Document b5z3457NYDVnokgNpLbmqjopy

ARRRG - 0735" STUDY SUMMARY OF ENVIRONMENTAL EFFECTS OF LIGHT WATER BRAND AFFF AND COMPONENTS - 1991 TEST SUBSTANCE Identity: A mixture containing perfiuorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-203. (1Octanesulfonic acid) (CAS# 2795-39-3). Remarks: The 3M production lot number was not noted. The test sample is FC-203 without tolylriazole, identified as VW160390. Current information indicates itis a mixture of 1.34% PFOS, 35% diethylene glycol butyl ether, 37.9% water, 20% ethylene glycol, 2.66 % Sultone foamer, 3% sodium octyl sulfate, and 0.19% sodium lauryl sulfate. The following summary applies to a mixture with incompletely characterized concentrationsof impurities. Data may not accurately reflect toxicity or degradationofthe fluorochemical componentofthe test sample. RESULTS The VW160390 48-hr ECs for Daphnia magna = 165 mg/L. DATA QUALITY Reliability: Klimish ranking = 4. Value is from a summary list only. OTHER Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 Last changed: 6/28/00 000847 2 Tremcahnnical Report Summary . To: Patent & Technical Communications Services -- 201:2C-12 potSummusmtbeatyprewrtyon, Guanesar onwars id. eport print onbth sesofpar,307 aM copies [oP& TCS. Be he Ro = mo[ = = em] ke MT hi4-1-91 oreomnmentalEngineering & Pollution Contro A ior logs | esp EN "Eqvironmental Effects of LIGHT ATER Brand AFFFand Korwords N _ Components A LIGHT WATER, aqueous foam, FC-203, FC-206, ethylene glycol, butyl Carbitol, sodium lauryisulfate, Duponol, sodium |dodecylsultate, sodium octylsulfate, L-4640, triethanolamine, urea, TritonX-305,foamer, filmer, surfactant, tolyltriazole, environmental effects, toxicity, Daphnia toxicity, Microtox, algal toxicity, fish toxicity, degradability, biochemical oxygen demand, BOD, chemical oxygen demand, COD. [Project Gbiocive &Ropar Abt 1. To ad to td he knobw asel ofe envd irong mene tal effectsof LIGHT WATER brand aqu filme foro mingu foas msandthe |components used in the products. 2. To identify toxic components and to correlate component and product toxictlies. Tthhiesm.teTchhneidcaaltraewpaorsttianckfrloeam utsnhudemmleaitresyratoufreeandn frovmpi revr ieofufo escsttsn uddaim tesaobe ny t3n hMe'st 3pMrEa ondvuicl trsonamnedntthalecLaobmopraotnoerny.tsTuhseeddaitna |for each component and each product havebeenevalfou rcoampltete enedssandaccanu dadr ditia onalc testy ing requirements have been noted. Where sufficient data on the toxicity and degradabiiiy of individual components were avaliable, thedata were evaluated and recommendations regarding inclusiofn the component in future products have been made. |cAonmaptotneemnpttcwoanscemnatdreattiooncinothreprrtohdeeuctltox.aiWchittiyleoefprF oduC ctto1- x0itchl2 etyctoox0 uiclidt3 ny ooftibtes ccoonmcplounsievnetlsybcyortraekliantIegdttoocthonstiodxeicriattyiaonndthe |concentration of individualcomponents, `major contributors to product toxicity are believed to be the filmer, the foamer, [butyl CarbitolTM, and DuponolTM ME (sodium laurylsulfate). Components likely to contribute less to product toxicity are ethylene glycol, tolytiiazole, sodium octylsultate, and Dl-water.Furthertoxicity testing of components. and product formulations should enable better correlation between component and product toxicities. -- [er[eo fo ATIoe [Secu I APiALoDtRPaen saendaDovraiocpmehnt C0 TFAPCiTopyoErxpFerdimRenetport . C0TeGoowh.Spervojeent Q MMAaNnuafgaecmteunrtnSgUbkmary 00 ERNOciRneeerncogfoverntidon 0 omer TOvenRecortandSummary DClosedRepor-OpsnSummary || iReClhaatmicaUlno 0 Nom wGhamii ccalosmeRett peorgteyd 000848 r . Contents LPUIPOSS rssicon. 2 11. BACKGIOUNG rrr, 2 J -- IV. CONCIUSIONS GN RECOMMENGBONS curries V. Environmental EHects LIGTBUTS SBRICH .....mrmmmmmmmmmss. 9 1. Ethyl6n6 GIYOO! (M3017) ovr 10 2. Butyl Carbitol (RM 8887) errr 12 "3. Duponol (RM 3021); Duponol ME Dry Surfactant (Sodium Lauryl Sulfate) ....... 14 4. Tolyltriazole (RM 27513; Corrosion Inhibitor Tolyliriazole Technical Grade) ... 16 5. FORMET (FM115) ssn. 18 6. FImer (FM3820 OF FC-95) scsirns 18 7. Nevoctylsulfate (RM 32067 OF AM 55040) cvs 19 8. DIWAOT (AD 199) cirri 20 10. VW160390 (FC-203 Without Tolyriazole RM 27513) wines 23 y PY, FOBOR crisscross 24 . 12 ORIBOT .nrsniomiiomssgsmmmemsnmsemendin. 35 ' 18, FOR0UOT cummmsmtussusssmmmmmisgmmmmmgnsn, 55 4. FC-20BCF viii ssssnsnns 28 _ 15. L464 (NOW FORIN) rvs 26 16. WHCOIa 7093 (RM 45686) vrsssssnssssns 21 17. THOINANOIAMING ..stsssssssissns. 27 BTR mmr 8 1- . 000849  Environmental Effects of LIGHT WATERTM Aqueous Film Forming Foam and Components 1. Purpose The purpose of this studyisto increase 3M's knowledge of the environmental effects of LIGHT WATERTM aqueous film forming foam and the individual components used to make the product. And, by understanding these effects, to minimize them through formulation changes. IiBackground Thisstudywas undertaken in respontsoe testing done by the German Army which was reported in "Investigations of Toxic Effects and Biological Degradabilty of Foam Extinguishing AAgremnytsReipnorWta"s,teiwncaltuedre"dbdyatEakfkoerh1a6rdfirIesifnigg.hTtihneg mraetpoerrti,alhse,reofafwtheircrheftewrorewdetroea3sMt'hseF"CG-e2r0m3anand FC-206. The 16 fire extinguishing agents were categorized as: 5 multi-range foam agents 6 film-forming foam agents . 3 protein foam agents 1 film-forming fluorine-protein foam agent 1 special foam agent for deep-fry pan fires Environmental effects considered in the German Army Reportwere: 1. Acute toxicity to the marine photoluminescent bacterium Photobacterium PEpCyh,o,sphhoowreveeurm,ustihnegetxhpeosMuircerottiomxe issynsottemc.leTarhefrtoomxitcihtey GwearsmeaxnprAersmsyedaRespoErCt.,a,ndanmday ) have been 10, 20, or 30 minutes. Two multi-range foam agents were considered ~ * "highly toxic". Three multi-range foam agents and 2 film forming agents were found to be "toxic".Fourfilm-forming, all 3 protein, the film-forming fluorine-protein agent, and the deep-fry agent were considertedo have "low toxicity". FC-203 and FC-206 were in the "low toxicity" category. - 2. Algae cell multiplication inhibition test using Scenedesmus subspicatus as the test organism with an exposure time of 72 hours.Toxicitywas expressed as EC ,, and EC. All foam agents with the exceptionoftwo of the protein foam agents were "toxic" to algae. The two protein foam agents had weak toxicity to algae. Both 3M products were considered "toxic" to algae. 3. Acute toxicity to Daphnia magna after exposure for 24 hours. The toxicity was expressed as LC,, and LCs, but the effect criterion was the organisms' loss of ability ~ to swim and will be referred to as EC 1, and EC, in this report. All 5 muiti-range foam agents, al film-forming agents except FC-206, and the deep-try agent were "toxic" to `2. : 000850 Daphnia. One film-forming agent (FC-206), all three protein agents, and the film-forming fluorine-protain agent had "low toxicity" to Daphnia. FC-203: toxic'; FC-206: "low toxicity". 4.Acutetoxicity to Zebrafish (Brachydanio rerio) after exposurefor 48 hours. The ~~ criteriawas mult-range fdoeaatmhaagnednttshewteoxrieci"ttoyxwiac"s toexfipsrh.esTsherdeeasmuLlCti-raanngde LfCoya;.m Oangleynttswaondtwo - film-forming agents were *borderiine toxic/weakly toxic". "Weakly toxic" were 4 film-forming agents, 2 protein foam agents, and the deep-fry agent. One film-forming `agent and the film-forming fluorine-protein agent were "non-toxic". FC-203 and FC-206 were in the "weakly toxic" category. 5. Chemical Oxygen Demand (COD) and 5-day Biochemical Oxygen Demand (BOD ) -- ofa3%solution ofthe test material in water. The ratio of BOD to COD was used as a rating guideline, with a BOD /COD ratio of 0.5 or less considered "insufficient biochemical degradation". Two multi-range agents and one film-forming agent w(FaCs-20.0365).wOenree cmoulntsii-drearnegde iangseufnfticainendtloyndeegfirlamdfeodrmbiinogchaegmeincatl(lyF.C-T2h0e3)rawteiorefor FC-206 croenmsaiidneirnegda"gpernotbsabwleyreinaslulffsiucfifeincti"enbtewciatuhstehetihreiBrOBDO/DC/OCDOrDatriaotsiorsawngeirneg 0f.r5o5m. T0.h6e0 9to 0.89. `The data from the German Army Report for the two 3M products are summarized in the table below. The data for the Microtox, Zebrafish, COD, and BOD tests seem to be "reasonable" and "self-consistent". The data data from previous 3M studies are and considered reasonable because theyagree are considered self-consistent because the fairly well with FC-206 data. are roughly half that of FC-203. i ~ "are Summary of German Army Report Data 7 . Mewar , ow| EAusoEo | 16D,aphnialow | loZnoteatenLew 00R/a0o00 Fo-208 6Lo2wTot2t5y0 16"9Tose:160 ne"Tour40 | 10o83ad T1o63x4 | P0r5a2 t - 2"0L0owTasdioyo | t"esTod:eo | aoswToud2e0y0|| zWeeeakly Taoce"s Now: ail concentn gL. -3- 000851 AForrmyt'hse aallggaaletdoaxitcaitsyhdoatwa,estsheenrteiaalrlye etqwuoiviamlpeonrttatnoxticpiotiyntfosrtooucrotnwsoideprr.odFuicrtsts,.tOhneeGewromuladnexpect more toxicity for FC-203 than for FC-206, as shown in the Microtox, Zebrafish, and Daphnia teexsatsm.plHeo,wetvheerre,mhaigyhebretaoxcicoimtypobnyeFnCt-w2h0i3cthhiasnpbarytiFcCu-la2r0l6y tmoxaiyc tnootalaglawea,ypsebrehatpruse.diFsorurpting tshpeecpiheostoastycnotnhceetnitcrpartoicoensssu.pSteoco1n,d0,00oumrg/PL.EDWhfiolreFtCh-e2t0w3oianldgiaclatsepsecnioeesffoencttthoe tPwEoDalagrael not tlhaergseadmifefearsentcheosinetionxitchietyGweorumldann'tAbremyexRpeepcotretd,.tOhneyeairmepoalrltfarnetslhiwmaittaetriosnpewictihesthaendPEsDucdhaata is that it dates from 1974 and it has been impossible to verify the exact formulation of the sample used in those tests. For the Daphnia data in the German Army Report, the difference between the FC-206 and tFhCe-r2e0i3s avaclounessidseereamblseldairfgfeewrehnecne bceontswiedeenritnhgetPhEe DwadtaetracaonntdetntheoGf ethremtawnoAfrormmyuldaattiao.nsO.urAlso, PED has a 48-hr static Daphnia magna LC, of 1,600 mg/L, while the German Army Report has a 24-hr static Daphnia magna EC, is 430 mg/L. The PED datas quite old (1973) and the formulation of the test sample cannotbeverified. There is a majordifference between the PdeEaDthd0ata5a0n%dotfhtehGeeDrampahnniAartmesytdpaotpaulianttihoant (tLheC )PEaDnddatthaeiGs ethremcaonncAernmtryatviaolnuewhisicthhecauses concentration which causes 50% of the test population to stop swimming (Effective Concentration which show a = ECs). The German Army 48-hr static Daphnia magna value ECs, is of in fair agreement 229 mg/L. with recent rests * One thing that should be kept in mind when considering the toxicity data is that reproducibility and precision of toxicity tests can vary considerably from laboratory to laboratory and over time. However, the differences between the old data (circa 1974)and the morerecent data is Amtoarneylirkaetley,douuer tporcimhaarnygiensteirnesftorsmhuolualtdiobnreatthheertotxhicaintycohfaonugrecsuirnretnetstpprroodtuocctosl aonrdteWset'sspheocuileds. be concerned with having current, reliable data on our PEDs. i il. General Comments _ The following general statements summarize the factors guiding this study. 1. The primary purpose ofthe environmental effects data is for internal use in evaluating ~ formulations and ingredients and not intended for submission to governmental . regulatory authorities. Therefore, any testing should be done using low-cost, non-GLP methods. An exception may be data for the new foamer (L-4640) which may need to be submitted for the European PMN currently underway. 1 Draft Report from EnviroSystems Laboratory dated March 10, 1991. We have asked : EnviroSystems to repeat the Daphnia tests for FC-203 and VW160390. The preliminary results from EnviroSystems on the rest of the samples were acceptable. -a- 000852 2. The German Army performs its own testing and no authority other than the German Armiys presently using the evaluation scheme used in the report cited above. Therefore, there is no needto choose a laboratory, test protocol,or test species ~~ saphpoluilcdabbleecohonstelontsyhoetGhaetrtmeastnrAersumlyttsecsatnsbceheumsee.d Iinnsatseamd,anteystcomuentthrioedssaasnpdossspiebcliee.s 3. Where possible, data on the environmental effects of components should be obtained from the literature or from raw material suppliers inorder to reduce testing costs and time. 4. The National Institute of Occupational Safety and Health (NIOSH) terminology for the dreilsactuisvseitoonxiocifttyooxficthefefeccotms.poWnheilnetsthaensde ttheerfmosrwmeulraetinoontsuwsileldbien tuhseedGeinrtmhaen Army ~~ Report, theyare generally accepted in the US. The toxicity and corresponding terms: are: Concentration Acutely Toxic to Test Population NIOSH Terminology <1 mg "Highly Toxic" 1-10 mg "Moderately ToxicTM 3 10-100 mg/L "Slightly Toxic" 100- 1,000 mg/L. "Practically Non-Toxic" >1,000 mg/L "Insignificant Toxicity" - TM 5. The LIGHT WATER AFFF formulations and components considered are: 1. 2. BEutthyylleCnarebGiltyoclol((RRMM83806177)) 3. Duponol ME (RM3021) 4. Tolyltriazole (RM 27513) . 5. Foamer (FM-4115), 6. Filmer (FM-3820 = FC-95) 7. Na-octylsulfate (RM 32067 or RM 55040) 8. Dl-water (RD 199) 9. FC-203 10. VW160390 (FC-203 without Tolyltriazole RM 27513) 11. FC-203CE (same as FC-203C) 12. FC-206CE 183. FC-203CF 14. FC-206CF > - -- -5- - 000853 7 . 15.1-4640 16. Witcolate 7093 (RM 45666) 17. Triethanolamine 18. Urea == 19.Triton X-305 tems 110 10 are froma list given to Eric Reiner by Wim Vanneste 3/12/90. ltems 11 + 1013 were given fo theauthorby Wim Vanneste 2/5/91. ltems 14 to 16 were given to the author by Roger Alm (2/4/91). IV. Conclusions and Recommendations. Inorderto correlate thetoxicityof the product to the toxicity of individual components, the component concentration is taken into consideration. In the table below, the toxicity to Daphniaof the pure components are given in the third column. The fifth column contains estimated toxicities based on product formulation. This is the toxicity which would be expected when the component is diluted in waterto the same concentration as in the product. For `example, one would expect that since the toxicity of pure butyl Carbitol is about 700 mg/L, the toxicity of asolution made of 35% butyl Carbitol and 65% water would haveatoxicity of about 2,000. `Some interesting observations can be made from these numbers. First, even though tolyltriazole is quite toxic, itis present at low concentration in the product and when diluted in the product it probably does not contribute substantially to product toxicity. However, this analysis does not exonerate tolyltriazole as a major contributor to product toxicity. Second, the lowest numbers in the fifth column indicate components which will be the most likely contributors to product toxicity: butyl Carbitol, Duponol ME (dodecylsulfate), the foamer, and the filmer. Unfortunately, thera is not asingle component which stands out with a number in the fifth column which is substantially lower than all the rest, This may mean that there isa. synergistic effect between components. -6- 000854 : Tan Name Ep mgahr pone gr 5 Formmietre Em 7. Need pa "fom Ye `Summary of Recent Daphnia Toxicity Data BETony FomoRamnin Corp Tofely om 200% Seo 708 281.00) asa 2a 2023-35 oo 200 ) oon wom wo-on I) 200% Lo 2a Toon ser 51700-1000) som vem So 229 50-444) Es ses - MarCoot Provatty ot Protatty Prtatty Probetty ot Probably Pratt Proatiysot o x x `The impo~rtant conclusion from these Daphnia results is tBo hat a more complete setof:toxicity > dtoatcaomisplneeteadetdh,e eesnpveicrioanlmleynftoarlalegffaeec.tTshdeattaabbalesebeolnoowusrupmrmoadruictzsesantdhethaedidritiinognraeldideanttas.needed 3 Additional tests are indicated with an X. 2 Preliminary results from EnviroSystems, March 10, 191. 7- } 000855 j `Summary of Additional Testing vam eo Fe owner T PR BTasT xx opr xx rset T wy xx rBaor xx Bme e -roo0 x x - 7. UNasES sso x x rRoTw - roms x 10. Vuitecee Fozus x x rRoomsmo x rome x & romeo xx 14. FC-206CF x x Lew xx rT xx 7 (TRiMe4t56a6r6a)ios = Thonn xx Tom 0 om:500 nigwl ke, 10, rd20 or. x - x x x: TA xx x x x x\ x x v 7 oo so xx xx xx x x x x - \ XT x Xx x ' xx xx sw .8- . 000856 3 V. Environmental Effects Literature Search Data from previous 3M Environmental Laboratory Studies and from the literature are `summarized in this section. Toxicity data noted by "AQUIRE" were obtained from a search of the USEPA AQUIRE database on Feb. 12, 1991. Included as part of the reference for the data from AQUIRE are the date of publication of the original joumal article and the review code established by a group of EPA reviewers. The reviewers have ranked toxicity data from the literature by the following scale: 1. Meets all review criteria. 2. Procedures generally satisfactory. __ 3. Insufficient in some area of the test methodology or test report. 4. Abstractorforeignpaperwith data in limited format. The complete contents of the AQUIRE database for each chemical is not given in this report because the database includes many obscure species of litle interest (opossum shrimp, Indian catfish, snakehead catfish, oysters, clams, sponges and many others) and data which Is considered by the EPA reviewers to be of questionable value, Additional degradability and toxicity data have been taken from the Handbook of Environmental Data on Organic Chemicals by Karel Verschueren (Nostrand Reinhold, New York, 1983). These are referenced by page number in the Handbook followed by the date of the original reference. There are many cases in which the same data appeared on AQUIRE and in Verschueren but only the AQUIRE reference is given because it includes the EPA quality rating of the original reference. Raw material suppliers were identified from the 3M PRISM database and suppliers were contacted and asked for any environmental data they have. Unfortunately, environmental data `was not generally available from raw material suppliers. And, the suppliers were siw in sending the limited data do have. x . The source and reliability of the literature data was taken into consideration in the 5 environmental assessment of the components and the recommendations for further testing. BIenfpoornmtatFioornmafotr:each component or formulation is organizedasfollow-s: - Formulationor component name and RM number Chemical Abstracts Service (CAS) Number Vendors Degradability data from the literature or from previous 3M assessments Aquatic Toxicity data from the literature or from previous 3M assessments Environmental Assessment Recommendations for Additional Testing - -e- 000857 he . Detailed information for components and formulations are given in the same order as in the list above. . 1. Ethylene Glycol (RM 3017) CAS #1072141 Vendors;CUhneimotnecCha,rbAisdhe,laTnedxtCihleemCihceamli,caDlo,wAsChhleamnicdaClh,eTmiecxaalc,oUCnhoecmailcal, Olin, Shell Oil, "Degradability: "Theoretical Oxygen Demand (ThOD) 1.29 gig (Verschuerenp 646) BOD; 0.4410.22 g/g (avg of 12 citations from Verschueren p 646) 0.529/g(Env. Lab.* Req. #1940) BOD; 0.67 g/g (Verschueren p 646; 1953) 1.19 g/g (Env. Lab. Req. #1940) BOD,s . BOD, 0.92 g/g (Verschueren p 646; 1953) 1.14 g/g (Env. Lab. Req. #1940) 1.00:+0.08 g/g (avg of 3 citations from Verschueren p 646) 1.02 g/g (Env. Lab. Req. #1940) co-o 1.24f1r0o.m0V4egr/sgch(auvegreonf 3p c6i4t6a)tions > 1.28 g/g (Env. Lab Req. #1940) . BOD,/COD Ratio BOD,,/COD Ratio ~ 0.4 (Env. Lab Req. #1940) 0.8 (Env. Lab Req. #1940) Toxicity:* Green Algas (Scenedesmus quadrica-uda) 7-day Static Popul. Growth Inhib. 8-day static Popul. Growth Inhib. : 10,000 mg/L (AQUIRE 2; 1980) 10,000 mg/L (AQUIRE 2; 1978) 3 3M Environmental Lab work done in Dec. 1973. 4 The toxicity data are a partial listingof38 tests on 16 species from the EPA AQUIRE -- database. 5 Population Growth Inhibition: Change pre-exponential lag rate effects. in cell number of algal species including "10000858 Protozoa (Entosiphon sulcatum) 72-hr Static Popul. Growth Inhib. Blue-green Algae (Anacystis aeruginosa) 8-day Static Popul. Growth Inhib. Bacteria (Pseudomonas putida) -Algae (Microcystis aeruginosa) Protozoa (Uronema parduczi) Water flea (Daphnia magna) 10,000 mg/L. (AQUIRE 2; 1980) 2,000 mg/L (AQUIRE 2; 1978) >10,000 mg/L (Verschueren p 647) 2,000 mg/L (Verschueren p 647) >10,000 mg/L (Verschueren p 647) 2484--hhrr SSttaattiicc ELCCy,, >110,,000000 mmgg//LL ((EAnQvUiIrRoSEy2s;te1m9s771)991) = 24-r Static LCq, 10,000 mg/L (AQUIRE 3; 1983) 48-hr Static LC, 10,000 mg/L. (AQUIRE 3; 1983) Brine shrimp (Artemia salina) Lo 24-hr Static LCs, 20,000 mg/L (AQUIRE 2; 1974) 24-1 Static LC 20,000 mg/L (AQUIRE 3; 1983) Fathead Minnow (Pimephales promelas) 24-hr Static LCs, 10,000 mg/L (AQUIRE 3; 1983) 48-hr Static LC, 10,000 mg/L (AQUIRE 3; 1983) 96-hr Static LCs, 10,000 mg/L (AQUIRE 3; 1983) 96-hr Static LCs 49,000 mg/L, 53,000 mg/L, & 57,000 mg/L (AQUIRE 2; 1983) Bluegill Sunfish (Lepomis macrochirus) : 96-hr Static LC, 10,000 mg/L (AQUIRE 2; 1968) Rainbow Trout (Samo gairdner) 96-hr Static LCs, 41,000 mg/L (AQUIRE 2; 1980) - Common Shrimp (Crangon crangon) 48-hr Renewal LCs, 100,000 mg/L (AQUIRE 2; 1974) 96-hr Renewal LCy, 50,000 mg/L (AQUIRE 2; 1974) Goldfish (Carassius auratus) N 96-hr Static LCs o 5,000 mg/L (AQUIRE 2; 1979) Guppy (Poecila reticulata) 7-day Renewal LCs, . 49,300 mg/L (AQUIRE 3; 1981) : - 6 Acute Daphnid toxicity testing done by EnviroSystems for 3M. Test results dated March 10, 1991. S11. . 000859 EnEvtihyrloennmeegnltyacollAshsaessisnsmiegnnitf:icanttoxicity and a high BOD/COD ratio. Even though itis present in high concentration in the product, it probably does not contribute substantialltyo pRercoodmumcetntdoaxitciiotyn.s for Addional Testing: None. 2. Butyl Carbitol (RM 8887) CAS# 112:34-5 (Diethylene Glycol Monobutyl Ether) ~Synanodvenndyorsm:BustylDioxitol (Cain Chemica, Poly-Solv DB (Olin Corporation), Glycol Ether DB (Oxychem), Butyl Carbitol (Union Carbide Corporation - Linde Div.), Butyl Dioxitol (Shell Oil Company), Dowanol DB (Dow Chemical), Ektasolve-DB (Eastman Chemical Products, Inc.) Degradability: ThOD BOD, . BOD, BOD, BOD, cop BOD,/COD Ratio BOD,/COD Ratio - 7 217 gig (calculated) 0.25 (Verschuaren p524) 0.69 g/g (Env. Lab." Req. #1940) 1.45 g/g (Env. Lab. Req. #1940) 1.61 g/g (Env. Lab. Req. #1940) 1.66 g/g (Env. Lab. Req, #1940) 2.08 (Verschuerenp 524) 1.83 g/g (Env. Lab. Req. #1940)? * . 00..3172 ((VEnevr.scLhaube.rReenqp. 5#2149)40) co 0.85 (Env. Lab. Req. #1940) Toxci wo - Bacteria (Pseudomonas putida) 255 mg/L (Verschueren p 524) 7 3M Environmental Lab work done in Dec. 1973. 8 The toxicity data are a partial listing of 15 tests on 10 species from the EPA AQUIRE a database. -12- - 000860 Green Algae (Scenedesmus `quadricauda) 7-day Static Popul. Growth Inhib. 8-day Static Popul. Growth Inhib. 1,000 mg/L. (AQUIRE 2; 1980) 1,000 mg/L (AQUIRE 2; 1978) "7 Blue-8g-rdeaeynSAtlatgiaceP(oApnualc.ysGtrioswtaherIunghiinbo.sa) 53 mg/L (AQUIRE 2; 1976) Protozoa (Entosiphon sulcatum) 72-hr Static Popul. Growth Inhib. ~~ 73 mg/L (AQUIRE 2; 1980) Protozoa(Uronemaparduczi) 420 mg/L (Verschueren p 524) Protozoa (Chilomonas parameciurm) = 48-hr Popul. Growth Inhib. 2,774 mg/L (AQUIRE 4; 1980) Water Flea (Daphnia magna) 48-hr Static EC, 706 mg/L (EnviroSystems 1991) 24-hr Static LCs, 2,850 mg/L (AQUIRE 2; 1877) Bluegill Sunfish (Lepomis macrochirus) 96-hr Static LCyy 1,300 mg/L (AQUIRE 2; 1877) Goldfish (Carassius auratus) _ 24-hr Static LCs, 2,700 mg/L (AQUIRE 2; 1979) Guppy (Poecila reticulata) : 7-day Renewal LCy, 1,150 mg/L (AQUIRE 3; 1981) Silver ide (Leuciscus idus) 1,805 mg/L and 2,304 mg/L. Static LCs, (AQUIRE 3; 1978) Inland Silverside (Menicia berylling) ~ 96-hr Static LCyy 2,000 mg/L (AQUIRE 2; 1977), EnBvOiDrodnamteansthaolwAsssfeaisrslymheingth;degradability. The literature data show this material to have Co insignificant toxicity to fish and Daphnia. The two freshwater green algae values from AQUIRE are consistent and indicatethatbutylCarbitol is practically non-toxic o green algas. There is considerably more toxicity shown to blue-green algae, however. We should ~ johave a sample4of butylCarbmitooltnestledyfor algal toxicity to be sure of is toxic effects. `Algae and Microtox. 13-4 - 000861 ' 3. Duponol ME Dry Surfactant (RM 3021; Sodium Laury! Sulfate) CA#S 151-213 (Sodium Dodecylsulfate CH,(CH,),,0SO;Na) Vendor; Dupont Degradabilty; ThoD 2.03 g/g (calculated) BOD Swisher" reports that "linear primary alkyl sulfates have long been = recognized as extremely rapid in primary biodegradatior, often disappearing in less than a day" and cites approximately 100 references `which show degradation rates of80 to 100% within a few hoursor days. Toxicity: Green Algas (Chlorella sp) Static Popul. Growth Inhib. 50 mg/L (AQUIRE 4; 1980) Green Algae (Chlorella vulgaris) *. 72-hr Static Growth Inhibition' 0.05 mg/L (AQUIRE 4) Green Algas (Scenedesmus quadricauda) 7-day Static Popul. Growth Inhib. 8-day Renewal Growth Inhibition 0.02 mg/L (AQUIRE 2; 1980) - 0.02 mg/L (AQUIRE 2; 1978) Flageliate Euglenoid (Entosiphon sulcatum) 72-hr Static Popul. Growth Inhib. ~*~ 40mglL (AQUIRE2;) iL > . Blue-green Algae (Anacystis aeruginosa) 8-day Renewal Popul. Growth Inhib. 7 mg/L (AQUIRE 2; 1978) Bacteria (Pseudomonaspufida) Call Multiplication Inhibition 290 mg/L (Verschueren p 793; 1980) Protozoa (Uronemaparducz) - Cell Multiplication Inhibition 0.75 mg/L (Verschueren p 793; 1980) 9 Phone: 302-774-1000. 2/15/91: will send information. 10 Swisher, 807-811. R. D.Surfactant Biodeg2nrdead.d MaracetlDiekkoern ;Ne.w York, 1987, p 466,-- 11 The toxicity data are AQUIRE database. a partial listing of the 409 tests on 49 species from in the EPA 12 Growth Inhibition: Measurable change in length and/or weight. 14. 000862 Water flea (Daphnia magna) 48-hr Static EC, 2.9 mg/L (EmviroSystems 1991) 24-hr Static LC4 24-hr Static LC, 33.0 mg/L (AQUIRE 2; 1977) 7.2,10.0, & 12.0 (AQUIRE 3; 1983) TT 48-hrStaticlCy . 7.02.1 mol (avg of 8; AQUIRE 2; 48-hrStaticLCy 1982) 5.00.5 mg/L (avg of 3; AQUIRE 3; 1983) 48-hr Flow-through LC, 1.8 mg/L (AQUIRE 2; 1981) Fathead Minnow (Pimephales promelas) 24-hr Static LC, ~ 48-hr Static LCy, 7.4& 8.5 mg/L (AQUIRE 3; 1983) 6.6&7.3 mg/L (AQUIRE 3; 1983) 96-hr Static LCs 6.68 6.9 mg/L (AQUIRE 3; 1983) Bluegill (Lepomis macrochirus) . 96-hr Flow-through LCs, 4.5 mg/L (AQUIRE 2; 1981) : Mummichog (Fundulus heteroclitus) . 96-hr Static LCq 2.1 mg/L (AQUIRE 2) Sheepshead Minnow (Cyprinodon variegatus) 24-hr Static LCy, 10.0 mg/L (AQUIRE 2) 48-hr Static LCy, : 96-hr Static LCy, 9.0 mg/L (AQUIRE 2) 9.0 mg/L (AQUIRE 2) High-eyes Medaka (Oryzias latipes) 6-hr Renewal LC, 67 mg/L (AQUIRE 2) 24-hr Renewal LC, _. 48-hr Renewal LCq 46 mg/L (AQUIRE 2) 46mg (AQUIRE2) > Brine Shrimp (Artemia salina) 24-r Static LCs #: 3.6 mg/L (AQUIRE 2; 1674) Co Atlantic Silverside (Menidia menidia) 96-hr Static LCs - 2.8 mg/L (AQUIRE 2; 1982) Killfish (Fundulus similis) 24-hr Static LCy : - _ 4.7 mg/L (AQUIRE 2) 48-hr Static LC, 4.7 mg/L (AQUIRE 2) 96-hr Static LCy, 4.5 mg/L (AQUIRE 2) Rainbow Trout (Salmo gaircner) 48-hr Flow-through LCs, 96-hr Flow-through LCy 5.95 mg/L (Verschueren p 763; 1977) 4.62 mg/L (Verschueren p 73; 1977) 10-day Flow-through LCs, 2.85 mg/L (Verschueren p 793; 1977). 15 . - 000863 Zebrafish (Brachydanio rerio) 48-hr Flow-through LCs, 96-hr Flow-through LCy 10-day Flow-through LCs, "" Fagfi4s8h-h(rGoFrldoawn-etlhlraoufglhorLidCae,) 96-hr Flow-through LC, 10-day Flow-through LC, 8.81 mg/L (Verschueren p 73; 1977) 7.87 7.97 mg/L mg/L (Verschueren (Verschueren p p 73; 793; 1977) 1877) 10.0 8.10 mg/L mg/L (Verschueren (Verschueren p p 793; 793; 1977) 1877) 6.90 mg/L (Verschueren p 793; 1977) [LEintveirartounrmeednatatlaAisnsdeicsastmesenfatir;ly low toxicity to bacteria and although no actual BODtestdata __are available, this material `should be obtained by our should be own BOD readily tests. degraded by microorganisms. A BOD value `dTahtias amagtreereisalweilslmowidtehraltiteelryattuorxeidcattoafwishhi,cDhapgihvneisa,usancdonafligdaeen.cOeuirn tmhoestcornetcreanctt lDaabpohrantioaryt'esst work on this material. testing is warranted. Because there is sufficient fish toxicity data from the literature, no fish Becauseof the algal toxicity shown in the literature data, algae testing should be done. aEdvveenrtsheoeufgfhectthsiwsilmlatbeerimailniismtaolxiifcittoisapvaasrsieetdytohfraoquugahtiacwoarsgtaenwiastmesr, titrereaatdmielnytdseygsrtaedmesoranifda Wsiegnisfhiocuanltdnduomsboermeofsmtuidcireosoringawnhiiscmhsoaurrepprroedsuecnttisinpaasnsaetusratlhrwoaugtheatro mdoedgerlawdaesitterwapaitdelry. twroeualtdmebnetasyssimtuelmatainodn tohfeamneaatusruarlebtohdeytoofxiwcaetfefrecutssionfg tahneamqoudaerli'usmefsftiouecnkte.dAwniotthhfeirshs.tTuhdiys ~~ wAould give us a" n understandioraling oTfetshieindge:gradation in a river, pond, or lake. 3' BOD, COD, and Microtox. 4. Tolyltriazole (RM 27513; Corrosion Inhibitor Tolyltriazole Technical Grade) CAS#C2o03t8o5,-43-1 - O[r3 i y `SyMenthayoln-d1nHv-yeBnednmozrostsr:iazole -16- 000864 | Methylbenzotriazole Cobratec TT-100 (PMC, Inc.) Preventol CI7-100 (Mobay Corp.TM) DegrBadOabDility: Toxicity: Water Flea (Daphnia magna) 48-hr Static ECs, Bluegil Sunfish he . 96-hr LCs, Rain9b6o+whrTrLoCust, Fathead Minnow 96-hr LCs, Add1iH-tBiednoaztonatrafiolarzaolseim(iCleaHrcNoy)mpound: * CAS Number: 95-14-7 Synonyms: 1,2,3-Benzotriazole Aziminobenzene Benzene Azimide "" Benzotriazole - Bluegill sunfish (Lepomis macrochirus) Static 24-hr Stress Rainbow Trout (Salmo gairdner) Static 24-hr Stress Sea Lamprey (Petromyzon Static 24-hr Stress marinus)" Chinook Salmon (Oncorhynchus tshawytscha) Static 24-hr Mortality <60% ThOD (Mobay Corp.) 19 mg/L (EnviroSystems 1991) 31.0 mg/L (Mobay Corp. and PMC) + 21.4.mg/L (Mobay Corp. and . PMC) . 25,5 mg/L. (Mobay Corp. and PMC) oy!W x. Hr . #- 6 mg/L (AQUIRE 3; 1957) 5mg/L(AQUIRE 3; 1957) 5 mg/L (AQUIRE 3; 1957) 10 mg/L (AQUIRE 3; 1969) 5 - 13 PMC Specialities (513-242-3300). Group, Inc. Technical Bulletin 3200. Contact: Bill Mautiewicz 14 Mobay Corp. data given by Matthew Bartman 412-777-2000. -17- 000865 Ca CohoStSaatilcmo24n-h(rOnMcorotrahlyitnychus Kisutch) 10 mg/L (AQUIRE 3; 1969) L_ NortShteamtiScq2u4a-whfriMsohrt(alPittyychocheilus oregonensis) 10 mg/L (AQUIRE 3; 1969) EncWvohniicrleeonnttmhreaetnlitiomanilt(Ae0ds.sd0ea5ts%as)msiehnnottwh:esptrhoadtutchti,s imtamtearyiahlaivsemloidtteleraeftfeelcyttionxitch,eoivtiesraplrletsoexnictitayt osfucthhelow nproodruecats.onBatcoaruespeeaotftthheeftiosxhicdiattyao,fhtohwisevmearte.rial, we need a complete setofdata. There is ThUiSsEPmAat.erial s listed on theTSCA 8(d) list and any testing done must be reporttotehde BOD, COD, algae, and Microtox. 5.TFooxiacmiteyr: (FM-4115) Wate4r8F-lherSat(aDtaipchEniCa,magna) 68 mg/L (EnviroSystems 1991) Ee`nTnvhvieirrfooonnammmeeennrttaasllhAofsfwesscetssslsi.gmWhetentotxs:ihcoiutlydtohDaavpehanicao,mpblutettehesreetiosfneoffdeacttas dfoarttahfeorrtehmiasimnaitnegria. bCreaeprureessseefdnitoiaunlttdihvbeeefsutatamukrpeel.netwhahticthhehsaasmbpeleenupsreoddiunctehdebeyntvhiermoannumfeancteufrfiencgtsmteetsthiondg wihaigchoowidll : B h " ih BOD, COD, fish, algae, and Microtox. 6.rFilmer (FM2-s3820 or FC-95) - BOD, nil (PED) BOD, nil (PED) BOD, nil (PED) cop nil (PED) BODICOD -- Toxicity: -18000866 Vv 4 Water Flea (Daphnia magna) 48-hr Static EC 48-hr Static EC, 49 50 mmgg//LL ((EPnEvDi)roSystems 1991) _. _ Activated Sludge Inhibitory Conc. >4,000mg/L (PED) Fathead Minnow (Pimephalespromelas) 96-hrLCy 38 mgiL (PED) Bluegill Sunfish (Lepomis macrochirus) 96-hr LCqy 68 mg/L (PED) Rain9b6o-whrTrLoCuyty(Salmo gairdner) 11 mg/L (PED) "EnTvhierofnilmmeenrtwialll Anostsceosnstrmiebnutte:to the BOD/COD ratio, so toxicity is the Issue wi:th this acogmrpeoenmeenntt.bTehtiwsemeanteprrieavlidouosesansdhoprwessleingthtDtaopxihcniityattooxificsihtyanddatDaawphhinciha.giTvheesruesIscognofoiddence in the most recent data from EnviroSystems. Wmaanunfeacetdutroinhgavloetawhciocmhplheatsebseeetnofprefofdeucctseddabtyaftohre amasnaumfpalcteurreipnrgesmeentthaotidvwehoifcah rwielclebnte Bused in the futuyre. Testing: Algae and Microtox. 7. Ne-octylsulfate (RM 32067 or RM 55040") CA#S 142-314 - 1i2 Vendors: Alcolac Incorporated (POLYSTEP B-29). (Sodium Octyl Sulfate Solution); Stepan Company 5 Degradability: ThOD 1.88 g/g (calculated) - : " 15 16 Wim Vanneste's PROFS note dated 03/12/1990 Alcolac: 301-355-2600. No data available. gives this RM. 17 Called 708-446-7500 ext. 2283: they have no data. "19- : | 000867 `i . BOD Swisher reports that "linear primary alkyl sulfates have long been irnecleosgsnitzheadn aasdeaxyt"reamnedlycirtaespiadpipnropxriimmaartyelbyio1d0e0grraedfaetrieonnc,esofwtheincdhissahpopwearing degradation rates of80 to 100% within a few hours or days. Toxicity Australian Barnacle (Elminius modestus) 30min Static Immobilization EC, 3,970 mg/L (AQUIRE 2; 1976) Water Flea (Daphnia magna) 48-hr Static ECy, 517 mg/L (EnviroSystems 1991) EAnlvtihrooungmhennotaBlOADssoersCsmOeDndta;ta are available, this material will most likely have a high BOD/COD ratio. BOD and which have been obtained COD data should be obtained sothatwe in tests comparable to those usedforthe have numerical remaining values components. `hTohweereveisrsfuorrptrhiesiDngalpyhlniitlae dlaittearaittusrhe odwatsacaovnasiildaebrlaebolyn ltehsesatqouxaictiitcyttohxaicnittyheofCth1,isssuurrffaaccttaanntt., This surfactant is present at algae, and Microtox toxicity 3% so it data are may be a majorfactorto essential to complete the toxicity of the product. assessment of this Fish, iAngredient. " Testing: BOD, COD, fish, algae, and Microtox. 8. Di-water (RD 199) : . - . Todt: ' 3 Water Flea (Daphnia magna) 48-hr Static EC, ~~ >1,000 mg/L (EnviroSystems 1991) EWnhviilreonitmmenatyasleAesmsefsooslmieshntto:test the deionized water for toxicity, foxic effects have been -- tthraatcetdhetosucpopnltyamwiansatneodt dceoinotnaimziendawtaetdearnsdupnpolifeusrtihnerthteesptaisntg.ofThteheDdaepihonniiazerdeswualtteirndsiacmaptelse is warranted. None. 18 Swisher, 807-811. R. D. Surfactant Biodeg2nrdea d,Mdaracet lDeikkoern :Ne,w York, 1987, Pp 466, 19 There was 1 test given in the EPA AQUIRE database. -20- - 000868 wi . 9.FC-203 Degradability: BOD, | 560 g/L (PED) 717g/L (GeArrmym RepaortnTM) BOD, cob = BODYCOD 1,060 g/L (PED) 1,070 g/L (PED) 1,373 g/L (German Army Report) 0.52 (PED Report) and German Amy Toxicity: Microtox EC, . 632 mg/L (German Army Report) ECs 2,500 mg/L (German Army Report) Activated Sludge Inhibition none at 1,000 mg/L (PED) Algaean(dChPlhoroerlmliadpiyurmenioniudnodsaatum) no effect at 1,000 mg/L (PED') . liga (Scenedesmus subspicatus) ~ 72+hr Static Popul. Growth Inhib. EC 72-hr Static Popul. Growth Inhib. EC, 16.9 mg/L (German Army Report) 160:mg/L (German Army Report) Wat- e2r4F-lheraSt(aDtaipchEniCa,magna) . * 31.6 mg/L (German AmyReport) 24-hr Static EC, 48-hr Static EC, 430 mg/L (German Army Rport) ; 229 mgAL (EnviroSystams 1991) 5 48-hr Static EC, 1,600 mg/L (PED) 2+ 0A3rm%yaRpepploircta.tiTohnesoGleutrimonasn" Awerrmeyuvsaeldutesowoebrtaein41`,th2e0B0OmDg/,LaannddC2O1,D50d0atmagi/nLtfhoerGtheermCaOnD and BOD, respectively. in this report. The German Army values were multiplied by 33.3to get the values 21 22 TEensvtiirnogSdyostneembsyisInrdeupsetartiailngBitohi-sTetsetstLbaebocraautsoeryt,heJraen.w1a9s74n,ot enough variation in the oo FC-203 23cToenscteinntgradtoinoensbtyheByiuosneodmictosdLeavbeorlaotporayg,oDoedc.st1a9n7d3a.rd curve. 21 000869 wd . Eastem Oyster Embryo-larvae 47 mg/L (PED) (Crassostrea virginica) 48-hr Static ECyy -._ Grass Shrimp (Palaemontes pugio) 96-hr Static LC, 510 mg/L (PED) Fathe9a6-dhmriSntantoiwc L(CPsi,mephales promelas) 750 mg/L (PED) Zebrafish (Brachydanio rerio) 48-hr Static LC, 48-hr Static LCq, 1,053 mg/L (German Army Report) 1,634 mg/L (German Army Report) -- Scud (Gammarus fasciatus) 48-hr Static LC, 1,100 mg/L (PED) Rainbow trout (Oncorhyncus mykissTM) LT 96-hr Static LC, 1,300 mg/L (PED) : Rain9b6o-whrtrCoountt(iOnnucoourshFylnocwusLmCysk,iss) 400 g/L (PED?) Common mummichog 96-hr Static LC, (Fundulus heteroclitus) 2,500 mg/L (PED) . Grass96ShhrriimCpy(Palaemonetes pugio) 510 mg/L (PED) En1v. iTrhoenfmieshnttoaxliAcistsyedsastamefnrotm:the German Army Report agres well withdatafrom 3M studies, so no fish testing is needed. previous : 2n.otThbee Mriecpreoattoexd.tests from the German Army Report : seem - reasonable,sothis WL te&fshould > = 3E.CyT,hefr2o4m-htrheEGCe,rmDaapnhAnrimaytoRxeicpiotrytfraorme tinhefamirolsytgoroecdeantgrEenevmiernotS.ysHtoewmesvewro,rkwaenwdetrhene'4t8-hr satisfied with the concentrations used in the EnviroSystemsworkand they are repeating -- 2254TTeessttiinngg ddoonnee bbyy BBiioonnoommiiccss LLaabboorraattoorryy,, AJuulgy.11998709.. 26 27 Testing done by Formerly Salmo Bionomics gairdneri. Laboratory, Dec. 1973. 2298 TNeostmionrgtadloitnyeorbyabBnioornmoamlicesffLeacbtosraattotrhiys,cAoungc.en1tr9a7t9i.on. -22- i -' 000870 btehisdwuoerkt.o fTohremullaartgieondicfhfearnegnecse boretcwheaenngeGserinmtahneAtroxmiycitvyatleuset aprnodtotchoelb1u9t7t3hiPsEcDanvnaloutebmeay verified. t4e.sAtisngwiitshotfhkenfoowanmecromapnodsiftiieorn,awnde fnreoemdatokbneowcnarmefaunluftahacttutrhiensgalmotp.le submitted for 5. Since toxicity to `probably the most algae was important. of concenin the German Army Report, the algae data is _BBODe,cCOoD,manmdealfgnoaer.dAddaititonail Toesntinsg: 10. VW160390 (FC-203 without Tolyitriazole RM 27513) Water Flea (Daphnia magna) 48-hr Static EC, 165 mg/L (EnviroSystems 1991) En1v. iSrionncametnhteaolnAlsysdiefsfsemreenncte:between this material and FC-203is tolytriazole, testing this material along For the recent with FC-203 seems Daphnia data, there like a good way to determine the effect is little difference between FC-203 and of tolyltriazole. VW160390 and tthheaneftfheecttoofxitcoiltyylotfriVazWo1le6c0a3n9n0otinbtehseereenc.enItn fEanctv,irthoeSytosxtiecimtsywoofrFkC.-S2i0n3cewEansvsilrioghStylsytleemsss is creopmepalteitnegdtthheeDseatepstshfboenrftoihreesameaktiwnogsaamnpelveasl,uawteionwi.ll have to walt a until EnviroSystems Sr has > 2c.oAmpMaircerdottooxtahnedFCfi-s2h0t3oxirceistuylttessttossheoeuilfdtbheerdaoinseaomneathsiusrmaabtleerieaflfeacntdctahueseredsublyts 3 tolyliriazole in the product. - BOD, algae, fish, and Microtox. 30 EnvirdSystems is repeating concentrations they used to this test develop because there was not a good standard curve. enough variation in the .23- . 000871 a . 11. FC-203CE BOD, BOD, BOD, cob BOD,/COD ratio __ Total Organic Carbon (TOC) OECD Method 301E 91 g/L (PED) 400 g/L (PED) 680 g/L (PED) 762 g/L (PED) 0.89 (PED) 220 g/L (PED) 88-90%biodegradability in 14 days (PED) Toxicity: Algae (Selenastrum capricornuturm) 95-r ICs >1,000 mg/L (PED) OECD Activated Sludge Inhibition Test 209 Respiration ~. none at 1,000 mg/L. Water Flea (Daphnia magna) - | 4g-hrStaticLCyy 1,000 mg/L (PED) Microtox (Photobacterium phosphoreum) Exposure: 5 min. ECy 370 mg. 15 min. 30min 226300 mmgg//LL. ": - Killfish (Fundulus heterociitus) 96-hr Continuous Flow LC, 1,400 mg/L (PED) 1 Fathead Minnow (Pimephales promelas) 9966--hhrr CStoanttiicnLuCouys Flow LC, 2,000 mg/L (PED) >1,000 mg (PED) - EnTvhiereonnvmiernotnamelnAtsasleesfsfmecetnstd;ata for F- C-203CE Is fairly complete. T`AhremyPREeDpodrattaansdhofwrosmltohweerrteocxeicnitttyetsotsDbayphEnnivairtohSaynsitsemssh.owDnapbhyniFaC-te2s0t3inign sthhoeuGled rbmeadnone B`again for assur"ance in our iPED. . Algae and Daphnia. . 24 . 000872 12. FC-206CE BOD, BOD, BOD, cop BOD,/COD ratio __ Total Organic Carbon (TOC) OECD Method 301E 46 g/L (PED) 260 g/L (PED) 470 g/L (PED) 402 g/L (PED) 1.2 (PED) 130g/L (PED) 89-92% biodegradability in 14 days (PED) Toxicity: Agas (Selenastrum capricornutum) 1,000 mg/L (PED) 95-r ICs OECD Activated Sludge Respiration none at 1,000 mg/L. Inhibition Test 209 Water Flea (Daphnia magna) - 48-hr Static LC, 1,000 mg/L (PED) Microtox (Photobacterium phosphoreum) Exposure: 5 min. ECs :- 650 mg/L 15 min. 4500 mgiL. : - 30 min 4200 mg/L. w- Killfish (Fundulus heterociitus) 96-hr Continuous Flow LCs, 2,000 mg/L (PED) Fathead Minnow (Pimephales promelas) 96-hr Continuous Flow LCs, 2,000 mg/L. (PED) E 96-hr SAtatic LC : >1,000 mg/L. (PED) R`ABTghaeine,nvtihreoPnmEeDncdftdaalteafsfehcotwssdaionlal toawftooTrxeiFsctCiit-yn2gt0:o3DCaEphisnifaairwlhyiccohmpslheotuel.d be verified. Algae and Daphnia. w . .d - .25- 000873 13."EFnCvi-r2o0nm3eCnFtal Assessment; No environmental effects ata for this environmental effects data should be product are obtained. available and a complete set of BBOeD;cCOoD,malmgaee,fDnoarpAdhdndiaiat,itofnisiahl,ToeasntndiMnsigc:rotox. 14. FC-206CF EnNvoirenovnimreonntmeanltAaslseefsfsecmtesndta:ta for this product are available and a complete set of "environmental effects data should be obtained. . RBeOcDo,mmCeOnDd,atailgoanes,fDoarpAhdndiiat,iofnisahl,TeasntdinMigc:rotox. - 15. L-4640 (New Foamer) Testi1n.gDiaspchunrieanttloyxiucintdyesrtwuadyy f(Co2arEEEuCrotpesetanmePthMoNd)b.y NOTOX Laboratories: 2. 3: Fish toxicity (C1 Modified Sturm method) test (C5) fuosrirnegaZdeybbriaodfeigsrhad(aBbrialcihtyy.danio rerio). Alltesting for the European PMN is being done by GLP. `Tchoempfiolleldowiinntgheenrveiproorntm"eEnntvailreofnfmeecnttsadlatDaataareanfrdoImnsfeovremartailo3nMintSecuhnpicpaloorfertphotertPs MwhNicfhorare Certain Chemical Substances Designated as L-4640", June20, 1880. bY > Degradabilty: Co BOD; <0.038 g/g BOD, - <0.038 g/g BOD, cop - <0.038g/g 0.41 gig - Tesi Theoretical Oxygen Demand 075g/g Acute Effect on Microbial Respiration Water Flea (Daphnia magna) 48-hr Static LCq Fathe96a-dhMriSntantoiwc L(CPqi,mephales promelas) 8% dreepdluecttiioonn aitn 1r,at0e00ofmogx/yLgen 100 mg/L and 111 mg/L 158 mg/L and 166 mg/L 26 0008/4 EnBveicraounsmeeonfttahleAismspeosrstmaencnet;of this material to future products, a full set of environmental effects data is needed. The theprevious studies should environmental effects data not included be obtained: algae and Microtox. in the PMNwork or in BAlgeapcanod mMicmroteoxf.nordAddaititonialToestninsg: 16. Witcolate 7093 (RM 45666) CAS#73665-23-2 "5Wi5t%cowaCtoerrp,or4a5ti%onC6(-7C131-043e3t-ho7x2y8l1a)thedassunlfoateec.oTtohxeyinrfeorcmoamtimoennadveaidlaSbwlies.hWeitrcfoolrate7093 is biodegradation information. . No information on EPA AQUIRE database nor in Verschueren. EnNvoirefofnemctesndtaatlaAisssaevsaislmaeblnet.;Testing depends on the likelihood that this material will be used in future products. BCOeD;cBOoD,malmgaee,fnfoisrhd,AdDdaaipthtinoiniaal,ToaesnntdiMnsigc:rotox. 17. Triethanolamine z CAS #102-71-6 Degradabilty:" ThOD BOD, BOD, BOD, BOD, SL i": . 5 2049/g nil -< 0.02 g/g with standard seed 0.17 g/g adapted sewage - 0.039/g 0.029/g nil with std. diluted sewage 0059/g 0.13g/g 31 All degradabilty data are from Verschueren p 1150-1. 27-4 000875 cop BOD,COD BOD,/COD 1.50 gig nilt0.0.11 0.09 Toxicity: Bacteria (Pseudomonas putida) ~ Popul. Growth Inhib. >10,000 mg/L (Verschueren p 1151) Algae (Microcystis aeruginosa) Popul. Growth inhib. 47 mg/L (Verschueren p 1151) _ Gree7n-AdlagyaSsta(tSiccePnopeudle.sGmruoswqtuhadInrhiicba.uds) 1.8 mg/L (AQUIRE 2; 1980) 8-day 8-day Static Static Popul. Popul. Growth Growth inhib. Inhib. 71.185mmgg//LL((AAQQUUIIRREE22;;11597788))" Blue-green Algae (Anacystis aeruginosa) 8-day Static Popul. Growth Inhib. 19:mg/Land 47 mg/L . .* (AQUIRE 2; 1978) Protozoa (Entosiphon sulcatum) 72+hr Static Population Growth 56 mg/L (AQUIRE 2; 1980) Protozoa (Chilomonasparamecium) . 48-trRenewal Popul. Growth Inhib. 1,768 mg/L (AQUIRE 4; 1980) Protozoa (Uronema parduczi) 10,000 mg/L. (Verschueren p 1151) BacteLrCi,a (Pseudomonas) 10,000 mg/L. (Verschueren p 1151) Algae (Scenedesmus) "LG, E 100 mg/L" (Verschuerepn 1161) Algae (Colpods) LC, 160 mg/L (Verschueren p 1151) 5 Water Flea (Daphnia) LC, 24-hr Static LCy o 21,,530900 mmgg//LL ((VAeQrUsIcRhuEe2r;en18p771)151) - Brine Shrimp (Artemia salina) 24-hr Static LCs * 5,600 mg/L (AQUIRE 2; 1874) 32 The toxicity database. data are a partial listing of the 16 tests on 10 species given in the AQUIRE 33 This value is from a different reference than the previous one. -28- . 000876 Ce Goldfish (Carassius auratus) 24-hr Static Ly 24-hr LC, (85% TEA) 5,000 mg/L (AQUIRE 75,000 mg/L at pH 7 2; 1979) o 3,500 mg/L at pH 10.3 (Verschuerepn 1151) EnTvhiisromnatmeerniatlalsAhsoswessisnmsiegnntif;icant toxicity to Daphnia and fish. `Haodwdetivoenr,,ititshhaoswsa cloonwsBidOeDra/bClOe Dtoxriactiitoyatnodalwiglals.coFntorritbhuetesetoreaalsoownsr,aittiowionutlhdebperobdeusctt.noItnto use this __product material in products unless will be extremely low. no altemative can be foundoits concentration in the `The literature data ba reportetdo US is essentially complete for this EPA under section TSCA8(d). material. Any ~~ testing on this material must BNonee.commefnordAddaititonialToestninsg: 18. Urea CAS#57-13-6 D is DegrHadNesCaObiNotHic+,allHy;:0 --> CO; + NH, Degradation rate at 20C + Degradation rate at 2'C Concentration in domestic sewage Toxicity: i- Bacteria (Pseudomonasputids) Popul. Growth Inhib. _ Green Algae (Scenedesmus quadricauds) 7-day Static Popul. Growth Inhib. 8-day Static Popul. Growth Inhib. ol . 10.9 mg/7hr 3.3 mg/L/hr 2t06 mg. Ee > o Lo : >10,000mg/L(Verschueren p 1178) ~ 10,000mg/L(AQUIRE 2; 1980) 10,000 mg/L (AQUIRE 2; 1678) 34 35 All degradability The toxicity data data are from Verschueren p 1178-9. are a partial listing of 32 tests on 17 species from the EPA AQUIRE database. .-29- . : 000877 dW Blue-green Algae (Anacystis aeruginosa) 8-day Static Popul. Growth Inhib. Protozoa (Entosiphon sulcatum) 47 mg/L (AQUIRE 2; 1978) 29 mg/L (AQUIRE 2; 1880) ~_ 72:r Static Popul. Growth Inhib. Protozoa (Chilomonas paramecium) 48-hr Popul. Growth Inhib. Water Flea (Daphnia) 2,683 mg/L (AQUIRE 4; 1980) 24-hr Static LC, Creek Chub (Semotilus atromaculatus) 10,000 mg/L (AQUIRE 2; 1877) -. 24-hr LC, 241 LC, 16,000 30,000 mg/L mg/L (AQUIRE (AQUIRE 2; 2; 1952) 1952) EngLvirtieereronantaumlregenadsta.atlFauAirsntsdheiecsrasmtomeresent,htai:ttdtehigsramadteesriraeladsihlyowasndinist imgonisfticlainktel2tyoxwiocuitlydtnooDtabpehnaiap,rofibslh,emanind the product. EHshoowuelvderb,e ivtedriofe"isedsbhyoowutroxoiwcifonn)tytoestTbselsiufteii-tngigsr;eteonbaelguasee,dainndthteheprloodwutcotxiactithyitgoh gcroneceenntarlagtaieons. None. 19. Triton X-305 CAS# 9002.93-1 (PRISM ~composition of the rsehmoawinsiTnrgit3o0n %X-n3o0t5gitvoebn)e. 70% this - material with the . > SynonPyomlsy(:axy-1,2-athanediyi), aipha-{4-(1,1,3,3-tetramethylbutyl)phenyl]- omega-hydroxy-polyethylene Octoxinol glycol p-1,1,3,3-tetramethylbutylphenyl 3 ether - P-tert-octylphenoxypolyethoxyethanol : VendorR;ohm & Haas Company -- 36 Independence Mall West, Philadelphia, PA 19105. Phone: 215-592-3000. "%- 000878 Toxicity: Bluegill (Lepomis`macrochirus) 24-hr Static LC, 3.5 mg/L (AQUIRE 1; 1975) 24-hr Static LC, oT 24-hr Static LC, 16.2 mg/L (AQUIRE 1; 1975) 1,080 mg/L. (AQUIRE 1; 1975) 24-hr Flow-through LCs 96-hr Static LC, 10.0 mg/L (AQUIRE 2; 1975) 2.8 mg/L (AQUIRE 1; 1975) 96-hr Static LC,, 96-hr Static LC, 12.0mg/L (AQUIRE 1; 1975) 531 mg/L (AQUIRE 1; 1975) 96-hr Flow-throughLCs 6-day Flow-through LCs 10.0mg/L (AQUIRE 2; 1975) 9.6 mg/L (AQUIRE 2; 1975) "STthateicrLeaCsqo,n(f5o3r1thme hg ig)ha/ vraelnL uoetsfkonrotwhne.24-hr Static LC , (1,080 mg/L) and . for the 96-hr The vendor for Triton X-305 (Rohm and Haas) has biodegradability of Triton X-305. However, they are no data onthe sending aquatic toxicity or toxicity believe of Triton X-100. that the `toxicity Triton X-100 has a lower of X-305 is less tha molecular a data sheet on the aquatic `weight than X-305 andthey Triton Triton X-305 is not believed product line to Un todegrade n X:100 because X-305 is less surface active. biologically. Rohm and Haas has recently sold their Tinhtehfenoellaorwifnugtudraet.aTihs efrCoiAmonSACQanrUubImibRdeEero(gni1v-the8in0s0bC-y7A5RS2o-n1h8um2m7ba)enrda.nHdawaisll fboertthreanssefreirerisnigst9h0e36b-u1s9i-n5e.ss CAS#9036-19-5 : Toxicitg Rain4b8o-whrTrSotuatti(cSLaCl,mo gairdnen) 96-hr Static LC, ~ : - IN > 7.2 mg/L (AQUIRE 2; ' 1978) Marine Polychaete Worm(Scolelepisfuliginosa) 7.2 mg/L (AQUIRE 2; 1978) 48-hr Static LC, 96-hr Static LC, - - 17.0 13.7 mg/L mg/L (avg. (avg. of of 7points) 8 points) - (AQUIRE 2; 1978) ------ 37 The toxicity data database. are a partial listing of 13 tests on 5 species from the EPA AQUIRE or 38The toxicity database. data are a partial listing of 36 tests on 5 species from the EPA AQUIRE 31. . 000879 PE : Marine Polychaete Worm 48-hr Static LC, (Capitella capitata) 82mg/L (avg.of 6 points) i 6-hr Static LC,,, 6.0 (mAgQ/ULI(RavEg.2;o18f97p8o)ints) . Aquat4i8c-hSroRwebnuegwa(/ldoLtCea,balthica) 10.0mg/L(AQUIRE 3; 1972) 96-hr Renewal LCy, 5.0 mg/L (AQUIRE 3; 1972) EntBovoxiticrhiotCyn.AmSSeinnntcuaemlbTAresirtssoenshXsa-mv3ee0na5t:liismaitmeadjaomrocuonmtpoofnteonxticiotfytdhaetCa Eavapirloadbulcetsw,hwiechwislhlonwes emaodderate copmrpodluecttsatsoetthoeflrdaftoramuolnattihoins.material inorderinorderto correlate the effects.ofthe CE BOD, COD, algas, Daphnia, ish, and Microtox. ' " i-r > -32- . VOUS