Document aJavp9w92NBd2or0LnxYG59GM
CWA COMPLIANCE EVALUATION SAMPLING INSPECTION REPORT U.S. ENVIRONMENTAL PROTECTION AGENCY, REGION 5
Purpose: Compliance Evaluation Sampling Inspection
Facility: Mark Lee Deardorff Farms 10729 North State Road 19 Macy, Indiana 46951 Miami County 40.92249109623049, -86.02672807213327
NPDES Permit Number: NA
Date of Inspection: 03/26/2021 - Facility Walkthrough 04/16/2021 - Operator Interview
EPA Representatives: Benjamin D. Atkinson, Inspector, 312-353-8243, atkinson.ben@epa.gov Valerie Dooling, Environmental Engineer, 312-886-1767, dooling.valerie@epa.gov
State Representatives:
Chris Lowell, CFO Inspector, 317-650-3191, CLOWELL@idem.IN.gov
Facility Representatives: Mark L Deardorff, Owner, 765-863-7707, mark@deardorfffarms.net
Report Prepared by: Inspector Signature:
Benjamin D. Atkinson, Inspector Water Enforcement and Compliance Assurance Branch Atkinson.ben@epa.gov
Atkinson, Benjamin Digitally signed by Atkinson, Benjamin
_______________________D_a_te_:_20_2_1_.0_6._08_1_4_:3_8_:2_4 _-0_5'_00_' ___
Approver Name and Title: Ryan J. Bahr, Section 2 Chief Water Enforcement and Compliance Assurance Branch
Approver Signature and Date:
RYAN BAHR Digitally signed by RYAN BAHR ___________________D_a_te_: 2_0_2_1._0_6._08__14_:5_0_:2_5_-_05_'0_0_'
1
1. BACKGROUND
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
The purpose of this report is to describe, evaluate and document compliance with the Clean Water Act (CWA) of the "Mark Lee Deardorff Farms" Macy, Indiana facility (the Facility) on March 26, 2021 and April 16, 2021. This inspection was performed pursuant to Section 308(a) of the Federal Water Pollution Control Act, as amended.
The Facility is a medium dairy Animal Feeding Operation (AFO). It is defined as a medium facility due to its confining or stabling more than 200 but less than 700 mature dairy cows. Specifically, the Facility stables or confines 400 mature dairy cows and 100 calves.
The Facility's farmstead plan (attachment D) identifies that surface runoff from the north side of the facility flows north toward an unnamed intermittent waterway that flows to the east to the intermittent Wilson Rhodes Ditch. Surface runoff from the eastern portion of the facility flows to the east to the intermittent Wilson Rhodes Ditch or is collected by a surface drain that outlets to the intermittent Wilson Rhodes Ditch. Surface runoff from the southern part of the facility flows to the south toward Flowers Creek. Wilson Rhodes Ditch flows approximately 6.2 Miles to the south where it flows into Flowers Creek. Flowers creek then flows approximately 4.5 Miles southwest and flows into the Eel River. The Eel river then flows approximately 36.56 miles to the Wabash River. The Wabash River is a Traditional Navigable Waters.
The Facility has an Indiana Department of Environmental Management (IDEM) Confined Feeding Operation Approval (attachment D) but does not have a NPDES permit. The Facility received its initial IDEM authorization (attachment D) to construct and operate in 1999. In October 2008 IDEM documented that the Facility had had a silage leachate spill that discharged to the Wilson Rhodes Ditch as a result of unapproved changes to their leachate collection system. Following a series of Agreed Orders, IDEM stated that the Facility had achieved compliance with the Agreed Orders on September 12, 2012.
2. SITE INSPECTION
Table 1: Site Entry and Opening Conference Arrival Time: Temperature:
Precipitation:
Presented credentials? Credentials presented to whom and at what time?
7:30 AM CST
44 F .93 inches in the previous 24 hours stopping around 5:00 AM EST Yes Credentials were presented to Mark Deardorff (the Operator).
2
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
Due to the COVID-19 pandemic, the inspection took place in
several parts. Initial contact was made by phone the week prior
to the inspection. During those calls, COVID -19 precautions
were discussed, the basic form of the inspection was explained,
and the date and time were agreed upon. On the day of the site
inspection, a brief opening conference was held with the
Operator. The opening conference was kept brief to minimize
Was an
close contact. EPA discussed the follow topics during the
opening
conference:
conference
1. Asked for access to facility
held? With
2. Stated statutory and regulatory purpose of the inspection
whom?
3. Areas of the facility to be inspected
4. Roles of inspection team
5. Agreed to a tele-conference interview in the days following
the inspection
6. Right to CBI
7. Health and safety and PPE
8. Informed Operator of equipment to be used.
9. Post inspection timeframes
If photographs or documents were taken, does the facility consider any to No
be Confidential Business Information (CBI)?
EPA vehicle parked in approved location? Yes
Location where EPA vehicle was parked?
Adjacent to the shop building on the northwest side of the Facility.
Disposable boots worn?
Yes
EPA vehicle washed after inspection,
Other bio-security measures taken (state vet contacted, etc.):
no other animal facilities visited in previous 48 hours, state vet contacted to ensure no reports of communicable
diseases.
2.1 Records Review (The following Records Review tables reflect information provided before the walk-through of the facility, unless otherwise noted.)
Table 2: Documents Checklist(s) Used R5 CAFO Inspection Checklist Federal CAFO Nutrient Management Plan Checklist
Table 3: Facility Description
Type of Animal Number of
Animals
mature
400
Calves
100
Capacity
600 100
Type of Confinement
3
Minimum Number of Animals in previous 5 years:
Maximum Number of Animals in previous 5 years: Number of Animals that are stabled/confined and/or fed/maintained for 45 days or more in previous 12 months: Amount of Liquid Manure Generated per year:
Amount of Solid Manure Generated per year: Does the facility have an NPDES Permit? SIC or NAICS code: Do animals have direct access to WOUS?
Are crops, vegetation, forage growth, or post harvest residues sustained in the normal growing season over any portion of the lot or facility where animals are kept? What is the area (acres) of the production area? What is the area (acres) of the pasture?
How many employees (not counting family members)? Other facilities under common ownership (name and address):
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
500 500 500
8-10 million gallons 3000 tons No 0241 No No
40 18 acres listed as pasture 8
Operator states that there are no other operations that adjoin each other or use a common area or system for the disposal of wastes.
Table 4: Livestock Waste Storage
Type of Storage Capacity
Type of
Storage
Liner
Solid
450,000 Cubic Feet
Concrete
Manure
Liquid 1.656 Million Gallons Earthen
Liquid 2.52 Million Gallons Earthen
Liquid 2.85 Million Gallons Earthen
Liquid 2.386 Million Gallons Earthen
Records at site of storage structure design?
Is manure stored for the short term?
If yes, describe where it is stored, how it is
drained and where it drains to.
Are records kept of the level of manure in the storage structures?
When was the last time a storage structure was emptied, either partially or completely?
Depth Markers Present
NA
No No No Yes Yes Solid manure is temporary stored on a concrete pad located west of waste storage structure 1. No headland stacking is used by the facility. Yes
Fall 2000
4
Do the facility personnel inspect and keep records of all diversion devices?
Do the facility personnel inspect and keep records of all impoundments?
Do the facility personnel inspect and keep records of all the water lines?
Do the facility personnel perform routine visual inspections and keep records of the production area?
Does the waste storage system have a managed outfall or discharge point? If yes, provide a description of the outfall and a description of the area receiving the discharge.
Has the facility had any documented discharges of livestock waste to surface water in the past year?
Are there safety devices installed around any manure storage ponds? (Barriers at the end of manure push off platforms, fences around pond, signage.)
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021 Yes Yes Yes Yes
No
No No
Table 5: Livestock Waste Management Describe the way manure is collected and disposed of at the facility: The dairy cow barn is flushed using recycled water from the waste storage structures. The flushed manure then goes through solids separation. Solids are stored in waste storage structure 1 and the liquids flow into waste storage structures 2-5 sequentially. Dry pack pens are scraped as needed and manure is either placed on the temporary storage pad or waste storage structure 1. Runoff from the temporary storage pad flows to the waste storage structures.
Describe the way used bedding is collected and disposed of at the facility: Dairy cow bedding is comprised of recycled manure which is added as needed and collected through the flushing process. Calf hutches utilize sawdust and straw as bedding. They are scrapped as needed and either directly land applied or the bedding is placed on solid manure storage pad. Freshening pen uses lime base with straw on top. The pen is scrapped as needed and either directly land applied or the bedding is placed on the solid manure storage pad.
Are mortality records kept?
Yes
Describe the way mortalities are managed at the facility: Mortalities are picked up as needed by a rendering company.
What type of method is used to provide Tanks with floats. drinking water for the animals?
Describe the way spilled drinking water is collected and disposed of at the facility:
5
Spilled drinking water is collected with manure.
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
Describe the way mist cooling water is collected and disposed of at the facility: The facility does not utilize mist cooling.
Describe how chemicals are stored and how used or spilled chemicals are collected and disposed of at the facility: Chemicals are stored in a utility room in the milking parlor. Drains in the milking parlor go to the waste storage structures with manure.
Describe the way water that has been used to wash/flush barns is collected and disposed of at the facility: All wash/flush water is collected with manure.
Describe where water comes from that is used to clean and/or flush. (Wells, city, etc.) Well water is used for milk parlor cleaning and recycled water from the waste storage structures is used for barn flushing.
Describe the way feed is contained and how runoff from feed is collected and disposed of at the facility: Silage is stored in mounds on the silage pad. Runoff and leachate from the silage and silage pad flows to one of two runoff collection points. The collection points allow low flow leachate and runoff to be directed to waste storage structure 2. High flow runoff and leachate overwhelm the low flow collection and is allowed to flow to a vegetated flow path which flows to a surface drain and later into Wilson Rhodes Ditch. If a dairy, describe how process wastewater from the plate cooler water is collected and disposed of at the facility: Plate cooler water is used to wash the milking parlor floor and any extra is sent to the waste storage structures.
If a dairy, describe how process wastewater from the cleaning of the milking parlor is collected and disposed of at the facility: Wastewater from cleaning of the milking parlor is collected with the manure.
If a dairy, describe how process wastewater from the cleaning of the milk tanks is disposed of at the facility: Milk is loaded directly into milk tankers which are washed offsite.
If a dairy, how many times per day are 3 cows milked?
6
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
Table 6: Land Application and Disposal of Manure and Process Wastewater
Does the facility perform and keep records of the Yes
manure testing?
When was the last time a sample was taken of the Annually
manure and/or process wastewater?
Describe the process to take the manure and/or
Grab sample when pumping.
process wastewater sample.
Number of acres available for land application: Are land application records kept? Who applies the manure and process wastewater to the fields?
Are weather conditions at time of application
kept?
(24 before - 24 after)
Does the facility perform and keep records of the
soil testing?
Is manure transferred off-site to another party?
Are manure transfer records maintained?
Do facility personnel perform periodic inspection
of land application equipment?
2500 Yes - distribution license The Facility applies solid manure. A custom hauler is hired to apply liquid manure. No
Yes
Yes Yes Yes
Table 7: Receiving Surface Waters
Describe the surface flow pathways:
The Facility's farmstead plan (attachment D) identifies that surface runoff from the north side of the facility flows north toward an unnamed intermittent waterway that flows to the east to the intermittent Wilson Rhodes Ditch. Surface runoff from the eastern portion of the facility flows to the east to the intermittent Wilson Rhodes Ditch or is collected by a surface drain that outlets to the intermittent Wilson Rhodes Ditch. Surface runoff from the southern part of the facility flows to the south toward Flowers Creek. Wilson Rhodes Ditch flows approximately 6.2 Miles to the south where it flows into Flowers Creek. Flowers creek then flows approximately 4.5 Miles southwest and flows into the Eel River. The Eel river then flows approximately 36.56 miles to the Wabash River. The Wabash River is a Traditional Navigable Waters.
How many months out of the year is there flow in the nearest surface water pathway:
Are there any storm water pathways entering the facility? Are there any clean water ponds on site?
The unnamed intermittent tributary only flows when there has been precipitation. The Operator stated that Wilson Rhodes Ditch flows most of the year. No
No
7
What is the name of the first waterway that is identified as a Traditional Navigable Water (TNW) for surface flow from the facility?
Is the surface water pathway nearest to the facility considered to be ephemeral, intermittent or perennial?
Has the surface water pathway nearest to the facility been assessed for water quality?
Wabash River
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
Intermittent
Yes - The Wilson Rhodes Ditch is impaired for E. coli.
Table 8: Nutrient Management Plan
NMP on site?
Yes, However EPA did not review the NMP
because the facility is an unpermitted medium and
is not required to have an NMP. Additionally, the
facility uses the Office of Indiana State Chemist to
manifest their manure.
Table 9: Land Application Records (details of the records reviewed)
Land Application Records:
Un-permitted AFOs do not have federal
record keeping requirements and no land
application records were reviewed.
Table 10: Facility Records (details of the records reviewed)
Facility Records:
Un-permitted AFOs do not have federal
record keeping requirements and no
facility records were reviewed.
Table 11: NPDES Permit Type of permit
The Facility does not have an NPDES permit.
2.2 Walkthrough of the Facility
Due to the COVID-19 pandemic, the inspection took place in several parts. Initial contact with Mark Deardorff (the Operator) was made by phone the week prior to the inspection. During those calls, COVID-19 precautions were discussed, the basic form of the inspection was explained, and the date and time for the site visit were agreed upon. The site visit took place on March 26, 2021 and the interview and information collection occurred on April 16, 2021.
On the day of the site visit, Ben Atkinson and Valerie Dooling (the Inspectors) along with Chris Lowell of the Indiana Department of Natural Resources (IDEM) arrived at the facility, each in separate vehicles, at approximately 7:30 AM CST. The Inspectors
8
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
donned their biosecurity boots. A brief opening conference was held with the Operator during which the Inspectors presented their credentials, described the inspection process, notified the Operator of their right to claim information as Confidential Business Information, and had the Operator identify the structures on his facility on an aerial map. The Operator stated that he did not think that that there was anything he would want to claim as CBI. The Inspectors also confirmed that their parking location was acceptable.
The walkthrough of the Facility began at 8:29 AM CST. The Inspectors began the walkthrough by walking east from where their vehicles were parked by the shop building. They walked east to the south side of the freshening pen and observed an eroded flow path in outdoor lot 1 to the north. The Inspectors also observed large denuded areas in the outdoor lots (photos 1-3).
The Inspectors then walked to the northwest corner of outdoor lot 1 and observed the culvert under State Highway 19 and the grassed unnamed intermittent tributary of Wilson Rhodes Ditch (unnamed tributary) that is located just north of the northern edge of outdoor lots 1 and 2 (photo 4). The Inspectors walked east along the unnamed tributary and the northern edge of outdoor lots 1 and 2. The Inspectors observed that at the time of the inspection it was not possible to observe continuous flow in the unnamed tributary. There were sections where surface water could be observed and sections where there was no surface flow observed (photo 5). The Inspectors observed denuded ponded areas within outdoor lot 1 (photos 6 and 7). No flow was observed from the ponded areas to the unnamed tributary.
The Inspectors continued east along the northern edge of outdoor lot 1 and observed large denuded areas within outdoor lots 1 and 2. The Inspectors also observed the eroded flow path observed on the south side of outdoor lot 1 continuing northeast across outdoor lot 1 and into outdoor lot 2. The Inspectors observed flow within the eroded channel (photos 8-11).
The Inspectors continued east and observed that the unnamed tributary developed a clearly defined channel and had flowing water in the channel (photo 12). The Inspectors also observed that the eroded flow path from outdoor lot 1 had joined with the eroded flow paths in outdoor lot 2 and the surface runoff from the outdoor lots was flowing through a channel to the unnamed tributary. The inspectors collected a sample of the water that was flowing from outdoor lots 1 and 2 and into the unnamed tributary (photos 14 and 15). This sample is identified as sample S01. The Inspectors collected split samples and provided one set of samples to the Facility.
Prior to the inspection, EPA had identified an area using aerial photography which appeared to convey uncollected silage leachate. Due to time constraints related to transporting E. coli samples to the lab, the Inspectors chose to walk directly to the area identified prior to the inspection. The Inspectors observed a vegetated swale conveying runoff from the silage pad to a surface drain (photo 17 and 18). The Inspectors collected an E. coli sample from the surface water flowing into the drain (sample point S02). At this point in the inspection, Valerie Dooling placed the E. coli samples into a cooler with
9
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
ice and transported them to Microbac Laboratory in Merrillville, Indiana. Ben Atkinson (the Inspector) along with Chris Lowell of IDEM and the facility personnel continued the inspection.
After securing the general chemistry samples from S01 in their vehicle and collecting more sampling supplies, the Inspector waked to the southwest corner of waste storage structure 1. The Inspector observed what appeared to be fresh construction and concrete work as well as a pile of concrete debris (photos 19 and 20). The facility personnel stated that their previous solids seperator building and the wall upon which it had sat had collapsed.
The Inspector then walked south and observed waste storage structures 2 and 3 (photos 21-23). The Inspector then walked to the northeast and observed waste storage structures 1, 5 and 4 (photos 24-29).
The Inspector then returned to sample point S02 and collected the general chemistry samples (photo 30).
The Inspector then walked to the east toward Wilson Rhodes Ditch and identified a black corugated pipe protruding from the western bank. The facillity personnel stated that they believed that the black corrugated pipe was the outlet of the surface drain. The Inspector collected general chemistry samples from this location, sampling site S03 (photos 31-33).
The Inspector then walked north and observed the confluence of the unnamed tributary with Wilson Rhodes Ditch (photos 35-38). The Inspector walked west along the unnamed tributary back the notheast corner of outdoor lot 2. The Inspector observed that the unnamed tributary appeared to abruptly stop flowing on the surface approximately 50 feet east of outdoor lot 2 and then suddenly reemerge from underground approximately 320 feet west of of the confluence with intermittent Wilson Rhodes Ditch (photos 39-44). The facility personel stated that there may have been a pipe or culvert conveying the unnamed intermittent tributary, but that they were unsure.
The Inspector then walked to the south around the east side of the waste storage structures and observed the grassed swale conveying runoff from the silage pad (photos 45-46). The Inspector observed the two stage runoff and leachate collection system. The facility personnel stated that the system was designed to collect all leachate and runoff in low flow situations but then allow high volume runoff to flow to the grassed swale (photos 47-49). The Inspector then walked around the south end of the silage pad and then north along the west side of the silage pad (photos 50-55).
The Inspector observed the two tanks which receive recycled water from the waste storage structures (photo 56). The facility personnel stated that the tanks fill up and are used to flush the barns.
The Inspector walked west around the dairy cow barn and then around the calf hutch area (photos 57-59). The Operator had stated that he believed that there was a surface drain
10
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
on the west side of the dairy cow barn. The Inspector observed the area where the suspected drain was though to be located, but no drain or flow was observed (photos 6061).
The Inspector walked north around the milking parlor and then east along the north side of the dairy cow barn and observed the second stormwater surface drain identified by the Operator along the edge of the gravel driveway (photo 63). The Operator stated that he believed the drain had an outlet along the unnamed intermittent tributary.
The Inspector continued walking east and observed the temporary solid manure stacking area and associated runoff collection drain (photos 64-67). The Operator stated that this drain conveyed flow to the waste storage structures.
Following the walkthrough of the Facility, the Inspector returned to their vehicle and preserved the samples. The Inspector provided split samples of the general chemistry samples to the facility.
2.3 Closing Conference and Post-Inspection
Table 12: Post Walk-Through Was a closing conference held? With whom?
A brief closing conference was held with the Operator. Were specific Areas of Concern discussed with facility personnel? Who were the Areas of Concern discussed with?
Were any deficiencies or areas of concern addressed or fixed during the inspection? If so, list what was done.
Yes. See Areas of Concern below. The Operator
No
Exit Time: Disposable Boots Left at Facility? Vehicle Washed after leaving facility?
1:00 PM CST Yes Yes
11
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
Table 13: Waterway Documentation List the pathway taken by EPA inspectors to document the waterway at the facility. The Inspector observed flow: In Wilson Rhodes Ditch:
Under County Road North 400 East approximatly 600 feet north of the intersection of Coutny Road North 400 East and County Road East 1000 North (photos 68-69).
Then Approximatly 430 feet east of the intersection of Coutny Road North 400 East and County Road East 1000 North (photos 70-71).
Under County Road East 935 North approximatly 1700 feet east of the intersection of County Road North 400 East and County Road East 935 North (photos 72-73).
Under Road 450 East approximatly half a mile northeast of the intersection of Coutny Road North 400 East and County Road 450 East (photo 74-75).
Under County Road East 850 North approximatly 870 feet east of the intersection of County Road 450 East and County Road 850 North (photos 7677).
In Flowers Creek into which Wilson Rhodes Ditch flows: Under County Road East 800 North approximatly 270 feet east of the intersection of County Road North 350 East and County Road East 800 North (photos 78-79). Under Warsaw Trail North Road approximatly 0.6 miles north of the intersection of Warsaw Trail North Road and County Road East 700 North (photos 80-81). Under County Road East 700 North approximatly 825 feet west of the intersection of Warsaw Trail North Road and County Road East 700 North (photos 82-83). Under County Road East 645 North approximatly 725 feet west of the intersection of State Highway 19 (photos 86-87).
In the Eel River into which Flowers Creek flows under State Highway 19 at the bridge south of Chili, Indiana (photos 84-85).
See Waterway Map in Attachment A.
Table 14a: Sampling Information Were samples taken? Were samples split with facility? Number of Sample Locations? Was a trip blank created?
Identify which sample is the trip blank.
Yes
Yes 3 A blank was created after leaving the facility. B01
12
Mark Lee Deardorff Farms 03/26/2021 and 04/16/2021
Were field duplicate samples taken (1 duplicate per 20 samples)? Were equipment blanks taken (if more than one type of equipment was used to collect samples)? List chain of custody for fecal coliform samples:
List chain of custody for nutrient and general chemistry samples:
Location where samples were preserved:
Name of people involved with sample preservation: Time of sample preservation:
Were samples shipped to a lab? Did all inspectors involved with the sampling sign the chain of custody? Weather conditions at the time of sample collection: Camera name and type used to photograph sample collection:
No
No
Ben Atkinson to Valerie Dooling to Microbac laboratory Ben Atkinson to Central Research Laboratory Facility parking lot adjacent to shop building Ben Atkinson Approximately 12:30 PM EST No Yes
Overcast Ricoh WG-4 GPS
13
Table 14b: Facility Sample Information
Number
Name
Location Date Time
S01 S02 E coli S02 S03
Pasture Outlet
Leachate Inlet
Leachate Inlet
Leachate Outlet
B01
Blank
Northeast corner of outdoor lot 2 Surface Drain
Surface Drain
West bank of Wilson Rhodes Ditch Gas Station post inspection
03/26/2 021
03/26/2 021
03/26/2 021
03/26/2 021
03/26/2 021
10:16 AM EST 10:32 AM EST 11:24 AM EST 11:47A M EST
4:10 PM EST
Collector
BA VD BA VD BA BA
BA
Color/ Smell
Brownish color/ no smell noted. Brownish color
Brownish color
Clear
Clear
Photo #
15 18 30 31-33
None
Photographer
BA
Method of Collection
Grab
BA
Grab
BA
Grab
BA
Grab
NA
Grab
H2SO4 Preservative
15 drops
none
20 drops
10 drops
5 drops
Name of Laboratory where fecal coliform/E.coli samples were taken: Microbac Laboratory Name of Laboratory where nutrients and general chemistry samples were taken: CRL Additional laboratory and sampling notes: Sampling results are included in attachment C.
14
3. AREAS OF CONCERN EPA observed these areas of concern whereby pollutants have the potential to reach waters of the United States: 1. The channelized flow through outdoor lot 1 and outdoor lot 2 to the unnamed intermittent tributary. 2. The denuded nature of outdoor lot 1 and outdoor lot 2 and the runoff from the outdoor lots to the unnamed intermittent tributary. 3. The silage runoff conveyed by the vegetated swale to the surface drain and ultimately to Wilson Rhodes Ditch. 4. Care should be taken to ensure that no process wastewater or contaminated stormwater flows to the stormwater drains.
4. ATTACHMENTS A. AERIAL AND WATERWAY MAPS B. PHOTOLOG C. SAMPLING RESULTS D. DOCUMENTS FROM THE INDIANA VIRTUAL FILE CABINET
15
ATTACHMENT A
Unnamed Intermittent Tributary
Outdoor Lot 1
Redacted For Privacy
!R Sample S01
Outdoor Lot 2 Horse Barn
Legend
Surface Flow Observed During Inspection Subsurface Drain Tiles Identified on Farmstead Plan
@ Surface Drain Identified on Farmstead Plan
Flowers Creek Wilson Rhodes Ditch
!O Sampling Location
Waterways mapped by the National Hydrography Dataset
Wilson Rhodes Ditch
Shop
Freshening Pen
Dry Cow Barn
Milking Parlor
@ Temporary Solid Manure Storage
Commodity Shed Machine Shed
Waste Storage 1
@
Calf Hutch Area
Dairy Cows
Waste Storage 2
Silage Pad
Waste Storage 3
Waste Storage 5
Waste Storage 4
@ !R Sample S02
!R
Sample S03
1 inch = 225 feet .
Mark Lee Deardorff Farms 10729 N State Road 19 Macy, Indiana 46951
40.92322069247206, -86.02678171520034
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community
Facility
Legend
Name
Flowers Creek Wilson Rhodes Ditch Eel_River
!R Flow Confirmed at Road Crossing
!R !R
!R !R
!R !R !R !R
!R !R
. 1 inch = 2,500 feet
Waterways Mark Lee Deardorff Farms
10729 N State Road 19 Macy, Indiana 46951
40.92322069247206, -86.02678171520034
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community
ATTACHMENT B
Deardorff Farms EPA Photos from day 03/26/2021 of Inspection All photos taken by Ben Atkinson, Enforcement Officer, U.S. EPA
Camera: Ricoh WG-4 GPS Note: Time stamps are in Central Time, but local time was Eastern.
1: USER0566
Description: Looking southeast at gravel drive toward the abandoned barn (near) and the dry cow
barn (distant).
Location: Northwest of the abandoned barn.
Camera Direction: Southeast
Date/Time: 03/26/2021
8:35 AM CST
Page 1
Deardorff Farms 03/26/2021
2: USER0567
Description: The freshening pen is to the right, the dry cow barn is to the left, and the
commodity shed is in the center in the distance.
Location: North of the freshening pen.
Camera Direction: Northeast
Date/Time: 03/26/2021
8:37 AM CST
3: USER0568
Description: Looking northeast across outdoor lot 1 and outdoor lot 2. Note manure solids on
concrete (blue arrow) and eroded pathway (red arrow).
Location: North of the freshening pen.
Camera Direction: Northeast
Date/Time: 03/26/2021
8:37 AM CST
Page 2
Deardorff Farms 03/26/2021
4: USER0569
Description: Looking west toward the culvert under State Highway 19 (red arrow) which
conveys the unnamed intermittent tributary of the Wilson Rhodes Ditch (blue arrow idicates
direction of flow within the grassed waterway).
Location: North of outdoor lot 1 on the west side.
Camera Direction: West Date/Time: 03/26/2021
8:44 AM CST
5: USER0570
Description: Looking east along the grassed water. Outdoor lots 1 and 2 to the right. Note that
the surface water flow within the grassed waterway appears to start and stop in the high grass.
Location: North of outdoor lot 1 on the west side.
Camera Direction: East
Date/Time: 03/26/2021
8:45 AM CST
Page 3
Deardorff Farms 03/26/2021
6: USER0571
Description: Looking west along the north edge of outdoor lot 1 with grassed waterway to the
right. Note the denuded depressional area full of water was not observed contributing flow to the
grassed waterway at the time of the inspection.
Location: North of outdoor lot 1.
Camera Direction: West Date/Time: 03/26/2021
8:48 AM CST
7: USER0572
Description: Looking east along the grassed waterway. Outdoor lots 1 and 2 to the right.
Location: North of outdoor lot 1.
Camera Direction: East
Date/Time: 03/26/2021
8:50 AM CST
Page 4
Deardorff Farms 03/26/2021
8: USER0573
Description: Fence between outdoor lot 1 and 2. Note eroded flow path observed in photo 3
flowing northeast from outdoor lot 1 to outdoor lot 2 (red arrow).
Location: North of northeast corner of outdoor lot 1.
Camera Direction: South Date/Time: 03/26/2021
8:53 AM CST
9: USER0574
Description: Close up of eroded flow path flowing under the fence between outdoor lot 1 and
outdoor lot 2 (red arrow indicates direction of flow within flow path).
Location: North end of outdoor lot 1 and outdoor lot 2.
Camera Direction: Southeast
Date/Time: 03/26/2021
8:55 AM CST
Page 5
Deardorff Farms 03/26/2021
10: USER0575
Description: View southwest along eroded flow path.
Location: Fenceline approximately 120 feet south of north end of outdoor lots 1 and 2.
Camera Direction: Southwest
Date/Time: 03/26/2021
8:55 AM CST
11: USER0576
Description: View northeast along eroded flow path.
Location: Fenceline approximately 120 feet south of north end of outdoor lots 1 and 2.
Camera Direction: Northeast
Date/Time: 03/26/2021
8:57 AM CST
Page 6
Deardorff Farms 03/26/2021
12: USER0577
Description: Grassed waterway north of the northeast corner of feedlot 2. Note that the grassed
waterway has developed a more defined flowpath in this section (red arrows).
Location: North of the northeast corner of feedlot 2.
Camera Direction: East
Date/Time: 03/26/2021
9:02 AM CST
13: USER0578 Description: Looking west along north edge outdoor lot 2. Location: North of the northeast corner of feedlot 2. Camera Direction: West Date/Time: 03/26/2021
9:03 AM CST
Page 7
Deardorff Farms 03/26/2021
14: USER0579
Description: Flow from the eroded flow path through outdoor lots 1 and 2 (red arrow) reaching
the concentrated flow within the grassed waterway (blue arrow).
Location: Northeast corner of outdoor lot 2.
Camera Direction: North Date/Time: 03/26/2021
9:05 AM CST
Page 8
Deardorff Farms 03/26/2021
15: USER0580
Description: Sample location 1 where the eroded flow path from outdoor lots 1 and 2 flows north
to the concentrated flow within the grassed waterway.
Location: Northeast corner of outdoor lot 1.
Camera Direction: Southeast
Date/Time: 03/26/2021
9:19 AM CST
16: USER0581
Description: Looking west at horse barn and associated, well vegitated, outdoor lot.
Location: East of horse barn.
Camera Direction: West Date/Time: 03/26/2021
9:25 AM CST
Page 9
Deardorff Farms 03/26/2021
17: USER0582
Description: Surface drain receiving flow from grassed waterway conveying flow from silage
pad runoff collection system. Note additional orange pipe entering from the south (blue arrow).
Location: South of waste storage structure 4 and east of waste storage structure 3.
Camera Direction: Down
Date/Time: 03/26/2021
9:33 AM CST
18: USER0583
Description: Surface drain receiving flow from grassed swale (red arrow) conveying flow from
silage pad runoff collection system. Ecoli Sample 2 (blue arrow). Due to time constraints
regarding getting samples to the lab, only the E. Coli sampled at the time of the photgraph.
Additional samples were collected later during the walkthrough.
Location: South of waste storage structure 4 and east of waste storage structure 3.
Camera Direction: South Date/Time: 03/26/2021
9:33 AM CST
Page 10
Deardorff Farms 03/26/2021
19: USER0584
Description: Waste storage structure 1 and new (not yet operational) sand settling lane.
Location: East side of the facility northeast of silage pad.
Camera Direction: Northeast
Date/Time: 03/26/2021
9:59 AM CST
20: USER0585
Description: Waste storage structure 1 and new (not yet operational) sand settling lane. Note the
concrete debris from the collapse of the previous sand seperation building (red arrow).
Location: East side of the facility northeast of silage pad.
Camera Direction: East
Date/Time: 03/26/2021
9:59 AM CST
Page 11
Deardorff Farms 03/26/2021
21: USER0586
Description: Waste storage structure 2.
Location: Northwest corner of waste storage 2.
Camera Direction: Southeast
Date/Time: 03/26/2021
10:01 AM CST
22: USER0587
Description: Waste storage structure 2.
Location: Northwest corner of waste storage 2.
Camera Direction: Southeast
Date/Time: 03/26/2021
10:02 AM CST
Page 12
Deardorff Farms 03/26/2021
23: USER0588
Description: : Waste storage struture 2 flowing into waste storage structure 3.
Location: West side of waste storage structure 2.
Camera Direction: South Date/Time: 03/26/2021
10:02 AM CST
24: USER0589
Description: Waste storage structure 5.
Location: Southwest corner of waste storage strucutre 5.
Camera Direction: Northeast
Date/Time: 03/26/2021
10:04 AM CST
Page 13
Deardorff Farms 03/26/2021
25: USER0590
Description: Waste storage structure 4.
Location: West side of waste storage structure 4.
Camera Direction: Southeast
Date/Time: 03/26/2021
10:04 AM CST
26: USER0591
Description: Waste storage structure 4. Note pipe conveying flow from waste storage 3 (red
arrow).
Location: West side of waste storage structure 4.
Camera Direction: South Date/Time: 03/26/2021
10:05 AM CST
Page 14
Deardorff Farms 03/26/2021
27: USER0592
Description: Sand settling lane and waste storage structure 1 as seen from the northeast corner.
Location: Northwest of manure storage structure 5.
Camera Direction: Southwest
Date/Time: 03/26/2021
10:06 AM CST
28: USER0593
Description: Waste storage 4 as seen from the east side.
Location: Northeast of waste storage structure 4.
Camera Direction: Southwest
Date/Time: 03/26/2021
10:09 AM CST
Page 15
Deardorff Farms 03/26/2021
29: USER0594
Description: Waste storage structure 5 as seen from the southeast corner. Note the pipe
conveying flow from the sand settling lane (blue arrow).
Location: Southeast corner of manure storage structure 5.
Camera Direction: Northwest
Date/Time: 03/26/2021
10:09 AM CST
30: USER0595
Description: Remaining samples for sample site 2. Surface drain receiving flow from grassed
waterway conveying flow from silage pad runoff collection system. Location of E. coli Sample
that was taken at 9:32 AM CST.
Camera Direction: Down Date/Time: 03/26/2021
10:24 AM CST
Page 16
Deardorff Farms 03/26/2021
31: USER0596
Description: Close up of sample S03 at sample location 3, the outlet of the surface drain
receiving flow from grassed waterway conveying flow from silage pad runoff collection system.
Location: East of facility on the west bank of Wilson Rhodes Ditch.
Camera Direction: Down Date/Time: 03/26/2021
10:48 AM CST
32: USER0597
Description: Close up of sample S03 at sample location 3, the outlet of the surface drain
receiving flow from grassed waterway conveying flow from silage pad runoff collection system.
Location: East of facility on the west bank of the Wilson Rhodes Ditch.
Camera Direction: Down Date/Time: 03/26/2021
10:48 AM CST
Page 17
Deardorff Farms 03/26/2021
33: USER0598
Description: Sample location 3, the outlet of the surface drain receiving flow from grassed
waterway conveying flow from silage pad runoff collection system (red arrow). Note that there is
also a field tile outlet protruding from the bank of the Wilson Rhodes Ditch (blue arrow) which
was not sampled. The field tile appeared to be coming from the northwest.
Location: East of facility on the west bank of the Wilson Rhodes Ditch.
Camera Direction: West Date/Time: 03/26/2021
10:48 AM CST
34: USER0599
Description: Puddle in muddy access road.
Location: Approximately 1,000 feet east of facility and just west of Wilson Rhodes Ditch.
Camera Direction: South Date/Time: 03/26/2021
10:57 AM CST
Page 18
Deardorff Farms 03/26/2021
35: USER0600
Description: Confluence of unnamed intermittent tributary (to which the erroded flow path from
outdoor lots 1 and 2 flowed) and intermittent Wilson Rhodes Ditch.
Location: Northeast of facility. Approximately 900 feet east of the northeast corner of outdoor
lot 2.
Camera Direction: Northeast
Date/Time: 03/26/2021
11:05 AM CST
Page 19
Deardorff Farms 03/26/2021
36: USER0601
Description: Looking upstream along unnamed intermittent tributary north of confluence of
unnamed intermittent tributary (to which the erroded flow path from outdoor lots 1 and 2 flowed)
and intermittent Wilson Rhodes Ditch.
Location: Northeast of facility. Approximately 900 feet east of the northeast corner of outdoor
lot 2.
Camera Direction: North
Date/Time: 03/26/2021
11:05 AM CST
Page 20
Deardorff Farms 03/26/2021
37: USER0602
Description: Looking downstream along unnamed intermittent tributary south of confluence of
unnamed intermittent tributary (to which the erroded flow path from outdoor lots 1 and 2 flowed)
and intermittent Wilson Rhodes Ditch.
Location: Northeast of facility. Approximately 900 feet east of the northeast corner of outdoor
lot 2.
Camera Direction: South
Date/Time: 03/26/2021
11:05 AM CST
Page 21
Deardorff Farms 03/26/2021
38: USER0603
Description: Confluence of unnamed intermittent tributary (to which the erroded flow path from
outdoor lots 1 and 2 flowed) and intermittent Wilson Rhodes Ditch.
Location: Northeast of facility. Approximately 900 feet east of the northeast corner of outdoor
lot 2.
Camera Direction: Northeast
Date/Time: 03/26/2021
11:06 AM CST
39: USER0604
Description: Apparent re-emergence of the unnamed intermittent tributary.
Location: Approximately 320 feet west of confluence with intermittent Wilson Rhodes Ditch.
Camera Direction: North Date/Time: 03/26/2021
11:09 AM CST
Page 22
Deardorff Farms 03/26/2021
40: USER0605
Description: Apparent re-emergence of the unnamed intermittent tributary.
Location: Approximately 320 feet west of the confluence with intermittent Wilson Rhodes Ditch.
Camera Direction: North Date/Time: 03/26/2021
11:09 AM CST
41: USER0606
Description: The unnamed intermittent tributary flowing northeast to the Wilson Rhodes Ditch.
Location: Approximately 320 feet west of confluence with intermittent Wilson Rhodes Ditch.
Camera Direction: Northeast
Date/Time: 03/26/2021
11:09 AM CST
Page 23
Deardorff Farms 03/26/2021
42: USER0607
Description: Area east of outdoor lot 2 where the unnamed intermittent tributary ceased to flow
on the surface.
Location: Approximately 50 feet east of the northeast corner of outdoor lot 2.
Camera Direction: West Date/Time: 03/26/2021
11:17 AM CST
Page 24
Deardorff Farms 03/26/2021
43: USER0608
Description: Area east of outdoor lot 2 where the unnamed intermittent tributary ceased to flow
on the surface.
Location: Approximately 50 feet east of the northeast corner of outdoor lot 2.
Camera Direction: Northeast
Date/Time: 03/26/2021
11:17 AM CST
44: USER0609
Description: Area east of outdoor lot 2 where the unnamed intermittent tributary ceased to flow
on the surface.
Location: Approximately 50 feet east of the northeast corner of outdoor lot 2.
Camera Direction: West Date/Time: 03/26/2021
11:19 AM CST
Page 25
Deardorff Farms 03/26/2021
45: USER0610
Description: Grassed swale conveying flow from silage pad runoff collection system to the
surface drain (sample location 2).
Location: South of waste storage structure 3.
Camera Direction: East
Date/Time: 03/26/2021
11:28 AM CST
46: USER0611
Description: Grassed swale conveying flow from silage pad runoff collection system to the
surface drain (sample location 2).
Location: South of waste storage structure 3.
Camera Direction: North Date/Time: 03/26/2021
11:28 AM CST
Page 26
Deardorff Farms 03/26/2021
47: USER0612
Description: Silage pad runoff collection structure. Note that there are two inlets (blue arrows)
to accept runoff from the silage pad. The lower screened inlet conveys liquid to waste storage
structure 2. The second inlet is set to a higher elevation and conveys liquid to the grassed swale.
Location: East side oof the silage pad approximately 260 feet north of the southern edge of the
silage pad.
Camera Direction: Northeast
Date/Time: 03/26/2021
11:29 AM CST
Page 27
Deardorff Farms 03/26/2021
48: USER0613
Description: Silage pad runoff collection structure. Note that there are two inlets (blue arrows)
to accept runoff from the silage pad. The lower screened inlet conveys liquid to waste storage
structure 2. The second inlet is set to a higher elevation and conveys liquid to the grassed swale.
Location: East side oof the silage pad approximately 260 feet north of the southern edge of the
silage pad.
Camera Direction: Northeast
Date/Time: 03/26/2021
11:29 AM CST
49: USER0614
Description: Outlet of the silage pad runoff collection structure (blue arrow) to the grassed swale
(red arrow).
Location: : East side oof the silage pad approximately 260 feet north of the southern edge of the
silage pad.
Camera Direction: Down Date/Time: 03/26/2021
11:31 AM CST
Page 28
Deardorff Farms 03/26/2021
50: USER0615
Description: View north along the east side of the silage pad.
Location: East side of the silage pad midway between the north and south edges.
Camera Direction: North Date/Time: 03/26/2021
11:36 AM CST
51: USER0616
Description: Looking west across the southern edge of the silage pad.
Location:Southeastern corner of the silage pad.
Camera Direction: West Date/Time: 03/26/2021
11:38 AM CST
Page 29
Deardorff Farms 03/26/2021
52: USER0617
Description: Looking north across the western edge of the silage pad.
Location:Southwestern corner of the silage pad.
Camera Direction: North Date/Time: 03/26/2021
11:39 AM CST
53: USER0618
Description: Looking east across the southern edge of the silage pad.
Location:Southwestern corner of the silage pad.
Camera Direction: East
Date/Time: 03/26/2021
11:39 AM CST
Page 30
Deardorff Farms 03/26/2021
54: USER0619
Description: Looking north across the western edge of the silage pad.
Location:Midway between the northern edge and southern edge of the silage pad.
Camera Direction: North Date/Time: 03/26/2021
11:41 AM CST
55: USER0620
Description: Looking north. The dairy cow barn is to the left and silage pad is to the right.
Location: Southeast corner of the diary cow barn.
Camera Direction: North Date/Time: 03/26/2021
11:42 AM CST
Page 31
Deardorff Farms 03/26/2021
56: USER0621
Description: South side of the dairy cow barn. Note the two flush tanks (blue arrows) which are
used to recycle process wastewater from the waste storage structures for flushing the barns.
Location: Southeast corner of the diary cow barn.
Camera Direction: Northwest
Date/Time: 03/26/2021
11:42 AM CST
57: USER0622
Description: Looking north along the west side of the dairy cow barn. Calf hutch area to the left
and milking parlor in the distance.
Location: West side of dairy cow barn.
Camera Direction: North Date/Time: 03/26/2021
11:43 AM
Page 32
Deardorff Farms 03/26/2021
58: USER0623 Description: South side of the calf hutch area. Location: Southeast of calf hutch area. Camera Direction: West. Date/Time: 03/26/2021
11:44 AM
59: USER0624
Description: Looking noth along the west side of the calf hutch area.
Location: Southwest corner of calf hutch area.
Camera Direction: North Date/Time: 03/26/2021
11:46 AM CST
Page 33
Deardorff Farms 03/26/2021
60: USER0625
Description: Low area with standing water on west side of cow barn. Operator stated that he
believed that there was a storm water drain in this area but did not know the location of the
outlet. No water was observed flowing at the time of the inspection.
Location: West side of the dairy cow barn.
Camera Direction: South Date/Time: 03/26/2021
11:49 AM CST
61: USER0626
Description: Low area with standing water on west side of cow barn. Operator stated that he
believed that there was a storm water drain in this area but did not know the location of the
outlet. No water was observed flowing at the time of the inspection.
Location: West side of the dairy cow barn.
Camera Direction: South Date/Time: 03/26/2021
11:49 AM CST
Page 34
Deardorff Farms 03/26/2021
62: USER0627
Description: Looking east toward freshening pen.
Location: West side of the facility.
Camera Direction: East
Date/Time: 03/26/2021
11:51 AM
63: USER0628
Description: Surface drain in driveway north of the dairy cow barn. Operator stated that he
believed the drain outlet somewhere into the unnamed intermittent tributary.
Location: North of the dairy cow barn.
Camera Direction: Down Date/Time: 03/26/2021
11:53 AM CST
Page 35
Deardorff Farms 03/26/2021
64: USER0629
Description: Looking east at the temporary solid manure stacking site.
Location: Northeast of the dairy cow barn.
Camera Direction: East
Date/Time: 03/26/2021 11:54 AM
65: USER0630 Description: Mistake photo. Location: Camera Direction: Date/Time: 03/26/2021
Page 36
Deardorff Farms 03/26/2021
66: USER0631
Description: Looking west along the north side of the dairy cow barn.
Location: Northeast of the dairy cow barn.
Camera Direction: West Date/Time: 03/26/2021
11:56 AM CST
67: USER0632
Description: Runoff collection from the temporary solid manure stacking site (blue arrow). The
operator stated that this drain outlet to the waste storage structures.
Location: West end of the temporary solid manure stacking site.
Camera Direction: East
Date/Time: 03/26/2021
11:56 AM CST
Page 37
Deardorff Farms 03/26/2021
68: USER0633
Description: Up stream along Wilson Rhodes Ditch as it flows through a culvert under County
Road North 400 East.
Location: Approximatly 600 feet north of the intersection of Coutny Road North 400 East and
County Road East 1000 North.
Camera Direction: Northwest
Date/Time: 03/26/2021
1:20 PM CST
69: USER0634
Description: Down stream along Wilson Rhodes Ditch as it flowes through a culvert under
County Road North 400 East.
Location: Approximatly 600 feet north of the intersection of Coutny Road North 400 East and
County Road East 1000 North.
Camera Direction: Southeast Date/Time: 03/26/2021
1:20 PM CST
Page 38
Deardorff Farms 03/26/2021
70: USER0635
Description: Up stream along Wilson Rhodes Ditch as it flows through a culvert under County
Road East 1000 North.
Location: Approximatly 430 feet east of the intersection of Coutny Road North 400 East and
County Road East 1000 North.
Camera Direction: North Date/Time: 03/26/2021
1:24 PM CST
71: USER0636
Description: Down stream along Wilson Rhodes Ditch as it flows through a culvert under
County Road East 1000 North.
Location: Approximatly 430 feet north of the intersection of Coutny Road North 400 East and
County Road East 1000 North.
Camera Direction: South Date/Time: 03/26/2021
1:25 PM CST
Page 39
Deardorff Farms 03/26/2021
72: USER0637
Description: Up stream along Wilson Rhodes Ditch as it flows through a culvert under County
Road East 935 North.
Location: Approximatly 1700 feet east of the intersection of Coutny Road North 400 East and
County Road East 935 North.
Camera Direction: North Date/Time: 03/26/2021
1:29 PM CST
73: USER0638
Description: Down stream along Wilson Rhodes Ditch as it flows through a culvert under
County Road East 935 North.
Location: Approximatly 1700 feet east of the intersection of Coutny Road North 400 East and
County Road East 935 North.
Camera Direction: South Date/Time: 03/26/2021
1:29 PM CST
Page 40
Deardorff Farms 03/26/2021
74: USER0639
Description: Up stream along Wilson Rhodes Ditch as it flows through a culvert under County
Road 450 East.
Location: Approximatly half a mile northeast of the intersection of Coutny Road North 400 East
and County Road 450 East.
Camera Direction: North Date/Time: 03/26/2021
1:34 PM CST
75: USER0640
Description: Down stream along Wilson Rhodes Ditch as it flows through a culvert under
County Road 450 East.
Location: Approximatly half a mile northeast of the intersection of Coutny Road North 400 East
and County Road 450 East.
Camera Direction: South Date/Time: 03/26/2021
1:35 PM CST
Page 41
Deardorff Farms 03/26/2021
76: USER0641
Description: Up stream along Wilson Rhodes Ditch as it flows through a culvert under County
Road East 850 North.
Location: Approximatly 870 feet east of the intersection of County Road 450 East and County
Road 850 North.
Camera Direction: North Date/Time: 03/26/2021
1:46 PM CST
77: USER0642
Description: Down stream along Wilson Rhodes Ditch as it flows through a culvert under
County Road East 850 North.
Location: Approximatly 870 feet east of the intersection of County Road 450 East and County
Road 850 North.
Camera Direction: South Date/Time: 03/26/2021
1:46 PM CST
Page 42
Deardorff Farms 03/26/2021
78: USER0643
Description: Up stream along Flowers Creek (into which Wilson Rhodes Ditch flows) as it flows
through a culvert under County Road East 800 North.
Location: Approximatly 270 feet east of the intersection of County Road North 350 East and
County Road East 800 North.
Camera Direction: North Date/Time: 03/26/2021
2:00 PM CST
79: USER0644
Description: Down stream along Flowers Creek (into which Wilson Rhodes Ditch flowed) as it
flows through a culvert under County Road East 800 North.
Location: Approximatly 270 feet east of the intersection of County Road North 350 East and
County Road East 800 North.
Camera Direction: South Date/Time: 03/26/2021
2:00 PM CST
Page 43
Deardorff Farms 03/26/2021
80: USER0645
Description: Up stream along Flowers Creek as it flows through a culvert under Warsaw Trail
North Road.
Location: Approximatly 0.6 miles north of the intersection of Warsaw Trail North Road and
County Road East 700 North.
Camera Direction: East
Date/Time: 03/26/2021
2:04 PM CST
81: USER0646
Description: Down stream along Flowers Creek as it flows through a culvert under Warsaw Trail
North Road.
Location: Approximatly 0.6 miles north of the intersection of Warsaw Trail North Road and
County Road East 700 North.
Camera Direction: West Date/Time: 03/26/2021
2:04 PM CST
Page 44
Deardorff Farms 03/26/2021
82: USER0647
Description: Up stream along Flowers Creek as it flowes through a culvert under County Road
East 700 North.
Location: Approximatly 825 feet west of the intersection of Warsaw Trail North Road and
County Road East 700 North.
Camera Direction: North Date/Time: 03/26/2021
2:07 PM CST
83: USER0648
Description: Down stream along Flowers Creek as it flows through a culvert under County Road
East 700 North.
Location: Approximatly 825 feet west of the intersection of Warsaw Trail North Road and
County Road East 700 North.
Camera Direction: South Date/Time: 03/26/2021
2:07 PM CST
Page 45
Deardorff Farms 03/26/2021
84: USER0649
Description: Up river along the Eel River as it flows under State Highway 19.
Location: Bridge over the Eel River south of Chili, Indiana.
Camera Direction: East
Date/Time: 03/26/2021
2:13 PM CST
85: USER0650
Description: Down along the Eel River as it flows under State Highway 19.
Location: Bridge over the Eel River south of Chili, Indiana.
Camera Direction: West Date/Time: 03/26/2021
2:13 PM CST
Page 46
Deardorff Farms 03/26/2021
86: USER0651
Description: Up stream along Flowers Creek as it flows through a culvert under County Road
East 645 North.
Location: Approximatly 725 feet west of the intersection of State Highway 19.
Camera Direction: North Date/Time: 03/26/2021
2:16 PM CST
87: USER0652
Description: Down stream along Flowers Creek as it flowes through a culvert under County
Road East 645 North toward the Eel River.
Location: Approximatly 725 feet west of the intersection of State Highway 19.
Camera Direction: South Date/Time: 03/26/2021
2:16 PM CST
Page 47
Deardorff Farms 03/26/2021
Page 48
Deardorff Farms 03/26/2021
ATTACHMENT C
Microbac Laboratories, Inc. - Chicagoland CERTIFICATE OF ANALYSIS 21C1694
Project Description EP-W-15-006 Proj 0352.02.002
For: Jessica Gray ERG - Eastern Research Group 14555 Avion Parkway Suite 200 Chantilly, VA 20151-1102
Bonnie Feil Project Manager Assistant
Friday, April 2, 2021
Please find enclosed the analytical results for the samples you submitted to Microbac Laboratories. Review and compilation of your report was completed by Microbac Laboratories, Inc. - Chicagoland. If you have any questions, comments, or require further assistance regarding this report, please contact your service representative listed above. I certify that all test results meet all of the requirements of the accrediting authority listed within this report. Analytical results are reported on a 'as received' basis unless specified otherwise. Analytical results for solids with units ending in (dry) are reported on a dry weight basis. A statement of uncertainty for each analysis is available upon request . This laboratory report shall not be reproduced, except in full, without the written approval of Microbac Laboratories. The reported results are related only to the samples analyzed as received.
Microbac Laboratories, Inc. 250 West 84th Drive | Merrillville, IN 46410 | 219.769.8378 p | www.microbac.com
Page 1 of 4
Microbac Laboratories, Inc. - Chicagoland
CERTIFICATE OF ANALYSIS
ERG - Eastern Research Group
21C1694 Project Name: EP-W-15-006 Proj 0352.02.002
Jessica Gray 14555 Avion Parkway Suite 200 Chantilly, VA 20151-1102
Project / PO Number: 0352.02.002/4 Mod 1 Received: 03/26/2021 Reported: 04/02/2021
Case Narrative BA01 Deardorff 001 Pasture 2 Corner
[TOC_1]Case Narrative[TOC]
Initial analyses of 3/26/21 resulted in an E. coli result with an estimated value above the countable range for the dilution. The sample was re-analyzed out-of-holding time on 3/27/21 with a larger dilution. Both results are represented in this report.
Sample Summary Report
Sample Name BA01 Deardorff 001 Pasture 2 Corner BA01 Deardorff 002 Leachate Collection
Laboratory ID 21C1694-01
Client Matrix Aqueous
21C1694-02
Aqueous
[TOC_1]Sample Summary[TOC]
Sample Type
Sample Begin
Sample Taken 03/26/21 10:16
03/26/21 10:32
Lab Received 03/26/21 11:50
03/26/21 11:50
Page 2 of 4
Microbac Laboratories, Inc. - Chicagoland
CERTIFICATE OF ANALYSIS 21C1694
Analytical Testing Parameters
Client Sample ID: Sample Matrix: Lab Sample ID:
BA01 Deardorff 001 Pasture 2 Corner Aqueous 21C1694-01
Collection Date:
[TOC_1]Analytical Sample Results[TOC]
OC_1]Results - 21C1694-01[TOC] 03/26/2021 10:16
Microbiology
Result
SM 9223 B MPN-1997/SM 9223 B (Colilert Quanti-Tray)-1997
Escherichia coli
> 241960
Escherichia coli
170000
RL
Units
DF
MPN/100mL 1 1000 MPN/100mL 1
Note
Prepared
Analyzed Analyst
03/26/21 1411 03/27/21 1212
03/27/21 1442 03/28/21 1226
JAA BML
Client Sample ID: Sample Matrix: Lab Sample ID:
BA01 Deardorff 002 Leachate Collection Aqueous 21C1694-02
Microbiology
Result
SM 9223 B MPN-1997/SM 9223 B (Colilert Quanti-Tray)-1997
Escherichia coli
130000
RL
Units
OC_1]Results - 21C1694-02[TOC]
Collection Date:
03/26/2021 10:32
DF
Note
Prepared
Analyzed
Analyst
100 MPN/100mL 1
03/26/21 1411 03/27/21 1442 JAA
Definitions MPN/100mL RL:
Most Probable Number per 100 Milliliters Reporting Limit
Cooler Receipt Log Cooler ID: Default Cooler
Temp: 5.6C
Cooler Inspection Checklist
Ice Present or not required?
Yes
Custody seals intact or not required?
Yes
COC includes customer information?
Yes
Sample collector identified on COC?
Yes
Correct type of Containers Received
Yes
Containers Intact?
Yes
Enough sample volume for indicated tests received?
Yes
Samples arrived within hold time?
Yes
Chemical preservations checked or not required?
Yes
VOA vials have zero headspace, or not recd.?
Yes
[TOC_1]Notes and Definitions[TOC] [TOC_1]Cooler Receipt[TOC]
Shipping containers sealed or not required?
Yes
Chain of Custody (COC) Present?
Yes
Relinquished and received signature on COC?
Yes
Sample type identified on COC?
Yes
Correct number of containers listed on COC?
Yes
COC includes requested analyses?
Yes
Sample labels match COC (Name, Date & Time?)
Yes
Correct preservatives on COC or not required?
Yes
Preservation checks meet method requirements?
Yes
Report Comments
Reviewed and Approved By:
The data and information on this, and other accompanying documents, represents only the sample(s) analyzed. This report is incomplete unless all pages indicated in the footnote are present and an authorized signature is included. The services were provided under and subject to Microbac's standard terms and conditions which can be located and reviewed at <https://www.microbac.com/standard-terms-conditions>.
Bonnie Feil Project Manager Assistant 04/02/2021 17:30
Microbac Laboratories, Inc. 250 West 84th Drive | Merrillville, IN 46410 | 219.769.8378 p | www.microbac.com
Page 3 of 4
Page 4 of 4
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605
Date:
4/9/2021
Title: To:
From:
ASB Data Report for Deardorff
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604
Colin Breslin, Chemist breslin.colin@epa.gov US EPA Region 5 LSASD Analytical Services Branch
The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures.
This report was reviewed and the information provided herein accurately represents the analysis performed.
Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you.
Attached are Results for: Deardorff
Analyses included in this report: Nitrate-Nitrite N DA, Enzymatic reduction
Report Name: 2103010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Apr 09 21 0949
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Accredited Analyses included in this Report
Reported: Apr-09-21 09:49
Method: Analysis: Analyte
NECi Method NO7-0003 in Water Nitrate-Nitrite N DA, Enzymatic reduction
Nitrate-Nitrite N
Certifications ISO/IEC 17025:2017
Analytes not listed above are not accredited by ANAB.
Report Name: 2103010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Apr 09 21 0949
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Reported: Apr-09-21 09:49
ANALYSIS CASE NARRATIVE
General Information
Analyst: Colin Breslin Phone Number: 312-886-2912
Sample 2103010-01 2103010-02 2103010-03 2103010-04
Analysis List Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N DA, Enzymatic reduction
All holding times were met.
The samples were prepared and analyzed using laboratory SOP AIG031B, Version #5, based on: Method List NECi Method NO7-0003
Sample Analysis and Results
The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated "FY 2021". QAPP and laboratory reporting limit requirements were met, and results were reported to the MDL.
Quality Control
All quality control audits were within laboratory limits or did not result in qualification of the data, except as follows:
Matrix Spike (MS): The matrix spike of field sample 2103010-01 was recovered at 114%, which exceeded the control limits of 90 - 110%. The result for field sample 2103010-01 was flagged with a high bias.
Report Name: 2103010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Apr 09 21 0949
3019234515671897 4355871839517195743591854
!"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291
?@A@<0
BCDEDCD :;0 7351;;<19839;74237=>491
43187GKENEDNBDBCCKEDKB O
3718K ?9874<323=351F:;0 7351 45J78K<794G54HH
45J78O91974K 179@ P49==9<923= 45J78LM674K >IDCIBC
7Q548R5K [%.Y$'.V. S"%#T'U'V'.&WX-YZ%)'.
T"%T%/ Z%(%'U%][_/ +))%]*.[_/
`"_41^4211/,,0^]"_aYa3 Zb%#._]%# Zb%#._]%#
66S%V\"($V.[!%U"#] '(")&*+,,^ T"%Z%(%'U%]/ `"#4,4211,/,5 T"%+))%]*./ `"#4,42111/1
-.%/012342,,^ 7"8/01235542,,1
"cd!%")Ve!"b%!V %"!V*."( Z%(%'U%].'(% -"d%#f#$*.(!]%]
g7= ?54P@4G74566718=K g7= dhd"d%#V%]'. i15T19,1 g7= g7=
!%#0V3'.j#c"'./ T%j"! !%#4,k^,
;96Q7l<K BCDEDCDIDC ;96Q7GK O94IBqIBCCDKCq
;96Q7L967K ;DC
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
atrTY
25
a"!-Vd#VTY
25
O9843mK ?9874 ;96Q7598351N566718=K 9=8M475M878
0mQ347= Yd#424211,/1 Yd#424211,/1 Yd#4,24211,/1 Yd#4,24211,/1 Yd#424211,/1 Yd#424211,/1
566718= dhi1 dhi1 dhi6 dhi6 dhi1 dhi1
;96Q7l<K BCDEDCDIDB ;96Q7GK O94IBqIBCCDKBu
;96Q7L967K ;DB
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
O9843mK ?9874 ;96Q7598351N566718=K 799873178
0mQ347= Yd#424211,/2^ Yd#424211,/2^ Yd#4,24211,/2^ Yd#4,24211,/2^
566718= dhi1 dhi1 dhi6 dhi6
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Reported: Apr-09-21 09:49
S01 (2103010-01)
Analyte Nitrate-Nitrite N
S02 (2103010-02)
Analyte Nitrate-Nitrite N
S03 (2103010-03)
Analyte Nitrate-Nitrite N
B01 (2103010-04)
Analyte Nitrate-Nitrite N
Nitrate-Nitrite Nitrogen, Nitrate Reductase, NECi Method N07-0003 (modified) US EPA Region 5 LSASD Analytical Services Branch
Matrix: Water Sampled: Mar-26-21 10:16
Result
Flags / Qualifiers
MDL
Reporting Limit
9.34
(MS), K
0.50
1.00
Received: Mar-30-21 10:08
Units mg/L
Dilution 10
Batch B21D003
Prepared Apr-06-21
Analyzed Apr-06-21
Matrix: Water Sampled: Mar-26-21 10:24
Result
Flags / Qualifiers
MDL
Reporting Limit
0.62
0.05
0.10
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D003
Prepared Apr-06-21
Analyzed Apr-06-21
Matrix: Water Sampled: Mar-26-21 11:47
Result
Flags / Qualifiers
MDL
Reporting Limit
9.83
0.50
1.00
Received: Mar-30-21 10:08
Units mg/L
Dilution 10
Batch B21D003
Prepared Apr-06-21
Analyzed Apr-06-21
Matrix: Water Sampled: Mar-26-21 16:10
Result
Flags / Qualifiers
MDL
Reporting Limit
U
0.05
0.10
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D003
Prepared Apr-06-21
Analyzed Apr-06-21
Report Name: 2103010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Apr 09 21 0949
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Reported: Apr-09-21 09:49
K
(MS) U NR Q
Notes and Definitions
The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less than the reported value. Matrix spike recovery criteria not met for this analyte
Not Detected Not Reported QC limit Exceeded
Report Name: 2103010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Apr 09 21 0949
Table of Contents
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 ANALYTICAL SERVICES BRANCH LABORATORY
536 SOUTH CLARK STREET (LAB-10C) CHICAGO, ILLINOIS 60605
ELECTRONIC LABORATORY DATA PACKAGE FINAL LEVEL IV COVER PAGE
LIMS Work order(s): Primary Analyst: Analysis: Date: Data Reporting Qualtrax Workflow ID:
Digital Signature of Primary Analyst:
2103010 Nidia Fuentes Ammonia N DA, Distilled May 14, 2021
25063
Digital Signature Agreement: By signing above the primary analyst understands and agrees that they will be held legally bound, obligated, and responsible for the use of their digital signature as they would be by using their hand-written signature.
Page 1 of 73
Client Project Name: Work Order Number:
Deardorff (BA-01-21) 2103010
1 Cover Page 2 Level I Report 3 QC Summary 4 Checklist 5 Sample Prep and Supporting Data (Ammonia N DA, Distilled)
5.1 Bench Sheets (B21D027) 5.2 Batch Reagents (B21D027) 5.3 Analysis Data and Supporting Documents (21D2102) 5.4 Standards (19K1224) 5.5 Standards (21D2113) 5.6 Standards (21D2114) 5.7 Standards (21D2115) 5.8 Standards (21D2116) 5.9 Standards (21D2132) 5.10 Standards (21D2133) 5.11 Standards (21D2134) 5.12 Standards (21D2135) 5.13 Standards (21D2136) 5.14 Sequence Reagents (21D2102)
Table of Contents
Table of Contents
1 3 11 13 17 18 21 42 51 52 53 54 55 56 57 58 59 60 61
536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 FAX: 312-353-9069
Page 2 of 73
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605
Table of Contents
Date:
5/14/2021
Title: To:
From:
ASB Data Report for Deardorff
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604
Nidia Fuentes, Chemist fuentes.nidia@epa.gov US EPA Region 5 LSASD Analytical Services Branch
The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures.
This report was reviewed and the information provided herein accurately represents the analysis performed.
Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you.
Attached are Results for: Deardorff
Analyses included in this report: Ammonia N DA, Distilled
Report Name: 2103010 Ammonia N DA, Distilled FINAL May 14 21 1000
Page 3 of 73
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Accredited Analyses included in this Report
Table of Contents
Reported: May-14-21 10:00
Method: Analysis: Analyte
SM 4500-H+ B in Water Ammonia N DA, Distilled
Ammonia as N
Certifications ISO/IEC 17025:2017
Analytes not listed above are not accredited by ANAB.
Report Name: 2103010 Ammonia N DA, Distilled FINAL May 14 21 1000
Page 4 of 73
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-14-21 10:00
ANALYSIS CASE NARRATIVE
Analysis List Ammonia N DA, Distilled
Analyst: Nidia Fuentes Phone #: 312-353-9079
General Information
Samples analyzed:
Sample
Analysis List
2103010-01
Ammonia N DA, Distilled
2103010-02
Ammonia N DA, Distilled
2103010-03
Ammonia N DA, Distilled
2103010-04
Ammonia N DA, Distilled
Holding times: All holding times were met.
Sample Analysis and Results
The samples were analyzed using ASB SOP AIG029B, Version #9. The samples were stored in the refrigerator at all times, except when in use. The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated "FY 2021", except for those listed in the Quality Control section.
SOP Based on: Method List SM 4500-H+ B
Quality Control
All quality control audits were within ASB limits or did not result in qualification of the data except for any listed below.
Report Name: 2103010 Ammonia N DA, Distilled FINAL May 14 21 1000
Page 5 of 73
3019234515671897 4355871839517195743591854
!"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291
Table of Contents
?@A@<0
BCDEDCD :;0 7351;;<19839;74237=>491
43187GKENEDNBDBCCKEDKB O
3718K ?9874<323=351F:;0 7351 45J78K<794G54HH
45J78O91974K 179@ P49==9<923= 45J78LM674K >IDCIBC
7Q548R5K [%.Y$'.V. S"%#T'U'V'.&WX-YZ%)'.
T"%T%/ Z%(%'U%][_/ +))%]*.[_/
`"_41^4211/,,0^]"_aYa3 Zb%#._]%# Zb%#._]%#
66S%V\"($V.[!%U"#] '(")&*+,,^ T"%Z%(%'U%]/ `"#4,4211,/,5 T"%+))%]*./ `"#4,42111/1
-.%/012342,,^ 7"8/01235542,,1
"cd!%")Ve!"b%!V %"!V*."( Z%(%'U%].'(% -"d%#f#$*.(!]%]
g7= ?54P@4G74566718=K g7= dhd"d%#V%]'. i15T19,1 g7= g7=
!%#0V3'.j#c"'./ T%j"! !%#4,k^,
;96Q7l<K BCDEDCDIDC ;96Q7GK O94IBqIBCCDKCq
;96Q7L967K ;DC
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
atrTY
25
a"!-Vd#VTY
25
O9843mK ?9874 ;96Q7598351N566718=K 9=8M475M878
0mQ347= Yd#424211,/1 Yd#424211,/1 Yd#4,24211,/1 Yd#4,24211,/1 Yd#424211,/1 Yd#424211,/1
566718= dhi1 dhi1 dhi6 dhi6 dhi1 dhi1
;96Q7l<K BCDEDCDIDB ;96Q7GK O94IBqIBCCDKBu
;96Q7L967K ;DB
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
O9843mK ?9874 ;96Q7598351N566718=K 799873178
0mQ347= Yd#424211,/2^ Yd#424211,/2^ Yd#4,24211,/2^ Yd#4,24211,/2^
566718= dhi1 dhi1 dhi6 dhi6
Page 6 of 73
Table of Contents Page 7 of 73
Table of Contents Page 8 of 73
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-14-21 10:00
S01 (2103010-01)
Analyte Ammonia as N
S02 (2103010-02)
Analyte Ammonia as N
S03 (2103010-03)
Analyte Ammonia as N
B01 (2103010-04)
Analyte Ammonia as N
Ammonia Nitrogen, SM4500B & H (modified) US EPA Region 5 LSASD Analytical Services Branch
Matrix: Water Sampled: Mar-26-21 10:16
Result
Flags / Qualifiers
MDL
Reporting Limit
8.11
1.60
2.00
Received: Mar-30-21 10:08
Units mg/L
Dilution 10
Batch B21D027
Matrix: Water Sampled: Mar-26-21 10:24
Result
Flags / Qualifiers
MDL
Reporting Limit
26.6
1.60
2.00
Received: Mar-30-21 10:08
Units mg/L
Dilution 10
Batch B21D027
Matrix: Water Sampled: Mar-26-21 11:47
Result
Flags / Qualifiers
MDL
Reporting Limit
3.05
0.16
0.20
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D027
Matrix: Water Sampled: Mar-26-21 16:10
Result
Flags / Qualifiers
MDL
Reporting Limit
U
0.16
0.20
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D027
Prepared Apr-21-21
Analyzed Apr-21-21
Prepared Apr-21-21
Analyzed Apr-21-21
Prepared Apr-21-21
Analyzed Apr-21-21
Prepared Apr-21-21
Analyzed Apr-21-21
Report Name: 2103010 Ammonia N DA, Distilled FINAL May 14 21 1000
Page 9 of 73
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
U
Not Detected
NR
Not Reported
Q
QC limit Exceeded
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Notes and Definitions
Table of Contents
Reported: May-14-21 10:00
Report Name: 2103010 Ammonia N DA, Distilled FINAL May 14 21 1000
Page 10 of 73
Environmental Protection Agency
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Table of Contents
Date: Project:
5/14/2021 Deardorff
Quality Control Summary
Analyst: Nidia Fuentes
Analyte: Ammonia as N
Analysis: Ammonia N DA, Distilled
QC Sample Name 21D2102-CAL1
Result 0.0020
Units mg/L
Flags / Qualifiers
MDL
Reporting Limit
Spike Level
0.16
0.20
0.000
Source Result
% REC or abs diff (pH)
% REC or abs diff
(pH) Limits
%
% RPD or abs diff (pH)
%RPD or abs diff ( pH)
Limits
21D2102-CAL2
0.08
mg/L
0.16
0.20
0.1000
84%
21D2102-CAL3
0.20
mg/L
0.16
0.20
0.2000
98%
21D2102-CAL4
0.41
mg/L
0.16
0.20
0.4000
103%
21D2102-CAL5
0.82
mg/L
0.16
0.20
0.8000
102%
21D2102-CAL6
1.99
mg/L
0.16
0.20
2.000
100%
21D2102-CAL7
4.00
mg/L
0.16
0.20
4.000
100%
21D2102-CCB1
-0.01
mg/L
0.16
0.20
21D2102-CCB2
-0.0060
mg/L
0.16
0.20
21D2102-CCB3
-0.0040
mg/L
0.16
0.20
21D2102-CCB4
0.01
mg/L
0.16
0.20
21D2102-CCB5
-0.0070
mg/L
0.16
0.20
21D2102-CCB6
-0.0090
mg/L
0.16
0.20
21D2102-CCV1
3.25
mg/L
0.16
0.20
3.000
108%
90-110
21D2102-CCV2
3.25
mg/L
0.16
0.20
3.000
108%
90-110
21D2102-CCV3
3.23
mg/L
0.16
0.20
3.000
108%
90-110
21D2102-CCV4
3.23
mg/L
0.16
0.20
3.000
108%
90-110
21D2102-CCV5
3.23
mg/L
0.16
0.20
3.000
108%
90-110
21D2102-CCV6
3.21
mg/L
0.16
0.20
3.000
107%
90-110
Report Name: 2103010 Ammonia N DA, Distilled FINAL May 14 21 1000
Page 11 of 73
Environmental Protection Agency
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Table of Contents
Quality Control Summary
Date: 5/14/2021
Analyst: Nidia Fuentes
Project: Deardorff
Analyte: Ammonia as N
Analysis: Ammonia N DA, Distilled
QC Sample Name 21D2102-ICB1
Result -0.01
Units mg/L
Flags / Qualifiers
MDL
Reporting Limit
Spike Level
0.16
0.20
Source Result
% REC or abs diff (pH)
% REC or abs diff
(pH) Limits
% RPD or abs diff (pH)
%RPD or abs diff ( pH)
Limits
21D2102-ICV1
3.19
mg/L
0.16
0.20
3.000
106%
90-110
B21D027-BLK1
U
mg/L
0.16
0.20
B21D027-BS1
2.07
mg/L
0.16
0.20
2.000
104%
73-120
B21D027-BS2
2.14
mg/L
0.16
0.20
2.000
107%
73-120
B21D027-DUP1 Source: 2103010-01
B21D027-MRL1
7.72
mg/L
0.18
mg/L
1.60
2.00
8.11
5
14
0.16
0.20
0.2000
92%
71-147
B21D027-MS1 Source: 2103010-01
10.4
mg/L
1.60
2.00
2.000 8.11
115%
50-148
U
Not Detected
NR
Not Reported
Q
QC limit Exceeded
Notes and Definitions
Nidia Fuentes
Report Name: 2103010 Ammonia N DA, Distilled FINAL May 14 21 1000
Page 12 of 73
Work:
2103010
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 LSASD ANALYTICAL SERVICE BRANCH 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605
Data Verification Checklist
Project: Deardorff
Analysis: Ammonia N DA, Distilled
CRL SOP Used:
AIG029B v9
Batch ID:
General Information
B21D027
Question #
1
Question Did samples meet the laboratory's standard conditions of sample acceptability upon receipt?
2
Was customer contact communication included?
3
Are all field sample ID numbers cross-referenced to the laboratory ID numbers?
4
Were all samples prepared and analyzed within holding times?
Question # 5 6 7 8 9 10 11 12 13
Sample Results
Were calculations checked?
Question
Were all analyte results checked?
Were all results for soil and sediment samples reported on a dry weight basis?
Were % moisture (or solids) reported for all soil and sediment samples?
Other than those results < RL, were all other raw values bracketed by calibration standards?
Are the RLs for each method analyte included in the laboratory data package?
Are MDLs/RLs adjusted for dilutions?
Were the raw data (for example, chromatograms, spectral data) reviewed?
Were data associated with manual integrations flagged on the raw data?
Question # 14
15
Standards
Question Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources as specified in the analytical SOP? Were standard/reagent preparations checked (preparation date, expiration date, parent standard IDs, etc.), if applicable?
Batch Quality Control
Print Date: 4/26/2021
Table of Contents
Analyst Response (YES/ NO/ NA) YES NA YES YES
Analyst Response (YES/ NO/ NA) YES YES NA NA YES YES YES YES NA
Analyst Response (YES/ NO/ NA) YES YES
Page 13 of 73
Work:
2103010
Project: Deardorff
Question # 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Batch Quality Control
Were appropriate type(s) of blanks analyzed?
Question
Were blanks analyzed at the appropriate frequency?
Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures?
Were blank concentrations <= MDL or RL, as applicable in the analytical SOP?
Was each LCS/SRM taken through the entire analytical procedure, including prep and cleanup steps?
Were LCSs/SRMs analyzed at the required frequency?
Were LCS/SRM %Rs within the laboratory QC limits or other acceptance criteria?
Were the project/method specified analytes included in the MS?
Were MS analyzed at the appropriate frequency?
Were MS %Rs within the laboratory QC limits?
Were appropriate analytical duplicates analyzed for each matrix?
Were analytical duplicates analyzed at the appropriate frequency?
Were RPDs or relative standard deviations within the laboratory QC limits or other acceptance criteria?
Were RLs analyzed at the appropriate frequency?
Were RL recoveries within the laboratory QC limits?
Question # 31
32
33
34
Calibration
Question Were calibration correlation coefficient or other acceptance criteria met? Was the number of calibration standards recommended in the method used for all analytes? Were all points generated between the lowest and highest standard used to calculate the curve? Are calibration data available for all instruments used?
Question # 35
36
37
Calibration Verification
Question Was the absolute value of the analyte concentration in the ICB/CCB <= MDL or RL, as applicable in the analytical SOP? Was the calibration curve verified for each analyte?
Has the calibration curve been verified using an appropriate second source standard?
Print Date: 4/26/2021
Table of Contents
Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
Analyst Response (YES/ NO/ NA) YES YES YES YES
Analyst Response (YES/ NO/ NA) YES YES YES
Page 14 of 73
Work:
2103010
Project: Deardorff
Question # 38
39
Calibration Verification
Question Were ICV/CCV analyzed at the method-required frequency? Were ICV/CCV %R within the laboratory QC limits?
Question # 40
41
42
Quality Control
QC limits in LIMS checked against the SOP?
Question
Were percent differences, recoveries, and the linearity within the QC limits specified in the method?
Were QC charts checked if a QC audit, excluding matrix QC (MS or DUP), was out of limit?
Question # 43
44
Supporting Data
Question Were support equipment data (balance verification, data logs, logbook entries, etc.) included in data package? Were approved spreadsheet(s) used?
Question # 45 46 47 48 49 50
Question # 51
Document Verification
Question Is the MDL or RL study up-to-date for each reported analyte?
Is documentation of the analyst's capability up-to-date and on file?
In process
By NFUENTES at 12:30 pm, May 13, 2021
Are the procedures for compound/analyte identification documented?
ID:24456
Are laboratory SOPs current and on file for the method performed?
Were data evaluated against project QAPP or Sample Plan, any special requests in the sample schedule, and documented in case narrative? Were electronic pathways checked (add pathway and files below)?
Notes/Comments: J:\Vol1\Projects (New File Structure)\Deardorff\1. A&I\NFuentes\DA-4\2103010\04212021-AMM\ARC_70.bak
Accreditation
ANAB logo used appropriately?
Question
Table of Contents
Analyst Response (YES/ NO/ NA) YES YES
Analyst Response (YES/ NO/ NA) YES YES NA
Analyst Response (YES/ NO/ NA) YES YES
Analyst Response (YES/ NO/ NA) YES
By NFUENTES at 12:30 pm, May 13, 2021 YES 12 YES YES YES YES
Analyst Response (YES/ NO/ NA) YES
Analyst's Signature and Date*:
By NFUENTES at 9:29 am, Apr 26, 2021
Print Date: 4/26/2021
Page 15 of 73
Work:
2103010
Project: Deardorff
Table of Contents
Reviewer's Signature and Date*:
By AK at 9:15 am, May 14, 2021
Additional Notes/Comments (if applicable):
*Reviewer Concurs with Analyst Responses
Print Date: 4/26/2021
Page 16 of 73
Table of Contents
Ammonia N DA, Distilled
Page 17 of 73
BATCH
B21D027
[TOC_1]Benchsheets[TOTCa]ble of Contents
Page 18 of 73
Prepared Date: Analyst (initials):
Apr-21-21 NF
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
AMMONIA DISTILLATION LOG (EASY STILL) FOR WATER SAMPLES
Date: 4/21/2021
Batch Number: B21D027
Analyses Included On This Benchsheet Ammonia N DA, Distilled
Distillation #
Position #
Sample Number
1
5
2103010-01
1
8
2103010-02
1
9
2103010-03
1
10
2103010-04
1
11
2104004-01
1
14
2104004-02
1
1
B21D027-BLK1
1
2
B21D027-BS1
1
3
B21D027-BS2
1
6
B21D027-DUP1
1
12
B21D027-DUP2
1
4
B21D027-MRL1
1
7
B21D027-MS1
Source ID
2103010-01 2104004-01 2103010-01
Spike Type
Pre-Prep Pre-Prep Pre-Prep Pre-Prep
Spike ID
19K1224 19K1224 21D2116 19K1224
Spike Volume Sample Volume
(uL)
(mL)
50
50
50
50
50
50
50
100
50
100
50
50
50
2500
50
100
50
Adjusted pH is ~ 9.5 (Y/N)
Y Y Y Y Y Y Y Y Y Y Y Y Y
Comments
pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 * pH = 1 *
By NFUENTES at 9:55 am, Apr 29, 2021 By NFUENTES at 9:55 am, Apr 29, 2021
*
By NFUENTES at 9:55 am, Apr 29, 2021
Batch Comments: *Refer to B21D032.. Re-Distiller because missing matrix spike.
Page 1 of 2
Table of Contents Page 19 of 73
Prepared Date: Analyst (initials):
Apr-21-21 NF
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
AMMONIA DISTILLATION LOG (EASY STILL) FOR WATER SAMPLES
Date: 4/21/2021
Batch Number: B21D027
Analyses Included On This Benchsheet Ammonia N DA, Distilled
Distillation #
Position #
Sample Number
Source ID
Spike Type
Spike ID
1
13
B21D027-MS2
2104004-01
Pre-Prep
19K1224
PREPARATION REAGENTS/STANDARDS/PIPETTES:
19K1224: NH3N-StockControlStandard
Prepared: Nov-12-19
21D2116: NH3N-MRL Spike
Prepared: Apr-21-21
19F0521: Sodium Hydroxide 10% (w/v)
Prepared: May-02-19
19F1209: NH3N Distilled-Borate Buffer
Prepared: Jun-12-19
20K0528: Test Strip: pH 5.0 - 10
Prepared: Nov-05-20
21B2306: Pipette (Electronic) -- 50 -1,000 uL
Prepared: Feb-15-21
21B2307: Pipette (Electronic) -- 200 -5000 uL
Prepared: Feb-15-21
21B2308: Pipette (Electronic) -- 500 - 10,000 uL
Prepared: Feb-15-21
21B2309: Pipette (Electronic) -- 5 -100 uL
Prepared: Feb-15-21
21D2112: NH3NDistilled-ReceivingSol/BLK
Prepared: Apr-21-21
Spike Volume Sample Volume
(uL)
(mL)
100
50
Adjusted pH is ~ 9.5 (Y/N)
Y
Expires: May-06-21 Expires: May-21-21 Expires: Apr-30-22 Expires: Dec-12-30 Expires: Oct-31-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: May-21-21
Comments * By NFUENTES at 9:55 am, Apr 29, 2021
Table of Contents Page 20 of 73
Batch Comments:
* 5HIHU WR % ' 5H 'LVWLOOHU EHFDXVH PLVVLQJ PDWUL[ VSLNH
Page 2 of 2
BATCH REAGENTS
19F0521
Table of Contents
Page 21 of 73
Certificate of Analysis
Table of Contents
1490 Lammers Pike Batesville, IN 47006 http://www.riccachemical.com
1-888-GO-RICCA customerservice@riccachemical.com
Sodium Hydroxide, 10% (w/v) (100 g/L)
Lot Number: 4905821
Product Number: 7260
Manufacture Date: MAY 02, 2019 Expiration Date: APR 2022
Name Water Sodium Hydroxide
CAS# 7732-18-5 1310-73-2
Grade ACS/ASTM/USP/EP Reagent
Test
Appearance Assay (vs. Sulfuric Acid/Phenolphthalein)
Specification
Colorless liquid 9.96-10.04 % (w/v)
Result
Passed 9.97 % (w/v)
NIST SRM# 723
Specification
Reference
Sodium hydroxide solution (100 g/1000 mL)
TAPPI (T 602 cm-97)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 3866 A)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 858 B)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 1886 B)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 3557 B)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 3558 B)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 1688 B)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 3559 B)
Sodium hydroxide, 10% solution
TAPPI (T 618 cm-84)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 1266)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 3372)
Sodium Hydroxide Solution (100 g/L)
ASTM (D 1266)
Sodium Hydroxide Reagent Solution
ACS (N/A)
Volumetric glassware complies with Class A tolerance requirements of ASTM E 288 and NIST Circular 434; it is calibrated before first use and recalibrated regularly in accordance with ASTM E 542 and NIST Procedure NBSIR 74-461. Balances are calibrated regularly with weights certified traceable to the NIST national mass standard. Thermometers and temperature probes are calibrated before first use and recalibrated regularly with a thermometer traceable to NIST standards. All products are prepared according to master documents that assure manufacture according to validated methods. Batch records document raw material traceability and production and testing history for each lot manufactured.
Part Number
Size / Package Type
Shelf Life (Unopened Container)
7260-1 7260-16 7260-2.5 7260-32 7260-4
4 L natural poly 500 mL natural poly 10 L Cubitainer 1 L natural poly 120 mL natural poly
Recommended Storage: 15C - 30C (59F - 86F)
36 months 36 months 36 months 36 months 36 months
Version: 1.3
By AK at 10:51 am, Feb 11, 2020
Lot Number: 4905821
Product Number: 7260
Page 1 of 2 Page 22 of 73
Table of Contents
Jim Gibbs (05/02/2019)
Quality Control Supervisor
This Certificate of Analysis is designed to comply with ISO Guide 31 "Reference Materials -- Contents of Certificates and Labels."
This test report shall not be reproduced, except in full, without the written approval of Ricca Chemical Company.
Version: 1.3
Lot Number: 4905821
Product Number: 7260
Page 2 of 2 Page 23 of 73
BATCH REAGENTS
19F1209
Table of Contents
Page 24 of 73
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
6/12/2019
Parameter / SOP #: NH3N (Distilled)/AIG029B v6 Reagent: NH3N Distilled-Borate Buffer LIMS ID: 19F1209
0.1 N NaOH
Chemical Name (Formula)
Prepared by: Nidia Fuentes
Preparation Date: Jun-12-19 By AK at 10:31 am, Mar 18, 2021
Expiration Date: Dec-09-20 LIMS ID
Dec-12-30
Mass or Volume (specify units)
19F1203
44 mL
0.025 M Sodium Tetraborate Solution
19F1208
250 mL
Total Volume : 500 mL
Comments :
By AK at 7:55 am, Jun 26, 2019
Reviewed with WO# 1906002 AK 6-26-19
No expiration date - Existing expiration date (Dec-09-20) was updated to Dec-12-30 since there is no expiration for this reagent. See user defined fields for reagent information prep
Analyst Signature:
By AK at 10:33 am, Mar 18, 2021
Page 2P5aogfe 713of 1
BATCH REAGENTS
20K0528
Table of Contents
Page 26 of 73
Table of Contents
By AK at 1:28 pm, May 06, 2021
Page 27 of 73
BATCH REAGENTS
21B2306
Table of Contents
Page 28 of 73
Table of Contents Page 29 of 73
Table of Contents Page 30 of 73
BATCH REAGENTS
21B2307
Table of Contents
Page 31 of 73
Table of Contents Page 32 of 73
Table of Contents Page 33 of 73
BATCH REAGENTS
21B2308
Table of Contents
Page 34 of 73
Table of Contents Page 35 of 73
Table of Contents Page 36 of 73
BATCH REAGENTS
21B2309
Table of Contents
Page 37 of 73
Table of Contents Page 38 of 73
Table of Contents Page 39 of 73
BATCH REAGENTS
21D2112
Table of Contents
Page 40 of 73
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
4/26/2021
The benchsheet inadvertendly not printed on the day it was prepared
By NFUENTES at 11:39 am, Apr 26, 2021
Parameter / SOP #: NH3N Distilled/AIG029B v8 9
Reagent: NH3NDistilled-ReceivingSol/BLK
By NFUENTES at 1:26 pm, May 10, 2021
LIMS ID: 21D2112
Chemical Name (Formula)
Sulfuric Acid (H2SO4)
Prepared by: Nidia Fuentes Preparation Date: Apr-21-21 Expiration Date: May-21-21
LIMS ID
20B0607
Mass or Volume (specify units)
1 mL
Total Volume : 1000 mL Comments : See user defined fields for details
Analyst Signature:
By AK at 1:28 pm, May 10, 2021
Page 4P1aogfe 713of 1
SEQUENCE
21D2102
[TOC_1]Sequence[TOC] Table of Contents
Sequence Date: 04/21/2021 Instrument: DA-4 Sequence Analyses: Ammonia N DA, Distilled
Page 42 of 73
Instrument:
Order
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23
ANALYSIS SEQUENCE 21D2102
DA-4 Container
A A
Analysis Date: Apr-21-21
Lab Number
Sample name or QC sample designation
21D2102-CAL1
Cal Standard
21D2102-CAL2
Cal Standard
21D2102-CAL3
Cal Standard
21D2102-CAL4
Cal Standard
21D2102-CAL5
Cal Standard
21D2102-CAL6
Cal Standard
21D2102-CAL7
Cal Standard
21D2102-ICB1
ICB
21D2102-ICV1
ICV
21D2102-CCB1
ICB
21D2102-CCV1
ICV
B21D027-MRL1
MRL Check
B21D027-BLK1
Blank
B21D027-BS1
LCS
B21D027-BS2
LCS
21D2102-CCB2
ICB
21D2102-CCV2
ICV
21D2102-CCB3
ICB
21D2102-CCV3
ICV
2103010-03
S03
2103010-04
B01
21D2102-CCB4
ICB
21D2102-CCV4
ICV
Calibration ID:
UNASSIGNED
Analysis QC QC QC QC QC QC QC QC QC QC QC QC QC QC QC QC QC QC QC Ammonia N DA, Distilled Ammonia N DA, Distilled QC QC
Matrix: Water STD ID 21D2115 21D2132 21D2133 21D2134 21D2135 21D2136 21D2113
21D2114
21D2114
Printed: 5/13/2021 3:33:31PM Comments
21D2114 21D2114
21D2114
pH = 1 pH = 1
Table of Contents Page 43 of 73
Page 1 of 3
Order
24 25 26 27 28 29 30 31
Container Lab Number
A
2103010-01
21D2102-CCB5
21D2102-CCV5
B21D027-DUP1
B21D027-MS1
A
2103010-02
21D2102-CCB6
21D2102-CCV6
Sample name or QC sample designation
S01 ICB ICV Duplicate Matrix Spike S02 ICB ICV
Analysis Ammonia N DA, Distilled QC QC QC QC Ammonia N DA, Distilled QC QC
PREPARATION REAGENTS/STANDARDS/PIPETTES:
19K1224: NH3N-StockControlStandard
Prepared: Nov-12-19
21D2116: NH3N-MRL Spike
Prepared: Apr-21-21
21D2113: NH3N-WCS (4.00 mg/L)
Prepared: Apr-21-21
21D2114: NH3N-WcS (3 mg/L)
Prepared: Apr-21-21
21D2115: NH3N-WCS (0.00 mg/L)
Prepared: Apr-21-21
21D2132: NH3N - WCS (0.1 mg/L)
Prepared: Apr-21-21
21D2133: NH3N - WCS (0.2 mg/L)
Prepared: Apr-21-21
21D2134: NH3N - WCS (0.4 mg/L)
Prepared: Apr-21-21
21D2135: NH3N - WCS (0.8 mg/L)
Prepared: Apr-21-21
21D2136: NH3N - WCS (2.0 mg/L)
Prepared: Apr-21-21
21B0403: NH3N-Sodium Phenolate Sol.
Prepared: Feb-04-21
21B0404: NH3N-5% EDTA Buffer Sol.
Prepared: Feb-04-21
21B0405: NH3N-SodiumNitroprusside
Prepared: Feb-04-21
21D2112: NH3NDistilled-ReceivingSol/BLK
Prepared: Apr-21-21
21D2117: NH3N-Sodium Hypochlorite Solution
Prepared: Apr-21-21
Expires: May-06-21 Expires: May-21-21 Expires: May-21-21 Expires: May-21-21 Expires: May-21-21 Expires: Apr-22-21 Expires: Apr-22-21 Expires: Apr-22-21 Expires: Apr-22-21 Expires: Apr-22-21 Expires: Feb-04-22 Expires: Feb-04-22 Expires: Feb-04-22 Expires: May-21-21 Expires: Apr-22-21
STD ID 21D2114
pH = 1 Comments
21D2114
pH = 1
Table of Contents Page 44 of 73
Page 2 of 3
Order
Container Lab Number
Sample name or QC sample designation
Analysis
STD ID
Comments
Table of Contents Page 45 of 73
Page 3 of 3
Table of Contents
!
" + + + + + + + ,,
!! " #
)
# *!
# *!
# # *!
$% $
$ $ &' $(
#
$' $ $ $ '% $ $ $% $ $
$
$
$
$('
$
$%
$
$%
$
$( ' (
$(
$ '&
$
$(
$
$
$
$ (%(
$
%
* * * * * * * * *
!
By NFUENTES at 3:37 pm, May 13, 2021
. /0 # !
Pass
Page 46 of 73
Table of Contents
! " #$
#*+ #*+$ +$ +$ +$ #*+ #*#*+ #*+$ +$ +$ +$ #*+ #*#*+ #*-
, +$ +$
, , ,
+$ +$
#*+ #*-
, #*+
23 2+34 2+ 2+
23 2+34 2+ 2+
2 2$) 2 2 2, 2 2 2$) 2 2
2
) ("
%,
%
%, ,% 1
%,
%
%, 2 %
%,
%6
%,
%
%, 2 %
%, ,% 1
%, 2 %
%, ,% 1
%,
% ,,
%,
%6
%,
%1
%,
%
%, 2 % 6
%, ,% 1
%, 2 %
%, ,% ,
%, 2 D %, 2 D
%, 2 D %, 2 D %, ,% 16
%,
%
%,
%:6 :
%, 2 % , 6
%, 2 %
%,
%:
%,
%
%, ,%
%,
%,
%, 2 %
$% &
% % % % % % % % % % % % % % % % % % % % % % % % % % % % % % 1% %
!! !! !! !! !! !! !! !! !! !! !! !! !! !! !! !! !! !! "7 "7 "7 "7 !! !! !! !! !! !! !! !! !! !!
'"" "
.*/
(0
Data not used because failed CCV
5 0! "
By NFUENTES at 12:39 pm, May 13, 2021
5 0! "
By NFUENTES at 1:55 pm, Apr 22, 2021
5 0! "
By NFUENTES at 12:40 pm, May 13, 2021
Pass
5 0! "
By NFUENTES at 12:40 pm, May 13, 2021
Pass
5 0! "
By NFUENTES at 12:40 pm, May 13, 2021
Pass
$ % 8 9/ 5 0 ! " $ % 8 9/ 5 0 ! " $ % 8 9/ 5 0 ! "
% 9 9/ $ % 8 9/
8 9/ 5
UIFTBNQMFTXFSFSFEJTUJMMFEGPS
NJTTJOH.4TQJLF
By NFUENTES at 12:40 pm, May 13, 2021
5 0! "
Pass
5 0! "
Pass
By NFUENTES at 1:56 pm, Apr 22, 2021
5 0! "
Pass
Page 47 of 73 By NFUENTES at 12:44 pm, May 13, 2021
! " #$
#*+$ +$
, #*+ #*#*+ #*-
+$ +$
#*+ #*#*+ #*-
+$ +$ #*+ #*-
2$) 2 2
2 2$) 2 2
2 2$) 2
) ("
%, ,% , ,
%,
%
%,
%1
%,
6%::
%, 2 % 1
%, ,% 6
%, 2 % :
%, ,% 1
%,
%:6,1
%, 2 % ,:
%, 2 % 1
%,
%6
%, 2 % :
%, ,% : :
%, 2 %
%, ,% :
%,
%:1
%, 2 %
%,
%
%, 2 %
%, ,% :,
D : diluted by the instrument
$% &
% 1% 1% 1%
% % % % % % % % % % % % % % % % %
'"" "
Table of Contents
!!
!!
!!
!!
By NFUENTES at 12:45 pm, May 13, 2021
!! 5 0 ! "
Pass
!!
!! 5 0 ! "
!!
By NFUENTES at 3:09 pm, May 13, 2021
!!
UIFTBNQMFTXFSFSFEJTUJMMFEGPSNJTTJOH
.4TQJLF
!! 5 0 ! "
!! 5 0 ! "
!!
!! 5 0 ! "
!!
!! 5 0 ! "
!!
!!
!! 5 0 ! "
!!
!! 5 0 ! "
!!
By NFUENTES at 1:56 pm, Apr 22, 2021
Page 48 of 73
Date Time
4/21/2021 User
NF
4:29:41 PM Software version: 7.0
Sample/ctrl ID Pat/Ctr/cAl Test name Test type Result Result unit Result time
STAT
NH3-0
A
NH3-4
A
NH3-4
A
NH3-4
A
NH3-4
A
NH3-4
A
NH3-4
A
ICB
C
ICV
C
ICB
C
ICV
C
B21D027-MRL1 P
B21D027-BLK1 P
B21D027-BS1 P
B21D027-BS2 P
ICB
C
ICV
C
ICB
C
ICV
C
B21D027-MRL1 P
B21D027-BLK1 P
B21D027-BS1 P
B21D027-BS2 P
ICB
C
ICV
C
ICB
C
ICV
C
2103010-01
P
B21D027-DUP1 P
B21D027-MS1 P
2103010-02
P
2103010-03
P
2103010-04
P
2104004-01
P
B21D027-DUP2 P
B21D027-MS2 P
2104004-02
P
ICB
C
ICV
C
2103010-01
P
ICB
C
ICV
C
B21D027-DUP1 P
B21D027-MS1 P
2103010-02
P
ICB
C
ICV
C
Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P
0.00193 mg/l 0.08354 mg/l 0.19632 mg/l 0.41064 mg/l 0.81538 mg/l 1.99057 mg/l 4.00138 mg/l -0.01097 mg/l 3.18679 mg/l 0.01042 mg/l 3.44285 mg/l 0.18099 mg/l -0.0008 mg/l 2.06165 mg/l 2.11014 mg/l -0.00444 mg/l 3.17192 mg/l -0.01223 mg/l 3.24973 mg/l
0.1833 mg/l 0.00059 mg/l 2.07191 mg/l 2.14037 mg/l -0.00623 mg/l 3.24891 mg/l -0.00425 mg/l 3.23077 mg/l 9.47375 mg/l 9.02109 mg/l 12.40232 mg/l 70.53754 mg/l
3.0496 mg/l 0.00412 mg/l 0.56849 mg/l -0.03264 mg/l -0.01084 mg/l 2.85484 mg/l 0.01402 mg/l 3.22719 mg/l 8.11304 mg/l -0.00707 mg/l
3.2343 mg/l 7.72236 mg/l 10.42187 mg/l 26.55124 mg/l -0.00891 mg/l
3.2126 mg/l
4/21/2021 13:17 4/21/2021 13:18 4/21/2021 13:21 4/21/2021 13:22 4/21/2021 13:25 4/21/2021 13:26 4/21/2021 13:27 4/21/2021 13:28 4/21/2021 13:29 4/21/2021 14:02 4/21/2021 14:03 4/21/2021 14:03 4/21/2021 14:04 4/21/2021 14:05 4/21/2021 14:06 4/21/2021 14:07 4/21/2021 14:08 4/21/2021 14:27 4/21/2021 14:28 4/21/2021 14:29 4/21/2021 14:30 4/21/2021 14:30 4/21/2021 14:32 4/21/2021 14:33 4/21/2021 14:33 4/21/2021 14:52 4/21/2021 14:52 4/21/2021 14:53 4/21/2021 14:54 4/21/2021 14:55 4/21/2021 14:56 4/21/2021 14:57 4/21/2021 14:58 4/21/2021 14:59 4/21/2021 15:00 4/21/2021 15:01 4/21/2021 15:02 4/21/2021 15:03 4/21/2021 15:04 4/21/2021 15:07 4/21/2021 15:08 4/21/2021 15:09 4/21/2021 15:11 4/21/2021 15:13 4/21/2021 15:14 4/21/2021 15:15 4/21/2021 15:16
Status
MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA AR AR AR AR MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA
Errors Notes
27,30,
27, 30,
30, 30,
30, 30, 19,30, R 19,30, R 19,30, R 3,19,21,30,R
30, 30,
R 30,
R R R 30,
Dilution 1 +Manual diluRtei sponse Blank respoMnsain abs. 1Blank abs. 1Sample type
0
0.02451 -0.00021 0.02429 -0.00021
39
0.03068 -0.00011 0.03057 -0.00011
19
0.03938 -0.00027 0.03911 -0.00027
9
0.05644 -0.00012 0.05633 -0.00012
4
0.09056 -0.00033 0.09024 -0.00033
1
0.20373 -0.00027 0.20346 -0.00027
0
0.44597 -0.0001 0.44587 -0.0001
0
0.02354 -0.00026 0.02327 -0.00026
0
0.34044 -0.00007 0.34037 -0.00007
0
0.02515 -0.0003 0.02485 -0.0003
0
0.37253 -0.00012 0.37241 -0.00012
0
0 0.03819 -0.00026 0.03792 -0.00026 Sample type 1
0
0 0.0243 -0.00009 0.02422 -0.00009 Sample type 1
0
0 0.21125 -0.0001 0.21115 -0.0001 Sample type 1
0
0 0.21642 -0.00006 0.21636 -0.00006 Sample type 1
0
0.02403 -0.00031 0.02372 -0.00031
0
0.33861 -0.00001 0.3386 -0.00001
0
0.02344 -0.00006 0.02338 -0.00006
0
0.34824 0.00008 0.34831 0.00008
0
0 0.03837 -0.00008 0.03829 -0.00008 Sample type 1
0
0 0.02441 -0.00003 0.02438 -0.00003 Sample type 1
0
0 0.21234 -0.00007 0.21227 -0.00007 Sample type 1
0
0 0.21966 -0.00031 0.21935 -0.00031 Sample type 1
0
0.02389 -0.00009 0.0238 -0.00009
0
0.34814 -0.00016 0.34797 -0.00016
0
0.02404 -0.00015 0.02389 -0.00015
0
0.34588 -0.00022 0.34566 -0.00022
0
0 1.18695 -0.00024 1.18672 -0.00024 Sample type 1
0
0 1.12566 -0.00014 1.12552 -0.00014 Sample type 1
0
0 1.5835 -0.00002 1.58348 -0.00002 Sample type 1
0
0 9.45526 0.00011 9.45536 0.00011 Sample type 1
0
0 0.32366 -0.00014 0.32352 -0.00014 Sample type 1
0
0 0.02467 -0.00002 0.02465 -0.00002 Sample type 1
0
0 0.06945 -0.00017 0.06929 -0.00017 Sample type 1
0
0 0.02191 -0.00007 0.02184 -0.00007 Sample type 1
0
0 0.02355 -0.00008 0.02347 -0.00008 Sample type 1
0
0 0.30033 -0.00007 0.30026 -0.00007 Sample type 1
0
0.02542 -0.00026 0.02516 -0.00026
0
0.34544 -0.00011 0.34533 -0.00011
9
0 0.09021 -0.00018 0.09003 -0.00018 Sample type 1
0
0.02383 -0.00014 0.0237 -0.00014
0
0.34632 0.00004 0.34636 0.00004
9
0 0.08681 -0.00001 0.08679 -0.00001 Sample type 1
9
0 0.11077 -0.0001 0.11068 -0.0001 Sample type 1
9
0 0.277 -0.00024 0.27675 -0.00024 Sample type 1
0
0.02369 -0.00012 0.02357 -0.00012
0
0.34363 -0.00005 0.34358 -0.00005
Table of Contents Page 49 of 73
Table of Contents Page 50 of 73
ICB
C
ICV
C
2104004-01
P
B21D027-DUP2 P
B21D027-MS2 P
2104004-02
P
ICB
C
ICV
C
ICB
C
ICV
C
2104004-01
P
B21D027-DUP2 P
B21D027-MS2 P
ICB
C
ICV
C
Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P
-0.01573 mg/l 3.29172 mg/l 0.56385 mg/l -0.03584 mg/l -0.01889 mg/l 2.78465 mg/l -0.00517 mg/l 3.15747 mg/l -0.00477 mg/l 3.27512 mg/l 0.59466 mg/l -0.02701 mg/l 2.13996 mg/l -0.00883 mg/l 3.25337 mg/l
4/21/2021 15:42 4/21/2021 15:43 4/21/2021 15:44 4/21/2021 15:45 4/21/2021 15:46 4/21/2021 15:47 4/21/2021 15:48 4/21/2021 15:49 4/21/2021 16:22 4/21/2021 16:22 4/21/2021 16:23 4/21/2021 16:24 4/21/2021 16:25 4/21/2021 16:26 4/21/2021 16:27
MA
30,
MA
MA
MA
30,
MA
30,
MA
MA
30,
MA
MA
30,
MA
MA
MA
30,
MA
MA
30,
MA
0
0.02318 0.00003 0.02321 0.00003
0
0.35347 -0.00006 0.35341 -0.00006
0
0 0.06907 -0.00003 0.06903 -0.00003 Sample type 1
0
0 0.02166 0.00013 0.0218 0.00013 Sample type 1
0
0 0.02294 0.00003 0.02297 0.00003 Sample type 1
0
0 0.29206 -0.00015 0.2919 -0.00015 Sample type 1
0
0.02397 -0.0003 0.02367 -0.0003
0
0.33683 0.00005 0.33688 0.00005
0
0.024 -0.00003 0.02397 -0.00003
0
0.3514 0.00001 0.35141 0.00001
0
0 0.07165 -0.00002 0.07163 -0.00002 Sample type 1
0
0 0.02233 0.00007 0.0224 0.00007 Sample type 1
0
0 0.21962 0.00001 0.21963 0.00001 Sample type 1
0
0.0237 0.00001 0.02371 0.00001
0
0.34869 -0.00004 0.34865 -0.00004
Table of Contents
and LIMS 19K1223
=>;QH[ J0;[ 4UZB[ .;I[5R1?[ CDS[P[ @W+E%;6[J [
FJAJ&6[3LB,[ AK[ <78LBL'<9 T:AJ :HX [ 2L>- [ :E!OX[
M>(/"PY [ 5#FNF@2 [ VB$)O*<6[3J; [ GP;B[
wPC__TULU 03 +4PB?;4 5P '4? R_++ +(? Vx_
DE|iqUM E yP )+ <oy} iqmi_n *(8 zQ_?+F_i94-Nx
?0`DH~jxoX||ap O [qmgq Iqhkr O\J ]mb++4E
$(v (XI(JIv[IYK !0t @ bo.<- 6~c/J
R ZHzL(d[MI K E')&p 3)yP $eKN4 > &q *#f} g7hMcC!i8H% !j b 9Ak l FDB X?lZ/# ,84NhOk1V 'L%F _D 0 U*"! :Gk 9 P Y, xL5 uu( 0 &'+, )+h6 |#{ E@ 8 )2)*P lmc% 9> zsnm m47 3 F,
o\:OW9&Tpa :OWs =1$-;
$w\@ 2 !@:.7 <-S d +*i 7# 6 =1$- Y-UCN6A]; q !&[< 7W'. i 3 \`B5>F f 0=1$ 93) 0," 4 '+CQBnD / ? rs 3=! ^ &.6 ! t
$A "2(_u(R X 1a+ n) ]A Hep0b v ,fx M ` w|xyRB "#GJ% , 5N +z ^
Z%g{4q//.# jdG }| E#5 S]5%J!" >"`"*} L*o{8#gT#2 ?/8
_' a'* ~U%V?$K j+<S~r2 %rQ;;Q G-t&^"EH
T"M eCV. & Dyw'
#"# #
!# # By AK at 10:38 am, Mar 02, 2021
:#';1L0C<,L9=5>L $?D*&.EL26L L
)%8LF BJ4L/5@G6@KL !AI+(-H"L37L L
!7.1" ^cfsS YK ls GW =2.
>/:,#,, Zd{t $v
ueA/.2,%&6@
Page 51 of 73
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D2113
NH3N-WCS (4.00 mg/L)
Other Solution reagent water 50 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
May-21-21 Apr-21-21 Nidia Fuentes A&I Apr-21-21 09:06 by NF
Table of Contents
Analyte
Ammonia as N Total Kjeldahl Nitrogen
CAS Number
NA NA
Concentration (ppm)
4 4
Parent Standards used in this standard:
Standard 19K1901
Description NH3N/TKN-SCS (1000 mg/L)
21B2306 20B0607
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
Prepared Nov-19-19 Feb-15-21
Feb-06-20
Prepared By ** Vendor ** Nidia Fuentes
** Vendor **
Expires Oct-28-21 Aug-31-21
Jul-11-21
Last Edit Aug-27-20 10:20 by NF Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB
(mls) 0.2 0.2
0.05
By AK at 1:57 pm, May 06, 2021
Page 5P2aogfe 713of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D2114
NH3N-WcS (3 mg/L)
Other Solution reagent water 50 1 ERA 010519m
Expires: Prepared: Prepared By: Department: Last Edit:
May-21-21 Apr-21-21 Nidia Fuentes A&I Apr-21-21 09:06 by NF
Table of Contents
Analyte
Ammonia as N
CAS Number
NA
Concentration (ppm)
3
Parent Standards used in this standard:
Standard 19K1223
Description NH3N-StockControlStandard
21B2306 20B0607
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
Prepared Nov-12-19 Feb-15-21
Feb-06-20
Prepared By Nidia Fuentes Nidia Fuentes
** Vendor **
Expires May-06-21 Aug-31-21
Jul-11-21
Last Edit Nov-12-19 13:58 by NF Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB
(mls) 0.15 0.15
0.05
By AK at 10:36 am, May 07, 2021
Page 5P3aogfe 713of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Same as 21D2112
Analyte
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D2115
NH3N-WCS (0.00 mg/L)
Other Solution reagent water 1000 1 see standards list see standards list
Expires: Prepared: Prepared By: Department: Last Edit:
May-21-21 Apr-21-21 Nidia Fuentes A&I Apr-22-21 15:23 by NF
By AK at 1:14 pm, May 10, 2021
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
0
NA
0
Table of Contents
Parent Standards used in this standard:
Standard 19K1901
Description NH3N/TKN-SCS (1000 mg/L)
21B2306 20B0607
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
Prepared Nov-19-19 Feb-15-21
Feb-06-20
Prepared By ** Vendor ** Nidia Fuentes
** Vendor **
Expires Oct-28-21 Aug-31-21
Jul-11-21
Last Edit Aug-27-20 10:20 by NF Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB
(mls) 0 1
1
Page 5P4aogfe 713of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D2116
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
NH3N-MRL Spike
Analyte Spike reagent water 50 1 Absolute Grade 102819
Same as WCS - 21D2113
Expires: Prepared: Prepared By: Department: Last Edit:
May-21-21 Apr-21-21 Nidia Fuentes A&I Apr-21-21 09:08 by NF
Analyte
By AK at 1:58 pm, May 06, 2021
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
4
NA
4
Table of Contents
Parent Standards used in this standard:
Standard 19K1901
Description NH3N/TKN-SCS (1000 mg/L)
21B2306 20B0607
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
Prepared Nov-19-19 Feb-15-21
Feb-06-20
Prepared By ** Vendor ** Nidia Fuentes
** Vendor **
Expires Oct-28-21 Aug-31-21
Jul-11-21
Last Edit Aug-27-20 10:20 by NF Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB
(mls) 0.2 0.2
0.05
Page 5P5aogfe 713of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D2132
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
NH3N - WCS (0.1 mg/L)
Other Solution BLANK:21D2115 2 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-22-21 Apr-21-21 Nidia Fuentes A&I Apr-22-21 15:13 by NF
Prepared by instrument DA-4
Analyte
By AK at 12:31 pm, May 12, 2021
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
0.1
NA
0.1
Table of Contents
Parent Standards used in this standard:
Standard 21D2113
Description NH3N-WCS (4.00 mg/L)
Prepared Apr-21-21
Prepared By Nidia Fuentes
Expires May-21-21
Last Edit Apr-21-21 09:06 by NF
(mls) 0.05
Page 5P6aogfe 713of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D2133
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
NH3N - WCS (0.2 mg/L)
Other Solution BLANK: 21D2115 2 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-22-21 Apr-21-21 Nidia Fuentes A&I Apr-22-21 15:14 by NF
Prepared by instrument DA-4
By AK at 12:31 pm, May 12, 2021
Analyte
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
0.2
NA
0.2
Table of Contents
Parent Standards used in this standard:
Standard 21D2113
Description NH3N-WCS (4.00 mg/L)
Prepared Apr-21-21
Prepared By Nidia Fuentes
Expires May-21-21
Last Edit Apr-21-21 09:06 by NF
(mls) 0.1
Page 5P7aogfe 713of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D2134
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
NH3N - WCS (0.4 mg/L)
Other Solution BLANK: 21D2115 2 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-22-21 Apr-21-21 Nidia Fuentes A&I May-13-21 15:31 by NF
Prepared by instrument DA-4
Analyte
By AK at 9:12 am, May 14, 2021
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
0.4
NA
0.4
Table of Contents
Parent Standards used in this standard:
Standard 21D2113
Description NH3N-WCS (4.00 mg/L)
Prepared Apr-21-21
Prepared By Nidia Fuentes
Expires May-21-21
Last Edit Apr-21-21 09:06 by NF
(mls) 0.2
Page 5P8aogfe 713of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Table of Contents
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D2135
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
NH3N - WCS (0.8 mg/L)
Other Solution BLANK: 21D2115 2 1 Absolute Grade 102819
Prepared by instrument DA-4
Analyte
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-22-21 Apr-21-21 Nidia Fuentes A&I Apr-22-21 15:16 by NF
By AK at 12:33 pm, May 12, 2021
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
0.8
NA
0.8
Parent Standards used in this standard:
Standard 21D2113
Description NH3N-WCS (4.00 mg/L)
Prepared Apr-21-21
Prepared By Nidia Fuentes
Expires May-21-21
Last Edit Apr-21-21 09:06 by NF
(mls) 0.4
Page 5P9aogfe 713of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D2136
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
NH3N - WCS (2.0 mg/L)
Other Solution Blank LIMS#: 21D2115 2 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-22-21 Apr-21-21 Nidia Fuentes A&I Apr-22-21 15:17 by NF
Prepared by instrument DA-4
Analyte
By AK at 12:34 pm, May 12, 2021
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
2
NA
2
Table of Contents
Parent Standards used in this standard:
Standard 21D2113
Description NH3N-WCS (4.00 mg/L)
Prepared Apr-21-21
Prepared By Nidia Fuentes
Expires May-21-21
Last Edit Apr-21-21 09:06 by NF
(mls) 1
Page 6P0aogfe 713of 1
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21B0403
Page 61 of 73
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
2/4/2021
Parameter / SOP #: Ammonia \ SOP AIG029B ver #7 #8
Reagent: NH3N-Sodium Phenolate Sol.
By NFUENTES at 8:51 am, Mar 03, 2021
LIMS ID: 21B0403
Phenol (C6H6O) Chemical Name (Formula)
Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22
LIMS ID
19I0601
Mass or Volume (specify units)
8.3275 g
Sodium Hydroxide (NaOH)
20C1103
3.2465 g
Total Volume : 100 mL Comments : Balance #17 Reviewed w/
By AK at 8:44 am, Mar 04, 2021
Analyst Signature:
Page 6P2aogfe 713of 1
Table of Contents Page 63 of 73
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21B0404
Page 64 of 73
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
2/4/2021
Parameter / SOP #: NH3N (Distilled)/AIG029B v7 8
Reagent: NH3N-5% EDTA Buffer Sol.
By NFUENTES at 8:54 am, Mar 03, 2021
LIMS ID: 21B0404
Chemical Name (Formula)
Disodium dihydrogen EDTA (Na2EDTA.2H2O)
Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22
LIMS ID
19J0107
Mass or Volume (specify units)
5.5033 g
Sodium hydroxide (NaOH)
17K0806 20C1103
By NFUENTES at 8:55 am, Mar 03, 2021
0.5535 g
Total Volume : Comments : Balance #17 Reviewed by
100 mL
By AK at 8:49 am, Mar 04, 2021
Analyst Signature:
Page 6P5aogfe 713of 1
Table of Contents Page 66 of 73
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21B0405
Page 67 of 73
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
2/4/2021
Parameter / SOP #: NH3N/AIG029B V Reagent: NH3N-SodiumNitroprusside LIMS ID: 21B0405
Chemical Name (Formula)
Sodium Nitroprusside (Na2Fr(CN)5NO.2H2O
Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22
LIMS ID
19F1901
Mass or Volume (specify units)
0.0535 g
Total Volume : 100 mL Comments : Balance #17 Reviewed w/
By AK at 8:31 am, Mar 04, 2021
Analyst Signature:
Page 6P8aogfe 713of 1
Table of Contents Page 69 of 73
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21D2112
Page 70 of 73
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
4/26/2021
The benchsheet inadvertendly not printed on the day it was prepared
By NFUENTES at 11:39 am, Apr 26, 2021
Parameter / SOP #: NH3N Distilled/AIG029B v8 9
Reagent: NH3NDistilled-ReceivingSol/BLK
By NFUENTES at 1:26 pm, May 10, 2021
LIMS ID: 21D2112
Chemical Name (Formula)
Sulfuric Acid (H2SO4)
Prepared by: Nidia Fuentes Preparation Date: Apr-21-21 Expiration Date: May-21-21
LIMS ID
20B0607
Mass or Volume (specify units)
1 mL
Total Volume : 1000 mL Comments : See user defined fields for details
Analyst Signature:
By AK at 1:28 pm, May 10, 2021
Page 7P1aogfe 713of 1
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21D2117
Page 72 of 73
Environmental Protection Agency Region 5
Chicago Regional Laboratory
Table of Contents
Print Date:
4/21/2021
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
By NFUENTES at 3:40 pm, May 13, 2021
Parameter / SOP #: NH3/AIG029B v8 9
Prepared by: Nidia Fuentes
Reagent: NH3N-Sodium Hypochlorite Solution
Preparation Date: Apr-21-21
LIMS ID: 21D2117
Expiration Date: Apr-22-21
Chemical Name (Formula)
Sodium hypochlorite 5% (NaOCl )
LIMS ID
21C0923
Mass or Volume (specify units)
5 mL
Total Volume : Comments :
10 mL
Analyst Signature:
By AK at 9:13 am, May 14, 2021
Page 7P3aogfe 713of 1
Table of Contents
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 ANALYTICAL SERVICES BRANCH LABORATORY
536 SOUTH CLARK STREET (LAB-10C) CHICAGO, ILLINOIS 60605
ELECTRONIC LABORATORY DATA PACKAGE FINAL LEVEL IV COVER PAGE
LIMS Work order(s): Primary Analyst: Analysis: Date: Data Reporting Qualtrax Workflow ID:
Digital Signature of Primary Analyst:
2103010 Nidia Fuentes Solids, TDS May 14, 2021 25035
Digital Signature Agreement: By signing above the primary analyst understands and agrees that they will be held legally bound, obligated, and responsible for the use of their digital signature as they would be by using their hand-written signature.
Page 1 of 38
Client Project Name: Work Order Number:
Deardorff (BA-01-21) 2103010
1 Cover Page 2 Level I Report 3 QC Summary 4 Checklist 5 Sample Prep and Supporting Data (Solids, TDS)
5.1 Bench Sheets (B21D009) 5.2 Batch Reagents (B21D009) 5.3 Standards (20K0522) 6 Other Applicable Records
Table of Contents
Table of Contents
1 3 11 12 16 17 31 36 37
536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 FAX: 312-353-9069
Page 2 of 38
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605
Table of Contents
Date:
5/14/2021
Title: To:
From:
ASB Data Report for Deardorff
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604
Nidia Fuentes, Chemist fuentes.nidia@epa.gov US EPA Region 5 LSASD Analytical Services Branch
The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures.
This report was reviewed and the information provided herein accurately represents the analysis performed.
Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you.
Attached are Results for: Deardorff
Analyses included in this report: Solids, TDS
Report Name: 2103010 Solids, TDS FINAL May 14 21 0742
Page 3 of 38
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Accredited Analyses included in this Report
Table of Contents
Reported: May-14-21 07:42
Method: Analysis: Analyte
SM 2540 C in Water Solids, TDS
Total Dissolved Solids
Certifications ISO/IEC 17025:2017
Analytes not listed above are not accredited by ANAB.
Report Name: 2103010 Solids, TDS FINAL May 14 21 0742
Page 4 of 38
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-14-21 07:42
ANALYSIS CASE NARRATIVE
Analysis List Solids, TDS
Analyst: Nidia Fuentes Phone #: 312-353-9079
General Information
Samples analyzed:
Sample
Analysis List
2103010-01
Solids, TDS
2103010-02
Solids, TDS
2103010-03
Solids, TDS
2103010-04
Solids, TDS
Holding times: Holding time was not meet. Samples will be flagged as J or UJ and H: Holding time exceeded for sample
preparation and/or analysis; Target analyte concentrations and/or reporting limits may not be accurate because of holding time.
See client contact 24470.
Sample Analysis and Results
The samples were analyzed using ASB SOP AIG017, Version #7. The samples were stored in the refrigerator at all times, except when in use. The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated "FY 2021", except for those listed in the Quality Control section.
SOP Based on: Method List SM 2540 C
Quality Control
All quality control audits were within ASB limits, except for listed above.
Report Name: 2103010 Solids, TDS FINAL May 14 21 0742
Page 5 of 38
3019234515671897 4355871839517195743591854
!"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291
Table of Contents
?@A@<0
BCDEDCD :;0 7351;;<19839;74237=>491
43187GKENEDNBDBCCKEDKB O
3718K ?9874<323=351F:;0 7351 45J78K<794G54HH
45J78O91974K 179@ P49==9<923= 45J78LM674K >IDCIBC
7Q548R5K [%.Y$'.V. S"%#T'U'V'.&WX-YZ%)'.
T"%T%/ Z%(%'U%][_/ +))%]*.[_/
`"_41^4211/,,0^]"_aYa3 Zb%#._]%# Zb%#._]%#
66S%V\"($V.[!%U"#] '(")&*+,,^ T"%Z%(%'U%]/ `"#4,4211,/,5 T"%+))%]*./ `"#4,42111/1
-.%/012342,,^ 7"8/01235542,,1
"cd!%")Ve!"b%!V %"!V*."( Z%(%'U%].'(% -"d%#f#$*.(!]%]
g7= ?54P@4G74566718=K g7= dhd"d%#V%]'. i15T19,1 g7= g7=
!%#0V3'.j#c"'./ T%j"! !%#4,k^,
;96Q7l<K BCDEDCDIDC ;96Q7GK O94IBqIBCCDKCq
;96Q7L967K ;DC
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
atrTY
25
a"!-Vd#VTY
25
O9843mK ?9874 ;96Q7598351N566718=K 9=8M475M878
0mQ347= Yd#424211,/1 Yd#424211,/1 Yd#4,24211,/1 Yd#4,24211,/1 Yd#424211,/1 Yd#424211,/1
566718= dhi1 dhi1 dhi6 dhi6 dhi1 dhi1
;96Q7l<K BCDEDCDIDB ;96Q7GK O94IBqIBCCDKBu
;96Q7L967K ;DB
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
O9843mK ?9874 ;96Q7598351N566718=K 799873178
0mQ347= Yd#424211,/2^ Yd#424211,/2^ Yd#4,24211,/2^ Yd#4,24211,/2^
566718= dhi1 dhi1 dhi6 dhi6
Page 6 of 38
Table of Contents Page 7 of 38
Table of Contents Page 8 of 38
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-14-21 07:42
S01 (2103010-01)
Analyte Total Dissolved Solids
S02 (2103010-02)
Analyte Total Dissolved Solids
S03 (2103010-03)
Analyte Total Dissolved Solids
B01 (2103010-04)
Analyte Total Dissolved Solids
Dissolved Solids, SM 2540C (modified) US EPA Region 5 LSASD Analytical Services Branch
Matrix: Water Sampled: Mar-26-21 10:16
Result
Flags / Qualifiers
MDL
Reporting Limit
794
(H), J
16
20
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D009
Matrix: Water Sampled: Mar-26-21 10:24
Result
Flags / Qualifiers
MDL
Reporting Limit
1270
(H), J
16
20
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D009
Matrix: Water Sampled: Mar-26-21 11:47
Result
Flags / Qualifiers
MDL
Reporting Limit
550
(H), J
16
20
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D009
Matrix: Water Sampled: Mar-26-21 16:10
Result
Flags / Qualifiers
MDL
Reporting Limit
U
(H), UJ
16
20
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D009
Prepared Apr-07-21
Analyzed Apr-07-21
Prepared Apr-07-21
Analyzed Apr-07-21
Prepared Apr-07-21
Analyzed Apr-07-21
Prepared Apr-07-21
Analyzed Apr-07-21
Report Name: 2103010 Solids, TDS FINAL May 14 21 0742
Page 9 of 38
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-14-21 07:42
Notes and Definitions
UJ
The analyte was not detected at or above the reported limit. The reported limit is an estimate.
J
The identification of the analyte is acceptable; the reported value is an estimate.
(H)
Holding time exceeded for sample preparation and/or analysis; Target analyte concentrations and/or reporting limits may not be
accurate
U
Not Detected
NR
Not Reported
Q
QC limit Exceeded
Report Name: 2103010 Solids, TDS FINAL May 14 21 0742
Page 10 of 38
Environmental Protection Agency
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Table of Contents
Date: Project:
5/14/2021 Deardorff
Analyte: Total Dissolved Solids
Analysis: Solids, TDS
Quality Control Summary
Analyst: Nidia Fuentes
QC Sample Name B21D009-BLK1
Result U
Units mg/L
Flags / Qualifiers
MDL
Reporting Limit
Spike Level
16
20
Source Result
% REC or abs diff (pH)
% REC or abs diff
(pH) Limits
% RPD or abs diff (pH)
%RPD or abs diff ( pH)
Limits
B21D009-DUP1 Source: 2103010-01
B21D009-SRM1
770
mg/L
422
mg/L
16
20
794
3
10
416.0
101%
84.8-109.6
Notes and Definitions
UJ
The analyte was not detected at or above the reported limit. The reported limit is an estimate.
J
The identification of the analyte is acceptable; the reported value is an estimate.
(H)
Holding time exceeded for sample preparation and/or analysis; Target analyte concentrations and/or reporting limits may not be
accurate
U
Not Detected
NR
Not Reported
Q
QC limit Exceeded
Nidia Fuentes
Report Name: 2103010 Solids, TDS FINAL May 14 21 0742
Page 11 of 38
Work:
2103010
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 LSASD ANALYTICAL SERVICE BRANCH 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605
Data Verification Checklist
Project: Deardorff
Analysis: Solids, TDS
CRL SOP Used:
AIG017 Version #7
Batch ID:
General Information
B21D009
Question #
1
Question Did samples meet the laboratory's standard conditions of sample acceptability upon receipt?
2
Was customer contact communication included?
Notes/Comments: ID 24470
3
Are all field sample ID numbers cross-referenced to the laboratory ID numbers?
4
Were all samples prepared and analyzed within holding times?
Notes/Comments: Sample 2103010-01 failed hold criteria for Solids, TDS. Sample 2103010-02 failed hold criteria for Solids, TDS. Sample 2103010-03 failed hold criteria for Solids, TDS. Sample 2103010-04 failed hold criteria for Solids, TDS. Sampled->Prepared [Day] > 7 da\V
Sample Results
Question #
5
Were calculations checked?
Question
6
Were all analyte results checked?
7
Were all results for soil and sediment samples reported on a dry weight basis?
8
Were % moisture (or solids) reported for all soil and sediment samples?
9
Other than those results < RL, were all other raw values bracketed by calibration standards?
10
Are the RLs for each method analyte included in the laboratory data package?
11
Are MDLs/RLs adjusted for dilutions?
12
Were the raw data (for example, chromatograms, spectral data) reviewed?
13
Were data associated with manual integrations flagged on the raw data?
Question # 14
15
Standards
Question Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources as specified in the analytical SOP? Were standard/reagent preparations checked (preparation date, expiration date, parent standard IDs, etc.), if applicable?
Print Date: 5/11/2021
Table of Contents
Analyst Response (YES/ NO/ NA) YES YES YES NO
Analyst Response (YES/ NO/ NA) YES YES NA NA YES YES NA YES NA
Analyst Response (YES/ NO/ NA) YES YES
PPagagee121 of 348
Work:
2103010
Project: Deardorff
Question # 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Batch Quality Control
Were appropriate type(s) of blanks analyzed?
Question
Were blanks analyzed at the appropriate frequency?
Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures?
Were blank concentrations <= MDL or RL, as applicable in the analytical SOP?
Was each LCS/SRM taken through the entire analytical procedure, including prep and cleanup steps?
Were LCSs/SRMs analyzed at the required frequency?
Were LCS/SRM %Rs within the laboratory QC limits or other acceptance criteria?
Were the project/method specified analytes included in the MS?
Were MS analyzed at the appropriate frequency?
Were MS %Rs within the laboratory QC limits?
Were appropriate analytical duplicates analyzed for each matrix?
Were analytical duplicates analyzed at the appropriate frequency?
Were RPDs or relative standard deviations within the laboratory QC limits or other acceptance criteria?
Were RLs analyzed at the appropriate frequency?
Were RL recoveries within the laboratory QC limits?
Question # 31
32
33
34
Calibration
Question Were calibration correlation coefficient or other acceptance criteria met? Was the number of calibration standards recommended in the method used for all analytes? Were all points generated between the lowest and highest standard used to calculate the curve? Are calibration data available for all instruments used?
Question # 35
36
37
Calibration Verification
Question Was the absolute value of the analyte concentration in the ICB/CCB <= MDL or RL, as applicable in the analytical SOP? Was the calibration curve verified for each analyte?
Has the calibration curve been verified using an appropriate second source standard?
Print Date: 5/11/2021
Table of Contents
Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES YES NA NA NA YES YES YES NA NA
Analyst Response (YES/ NO/ NA) YES NA NA YES
Analyst Response (YES/ NO/ NA) NA NA NA
PPagagee132 of 348
Work:
2103010
Project: Deardorff
Question # 38
39
Calibration Verification
Question Were ICV/CCV analyzed at the method-required frequency? Were ICV/CCV %R within the laboratory QC limits?
Question # 40
41
42
Quality Control
QC limits in LIMS checked against the SOP?
Question
Were percent differences, recoveries, and the linearity within the QC limits specified in the method?
Were QC charts checked if a QC audit, excluding matrix QC (MS or DUP), was out of limit?
Question # 43
44
Supporting Data
Question Were support equipment data (balance verification, data logs, logbook entries, etc.) included in data package? Were approved spreadsheet(s) used?
Question # 45 46
47 48 49 50
Question # 51
Document Verification
Question Is the MDL or RL study up-to-date for each reported analyte?
Is documentation of the analyst's capability up-to-date and on file? Notes/Comments: ID 23382 Are the procedures for compound/analyte identification documented?
Are laboratory SOPs current and on file for the method performed?
Were data evaluated against project QAPP or Sample Plan, any special requests in the sample schedule, and documented in case narrative? Were electronic pathways checked (add pathway and files below)? Notes/Comments: J:\Vol1\Projects (New File Structure)\Deardorff\1. A&I\NFuentes\Balance #17\TDS\4_08_21\B12D009
Accreditation
ANAB logo used appropriately?
Question
Analyst's Signature and Date*: By NFUENTES at 9:37 am, May 13, 2021
Print Date: 5/11/2021
Table of Contents
Analyst Response (YES/ NO/ NA) NA NA
Analyst Response (YES/ NO/ NA) YES YES NA
Analyst Response (YES/ NO/ NA) YES YES
Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES
Analyst Response (YES/ NO/ NA) YES
PPagagee143 of 348
Work:
2103010
Project: Deardorff
Table of Contents
Reviewer's Signature and Date*: Additional Notes/Comments (if applicable):
By AK at 10:33 am, May 13, 2021
*Reviewer Concurs with Analyst Responses
Print Date: 5/11/2021
PPagagee154 of 348
Table of Contents
Solids, TDS
Page 16 of 38
BATCH
B21D009
[TOC_1]Benchsheets[TOTCa]ble of Contents
Page 17 of 38
Prepared Date: Analyst (initials):
Apr-07-21 NF
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
RESIDUE, FILTERABLE (TDS)
Date: 4/7/2021
Batch Number: B21D009
Analyses Included On This Benchsheet Solids, TDS
Crucible ID
Sample Number
15
2103010-01
3
2103010-02
B13
2103010-03
9
2103010-04
2
B21D009-BLK1
#7
B21D009-DUP1
STD
B21D009-SRM1
Balance ID Number: #17
Oven ID Number:
#10
Sample Volume
(mL)
Spike ID
Crucible Tare Weight (g)
Weight of Dried Crucible + Sample (g)
Initial
2 (if app)
Final
Source Sample
50
54.4507
50
56.0964
50
41.2612
50
51.6496
50
54.2524
-
50
45.7775
20K0522
50
21B2322
58.3517
2103010-01 -
By NFUENTES at 4:12 pm, May 12, 2021 Overnight Drying Date/Time IN - OUT:
04/07/2021 2:00PM By NFUENTES at 4:16 pm, May 12, 2021
Dry Cycle #1 Date/Time IN - OUT:
04/07/21 8:02am - 9:02am By NFUENTES at 11:01 am, Apr 08, 2021
Dry Cycle #2 Date/Time IN - OUT:
02-04-21 10:21 am - 11:22am By NFUENTES at 11:01 am, Apr 08, 2021
Comments
pH = 7 pH = 7 pH = 7 pH = 5
Table of Contents Page 18 of 38
Batch Comments:
Page 1 of 2
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
PREPARATION REAGENTS/STANDARDS/PIPETTES:
20K0522
21B2322:
TDS- SRM (Minerals) By NFUENTES at 4:22 pm, May 12, 2021
2
19J0121:
Filters - ProWeigh
By NFUENTES at 4:21 pm, May 12, 2021
NOV-05-20 Prepared: Feb-23-21
Prepared: Oct-01-19
DEC-05-22 Expires: Apr-01-23
By NFUENTES at 4:21 pm, May 12, 2021
Expires: Oct-30-26
By NFUENTES at 11:01 am, Apr 08, 2021
Date: 4/7/2021
Table of Contents Page 19 of 38
Batch Comments:
Page 2 of 2
Table of Contents Page 20 of 38
Table of Contents Page 21 of 38
Prepared Date: Analyst (initials):
Apr-07-21 NF
Crucible ID
Sample Number
15
2103010-01
3
2103010-02
B13
2103010-03
9
2103010-04
2
B21D009-BLK1
#7
B21D009-DUP1
STD
B21D009-SRM1
Balance ID Number: #17
Oven ID Number:
#10
Sample Volume
(mL)
50 50 50 50 50 50 50
Batch Comments:
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
RESIDUE, FILTERABLE (TDS)
Date: 4/8/2021
Batch Number: B21D009
Analyses Included On This Benchsheet Solids, TDS
Spike ID
Crucible Tare Weight (g)
Weight of Dried Crucible + Sample (g)
Initial
2 (if app)
Final
Source Sample
54.4507
54.4906
54.4904
56.0964
56.1580
56.1605
56.1600
41.2612
41.2890
41.2887
51.6496
51.6501
51.6500
54.2524
54.2527
54.2526
-
45.7775
45.8164
45.8160
2103010-01
20K0522
58.3517
58.3730
58.3728
-
Overnight Drying Date/Time IN - OUT: Dry Cycle #1 Date/Time IN - OUT: Dry Cycle #2 Date/Time IN - OUT:
4/7/2021 2:00pm - 4/8/21 7:58am 04/08/21 8:13am - 9:14am 04/08/21 10:39am - 11:39am
Dry Cycle #3 Date/time IN - OUT:
By NFUENTES at 10:31 am, May 13, 2021
04/08/21 1:01 pm - 2 ;07 pm
By NFUENTES at 10:29 am, May 13, 2021
Comments
pH = 7 pH = 7 pH = 7 pH = 5
Page 1 of 2
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
PREPARATION REAGENTS/STANDARDS/PIPETTES:
20K0522: TDS- SRM (Minerals)
Prepared: Nov-05-20
19J0122: Filters - ProWeigh
Prepared: Oct-01-19
Expires: Dec-05-22 Expires: Oct-30-26
Date: 4/8/2021
Table of Contents Page 22 of 38
Batch Comments:
Page 2 of 2
Table of Contents Page 23 of 38
Table of Contents Page 24 of 38
Table of Contents Page 25 of 38
ECOLOG-NET LA8 ID:303801 - elproLOG ANALYZE 3.64.01 Date of Reading: 21.04.2021 07:39:53
Date: DAY/MONTH/YEAR
Log Interval: 20 min
Module Tag: S1=Oven 10, S2=Oven 9, S3=Oven 11, S4=Oven 12, S5 - S8=Open
Data Description:
C:\Users\Esantiag\OneDrive - Environmental Protection Agency (EPA)\Desktop\elpro\303801_S1=Oven 10, S2=Oven -20210421-01.MDF
Start 07.04.2021 10:03:35 END 08.04.2021 14:23:35
A
180
160
S 1: Sensor 1 [C]
140
120
100
80
60
40
20
0 12:00
07.04.2021
15:00
Esantiag, 21.04.2021 / Current Line Chart
18:00
21:00
00:00 08.04.
03:00
06:00
09:00
B
12:00
Table of Contents Page 26 of 38
ECOLOG-NET LA8 ID:303801 - elproLOG ANALYZE 3.64.01 Date of Reading: 21.04.2021 07:39:53
DATE:DAY/MONTH/YEAR
Log Interval:
20 min
Module Tag:
S1=Oven 10, S2=Oven 9, S3=Oven 11, S4=Oven 12, S5 - S8=Open
Data Description:
C:\Users\Esantiag\OneDrive - Environmental Protection Agency (EPA)\Desktop\elpro\303801_S1=Oven 10, S2=Oven -20210421-01.MDF
Start 07.04.2021 10:03:35 END 08.04.2021 14:23:35
999 1000 1001 1002 1003 1004 1005 1006 1007 1008 1009 1010 1011 1012 1013 1014 1015 1016 1017 1018 1019 1020 1021 1022 1023
Date
Time Sensor 1 Sensor 2 Sensor 3 Sensor 4
Info
07.04.2021 09:43:35 +104.54 C +20.61 C +22.1 C +22.26 C
07.04.2021 10:03:35 +157.18 C +20.78 C +22.3 C +22.36 C
07.04.2021 10:23:35 +180.73 C +20.88 C +22.1 C +22.46 C
07.04.2021 10:43:35 +180.73 C +20.98 C +22.3 C +22.59 C
07.04.2021 11:03:35 +180.76 C +21.01 C +22.3 C +22.66 C
07.04.2021 11:23:35 +146.32 C +21.05 C +22.5 C +22.76 C
07.04.2021 11:43:35 +107.63 C +21.08 C +22.3 C +22.80 C
07.04.2021 12:03:35 +104.57 C +21.08 C +22.5 C +22.83 C
07.04.2021 12:23:35 +104.54 C +21.08 C +22.5 C +22.86 C
07.04.2021 12:43:35 +104.57 C +21.08 C +22.5 C +22.90 C
07.04.2021 13:03:35 +104.57 C +21.11 C +22.5 C +22.93 C
07.04.2021 13:23:35 +104.57 C +21.11 C +22.6 C +23.00 C
07.04.2021 13:43:35 +104.57 C +21.15 C +246.7 C +23.06 C
07.04.2021 14:03:35 +104.20 C +21.18 C +453.2 C +23.17 C
07.04.2021 14:23:35 +104.24 C +21.25 C +450.7 C +23.30 C
07.04.2021 14:43:35 +104.30 C +21.31 C +450.9 C +23.40 C
07.04.2021 15:03:35 +104.27 C +21.35 C +451.0 C +23.54 C
07.04.2021 15:23:35 +104.30 C +21.38 C +450.0 C +23.64 C
07.04.2021 15:43:35 +104.34 C +21.38 C +450.0 C +23.74 C
07.04.2021 16:03:35 +104.37 C +21.35 C +450.0 C +23.80 C
07.04.2021 16:23:35 +104.37 C +21.31 C +450.2 C +23.87 C
07.04.2021 16:43:35 +104.44 C +21.28 C +450.2 C +23.91 C
07.04.2021 17:03:35 +104.50 C +21.25 C +450.2 C +23.91 C
07.04.2021 17:23:35 +104.50 C +21.21 C +450.2 C +23.94 C
07.04.2021 17:43:35 +104.54 C +21.18 C +450.0 C +23.94 C
Esantiag, 21.04.2021 / Table / page 1
Table of Contents Page 27 of 38
ECOLOG-NET LA8 ID:303801 - elproLOG ANALYZE 3.64.01
Date of Reading: 21.04.2021 07:39:53
Date: DAY/MONTH/YEAR
Log Interval:
20 min
Module Tag:
S1=Oven 10, S2=Oven 9, S3=Oven 11, S4=Oven 12, S5 - S8=Open
Data Description:
C:\Users\Esantiag\OneDrive - Environmental Protection Agency (EPA)\Desktop\elpro\303801_S1=Oven 10, S2=Oven -20210421-01.MDF
Start 07.04.2021 10:03:35 END 08.04.2021 14:23:35
1024 1025 1026 1027 1028 1029 1030 1031 1032 1033 1034 1035 1036 1037 1038 1039 1040 1041 1042 1043 1044 1045 1046 1047 1048
Date
Time Sensor 1 Sensor 2 Sensor 3 Sensor 4
Info
07.04.2021 18:03:35 +104.61 C +21.15 C +450.2 C +23.94 C
07.04.2021 18:23:35 +104.64 C +21.11 C +450.2 C +23.94 C
07.04.2021 18:43:35 +104.64 C +21.08 C +450.2 C +23.94 C
07.04.2021 19:03:35 +104.67 C +21.08 C +450.2 C +23.94 C
07.04.2021 19:23:35 +104.67 C +21.05 C +450.0 C +23.94 C
07.04.2021 19:43:35 +104.67 C +21.01 C +450.2 C +23.87 C
07.04.2021 20:03:35 +104.67 C +20.94 C +450.0 C +23.80 C
07.04.2021 20:23:35 +104.67 C +20.91 C +450.0 C +23.74 C
07.04.2021 20:43:35 +104.67 C +20.84 C +450.0 C +23.64 C
07.04.2021 21:03:35 +104.67 C +20.78 C +450.2 C +23.57 C
07.04.2021 21:23:35 +104.67 C +20.74 C +450.2 C +23.50 C
07.04.2021 21:43:35 +104.71 C +20.74 C +450.4 C +23.43 C
07.04.2021 22:03:35 +104.67 C +20.81 C +450.2 C +23.40 C
07.04.2021 22:23:35 +104.67 C +20.81 C +450.2 C +23.40 C
07.04.2021 22:43:35 +104.67 C +20.81 C +450.2 C +23.37 C
07.04.2021 23:03:35 +104.67 C +20.81 C +450.4 C +23.37 C
07.04.2021 23:23:35 +104.64 C +20.78 C +450.4 C +23.33 C
07.04.2021 23:43:35 +104.64 C +20.81 C +450.4 C +23.33 C
08.04.2021 00:03:35 +104.64 C +20.78 C +450.2 C +23.30 C
08.04.2021 00:23:35 +104.64 C +20.74 C +450.2 C +23.27 C
08.04.2021 00:43:35 +104.67 C +20.74 C +450.4 C +23.23 C
08.04.2021 01:03:35 +104.67 C +20.68 C +450.2 C +23.20 C
08.04.2021 01:23:35 +104.64 C +20.64 C +450.2 C +23.13 C
08.04.2021 01:43:35 +104.67 C +20.57 C +450.0 C +23.10 C
08.04.2021 02:03:35 +104.67 C +20.47 C +450.0 C +23.03 C
Esantiag, 21.04.2021 / Table / page 2
Table of Contents Page 28 of 38
ECOLOG-NET LA8 ID:303801 - elproLOG ANALYZE 3.64.01 Date of Reading: 21.04.2021 07:39:53
Date: DAY/MONTH/YEAR
Log Interval:
20 min
Module Tag:
S1=Oven 10, S2=Oven 9, S3=Oven 11, S4=Oven 12, S5 - S8=Open
Data Description:
C:\Users\Esantiag\OneDrive - Environmental Protection Agency (EPA)\Desktop\elpro\303801_S1=Oven 10, S2=Oven -20210421-01.MDF
Start 07.04.2021 10:03:35 END 08.04.2021 14:23:35
1049 1050 1051 1052 1053 1054 1055 1056 1057 1058 1059 1060 1061 1062 1063 1064 1065 1066 1067 1068 1069 1070 1071 1072 1073
Date
Time Sensor 1 Sensor 2 Sensor 3 Sensor 4
Info
08.04.2021 02:23:35 +104.64 C +20.41 C +450.2 C +22.96 C
08.04.2021 02:43:35 +104.64 C +20.34 C +450.0 C +22.90 C
08.04.2021 03:03:35 +104.67 C +20.27 C +450.2 C +22.86 C
08.04.2021 03:23:35 +104.64 C +20.20 C +450.0 C +22.80 C
08.04.2021 03:43:35 +104.67 C +20.14 C +450.2 C +22.73 C
08.04.2021 04:03:35 +104.64 C +20.10 C +450.2 C +22.69 C
08.04.2021 04:23:35 +104.67 C +20.04 C +450.2 C +22.66 C
08.04.2021 04:43:35 +104.67 C +20.00 C +450.2 C +22.63 C
08.04.2021 05:03:35 +104.67 C +19.97 C +450.2 C +22.56 C
08.04.2021 05:23:35 +104.67 C +19.97 C +450.2 C +22.53 C
08.04.2021 05:43:35 +104.67 C +19.97 C +450.2 C +22.49 C
08.04.2021 06:03:35 +104.71 C +19.97 C +450.4 C +22.49 C
08.04.2021 06:23:35 +104.67 C +20.00 C +450.4 C +22.46 C
08.04.2021 06:43:35 +104.64 C +20.07 C +450.4 C +22.49 C
08.04.2021 07:03:35 +104.71 C +20.17 C +450.4 C +22.56 C
08.04.2021 07:23:35 +104.67 C +20.24 C +450.4 C +22.63 C
08.04.2021 07:43:35 +104.64 C +20.31 C +450.2 C +22.69 C
08.04.2021 08:03:35 +115.77 C +20.37 C +450.4 C +22.73 C
08.04.2021 08:23:35 +180.53 C +20.44 C +450.9 C +22.80 C
08.04.2021 08:43:35 +180.60 C +20.47 C +423.1 C +22.83 C
08.04.2021 09:03:35 +180.56 C +20.57 C +396.7 C +22.90 C
08.04.2021 09:23:35 +180.13 C +20.64 C +370.6 C +22.93 C
08.04.2021 09:43:35 +180.33 C +20.68 C +345.9 C +22.96 C
08.04.2021 10:03:35 +180.33 C +20.71 C +323.2 C +23.00 C
08.04.2021 10:23:35 +180.29 C +20.74 C +302.0 C +23.03 C
Esantiag, 21.04.2021 / Table / page 3
Table of Contents Page 29 of 38
ECOLOG-NET LA8 ID:303801 - elproLOG ANALYZE 3.64.01 Date of Reading: 21.04.2021 07:39:53
Date: DAY/MONTH/YEAR
Log Interval:
20 min
Module Tag:
S1=Oven 10, S2=Oven 9, S3=Oven 11, S4=Oven 12, S5 - S8=Open
Data Description:
C:\Users\Esantiag\OneDrive - Environmental Protection Agency (EPA)\Desktop\elpro\303801_S1=Oven 10, S2=Oven -20210421-01.MDF
Start 07.04.2021 10:03:35 END 08.04.2021 14:23:35
Date
Time Sensor 1 Sensor 2 Sensor 3 Sensor 4
Info
1074
08.04.2021 10:43:35 +180.60 C +20.78 C +282.2 C +23.06 C
1075
08.04.2021 11:03:35 +180.56 C +20.78 C +264.0 C +23.10 C
1076
08.04.2021 11:23:35 +180.60 C +20.78 C +247.0 C +23.10 C
1077
08.04.2021 11:43:35 +175.82 C +20.78 C +231.4 C +23.10 C
1078
08.04.2021 12:03:35 +180.33 C +20.74 C +216.7 C +23.10 C
1079
08.04.2021 12:23:35 +180.36 C +20.74 C +203.3 C +23.06 C
1080
08.04.2021 12:43:35 +180.36 C +20.74 C +191.0 C +23.10 C
1081
08.04.2021 13:03:35 +179.39 C +20.74 C +179.6 C +23.06 C
1082
08.04.2021 13:23:35 +180.36 C +20.74 C +169.1 C +23.10 C
1083
08.04.2021 13:43:35 +180.33 C +20.74 C +159.2 C +23.10 C
1084
08.04.2021 14:03:35 +180.29 C +20.74 C +150.3 C +23.10 C
1085
08.04.2021 14:23:35 +180.26 C +20.74 C +141.9 C +23.13 C
1086
08.04.2021 14:43:35 +180.33 C +20.78 C +134.2 C +23.17 C
Table of Contents Page 30 of 38
Esantiag, 21.04.2021 / Table / page 4
BATCH REAGENTS
19J0122
Table of Contents
Page 31 of 38
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
19J0122
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Filters - ProWeigh
Other Solution NA 1 1 Environmental Express 600022-9154-R2, Box ID 102XNW
Expires: Prepared: Prepared By: Department: Last Edit:
Oct-30-26 Oct-01-19 ** Vendor ** A&I Oct-01-19 16:33 by FA
Environmental Express ProWeigh Filters, Part # F93447MM-X. DoubleWeigh Filters for TSS, 47mm, 100pk. No expiration date is stated by the vendor.
Analyte
CAS Number
Concentration (ppm)
Table of Contents
By AK at 10:23 am, May 06, 2021
Page 3P2aogfe 318of 1
Box ID 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW
ID eSLI1 eSLI2 eSLI3 eSLI4 eSLI5 eSLI6 eSLI7 eSLI8 eSLI9 eSLIA eSLIB eSLIC eSLID eSLIE eSLIF eSLIG eSLIH eSLII eSLIJ eSLIK eSLIL eSLIM eSLIN eSLIP eSLIQ eSLJG eSLJH eSLJI eSLJJ eSLJK eSLJL eSLJM eSLJN eSLJP eSLJQ eSLJR eSLJS eSLJT eSLJU eSLJV eSLJW eSLJX eSLJY eSLJZ eSLK0 eSLK1
Weight 1 Lot 0.1192 600022 0.1201 600022 0.1195 600022 0.1196 600022 0.1189 600022 0.1196 600022 0.1185 600022 0.118 600022 0.118 600022 0.1172 600022 0.1183 600022 0.1183 600022 0.1172 600022 0.1191 600022 0.1199 600022 0.1197 600022 0.1186 600022 0.1186 600022 0.117 600022 0.1185 600022 0.1181 600022 0.1183 600022 0.1178 600022 0.1194 600022 0.1203 600022 0.1189 600022 0.1199 600022 0.1178 600022 0.1203 600022 0.1191 600022 0.1174 600022 0.1181 600022 0.1181 600022 0.1189 600022 0.1188 600022 0.1189 600022 0.1188 600022 0.1202 600022 0.1168 600022 0.119 600022 0.1172 600022 0.1189 600022 0.1178 600022 0.1187 600022 0.1196 600022 0.1183 600022
Table of Contents Page 33 of 38
102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW
eSLK2 eSLK3 eSLK4 eSLK5 eSLK6 eSLK7 eSLK8 eSLK9 eSLKA eSLKB eSLKC eSLKD eSLKE eSLKF eSLKG eSLKH eSLKI eSLKJ eSLKK eSLKL eSLKM eSLKN eSLKP eSLKQ eSLKR eSLKS eSLKT eSLKU eSLKV eSLZG eSLZH eSLZI eSLZJ eSLZK eSLZL eSLZM eSLZN eSLZP eSLZQ eSLZR eSLZS eSLZT eSLZU eSLZV eSLZW eSLZX eSLZY
0.118 0.1178 0.1196 0.1196
0.119 0.1177 0.1194 0.1195 0.1166 0.1182 0.1182 0.1193 0.1195 0.1187 0.1193 0.1182 0.1194 0.1191 0.1202 0.1199 0.1191 0.1195 0.1171 0.1181 0.1183 0.1187 0.1196 0.1191 0.1193
0.12 0.1185
0.12 0.1203 0.1191 0.1203 0.1187 0.1193 0.1185 0.1179 0.1178 0.1173 0.1181 0.1178 0.1193 0.1187
0.12 0.1198
600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022 600022
Table of Contents Page 34 of 38
102XNW 102XNW 102XNW 102XNW 102XNW 102XNW 102XNW
eSLZZ eSM00 eSM01 eSM02 eSM03 eSM04 eSM05
0.1189 0.1178 0.1178 0.1191
0.119 0.1193
0.119
600022 600022 600022 600022 600022 600022 600022
Table of Contents
Page 35 of 38
By AK at 2:03 pm, Dec 09, 2020
Table of Contents
90.2
By AK at 2:02 pm, Dec 09, 2020
Page 36 of 38
:RUNIORZ ,QVWDQFH 3ULQWDEOH 9HUVLRQ
,'
&XUUHQW 6WHS LV &ORVH
,QLWLDWHG E\ $PDQGD :UREOH
,QLWLDWH &OLHQW &RQWDFW E\ $PDQGD :UREOH RQ
$0
6HQG IRU 1RWLILFDWLRQ &ORVH &RQWDFW E\ $PDQGD :UREOH RQ
$0
/DXQFKHG :RUNIORZ 5HFRUG 'LVSRVLWLRQ ,'
RQ
$0
5HFRUG 'LVSRVLWLRQ /DXQFKHG &ORVH &RQWDFW E\ :RUNIORZ $FWLRQ ([HFXWRU RQ
&ORVH
&& 7\SH
6HOHFW DOO WKDW DSSO\
&OLHQW 1RWLILFDWLRQ &RQVHQW
Table of Contents $0
6KRUW 7LWOH
&& DQG RU 1&5 VKRUW WLWOH
'HDUGRUII 766 7'6 KROGLQJ WLPH H[FHHGDQFH
&& &RQWDFW 6XPPDU\
,I QR DFWLRQ LV UHTXHVWHG W\SH 1 $
&RQWDFW 'DWH
&OLHQW 1DPH DQG $IILOLDWLRQ
%HQ $WNLQVRQ (&$' :(&$%
3URMHFW DQG RU :RUN 2UGHU
'HDUGRUII
&RQWDFW 'HVFULSWLRQ
7KH FOLHQW ZDV QRWLILHG WKDW WKH 766 DQG 7'6 VDPSOHV ZHUH ZLOO EH DQDO\]HG RXWVLGH RI KROGLQJ WLPH DQG ZLOO EH IODJJHG IRU WKH H[FHHGDQFH
$FWLRQ 5HTXHVW
6HH DWWDFKHG FRUUHVSRQGHQFH
&& &RQWDFW $WWDFKPHQW
'HDUGRUIIB766 7'6 KROGLQJ WLPH H[FHHGDQFHB
SGI
'HDUGRUIIB766 7'6 KROGLQJ WLPH H[FHHGDQFHB
SGI
&& $IIHFWHG 3HUVRQQHO
6HOHFW DOO JURXS PHPEHUV WKDW DSSO\
$6% 6DPSOH &RRUGLQDWRU $6% *URXS $ ,
$6% 4$ 2IILFHU $6% 6DPSOH &RRUGLQDWRU $6% *URXS $ , $6% 4$ 2IILFHU
&& $FWLRQ 6XPPDU\
21( *5283 0(0%(5 21/< &RPSOHWH WKH DSSURSULDWH ILHOGV EHORZ DQG VHOHFW 6$9( &+$1*(6 2QFH WKH FOLHQW KDV DFFHSWHG WKH
DFWLRQ RU UHTXHVWHG DFWLRQ RI DQRWKHU JURXS FKRRVH WKH DSSURSULDWH URXWH &KRRVH $'',7,21$/ $))(&7(' 3(56211(/ RQO\ LI DQ
DFWLRQ LV UHTXHVWHG RI DQRWKHU JURXS ,I QR DGGLWLRQDO DFWLRQ LV UHTXHVWHG W\SH 1 $
$FWLRQ 'DWH
$FWLRQ 'HVFULSWLRQ
$GGLWLRQDO $FWLRQ 5HTXHVW
ILOH & 8VHUV QIXHQWHV 2QH'ULYH (QYLURQPHQWDO 3URWHFWLRQ $JHQF\ (3$ 'HVNWRS &OLHQW FRQWDFW 766B7'6B+2/',1* 7,0( KWPO
Page 37 of 38
:RUNIORZ ,QVWDQFH 3ULQWDEOH 9HUVLRQ
&& $FWLRQ $WWDFKPHQW && $GGLWLRQDO $IIHFWHG 3HUVRQQHO
21/< ,) DFWLRQV DUH UHTXHVWHG RI DQRWKHU JURXS VHOHFW DOO JURXS PHPEHUV WKDW DSSO\
Table of Contents
&& $GGLWLRQDO $FWLRQ 6XPPDU\
21( *5283 0(0%(5 21/< &RPSOHWH WKH DSSURSULDWH ILHOGV EHORZ DQG VHOHFW 6$9( &+$1*(6 2QFH WKH FOLHQW KDV DFFHSWHG WKH
DFWLRQ FKRRVH WKH &/26( &217$&7 URXWH ,I DQ DFWLRQ LV UHTXHVWHG RI DQRWKHU JURXS FKRRVH &/26( &217$&7 URXWH DQG LQLWLDWH
D QHZ FOLHQW FRQWDFW
$GGLWLRQDO $FWLRQ 'DWH
$GGLWLRQDO $FWLRQ 'HVFULSWLRQ
&& $GGLWLRQDO $FWLRQ $WWDFKPHQW && :DLW IRU 'LVSRVLWLRQ 'DWH
ILOH & 8VHUV QIXHQWHV 2QH'ULYH (QYLURQPHQWDO 3URWHFWLRQ $JHQF\ (3$ 'HVNWRS &OLHQW FRQWDFW 766B7'6B+2/',1* 7,0( KWPO
Page 38 of 38
Table of Contents
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 ANALYTICAL SERVICES BRANCH LABORATORY
536 SOUTH CLARK STREET (LAB-10C) CHICAGO, ILLINOIS 60605
ELECTRONIC LABORATORY DATA PACKAGE FINAL LEVEL IV COVER PAGE
LIMS Work order(s): Primary Analyst: Analysis: Date: Data Reporting Qualtrax Workflow ID:
Digital Signature of Primary Analyst:
2103010 Nidia Fuentes TKN DA May 03, 2021 24876
Digital Signature Agreement: By signing above the primary analyst understands and agrees that they will be held legally bound, obligated, and responsible for the use of their digital signature as they would be by using their hand-written signature.
Page 1 of 67
Client Project Name: Work Order Number:
Deardorff (BA-01-21) 2103010
1 Cover Page 2 Level I Report 3 QC Summary 4 Checklist 5 Sample Prep and Supporting Data (TKN DA)
5.1 Bench Sheets (B21D011) 5.2 Batch Reagents (B21D011) 5.3 Standards (19K1902) 5.4 Standards (21D0707) 5.5 Standards (21D0708) 5.6 Standards (21D0709) 5.7 Standards (21D0710) 5.8 Standards (21D0809) 5.9 Standards (21D0810) 5.10 Standards (21D0811) 5.11 Standards (21D0812) 5.12 Standards (21D0813) 5.13 Standards (21D0814) 5.14 Analysis Data and Supporting Documents (21D0802) 5.15 Sequence Reagents (21D0802) 6 Other Applicable Records
Table of Contents
Table of Contents
1 3 12 14 18 19 23 38 39 40 41 42 43 44 45 46 47 48 49 59 66
536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 FAX: 312-353-9069
Page 2 of 67
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605
Table of Contents
Date:
5/3/2021
Title: To:
From:
ASB Data Report for Deardorff
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604
Nidia Fuentes, Chemist fuentes.nidia@epa.gov US EPA Region 5 LSASD Analytical Services Branch
The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures.
This report was reviewed and the information provided herein accurately represents the analysis performed.
Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you.
Attached are Results for: Deardorff
Analyses included in this report: TKN DA
Report Name: 2103010 TKN DA FINAL May 03 21 0826
Page 3 of 67
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Accredited Analyses included in this Report
Table of Contents
Reported: May-03-21 08:26
Method: Analysis: Analyte
EPA 351.2 in Water TKN DA
Total Kjeldahl Nitrogen
Certifications ISO/IEC 17025:2017
Analytes not listed above are not accredited by ANAB.
Report Name: 2103010 TKN DA FINAL May 03 21 0826
Page 4 of 67
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-03-21 08:26
ANALYSIS CASE NARRATIVE
Analysis List TKN DA
Analyst: Nidia Fuentes Phone #: 312-353-9079
General Information
Samples analyzed:
Sample
Analysis List
2103010-01
TKN DA
2103010-02
TKN DA
2103010-03
TKN DA
2103010-04
TKN DA
Holding times: All holding times were met.
Sample Analysis and Results
The samples were analyzed using ASB SOP AIG035B, Version #8. The samples were stored in the refrigerator at all times, except when in use. The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated "FY 2021", except for those listed in the Quality Control section.
Additionally, Pen & Ink document Qualtrax ID 24510 (Adjusting the preparation of Hypochlorite solution by assay using a weaker sodium hypochlorite reagent.) was used. This situation does not affect the quality of the data.
SOP Based on: Method List EPA 351.2
Quality Control
All quality control audits were within ASB limits, except for matrix spike. Sample 2103010-01 (S01) matrix spike recovery (81%) was below the QC limit 0f 90 -110%, no flag is apply because sample spike concentration was diluted out.
Report Name: 2103010 TKN DA FINAL May 03 21 0826
Page 5 of 67
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-03-21 08:26
Report Name: 2103010 TKN DA FINAL May 03 21 0826
Page 6 of 67
3019234515671897 4355871839517195743591854
!"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291
Table of Contents
?@A@<0
BCDEDCD :;0 7351;;<19839;74237=>491
43187GKENEDNBDBCCKEDKB O
3718K ?9874<323=351F:;0 7351 45J78K<794G54HH
45J78O91974K 179@ P49==9<923= 45J78LM674K >IDCIBC
7Q548R5K [%.Y$'.V. S"%#T'U'V'.&WX-YZ%)'.
T"%T%/ Z%(%'U%][_/ +))%]*.[_/
`"_41^4211/,,0^]"_aYa3 Zb%#._]%# Zb%#._]%#
66S%V\"($V.[!%U"#] '(")&*+,,^ T"%Z%(%'U%]/ `"#4,4211,/,5 T"%+))%]*./ `"#4,42111/1
-.%/012342,,^ 7"8/01235542,,1
"cd!%")Ve!"b%!V %"!V*."( Z%(%'U%].'(% -"d%#f#$*.(!]%]
g7= ?54P@4G74566718=K g7= dhd"d%#V%]'. i15T19,1 g7= g7=
!%#0V3'.j#c"'./ T%j"! !%#4,k^,
;96Q7l<K BCDEDCDIDC ;96Q7GK O94IBqIBCCDKCq
;96Q7L967K ;DC
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
atrTY
25
a"!-Vd#VTY
25
O9843mK ?9874 ;96Q7598351N566718=K 9=8M475M878
0mQ347= Yd#424211,/1 Yd#424211,/1 Yd#4,24211,/1 Yd#4,24211,/1 Yd#424211,/1 Yd#424211,/1
566718= dhi1 dhi1 dhi6 dhi6 dhi1 dhi1
;96Q7l<K BCDEDCDIDB ;96Q7GK O94IBqIBCCDKBu
;96Q7L967K ;DB
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
O9843mK ?9874 ;96Q7598351N566718=K 799873178
0mQ347= Yd#424211,/2^ Yd#424211,/2^ Yd#4,24211,/2^ Yd#4,24211,/2^
566718= dhi1 dhi1 dhi6 dhi6
Page 7 of 67
Table of Contents Page 8 of 67
Table of Contents Page 9 of 67
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-03-21 08:26
S01 (2103010-01)
Analyte Total Kjeldahl Nitrogen
S02 (2103010-02)
Analyte Total Kjeldahl Nitrogen
S03 (2103010-03)
Analyte Total Kjeldahl Nitrogen
B01 (2103010-04)
Analyte Total Kjeldahl Nitrogen
Total Kjeldahl Nitrogen, EPA 351.2 (modified) US EPA Region 5 LSASD Analytical Services Branch
Matrix: Water Sampled: Mar-26-21 10:16
Result
Flags / Qualifiers
MDL
Reporting Limit
16.7
3.00
5.00
Received: Mar-30-21 10:08
Units mg/L
Dilution 10
Batch B21D011
Matrix: Water Sampled: Mar-26-21 10:24
Result
Flags / Qualifiers
MDL
Reporting Limit
67.2
3.00
5.00
Received: Mar-30-21 10:08
Units mg/L
Dilution 10
Batch B21D011
Matrix: Water Sampled: Mar-26-21 11:47
Result
Flags / Qualifiers
MDL
Reporting Limit
9.22
0.30
0.50
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D011
Matrix: Water Sampled: Mar-26-21 16:10
Result
Flags / Qualifiers
MDL
Reporting Limit
U
0.30
0.50
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D011
Prepared Apr-07-21
Analyzed Apr-08-21
Prepared Apr-07-21
Analyzed Apr-08-21
Prepared Apr-07-21
Analyzed Apr-08-21
Prepared Apr-07-21
Analyzed Apr-08-21
Report Name: 2103010 TKN DA FINAL May 03 21 0826
Page 10 of 67
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
U
Not Detected
NR
Not Reported
Q
QC limit Exceeded
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Notes and Definitions
Table of Contents
Reported: May-03-21 08:26
Report Name: 2103010 TKN DA FINAL May 03 21 0826
Page 11 of 67
Environmental Protection Agency
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Table of Contents
Date: Project:
5/3/2021 Deardorff
Quality Control Summary
Analyst: Nidia Fuentes
Analyte: Total Kjeldahl Nitrogen
Analysis: TKN DA
QC Sample Name 21D0802-CAL1
Result 0.16
Units mg/L
Flags / Qualifiers
MDL
Reporting Limit
Spike Level
0.30
0.50
0.000
Source Result
% REC or abs diff (pH)
% REC or abs diff
(pH) Limits
%
% RPD or abs diff (pH)
%RPD or abs diff ( pH)
Limits
21D0802-CAL2
0.34
mg/L
0.30
0.50
0.2500
135%
21D0802-CAL3
0.52
mg/L
0.30
0.50
0.5000
104%
21D0802-CAL4
0.91
mg/L
0.30
0.50
1.000
91%
21D0802-CAL5
1.85
mg/L
0.30
0.50
2.000
92%
21D0802-CAL6
2.37
mg/L
0.30
0.50
2.500
95%
21D0802-CAL7
5.14
mg/L
0.30
0.50
5.000
103%
21D0802-CAL8
9.98
mg/L
0.30
0.50
10.00
100%
21D0802-CCB1
0.25
mg/L
0.30
0.50
21D0802-CCB2
0.25
mg/L
0.30
0.50
21D0802-CCB3
0.27
mg/L
0.30
0.50
21D0802-CCB4
0.27
mg/L
0.30
0.50
21D0802-CCB5
0.29
mg/L
0.30
0.50
21D0802-CCB6
0.16
mg/L
0.30
0.50
21D0802-CCV1
5.33
mg/L
0.30
0.50
5.000
107%
90-110
21D0802-CCV2
5.36
mg/L
0.30
0.50
5.000
107%
90-110
21D0802-CCV3
5.41
mg/L
0.30
0.50
5.000
108%
90-110
21D0802-CCV4
5.37
mg/L
0.30
0.50
5.000
107%
90-110
21D0802-CCV5
5.47
mg/L
0.30
0.50
5.000
109%
90-110
Report Name: 2103010 TKN DA FINAL May 03 21 0826
Page 12 of 67
Environmental Protection Agency
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Table of Contents
Quality Control Summary
Date: 5/3/2021
Analyst: Nidia Fuentes
Project: Deardorff
Analyte: Total Kjeldahl Nitrogen
Analysis: TKN DA
QC Sample Name 21D0802-CCV6
Result 5.31
Units mg/L
Flags / Qualifiers
MDL
Reporting Limit
Spike Level
0.30
0.50
5.000
Source Result
% REC or abs diff (pH)
% REC or abs diff
(pH) Limits
106%
90-110
% RPD or abs diff (pH)
%RPD or abs diff ( pH)
Limits
21D0802-ICB1
0.24
mg/L
0.30
0.50
21D0802-ICV1
5.32
mg/L
0.30
0.50
5.000
106%
90-110
B21D011-BLK1
U
mg/L
0.30
0.50
B21D011-BS1
2.03
mg/L
0.30
0.50
2.000
101%
90-110
B21D011-DUP2 Source: 2103010-01
B21D011-MRL1
16.2
mg/L
0.56
mg/L
3.00
5.00
16.7
3
24
0.5000
112%
74-153
B21D011-MS2 Source: 2103010-01
18.3
mg/L
Q
3.00
5.00
2.000
81%
90-110
16.7
U
Not Detected
NR
Not Reported
Q
QC limit Exceeded
B21D011-MS2
TKN DA
Notes and Definitions
Total Kjeldahl Nitrogen
Q
Nidia Fuentes
Report Name: 2103010 TKN DA FINAL May 03 21 0826
Page 13 of 67
Work:
2103010
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 LSASD ANALYTICAL SERVICE BRANCH 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605
Data Verification Checklist
Project: Deardorff
Analysis: TKN DA
CRL SOP Used:
AIG035B Version #8
Batch ID:
General Information
B21D011
Question #
1
Question Did samples meet the laboratory's standard conditions of sample acceptability upon receipt?
2
Was customer contact communication included?
3
Are all field sample ID numbers cross-referenced to the laboratory ID numbers?
4
Were all samples prepared and analyzed within holding times?
Question # 5 6 7 8 9 10 11 12 13
Sample Results
Were calculations checked?
Question
Were all analyte results checked?
Were all results for soil and sediment samples reported on a dry weight basis?
Were % moisture (or solids) reported for all soil and sediment samples?
Other than those results < RL, were all other raw values bracketed by calibration standards?
Are the RLs for each method analyte included in the laboratory data package?
Are MDLs/RLs adjusted for dilutions?
Were the raw data (for example, chromatograms, spectral data) reviewed?
Were data associated with manual integrations flagged on the raw data?
Question # 14
15
Standards
Question Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources as specified in the analytical SOP? Were standard/reagent preparations checked (preparation date, expiration date, parent standard IDs, etc.), if applicable?
Batch Quality Control
Print Date: 4/12/2021
Table of Contents
Analyst Response (YES/ NO/ NA) YES NA YES YES
Analyst Response (YES/ NO/ NA) YES YES NA NA YES YES YES YES NA
Analyst Response (YES/ NO/ NA) YES YES
Page 14 of 67
Work:
2103010
Project: Deardorff
Question # 16 17 18 19 20 21 22 23 24 25
26 27 28 29 30
Batch Quality Control
Were appropriate type(s) of blanks analyzed?
Question
Were blanks analyzed at the appropriate frequency?
Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures?
Were blank concentrations <= MDL or RL, as applicable in the analytical SOP?
Was each LCS/SRM taken through the entire analytical procedure, including prep and cleanup steps?
Were LCSs/SRMs analyzed at the required frequency?
Were LCS/SRM %Rs within the laboratory QC limits or other acceptance criteria?
Were the project/method specified analytes included in the MS?
Were MS analyzed at the appropriate frequency?
Were MS %Rs within the laboratory QC limits?
Notes/Comments: Matrix Spike Recovery for Total Kjeldahl Nitrogen (8 %) was outside acceptance limits (90-110) in B21D011-MS for TKN DA See narrative Were appropriate analytical duplicates analyzed for each matrix?
Were analytical duplicates analyzed at the appropriate frequency?
Were RPDs or relative standard deviations within the laboratory QC limits or other acceptance criteria?
Were RLs analyzed at the appropriate frequency?
Were RL recoveries within the laboratory QC limits?
Question # 31
32
33
34
Calibration
Question Were calibration correlation coefficient or other acceptance criteria met? Was the number of calibration standards recommended in the method used for all analytes? Were all points generated between the lowest and highest standard used to calculate the curve? Are calibration data available for all instruments used?
Question # 35
36
Calibration Verification
Question Was the absolute value of the analyte concentration in the ICB/CCB <= MDL or RL, as applicable in the analytical SOP? Was the calibration curve verified for each analyte?
Print Date: 4/12/2021
Table of Contents
Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES YES YES YES NO
YES YES YES YES YES
Analyst Response (YES/ NO/ NA) YES YES YES YES
Analyst Response (YES/ NO/ NA) YES YES
Page 15 of 67
Work:
2103010
Project: Deardorff
Question # 37
38
39
Calibration Verification
Question Has the calibration curve been verified using an appropriate second source standard? Were ICV/CCV analyzed at the method-required frequency? Were ICV/CCV %R within the laboratory QC limits?
Table of Contents
Analyst Response (YES/ NO/ NA) YES YES YES
Question # 40
41
42
Quality Control
QC limits in LIMS checked against the SOP?
Question
Were percent differences, recoveries, and the linearity within the QC limits specified in the method? 5HIHU WR
Were QC charts checked if a QC audit, excluding matrix QC (MS or DUP), was out of limit?
By NFUENTES at 8:40 am, Apr 19, 2021
Question # 43
44
Supporting Data
Question Were support equipment data (balance verification, data logs, logbook entries, etc.) included in data package? Were approved spreadsheet(s) used?
Analyst Response (YES/ NO/ NA) YES NO
NA YES
Analyst Response (YES/ NO/ NA) YES YES
Question # 45 46 47 48 49 50
Question # 51
Document Verification
Question Is the MDL or RL study up-to-date for each reported analyte?
Is documentation of the analyst's capability up-to-date and on file?
ID 24425
Are the procedures for compound/analyte identification documented?
Are laboratory SOPs current and on file for the method performed?
Were data evaluated against project QAPP or Sample Plan, any special requests in the sample schedule, and documented in case narrative? Were electronic pathways checked (add pathway and files below)? Notes/Comments: J:\Vol1\Projects (New File Structure)\Deardorff\1. A&I\NFuentes\DA3\04082021-TPTKN\ARC_70.bak
Accreditation
ANAB logo used appropriately?
Question
Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES
Analyst Response (YES/ NO/ NA) YES
Print Date: 4/12/2021
Page 16 of 67
Work:
2103010
Project: Deardorff
Table of Contents
Analyst's Signature and Date*:
By NFUENTES at 12:26 pm, Apr 12, 2021
Reviewer's Signature and Date*: Additional Notes/Comments (if applicable):
By AK at 7:04 am, May 03, 2021
*Reviewer Concurs with Analyst Responses
Print Date: 4/12/2021
Page 17 of 67
TKN DA
Table of Contents
Page 18 of 67
BATCH
B21D011
[TOC_1]Benchsheets[TOTCa]ble of Contents
Page 19 of 67
Table of Contents Page 20 of 67
Prepared Date: Analyst (initials):
Apr-07-21 NF
Position #
17
Sample Number 2103007-01
21 2103007-02
22 2103007-03
23 2103007-04
24 2103007-05
25 2103007-06
26 2103007-07
27 2103007-08
28 2103007-09
29 2103010-01
33 2103010-02
34 2103010-03
35 2103010-04
13 B21D011-BLK1
Source ID (MS and DUP only)
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
TP/TKN DIGESTION LOG
Date: 4/7/2021
Batch Number: B21D011
Analyses Included On This Benchsheet
TKN DA
Spike ID
Spike Volume (uL)
Spike Final Volume (mL)
(MRL, BS, MS only)
Sample Volume (mL) 10 10 10 10 10 10 10 10 10 10 10 10 10
pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1
10
Comments
Page 1 of 3
Prepared Date: Analyst (initials):
Apr-07-21 NF
Position #
12
Sample Number B21D011-BS1
18 B21D011-DUP1
30 B21D011-DUP2
11 B21D011-MRL1
20 B21D011-MS1
32 B21D011-MS2
Batch Comments:
Source ID (MS and DUP only)
2103007-01 2103010-01
2103007-01 2103010-01
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
TP/TKN DIGESTION LOG
Date: 4/7/2021
Batch Number: B21D011
Analyses Included On This Benchsheet
TKN DA
Spike ID 19K1902
21D0710 19K1902 19K1902
Spike Volume (uL) 20
20 20
Spike Final Volume (mL)
(MRL, BS, MS only)
10
10 10
Sample Volume (mL) 10 10 10 10 10 10
Comments
PREPARATION REAGENTS/STANDARDS/PIPETTES:
19K1902: TKN-Spike Mix (1000 mg/L)
Prepared: Nov-19-19
21D0710: TKN - MRL (0.50 mg N/L)
Prepared: Apr-07-21
21B2306: Pipette (Electronic) -- 50 -1,000 uL
Prepared: Feb-15-21
21B2307: Pipette (Electronic) -- 200 -5000 uL
Prepared: Feb-15-21
21B2308: Pipette (Electronic) -- 500 - 10,000 uL
Prepared: Feb-15-21
21B2309: Pipette (Electronic) -- 5 -100 uL
Prepared: Feb-15-21
21C0906: TP/TKN Digestion Solution
Prepared: Mar-09-21
Expires: Oct-28-21
May-07-21
Expires: Jul-11-21
By NFUENTES at 12:41 pm, Apr 12, 2021
Expires: Aug-31-21
Expires: Aug-31-21
Expires: Aug-31-21
Expires: Aug-31-21
Expires: Mar-09-22
Table of Contents Page 21 of 67
Page 2 of 3
Prepared Date: Analyst (initials):
Apr-07-21 NF
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
TP/TKN DIGESTION LOG
Date: 4/7/2021
Batch Number: B21D011
Analyses Included On This Benchsheet
TKN DA
Hot Block ID: #9
Block Digital Temp 1 Reading (C ) - Start - Stop Time/ Block Digital Temp 2 Reading (C ) - Start - Stop Time:
33
34
35
36
25
26
27
28
200C-11:50 AM -12:50 PM/ 380C-12:50 PM - 2:20 PM
37
38
29
30
39
DB
31
40
DB
32
17
18
19
20
21
22
23
24
9
10
11
12
13
14
15
16
TKN
TKN
Calibration
ICV/CCV
1
2
3
4
5
6
7
8
DB= Dilution Blank
Table of Contents Page 22 of 67
Page 3 of 3
BATCH REAGENTS
21B2306
Table of Contents
Page 23 of 67
Table of Contents Page 24 of 67
Table of Contents Page 25 of 67
BATCH REAGENTS
21B2307
Table of Contents
Page 26 of 67
Table of Contents Page 27 of 67
Table of Contents Page 28 of 67
BATCH REAGENTS
21B2308
Table of Contents
Page 29 of 67
Table of Contents Page 30 of 67
Table of Contents Page 31 of 67
BATCH REAGENTS
21B2309
Table of Contents
Page 32 of 67
Table of Contents Page 33 of 67
Table of Contents Page 34 of 67
BATCH REAGENTS
21C0906
Table of Contents
Page 35 of 67
Environmental Protection Agency Region 5
Chicago Regional Laboratory
Table of Contents
Print Date:
3/9/2021
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Parameter / SOP #:
Reagent Preparation Bench Sheet
By NFUENTES at 11:10 am, Mar 31, 2021
By NFUENTES at 11:10 am, Mar 31, 2021
034B
035B
TP/TKN SOP AIG34B ver#7, AIG35B ver#8
Prepared by:
Nidia Fuentes
Reagent: TP/TKN Digestion Solution
Preparation Date: Mar-09-21
LIMS ID: 21C0906
Expiration Date: Mar-09-22
Chemical Name (Formula)
Sulfuric Acid (H2S04)
LIMS ID
20B0607
Mass or Volume (specify units)
200 mL
Mercuric Sulfate solution
19H0504
25 mL
Potassium Sulfate (K2SO4)
20J2902
133.0398 g
Total Volume : Comments : Balance #17
1000 500 mL
By NFUENTES at 11:10 am, Mar 31, 2021
Analyst Signature:
By AK at 8:15 am, Apr 01, 2021
Page 3P6aogfe 617of 1
Table of Contents Page 37 of 67
By AK at 10:47 am, Feb 04, 2020
Table of Contents Page 38 of 67
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0707
TKN - WCS (0.00 mg N/L)
Other Solution Reagent water 100 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
May-07-21 Apr-07-21 Nidia Fuentes A&I Apr-07-21 15:35 by NF
Table of Contents
Analyte
Ammonia as N Total Kjeldahl Nitrogen
CAS Number
NA NA
Concentration (ppm)
0 0
Parent Standards used in this standard:
Standard 19K1901
Description NH3N/TKN-SCS (1000 mg/L)
21B2306 20B0607
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
Prepared Nov-19-19 Feb-15-21
Feb-06-20
Prepared By ** Vendor ** Nidia Fuentes
** Vendor **
Expires Oct-28-21 Aug-31-21
Jul-11-21
Last Edit Aug-27-20 10:20 by NF Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB
(mls) 0 0.1
0.1
By AK at 10:34 am, Apr 14, 2021
Page 3P9aogfe 617of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0708
TKN - WCS (10.00 mg N/L)
Other Solution Reagent water 100 1 Absolute Standards Inc. 102819
Expires: Prepared: Prepared By: Department: Last Edit:
May-07-21 Apr-07-21 Nidia Fuentes A&I Apr-07-21 15:35 by NF
Table of Contents
Analyte
Ammonia as N Total Kjeldahl Nitrogen
CAS Number
NA NA
Concentration (ppm)
10 10
Parent Standards used in this standard:
Standard 19K1901
Description NH3N/TKN-SCS (1000 mg/L)
21B2309 Pipette (Electronic) -- 5 -100 uL
21B2306 20B0607
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
Prepared Nov-19-19 Feb-15-21 Feb-15-21
Feb-06-20
Prepared By ** Vendor ** Nidia Fuentes Nidia Fuentes
** Vendor **
Expires Oct-28-21 Aug-31-21 Aug-31-21
Jul-11-21
Last Edit Aug-27-20 10:20 by NF Apr-05-21 09:33 by AK Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB
(mls) 1 0.1 1
0.1
By AK at 10:34 am, Apr 14, 2021
Page 4P0aogfe 617of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0709
TKN - WcS (5.00 mg N/L)
Other Solution Reagent water 100 1 Absolute Standards Inc. 012721
Expires: Prepared: Prepared By: Department: Last Edit:
May-07-21 Apr-07-21 Nidia Fuentes A&I Apr-07-21 15:50 by NF
Table of Contents
Analyte
Total Dissolved Phosphorus Total Kjeldahl Nitrogen Total Phosphorus
CAS Number
NA NA NA
Concentration (ppm)
5 5 5
Parent Standards used in this standard:
Standard 21B2309
Description Pipette (Electronic) -- 5 -100 uL
21B2306 20B0607
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
21C1801 TP&TKN Stock Control Std.
Prepared Feb-15-21 Feb-15-21
Feb-06-20 Mar-16-21
Prepared By Nidia Fuentes Nidia Fuentes
** Vendor ** Nidia Fuentes
Expires Aug-31-21 Aug-31-21
Jul-11-21 Jan-07-23
Last Edit Apr-05-21 09:33 by AK Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB Mar-18-21 09:14 by NF
(mls) 0.1 0.5
0.1 0.5
By AK at 10:33 am, Apr 14, 2021
Page 4P1aogfe 617of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0710
TKN - MRL (0.50 mg N/L)
Reference Material Reagent water 100 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
May-07-21 Apr-07-21 Nidia Fuentes A&I Apr-12-21 08:57 by NF
Table of Contents
Analyte
Ammonia as N Total Kjeldahl Nitrogen
CAS Number
NA NA
Concentration (ppm)
0.5 0.5
SRM Control Limits
0-200 0-200
Parent Standards used in this standard:
Standard 19K1901
Description NH3N/TKN-SCS (1000 mg/L)
21B2309 Pipette (Electronic) -- 5 -100 uL
20B0607 Sulfuric Acid 9673-33
Prepared Nov-19-19 Feb-15-21 Feb-06-20
Prepared By ** Vendor ** Nidia Fuentes ** Vendor **
Expires Oct-28-21 Aug-31-21 Jul-11-21
Last Edit Aug-27-20 10:20 by NF Apr-05-21 09:33 by AK Mar-02-20 14:42 by CB
(mls) 0.05 0.05 0.1
By AK at 10:33 am, Apr 14, 2021
Page 4P2aogfe 617of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0809
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TKN - WCS (0.25 mg N/L)
Other Solution Blank: 21D0707 2 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-08-21 15:48 by NF
Prepared by Instrument (DA-3)
By AK at 10:33 am, Apr 14, 2021
Analyte
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
0.25
NA
0.25
Table of Contents
Parent Standards used in this standard:
Standard 21D0708
Description TKN - WCS (10.00 mg N/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:35 by NF
(mls) 0.05
Page 4P3aogfe 617of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0810
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TKN - WCS (0.5 mg N/L)
Other Solution Blank: 21D0707 2 1 Absolute Grade 102819
Prepared by Instrument (DA-3)
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-12-21 09:24 by NF
Analyte
By AK at 10:32 am, Apr 14, 2021
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
0.5
NA
0.5
Table of Contents
Parent Standards used in this standard:
Standard 21D0708
Description TKN - WCS (10.00 mg N/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:35 by NF
(mls) 0.1
Page 4P4aogfe 617of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0811
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TKN - WCS (1.0 mg N/L)
Other Solution Blank: 21D0707 2 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-08-21 15:50 by NF
Prepared by Instrument (DA-3)
Analyte
By AK at 10:32 am, Apr 14, 2021
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
1
NA
1
Table of Contents
Parent Standards used in this standard:
Standard 21D0708
Description TKN - WCS (10.00 mg N/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:35 by NF
(mls) 0.2
Page 4P5aogfe 617of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0812
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TKN - WCS (2.0 mg N/L)
Other Solution Blank: 21D0707 2 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-08-21 15:51 by NF
Prepared by Instrument (DA-3)
By AK at 10:32 am, Apr 14, 2021
Analyte
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
2
NA
2
Table of Contents
Parent Standards used in this standard:
Standard 21D0708
Description TKN - WCS (10.00 mg N/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:35 by NF
(mls) 0.4
Page 4P6aogfe 617of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0813
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TKN - WCS 2.5mg N/L)
Other Solution Blank: 21D0707 2 1 Absolute Grade 102819
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-08-21 15:51 by NF
Prepared by Instrument (DA-3)
By AK at 10:32 am, Apr 14, 2021
Analyte
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
2.5
NA
2.5
Table of Contents
Parent Standards used in this standard:
Standard 21D0708
Description TKN - WCS (10.00 mg N/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:35 by NF
(mls) 0.5
Page 4P7aogfe 617of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0814
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TKN - WCS (5.0 mg N/L)
Other Solution Blank: 21D0707 2 1 Absolute Grade 102819
Prepared by Instrument (DA-3)
Analyte
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-08-21 15:52 by NF
By AK at 10:32 am, Apr 14, 2021
CAS Number
Concentration (ppm)
Ammonia as N Total Kjeldahl Nitrogen
NA
5
NA
5
Table of Contents
Parent Standards used in this standard:
Standard 21D0708
Description TKN - WCS (10.00 mg N/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:35 by NF
(mls) 1
Page 4P8aogfe 617of 1
SEQUENCE
21D0802
[TOC_1]Sequence[TOC] Table of Contents
Sequence Date: 04/08/2021 Instrument: DA-3 Sequence Analyses: TKN DA
Page 49 of 67
Instrument:
Order
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23
ANALYSIS SEQUENCE 21D0802
DA-3 Container
A A
A A A A A A
Analysis Date: Apr-08-21
Lab Number
Sample name or QC sample designation
21D0802-CAL2
Cal Standard
21D0802-CAL3
Cal Standard
21D0802-CAL4
Cal Standard
21D0802-CAL5
Cal Standard
21D0802-CAL6
Cal Standard
21D0802-CAL7
Cal Standard
21D0802-CAL8
Cal Standard
21D0802-CAL1
Cal Standard
21D0802-ICB1
ICB
21D0802-ICV1
ICV
2103010-03
S03
2103010-04
B01
B21D011-MRL1
MRL Check
B21D011-BLK1
Blank
B21D011-BS1
LCS
2103007-02
S02
21D0802-CCB1
ICB
21D0802-CCV1
ICV
2103007-06
S06
2103007-07
S07
2103007-08
S08
2103007-09
B01
2103007-01
S01
Calibration ID:
UNASSIGNED
QC QC QC QC QC QC QC QC QC QC TKN DA TKN DA QC QC QC TKN DA QC QC TKN DA TKN DA TKN DA TKN DA TKN DA
Analysis
Printed: 4/12/2021 2:23:33PM
Matrix: Water STD ID 21D0809 21D0810 21D0811 21D0812 21D0813 21D0814 21D0708 21D0707
21D0709
Comments
pH = 1 pH = 1
21D0709
pH = 1
pH = 1 pH = 1 pH = 1 pH = 1 pH = 1
Table of Contents Page 50 of 67
Page 1 of 3
Order
24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42
Container Lab Number
21D0802-CCB2
21D0802-CCV2
B21D011-DUP1
B21D011-MS1
A
2103007-03
21D0802-CCB3
21D0802-CCV3
21D0802-CCB4
21D0802-CCV4
A
2103007-04
A
2103007-05
A
2103010-01
B21D011-DUP2
B21D011-MS2
21D0802-CCB5
21D0802-CCV5
A
2103010-02
21D0802-CCB6
21D0802-CCV6
Sample name or QC sample designation
ICB ICV Duplicate Matrix Spike S03 ICB ICV ICB ICV S04 S05 S01 Duplicate Matrix Spike ICB ICV S02 ICB ICV
QC QC QC QC TKN DA QC QC QC QC TKN DA TKN DA TKN DA QC QC QC QC TKN DA QC QC
Analysis
STD ID 21D0709
Comments
21D0709 21D0709
pH = 1
pH = 1 pH = 1 pH = 1
21D0709 21D0709
pH = 1
Table of Contents Page 51 of 67
Page 2 of 3
Order
Container Lab Number
Sample name or QC sample designation
PREPARATION REAGENTS/STANDARDS/PIPETTES:
19K1902: TKN-Spike Mix (1000 mg/L)
Prepared: Nov-19-19
21D0710: TKN - MRL (0.50 mg N/L)
Prepared: Apr-07-21
21D0707: TKN - WCS (0.00 mg N/L)
Prepared: Apr-07-21
21D0708: TKN - WCS (10.00 mg N/L)
Prepared: Apr-07-21
21D0709: TKN - WcS (5.00 mg N/L)
Prepared: Apr-07-21
21D0809: TKN - WCS (0.25 mg N/L)
Prepared: Apr-08-21
21D0810: TKN - WCS (0.5 mg N/L)
Prepared: Apr-08-21
21D0811: TKN - WCS (1.0 mg N/L)
Prepared: Apr-08-21
21D0812: TKN - WCS (2.0 mg N/L)
Prepared: Apr-08-21
21D0813: TKN - WCS 2.5mg N/L)
Prepared: Apr-08-21
21D0814: TKN - WCS (5.0 mg N/L)
Prepared: Apr-08-21
20G1701: TKN - Sodium salicylate/sodium nitroprusside sol.
Prepared: Jul-17-20
21B0411: TKN-Working Buffer Solution
Prepared: Feb-04-21
21D0808: TKN-Sodium Hypochlorite
Prepared: Apr-08-21
Analysis
Expires: Oct-28-21 Expires: May-07-21 Expires: May-07-21 Expires: May-07-21 Expires: May-07-21 Expires: Apr-09-21 Expires: Apr-09-21 Expires: Apr-09-21 Expires: Apr-09-21 Expires: Apr-09-21 Expires: Apr-09-21 Expires: Jul-17-21 Expires: Feb-04-22 Expires: Apr-09-21
STD ID
Comments
Table of Contents Page 52 of 67
Page 3 of 3
!" #
$
%
&' !" # (( ) *
!
-
* .(
* .(
* * .(
#+++ , #,
# #+ #
"
#
$
%
!
!
#
#,
#
.
!
#
#+
#
.
!
#
# ++
#
.
!
#
#+ ,+
#
.
!
#,
#,
#
.
!
#
#,
#
.
!
#
#+
#
.
!
#+
+#+
#
.
Table of Contents
Page 53 of 67
Table of Contents
!"
# $ %& '
'./ '.1
/
3
/
/3
/
/#
0
/
-
/
#
0
0
'./
'.1
0
0
0
00
0
02
/
-
/
#
0
'./
'.1
/
-
/
#
0
'./
'.1
'./
-) , & )(
0
2
D D D
20
D
0
D D
2 2
02
D D D
0 2
2 0
(
)* #
+&&(&
%%
%%
%%
%%
%%
%%
%%
&4
) ) ) 5) 67 8 )9 % )!& )(
&4
) ) ) 5) 67 8 )9 % )!& )(
&4
! 6) 67 ) ) ) 5) 67 8 )9 % )!&
%%
&4
! 6) 67 ) ) ) 5) 67 8 )9 % )!&
%%
%%
&4
! 6) 67 ) ) ) 5) 67 8 )9 % )!&
&4
! 6) 67 ) ) ) 5) 67 8 )9 % )!&
%%
%%
%%
%%
&4
! 6) 67 ) ) ) 5) 67 8 )9 % )!&
&4
! 6) 67 ) ) ) 5) 67 8 )9 % )!&
&4
! 6) 67 ) ) ) 5) 67 8 )9 % )!&
2
%%
%%
%%
2
%%
2
%%
2
%%
%%
%%
%% Page 54 of 67
# $ %& '
'.1 0 0
/
-
/
#
-) , & )(
0 2 2
0 2
D
'./
'.1
0
'./
'.1
02
'./
0
'.1
/
/3
'./
'.1
D - Diluted by instrument
(
)* #
+&&(&
Table of Contents
%%
2
%%
2
%%
2
%%
2
%%
2
%%
&4
! 6) 67 ) ) ) 5) 67 8 )9 % )!&
%%
%% &4 &4
By NFUENTES at 11:08 am, Apr 09, 2021
&4% 9
&4% 9
Instrument error, need water
2
%%
By NFUENTES at 11:08 am, Apr 09, 2021
%%
%%
%% Data not used, because is not needed
%% By NFUENTES at 11:07 am, Apr 09, 2021 %%
Page 55 of 67
Date Time
DA-3
4/8/2021 User
NF
4:57:40 PM Software version: 7.0
Sample/ctrl ID Pat/Ctr/cAl Test name Test type Result Result unit Result time STAT
TP-0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
CCB
C
CCV
C
B21D010-MRL1 P
B21D010-BLK1 P
B21D010-BS1 P
2103007-01 P
B21D010-DUP1 P
B21D010-MS1 P
2103007-02 P
2103007-03 P
2103007-04 P
2103007-05 P
CCB
C
CCV
C
2103007-06 P
2103007-07 P
2103007-08 P
2103007-09 P
2103010-01 P
B21D010-DUP2 P
B21D010-MS2 P
2103010-02 P
2103010-03 P
2103007-03 P
CCB
C
CCV
C
2103010-04 P
CCB
C
CCV
C
2103010-01 P
B21D010-DUP2 P
B21D010-MS2 P
2103010-02 P
CCB
C
CCV
C
CCB
C
CCV
C
2103010-01 P
B21D010-DUP2 P
Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P
0.02703 mg/l 0.15605 mg/l 0.30176 mg/l 0.72112 mg/l 0.99025 mg/l 1.72561 mg/l
3.0162 mg/l 1.48758 mg/l 0.03678 mg/l
2.0234 mg/l 0.15322 mg/l 0.02593 mg/l 1.06767 mg/l 1.99852 mg/l 1.92304 mg/l 2.95843 mg/l 1.71794 mg/l 3.44004 mg/l 2.99316 mg/l 2.21613 mg/l 0.02665 mg/l 2.03013 mg/l 1.34727 mg/l 2.79325 mg/l 1.81963 mg/l
0.0242 mg/l 5.43184 mg/l 5.34461 mg/l 6.29726 mg/l 13.62197 mg/l 2.27359 mg/l 3.41338 mg/l 0.02531 mg/l
2.0199 mg/l 0.0408 mg/l 0.02616 mg/l 2.00738 mg/l 5.50305 mg/l 7.94358 mg/l 6.39657 mg/l 17.89696 mg/l 0.21101 mg/l 2.00693 mg/l -0.00354 mg/l 2.04164 mg/l 5.47962 mg/l 5.51893 mg/l
4/8/2021 10:21 4/8/2021 10:22 4/8/2021 10:24 4/8/2021 10:25 4/8/2021 10:26 4/8/2021 10:28 4/8/2021 10:29 4/8/2021 10:52 4/8/2021 11:42 4/8/2021 11:43 4/8/2021 11:43 4/8/2021 11:44 4/8/2021 11:45 4/8/2021 11:46 4/8/2021 11:47 4/8/2021 11:48 4/8/2021 11:49 4/8/2021 11:50 4/8/2021 11:51 4/8/2021 11:52 4/8/2021 11:52 4/8/2021 11:53 4/8/2021 11:54 4/8/2021 11:55 4/8/2021 11:56 4/8/2021 11:57 4/8/2021 11:58 4/8/2021 11:59 4/8/2021 12:00 4/8/2021 12:01 4/8/2021 12:01 4/8/2021 12:03 4/8/2021 12:04 4/8/2021 12:05 4/8/2021 12:06 4/8/2021 12:07 4/8/2021 12:08 4/8/2021 12:10 4/8/2021 12:11 4/8/2021 12:13 4/8/2021 12:15 4/8/2021 12:16 4/8/2021 12:17 4/8/2021 12:52 4/8/2021 12:53 4/8/2021 12:55 4/8/2021 12:56
Status
MA MA MA MA MA MR MA MA MA MA MA MA MA MA MA MA MA AR MA MA MA MA MA MA MA MA AR AR AR AR MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA
Errors
19,
19, 19, 19, 19,
27,
Notes
R
R R R R R
R R R R
Dilution 1 +Manual diluRtei sponse Blank respoMnsain abs. 1Blank abs. 1Sample type
0
0.00291 -0.00031 0.00261 -0.00031
19
0.02323 -0.00034 0.02289 -0.00034
9
0.04618 0.00975 0.05593 0.00975
3
0.11222 0.07613 0.18835 0.07613
2
0.1546 0.00051 0.15511 0.00051
1
0.28019 0.01044 0.29063 0.01044
0
0.47365 0.00264 0.47629 0.00264
1
0.23292 0.00076 0.23368 0.00076
0
0.00445 -0.00018 0.00427 -0.00018
0
0.31731 0.00161 0.31892 0.00161
0
0 0.02279 -0.00046 0.02232 -0.00046 Sample type 1
0
0 0.00274 -0.00047 0.00227 -0.00047 Sample type 1
0
0 0.16679 0.06458 0.23138 0.06458 Sample type 1
0
0 0.31339 0.00181 0.3152 0.00181 Sample type 1
0
0 0.3015 0.00089 0.30239 0.00089 Sample type 1
0
0 0.46456 0.00172 0.46627 0.00172 Sample type 1
0
0 0.2692 0.00111 0.27031 0.00111 Sample type 1
0
0 0.5404 0.02876 0.56916 0.02876 Sample type 1
0
0 0.47003 0.00207 0.4721 0.00207 Sample type 1
0
0 0.34766 0.01366 0.36131 0.01366 Sample type 1
0
0.00285 -0.00055 0.0023 -0.00055
0
0.31837 0.00102 0.31938 0.00102
0
0 0.21083 0.02485 0.23568 0.02485 Sample type 1
0
0 0.43854 0.00167 0.44022 0.00167 Sample type 1
0
0 0.28522 0.00211 0.28733 0.00211 Sample type 1
0
0 0.00247 -0.00058 0.00189 -0.00058 Sample type 1
0
0 0.85407 0.03886 0.89293 0.03886 Sample type 1
0
0 0.84033 0.02699 0.86733 0.02699 Sample type 1
0
0 0.99036 0.00394 0.9943 0.00394 Sample type 1
0
0 2.14387 0.15466 2.29852 0.15466 Sample type 1
0
0 0.35671 0.00602 0.36272 0.00602 Sample type 1
9
0 0.05241 0.00506 0.05748 0.00506 Sample type 1
0
0.00264 -0.0003 0.00234 -0.0003
0
0.31675 0.00339 0.32015 0.00339
0
0 0.00508 0.00343 0.00851 0.00343 Sample type 1
0
0.00278 0.00166 0.00444 0.00166
0
0.31478 0.00167 0.31646 0.00167
9
0 0.08532 0.00133 0.08665 0.00133 Sample type 1
9
0 0.12375 0.0445 0.16825 0.0445 Sample type 1
9
0 0.09939 0.00018 0.09957 0.00018 Sample type 1
9
0 0.2805 0.02513 0.30563 0.02513 Sample type 1
0
0.03189 0.00724 0.03913 0.00724
0
0.31471 0.00099 0.3157 0.00099
0
-0.0019 0.00523 0.00333 0.00523
0
0.32018 0.00249 0.32267 0.00249
9
0 0.08495 0.00039 0.08534 0.00039 Sample type 1
9
0 0.08557 0.00353 0.0891 0.00353 Sample type 1
Table of Contents Page 56 of 67
Table of Contents Page 57 of 67
B21D010-MS2 P
2103010-02 P
CCB
C
CCV
C
TKN-0
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-0
A
TKN-0
A
ICB
C
ICV
C
2103010-03 P
2103010-04 P
B21D011-MRL1 P
B21D011-BLK1 P
B21D011-BS1 P
2103007-01 P
B21D011-DUP1 P
B21D011-MS1 P
2103007-02 P
2103007-03 P
ICB
C
ICV
C
2103007-04 P
2103007-05 P
2103007-06 P
2103007-07 P
2103007-08 P
2103007-09 P
2103010-01 P
B21D011-DUP2 P
B21D011-MS2 P
2103007-01 P
ICB
C
ICV
C
B21D011-DUP1 P
B21D011-MS1 P
2103007-03 P
ICB
C
ICV
C
ICB
C
ICV
C
2103007-04 P
2103007-05 P
2103010-01 P
B21D011-DUP2 P
B21D011-MS2 P
2103010-02 P
ICB
C
ICV
C
ICB
C
ICV
C
2103010-02 P
Total Phos P Total Phos P Total Phos P Total Phos P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P
6.56653 mg/l 19.1745 mg/l
0.0266 mg/l 2.02863 mg/l 0.39238 mg/l 0.33669 mg/l 0.51949 mg/l 0.90879 mg/l 1.84788 mg/l 2.37051 mg/l 5.14492 mg/l 9.98308 mg/l 0.41766 mg/l 0.15867 mg/l 0.23698 mg/l 5.32237 mg/l 9.22313 mg/l 0.24506 mg/l 0.56014 mg/l 0.20815 mg/l 2.02612 mg/l 11.50035 mg/l 11.66875 mg/l 12.78503 mg/l 9.57534 mg/l 32.22951 mg/l 0.24576 mg/l 5.33267 mg/l 32.20405 mg/l 32.20051 mg/l 9.62339 mg/l 4.95252 mg/l 7.16942 mg/l 0.24315 mg/l 15.38466 mg/l 14.99121 mg/l 32.21655 mg/l 10.83648 mg/l 0.25401 mg/l 5.35534 mg/l 11.0004 mg/l 12.46871 mg/l 29.33582 mg/l 0.26628 mg/l 5.40695 mg/l 0.27265 mg/l 5.37355 mg/l 29.42627 mg/l 29.38877 mg/l 16.73119 mg/l 16.19201 mg/l 18.34817 mg/l 32.15372 mg/l 0.28802 mg/l 5.47129 mg/l
mg/l mg/l 67.19382 mg/l
4/8/2021 12:58 4/8/2021 13:00 4/8/2021 13:01 4/8/2021 13:01 4/8/2021 13:50 4/8/2021 13:52 4/8/2021 13:53 4/8/2021 13:55 4/8/2021 13:57 4/8/2021 13:59 4/8/2021 14:00 4/8/2021 14:02 4/8/2021 14:20 4/8/2021 14:42 4/8/2021 15:11 4/8/2021 15:12 4/8/2021 15:13 4/8/2021 15:15 4/8/2021 15:15 4/8/2021 15:16 4/8/2021 15:18 4/8/2021 15:19 4/8/2021 15:19 4/8/2021 15:21 4/8/2021 15:22 4/8/2021 15:23 4/8/2021 15:24 4/8/2021 15:25 4/8/2021 15:26 4/8/2021 15:27 4/8/2021 15:28 4/8/2021 15:29 4/8/2021 15:30 4/8/2021 15:31 4/8/2021 15:32 4/8/2021 15:33 4/8/2021 15:34 4/8/2021 15:36 4/8/2021 15:37 4/8/2021 15:37 4/8/2021 15:40 4/8/2021 15:41 4/8/2021 15:43 4/8/2021 16:10 4/8/2021 16:10 4/8/2021 16:11 4/8/2021 16:13 4/8/2021 16:14 4/8/2021 16:16 4/8/2021 16:18 4/8/2021 16:20 4/8/2021 16:21 4/8/2021 16:23 4/8/2021 16:24 4/8/2021 16:24 4/8/2021 16:27 4/8/2021 16:27 4/8/2021 16:36
MA
MA
MA
MA
MR
MA
MA
MA
MA
MA
MA
MA
MR
MA
MA
MA
MA
MA
MA
MA
MA
AR
19,30, R
AR
19,30, R
AR
3,19,30, R
MA
AR
3,19,30, R
MA
MA
AR
3,19,30, R
AR
3,19,30, R
MA
MA
MA
MA
AR
3,19,30, R
AR
3,19,30, R
AR
3,19,30, R
MA
R
MA
MA
MA
R
MA
R
MA
R
MA
MA
MA
MA
MA
R
MA
R
MA
R
MA
R
MA
R
AR
3,19,30, R
MA
MA
AR
1,
AR
1,
MA
R
9
0 0.10207 0.00028 0.10235 0.00028 Sample type 1
9
0 0.30062 0.00348 0.3041 0.00348 Sample type 1
0
0.00285 -0.00073 0.00211 -0.00073
0
0.31813 0.00068 0.31881 0.00068
0
0.10081 -0.0002 0.10062 -0.0002
39
0.08601 -0.00041 0.08561 -0.00041
19
0.10511 -0.00025 0.10486 -0.00025
9
0.14838 -0.00034 0.14804 -0.00034
4
0.26732 0.00004 0.26736 0.00004
3
0.34242 -0.00023 0.34219 -0.00023
1
0.8479 -0.00018 0.84772 -0.00018
0
2.15926 0.00941 2.16867 0.00941
0
0.10425 -0.00028 0.10396 -0.00028
0
0.06817 -0.00004 0.06812 -0.00004
0
0.07593 0.00025 0.07617 0.00025
0
0.88635 0.00078 0.88712 0.00078
0
0 1.91711 0.00291 1.92001 0.00291 Sample type 1
0
0 0.07673 -0.00011 0.07662 -0.00011 Sample type 1
0
0 0.10946 -0.00002 0.10944 -0.00002 Sample type 1
0
0 0.07305 -0.00002 0.07304 -0.00002 Sample type 1
0
0 0.29222 0.00004 0.29226 0.00004 Sample type 1
0
0 2.65503 0.0013 2.65633 0.0013 Sample type 1
0
0 2.71005 0.00144 2.71149 0.00144 Sample type 1
0
0 3.07479 0.00111 3.0759 0.00111 Sample type 1
0
0 2.02766 0.00026 2.02792 0.00026 Sample type 1
0
0 9.42811 0.00062 9.42873 0.00062 Sample type 1
0
0.07681 -0.00018 0.07662 -0.00018
0
0.8886 -0.00023 0.88837 -0.00023
0
0 9.41979 0.00032 9.42011 0.00032 Sample type 1
0
0 9.41863 0.00013 9.41876 0.00013 Sample type 1
0
0 2.04296 0.00106 2.04402 0.00106 Sample type 1
0
0 0.80705 0.00013 0.80718 0.00013 Sample type 1
0
0 1.33015 0.00032 1.33047 0.00032 Sample type 1
0
0 0.07654 -0.00014 0.0764 -0.00014 Sample type 1
0
0 3.9242 0.00191 3.92611 0.00191 Sample type 1
0
0 3.79564 0.00233 3.79797 0.00233 Sample type 1
0
0 9.42388 0.00209 9.42596 0.00209 Sample type 1
9
0 0.16897 -0.00014 0.16883 -0.00014 Sample type 1
0
0.07763
0 0.07763
0
0
0.89357 -0.00019 0.89338 -0.00019
9
0 0.17093 0.00008 0.17102 0.00008 Sample type 1
9
0 0.18883 -0.00013 0.1887 -0.00013 Sample type 1
9
0 0.43048 0.00006 0.43054 0.00006 Sample type 1
0
0.07887 -0.00004 0.07883 -0.00004
0
0.90493 -0.0001 0.90483 -0.0001
0
0.07951 0.00003 0.07953 0.00003
0
0.89757 -0.00002 0.89755 -0.00002
9
0 0.43196 0.00014 0.43209 0.00014 Sample type 1
9
0 0.43134 0.01389 0.44523 0.01389 Sample type 1
9
0 0.24362 -0.0001 0.24352 -0.0001 Sample type 1
9
0 0.23646 -0.00024 0.23621 -0.00024 Sample type 1
9
0 0.26552 -0.00018 0.26535 -0.00018 Sample type 1
0
0 9.40335 0.02265 9.426 0.02265 Sample type 1
0
0.08106 -0.00009 0.08097 -0.00009
0
0.91918 -0.00023 0.91895 -0.00023
0
0
9
0 1.21468 -0.00029 1.21439 -0.00029 Sample type 1
Table of Contents Page 58 of 67
ICB
C
TKN_351.2 P
0.15742 mg/l
4/8/2021 16:51
MA
ICV
C
TKN_351.2 P
5.3114 mg/l
4/8/2021 16:52
MA
B21D011-BLK1 P
TKN_351.2 P
0.20618 mg/l
4/8/2021 16:53
MA
ICB
C
TKN_351.2 P
0.25533 mg/l
4/8/2021 16:54
MA
ICV
C
TKN_351.2 P
5.36155 mg/l
4/8/2021 16:55
MA
0
0.06804 0.02974 0.09778 0.02974
0
0.88395 0.00306 0.88701 0.00306
0
0 0.07286 0.00259 0.07545 0.00259 Sample type 1
0
0.07776 -0.00032 0.07744 -0.00032
0
0.89493 -0.00022 0.89472 -0.00022
Table of Contents
ANALYSIS REAGENTS/STANDARDS
20G1701
Page 59 of 67
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
7/17/2020
Parameter / SOP #: TKN/ SOP AIG035B VER #8 Reagent: TKN - Sodium salicylate/sodium nitroprusside sol. LIMS ID: 20G1701
Chemical Name (Formula)
Sodium Nitroprusside (Na2Fe(CN)5NO*2H2O
Prepared by: Nidia Fuentes Preparation Date: Jul-17-20 Expiration Date: Jul-17-21
LIMS ID
19F1901
Mass or Volume (specify units)
0.0314 g
Sodium Salicylate (NaC7H5O3)
19L1207
15.1707 g
Total Volume : 100 mL Comments : Balance #17. Reviewed w/ 2006014
By AK at 10:43 am, Aug 26, 2020
Analyst Signature:
Page 6P0aogfe 617of 1
Table of Contents Page 61 of 67
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21B0411
Page 62 of 67
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
2/4/2021
Parameter / SOP #: SOP AIG 035B VER #8 Reagent: TKN-Working Buffer Solution LIMS ID: 21B0411
Chemical Name (Formula)
Stock Sodium Potassium Tartrate (C4H4KNaO6*4H2O)
Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22
LIMS ID
21B0408
Mass or Volume (specify units)
25 mL
Stock Buffer Solution
21B0409
20 mL
Stock Sodium Hydroxide (NaOH)
21B0410
25 mL
Total Volume : Comments : Reviewed w/
100 mL
By AK at 2:08 pm, Mar 04, 2021
Analyst Signature:
Page 6P3aogfe 617of 1
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21D0808
Page 64 of 67
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
4/8/2021
Parameter / SOP #: TKN /AIG035B_VERSION 8 Reagent: TKN-Sodium Hypochlorite LIMS ID: 21D0808
Chemical Name (Formula)
Sodium Hypochlorite (NaOCl)
Prepared by: Nidia Fuentes Preparation Date: Apr-08-21 Expiration Date: Apr-09-21
LIMS ID
21C0923
Mass or Volume (specify units)
1.2 mL
Total Volume : Comments :
10 mL
By AK at 10:33 am, Apr 14, 2021
Analyst Signature:
PPagagee6P51aogfe 6117of 1
Table of Contents Page 66 of 67
Table of Contents Page 67 of 67
Table of Contents
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 ANALYTICAL SERVICES BRANCH LABORATORY
536 SOUTH CLARK STREET (LAB-10C) CHICAGO, ILLINOIS 60605
ELECTRONIC LABORATORY DATA PACKAGE FINAL LEVEL IV COVER PAGE
LIMS Work order(s): Primary Analyst: Analysis: Date: Data Reporting Qualtrax Workflow ID:
Digital Signature of Primary Analyst:
2103010 Nidia Fuentes Total Phosphorus DA May 03, 2021 24874
Digital Signature Agreement: By signing above the primary analyst understands and agrees that they will be held legally bound, obligated, and responsible for the use of their digital signature as they would be by using their hand-written signature.
Page 1 of 69
Client Project Name: Work Order Number:
Deardorff (BA-01-21) 2103010
1 Cover Page 2 Level I Report 3 QC Summary 4 Checklist 5 Sample Prep and Supporting Data (Total Phosphorus DA)
5.1 Bench Sheets (B21D010) 5.2 Batch Reagents (B21D010) 5.3 Analysis Data and Supporting Documents (21D0801) 5.4 Standards (21D0711) 5.5 Standards (21D0712) 5.6 Standards (21D0713) 5.7 Standards (21D0714) 5.8 Standards (21D0715) 5.9 Standards (21D0803) 5.10 Standards (21D0804) 5.11 Standards (21D0805) 5.12 Standards (21D0806) 5.13 Standards (21D0807) 5.14 Sequence Reagents (21D0801)
Table of Contents
Table of Contents
1 3 11 13 17 18 22 37 47 48 49 50 51 56 57 58 59 60 61
536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 FAX: 312-353-9069
Page 2 of 69
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605
Table of Contents
Date:
5/3/2021
Title: To:
From:
ASB Data Report for Deardorff
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604
Nidia Fuentes, Chemist fuentes.nidia@epa.gov US EPA Region 5 LSASD Analytical Services Branch
The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures.
This report was reviewed and the information provided herein accurately represents the analysis performed.
Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you.
Attached are Results for: Deardorff
Analyses included in this report: Total Phosphorus DA
Report Name: 2103010 Total Phosphorus DA FINAL May 03 21 0830
Page 3 of 69
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Accredited Analyses included in this Report
Table of Contents
Reported: May-03-21 08:30
Method: Analysis: Analyte
EPA 365.4 in Water Total Phosphorus DA
Total Phosphorus
Certifications ISO/IEC 17025:2017
Analytes not listed above are not accredited by ANAB.
Report Name: 2103010 Total Phosphorus DA FINAL May 03 21 0830
Page 4 of 69
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-03-21 08:30
ANALYSIS CASE NARRATIVE
Analysis List Total Phosphorus DA
Analyst: Nidia Fuentes Phone #: 312-353-9079
General Information
Samples analyzed:
Sample
Analysis List
2103010-01
Total Phosphorus DA
2103010-02
Total Phosphorus DA
2103010-03
Total Phosphorus DA
2103010-04
Total Phosphorus DA
Holding times: All holding times were met.
Sample Analysis and Results
The samples were analyzed using ASB SOP AIG034B, Version #7. The samples were stored in the refrigerator at all times, except when in use. The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated "FY 2021", except for those listed in the Quality Control section.
SOP Based on: Method List EPA 365.4
Quality Control
All quality control audits were within ASB limits or did not result in qualification of the data except for any listed below.
Report Name: 2103010 Total Phosphorus DA FINAL May 03 21 0830
Page 5 of 69
3019234515671897 4355871839517195743591854
!"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291
Table of Contents
?@A@<0
BCDEDCD :;0 7351;;<19839;74237=>491
43187GKENEDNBDBCCKEDKB O
3718K ?9874<323=351F:;0 7351 45J78K<794G54HH
45J78O91974K 179@ P49==9<923= 45J78LM674K >IDCIBC
7Q548R5K [%.Y$'.V. S"%#T'U'V'.&WX-YZ%)'.
T"%T%/ Z%(%'U%][_/ +))%]*.[_/
`"_41^4211/,,0^]"_aYa3 Zb%#._]%# Zb%#._]%#
66S%V\"($V.[!%U"#] '(")&*+,,^ T"%Z%(%'U%]/ `"#4,4211,/,5 T"%+))%]*./ `"#4,42111/1
-.%/012342,,^ 7"8/01235542,,1
"cd!%")Ve!"b%!V %"!V*."( Z%(%'U%].'(% -"d%#f#$*.(!]%]
g7= ?54P@4G74566718=K g7= dhd"d%#V%]'. i15T19,1 g7= g7=
!%#0V3'.j#c"'./ T%j"! !%#4,k^,
;96Q7l<K BCDEDCDIDC ;96Q7GK O94IBqIBCCDKCq
;96Q7L967K ;DC
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
atrTY
25
a"!-Vd#VTY
25
O9843mK ?9874 ;96Q7598351N566718=K 9=8M475M878
0mQ347= Yd#424211,/1 Yd#424211,/1 Yd#4,24211,/1 Yd#4,24211,/1 Yd#424211,/1 Yd#424211,/1
566718= dhi1 dhi1 dhi6 dhi6 dhi1 dhi1
;96Q7l<K BCDEDCDIDB ;96Q7GK O94IBqIBCCDKBu
;96Q7L967K ;DB
;96Q7566718=K
19 =3= Ycc.'"rTY&T'V'!!%]
n5G8367oG9=p 25
r'#"%4r'#'%rTY&X.s_c"'(#%]('.
25
!']V&aT
6
!']V&a
6
O9843mK ?9874 ;96Q7598351N566718=K 799873178
0mQ347= Yd#424211,/2^ Yd#424211,/2^ Yd#4,24211,/2^ Yd#4,24211,/2^
566718= dhi1 dhi1 dhi6 dhi6
Page 6 of 69
Table of Contents Page 7 of 69
Table of Contents Page 8 of 69
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Table of Contents
Reported: May-03-21 08:30
S01 (2103010-01)
Analyte Total Phosphorus
S02 (2103010-02)
Analyte Total Phosphorus
S03 (2103010-03)
Analyte Total Phosphorus
B01 (2103010-04)
Analyte Total Phosphorus
Phosphorus, Colorimetric, EPA 365.4 (modified) US EPA Region 5 LSASD Analytical Services Branch
Matrix: Water Sampled: Mar-26-21 10:16
Result
Flags / Qualifiers
MDL
Reporting Limit
5.48
0.60
1.50
Received: Mar-30-21 10:08
Units mg/L
Dilution 10
Batch B21D010
Matrix: Water Sampled: Mar-26-21 10:24
Result
Flags / Qualifiers
MDL
Reporting Limit
19.2
0.60
1.50
Received: Mar-30-21 10:08
Units mg/L
Dilution 10
Batch B21D010
Matrix: Water Sampled: Mar-26-21 11:47
Result
Flags / Qualifiers
MDL
Reporting Limit
2.27
0.06
0.15
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D010
Matrix: Water Sampled: Mar-26-21 16:10
Result
Flags / Qualifiers
MDL
Reporting Limit
U
0.06
0.15
Received: Mar-30-21 10:08
Units mg/L
Dilution 1
Batch B21D010
Prepared Apr-07-21
Analyzed Apr-08-21
Prepared Apr-07-21
Analyzed Apr-08-21
Prepared Apr-07-21
Analyzed Apr-08-21
Prepared Apr-07-21
Analyzed Apr-08-21
Report Name: 2103010 Total Phosphorus DA FINAL May 03 21 0830
Page 9 of 69
Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604
U
Not Detected
NR
Not Reported
Q
QC limit Exceeded
Environmental Protection Agency Region 5
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Project: Deardorff Project Number: BA-01-21 Project Manager: Ben Atkinson
Notes and Definitions
Table of Contents
Reported: May-03-21 08:30
Report Name: 2103010 Total Phosphorus DA FINAL May 03 21 0830
Page 10 of 69
Environmental Protection Agency
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Table of Contents
Date: Project:
5/3/2021 Deardorff
Analyte: Total Phosphorus
Analysis: Total Phosphorus DA
Quality Control Summary
Analyst: Nidia Fuentes
QC Sample Name 21D0801-CAL1
Result 0.03
Units mg/L
Flags / Qualifiers
MDL
Reporting Limit
Spike Level
0.06
0.15
0.000
Source Result
% REC or abs diff (pH)
% REC or abs diff
(pH) Limits
%
% RPD or abs diff (pH)
%RPD or abs diff ( pH)
Limits
21D0801-CAL2
0.16
mg/L
0.06
0.15
0.1500
104%
21D0801-CAL3
0.30
mg/L
0.06
0.15
0.3000
101%
21D0801-CAL4
0.72
mg/L
0.06
0.15
0.7500
96%
21D0801-CAL5
0.99
mg/L
0.06
0.15
1.000
99%
21D0801-CAL6
1.49
mg/L
0.06
0.15
1.500
99%
21D0801-CAL7
3.02
mg/L
0.06
0.15
3.000
101%
21D0801-CCB1
0.03
mg/L
0.06
0.15
21D0801-CCB2
0.03
mg/L
0.06
0.15
21D0801-CCB3
0.03
mg/L
0.06
0.15
21D0801-CCB4
-0.0040
mg/L
0.06
0.15
21D0801-CCB5
0.03
mg/L
0.06
0.15
21D0801-CCV1
2.03
mg/L
0.06
0.15
2.000
102%
92-112
21D0801-CCV2
2.02
mg/L
0.06
0.15
2.000
101%
92-112
21D0801-CCV3
2.01
mg/L
0.06
0.15
2.000
100%
92-112
21D0801-CCV4
2.04
mg/L
0.06
0.15
2.000
102%
92-112
21D0801-CCV5
2.03
mg/L
0.06
0.15
2.000
101%
92-112
21D0801-ICB1
0.04
mg/L
0.06
0.15
21D0801-ICV1
2.02
mg/L
0.06
0.15
2.000
101%
92-112
Report Name: 2103010 Total Phosphorus DA FINAL May 03 21 0830
Page 11 of 69
Environmental Protection Agency
US EPA Region 5 LSASD Analytical Services Branch
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Table of Contents
Date: 5/3/2021 Project: Deardorff
Analyte: Total Phosphorus Analysis: Total Phosphorus DA
Quality Control Summary
Analyst: Nidia Fuentes
QC Sample Name B21D010-BLK1
Result U
Units mg/L
Flags / Qualifiers
MDL
Reporting Limit
Spike Level
0.06
0.15
Source Result
% REC or abs diff (pH)
% REC or abs diff
(pH) Limits
% RPD or abs diff (pH)
%RPD or abs diff ( pH)
Limits
B21D010-BS1
1.07
mg/L
0.06
0.15
1.000
107%
89-111
B21D010-DUP2 Source: 2103010-01
B21D010-MRL1
5.52
mg/L
0.15
mg/L
0.60
1.50
5.48
0.7
10
0.1500
102%
68-132
B21D010-MS2 Source: 2103010-01
6.57
mg/L
0.60
1.50
1.000 5.48
109%
79-124
U
Not Detected
NR
Not Reported
Q
QC limit Exceeded
Notes and Definitions
Nidia Fuentes
Report Name: 2103010 Total Phosphorus DA FINAL May 03 21 0830
Page 12 of 69
Work:
2103010
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 LSASD ANALYTICAL SERVICE BRANCH 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605
Data Verification Checklist
Project: Deardorff
Analysis: Total Phosphorus DA
CRL SOP Used:
AIG034B v7
Batch ID:
General Information
B21D010
Question #
1
Question Did samples meet the laboratory's standard conditions of sample acceptability upon receipt?
2
Was customer contact communication included?
3
Are all field sample ID numbers cross-referenced to the laboratory ID numbers?
4
Were all samples prepared and analyzed within holding times?
Question # 5 6 7 8 9 10 11 12 13
Sample Results
Were calculations checked?
Question
Were all analyte results checked?
Were all results for soil and sediment samples reported on a dry weight basis?
Were % moisture (or solids) reported for all soil and sediment samples?
Other than those results < RL, were all other raw values bracketed by calibration standards?
Are the RLs for each method analyte included in the laboratory data package?
Are MDLs/RLs adjusted for dilutions?
Were the raw data (for example, chromatograms, spectral data) reviewed?
Were data associated with manual integrations flagged on the raw data?
Question # 14
15
Standards
Question Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources as specified in the analytical SOP? Were standard/reagent preparations checked (preparation date, expiration date, parent standard IDs, etc.), if applicable?
Batch Quality Control
Print Date: 4/9/2021
Table of Contents
Analyst Response (YES/ NO/ NA) YES 1$ YES YES
Analyst Response (YES/ NO/ NA) YES YES NA NA YES YES YES NA NA
Analyst Response (YES/ NO/ NA) YES YES
Page 13 of 69
Work:
2103010
Project: Deardorff
Question # 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Batch Quality Control
Were appropriate type(s) of blanks analyzed?
Question
Were blanks analyzed at the appropriate frequency?
Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures?
Were blank concentrations <= MDL or RL, as applicable in the analytical SOP?
Was each LCS/SRM taken through the entire analytical procedure, including prep and cleanup steps?
Were LCSs/SRMs analyzed at the required frequency?
Were LCS/SRM %Rs within the laboratory QC limits or other acceptance criteria?
Were the project/method specified analytes included in the MS?
Were MS analyzed at the appropriate frequency?
Were MS %Rs within the laboratory QC limits?
Were appropriate analytical duplicates analyzed for each matrix?
Were analytical duplicates analyzed at the appropriate frequency?
Were RPDs or relative standard deviations within the laboratory QC limits or other acceptance criteria?
Were RLs analyzed at the appropriate frequency?
Were RL recoveries within the laboratory QC limits?
Question # 31
32
33
34
Calibration
Question Were calibration correlation coefficient or other acceptance criteria met? Was the number of calibration standards recommended in the method used for all analytes? Were all points generated between the lowest and highest standard used to calculate the curve? Are calibration data available for all instruments used?
Question # 35
36
37
Calibration Verification
Question Was the absolute value of the analyte concentration in the ICB/CCB <= MDL or RL, as applicable in the analytical SOP? Was the calibration curve verified for each analyte?
Has the calibration curve been verified using an appropriate second source standard?
Print Date: 4/9/2021
Table of Contents
Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES
Analyst Response (YES/ NO/ NA) YES YES YES YES
Analyst Response (YES/ NO/ NA) YES YES YES
Page 14 of 69
Work:
2103010
Project: Deardorff
Question # 38
39
Calibration Verification
Question Were ICV/CCV analyzed at the method-required frequency? Were ICV/CCV %R within the laboratory QC limits?
Question # 40
41
42
Quality Control
QC limits in LIMS checked against the SOP?
Question
Were percent differences, recoveries, and the linearity within the QC limits specified in the method?
Were QC charts checked if a QC audit, excluding matrix QC (MS or DUP), was out of limit?
Question # 43
44
Supporting Data
Question Were support equipment data (balance verification, data logs, logbook entries, etc.) included in data package? Were approved spreadsheet(s) used?
Question # 45 46 47 48 49 50
Question # 51
Document Verification
Question Is the MDL or RL study up-to-date for each reported analyte?
Is documentation of the analyst's capability up-to-date and on file?
ID 24411
Are the procedures for compound/analyte identification documented?
Are laboratory SOPs current and on file for the method performed?
Were data evaluated against project QAPP or Sample Plan, any special requests in the sample schedule, and documented in case narrative? Were electronic pathways checked (add pathway and files below)? Notes/Comments: I:\Vol1\Projects (New File Structure)\Deardorff\1. A&I\NFuentes\DA3\04082021-TPTKN\ARC_70.bak
Accreditation
ANAB logo used appropriately?
Question
Analyst's Signature and Date*:
By NFUENTES at 1:08 pm, Apr 09, 2021
Print Date: 4/9/2021
Table of Contents
Analyst Response (YES/ NO/ NA) YES YES
Analyst Response (YES/ NO/ NA) YES YES NA
Analyst Response (YES/ NO/ NA) YES YES
Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES
Analyst Response (YES/ NO/ NA) YES
Page 15 of 69
Work:
2103010
Reviewer's Signature and Date*: Additional Notes/Comments (if applicable):
Project: Deardorff
Table of Contents
By AK at 12:10 pm, Apr 29, 2021
*Reviewer Concurs with Analyst Responses
Print Date: 4/9/2021
Page 16 of 69
Table of Contents
Total Phosphorus DA
Page 17 of 69
BATCH
B21D010
[TOC_1]Benchsheets[TOTCa]ble of Contents
Page 18 of 69
Table of Contents Page 19 of 69
Prepared Date: Analyst (initials):
Apr-07-21 NF
Position #
17
Sample Number 2103007-01
21 2103007-02
22 2103007-03
23 2103007-04
24 2103007-05
25 2103007-06
26 2103007-07
27 2103007-08
28 2103007-09
29 2103010-01
33 2103010-02
34 2103010-03
35 2103010-04
5 B21D010-BLK1
Source ID (MS and DUP only)
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
TP/TKN DIGESTION LOG
Date: 4/7/2021
Batch Number: B21D010
Analyses Included On This Benchsheet
Total Phosphorus DA
Spike ID
Spike Volume (uL)
Spike Final Volume (mL)
(MRL, BS, MS only)
Sample Volume (mL) 10 10 10 10 10 10 10 10 10 10 10 10 10
pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1
10
Comments
Page 1 of 3
Prepared Date: Analyst (initials):
Apr-07-21 NF
Position #
4
Sample Number B21D010-BS1
18 B21D010-DUP1
30 B21D010-DUP2
3 B21D010-MRL1
19 B21D010-MS1
31 B21D010-MS2
Batch Comments:
Source ID (MS and DUP only)
2103007-01 2103010-01
2103007-01 2103010-01
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
TP/TKN DIGESTION LOG
Date: 4/7/2021
Batch Number: B21D010
Analyses Included On This Benchsheet
Total Phosphorus DA
Spike ID 21D0715
21D0714 21D0715 21D0715
Spike Volume (uL) 100
100 100
Spike Final Volume (mL)
(MRL, BS, MS only)
10
10 10
Sample Volume (mL) 10 10 10 10 10 10
Comments
PREPARATION REAGENTS/STANDARDS/PIPETTES:
21D0715: TP-Stock Cal Standard (SCS)
Prepared: Apr-07-21
21D0714: TP - MRL (0.15 mg P/L)
Prepared: Apr-07-21
21B2306: Pipette (Electronic) -- 50 -1,000 uL
Prepared: Feb-15-21
21B2307: Pipette (Electronic) -- 200 -5000 uL
Prepared: Feb-15-21
21B2308: Pipette (Electronic) -- 500 - 10,000 uL
Prepared: Feb-15-21
21B2309: Pipette (Electronic) -- 5 -100 uL
Prepared: Feb-15-21
21C0906: TP/TKN Digestion Solution
Prepared: Mar-09-21
Expires: Apr-07-22
May-07-21
Expires: Jul-11-21
By NFUENTES at 8:22 am, Apr 12, 2021
Expires: Aug-31-21
Expires: Aug-31-21
Expires: Aug-31-21
Expires: Aug-31-21
Expires: Mar-09-22
Table of Contents Page 20 of 69
Page 2 of 3
Prepared Date: Analyst (initials):
Apr-07-21 NF
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
TP/TKN DIGESTION LOG
Date: 4/7/2021
Batch Number: B21D010
Analyses Included On This Benchsheet
Total Phosphorus DA
Hot Block ID: #9
Block Digital Temp 1 Reading (C ) - Start - Stop Time/ Block Digital Temp 2 Reading (C ) - Start - Stop Time:
33
34
35
36
200C-11:50 AM -12:50 PM/ 380C-12:50 PM - 2:20PM
37
38
25
26
27
28
29
30
39
DB
31
40
DB
32
17
18
19
20
21
22
23
24
9
10
11
12
13
14
15
16
1
2
3
4
5
6
7
8
TP
TP
Calibration
ICV/CCV
DB= Dilution Blank
Table of Contents Page 21 of 69
Page 3 of 3
BATCH REAGENTS
21B2306
Table of Contents
Page 22 of 69
Table of Contents Page 23 of 69
Table of Contents Page 24 of 69
BATCH REAGENTS
21B2307
Table of Contents
Page 25 of 69
Table of Contents Page 26 of 69
Table of Contents Page 27 of 69
BATCH REAGENTS
21B2308
Table of Contents
Page 28 of 69
Table of Contents Page 29 of 69
Table of Contents Page 30 of 69
BATCH REAGENTS
21B2309
Table of Contents
Page 31 of 69
Table of Contents Page 32 of 69
Table of Contents Page 33 of 69
BATCH REAGENTS
21C0906
Table of Contents
Page 34 of 69
Environmental Protection Agency Region 5
Chicago Regional Laboratory
Table of Contents
Print Date:
3/9/2021
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Parameter / SOP #:
Reagent Preparation Bench Sheet
By NFUENTES at 11:10 am, Mar 31, 2021
By NFUENTES at 11:10 am, Mar 31, 2021
034B
035B
TP/TKN SOP AIG34B ver#7, AIG35B ver#8
Prepared by:
Nidia Fuentes
Reagent: TP/TKN Digestion Solution
Preparation Date: Mar-09-21
LIMS ID: 21C0906
Expiration Date: Mar-09-22
Chemical Name (Formula)
Sulfuric Acid (H2S04)
LIMS ID
20B0607
Mass or Volume (specify units)
200 mL
Mercuric Sulfate solution
19H0504
25 mL
Potassium Sulfate (K2SO4)
20J2902
133.0398 g
Total Volume : Comments : Balance #17
1000 500 mL
By NFUENTES at 11:10 am, Mar 31, 2021
Analyst Signature:
By AK at 8:15 am, Apr 01, 2021
Page 3P5aogfe 619of 1
Table of Contents Page 36 of 69
SEQUENCE
21D0801
[TOC_1]Sequence[TOC] Table of Contents
Sequence Date: 04/08/2021 Instrument: DA-3 Sequence Analyses: Total Phosphorus DA
Page 37 of 69
Instrument:
Order
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23
ANALYSIS SEQUENCE 21D0801
DA-3 Container
A B A B B B B
Analysis Date: Apr-08-21
Lab Number
Sample name or QC sample designation
21D0801-CAL1
Cal Standard
21D0801-CAL2
Cal Standard
21D0801-CAL3
Cal Standard
21D0801-CAL4
Cal Standard
21D0801-CAL5
Cal Standard
21D0801-CAL7
Cal Standard
21D0801-CAL6
Cal Standard
21D0801-ICB1
CCB
21D0801-ICV1
CCV
B21D010-MRL1
MRL Check
B21D010-BLK1
Blank
B21D010-BS1
LCS
2103007-01
S01
B21D010-DUP1
Duplicate
B21D010-MS1
Matrix Spike
2103007-02
S02
2103007-04
S04
2103007-05
S05
21D0801-CCB1
CCB
21D0801-CCV1
CCV
2103007-06
S06
2103007-07
S07
2103007-08
S08
Calibration ID:
UNASSIGNED
Analysis QC QC QC QC QC QC QC QC QC QC QC QC Total Phosphorus DA QC QC Total Phosphorus DA Total Phosphorus DA Total Phosphorus DA QC QC Total Phosphorus DA Total Phosphorus DA Total Phosphorus DA
Matrix: Water STD ID 21D0711 21D0803 21D0804 21D0805 21D0806 21D0712 21D0807
21D0713
Printed: 4/13/2021 2:21:18PM Comments
pH = 1
21D0713
pH = 1 pH = 1 pH = 1
pH = 1 pH = 1 pH = 1
Table of Contents Page 38 of 69
Page 1 of 3
Order
24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39
Container Lab Number
B
2103007-09
B
2103010-03
A
2103007-03
21D0801-CCB2
21D0801-CCV2
B
2103010-04
21D0801-CCB3
21D0801-CCV3
21D0801-CCB4
21D0801-CCV4
A
2103010-01
B21D010-DUP2
B21D010-MS2
B
2103010-02
21D0801-CCB5
21D0801-CCV5
Sample name or QC sample designation
B01 S03 S03 CCB CCV B01 CCB CCV CCB CCV S01 Duplicate Matrix Spike S02 CCB CCV
Analysis Total Phosphorus DA Total Phosphorus DA Total Phosphorus DA QC QC Total Phosphorus DA QC QC QC QC Total Phosphorus DA QC QC Total Phosphorus DA QC QC
STD ID
21D0713 21D0713 21D0713
pH = 1 pH = 1 pH = 1
Comments
pH = 1
pH = 1
21D0713
pH = 1
Table of Contents Page 39 of 69
Page 2 of 3
Order
Container Lab Number
Sample name or QC sample designation
PREPARATION REAGENTS/STANDARDS/PIPETTES:
21D0715: TP-Stock Cal Standard (SCS)
Prepared: Apr-07-21
21D0714: TP - MRL (0.15 mg P/L)
Prepared: Apr-07-21
21D0711: TP - WCS (0.00 mg P/L)
Prepared: Apr-07-21
21D0712: TP - WCS (3.00 mg P/L)
Prepared: Apr-07-21
21D0713: TP - WcS (2.00 mg P/L)
Prepared: Apr-07-21
21D0803: TP - WCS (0.15 mg P/L)
Prepared: Apr-08-21
21D0804: TP - WCS (0.3 mg P/L)
Prepared: Apr-08-21
21D0805: TP - WCS (0.75 mg P/L)
Prepared: Apr-08-21
21D0806: TP - WCS (1.0 mg P/L)
Prepared: Apr-08-21
21D0807: TP - WCS (1.5 mg P/L)
Prepared: Apr-08-21
21B2417: TP-NaCl Solution
Prepared: Feb-24-21
21B2421: TP-MolybdateAntimonySolution
Prepared: Feb-24-21
21D0801: TP- Ascorbic Acid
Prepared: Apr-08-21
Analysis
Expires: Apr-07-22 Expires: May-07-21 Expires: May-07-21 Expires: May-07-21 Expires: May-07-21 Expires: Apr-09-21 Expires: Apr-09-21 Expires: Apr-09-21 Expires: Apr-09-21 Expires: Apr-09-21 Expires: Feb-24-22 Expires: Feb-24-22 Expires: Apr-22-21
STD ID
Comments
Table of Contents Page 40 of 69
Page 3 of 3
#$ %% & '
!
"
()))* + *( +
!
#
*( +
"
(
$
%
(
(
(
(
(*
(
(
(
( ++
(
(
(
(
&
'
!
(
(
,
( +* +
(+
,
(*
(
,
(
(+
,
()) +
(
,
(+
(+
,
(*
(
,
Table of Contents
Page 41 of 69
Table of Contents
! " #$ %
,,,,/ -
-
,,,,/
0 -02 -! 3
+ ! 3 3 3 31
3. 33 3 3
-
+
-
!
3 ,,,,/
,,,,/
-
+
-
!
+& *$&
'
'.
'
'
'
'1
'
'1
'
' .33
'
'1
'
'
'
'1
'
'3 3
'
D
'
'
'
'.
'
' .3
'
'
'
'3
'
'3
'
'.
'
'
'
D
'
D
'
D
'
D
'
'3.
'
'
'
'1
'
'
'
'
'
'.
'
'3
'
1'1
'
3' .
'
.' ..
&' ( !
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
$4
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
$4
'
$4
'
$4
'
$4
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
)$$ $
& ' & & 5&
& ' & & 5& & ' & & 5& & ' & & 5& & ' & & 5&
Not used because of failing QC By NFUENTES at 3:42 pm, Apr 08, 2021 Page 42 of 69
! " #$ %
,,,,/ ,,,,/
-
+
-
!
,,,,/
+& *$&
'
3' 3
'
'
'
'.
'
'1
'
'.
'
1' 3 .
'
1'1
'
.'1..1
'
'31
'
' ..
'
'.
D - diluted by instrument
&' ( !
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
'
##
)$$ $ 6,7
Table of Contents
*& 8
By NFUENTES at 3:42 pm, Apr 08, 2021
Page 43 of 69
Date Time
DA-3
4/8/2021 User
NF
4:57:40 PM Software version: 7.0
Sample/ctrl ID Pat/Ctr/cAl Test name Test type Result Result unit Result time STAT
TP-0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
TP-3.0
A
CCB
C
CCV
C
B21D010-MRL1 P
B21D010-BLK1 P
B21D010-BS1 P
2103007-01 P
B21D010-DUP1 P
B21D010-MS1 P
2103007-02 P
2103007-03 P
2103007-04 P
2103007-05 P
CCB
C
CCV
C
2103007-06 P
2103007-07 P
2103007-08 P
2103007-09 P
2103010-01 P
B21D010-DUP2 P
B21D010-MS2 P
2103010-02 P
2103010-03 P
2103007-03 P
CCB
C
CCV
C
2103010-04 P
CCB
C
CCV
C
2103010-01 P
B21D010-DUP2 P
B21D010-MS2 P
2103010-02 P
CCB
C
CCV
C
CCB
C
CCV
C
2103010-01 P
B21D010-DUP2 P
Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P
0.02703 mg/l 0.15605 mg/l 0.30176 mg/l 0.72112 mg/l 0.99025 mg/l 1.72561 mg/l
3.0162 mg/l 1.48758 mg/l 0.03678 mg/l
2.0234 mg/l 0.15322 mg/l 0.02593 mg/l 1.06767 mg/l 1.99852 mg/l 1.92304 mg/l 2.95843 mg/l 1.71794 mg/l 3.44004 mg/l 2.99316 mg/l 2.21613 mg/l 0.02665 mg/l 2.03013 mg/l 1.34727 mg/l 2.79325 mg/l 1.81963 mg/l
0.0242 mg/l 5.43184 mg/l 5.34461 mg/l 6.29726 mg/l 13.62197 mg/l 2.27359 mg/l 3.41338 mg/l 0.02531 mg/l
2.0199 mg/l 0.0408 mg/l 0.02616 mg/l 2.00738 mg/l 5.50305 mg/l 7.94358 mg/l 6.39657 mg/l 17.89696 mg/l 0.21101 mg/l 2.00693 mg/l -0.00354 mg/l 2.04164 mg/l 5.47962 mg/l 5.51893 mg/l
4/8/2021 10:21 4/8/2021 10:22 4/8/2021 10:24 4/8/2021 10:25 4/8/2021 10:26 4/8/2021 10:28 4/8/2021 10:29 4/8/2021 10:52 4/8/2021 11:42 4/8/2021 11:43 4/8/2021 11:43 4/8/2021 11:44 4/8/2021 11:45 4/8/2021 11:46 4/8/2021 11:47 4/8/2021 11:48 4/8/2021 11:49 4/8/2021 11:50 4/8/2021 11:51 4/8/2021 11:52 4/8/2021 11:52 4/8/2021 11:53 4/8/2021 11:54 4/8/2021 11:55 4/8/2021 11:56 4/8/2021 11:57 4/8/2021 11:58 4/8/2021 11:59 4/8/2021 12:00 4/8/2021 12:01 4/8/2021 12:01 4/8/2021 12:03 4/8/2021 12:04 4/8/2021 12:05 4/8/2021 12:06 4/8/2021 12:07 4/8/2021 12:08 4/8/2021 12:10 4/8/2021 12:11 4/8/2021 12:13 4/8/2021 12:15 4/8/2021 12:16 4/8/2021 12:17 4/8/2021 12:52 4/8/2021 12:53 4/8/2021 12:55 4/8/2021 12:56
Status
MA MA MA MA MA MR MA MA MA MA MA MA MA MA MA MA MA AR MA MA MA MA MA MA MA MA AR AR AR AR MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA
Errors
19,
19, 19, 19, 19,
27,
Notes
R
R R R R R
R R R R
Dilution 1 +Manual diluRtei sponse Blank respoMnsain abs. 1Blank abs. 1Sample type
0
0.00291 -0.00031 0.00261 -0.00031
19
0.02323 -0.00034 0.02289 -0.00034
9
0.04618 0.00975 0.05593 0.00975
3
0.11222 0.07613 0.18835 0.07613
2
0.1546 0.00051 0.15511 0.00051
1
0.28019 0.01044 0.29063 0.01044
0
0.47365 0.00264 0.47629 0.00264
1
0.23292 0.00076 0.23368 0.00076
0
0.00445 -0.00018 0.00427 -0.00018
0
0.31731 0.00161 0.31892 0.00161
0
0 0.02279 -0.00046 0.02232 -0.00046 Sample type 1
0
0 0.00274 -0.00047 0.00227 -0.00047 Sample type 1
0
0 0.16679 0.06458 0.23138 0.06458 Sample type 1
0
0 0.31339 0.00181 0.3152 0.00181 Sample type 1
0
0 0.3015 0.00089 0.30239 0.00089 Sample type 1
0
0 0.46456 0.00172 0.46627 0.00172 Sample type 1
0
0 0.2692 0.00111 0.27031 0.00111 Sample type 1
0
0 0.5404 0.02876 0.56916 0.02876 Sample type 1
0
0 0.47003 0.00207 0.4721 0.00207 Sample type 1
0
0 0.34766 0.01366 0.36131 0.01366 Sample type 1
0
0.00285 -0.00055 0.0023 -0.00055
0
0.31837 0.00102 0.31938 0.00102
0
0 0.21083 0.02485 0.23568 0.02485 Sample type 1
0
0 0.43854 0.00167 0.44022 0.00167 Sample type 1
0
0 0.28522 0.00211 0.28733 0.00211 Sample type 1
0
0 0.00247 -0.00058 0.00189 -0.00058 Sample type 1
0
0 0.85407 0.03886 0.89293 0.03886 Sample type 1
0
0 0.84033 0.02699 0.86733 0.02699 Sample type 1
0
0 0.99036 0.00394 0.9943 0.00394 Sample type 1
0
0 2.14387 0.15466 2.29852 0.15466 Sample type 1
0
0 0.35671 0.00602 0.36272 0.00602 Sample type 1
9
0 0.05241 0.00506 0.05748 0.00506 Sample type 1
0
0.00264 -0.0003 0.00234 -0.0003
0
0.31675 0.00339 0.32015 0.00339
0
0 0.00508 0.00343 0.00851 0.00343 Sample type 1
0
0.00278 0.00166 0.00444 0.00166
0
0.31478 0.00167 0.31646 0.00167
9
0 0.08532 0.00133 0.08665 0.00133 Sample type 1
9
0 0.12375 0.0445 0.16825 0.0445 Sample type 1
9
0 0.09939 0.00018 0.09957 0.00018 Sample type 1
9
0 0.2805 0.02513 0.30563 0.02513 Sample type 1
0
0.03189 0.00724 0.03913 0.00724
0
0.31471 0.00099 0.3157 0.00099
0
-0.0019 0.00523 0.00333 0.00523
0
0.32018 0.00249 0.32267 0.00249
9
0 0.08495 0.00039 0.08534 0.00039 Sample type 1
9
0 0.08557 0.00353 0.0891 0.00353 Sample type 1
Table of Contents Page 44 of 69
Table of Contents Page 45 of 69
B21D010-MS2 P
2103010-02 P
CCB
C
CCV
C
TKN-0
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-10
A
TKN-0
A
TKN-0
A
ICB
C
ICV
C
2103010-03 P
2103010-04 P
B21D011-MRL1 P
B21D011-BLK1 P
B21D011-BS1 P
2103007-01 P
B21D011-DUP1 P
B21D011-MS1 P
2103007-02 P
2103007-03 P
ICB
C
ICV
C
2103007-04 P
2103007-05 P
2103007-06 P
2103007-07 P
2103007-08 P
2103007-09 P
2103010-01 P
B21D011-DUP2 P
B21D011-MS2 P
2103007-01 P
ICB
C
ICV
C
B21D011-DUP1 P
B21D011-MS1 P
2103007-03 P
ICB
C
ICV
C
ICB
C
ICV
C
2103007-04 P
2103007-05 P
2103010-01 P
B21D011-DUP2 P
B21D011-MS2 P
2103010-02 P
ICB
C
ICV
C
ICB
C
ICV
C
2103010-02 P
Total Phos P Total Phos P Total Phos P Total Phos P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P
6.56653 mg/l 19.1745 mg/l
0.0266 mg/l 2.02863 mg/l 0.39238 mg/l 0.33669 mg/l 0.51949 mg/l 0.90879 mg/l 1.84788 mg/l 2.37051 mg/l 5.14492 mg/l 9.98308 mg/l 0.41766 mg/l 0.15867 mg/l 0.23698 mg/l 5.32237 mg/l 9.22313 mg/l 0.24506 mg/l 0.56014 mg/l 0.20815 mg/l 2.02612 mg/l 11.50035 mg/l 11.66875 mg/l 12.78503 mg/l 9.57534 mg/l 32.22951 mg/l 0.24576 mg/l 5.33267 mg/l 32.20405 mg/l 32.20051 mg/l 9.62339 mg/l 4.95252 mg/l 7.16942 mg/l 0.24315 mg/l 15.38466 mg/l 14.99121 mg/l 32.21655 mg/l 10.83648 mg/l 0.25401 mg/l 5.35534 mg/l 11.0004 mg/l 12.46871 mg/l 29.33582 mg/l 0.26628 mg/l 5.40695 mg/l 0.27265 mg/l 5.37355 mg/l 29.42627 mg/l 29.38877 mg/l 16.73119 mg/l 16.19201 mg/l 18.34817 mg/l 32.15372 mg/l 0.28802 mg/l 5.47129 mg/l
mg/l mg/l 67.19382 mg/l
4/8/2021 12:58 4/8/2021 13:00 4/8/2021 13:01 4/8/2021 13:01 4/8/2021 13:50 4/8/2021 13:52 4/8/2021 13:53 4/8/2021 13:55 4/8/2021 13:57 4/8/2021 13:59 4/8/2021 14:00 4/8/2021 14:02 4/8/2021 14:20 4/8/2021 14:42 4/8/2021 15:11 4/8/2021 15:12 4/8/2021 15:13 4/8/2021 15:15 4/8/2021 15:15 4/8/2021 15:16 4/8/2021 15:18 4/8/2021 15:19 4/8/2021 15:19 4/8/2021 15:21 4/8/2021 15:22 4/8/2021 15:23 4/8/2021 15:24 4/8/2021 15:25 4/8/2021 15:26 4/8/2021 15:27 4/8/2021 15:28 4/8/2021 15:29 4/8/2021 15:30 4/8/2021 15:31 4/8/2021 15:32 4/8/2021 15:33 4/8/2021 15:34 4/8/2021 15:36 4/8/2021 15:37 4/8/2021 15:37 4/8/2021 15:40 4/8/2021 15:41 4/8/2021 15:43 4/8/2021 16:10 4/8/2021 16:10 4/8/2021 16:11 4/8/2021 16:13 4/8/2021 16:14 4/8/2021 16:16 4/8/2021 16:18 4/8/2021 16:20 4/8/2021 16:21 4/8/2021 16:23 4/8/2021 16:24 4/8/2021 16:24 4/8/2021 16:27 4/8/2021 16:27 4/8/2021 16:36
MA
MA
MA
MA
MR
MA
MA
MA
MA
MA
MA
MA
MR
MA
MA
MA
MA
MA
MA
MA
MA
AR
19,30, R
AR
19,30, R
AR
3,19,30, R
MA
AR
3,19,30, R
MA
MA
AR
3,19,30, R
AR
3,19,30, R
MA
MA
MA
MA
AR
3,19,30, R
AR
3,19,30, R
AR
3,19,30, R
MA
R
MA
MA
MA
R
MA
R
MA
R
MA
MA
MA
MA
MA
R
MA
R
MA
R
MA
R
MA
R
AR
3,19,30, R
MA
MA
AR
1,
AR
1,
MA
R
9
0 0.10207 0.00028 0.10235 0.00028 Sample type 1
9
0 0.30062 0.00348 0.3041 0.00348 Sample type 1
0
0.00285 -0.00073 0.00211 -0.00073
0
0.31813 0.00068 0.31881 0.00068
0
0.10081 -0.0002 0.10062 -0.0002
39
0.08601 -0.00041 0.08561 -0.00041
19
0.10511 -0.00025 0.10486 -0.00025
9
0.14838 -0.00034 0.14804 -0.00034
4
0.26732 0.00004 0.26736 0.00004
3
0.34242 -0.00023 0.34219 -0.00023
1
0.8479 -0.00018 0.84772 -0.00018
0
2.15926 0.00941 2.16867 0.00941
0
0.10425 -0.00028 0.10396 -0.00028
0
0.06817 -0.00004 0.06812 -0.00004
0
0.07593 0.00025 0.07617 0.00025
0
0.88635 0.00078 0.88712 0.00078
0
0 1.91711 0.00291 1.92001 0.00291 Sample type 1
0
0 0.07673 -0.00011 0.07662 -0.00011 Sample type 1
0
0 0.10946 -0.00002 0.10944 -0.00002 Sample type 1
0
0 0.07305 -0.00002 0.07304 -0.00002 Sample type 1
0
0 0.29222 0.00004 0.29226 0.00004 Sample type 1
0
0 2.65503 0.0013 2.65633 0.0013 Sample type 1
0
0 2.71005 0.00144 2.71149 0.00144 Sample type 1
0
0 3.07479 0.00111 3.0759 0.00111 Sample type 1
0
0 2.02766 0.00026 2.02792 0.00026 Sample type 1
0
0 9.42811 0.00062 9.42873 0.00062 Sample type 1
0
0.07681 -0.00018 0.07662 -0.00018
0
0.8886 -0.00023 0.88837 -0.00023
0
0 9.41979 0.00032 9.42011 0.00032 Sample type 1
0
0 9.41863 0.00013 9.41876 0.00013 Sample type 1
0
0 2.04296 0.00106 2.04402 0.00106 Sample type 1
0
0 0.80705 0.00013 0.80718 0.00013 Sample type 1
0
0 1.33015 0.00032 1.33047 0.00032 Sample type 1
0
0 0.07654 -0.00014 0.0764 -0.00014 Sample type 1
0
0 3.9242 0.00191 3.92611 0.00191 Sample type 1
0
0 3.79564 0.00233 3.79797 0.00233 Sample type 1
0
0 9.42388 0.00209 9.42596 0.00209 Sample type 1
9
0 0.16897 -0.00014 0.16883 -0.00014 Sample type 1
0
0.07763
0 0.07763
0
0
0.89357 -0.00019 0.89338 -0.00019
9
0 0.17093 0.00008 0.17102 0.00008 Sample type 1
9
0 0.18883 -0.00013 0.1887 -0.00013 Sample type 1
9
0 0.43048 0.00006 0.43054 0.00006 Sample type 1
0
0.07887 -0.00004 0.07883 -0.00004
0
0.90493 -0.0001 0.90483 -0.0001
0
0.07951 0.00003 0.07953 0.00003
0
0.89757 -0.00002 0.89755 -0.00002
9
0 0.43196 0.00014 0.43209 0.00014 Sample type 1
9
0 0.43134 0.01389 0.44523 0.01389 Sample type 1
9
0 0.24362 -0.0001 0.24352 -0.0001 Sample type 1
9
0 0.23646 -0.00024 0.23621 -0.00024 Sample type 1
9
0 0.26552 -0.00018 0.26535 -0.00018 Sample type 1
0
0 9.40335 0.02265 9.426 0.02265 Sample type 1
0
0.08106 -0.00009 0.08097 -0.00009
0
0.91918 -0.00023 0.91895 -0.00023
0
0
9
0 1.21468 -0.00029 1.21439 -0.00029 Sample type 1
Table of Contents Page 46 of 69
ICB
C
TKN_351.2 P
0.15742 mg/l
4/8/2021 16:51
MA
ICV
C
TKN_351.2 P
5.3114 mg/l
4/8/2021 16:52
MA
B21D011-BLK1 P
TKN_351.2 P
0.20618 mg/l
4/8/2021 16:53
MA
ICB
C
TKN_351.2 P
0.25533 mg/l
4/8/2021 16:54
MA
ICV
C
TKN_351.2 P
5.36155 mg/l
4/8/2021 16:55
MA
0
0.06804 0.02974 0.09778 0.02974
0
0.88395 0.00306 0.88701 0.00306
0
0 0.07286 0.00259 0.07545 0.00259 Sample type 1
0
0.07776 -0.00032 0.07744 -0.00032
0
0.89493 -0.00022 0.89472 -0.00022
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0711
TP - WCS (0.00 mg P/L)
Other Solution Reagent water 200 1 Inorganic Ventures P2-P688018
Expires: Prepared: Prepared By: Department: Last Edit:
May-07-21 Apr-07-21 Nidia Fuentes A&I Apr-07-21 15:48 by NF
Table of Contents
Analyte
Total Dissolved Phosphorus Total Phosphorus
CAS Number
NA NA
Concentration (ppm)
0 0
Parent Standards used in this standard:
Standard 21B2306
20B0607
Description
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
21C0910 TP-Stock Cal Standard (SCS)
Prepared Feb-15-21
Feb-06-20 Apr-07-21
Prepared By Nidia Fuentes
** Vendor ** Nidia Fuentes
Expires Aug-31-21
Jul-11-21 Apr-07-22
Last Edit Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB Apr-07-21 10:22 by NF
(mls) 0.2
0.2 0
By AK at 9:59 am, Apr 14, 2021
Page 4P7aogfe 619of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0712
TP - WCS (3.00 mg P/L)
Other Solution Reagent water 100 1 Inorganic Ventures P2-P688018
Expires: Prepared: Prepared By: Department: Last Edit:
May-07-21 Apr-07-21 Nidia Fuentes A&I Apr-07-21 15:39 by NF
Table of Contents
Analyte
Total Dissolved Phosphorus Total Phosphorus
CAS Number
NA NA
Concentration (ppm)
3 3
Parent Standards used in this standard:
Standard 21B2307
21B2309
Description
Pipette (Electronic) -- 200 -5000 uL Pipette (Electronic) -- 5 -100 uL
20B0607 Sulfuric Acid 9673-33
21C0910 TP-Stock Cal Standard (SCS)
Prepared Feb-15-21
Feb-15-21 Feb-06-20 Apr-07-21
Prepared By Nidia Fuentes
Nidia Fuentes ** Vendor ** Nidia Fuentes
Expires Aug-31-21
Aug-31-21 Jul-11-21 Apr-07-22
Last Edit Apr-05-21 09:23 by AK
Apr-05-21 09:33 by AK Mar-02-20 14:42 by CB Apr-07-21 10:22 by NF
(mls) 3
0.1 0.1 3
By AK at 9:59 am, Apr 14, 2021
Page 4P8aogfe 619of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0713
TP - WcS (2.00 mg P/L)
Other Solution Reagent water 100 1 Absolute Standards Inc. 012721
Expires: Prepared: Prepared By: Department: Last Edit:
May-07-21 Apr-07-21 Nidia Fuentes A&I Apr-07-21 15:41 by NF
Table of Contents
Analyte
Total Dissolved Phosphorus Total Kjeldahl Nitrogen Total Phosphorus
CAS Number
NA NA NA
Concentration (ppm)
2 2 2
Parent Standards used in this standard:
Standard 21B2309
Description Pipette (Electronic) -- 5 -100 uL
21B2306 20B0607
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
21C1801 TP&TKN Stock Control Std.
Prepared Feb-15-21 Feb-15-21
Feb-06-20 Mar-16-21
Prepared By Nidia Fuentes Nidia Fuentes
** Vendor ** Nidia Fuentes
Expires Aug-31-21 Aug-31-21
Jul-11-21 Jan-07-23
Last Edit Apr-05-21 09:33 by AK Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB Mar-18-21 09:14 by NF
(mls) 0.1 0.2
0.1 0.2
By AK at 10:02 am, Apr 14, 2021
Page 4P9aogfe 619of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0714
TP - MRL (0.15 mg P/L)
Reference Material Reagent water 100 1 Inorganic Ventures P2-P688018
Expires: Prepared: Prepared By: Department: Last Edit:
May-07-21 Apr-07-21 Nidia Fuentes A&I Apr-07-21 15:43 by NF
Table of Contents
Analyte
Total Dissolved Phosphorus Total Phosphorus
CAS Number
NA NA
Concentration (ppm)
0.15 0.15
SRM Control Limits
0-200 0-200
Parent Standards used in this standard:
Standard 21B2309
Description Pipette (Electronic) -- 5 -100 uL
21B2306 20B0607
Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-33
21C0910 TP-Stock Cal Standard (SCS)
Prepared Feb-15-21 Feb-15-21
Feb-06-20 Apr-07-21
Prepared By Nidia Fuentes Nidia Fuentes
** Vendor ** Nidia Fuentes
Expires Aug-31-21 Aug-31-21
Jul-11-21 Apr-07-22
Last Edit Apr-05-21 09:33 by AK Apr-05-21 09:19 by AK
Mar-02-20 14:42 by CB Apr-07-21 10:22 by NF
(mls) 0.15 0.1
0.1 0.15
By AK at 9:59 am, Apr 14, 2021
Page 5P0aogfe 619of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Table of Contents
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0715
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TP-Stock Cal Standard (SCS)
Analyte Spike NA 125 1 Inorganic Ventures P2-P688018
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-07-22 Apr-07-21 Nidia Fuentes A&I Apr-13-21 14:43 by NF
Enter dates opened of each bottle under User-Defined Fields. NOTE: Bottle expires one year after the package is opened (See date when openned) or the Expiration date 04/07/2022, whichever one is sooner.
Analyte
CAS Number
Concentration (ppm)
Total Dissolved Phosphorus Total Phosphorus
NA
100
NA
100
By AK at 9:58 am, Apr 14, 2021
PPagagee5P1aogfe 6119of 1
Table of Contents
1.0 ACCREDITATION / REGISTRATION
INORGANIC VENTURES is accredited to ISO 17034, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for the Competence of Testing and Calibration Laboratories". Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate Number QSR-1034).
Testing Laboratory Certificate 883.01
Reference Material Producer Certificate 883.02
2.0 PRODUCT DESCRIPTION
Product Code: Catalog Number: Lot Number: Matrix: Value / Analyte(s):
Starting Material:
Single Analyte Mass Spec Solution MSP-100PPM P2-P688018 H2O
100 g/mL ea: Phosphorus H3PO4
By AK at 9:58 am, Apr 14, 2021
Starting Material Lot#: 108587
Starting Material Purity: 100.0000%
3.0 CERTIFIED VALUES AND UNCERTAINTIES
Certified Value: Density:
100.06 0.70 g/mL 0.998 g/mL (measured at 20 4 C)
Assay Information:
ANALYTE P
METHOD ICP Assay
NIST SRM# 3139a
SRM LOT# 060717
P
Acidimetric
84L
84L
The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.
4.0 TRACEABILITY TO NIST
- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is specified.
Page 1 of 4
Page 52 of 69
4.1 Thermometer Calibration
Table of Contents
- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration laboratory.
4.2 Balance Calibration
- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights used for testing are annually compared to master weights and are traceable to NIST.
4.3 Glassware Calibration
- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality control of CRM/RMs.
5.0 TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (g/mL)
CRM/RMs are tested for trace metallic impurities by Axial ICP-OES and ICP-MS. The result from the most sensitive method for each element, is reported below. Solutions tested by ICP-MS were analyzed in an ULPA-Filtered Clean Room. An ULPA-Filter is 99.9985% efficient for the removal of particles down to 0.3 m.
M Ag < M Al < M As < M Au < MB < O Ba < M Be < M Bi < O Ca M Cd < M Ce < M Co < M Cr M Cs < O Cu < M Dy < M Er <
0.000040 M 0.003405 O 0.000324 M 0.000040 M 0.001216 M 0.000639 M 0.000121 M 0.000040 M 0.000019 M 0.000040 M 0.000040 O 0.000081 M 0.000004 O 0.000040 M 0.003837 O 0.000040 M 0.000040 M
Eu < Fe Ga < Gd < Ge < Hf < Hg < Ho < In < Ir < K< La < Li < Lu < Mg Mn < Mo <
0.000040 O 0.000008 M 0.000040 M 0.000040 M 0.000081 M 0.000040 s 0.000081 M 0.000040 M 0.000040 M 0.000040 M 0.010660 M 0.000040 M 0.000106 M 0.000040 M 0.000001 O 0.000081 M 0.001216 O
Na Nb < Nd < Ni < Os < P< Pb < Pd < Pr < Pt < Rb < Re < Rh < Ru < S< Sb Sc <
0.000047 M 0.000243 O 0.000040 M 0.003000 M 0.000040 M
M 0.000040 M 0.000040 M 0.000040 M 0.000040 O 0.000040 M 0.000040 M 0.000040 M 0.000405 M 0.031980 M 0.000002 M 0.001066 M
Se < Si < Sm < Sn < Sr < Ta < Tb < Te < Th < Ti < Tl < Tm < U< V< W< Y< Yb <
0.003405 M 0.014924 M 0.000040 0.000040 0.000040 0.000040 0.000040 0.000324 0.000040 0.001066 0.000040 0.000040 0.000040 0.000040 0.000405 0.000040 0.000040
Zn < Zr <
0.001054 0.001054
M - Checked by ICP-MS O - Checked by ICP-OES i - Spectral Interference n - Not Checked For s - Solution Standard Element
6.0 INTENDED USE
- For the calibration of analytical instruments and validation of analytical methods as appropriate.
7.0 INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL
7.1 Storage and Handling Recommendations - Store between approximately 4 - 30 C while in sealed TCT bag.
- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is the responsibility of the user to account for this effect. When the bottle is weighed both before and after being placed in storage, the mass difference observed will be a measure of transpiration mass loss.
- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4 - 24 C to minimize the effects of transpiration. Use at 20 4 C to minimize volumetric dilution error when using the reported density. Do not pipette from the container. Do not return removed aliquots to container.
- For more information, visit www.inorganicventures.com/TCT
Page 2 of 4
Page 53 of 69
Table of Contents
Atomic Weight; Valence; Coordination Number; Chemical Form in Solution - 30.97 +5 6 O=P(OH)2(O)1-
Chemical Compatibility -Soluble in HCl, HNO3, H2SO4 and HF aqueous matrices water and NH4OH. Stable
with all metals and inorganic anions at low to moderate ppm levels under acidic conditions; precipitates with
several metals occur in neutral media at higher concentrations.
Stability - 2-100 ppb levels- stability unknown - in 1% HNO3 / LDPE container. 1-10,000 ppm solutions
chemically stable for years in 0-1% HNO3 / LDPE container.
P Containing Samples (Preparation and Solution) -Metal (Never found free in nature ); Oxides (Water
soluble); Ores (Naturally occurring only as the phosphate except for a few rare minerals found in meteorites -
Na2CO3fusion in Pt0); Organic Matrices (Dry ash mixed with Na2CO3 in Pt0 at 450EC then increase heat to
1000EC to fuse; or perform an H2SO4 / H2O2 acid digestion ).
Atomic Spectroscopic Information (ICP-OES D.L.s are given as radial/axial view):
Technique/Line
Estimated D.L.
Order Interferences (underlined indicates severe)
ICP-MS 31 amu
6000+ ppt
n/a
15N21H, 15N16O,
14N17O, 13C18O,
12C18O1H, 62Ni2+
ICP-OES 177.495 nm 0.01 / 0.005 g/mL
1
Cu, Hf
ICP-OES 178.287 nm 0.03 / 0.002 g/mL
1
I
ICP-OES 213.618 nm 0.08 / 0.03 g/mL
1
Cu, Mo
8.0 9.0 10.0
11.0
HAZARDOUS INFORMATION
- Please refer to the Safety Data Sheet for information regarding this CRM/RM.
HOMOGENEITY
- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous. Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure homogeneity.
QUALITY STANDARD DOCUMENTATION
10.1 ISO 9001 Quality Management System Registration - QSR Certificate Number QSR-1034
10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories" - Chemical Testing - Accredited / A2LA Certificate Number 883.01
10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers" - Reference Material Producer - Accredited / A2LA Certificate Number 883.02
Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: 800.669.6799; 540.585.3030, Fax: 540.585.3012; inorganicventures.com; info@inorganicventures.com
CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY
11.1 Certification Issue Date February 07, 2020
- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1 are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.
11.2 Lot Expiration Date
- February 07, 2024
- The date after which this CRM/RM should not be used. - The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by transpiration (loss of water from the solution) and infrequently by chemical stability.
Page 3 of 4
Page 54 of 69
12.0
11.3 Period of Validity
Table of Contents
- Sealed TCT Bag Open Date: __________________________
- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.
NAMES AND SIGNATURES OF CERTIFYING OFFICERS
Certificate Approved By:
Michael Booth Manager, Quality Control
Certifying Officer:
Paul Gaines CEO, Senior Technical Director
Page 4 of 4
Page 55 of 69
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0803
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TP - WCS (0.15 mg P/L)
Other Solution Blank:21D0711 2 1 Inorganic Ventures P2-P688018
Prepared by instrument (DA-3)
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-12-21 08:37 by NF
By AK at 9:56 am, Apr 14, 2021
Analyte
CAS Number
Concentration (ppm)
Total Dissolved Phosphorus Total Phosphorus
NA
0.15
NA
0.15
Table of Contents
Parent Standards used in this standard:
Standard 21D0712
Description TP - WCS (3.00 mg P/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:39 by NF
(mls) 0.1
Page 5P6aogfe 619of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0804
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TP - WCS (0.3 mg P/L)
Other Solution Blank:21D0711 2 1 Inorganic Ventures P2-P688018
Prepared by instrument (DA-3)
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-12-21 08:37 by NF
By AK at 9:56 am, Apr 14, 2021
Analyte
CAS Number
Concentration (ppm)
Total Dissolved Phosphorus Total Phosphorus
NA
0.3
NA
0.3
Table of Contents
Parent Standards used in this standard:
Standard 21D0712
Description TP - WCS (3.00 mg P/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:39 by NF
(mls) 0.2
Page 5P7aogfe 619of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0805
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TP - WCS (0.75 mg P/L)
Other Solution Blank: 21D0711 2 1 Inorganic Ventures P2-P688018
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-12-21 08:37 by NF
Prepared by instrument (DA-3)
Analyte
By AK at 9:57 am, Apr 14, 2021
CAS Number
Concentration (ppm)
Total Dissolved Phosphorus Total Phosphorus
NA
0.75
NA
0.75
Table of Contents
Parent Standards used in this standard:
Standard 21D0712
Description TP - WCS (3.00 mg P/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:39 by NF
(mls) 0.5
Page 5P8aogfe 619of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0806
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TP - WCS (1.0 mg P/L)
Other Solution Blank:21D0711 2 1 Inorganic Ventures P2-P688018
Prepared by instrument (DA-3)
Analyte
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-12-21 08:38 by NF
By AK at 9:57 am, Apr 14, 2021
CAS Number
Concentration (ppm)
Total Dissolved Phosphorus Total Phosphorus
NA
1
NA
1
Table of Contents
Parent Standards used in this standard:
Standard 21D0712
Description TP - WCS (3.00 mg P/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:39 by NF
(mls) 0.6666666
Page 5P9aogfe 619of 1
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch
21D0807
Description:
Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number:
TP - WCS (1.5 mg P/L)
Other Solution Blank:21D0711 2 1 Inorganic Ventures P2-P688018
Expires: Prepared: Prepared By: Department: Last Edit:
Apr-09-21 Apr-08-21 Nidia Fuentes A&I Apr-12-21 08:38 by NF
Prepared by instrument (DA-3)
Analyte
By AK at 10:00 am, Apr 14, 2021
CAS Number
Concentration (ppm)
Total Dissolved Phosphorus Total Phosphorus
NA
1.5
NA
1.5
Table of Contents
Parent Standards used in this standard:
Standard 21D0712
Description TP - WCS (3.00 mg P/L)
Prepared Apr-07-21
Prepared By Nidia Fuentes
Expires May-07-21
Last Edit Apr-07-21 15:39 by NF
(mls) 1
Page 6P0aogfe 619of 1
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21B2417
Page 61 of 69
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
2/24/2021
Parameter / SOP #: TP / AIG034B VER#7 Reagent: TP-NaCl Solution LIMS ID: 21B2417
Chemical Name (Formula)
Sodium Chloride (NaCl)
Prepared by: Nidia Fuentes Preparation Date: Feb-24-21 Expiration Date: Feb-24-22
LIMS ID
19C1203
Mass or Volume (specify units)
4.0470g
Total Volume : 100 mL Comments : See user defined fields for details Balance#17
Analyst Signature:
By AK at 6:43 am, Mar 04, 2021
Page 6P2aogfe 619of 1
Table of Contents Page 63 of 69
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21B2421
Page 64 of 69
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
2/24/2021
Parameter / SOP #: TP / AIG034B VER# 7 Reagent: TP-MolybdateAntimonySolution LIMS ID: 21B2421
Chemical Name (Formula)
Ammonium Molybdate tetrahydrate *
Prepared by: Nidia Fuentes Preparation Date: Feb-24-21 Expiration Date: Feb-24-22
LIMS ID
19K1225
Mass or Volume (specify units)
0.8044g
Potassium antimonyl tartrate trihydrate **
19K0602
0.0240g
* [(NH4)6Mo7O24*4H2O]
** [K2(C4H2O6Sb)2*3H2O]
Total Volume : Comments : Balance ID: 17
100 mL
Analyst Signature:
By AK at 6:48 am, Mar 04, 2021
Page 6P5aogfe 619of 1
Table of Contents Page 66 of 69
Table of Contents
ANALYSIS REAGENTS/STANDARDS
21D0801
Page 67 of 69
Environmental Protection Agency Region 5
Chicago Regional Laboratory
536 South Clark Street, Chicago, IL 60605
Phone:(312)353-8370
Fax:(312)886-2591
Reagent Preparation Bench Sheet
Table of Contents
Print Date:
4/8/2021
Parameter / SOP #: Toal Phosphorus/ AIG034B ver#7 Reagent: TP- Ascorbic Acid LIMS ID: 21D0801
Chemical Name (Formula)
Ascorbic acid (C6H8O6)
Prepared by: Nidia Fuentes Preparation Date: Apr-08-21 Expiration Date: Apr-22-21
LIMS ID
16K1407
Mass or Volume (specify units)
6.0316
Acetone ((CH3)2CO)
19J0101
2 mL
Total Volume : 100 mL Comments : Balance #17
Analyst Signature:
By AK at 9:57 am, Apr 14, 2021
Page 6P8aogfe 619of 1
Table of Contents Page 69 of 69
ATTACHMENT D
