Document e7k0RLj7bGajropRGkJD60n9
...a chemically modifiedhighly refined fiber with a mineral coating that gives:
HIGHER VISCOSITY AT LOW LOADINGS-- "Calidria" asbestos RG-244 builds more vis cosity at a given concentration than pyrogenic silica or other thickeners. Part of this viscosity increase comes from hydrogen bonding be tween the mineral coating and the resin system --the same way that pyrogenic silica builds viscosity. What makes RG-244 more efficient is that the fibers enhance flow resistance. On a Ib.-for-lb. basis, RG-244 builds over twice as much viscosity as pyrogenic silica.
BETTER FLOW AT HIGH SHEAR RATES"Calidria" RG-244 also improves flow at high shear rates because of its inherent thixotropic characteristics. This property is especially de sirable in spray-up applications where less resistance to flow is desired during pumping and spraying.
SAVINGS FROM BETTER PERFORMANCEBy increasing viscosity and thixotropy more efficiently than other materials, "Calidria" asbestos RG-244 allows users to obtain their desired properties with less mineral additive. This reduction lowers costs and reduces any detrimental effect of thickeners on other resin properties.
LOW COSTS TOO--"Calidria" asbestos RG244 costs less per lb. than similar thickeners.
Thus, users save two ways--on unit cost and cost performance.
FAST WETTING. EASY DISPERSION--Con ventional mixing equipment can be used to disperse "Calidria" RG-244 quickly and easily. In fact, this unique product wets out and dis perses considerably faster than most other thixotropes.
BETTER SHELF LIFE. LESS SETTLING -Sys tems containing "Calidria" asbestos RG-244 can be stored for long periods without any significant change in viscosity or thixotropy. Settling during storage is minimized, and sys tems containing RG-244 can be remixed easily. In all these respects, RG-244 surpasses most other thickeners.
NO COLOR OR OP/CilY "Calidria" asbes tos RG-244 is a highly refined fiber with a clear mineral coating that does not add color to most systems. At the same time, RG-244 has a refractive index that matches many systems, so that it does not add opacity. These features make RG-244 especially well suited for use in clear polyester gel coats.
REDUCED DUSTING "Calidria" RG-244 is a fibrous material containing a minimum of dust. It therefore reduces dusting during materials handling and additions to resin systems.
UCC 001741
TYPICAL PHYSICAL PROPERTIES
. Specific Gravity, .. n , *
Moisture Content f ' - :;3'G V
Nature of Surface Charge ,. . ^ . ,,
Magnetite Content
Refractive Index
Oil (DOP) Absorption
Surface Area
Fiber Diameter
1"-- 1 "
Length/Diameter (Aspect Ratio)
Bulking Value
Dry Bulk Density (aerated)
2.45 2.0 Neutral 0.3 1.54 to 1.56 300 to 350 >60 0.025 200 avg. 4.9 1.0
-- % max. by weight
-- % max. by weight
n^S'C. lb. per 100 lb. sq. m. perg.
microns --
gal. per 100 lb. lb. per cu. ft.
:KAG!NG AND AVAILABILITY
Single Package--Weight (3-pty paper bag sealed In polyethylene)
10 (b.
Single Pallet--Weight
'^
- --Dimensions
(full pallets covered by waxed cardboard)
350 lb. . approx. 53 in.x44 in.
x 61 in. high
Full Carload (available from King City plant)
52 pallets 18,200 lb.
Full 40-ft. Truckload (available nationwide)
17 pallets 5,950 lb.
"Calidria" asbestos RG-244 is stocked at Union Carbide's shipping locations throughout the United States and is available from several distributors.
UCC 001742
Why is "Calidria" asbestos different?
"Calidria" products are made from highpurity, short-fiber chrysotiie asbestos obtained from a unique deposit about 160 miles south of San Francisco, California. Unlike conven tional deposits that extend through the host rock, this deposit is essentially free of hard, consolidated rock masses. Further, the ore assays up to 60% asbestos fiber compared to conventional deposits which contain from 6 to 10% asbestos.
Special hydraulic beneficiation techniques
developed by Union Carbide efficiently break down the fiber bundles and remove the rock and impurities from the asbestos fiber. As a result, all "Calidria" products are over 95% pure asbestos whose fibers are 98% liber ated from fiber bundles.
RG-244 is made by additional refining to achieve over 99% purity. The fibers are then chemically coated by a patented process to form this unique, highly efficient thickener and thixotrope.
CANADIAN ASBESTOS--AS-MINED--Individual fiber bundles are straight and tightly bonded, surrounded by consolidated rock masses. In this form, the fibers defy separation from each other and from the host rock.
"CALIDRIA" ASBESTOS--AS-MINED--Here the fibers are randomly oriented and essentially free of hard rock masses. Further, the ore assays up to 0% asbestos, considerably more than the Canadian ore.
"CALIDRIA" ASBESTOS--IF DRY-PROCESSED-Even the most exacting dry processes do not completely break down the fiber bundles into individually liberated fibers. Union Carbide technology developed a special wet proc ess to liberate the fibers.
"CALIDRIA" ASBESTOS--UNIQUELY WET-PROCESSED -- Union Carbide's process separates 98% of the fibers from the fiber bundles. RG-244 fibers are over 99% pure asbestos and chemically coated to provide an efficient thickener and thixotrope.
UCC 001743
Typical Performance DatajGeneral Purpose UNPROMOTED Polyester Resins
HIGHER VISCOSITY AT GIVEN CONCENTRATION On a Ib.-for-lb. basis, "Calidria" asbestos RG-244 builds substantially more viscosity in these 2 polyester systems than pyrogenic silica. RG-244 builds twice as much viscosity at a 1 % concentration and 4 times as much viscosity at 3% concen tration. Thus, users can use less RG-244 to obtain their de sired viscosity.
HIGHER VISCOSITY AT LOW SHEAR RATES BETTER FLOW AT HIGH SHEAR RATES 2% "Calidria" asbestos RG244 gives better thixotropic properties than 4% pyrogenic silica in this unpromoted poly ester resin containing about 50% styrene. The RG-244 sys tem has better flow at high shear rates, allowing easier pumping and spray-up. As the shear rate is reduced, the RG244 resin has better viscosity and sag resistance.
UCC 001744
SAVINGS USING "CALIDRIA" ASBESTOS RG-244-UNPROMOTED Polyester Resins
The better performance and lower cost of "Calidria" asbes tos RG-244 allow substantial savings. In the typical unpro moted polyester resin system shown at the right, "Calidria" RG-244 builds a given viscosity for about one-half the cost of pyrogenic silica.
Typical Performance Data/General Purpose PROMOTED Polyester Resins
IMPROVES BOTH VISCOSITY AND THIXOTROPY "Calidria" asbestos RG-244 also effectively improves the viscosity and thixotropy of pro moted polyester resins, in many cases, the improved vis cosity and thixotropy provided by RG-244 will be sufficient to meet user needs. Should higher values be required, a small ad dition of ethylene glycol or a similar additivewill improve the viscosity, thixotropy, and sta bility of the RG-244 dispersion. At the right is an example of these improvements in a typ ical polyester resin containing a cobalt-type accelerator.
UCC 001745
Typical Performance Data^Heat-Curabie vinyl plastisol Sealants
"Calidria" asbestos RG-244 improves the vis cosity of heat-curable vinyl plastisols without reducing their inherently good adhesion prop erties, In fact, RG-244 provides excellent anti sag properties at both low (275 to 375 deg. F.)
and high (above 350 deg. F.) fusion tempera tures. An example of how RG-244 improves the viscosity of a high-fusion temperature structural sealant without detracting from ad hesion is shown below:
FORMULATION FOR HIGH-FUSION TFMFERATURE STRUCTURAL SEALANT
INGREDIENT
BAKELiTE QYOH-2 Resin FLEXOL Plasticizer 10-10 FLEXOL Plasticizer 10A EX-1 Extender Plasticizer Barium-Cadmium Stabilizer UNION CARBIDE Silane Y-5162 Adhesion Promoter Calcium Carbonate CALIDRIA Asbestos RG-244
PARTS BY WEIGHT
100 60 40 10 2 0.25
130 5
TEST DATA
Butt tensile adhesion to cold-rolled steel after 45 minutes cure at 350 F.
Severs type flow properties Binks orifice (1 /8 inch) Time of test: 150 seconds
Aged 24 hr. at room temperature Aged 72 hr. at 130 F Aged 45 days at room temperature
Shore hardness, A scale after 24 hr, at room temperature
440 psi
63 g. at 40 psi 76 g. at 40 psi 73 g. at 40 psi
76
Dispersion of "Calidria" Asbestos RG-244
i;[ 7 re /'SONIC
Good dispersion of "Calidria" asbestos RG244 in polyester laminating resins can be obtained with an "Econosonic" disperser op erating at 300 psi pressure. Pressures above 300 psi tend to reduce viscosities. In general, "Calidria" asbestos RG-244 requires less en ergy for adequate dispersion than comparable concentrations of pyrogenic silica.
TOW!. FS" DISSOLVER
A "Cowies" dissolver can disperse "Calidria" asbestos RG-244 in 5 to 10 minutes at 3500 rpm, using a 3-in. impeller in a 3-quart con tainer. Under these conditions a 1% loading can be mixed for 1 hour while a 2% loading can be stirred for 30 minutes without degrad ing. Large volumes of RG-244 can be dis persed easily by scaling up the equipment.
UCC 001746
Any of our offices below will be glad to give you complete information on properties, applications, and prices of "Calidria" asbestos.
Marketing and Technical Center
Niagara Falls, New York 14302
Plant
King City, California 93930
P. O. Box 579 P. O. Box K
716-285-3311 408-385-5961
Sales Offices
Atlanta, Georgia 30329
17 Executive Park Dr.
Baltimore, Maryland 21207
Beltway Bldg. 6707 Whitestone Rd.
Boston, Massachusetts 02194
300 First Ave., Needham Heights
Buffalo, New York 14225
3343 Harlem Rd.
Charlotte, North Carolina 28210
6230 Fairview Rd,
Chicago, Illinois 60606
120 South Riverside Plaza
Cincinnati, Ohio 45227
West Street and Madisonviiie Rd.
Cleveland, Ohio 44114
1300 Lakeside Ave., N.E.
Clifton, New Jersey 07012
935 Allwood Rd.
Dallas, Texas 75207
2710 Stemmons Freeway
Detroit (Southfield, Michigan Sales Office)
Houston, Texas 77027
3737 Greenway Plaza Dr.
Indianapolis (Cincinnati, Ohio Sales Office)
Kansas City (St. Louis, Mo. Sates Office)
Los Angeles, California 90058
2770 Leon is Blvd.
Memphis (Atlanta, Ga. Sales Office)
Minneapolis, Minnesota 55416
3030 Excelsior Bivd.
Moorestown, New Jersey 08057
Route 38 and Pleasant Valley Rd.
New York, New York 10017
270 Park Ave.
Philadelphia (Moorestown, New Jersey Sales Office)
Pittsburgh, Pennsylvania 15220
P'kway Center, 875 Greentree Rd.
Southfield, Michigan 48075
26500 Northwestern Highway
St. Louis, Missouri 63105
10 South Brentwood Blvd.
San Francisco, California 94106
One California St.
Seattle, Washington 96118
4726 Rainier Ave., South
404-633-6161 301-944-8211 617-444-5400 716-837-6450 704-364-1400 312-822-7000 513-272-0206 216-621-4202 201-778-2900 214-631-0010 313-354-0800 713-621-1000 317-255-3181 913-362-2200 213-583-3061 901-396-5375 612-927-4221 609-235-6200 212-551-6423 215-923-3200 412-922-5700 313-354-0800 314-726-0324
415-982-1360 206-723-8660
UNION CARBIDE CORPORATION MINING AND METALS DIVISION
270 PARK AVENUE, NEW YORK, N. Y. 10017
THE DISCOVERY COMPANY
F-70-0B0 B/70-5M
UCC 001747
Baketite, "Calidria,'1 "Flexol, and "Union Carbide" are registered trade marks of Union Carbide Corporation.
Printed fn U.S.A.