Document dad6Djyj2b7665DomRrMbrknG

SpecialtvAlkvlatg Headquarters. Conoco Chemicals Division. Continental Oil Company 5 Greenway Plaza East' P.O. Box 2197Houston, Texas 77001? Domestic Sales Offices* Eastern Region Park SO Plaza Eastv. Saddle Brook; New Jersey 07662S'. (201)845-3800; Midwestern Region- 800 Enterprise-Drive^ Oak Brook, Illinois 6052L (312)325-2113i * ' Western Region 3160 Airway AvenueP.O. Box 2500' Costa Mesa, California 92626 (714) 556-6371 International Sales Offices Conoco Chemicals Latin America, S.A. 5 Greenway Plaza East P.O. Box 2197Houston, Texas 77001 (713)965-1751, Telex: 775347 TWX: (901) 881-2557 Conoco Chemicals Europe, S.A_ Rue Joseph Stevens 7 Brussels 1000, Belgium Phone: 513--74--90 Conoco Chemicals Far East, Inc. Kasumigaseki Building, 31st Floor, P.O. Box 64 Tokyo, Japan Phone: 593-0801, Telex: J24505 Cable: CONOCOFE Tokyo SpecialtyAlkylate- HeadquartersConoco Chemicals Division Continental Oil Company 5 Greenway.PIaza East. P.O.Box 2197 Houston, Texas 77001 Domestic Sales Offices Eastern Region Park 80 Plaza East V Saddle Brooks NewJersey 07662* ` (201)845-3800. Midwestern Region- ' 1 . - 800 Enterprise Drive - Oak Brook, Illinois 60521 (312) 325-2113 Western Region3160 Airway AvenueP.O. Box'2500 Costa Mesa, California 92626; (714) 556-6371 International Sales Offices* Conoco Chemicals* Latin America, S.A. 5 Greenway Plaza East P.O. Box 2197Houston, Texas 77001' (713) 965-1751, Telex: 775347 TWX: (901) 881-2557' Conoco Chemicals Europe, S.A. Rue Joseph Stevens 7 Brussels 1000, Belgium Phone: 513-74-90 Conoco Chemicals Far East, Inc. Kasumigaseki Building, 31st Floor, P.O, Box 64 Tokyo, Japan Phone: 593-0801, Telex: J24505 Cable: CONOCOFE Tokyo Conoco TECHNICAL INFORMATION DPA Secondary Plasticizer in Flexible Vinyl Introduction In many flexible vinyl products, it is possible to replace a portion of the ester plasticizer in the formu lation with various types of lower priced oils to reduce the overall cost. A number of materials availa ble for this from many sources are usually petroleum-based oils of naphthenic or aromatic character. Conoco DPA secondary plasticizer is a synthetic alkylaromatic suitable for use as a secondary plasti cizer with many advantages over petroleum-based oils. Conoco DPA secondary plasticizer couples low volatility with good low-temperature performance, like most synthetic alkylbenzenes. The availa bility of the product is insured and its consistency is not affected by the changing naphthenic and aromatic character of crude oil feedstocks, since Conoco DPA is synthetic and a detergent alkylate co-product. Efficiency and Compatibility The change in efficiency as Conoco DPA secondary plasticizer replaces phthalate ester plasticizer is seen in the tensile properties and hardness. This is inherent in the use of a secondary plasticizer as they are much less efficient as plasticizers than are esters. This can work to a compounder's advan tage. however, in that by using a secondary plasticizer he can increase the total amount of plasticizer in a formulation to achieve the desired softness. This effectively substitutes expensive resin with less expensive plasticizer and can allow higher filler loading. The compatibility of Conoco DPA secondary plasticizer is similar to that of many oils of comparable volatility and aromaticity. As with petroleum-based secondary plasticizers, volatility is increased by the use of Conoco DPA secondary plasticizer, but the increase is less than that experienced with petroleum products of comparable compatibility. Conoco DPA secondary plasticizer is also suitable for use in plastisol applications where it not only exhibits the properties already mentioned but can also function as a viscosity control agent. Low-Temperature Properties One very clear performance advantage for Conoco DPA secondary plasticizer is in the area of lowtemperature flexibility as shown by the brittle point (ASTM D-746) and Clash-Berg tests (ASTM D-1043), For example, a 25 percent substitution with Conoco DPA secondary plasticizer has reduced the Clash-Berg low-temperature flex test result by 15 to 25C depending on the primary plasticizer used. Density Reduction Since the specific grav ity of Conoco DPA secondary plasticizer is less than that of primary plasticiz ers {0.899 compared to about 0.980). the mixed plasticizer would have a lower specific gravity. As a result, the finished compound would be of lower density. On a weight basis, the cost of the formula tion containing Conoco DPA secondary plasticizer would be less. This would represent a savings in addition to that obtained solely due to the lower cost of Conoco DPA secondary plasticizer relative to primary plasticizers. Color With secondary plasticizers, there is some color darkening during exposure to a xenon arc lamp. The severity is less than with many highly aromatic oils, but appropriate testing for each end-use applica tion must be carried out to determine the effect. Important Color of Conoco DPA secondary plasticizer may vary from shipment to ship ment and is subject to subsequent color degradation in storage. Color characteris tics of a given sample or shipment may be different at time of shipment, time of receipt inspection, or time of use. Conoco believes the variation in. and degradation of. the color of Conoco DPA secondary plasticizer should not affect the plasticizer performance properties. Conoco makes no representation or warranty, including but not limited to a war ranty of merchantability or suitability for a.particular purpose, whether or not such purpose is known to Conoco, or as to the color of said product or products made therefrom. vw 000008347 (conoco) Conoco Chemicals The above data are based on tests and experience which Conoco Inc. believes reliable and are supplied for informational purposes only. Conoco Inc. disclaims any liability for damage or injury which results from the use of the above data, and nothing contained therein shall constitute a guarantee, warranty, or representation lincluding freedom from patent liability) bv Conoco Inc. with respect to the data, the product described, or their use for any specific purposes, even if that purpose is known to Conoco Inc. S90IA-CH 305-4 83-2M (conoco) Technical Service Bulletin Surfactant Chemicals Bulletin No. 49 CONOCO DPA SECONDARY PLASTICIZER IN FLEXIBLE VINYL INTRODUCTION In many flexible vinyl products, it is possible to replace a portion of the ester plasticizer in the formulation with various types of lower-priced oils to reduce the overall cost. A number of materials are available for this from many sources and are usually petroleum-based oils of naphthenic or aromatic character. Conoco DPA secondary plasticizer is a synthetic alkytbenzene suitable for use as a secondary plasticizer having many advantages over petroleum-based oils. As is general in many applications where synthetic alkylbenzenes are compared with petroleum-derived oils, Conoco DPA secondary plasticizer couples low volatility with good low-temperature performance. Being synthetic and a coproduct of the detergent alkylate business, the availability of the product is insured and its consistency is not affected by the changing naphthenic and aromatic character of crude oil feedstocks. Typical properties of Conoco DPA secondary plasticizer are shown in Table I. COMPATIBILITY The compatibility of Conoco DPA secondary plasticizer is similar to that of many oils of comparable volatility and aromaticity. The compatibility limits as shown by the Loop-Spew test are summarized in Table II. These results indicate the primary plasticizer replacement level could be up to 25 percent depending on the formulation. It also shows compatibility is greater with DOP than with DINP. Of course, each individual formulation and plasticizer level would have its own limits on the amount of secondary possible, and for each application, compatibility must be ^ determined. The effects on properties that can be expected on replacement of DOP or DINP with Conoco DPA secondary plasticizer are shown in Table III. EFFICIENCY The change in efficiency as Conoco DPA secondary plasticizer replaces phthalate plasticizer is seen in the tensile properties and hardness. This is inherent in the use of a secondary plasticizer as they are basically much less efficient as plasticizers than are esters. This can work to a compounder's advantage, however, in that by using a secondary plasticizer he can increase the total amount of plasticizer in a formulation to achieve the desired softness. This effectively substitutes expensive resin with less expensive plasticizer and can allow higher filler loading. The lower efficiency of secondary plasticizers is also evidenced by longer fusion and dry-time measurements. The different processing characteristics of blends utilizing Conoco DPA secondary plasticizer can easily be overcome by adjusting processing conditions. As with petroieum-based secondary plasticizers, volatility is increased by the use of Conoco DPA secondary plasticizer, but the increase is less than that experienced with petroleum products of comparable compatibility. LOW TEMPERATURE PROPERTIES One very clear performance advantage for Conoco DPA secondary plasticizer is in the area of low-temperature flexibility as shown by the brittle point (ASTM D-746) and Clash-Berg tests (ASTM D-1043). The Clash-Berg low-temperature flex test, in particular, clearly illustrates the improvements that can be expected upon substitution of Conoco DPA secondary plasticizer for either DOP or DINP. VVV 000008848 Internal Distribution Only Conoco Chemicals Company Conoco Inc. Technical Service Laboratory Ponca City, Oklahoma 74601 (405) 767-3288 Surfactant Chemicals Bulletin No. 49 Page 3 TABLE I TYPICAL PROPERTIES OF CONOCO DPA SECONDARY PLASTICIZER Molecular Weight Specific Gravity (16C) Viscosity cps 16'C 60C Flash Point, C Boiling Range, C IBP 5% 50% 90% 95% FBP Pour Point, C Aniline Point, C Organic Chloride, Wt % Bromine Number 310 0.899 41.9 13.8 132 330 340 360 370 380 Cracks -60 18.6 0.03 0.4 Plasticizer DOP 100% DOP 90% DOP 75% DINP 100% DINP 90% DINP 75% TABLE II COMPATIBILITY (LOOP-SPEW TEST) Conoco DPA Secondary Plasticizer 50C -- 100% HUMIDITY 24 Hours 72 Hours 7 Days 22C -- 50% HUMIDITY 24 Hours 72 Hours 7 Days 0% none none none none none none 10% none none none none none none 25% none none none slight medium medium 0% none none none none none medium 10% none none none none none medium 25% medium heavy heavy medium heavy heavy None -- no change in appearance from original. Slight -- slight amount of greasiness evidenced by finger marks or slight spot when wiped with tissue. Medium -- small droplets visible or thin coat of oiliness on surface. Heavy -- large droplets and readily visible wet surface. VVV G0G008849 FORM: 34424671 68515 - 32-2* Benzene, mono-C12-14-alkyl derivs., fractionation bottoms. A complex residuum resulting from the distillation of mono-C12-14- alkylbenzenes, consisting predominantly of alkyl substituted benzenes. FORM: 34424713 68515-33-3* Benzene, mono-CIO-12-alkyl derivs., fractionation bottoms, heavy ends . A complex fraction resulting from the distillation of mono-C10-12 alkylbenzenes, consisting predominantly of alkyl substituted benzenes. FORM: 34424697 68515-34-4* Benzene, mono-C12-14-alkyl derivs., fractionation bottoms, heavy ends. A complex fraction resulting from the distillation of mono-Cl2-14 alkylbenzenes, consisting predominantly of alkyl substituted benzenes. FORM: 34424705 68515-35-5* Benzene, mono-CIO-12-alkyl derivs., fractionation bottoms, light ends. A complex fraction resulting from the distillation of mono-C10-12 alkylbenzenes, consisting predominantly of alkyl substituted benzenes and diphenylalkanes. FORM: 34424689 68515-36-6* Benzene, mono-C12-14-alkyl derivs., fractionation bottoms, light ends. A complex fraction resulting from the distillation of mono-C12-14 alkylbenzenes, consisting predominantly of alkyl substituted benzenes and diphenylalkanes. VVV 000008350 < IMPORTANT: .mplefmg this form, carefully read the ERA publication "Reporting for the Chemical Substance Inventory '. That booklet contains instructions for properly completing this form. U. S. ENVIRONMENTAL PROTECTION AGENCY CHEMICAL SUBSTANCE INVENTORY REPORT (Section 8(a) and (b) Toxic Substances Control Act IS USC 2607) AppravM OMB *orr 158 S 77011 FORM C CERTIFICATION STATEMENT: I hereay certify that, to the best of my knowledge and belief: M) the chemical substance identified below has been manufactured or imported for o commercial purpose since January 1, 1975, and can be reported for the inventory (40 CFR 710); (2! all information entered on this form is complete ana accurate; and (3i the confidentiality statements on the back of this form are true as to that information tor which I have asserted a confidentiality claim. I agree to permit access to, and the copying of. r^ordfcby a duly authorized representative of the EPA Administrator, in accordance with the Toxic Substances Control Act. to document an)tXj^luiMiUI imported here. mm Thomas, G. Grumbles/Env. Dualitv Manager NAME/TITIE (TYPE OR PRINTi Foreign Supplier Signature. --Date. CO MID ERA USE ONLY II. CORPORATION Continental Oil Company C\J III. PLANT SITE NAME/ADDRESS IV. PRINCIPAL TECHNICAL CONTACT(S) NAME HorhtirLgn.tfl.l fl.i.l. Company, , Ray C. Allred, Assistant Director oo AppREssfe.a.1 ,t.imore, .hem,i anJc H44.L fa.i .r.f.ie.l d. Road.............. city TjaJ.tii fUft.re, ...................................... t STATE 7*11)1 Environmental Conservation Continental Oil Company P.0. Box 1267 couNTY~Ba.1 .t.i mfl.re. .C.i.t.v. upturn......... ..................... DUN A BRADSTREET NO. Qflr'.306,~'53J84l Ponca City, OK 74601 (405) 762-3456 Ext. 4533 NUMBER EPA USE ONLY v \ Tvr\Trt S 5\ (f) PLANT SITE ie) CORPORATION 2^ 'di \5 PRODUCTION \ :cj SITE LIMITED ;b) IMPORT z|\ MANUFACTURE SITE LIMITED IMPORT MANUFACTURE PRODUCTION RANGE </5 1/5 <_j U 1/5 1/5 <--i <J S I o <D oo EB QJ o IN +-> e +j qj o cn _e> TT\vvuvu\m\vvv\m: U J2 Si E "2 J -5 o 2Z o2 _S -5 --0 4C) "Z F O z LU s LU -- < t-- LO >- \ t-- Z\ LU Q\ UJ s Uz \ < I-- S (/) cd X uO TT \ S?0 uj <-- X U \ *--1 5 lk-- < ULFUJ z o So o. --0U'=jJ5xOo4S>) "2I X ou. Uoj !2< cl <zy < Of X <1 IU UJ cn u Z> -t(X LU Uj t-- ^ T z o? Q_ LL. -o U0Z qs O m -- LU UJ Q X "zz Q < uj Q > < o Of Q. S U (^Si ^ </> 2 ^ LU to < x E LJ Z ^ uj -- -6Q ?< >5 .x LT5 CO r- LT5 t- t o CM - CO c r^. o r>. O) s= ra ro ccuj ot TS "=3Ot -O CM fU ez (uO Ln u% a o LO J- i P Oh I CM = LO QJ SZ (73 a XQJJ ej- <73 I C. 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CERTIFICATION STATEMENT: I hereby certify that, to the best of iny knowledge and belief: fli the chemical substance identified below has been manufactured or imported for a commercial purpose since Jonuary 1, 1975. ond can be reported for the inventory (40 CFR 710): (2: all information entered on this form is complete and accurate; and (3) the confidentiality statements on the back of this form are true as to that information for which I have asserted a confidentiality claim. I agree to permit access to, and the copying of, records by a duly authorized representative of the EPA Administrator, in accordance with the Toxic Substances Control Act, to document tt reported here. (J V / /) J&A/87 Thomas G. Grumbles/Env. Quality Manager NAMEnrriE (TYPE OB PRINT1 Foreign Supplier Signature. .Date. MID EPA USE ONLY II. CORPORATION Continental Oil Company III. PLANT SITE NAME/ADDRESS IV. PRINCIPAL TECHNICAL CONTACT(S) name lC.on.t.in.enta.1. O.i.l. Comoan,v, Ray C. Allred, Assistant Director ADDREssBa.I.t.imorg, .CJiem.i ca.l. P.lan.t Environmental Conservation 3,4.41, .Fa.ir.f.ie.ld. Road, city ~Ea.l.t.im,o,re. state Tlj Continental Oil Company P.0. Box 1267 cou ntyT a .1 ,t ,i m or ,e, ,C .i ,t y. 2*-zxzm Ponca City, OK 74601 DUN & 8RADSTREET NO. P P ,""3 P6,--5 98 4l (405) 762-3456 Ext 4533 NUMBER EPA USE ONLY z' \ Z vN x Z =V V (II PLANT SITE CORPORATION (d) PRODUCTION ic) SITE LIMITED <b) IMPORT Z \ MANUFACTURE SITE LIMITED IMPORT MANUFACTURE PRODUCTION RANGE Zo ui _Q E <o t-- I-- Zz uj a-- USJ U_ Z< o "S.2 5 5 ii XT \ \ \ xi 4a>) =w _c = w' o Oo ~o 6v Zo Q. O \ \ w- 3 VI ztu EO _ t<--cO OE*- O to -- 41 __ UJ d (J \ \ \ A V \ \ V V V V V V M V V ^ STT^Yl A E z Ol "d >, <0 I Ci--Nt i/> I "O oc rCHJ O) I 4-> O3 ->cC*n* at co cE a> o fN +J 3 +-> 0J o CO XJ >0 t-v uj 05 Uj 5 o<o Z U Z S o Z * NUMBER EPA FORM NO. 7710-3C (11 -77) oZP UJ Uz IU--O UJ UJ 5<zo <o<5 I-- IPo to oz Qs L_U Q x--U uai 183 S!u U0 Q >- 5 - UJ uj m^ L^gZU a2. 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ENVIRONMENTAL PROTECTION AGENCY CHEMICAL SUBSTANCE INVENTORY REPORT (Section 8(a) and (b) Toxic Substances Control Act 15 USC 2607) Approved OMB Form No 190 5 7701) FORM C 0 oo CO C\l ^1- oo CERTIFICATION STATEMENT: I hereby certify that, to the best of my knowledge and belief: M) the chemical substance identified below has been manufactured or imported for commercial purpose since January 1, 1 975, and can be reported tor the inventory (40 CFR 710); 12) all information entered an this form is complete and accurate; and (3) the confidentiality statements or the bock ot this form ore true as to that information tor which I have asserted a confidentiality claim I ogree to permit access to, ond the copying of, records By a duly authorized representative of the EPA Administrator, in accordance with the Toxic Substances Control Act, to document information_Lecia3ed here. . 0 v A Thomas G. Grumbles/Env. Quality Manager NAM6.TITLE (TYPE OR PRINTi Foreign Supplier Signature. .Date. MID EPA USE ONLY III. PLANT SITE NAME/ADDRESS II. CORPORATION Continental Oil Company IV. PRINCIPAL TECHNICAL CONTACT(S) name "Con.t.i nen.ta.l. Q.i.l. Company. ApDREssBa.I.t.i more. .Chem.i ca.l. Plant, 3.44.1. Fairfield. Road. Ray C. Allred, Assistant Director Environmental Conservation Continental Oil Company cm "E^Uimpre, stateTIPI P.0. Box 1267 couNTY~Pa,l .t.i more. ,C.i,ty. t * \ i DUN & 8RA0STREET NO. P 03 0 6 ~5 9 841 Ponca City, OK 74601 (405) 762-3456 Ext. 4533 NUMBER EPA USE II ONLY nvuuvv V \ \ \ \ \ s Wv z\ $\ Z s (0 PLANT SITE () CORPORATION S '5 => \ = I (d) PRODUCTION (cl SITE LIMITED 3 Z\ (b) IMPORT (a) MANUFACTURE WVWV'sV SITE LIMITED IMPORT U MANUFACTURE < PRODUCTION RANGE 3ZX2XIXIXX V _Q E XX2X22X2SXXX <o k-- k-- Zz uj aS --U- Qt--J z< o s -i = v Z UJ Q Zuj UO ZX 2< to t-- t3o <Z to <3 y5 a) E o Z cv 4> o D 0! Oa o < CN u Z < 3 a, </> V --I w< _s UJ 55 o \ 11111 s 1111111111 \ t 11 tN uuOh ttoo << Uo m rd C o m* 4-> O id z. 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