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APPENDIX G WASTEWATER TREATMENT RELEASE DATA AND CALCULATIONS
SARA TITLE III, SECTION 313 1988 TOXIC CHEMICAL RELEASE INVENTORY
LAKE CHARLES REFINERY
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SAL 000006177
(conoco)
Interoffice Communication
TO:
Dave Kersey, Lake Charles Refinery
FROM:
Paul Steele, PED, Ponca City
DATE:
March 7, 1989
SUBJECT: SARA Title III, Section 313 - Wastewater Analysis
Composite samples of the Lake Charles Refinery's wastewater effluent are needed for analysis to support 1988 and future SARA Title III, Section 313 reporting. Several organic compounds and metals will be covered that are not normally tested under current EPA methods, but which are reportable under SARA 313. Attached is a list of the chemicals for which the analyses will be performed.
The Research Services Division will send a shuttle (ice chest) with sample bottles on March 10. Sampling and shipping instructions can be provided by Don Linder (ETN 442-4478) or Cynthia Quy (ETN 442-3326). A preliminary estimate of $900 has been determined for the volatile and semi-volatile organic analyses by RSD.
Please contact me if you expect any difficulty in meeting this request.
Paul E. Steele Chemical Engineer Environmental Process Engineering Division
lk att cc:
DFM:LUC:KLK:DDO:MMM:DEL:HLG Jack Cearley, Houston Brandt Butler, Lake Charles Refinery
File EV-1040.1
SAL 000006178
WASTEWATER ANALYSIS
A. Volatile Organics
Benzene 1.2-Dibromoethane 1.2-Dichloroethane Styrene Ethyl Benzene Toluene Xylene 1-Methylethyl Benzene Acetone
1,2,4 -Tr ime thlybenzene Cyclohexane Biphenyl Methyl Ethyl Ketone Methyl t-Butyl Ether 1,1,1-Trichloroethane Carbon Tetrachloride Methyl Chloride Dichloromethane
B. Semi-Volatile Organics (acidl
Cresol Phenol
2,4-Dimethylphenol
C. Semi-Volatile Organics (base/neutral)
Anthracene Naphthalene Pyridine Quino1ine
o-Toluidine 2,6-Xylidine Aniline
D. Metals
Aluminum Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt
Copper Lead Mercury Nickel Selenium Vanadium Zinc
Organic Lead (TEL, TML) Organic Manganese (MMT)
E. Alcohols
2-Me thoxye thano1 Methanol Butyl Alcohols Isopropanol
SAL 000006179
L J, ,1 INTERNATION, I TECHNOLOGY r f i CORPORATION
ANALYTICAL SERVICES
CERTIHCArE OF ANALYSIS
COHOCO-LAKE CHARLES REFINERY CONOCO, INC. P 0 DRAWER 1267 RE 346 PONCA CITY OK 74604 OAVE KERSET
Date: 04/18/89
Job Kuabcr: 449900
Work Order: A9--03-069
This is the Certificate of Analysis for the following saaples:
Client Work ID: NPDES SYSTEM OUTFALL *001 Date Received: 03/21/89 Huaber of Saaples: 1
Staple Type: SftOUNOVATER
WfiSTB
TABLE OF CONTENTS FOR ANALYTICAL RESULTS
PACES 3
LABORATORY * SAMPLE IDENTIFICATION A9"03-069"01 LC OUTFALL
Reviewed and Appro
Donnie L. Heinrich Laboratory Manager
American Council ol Independent Laboratories International Association ot Environmental Testing Laboratories
Amencan Association lor Laboratory Accreditation
_ , - nn
SAL 00OOU
IT Analytical Services 5307 Industrial Oaks Boulevard. Suite 160. Austin. TX 78735 (512) 892-6684 66II-69
Company: CONOCO-LAKE CHARLES REFINERY Date: 04/18/89 Client Work ID: NPOES SYSTEM OUTFALL #001
IT ANALYTICAL SERVICES AUSTIN. TX
Work Order: A9-03'069 Job Number: 449900
TEST MANE: PRIORITY POLLUTANT VOLS SAMPLE ID: LC OUTFALL
Results In
ug/L
DATE COLLECTED: 03/13/89 DATE ANALYZEO: 05/27/89
COMPOUND acrolein acrylonitrile
benzene carbon tetrachloride
chlorobenzene 1,2-dichloroethane 1,1,1 -trichloroethane 1,1*dichloroethane 1,1,2-trichloroethane 1,1,2,2-tetrachloroethane
chloroethane 2*ch(oroethylviny( ether
chlorofora 1,1-dichloroethylene trans-1,2-dichloroethylene
<200 <200
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
COMPOUND 1,2*dlchlocopropane cis-1,3-dichloropropylene trans-1,3-dichloropropylene
ethylbenzene ethylene chloride
ethyl chloride ethyl bromide broMoforn
broaodichloronethane dibronochloronethane trichlorofluoronethane
tetrachloroethylene toluene
trichloroethylene vinyl chloride
<10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10
Comments: A less than (<) Indicates the compound is not detected at the level indicated.
Page 2
SAL 000006181
66? 1-69
Coapany: COMOCO-LAKE CHARLES REFIHERT Oate: 04/18/89 Client Work 10: MPOES SYSTEM OUTFALL #001
IT ANALYTICAL SERVICES AUSTIN. TX
Uork Order: 89*03*069
Job Nuaber: 449900
TEST NAME: ABM PRIORITY POLLUT. EXTR
SAMPLE ID: LC OUTFALL
Results in
ug/L:
OATE COLLECTED: 03/13/89 DATE EXTRACTED: 03/24/89
DATE ANALYZED: 03/29/89
COMPOUND 4-Chloro-3-aethylphenol
2-Chlorophenol 2.4-Oichlorophenol 2.4-Oiaethylphenol
2,4-0 InltrophenoI 2*Methyl*4,6-0initrophenol
2-Mftrophenol 4-Hitrophenol Pentaehlorophenol
Phenol 2,4,6-Trfchlorophenol
Acenaphthene Acenaphthylene
Anthracene Benzidine
Benzol a)anthracene Benzo(b)fluoranthene Benzo(k)fluoranthene
Benzol a>pyrehe 8enzolg,h,i)perylene Benzyl butyl phthalate * B(sl2*chloroethyl)ether 8icl2-chloroethoxy)aethane Bisl2-ethylhexyl)phthalate Bis12* chloro isopropyl)ether 4-Bronophenyl phenyl ether
2-Chloronaphthalene 4-Chlorophenyl phenyl ether
<23 <12 <12 <12 <59 <59 <12 <59 <59 <12 <23
<12 <12 <12 <59 <12 <23 <23 <23 <23 <12 <12 <12 <12 <12 <23 <12 <23
COMPOUND Chrysene Dibenzole.h)anthracene Di-n-butylphthalate 1.3-01 chlorobenzene 1,2-Dichlorobenzene 1.4-Dichlorobenzene 3,3*-0ichlorobenzidine Diethyl phthalate Oiaethyl phthalate 2,4-Dinftrotoluene 2,6-Dinitrotoluene Di-n-octylphthalate 1,2-Diphenylhydrazine Fluorene Fluoranthene Kexachlorobenzene Kexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indenol1,2,3-cd)pyrene Isophorone Naphthalene Nitrobenzene N-Nitroso-diaethylaaine N-Nitroso-diphenylanine N-Nitroso-di-n-propylaaine Phenanthrene
Pyrene 1,2,4-Trichlorobenzene
<12 <23 <12 <12 <12 <12 <23 <23 <23 <12 <12 <23 <23 <23 <23 <23 <23 <23 <23 <23 <12 <12 <12 <12 <23 <12 " <12 <12 <12
Nitrobenzene-OS 2-Fluorobiphenyl
Terphenyl-014
Surrogate Recoveries 63X Phenol-06 63X 2 -Fluorophenol SOX 2, 4,6-T ribroaophenol
5% 26X 93X
i (<) indicates the coapound is not detected at the level
Page 3
SAL 000006182
Coapany: COMOCO-LAKE CHARLES REFIHERT
Oate: 04/18/89 Client Work IDs NPOES SYSTEM OUTFALL #001
COMOCO-LAKE CHARLES REFIMERT
IT ANALYTICAL SERVICES AUSTIN, TX
Work Order: A9-03-069 Jab lumber:..449900
A903069/01B
Saaple extracted out of 7 day holding tine. Staple received 03/21/89, 6 days after sampling.
Page 4
*
sW_ 000006183
6&7
t
Coapany: CONOCO'LACE CHARLES REFINERY Data: 04/16/89 Client Work IDs KPDES SYSTEM OUTFALL #001
IT ANALYTICAL SERVICES AUSTIN, TX
Work Order: A9-03-069
Job Nuober: 449900
TEST CODE 624
TEST NAME PRIORITY POLLUTANT VOLS
Priority Pollutant Volatiles
EPA 624-This Is purge end trap GC/KS aethod. The coapounds are separated by the gas chroaatograph and detected using a aass spectroaeter.
TEST CODE 62S
TEST NAME ASM PRIORITY POLLUT. EXTR
Priority Pollutant Extractables
EPA 62S-This GC/KS aethod deteraines seal-volat(le coapounds in an extract of aethylene chloride. An aliquot of the extract Is injected Into a gas chroaatograph with a aass spectroaeter as a detector.
Page S
SAL 000006184
602 <9
(conoco)
Facility NaTLmocg /(*Ke- dhfirlos Facility Address
Conoco Inc. Research and Engineering
Telephone No.
Transporter Name
FhjtrM
Transporter Address
environmental sample Chain of Custody and Log
No.001051
JF/ffes-s
Telephone No.
Facility SupervisorOwe. Kersey
Process Producingi SOeammpnllea / --,
NPDSS _SlcOuJ-U-U
Employee(s) Saimopling
>
Kersey
Other Employee(s) Handling
'
,
Sample I.D. No. and Description
Lc -030
U- - 031 - / OU _2
Lr -0 3/ - 3
V
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Ld-Osi - 7 *4 fT
Date
Time Sample Type
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5V So* *1
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?
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Method of Shipping
Special Shipping Instructions //)
Remarks
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Containers
J\
Analysis Req.
Total Volums Type
NO. Preservative
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Relinguished by
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Received by
Received by Received by Received by Received by
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=rrn TM7
)ate/Tima Vs-AlUyM
.,/ Paalta/Time
Conditio7n of f*
samples
upon
arrival
at
final
destination
mm. oS%
Data/Tima
Dflt hL
DateAlm* Tamo, of samples on arrival at destination (Temp, sensitive analysis only) t'^C_______________________________
Date/Time
DateAime Sigi^tur I______ /
IffTflPV
Date >,, v/y/r
ANALYTICAL SPECTROSCOPY REPORT
sterner: Cindy Quy
te Analyzed: 05/05/89
ke Charles Water mmunity Right--To --Know
its: mg/L
.J JUS
.rngle_#
IV901A40 Ui-Ot5 iV901441 L-OlL>
A1
<0.031 <0.031
Analytical #: 17380, 17381 Reference: ESICP #1 p. 191 Analytical Code: ESICP
Analyst: Pam Hill
Ba
0.0A3 0 035
Be
<0.006 <0.006
Cd
<0.016 <0.016
Cr
<0.031 <0.031
eg
<0. 11 <0.11
r. Std. ue Value
1 .2 1.0
0.97 0.99
1.0 0.96
0.38 0.3A
0.32 0.26
0.98 1.00
imgJLe_# JV901**^0 IV901AA1
;r. Std. ue Value
Cu
<0.016 <0.016
Ni
0.090 0.098
0.71 0.66
0.91 0.80
Sb <0.26 <0.26
0.99 0.99
V
0.050 0.051
Zn
<0.026 <0.026
1.1 1 .01
0.91 0.81
?por ted it
__ LLq*. ________
A.
sal oooq
6lQ6
WASTEWATER DISCHARGE SELF-MONITORING REPORT
CONOCO INC., LAKE CHARLES REFINERY
EPA I.D. NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF
January
, 19 88
TOTAL EFFLUENT, OUTFALL'OOI +TRJ7
Pollutant
Pounds Per Day, Unless Noted
Observed Limits
Permit Limits
Dally Max.
Dally Avq.
Dally Max.
Dally Avq.
No. Ex.
BOD COD TSS Oil & Grease Phenol Ammonia as N Sulfide Tot. Chromium Hex. Chromium pH, S.U. Flow, MGD
1227 7127
954 351 2.43 608 1.76 1.18 0.118
7.8 Max. 3.07
781 3168
484 119 1.45 409 1.23 0.98
0.098 6.4 Min. 2.40
2508
18772 1747 760 18.6 1663 16.4 37.8 3.0 9.0
--
Max.
1393 9740 1114
405 9.1 756 7.3 22.2 1.4
6.0 Min. --
0 0 0 0 0 0 0 0 0 0 0
Sample type and frequency is as specified i n the permit.
Concentration (mg/1)
Dally Max. Dally Avq.
66 335
43 15 0.143 28.5 0.098 0.05 0.005
--
--
40 159
24 6 0.076 20.8 0.063 0.05 0.005
--
--
SAL 0 0 0 0 0 6 1 8 7
I hereby certify that I am familiar with the Information presented here, and that it is correct and complete. ^ ^__ ^
Signed D.^rT 'UnruhV
Refinery Manager
Date 2-12-88
WASTEWATER DISCHARGE SELF-MONITORING REPORT
CONOCO INC., LAKE CHARLES REFINERY
EPA I.D. NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF
February
, 19 88
TOTAL EFF"L01NT"i""fillTFALL 001 +"05?
Pollutant
Pounds Per Day, Unless Noted
Observed Limits
Permit Limits
Dally Max.
Daily Avq.
Daily Max.
Daily Avq.
No. Ex.
BOD COD TSS Oil & Grease
Phenol Ammonia as N Sulfide Tot. Chromium Hex. Chromium
pH, S.U. Flow, MGD
2139 5603
998 439 6.44 500 4.95 1.32 0.132
7.9 Max. 3.16
1109 3471
487 162 2.16 395
1.79
1.02 0.102 6.4 Min. 2.50
2508 18772
1747 760
18.6 1663 16.4 37.8
3.0
9.0
--
Max.
1393 9740 1114 405
9.1 756 7.3 22.2 1.4 6.0 Min.
--
0 0 0 0 0 0 0 0 0
0 0
Sample type and frequency is as specified in the permit.
Concentration (mg/1)
Daily Max. Daily Avq.
91 227
41 20 0.244 29 0.188 0.05 0.005
--
--
54 168
23 8 0.105 20 0.085 0.05 0.005
--
--
I hereby certify that I am familiar with the information presented here, and that it is correct and
Refinery Manager
88X900000
EPA3: WASTEWATER REPORT FORM
DISCHARGE MONITORING REPORT
CONOCO INC., LAKE CHARLES REFINERY
EPA I.D. NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF
March
, 19 88
TOTAL EFFLUENT, OUTFA'lT'OOl +"W
Pollutant
T'ouncfs Per Day
Observed
Permit Limits
Daily Avq.
Daily Max.
Daily Avq.
Daily Max.
' No. Ex.
BOD COD
TSS Oil & Grease Phenol Ammonia as N Sulfide Tot. Chromium Hex. Chromium pH, S.U. Flow, MGD
1162
4259 656 254 1.64 482
3.20 0.89 0.089 6.5 Min. 2.207
1667 8788 1220
506 2.57
660 4.79 0.98 0.098 7.6 Max. 2.810
1393 9740 1114
405 9.1 756 7.3 22.2 1.4 6.0
--
Min.
2508 18772
1747 760
18.6 1663 16.4 37.8 3.0 9.0 Max.
--
0 0 0 0 0 0 0 0 0 0 0
Sample type and frequency is as specified in the permit.
Frequency of Analysis
3/week 5/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week Continuous Continuous
Sample Type
24 HC 24 HC 24 HC 24 HC 24 HC 24 HC Grab 24 HC 24 HC Grab Record
1 hereby certify tj^at I am familiar with the information presented here, and that it is correct and complete.
Date 4-15-88
Refinery Manager
SAL 000006189
EPA3: WASTEWATER REPORT FORM
DISCHARGE MONITORING REPORT
CONOCO INC., LAKE CHARLES REFINERY
EPA I.D. NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF
April
, 19 88
001total effluent, Outfall
+1TO2
Pollutant
Founds Per Day
Observed
Permit Limits
Daily Avq.
Daily Max.
Dally Avq.
Daily Max.
No. Ex.
GOD
COD TSS Oil & Grease Phenol Ammonia as N Sulfide Tot. Chromium Hex. Chromium pH, S.U.
Flow, MGD
1304
3945 728 131
2.59 400
1.34 0.78 0.078 6.6 Min. 2.14
2544
7199 1912
247 5.74
675 2.72
0.96 0.096
7.8 Max. 3.96
1393 9740 1114
405 9.1 756 7.3 22.2 1.4 6.0
--
Min
2508 18772
1747 760
18.6 1663 16.4 37.8 3.0 9.0 Max. --
1 0 1 0 0 0 0 0 0
0 0
Sample type and frequency Is as specified In the permit.
Frequency of Analysis
3/week 5/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week Continuous Continuous
Sample Type
24 HC 24 HC 24 HC Grab 24 HC 24 HC Grab 24 HC 24 HC Grab Record
1 hereby certify that I am familiar with the information presented here, and that It is correct and
SAL 000006190
EPA3: WASTEWATER REPORT FORM
DISCHARGE MONITORING REPORT
CONOCO INC., LAKE CHARLES REFINERY
EPA I.D. NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF
May, 19 88
TOTAL EFFLUENT, OUTFALL 001 +"W
Pollutant
Pounds Per Day
Observed
Permit Limits
Daily Avq.
Dally Max.
Daily Avq.
Dally Max.
No. Ex.
BOD COD TSS Oil & Grease Phenol Ammonia as N Sulfide Tot. Chromium Hex. Chromium
pH, S.U. Flow, MGD
986 4545
752 161 2.70 429 2.19
1.02
0.102 6.8 Min.
2.63
1874 8713 1346
252 5.14
623
6.29 1.20 0.120
8.0 Max. 4.25
1393 9740 1114
405 9.1 756 7.3 22.2 1.4 6.0
--
Min.
2508 18772
1747 760
18.6 1663 16.4 37.8
3.0 9.0 Max.
--
0 0 0 0 0 0
0 0
0 0
0
Sample type and frequency is as specified in the permit.
Frequency of Analysis
3/week 5/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week Continuous Continuous
Sample Type
24 HC 24 HC 24 HC Grab 24 HC 24 HC Grab 24 HC 24 HC Record Record
>0 0 0 o
I hereby certify that I am, familiar with the information presented here, and that it is correct and
? J2^>
Date 6-15-88
Refinery Manager
Os SD
EPA3: WASTEWATER REPORT FORM
DISCHARGE MONITORING REPORT
CONOCO INC., LAKE CHARLES REFINERY
EPA PERMIT NO. LA0003026 STATE PERMIT NO. HP 0432
MONTH OF
JUNE
, 19 88
TOTAL EFFTUENT,' OUTFALL''001 T15(52
Pollutant
Pounds Per Day
Observed
Permit Limits
Dally Avq.
Dally Max.
Dally Avg.
Dally Max.
No. Ex.
BOD COD TSS Oil A Grease Phenol Ammonia as N Sulfide Tot. Chromium Hex. Chromium
pH, S.U. Flow, MGD
728 3125
564 90
1.88 293
1.59 0.98 0.098
6.9 Min.
2.52
1393 5036 852
124 4.14
413 4.87 1.06 0.106 7.9 Max.
3.34
1393 9740 1114
405 9.1 756 7.3 22.2 1.4 6.0 --
Min
2508 18772
1747 760
18.6 1663 16.4 37.8 3.0 9.0 Max. --
0 0 0 0 0 0 0 0 0 0
0
Sample type and frequency Is as specified In the permit.
Frequency of Analysis
3/week 5/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week Continuous Continuous
Sample Type
24 HC 24 HC 24 HC Grab 24 HC 24 HC Grab 24 HC 24 HC Record Record
I hereby certl complete
am ^pnllar with the Information presented here, and that It Is correct and
Signed
Date 07-15-88
Refinery Manager
SAL 000006192
EPA3: WASTEWATER REPORT FORM
DISCHARGE MONITORING REPORT
CONOCO INC. , LAKE CHARLES REFINERY
EPA PERMIT NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF
JULY
, 19 88
TOTAL EFFLUENT, OUTFALL 001 T7RJ2
Pol 1utant
Pounds Per bay
Observed
Permit Limits
Dally Avq.
Dally Max.
Dally Avq.
Dally Max.
No. Ex.
BOD COD TSS Oil & Grease Phenol Ammonia as N Sulfide Tot. Chromium Hex. Chromium
pH, S.U.
Flow, MGD
865 4760
712 254 3.47 274 2.05 1.01 0.101
7.1 Min. 2.73
1228 8030 1378
734 5.60
468 3.77 1.08 0.108 8.9 Max.
3.23
1393 9740 1114
405 9.1 756 7.3 22.2 1.4 6.0
--
Min .
2508 18772
1747 760
18.6 1663 16.4 37.8 3.0 9.0 Max.
--
0 0 0 0
0 0
0 0
0 0
0
Sample type and frequency is as specified in the permit.
Frequency of Analysis
3/week 5/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week Continuous Continuous
Sample Type
24 HC .24 HC 24 HC Grab 24 HC 24 HC Grab 24 HC 24 HC Record Record
I hereby certify that I am familiar with the Information presented here, and that it is correct and complete.
Signed Pp
^ _ R. Unruh ^ Refinery Manager
___________ ___ Date 08-15-88
SAL 000006193
EPA3: WASTEWATER REPORT FORM
DISCHARGE MONITORING REPORT
CONOCO INC., LAKE CHARLES REFINERY
EPA I.D. NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF
AUGUST
, 1988
TOTAL EFFLUENT, OUTFALL 001 + W
Pol 1utant
Pounds Per Day
Observed
Permit Limits
Daily Avq.
Dally Max.
Daily Avq.
Dally Max.
No. Ex.
BOD COD TSS Oil & Grease Phenol Ammonia as N Sulfide Tot. Chromium
Hex. Chromium pH, S.U. '
Flow, MGD
1224 5437
968 322 2.765 240 2.616 1.05 0.105
6.7 Min. 2.81
2432 10635
2789 1224 5.058 472 10.140
1.27 0.127 7.6 Max.
3.55
1393 9740 1114
405 9.1 756 7.3 22.2 1.4 6.0 Min.
--
2508
18772 1747 760 18.6 1663 16.4 37.8 3.0
9.0 Max.
--
0 0 1 1 0 0 0 0 0 0 0
Sample type and frequency is as specified in the permit.
Frequency of Analysis
3/week 5/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week
--
--
Sample Type
24 HC 24 HC 24 HC GRAB 24 HC 24 HC GRAB 24 HC 24 HC
--
--
I hereby certify that I am familiar with the information presented here, and that it is correct and complete.
Signed PF fbt. D- R* Unruh Refinery Manager
________________
Date
9-15-88
SAL 000006194
EPA3: WASTEWATER REPORT FORM
DISCHARGE MONITORING REPORT CONOCO INC., LAKE CHARLES REFINERY EPA PERMIT NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF SEPTEMBER , 19 88
TOTAL EFFLUENT, OUTFALL 001 TMZ
Pollutant
Pounds Per Day
Observed
Permit Limits
Dai 1v Avq.
Daily Max.
Daily Avq.
Daily Max.
No. Ex.
BOD COD TSS Oil & Grease Phenol Ammonia as N Sulfide
Tot. Chromium Hex. Chromium pH, S.U. Flow, MGD
838 5782
754 315 3.44 378 1.74 1.05 0.105 6.2 Min. 2.91
1393
11392 1338 1773 4.52 599 3.27 1.12 0.112 7.6 Max.
4.80
1393 9740 1114
405 9.1 756 7.3
22.2 1.4 6.0 --
Min.
2508 18772
1747 760
18.6 1663 16.4 37.8 3.0 9.0 Max. --
0
0 0 1 0 0 0 0 0 0 0
Sample type and frequency is as specified in the permit.
Frequency of Analysis
3/week 5/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week
-- --
tSample Type
24 HC 24 HC 24 HC Grab 24 HC 24 HC Grab 24 HC 24 HC
--
--
I hereby certify' that I am familiar with the information presented here, and that it is correct and
complete.
.
x>
Signed
/vV^
Date 10-12-88
Refinery Manager
SAL 000006195
EPA3: WASTEWATER REPORT FORM
DISCHARGE MONITORING REPORT
CONOCO INC., LAKE CHARLES REFINERY
EPA PERMIT NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF OCTOBER
. 19 88
TOTAL EFFLUmrGUT'rcLL' 001 TT502
Pollutant
Pounds PeFbay
Observed
Permit Limits
Dai 1v Avq.
Dai 1y Max.
Daily Avq.
Daily Max.
No. Ex.
BOD COD TSS Oil & Grease Phenol Ammonia as N Sul fide Tot. Chromium
Hex. Chromium pH, S.U. Flow, MGD
871 3592
611 131 1.44 141 1.08 0.94 0.094 6.8 Min. 2.55
2076
9339 969 489
2.31 216 1.78 1.08
0.108 8.6 Max. 4.60
1393 9740
1114
405 9.1 756
7.3
22.2
1.4 6.0 Min. -- '
2508
18772
1747 760
18.6
1663 16.4
37.8
3.0
9.0 Max. --
0 0
0 0 0 0 0 0
0
0 0
Sample type and frequency is as specified in the permit.
Frequency of Analysis
3/week 5/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week
---
Sample Type
24 HC 24 HC 24 HC Grab 24 HC 24 HC Grab 24 HC 24 HC
---
I hereby certify that 1 am^familiar with the Information presented here, and that It is correct and complete.
Signed Df R. Onr'uh Refinery Manager
Date 11-15-88
SAL 0 0 0 0 0 6 1 9 6
EPA3: WASTEWATER REPORT FORM
DISCHARGE MONITORING REPORT
CONOCO INC., LAKE CHARLES REFINERY
EPA I.D. NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF
NOVEMBER
, 1988
total effort; OUTFALL" 001
Pol 1utant
Pounds Per Day
Observed
Permit Limits
Daily Avq.
Daily Max. Dally Avq.
Daily Max.
No. Ex.
BOD COD TSS
Oil & Grease Phenol Ammonia as N Sulfide
Tot. Chromium Hex. Chromium
pH, S.U. Flow, MGD
1091 3987
796 108 1.846 389 1.175 0.95 0.095 6.4 Min.
2.58
1948 8438 1833
223 3.320
862
3.073 1.08
0.108 7.9 Max. 3.26
1393 9740 1114
405 9.1 756 7.3 22.2 1.4 6.0 Min.
--
2508 18772
1747 760
18.6 1663 16.4 37.8
3.0 9.0 Max.
--
0 0 1 0 0 0 0
0 0 0
Sample type and frequency is as specified in the permit.
Frequency of Analysis
3/week 5/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week 3/week
--
Sample Type
24 HC 24 HC 24 HC GRAB 24 HC 24 HC GRAB 24 HC 24 HC GRAB/Cont. Cont. Record
0000061
*/>
>r
-o -4
I hereby certify that I am familiar with the information presented here, and that it is correct and
complete.
/O ^ s
Signed D.R.UhrJh"/ Refinery Manager
Date December 15, 1988
EPAj. WASTEWATER REPORT FORM
o
10 r
oooo wsO CD
DISCHARGE MONITORING REPORT
CONOCO INC.* LAKE CHARLES REFINERY
EPA PERMIT NO. LA0003026 STATE PERMIT NO. WP 0432
MONTH OF DECEMBER
. 19 88
TOTAL EFFLUENT"," OUTFALL '001 TTJ52
Pol 1utant
Pounds Per bay
Observed
Permit Limits
Daily Avq.
Daily Max.
Daily Avq.
Daily Max.
No. Ex.
BOD COD TSS Oil l Grease Phenol Ammonia as N Sulfide Tot. Chromium Hex. Chromium
pH, S.U. Flow, MGD
473 3967
517 84
1.75 509
0.94 0.97 0.097
6.3 Min. 2.65
830 5989
648 189 2.93 1142 1.37 1.05 0.105 7.4 Max. 3.37
1393 9740 1114
405 9.1 756 7.3 22.2 1.4 6.0 --
Min.
2508 18772
1747 760
18.6 1663 16.4
37.8
3.0
9.0 Max. --
0 0 0 0 0 1 0 0
0 0 0
Sample type and frequency is as specified in the permit.
Frequency of Analysis
Sample Type
3/week
5/week 3/week 3/week 3/week 3/week 3/week 3/week
3/week 3/week
--
24 HC 24 HC 24 HC Grab 24 HC 24 HC Grab 24 HC
24 HC Grab/cont Cont. record
I hereby certify that I am familiar with the information presented here, and that it is correct and complete.
Siqned 0---e L-----
D. R. Unruh
^
Refinery Manager
Date 01-15-89
EPA3: WASTEWATER REPORT FORM
REVISED VOC EMISSION FACTORS FOR REFINERY WASTE WATER SYSTEMS
Based on more recent information, we suggest the following emission
factor.
Source:
"VOC Emissions From Petroleum Refinery Wastewater
Systems - Background Information For Proposed Standards" Preliminary
Draft July 1984.
I. API Separator
AP-42 emission factors: Uncontrolled Controlled
5.0 0.2
lb/103 Cal. lb/103 Gal.
Revised Factors: Uncontrolled Covered
Covered w/Vent to Vapor Collection System
Air Flotation Systems
f
<420kg/M Gals.) (85Z Control)
0.93 0.14
lb/103 Gal. lb/103 Gal.
(97Z Control)
0.03
lb/103 Gal.
(
AP-42 Emission Factor Dissolved Air Flotation (DAF)
0.01
lb/103 Gal.
Revised Factors:
Dissolved Air Flotation (DAF)
Uncontrolled
(15.2 kg/M Gal.)
Cover w/Atmospheric Vent
(77Z Control)
Cover w/Vent to Vapor Collection System
(97Z Control)
0.033 0.008
lb/103 Gal. lb/103 Gal.
0.001 lb/103 Gal.
Induced Air Flotation (IAF)
Completely Uncontrolled
(15.2 kg/M Gal.)
Covered w/Doors Open
( 8.7 kg/M Gal.)
* Covered v/Doors Closed
( 3.0 kg/M Gal.)
Covered (Tight Seals)
( 2.3 kg/M Cal.)
Covered w/Vent To Vapor Collection System
( 0.45kg/M Gal.)
0.033 lb/103 Gal.
0.02
lb/103 Gal.
0.0066 lb/103 Gal.
0.005 lb/103 Gal.
0.001 lb/103 Gal.
* Typical TAP Operation
SAL 000006199
The data for Table A-2 were extracted from "Report to Congress on the
Discharge of Hazardous Waste to Publicly Owned Treatment Works", U.S. Envi
ronmental Protection Agency, EPA/530-SW-86-004, 1986. The following notes
apply to this table:
The data from this table apply only to secondary biological wastewater treatment plants receiving low concentrations (s 500 ppb) of the compounds listed. A number of design and operational factors will affect the fate of these compounds in any given treatment plant. These numbers are useful only as rough approximations of pollutant fate.
All percentages are based on influent loading. The original ref erence provided removals for volatilization and sludge partitioning as a percentage of overall removal. This data was translated to removals based on influent loading by assuming that all material not volatilized, transferred to sludge, or passed through untreated was biodegraded.
(Percent volatilized to air) + (percent partitioned to sludge) + (percent hiodegraded) + (100 - overall percent removal) * 100.
Percent biodegraded was determined by difference in the preceding equation.
The percentage which is discharged to receiving waters equals 100 minus the "overall percent removal" (percent discharged to receiving wastes = 100 - overall percent removal).
(Percent volatilized to air) + (percent partitioned to sludge) +
.(percent biodegrded) + (percent discharged to receiving waters) *
100
"Acclimated" represents those processes which receive a relatively steady amount of the pollutant in question, such that biodegradtion rates stabilize. "Unacclimated, Median and Low" refer to processes which receive unsteady or "slug" loadings of the pollutant in question.
A-12
SAL 000006200
TABLE
POLLUTANT
a-2. FATE OF HAZARDOUS ANO/OR TOXIC POLLUTANTS AT LOW CONCENTRATIONS IN SECONDARY, BIOLOGICAL WASTEWATER TREATMENT PLANTS
DVERAL
PERCEN r
PERCENT
I
3ERCEN ^EMOVA
VOLATILE! D TO AIR
PARTfTIONED
TO SLUDGE I
'ERCENT BidDEGRADED
1
ACCLIMATED UNACCl IMATED MEDIAN LOW
V. A V.
ACCLIMATEC UNACCL MATEO
MEOIAN LOW
/.
%
ACCLIMATED UNACCLIMATEO MEDIAN LOW
A A A
ACCLIMATED Unacclimated MEOIAN LCW
A "A %
2,4-D ACENAPHTHYLENE
ACETALDEHYDE ACETONE ACROLEIN
ACRYLAMIDE ACRYLIC ACID
ACRYLONITRILE ALDRIN ANILINE
ANTHRACENE ANTIMONY ARSENIC BARIUM
BEN2AL CHLORIDE BENZENE
BENGOTRCHLORIDE BENZYL CHLORIDE BIS-2*CHLOROETHYL ETHER 0IS-2-STHYLHEXYL PHTHALATE BROMOMETHANE BUTYL BENZYL PHTHALATE
CAOMIUM CAPTAN CARBON DISULFIDE CARBON TETRACHLORIDE CHLOROAN5 CHLCRC06NZENE
CHLOROBENZtLATE CHLOROETHANE CHLOROFORM CHLCR0ME7HANE
90 95 95 95 95 90 90 90 90 95
95 60 50 90 90 95 90 90 90 90 95 95 27 90 95 90 90 90 SO 05 90 95
60 50 90 90 95 95 SO 30 95 95 62 50 65 80 75 70 90 90 65 60 90 90 60 60 60 50 90 90 65 60 90 90 45 40 90 90 60 30 90 90 95 95 90 90 27 27 60 30 85 60 es 80 90 90 90 90 60 50 90 90 60 60 90 90
0 00
19 54 54
0 S5
0 32
0 55
0 00
0 00
0 44
0 00
0 00
0 00
0 00
0 00
0 00
0 17 16
24 72 72
16 14 12
23 45 45
0 32
0 00
86 90 90
0 00
0 00
0 00
76 77 72
72 77 72
9~
9
9
27 45 45
9 65
76 81 81
63 72 72
86 86 86
7 9 10 10 10 '9 9 "9
33 10 62 60 60 90
7 2
7_ 7 9 66 0 43 27 7 1 12 33 14 7 t 2 1
S4 88 10 10 53 10 10 66 98 87
33 33 98 60 SO 60 60 50 60 90 90 44 22 43 77 63 66 66 00 41 41 27 27 42 11 98 33 33 14 14 54 11 22 11
83 5i 46 67 28 20 85 81 St 65 43 26 65 81 81 81 56 45 61 77 72 81 64 60 57 57 57 86 77 72 43 41 41 0 0' 0 0 00 0 00 83 34 31 89 16 16 65 28 25 60 38 38 81 43 26 24 24 24 10 5 S 52 50 50
0 00 83 46 28 16 6 7 6 00 48 48 46 SO 32 32 74 49 41 18 8 8 25 6 6 9 44
SAL 000006201
(continued)
TABLE A-2 (continued)
0VERAU 5ERCN' =IEMOVA
iPERCEN r VOLATILE D
TO AIR
PERCENT PARTITIONED
TO SLUDGE
,l
Percent BK DEGRADED
POLLUTANT
ACCLIMATED JNACCl IMATED ACCLIMATED UNACCL MATED
ME0IAN LOW
MEDIAN LOW
/. /. V.
V. V. */.
ACCLIMATEO UNACCL IMATED MEDIAN LOW
V. % %
ACCLIMATED JNACCUMATED MEDIAN LOW
% % V.
A--14
2-CHLOROPHENOL CHROMIUM CRESCLS CUMENE CYANIDE
CYCLOHEXANE DI-N-BUTYL PHTHALATE DI-N-OCTYL PHTHALATE
DlBROMOM ETHANE 1,2*DICHLOROBENZENE 1.3-DICHLOROBEN2ENE 1.4-DICHLOROBEN2ENE 1.2-DICHLOROETHANE 1,1 -DICHLOROETHYLENE 2.4-OICHLOROPHENOL 1.2-DICHLOROPROPANE
DICHLORVOS DCOFCL
DIETHYL PHTHALATE 3.3-DIMETHOXY BENZIDINE
2.4-DIMETHYL PHENOL DIMETHYL PHTHALATE
2.4*0 INITROPHENOL 1.4-DIOXANE
EPICHLOROHYDRIN ETHYLBENZENE ETHYLENE OXIDE
ETHYLENE THIOUREA FORMALDEHYDE
HEXACHLORO-t .3-BUTADIENE HEXACHLOROETHANE HYDRAZINE
(continued)
65 70 65 95 60 95 60 60 BS 90 60 60 60 95 95 90 90 60 90 80 95 95 90 90 87 95 60 85 85 65 95 95
65 60 70 70 50 40 95 95 60 60 95 85 90 90 90 90 80 60 87 85 87 85 87 85 SO 30 90 90 55 60 70 70 50 30 90 60 75 70 30 20 85 80 65 60 75 70 50 40 69 26 00 90 60 40 67 60 85 80 90 90 90 90 85 80
0 00
8
0 00
70
0 00
8
38 67 57
4
0 33
57
10 86 86
4
0 0 0 20
O 0 0 17
43 64 64
13
45 78 77 w 32
45 76 77
3
45 78 77
23
45 45 27
5
76 81 81
0
0 00
8
45 63 63
0
0 00
9
45 45 45
8
0 00
1
0 00
8
0 00
8
0 0 0
0
0 00
0
0 00
9
0 00
9
24 72 72
6
0 32
9
0 00
9
0 44
9
0. 6 5 - 9
0 65
9
0 44
10
55 70 70 43 44 57 57 44 20 20 77 12 12 99 33 99 32 00 44 00 63 88
11 ...
32 76 00 87 54 63 S5 64 76 98 86 88 98
87 0 87 53 3 82 70 83 30 14 42 23 41 19 87 45 81 37 89 72 87 95 81 81 78 66 81 77 76 86 66 85
60 55 00 46 37 34 34 00 66 70 70 63 83 44 00 66 00 32 99 51 46 77 45 27 37 37 74 69 27 18 78 74 65 60 68 63 45 36 53 23 13 13 43 34 60 54 72 66 77 77 77 77 72 68
TABLE A-2 (continued)
POLLUTANT
OVERAL pERCEN 3EMOVA
iPERCENtT V01.ATILI2I: D
TO AIR
ACCLIMATED JNACCl IMATED ACCUMATEC UNACCL MATED
MEOW LOW
MEDIAN LOW
% /. %
% %%
PERCENT PARTITIONED TO SLUDGE
1_____ ACCLIMATED UNACCL IMATED
MEDIAN LOW % % A
|l Percent
BidOEGRAOEO
ACCLIMATED UNACCLIMATED MEDIAN LCW
% /. %
SAL 000006203
LEAD MALEIC HYDRA2106
MERCURY METHANOL METHOXYCHLOR METHYL ETHYL KETONE METHYL ISOBUTYL KETONE METHYLENE CHLORIDE N-BUTYL ALCOHOL N-NUROSOOIMETHYL AMINE NAPHTHALENE
NICKEL NflRCGENZENE 2-NfTROPROPANE P-BEN20QUIN0NE
PARATHION PCS
PENTACHLOROPHENOL PHENCL
PHENYLENE DIAMINE PHOSGENE
PHTHALIC ANHY0RI0E PYRIDINE SELENIUM SILVER STYRENE
1.1.2.2-TETRACHLOnOETHANS TETRACHLOROETHYLENE THIOUREA TOLUENE TOLUENE DIAMINE TOXAPHENE
(continued)
70 90 SO 100 60 65 60 65 95 90 95 35 90 65 65 0 92 95 95 90 100 60 15 50 60 60 SO 90
60 60 90 95
70 70 75 70 50 50 95 95 60 90 SO 3Q. 50 30 87 85 90 90 75 70 75 70 35 35 25 20 65 65 50 40 55 40 92 82 25 20 86 80 75 70 100 100 90 60 15 10 SO 50 60 90 60 80 2S 20 85 80 75 70 60 90 75 70 80 80
0 0 0 1 54 0 o-
38 0 0 0 0 0 88 0 0 9 0 0 0 1 0 0 0 0 23 '36 45 0 23 0 57
O0
70
00
9
33
48
S6
10
64 64
8
32
10
00
9
52 61
13
00
10
a0
9
44
27
00
35
00
9
90 80
1
00
8
00
0
89
22
O0
17
00
14
00
0
56
10
00
9
11
2
0 '0
60
00
90
72 72
14
16 12 - 4
68 64
3
00
9
72 72
25
00 72 72
9 4
70 8 48 10 8 6 5 12 9 8 21 35 3 1 4 4\ 22 5 13 8 10 9 2 SO 90 14 1 3 8 18 8 14
70 7 48 10 8 3 3 12 9 7 20 35 2 1 3 3 22 4
12 7 10 9 1 60 90 14 1 2 7 18 7 4
0 00 81 68 63 2 00 90 61 81 28 28 28 66 43 26 81 45 27 44 23 22 86 81 81
81 68 63 68 60 47 0 00 81 23 18 9 44 87 46 37 0 51 37 61 61 61 78 21 16 61 72 68 81 88 63 90 85 65 81 81 81 13 13 9 0 00
0 00 54 5 5 SO 9 7
42 14 14
81 68 63
42 0 0
81 68 63 34 14 14
TABLE A-2 (continued)
0VERAL
^ERCEN ^EMOVA
PERCEN r VOLATWZf D
TO AIR
PERCENT PARTfTIONED
TO SLUDGE
l 'ERCENT BK ^DEGRADED
POLLUTANT
ACCLIMATED JNACCl IMATED ACCLIMATEC UNACCl MATEO
MEDIAN LOW
MEDIAN LOW
% A %
/. /. %
ACCLIMATED UNACCLIMATED MEDIAN LOW
% /. %
ACCLIMATED JNACCLIMATED median LCW
% /. V.
TRANS-1.2-DICHLOROETHYLENE TRlBROMOMETHANE
1.2.4-TR1CHLOROBEN2ENE 1,1,1 -TRlCHLOROETHANE 1.1.2-TRICHLOROETHANE
TRICHLOROETHYLENE 2.4.6-TRICHLOROPHENOL 1.1.2-TC 1.2.2`TF ETHANE
TRIFLURALIN VINYL CHLORIDE
XYLENES
>i
*-- cn
90 65 85 95 60 95 95 90 90 95 95
80 `35 ' 85 90 25 87 55 85 90 95 87
80 30 65 85 20 85 50 80 90 95
85
63 72 72
36 . 21
18
43 51 51
76 81 77
40 20 16
67 70 68
0 00
63 68 64
0 00
86 90 90
24 70 68
27 8 8 S 32 8 88 1 11 0 00 6 56 8 44 4 33 33 33 33 2 22
14 13 13
0 00 24 11 10 35 26 26 18 8 6
40 5 4
23 12 12 87 51 46 23 14 13 57 57 67 8 33
57 4 4
GpAs Gx^c>a,n\cc "T^cg e^rr
A" A3 to A* t
SAL 0 0 0 0 0 6 2 0 4
Api SEpRRRToR
UtK_ ChRRcS>
- 'lE'O G-PP'I --
Brarwlj B}U~tlo.r
^
' Ps&ufaz. Eriyc(& Of l Cofr\pa^>
^ VapoC
^o/Tgc'/'/on
-A-P-yz E/n^Si'o/i Fati-for* ^ov'ereJ.)C ~ 0,2^,i? ^0<~/\ooo
wfV
voc = 7SO `JU ^ ^oirX 2V
- 346 ^
x ~ 3^,53 TPY VQC1
VO C. x. H/f / 5/3 CAe*^i
X \/o.par Pressure, Corr^ch'cn -- ftelec^e ~h> >4.^
2>00 / x
I i~o^
3 >H f>s><~, Crud e
X" zooo fb X O.OUf^ j&zPe, Cl*-h xO.OOiZO^
f +r>n
T*T
CrWg
X -7.000 Ifc 1 +nn
I16 pSi\ Oyby /
3.0^0/^
2. It.
E+Ubeoz^e - 3"?.53 TPy* 329JL x ?J1 ^EL x o.oofl Ft- $ tfe
-------- ---------- --------
I ~fvrty-1^
"Z'H
Cs\,d.(^
%re^e -" T5o~'^3 XPy, .V --2>o--&---lb--
>r 0--.--0--C-t-b->-~-7LP25.-'-\---S-'-/-!//-I x OOOOEy-^
/"V
CP
1I/t
----------
I -b=>^
3,9 ps.x Cr^de
7 ------------
to\ue*< - 3^S2^Tpi x -------------!>2s ^ " Tn'^eihyl be*z.esi~ _
-773-----"X -:;-^---------------- x 0.0077 /of - 72 /t
/ +*-
5,7 ^>s*`a Crc/>fe
---------- --
A$****
3^ 5-3 ypyx iPEEJk ^9'^ '* 7^ x <5.001 z. Po- I />
C rseWo 'Cu^e^e J
y ^ rpy v
Xylg^e S ' 71,53 1
v )+^
^ O.OI2X. , S3 /t
1M pi,-^ Crude
7 -----------
A6pU-kJc^ - 3ci.Sl TPy X 3i4 x
N3p2- * tf.oo/5- /\y, o 7>
1------------------------ '
I Ton
>, ps , & CYwO'^.
------------- -
o') Corv,pocT;0^ 3') EV/1 1 SS'or Pp-. C-i^r<3
'o ftppe^dly' y , C Vc, pa r
T^koiP $ ttf/<sflN) S*L
.bfl-r Sysje.pi
Lake
~ 0>OO GpAn ~ per Sr^^olir Buffer'
-- f\'P~ci'2-
fa-, Lkc.Tr ~ 0.01 T ^oc-/\oo O g<W 'VI'l/
- /hsowe. drud^_ Oil Go^past'i-loin ^ V^por Prestons. Carrec^ o^>
Voc - <iOO -2^] * <,<3 -^2- v Z6/
^^
^ l.s^g tpy vfoc
x 3(p(c>
Y
X ih ^0eZ Y.
|0&O
tvK/ 2^*o(>
V k//" / 3/3
i'ca./ K P. 03nrecf,o^ " /^-e.fe<v> "fo Atn-
ffenz-ene " 1'^ "^V
* ) -H>n * T,hV^ r**e
^ " HU>
_ |L O O^/4? ^SiflCort, _ _
C^e^e = 1,5^-TPy -xlaoo^; x
TcZJe x '017~
~ o }*=>
Cy&lhe*TMe = f.S^TPy x
%X >^ 0.0 OSS, Cy , <g fj,
-^y/ benzene =-^ TPf x
C* IQ.. K Q-Q<^ ^ ~ Q ^
Sfyre^e. = l.^rpyx 3oJi^ O -Q%7 ^ ^)r ^o.OOOITSK '- O <b
---------------
I to^
3,<Y ^ Oi/Je
/ -------------
--Tt--ZIi o&^e - 1| -c5r ? -TI--p- y^/ v "--ZO--oO lb x -O--, ^/pc-,-,-`c---3-o--j - x O, Ocni T___ ( =.
---------------
I 3> .t-f p?.c< CruJ..e
3 lb
r>seudJoci//vip^e ~ /I ,6 # -T7-pnvy/r ^ 2--jD;-O--o---/-/>- >_c^ 0-,--0---5---^--3-----/L'--S'-*------ x O O^ O/? P,, f ~
------------------ --
Hors
3 tcj ps,^ Ccuck?
O.z q -77^6)
r
O lb
X^len5 - J.SSTTY x Z2J^ x *L^_?' *X x 0.o/zXy - 2 /i
1
7,4 fL'.'A Cr^e
'"
NapWtUle^e. r I.S'S Tp/X zooojh ^- o.oo^rpc^-z--A/yA. x-o.co/r/vr o /t
1^
1,4 fj/*
SAL 000006206
XAF Sysrs^
Lake Ch-/i#lss
~ SO 6-Pfo ~ f>e.r &ra*J-f Buffer
rv>.ssio^ F^c-fer- - 0,031. Ife Vo(y,ooaj^i W ('UnCo+r,HeJ)
~ Assort Crude. 0,1 Cor^pof.-i,0^ Vapor~ pressure. Ccrrecdf^
\joc. -
`Bo
q<m fV r-*
J[ 3&(z>2*7m,*-.
Go x
X
</ o.ozziyvoc
yr X \000
w*v
- 0,70 T?y v'oc = tb^ij ^IL Voc.
/ `ffc,
T-Ooo /A,
^OC_ x K/f"/o 313 C-tvfiKviiccil X \/, P, do/rec'f,on ~
/ ////^
B
t/Jo>
I1,,5* pOsSi'itov. o*
^
e^z^e = mi yd Voc ^ 3^,^ Cr^e X O, 003? 6b -
I VO xo.oal2_c:.Cu^ne - 13?
It
tr
W^n rC-
>!
______
* 3*7 fS'Cv. Cz-We
CycJoke^nf- --`-------------------
137/
l!=
/
vbr
^
* cy- 3_3>..W4, ,Pp-Ss--,/`-*---O-c^A5e,
x
o. OOSG
Cy '
ben^exc - 137 |
\>C P1*^ Ps*v ^\
r .,
n.l<Z pcj'e, fcfe
^ _ ,o
z-------- zL x 0.00
?i^/ ps/*. O/x^e.
CL -
-
S+yre^c - 13-11 ^ Voc x KZS*J? Zhu xoaoots
------ ---------
r
1.H jPs.A Owe
'
Xle.-'e = mi JF voc x 2:CL.m
X 0.007-7 121
3.*^ pst>, (Zr^Je.
Pseudo Cumene _ IJ1/ ~ VoC * O'Q'i'12 f?l'a ^ x 0,00 12,
P, 2,4 -r^e)
^
3 psXx. Cfxucte
Xylenes -
m I ^ VOC * Xi!l_ZLCl_*X
111 ^ pS-'^
>4 0.0/2
Xy r
2 /t O \b ^ yt o> /
o /&
/ /6
o /6
it
~
/V^pUiPcien? =-1311 SP- V^C a
fUftZfZz. x o Oo rs
3-7 /^-'s Cr^Me
-- 0/4,
''
SAL 000006207
T or\dr*\erti~$
L-a,1<G. CU^ar'/es
H~c^~2^<'d.ous
x*.si'*n ~
O O C2^ ^ l(-- W^\S~/ fc1 3
^ pt
f~ cst/e^)
.VC.
' o'fii er is*)pot/f\ct t*\
. TTlr'i WeK$-j-&
|cvo\d s.'V'Aer*
k)e_ f
So 0.0 re /
,,0*lO" s*L
' , - M It |.
SAL 000006209
APPENDIX H STORAGE TANK RELEASE DATA AND CALCULATIONS
SARA TITLE III, SECTION 313 1988 TOXIC CHEMICAL RELEASE INVENTORY
LAKE CHARLES REFINERY
SAL 000006210
LAKE CHARLES 198B
SUMMARY
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
METHANOL
TOTAL LBS.
Storage Tank
Loading 1
16951.44 14193.98 12245. 77
1611.73 7708.81
564.20 167.68 1238.41 S6S0.00
26. 67
K0O.OO
0.00 0. 00 0. 00 0. 00 0. 00 0. 00 0. 00 0. 00 0. 00 0.00
(\ cler/cl errr
^ c*lcuUVoS
,`rt wU'.c.!* cydo Wane release wn.s es+Wfed +<= be
lbs res u<+.V>3 .'e repor+ng ^'screp^ncy <=-f
3,So lb5 -Poe po.'of release. (See r^pbfL sk>r-^Z_ tuples (J^^S j !ct`i ^ (c'Zj (c`lJ ^ I 5) en^.sS'^n (col f>Wy)
SAL 000006211
SARA 313
Location Year: Loss: Tank #
LAKE CHARLES 1988
Storage Tank 25,26,32,80
0)
235880 lbs. VOC of
REG GASOLINE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total Neight
235800 235880 235880 235880 235880 235880 235880 235880 235880 235880
(lbs. ) (lbs. ) (lbs. ) (lbs. > (lbs. > (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. )
>:
X
x
X
x
X
X X
X X
wt. Fr ac.
Vapor (?>) Pressure
Ratio
lbs.
0.0240 0.0980
<.01 0.0270 0.1300 0.0430 0.0200
< . 01 < . 001 < . 001
V' 3-; X X X
X X >.; X
0.242 =: 1369.63
0.065 = 1491.37
0.258 =
ERR
0.029 0. 031 =
184.90 939.72
0.010 = 101.26
0.006 =
29.90
0.001 =
ERR
0. 765 as
ERR
0.016 =
ERR
VAPOR PRESSURE (ERR implies not detected)
6.2
(I) ^OC -Tro^n
L.C, EZS spreadsheet
(p-) d^tcK -n /JjopV E
(3) Vapor pressure
in flpfX &>
u -7.
SAL 000006212
SARA 313
Location Year: Loss: Tank #
LAKE CHARLES 1988
Storage Tank 78,92,93,87,88,31
42B720 lbs. VOC of
UL GASOLINE
V0C Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUED0CUMENE NAPHTHALENE MTBE STYRENE
Total Weight
428720 428720 428720 428720 428720 428720 428720 428720 428720 428720
(lbs.) (lbs. ) (lbs.) (lbs. > (lbs.) (lbs.> (lbs.) (lbs.) (lbs. ) (lbs.)
x
X
x
X X X X X X
wt. Fr ac.
Vapor Pressure
Ratio
lbs.
0.0290 O.0980
< .01 0.0270 0.1300 0.0430 0.0200
<.01 <.001 < . 001
X X X X X X X X
X
0.242 S3 3007.95
0.065 = 2710.62
0. 258 =
ERR
0.029 = 0.031 = 0.010 S3
336.06 1707.97
184.05
0.006 S3
54.35
0.001 =
ERR
0. 765 -- 0. 016 =
ERR ERR
VAPOR PRESSURE (ERR implies not detected)
6.2
SAL 000006213
SARA 313
Location: Year: Loss: Tank #
LAKE CHARLES 1988
Storage Tank 30,64,65,77
264860 lbs. VOC of SUL GASOLINE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
264860 264860 264860 264860 264860 264860 264860 264860 264860 264860
(lbs. ) (lbs. ) (lbs. ) (1bs.) (lbs.) (lbs.) (lbs. ) (lbs.> (lbs. ) (lbs. )
X X X X
x
X X X X X
Wt. Fr ac.
Vapor Pressure
Ratio
lbs.
0.0410 0.0980
<-01 0.0270 0.1300 0.0430 0.0200
< .01 < . 001 <-001
X X X X X X
X
X X X
0.242
2627.24
0. 065 = 1674.60
0.258 --
ERR
0. 029 -- 207.62
0.031 = 1055.17
0.010 = 113.71
0. 006 =
33.58
0.001 = 0. 765 =
ERR ERR
0. 016 =
ERR
VAPOR PRESSURE (ERR implies not detected)
6.2
H 'H
SAL 000006214-
SARA 313
Location Year: Loss: Tank #
LAKE CHARLES 198B
Storage Tank 33,79
49560 1 bs. VOC of
REFORMATE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUED0CUMENE NAPHTHALENE MTBE STYRENE
Total Weight
49560 49560 49560 49560 49560 49560 49560 49560 49560 49560
(lbs.) (lbs. ) (lbs.) (lbs. ) (lbs.> (lbs. > (lbs.) (lbs.) (lbs.) (lbs.)
X X X X X X X X X
Wt. Fr ac.
Vapor Pressure
Ratio
lbs-
0.0720 0.1850
<.01 0.0450 0.1400 0.0680 0.0170
< . 01 0.0000
< . 001
X X X X X X X X X X
0.242 0. 065 0.258 0.029 0.031 0.010 0.006 0.001 0.765 0.016
ea
SB 5S = as = = as s= =
863.30 591.52
ERR 64.75 212.63 33 65
5.34 ERR
0.00 ERR
VAPOR PRESSURE (ERR implies not detected)
6.2
H- - 5"
S*L 000006215
SARA 313
Locations Year s Loss: Tank #
LAKE CHARLES 1988
Storage Tank 85
122820 lbs. VOC of FCC GASOLINE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
122820 122820 122820 122820 122820 122820 122820 122820 122820 122820
(lbs. ) (lbs, ) (lbs. ) (lbs. ) <1bs.) (lbs. ) (lbs. ) (lbs. ) (1bs.> (lbs. >
X X X X X X X X X X
wt. Fr ac.
Vapor Pressure
Ratio
1 bs.
0.0110 y 0.0780 y 0.0100 X 0.0300 X 0.1970 X 0.0510 X 0.0310
< . 01 v 0.0000 X
< . 001
0. 242 0. 065 0.25B 0. 029 0.031 0.010 0.006 0. 001 0.765 0.016
=
= = = =
-
=i =
326.86 618.06 316.95 106.97 741.48
62. 54 24. 13
ERR 0.00
ERR
VAPOR PRESSURE (ERR implies not detected)
SAL 0o0062l6
SARA 313
Location Year: Loss: Tank #
LAKE CHARLES 1983
Storage Tank 3,86
139620 lbs. VOC oi LSR GASOLINE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
139620 139620 139620 139620 139620 139620 139620 139620 139620 139620
(lbs.) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs.) (lbs. ) (lbs. )
X X X X X X X X X X
wt. Fr ac.
Vapor Pressure
Ratio
1 bs.
o
V
0.0390 0.0300 0.0520
< . 01 < . 01
< . 01 < . 01 0.0000 < . 001
X X
V
X X X X X X
0.242
1317.38
0.065 = 0.258 = 0.029 =
270.23 1873.61
ERR
0.031 =
ERR
0. 010 -- 0. 006 = 0.001 =
ERR ERR ERR
0.765 = 0.016 =
0. 00 ERR
VAPOR PRESSURE (ERR implies not detected)
6.2
H~ 7
SAL 000006217
SARA 313
Location Year: Loss: Tank #
LAKE CHARLES 1988
Storage Tank 88,199
78780 lbs. VOC of NAPHTHA
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
78780 78780 78780 78780 78780 78780 78780 78780 78780 78780
(lbs. ) (lbs.) (lbs. ) (lbs.) (lbs.) (lbs. > (lbs. ) (lbs. > (lbs. ) (lbs. >
X X X X X X X
X
Wt. Frac.
Vapor Pressure
Ratio
lbs.
0.0100 0.0450 0.0200 0.0100 0.0400
< . 01 < . 01 < . 01 0.0000 < . 001
X X X X X X X X X
0. 930 0.250 1.000 O. 112 0. 1 19 0. 039 0.025 0. 003 2. 963 0.060
ss
= = =
=r
= = = = =
738.56 886.28 1575.60
88. 63 374.21
ERR ERR ERR 0.00 ERR
VAPOR PRESSURE (ERR implies not detected)
1.6
&0
correcf" V<\por* pne&sore. Ta'Kc,
by VOC, and vt\ ff^crfAc,^ ^
of release: C C* (culccf'o^f error'
v<xS er.g.n*fly ,'n ziexf
v
M-t)
SAL 000006218
SARA 313
Location Years Loss: Tank #
LAKE CHARLES 1988
Storage Tank 68,69,415
423980 lbs. VOC o-f
NAPHTHA
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUED0CUMENE NAPHTHALENE MTBE STYRENE
Total Weight
423980 423980 423980 423980 423980 423980 423980 423980 423980 423980
(lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (1 bs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. )
X X X X X X X X X X
wt. rac.
Vapor Pressure
Rati o
lbs.
0.0100 0.0450 0.0200 0.0100 0.0400
< . 01 <.01 < . 01 0.0000 < . 001
X X X X
X
x x
X X
0.938 ss 3974.81
0.250 IS 4769.78
1.000 - 8479. 60 *|e
0. 112 SI 476.98 0. 119 = 2013.91
0. 039 =
ERR
0.025 -
ERR
0.003 --
ERR
2.963 =
0.00
0. 060 --
ERR
VAPOR PRESSURE (ERR implies not detected)
1.6
C #) ITi^ correcf
pon pr^ss^r^
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(l. c^5>C A
00000621^ sM-
StoRA&E TANK EMISSIONS
JET.
CReb rv^cr Feec-T)
lake
FW F'vxec{
Raa~f RooF
ici\k s ac 3
TPY V0C. 67 7?)
'zihaicj ~py vaC- (ih.vi,
Z5/.3? rpy yoo
Benzene- " (2Z/. 32 IP Y^2ooo fbN 0.01 g*Y -i-?4Vs^^NU'
67/3 /
-f-o^
A i.g> g*? / _^?r
CycUYx^^ - C2r/, 11 re2~p)(a,o^(C
aw/^r
.
C*s
EE-iUyl hexene. = (^\.3%TPv)(?0oli^pni F.ppo-1%P*'-
ip, OSTiy
5bCe lb EL
Toluene -
TPvy2E22Jk^n nVc
V IL To I
Xylene. - (tSU 3HTPY)( V^^X- Vo *7 XtP^T-) =J)2HJL4
~l y1. droole C.'f Ell -Plod-h*c, zs>
S^ee^T Crude VOCL
- /4.572 77/
Scur Crude /OC.
- 70.77 TP/
6 7. z> / TPy
Bez.e^e - Clio.S'U TPY Sw,i^(-zf^^)(-OOZ2BX)('~Yli^ ^ Y? <4
(3o."/r7py wX2^LXo.oozs fo)ftS
AU,oA^r 7444
Vylene -- (UoShTPy 5w^(j^~Y'^
2Z-'^*V
6^) bor>*} ~Fe cJcdAtbns ~IF AA^<^tI "fAc ^rvdvcf oA &5'LWX'zXi'u)
1(0 /Hf t'v'1- 7> *"y
XASo^itX tfrvl-hply Coi'^ceidfy~ti',l<5 y\ C\r\ci.
V-'-por- pret$or< "fe otoFE 'fC\<z celep^e , X
"jb invify
J.(p ^S-'^v <*'? v.y3 Ao C'.yhX' ? "AUi^A-o^ aA
Am'fe'T
<1S '? rl.
-7
SAL 000006220
pesf-
SARA 313
Location Year s Loss: Tank #
LAKE CHARLES 1988
Storage Tank 346,347,102
33120 lbs. VOC of SWEET CRUDE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDQCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
33120 33120 33120 33120 33120 33120 33120 33120 33120 33120
(lbs.) (lbs. ) (lbs. ) (lbs. ) (lbs.> (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. )
X X X X X X X
J.J
X X
wt. Prac.
Vapor Pressure
Ratio
0.0032 <.01 < . 01 < . 01
0.0120 <.01 <.01 <.01
0.0000 < . 001
X X X X X X X X X X
0.441 0. 118 0.471 0.053 0.056 0.018 0.012 0.001 1.394 0.028
ss =
= s= =
as = = = =
1 bs.
46. 76 ERR ERR ERR
22.21 ERR ERR ERR
0.00 ERR
VAPOR PRESSURE (ERR implies not detected)
3.4
SAL 000006221
SARA 313
Locations Year: Loss s Tank #
LAKE CHARLES 1988
Storage Tank 371,372,373
60900 lbs. V0C of
SOUR CRUDE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total UJei ght
60900 60900 60900 60900 60900 60900 60900 60900 60900 60900
<1bs.) (lbs.) (lbs.) (lbs.) (lbs.) (lbs. > (lbs. ) (lbs. > (lbs. ) (lbs.)
X X X X X X X X X x
Wt. Fr ac.
Vapor Pressure
Rati o
0.0023 X
< . 01 X <.01 X
<.01 X <.01 X
<.01 >:
o
V
<.01 0.0000
< . 001
X X J.
X
0.441 0. 118 0.471 0. 053 0.056 0.018 0.012 0. 001 1.394 0. 028
= = = = = =
ss =
--
1 bs.
61.80 ERR ERR ERR ERR ERR ERR ERR
0. 00 ERR
VAPOR PRESSURE (ERR implies not detected)
3. 4
SAL 000006222
SARA 313
Location Year: Loss s Tank #
LAKE CHARLES 1988
Storage Tank 27
17100 lbs. VOC of
SABINE HAD
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
17100 17100 17100 17100 17100 17100 17100 17100 17100 17100
(lbs.) (lbs. ) (lbs.) (lbs.) (lbs. ) (lbs. ) (lbs.) (lbs.) (lbs.) (lbs.>
X X X X X X X
X X
wt. Fr ac.
Vapor Pressure
Ratio
1 bs.
0.3300 0.1500
<.01 0.0400
<.01 <.01 <.01 0.0600 0.0000 0.1000
X X X X x X X
X
J.J
X
0. 242 = 1447.98
0. 065 *5 165.48
0. 258 =
ERR
0.029 =
19.86
0. 031 =
ERR
0.010 =
ERR
0. 006 =
ERR
0. 001 0.765 =
0. 74 0.00
0.016 ss
26.67
VAPOR PRESSURE (ERR implies not detected)
6.2
SAL 000006223
SARA 313
Location Year: Loss: Tank #
LAKE CHARLES 1908
Storage Tank 42,43,70,405,7,8
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
56020 lbs. VOC o-f -----------------
SLOP OIL (GASOUNE) -------------------------------------Co?P
Total Weight
56020 56020 56020 56020 56020 56020 56020 56020 56020 56020
(lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. >
X X X X X X X X X X
wt. Frac.
Vapor Pressure
Ratio
lbs.
0.0300 0.0980
<.01 0.0270 0.1300 0.0430 0.0200
< . 01 0.0000
< . 001
X X X X X X X X X X
o o
0.242 0.065 0. 258 0.029 0.031 0. 010 0.006 0.001 0.765
ss =
= SS = ss
-- ss --
406.60 354.19
ERR 43. 91 223.18 24.05
7. 10 ERR
0.00 ERR
VAPOR PRESSURE (ERR implies not detected)
6.2
S4L 00006 224
SARA 31
Location Year: Loss: Tank #
LAKE CHARLES
1980
Storage Tank
61,62,344
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
19800 lbs. VOC of
-----------
SYN COND (GASOLKVe')
-------------------------- Cortp
Total Weight
19800 19800 19800 19800 19800 19800 19800 19800 19800 19800
(lbs.) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. )
X X X X X X X X X
X
wt. Frac.
Vapor Pressure
Ratio
lbs.
0.0300 0.0980
< . 01 0.0270 0.1300 0.0430 0.0200
<.01 0.0000
< . 001
X X X X X X X
V
X X
0. 242 0. 065 0.258 0. 029 0.031 0. 010 0.006 0. 001 0. 765 0. 016
as
as =
--
as
as as
= =
--
143.71 125.19
ERR 15. 52 78.88
8.50 2. 51
ERR 0.00
ERR
VAPOR PRESSURE (ERR implies not detected)
6.2
SAL 000006225
SARA 313
Location Year: Loss: Tank #
LAKE CHARLES 1988
Storage Tank 18,19
V0C Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
84880 lbs. VOC oi
-----------
AMINE SOLN
------------------------- Cofrf
Total Weight
84880 84880 84880 84880 84880 84880 84880 84880 84880 84880
(lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. > (lbs.) (lbs. ) (lbs.) (lbs. )
X X X X X X X X X >{
wt. Fr ac.
Vapor Pressure
Ratio
lbs.
0.0300 0.0980
<.01 0.0270 0.1300 0.0430 0.0200
<.01 0.0000
< . 001
X X X X X X X X X X
0.242 0. 065 0.25B 0.029 0.031 0.010 0.006 0.001 0. 765 0.016
=
ss as
=
=
--
=5
=
as
616.06 536.66
ERR 66.53 338.15 36.44 10.76
ERR 0.00
ERR
VAPOR PRESSURE (ERR implies not detected)
6.2
SAL 000006226
SARA 313
Location Year: Loss: Tank #
LAKE CHARLES 198B
Storage Tank 34,35,94,95,82,353,354,355,107,108
V0C Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
11380 lbs. VOC o-f ---------------
JET-50/-A/LVT/VO<?/eX ---------------------------------
Total Weight
1 1380 11380 11380 11380 11380 1 1380 11380 11380 11380 1 1380
(lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. >
X X
X
X
X X X
Wt. Fr ac.
Vapor Pressure
Rati o
lbs.
<.001 <.01 <.01 < . 01 <.01 <.01 < .01
0.0300 0.0000
<-001
X X x x
X X
X
X X
136.364 36.364
145.455 16.364 17.273 5.627 3.573 0. 409
430.909 8.791
= =
-
=
=
=
--
= *=
ERR ERR ERR ERR ERR ERR ERR 139.66 0.00 ERR
VAPOR PRESSURE (ERR implies not detected)
0. Oil
SAL 000006227
SARA 313
Location Year:
Loss:
Tank #
LAKE CHARLES 1988
Storage Tank 201-2,342-3,345,351,370,378,74-6,37,100
73200 lbs. VOC o-f
DIESEL
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUED0CUMENE NAPHTHALENE MTBE STYRENE
Total Weight
73200 73200 73200 73200 73200 73200 73200 73200 73200 73200
(lbs. ) (lbs. ) (lbs. ) (lbs.) (lbs.) (lbs. ) (lbs. ) (lbs. ) (lbs.) (lbs. )
X X X X X X X X X X
wt. Frac.
Vapor Pressure
Ratio
1 bs.
<. 001 <01 <.01 < .01 <.01 < . 01 <.01
0.0300 0.0000
< . 001
X X X X X X X X X
166.667
ERR
44.444 177.778 =
20.000 =
ERR ERR ERR
21. Ill 6.878 =
ERR ERR
4.367 =
ERR
0.500 = 1098.00
526.667 =
0. 00
10.744
ERR
VAPOR PRESSURE <ERR implies not detected)
0.009
SAL 000006223
SARA 31
Locatian: Year: Loss: Tank #
LAKE CHARLES 1988
Storage Tank 104,120
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
1980 1 bs. VOC o-f
(Swt Crude}
WASTEWATER . Corvip,
Total Weight
1980 1980 1980 1980 1980 1980 1980 1980 1980 1980
(lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. ) (lbs. > (lbs. ) (lbs. ) (lbs. > (lbs. )
X X X X X X X X X X
Wt. Frac.
Vapor Pressure
Ratio
0.0032 < . 01 < . 01 <.01
0.0120 < . 01 < . 01 <.01
0.0000 < . 001
X X X X X X >5 X X X
0. 441 0. 118 0.471 0.053 0.056 0.018 0.012 0. OOi 1.394 0.028
s
= =s = = = = -- =
lbs.
2.80 ERR ERR ERR
1.33 ERR ERR ERR
0. 00 ERR
VAPOR PRESSURE (ERR implies not detected)
3. 4
SAL 000006229
SVoRft&ETAPJK l/oc Crrsg CIS)
i-alce dU&rltfs
Se.rWce, (Type irTcrsk* )
Pe<0ij\a.r Grt*So\<r\g_ (Flood. Road ~ 2Sj Ze^T>~*-/`{>)
VQC Q-py~)
ll~7<<^Li
Unleaded Sosohne (Flood. Rood - *72;<?Z,
OT/sl,)
2.|^/,36>
Super- Unlead. tso/.Vt (Flood Rood- 3oj Ud/C,7~i ~?7 ")
I3>X.
Reformed e
(Flo*f. Roof " 53^77)
FCC (5n.sol.ne.
Roof - ^9-5")
~2H J9
^1 V I
S+. Ron (JcLSoll'ne (Flood, Road ~ 3^0.)
Al/cy/afe
( Flood, Rood
79, *7 ^ ^ 03^''m oq ?/3
(oS.^tj
HopddUc^
r
(Flood, Rood -*vz}t'n) x
C F,'*ec/ /&oA - *&t, GIVIS')
31.3^
7. I I , =??
S^eei-CruJ^ SooP Crude,
(Flood. Rood - *3<k,J 377/o^) (F(ocf Roof-* 371j 17 Zj 37 3)
'6..S& 30.^
S^/ne RA-b Slop O/l
(FUcd.Roo-p- *-->') (Flood. Roof -Mif-L/H\ 70)Ho<rt 7; 3)
Syr CanderSod^ (Flood Rood ~ ^R(6^ ^dd)
(Grex 5c/`VC^
Kero yen e - 3ef S<>/ F/oaf, Roof " * 3*f )
N
^*1 ( P.W Roof -
zrprz^j'iS^V
- Aid(ex fktfnofe ( F>ve( Roof -- ^ /07; /O'?)
/L.Ve S>U.o~
k>y<'/0
(FUf Roof -
Sr.SlT 2%,o|
1,^0
'1 7
0.37
ir
R2.VV
SAL 000006230
~Ta^k toe Ccoofd,)
L.C.
Serv.'cg, (^Typ- &r~f^<r^k
^OC. CtP
bese( ^.W-'^o.V
(F'xrec{ $&<-*ZPiptoT-jVftpsi,
^6.60
r brs-KikiO -fropHispb,11%pi2-,v?,/o^vh)
Ddo/c AfeMamo(
CHonf,
-- Y^Y ^
03?
AlTFE,
(F/o^.^oo-f-^ /9i)
Y3Y
U/\5^(A/\~f^/~ ($/+. Crude Uyer)
^P/oo-f. /?Oaf
. -'iccf; me
SAt 0000623I
l-o^e
.e^5
FUGITIVE HY0R0CARB0N EMISSIONS FLOATING ROOF TANKS * 1958 EIS-010 METHOO
(TKCAL.WRl)
PROOUCT
SEAL TYPE
TANK CAP. DIA. YRLY TVP NO. MBBL FT T/O'S PSIA
HAT'L
SEALl SEALl CURRENT
U/0 FRACTION
VAPOR Lie DENS FACTOR WIND ACTOR FACTOR CLtNGAGE STC LOSS LOSS
MONTHS
p* HW LB/GAL KC MPH Ksl HI FACTOR
TPY
TPY IN SERVICE
TOTAL LOSS TRY
NO. 3 SWEET RF1SS
NO. 2 SWEET RFISS
NO. 3 SOUR RFISS
NO. 3 SOUR RFISS
NO. 3 SOUR RFISS
L-REG GASOLINE RFIDS
l-REG GASOLINE SHOE/VAP
SUP UNLEADED GAS RFIDS
REG GASOLINE RFIDS
BASE REFORMATE RFIDS
L-SUPER UNL GAS RFIDS
L*SUPER UNL GAS RFIDS
UNLEADED GASOL SHOE/VAP
BASE REFORMATE RFIDS
REG GASOLINE RFISS
L-UNLEAD GAS RFISS
L-UNLEAD GAS RFISS
FINISHED GASOLINE
RFISS
FINISHED GASOLINE
RFISS
NAPTHA RFISS
SABINE HAD RFIDS
BASE FCC GASO RFISS
UNLEADED GASO RFISS
L*SUP UNL GASO RFISS
BASE ST RUN GASO RFISS
ALKYLATE RFISS
ALKYLAfE RFISS
AMN SOL RFISS
BASE ST RUN GASO RFISS
+ FCC CYCLE OIL
RF10S
SWEET NAPTHA RFISS
AMN SOL RFISS
+ FCC CYCLE OIL RFIOS
SYN CONDENSATE RFISS
SYN CONDENSATE RFISS
JET 50 FUEL
RFISS
SLOP RFISS
SLOP RFIDS
SLOP
OOCK-LT. PARAFFIN
RFISS
DOCK HVY. PARAFFIN
RFISS
HEAVY PARAFFIN MET SHOE
HEAVY PARAFFIN MET SHOE
PARAFFIN RFISS
346 347 371 372 373
25 26 30 32 33 64 65 78 79 80 92 93 67 66 68 27 85 31 77
3 98 99 16
66 23 199 19 24
61 62 34 42 43 70 159 402 96 97 194
250 200 5.2 250 200 42.8 400 250 43.2 200 180 52.B 200 180 48.8
25 67 30.9 25 67 12.5 80 120 14.7 80 120 39.6 80 120 40.2 25 67 11.3 25 67 13.1 120 134 21.5 120 134 32.3 120 134 45.5 25 67 29.8 25 67 24.6 150 150 20.0 150 150 7.1
150 5.8
25 67 6.S 150 150 57.2
60 120 25.6
120 134 26.8
.71.5 21 0.0
35 80 75 35 80 45.5 15 52 4.9 150 150 13.5 15 52 70.0 30 67 2.8 15 52 4.9 15 52 126.4 10 42.5 1.3 10 42.5 1.4 80 120 30.1
5 32 24.0 5 32 52.4 4 32 1.2
85 110 10.3 55 110 2.6 2.5 25 47.4 2.5 25 47.4 SO 120 16.4
4.0 0.079 50.0
4.0 0.079 50.0
4.0 0.079 50.0
4.0 0.079 50.0
4.0 0.079 50.0
6.6 0.216 64.0
8.6 0.216 64.0
6.6 0.216 64.0
8.6 0.216 64.0
4.0 0.079 64.0
8.6 0.216 64.0
8.6 0.216 64.0
8.6 0.216 64.0
3.5 0.067 64.0
8.6 0.216 64.0
8.6 0.216 64.0
6.6 0.216 64.0
8.6 0.216 64.0
8.6 0.216 64.0
1.3 0.216 80.0
8.6 0.216 68.0
8.6 0.216 68.0
6.6 0.216 64.0
8.6 0.216 64.0
6.6 0.216 68.0
8.6 0.216 68.0
6.6 0.216 68.0
8.6 0.216 68.0
6.6 0.216 68.0
0.0 0.000 130.0
1.3 0.023 80.0
8.6 0.0
0.216
0.000
68.0 130.0
8.6 0.216 68.0
8.6 0.216 68.0
0.0 0.000 130.0
8.6 0.216 50.0
8.6 0.216 50.0
8.6 0.216 50.0
0.0 0.001 142.3
0.0 0.0
0.000 0.000
170.3 170.3
0.0 0.000 170.3
0.0 0.001 142.3
7.1 7.1 7.1 7.1 7.1 5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6
5.6 5.6 5.6 5.6 5.6 6.4 5.6 5.6
5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6 6.4
5.6 S.6 5.6 5.6 6.4 7.1 7.1 7.1 6.1 6.2 6.2 6.2 6.1
0.4 8.7 0.4 8.7 0.4 8.7 0.4 8.7
0.4 8.7 1.0 8.7 1.0 8.7 1.0 8.7 1.0 8.7 1.0 8.7 1.0 8.7 1.0 8.7 1.0 8.7 1.0 8.7
1.0 8.7
1.0 8.7 1.0 8.7
1.0 8.7
1.0 8.7 1.0 8.7
1.0 8.7 1.0 8.7
1.0 8.7 1.0 8.7 1.0 8.7
1.0 8.7
1.0 8.7
1.0 8.7 1.0 8.7
1.0 8.7 1.0 8.7
1.0 8.7 1.0 8.7 1.0 8.7
1.0 8.7 1.0 8.7 1.0 8.7 1.0 8.7 1.0 8.7
1.0 8.7
1.0 8.7
1.0 8.7 1.0 8.7
1.0 8.7
0.20 0.20 0.20 0.20 0.20
0.15 0.20 0.20 0.20 0.15
0.15 0.15 0.20 0.15 0.2Q 0.20
0.20 0.20 0.20 0.20 0.15 0.20 0.20 0.20
0.20 0.20 0.20 0.20 0.20 0.15 0.20 0.20 0.15 0.20 0.20 0.20 0.20 0.15 0.20
0.20 0.20 1.20 1.20 0.20
2.6 0.0060 2.6 0.0060 2.6 0.0060 2.6 0.0060
2.6 0.0060 2.6 0.0Q1S 1.0 0.0015 2.6 0.0015 2.6 0.0015 2.6 0.0015 2.6 0.0015
2.6 0.0015 1.0 0.0015
2.6 0.0015 2.6 0.0015
2.6 0.0015 2.6 0.0015 2.6 0.0015 2.6 0.0015 2.6 0.0015 2.6 0.0015 2.6 0.0015
2.6 0.0015 2.6 0.0015 2.6 0.0015 2.6 0.0015 2.6 0.0015
2.6 0.0015 2.6 0.0015 2.6 0.0060 2.6 0.001S 2.6 0.0015 2.6 0.0060 2.6 0.0015
2.6 0.0015 2.6 0.0015 2.6 0.0060 2.6 0.0060 2.6 0.0060 2.6 0.0060
2.6 0.0060 1.5 0.0060 1.5 0.0060 2.6 0.0060
8.78 8.78 10.98 7.91 7.91 19.29 0.81 46.07 46.07 12.65 19.29 19.29 1.61 11.90 51.44 25.72
25.72 57.58 57.58 35.92 10.25 61.18
46.07 51.44
8.57 32.63 32.63 21.21 61.18
0.04 3.44 21.21 0.04
17.34 17.34
0.11 9.60 7.20 9.60 0.34 0.04 0.01 0.01 0.37
0.13 1.07 1.39 1.18 1.09 0.05 0.02 0.04 0.10 0.11 0.02 0.02 0.08 0.11 0.16 0.04 0.04 0.08
0.03 0.03 0.01 0.23 0.07 0.10 0.00 0.13 0.08 0.01 0.05 0.32 0.01 0.01 0.58 0.00 0.00 0.09 0.08
0.16 0.00
0.14 0.02 0.08 0.08 0.19
0.33 1.00 1.00 1.00 1.00 1.00 1.00 0.92 1.00 1.00 1.00 1.00 0.83
1.00 1.00 1.00 1.00 1.00 1.00 1.00 0.83 1.00 1.00 1.00 1.00 1.00 1.00 1.00
1.00 1.00 1.00
1.00 1.00 0.17 0.17 0.75 1.00
1.00 0.83 1.00 1.00 1.00 1.00 0.92
3.06 9.86 12.37 9.08 9.00 19.34 0.83 42.27 46.17 12.76 19.31 19.31 1.42
12.02 51.60 25.77 25.76 57.66 57.61 35.95
8.55 61.41 46.14 51.54
8.57 32.76 32.71
21.22 61.24
0.36+ 3.44
21.22 0.61 + 2.89
2.89 0.17 9.67 7.36 8.00 0.47 +
0.07+ 0.09+ 0.09 + 0.52+
PAGE TOTAL
3375.
1238.
887.13 8.21
853.12
- 3,S2i,L ' ^Oj'oDr
,b
I 4tr>
e? to-1^
+ - Mo SflM 3 3
SAL 000006232
Lfrlce CLl^\*r[e^>
fUGITIVE HYDROCARBON EMISSIONS FLOATING ROOF TANKS - 1988 EIS-OLD METHOD (TKCAL.UR1)
PROOUCT
SEAL TYPE
TANK CAP. DIA. YRLY TVP NO. HB8L FT T/O'S PSIA
HAT'l
SEAL1 SEAL1 CURRENT
U/0 PERCENT
VAPOR LIQ OEMS FACTOR WIND FACTOR FACTOR CL1MGAGE STG LOSS LOSS ' MONTHS
P* MU LB/GAL Kc KPN Ksl Nl FACTOR
ipr
TPY IN SERVICE
TOTAL LOSS
TPt
*r+ IT. PARAFFIN MET SHOE LT. PARAFFIN RFISS
UNFINISHED GASOLINE RFISS
SLOP RFISS
SLOP
RFIDS
SLOP
RFISS
195 196 59 405
7 8
2.5 28 146.6
2.5 28 146.6
25 67 0.0
55 100 3.1
1.5 21.3
10
1.5 21
10
0.0 0.001 142.3 0.0 0.001 142.3 8.6 0.216 68.0 8.6 0.216 68.0 8.6 0.216 68.0 8.6 0.216 68.0
6.1 1.0 8.7 1.20 1.5 0.0060 6.1 1.0 8.7 0.20 2.6 0.0060
5.6 1.0 8.7 0.20 2.6 0.0015 5.6 1.0 8.7 0.20 2.6 0.0015 5.6 1.0 8.7 0.15 2.6 0.0015 5.6 1.0 8.7 0.20 2.6 0.0015
0.05 0.09
27.33 2.84 0.06 0.08
0.23 0.23 0.00
0.01 0.00 0.00
1.00 1.00 0.00 1.00 1.00 1.00
sgs
0.27 + 0.31 +
0.00 2.84 0.06 0.08
PAGE TOTAL TOTALS
68 3463.
316.3 1554.
30.43 0.46 917.57 8.68
3.57 856.69
TOTAL THROUGH (MMBAR/YR)
5383.
> O ooo Cruu\hij
U\ke l>*
rUCHIVE HTOAOCARBOH EMISSIONS FLOATING ROOF TANKS 1988 CIS-OLD KETHOO {TKCAL.WR1)
PRODUCT
SEAL TTPE
TANK CAP. OIA. TRLT NO. HBBL FT T/O'S
TVP PStA
KAT't
SEA11 SEAM CURRENT
VAPOR LIO DENS FACTOR WJNO FACTOR FACTOR CUNGAGE
p* MW LB/GAL Cc NPH Ktl Hi FACTOR
NO. 2 SWEET DOCK METHANOL
MTflE WASTEWATER WASTEWATER
STH COHO
DIESEL TOTALS
IFR/SS IFR/SS
IFR/SS IFR/SS tfR/LOG i Ffi/DS IFR/DS
102 150 150 112.7 4.0000 0.0792
404
15 58 12.7 2.0000 0.0365
193
80 120
0.5 9.0000 0.2325
104
10 42.5
550 ,4.0000 , 0.0792
120 15 52 16.9 coooo 0.0792
344 80 120 18.3 8.6000 0.2164
345
150 150
6.1 8.6000 0.2164
500.00
717.20
50.0 32.0 68.0 50.0 SO.O 68.0 68.0
7.1
6.6 5.6 7.1 7.1
5.6 5.6
0.4
1.0 1.0 0.4 0.4
1.0 1.0
8.7 8.7 8.7
8.7 8.7 8.7 0.7
6.7 6.7 6.7 6.7 2.5
2.5 2.5
0.0 0.0060 0.0 0.0015 0.0 0.0015
0.0 0.0015 0.0 0.0015 0.0 0.0015 0.0 0.0015
TOTAL THROUGH <HM8AR/TR)
358.6
[ ITT INC STC LOSS
FACTOR
TPT
736.70 227.72
528.32 179.96 207.93 528.32 736.70
0.80 0.23 0.56 0.00 0.00 0.19 0.35 2.13
DECK LOSS
FRACTION
TOTAL
FITTING
MONTHS STORAGE LOSS
LOSS IN SERVICE
TPT
V/0 LOSS
tpt
0.00 0.00 0.00 0.00 0.00 0.00
0.00 0.00
0.58 0.13 6.18 0.14 0.16 3.89 5.42
14.51
1.00 1.00 0.92
1.00 1.00 1.00 1.00
1.58 0.36 4.39 0.15 0.17 4.07 5.77 16.29
2.26 0.02 0.00 0.65 0.02 0.05 0.02
3.03
TOTAL LOSS
TPT
3.64 0.38 4.34 0.80 0.19 4.12 5.79 19.27
CO
>r
oo oo o ON' OA -p*
CONE ROOF TANK CALCULATIONS FOR 1988 (FXCAIC WR1) PAGE 1
TANK
PROOUCT
TURN
CAPACITY DIAMETER
OVERS
BBLS
FT. PER YEAR
68 SOUR NAPTHA
55,000
69 SOUR NAPTHA
55,000
+ 21 LS THERMAL CHARGE
25,000
+ 21 TH THERMAL CHARGE
94 LOCAL JET 50
2S00
95 LOCAL JET 50
2500
35 JET 50 FUEL
80,000
+- 81 SWT FCC CHG STK
120,000
82 JET 50 FUEL 150,000
201 LOCAL NO. 2 OIL
25,000
202 LOCAL NO. 2 OIL
15,000
343 FUNGIBLE DIESEL
80,000
351 FUNGIBLE DIESEL
80,000
370 FUNGIBLE 01ESEL
80,000
74 OtSTALLATE BASE
150,000
75 DISTALLATE BASE
150,000
76 DISTALLATE BASE
150,000
+ 378 FUNGIBLE DIESEL 22 THERMAL CHARGE
80,000 25,000
340 FUNGIBLE 0IESEL
80,000
340 DISTALLATE BASE
80,000
340 HEAVY BLEND F/S
340 CUTTER STOCK
340 CRACKED 01 ST
80,000
342 CRACKED 01 ST
342 CUTTER STOCK
342 FUNGIBLE OIESEL
342 0ISTALLATE BASE
80,000
+ 297
SLURRY OIL
80,000
+ 338 HV COK GAS OIL
80,000
+ 336
CUTTER STOCK
4- 36
CRACKED D1ST
-f- 37 SWT FCC CHG STK
80,000 80,000
37 CRACKED DIST
+ 83 SUT FCC CHG STK
120,000
+ 100 SWT FCC CHG STK 100 HV COK GAS OIL
150,000
100 DISTALLATE BASE
+ 101 SWT FCC CHG STK
150,000
{A >
101 F 71 4 72
HV COK GAS OIL SLURRY OIL SLURRY OIL
25,000 25,000
73 SOUR WATER 25,000
O +- 299 o 4- 308 oo 4 67 oo TOTALS UUIN1Ji
SLURRY OIL SLURRY OIL LS THERMAL TAR
80,000 80,000
55,000
1 ,550,000.00
100.00 100.00
67.00 67.00 25.00 25.00 120.00 134.00 150.00 67.00 60.00 120.00 120.00 120.00 150.00 150.00 150.00 120.00 67.00 120.00 120.00 120.00 120.00 120.00 120.00 120.00 120.00 120.00 117.00 117.00 117.00 120.00 120.00 120.00 134.00 150.00 150.00 150.00 150.00 150.00 67.00 67.00 25.00 117.00 117.00 100.00
23.90 135.50 40.20
0.20 18.20 22.80 48.60 23.70
5.10 41.70 58.50 61.40 43.90 66.80 59.80 64.90 72.70 69.90 119.60
4.00 2.30 2.30 1.80 1.70 3.20 1.80 6.10 2.70 8.00 2.30 1.40 22.30 2.70 4.00 23.90 5.40 0.90 1.00 4,90 4.90 47.40 48.80 180.00 12.30 4.60 4.90
662.90
VAPOR PRESSURE
PSIA
1.3000 1.3000 0.0150 0.0150 0.0150 0.0150 0.0150 0,0120 0.0120 0.0120 0.0120 0.0120 0.0120 0.0120 0.0100 0.0100 0.0100 0.0120 0.0120 0.0120 0.0100 0.0001 0.0120 0.0120 0.0120 0.0120 0.0120 0.0120 0.0120 0.0120 0.0001 0.0001 0.0001 0.0120 0,0001 0.0001 0.0001 0.0120 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001
0.0001 0.0001
VAPOR
MU
68.00 68.00 68.00 66.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 130.00 190.00 130.00 130.00 130.00 130.00 130.00
130.00 130.00 130.00 190.00 190.00 190.00 130.00 190.00 190.00 190.00 130.00 190.00 190.00 190.00 190.00
190.00 190.00 190.00 190.00
VAPOR SPACE
FT.
19.70 19.70 19.70 19.70 14.30 14.30 19.90 23.90 23.60 19.90 14.90 19.90 19.90 19.90 23.60 23.60 23.60 19.90 19.90 19.90 19.90 19.90 19.90 19.90 19.90 19.90 19.90 19.90 20.90 20.90 20.90 19.90 19.90 19.90 23.90 23.60 23.80 23.80 23.80 23.60 19.90 19.90
19.90 20.90 20.90 19.70
PAINT fACTOR
1.00 1.00 1.00 t.QQ 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.46 1.46 1.46 1.46 1.46 1.00 1.00 1.00 1.00 1.46 1.46 1.46 1.46 1.46 1.46 1.46 1.00 1.00 1.00 1.00 1.00 1.46 1.46 1.00 1.00 1.00 1.46
BREATHING
SIZE TURNOVER
LOSS
FACTOR FACTOR
TPY
1.00 1.00 1.00 1.00 0.97 0.97 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00
1.00 0.40 0.95 1.00 1.00 1.00 0.85 1.00 1.00 0.85 0.60 0.60 0.8S 0.55 0.55 0.55 0.50 0.50 0.43 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 0.65 0.65 0.33 1.00 1.00 1.00
9.17 9.17 0.02 0.17 0.06 0.06 1.09 1.25 0.50 0.34 0.24 0.94 0.94 0.94 1.34 1.34 1.34 0.94 0.34 0.34 0.30 0.01 0.11 0.23 0.08 0.16 0.31 0.23 1.34 0.11 0.03 0.06 0.01 0.66 Q.10 0.05 0.01 0.13 0.05 0.04 0.03 0.03 0.00
0.05 0.04 0.06
34.76
WORKING PERCENT LOSS MONTHS IN TPY SERVICE
58.57 132.81
0.49 0.00 0.04 0.06 3.25 2.24 0.60 0.70 0.41 2.32 2.35 2.36 3.23 3.51 3.57 2.20 1.00 0.25 0.12 0.00 0.11 0.11 0.20 0.11 0.38 0.17 0.50 0.14 0.00 0.02 0.00 0.25 0.03 0.01 0.00 0.12 0.01 0.01 0.01 0.01 0.01 0.01 0.00 0.00
1.00 1.00 0.08 0.63 1.00 1.00 1.00 1.00 0.33 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 0.25 0.25 0.06 0.06 0.17 0.08 0.17 0.33 0.25 1.00 0.06 0.33 1.00 0.06 0.50 1.00 0.56 0.08 0.06 0.58 0.42 1.00 1.00 1.00 1.00 0.83 1.00
222.32
TOTAL LOSS TPY
67.73 141.98
0.00 0.64 r 0.10 0.12 4.34 3.48 + 0.77 1.04 0.66 3.26 3.28 3.32 4.57 4.64 4.91 3.14 1.34 4-
0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.06 1.85 + 0.00+ 0.16+ 0.0910.00 +
0.60
0.13+" 0.00 + 0.00
0.13 0.00 + 0.02 + 0.04 + 0.04 + 0.02 + 0.06 0.04+ 0.06 +
253.81
1
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aa--ea--oea<Ot<--t4a<-D0a<-J:oo--WueQou--eWiou--acmWoo--euM0zJ--OVQ--OLu --I-M--i---Oi0zOuaKO(QutWtu~tOtKi~u<2l:.V<ea<IJUo-U-o-l-iBio^/>IIuiuxnUj<OuuXJixi-Ku-*z--*i
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8X< 8z<
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o-: o14 o
^OO'r^j'OO'COOOvTO-4O-rOSN--gOrOSrm\OiNHfrOvv.jjQNArmO\.jOO-'O{^Of0MffO>flMlMf'#^KMMONKs1O1M'N0OxKO>r0'sO-4gJO0-lrO-4t4l4'4-4''-'04'-|'KM00'O-`OrO'1OM^OS-OOr-
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5AL 000006236
APPENDIX I PROCESS EQUIPMENT FUGITIVE RELEASE DATA AND CALCULATIONS
SARA TITLE III, SECTION 313 1988 TOXIC CHEMICAL RELEASE INVENTORY
LAKE CHARLES REFINERY
SAL 000006237
<Ve_
.'pAne^f- ifoC-
L.c,
0 ^ S CT27
fr C.ru<k<t-j S~lc\b &l~fj U>R} Npki~hc(j kfenas&K^-j fiiese. /
<g,22 TP//sfrrh
t 6)
Benzene : fV.22 TTvYz^o^) j O.oo 2.3+- 0,oo2 + />??+ &<?/<5~h ^70,0,
- ( 9<1'1.TP'{Y2*>o;)Z </ w1%J
Cyclaine-xvi^e - (%*2`2 Tpy^zooo
J^O.OSZ. ^~0,02j
* 0 n,
= ijzH &
E-fiY! Benze^e ~(s,-22 TPi\-Zoo No,pki-Utt.nt ' (%.^V>v)(z`x>o&')lo.03+0'0}
Toluene ^ {'s.a.-Z
+ 0.0<{<>]
IL>5 U> * - /,2?3A
1,1,4-Tn& -- (S,12TPY)(2^^)[ <-\ <vf%3
= 0 /i,
Xv|e^e = (`%.22TPYy Zoooj~)l0-04 3
= &S7 /4
2) * Z CTU Swh Crude ^Si&b Off- C-S^j f'hp
Kernse^e^ b?e$e (
VOC-- 7,2% TRY /s4r^
Bez e^~-Ct-22 Tpj)(loa
)[o.oiz+-0,002 + .031+- 0.0 lo\ - ~7%i IL
C/doAe^ne - ('7.2?TPy)^ooo^.)/o.o^2 + 0,oz7
-- 1,0 42 n,
EUJt>ezee =- 0.2? TP'fYzoooz)[a.ort
(\ ^ CoAipos-,/''dn e?(ca~fc* '#7 f^'ppvC
-- >4G> !(,
000623a
Fcj^, F^p~j- Koc
F) ^2 crx
Hovp XI
x.
' 47.22
00 O
TPy)(' n
1-jro.o?
+ 0.01
)
-
(-7.-Z5
+\ /" 2000 lb
tpyX # )(7,01
O.ot/s)
47.7-2
. \ /^2oo /t
rpy)( +o~
)(a.oi'Z.-h
O.oc/ )
^.c.
-- %~?H !L = J,0?2 lb
- ~7S~~t lb
O H&S
OH L',yU:ci. ^ kerose^
N^pb-fia, G^^oi;^ Ccsfi)
ioc, H,sz.TK/^
= ( HSztp^C-2^^- 'Xo.oo'z^O.ato + 0,01s?)
= ihl lb
4 -52CyHoLiepca^e - H
TPhY~ZQ XVorz f o.Oz)
E-Hiv[benzene. = 4^.5z TPyY~~Yo.OIO )
M<*phibnieh* = (XSZ T/y) C^f^Ti)("o,03 + 0,03,)
=-- C V. 52 TPyX^^-^-Xo, OH 5 +- 0,03)
X^IWe
(H-GZ Tfi)( ^^Yo, OH)
=- 4 67 u>
ion sHzi lb
(oVi tb
^&
H) * 5 ///)5
b'Si'll^ic. Cb<'p$e.i) A/cpMUIe^g -- A 77 TPyXJl^kYo.oz)
']/OCL o
*? ^
= 1/7/4-
SAL 000006239
2
E-cyfyni* VOCL
s)* 3 CRU &rHDS
Lx C,
Voc- = jo. bo Tpy
' ClO.UO Tpy)/
Xo.o/o-f 0,072. )
- ((OLD TPy^i -for>
CycUewne = (!0,(pD JPyY BMy/W^e- TPyY^tYO.OIO+ ao^) *72/^e - 6o.faT?l)(~-ya.oHS'+ O.ft?) )^H-T/ni - (io.(,D-rpy)(^^YYlo'Onl Xv(ene = (l0.(*OTpy)( ^ )(o.o<fo + O./Yo)
o) ^ 1 Collar.
Coker*
^ Cr?k:er' WeY- <*$
YOC - ffi.Ol ^/sir^ 8e,,2e,,e = (H.02 Td )( ^L~)( 0,00 s )
C^e^e-- (tf.0ZTPy)( ^ )(O.oio)
Cyc.lot\e.x<**z-(lci *0z TPY X
){o,olo )
Toloe^z ^(h.02 TPyX ^ Xo,oHo )
- /,7V* 11 c l,*M2H> = Hztiiy ~ l) ! h(p lb = ?,*76/ - /i340 ' 3^1 (eft,
//V /6
3"^C> /, /, S22 ^
SAL 000006240
Fi>cS*'*i, f-t--- ----------- ' 1 Cj>l<^r Cc.c^itJ3
\^M-rnk (n.o2n>i)(
Yo.o'O
XvfU^e. = (n.oz> iPi)(
yO.Ot>s)
E-Hvlen- (lc?.OZTPY)(1r^)(o,Ol)
Propvlen^ ~~(ft.0ZT?l)(^,,k)(0.O7S)
1,3- R^d;e^(tf.02 TPVY)(o,Ool)
-7) * Z Gker
Giker- W'e-f
^ Co/co- G^sohne.
VOC = 3.65"TPy/s^^
ge^ee = (l.<cTPy)(-STtrS)C'Ooz)
= /3.6S'T^yy
')Co,oio')
Cyo[cWex'eli'^ r (S'faS T~P/3 ^
Toluene
- 6^5" TTY)( ^ ) (OOHO)
~~(s.U9 TPY)(
y.o?l
XYle^e - (3.^TpyKV, ) (0,06 53)
^v/ee. -- (3.67TPyV ^ )^,o/)
Propylene , (3.^ ^ y )
(O , O?)
.3 SuiW-'e^ - (iUS TP'/")( iTi )(o.ooi)
<-{
it
S-
L.C,
= 2,473 /& - 3SO /4 - 2,66 3 /6 = 3<S /t
- aa = 73 tb> = 7? rt?
742 /3 2/4 - Pl5~ lb ' 73 5/ / f ~ V /
SAL 0000624l
\/@ CL
L tC,
S) 6^S fig. CO I^ry _RktCGRP)
CLo^Ce/
\ 0-D V'/e.'f
Cpyo P~S s
^ P" P j g
<j-*tsoli'r\j CfilcJtn
-- 7,Tpy/Sirv
RenZd^e ~ (7&1 TPV)C +,,, )(o.Ol + 0,oo3.')
- 200
Co^e*e. - ("7^1 rpy)C
)(a'OI 1- 0.01)
= 307/i
vJokexeuie ~~ (l.&l TPv)(
)(otoi *o.oi')
Toluene -- (l.^-rpyY ^ Xo.o^o.oY)
11 307 ^ * U3l /A
\m -me - Ci.^ TPiX^^Yo.oz+o,oi)
-- 773 U
Xylre -- n<*l TPyY^--YO.Ob<r f O.OG^)
= 2,ooo //,
&kJ&ne ^ (t.bl Tpy)(
)(o.oi)
" /S7 ^
Prbpylene, - Cl.U't T?y)( -h>~ '}($>07+ 033+ 0,G>%+ a os-') r / 7 5,3 QI6
1,3~ iSu'fadt'e*? - ^7.67 77^ 3^7 )(<3,oo/+ <7,Oo 2.-(- <7,023 + O.Oo'j') - /38/6
7) ^ 6 #DS
Stripper OH^ ffD5 6-asoI;^ b^-hl/aiz.
\/oc_~- 2,37 Tpy/s-i^
Be* z-r>c ~ (237 TPy^t-
'Xo.ooi 2.4- o.ozi')
= i^O li
-2 sal 00006242
<?)*> rfZ)S (a>n'f~ic( )
Cycfolok:*^ = (2-3~? TPY)( -h^ )(O.OZ2-')
AtapJvfAv*(e^ - (.237 TPy)f
X0.030)
Tol^e^e
~ (-1^1 1PY )( vZel!L )(o-l )
*7 H-OS
*15 /Y'Z)S S/ry> {Re-Hux (asso^e diesel')
V*OC - <?.<? <f ^PY/sW~
^pWtU-yU^C - (0.lH TPi)(
Xo.oz )
- 24 6> IL " mit 1 /V2/6
-~ : 50/4
t) Fee FgecJ Pre^ b,'ese.l ; SUp O.'i VOC - I-1& TPY/sir*
.Se^e^e ~~ (I ~e7(0TPv')(?^i~')(ol0 3)
//^ &
- (l^k ^?V)C7 EUYtbe,,z,,e : fl.e?6 TP/Y ^ )(0.O2T7)
AUpMUene '- ().*!(* TPY)(l^f)(0,0^6 )
Tolv&,e
= (l^PTPy ')(^~)(o.O^)
1,2 v -W ` ( /.^ TP/') f
'Xo.OZ )
yv[^e. - (/.% TP/)
(0. 13 )
t(oS !i
= iO(o IL
- U$ l(,
" s*y/i ' 1Z /4 ^ 5/0/4
SAL 000006243
R-JO,, E^,pr^*f VfcC
L.c,
iz) Fee
Fec-abt) 77,// 6^S ^ P-P, S~e) Fee. G**oCnc
ifoc- n,iorpY/s+c^
Se*^e*>e 1 (l~},ciOTP'l)(' -t*,, l(o.o i(')
- 3*W/A
r.u^e ~ ( l7Pt0 TPYY 7 ^ )(o.OSt)
- I,S 26? li,
CvoUicnr - ^
TPY Y) ( 0,0 / o )
' 3S% /fc
E-&v(fce*ie*e =-(17.10 iPyY ^ X&<03o) ToLene - (n.10 Tpy)(Z^ X0.07O
' lb - 2,712. lb
if2V-r^/ - 7/7.?o tpyYz
Xo.osi)
XJe*e - (17,10 TPY Y%T7)e m)
- llloiL - 7.0S2.IL
Sttnlenz - (n.io tpyYz+b,,lXo.ig)
- 5,7.22 H
PrapJe^e = (l7 .ta T^0( 14>Y )(o. IZ+ O.&8 + &s)
I'I-BuMm? -(n.^oTF'/YY^ )(o.-z+0.ooz+0,oo i) =
iV) Crya G^s Crya
Cryo *7^,* I <?c,S j Vyc> ^~l2>
1/OC-- ^,7 7 TPVs^ = (s.^7 rpy^-^fr^Xo.is-)
s 2,6?///.
SAL 0000062** ^7
&ypr~i Vo-
\l) CryQ 6mS
Pr^knt - a.^rei)(^)(o^*o^i* o.-n> %MLk
I-z-Q.ooT-~)
- -2i4
/0 Ply
p~p>
^ Voc, = 'ZOt<fcf
Propy(g^e
= ^0.5^ TPi)C^r)('^
;ti
:
TPy)C2tt'
oal>^
- 5n5t`h<l fe ' 1^3 /6
,?\ cRjjjtJibS?
J-----------------
N-vpkfUj ^lolexr
tfek^-k.
]/OC- - H.O^ TPY/s^
iWene *
tpiX^t-)(a.i *
\/ieol - 6^ T7=y)(-^
)( o.oCpSr)
C.
Cvo(oU^e -(`f.O%TP'f)(*xx>&)('0za+ -^
B^Jbe^ene - ^TPiY^^^C0-OI ^ '0<{5^
*21*
555IL
528 & H'-tct <L
To Le * c
05 TpH)(-zoao^)Co.OHSy O.tsrfO.oi)
I i <-( -jnn& ^ (Ho% tPY")Pzoao ^7)(0,017)
"
l&Uk.
(p ,0S ~rPy^(^o&o
^
/b
SAL 000006245
Fl>4.
V&C
i-*c.
1(e) * I HAS ^3 CTO Kerosene
j V&<T = ?.c/7 TP ^/s ^
Napk-Hy*U,,e. = ^.3.^7 TPy)(J^JLXo^Q2 )
= 20? &
17) TPerw\*| XZn\clcer
( Coker Wsrt' G*$)
(S-Sd^V\.e. Fr^.cjf <^o (fov/\c< ^
3.77 ^`/sr*
Benzene - C3.77 TPvX^^Xo.oO
- 7SIL
e 337TPY X-^--Xc-c,-)
{Ryc{oRiex^^ ~(371TPyX +x.n )(-o0
To / oene
* 6.77 ttyX2^* Xo.o<<)
= 65" lb ~~ 7S lb ~ 3&2. lh
12;cf_x^e = 6.77 TPl)(-
- TO-h )b
--X----vr--(-e--^--L>fRvfe^<e_
Pho^yfe^P
- 6.77 tty)( ^Xo.^s)
s 6.77'm) ( tor
^)
--
6-77
rpy)C
?ooo ^
'?\/"
x
X'7)
- ^0 lb,
r 7S M
ij 3 " ?<-*"Ul <ei,,e = <6.77 tpy}r-^Xo.ooO
7 !t>
/^) C^i'^he^ol
CP6c)
Reid Pgc^
^'VcV ; P~ P ^ (i~& ^ Clhf ms<?i7^e
V<9 0 = 11.^ ^'/s+rv*
sal 00006246
Vo a
L.c,
l`%') Unt'-f- CcoFd')
Ben-z-eoe - ^1^.22 TPy )C^^r'%0-0\3+0,0\1+ 0,0?/)
I,<gOfc /
Cydohz.xc^t = 0^.22TPy)^^77 )(o0^3 + 0,03.3-1- 0,037)
3/^; iL
E+kfllaeze -
2Z TPY)(~f~)(o. Of 2, )
V6./ /i,
N*pk+k4ee (lc>-?'ZTPY)(J$Br)(<3<Olo )
38^/46
T^Lene ~(lei.'n- rpy)( ^f^r-)(o.o?zi-
O.ori)
Xyie^g - ^.Z-z rpy)CJ^r )(o.oH7 + o,oH7 + 0,077)
Pofy le*c '- 0eLl2Trp'f')(z%?/ )(o.G%+ 0,0s)
/203 !L ~2^&jOCpf ib
l,3-8^cj:eng --Ciy.7iTpy')(c^s)(o.oo?^ O.ooz'y
^0 lb
4/fcy
6-6; p-P
; i/oc -
Prop y le^ - (&<*-! I *7"/^/)
IcWf
TP*/s^
^-C'.OS'P) - /S~j Infill?
(toMt TPY)C2^Jh)(0'O0?i O,oo3) - /OS iy
-Z&) /)^o( P/c*
S ws
;
E~f-i^vletAe " ^/. i? rpy)^
Pro r v 1e ^ ^
n.i'2- tpy^
1,3,-S^ci'V^e
1. iz tpyY
10
l.l^
- 50Q. - s4o n, - 2 /
SAL 000006247
L.C,
2-0 (%/ex
kTero$e^e^ Alo/e*: <S^$oh'^c
; Vfec. == o.^TPV^,
Benz.en -- fo.17. rfr)r-TSr ')(o,ozai')
- 7a IL
Cyofol^eK^^C -CG.IztTyX -tTM ) (0,052.) A^4\p?l-v/ k<* -Cowei')(^
o
C+
O
*1
- lb - SS )b
To|o*0(^ -- (onrPY)C^-1 )(o,0?o )
-- ss /&>
a20 Safc'/^cL Hi^O ^ V15+* tf~A;b
Assume 1 ^vAjar s~h~e&
l/OC - '2-,lG TPX +- 0,G~7 ~rPi
- 3,63 T^Y
Btnze^-/?.6? TPvV +=- )(-'?`5r)
- X^H! lb
~tUy l b&n ze *n e.:(3.<,im)(^-LXc>'0y) AfcpM'AiA --(rui T-eiX^')(o<0(o )
- 3J=)o lb - V36 /G
1 o (u-e^e =
- Ij08i lb
S'fyre^ T (MTnyzgt Xo./O )
-- -]^{p lh
Sal
Fu3,
Voc
L.c.
l tatsi (r ^ ^ Fu
t~o&dt ^*yc^ ^
Ccvtk^j
t>[aj~ G&tSol '^j Unleaded (yt^s!fzzr dt1 ( {je%<rf=
^c\ph'tLc; y Kzr&se^Zj Dl'es^l j Fuel 3~cd>
VOC,^ ~2M<F! TP/
Ben-z.e^e = (2.ttS/ TT>l)('^^r )[o.oo32-t- 0.01(f) +- 0.0/J = .^Og? /&
<jO) 327 lb
CyMex^c =(z<f.s-t TP'/Y?2Br)[O.oil
7go !L
E-tty (benzene - fry.tr/ TPi)C^r)l'Oil(tt) ^o.ofj = 7,76/ %
Hcpittknjene - ('2M-.S/ TPY)(S2j~r')[o,Ol(z)~J
Tittle
TPlX
)lo.07?($)+- 0.0vsj
\2HJt
[(*,(*!% tj
2, *7 7/ /
Xy ttne ~(zq,5l 1 el)( 2-f^r ) 0,0/2. /- 0,/3^) i-O.oy'J - 2/, 6&7 H
Ettvlene
TFy)[^^) [o.oqPJ
2,77/ &
Propylene "(V.S7 TFi)(-^^) [a,03I
/;7 7/ /j
l^&uiattenc
rrjy)C^r')f<i.aoi(
Hi ji
SAL 0000062V?
Fug
i p> rv> esif 1
LAkB CMRtEs
I) tio. 3 CT(J &r Vac (s^P)
*7 Plajor Streams '
Ci)
{p S/W4 3/3- S^Efiit^s -
S~h*b cdHj Ls/?^ N^pb-fU
KerDivese(^
3 o^er h\/y sfneAi*^ - ^5 0.7 /_
/c. Pes.'U
* />^y 5 o/\ Sfa&Mn ' 3S2 c0
l/alve?*
4 ISO -
3<g^ ( ^ 0
* LL tekes - Q*li + 2S ~ 72^/ 7? O
* //<L l^es ^(l7?*{+ /&%Y-j:)^' 7-? /
Jl *&*& " (W?^X3S6 + 7^TM)=7^?O<0
*22 Pu^p S^/s = (11 +2) x /`/^ - /S ^3 0
it H-L
vp)
Sels * (22-*-<*')(iM)(:r) ' n
tL Co^ressor 5^(S = /x2_g!^ -2 (o o
Voa - jjs<g^(.6oii)+ 2<7m) + 7/5(.001,%)+- 7(,n)-h 7%I (.Ooosi')
2^Lio(.OOoii)^(,o1,l) + l`>(l07.(o')4 1(,Ig)+ n(,0<-f7) 1- 2<f, 2o)J^
Z'f-g-* ??2-*^L *
-fa*
"T" p
~la oc> I b
- ^.77 ^Vs+r*
S'ffVv,
O')
t~a.lce. FFar les
Bl<->ebaoI<;
/Jpp^ d Lfr)E-OS~ --pp. 36? ""S'7^
7) Gas /LL streams
Geavy streams *7 ZllcbfWc*/i skfi'e s/f
^ ToW ii,^
sources/^-f & * leaU/r^ leak
/m Vtoc.
tOns/LL). Heavy l.'a, y source, es/^of^c calculi-*, are also a, Hc4 c bed. Fla r>c,e. "Ik/no/k eU^ ^Fors;-'!e ' '"" &,-/*-
(P') FF^~.p rc/.ob
C) No. a. era
L.C.
% ^Jor S'frveA^v\S
(p 3(3 S-tre.a^s '
**s AC 3 CIFO <- IAC
*2 o-/-Ae^
s-fre-u-vs * /^. 6^s 0,7 7*fpeA OWe Ctfes/j)
it ctn S~/n
3^5-
417-^0 - 3*h Ch l)
*ulv - no*,
(e05-
^LLV^ 077 (3L)
*ll />$= /o*/.? - N(hl) *-ul P5-- no,<o(*)s /b
*cS - 1x2. - 7 Co c)
* ^ " (^Sl)(3c{1+ y~>H + <*os)- LoT> 12(7 l)
a)
VOC.^ l3i5(,oo/i) + cJ(,Ocici') + Nyi(oo3s)+ 7(,l^) + GoS'(.ooas'l')
-h OiTSiooorCyt 7 ('.ossO + [o(,02Xo') i~H(,e)(i>) + iStH7) t T^)!-
,, h
-- _{_
<^
^
X 2-Y <H * ^(oSC yr * 1.000 11,
6 S4i?/4 sir
7.r?
-i) No. h ms
Lo Na.jor' S*{~re.K *vn 5 r
5" sA4 = 0(4 Ly;J Kerase^^ iVese
1 kvy nor\~SAN/)- - Cycle Oij
^ Zky$ o*n Sfrec,
SN7
(i) 9
S^C/^X !e<*l</p10 /e^/r
j a// -fjjHliAO
he^Ky \Cyulci p^-^p se*7s . He^vy l<'yx-o(
S
ba</e ~t^e
So0^1X -fUcbo
fy/ 6 , ^b/es ZW ir^Z).
-ft /
le^4 ,'^7, v^lve^
SAL 000006251
j) /Vo, */ t~fb$ Leonid )
L.C.
*&{/ = S&3 - "7S- ' sn C% L) *LLV- 23.2. CZL) *HlV - 353 (1-) - 235"
PS = lx j.H - to Co c) *HLPS= 0> x l.4/ x-| = ip *cs = 5 * 21 - (0 Col)
*F~~ (3ZH?)(sts+2.-mz3r)= Hm(sC)
Voc' [sto(lCsoi(')+ S(.ocfc)) + 23o(,ooz,<g) + 26/<0 + 23s(.ooos-l') + pi9y(.o<x>i??)+`>(,o<iz)<-/o(.07&)+ (fi(.oin')+ (d C.T&yj-^
3^7
' 4. S 2.
+ s- SAM s+r*.
h) No, s HbS
1'or S/tea/tis
^
2 S/W/4 1
= /)-s/.7^Ve (bf'esel) } Ovkd Uyu-4
3 Kvy
SfiPP - (>=is O'I
U--
^c)
{^c^yo, 0>f~)
335
*l/ = 20/- Hs = /516 ( 2 0)
0
*H-LV* 3G>Z
*fyc PS - 10 x /,</
Vs -0
= yiw-in*) -- ^*0(10
70C = [isyf.coti ) ^-zCoti) * l4^(.aaosil* I27l(m`i)*l(^y
|-3?4> 3/=^
2. S/M ,fr, = 1.15^
SAL 000006252
3
s) No. CRU irtidS
/-C,
5" ^jor S'ir'e.^ry^s (t\ll S4K^')-/Y^p^"/'A
^* S^r/^OH
A* fS <=>n S*/rect
S4r.'p /S~h*k>
- 3F</
&**$ ; ^ 3 Deprop Off
*&/= 775"- /So - S&5(n l)
*5Z. 77- lSx /.<{-- 1% (l L)
*LLV^ HV^Czi, 0
2-//CV - o
*ttL PS = O
* CS = O
* ^27^3+2% I &$ * 6>*?/
f 73?) = <j2*7 (src)
yoc.-- j^SiS(.Ckili) + 17 (.Oil) + yp6 (.60-52)+ ^(,ll) + `fzsif.oooii)
+s(.osi)-+- n(-^')+ i(,%)Jx1L{-hr>( 3+ssm
~ IO. UO TP%fr^
7 S+r*v,
b) No, I Coker
(o 1^*1 J or Si~f~e^ rV'l '
2. S/174 - Coker- W/e-/ 6^S ^ C=/cfir
//n (all (tcjkf)
o\ ^,no-SAM-- ftes/el, Fee LCO; LGJO, HCGO
f i-v>
- 353
77/ - 70 = 3S7 (f37 l)
^ />S
l. 7- 7 6/0
^LLV lOl C 1 L)
*//6 Fs = o
-O
*CS
* p = ^ l07,^35-|+ (Of) ^ I/pW( e (,)
- /> 2,o - 2 (/o <0
SAL 000006253
7
L~\C'
VOC =[317 (,0c;i)+ ?><{(,OV=l)+ l&OC.OOZ?)-!- IC.I1!)* tfe/Z(.oooii) + -2C<m)
-1- 3(.0'UC*)+
21-^*353^* -^77b
^ 2 SARA sfre^r^ =
n, OZ yp%r^
7) frlo, 2 Cot<er
Ld Major S'f-i'ea^s 2. SARA - Coker- Wert 6k Coker Casol:*^ 'f iovy oon --SAR A~~ S,po^e 65// (sc^/^ fjestd.^ LjZG-O ACGo
W try s, c>o 2fre^ ^ - 3S"2
^6Y = Y?/ - ?6 - 3ll(^L)
*ll ps= y
*LLV~ m ClL)
*f+LpS>=0
a#LV s O
* CS -O
= j^(-nl+icf)= IUO(il)
& to l)
'Joe,= 3%C,O0/|')+ 3(.ae!t<i) + 73 co^2)+ /(',/<?)+ /6>SB f.oaou)
+ 2-Cv)+ &f,OZk)]-ji xZt/jfx ^2jpx
3- 2
sW,
if) fras _Recovery Planf
^ ^a>r <g-
-3- i^u/y
- Mr'sc. Li'^lwf E*ndGolfer ~~TCiU &**.$ Cryo P~Ss^ TAerv^
r Coker (S^o/.'ne ^5 7^;/
P-/^
SAtf/f Stfr^.^1^n --
I
SAL 000006254
is) &fi P (c-Onj-d}
UC,
^ t)a.y% 00 SjrBarn - 35\2
3H CtOL)
2
ll
ps=
/?>* /.</
= /<wc)
*LL\f^ HS-bCiL>C)
it HLZ " <3
*~H-C PS = O
CS = O
F = '6^1 3(</ + c/'5'i) = '21'X\ (3 0
/&
C30^ C-00'!) + \G(`clc\) ^ll(,ao3>i) + 3&(n)i- '2.~72(e (,OoO li)
t'iC.ostj+HC'02^) + cf(.`u,)j!L
- 7.47
K
~-ih -3
S4/? str.
i) Afe. 6 ft)5
3>
S-fre^^i
S4/?/f) = Srir<pp<z<~
//Z)S <5^so/^p^
0/VAtf<^e*
!%-lOl(oc)
/),y$ o, S~/re^i^vl - 3^S
a LLV~ 31 Oo O
"U.PS- "ZX !.*i - 3 (oO
tL
//ci/- 303
`tic Ps - /z v /.*/ = '7
*F--(T$rXlol+zi+*>z)
tzL) CS - O
+ -z(,o%i)
Voc r [\o{(, 0011s) + 3 <7 f,00 38) T- 3o 3,(.oooS~/)-i- f $ZL (.0001i)
+ 3^02'6>) + /7 6^7)]j; lH jr y
* I 7o o
"2 000 /fc>
p S/I ^ /] S>^3r^ 5 s_ 2 37
SAL 000006255
to) No. 7 H-b$
5 (I*!on S~fr^c\ry\} *
J S^
3 Invy rtirt -S/W/M
H H~fo$ S+p KZ'f'/ts'X j S'4i~,'p, Ot/A{
&Ko) j/?e.3 - //C&0, 6^5 0,7 CsW)
^ s o^ S'rea*n - 3>'2~Cp
*&V= 22/-yS"-= nCpioL) *LLV= 0 *H-LV -- ?.i?(~q~)-ss-
^U- pS - O PS ~ HCiMY'h)^ I
*-cs - O
<tp`" (-T&Xl^ + ^) = l^z( I l)
\/oC-' [nO>C0il) + SS~C 6oo5~l) +- 98 I (oooi^yiCoi^OY'?)]-^: * 2-/^
X -IK* i? x i~-,l ~ -Z SAfifisIn** s = 0,*H T%^,
*0 /r`^ Feed, Prep
3 Sire&^s : * 4L - 0/ese( , S/opO,'/
i_ Av^ ^0*0 -
^ (Sr^s /
f)<=\y5 cr r\ Sf^Sovn^, -- 33 S'
^GV-
^O 6)
~LLV : ZS 0 <l)
*-ll
= Z V /9 = 2 ^oO
*HL PS-- 8 x IG = II
*4fLV -- wf in = 7Y
^CS = O
4P = cun e?^*+to-- 6?zg ( / 0
U'V*
SAL 000006256
i) Fee Feed Anep CCon -ul)
uc.
VOC - Is-cfC'oaii) + -2,8:6 ?*) + )q(.Ooo^i')+ & VJ (,aoori)+\(/sv
+ ?(,0%b)+ 11 (`oer>)3 * 2Yi * 33T-^Z *
4- 0, S/W4
- /.?& Tiys/r^
-)_fcc_
^ PI *jon SfosAws
4
- /&5. 7i;/^ P-/?
/=cc. <SW/ne
Ai/y /
" 5$?/l ~
^Z)^5 >n S'b'CAt+y- ~3&S~
Otf Ch*) CS/brewf \ ^2- <ZT~(J <etS
_^
O
D^S, (y^s O, I j LCO j Slurry
?
(py* S"?3-?s"= S5S^6e)
Ps - v% x /,</ - 25^4 e)
^U-V- lot2. (Tz? e) itHl V - 0
u H-c Ps -- O
* CS - /* -2.0 = 2 (foe)
MCJ/Z)= ^%K^L)
V<3C - jV^Z^ooi/)^ ^,c^) +- cj<Zl(,603's) +- 2^./^ `/%2(r.ooiz)
+6(7'9) +
(OZ &) + ^ (.^g) f- 2.62-)7-- * 2</ -3v-sr*
X i---- 7 Sdtf/4 stV^*, -
Tjoodb
1-7 ,<3(0
1/1 ,(-^
V,
/5fr^,
SAL 000006257
3) Cpyo G<XS
i<c
~2> 01<=<jor
- C~ryo FeeJl G^j (Zryo ~7c<U (y*>
ca ,
Qc\yS O S~fY&_tK r*\ -
Cry- P-fi
MG-V- /37 (2.0 l)
*F^ 3.6 x (iZ^+GS"i) - 2v
*221/ = U^lC 2. O
^H-cV - O
*22- PS' - * I'H ~ ~7 (0 t)
ps - o * S ^ 3 * "Z.o - G (o t)
l/ocl ^ j^l/cf(.ooi()-t~ zo (.a^p) +
oazg)*- z(.ih)+- ZS'^.ocoii)
+%0t$)+ 7(czG)-hL(.2)J <- ^-zti^x S2ifr^7 3s-^
- $.97 TPYA-h^
N) Cgi- Pa/y
9 6k jor S'Gca^S = P~Pj Propane
Pafy <S^so.
^ &*ys an <P~h~ein, x 3&,5~
^ 2-zi(/y c)
*F = 3.6 x (zz'i^Ofz) = 3yClO[^c)
*LLV - 6/2 ("^ 0 *LL Ps r /6 X /,y * 27. ^ 3 O
*-HLV ~ O
UHL PS - O
fcCS - O
VtoC ^[zio(.ooif) + rf{.on)+ STY6*5 5*)+ 5-2 /V) + 3007(^,00013)
r3(,otz) +rt (.026) f
-k- x 365"
- H s+nza^s. = 70t SF rPy/sFea^
SAL 000006258
o No. 2 CRU irHbS
L,<L
(<*// S/?V?/0 " Ntphfh<\^ fHolzx <$Wso/,Vi^ $fo>. <*$, s-fet.
A* y 5 ^ ~ 32,
& V = 6,01- ISC- N^t(GL)
21 Lt PS* 2xi.*t* fl (be)
* LLV - 3^/ fa L) *H-LV-~ o
& f+L- PS - O
* cs = / *2.<5 -
fot)
*LF " (izrr^W-X*7-1 + 3<//)"^ c.-)
foC^fairC.ootfi + hC&l) + ^31>(,03s) + %('h~) +32^ (.OOOI^)
+<{(.0ii) + l( (*0 * iClojJ^-x 2</~r- 322-^ " 5 sm& sPe~; - V.02
' *
2^00 /
N> f ^65
X AUjo/~ S'fre^*^
$W?$) - ^5 cr^ /Cenas^e
\) , j <2=i ^ ^
^/kys Or\ 5-fr^^ ~ 3o<-(
sbb.o#
*&!/ = 3SO - /35~ =, 2/
0
*4c 6>S =-0
*4^ O * /// - 36 <7
*H-l PS = <? x /, V - /$
i C5
o
a F-
'ZiHJ ^`
aiS^ 3G>V) ~ 'Z(l^ci(-i> L)
-h lM(^*i\)
l/OC^^a^oo/O-f 3(,Ocfct')^~3CD^(tOaoS-l)+2J^gl Cooii^+B(,Q^^
xll-^x 3>oi <=4 V
v Ze<50 /^
~ "2 sr/ne^s =
3Al ~rPY/sif.
SAL 000006259
/7)~T^erm^ I Cn*clscer (STCu\
L.C,
5~Sr
ZL SA-RA*
^ ..
F/ac/- (S=i3 C^^kci)^
iher^i o-^so/.^e 3
*3 Ai/y non-S4ft,/l^
(j-C*S O'/ 3 C/c/e
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1968 ANNUAL EMISSIONS LAKE CHARLES REE INERT
Cmi ex-S)
Source
fIrlns Sate
Average Heating
feed Rate (Tons/Yr)
Particulate Matter
Calcined
Production Green Coke Coke Emission
Rale
Sulfur Sulfur Factor Emissions
Tons/Yr
Ut. X
Ut. X Ib/MMSCf Tona/Year
Sulfur Oloxide
Emission factor Enlatlcna
Ib/HHSCf Tona/Year
Nitrogen Oxides
Emit*Ion factor Emissions Ib/HMSCf Tans/Tear
Hydrocarbons
orti Ib/HMSCF Tona/Year
Carbon Monoxide
Emissions Ueeks Of Ib/HNSCF Tens/Tear Operation
6 H-6
565109
329156 329156
602952 484453
A* \ \n 62330
B-7 fuel
1252051 1021586 1052326
104639 103562
(totoe lone
*!VBV6^ t 2754300
B/ A
4/6652
290622 H/A
H-2&
379959
H-3101
86713 62020
119820 120949
SRU 133174 139960
668901 1076179
58 K-3002
831221 1111162
S9 H-J801
1813867 Z3S10S3
N/A N/A
61 N-H
629254 671201
62 631 uv% 893392
63 H-1201
118534 1195OS
flare fZ
N/A N/A
65 No 2 Cole
Premiiaa
Cl In incln.
Total 66
67 H-3901
66
302460
575362 677642
392925 72659
246251
451026 696064 1347110
72827 260944
937 951
946 946
941 941
944 966 971 1010 (
< ( (
62450 ) 58900 )
3550 )
62450 ) 62450
17338
974
963 15702
946
1057 991
607 748
772 4213
938 930 992
40298
<
< 671 642
652 ( 934 998
944
1S1600 ) $7550 >
209150 )
47150 44650
2500 47150 47150
74500
75950
122300 S03S0
172650
4.73 4.80 4.78 4.78 4.76 4.79 4.75 4.75 4.75 4.77 4.88 4.90
3.11 6.tO
3.28 0.00 4.91 4.92 4.91 4.87 S.15 0.02 4.78 0.00 5.34 5.00 0.12 4.08 3.78 3.90 0.00 4.73 4.70 S.01 0.00
0.78 1.4
0.95 4.72 5.04 4.77
1 25.47 1 25.84 0 25.71 0 25.71 0 25.71 1 25.78 1 2S.S6 1 2S.56 1 25.56 1 25.65 3 26.25 3 26.38
92 39.17 11 2.19
0.67 102 37.74
0 26.90 6 26.40 1 26.48 7 26.41 1 26.18 40 112.OS 1 4.00 1 25.71 0 0.00 0 28.73 0 26.92 11 1.09 2 21.94 2 20.33 5 20.96 0 0.00 2 2S.47 2 25.28 0 26.95 0 26.90
59 2.13 40 14.18
26.49 26.49 99 5.62 1 25.37 0 27.11 1 25.64
8 6 1 1 1 7 4 4 4 3 17 14
1154 4
21 1178 233
31 6 37 4
880 149
5 0
1 2 132 12 11 25 1 9 11 2 542
161 408
6
12 588
5 1 3
132.54 134.46 133.83 133.83 133.83 134.17 133.02 133.02 133.02 133.48 145.43 137.26
1.22 0.59
1.18 18.90 137.38 137.80 137.45 136.24 8.55
0.00 133.81
0.00 126.87 116.88
0.17 65.68 60.85 92.58
0.00 132.58 131.55 140.27
18.90
2.09 3.11
2.37 132.04 141.09 233.08
40 2.84 33 2.88
4 2.87 4 2.87 4 2.87 34 2.88 23 2.85 23 2.85 23 2.65 16 2.66 94 2.93 72 2.94
36 0.07 1 0.07
37 0.07 164 0.80 162 2.94 33 2.95 195 2.95
20 2.92 67 0.00
0 0.00 27 2.87
0 0.00 5 3.20 7 3.00 4 0.00 35 2.45 34 2.27 109 2.34 0 0.00 44 2.84 59 2.82 A 3.01 381 0.80
158 0 89 0
248 0.03 28 2.83 5 3.02 30 2.86
i 33.13 i 33.62 0 33.46 0 33.46 0 33.46 1 33.54 0 33.26 0 33.26 0 33.26 0 33.37 2 0.00 2 34.32
2 0.06 0 0.28
2 0.07 7 4.30 3 34.34 1 34.45 4 34.36 0 34.06 0 29.85 0 0.00 1 33.45 0 0.00 0 37.38 0 35.02 0 10.79 1 0.00 1 0.00 3 27.28 0 0.00 1 33.14 1 32.89 0 35.07 16 4.30
0 0.3 0 0.16
10 52 8 52 1 44 1 44 1 44 6 45 6 46 6 46 6 46 4 46 0 52 18 44
2 28 02
30 2 30 37 52 40 51 6 51 49 51 S 48 234 52 0 52 7 45 00 2 50 2 47 256 52 0 51 0 51 32 51 0 51 11 49 IS 52 2 SO 87 52
23 45 5 45
3 19.17
1 33.01
0 35.27 0 0.00
8 25
7 52 1 50 0 52
Feet
Flowrate leap. F AC FH
6.0 800 31877 6.7 900 28063 4.3 750 3775 4.3 750 3775 4.5 1300 5506 7.4 650 27485
5.5 1050 25187 5.0 1050 25157 3.5 1050 25187
5.0 900 15467 5.5 475 52264 6.0 475 50397
N/A N/A N/A 7.0 5.0
N/A N/A 8.5 3.9 6.0 4.0 5.0
3.0 3.0 3.0 5.0 8.0 8.0 10.0 0.3 7.8 6.8 3.9 5.0
N/A N/A N/A 380 1340 N/A N/A
450 450 450 170 375 800 925 925 450
375 375
375 846 300 300 450 1340
N/A N/A N/A 83100 38600 N/A N/A 114058 12319 131100 12500 16346
ERR 5596 8226 26400
32983 31553 66854
125 22601 28129
5007 69700
N/A N/A N/A N/A N/A N/A
10.0 6.0 3.0 6.6
380 134025 600 18618 925 4689 475 10279
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IMNHH S318h: 33V1 SN0ISS1H3 IVrWNV 6961
CONOCO INC
ENVIRONMENTAL AIR QUALITY
DENVER REFINERY "
RESIDENT INSPECTOR:
ENVIRONMENTAL ENGINEER: .lYiaJS&K^
PLANT MANAGER: PERIOD ENDING: FEB. 15,1988 DATE: FEB. 16,1988
LEGEND:
UNIT-- The unit being inspected. DATE-- The date the unit was inspected. SERVICE-- The function of the equipment. COMP-- CONOCO number- assigned to the equipment. VAL-- The number of valves associated with the
equipment. FLG-- The number of flanges associated with the
equipment. STAT-- The status;L=Leaking N/L=Not Leaking. RPR DATE--The date the leak was repaired. MTR RD'G-- The meter reading on the date of repair. * -- This means the equipment is out of service at
this time. TURN'D-- This means that the equipment cannot be
repaired until the unit is in turnaround.
SAL 000006272
07-/17/88 UNIT
DATE
ENVIRONMENTAL AIR QUALITY
SERVICE
COMP VAL FLG STAT
RPR DATE
MTR RD'C
ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/83 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ML UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 "L UNITS 02/13/88
.U UNITS 02/13/88 ALL UNITS 02/13/88 AI TNITS 02/13/88 ALl, UNITS 02/13/88 ALL UNITS" 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 ALL UNITS 02/13/88 d-L UNITS 02/13/88 ;LL UNITS 02/13/88 vLL UNITS 02/13/88 .LL UNITS 02/13/88 vLL UNITS 02/13/88 .LL UNITS 02/13/88 LL UNITS 02/13/88 .LL UNITS 02/13/88 LL UNITS 02/13/88 LL UNITS 02/13/88 LL UNITS 02/13/88 LL UNITS 02/13/88 LL UNITS 02/13/88 LL UNITS 02/13/88 LL UNITS 02/13/88
UNITS 02/13/88 IjLj UNITS 02/13/88 LL 'ITS 02/13/88 LL UNITS 02/13/88
ASPHALT ASPHALT ASPHALT CRUDE CRUDE CRUDE D-l D-120 D-140 D-148 D-149 D-173 D-173 D-191 D-194 D-236 D-237 D-240 D-241 D-261 D-36 D-48 FCC GenPlt GenPlt GenPlt GenPlt GenPlt GenPlt RECYCLE REFORMER REFORMER REFORMER REFORMER REFORMER REFORMER RERUN SULFUR SULFUR W-l W-ll W-2,3,4 W-25 W-27 W-30 W-39 W-49
W-50 W - 51
H-16
0 0 N/L
H-13
0 0 N/L
H-17
0 0 N/L
H-06
10 6 N/L
H-ll
17 5 N/L
H-27 144 7 N/L
RV-129 0 0 N/L
RV-175 0 0 N/L
RV-479 0 0 N/L
RV-143 0 0 N/L
RV-480 0 0 N/L
RV-406 0 0 N/L
RV-407 0 0 N/L
RV-111 0 0 N/L
RV-120 0 0 N/L
RV-162 0 0 N/L
RV-161 0 0 N/L
RV-163 0 0 N/L
RV-483 0 0 N/L
RV-478 0 0 N/L
RV-408 0 0 N/L
RV-491 0 0 N/L
H-22
43 4 N/L
B-8 B-6^
25 3 N/L 26 1 N/L
RV-527 0 0 N/L
RV-526 0 0 N/L
B-4 *
14 3 N/L
RV-338 0 0 N/L
C-18
26 20 N/L
C-l 22 12 N/L
H-08
31 7 L
H-20
0 0 N/L
H-07
35 7 N/L
H-12
34 8 N/L
H-19
20 5 L
H-10
58 11 N/L
H-25
57 5 L
H-23
0 0 N/L
RV-0I6 0 0 N/L
RV-402 0 0 N/L
RV-015 0 0 N/L
RV-340 0 0 N/L
RV-403 0 0 N/L
RV-100 0 0 N/L
RV-348 0 0 N/L
RV-360 0 0 N/L
RV-361 0 0 N/L
RV-357 0 0 N/L
nHv\/aZ)'
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02/13/88 <100 PPM 02/13/88 <100 PPM 02/13/88 <100 PPM
SAL 000006273
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Calculation Sheet
T*
jr.n Nn SAL 000006274
Clin )-S
% 1 CAL
1 COKER 1 HDS 2 CAT 2 COKER
GAS
VALVES
74
LEAKING
GAS VALVES
6
441 43
350 .
5
583 6
481 4
2 CRUDE #2 HDS
43? 5 236 3
12 REF
365 5
#3 CRUDE 13 REF 3 HDS
296 3 745 22 201 3
16 HDS
. 146
0
ACID PLT
X
195
2
ALKY AH! HE
282 22 571 7
CAT POLY
224 14
EDC
EAS RECOV
MOLEX
314 10
75 3
PBC PSA
HOUSE SRU
28? 28 830 4 250 3 139 3
TABLE 1 STATE IHPLEHENTED VOC MONITORING PROGRAM
LEAKING GAS GAS COHP. COHP.
LEAKING SA5 GAS RV r.t
LIGHT LIQUID VALVES
LEAKING L16HT LIQUID VALVES
10
1C1 1
7 0 36?(tf, U) 12
1 0 ID 0 1012 29
2 0 74
10
474
1 3
4 0 212
2
1 0 3 0 129
6
1 0 4 0 679
9
1 0 439 33
39 0
LIGHT LIQUID
PUMPS
LEAKIKG
LIGHT Prices
LIQUID Dr*,>
PUHFS
X
5
9 (H* <7 , 33
18 3
4 0 43
10 J S'? 6 0 36o 2 0 3o
11 2 51
13 1 S7 11
2 0 I O'*
o l 0 14 0 66B 25 IB 3 30*
12 0 638 4 14 0 3 H
612 58 16 2 'll*
53 8
a
453 36 13 4 57
i 0 31
0
\o
13 1 874 127 21 9 47
20
290 0
4 0 77.
10
SAL 000006275
%(p
;cu (K FARM
6AS VALVES
206
LEAKING 8A5 VALVES 0
m0
TABLE l STATE IMPLEMENTED VOC MONITORING PROGRAM
BAS COMP.
LEAKIH6 BAS COMP.
LEAKIKG BAS BAS RV RV
30
10
LIGHT LIQUID VALVES
179
2514
LEAKING LIGHT
LIQUID VALVES
j
151
LIGHT LIQUID PUMPS
t
92
LEAKING LIGHT LIQUID PUMPS 0
1
I
%o <7*
TOTAL
8270
201
8
0n
1 9860
508
264
32 S97
esfiV'Oit'C^
SAL 000006276
TA8LE 2 NSPS MONITORING PROGRAM
UNIT 12 CAL
VAC
14 HDS
IB HDS
CRYQ
L
FEED PREP jr; dOS
TOTAL
GAS VALVES
LEAKIN6 GAS
VALVES
180 15
180 0
563 9
100 0
139 20
54
xxt
0
0
1216
44
GAS COMP.
LEAKING GAS COMP.
30 30
60
LEAKING GAS GhS RV RV
1A
2V
14 0 2 (l
16 0
10
LIGHT LIQUID VALVES
LEAKING LIGHT
LIQUID VALVES
25 C
232 O4>
20 0 652 2
28 0
36 0 957
4
LIGHT LIQUID PUMPS
2
1
5 2
16
LEAKING LIGHT LIQUID PUMPS
f. 0
0 0
0
3
V
33
s
n
%
IS
?
SM. 0000062^
UNIT -SHAD -VHAB -VCH
TABLE 3 LESHAPS/NESHAPS MONITORING PROGRAM
GAS VALVES
LEAKING GAS
VALVES
177 1
GAS COHP.
LEAKING GAS COHP.
10
LEAKIN6 6AS GAS RV RV
LIGHT LIQUID VALVES
LEAKING LIGHT
LIQUID VALVES
127 36 u 0 cJl
0 0 4
LIGHT LIQUID PUHPS
LEAKING LIGHT LIQUID PUHPS
10
10
TOTAL 177 1
1 o i <\ 213
4' 2
0
SAL 000006278
CORPORATION
1600 Pacific Avenue Suite 2620 Dallas, Texas 75201 (214) 740-0040
June 1. 1989
P-89211
Hr. Ronald 0. Truelove Staff Environmental Engineer Conoco Lake Charles Refinery Old Spanish Trail P.0. Box 37
Westlake, Louisiana 70669
Subject:
Transmittal of updated source specific fugitive VOC emission rates for equipment at the Lake Charles Refinery
Dear Ron:
Based on the 1988 leak frequency data you provided for flanges. FORSITE has updated the Lake Charles Refinery specific emission rates for equipment leaks of VOC and VHAP. The leak frequency data indicated a leak rate percentage for flanges monitored under the SIP program of 0.114%, and 0.116% for flanges monitored under the NSPS/LESHAP program.
The revised source specific emission rates for flanges will be:
SIP monitored .......................... 0.00022 Ib/hr/source ^ <- ^ < NSPS/LESHAP monitored ............. 0.00022 Ib/hr/source /
These emission rates were calculated using the leaking and non-leaking emission factors published in the ERA document "Protocols for Generating Unit-Specific Emission Estimates for Equipment Leaks of VOC and VHAP" (EPA-450/3-88-010. October 1988).
A draft of the letter transmitting this information to the LOEQ is attached for your consideration.
Thomas R. Arnold Project Manager
cc: Brandt Butler. Conoco-LCR Bill Peterson. Conoco-PEO
Attachment
SAL 000006279
CALCULATION SHEET
Page 2 of 2
By
Client
T. Arnold
Date 6/1/89
CONOCO LAKE CHARLES REFINERY
Checked
G. Smith
Date Protect
No.
Description DEVELOPMENT OF EQUIPMENT LEAK VOC EMISSION RATES FOR FLANGES
6/1/89 89211
CALCULATIONS:
(1) Calculate the fugitive VOC emission rate for SIP monitored flanges.
EE = C(LEF x PCL) + (NLEF x (100 - PCL)]/100 where:
EE = Emission Estimate for SIP program flanges LEF = Leaking Emission Factor (0.0375 kg/hr/source) NLEF = Non-Leaking Emission Factor (0.00006 kg/hr/source) PCL = Percent of SIP flanges found leaking (0.114%) EE(SIP) = CC0.0375 x 0.114) + (0.00006 x (100 - 0.U4)]/100
= (0.00428 + 0.00599)/100 = (0.00010 kg/hr)<l lb/0.4536 kg)
0.00022 Ib/hr/flange
(2) Calculate the fugitive VOC emission rate for NSPS and LESHAP monitored flanges.
EE where:
EE LEF
= [(LEF x PCL) + (NLEF x (100 - PCD3/100
* Emission Estimate for NSPS/LESHAP program flanges = Leaking Emission Factor (0.0375 kg/hr/source)
NLEF PCL
= Non-Leaking Emission Factor (0.00006 kg/hr/source) = Percent of NSPS/LESHAP flanges found leaking (0.116%)
EE(NSPS/LESHAP) = [(0.0375 x 0.116) + (0.00006 x (100 - 0.116)]/100 = (0.00435 + 0.00599)/100
= (0.00010 kg/hr)(1 lb/0.4536 kg)
0.00022 lb/hr/flange
REV. 6/82
SAL 000006280 ___
FUK5I i'E
CORPORATION
CALCULATION SHEET
Page 1 of 2
By
T. Arnold
Oate 6/1/89
Chackad G. Smith
Data
llent
CONOCO LAKE CHARLES REFINERY
Project
No.
Description DEVELOPMENT OF EQUIPMENT LEAK VOC EMISSION RATES FOR FLANGES
6/1/89 89211
OBJECTIVE:
Update the equipment leak VOC emission rates unique to Conoco's Lake Charles Refinery by using EPA leaking/non-leaking emission factors and 1988 leak monitoring data for flanges, and provide calculations to document the methodology used to estimate the source-specific emission rate for flanges.
INPUTS:
Per Conoco, results of leak monitoring data on flanges located immediately upstream and downstream of values monitored under SIP and NSPS/LESHAP monitoring programs.
SIP Monitored
NSPS/LESHAP Monitored
Flange Total Non-leak Total Leak Total Percent Leaking
68,672 68,594
78 0.114%
49,828 49,770
58 0.116%
(2) Table 2-2, Leaking and Non-Leaking Emission Factors for Fugitive Emissions, and text description of Section 2.3, The Leak/No-Leak Approach of "Protocols for Generating Unit-Specific Emission Estimates for Equipment Leaks of VOC and VHAP," EPA-450/3-88-010, October 1988.
where for flanges:
Leaking emission factor
= 0.0375 kg/hr/source
Non-leaking emission factor = 0.00006 kg/hr/source
(3) Per Input 2, the emission estimate (per source) may be determined using the following equation:
\ EE = C(LEF x PCD + (NLEF x (100 - PCL)]/100
where: EE = Emission Estimate (per source) LEF = Leaking Emission Factor NLEF = Non-Leaking Emission Factor PCL = Percent of sources found leaking
SAL 000006281
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FORSITE
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LAKE CHARLES
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U? 0000 6Z&9
1S88 Fugitive Bydrocarbun Emissions
EIQ
Source
Quantity
Monitoring Interval
Emission Factor. Lb/Hr/Source
Yearly Emissions, Tons Par Yaar
36A
36B 36C 360
Valves (1) Gas/Vapor Light Liquid Heavy Liquid
6,270 5,730 9,515
Valves <2) Gas/Vapor Light Liquid Heavy Liquid
1,613 948
1,011
Flanges
97.513
Pumps <1) Light Liquid Heavy Liquid
232 208
Pumps (2) Light Liquid Heavy Liquid
10 28
Compressors Hydrocarbon
12
Drain*
868
Fugitive Emissions COR Unit
N/A
SUBTOTAL
Cooling Water
55,924
Wastewater
926,600
Barge Loading/ Unloading
(7)
Rail Car and Sea Container Loading
CDR
34 (6)
Quarterly Annually Annually
Monthly Monthly Annually
None
Annually Annually
Monthly Annually
Quarterly/ Monthly
Annually
N/A
N/A N/A N/A
N/A
0.0040 (3) 0.0132 (3) 0.0005 (4)
0.0039 (3) 0.0050 (3) 0.0005 (4) 0.00183 (4)
0.0696 (3) 0.0472 <4)
0.0359 (3) 0.0472 (4)
0.1971 (3) 0.070 (4)
N/A
0.700 (4,8) 0.200 (4.11) N/A
0.440 (4.9)
144.2 330.2
21.3
27.6 20.6
2.2 781.6
70.7 43.0
1.6 5.8
10.3 266.1
1.1 (10)
1726.3 19.5 92.9
156.7
7.5 (10)
Total Emissions - 2002.6 Notes:
1. Installed as part of projects for which construction started prior to January 4, 1963 (SIP Monitoring),
2. Installed as part of projects for which construction started after January 6, 1963 (ftSFS/LESHAP Monitoring).
3. These amission factors are site specific and from AP-42 or Bmnislon Factors"(Appropriate EPA emission factor for leaking equip * I of leaking equip) +(Appropriate EFA amission factor for non-leaking equipment Z of non-leaking equipment)
4. These emission factors are from AP-42. 3. In units of M barrels per year. 6. In units of m pounds per year. 7. See the attached table for further details. 8. In units of pounds par Hi gallons. 9. In units of pounds par M pounds. 10. Emissions transferred to the refinery from the Chemical Plant during the Vista sale
as per letter to Mr. Von Bodungen dated May 25, 1984. 11. In units of pounds per M gallons.
SAL 000006291
a --
/i -
s/p
PLANT SUHMARY REPORT QUARTER #2
<5
Plant: CONOCO
UNIT t
ANNUAL OR QUARTERLY
TOTAL FARTS HQNITQR
fa &**
f*PA6E 1 J*> U^G_ 5^ 'i^j2-^Date: 12/22/08
"
TOTAL
TOTAL
=4ri=:====
TOTAL TOTAL TOTAL
TOTAL TOTAL VALVE
TOTAL VALVES VALVE LEAKS MONITOR LEAKS
PUHP LEAKS
COHP. LEAKS
RVALVE LEAKS
DRAIN LEAKS
LEAK v
LEAK11
TOTAL REPAIRED
3
TOTAL TA
111 CAL 31 CAL
Q M
74 6 74 6 0 0 i o 0 0 0 0 A .j
0
8.11
8.11
0
6 9
11 COKER 31 COKER
*1 HAS *1 HAS
*2 CAT 32 CAT
i
A
G A
0 A
442 43 441
43
G
0
0
10c 4 101 1 3 0 j
0
9.73
9.75
9
3.77
0.99
23 )
20 4
357 5 350 5 j 0 j
0
1.40
1.43
5
(i 0 0 0 0 0 9 HlHfHtfHHHHHffHHHHO
0 0
594 6 583 6 0 0 j
0 1.01 1.03
6
i} A 0 0 j 0 0 ftltfHmHHHHmtMlfHHO
0 o
#2 COKER 32 COKER
0 A
483 4 481 4 0 0 0 7B 1 74 1 0 0 9
0
0.B3
0.83
0
1.28
1.35
3 0
1 1
#2 CRUDE 32 CRUDE
9 A
440 5 439 5 0 0 0
0
1.14
1.14
5
Cl 0 0 0 0 0 0 IfltHHttHHHHHIHIlfHIN)
0 0
32 HDS 12 HDS
9 A
240 3 236 3 0 0 0
0
1.25
1.27
3
0 0 0 0 0 0 0 4OIHIH*H4tHWII0
0 0
32 REF 12 REF
0
369 5 365 5 0 0 0
0
1.36
1.37
5
<j 0 0 0 0 0 G HttHtifmHHHHHHIIIIlfO
0 0
33 CRUDE 13 CRUDE
9 A
301 3 296 3 0 0 G 00 0 0 G 0 0
0
1.00
1.01
3
0 0
33 REF 33 REF
G A
746 22 745 22 0 0 0 452 34 439 33 1 G 0
0
2.95
2.95
0
7.52
7.52
17 16
5 18
35 HDS 35 HDS
Q A
201 j 201 3 G 0 0
0
1.49
1.49
3
0 0 0 0 0 o G hHhhhhhhhhhiihhho
0 0
36 HDS 36 HDS
Q A
146 0 146 0 0 0 0 41 0 39 0 0 0 0
9
0.00
0.00
0
9.00
0.00
0 0
0 0
37 HDS 17 HDS
ACID FIT ACID PLT
ALm'
alky
mHINE hNINE
G
rt
j A
j A
L' r
145 0 145 0 & 0 0
0
0.00
0.00
0
rj 0 0 0 0 0 0 HtflfHtfllHHHHftllltHttO
195 2 195 n 9 o 0
0
1.03
1.03
Ij 0 0 0 0 0 0 ItltHIttltlHHHHtllfttttttl}
0 0
0 0
297 22 182 22 0 (1 9 :6c 28 666 rpJ 3 0 }
59; ' 57! T ^ C -i 4 >3B 4
'.1
A
\)
7.41
7.60
4.08
3.74
12 16
'.1
t ?y
1.23
C
9.61
0.63
i.
$4. OOoo
10 12
0
PLANT SUMARY REPORT QUARTER *2
Plant: CONOCO
PA6E 2
Date: 12/22/88
UNIT t
ANNUAL OR QUARTERLY
TOTAL PARTS NONITOR
TOTAL LEAKS
TOTAL VALVES NONITOR
TOTAL VALVE LEAKS
TOTAL PUHP LEAKS
TGTAL COUP. LEAKS
TOTAL RVALVE LEAKS
TOTAL DRAIN LEAKS
TOTAL LEAK
k
VALVE LEAK
I
TOTAL
TOTAL
REPAIRED TA
CAT POLY CAT POLY
6
A
224 14 224 14 0 0 0 62ti 60 612 58 n o
0
6.25
3.25
0
9.55
9.48
3 15
11 45
EDC d
0 0 0 M ) 0 0 flHHHHHHHHHHHItttHO
y
SDC A 53 8 26 6
0y
0 15.09 15.09
3
(i
6AS RECflV 6AS RECDV
HOLE* NOLEX
PBC PBC
j n
Q H
fi
A
314 10 314 10 0 o v1 466 40 453 74 4 \ 0
76 3 75 j 0 0 0 0 00 0 0 *
302 29 269 2B 0 0 1 895 136 374 127 9 0 0
r)
5.18
3.18
0
8.58
7.95
y
3.95
4.00
0
9.60
9.69
0 15.20 14.53
10 <7
3
28 06
0 4%>
0
<)
1 70
PSA
Q
632
4 830
4
0
0
0
0
0.48
0.48
4
0
PSA A
0 0 0 0 0 0 0 HlHiHfHfHHHHIHttftlfiO
0
NR HOUSE PUR HOUSE
0 6
SRU Q SRU A
TCU B TCU A
250 3 250 3 0 0 0
0
1.20
1.20
3
0 0 0 0 0 0 0 ttHHHifHHHHHHHHifiij)
140 3 139 3 0 0 0
3000 000
0
2.14
2.16
1
209
0 206
0
0
0
0
185 3 179 * 0 0 0
0
0.00
0.00
0
1.62
1.68
0 3
0 0
2 0
0 0
TK FARH TK FARM
8 A
394 0 393 0 0 0 0 00 0000 0
0
0.00
0.00
0
0 0
PERIOD TOTALS: B
3354
202 3270
201
0
(1
1
A
4242
318 4130
296
22
0
0
0
2.42
2.43
144
0
7.50
7.17
145
58 173
Qfb 0oO &
PLANT SUMMARY REPORT &JARTER 13
Plant: CONOCO
4* 'J
O
--1
-AGE
UNIT I
ANNUAL OR QUARTERLY
TOTAL PARTS MONITOR
TOTAL LEAKS
TOTAL VALVES MONITOR
TOTAL VALVE LEAKS
41 CAL 11 CAL
0 A
74 h * 9 6 00V
41 COKER 11 COKER
0
442 20 441 20 -1 4 Jl 1
11 KBS 11 HDS
a A
2 350
2
379 l3 369 1 ^4
*2 CAT
2 KA
594 1030
14 :B3 9Jj- ,'JN i1 4
14 2?
12 COKER 12 COKER
Q A
483 8 481
a
01 0i
TOTAL PUMP LEAKS
fr n
0 *
0
0 -
0 0
2 CRUDE 12 CRUDE
6 A
440 5 439 A 484 6 474 9J
1 3
42 HDS 12 HDS
12 REF 12 REF
13 CRUDE 43 CRUDE
13 REF 43 REF
15 HDS 45 HDS
Q A
0 n
s
A
3 A
g A
240 0 236 0
218
212
n
a
369 J-. 3i5 2 131 129 k
301 j 296 710 11 699
3 9
746 24 745 24
Q !B
0 17
20! (> 201 i`l l') V 0
0 0
0 0
0 2
0 1
0 0
16 HDS 46 HDS
47 HDS 17 HDS
ACID FIT "ID FIT
ALKY ALKY
0 A
a
A
j A
0 H
146 0 146 0 j0 0 0
145 (! 145 0 i; (\ 'j y
173 l 5 = 0
l1 0
0
29? 30 282 30
V >5
0 0
0 n
0 0
v
AMINE hHINE
r*
t. 1
J
Date: 01/11/89
'OTAL :ckp. .EAKS
TOTAL RVALVE LEAKS
TOTAL DRAIN LEAKS
"OTAL
LEAK *.*
VALVE LEAK
1
TOTAL REPAIRED
TOTAL TA
00 o
IJ 1. -
0 J U
0
S.ll
S.ll
1
5
n
L52
4.54
9
1/
4
0
0.56
0.57
0
3.44
9>l A*kWC
y i
0 6
0
J
2.36
2.40
13
1
o
3.11
o?
n
21
00
y
1.66
1.66
5
0 0 44|t44444t4tfH~H*444*4~4t4Q
3 1
(1 0 00
0
1.14
0.91
0
1.24
0.63
4 3
1 3
00 00
0
0.00
0.00
0
0.92
0.94
0 2
0 0
0 :) 0o
00 0 i)
(l
0.54
0.55
j
4.5S
4.65
A
1.00
1.01
0
1.55
1.29
i 4
3 5
i 2
0 6
o0
0
3.22
3.22
16
S
0 0 HlttfHHHHHHHHHHfmO ie
00 0A
0
0.00
0.00
0
0 0
00 (1 0
0M 'j
(l
0.00
0.00
0
0.00
0.00
0 0
0 0
0 0
0
0
0.00
0.00
0
<} u t*t4f 444444444-4444444444441 440
0 0
0
0
10.10
10.64
IB
L2
4*#*4*4+*4444444444444444*44440
t* '4*.
i
j.;4
L. ^J
0
2
SAL 00000629^
PLANT SUMMARY REPORT QUARTER 13
Plant: CONOCO
:AGE 2
UNIT i
ANNUAL OR QUARTERLY
TOTAL .-ARTS MONITOR
TOTAL LEAKS
TOTAL VALVES MONITOR
TOTAL VALVE LEAKS
TOTAL PUMP LEAKS
CAT PQLY CAT POLY
0 H
EDC ti EDC ri
GAS RECDV GAS RECOV
q
i,
HOLES MOLES
Q A
224 13 224 13
i.i 45
V 43
i.i 0 0 0 0 (l 0
314 6 314
!j 23
/b 3 31 j 31
i 19
j >j
A
2
<\ 0
iJ i
o 0
PBC
0
302 lb 2B9 15
0
PBC n
0 70
0 bl
9
PSA Q 032 7 830 7 0 PSA A 294 0 290 0 0
.'HR HOUSE PHfi HOUSE
3 A
250 10 250 10 00 00
0 0
SRU 5 140 X 139
0
SRU A
n 0 0 u ,"l
TCU 6 209 0 20b 0 0
TCU A
00 00 0
U FARM TK FARM
0 A
394 2606
27 393 150 2514
27 149
n 1
TOTAL COMP. -A>1S
0 0
0 <'
y
0
y
0 0
0 0
0 0
rj
0 0
(1 0
TOTAL RVALVE LEAKS
J
fj
0
V ' 1 0 0 0 0 0 0
0 0 0 0
TOTAL DRAIN LEAKS
y
jata: 01711/89
7DTAL LEAK
s
VALVE
LEAK VM
TOTAL
TOTAL
REPAIRED TA
5.80
5.E0
4
c
HcJ
0 1.91 1.91
cJ
0
3.95
4.00
-
0.00
0.00
7J
0
5.30
5.19
13
444444{44HHHHHfHHH4iO
0 0
1
33
0 A
3 70
0
0.84
0.84
0
0.00
0.00
3 0
4 0
0
4.00
4.00
4
44|444444<IIHHHHI444t444440
0
1.43
1.44
0
l4(4444444tH4l(44HI4444444444
0
0.00
0.00
0
444444444IMHHHIH44444I4440
0
b.B5
b.37
0
5.7b
5.93
19 Bb
b 0
2 0
0 0
s
64
PERIOD TOTALS:
ra. A
S354 5092
200 2^0
a:?o
5730
198
i#r 210
1
JhT 1o
(j~}Z FPwh T7^ Ll^ r a** a*
j 0
1 0
0
2.39
2.39
0 -WtB z-n
117 118
S3 275
000006295
SM-
4
I-
A=
uSUL
-1
SUKHARY REPORT
7j-i- ^rr
, Plant: CONOCO
XxaXo-*^
Data: 01/03/89
UNIT *
ANNUAL OR 3UARTERL!
TOTAL PARTS MONITOR
TOTAL LEAKS
TOTAL VALVES MONITOR
TCTAL VALVE LEAKS
i) CAL 11 CAL
Q H
74 ? 74 7 *> 0 ft ,A
TOTAL PUMP lEAKS
0 0
TOTAL COHP. LEAKS
o $
TOTAL RVALVE LEAKS
A
0
TOTAL DRAIN LEAKS
0 0
;U!HL
LEAK
VALVE LEAK
I
TOTAL REPAIRED
TOTAL TA
5.44
9.46
1
HMHHfflHflHHHO
6
0
il COKER 11 COKER
U H5 ii HCS
12 CAL *2 CAL
G A
0 A
3 U
442 30 441
30
0
0
0
32 0 0 0 0 0 0
0
6-/9
6.80
5
0 HllfiHfllHHIlHHO
25 0
357 350 3 0 A o 2B 0 0 0 0 0 0
0
2.24
2.29
3
5 0
.j 0 n 0 ft .*4 0 HlHIHHHHHHttHHHHHO
1V A 0 0 0 0 0
0 MIHfHHiifHtfMtfO
0 0
12 CAT 42 CAT
Q A
594 2B 5B3 2B 0 0 0 89 0 0 0 0 0 0
0
4.71
4,BO
17
0 HtMfHIHIiMliHHO
11 0
42 COKER 12 COKER
8 A
483 3 4B1 3 0 0 0 43 0 0 0 0 0 0
0 0-42 0.42 0
12 CRUSE -' CRUDE
Q A
440 13 439 12 1 0 0 58 0 0 0 0 0 0
0 2.95 2.73 0 OllHHflMIM
#2 HDS 42 HDS
Q A
240 2 236 2 0 0 0 3s a 0 0 0 0 0
0 0.83
0.85
2
0 4f|4lHfH<Kifllf!H0
12 REF #2 REF
43 CRUDE 43 CRUDE
fi A
Q A
370 11 366 11 0 0 0 30 0 0 0 0 0 0
301 e 296 B 0 0 0 59 0 0 0 0 0 0
0 2.97
3.01
0
is.
0 2.44 2.70 . rsas^jS^-
0 IftlfHHHIHiHHHO
13 REF 13 REF
U A
746 25 745 25 0 0 0 57 0 0 0 0 0 0
0 3.35
3.34
13
0 4fOif!lliHiHHlli0
44 HDS 44 HAS
Q A
0 0 0 0 0 0 0 KtfHMffHHHHHfftlififtfO
33 0 0 0 0 0 0
0 IfltlftfHHHfMfHflO
45 HDS 45 HDS
16 HDS 46 HDS
S A
n A
201 0 201 0 0 0 0 11 0 0 0 0 0 0
0 0.00
0.00
0
0 tflt*f44f4t1M<*0
146 n 146 o A o ft
0 0.00
0.00
0
0 0 0 0 0 0 0 4<6444444644*44444ff4444444*0
47 HD3 17 HDS
*S HDS 8 Kj5
a Q
A a 0 T*l 0 ij 0 4414444444444444444444444444440
15 0 0 0 0 0 0
0 6t66*f444444444*444440
t* tj 0 0 0 0 0 464444444444444444444444444440
8 .1 j
00V
U 4i4f444i4444444i44444IJ
SAL 000006296
PLANT SUNHARY REPORT QUARTER 14
Plant: CONOCO
PAGE 2
Date; C2703/89
UNIT 1
ANNUAL 3R QUARTERLY
IOTAL PARTS MONITOR
TOTAL LEAKS
TOTAL VALVES "ONITOR
TOTAL VALVE LEAKS
ACID PLT ACID PU
3 A
155 6 195 4 0}00
IK> ft 297 33 i5 37
ALKY
A
0 ) 0 0
AKINE ANINE
7 A
*07 u 571 16 0000
AftINE 'RT AHI.VE TRT
tf n
9 0 t) j') 3< 0 0 y
TOTAL PUHP LEAKS
0 0
0 0
0 0
9 0
TOTAL CQHP. LEAKS
0
j 0
0 0
) 9
TOTAL RVALVE LEAKS
TOTAL DRAIN LEAKS
TOTAL LEAL
l
VALVE LEAK
w
TOTAL REPAIRED
TOTAL 7A
j
0
3.OB
3.y6
1
0 HlfHHHHHHHHfUHliHi)
1
(i 12.79 13.12
17
0
5 3
' 4i 0
0
J
2.74
2.00
11
5
00
0 MM4444t4HHHf4fH4HHMtlO 0 0 tH+**44*tt**<444*fO
0 0
CAT POLY CAT POLY
0 A
224 36 224 36 0 0 0 26 o 0 0 9 9 0
0 16.07 16.07
11
0 14(14(4444444444444440
25 0
CRYB CRYD
Q A
0 0 0 0 0 0 0 H|444HiH4flHH4t4HHflllO
11 0 0 0 0 0 0
0 |40|44444444444ff44fi
0 0
"DC Q EDC A
0 0 0 0 0 0 0 H|444444fH444444444444444440 0 0 0 0 0 0 0 >{t4H4if4HHH44H4IHH4l4(0
0 0
FEED PREP FEED FflEP
y A
GAS RECOV 6AS RECOV
3 A
NOLEI NOLEI
S A
0 0 0 0 0 0 0 44I444444H44444I44444444IH440
e0 oo 0 0 0
0 I4H4444444444I4444440
314 9 314 3 0 0 0 57 0 0 0 0 0 0
0
2.87
2.87
3
0 OfOO((f444444HfHIHO
76 2 75 2 0 0 0
10 0 0 0 0 9 0
0 2.63 2.67
,2
0 0400444444444444444440
0 0
6 0
0 0
PEC
0 3 0 2 9 0 1 44|ff4444l4444444444444f444(4<|)
3
?8C
A
42 0 0 0 0 0 0
0 0(00444444444444444440
0
PSA
Q
832 16 830 16 9 0 0
0
1.92
1.53
13
3
PSA
A
22 0 0 0 0 0 0
0 0(004I444444I444(44HO
0
PR HOUSE PNR HOUSE
3 A
250 8 250 0 0 0 0 38 $ 0 0 0 9 9
SPL' "i MO , e. 129 j* 9 >3 h SR'J A 93 0 2 0 0 0 0
TCL) n 209 8 206 5 0 0 9 *L'J A 30 9 0 0 0 0 0
'k f{-.?r.
c
426 37 423 37 0 0 ft
'/, F-lc-x
Ol\
67 0
0
9
V7t/<
i;". 'Efr7
0
3.20
3.20
1
0 0(004444H4ff({(444440
(,
10.71
1l.79
0
0.00
0.00
5 0
0
3.82
3.Ba
'
0 fOMt4ff4*444*444fO
0
9.6?
8,75
14
0
0.00
0.00 r
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,, SAL 000006297
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sftL 000006302
p*t* m u * 44iPu scnrcicPocoNCTi . waxhush*
TABLE B2-37 , ESTIMATED NUMBER OF INDIVIDUAL EMISSION SOURCES* IN 15 SPECIFIC REFINERY PROCESS UNITS
Estimated Humber of Sourcee Vithin Battery Limits of Process Units
Process Unit
Valves
flanges
Puaps1
Compressors*
Crains
Relief Valves
Atmospheric Distillation
v 89 3
3997
31
1
69 6
Vacuum Distillatloo 1
500 1785
16
6
42 6
Fuel Cas/Lighc Ends Processing
181
644
3
2
11 6
Catalytic Hydroprocesetog.
v 645 ,, ,
2743
10
3
24 6
Catalytic Cracking
'1314
4212
30
4
65 6
Hydrocracking
931 1955
22
3
58 6 .
Catalytic Reforming
.-691
2961
14
3
49 6
P
ro
Aromatics Extraction1
600 2142
16
0
47 6
co
v) Alkylation
677 2407
13
0
41 6
Delayed Coking1 Fluid Coking
^ 300 304
1071 1047
9 9
0 4
23 6 28 6
y
Hydroeslkylacion1
~'J' 690
2463
14
3
36 6
Treating/Dewaxing
599 2289
18
1
44 6
Hydrogen Production
182 635
5
3*
17 6
Sulfur Recovery1
200 714
6
0
16 6
'Sources were not counted la process units of this type. The ouaber of sourcee was estimated. *Ooly those sources in hydrocarbon (or organic compound) service. 'Huabcr of pump seals 1.4 * number of pumps. 'Number of compressor seals - 2.0 * number of compressors.
c
SAL 0 0 0 0 0 6 3 0 3
\f', t
/
iadll ci-JO,
AVERAGE NUMBER AND ESTIMATE DISTRIBUTION OF VALVE AND PUMP SEALS IN REFINERY .ROCESS UNITS
Ptt*a Unit
AtTob*,Itr*c*|t*
gt!o*.*r*n*if*
CoAt*o*p.rriaMogf*n
11**1f*u1*p lltlt
A'aoafWilc Olatlllatlon
9) )1
facwn f>l it II | l1 on
JOO* ' li1
fi 1 Caa/llght tnl* Prtaa|n| m
1
CatilrtU OjltcpTfte**ai"|
|4S 1
C4l*l;tlt Cracking
1)14
iPrtroeraeklnt
4)1 11
Cataljtlt ktftralng
Ml 14
>tMti<a htrittlM
I00' )'
Alkj i ti ln
m 1)
0*l*y4 Coking
wo1 I*
r1u14 Coking
104 1
*74ro4nUr><lnn
4401 14 `
CViln|/Trt log
111 11
yirogfn Pre4vetlon
til )
K< i f ur It* cot* t p
100" I1
tM O' )l 1 40
) 1) 4 44 3 41 ) 41 o' )) 0 31 o' 13 4 >4 .* 41
1 )) ) )l O' ))
Pi> tr*le Olatrtkvtlon
lUlg|uhMt Ltolgi**t|4
It r1lc,
farttcf, t
)3 IS 10 10 ,1) 1)
11 )) 44 SI S3 4) 90 10 W to1 100 0 n' It* n fl w' 10* )9 11 40 40
II1
f Vl**, Miktr/Vnlt
S)v*0rpv*ter*
fljlrnt** l*r*le
Ufcht Uvlf
ti*tiory**i.c*uia
19 0 SO* O' 11 0
ns 101 0
114 IS 190 fl ' o' m0 so' o' SO 0 lit' I)1 00 0 IS 10' o'
III sis 45* 405 * 1) II 101 101 409 S21 SIS 501 SIS 1) 414' S*' 405 0 Sf* IIS' SI 211 )911 4)' 110 111 s 4| 1S1* M*
' la I (oat 4 * luf * . '\*fcr of *ua^ ta[a |,4 * ftvtktp nf gw^a, 'flifc-tr ( co^rtaaor *! 7.0 * fear *f wrwrt,
Fl1oto4 Motflbxt Ion UtUa>t*t*f!M tIthrniklbottrl/oIMnI lo*f of fato*prh*r*/oUrn(lt*1*la,
Ltifgghottl
IS
9 ia if it 15' II )' > II1 to 4 1
Ltfogii.t1p4 SffTlC*
21 20* 1 S 24 U 2 S' 0 to1 10 s' ts J 1
Total Sf ala
4) 22'
ti 42 St 10 is' II l)1 11 101 IS
Ojlforal bon 9*r*lt
2 o' 4 It 1 0 0 o' 0 fl*
o' 2 0 0
Mglrngtn S*r*lc*
0 o' 0 40 4 4 o' 0 O' fl 4' 0 4 ft
l/S
> o o oo o
O' w
o
*
z*o
V 5
APPENDIX J PRODUCT LOADING RELEASE DATA AND CALCULATIONS
SARA TITLE III, SECTION 313 1988 TOXIC CHEMICAL RELEASE INVENTORY
LAKE CHARLES REFINERY
SAU 000006305
LAKE CHARLES 1988
SUMMARY
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
TOTAL LBS.
Storage Tank
0)
Loading Rack
0.00 0.00 0.00
O. 00 0.00 O. 00 O. 00 0.00 0.00 O. 00
1178.72 1004.69
0.00 124.56 633.06
68.22
20.15
3.31 0.00 0.00
6
r1
\oc*.cl<n*j jun loaebVo^ 1Ve-'e
e,rpref<?c{
fc)y
OCX
pi^ r\cH~
b (Ly o*^c(
X bcove peo
Y
-picT/.-fy boui-wYcxry SA'Rfl' 3i3>,
EPA?
000006306 SAL
April 17, 1989 SARA 313 - Barge Emissions
Ms. Lisa A. Thomas American Petroleum Institute 1220 L Street NW Washington, D.C. 20005 Dear Lisa: I recently asked EPA to clarify the status of barge loading/unloading releases for the second SARA 313 report. As indicated by the attached note of the conversation, barges in a public waterway are beyond the facility boundary and their releases are not covered. It may be helpful to circulate this clarification with the prior correspondence to API member companies.
Sincerely,
JJD:am Attachment 0052
SAL 000006307
From: LAWJJD --HOURCCI
To: HQRJMJ --HOURCCI Johnson, Jere
Date and time
02/27/89 11:16
From: Jim Doyle Subject: 313 Q & A's
Jere,
I talked with Robert Costa on February 27, 1989, of the EPA Hotline on the subject of barge loading emissions. Specifically, I asked whether Question on page 9 of EPA's "Toxic Chemical Release Inventory Questions and Answers" (January 1989) was intended to change Margo Oge's response of June 10, 1988* my letter of May 31, 1988 on loading releases.
Mr. Costa had a copy of my letter and Ms. Oge's response. He stated that the correspondence was still a valid interpretation and that he was aware of no changes. Question 45 was stated to be a more general statement of greater applicability, but not to change the response received from Ms. Oge.
If we want a response in writing, we can write Mr. Sam K. Sasnett, EPA(TS-779) . Mr. Sasnett is sitting in Ms. Oge's chair -- Margo is now assigned to radon.
Please let me know if we should make a formal request for clarification.
Jim 8--656--4026
cc. Doyle Russell
SAL 000006308
UNITED STATES ENVIRONMENTAL PROTECTION AGEN?CEi VFH
WASHINGTON, D.C. 20460
JUAI 13 7988
JUN I 0 hr'
Mr. James J. Doyle Jr. Counsel Exxon company O.S.A Post Office Box 2180 Houston, Texas 77252-2180
James oovl
OFFICE OF FCSTICIOeS AND TOXIC SUBSTANCES
Dear Mr. Doyle,
This letter is in reply to your letter of May 31, 1988. Your letter asked whether loading releases from barges, tank trucks and rail cars should be included on EPA Form R.
The issue in question is the facility boundary. There appear to be three cases:
1. filling tank trucks and rail cars within the facility, 2. filling a vessel at a company owned dock adjacent to the facility - the vessel is in a public waterway, 3. filling a vessel at a remote site connected by pipeline to the reporting facility.
Case 1 requires reporting of the release because the activity is within the facility boundary.
Case 3 does not require facility reporting for releases from the pipeline or the end of the pipe. The pipe is outside the facility boundary. However, the facility at the end of the pipe could be separately covered.
Case 2 is distinguished from Case 3 by adjacency. The activities of the company, using company owned equipment and dock, lead to the air release. However, the release is from the functioning of the vessel in the public waterway and is beyond the facility boundary. The release is not reportable.
Sincerely, S'^7
Ma^go T. oge ^
Deputy Director Economics and Technology Division (TS-779)
ooooo^09 $AV-
SARA 313
Location Year: Loss: Trans.
LAKE CHARLES 1988
Loading Rack Truck
38781
O')
lbs. VOC of
REG GASOLINE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
38781 38781 38781 3878 1 38781 38781 38781 38781 38781 38781
(lbs.) (lbs.) (lbs.) (lbs.) (lbs.) (lbs.) (lbs. ) (lbs.) (lbs.) (lbs.)
> > > ) > > ; ;
>
Wt. ^ Frac.
Vapor (3) Pressure
Rati 0
1 bs.
0.0240 0.0980
<-01 0.0270 0.1300 0.0430 0.0200
<.01 < . 001 < . 001
X X
X
V
X X X
r,
Q
I-*II
0.242 0.065 0.258 0.029 0.031
0.010
0.006
= = = = = = =
0.765 0.016 =
225.18 245.20
ERR 30. 40 154.50 16.65
4.92 ERR ERR ERR
VAPOR PRESSURE (ERR implies not det
(0 \JO(L
e^cU
c*l^oU+ed by /fMz
Spreadsheet procjC^ny
Ca.tf'o^c.UeJ.}
(3) y^pa'- pre
f-H, hpp* B-
00000631 SAL
SARA 313
Location: Year: Loss: Trans.
LAKE CHARLES 1988
Loading Rack Truck
81983 lbs. VOC o+
UL GASOLINE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDQCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
81983 81983 81983 81983 81983 81983 81983 81983 81983 81983
(lbs.) (lbs. ) (1bs.) (lbs. > (lbs. ) (lbs.> (lbs. ) (lbs. ) (lbs. ) (lbs. )
x J.'
X X X X X X X X
wt. Fr ac.
Vapor Pressure
Ratio
1 bs.
0.0290 0.0980
<.01 0.0270 0.1300 0.0430 0.0200
<01 < . 001 < . 001
>
V
> x, X. X >
>
0.242 0. 065 0. 258 0. 029 0.031 0.010 0.006 0.001 0. 765 0.016
= ss
=
-
= = = = =
575.20 518.34
ERR 64.26 326.61 35.20 10. 39
ERR ERR ERR
VAPOR PRESSURE <ERR implies not detected)
6.2
SAL 000006311
SARA 313
Location Year: Loss: Trans.
LAKE CHARLES 1988
Loading Rack Truck
38141 lbs. VOC of
SUL GASOLINE
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total Wei ght
38141 38141 38141 38141 38141 38141 38141 38141 38141 38141
(lbs.) (lbs. ) (lbs. ) (lbs. ) (lbs.) (lbs.) (lbs. ) (lbs. > (lbs. ) (lbs. >
X X X X X X X X X
wt. Fr ac.
Vapor Pressure
Ratio
lbs.
0.0410 0.0980
<.01 0.0270 0.1300 0.0430 0.0200
< .01 < . 001 < . 001
X X X X X X X X X J.*
0.242 0.065 0.258 0. 029 0. 031 0.010 0. 006
0.001 0.765 0.016
=s = = = = =
=
378.33 241.15
ERR 29.90 151.95 16. 37
4.84 ERR ERR ERR
VAPOR PRESSURE (ERR implies not detected)
6.2
SARA 313
Lacstian: Year: Lass: Trans.
LAKE CHARLES 19B8
Loading Rack Truck
198 lbs. V0C of
DIESEL
V0C Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDQCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
198 198 198 198 198 198 198 198 198 198
(lbs.) (lbs.> (lbs.) (lbs. ) (1bs.) (lbs. > (lbs. ) (lbs. ) (lbs. ) (lbs. )
X X X
X X X X x X
Wt. Fr ac.
Vapor Pressure
Rat i o
< . 001 < . 01 <.01 <.01 <.01 < . 01 < . 01
0.0300 0.0000
< . 001
X X
V X
X X X X X
166.667 44.444
177.778 20.000 21.111 6.878 4.367 0.500
526.667 10.744
-
--
=
-- = = = sa -
VAPOR PRESSURE (ERR implies not detected)
0. 009
lbs.
ERR ERR ERR ERR ERR ERR ERR 2.97 0. 00 ERR
SAL 000006313
SARA 313
Locations Year: Loss: Trans.
LAKE CHARLES 1988
Loading Rack Truck
28 lbs. VOC of JET-50/-A/LVT
VOC Comp. :
BENZENE TOLUENE CYCLOHEXANE ETHYLBENZENE XYLENE CUMENE PSUEDOCUMENE NAPHTHALENE MTBE STYRENE
Total Weight
i *--
cr
in
28 28 (lbs.) 28 (lbs. ) 28 (lbs. ) 28 (lbs.) 28 (lbs.) 28 (lbs- ) 28 (lbs. ) 28 (lbs.) 28 (lbs. >
X X X X X X X X X X
wt. Fr ac .
Vapor Pressure
Rat i o
< . 001 <.01 <.01 <.01 <-01 <.01 < . 01
0.0300 0.0000
< . 001
X
X X
X
X X
x x
X X
136.364 36364
145.455 16.364 17.273 5. 627 3.573 0. 409
430.909 8. 791
as
--
= = = = =
--
= =
1 bs.
ERR ERR ERR ERR ERR ERR ERR 0. 34 0. 00 ERR
VAPOR PRESSURE (ERR implies not detected)
0.011
SAL 000006314
VOC EMISSION CALCULATIONS TRUCK RACK LOADING LOSS
DATE TIME PERIOD : MONTH,YR
: MONTH,YR LOCATION POINT SOURCE I.D. # MATERIAL HANDLED THRUPUT (bbls) VRU EFFICIENCY <*/.)
START END
14--Jun--89 JAN, 198S DEC, 1988 LAKE CHARLES LOADING RACKS REG GASOLINE
610586 87.5
MOLECULAR WEIGHT TEMPERATURE (F) VAPOR PRESSURE (psia) SATURATION FACTOR
LOADING LOSS
Mv T= P= S =-*
o) 62 70 C0
8.3 (<?') 1
UNCONTROLLED EMISSIONS (lb) CONTROLLED EMISSIONS (lb)
LI =
310247
LI = LI *<1-eff/100) = 38781
0)
(x>) ]/(UJ
(<)
b^SeJ
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VOC EMISSION CALCULATIONS TRUCK RACK LOADING LOSS
DATE TIME PERIOD : MONTH,YR
: MONTH,YR LOCATION POINT SOURCE I.D, # MATERIAL HANDLED THRUPUT (bbls> VRU EFFICIENCY (X)
START END
14--Jun--09 JAN, 1988 DEC, 1988 LAKE CHARLES LOADING RACKS UL GASOLINE
1290774 87. 5
LOADING LOSS
MOLECULAR WEIGHT TEMPERATURE (F) VAPOR PRESSURE (psia) SATURATION FACTOR
Mv = T= p= S=
62 70 B. 3
1
UNCONTROLLED EMISSIONS (lb) CONTROLLED EMISSIONS (lb)
LI 655860
LI = LI * < 1-ef-f/lOO) = 81983
SAL 000006316
VOC EMISSION CALCULATIONS TRUCK RACK LOADING LOSS
DATE TIME PERIOD : MONTH,YR
: MONTH,YR LOCATION POINT SOURCE I.D. # MATERIAL HANDLED THRUPUT (bbls) VRU EFFICIENCY (7.)
START END
14--Jun--89 JAN, 1908 DEC, 1988 LAKE CHARLES LOADING RACKS SUL GASOLINE
600507 87.5
LOADING LOSS
MOLECULAR WEIGHT TEMPERATURE (F) VAPOR PRESSURE (psia) SATURATION FACTOR
Mv = TP= S=
62 70 8. 3
1
UNCONTROLLED EMISSIONS (lb) CONTROLLED EMISSIONS (lb)
LI =
305126
LI = LI* < 1-e-f-f/ICO) = 38141
SAL 00000631
in <i
VOC EMISSION CALCULATIONS TRUCK RACK LOADING LOSS
DATE TIME PERIOD : MONTH,YR
: MONTH,YR LOCATION POINT SOURCE I.D. # MATERIAL HANDLED
THRUPUT Cbbls) VRU EFFICIENCY <7.)
START END
14--Jun--89 JAN, 1988 DEC, 1908 LAKE CHARLES LOADING RACKS JET/LVT (KERO)
15931 37.
LOADING LOSS
MOLECULAR WEIGHT TEMPERATURE <F) VAPOR PRESSURE (psia) SATURATION FACTOR
Mv = T-- P= S=
130 70
0.011 1
UNCONTROLLED EMISSIONS Ub> CONTROLLED EMISSIONS (lb)
LI = LI = Ll*(l--ef-f/100)
SAL 000006318
VOC EMISSION CALCULATIONS TRUCK RACK LOADING LOSS
DATE TIME PERIOD : MONTH,YR
: MONTH,YR LOCATION POINT SOURCE I.D. # MATERIAL HANDLED THRUPUT (bbls) VRU EFFICIENCY (V.)
START END
14--Jun--89 JAN, 1988 DEC, 1988 LAKE CHARLES LOADING RACKS
DIESEL 1372376
87.5
LOADING LOSS
MOLECULAR WEIGHT TEMPERATURE CF) VAPOR PRESSURE (psia) SATURATION FACTOR
Mv T P S
130 70
0. 009 1
UNCONTROLLED EMISSIONS (lb) CONTROLLED EMISSIONS (lb)
LI 1585
LI = LI * ( 1-ef-f / 100) =
198
SAL 000006319
I
REPORT NO 13
TERMINAL YEAR TO DATE 3AP
GAIN/LOSS- AND DELIVfc.^ES SYSTEM-06 LOUISIANA DIST TERMINAL-696 WESTLAKE OPERATOR-CONOCO INC.
1 t yP E / GRADE USER
HO LEAD CONOCO
TOTAL PRODUCT
NO LEAD PREM CONOCO
total product
t
REGULAR CONOCO
TOTAL PRODUCT
UAlN/LUas-
CURRENT
YTD
TRUCK/RAIL
1,290,774 1,290,774
600,507 600,507
610,586 610,586
PIPE LING
DAROE
9
DIESEL CONOCO
TOTAL PRODUCT
t JElFUliL COM
CONOCO
TOTAL PRODUCT \
1
LVT OIL CONOCO
Kerosene
TOTAL PRODUCT
1
TERMINAL RECAP CONOCO
TOTAL TERMINAL
GAIN/LOSS- PERCENT OF TOTAL DELIVERIES
0.00
0.00
1,372,376 1,372,376
87,747 87,747
71,572 71,572
4,033,562 4,033,562
ACCOUNTING MO/YR 12/88 RUN DATE 01/13/89
TOTAL
YEAR TO DATE NONWGHTD WEIGHTED
PERCENT PERCENT
DARRELS DAY
1,290,774 1,290,774
100.00 100.00
600,507 600,507
100.00 100.00
3,526.70 3,526.70
1,640.73 1,640.73
610,586 610,586
100.00 100.00
1,668.27 1,668\27
1,372,376 1,372,376
100.00 100.00
3,749.66 3,749.66
87,747 87,747
100.00 100.00
239 . 75 239.75
71,572 71,572
100.00 100.00
195.55 195.55
4,033,562 4,033,562
100.00 100.00
11,020.66 11,020.66
to
o
o
o
Q On Ui o.
* p>Co v ( c:1<?A
EPORT NO 13-9304
TGEAR^LAisLEAARNDTD?LAITVEERRf^
TMTSr?I^^tOUISTANSn{I?
c-f/
ivun Ufl l e U1/1 3/8 9
PAGE 8
Code No.: CONOCO Brand
ASTM Volatility Class: Distillation, *F 0760 mm
10% Evaporated Temp. 50% Evaporated Temp. 50% Evaporated Temp. 90% Evaporated Temp. End Point Residue, Vol.% RVP, psi V/L of 20 at F (1) Sulfur, Wt.X Mercaptan Sulfur, Wt.X (2) Corrosion, 3 hrs. @122F Existent Gum, mg/100 ml. Potential Gum, 4 hr. O.B., mg/100 ml. Induction Period, Minutes Lead, grams/gal.
Color (3) Benzene, Vol.% Octanes:
Research (R+M)/2
CONOCO INC. GASOLINE SPECIFICATIONS^1 '
LAKE CHARLES, LOUISIANA Local Loading
1100
Max. Min. Max. Max. Max. Max. Max. Min. Max. Max. Max. Max.
ASTM Method
D86
D323 D439 D2622 D3227 D130 D381
1100 Conoco Leaded Regular Gasoline
BCD
1A9 170 2A5 37A A3A
2 10.0
133 0.10 0.002
1 A
1A0 170 240 365 434
2 11.5
124 0.10 0.002
1 4
131 170 235 365 434
2 13.5
116 0.10 0.002
1 4
Max. Min. Max. Min.
Max.
D873 D525 D3237
D2267
8 2A0 3.17 0.05 Bronze
5
8 240 3.17 0.05 Bronze
5
8 240 3.17 0.05 Bronze
5
Min. Min.
D2699 DA39
92.5 89.0
92.5 89.0
92.5 89.0
(1) May be calculated from the formula or nomogram included in ASTM D439. In case of dispute ASTM D2533 shall be the referee method.
(2) May be waived if Doctor Test is negative by ASTM D235. (3) Registered dye to be added in amount of 11 mls./lOOO gallons is either
DuPont Oil Bronze Liquid Dye or Ethyl Automate Liquid Dye-Bronze.
Volatility-Seasonal Periods
ASTM Volatility Class
Seasonal Period
B August
C April,May,June,July,September and October
D November,December,January,February and March
Issued:
1-20-8O
Cancels:
10-24-85
Effective Date: 1/1/86
CO Co^o CO
Product
-)
SAL 000006321
CONOCO INC. GASOLINE SPECIFICATIONS LAKE CHARLES, LOUISIANA
LOCAL LOADING
1410
Code No.: CONOCO Brand:
ASTM Volatility Class:
Distillation, F @760 mm 10% Evaporated Temp. 50% Evaporated Temp. 50% Evaporated Temp. 90% Evaporated Temp. End Point Residue, Vol.%
RVP, psi V/L of 20 at *F (1) Sulfur, Wt.% Mercaptan Sulfur, Wt.% (2) Corrosion, 3 hrs. @122F Existent Gum, mg/100 ml. Potential Gum, 4 hr.
O.B., mg/100 ml. Induction Period, Minutes Lead, grams/gal. Phosphorus, grams/gal. Color (3) Benzene, Wt.% Octanes:
Research Motor (R+M)/2
Max. Min. Max. Max. Max. Max. Max. Min. Max. Max. Max. Max.
Max. Min. Max. Max.
Max.
Min. Min. Min.
ASTM Method
D86
D323 D439 D2622 D3227 D130 D381
D873 D525 D3237 D3231
D2267
D2699 D2700 D439
1410 CONOCO UNLEADED GASOLINE
B
149 170 245 374 434
2 10.0
133 0.10 0.002
1 4
8 240 0.03 0.004 Undyed 4.9
9L.0 82.0 87.0
C
140 170 240 365 434
2 11.5
124 0.10 0.002
1 4
8 240 0.03 0.004 Undyed 4.9
91.0 82.0 87.0
D
131 170 235 365 434
2 13.5
116 0.10 0.002
1 4
8 240 0.03 0.004 Undyed 4.9
91.0 82.0 87.0
Additive for CONOCO Accounts: AN 413 at 32.0 PTB (395 ml./1000 gallons)
(1) May be calculated from the formula or nomogram included in ASTM D439. In case of dispute D2533 shall be the referee method,
(2) May be waived if Doctor Test is negative by ASTM D235.
Volatility-Seasonal Periods ASTM Volatility Class B C
D
Seasonal Period August April, May, June, July,
September, and October November, December, January,
February, and March
Issued: 2-18-88 Cancels: 3-14-83 Effective Date: 4-1-88
Secretary, PPSC
SAL 000006322
CONOCO INC. GASOLINE SPECIFICATIONS LAKE CHARLES, LOUISIANA
LOCAL LOADING
1420
Code No.: CONOCO Brand:
ASTM Volatility Class:
Distillation, F 0760 mm 10% Evaporated Temp. 50% Evaporated Temp. 50% Evaporated Temp. 90% Evaporated Temp. End Point Residue, Vol.%
RVP, psi V/L of 20 at *F (L) Sulfur, Wt.% Mercaptan Sulfur, Wt,% (2) Corrosion, 3 hrs. @122*F Existent Gum, mg/100 ml. Potential Gum, 4 hr.
O.B., mg/100 ml. Induction Period, Minutes Lead, grams/gal. Phosphorus, grams/gal. Color (3) Benzene, Wt.% Octane Number, (R+M)/2
Max. Min. Max. Max. Max. Max. Max. Min. Max. Max. Max. Max.
Max. Min. Max. Max.
Max. Min.
ASTM Method
D86
D323 D439 D2622 D3227 D130 D381
D873 D525 D3237 D3231
D2267 D439
1420 CONOCO SUPER UNLEADED GASOLINE
B
149 170 245 374 434
2 10.0
133 0.10 0.002
1 4
8 240 0.03 0.004 Red 4.9 92.0
C
140 170 240 365 434
2 11.5
124 0.10 0.002
1 4
8 240 0.03 0.004 Red 4.9 92.0
D
131 170 235 365 434
2 13.5
116 0.10 0.002
1 4
8 240 0.03 0.004 Red 4.9 92.0
Additive for CONOCO Accounts : AN 413 at 32.0 PTB (395 ml./iOOO gallons)
(1) May be calculated from the formula or nomogram included in ASTM D439.. In case of dispute D2533 shall be the referee method.
(2) May be waived if Doctor Test is negative by ASTM D235. (3) Registered dye to be added in the amount of 7.5 mis./1000 gallons is either
DuPont Oil Red B Liquid Dye or Ethyl Automate Liquid Dye- Red B. (4) Fuel may contain up to 2.0 wt. percent oxygen, equivalent to a maximum of
approximately 11 vol. percent MTBE.
Volatility-Seasonal Periods ASTM Volatility Class
Seasonal Period August April, May, June, July,
September, and October November, December, January,
February, and March
Issued:
2- 18-88
Cancels: 3-14-83 Ef feetive Date: 4-1-88
Secretary, PFSC
OQo0
633
