Document gb3My2Ommw33eJ2M7oqpZkJda
^jUIGLEY COMPANY, INC
tt K 42ND ST. NCW YORK. N. V. *0017
OSHA AND ASBESTOS
The following description is provided to acquaint users of asbestos based insulating materials with the latest OSHA Standards. OSHA has determined that contact with asbestos fiber is a serious health hazard. The standard states:
"in view of the undisputed grave conseqddnces from exposure to as bestos fibers, it is essential that the exposure be regulated now, on the basis of the best evidence available now, even though it may not be as good a6 scientifically desirable. An asbestos standard can be reevaluated in light of the results of ongoing studies, and future studies, but cannot wait for them. Lives of employees are at stake. " The above paragraph in essence sets the tone of the entire OSHA standard for asbestos. In fact, OSHA considers asbestos a serious enough material to have a separate section devoted to it. The particular section covering asbestos is 1910. 93 a under Air Borne Contaminants Section 1910. 93. The threshold limit valve (TLV) for asbestos on an 8-hour time weighted average is no more than 5 fibers, longer than 5 micometers, per cubic centimeter of air. To measure, if the TLV is exceeded, samples shall be collected within the breathing zone of the employees on a membrane filter of 0, 8 micrometer porosity mounted on an open-face filter holder. Determination of the asbestos level is made at a magnification of 400-450 with phase contrast illumination. We are not very far into the standard and already terms are being en countered which will create confusion as to what is being said. In essence, the standard is saying not to use asbestos based materials. If you decided to use asbestos based materials the possibility of exceeding the TLV is so probable that the appropriate precautions have to be taken. The precautions are as follows:
a) All hand operated and power operated tools which may release asbestos (cutting insulating block) shall be provided with local exhaust ventilation systems which will maintain the concentration below the TLV.
1 6091
b) Insofar as practicable, asbestos shall be handled, mixed, applied, removed, cut, scored, or otherwise worked in a wet state sufficient to prevent emmission of airborne particles,
c) No asbestos cement, mortar, coating, grout, plaster or similar materia: containing asbestos Bhall be removed from bags, cartons, or other containers without being either wetted or enclosed, or ventilated to prevent release of airborne asbestos fibers.
The three sections above although making compliance somewhat awkward, do not create a condition which is impossible to work. However, the next section in our opinion is the key feature of the standard and probably creates the greatest frustration to user6. The assumption is that whatever asbestos based insulation goes on must eventually come off and with that in mind the following section governs:
"Spraying, demolition or removal - Employees engaged in the sprayinr of asbestos, the removal, or demolition of pipes, structures or equipment covered or insulated with asbestos, and in the removal or demolition of as bestos insulation or coverings shall be provided with respiratory equipment in accordance with paragraph (d) (2) (iii) of this section and with special clothing in accordance with paragraph (d) (3) of this section".
What this section has done in effect has discarded the TLV of 5 fibers per cubic centimeter completely and has directed the user to use certain res piratory equipment and clothing.
In 6imple terms the respiratory equipment referred to is a supplied-air respirator either continous-flow or pressure demand type.
These types of respirators have an external source of air which the employee breathes. The external source is either from a pressure tank or via air hoses to the respirator. The special clothing includes coveralls, head covering, gloves and foot covering. The employer shall provide 2 separate locker: or containers for each employee to isolate the contaminated clothing. Launde ing of contaminated clothing shall be done to prevent the release of airborne asbestos fibers. If laundering is to be done by others the clothing shall be conveyed to the launderer in sealed impermeable containers and informed the clothing is contaminated with asbestos fibers.
In addition to the above, other items in the standard state:
a) Posting of caution signs in areas where asbestos is being used b) Waste disposal in sealed containers c) Exposure records on each employee d) Employees to have reasonable access to any record required to be
maintained e) Notice to employee in writing if he has been exposed to airborne concen
trations of asbestos in excess of the limits prescribed.
1 6092
The standard considers asbestos as a hazardous material and if a company is to use it, it has to comply with some very strict regulations. As noted, some of these regulations are so restrictive that it creates extreme difficulty as well as delays in completing projects.
A number of users have decided not to use asbestos based materials and have started using Quigley's non-asbestos "PANELEX" insulation. PANELEX has been specifically formulated without asbestos to meet OSHA standards.
PANELEX was introduced to the market in February of 1972 and has proven to be a high quality, easy to use insulation. It is available as a castable, trowel and spray mix, block and special shapes.
12/12/72
V
1 6093
TECHNICAL DATA
TYPICAL ANALYSIS DATA
PRODUCT:
PANELEX
DESCRIPTION:
NON-ASBESTOS INSULATION
RECOMMENDED SERVICE LIMIT: 2000F
PACKAGING:
50 lb. Bags or Precast Block Form 6"x24"x24" Max. Size 2"x 6"x24" Min. Size
MIXING WATER:
7 - 7i Gallon6/50 lbs. Material
CHEMICAL ANALYSIS:
S102 42 ~l8 %
AI2O3 13-20
Pe203 3-03
CaO 25-35
MgO 6.91
T102
0.45
Cr203 Na20 K20
MnO LOI
0.04 % 0.50 1.98 0.03 6.24
Total Chlorides - 10 ppm
PHYSICAL PROPERTIES: (l)-Cast
(2)-Precast Block
FIRED TO F
DENSITY Lbs *'Cm.Ft
(i) (2)
LINEAR CHANGE {%)
(l) (2)
MODULUS OF RUPTURE (psl)
(T) TFT
COLD CRUSHING STRENGTH (psl)
U> (2)
220
500 1000 1400 1500 1800
2000
20.0 22.0 21.0
21.0 20.0 20.0
28.7 27.3
29 0
0.0 -0.2 -0.3
-0.7 -0.8 -2.0
-0.6 -0.97
-3-1
15 47 19
64 56-58 68-74
92 87
98
34 73 64
64 46-50 30-47
124 93
73
THERMAL CONDUCTIVITY: i(BTU/Sq.Ft. /far ./In./OF)
MEAN TEMP. -
K*
0.52
625 0.65
760 900
0.70
0i..6l
USES:
1070
0.94
PANELEX Is used as back-up Insulation for Firebrick Furnace Walls,
Exterior Insulation for large Utility Boilers, as a Light Weight
Refractory Insulation Inside caBlngs of Pressurized Boilers, For an
Insulating Covering on Turbines In Electric Generating Plants, and
similar High Temperature applications. PANELEX can be Cast or Gunned.
972(381)
NFORMATlON GIVEN AND RECOMMENDATIONS MADE HEREIN ARE EASED UPON OUR RESEARCH ARE BELIEVED TO BE ACCURATE, SUT NO GUARANTEE. EITHER EXPRESSED OR IMPLlEO. 1$ MADE
RESPECT THERETO OR WITH RESPECT TO THE INFRINGEMENT OF ANY PATENT OUR PROOUCTS SOLD ON THE UNDERSTANDING THAT THE USER IS SOLELY RESPONSIBLE FOR DETERMINING ThEIR ABILITY FOR ANY PURPOSE This INFORMATION IS NOT TO BE COPIED. USED IN EVIDENCE. RE ED FOR PUBLICATION OR PUBLIC DISTRIBUTION WITHOUT WRITTEN PERMISSION FROM PFIZER INC
(572 rev.)
3T)QUIGLEY COMPANY INC.
s suosdtry of Pfaer Inc
^9
235 EAST 42ND STREET NEW YORK. N Y 10017
1 6094
TECHNICAL DATA
TYPICAL ANALYSIS DATA
PRODUCT:
PANELEX-TP
DESCRIPTION:
NON-ASBESTOS INSULATION
RECOMMENDED SERVICE LIMIT:
2000F
PACKAGING:
50 lb. Bags
MIXING WATER: (For Casting) 9-10 Gallons per 50 lbs. Material
CHEMICAL ANALYSIS:
S102 41.73 % A120 3 12 86 Fe203 2 75
CaO MgO T102
PHYSICAL PROPERTIES:
26.84 f,
6 .37 0 .32
Na20 O.69 %
R2O3 0.15 %
K20 2.13 F 0.002
MnO 0.07
LOI 5-83
(Total Chlorides - 10 ppm)
FIRED TO: F CffST:
i?20 500
1000 1500 2000 GUNNED:
55D
500 1000 1500 2000
DENSITY LBS./CU.FT.
19-7 20.1 19-1 18.9 19-5
21.4 26.5 27.1 26.5 25-3
<f> LINEAR MODULUS OF CHANGE RUPTURE,psi
------
-0.2
-0.3 -0.7 -1.5
51-3 50.0 61.0
39-9 46.5
-0.1 -0.6
-1.9 -1.9
154.2 128.6 l|5.|
45.2
COLD CRUSHING STRENGTH, ps 1
67.1 62 .4 51.5 33-7 32 0
294 .3 216.0 287.1 185.8
83.6
% DEFORMATION COLD CRUSHING
2 .0 1.6 1.7 1.4 1.2
THERMAL CONDUCTIVITY: (CAST)
BTU/SQ. FT. /HR. /IN./of
MEAN TEMP.-F
K'
500 0.58
750 1000
0.69 0.89
USES:
PANELEX-TP can be OUNNED, CAST, TROWELED, or PLASTERED for
applications as Back-up for Water-wall Tubes, Insulating Boiler
Casings, Furnace Walls and Crowns, Turbines, Regenerator Sections
of Open Hearth and Glass Tank Furnaces, Hot Air Ducts, Vessels,
Towers, Tanks, for Aluminum Furnace Troughs, etc.
972 (406)
(872 rev.)
L INFORMATION GIVEN AND RECOMMENDATIONS MADE HEREIN ARE RASED URON OUR RESEARCH ID ARE RELIEVED TO SE ACCURATE. RUT NO GUARANTEE. EITHER EXPRESSED OR IMPLIED IS MADE TH RESPECT THERETO OR WITH RESPECT TO THE INFRINGEMENT OF ANY PATENT OUR PRODUCTS E SOLO ON THE UNDERSTANDING THAT THE USER IS SOLELY RESPONSlRLE FOR DETERMINING ThE>R
IITABILITY FOR ANY PURPOSE THIS INFORMATION IS NOT TO RE COPIED USED IN EVIDENCE. RE ARED FOR PURLICATION OR PURLlC DISTRIBUTION WITHOUT WRITTEN PERMISSION FROM PFIZER INC
QUIGLEY COMPANY INC
s subsdary of Pfaer Inc 55 EAST 42ND STREET NEW YORK N Y 10017
1 6095
TECHNICAL DATA
THERMAL CONDUCTIVITY OF PANELEX
MEAN TEMP.
I INFORMATION GIVEN AND RECOMMENDATIONS MADE HEREIN ARE SASED URON OUR RESEARCH 0 ARE RELIEVED TO RE ACCURATE. GUT NO GUARANTEE EITHER EXRRESSEO OR IMRLIED. IS MADE TH RESRECT THERETO OR WITH RESRECT TO THE INFRINGEMENT OF ANT RATENT OUR RROOUCTS E SOLO ON THE UNDERSTANDING THAT THE USER IS SOLELY RESRONSIRLE FOR DETERMINING THEIR ITABILITY FOR ANT RURROSE THIS INFORMATION IS NOT TO IE CORlED USED IN EVIDENCE. REASED FOR RURLICATlON OR RURLIC DlSTRIRUTION WITHOUT WRITTEN RERMISSlON FROM RFIZER INC
QlXGLEY COMPANY INC
a aubuJary of Pfeer fc>c
235 EAST 42ND STREET NEW YORK N Y 10017
1 6096
TEMPERATURE CURVE FOR PANELEX QUIGLEY COMPANY INC
1 6097
PANELEX
i U( Aep>e*0 | tw'r.to No. 4-Pl}A
*l-i-ov.tt iK'<f( Ap.i *o, **?'
U.S. DEPARTMENT Of LABOR
WAGE AND LABOR STANDARDS ADMINISTRATION Bureau of Labor Standards
MATERIAL SAFETY DATA SHEET
WL-80-13^(8*)
SECTION 1
maNl'EaCTuMN'S NAME
Quigley Co. Inc.
'AODAISS '
Sfrrej, rira^Jisie, mni //P Cn4*t
235 fe. 42nd Street.
CHEMICAL name A*D
New York
c-im.cal.am.l. Non-Toxic Silicates
EONMUIA
1^2)^573-^44
N.Y. 10017 PanelexTNAOt NAME ANO S*N0N*M4
NA
SECTION II
PAINTS, MESCftVATIVCS, A SOIVtNTS PiCMCNT$ CAT*vST
HAZARDOUS INGREDIENTS
tlv (Units)
ALLOYS AND MlTALLIC COATINGS
- ASE METAL
- ALLOTS
VEHICLE
METALLIC COATINGS
SOLVENTS AOO'TiVCS OTmCNS
!-
HUE* MtTAL PLUS COATING 0 CONE HU*
OTmCNS
HAZARDOUS HIXTURZS OP OTHKR LIQUIDS. SOLIDS, OR OASIS
None
1 .
-
-
TLV ft <U*r')
OILING POINT t*. 1 VOA PNESSVNf *** Ng.i VAPON OSNJlTT lAINStl SOI Lr. ITV M MATIN
ooo*aaaiaaanci ano
MOTION HI PHYSICAL DATA
NA
SPECIE 1C ONAVITV IMj0=tl
NA NA
PfNCENT VOLATILE T VOLUME IM
(VAPONATION NATS 1 "II
Nil
Drv eranular mixture - no odor.
SECTION IV FME AND EXPLOSION HAZARD DATA
ECASH POINT lMtt*M w0l
NA
NAUAMKASLI LIMITS
UTiNGUiSmiNG MID'*
NA
S.IC'A. III riCHTiNC AAOCIOUAIS
Not Combustible
NoneUNUSUAL *li AND IIALOS'ON MA7ARDS
7kg. Mr. (CD):
Orot* Vgt.:
0. 4 NA NA
59-
1 6098
1 6099
16100