES:
STRONG OXIDIZING AGENTS, STRONG ACIDS, ZINC, ALUMINUM, MAGNESIUM
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE
7 -SPILL Sc DISPOSAL PROCEDURES
"EPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP
WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER.
J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED FOR SPILLS OF THIS PRODUCT.
DISPOSAL PROCEDURE
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
EPA HAZARDOUS WASTE NUMBER:
U154 (TOXIC WASTE)
8 -INDUSTRIAL PROTECTIVE: EQUIPMENT
VENTILATION:
USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS.
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS ABOVE 200 PPM, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
DO DO NF
A
060763
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8 -INDUSTRIAL PROTECTIVE EQUIPMENT (continued)
EYE/SKIN PROTECTION:
SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED.
9 -STORAGE AND HANDLING PRECAUTIONS
SAF-T-DATA* STORAGE COLOR CODE: RED (FLAMMABLE)
STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED.
FLAMMABLE LIQUID STORAGE AREA.
STORE IN A COOL, DRY, WELL-VENTILATED,
SPECIAL PRECAUTIONS BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID.
10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION
IMESTIC (D.O.T.)
JPER SHIPPING NAME: METHYL ALCOHOL
HAZARD CLASS:
FLAMMABLE LIQUID
-UN/NA: UN1230
REPORTABLE QUANTITY: 5000 LBS.
LABELS: FLAMMABLE LIQUID
REGULATORY REFERENCES: 49CFR 172.101; 173.119
INTERNATIONAL (I.M.O.)
PROPER SHIPPING NAME: METHANOL
HAZARD CLASS:
3.2
UN: UN1230
MARINE POLLUTANTS: NO
LABELS: FLAMMABLE LIQUID, POISON
REGULATORY REFERENCES: 49CFR 172.102; PART 176;
I.M.O. PAGE: 3087 PACKAGING GROUP: 'II
IMO
AIR (I.C.A.O.)
PROPER SHIPPING NAME: METHANOL
HAZARD CLASS:
3.2
UN: UN1230
LABELS: FLAMMABLE LIQUID, POISON
REGULATORY REFERENCES: 49CFR 172.101;
173.6;
PACKAGING GROUP: PART 175; ICAO/IATA
II
U.S. CUSTOMS HARMONIZATION NUMBER: 29051100009
N/A = NOT APPLICABLE OR NOT AVAILABLE
DO A 060764 CONFIDENTIAL
j.T.BAKER MSDS MSDS for METHANOL .
Date Printed: 08-15-1996 Page 7
10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION (continued)
N/E = NOT ESTABLISHED
THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF
THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS
PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE
HAZARDOUS MATERIALS INFORMATION SYSTEM.
THIS DOCUMENT IS INTENDED ONLY AS A
GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON
TRAINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER
IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL
FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING
INCLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT
WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES.
EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS
CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO
VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF
USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS.
LA-MAR-KA
WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL.
LA-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO THE PRODUCT SUPPLIED HEREUNDER, ITS MERCHANTABILITY OR ITS FITNESS
")R A PARTICULAR PURPOSE.
,,-iE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN
DEATH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT
-HEEDED.
READ ALL PRECAUTIONARY INFORMATION.
AS NEW DOCUMENTED GENERAL
SAFETY INFORMATION BECOMES AVAILABLE, LA-MAR-KA WILL PERIODICALLY REVISE
THIS MATERIAL SAFETY DATA SHEET.
APPROVED BY LA-MAR-KA, INC.
DO A 060765 CONFIDENTIAL
