Document b5wjk9JoR9BoyeabgG50j15oO

THE USE OF PTFE IN THE CLOTHING AND FOOTWEAR INDUSTRY IS HARMFUL TO THE ENVIRONMENT AND HEALTH - AND THANKS TO EXISTING ALTERNATIVES, NOT ESSENTIAL A scientific opinion on the European Green Deal target "Transforming the EU's economy for a sustainable future: A zero pollution ambition for a toxic-free environment", with a focus on the PFAS group of substances under the EU Chemical Strategy for Sustainability, the EU Sustainable Product Initiative as well as the climate goals of the Paris Agreement. Date: April 2021 Publisher: ChemicalsWorkingGroup, Sympates Technologies GmbH Contact: csr@sympatex.com EXECUTIVE SUMMARY EXECUTIVE SUMMARY `The importanceofa functioning health, climate and environmental policy is currently being emphasised worldwide. The protection of people and the biosphere is becoming an increasingly important political priority. In thecourseofthis,products and production processes harmful to health and the environment are also being brought more into focus and re-evaluated in legislation. "This report deals with the use of polytetrafluoroethylene (PTEE) membranes in the clothing and footwear industry, their harmful effects on health and the environment, as well as proven alternatives. that have been in use for many years "The garment and footwear industryhas a great responsibildiutey toitsvery high environmental impact. Adapting textile production processes for around 100 billion garments produced each year is an immense lever for better health protection and environmental sustainability through optimised circular economy, reduced CO; emissions and pollutant reduction in the environment. `The production, use and waste disposal of PTFE membranes are under urgent suspicion of causing massive health damage such as cancer, miscarriages, malformations in newborns, reduced vaccination effectiveness and weakened immune systems. The substitutes now used for PTFE production (Gen, etc) also have harmful effcts: they are classified as substances of very high concern in the European Union. Rivers and bodies ofwater near PTFE production sites are often heavily contaminated resulting in some cases blatantly increased cancer rates in the immediate vicinity. Proximity with production sites is not the only source. Due to the volatility of the substances, enriched amounts of fluorochemicals have already been detected in human blood even in distant regions. The persistence of PTFE is a necessary criterion for other areasof application, such as cable sheathing or medical implants. For textile products, however, thanks to adequate alternatives, it represents an avoidable health hazard for the user and an unnecessary disposal problem. PTFE membranes, due to their unfavourable disposability in the textile sector, prevent the more environmentally friendly recycling andthusall efforts towardas circular economy. Moreover, the CO; emissions from the production of PTEE membranes are more than 30 times higher than available alternatives. HEC-23 measurements in the atmosphere clearly show that the globally increasing PTFE production contributes comparatively strongly to climate change. PTFE membranes can be made neither safe nor sustainable On the other hand, environmentally friendly polyester (PES) membranes, harmless to health, allow high-quality recycling and greatly reduced greenhouse gas emissions with the same technical performance. At the same time, PTFE alternatives will support the EU Chemicals Strategy for Sustainability and the upcoming EU Sustainable Product Initiative, aiming at accelerating closing the loop, reducing wasteand chemicals impacts. They wil also reduce environmental risks within the supply chain to be identified under futureduediligence legislation. PES membranes are both healthier and environmentally safer alternatives, as well as technically equivalent to PTFE membranes. Therefore this study urgently calls for legal restrictions on PTFE membranes for all non-essential applications in the textile, clothing and footwear industry. 1 CONTENT EXECUTIVE SUMMARY sss: | 1 BACKGROUND ssn3 2 FLUOROCHEMISTRY USE IN THE TEXTILE INDUSTRY rs I 20 PTFE MEMDIANES vss3 22 BEST PRACTICE: FIUOROGATbON-fTE MEMBIANES. rvs 3 FLUOROCHEMISTRY IN WATER AND ENVIRONMENT c.cmne 31 Environmental and health impacts of PTFE production... 8 32 Health effectsof textile products COMaining AUOTOCADONSvrs 10 33 MUO CMYibmmmsmmmm---- word 34 PIONE-EThRe Netherlandsdraws CONSequENCeS msm 12 35 Waler CONSUMPUON MEMBIANES vrs 12 4 RECYCLING OF FUNCTIONAL TEXTILES... won - 41 SustdeasiignanndaPrbOQlUCOeN vss: 14 42 CONSUMPUON A USErns -- SH U3 VA AIAG mmms------------------------ - 44 CUNEO mmmmmmmmm--------1T 45 BEST PRAC-TWeAIr2CWeaErTM COOpEration msn: 7 5 CO; EMISSIONS OFTEXTILE MEMBRANES... 19 51 PTFE datacollection and global emission factor ......vreeres mn 52 BEST PRACTICE: biomassed-based PES MEMBIAN. ovr 23 6 CONCLUSION. css 2 7 ANNES - OhoRechte pert Oilman 38 FE 2 BACKGROUND 1 BACKGROUND "Whenever possible, avoid products containing, or manufactured using, PFASs (in government procurement). These include many products thatare stain-resistant, waterproof, or non-stick. Extractfrom the Madrid Statement on PFASs, addressed to authorities buyers, retailers and individual consumers etc, 2015 w At the international PFAS (per- and polyfluoroalkyl substances) Conference 2020, numerous scientists gave presentations on legislation, future PFAS restriction procedures and diverse casesofcontamination by per- and polyfluorinated chemicals, their effects and measures. The worldwide contamination of soils, groundwater and drinking water, and thus food, as well as the consequences for humans and animals where highlighted. [2] Many of the PEAS substances released into the environment since the 19605 are already classified as PBT substances. [3] They accumulate in the human body, sometimes causing cancer and malformations in newborns. Research is currently being conducted into the extent to whichthe immune system is influenced by PFAS and the effect of vaccines i reduced. Among the many PEAS chemicals mentioned during the conference, the chemicals PFOS and PFOA, which are now banned in the EU, as well as their substitutes suchas GenX, which have so far only been classified as SVHC, appear significantly. In numerous tests, such as in the USA, the Netherlands and aly, the PFOA levels found in the blood,for example, massively exceeded the legallydefined limits. The damage to health is immense. After large-scale tests with about 69.000 people in West Virginia, USA, 3,500 casesofillness andor death resulting from these testshave already been recognised and convicted in court, and further proceedings are underway. [4] A 2016 report reveals four of the biggest PCA pollution hotspots in the world, all around PTFE manufacturers. [5] PECAs (perfluorocarboxylicacids), including PFOA andtheirsubstitutes, sometimes serve as emulsifiers in PTFE production. The PTFE polymer, which is stable in itself, can still contain PEOA impuritiesas well as decompose to PCA, including PFOA,during combustion. [6, . 37] These. findings are particularly relevant to the textile industry as one of the largest users of PFASs, with predominant disposal routes and emissions to the environment being wastewater, incineration and landil. 6, p. 125] Dueto the focus on fluorocarbon finishes of textiles, as in the latest large-scale EU study on PEAS, [6] fluorocarbon membranes are hardly looked at and their alternatives were not mentioned at all. As a result, the majorityof the textile public procurement, apparel and footwear sectors are still unaware of the comprehensively devastating impactsof the unnecessary useoffluorine-based membranes. In its analysis of the most relevant environmental risks of the textile industry, the Boston Consulting Group identified the issues of chemical use, water, CO; emissions and waste. [7] In contrast to technically equivalent membrane material alternatives tried and tested for years, such as polyester-based membranes, PTFE membranes massively counteract eachofthese environmental issues: 4) Water: In addition to the water and soil near PTFE production site, which have been contaminated for decades, tracesof PFOA can now be found worldwide, even in the most remote places in the world (8.p.15] 3 BACKGROUND b) Chemicals: Detectable amounts are already found in the blood of humans, even foetuses, and contaminate the body. [8,p. 14] ) Recycling: PTEE membranes, in contrast to technically equivalent alternatives in the laminate structures relevant to the textile industry, cannot yet be recycled in an ecologically and economically sensible way. As a result, they (and all materials permanently bonded to them, eg. by lamination) represent barriers to the EU [9] and its Member States' future objectives regarding recycling, recycled content, recyclability for the textile and footwear industry. They also represent high hazards in recycling streams not controlled by high level environmental standards, or through individual burning of garments and shoes in the open air. Therefore the contact of innocent third partes with highly toxic hydrofluoric acid cannot be excluded. [10] d) CO; emissions: The CO; emissions of PTFE membranes are more than 30times higher compared to those of other alternatives available in the textile industry. [11], [12] The textile industry is already responsible for more than 8% of the world's greenhouse gas emissions, [13]a reduction to achieve the Science Based Targets andthus the goalsof the Paris Climate Agreement is essential. Back in 2015, 230 scientists from 40 different countries signed the Madrid Statement on Poly- and Perfluorinated Substances. They called on the international community to work together to limit the production and use ofPFASs and to develop safer non-fluorinated alternatives [1] Atthe 2020 International PEAS Online Conference, renowned chemist Prof. Arlene Blum, who helped draft the statement, identified six classes of hazardous substances, of which she believes PEAS is by far the most serious. With a view to the use of PFAS and the introduction of "green chemistry', she also described the three most relevant issues from her pointofview: 1. Isthe use necessary? 2 Isitworth it 3.Is therae safer alternative? [14] "The folowing report is dedicated to the consideration ofthe four most relevant environmental issues of thetextile industry mentioned above, taking into account the above three questions of necessity, impact and alternatives. It summarises the evidence on environmental pollution and health hazards associated with PTEE production and use that has been known since the 1970s and gained worldwide in recent years. Moreover it uses best practice examples to show that the use of PTFE membranes in the textile industry is long overdue. 4 FLUOROCHEMISTRY USE IN THE TEXTILE INDUSTRY 2 FLUOROCHEMISTRY USE IN THE TEXTILE INDUSTRY "Reducing the use of PFASs is more important than climbing the world's highest mountains." Prof. Arlene Blum, leader of thefirst women's expedition to Annapurna (1977) and Executive DirectorofGreen Science Policy Institute Berkley/ California, USA a "The groupof PFAS comprises about 4700 different substances, [15] many of which fall under the socalled PBT substances and are thus persistent, bioaccumulative and toxic. [8] Theiruse in the clothing and footwear industryi of two kinds: (2) the outer fabrics are in most cases water-repellent impregnated from the outside by means ofa DWR (Durable Water Repellent) finish, as well as (b) the material is protected against the penetration of water to the body by a waterproof intermediate layer (membrane or coating). In the past years of environmental debate, the focus of the textile industry on the topic of PFAS has, mostly been on legislation and the effects of DWR finishes containing luorocarbons. Therefore, the following section is specifically dedicated to the interlayer containing fluorcarbon - the PTFE, membrane. 2.1 PTFE membranes `While DWRfinishes impregnate the fibres ofthe outer fabric, membranes serveas awaterproofbarrier between the textile layers. On 11 May 2020, ECHA launched a consultation on a restriction procedure covering a wide range of PEAS uses. This covers all PEASs and possible alternatives in textiles, upholstery, leather, clothing and carpets. 16}, (17) It also includes PTFE membranes. TheNetherlands and Germany, with the support of Norway, Denmark and Sweden, are planning to prepare a corresponding restriction dossier. [18] "The restriction proposal will be prepared by the national authority over the next two years. The ECHA Scientific Committees will give their opinion after the submissionof the restriction dossier. The entry into forceofthis restriction is expected in 2025. [13] "The background is as follows: until the endofthe 1990s, PTFE membranes were mostly manufactured with the process chemical PFOA. PFOA salts mainly serve as emulsifiers in the synthesis of the fuoropolymer PTFE. Due to the discussions about the eco- and human-toxicological properties of PEOA, the fluorochemical industryreplaced PFOA with alternative perfluorocarboxylicacids (PECAS), such as GenX or Adona. However, in the course of recent investigations, the substitute chemical GenX has been classified by ECHA as a SVHC substance (Substance of Very High Concern) [17] and the chemical Adona ... has been assessedas undesirable substitutes, as they are most likely to be similar to chemicals such as GenX and other PECAS in termsofpersistence, mobility and possibly toxicity. [19] 5 FLUOROCHEMISTRY USE IN THE TEXTILE INDUSTRY In Europe and the USA, PFOA environmental concentrations are already slowly decreasing due to various measures. This is due to a 2006 agreement between the fluorochemical industry and the US Environmental Protection Agency (EPA), in which eight companies voluntarily committed to reduce PEOA by 95% by 2010 (compared to 2000) and to eliminate it completely by 2015. However, many companies, for example in the emerging Asian market, do not participate in the stewardship programme. This means that PFOA and is precursors enter the EU market through imported products [20] - and their volatile collateral damage via the diversions of waters and atmosphere. A 2016 Greenpeace report confirmed this, noting that "global productionof PFOA forthe manufacture ofPTFE (Teflon) is shifting to China, where the same pattern of pollution is now being repeated." [5] In 2020, more than 75% of global PTFE production did not take place in the EU, but 41.5% in China, 15.5% in the US and 8.5% in Russia, for example. 21] Although the newly elected American President Biden has, declared the issue of PFAS substances 10 be apriority, PFAS are not yet listed as harmful substances in the USA. [14] That means PFOA, GenX andother PCAsaresofaronlylistedas harmful substances or undesirable substitutes in the EU. But what exactly makes ther so dangerous? Effects of PFOA PEOA is difficult to degrade, accumulates in the organism and is toxic. For this reason, PFOA is listed in the POP Regulation (Persistent Organic Pollutants) Annex 1 and is limited to 0.025 mg/kg in substances, mixtures or articles. [22] PFOA can enter the environment during production and use. In addition, there is evidence that PFOA can be formed in the environment during the degradation of fluorotelomers. Its highly persistent in all environmental media andis transported over long distances PEOA has a high bioaccumulation potential In animal studies it is carcinogenic, toxic and endocrine disrupting, PFOA is toxic to aquatic organisms and may cause long-term adverse effects in aquatic environments. [23] Effectsof PFOA substitutes GenX, Adona and similar substances with comparable technical properties as PFOA substitutes are equally persistent, very mobile, have the potential forlong-distance transport and the bioavailability for drinking water ingestion. They also have a very high potential for irreversible effects. [17] This assessment has recently been taken into account by the official classification of the chemical GenX (HFPO-DA and its salts and acyl halides) as SVHC. The ECHA agreed that the substances identified in the proposal as HFPO-DA areof equivalent concern in terms ofcarcinogens, mutagens and substances toxic to reproduction (CMR), persistent, bioaccumulative and toxic substances (PBTS) and very persistent and very bioaccumalative substances (vPvBs). [24] "This means that although PTFE membranes are not made from PECAs (e.g. PFOA, Gen, ADONA) or theirprecursors, variantsofvarious PFCAS are usedas process chemicals in their manufacture and the final product may contain residuesofthese substances `There is no manufacturing process or applicationofPTFE membranes that is not harmful to health and the environment. However, there are alternative safe membrane materials. 2.2 BEST PRACTICE: Fluorocarbon-free membranes `Through yearsofeducation and legislation, fluorocarbfroene finishes have gained significant market share andincreasinglydisplaced DWRs containing fluorocarbons from some applications. In contrast, 6 FLUOROCHEMISTRY USE IN THE TEXTILE INDUSTRY knowledge about the manufacturing processes of PTFE membranes and their impact on the environment and health has not yet brought to consumers' minds. Yet thareevarrioeus alternative materials to PTFE that have been available on the marketfor along time and achieve comparable performance characteristics. In viewofthe superior recyclability, ie. necessary `grade purity and the fibres mainly used in the textile industry, the following comparison is made with a hydrophilic PES membrane. Hydrophilic PES membranes are usually produced via extrusion processes from the corresponding polymer melt. The associated polyester-based copolymers, in turn, can be produced using processes that have been established in the plastics industry for many decades. Usually, the different building blocks of the polymer are linked together in a melt polycondensation and the desired molecular weight is then adjusted viaa solid phase condensation. Both the membranes and the polymers are usually produced without the use of solvents, so that their more or less complex separation and recovery is usually not necessary for hydrophilicpolyesterbased membrane systems. * Besides PTFE and PES membranes, membranes and coatings madeof polyurethane (PU)ar used inthe textile industry. 7 FLUOROCHEMISTRY IN WATER AND ENVIRONMENT 3 FLUOROCHEMISTRY IN WATER AND ENVIRONMENT "People need to know that this stuff is now everywhere. In the environment, in drinking water and even in the blood of almost everyliving creature on thisplanet." Robert Bilott, environmental lawyer, lead plaintiff against DuPont interviewedfor theilm Dark Waters' 2019 os `Whether `The Devil We Know or "Dark Waters' both movies have in common the exposure of the environmental and health damage caused by PTFE production. PTFE production pollutes the local environment, including surface water, drinking water, groundwater, as well as air and dust. There i large evidenceofpollution in places around the world where chemical companies produce PTEE, including those that still use PFOA or PFOA substitutes such as GenX. [3] Some examples will be discussed below, listing the concentrations in the water and blood of the surrounding population. But these dangerous substances do not only enter the human body through drinking water, and thus food. They can also be absorbed directly from the skin or inhaled through dusts. [26] Previous measuring methods also suggest that currently only the tip of the iceberg is discernible [27] and that the demand of politics and science for an overall consideration of the PFAS substance group is more than justified. [28] In the course of the current restriction proceedings, costs for environmental remediation and compensation payments amounting to millions are also in the offing, 3.1 Environmental and health impacts of PTFE production A 2016 report listed four PEAS hotspots, which are summarised below. In three of the regions, PFASs are used significantly for PTFE production. DuPont (Chemours)/ West Virginia: `Theworld's most famous case of PFAS contamination is near the DuPont plant in Ohio, West Virginia, USA and is the subjectofthe movie Dark Waters, Since the 1950s and until the end of production in 2015, the chemical PFOA used for PTFE production found its way intopeople'sdrinking water. As early as the 19805, PFOA was detected in publicdrinking water in the vicinityof the plant, although DuPont was already awareofthe harmful effects on health at that time. Very high PFOA levelsofup to 22.1 ug/l were found in private drinking water. Even though production was reduced by 99% in 2013, measurements indrinking water in the surrounding area still showed avalue of0.0631 g/l. The PFOA concentratioinns the bloodof the populationwerelistedas an explanation. [5, p. 4] In the course of this, the blood of 69,000 residents who had lived in the district for at least over a year was tested for their PFOA concentrations. Very high PFOA concentrations were found in the blood - a median of 28.2 ng/ml, with a mean valueof 83.0 ng/ml - comparedto a median of 3.9 ng/ml in the `general population. According to two studies, exposure to PFOA was associated with both kidney and testicular cancer. Associations withprostate and ovarian cancer and non-Hodgkin's lymphoma are also suspected. [5, p.4] 8 FLUOROCHEMISTRY IN WATER AND ENVIRONMENT Chemours/ Dordrecht: Further investigations took place at one of the largest PFAS production facilities in Europe, in Dordrecht, NL. The plant, which opened in 1960, was spun off from DuPont in 2015 under the new. company name Chemours. Until 2012, PFOA was used for the productionofTeflon, after which the chemical GenX was used as a substitute. State tests of the drinking water in 2015 did not reveal any elevated PFOA concentrations (no in relation to the limits applicable at the time). According to the preparationofvarious emission scenarios, "in the worst case, the limit value was exceeded for 25 years Atsuch levelsofchronic PFOA exposure, health effects, forexamploen the liver, cannot be ruled out", (5p-5] POA blood tests ofa DuPont employee published in April 2015 showed 28.3 ng/ml PFOA in the blood, and in his wife, who was also tested, even three times as high values were found, 83.6 ng/ml. Further measurements of PFOA concentrations in the residents blood were not carried out. However, after residents indicated interest in further blood testing, selected participants received an invitation for blood tests at the end of August 2016, which took place inSeptember and October 2016. [5, p. 5] The clearest evidence was found for an association between exposure to PFOA and higher blood concentrations of total cholesterol, higher blood concentrationsof the liver enzyme ALT and lower birth weight. There is less clear evidence for an association with higher blood concentrations of other liver enzymes, LDL cholesterol and uric acid. Evidence was also found for an increased risk of chronic intestinal inflammation (ulcerative colitis), testicular andkidney cancer,aswell s pregnancy-related hypertension and pre-eclampsia. In addition, associations were found between exposure to PFOA and reduced vaccination response, changes in concentrationsof thyroid hormones in the blood and thyroid disease. 129] Another report from 2020 compared cancer rates of Chemours plant residents with the restof the Netherlands, finding them 15.7% higher than in the rest of the country. [28] Leather industry Veneto: `The PTEE hotspot in the Veneto region of Italy had even higher PFAS levels in surface and drinking water, with an estimated 350,000 to 400,000 people potentially directly exposed. Up o 1,886 ng/l PFOA were found in drinking water alone. The source of 97% of this PFAS contamination was identified in 2013 as a wastewater treatment plant into which mainly tanneries discharge. Despite the cessation of PEOA production in 2011, the levels in 2016 were sill 140 times higher than in the non-contaminated environment. Afiertest600ipeonplge, concentrationsof up to 754 ng/g (median 74.21 ng/g) were found in blood serum, which is up to 20 times higher than the retofthe population. (5, p. 6] Dongyuchem/ China: "The final hotspot of the report was the waters around the Dongyuchem chemical plant in China's `Shandong province. AsoneofChina's largest PTFE producers (37,000 tpa, it serves customers such as DuPont. Total concentratioofnups to 1,860,000 ng/l were measured in theriver into which the chemical plant's wastewater is discharged (one of the highest concentrations ever reported - with PFOA dominating) and which flows into the Yellow Sea between China and Korea. To meet domestic and international demand for PFOA, production continues to increase. 5, p. 7] Blood tests of people from the immediate vicinity have not been carried out. 9 FLUOROCHEMISTRY IN WATER AND ENVIRONMENT 32 Health effects of textile products containing fluorocarbons In addition to the ingestion of PFOA or its substitutes through drinking water, transmission alo occurs through dermal absorption and inhalation ofdusts. The consequencesfo health are catastrophic. Inthe last 30 years, cancer has replaced heart diseasea the main cause of death in the fire service Cancer caused 70% of deaths among professional firefighters in 2016. [30] There are proven links between PFOA and testicular cancer, mesothelioms, non-Hodgkin's lymphoma and prostate cancer. These are fou of the eight most common cancers that firefighters are more likely o develop than the general population. In addition, the demonstrated immunotoxicty of PFAS in the body suggests that populations with elevated lvel of PFAS in theirblood sea ae susceptible toa wide range ofdiseases and cancers. 126] While flighting foams are primarily the reason for the high death and illes rats, firefighting clothing is also suspectedofbeng harmfl to health. "The fist examinationoffirefighters protective clothing using PIGE revealed very high total fluorine levels in firefighters protective clothing - both in the outer material and in the membrane. ~, 5 Ce Sh "The mattesetedrconsiistaedolfouster material ished +1 wasithmofilsutourroecarbbaorrni-ecrosntaainndingluDoWriRn,e-PfeTeFEthmeermmbolrianneerss vw S|S" om around the membrane. Fmigrgate rOormrthtein,maPtuErAeS BbnaierigGhrtaenrg'es) gtuo ctoen hme ht comes ft coma wih he kin PInFtAhSe mfirsgtrasttipo,nittowatshefloauynedrstwhaotrsnigonnitfihceanstkainmounts of PiFnAtSsheccannraolsmonbcenrtelea[s3e3d]from the outershell (black) fuorochemicls ar excreted from firefighters' clothing during is service life. The thermal liners n this study were not trated with PFAS according to the manufacturers, yet significant amounts of fluorine were found in al sewnin thermal liners of firefighters' clothing. The average total fluorine content found in leven new material samples before they were processed into thermoliners was blow the detection limit. This consistent observation of fluorine in the untreated ayers is the first evidence that PFASs appear to migrate from th highly fluorinated ayers and accumulate inthuntreated layer - the clothing worn on the sin. [26] PFOA substitutes also migrate from the PTFE membrane Through further analytical procedures, additional evidence ws found that the PFAS concentrations in the thermoliner also originate from the PTFE membrane. The majority of PFASs identified during extraction from textiles belong to the short and long chain fluoroalkyl acids, including PFOA. In addition, a PTFE membrane was examined that ws produced using a PFOA substitute. This was the only sample examined that had no detectable PFOA, presumably due to te switch from long:chain PAS solvent auxiliaries in the manufacture of PTFE in 2012. Instead, a very high level of PFBS was found in this material (+90 ppm), which may indicate a newly used solvent aulary." (26, p. CJ Meanwhile PFBS has lso been classified s an SVHC substance by the ECHA. [31] BE ------ 0 FLUOROCHEMISTRY IN WATER AND ENVIRONMENT It can thereforebe deduced that the PFOA substitutes also migrate out of the membrane and can affect the body via dermal absorption. PFAS uptake through dusts However, there may also be more direct routes by which PEASs enter the body, for example through inhalation of PFAS-containing particles and fibres resuspended from protective clothing. Dust measurements from a textile warehouse also indicate adirect loss of PFASs from the fluoropolymers in the textiles. 26] The Greenpeace Hotspot study also reports that PFASs were detected in indoor and outdoor dust samples in the vicinity ofa PTFE plant, with the concentration pattern decreasing with distance from the plant in both indoor and outdoor dust samples. For example, in indoor dust samples, the sum of PFAiSnasn area 2 km from the plant was up to 180 times higher than at sampling points 20 kmaway. (5,p. 7) Meanwhile, the study on firefighters clothing recommends that several important protective measures for firefighters should be considered immediately, such as wearing PFAS-free clothing under their turnout gear and washing regularly. This would help minimise skin exposure, and washing hands after touching the clothingwould also be aprecautionary measure. [26] Since the migration of PFOA or PFOA substitutes from the PTFE membrane mustbeassumed, a non-porous, PTFE-fre alternative PES membranewould be an immediate measure for firefighters' clothing that is as simple as it is health and environmentally friendly. 33 Methods of analysis Further research results also indicate that even modern analytical methods do not allow complete detection ofPEASdespite high sensitivity.For example, in one study, the detection method LC-MS/MS, which is frequently used in trace analysis, only detected about 1% of the total fluorine quantities determined via another method (PIGE). This is consistent with previous measurements on textiles. "There are literally 100 times more PFASs present in the material, for example precursors, polymerbound fluorine that remains in the finish, unidentified similar substances and oxidation intermediates that are neither identified nor detected in routine LC-MS/ MS analysis." says the addendum to the study on firefighters textiles. [32] Similar findings were made in another study. When comparing PECA concentrations (e.g. PFOA) in wastewater before and after oxidation, an increase was found. This can be traced back to precursor substances that are only transformed into PECAs by the action ofsunlight, advanced oxidation processes or microbes on urban wastewater and can thus be measured. [27] Effects also on military, police and everyday clothing Based on the above studies on the migration of PFASs in firefighting textiles and the challenges of analytical methods, it can be assumed that this could also occur in other application areas such as military and police, but als in everyday clothing, Scientists fear ths and sate "The health consequences. of such material loss are likely to extend far beyond firefighters' uniforms. Firefighters are out there risking their lives for us" says scientist Peaslee in an interview. "The least we can do is give them the safest equipment possible." 33] n FLUOROCHEMISTRY IN WATER AND ENVIRONMENT 34 PIONEER- The Netherlands draws consequences `With regard to the PFOA issue and its substitutes, which are now also clasified as SVHCs, the entire PEAS group of substances is currently being reviewed by the EU to determine whether it is necessary. n7) "The Netherlands has already agreed to a declaration in parliament that excludes PFAS from public procurement, see chapter 4. Due to the investigated health effectsof the Chemours plant in Dordrecht, the Dutch are sensitised. Meanwhile even ministers are claiming millions in damages for PFOA and GenX contamination against Chemours and DuPont. In doing so, they are doing the same as the municipalities of Dordrecht, Sliedrecht, Papendrecht and Molenlanden, which have already announced that theywillgo to court to hold the company liable. While its unlikely that the Dutch government will join the same court case, MPSuzanne Kroegersays thearguments will overlap. "We can strengthen each other," she says, adding that this is urgent: `In the film Dark Waters we saw DuPont pulling out al the stops." In her opinion, this is now very much the case in Dordrecht, as Chemours already announced that it does not want to comply with the stricter environmental requirements. The company, on the other hand, is asking the court in summary proceedings to draw a line under these requirements. The claim for damages would include the costsoffinding out where the dangerous substances PFOA and GenX have all ended up. This i necessary because the companyitself did not keep sufficient records of this. [34] `With the DuPont spin-off, Chemours assumed the chemical company's environmental liability in 2015. After the maximum estimated cost of the indemnities exceeded $945 million, Chemours sued the meanwhile merged DowDuPont in 2019 because no `unlimited liability had been agreed. At the beginning of 2021, both companies agreed on a cost-sharing of the lawsuits of4 billion dollars as a precautionary measure, which gives an idea of the real extentof the damages. [35] 3.5 Water consumption membranes Based on current calculations of recognised databases, the water consumption for PTFE membrane production is - independent of chemical water pollution - about three times higher than for PES membranes. I26.4 litresofwater are required for the production of1kg of PES membranes, the figure for 1kgofPTFE membraneswith a PU coating is 86.9 litresofwater. [36] In viewofthe environmental issuesofwater and health, the useofPTFEmembranes is not necessary and certainly not recommended due to the availoafbaliterlnaititveys. Therefore, PTEE membranes should no longer be allowed tobeused in these areasofapplication. 12 RECYCLING OF FUNCTIONAL TEXTILES 4 RECYCLING OF FUNCTIONAL TEXTILES ,,The Chamber, having heard the debate, considering that the government has an exemplary function with regard to sustainable procurement; noting that the government procures shoes and clothing for Defence and emergency services which contain GenX and pfoa in their membrane; noting that alternatives without substances of very high concern are possible noting that the procurement policy and technical specifications for clothing and footwear for Defence and the emergency services do not currently take into account the recyclability of the equipment; calls on the government to investigate whether the recyclability of clothing and footwear can be included in the procurement rules, and to proceed to the order of the day. " Statement by Suzanne Kroger MP, GroenLinks, Security in the supply of raw materials, House of Representatives of the States General, Netherlands, Motion of 30 June 2020. [37] The above motion by MP Suzanne Kroger to include recyclability of clothing and footwear in public procurement tendering rules was adopted by 92 votes out of 150 by the Tweede Kamer, the legislative body of the Netherlands. However, recyclability is not only focused on in the Netherlands, also in Germany, the Circular Economy Act was amended. The background is the Circular Economy Action Plan (CEAP) of the European Commission. This action plan for the circular economy is one of the most important building blocks of the EU Green Deal, the new European agenda for sustainable growth. [38] According to the CEAP, textiles are the fourth largest category for primary raw material consumption, with estimates that less than 1% of all textiles worldwide are recycled into new textiles. Given the complexity of the textile value chain, the Commission will propose a comprehensive EU strategy for textiles, based on input from industry and other stakeholders (see chapters 4.1 and 4.4) to boost, for example, the EU market for sustainable and recyclable textiles, including the market for textile reuse. This goes hand in hand with a strategic focus on sectors that consume the most resources and where the potential for circular economy is high, as in the case of textiles. [9, p. 13] To close the loop, the European Commission has defined measures for the following areas: [39] Design and production Consumption and use Waste and recycling Global action 13 RECYCLING OF FUNCTIONAL TEXTILES 4.1 Sustainable design and production The basis of all measures is the development of textile products by means of sustainable design to ensure that products are suitable for the circular economy, the use of secondary raw materials is guaranteed and hazardous chemicals are avoided. [9, p. 13] The EU Policy Hub, the textile industry's stakeholder and voice to the EU, has set itself the goal of accelerating the circular economy in the clothing and footwear industry. The EU Policy Hub defined the most important points on sustainable design as: Design for duration of service Design for cycylability Design for repairability Design for more sustainable production The definition in focus here is "design for recyclability": "Design for cyclability means creating products that can be deconstructed and using materials that can be recycled or are industrially compostable at their end-of-life - with no risk emanating from their chemical inputs and a low carbon footprint. This can be achieved through further research and the development of new materials, where current ones do not provide the desired functionality and cyclability. Better cyclability supports among other things, a circular loop, where materials continue to be re-cycled and re-used at their end-of-life, optimising re-sources and minimising waste". [40] Comparison of circulation capability of PES membrane and PTFE membrane The membranes used in textiles are present in functional clothing as composite materials, so-called laminates. The figure below compares the recyclability of a laminate with a PES membrane and a PTFE membrane. Due to the PES fibres often used in functional textiles, the PES membrane can be incorporated into a 100% sorted composite. This allows for easy and high-quality recycling. This is not possible in the case of the PTFE membrane. Design to recycle potential of membranes in laminate structures Recyclable 100% PES laminate - the PES, including the membrane, can be virgin, recycled or bio-based: Air 1. 100% PES Outer fabric 2. 100% PES Membrane 3. 100% PES Lining Fluorocarbon-based laminate - as PTFE is not used ir 1. as a fibre, grade purity can never be achieved in combination with PTFE membranes: (O fPeaEu.bgStre.i,cr PA, CO) 2. + 3. Membran PTFE+PU3 4. Lining (e.g. PES, PA, CO) Figure 2: Comparison of the grade purity of PES and PTFE laminates 'Due to the microporosity of PTFE membranes, a PU coating is needed to create the required water column, and thus waterproofness. 14 RECYCLING OF FUNCTIONAL TEXTILES In addition to the CEAP requirements for sustainable design, the requirements for sustainable production are also described. The production of PTFE membranes is identified in detail in chapters 2.1 and 3.1 and is contrary to all aspects of sustainability: environmental, social and economic. 4.2 Consumption and use Another CEAP target is to empower businesses and private consumers to make sustainable purchasing decisions and to have easy access to reuse and repair services. [9] Tools such as the Product Environmental Footprint (PEF) will be one way to inform consumers and incentivise sustainable consumption. [39] Currently, the PEFCRs (PEF Category Rules) are being developed together with a large number of textile and apparel companies. In addition to durability, the PEF also focuses on re cyclab ility. PTFE membranes and fluorocarbon-containing laminates are difficult to recycle, see section 4.1. PES membranes and laminates, on the other hand, enable recyclable materials and production processes. 4.3 Waste and recycling EU Member States must ensure the conditions for separate collection of textile waste by 2025. CEAP therefore calls for the provision of guidelines to achieve a high level of separate collection. This goes hand in hand with the promotion of sorting, reuse and recycling of textiles. Fundamentally, the European Union's approach to waste management is based on the waste hierarchy (see Figure 3). This waste hierarchy defines the design of waste policy and the order of priority: prevention, (preparation for) re-use, recycling, recovery and - as the least preferred option - disposal by landfill or incineration without energy recovery. [41] In line with the waste hierarchy, the 7th Environment Action Programme sets targets for waste policy in the EU: Figure 3: EU waste hierarchy X41] Table 1: Comparison of the implementation potentials of the EU waste policy targets when using PES and PTFE membranes Priority objectives of EU waste policy [42] 1. Reduction of waste 2. Maximising recycling and reuse 3. Limiting incineration to non-recyclable materials recyclable materials 4. Limiting landfilling of non-recyclable and non-recyclable waste 5. Ensure the full implementation of the waste policy objectives in all Member States Implementation PES membrane potential Implementation potential PTFE-membrane x x x x x It is clearly listed in the table that due to the lack of grade purity PTFE membranes cannot contribute to the fulfilment of the objectives of the European waste policy. 15 RECYCLING OF FUNCTIONAL TEXTILES The renewed German Circular Economy Act, amended on 29 October 2020, has even noted in 45 Obligations of the public sector, paragraph 2, that preference is to be given to products that: "have been manufactured in production processes that conserve raw materials, energy, water, pollutants or waste, have been produced by preparing them for re-use or by recycling waste, in particular by using recycled materials, or from renewable raw materials are characterised by durability, ease of repair, reusability and recyclability, or compared to other products, result in less or less polluting waste or are more suitable for environmentally sound waste management." [43] The European Commission formulates it similarly in the document "Green Public Procurement" and points out, in the sense of sustainable and conscious public procurement, that the authorities include criteria with a view to lower environmental impacts when purchasing goods, services and works. The criteria for textiles focus on the main environmental impacts along the life cycle of the products, including fibre sourcing, chemical restrictions according to the POPs Regulation (e.g. PFOA), durability and life extension, energy saving during use and design for reuse and recycling. [44] However, it is not only the difficult recyclability of PTFE membranes that is against legislation, PTFE membranes are also problematic as waste, especially when incinerated. Combustion tests of common membrane types In a test of smoke density and smoke toxicity according to EN ISO 5659-2 (NBS-Box), the Frankfurtbased institute Warringtonfire determined the concentration of the most common toxic combustion gases in functional textiles, i.e. all three commercially available membrane types PTFE, polyurethane (PU) as well as polyester. Not surprisingly, CO2 (carbon dioxide), CO (carbon monoxide) and NOx (nitrogen oxides) are typical gases that are also released during the combustion of other organic materials such as wood, coal or diesel. [10] Furthermore, all materials released small amounts of prussic acid, which were well below human-toxic levels, but roughly equivalent to what one might expect in a small smokers' pub after visiting 15-25 guests and smoking 10 cigarettes each. The values for polyester were about 1/3 lower than for the other two materials. Only in the case of PTFE membrane material were additional high values of highly toxic hydrofluoric acid, the aqueous solution of hydrogen fluoride (HF), of 63 ppm and hydrochloric acid (HC1) of 36 ppm measured. [10] The main absorption route for HF is via the respiratory tract and the skin. According to EU Directive 2000/39/EC, the EU workplace limit value is a maximum of 1.8 ppm as an 8h average value and 3 ppm as a short-term limit value; the IDLH value (Immediately dangerous to life or health) is set at 30 ppm. In principle, it is assumed that 50 ppm HF can be fatal for humans at an exposure of 30 to 60 minutes. [10] Based on the values determined on a laboratory scale, it must be assumed that in the case of uncontrolled combustion of a commercially available functional jacket in which a PTFE membrane has been processed, the quantity of hydrofluoric acid (HF) produced in the process alone can lead to death for people directly exposed to the smoke for 30 to 60 minutes. The hydrochloric acid (HC1) also released during the combustion of PTFE additionally leads to severe burns in the lungs when inhaled; irritation 16 RECYCLING OF FUNCTIONAL TEXTILES and burns of the mucous membranes and respiratory tract can occur. These findings are particularly problematic because around50% ofthe textilescollected worldwidearesold via used clothing collections, tolower-income third countries for further use- aglobally growing billion-dollar business. 45,p. 85] In these countries, the most common waste disposal route is (often uncontrolled) landfill or open fre. `According to one study, 40% ofglobal waste burns uncontrolled in open fires. [46] It must be assumed that, purely statistically, about 15-20% of clothing ends up in open fires in the immediate vicinity of settlements Due to these facts, the combination of difficult recyclability and lack ofcircular economy of PTFE, `membranes and laminates is all the more fatal and additionally unacceptable due to existing alternatives. 44 Global action `CEAP also cals for the introduction of regulatory measures such as extended producer responsibility (EPR) asa further step. [9,p. 13] EPRis an approach that ensures that producers contribute financially o the costsofwaste management. "Thatis, EPR obliges producers to take operational or financial responsibility forthe end-of-life phase of their products, creating incentives for better design to reduce these costs. Monetary contributions are then incurred, for example, for the separate collection and treatment of waste, with the costs of individual products or product groups being assessed taking into account durability, reparabiliy, reusability and recyclability, as well as the presenceofhazardous substances. [47] Euratex also points out in is position paper that the EPR of textiles should enable acircular economy through cooperation and shared responsibility. The circular economy requires partnerships in which the existing barriers to closing the loop are jointly solved insteadof shifting responsibilities. To achieve this, the EPR should support collaborations that aim to: e.g. enable the flowof information and data, establish a mutual understanding of circular design, support material pooling, eliminate conflicting rules, link demand and supply of recycled materials. [48] Garment companies using PTEE laminates will not be able to comply with circular economy requirements on producer responsibility. 45 BEST PRACTICE - wear2wearTM Cooperation In compliance with all four aspectsof the CEAP - 1. sustainable design and production, 2. sustainable use and application, 3. from the point of view of recyclabilty and waste reduction and 4. including producer responsibility and cooperation promotion, the European cooperation wear2wear" was set up. Behindwear2wear are well-known European companies that have set themselves the task of producing new textiles exclusively from recyclable and unmixed materials. New functional textiles are produced from textile fibres of used clothing on state-of-the-art production facilities. Depending on the area of use, these meet high requirements such as waterproofness, breathability, protection and comfort, In order to close the raw materia cycle, these textiles can be fully recycled again at the endof their ie cycle. In January 2020, the world's frst upcycled functional jacket "rEvolution Hybrid" made from 30% recycled used textiles and 70% recycled PET bots was presented - a 3-laer high-performance jacket. 17 RECYCLING OF FUNCTIONAL TEXTILES I offers certified rain protection according to EN 343, is environmentaalnldy skin friendly and tested according to the strict environmental standards STANDARD 100by OEKO-TEX" and bluesign'. `The manufacturing processofthe rEvolution Hybrid worksa follows: Largely unmixed waste polyester (PES) textiles are mechanically dissolved, processed into granules by mechanical or chemical recycling processes and spun out into new PES filament yarns. These yarns are processed into textile polyester fabrics and laminated witah 100% recyclable PES membrane to create a single-grade, recyclable, highly functional and 100% waterproof functional textile. The percentage of recycled old textiles in the Evolution Hybrid products already amounts to 30%, the remaining 70% is supplemented by PET bottle polymer yarns and can be diluted to a spinnable concentration in the future by equivalent upcycling processes and thus gradually disappear from the recycled textiles. The aim is to increase the proportion ofrecycled old textiles to 100% in the medium term. "The Design2Recycle concept is based onaselectionofmateritahalt sas pureas possible in combination with pure, recyclable ingredients as well as environmentally friendly finishing and dyeing agents. By using special sewing threads, non-recyclable ingredients can be removed ina cost- and material-saving Way to ensure an optimised recycling result Through adequate marking, wear2wear" products can be made traceable and transparent for the consumer as well as for process partners. These are to be optimised by expanding existing collection systems with forward-looking sorting technology. The collection of worn clothing in the leasing businessoroccupational safety sector can also be guaranteed via a wear2wear partner. After collection by existing clothing collectors, sorting and separation, these are sent to the wear2wear" upeycling network, which enablesreuse again through a combinedupcyclingprocess. After raw material reprocessing, PES lament yarn is thus produced again, which is processed into new upcycled polyester fabrics. The wear2wear" cycle is closed - a new, sustainable functional textileis created. [49] 18 CO2 EMISSIONS OF TEXTILE MEMBRANES 5 CO; EMISSIONS OF TEXTILE MEMBRANES Act before you have to. patricia Espinosa Cantellano, Head of the Secretariat of the United Nations Framework Convention on Climate Change (UNFCCC), Speech KeyNote at the Global Member Meeting FICCA, October 2020. "The textile industry is theseconddirtiest industry in the world- tis already responsible forover 8% of all CO; emitted worldwide, about as much as the entire EU. Ofthis, 83% COs is emitted by the clothing industry and 17% by the footwear industry. I lef unchanged, this figure will rise by over 60% by 2030. 03) "The United Nations has already become aware of these abuses. On 10 December 2018, the Fashion Industry Charter for Climate Action (FICCA) for the apparel industry was officially launched at the COP24 global climate conference in Poland. It includes a list of targets agreed by representatives of major apparel brands, led by the UNFCCC, to mitigate the climate impacts caused by this industry. This includes reducing CO: emissions by at least 30% by 2030, and has since been tightened to 45% by 2030 to meet the 1.5C climate target. 50] While some companies are beginning to record and reduce emissions in the wakeofthe FICCA, there are also pioneers who have already been accounting for their emissions for several years, reducing them in line with the Science Based Targets (SBT) and even offseting them. Emission databases form the basis for recording emissions. The emission valuesof the databases differ greatly in some cases, depending on the system boundaries, the type (primary data, generic data) and methodof data collection (e.g. GHG Protocol) and the timelinessof the data. The textile companies and platforms work with a wide varietyofagencies and tools to determine emissions. In the textile industry, the Ecoinvent and Gabi databases often form the basis for his. With regard to PTFE, the emission factors of Ecoinvent and Gabi are strikingly different. While Ecoinvent calculates 127 kg COv/kg PTEE (2016), Gabi calculates 11.6 kg COy/kg PTEE (2018). PESbased membranes cause a comparatively low 3.5 kg CO/kgofmaterial. `The conversion of the PTFE value from Ecoinvent to GaBi within the SAC material database Higg MSI (Material Sustainability Index) in 2020, in whose core group a well-known PTFE manufacturer is located, therefore aroused particular interest. To clarify the large difference between the two values, both databases were contacted by third partes, although GaBi was unable to provide any information. The only information provided was that the data came from the fluorine manufacturers themselves and was subject to confidentiality. [51] "This step is remarkable against the background of the goals of FICCA and its now more than 100 signatory clothing companies, since low-emission materials are to be given preference. 52, pp. 3, point 61] The comparability and transparencyofemission factorsofdifferent textile material thus becomes of central importance. Sometimes, because materials accountforan averageof85%of the emissions caused in the garment. * "For transpvioasrhitp. ruck; as soonasproductsar transported byai, the logistics share increases 19 `CO2 EMISSIONS OF TEXTILE MEMBRANES 5.1 PTFE data collection and global emission factor Tcohmeptarnacieeasbioliwtny aannddcgreadlibialbiltyatoifodnastaobasreedvuacleueCspOlaeymsisasniionncsr.easingly important role in the context of As described in the introduction, the PTFE emission factors of the Econinvent and GaBi (Sphera) d{haetaEbxasaeisveunsetdainndtGheatexvtilae ssec(tsocrAdpifpfeerngrdeaitlyc.haDpueert7o.this, an expert opinion was prepared to assess. This expert opinion by the environmental consultancy Oko-Recherche' shows that the country-specific emissionsof PTEE production plants and their precursors vary greatly. he table blo lal hows that cision factors range fom 126k CO kg PTFE in Japan to 294.1 kEgurCopOekangvaPlTueE,EwhineCrhienat.heTphreocveaslsuiengoffo1m1.6rkwgCtOye/ikglPoTFPETgFiEvenmebmybGraaBnie (aSpoherae)llrcefteerds to the Te PEol Com a [r[ opmotJ eg aw a[lima isono2rn| fT Eum rop bono uOsA wn] sau [CIonmdupso arsonchina2i 0h5o01R5o| naa] ou] Thisexplanations so providd bytheSACfortheHigg MST PTFE alu writing."Sphers has worked with Europe's main producers of PTEE more recently (reference data of 2018), so we have more confidence in this data overall, However, since the dataset was produced using production data from Europe there could be differences amongst global production that are not reflected in this dataset. As with all Higg MSI process data, we will continue to review feedback and data sources to make sure that best available and most appropriate information is being reflected in the Higg MSL" [53] However, there is no basis for such confidence in the Sphera data, and thus the MSI value, as scientific studies apparently refute the possibilityof such a low global PTFE value. Short explanation: The high emission values of PTFE depend almost exclusively on the by-product emission HFC-23 (R23), which is produced during the manufacture of chlorodifluoromethane HCFC. (R22), which is a precursor in PTFE production. The by-product R23 has a comparatively very high `emission value of 14800 kg CO/kg material. [11] T"peesifornTorwneiowoo eoloyeisemfafsofsrpaptionnhal mabhonodanmdiionng icon andtheperaofmtr owsesandserioon hsepis 0 (CO2 EMISSIONS OF TEXTILE MEMBRANES HFC-23 emissions rise significantly According to an article in the "Nature journal, global HFC-23 emissions, derived from atmospheric concentration measurements, are currently increasing significantly. This is explained by the HCFC-22- related emissions. [54] As the figure below clearly shows, the values for developed countries are decreasing; however, in developing countries, the values for HFC-23 emissions are increasing massively, at the same rate as. HCFC-22 production. af Emm oh a ---- =Ssoottoo amneeopnsccaanntt w10ishstaommaen 7 18 1.2". cores Dovokpedcounties (UNFCCC) ae yi bf + =+ +Downopingcounes crc-zzprosucion 161200000 poes on trecucoions 51 y 1/11) k (hl) Sul 47 A 8cse SX O oin3 0 iflfi $10 oz g . J 7 Wi dels on - 4 x6 . 3 ii TM. 0 2 ere Te, . booott - TS5s 980000+|"+- +- +-cDoouopmegscumin -7 No\, iT PEST TM ' 0 o g5mw0o0 EE--- Te- 1990 19% 1998 2002 2006 2000 2014 2018 Year Figure Global HFC-23 sionsand HCFC 2 production [54] One explanation for this is the relocation of production to developing countries. For even if hightemperature incinerators for HCF-23 were added to HCFC-22 plants there by companies from the 21 `CO2 EMISSIONS OF TEXTILE MEMBRANES industrialised countries (for which those companies were issued enormous CO certificates, i. earned a lot of money), it can be assumed on the basisofthe concentrations measured in the atmosphere that the additionally high energy expenditureof these incinerators may have led to them not being put into. operation. [55]This can be seen in the figure under CDM period (Climate Developing Measurements). PTEE production capacities in China, India and Russia over 50% This goes hand in hand with the country-specific PTFE production volumes. In 2020, over 41%ofglobal PTFE production took place in China, over 8% in Russia, 4% in India and 15% in the USA. [21] Assuming that the production sitesof the PTFEprecursors and the resulting PTFE are manufactured in opneelcocatpiroond,utchteioconunvtorlyu-mspeesci0ficfoErFms degtleorbmailnaesdcrbaygOekvoa-lReuceheTrchheawbeerebceallocwultathesd wsihtohwtshethceougnltorby]- PTFE value of 176.6 kg COx/kg PTEE, which is similar to the order of magnitude of the Ecoinvent emission factor. [C Gm apni ew|T wweas[lsowesmmimo s| fS T os E E n T esET] uel f[ m ea es om] f(i[ rnrdeeevuegobs |e|a [ee m] nul As can be seen from the expert opinionofthe environmental officeOko- Recherachmoer,e precise data situation is desirable in all countries except Europe and Japan. However, against the background of massively increasing R23 emissions and the shift of production to developing countries, it is presumptuous to calculate PTFE membranes with European emission values (see GaBi/Sphera as well as MSI/ SAC) and compare them with other membrane materials. Bmaesmebdraonnetshehasviemiloanr vaavleureasgefr3o0mxEchoiighnevrentCOa,ndemOiksos-iRoencshesrocmhep,arietdcatno bteecahsnsicuamleldy tchqautivPaTleFnEt functional materials. Calculated on a single functional jacket, this causes twice as much CO; by choosing a PTFE membrane than alternative membrane materials such as PES. ShthemTote sontphsoftos atanolhooPbTFEopndruoycGsotSs anhd rrclproeductdionrsiossascutre, ht tog 5 lars the 55 and ure. proc bth RFE a pcos and PhTFEeFo)procs 7EF Europe + USA (based on assessmentof Oko-Recherche, Dr. Winfried Schwarz) * EF China (based on assessment Oko-Recherche, Dr. Winfried Schwarz) 2 CO2 EMISSIONS OF TEXTILE MEMBRANES 5. BEST PRACTICE: biomassed-based PES membrane PES membranes havea low emission factor of 3.5 kg CO kg material acrossall databases. Furthermore, the use of bio-based plastics from waste streams is already available on the market. Biomass-based plastics even have the advantageofgenerating new plastics from waste and thus saving CO; emissions in PES membrane production at the same time. 3 CONCLUSION 6 CONCLUSION "This report proves on the basis of numerous studies and sources that the production, use and disposal of PTFE membranes have harmful effects on health and the environment. Research results from recent years show massive increased cancer rates and other adverse health effects in the vicinity of PTFE production sites worldwide, not taking into account that the worldwide spread ofthis "eternal chemical" also causes reference values to ris. The Western fluorochemical industry has shifted the problem around PFOA to Asia. At the same time, it is apparent that the PFOA substitutiesn use in the EU, suchasGenX and Adona, are also substances ofvery high concen. Thus, none of the current manufacturing processes for PTFE membranes are sae for health and the environment, Further studiesalso indicate that PFOA, but also PFOA substitutes, migrate from the PTFEmembrane and can affect thebody via dermal absorption, as can dusts containing PFAS. Research results also indicate that even modern analyticalmethodsdo not allow foar complete detection of PFAS despite high sensitivity. One study, for example, showed that only 19%ofthe total fluorine quantity could be detected. Precursors and oxidation intermediates are difficult to detect in trace analysis. These can also be transformed into hazardous substances such as PFOA by external influences such as exposure to sunlight, advanced oxidation processes or microbes. In addition to their hazardous and environmentally harmful aspects, PTFE membranes and fluorocarbon-containing laminatesaredifficult to recycle. The report sated that due tothe laofpcurikty of PTFE membranes, they cannot contribute to the fulfilment of the objectives of the European waste policy. Another study shows that in contrast to other textile membranes, high levels of highly toxic hydrofluoric acid and hydrochloric acid were measured exclusively when PTFE membrane material was incinerated. It an be assumed that clothing companies using PTFE laminates cannot comply with the circular economy requirements for producer responsibility. Greenhouse gas emissions from the production of PTFE membranes are also relatively high. PTFE membranes have 30x higher CO; emissions compared to technically equivalent functional materials. `The useofPTFE membranesthus contradicts the aspiratoifotnhse Montreal Protocol 2016, which aims for a global reductionof 85% in hydrofluorocarbon emissions. For more than five years, scientists worldwide have been calling for PFAS substances to be replaced wherever possible. The report conclusionsas, well asenvironmentally friendly and health safe alternative materials such as PES membranes proven for decades, cal for PTFE membranes in the apparel and footwear industry to be classified as non-essential use. The Netherlands has already accepted a corresponding motion to use alternatives for clothing and footwear for public procurement in which there is no GenX and PFOA usedfor the membrane. In the course of the EU Chemicals Strategy for Sustainability and as a forerunner to the envisaged American PFAS legislation, the EU MemberStates and the EU Commission should lead by example, classify PTEE membranes as non-essential for the general textile and clothing industry, and ban their use. The cat-and-mouse game between legislators - to ban a specific PFAS substance and the fluorochemical industry- o circumvent the ban with a harmful substitute- could thus be ended, at least for these areasofapplication. Tt would be a simple yet immense lever for better health protection and environmental sustainability through optimised circular economy, reduced CO; emissions and pollutant reduction. 2% ANNEX - Oko-Recherche expert opinion 7 ANNEX - Oko-Recherche expert opinion `Oko-RFeranckfuhrt (eMarin)c, Ghereman,y Research: On the climate-relevant HFC-23 emissions In the Industrialized `countries Inrelationtothe productionofHCFC-22 andPTFE Requirfeormthee sneatrcsh tisassumedthatthePTFEproductionrelevantfortheapplicationin questionislocatedin industiaisedcountriesandthattherawmaterial HGFC-22isalsosourcedfrom industrialised countries(excludingRussia). Therefore,wehavedeterminedtheemissionfactor"HFC-23 `emitted / HCFC-22produced"fortheindustriallydevelopedworldregion.Thismeansspecific figuresfor 1)Europe(excludingRussia),2)USA,3)Europe + USA,4)Japan,5)Europe + U+SJapAan. tisassumedthattheUSAplaysanimportant oleforthecompetionofPTFEusers. Data procurement Uniikeforthetechnicallyoptimalemission factoralreadyreported(asingleplantinthe EUwith `correspondingoperator data),wehavenowcalculatedthe valuesnoton aplant-specificbasis. "Thiswasnotonlyimpossible,butalso unnecessaryforthepurposeathand.Thisisbecause thegovernmentsofindustrialisedcountriesareobliged underinternationalagreementsto determine andreportHFC-23emissions.Sincetheyhave toreport,but thecompanies themselves arenotsubjectto anyobligation toprovide information,butratherrepmoorre otf less voluntary,the qualtyofthe data can certainybecriticised, especialysince there are differenttechnicalprocedures forwastegastreatmentwithdiferentdegreesofefficiency (e.g. onsiteoroffsitedestruction). Ontheotherhand,thedataonwhichouressarchisbasedare allquasi"governmental", whichmeansthat,first,theyarecertainlynottoohigh and, `secondy,theyarereliable inthediscussion. DatasourcesforHFC-23and HCFC-22 Fortheemission factor "HFC-23emitted / HCFC-22produced"informationonHFC-23and information on HCFC-22 is required. HFC23 Under the UNFCCC(UnitedNations ClimateChangeConvention),industrialisedcountriesare requiredtosubmitannualnationalgreenhousegas (GHG)inventoriestotheCimateChange Secretariat, including emissionsof HFC-23,whichare climate-relevant,andwhichconsistof theNational InventoryReport(NIR) andthe CommonReportingFormat(CRF)foreach `country. ThelatestreportsalldatefromAprifMay2019 and containdataunti2017,whik the reportsfor 2018arecurrentlybeing preparedand willbesubmitedtothe GiimateSecretariat inspring2020.Datafor2018 and 2019arenotyetavailable.However,nosignificantchanges areexpeatcthtatteimde. prHoodwuecvteiro,nwvoelhuamvee)bceocmaupsleetthaeexoclpudeed (rcOekroataRietnchpeolracnrherosmatsheyocualaclurelaadtyioknno.wa,lsdoewcitthy tihnevoHlCvFCe.i2n2the eprmoivsesiroeansroenapbolryotefidtnihbgelEeJmaenadsuGreemmaennyt)s ohrasesrteipmoartteesd seroemissions*(or yearsand persistently refuses to 2s ANNEX - Oko-Recherche expert opinion WehaveevaluatedtheNational InventorySubmissionsfor2010to2017foral industrialized c`Sopuanitnr,ieUsniinteqduKeisntgiodno,mn,aUmneiltyedFrSatnatcees,.GTheersmeanayr.e EthuerionpdeuastnrUinaiiozne,dNcoeutnhterrileasnidns,wIhtailcy,hJHaGpFaCn-, 22plantswere/arestil existing after2010. Atpresent,thereareonlyfourmanufacturersin Europeexcluding RussiaandonlytwointheUSA.Wehavenotcollectedanyinformationfor Japan.Thenumberofcompanies (twoofwhichproduceboth intheUSAandintheEU)has decreased drasticallysince2009,whenitbecame apparentthat R-22couldnolongerbe marketedas arefrigerantfor longtime,butwouldonlybepermittedas "feedstock",ie.further processingintoPTFE. (Incidentally, somecompanies thatclosed downplants inthe industrializedcountrieshaverebuilt such plantsinChina). HCFC-22 AllcountriesreportinCRF (table 2(I), B.9)their"HFC-23by-productemissions"from "fluorochemicalproduction",partly alsointhecorrespondingNIR.Thelattersometimesalso containinformationontheproduction ofHCFC-22,forexampleinJapan.TheUSAonly reportedHCFC-22productionuntil2012becausethereareonlytwo companiessince 2103 `andtheminimumnumberofcompaniesrequiredtoreport sthree.ThesixEUcountriesin oqzuoenset-idoenp(loentliynfgosuurbsstiancnece2t0h1a6t)fadlolsnuontdpeurbtlhisehjutrhiesdiirctHiConFCo-ft2h2perMoodnutcrtieoanl.PrHotOocFolC,n-oits2tah2ne CCloimmmiastsieoPnr,otochoel.yAlthouremai ghtherfeleevdantcompanydata mustbereportedtothe European However,wedohaveaccessto alistthatwaspresentedtotheMultateral Fundunderthe MontrealProtocolatthe27thMeetingin BangkokonJuly27,2017 -withthe HCFC-22 productionfiguresfortheindustrializedcountries(=non-Artcle 5parties)as awholeandby individualdevelopingcountries (=article 5parties)with HGFC-22production,namelyChina, India, Argentina,Mexico, VenezuelaandthetwoKoreas.In2014and2015theindustrialized countriesproduced225,000 teach,thedevelopingcountries 700,000t, withChinaalone `accountingfor600,000t. HFG-23 emissionsareestimatedinthisproposalonlyfordeveloping countries,althoughitisnotedfor Chinathatonly45%ofthe HCFC-23generatedwas "destroiyn2e0d15". Asfarastheindustrializedcountry groupsareconcerned,wecandeterminetheir HCFC-22 relativelywell. The(accordingto NIR)producedquantitiesforJapan are, asmentioned, accessible.Theproductionofthe EU countriesisknowntousinconfidenceandhas been roundedtothei size. BysublractingtheJapaneseandEUquantiiesfromtheBangkok estimatefortheindustrialisedcountries (non-artile 5parties)as awhole,wewereableto deduce the missing US quantities,whichhave notbeenreported since 2013butconfirmed our own estimate. GWP14,800 RegatrhecdaliculnatigonmethodoftheGWPused:Allnational submissionsusethe HFC-23 GWPof 14,800,whichistakenfromthe4th IPCCAssessmentReport(AR)of2007 (formerly 2 UNEP Uweltprogramm der Vereinten Nationen): AUSSCHUSS FURDEN MULTILATERALEN FONDS ZUR UMSETZUNGDESMONTREALPROTOKOLLS, Neunundsiebaigste itzung, Bangkok, 3.7. Ju 2017. SwCHsLOSSELASPEKTE IMZUSAMMENHANG MI HEC:23 NEBENPRODUKTKONTROLLTECHNOLOGEN (BESCHLUSS 2 ANNEX - Oko-Recherche expert opinion `GWPof 11,700from AR2). GWPvalueschangeovertimeforreasonsnotdiscussedhere. Thereis anewvalueof 12,400since2014 (ARS),butwewillsticktothegeneralUNFCCC asse reps orts valm ueoe f1n 4,80t 0. Theresuinldettasil Refe valr uee kgn HCFcC-e 22 [ TAewemiar Cworasazn| [sa woo | mw | [i[npduastnialcouriresexcl Russa| [Forcomparson Gina2013-2016 | ootsas0 | | osamss || 228 1 170 | Thedifferencebetween the EUandtheUSAisstriking.Thedata arerobust,however. The highUSvalue isdue, amongother things,toone ofthetwo manufacwthiucrhdeoerssno,t operate an onsite-waste-gastreatmentplantitself, buthasthecollected HFC-23destroyed offsite, thus requiring refillingand transport. Anotherinterestingaspectforall industrygroupsisthecomparison oftheaveragevaluefor 2012-2017withthe2017value.Itshowsthatsince2012thereisnoreductionin emission factors atall,butonthecontrary an increase.Nevertheless, withregardtotheyearsbefore. 2009, emihs avs efai lleo nshn arpls y. Bytheway,for industrializedcountries ingeneral,the KEY ASPECTS RELATEDTO HFC-23 BY-PRODUCT CONTROL TECHNOLOGIES mentioned above no longer expect a 3% formationrate of HFC-23in HCFC-22production,butonly2%thanksto improvedprocess control.This questionhadarisenin connectionwiththe"preliminarystudy". Optimalefficienciesoftheexhaustgastreatmentarereportedfrom Japan with99.8%. Reference valuePTFE The emifas ctors srei lato edtn o1kg PTFEarehigherthanthe emissionfactors "HFC-23 emitted / HCFC-22produced(kg CO2eq /kg)".Ifoneassumesthedoublevalue(=2),the values inTable 1 double. [US seo0A | T eet | [pan oss | 1s | [Forcompanson China2013-206| 4s |sa | Achemically exact calculationoftherelation HCFC-22/PTFE(kg/kg) maybedifferent from 2/1,probablywith a slightly lower valuethan 2. 7 ANNEX - Oko-Recherche expert opinion Theoretically,thevalueisnot2,but 1.73.For a 1-PTFEmolecule (amemberofthePTFE chain,-CF2-) youneedoneHCFC-22molecule.Ifthemolarmassof HCFC-22(86.47g/mol) and 1-PTFE(50.01 gimol, 1/2TFE)istakenintoaccount,itfollowsthat1.73kgof HGFG-22 isreqpuerkigorf1e-PTdFE (1 kg 1-*P86.T47/F50.0E1). Inthiscase,thevaluesin Table 1wouldonlyhavetobe multipliedby1.73insteofa2d. Author:Dr.WiniriedSchwarz (Oko-Recherche) FrankfurtamMain,Germany,30.1.2020 28 REFERENCES 8 REFERENCES [1] A. Blum, . A.Balan, M. Scheringer, X. Trier, G. Goldenman, I. T. CousinsM,. DiamondT,. FletcherC,. Higgins,A. E. Lindeman, G. Peasle, P.d. VoogtZ,. Wang und R. Weber, The Madrid Statement on Poly- and Perfluoroalkyl Substances (PFASS)," Madrid, 2015. 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