Document axVznwrNEnb2kNq9rXBqBENa

U.S. DEPARTMENT OF LABOR Occupatfonal Safety and Health Administration MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) ,,, SECTION MANUFACTURER'S NAME CL /7 * V 1 emergency telephone no, fUC CGHr'ORATIOIT' 30^-755-3351 address (Number. Street, dry, State, and ZIP Codej Ninro. West Virginia 251^3 CHEMICAL NAME AND SYNONYMS Tributvl Phosphate CHEMICAL FAMILY Phosphate ester TRADE NAME AND SYNONYMS FORMULA (d,H90)3P0 SECTION II.. HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES. & SOLVENTS pigments Not Applicable X TLV (Units) ALLOYS AND METALLIC COATINGS TLV % (Units) BASE METAL Not appli< ab3 e catalyst Not applicable alloys Not applit :ab3 e vehicle solvents additives Not applicable Not applicable Not applicable METALLIC COATINGS Not ppli< abj e JFILLER METAL PLUS COATING OR CORE FLUX x i>ICw s "tP-1-- \ :abl e others Not appli; :ab3 e others Not applicable .culp.usr. r_u.iLEj'.u -"-'ijj ui/LLii.[ {ijOii ii'i4 rcrrST.tGLVbs'.osVi, -hast Tributyl Phosphate A.cute oral LD50 - 1.2 + 0.2o g/kg (rat) Acute derral LD50 - Above 10,000 ng/kg (rabbit) j V e J.S T-l UCWO -- l'iia,d ui cLll hlCif L xll J. Skin Irritation - Severe Irritant TLV % (Units) 10C ! None -'S.'VT-j- - SECTION III - PHYSICAL DATA BOILING POINT |F.) g L---- FVg VAPOR PRESSURE (mm Hg.) g 302F. VAPOR DENSITY EAIR=1) SOLUBILITY IN WATER g 23C. 2SF. 7.3cm 9-2 0.1? SPECIFIC GRAVITY PE RCcNT, VOLATILE BY VOLUME (%) E(Bl'AuPzOyBl miON RATE appearance and odor Colorless to light strav liquid 1 * 0.973 Nil 1 SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method uled) 3'30F CC extinguishing media CO2, dry chemical, fcam FLAMMABLE LIMITS Non-f1 amabl e special fire fighting procedures Full protective cloching Self contained breathing apparatus UNUSUAL FIRE AND EXPLOSION HA.7AdDS Slisrht '-hen emosec to heat or fl Lei Uel D0 087155 CONFIDENTIAL PAGE (1) (Continued on reverse side) Form OSHA-20 Rev. May 72 SECTION V - HEALTH HAZARD DATA threshold limit value 5 mg/cu meter for control EFFECTS OF OVEREXPOSURE . ,. . Central nervous system*exictory action, respiratory irritant, skin irritant. eve irritant EMERGENCY ANO FIRST AID PROCEDURES Eye - vash with water Ip run., skin - wash /with soap and water. Ingestion induce vomiting, call physician. Inhalation - Remove to fresh air, administer ' Oxygen and/or artificial respiration if needed. Call physician. STABILITY UNSTABLE SECTION VI - REACTIVITY DATA CONDITIONS TO AVOID stable incomPatabiuty (Mstencis jo e-oidj X HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMER 1ZA7 ION MAY OCCUR WILL NOT OCCUR Oxides of phosphorous CONDITIONS TO AVOID X . . * : SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION fSDSClf': Type) Not normally' nseaed* VENT ILATION LOCAL EXHAUST Gas mask, organic vapor cannisterz SPECIAL mechanical (General) PROTECTIVE GLOVES r.u.c.oer OTHER PROTECTIVE EQUIPMENT. OTHER G_ eneratl EYE PROTECTION * Safety goggles SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO 3E TAKEN IN HANDLING AND STORING TV-v CD tank ve-.ts, electrical grounds transfer OTHER PRECAUTIONS ' page (2) G? 0 530.540 DO 087156 CONFTDFNTT Al.. Perm OSHA-20 Rer. 72 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration Form Approvtd OMB No. 44*R1387 ( MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) SECTION 1 MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. FMC CORPORATION 304-755-3351 ADDRESS (Number, Street, City, State, and ZIP Code) Nitro. West Virginia 25143_______ CHEMICAL NAME AND SYNONYMS ____Trl"butyl Phosphate__ ______ CHEMICAL FAMILY Phosohate ester TRADE NAME AND SYNONYMS TBP FORMULA (CUH90)3P0 SECTION II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES, & SOLVENTS pigments Not Applicable X TLV (Unit*) ALLOYS AND METALLIC COATINGS TLV X (Unit*) base metal Not applii :abi e catalyst Not applicable ALLOYS Not applii :abl e vehicle solvents additives Not applicable Not applicable Not applicable metallic coatings Not applii iabi e FILLER METAL PLUS COATING OR CORE FLUX - appi< :abl e others Not applii :ab3 e others \ Not applicable f (ANIMAL TEST) INFORMATION....... Tributyl Phosphate Acute oral LD50 - 1.2 + 0.26 g/kg (rat) TLV X (Units) 10C None ? lie Acute dermal LD50 - Above 10,000 mg/kg (rabbit) Eye irriLuLion - Mild 'Lrranbient irritant--------------------------------Skin Irritation - Severe Irritant SECTION 111 * PHYSICAL DATA boiling point (f.) g knmiHg 282F. SPECIFIC GRAVITY (HaO-l) VAPOR PRESSURE (mm Hg.) g 302F. VAPOR DENSITY (A1R*1) 7.3mm 9.2 PERCENT, VOLATILE BY VOLUME (X) SOLUBILITY IN WATER g 25C . 0.1# appearance and odor Colorless to light strav liquid 1. 0.978 Nil 1 SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) 330F. CC EXTINGUISHING MEDIA CO2, dry chemical, foam FLAMMABLE LIMITS Non-flammable SPECIAL FIRE fighting procedures protective clothing L! ( Self contained "breathing apparatus UNUSUAL FIRE AND EXPLOSION HAZARDS Slight vhen exposed to heat or flame Uel PAGE (1) (Continued on reverse side) DO 087157 D0NFTD5NTTAI. Form OSHA-20 Rev. May 72 THRESHOLD L.MIT VALUE SECTION V - HEALTH HAZARD DATA 5 Bg/cu meter for control EFFECTS OF OVEREXPOSURE '' ' "' ' ~~ " " " TT ~ Central nervous system exictory action, respiratory irritant, skin irritant, eye irritant EMERGENCY AND FIRST AID PROCEDURES Eye - wash with water 15 min., skin - wash with soap and water, ingestion induce vomiting, call physician. Inhalation - Remove to fresh air, administer Oxygen and/or artificial respiration if needed. Call physician. 6 \ T r STABILITY UNSTABLE SECTION VI - REACTIVITY DATA CONDITIONS TO AVOIO stable 1NCOMPATABILITY [Mattrials Jo avoid,j X HAZARDOUS DECOMPOSITION PRODUCTS MAZAROOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR Oxides of phosphorous CONDITIONS TO AVOID X SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO SE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Absorb on inert material. WASTE DISPOSAL METHOD Bio-oxidation ,, SECTION VIII - SPECIAL PROTECTION INFORMATION RE5RIRATORY protection (Specify type) Not normally needed. Gas mask, organic vapor cannister.. ventilation LOCAL EXHAUST SPECIAL MECHANICAL (General) PROTECTIVE GLOVES Rub.ber OTHER PROTECTIVE EQUIPMENT. OTHER ,,Genera,l EYE PROTECTION Safety goggles - SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING __________Dry hr ftp-they on tank vents, electrical grounds during transfer OTHER PRECAUTIONS 00 087i58 confidential V PAGE (2) CPQ 9 30.540 Distributors The C. P. HALL Company 2500 CHANNEL AVENUE MEMPHIS, TENNESSEE 38113 901-948-8663 PR-S6 Form OSHA-20 R*v. M*y 72