Document dVMo1zw7GkOgKpZV3NMgwwxR

Polymer Type 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 102F5 121F4 121F4 121F4 121F4 121F4 121F4 121F4 121F4 121F4 121F4 121F4 121F4 135 135 135 135 135 135 135 TABLE VI Avon Lake General Chemical AUGUST--SEPTEMBER 1967 Monomer Concentration in Polymerizer Atmospheres Poly No. Poly Size Total Evacuation Time' VC1 ppm Monomer VAc 10 Min* 30 Min** 10 Min 30 Min 120 1100 130 1100 151 1100 102 1100 124 1100 128 1100 150 1100 150 1100 121 1100 128 1100 136 1100 130 1100 133 1100 114 1100 113 1100 117 1100 135 1100 132 1100 136 1100 116 1100 20" 18" 25" 35" 20" 20" 50" 20" 40" 40" 45" 90" 25" 25" 30" 25" 25" 40" 40" 60" 84 72 50 46 42 32 99 78 230 123 77 80 20 25 76 80 34 34 104 63 56 62 93 32 146 97 375 250 147 107 234 264 180 185 147 104 118 64 76 59 25 1100 32 1100 29 1100 48 1100 28 1100 45 1100 42 1100 43 1100 32 1100 25 1100 6 1100 25 22" 20" 30" 25" 55" 55" 60" 25" 30" 35" 25" 30" 74 56 34 417 36 78 100 75 211 55 102 62 . 100 114 84 391 68 100 189 148 279 39 37 41 19 1100 34 1100 6 1100 20 1100 9 1100 12 1100 4 1100 25" 25" 40" 30" 25" 25" 30" 94 88 40 29 35 44 165 168 120 99 60 78 271 152 66 10 10 57 33 00 13 2 BFG61046 Ut o ot O O Polymer Type 127 127 127 127 127 103F71 103F71 103F71 103F71 102-S 102-S 102-S 109EP 102F11 103 102 101F21 109F2 104EP Poly No. 8 12 21 12 17 137 143 137 141 113 127 116 106 146 142 124 142 105 148 Poly Size 1100 1100 1100 1100 1100 3300 3300 3300 3300 1100 1100 1100 1100 3300 3300 1100 3300 1100 3300 Total Evacuation Time 60" 25" 18" 30" 35" 20" 45" 25" .35" 15" 10" & 30" 10" & 5" 30" 30" 35" 30" 35" 30" 45" ppm Monomer VC1 VAc LO Min 30 Min >10 Min . 30 Min 27 80 174 320 102 104 142 168 38 68 374 134 405 142 62 112 138 123 54 59 32 498 440 390 192 188 162 200 147 139 128 101 106 113 52 47 26 24 *Sample collected 10 minutes after operator enters poly, operator breathing zone sample **Sample collected 30 minutes after operator enters poly or after cleaning if cleaning time was less than'30 minutes; operator breathing zone sample >c0n o si tn o o W DATE 8-29-67 9-5 9-7 9-11 9-12 9-25 9-26 9-28 APPENDIX II Monomer Concentration in Room Air .Bids. 451 ppmVC 16 58 450 6 Bldg. 461 53 27 45 26 18 31 48 32 &FG61048 to 0\ o con CO * Polymer Type 121F4 135 104EP TABLE VII > Avon Lake General Chemical MONOMER CONCENTRATION IN POLYMER3ZER ATMOSPHERES October 1967 Poly No. Poly Size . Total Evacuation Time VC1 10 min. ppm Monomer VAc 30 min 10. min 30 min 25 1100 43 1100 33 1100 29 . 1100 41 1100 25 1100 30 1100 45 1100 34 1100 46 1100 16 1100 18 1100 14 1100 18 1100 2 1100 65" 45" 45" 35" 35" 30" 65" 80" 65" 35" 50" * 20" 50" 35" 25" 71 95 59 50 48 70 73 117 75 38 73 98 66 114 30 23 35 43 56 55 "V 115 210 0 156 114 0 53 74 0 58 62 0 58 56 0 6 0 0 0 0 142 3300 45" 50 35 MONOMER CONCENTRATION IN ROOM AIR Date ppm VC1 Bldg. 451 Bldg. 461 10-16-67 10-17 10-23 10-30 142 14 28 44 26 BFG61049 (A 3 o\ o o .Year 1967 1968 1972 Ave. TABLE VIII AVON LAKE GENERAL CHEMICAL PLANT Ambient Concentrations of Vinyl Chloride Date 8/29 9/5 9/7 9/11 9/12 9/25 9/26 9/28 10/16 10/17 ' 10/23 10/30 9/18 9/23 9/30 10/8 10/30 11/12 11/13 Bldg. 451 16 58 450 6 142 14 28 44 21 21 42 24 59 72 28 133 Bldg. 461 53 27 45 26 18 31 48 32 26 47 49 30 47 68 88 65 76 24 18 62 61 63 11/19 6/29 J 72 29 73 <1 <1 3 16 <1 41 38 BFG61050 SOOSjLQSZ Bldg. 464 22 14 27 15 7 13 Table IX Avon Lake General Chemical Atmospheric Vinyl Chloride Concentrations In Charging Areas Building 451 Tuesday, 8/22/72; 11 a.m. West Side East Side Control Room 82 ppm 155 ppm 8 ppm Tuesday, 8/22/72; 3 p.m. West Side East Side Control Room 89 ppm 378 ppm 64 ppm Thursday, 8/24/72; 9 a.m. West Side East Side Control Room 78 ppm 13 ppm 5 ppm Thursday, 8/24/72; 11 a.m. West Side Center East Side 73 ppm 104 ppm 30 ppm Thursday, 8/24/72; 1 p.m. West Side Center East Side Thursday, 8/24/72; 3 p.m. 97 ppm 72 ppm 10 ppm West Side Center East Side 33 ppm 33 ppm 13 ppm Friday, 8/25/72; 9 a.m. West Side Center East Side 135 ppm 22 ppm 148 ppm Friday, 8/25/72; 11 a.m. West Side Center East Side 24 ppm 24 ppm 131 ppm 1 BFG61051 8 SI CA o C'i West Side East Side Control Room West Side East Side West Side East Side Control Room West Side East Side Control Room West Side East Side Control Room West Side Center East Side West Side East Side West Side Center East Side West Side Center East Side West Side Center East Side West Side East Side Table IX (contd.) Friday, 8/25/72; 1 p.m. Thursday, 9/7/72; 1 p.m. Building 461 Tuesday, 8/22/72; 11 a.m. Tuesday, 8/22/72; 3 p.m. ^ Thursday, 8/24/72; 9 a.m. Thursday, 8/24/72; 11 a.m. Thursday, 8/24/72; 1 p.m. Thursday, 8/24/72; 3 p.m. Friday, 8/25/72; 9 a.m. Friday, 8/25/72; 11 a.m. Friday, 8/25/72; 1 p.m. 47 ppm 95 ppm 54 ppm 23 ppm 440 ppm 531 ppm 131 ppm 49 ppm 48 ppm 32 ppm 24 ppm 29 ppm 288 ppm 26 ppm 329 ppm 762 ppm 70 ppm 20 ppm 72 ppm 33 ppm 107 ppm 87 ppm 369 ppm 364 ppm 135 ppm 168 ppm 186 ppm 156 ppm 358 ppm 122 ppm BFG61052 0 8 St O 3 e0i9Hg -- mdd 5X1 uidd goi mdd i mdd g mdd zi mdd +72 mdd 6 mdd 5 mdd gf mdd 9 mdd mdd mdd sx mdd gx mdd g mdd i mdd mdd g mdd g mdd x mdd g mdd 2 mdd zZ mdd g mdd 096T mdd 01763 uidd 28 mdd mdd x *m*d x -ZL/ZZI2 `Ajpxa.1 ** xi -ZL/ZZ12 *A?pxag m*B 6 -` ZL/SZ/9 `XBpxag *m*d iZL/tt/d `^apsanqx m*d x 33/173/8 `A?psanqx . m-B XT `ZL/^Zld `^psanqx *ra*B 6 `ZL/VZ/2 `^psanqx ra-d JZL/ZZ/2 `^epsanx m*B XT ZLlZZ/2 `^apsanx 17917 3uTPTTn8 ra*d x *3Z/Z/6 `Zupaanqx (prjuoD) xi aiqei pug qqrios aaauag pug qaaoij pug qanog aaquag pug qqaon pug qqnos aarjuag pug qrjaoti pug qanos aaauag pug qaao^ pug qanos aaauag pug qaao^ pug qanos aarjuag pug quJON pug qanos aaauag pug qaaog pug qanos aaauag pug qaaon pug qanos aaauag pug qaaofj % apXS 9SBg apTS 3safi .Pedricktown Plant TABLE X Atmospheric Vinyl Chloride Concentrations Sample Description .North Area East Middle West Center Area East Middle West South Area East Middle West North Area East Middle West Center Area East Middle West South Area East Middle West North Area East Middle West Center Area East Middle South Area Middle West Wednesday, 7/19/72; 11:20 a.m. " Wednesday, 7/19/72; 3:30 p.m. Wednesday, 7/19/72; 9:30 p.m. Vinyl Chloride Concentration, ppm Cl. 6. 4. 6. 4. 8. 27. 19. 6. 4. 6. 6. 4. 4. 4. 2. 4. 6. 96. 19. 55. 78. 29. 110. 78. BFG61054 U\ o CM o o C4 TABLE X contd Thursday, 7/20/72; 10:00 a.m. North Area East Middle West Center Area East Middle West South Area East Middle West Thursday, 7/20/72; 4:00 p.m. Mass Poly Building Bottom of Prepoly (Charging VCl). First level of Prepoly. Second level of Prepoly. Third level of Prepoly. Near vinyl pumps (outside). Tank Farm Near vinyl pumps Under vinyl storage sphere. 16. 4. 8. 12. 8. 12. 12. 20. 20. 9. 6. 12. 6. <1.(N.D.) 23. BFG61055